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The Remediation of Chemical Groundwater Contamination at Harwell

The Remediation of Chemical Groundwater Contamination at Harwell

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<strong>The</strong> <strong>Remedi<strong>at</strong>ion</strong> <strong>of</strong> <strong>Chemical</strong> <strong>Groundw<strong>at</strong>er</strong> <strong>Contamin<strong>at</strong>ion</strong> <strong>at</strong> <strong>Harwell</strong>GLOSSARYAODAquiferBoreholeChlorin<strong>at</strong>edsolventsGAC<strong>Groundw<strong>at</strong>er</strong>LevelHGCP<strong>Remedi<strong>at</strong>ion</strong>SSASVETEVEUns<strong>at</strong>ur<strong>at</strong>edzoneVacuumextractionVOCsW<strong>at</strong>er TableWSAZone <strong>of</strong>w<strong>at</strong>er tablefluctu<strong>at</strong>ionAbove Ordnance D<strong>at</strong>um. <strong>The</strong> height <strong>of</strong> a point (eg the w<strong>at</strong>er table or groundlevel) above mean sea level (the Newlyn d<strong>at</strong>um, since 1921), usually expressedin metres (eg 120 m AOD).An aquifer is a permeable rock th<strong>at</strong> stores and allows groundw<strong>at</strong>er flow readilythrough it.A deep, narrow vertical shaft used for the extraction or monitoring <strong>of</strong> groundw<strong>at</strong>eror soil vapour. Typically, boreholes drilled <strong>at</strong> <strong>Harwell</strong> in rel<strong>at</strong>ion to the chemicalgroundw<strong>at</strong>er contamin<strong>at</strong>ion programme are between 50 and 200 mm in diameterand up to 55 metres deep.Liquids used to remove grease from metal components in engineering workshopsand also as labor<strong>at</strong>ory reagents. <strong>The</strong>se were disposed <strong>of</strong> in large quantities to thewaste pits <strong>at</strong> the SSA and WSA. <strong>The</strong> principal groundw<strong>at</strong>er contaminants are allchlorin<strong>at</strong>ed solvents:• carbon tetrachloride;• chlor<strong>of</strong>orm;• 1,1,1-trichloroethane;• trichloroethene; and• tetrachloroethene.Chlorin<strong>at</strong>ed solvents form part <strong>of</strong> a larger grouping <strong>of</strong> chemicals called VOCs(see below).Granular Activ<strong>at</strong>ed Carbon. A product <strong>of</strong>ten derived from coal or coconut husks,which readily adsorbs organic chemicals. Widely used in many industries for thetre<strong>at</strong>ment <strong>of</strong> contamin<strong>at</strong>ed liquids and gases.See W<strong>at</strong>er Table.<strong>Harwell</strong> <strong>Groundw<strong>at</strong>er</strong> Containment Plant – the replacement w<strong>at</strong>er tre<strong>at</strong>ment plant<strong>at</strong> the WSA, which became fully oper<strong>at</strong>ional in June 2007.In the context <strong>of</strong> pollution, used to describe works carried out to reduce theimpact <strong>of</strong> the pollution.Southern Storage Area. <strong>The</strong> former RAF bomb dump, used for wastemanagement and disposal oper<strong>at</strong>ions by UKAEA from the 1940s to the 1970s.Soil Vapour Extraction. A technique used for removing VOC contamin<strong>at</strong>ion fromsoils and rocks, usually above the w<strong>at</strong>er table.<strong>The</strong>rmally enhanced vacuum extraction. Collective term for a group <strong>of</strong> techniqueswhich use he<strong>at</strong> energy to improve the r<strong>at</strong>e <strong>of</strong> contaminant removal using SVE. Inthe case <strong>of</strong> the WSA project, conductive he<strong>at</strong>ing elements are used to he<strong>at</strong> thechalk above the w<strong>at</strong>er table.<strong>The</strong> part <strong>of</strong> the aquifer above the w<strong>at</strong>er table.See SVE.Vol<strong>at</strong>ile Organic Compounds. A broad grouping for a range <strong>of</strong> different organiccompounds characterised by their readiness to evapor<strong>at</strong>e under normalconditions. Many <strong>of</strong> the chlorin<strong>at</strong>ed solvents fall within this c<strong>at</strong>egory.Th<strong>at</strong> level bene<strong>at</strong>h the land <strong>at</strong> which the pores <strong>of</strong> rock or soil become completelyfull <strong>of</strong> groundw<strong>at</strong>er. Also referred to as the groundw<strong>at</strong>er level.Western Storage Area. Licensed landfill, used for the disposal <strong>of</strong> chemical wastesfrom the 1970s to 1980s.<strong>The</strong> part <strong>of</strong> the chalk th<strong>at</strong> is between the lowest and highest observed w<strong>at</strong>er tablelevels. At <strong>Harwell</strong>, the Chalk w<strong>at</strong>er table fluctu<strong>at</strong>es by up to 18 metres, from thelowest to highest levels. Depending on the elev<strong>at</strong>ion <strong>of</strong> the w<strong>at</strong>er table, this part<strong>of</strong> the aquifer may be available for SVE or TEVE.LSG <strong>Groundw<strong>at</strong>er</strong> Report vi March 2009

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