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Scientific program - ILED 2012

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Wednesday May 30 th<br />

9. 00-10. 00 Registration and Coffee<br />

Session: General<br />

Chairman : M. Salomon<br />

10. 00-10. 10: Welcome address<br />

B. Scrosati<br />

<strong>Scientific</strong> <strong>program</strong><br />

10. 10-10. 40 Nuclear Magnetic Resonance Investigations of Charge and Mass<br />

Transport in Ionic Liquids and IL/Gel Systems<br />

S. Khatun, M. Berman, S. Greenbaum<br />

Hunter College of CUNY, New York, USA<br />

10. 40-11. 00 Structure and dynamics of Li salts and other electrochemically interesting<br />

electrolytes in mixtures with ionic liquids<br />

J. Carrete, T. Méndez-Morales, L. J. Gallego, O. Cabeza , L. M. Varela<br />

Departamento de Física da Materia Condensada, Universidade de Santiago de<br />

Compostela, and Facultade de Ciencias, Universidade da Coruña, Spain<br />

11. 00-11. 20 Water-soluble, triflate-based, pyrrolidinium ionic liquids: I. Synthesis,<br />

thermalcharacterization and transport properties<br />

M. Moreno, M. Montanino, M. Carewska, S. Jeremias, S. Passerini,<br />

F. Alessandrini, G. B. Appetecchi<br />

ENEA (Italian National Agency for New Technologies, Energy and<br />

Sustainable Economic Development) UTRINN-IFC, Rome, Italy and<br />

University of Muenster, MEET Battery Research Centre, Institute of Physical<br />

Chemistry, Germany<br />

11. 20-11. 40 Influence of Li-salt doping on the properties of ionic liquid based gel-<br />

electrolytes<br />

A. Matic, J. Pitawala, L. Aguilera, J. Nordström, P. Jacobsson<br />

Department of Applied Physics, Chalmers University of Technology, Göteborg,<br />

Sweden<br />

11. 40-12. 00 Ionic Liquid electrolytes for electrochemical devices<br />

S. Fantini, Solvionic, France<br />

12. 00-12. 20 Confined ionic liquids within host networks: from fundamental studies to<br />

marketable devices.<br />

P. -E. Delannoy, N. Buchtova, A. Lack, B. Lestriez, T. Brousse, D. Guyomard,<br />

J. Le Bideau<br />

Institut des Matériaux Jean Rouxel de Nantes (IMN), France


12. 20-12-40 Water-soluble, triflate-based, pyrrolidinium ionic liquids: II. Influence of<br />

the oxygen introduction into the cation alkyl side chain.<br />

M. Montanino, M. Moreno, M. Carewska, S. Jeremias, S. Passerini,<br />

F. Alessandrini,<br />

G. B. Appetecchi ENEA (Italian National Agency for New Technologies,<br />

Energy and Sustainable Economic Development), Rome, Italy and Universität<br />

Muenster Institut für Physikalische Chemie, Germany<br />

12. 40-14.40 Lunch<br />

Session: General<br />

Chairman: F. Endres<br />

14. 40-15. 10 Catalyst Materials for Fuel Cell Voltages beyond 1. 23 V - Purpose,<br />

Synthesis and Application<br />

R. T. Atanasoski, L. L. Atanasoska, D. A. Cullen, G. M. Haugen, K. L. More,<br />

G. D. Vernstrom<br />

3M Fuel Cell Components Program, St. Paul, MN, USA and Materials<br />

Science & Technology Division, Oak Ridge National Laboratory, Oak Ridge,<br />

TN, USA<br />

15. 10-15. 30 Broadband electric spectroscopy of sulfonated polyetherether ketone and<br />

polybenzimidazole-based proton-conducting materials<br />

V. Di Noto, E. Negro, G. A. Giffin, G. Pace, S. Lavina<br />

Dip. Scienze Chimiche, Università di Padova and Istituto di Scienze e<br />

Tecnologie Molecolari, ISTM-CNR and INSTM, Padova, Italy<br />

15. 30-15. 50 Ionic liquid-insalt:Electrolytes for high temperature batteries<br />

M. J Marczewski, J. Scheers, P. Johansson<br />

Dept Applied Physics, Chalmers University of Technology, Goteborg, Sweden<br />

15.50- 16.10 Aluminum barrier deposition from ionic liquid solution for Organic Light<br />

