Curriculum Vitae - The University of North Carolina at Chapel Hill

Jennifer Krumper Department of ChemistryKenan B126The University of North Carolina at Chapel Hill 919-966-3869jkrumper@email.unc.eduEDUCATIONUniversity of California, Berkeley, CA (2003)Ph.D. (chemistry)Advisors: Professors Robert G. Bergman and T. Don TilleyBowdoin College, Brunswick, ME (1998)A.B. (chemistry with honors, minor in mathematics, summa cum laude)Advisor: Professor Richard D. BroeneCURRENT POSITIONThe University of North Carolina at Chapel HillLecturer(2010 – present)PREVIOUS POSITIONSBowdoin College, Brunswick, ME (2009 – 10)Visiting Assistant Professor of ChemistryUniversity of California, Irvine, CA (2007 – 09)NIH Kirschstein-NRSA Postdoctoral Research FellowAdvisor: Professor Keith A. WoerpelIdaho State University, Pocatello, ID (2004 – 07)Assistant Professor of ChemistryUniversity of California, Berkeley, CA (2003 – 04)Postdoctoral Research AssociateAdvisors: Professors F. Dean Toste and Robert G. BergmanAWARDS AND PROFESSIONAL AFFILIATIONSNational Institutes of Health Kirschstein-NRSA Postdoctoral Fellowship (2007 – 2009)Ralph E. Powe Junior Faculty Enhancement Award, Oak Ridge Associated Universities (2005)Outstanding Graduate Student Instructor Award, UC Berkeley Chemistry (1999)National Science Foundation Predoctoral Fellowship (1998 – 2001)Phi Beta Kappa, member(1998 – present)William Campbell Root Award for Chemistry Research, Bowdoin College (1998)Merck Council on Undergraduate Research Fellowship (1997)American Chemical Society, member(1997 – present)Kamerling Award for Excellence in Chemistry, Bowdoin College (1996)TEACHING EXPERIENCEVisiting Assistant Professor of Chemistry, Bowdoin College (2009 – 10)Taught lecture (30-45 students) and laboratory (20 students) sections of Organic Chemistry II.Assistant Professor of Chemistry, Idaho State University (2004 – 06)Taught lecture (60-110 students) and laboratory (20 students) sections of Organic Chemistry I and II, InorganicChemistry (25 students), and Graduate Inorganic Chemistry (8 students).Graduate Student Instructor, University of California, Berkeley (1998 – 2001)Presented review sessions (30-300 students), graded course materials, and supervised laboratory sections.

