SAFETY DATA SHEET CtP Plate Cleaner - Offset Supplies

REVISION DATE: 08/01/07SAFETY DATA SHEETCtP Plate Cleaner1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKINGPRODUCT NAMEAPPLICATIONSUPPLIERCtP Plate CleanerA Lithographic plate cleanerDay International ChemicalProducts Division,Varn House, NorthbankIndustrial Park, Irlam, GreaterManchester,M44 5BL, EnglandTel. + 44 (0)161 775 5412Fax. + 44 (0)161 775 54152 COMPOSITION/INFORMATION ON INGREDIENTSNameEC No.CAS-No.ContentClassificationCITRIC ACID201-069-177-92-9 1-5%Xi;R36/37/38.ETHOXYLATED ISOTRIDECYLALCOHOL (EINECS OECD Polymer)NAPHTHA (PETROLEUM),HYDROTREATED HEAVY (2)PHOSPHORIC ACID ...%265-150-3231-633-224938-91-8 1-5%64742-48-9 50-70%7664-38-2 1-5%Xn;R22. Xi;R41.Xn;R65. R10,R66.C;R34The Full Text for all R-Phrases are Displayed in Section 16COMPOSITION COMMENTSAn emulsion (aqueous/petroleum distillate)3 HAZARDS IDENTIFICATIONFlammable. Repeated exposure may cause skin dryness or cracking.CLASSIFICATION R10, R66.4 FIRST-AID MEASURESINHALATIONMove the exposed person to fresh air at once. For breathing difficulties oxygen may be necessary. If breathingstops, provide artificial respiration. Keep the affected person warm and at rest. Get prompt medical attention.INGESTIONDo not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter thelungs. Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medicalattention immediately!SKIN CONTACTRemove affected person from source of contamination. Remove contaminated clothing. Wash the skinimmediately with soap and water. Get medical attention if irritation persists after washing.EYE CONTACTMake sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of waterwhile lifting the eye lids. Continue to rinse for at least 15 minutes. Contact physician if irritation persists.5 FIRE-FIGHTING MEASURES1 / 5

REVISION DATE: 08/01/07CtP Plate CleanerEXTINGUISHING MEDIAFire can be extinguished using: Carbon dioxide (CO2). Foam. Dry chemicals, sand, dolomite etc.SPECIAL FIRE FIGHTING PROCEDURESAvoid breathing fire vapours. Cool containers exposed to flames with water until well after the fire is out. Keeprun-off water out of sewers and water sources. Dike for water control.6 ACCIDENTAL RELEASE MEASURESSPILL CLEAN UP METHODSExtinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, drysand or earth and place into containers. Do not let washing down water contaminate ponds or waterways. Wearnecessary protective equipment.7 HANDLING AND STORAGEUSAGE PRECAUTIONSMaintain good standards of hygiene and work practices. Avoid spilling, skin and eye contact. Keep away fromheat, sparks and open flame. Ventilate well, avoid breathing vapours. Use approved respirator if aircontamination is above accepted level.STORAGE PRECAUTIONSFlammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container ina dry and cool place. Keep in original container. Protect against physical damage and/or friction. May attacksome plastics, rubber and coatings.STORAGE CLASSFlammable liquid storage.8 EXPOSURE CONTROLS/PERSONAL PROTECTIONNameNAPHTHA (PETROLEUM),HYDROTREATED HEAVY (2)PHOSPHORIC ACID ...%INGREDIENT COMMENTSWEL = Workplace Exposure LimitsPROTECTIVE EQUIPMENTStdWELWELLT - ppm LT - mg/m3 ST - ppm ST - mg/m3170 ppm 1000 mg/m31 mg/m32 mg/m3ENGINEERING MEASURESProvide adequate general and local exhaust ventilation.RESPIRATORY EQUIPMENTRespiratory protection must be used if air contamination exceeds acceptable level.HAND PROTECTIONNitrile.EYE PROTECTIONUse approved safety goggles or face shield.OTHER PROTECTIONWear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.HYGIENE MEASURESDO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and usingthe toilet. Wash promptly with soap & water if skin becomes contaminated. Promptly remove any clothing thatbecomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink orsmoke.2 / 5