Emitting Diodes (OLEDs)<br />

Peter Bressers a , Henk Rendering a and Ton van Mol b<br />

a TNO: PO Box 6235, 5600HE Eindhoven The Netherlands<br />

b Holst Centre: PO BOX 8550, 5605KN Eindhoven, The Netherlands<br />

16. 10-16. 30 Lithium conducting TDI-based ionic liquid electrolytes<br />

L. Niedzicki, E. Karpierz, M. Zawadzki, M. Kasprzyk, U. Domańska,<br />

M. Marcinek, W. Wieczorek<br />

Warsaw University of Technology, Faculty of Chemistry, Warsaw, Poland<br />

16. 30-16. 50 Coffee Break<br />

2


Session: Lithium Batteries 1<br />

Chairman : E. Peled<br />

16. 50-17. 10 Overview of the Ionic Liquids for Li and Li-Ion Batteries<br />

A. Guerfi, M. Koželj, K. Zaghib<br />

Direction Stockage et Conversion d’Énergie, Institut de Recherche d’Hydro<br />

Québec, Canada<br />

17. 10-17. 30 Ethoxy-Alkylimidazolium-based ionic liquids as electrolytes for Li<br />

Batteries<br />

E. Quartarone, S. Ferrari, C. Tomasi, P. Mustarelli, M. Fagnoni, S. Protti<br />

Dip. di Chimica, Sezione di Chimica Fisica, Università di Pavia, IENI-CNR,<br />

and Dip. di Chimica, Sezione di Chimica Organica, Università di Pavia, Italy<br />

17. 30-17.50 Improvement of electrochemical performance of LiMO2-Li2MnO3 cathode<br />

materials with ILs electrolyte for lithium ion batteries<br />

J. Li, S. Jeong, R. Kloepsch, M. Winter, S. Passerini<br />

Muenster Electrochemical Energy Technology, University of Muenster, German<br />

17. 50-18. 10 Redox behaviors and stability of polysulfide species in PP14-TFSI and<br />

PYR14-TFSI ionic liquid electrolytes for lithium/sulfur batteries<br />

Y- J Choi, E. Blomberg, K- W. Kim, P. Jacobsson, A. Matic<br />

School of Nano and Advanced Materials Engineering, Gyeongsang National<br />

University, Korea and Dept. Applied Physics, Chalmers University of<br />

Technology, Göteborg, Sweden<br />

18. 10-18. 30 Improving Safety of Lithium-Ion Batteries with Redox-Shuttle Electrolyte<br />

Additives – Prospects and Limits<br />

M. Wachtler, S. Kaymaksiz, S. Hess, M. Wohlfahrt-Mehrens<br />

ZSW – Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-<br />

Württemberg, Helmholtzstraße 8, 89081 Ulm, Germany<br />

20. 30 Reception Dinner<br />

3


Thursday, May 31 st<br />

Session: Lithium Batteries 2<br />

Chairman : K. Zaghib<br />

9. 00-9. 30 Advanced olivine cathode material for high energy density lithium batteries<br />

Y. -K Sun, S-M. Oh<br />

Department of WCU Energy Engineering, Hanyang University, Seoul Republic of<br />

Korea<br />

9. 30-9. 50 Solid Electrolyte Interphase on Anode Material for Lithium Battery Using<br />

BMP-TFSI Based Electrolyte<br />

T. Momma, H. Nara, S. Yamagami, C. Tatsumi, T. Osaka<br />

Department of Applied Chemistry, Waseda University, Japan<br />

9. 50-10. 10 Aluminum corrosion in ionic liquid-based electrolytes for lithium-ion<br />

batteries<br />

R. -S. Kühnel, M. Lübke, S. Passerini, M. Winter, A. Balducci<br />

University of Muenster, MEET Battery Research Centre, Institute of Physical<br />

Chemistry, Germany<br />

10. 10-10. 30 Lithium-ion batteries and supercapacitors with ionic liquid based<br />

electrolytes for hybrid electric vehicle application<br />

C. Arbizzani, L. Damen, M. Lazzari, F. Soavi , M. Mastragostino<br />

Dip. Scienza dei Metalli, Elettrochimica e Tecniche Chimiche, University of<br />

Bologna, Italy<br />

10. 30-11. 00 Coffee Break<br />

Chairman: S. Panero<br />

11. 00-11. 30 Ionic Liquid-based Electrolytes for High Energy Devices<br />

R. S. Kühnel, M. Lübke, S. Passerini, M. Winter, A. Balducci<br />

University of Muenster, MEET Battery Research Centre, Institute of Physical<br />