Jennifer Krumper curriculum vitaeRESEARCH EXPERIENCEUniversity of California, Irvine (2007 – 09)Project Titles: “Nucleophilic Substitution Mechanisms for C-Glycosylations of Acetals” and “CoulombicControl in the Stereoselective Synthesis of Piperidines”Idaho State University (2004 – 06)Led a group of five undergraduates in development of novel organometallic and inorganic catalysts. Researchefforts targeted development of new processes for aziridination and C-H activation.University of California, Berkeley (2003 – 04)Project Title: “Mechanistic Investigation of Rhenium Oxo Catalyzed Hydrosilylation Reactions”University of California, Berkeley (1998 – 2003)Thesis Title: “Synthesis and Catalytic Activity of Group 7 and 9 Carbene Complexes”Bowdoin College (1996 – 98)Thesis Title: “Progress Toward the Total Synthesis of (+)-Rosemarinecine”ACADEMIC SERVICEMember, Bowdoin College Radiation Safety Committee (2010)Member, ISU Faculty Senate Academic Standards Council (2006)Chair, ISU Chemistry Department Teaching Activities Committee (2006)Co-Organizer, ACS Chemistry Olympiad, Idaho District (2006)Idaho State University Chemistry Department NMR Administrator (2004 – 06)Member, ISU Chemistry Department Promotion and Tenure Committee (2005 – 06)PUBLICATIONS9. “Correlations Between Nucleophilicities and Selectivities in the Substitutions of Tetrahydropyran Acetals,”J. R. Krumper, W. A. Salamant, and K. A. Woerpel, Journal of Organic Chemistry, 2009, 74, 8039-8050.8. “Continuum of Mechanisms for Nucleophilic Substitutions of Cyclic Acetals,” J. R. Krumper, W. A.Salamant, and K. A. Woerpel, Organic Letters, 2008, 10, 4907-4910.7. “Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation of Carbonyl Compounds,” K.A. Nolin, J. R. Krumper, M. D. Pluth, R. G. Bergman, and F. Dean Toste, Journal of the American ChemicalSociety 2007, 129, 14684-14696.6. “Synthesis and Reactivity of the Hydrido- and Alkylrhenium Methylidene ComplexesCp*(PMe 3 ) 2 (R)Re=CH 2 , (R = H, CH 3 ),” J. R. Krumper, R. L. Martin, P. J. Hay, C. M. Yung, J. Veltheer, and R.G. Bergman, Journal of the American Chemical Society 2004, 126, 14804-14815.5. “Unusual Ar-H/Rh-H J HH NMR Coupling in Complexes of Rhodium(III): Experimental Evidence andTheoretical Support for an η 1 -Arene Structure” J. R. Krumper, M. Gerisch, A. Magistrato, U. Röthlisberger, R.G. Bergman, and T. D. Tilley, Journal of the American Chemical Society 2004, 126, 12492-12502.4. “Sodium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, Na[B(3,5-(CF 3 ) 2 C 6 H 3 ) 4 ]” D. L. Reger, C. A. Little,J. J. S. Lamba, K. J. Brown, J. R. Krumper, R. G. Bergman, M. Irwin, J. P. Fackler, Jr., Inorganic Syntheses,2004, 34, 5-8.3. “Monomeric Rhodium(II) Catalysts for the Preparation of Aziridines and Enantioselective Formation ofCyclopropanes from Ethyl Diazoacetate at Room Temperature” J. R. Krumper, M. Gerisch, J. M. Suh, R.G.Bergman, and T. D. Tilley, Journal of Organic Chemistry 2003, 68, 9705-9710.

Jennifer Krumper curriculum vitaePUBLICATIONS, CONT’D2. “Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands” M. Gerisch, J. R.Krumper, R. G. Bergman, and T. D. Tilley Organometallics, 2003, 22, 47-58.1. “Novel Bis(oxazoline) Pincer Ligands: Formation of Mononuclear Rhodium(II) Complexes” M. Gerisch, J.R. Krumper, R. G. Bergman, and T. D. Tilley Journal of the American Chemical Society 2001, 123, 5818-5819.SELECTED PRESENTATIONS6. Continuum of Mechanisms for Nucleophilic Substitution Reactions of Cyclic Acetals,” J. R. Krumper,Bowdoin College Chemistry Seminar, February 2009.5. “Progress Toward Development of Rhenium Catalysts for the Conversion of Epoxides to Aziridines,” M.Moreno, A. W. Fielding, and J. R. Krumper*, Contributed Poster, CHED-933, 231 st National Meeting of theAmerican Chemical Society, Atlanta, GA, March 2006.4. “New Boryl Ligands for C-H Activation Reactions,” D.X. Denty and J. R. Krumper*, Contributed Poster,CHED-923, 231 st National Meeting of the American Chemical Society, Atlanta, GA, March 2006.3. “Structural, Mechanistic, and Catalytic Studies of Organometallic Rhodium and Rhenium Complexes,” J. R.Krumper, Wooster College, Stanford University, University of Rhode Island, Idaho State University, Universityof Illinois, Urbana-Champaign, Emory University, Georgia Institute of Technology, University of California,Irvine; December 2003 – January 2004.2. “Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands,” J. R. Krumper, M.Gerisch, R. G. Bergman, and T. D. Tilley, Poster, Gordon Conference on Organometallic Chemistry, Summer2002.1. “Synthesis, Reactivity, and Theoretical Studies of Cationic Re(III) Methyl and Hydrido MethyleneComplexes,” J. R. Krumper, P. J. Hay, R. L. Martin, and R. G. Bergman, Contributed Talk, INOR-521, 220 thNational Meeting of the American Chemical Society, Washington D.C., August 2000.