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Managing and Treating Landfill Leachate

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Lower Berkeley WWTF - Headworks Analysis<br />

EPA WQC Allowable POTW Allowable Inhibitory POTW Allowable MinimumAllowable Typical Industrial Allocations<br />

Pollutant In Stream Discharge Removal @ POTW Threshold Removal at POTW A,or B @ POTW Domestic Loading Capacity Available to Non-domestic US Water Navy Navy BCW&SA ALCOA Available Remaining Pollutant<br />

(mg/l) (mg/l) % (mg/l) (mg/l) Primary (mg/L) (mg/l) (#/day) (mg/l) (#/day) (mg/l) (#/day) % Recovery 1 Line 2 Line<br />

A % B Lesser (#/day) (#/day) (#/day) (#/day) (#/day) (#/day) %<br />

Antimony Avg 0.64000 75.56 70 251.88 x x x 251.88 47264.4 0.0050 0.9039 6139.86 47263.5 100.00 47263.5441 100.00 Antimony Avg<br />

Arsenic Avg 0.03600 4.25 45 7.73 0.1 x 0.1 0.10 18.8 0.0070 1.2655 2.2733 17.5 93.26 1.5200 15.9795 85.16 Arsenic Avg<br />

Arsenic Max 0.06900 8.15 45 14.81 0.1 x 0.1 0.10 18.8 0.0070 1.2655 2.2733 17.5 93.26 2.2800 15.2195 81.11 Arsenic Max<br />

Cadmium Avg 0.00930 1.10 67 3.33 1 15 1.176471 1.18 220.8 0.0080 1.4463 28.49 219.3 99.34 4.6700 17.3800 6.6700 190.5984 86.34 Cadmium Avg<br />

Cadmium Max 0.04300 5.08 67 15.38 1 15 1.176471 1.18 220.8 0.0080 1.4463 28.49 219.3 99.34 7.0000 26.0700 10.0000 176.2484 79.84 Cadmium Max<br />

Chromium Avg 0.05000 5.90 82 32.80 1 27 1.369863 1.37 257.1 0.0340 6.1467 32.59 250.9 97.61 0.028 4.340 246.5401 95.91 Chromium Avg<br />

Chromium Max 1.10000 129.87 82 721.52 1 27 1.369863 1.37 257.1 0.0340 6.1467 32.59 250.9 97.61 0.065 6.510 244.3331 95.05 Chromium Max<br />

Copper Avg 0.00370 0.44 86 3.12 1 22 1.282051 1.28 240.6 0.1400 25.3101 27.96 215.3 89.48 0.0210 2.8000 10.4200 4.0000 198.0259 82.31 Copper Avg<br />

Copper Max 0.00580 0.68 86 4.89 1 22 1.282051 1.28 240.6 0.1400 25.3101 27.96 215.3 89.48 0.0430 4.2000 15.6400 6.0000 189.3839 78.72 Copper Max<br />

Cyanide Avg 0.00100 0.12 69 0.38 0.1 27 0.136986 0.14 25.7 0.0820 14.8245 1.4135 10.9 42.33 10.8810 42.33 Cyanide Avg<br />

Cyanide Max 0.00100 0.12 69 0.38 0.1 27 0.136986 0.14 25.7 0.0820 14.8245 1.4135 10.9 42.33 10.8810 42.33 Cyanide Max<br />

Lead Avg 0.00850 1.00 61 2.57 1 57 2.325581 2.33 436.4 0.0580 10.4856 55.3286 425.9 97.60 0.0140 0.1900 0.6900 0.2600 424.7558 97.33 Lead Avg<br />

Lead Max 0.22000 25.97 61 66.6060 1 57 2.325581 233 2.33 436.44 0.05800580 10.4856 55.3286 425.9 97.60 0.03000300 0.2800 1.0400 0.4000 424.1598 97.20 Lead Max<br />

Mercury Avg 0.000051 0.0060 60 0.02 0.1 10 0.111111 0.02 2.8 0.0020 0.3616 0.3200 2.5 87.20 2.4632 87.20 Mercury Avg<br />

Mercury Max 0.000051 0.0088 60 0.02 0.1 10 0.111111 0.02 4.1 0.0020 0.3616 0.4888 3.8 91.23 3.7626 91.23 Mercury Max<br />

Nickel Avg 0.00830 0.98 42 1.69 1 14 1.162791 1.16 218.2 0.0470 8.4970 27.24 209.7 96.11 4.3400 3.3400 202.0207 92.59 Nickel Avg<br />

Nickel Max 0.07500 8.86 42 15.27 1 14 1.162791 1.16 218.2 0.0470 8.4970 27.24 209.7 96.11 6.5100 5.0000 198.1907 90.83 Nickel Max<br />

Silver Avg 0.00120 0.14 75 0.57 0.25 20 0.3125 0.31 58.6 0.0190 3.4349 7.17 55.2 94.14 1.1700 4.3400 49.6957 84.75 Silver Avg<br />

Silver Max 0.00120 0.14 75 0.57 0.25 20 0.3125 0.31 58.6 0.0190 3.4349 7.17 55.2 94.14 1.7500 6.5100 46.9457 80.06 Silver Max<br />

Thallium Avg 0.00047 0.0555 70 0.18 x x x 0.18 34.7 0.0005 0.0904 4.50 34.6 99.74 0.8700 33.7494 97.23 Thallium Avg<br />

Thallium Max 0.00047 0.0810 70 0.27 x x x 0.27 50.7 0.0005 0.0904 6.57 50.6 99.82 1.3000 49.2860 97.26 Thallium Max<br />

