material safety data sheet lubrimatic multi-purpose lithium grease

12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASEMATERIAL SAFETY DATA SHEETLUBRIMATIC MULTI-PURPOSE LITHIUM GREASE(11300-11302-11306-11315-11316-11328-11330-11332)1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONTRADE NAMELUBRIMATIC MULTI-PURPOSE LITHIUM GREASEPART No. 329050PRODUCT USESUPPLIEREMERGENCY TELEPHONELubricating GreaseChemtool IncorporatedP.O. Box 5388200 Ridgefield RoadCrystal Lake, IL 60039-0538 USATel: (815) 459-1250Fax: (815) 459-1955InfotracU.S. and Canada - (800) 535-5053Outside the U.S. and Canada - +01-352-323-35002. COMPOSITION, INFORMATION ON INGREDIENTSINGREDIENT NAME CAS No. WEIGHTLUBRICANT BASE OIL (PETROLEUM), HIGHLY REFINED**(2) Mixture 70-90 %*LITHIUM SOAP AND MIXED BASE THICKENERS Proprietary 5-15 %*PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS 68649-42-3

12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300)refined by a variety of processes including solvent extraction, solvent dewaxing andhydrotreating to remove aromatics and improve performance characteristics. None ofthe oils used are listed as a carcinogen by NTP, IARC, or OSHA.3. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEWHEALTH HAZARDS, GENERALSENSITIZATIONCARCINOGENICITYHEALTH WARNINGSROUTE OF ENTRYMEDICAL SYMPTOMSExposure to vapors generated at high temperatures may cause respiratory irritation.No known information.See Section 11 for carcinogenicity data of ingredients.INHALATION. Heating can generate vapors that may cause respiratory irritation,nausea and headaches. Inhalation hazard at room temperature is unlikely due to thelow volatility of this product. SKIN CONTACT. Repeated or prolonged contact canresult in drying of the skin. EYE CONTACT. Irritating. INGESTION. Can cause stomachache and vomiting. Main hazard, if ingested, is aspiration into the lungs andsubsequent pneumonitis.Inhalation. Skin and/or eye contact. Ingestion.MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not determined4. FIRST AID MEASURESINHALATIONEYESSKININGESTIONVapor inhalation under ambient conditions is normally not a problem. If overcome byvapor of hot product, immediately remove from source of exposure. Move the exposedperson to fresh air at once. For breathing difficulties oxygen may be necessary. Getmedical attention if any discomfort continues.Rinse the eye with water immediately. Continue to rinse for at least 15 minutes.Contact physician if discomfort continues.Remove contaminated clothing. Wash skin thoroughly with soap and water. Getmedical attention if any discomfort continues.DO NOT INDUCE VOMITING! Get medical attention immediately!5. FIRE FIGHTING MEASURESFLASH POINT (°C) 224 (435°F) Cd OC (Cleveland open cup).FLAMMABILITY LIMIT - LOWER(%)FLAMMABILITY LIMIT - UPPER(%)EXTINGUISHING MEDIASPECIAL FIRE FIGHTINGPROCEDURESN/DN/DUse: Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Alcohol resistantfoam. Water spray, fog or mist.Use water to keep fire exposed containers cool and disperse vapors. Water spraymay be used to flush spills away from exposures and dilute spills to non-flammablemixtures. Avoid water in straight hose stream; will scatter and spread fire. Keep run-offwater out of sewers and water sources. Dike for water control.2 /7

