EQC <strong>Eighth</strong> <strong>Annual</strong> <strong>Report</strong> - Page 4and people with health problems are especially sensitiveto sulfur pollution.Most observations of the health effects of sulfurcompounds come from episodes of high SO2 at thesame time total suspended particulate levels are high.Normally, the upper respiratory tract absorbs SO2,but particulate matter can carry sulfur compounds tothe innermost recesses of the lungs, thereby causinggreater damage than either would cause alone. Thepollutants act synergistically; their effect together isgreater than the sum of their individual effects.High concentrations of SO2 can cause chlorosis inplants, which is a discoloring of leaf tissue due to aloss of chlorophyll. During acute exposure, leaf tissuemay die. Sternberg (1981) documented significantdecreases in crop yield from SO2 pollution. Becausemany forage plants are sensitive to SO2, livestockgrazing can be adversely affected. The SO: also reactssynergistically with ozone and NO:, damaging plantsat lower concentrations than any of the pollutantswould by itself.Acid mists, or high concentrations of suspendedacidic droplets, can corrode metals and cause extensivedamage to steel rails,buildings and structures.Carbonate building materials, such as marble, concreteand mortar, are particularly susceptible todamage from acid mist. H2S can also tarnish and corrodemetals, particularly silver and copper.pulmonary edema, can result from high NO2 concentrations.Studies have yet to demonstrate direct humanhealth problems caused by hydrocarbons. However,hydrocarbons contribute to photochemical oxidants,which do affect people. The oxidants irritate the eyes,nose and throat, and often the respiratory tract. Manyresearchers believe that high oxidant levels alsodebilitate athletic performance and harm asthmatics.Photochemical oxidants significantly reduce visibility.This can reduce tourism and population growthin certain areas. Ozone damages many materials. Forexample, it attacks organic and synthetic fibers anddeteriorates rubber. Photochemical oxidants are thecountry's most significant plant-damaging pollutant.Carbon MonoxideThe incomplete combustion of organic fuel producescarbon monoxide (CO), a colorless and odorlessgas. The principal sources of CO are motor vehicles,but other sources in <strong>Montana</strong> include oil refineries,the wood products industry, and wood stoves andfireplaces.Photochemical OxidantsIt takes a complex series of chemical reactionsamong nitrogen oxides, hydrocarbons, and sunlight toproduce photochemical oxidants. These are compoundscapable of oxidizing substances that commonoxygen in the air cannot. The nitrogen oxides usuallyoriginate from the high-temperature combustion offossil fuels, particularly in automobile engines.Hydrocarbons, containing only carbon and hydrogen,also mainly originate in motor vehicles. Smallersources include petroleum refining and transfer operationsand evaporation of industrial solvents used inpainting and dry cleaning.EffectsCarbon monoxide outcompetes oxygen for theblood's hemoglobin. High levels of CO significantlydecrease the flow of oxygen to the areas of the bodythat depend on it most: the heart and the brain. Asthe oxygen concentration carried by the hemoglobindecreases, the heart must work harder to compensate,in turn increasing its need for oxygen. Symptoms ofexcess CO exposure include headaches, dizziness,fatigue, and sluggish reactions; excessive exposure canlead to death. CO may inhibit the bioelectric functionsof the brain, and thus impair intellectual ability.Heart patients, smokers, young and old people, pregnantwomen and persons on medication may be particularlysusceptible to high concentrations of CO.EffectsNitrogen dioxide in high concentrations creates anunpleasant odor and diminishes night vision. A studyof school children living near an explosives plant thatproduced NO2 showed an increase in respiratoryillness and decreased ventilatory function. Lungdamage, including bronchial damage and acuteFluorideFluoride sources include aluminum, glass, brick,phosphate fertilizer and elemental phosphorus plants;