Zinc Avg 0.08600 10.15 79 48.35 0.3 27 0.410959 0.41 77.1 0.2310 41.76 4.59 35.4 45.85 0.0009 0.9900 3.6900 1.4200 29.2540 37.93 Zinc Avg<br />

Zinc Max 0.09500 11.22 79 53.41 0.3 27 0.410959 0.41 77.1 0.2310 41.76 4.59 35.4 45.85 0.0009 1.4900 5.5400 2.1400 26.1840 33.95 Zinc Max<br />

Phenol x x x x 50 8 54.34783 54.35 10198.4 0.000025 0.00452 1324.84 10198.4 100.00 1303 8895.3650 87.22 Phenol<br />

Molybdenum x x x x x x x 0.00 548.4 0.02 3.6157 70.7712 544.8 99.34 544.7843 99.34 Molybdenum<br />

Selenium Avg 0.07100 8.38 50 16.77 x x x 16.77 1096.9 0.005 0.9039 142.3775 1096.0 99.92 0.560 1095.4361 99.87 Selenium Avg<br />

Selenium Max 0.29000 34.24 50 68.48 x x x 68.48 1096.9 0.005 0.9039 142.3775 1096.0 99.92 0.840 1095.1561 99.84 Selenium Max<br />

Ammonia Avg 20.00 72.5 72.73 480 x 480 72.73 13647.3 30 5423.6 1068.3 8223.7 60.26 8223.6873 60.26 Ammonia Avg<br />

Ammonia Max 30.00 72.5 109.09 480 x 480 109.09 20470.9 30 5423.6 1954.75 15047.3 73.51 15047.3237 73.51 Ammonia Max<br />

Chloride Avg 230.0000 27155.33 0 27155.33 180 x 180 180.0000 33777.0 005 0.05 90 9.0 4386.6969 33768.0 99.9797 33767.9607 99.9797 Chloride Avg<br />

Chloride Max 860.00 101537.33 0 101537.33 180 x 180 180.00 33777.0 0.05 9.0 4386.69 33768.0 99.97 33767.9607 99.97 Chloride Max<br />

CBOD Avg 25 95 500 x x x 500.00 93825.0 300 54235.9 5143 39589.1 42.19 39589.1460 42.19 CBOD Avg<br />

CBOD Max 38 95 750 x x x 750.00 140737.5 300 54235.9 11237 86501.6 61.46 86501.6460 61.46 CBOD Max<br />

TSS Avg 30 95 600 x x x 600.00 112590.0 300 54235.9 7581 58354.1 51.83 58354.1460 51.83 TSS Avg<br />

TSS Max 45 95 900 x x x 900.00 168885.0 300 54235.9 14894 114649.1 67.89 114649.1460 67.89 TSS Max<br />

O & G Avg 100 0 100 x x x 100.00 18765.0 100 18078.62 89.17 686.4 3.66 8.757 42.95 166.800 467.8750 2.49 O & G Avg<br />

O & G Max 150 0 150 x x x 150.00 28147.5 100 18078.62 1308.02 10068.9 35.77 13.135 64.42 250.200 9741.1270 34.61 O & G Max<br />

Input Values:<br />

Method of Calculation:<br />

Allowable Headworks Loading - Sludge<br />

Domestic Design Flow 15.000 mgd In stream concentrations are based upon EPA Water Quality Criteria Formuli.<br />

Allowable<br />

POTW<br />

Industrial Design Flow 3.000 mgd Discharge is based upon a dilution ratio of Total Flow plus 7Q10 to Total Flow.<br />

Concentration Headworks<br />

Pollutant Removal<br />

I/I allowance 4.500 mgd The 7Q10 is that of the Cooper River at the potential POTW discharge location.<br />

(mg/kg) Loading<br />

%<br />

Total Design Flow 22.500 mgd Allowable concentration at POTW is based upon the removal efficiency for that parameter,<br />

(#/day)<br />

7Q10 2634 mgd BOD <strong>and</strong> TSS loading is a design parameter of the plant. Arsenic 0.45 75.00 914.064<br />

4076 cfs Inhibitory threshold of combined flow @ POTW, rather than @ industrial discharge, is considered. Cadmium 0.67 85.00 695.78006<br />

Assumed Hardness 25 mg/l Typical domestic loading is subtracted from plant capacity to determine capacity that is available Copper 0.86 4300.00 27421.92<br />

Permitted Domestic Flow 21.677 mgd for non-domestic (industrial) allocation. Lead 061 0.61 840.0000 7552.2664926649<br />

Permitted Industrial Flow 0.923 mgd Molybdenum allowable discharge was calculated from typical sludge production of biological processes Mercury 0.60 57.00 521.01648<br />

Remaining Flow 0 mgd used at the plant <strong>and</strong> allowable concentration in sludge disposable from Table 1 503.13 of 40 CFR Part 503. Molybdenum 0.75 75.00 548.4384<br />

All inhibition values were taken from EPA's Local Limits Development Guidance (x - indicates Nickel 0.42 420.00 5484.384<br />

Sludge Values: research yielded no inhibition values) Selenium 0.50 100.00 1096.8768<br />

Sludge Flow to Disposal 4.8 mgd Typical domestic loading values were taken from EPA's Local Limits Development Guidance, SCDHEC's Zinc 0.79 7500.00 52066.9367<br />

Percent Solids 13.7 % Practical Quantitation Limits (PQLs), Berekeley Counties Sewer Use Ordinance, or Wastewater Engineering<br />

by Metcalf & Eddy, Inc. (only used for O & G).<br />

AHLs for Cadmium Max <strong>and</strong> Molybdenum are based on Sludge Calculations because of a lower yielded<br />

AHL<br />

% Removal assumed to be zero if research yielded no values.

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