Material Safety Data Sheet - Kremer Pigmente
Material Safety Data Sheet - Kremer Pigmente
Material Safety Data Sheet - Kremer Pigmente
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<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
According to regulation (EC) No. 1907/2006 (REACH)<br />
31402 - Lithium Waterglass<br />
Revised edition: 02.03.2011 Printed: 09.03.2011<br />
1. Identification of the Substance/Preparation and of the Company/Undertaking<br />
Identification of the Product<br />
Product Name: Lithium Waterglass<br />
Article No.: 31402<br />
Use of the Substance/Preparation: Artists´ and Restoration <strong>Material</strong><br />
Company<br />
Company: <strong>Kremer</strong> <strong>Pigmente</strong> GmbH & Co. KG<br />
Address: Hauptstrasse 41-47, D 88317 Aichstetten<br />
Tel/Fax: Tel +49 7565 91120, Fax +49 7565 1606<br />
Internet: www.kremer-pigmente.de, kremer-pigmente@t-online.de<br />
Emergency No.: +49 7565 91120, Mon-Fri 8:00 - 17:00<br />
2. Hazard Identification<br />
Hazard designation: Xi Irritating<br />
GHS Classification Eye irritation, category 2<br />
Risk Phrases: R36 Irritating to eyes.<br />
Additional information: The classification is according to current EC listing, however, some<br />
information from literature were added by the supplier.<br />
3. Composition/Information on Ingredients<br />
Chemical Characterization: This product is a preparation.<br />
Hazardous Ingredients: Silicon dioxide, lithium silicate (Xi; R36; H319) 25-50 %<br />
CAS-Nr: 12627-14-4 EINECS-Nr: 235-730-0 EC-Nr:<br />
4. First Aid Measures<br />
After skin contact: Wash off immediately with plenty of soap and water and rinse<br />
thoroughly.<br />
After eye contact: Rinse open eyes with plenty of water. In case of discomfort seek<br />
medical help.<br />
After ingestion: Rinse mouth with water and drink plenty of water.<br />
Immediately get medical help.<br />
General information: Remove contaminated clothes.<br />
5. Fire-Fighting Measures<br />
Suitable extinguishing media: Product itself does not burn.<br />
Use extinguishing media for surrounding fire.<br />
Protective equipment: No special measures required.<br />
6. Accidental Release Measures<br />
Personal precautions: Floor may be slippery; use care to avoid falling.<br />
Environmental precautions: Prevent contamination of soils, drains and surface water.<br />
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<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
According to regulation (EC) No. 1907/2006 (REACH)<br />
31402 - Lithium Waterglass<br />
Revised edition: 02.03.2011 Printed: 09.03.2011<br />
Methods of cleaning/absorption: Contain with inert absorbent material (e.g. sand, acid binder,<br />
universal binder, sawdust) and collect in appropriate containers for<br />
disposal.<br />
7. Handling and Storage<br />
Handling<br />
Instructions on safe handling: No special measures necessary if properly handled.<br />
Information on fire and explosion No special measures necessary.<br />
protection:<br />
Storage<br />
Storage conditions: Protect from frost.<br />
Floor must be alkali resistant.<br />
Requirements for storage areas Unsuitable container material: light metal.<br />
and containers:<br />
Suitable container material: steel or stainless steel.<br />
Unsuitable container material: aluminum, zinc.<br />
Unsuitable container material: glass, ceramic.<br />
Storage compatibility: Do not store together with: acids.<br />
Storage class (VCI): 10-13<br />
8. Exposure Controls/Personal Protection<br />
Additional information about<br />
design of technical systems:<br />
Components with workplace<br />
control parameters (Germany):<br />
No further measures, see Section 7.<br />
The product does not contain any relevant amounts of substances<br />
with critical values that require monitoring at the workplace.<br />
Personal protective equipment<br />
General protective measures: Keep away from foodstuffs and drinks. Do not eat, drink or smoke<br />
during work. Wash hands before breaks and at the end of the shift.<br />
Respiratory protection: Not required.<br />
Hand protection:: Protective gloves which are alkali-resistant.<br />
Protective glove material: Please note the manufacturers´ detailed statements, especially about<br />
the minimum thickness and the minimum breakthrough time.<br />
Natural rubber with a low percentage of chloroprene rubber.<br />
Recommended: Protective index 6, > 480 min. of permeation time<br />