Chemistry, Germany<br />

11. 30-11. 50 Electrochemical-based syntheses in Ionic Liquids: applications to<br />

Inorganic materials synthesis for Li-based electrochemical systems<br />

C. Guéry, Y. Chen, M. Tulodziecki, J-M. Tarascon<br />

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules<br />

Verne, France<br />

11. 50- 12. 10 RTIL as electrolyte component for Li-based cells<br />

N. Penazzi<br />

Dip. di Scienza dei Materiali e Ingegneria Chimica – Politecnico di Torino,<br />

Italy<br />

4


12. 10-12. 30 Fast switching flexible electrochromic device with ionic liquid gel polymer<br />

electrolytes<br />

N. Garino , S. Bodoardo, , J. R. Nair, S. Zanarini, M. Destro, N. Penazzi,<br />

L. Pereira, P. J. Wojcik.<br />

Istituto Italiano di Tecnologia, Torino; Dip. Scienza Applicata e Tecnologia,<br />

Politecnico di Torino, Italy;Faculdade de Ciências e Tecnologia, Universidade<br />

Nova de Lisboa, Portugal.<br />

12. 30-12. 50 Electrode Processes in Rechargeable Sodium – Air Cells Based on Ionic<br />

Liquid (IL) Electrolytes<br />

E. Peled, D. Golodnitsky, R. Hadar, H. Mazor, M. Goor<br />

School of Chemistry and Wolfson Applied Materials Research Center, Tel Aviv<br />

University, Israel<br />

12. 50-15. 00 Lunch<br />

Chairman: : S. Greenbaum<br />

15. 00-15. 30 Recent progresses in the APPLES European project.<br />

S. Panero,<br />

Dept. Chemistry, University Sapienza, Rome, Italy<br />

15. 30-15. 50 Two-Dimensional Nanosheets of Layered Inorganic Solids and Graphene:<br />

Emerging Nanomaterials for Electrical Energy Storage Application<br />

Seong-Ju Hwang<br />

Center for Intelligent Nano-Bio Materials (CINBM), Dep. Chemistry and Nano<br />

Sciences, Ewha Womans University, Seoul, Korea<br />

15. 50-16. 10 Influence of Lithium Salt Doping in Ionic Liquids based Electrolyte for<br />

Rechargeable Lithium Batteries<br />

J-K. Kim, P. Johansson, J-H. Ahn, P. Jacobsson, A. Matic<br />

Dept Applied Physics, Chalmers University of Technology, Göteborg, Sweden<br />

and Dept Chemical & Biological Engineering, Gyeongsang National<br />

University, Jinju, Korea<br />

16. 10-16. 30 Cycling Performance and Thermal Stability of Rechargeable Lithium<br />

Batteries based on Ionic Liquid Electrolytes<br />

J. -A. Choi, Y. -S. Yun, S. -Y. Bae, B. Scrosati, D. -W. Kim<br />

Department. of Chemical Engineering, Hanyang University, Seoul, Korea<br />

16. 30 -18. 30 Coffee and Poster Session<br />

20. 30 Conference Dinner<br />

5


Friday June 1 st<br />

Session: Metal-air batteries<br />

Chairman: S. Passerini<br />

9. 00-9. 30 New Insights on Oxygen Reduction Reactions in Ionic Liquids for the Li-air<br />

Battery<br />

K. M. Abraham<br />

Northeastern University Center for Renewable Energy Technology Boston MA,<br />

USA<br />

9. 30-9. 50 Ionic Liquid-plasticized composite PEO Polymer Electrolyte Membranes<br />

for Lithium Batteries<br />

M. Wetjen, J. Hassoun, M. A. Navarra, S. Panero, S. Passerini, B. Scrosati<br />

University of Muenster, MEET Battery Research Centre, Institute of Physical<br />