REVISION DATE: 08/01/079 PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCECOLOURODOURSOLUBILITYLiquidWhiteSolvent.CtP Plate CleanerForms an emulsion with water.BOILING POINT (°C) > 100 @ 760 mm Hg RELATIVE DENSITY 0.90 g/ml @ 20°CVAPOUR PRESSURE 0.11 (excluding water pH-VALUE, CONC.1.5 - 2.0content) kPa @ 20°C SOLUTIONFLASH POINT (°C)36 CC (Closed cup).10 STABILITY AND REACTIVITYSTABILITYAvoid: Heat, sparks, flames. Stable under normal temperature conditions.CONDITIONS TO AVOIDAvoid contact with strong oxidisers. Avoid heat, flames and other sources of ignition.HAZARDOUS DECOMPOSITION PRODUCTSNot known.11 TOXICOLOGICAL INFORMATIONHEALTH WARNINGSINHALATION. May cause irritation to the respiratory system. Solvent vapours are hazardous and may causenausea, sickness and headaches. SKIN CONTACT. Acts as a defatting agent on skin. May cause cracking ofskin, and eczema. EYE CONTACT. Direct contact with the eye may cause irritation. INGESTION. May causediscomfort.12 ECOLOGICAL INFORMATIONECOTOXICITYVolatile Organic Content (%) is equal to 50 - 55MOBILITYSolubility in water: Forms an emulsion with waterBIOACCUMULATIONNo data available.DEGRADABILITYNo data available.ACUTE FISH TOXICITYNo data available.13 DISPOSAL CONSIDERATIONSDISPOSAL METHODSDispose of waste and residues in accordance with local authority requirements.WASTE CLASSRegulation 2000/532/EC - Chapter Heading: Waste from MFSU of fine chemicals and chemical products nototherwise specified - 070704. Description: Other organic solvents, washing liquids and mother liquors.14 TRANSPORT INFORMATION3 / 5

REVISION DATE: 08/01/07CtP Plate CleanerPROPER SHIPPING NAMEPetroleum Distillates N.O.S. (Refined Hydrocarbons)UN NO. ROAD1268UK ROAD PACK GR. IIIADR CLASS Class 3: Flammable ADR LABEL NO.3liquids.RID CLASS NO. 3UN NO. SEA1268IMDG CLASS3IMDG PACK GR.IIIEMSF-E , S-E15 REGULATORY INFORMATIONRISK PHRASESSAFETY PHRASESR10R66S37S51Flammable.Repeated exposure may cause skin dryness or cracking.Wear suitable gloves.Use only in well-ventilated areas.EU DIRECTIVESDangerous Substances Directive (67/548/EEC). Dangerous Preparations Directive (1999/45/EC). Safety DataSheets Directive (91/155/EEC) (As amended).STATUTORY INSTRUMENTSChemicals (Hazard Information and Packaging) Regulations. Control of Substances Hazardous to Health.APPROVED CODE OF PRACTICEClassification and Labelling of Substances and Preparations Dangerous for Supply.GUIDANCE NOTESWorkplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyoneHSG(108).16 OTHER INFORMATIONGENERAL INFORMATIONThe Flow Time of the product is >30 seconds in a 3mm ISO Cup according to ISO 2431. The product is exemptto R65 Labelling.REVISION COMMENTSUPDATESISSUED BYDay International Chemical Products DivisionREVISION DATE 08/01/07REV. NO./REPL. SDS 07/09/04GENERATEDSDS NO. 24 / 5

REVISION DATE: 08/01/07CtP Plate CleanerRISK PHRASES IN FULLR10Flammable.R22Harmful if swallowed.R34Causes burns.R36/37/38Irritating to eyes, respiratory system and skin.R41Risk of serious damage to eyes.R65Harmful: may cause lung damage if swallowed.R66Repeated exposure may cause skin dryness or cracking.DISCLAIMERThe information in this material Safety Data Sheet is based on the present state of our knowledge and on the current EC andNational Regulations. The information relates to the specific product designated and may not be valid if it is used incombination with other materials or process. Nothing herein is to be contrued as warranty, expessed or implied. It is always theresponsibility of the user to take the necessary steps in order to fulfil the demands laid down in the rules and legislation. Theproduct is for Industrial use only.5 / 5