70520 - Shellsol® A - Kremer Pigmente

Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
70520 - Shellsol® A
Revised edition: 24.05.2011 Printed: 07.11.2011
1. Identification of the Substance/Preparation and of the Company/Undertaking
Identification of the Product
Product Name: Shellsol® A
Article No.: 70520
Use of the Substance/Preparation: Artists´ and Restoration Material
Relevant identified Uses of the Substance or Mixture and Uses advised against
Identified uses: No information available.
Company
Company: Kremer Pigmente GmbH & Co. KG
Address: Hauptstrasse 41-47, D 88317 Aichstetten
Tel/Fax: Tel +49 7565 91120, Fax +49 7565 1606
Internet: www.kremer-pigmente.de, kremer-pigmente@t-online.de
Emergency No.: +49 7565 91120, Mon-Fri 8:00 - 17:00
2. Hazard Identification
Designation according to EC Regulation No.1272/2008
GHS Classification Flammable liquids, category 3
Specific Target Organ Toxicity (single exposure), category 3
Aspiration hazard, category 1
Chronic aquatic toxicity, category 2
Hazard designation: GHS03
GHS09
GHS07
GHS08
Signal word: Danger
Hazard designation: H226 Flammable liquid and vapour.
H411 Toxic to aquatic life with long lasting effects.
H336 May cause drowsiness or dizziness.
H304 May be fatal if swallowed and enters airways.
H335 May cause respiratory irritation.
-- EUH066 Repeated exposure may cause skin dryness or cracking.
Safety designation: P301+P310 If swallowed: Immediately call a poison center or
physician.
P280 Wear protective gloves/protective clothing/ eye protection/face
protection.
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
70520 - Shellsol® A
Revised edition: 24.05.2011 Printed: 07.11.2011
Safety designation: P210 Keep away from heat/sparks/open flames/hot surfaces – No
smoking.
P273 Avoid release to the environment.
P331 Do not induce vomiting.
P403+P235 Store in a well ventilated place. Keep cool.
P304+P340 IF inhaled: Remove victim to fresh air and keep at rest
in a position comfortable for breathing.
Hazardous components for
Hydrocarbons, C9, aromatics
labelling:
Designation according to EC Regulation No. 67/548 or No.1999/45
Hazard designation: N Hazardous to the environment
Xn Harmful
Risk Phrases: R37 Irritating to respiratory system.
R67 Vapours may cause drowsiness and dizziness.
R65 Harmful: May cause lung damage if swallowed.
R53 May cause long-term adverse effects in the aquatic environment.
R51 Toxic to aquatic organisms.
R66 Repeated exposure may cause skin dryness or cracking.
R10 Flammable.
Safety Phrases: S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to
be specified by the manufacturer).
S61 Avoid release to the environment. Refer to special instructions /
Safety data sheets.
S24 Avoid contact with skin.
S62 If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.
S57 Use appropriate container to avoid environmental contamination.
3. Composition/Information on Ingredients
Mixture :
Chemical Characterization: Mixture of aromatic hydrocarbons C9-C10.
Hazardous Ingredients: Hydrocarbons, C9, Aromatics (Xi,N; R10-37-65-66-67-51/53; H226-
336-335-304-411) 100 %
CAS-Nr: --- EINECS-Nr: 918-668-5 EC-Nr:
Additional information: Benzol concentration < 0.1 weight%
4. First Aid Measures
Description of the First Aid Measures
After inhalation: Supply fresh air. If required give artificial respiration. Keep patient
warm.
In case of unconsciousness place patient stable in side position for
transportation.
Oxygen therapy in case of impaired breathing.
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
70520 - Shellsol® A
Revised edition: 24.05.2011 Printed: 07.11.2011
After inhalation: Consult physician immediately.
After skin contact: Remove contaminated clothing immediately. Wash off immediately
with plenty of water and soap.
If irritation continues consult a physician.
After eye contact: Rinse open eye for several minutes under running water. Should
irritation continue, seek medical advice.
After ingestion: Rinse mouth with plenty of water.
Do not induce vomiting. Consult physician immediately.
Careful when vomiting. Risk of aspiration. Keep respiratory tract
open.
In case of spontaneous vomiting, bring unconsciousness person in a
stable side position.
Important Symptoms and Effects
Possible symptoms: Headache, drowsiness, unconsciousness, dry skin.