EQC <strong>Eighth</strong> <strong>Annual</strong> <strong>Report</strong> - Page 5coal-burning industries can also emit fluoride. In<strong>Montana</strong> there are two major stationary sources offluoride: the ARCO aluminum smelter in ColumbiaFalls and Stauffer Chemical Company's elementalphosphorus plant in Ramsay. The coal-fired powerplants in Colstrip, BilHngs and Sidney and oilrefineries in Billings and Great Falls also release somefluorides.EffectsHigh concentrations of fluoride can harm vegetation,animals and humans. Some researchershypothesize that fluorides are carcinogens and cocarcinogens.Fluoride can reduce the red blood cellcount, thereby decreasing oxygen uptake within thebody. Plants accumulate fluoride. Excessive amountsinhibit the plants' metabolic processes of photosynthesis,growth, and reproduction. Such damageultimately kills the affected tissue. Animals that grazeon vegetation contaminated by fluoride also accumulatethe pollutant in their bones and teeth, causingtooth loss and fluorosis, a crippling bone disease. Thiscan be fatal for such grazing animals as cattle.Therefore, fluoride pollution can cause majoreconomic damage.beryllium, cadmium and lead, are toxic. Second, theaccumulation of non-toxic fine particles can"overload" the lung and interfere with its selfcleaningability. Third, the particulate can enhance theharmful effects of other pollutants. The particles maycarry carcinogenic substances to the lungs. Throughinjury to lung and throat linings, TSP weakens thebody's resistance to infection. In general, high levelsof particulate matter increase new respiratorydisorders, aggravate existing respiratory diseases, andirritate eyes, nasal passages and skin. People sufferingfrom respiratory and heart ailments are extremely susceptibleto elevated particulate concentrations. Currently,the EPA is considering implementing an ambientstandard based on inhalable particulate toreplace the total suspended particulate standard it nowuses.Particulate in the air reduces visibility;large particlesabsorb light and small particles scatter light.Particles can also modify such weather conditions astemperature, humidity, cloud cover, precipitation andfog. It can help form secondary particles, such as acidsulfates and nitrates, that as acid snow or rain canseriously affect plants, animals and materials. Thecombination of sulfur oxides and particulate mattercauses serious economic loss through soiling anddeteriorating material. In addition, particles containingheavy metals accumulate in plants and animalsand may damage them after extended periods of lowlevelpollution.Suspended ParticulateSuspended particulate matter, or airborne particles,originate from both natural and man-made sources.Natural sources include forest fires and erosion. Manmadesources include industrial processes, unpavedroads, gravel and asphalt batch plants, agriculture,motor vehicles, transportation, incinerators, construction,residential heating devices and refuse-burningoperations. The particulate varies in size, form (solidor liquid) and chemical makeup. Coarse particlesrange between 2.5 micrometers (um) and 15 um indiameter. Fine particles range up to 2.5 um indiameter. Fine particulate remains suspended in theatmosphere for long periods, while coarse particulateusually settles out close to the source.Trace MetalsAirborne trace metals generally result from combustion,smelting, open pit mining and automobiles.Principal stationary sources of trace metals in <strong>Montana</strong>include the ASARCO smelter in East Helena(lead, cadmium and arsenic); the Berkeley open pitmine in Butte (pulverized ore and unconsolidated soilexposed to wind); and coal-fired power plants (lead,arsenic, nickel, copper, zinc, selenium and cadmium).The emissions from coal-burning facilities vary considerablywith the composition of the coal.Automobiles using leaded gasoline are a major nonstationarysource of airborne lead particles.EffectsEffectsThe nose and throat usually trap coarse particles,preventing serious health threats. But fine particulatecan penetrate the deep recesses of the lungs. Fine particulatecan adversely affect health in three ways.First, some airborne particles, such as asbestos.Trace metals present a serious health risk, even insmall concentrations, because many are highly toxic.They can accumulate and cause injury after longexposure to low levels. Lead can cause anemia, kidneymalfunction, brain damage and, ultimately, death.
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