Solargard Acrylic Sealer MSDS - Republic Powdered Metals

Material Safety Data SheetSOLARGARD ACRYLIC SEALER 5 GALVersion 5.0 Print Date 03/07/2014REVISION DATE: 03/06/2014SECTION 1 - PRODUCT IDENTIFICATIONTrade name : SOLARGARD ACRYLIC SEALER 5 GALProduct code : 110005PCOMPANY : Republic Powdered Metals2628 Pearl RoadMedina, OH 44256Telephone : (800) 551-7081Emergency Phone: : 1-800-551-7081After Hours: Chemtrec 1-800-424-9300Product use : SealantSECTION 2 - HAZARDS IDENTIFICATIONEmergency OverviewWhite. Non-sag gunnable paste. May cause slight irritation to the respiratory system. Leave area to breathefresh air. Avoid further overexposure. If symptoms persist, get medical attention.Acute Potential Health Effects/ Routes of EntryInhalation : May cause slight irritation to the respiratory system.Eyes : Slightly irritating.Ingestion : May cause irritation to the mouth, throat and stomach.Skin : Irritant effect may be delayed.Aggravated Medical ConditionsPre-existing eye, skin and respiratory disorders may be aggravated by exposure.Chronic Health EffectsFillers are encapsulated and not expected to be released from product under normal conditions of use.SECTION 3 - PRODUCT COMPOSITIONChemical Name CAS-No. Weight %Calcium salt 7778-18-9 30.0 - 60.0Water 7732-18-5 30.0 - 60.0Ethyl Acrylate, 2-ethylhexylacrylate,acrylonitrile, acrylic acid, n-52640-81-0 15.0 - 40.0methylolacrylamide polymerTitanium dioxide 13463-67-7 5.0 - 10.0Acrylic polymer NJTSRN# 51721300-6487P 1.0 - 5.0Ammonium hydroxide 1336-21-6 0.1 - 1.01-(3-Chloroallyl)-3,5,7-triaza-1- 4080-31-3 0.1 - 1.01/6 110005P

Material Safety Data SheetSOLARGARD ACRYLIC SEALER 5 GALVersion 5.0 Print Date 03/07/2014REVISION DATE: 03/06/2014azoniaadamantane chlorideSECTION 4 - FIRST AID MEASURESGet immediate medical attention for any significant overexposure.Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, getmedical attention.Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.Skin contact : Wash with water. If irritation, rash or other disorders develop, get medical attentionimmediately.Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison ControlCenter or Physician immediately.SECTION 5 - FIRE FIGHTING MEASURESFlash point : Not available.Method : Not applicable.Lower explosion limit : Not available.Upper explosion limit : Not available.Autoignition temperature : Not available.Extinguishing media : This product is not expected to burn under normal conditions of use.Usethat which is appropriate to the surroundings.Hazardous combustionproductsProtective equipment forfirefighters: Smoke, fumes.: Not applicable. Product is not expected to burn.Fire and explosion conditions : This product not expected to ignite under normal conditions of use.SECTION 6 - ACCIDENTAL RELEASE MEASURESUse appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriatecontainer for disposal. Keep out of water courses.SECTION 7 - HANDLING AND STORAGEPrevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed whennot in use. Precautions also apply to emptied containers. Do not use in confined or poorly ventilated areas.Store in sealed containers in a dry, ventilated warehouse location above freezing.SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONPersonal protection equipment2/6 110005P