Information Regarding First-Aid or Special Treatment
Information for physician: If vomiting occurs after ingestion, aspiration into the lungs can occur
which can cause a chemical pneumonia or suffocation.
5. Fire-Fighting Measures
Extinguishing Media
Suitable extinguishing media: Foam, carbon dioxide (CO2), extinguishing powder, water jet.
Fight larger fire with water jet or alcohol resistant foam.
Unsuitable extinguishing media: Water with full jet.
Special Hazards
Special hazards: Combustible.
Fumes can form an explosive mixture with air.
The vapor is heavier than air, spreads along the ground and distant
ignition is possible.
In case of fire: formation of carbon oxides.
Fire-Fighting Measures:
Protective equipment: Wear self-contained respiratory protective device and full protective
gear.
Further information: Cool exposed containers with water mist.
Collect contaminated extinguishing water and debris separately;
avoid contamination of sewage system.
6. Accidental Release Measures
Personal Precautions and Protective Measures
Personal precautions: Wear appropriate protective equipment. Keep spectators away.
Close leaks without taking any risk.
Provide adequate ventilation. Keep away from sources of ignition.
Environmental precautions: Prevent contamination of soils, drains and surface water.
Contact local authorities if product pollutes soil or vegetation.
Methods of cleaning/absorption: Contain with absorbent material (sand, diatomaceous earth, universal
absorbent, Oil Dri) and dispose accordingly.
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
70520 - Shellsol® A
Revised edition: 24.05.2011 Printed: 07.11.2011
Methods of cleaning/absorption: Dispopse of contaminated material as waste according to section 13.
Vapors in combination with air can form an explosive compound.
Reference to other Sections: Protective clothing, see para. 8.
7. Handling and Storage
Handling
Instructions on safe handling: The usual precautionary measures are to be adhered to when
handling chemicals.
Provide adequate ventilation.
Avoid contact with eyes and skin.
Do not breathe vapors, aerosols.
Information on fire and explosion
protection:
Keep away from sources of ignition - do not smoke. Take measures
to prevent electricity static discharge.
Storage
Storage conditions: Store in tightly sealed containers in a dry and cool room.
Store out of direct sunlight.
Product is combustible.
Keep away from ignitable sources and fire.
Requirements for storage areas Store in a room with a solvent-proof floor.
and containers:
Storage compatibility: Do not store together with: strong oxidants.
Storage class (VCI): 3: Flammable liquids
8. Exposure Controls/Personal Protection
Technical protective measures: No further measures, see Section 7 and 8.
Parameters to be controlled (DE): TRGS 900
C9-C15 Aromatics
Value: AGW (D): 100 mg/m3; 2(II)
Personal Protective Equipment
General protective measures: Keep away from foodstuffs and drinks. Do not eat, drink or smoke
during work. Wash hands before breaks and at the end of work.
Avoid contact with eyes and skin.
Respiratory protection: Respirator mask required if ventilation is insufficient. Wear filter
respirator in case of short-term or low exposure, and wear a selfcontained
breathing apparatus in case of long-term or higher
exposure.
Hand protection: Protective gloves. The glove material has to be impermeable and
resistant to the product / substance / preparation.
Protective glove material: Fluoro carbon rubber, nitrile rubber.
Eye protection: Tightly fitting safety goggles.
Body protection: Protective clothing (flame-proof, antistatic).
Environmental precautions: Avoid contamination of sewage system, open water ways and ground
water.
9. Physical and Chemical Properties
General Information
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
70520 - Shellsol® A
Revised edition: 24.05.2011 Printed: 07.11.2011
Form: liquid
Color: colorless
Odor: aromatic
Melting temperature: -50°C
Boiling temperature: 140-200°C
Flash point: > 35°C
Ignition temperature: 450°C
Self-ignition: Product is not auto-ignitable.
Explosion risk: Product is not explosive; however, an explosive vapor/air mixture
can be formed.
Lower explosion limit: 0.8 Vol.%
Upper explosion limit: 7.0 Vol.%
Vapor pressure: 5 hPa (20°C)
Density: 0.868 - 0.878 g/cm3 (15°C)
Solubility in water: insoluble
Viscosity dynamic: 1.0 mm2/s (20°C)
10. Stability and Reactivity
Reactivity: No decomposition if used according to specifications.
