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<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
PREMIUM DISH-WASH DETERGENT 5L<br />
Page 1/3<br />
Issued: 30.10.2013<br />
Revision No: 4<br />
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING<br />
Product Name:<br />
PREMIUM DISHWASH DETERGENT 5L<br />
Product Code: 74.9991<br />
Company Name:<br />
<strong>GPP</strong> <strong>Hygiene</strong><br />
Bowcare House, Stephenson Drive<br />
Waterwells Business Park<br />
2<br />
Quedgeley<br />
Gloucestershire<br />
2<br />
GL2 2AG<br />
TEL: 01452 883 447<br />
FAX 01452 690 078<br />
Emergency Tel: 0161 476 3607<br />
2. HAZARDS IDENTIFICATION<br />
Main hazards:<br />
Harmful if swallowed. Causes severe burns.<br />
3. COMPOSITION / INFORMATION ON INGREDIENTS<br />
Hazardous ingredients: SODIUM HYDROXIDE 5 - 10 %<br />
EINECS: 215-185-5 CAS: 1310-73-2<br />
[C] R35<br />
4. FIRST AID MEASURES (SYMPTOMS)<br />
NITRILOTRIACETIC ACID TRISODIUM SALT 30 - 50 %<br />
CAS: 5064-31-3<br />
[Xn] R22; [Xi] R36; [Xi] R38<br />
Skin contact:<br />
Eye contact:<br />
Ingestion:<br />
Inhalation:<br />
There may be irritation and redness at the site of contact.<br />
There may be irritation and redness. The eyes may water profusely.<br />
There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur.<br />
There may be vomiting.<br />
There may be irritation of the throat with feeling of tightness in the chest.<br />
4. FIRST AID MEASURES (ACTION)<br />
Skin contact:<br />
Eye contact:<br />
Remove all contaminated clothes and footwear immediately unless stuck to the skin.<br />
Drench with running water for 10 minutes or longer if substance is still on skin. Consult a doctor<br />
Bathe the eye with running water for 15 minutes. Consult a doctor.<br />
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give 0.5 litre of water to drink<br />
immediately. Consult a doctor.<br />
Inhalation:<br />
Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor.<br />
5. FIRE-FIGHTING MEASURES<br />
Extinguishing media:<br />
Exposure hazards:<br />
Protection of fire-fighters:<br />
Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers<br />
In combustion emits toxic fumes.<br />
Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes<br />
6. ACCIDENTAL RELEASE MEASURES<br />
Personal precautions:<br />
Environmental precautions:<br />
Clean-up procedures:<br />
Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. Keep<br />
bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent<br />
access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid.<br />
Do not discharge into drains or rivers. Contain the spillage using bunding.<br />
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an<br />
appropriate method.
7. HANDLING AND STORAGE<br />
Handling requirements:<br />
Storage conditions:<br />
Suitable packaging:<br />
<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
PREMIUM DISH-WASH DETERGENT 5L<br />
Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.<br />
Do not handle in a confined space. Avoid the formation or spread of mists in the air.<br />
Store in cool, well ventilated area. Keep container tightly closed.<br />
Must only be kept in original packaging.<br />
8. EXPOSURE CONTROLS / PERSONAL PROTECTION<br />
Hazardous ingredients: SODIUM HYDROXIDE WEL (15 min STEL): 2 mg/m3<br />
Engineering measures:<br />
Respiratory protection:<br />
Hand protection:<br />
Eye protection:<br />
Skin protection:<br />
Ensure there is sufficient ventilation of area.<br />
Self-contained breathing apparatus must be available in case of emergency.<br />
Impermeable gloves<br />
Safety glasses/goggles. Ensure eye bath is to hand.<br />
Impermeable protective clothing.<br />
9. PHYSICAL AND CHEMICAL PROPERTIES<br />
State:<br />
Colour:<br />
Odour:<br />
Oxidising:<br />
Solubility in water:<br />
Viscosity:<br />
Liquid<br />
Colourless<br />
Characteristic odour<br />
Non-oxidising (by EC criteria)<br />
Soluble<br />
Flash point°C : >70<br />
pH: 13<br />
10. STABILITY AND REACTIVITY<br />
Non-viscous<br />
Page 2/3<br />
Issued: 30.10.2013<br />
Revision No: 4<br />
Stability:<br />
Conditions to avoid:<br />
Materials to avoid:<br />
Haz. decomp. products:<br />
Stable under normal conditions.<br />
Heat.<br />
Strong oxidising agents. Strong acids.<br />
In combustion emits toxic fumes.<br />
11. TOXICOLOGICAL INFORMATION<br />
Hazardous ingredients: SODIUM HYDROXIDE IPR MUS LD50 40 mg/kg<br />
ORL RBT LDLO 500mg/kg<br />
Routes of exposure:<br />
12. ECOLOGICAL INFORMATION<br />
NITRILOTRIACETIC ACID TRISODIUM SALT<br />
ORL RAT LD50 1000-2000 mg/kg<br />
Refer to section 4 of SDS for routes of exposure and corresponding symptoms.<br />
Mobility:<br />
Persistence and degradability:<br />
Bioaccumulative potential:<br />
Other adverse effects:<br />
Readily absorbed into soil.<br />
Biodegradable.<br />
No bioaccumulation potential.<br />
Negligible ecotoxicity.<br />
13. DISPOSAL CONSIDERATIONS<br />
NB:<br />
The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
14. TRANSPORT INFORMATION<br />
ADR / RID<br />
<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
PREMIUM DISH-WASH DETERGENT 5L<br />
Page 3/3<br />
Issued: 30.10.2013<br />
Revision No: 4<br />
UN no: 1824 ADR Class: 8<br />
Packing group: III Classification code: C5<br />
Shipping name:<br />
SODIUM HYDROXIDE SOLUTION<br />
Labelling: 8 Hazard ID no: 80<br />
IMDG / IMO<br />
UN no: 1824 Class: 8<br />
Packing group: III EmS: 8-06<br />
Marine pollutant: No Labelling: 8<br />
IATA / ICAO<br />
UN no: 1824 Class: 8<br />
Packing Group: III<br />
Packing Instructions: 819 (P&CA); 821 (PAO) Labelling: 8<br />
15. REGULATORY INFORMATION<br />
Hazard symbols:<br />
Risk phrases:<br />
Safety phrases:<br />
Haz. ingredients (label):<br />
Note:<br />
16. OTHER INFORMATION<br />
Risk phrases used in s.3:<br />
Legal disclaimer:<br />
CORROSIVE<br />
R22: Harmful if swallowed.<br />
R35: Causes severe burns.<br />
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice<br />
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.<br />
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label<br />
where possible)<br />
SODIUM HYDROXIDE; NITRILOTRIACETIC ACID TRISODIUM SALT<br />
The regulatory information given above only indicates the principal regulations specifically<br />
applicable to the product described in the safety data sheet. The user's attention is drawn to<br />
the possible existence of additional provisions which complete these regulations. Refer to all<br />
applicable national, international and local regulations or provisions.<br />
R22: Harmful if swallowed.<br />
R35: Causes severe burns.<br />
R36: Irritating to eyes.<br />
R38: Irritating to skin.<br />
The above information is believed to be correct but does not purport to be all<br />
inclusive and shall be used only as a guide. This company shall not be held liable for<br />
any damage resulting from handling or from contact with the above product.
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