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Corrosion behaviour of copper alloys in natural sea water and ...

Corrosion behaviour of copper alloys in natural sea water and ...

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A45 - <strong>natural</strong> <strong>sea</strong><strong>water</strong> + NH3 pollution (1700 ppm)at ambient temperature1,00E-02- A45 one month <strong>in</strong> circulat<strong>in</strong>g <strong>natural</strong> <strong>sea</strong><strong>water</strong>(reference)1,00E-03current density (A/cm²)1,00E-041,00E-051,00E-06- A45 one month <strong>in</strong> circulat<strong>in</strong>g <strong>natural</strong> <strong>sea</strong><strong>water</strong> then <strong>sea</strong><strong>water</strong>treated with NH3 (1700 ppm)45945545231,00E-07-A45 one month <strong>and</strong> 3 weeks <strong>in</strong> circulat<strong>in</strong>g <strong>sea</strong><strong>water</strong>then t<strong>sea</strong><strong>water</strong> teated with NH3 (1700ppm)1,00E-08-400 -300 -200 -100 0 100 200 300 400Scann<strong>in</strong>g rate 0.05 mV/sE (mV/SCE)Figure 9: A45 Anodic polarization curves after exposure to <strong>natural</strong> <strong>sea</strong> <strong>water</strong> <strong>and</strong> polluted<strong>sea</strong> <strong>water</strong> with ammonia1,00E-02CuAl9Ni3Fe2 - Natural <strong>sea</strong><strong>water</strong> + NH3 pollution (1700 ppm) at 20°C1,00E-03Natural <strong>sea</strong><strong>water</strong>1,00E-04current density (A/cm²)1,00E-051,00E-06C23C6C251,00E-07C23 <strong>in</strong> <strong>natural</strong> <strong>sea</strong><strong>water</strong> one month before NH3 treatment ( 1700 ppm)1,00E-08C25 <strong>in</strong> <strong>natural</strong> <strong>sea</strong><strong>water</strong> one month <strong>and</strong> a half beforeNH3 treatment ( 1700 ppm )1,00E-09-400 -300 -200 -100 0 100 200 300 400scann<strong>in</strong>g rate 0.05 mV/sE (m V/SCE)Figure 10: CuAl9Ni3Fe2Anodic polarization curves after exposure to <strong>natural</strong> <strong>sea</strong> <strong>water</strong> <strong>and</strong> polluted <strong>sea</strong> <strong>water</strong>with ammonia14

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