Material Safety Data SheetSOLARGARD ACRYLIC SEALER 5 GALVersion 5.0 Print Date 03/07/2014REVISION DATE: 03/06/2014Respiratory protection : Not required under normal conditions of use.Hand protection : Protect hands with impervious gloves.Eye protection : Use safety glasses if eye contact is likely.Protective measures : Use professional judgment in the selection, care, and use.Other equipmentnot normally required.Engineering measures : General ventilation is sufficient.Use local exhaust when the generalventilation is inadequate.Exposure LimitsChemical Name CAS Number Regulation Limit FormCalcium salt 7778-18-9 ACGIH TWA: 10 mg/m3OSHA PEL: 5 mg/m3 Respirable fraction.OSHA PEL: 15 mg/m3 Total dust.OSHA TWA: 15 mg/m3 Total dust.OSHA TWA: 5 mg/m3 Respirable fraction.ACGIH TWA: 10 mg/m3 Inhalable fraction.Titanium dioxide 13463-67-7 ACGIH TWA: 10 mg/m3OSHA PEL: 15 mg/m3 Total dust.OSHA TWA: 15 mg/m3 Total dust.OSHA TWA: 5 mg/m3 Respirable fraction.Ammonium hydroxide 1336-21-6 ACGIH TWA: 25 ppmACGIH STEL: 35 ppmOSHA PEL: 35 mg/m3SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIESForm: Non-sag gunnable pasteColor: WhiteOdor: AcrylatepH : 8 - 9Vapour pressure: Not available.Vapor density: Heavier than airMelting point/range: Not available.Freezing point: Not available.Boiling point/range: Not available.Water solubility: MiscibleSpecific Gravity : 1.3445% Volatile Weight : 34 %3/6 110005P

Material Safety Data SheetSOLARGARD ACRYLIC SEALER 5 GALVersion 5.0 Print Date 03/07/2014REVISION DATE: 03/06/2014SECTION 10 - REACTIVITY / STABILITYSubstances to avoid: Oxidizing agents.Strong acids.Strong bases.SECTION 11 - TOXICOLOGICAL INFORMATIONAmmonium hydroxide, CAS-No.: 1336-21-6Acute oral toxicity (LD-50 oral) 350 mg/kg ( Rat )1-(3-Chloroallyl)-3,5,7-triaza-1-azoniaadamantane chloride, CAS-No.: 4080-31-3Acute oral toxicity (LD-50 oral) 500 mg/kg ( Rat ) 78.5 mg/kg ( Rabbit )Acute dermal toxicity (LD-50 dermal) 565 mg/kg ( Rabbit )SECTION 12 - ECOLOGICAL INFORMATIONNo Data AvailableSECTION 13 - DISPOSAL CONSIDERATIONSDisposal Method : Waste not regulated under RCRA. Incinerate at EPA approved facility or dispose ofwaste in compliance with state and local regulations.SECTION 14 - TRANSPORTATION / SHIPPING DATACFR / DOT:Not RegulatedTDG:Not RegulatedIMDG:Not RegulatedSECTION 15 - REGULATORY INFORMATIONNorth American Inventories:All components are listed or exempt from the TSCA inventory.This product or its components are listed on, or exempt from the Canadian Domestic Substances List.4/6 110005P

Material Safety Data SheetSOLARGARD ACRYLIC SEALER 5 GALVersion 5.0 Print Date 03/07/2014REVISION DATE: 03/06/2014U.S. Federal Regulations:SARA 313 Components : None present or none present in regulated quantities.SARA 311/312 Hazards : Acute Health HazardOSHA Hazardous Components :Calcium salt 7778-18-9Titanium dioxide 13463-67-7Ammonium hydroxide 1336-21-61-(3-Chloroallyl)-3,5,7-triaza-1-4080-31-3azoniaadamantane chlorideOSHA Status: Consideredhazardous based on thefollowing criteria:: IrritantOSHA Flammability : Not RegulatedRegulatory VOC (less water andexempt solvent): 47 g/lVOC Method 310 : 1.96 %U.S. State Regulations:MASS RTK Components : Calcium salt 7778-18-9Titanium dioxide 13463-67-7Penn RTK Components : Calcium salt 7778-18-9Water 7732-18-5Ethyl Acrylate, 2-ethylhexylacrylate, 52640-81-0acrylonitrile, acrylic acid, n-methylolacrylamide polymerTitanium dioxide 13463-67-7NJ RTK Components : Calcium salt 7778-18-9Water 7732-18-5Ethyl Acrylate, 2-ethylhexylacrylate, 52640-81-0acrylonitrile, acrylic acid, n-methylolacrylamide polymerTitanium dioxide 13463-67-7Acrylic polymer NJTSRN# 51721300-6487PComponents under California Proposition 65:WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or otherreproductive harm5/6 110005P