12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300)UNUSUAL FIRE & EXPLOSIONHAZARDSHAZARDOUS COMBUSTIONPRODUCTSPROTECTIVE MEASURES IN CASE OFFIREPressure will increase in over heated, closed containers.Oxides of: Carbon.Self-contained breathing equipment and chemical resistant clothing recommended.6. ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTIONSPRECAUTIONS TO PROTECT THEENVIRONMENTSPILL CLEAN-UP PROCEDURESMinimize skin contact.Keep product out of sewers and watercourses by diking or impounding. Adviseauthorities if product has entered or may enter sewers, watercourses or extensiveland areas. Assure conformity with applicable government regulations.Contain spill. Absorb small amounts. Collect and return large amounts to shippingcontainer. Rinse area with water.7. HANDLING AND STORAGEHANDLING PRECAUTIONSSTORAGE PRECAUTIONSSTORAGE CRITERIAVentilate well, avoid breathing vapors. Use approved respirator if air contamination isabove accepted level. Do not reuse container. Keep lid closed when not in use. Do notstore or mix with strong oxidizers. Avoid spilling, skin and eye contact. Eye wash andemergency shower must be available at the work place.Store separate from strong acids and oxidizers. Keep away from heat, sparks andopen flame.Chemical storage.8. EXPOSURE CONTROLS, PERSONAL PROTECTIONCOMPONENT STD TWA STEL TWALUBRICANT BASE OIL (PETROLEUM), HIGHLYREFINED**(2)CARBON BLACKANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN800983-5015P OR CAS# 15890-25-2)OSHAACGIHOSHAACGIHNIOSHOSHAACGIH3.5 mg/m3 **Ca5 mg/m3 (oil mist)5 mg/m3 (oil mist)3.5 mg/m33.5 mg/m30.5 mg/m3 as Sb0.5 mg/m3 as SbSTEL10 mg/m3 (oil mist)**A4INGREDIENT COMMENTSPROTECTIVE EQUIPMENT**ACGIH A4: Not Classifiable as a Human Carcinogen.**NIOSH Ca: Potential Occupational Carcinogen.3 /7

12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300)ENGINEERING CONTROLSVENTILATIONRESPIRATORSPROTECTIVE GLOVESEYE PROTECTIONPROTECTIVE CLOTHINGHYGIENIC WORK PRACTICESUse engineering controls to reduce air contamination to permissible exposure level.No specific ventilation requirements noted, but forced ventilation may still be requiredif air contamination exceeds acceptable level.No specific recommendation made, but respiratory protection may still be requiredunder exceptional circumstances when excessive air contamination exists.Chemical resistant gloves recommended to prevent prolonged or repeated contact.Wear splash-proof eye goggles to prevent any possibility of eye contact.Wear appropriate clothing to prevent repeated or prolonged skin contact.Wash at the end of each work shift and before eating, smoking and using the toilet.9. PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE/PHYSICAL STATECOLORODORSOLUBILITY DESCRIPTIONDENSITYGrease.Black.Mild (or faint). Petroleum.Insoluble in water.0.89 Temperature (°C) 15.6 (60°F)VAPOR DENSITY (air=1) > 5VAPOR PRESSUREEVAPORATION RATEpH-VALUE, CONC. SOLUTION< 0.1 mmHg Temperature (°C) 20 (68°F)< 0.01 Reference BuAc=1N/A10. STABILITY AND REACTIVITYSTABILITYCONDITIONS TO AVOIDHAZARDOUS POLYMERIZATIONPOLYMERIZATION DESCRIPTIONHAZARDOUS DECOMPOSITIONPRODUCTSNormally stable.Avoid contact with acids and oxidizing substances.Will not occur.Not applicableOxides of: Carbon.4 /7

12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300)11. TOXICOLOGICAL INFORMATIONTOXICOLOGICAL INFORMATIONCOMPONENTTOXICOLOGICAL DATATOXIC DOSE - LD 50TOXIC DOSE - LD 50 SKINTOXIC CONC. - LC 50COMPONENTTOXICOLOGICAL DATATOXIC DOSE - LD 50TOXIC DOSE - LD 50 SKINCARCINOGENICITYNo experimental toxicological data on the preparation as such is available.LUBRICANT BASE OIL (PETROLEUM), HIGHLY REFINED**(2)Carcinogenicity. IP 346 5000 mg/kg (oral rat)> 2000 mg/kg (skn rbt)N/A.CARBON BLACKCarcinogenicity. WHMIS (Canada) D2AAcute toxicity. TCLo 6 hours. Inhalation. Rat. 7 mg/m3> 15400 mg/kg (oral rat)> 3000 mg/kg (skn rbt)NTP: Not listed. MAK-3 designation: Substances which cause concern that theycould be carcinogenic for man. IARC-2B: The agent is possibly carcinogenic tohumans (limited evidence of carcinogenicity in humans).12. ECOLOGICAL INFORMATIONECOLOGICAL INFORMATIONThere is no ecological data on the product itself.13. DISPOSAL CONSIDERATIONSDISPOSAL METHODSSpilled material, unused contents and empty containers must be disposed of inaccordance with local, state and federal regulations.14. TRANSPORT INFORMATIONDOT HAZARD CLASSTDGR CLASSSEA TRANSPORT NOTESAIR TRANSPORT NOTESNot regulated.Not Regulated.Not regulated per IMDG.Not regulated per IATA.15. REGULATORY INFORMATIONUS FEDERAL REGULATIONS5 /7