Chemistry, Germany and Dept. Chemistry, Sapienza University of Rome, Italy<br />

9. 50-10. 10 Electrolyte solutions for nonaqueous Li-air batteries<br />

L. Cecchetto, B. Scrosati, F. Croce, O. Crowther, M. Salomon<br />

MaxPower Inc. Harleysville, PA, USA; Dept Chemistry, University of Rome;<br />

Dip. Di Scienze del Farmaco, University “d’Annunzio” Chieti-Pescara, Italy<br />

10. 10-10. 30 A high performance lithium-air battery<br />

J. Hassoun, H. G. Jung, Y. -K. Sun, B. Scrosati<br />

Dept Chemistry, University Sapienza, Rome and Dept. WCU Energy<br />

Engineering, Hanyang University, Seoul, Republic of Korea<br />

10. 30-11. 00 Coffee break<br />

Session: General<br />

Chairman: B. Scrosati<br />

11. 00-11. 30 Aluminium nanowires and macroporous structures as possible host<br />

materials for future generation batteries<br />

F. Endres, TU Clausthal D-38678 Clausthal-Zellerfeld, Germany<br />

11. 30 -11 50 Novel Electrolytes for Lithium-Ion Batteries<br />

B. Iliev, M. Taige, T. J. S. Schubert,<br />

Iolitec Ionic Liquids Technologies GmbH, Heilbronn, Germany<br />

11. 50-12. 10: New ionic liquids based on pyrrolidinium and asymmetric perfluorinated<br />

Sulfonylimides<br />

J. Reiter, E. Paillard, M. Winter, S. Passerini<br />

MEET Battery Research Centre, University of Muenster, Germany<br />

12. 10-12. 30 Advanced electrolytes containing ionic liquids for safe lithium batteries<br />

M. A. Navarra, J. Manzi, A. Tsurumaki, S. Panero, H. Ohno, B. Scrosati,<br />

Dept. Chemistry, Sapienza University of Rome, Italy and Dept. Biotechnology,<br />

University of Agriculture and Technology, Tokyo,Japan.<br />

6


12. 30-12. 50 Non-aqueous Sodium Conducting Electrolyte Containing Ionic Liquid<br />

M. Egashira, T. Asai, T. Tanaka, N. Yoshimoto, M. Morita<br />

Graduate School of Science and Engineering, Yamaguchi University, Japan<br />

12. 50 : Closing Remarks<br />

7


POSTER PRESENTATIONS<br />

Thursday, May 31 st 16:30-18:30<br />

Poster # 1 -An Advanced Reference Electrode Employed in RTIL's<br />

B. Shvartsev, H. Shasha, Y. Ein Eli<br />

Cae Group, Faculty of Materials Engineering Technion, Israeli Institute of<br />

Technology, Haifa, Israel<br />

Poster # 2- New ionic liquids electrolytes based on TDI anion<br />

M. Kasprzyk, L. Niedzicki, M. Zawadzki, U. Domańska, J. Dumińska,<br />

M. Marcinek, W. Wieczorek<br />

Warsaw University of Technology, Faculty of Chemistry, Warsaw, Poland<br />

Poster # 3 -Temperature dependence of the electrical conductivity in the ternary<br />

mixture butyrolactone+emim-I+I2 to be used in dye-sensitized solar cells<br />

S. García-Garabal Mosquera, L. M. Segade, M. Domínguez-Pérez, E. Rilo,<br />

M. Cabanas, O. Cabeza<br />

Departemento de Fisica da Universidade da Coruña, Spain<br />

Poster # 4 -Benchmarking of Li-TFSI doped ionic liquids using normalised potential<br />

gradient<br />

H. Lundgren, J. Lindberg, A. Nyman, M. Behm, G. Lindbergh<br />

Department of Chemical Engineering, School of Chemical Science and<br />

Engineering, KTH Royal Institute of Technology, Stockholm, Sweden<br />

Poster # 5 -Characterization of PYR14-TFSI/LP30 mixtures for safer Li-batteries<br />

L. Aguilera, P. Jacobsson, A. Matic<br />

Department of Applied Physics, Chalmers University of Technology, Göteborg,<br />

Sweden.<br />

Poster # 6- A Graphene-Assisted Phase Transition Route to Mesoporous 2D Aggregate of<br />

Anatase TiO2 Nanoparticles with Improved Electrode Performance<br />

J. - M. Lee, I. - Y. Kim, S. -Y. Han, S. -J. Hwang<br />

Center for Intelligent Nano-Bio Materials (CINBM), Department of Chemistry and<br />

Nano Sciences, Ewha Womans University, Seoul, Korea<br />

Poster # 7-A Beneficial Role of Layered Titanate Nanosheet on the Electrocatalytic<br />