accord. EN 374.<br />
Eye protection: <strong>Safety</strong> glasses with protective shields (EN 166).<br />
Body protection: Protective clothing, alkali-resistant.<br />
9. Physical and Chemical Properties<br />
Form: liquid<br />
Color: opaque<br />
Odor: odorless<br />
Boiling temperature: > 100°C<br />
Self-ignition: is not auto-ignitable<br />
Explosion risk: Product does not present an explosion hazard.<br />
Density: ca. 1.26 g/cm3 (20°C)<br />
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<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
According to regulation (EC) No. 1907/2006 (REACH)<br />
31402 - Lithium Waterglass<br />
Revised edition: 02.03.2011 Printed: 09.03.2011<br />
Solubility in water: completely miscible<br />
pH-Value: ca. 12.5 (20°C)<br />
Viscosity dynamic: ca. 20 mPa.s (20°C)<br />
10. Stability and Reactivity<br />
Thermal<br />
No decomposition if used according to specifications.<br />
decomposition/Conditions to be<br />
avoided:<br />
Hazardous reactions: Reacts with acids (exothermal reactions)<br />
Reactions with light metals in presence with humidity under<br />
development of hydrogen.<br />
Hazardous decomposition<br />
None known.<br />
products:<br />
11. Toxicological Information<br />
Primary effects<br />
Irritant effect on skin: Causes skin and mucous membrane irritation.<br />
Irritant effect on eyes: Intensive irritation. Can damage eye (rabbit).<br />
Sensitization: Not known.<br />
12. Ecological Information<br />
Elimination (Persistency and Can be eliminated from water by chemical flocculation.<br />
Degradability):<br />
Inorganic substance. Biological degradability is not affected.<br />
Behaviour in sewage system: The product is alkaline.<br />
Product should be neutralized before discarding to sewage system.<br />
Further ecological effects: Not toxic after neutralization.<br />
Further information<br />
Water hazard class: 1<br />
Do not let product contaminate ground water, waterways or sewage<br />
system.<br />
13. Disposal Considerations<br />
Product: Dispose of according to official national and local regulations.<br />
Waste Code No.: The waste code is determined according to the code of the European<br />
Waste Catalog.<br />
Uncleaned packaging: Dispose of according to official local regulations.<br />
14. Transport Information<br />
Further information: Not classified as a dangerous good under transport regulations.<br />
15. Regulatory Information<br />
Designation according to GHS<br />
guidelines:<br />
Harmful<br />
Signal word: Warning<br />
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<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
According to regulation (EC) No. 1907/2006 (REACH)<br />
31402 - Lithium Waterglass<br />
Revised edition: 02.03.2011 Printed: 09.03.2011<br />
Hazard designation: H319 Causes serious eye irritation.<br />
<strong>Safety</strong> designation: P305+P351+P338 If in eyes: Rinse cautiously with water for several<br />
minutes. Remove contact lenses if present and easy to do. Continue<br />
rinsing.<br />
P280 Wear protective gloves/protective clothing/ eye protection/face<br />
protection.<br />
P264 Wash thoroughly after handling.<br />
P337+P313 If eye irritation persists: Get medical advice/attention.<br />
Designation according to EC The material is subject to classification according to EC lists.<br />
Guidelines:<br />
Hazard designation: Xi Irritating<br />
Hazardous components for<br />
Silicon dioxide, lithium salt<br />
labelling:<br />
Risk Phrases: R36 Irritating to eyes.<br />
<strong>Safety</strong> Phrases: S26 In case of contact with eyes, rinse immediately with plenty of<br />
water and seek medical advice.<br />
S60 This material and its container must be disposed of as hazardous<br />
waste.<br />
S25 Avoid contact with eyes.<br />
S37 Wear suitable gloves.<br />
S39 Wear eye/face protection.<br />
S24 Avoid contact with skin.<br />
Water hazard class: 1, slightly hazardous for water<br />
16. Other Information<br />
This product should be stored, handled and used in accordance with good hygiene practices and in<br />
conformity with any legal regulations.<br />
This information contained herein is based on the present state of knowledge and is intended to describe<br />
our product from the point of view of safety requirements. It should be therefore not be construed as<br />
guaranteeing specific properties.<br />
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