12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300)COMPONENT SARA 302 CERCLA SARA 313LUBRICANT BASE OIL (PETROLEUM), HIGHLY REFINED**(2)LITHIUM SOAP AND MIXED BASE THICKENERSBENZENESULFONIC ACID, DODECYL-, CALCIUM SALTCARBON BLACKANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN 800983-5015P OR CAS#15890-25-2)PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTSNo No NoNo No NoNo 1 000 lbs NoNo No NoNo *** N010 - SbNo *** N982 - ZnREGULATORY STATUS*** Indicates that no RQ is assigned to this generic or broad class, although the classis a CERCLA hazardous substance. See 50 Federal Register 13456 (April 4, 1985).Values in Section 313 column represent Category Codes for reporting under Section313.CLEAN AIR ACTSARA HAZARD CATEGORIESNoneUS STATE REGULATIONSCOMPONENT CA MA FL MN NJ PA RILUBRICANT BASE OIL (PETROLEUM), HIGHLYYes YesREFINED**(2)PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYLYes Yes EHESTERS, ZINC SALTSBENZENESULFONIC ACID, DODECYL-, CALCIUMEHSALTCARBON BLACK C Yes Yes HSANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN800983-5015P OR CAS# 15890-25-2)Yes EHSTATE REGULATORY STATUSCALIFORNIA PROPOSITION 65: This product may contain the following chemical(s)considered by the State of California's Safe Drinking Water and Toxic Enforcement Actof 1986 as causing cancer or reproductive toxicity, and for which warnings are nowrequired:Carbon black (airborne, unbound particles of respirable size), cancer hazard, CAS#1333-86-4.PENNSYLVANIA RIGHT-TO-KNOW: This product contains the following chemicalsthat the state of Pennsylvania has identified as Special Hazardous Substances (SHS),Environmental Hazards (EH), or both (ESHS). The PA regulations require that theMSDS identify all SHS or EH chemicals by chemical name, common name, and CASNumber if they comprise 0.01% or more.Zinc compounds regulated under CERCLA and SARA 313, Environmental HazardAntimony compounds regulated under CERCLA and SARA 313, EnvironmentalHazardBenzenesulfonic acid, dodecyl-, sodium salt, Environmental Hazard, CAS#25155-30-0WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMISThis product has been classified in accordance with the hazard criteria of theControlled Products Regulations and the MSDS contains all the information requiredby the Controlled Products Regulations.6 /7

12271 - LUBRIMATIC MULTI-PURPOSE LITHIUM GREASE (11300)CONTROLLED PRODUCTCLASSIFICATIONNot a controlled product.GLOBAL INVENTORIESCOMPONENT CAN US EU AUS JAP KOR PHLP CHNBENZENESULFONIC ACID, DODECYL-, CALCIUM DSL Yes EINECS Yes Yes Yes Yes YesSALTCARBON BLACK DSL Yes EINECS Yes Yes Yes Yes YesANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN NPRI Yes EINECS Yes Yes Yes Yes Yes800983-5015P OR CAS# 15890-25-2)LUBRICANT BASE OIL (PETROLEUM), HIGHLY DSL Yes EINECS Yes Yes Yes Yes YesREFINED**(2)LITHIUM SOAP AND MIXED BASE THICKENERS DSL Yes EINECS No No No No NoPHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYLESTERS, ZINC SALTSNPRI Yes EINECS Yes Yes Yes Yes YesCANADA CEPA: All components of this product comply with new substancenotification requirements under the Canadian Environmental Protection Act (CEPA).16. OTHER INFORMATIONNFPA-HMIS HAZARD RATINGHEALTHFLAMMABILITYREACTIVITYPERSONAL PROTECTION INDEXREVISION COMMENTSPREPARED BYIrritation, minor residual injury (1) - HMIS/NFPABurns only if pre-heated (1) - HMIS/NFPANormally Stable (0) - HMIS/NFPAB - Safety Eyewear and GlovesSection 2: IngredientsSection 8: Exposure Limits.Section 11: Toxicological InformationSection 15: WHMISJohn DingessJames W. HermannReplacement MSDS of 2003-09-03DATE 2005-10-28PRINTING DATE: 2006-01-03DISCLAIMER* Information revised since previous MSDS versionWhile the information and recommendations set forth herein are believed to beaccurate as of the date thereof, the company makes no warranty with respect theretoand disclaims all liability from reliance therein.7 /7