Activity of Pt-Graphene Nanocomposite<br />

S. - I. Shin, A. Go, Y. Lee, S-J. Hwang<br />

Center for Intelligent Nano-Bio Materials (CINBM), Department of Chemistry and<br />

Nano Sciences, Ewha Womans University, Seoul 120-750, Korea<br />

Poster # 8-Remarkable Increase of the Formation Rate of Electrochemically Active<br />

MnO2 Nanoplates upon the Incorporation of Graphene Nanosheets<br />

D. - Y. Sung, Y. - R. Lee, J. L. Gunjakar, S. -J Hwang<br />

Center for Intelligent Nano-Bio Materials (CINBM), Department of Chemistry and<br />

Nano Sciences, Ewha Womans University, Seoul, Korea<br />

8


Poster # 9 -Polymer electrolytes encompassing room temperature ionic liquids for<br />

Li-based batteries by single step photo-polymerization<br />

M. Destro, J. . R. Nair, S. Ferrari, C. Gerbaldi, S. Bodoardo, P. Mustarelli,<br />

N. Penazzi, R. Bongiovanni<br />

Department of Applied Science and Technology, Politecnico di Torino and<br />

Department of chemistry, University of Pavia, , Italy<br />

Poster # 10 -Integrating experiments and computations to model the conductivity of ionic<br />

Liquids<br />

B. Ahlström, M. Marczewski, P. Johansson<br />

Department of Applied Physics, Chalmers University of Technology, Göteborg,<br />

Sweden<br />

Poster # 11 -Gel polymer electrolytes for lithium-ion batteries<br />

L. Lombardo a , M. A. Navarra, S. Panero, B. Scrosati<br />

Sapienza Universiy of Roma, Italy<br />

Poster # 12 -The effect of the addition of ionic liquids on conventional electrolytes for<br />

lithium Batteries<br />

J. Manzi , A. Tsurumak b , M. A. Navarra, H. Ohno, S. Panero, B. Scrosati<br />

Dept Chemistry, Sapienza University of Rome, Italy and Dep.Biotechnology,<br />

Tokyo University of Agriculture and Technology, Tokyo, Japan<br />

Poster # 13 -Structure and properties of Li-ion conducting polymer gel electrolytes<br />

based on ionic liquids of the pyrrolidinium cations and bis<br />

(trifluoromethanesulfonyl) imide anion.<br />

J. Pitawala, M. A. Navarra, B. Scrosati, P. Jacobsson, A. Matic<br />

Department of Applied Physics, Chalmers University of Technology, Göteborg,<br />

Sweden and Dept. Chemistry, University of Rome La Sapienza, P. le Aldo Moro 5,<br />

00185 Rome, Italy<br />

Poster # 14-RTIL-based electrolyte for Li-air cells<br />

J. Zeng, J. R Nair, C. Francia, M. A. Dumitrescu, S. Bodoardo, A. Vertova,<br />

N. Penazzi<br />

Department of Applied Science and Technology, Politecnico di Torino, Turin,<br />

Italy; Lithops S. r. l. , Via della Rocca 27, 10123 Turin, Italy and Department of<br />

Physical Chemistry and Electrochemistry, University of Milan, Milan, Italy<br />

Poster # 15 -Study of a Li-Air battery having an electrolyte solution formed by a mixture<br />

of an ether-based aprotic solvent and an ionic liquid<br />

L. Cecchetto, M. Salomon, B. Scrosati, F. Croce<br />

Dep. Chemistry, University Sapienza, Rome, Italy; Dip. Scienze del Farmaco,<br />

University Chieti, Italy; MaxPower Inc. Harleysville, PA, USA<br />

Poster # 16 -3D Microbatteries with Ionic Liquid Electrolytes for Medical Applications<br />

K. Freedman, G. Ardel, H. Mazor, R. Blanga, D. Golodnitsky, E. Peled<br />

School of Chemistry and Wolfson Applied Materials Research Center, Tel Aviv<br />

University, Israel<br />

9


Poster# 17 -Performance of carbon coated Si / graphite composite in IL based<br />

electrolytes<br />

Volodymyr Khomenko, Elie Paillard, Stefano Passerini, Viacheslav Barsukov<br />

Kiev National University of Technologies and Design (KNUTD), Ukraine;<br />

Westfalische<br />

Wilhelm University (WWU), Institute of Physical Chemistry, Muenster Germany<br />

10

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