Chemical stability: Stable if used according to specifications.
Réactions dangereuses: Formation of explosive vapor-air-mixtures possible.
Conditions to be avoided: Avoid contact with heat, sparks and open fire.
Avoid direct sunlight.
Substances to be avoided: Strong oxidizing agents.
Hazardous decomposition
products:
Carbon oxides
11. Toxicological Information
Acute Toxicity
LD50, oral: > 2000 mg/kg (rat)
LD50, dermal: > 2000 mg/kg (rabbit)
Primary effects
Irritant effect on skin: Causes mild skin irritation. Prolonged contact may cause dermatitis.
Irritant effect on eyes: Causes eye ailments, however does not damage the eye tissue.
Iinhalation: Irritates the respiratory tract.
Ingestion: Small amounts which can intrude the lungs after swallowing or by
aspiration after vomiting, can cause a pulmonary edema or
pneumonia.
Sensitization: No sensitizing effects known.
Further toxicological effects: Aspiration into the lungs when swallowed or vomited may cause
chemical pneumonitis. Product is irritating, respectively, caustic for
the respiratory tract.
Inhalation of high vapor concentrations can be narcotic and may
cause depression of the central nervous system.
12. Ecological Information
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
70520 - Shellsol® A
Revised edition: 24.05.2011 Printed: 07.11.2011
Persistency and Degradability: The product floats on the water surface and does not dissolve.
Readily biodegradable.
The product evaporates slowly.
Bioaccumulation: The main components float on the water surface and do not dissolve.
Mobility: Insoluble.
- Fish toxicity: LL50: 9.22 mg/l (96h, Oncorhynchus mykiss)
EL50: 3.2 mg/l (48h, Ceriodaphnia Dubia (Crustacea))
- Algae toxicity: EC50: 2.6-2.9 mg/l (72h; Pseudokirchneriella subcapitata)
Results of PBT vPvB assessment: This product is neither a PBT or vPvB substance nor does it contain
a PBT or vPvB substance.
Further information
Water hazard class: 2
Do not let product contaminate ground water, waterways or sewage
system.
Danger to drinking water even if small quantities leak into the
ground. Also poisonous for fish and plankton in water bodies.
13. Disposal Considerations
Methods
Product: Must not be disposed together with household garbage.
Do not let product enter water systems.
Dispose of according to official national and local regulations.
Uncleaned packaging: Dispose of according to official local regulations.
Uncontaminated packaging may be recycled. Completely empty
packaging can be disposed of with the regular waste.
Do not puncture, cut or weld uncleaned drums.
14. Transport Information
Road Transportation ADR/RID
Class: 3
Packaging group: III
UN No.: 3295
Classification code: F1
Tunnel No.: D/E
Hazard No.: 3
Correct technical name: HYDROCARBONS, LIQUID, N.O.S. (Solvent naphtha (petroleum),
light aromatic)
Sea transportation
IMDG/GGVSee Class: 3
Packaging group: III
UN No.: 3295
EmS No.: F-E,S-D
Hazard No.: 3
Marine pollutant: P
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
70520 - Shellsol® A
Revised edition: 24.05.2011 Printed: 07.11.2011
Correct technical name: HYDROCARBONS, LIQUID, N.O.S. (Solvent naphtha (petroleum),
light aromatic)
Air transportation
ICAO/IATA Class: 3
Packaging group: III
UN No.: 3295
Hazard No.: 3
Correct technical name: HYDROCARBONS, LIQUID, N.O.S. (Solvent naphtha (petroleum),
light aromatic)
15. Regulatory Information
National Regulations (D)
Local regulations on chemical Underlies the Accident Ordinance 13
accidents:
Employment restrictions: The employment restrictions for young workers in accordance with
the Youth Employment Protection Law (94/33/EC) are to be
observed.
The employment restrictions for expectant and nursing mothers in
accordance with the Maternity Protection Guideline (94/85/EEC) are
to be observed.
Water hazard class: 2, hazardous for water
Chemical safety assessment
Chemical safety assessment: No information available.
16. Other Information
This product should be stored, handled and used in accordance with good hygiene practices and in
conformity with any legal regulations.
This information contained herein is based on the present state of knowledge and is intended to describe
our product from the point of view of safety requirements. It should be therefore not be construed as
guaranteeing specific properties.
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