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SAFETY DATA SHEET SIGMADUR 520/550 HARDENER - Promain

SAFETY DATA SHEET SIGMADUR 520/550 HARDENER - Promain

SAFETY

SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.SIGMADUR 520/550 HARDENERMSDS UK 01 / EN Version 1.3 Print Date 3/30/2007Revision date 17-03-07Acute Toxicity Data for Componentshexamethylene diisocyanate(822-06-0)Acute oral toxicity : LD50: 746 mg/kg (rat)Acute inhalation toxicity : LC50: 0.15 mg/l (rat, 4 h)Acute dermal toxicity : LD50: 599 mg/kg (rabbit, )12. ECOLOGICAL INFORMATIONFurther information : The preparation has been assessed following the conventional method of theDangerous Preparations Directive 1999/45/EC and is not classified asdangerous for the environment. See section 2 for details on components.13. DISPOSAL CONSIDERATIONSProduct : The product should not be allowed to enter drains, water courses or the soil.Disposal together with normal waste is not allowed. Special disposal requiredaccording to local regulations.Waste key for the unusedproduct: The European Waste Catalogue classification of this product, when disposedof as waste is:08 05 01 Waste isocyanates.If this product is fully cured or mixed with other wastes, this code may nolonger apply. If mixed with other wastes, the appropriate code should beassigned. For further information contact your local waste authority14. TRANSPORT INFORMATIONTransport within user's premises: always transport in closed containers that are upright, labelled and secure. Ensure thatpersons transporting the product know what to do in the event of an accident or spillage.Transport to be in accordance with ADR for road, IMDG for sea and IATA for air transport:UN-No : 1263Proper shipping name : PAINT RELATED MATERIALClass : 3Packing group : IIILabel : 3Proper shipping name (ADR) : PAINT RELATED MATERIALMarine Pollutant (IMDG)(P,PP,-) : -EmS (IMDG) : F-E, S-ELimited quantity (ADR) : Max. per inner pack. : 5.00 LMax. per outer pack. : 30.00 KGLimited quantity (IMDG) : Max. per inner pack. : 5.00 LMax. per outer pack. : 30.00 KG6/8

SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.SIGMADUR 520/550 HARDENERMSDS UK 01 / EN Version 1.3 Print Date 3/30/2007Revision date 17-03-0715. REGULATORY INFORMATIONThe product is classified and labelled in accordance with Directive 1999/45/EC.HarmfulHazardous components which must be listed on the label:• isocyanic acid, hexamethylene ester, polymersR-phrase(s) : R10 Flammable.R20Harmful by inhalation.R43May cause sensitization by skin contact.S-phrase(s) : S23 Do not breathe spray.S36/37 Wear suitable protective clothing and gloves.S38In case of insufficient ventilation, wear suitablerespiratory equipment.P-phrase(s) : Contains isocyanates. See information supplied by themanufacturer.The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks, asrequired by other health and safety legislation. The provisions of the national health and safety at work regulationsapply to the use of this product at work.National legislationFurther information : HS (G) 178, Spraying of Flammable Liquids, HSE., HS (G) 176, Storage ofFlammable Liquids in Tanks, HSE., HS (G) 51, Storage of Flammable Liquidin Containers, HSE., HS (G) 37, An introduction to Local ExhaustVentilation, HSE., Health and Safety at Work etc Act, 1974, and relevantStatutory Provisions., Environmental Protection Act, 1990 and associatedlegislation., The Special Waste Regulations, 1996 and amendments., TheChemicals (Hazard Information and Packaging for Supply) Regulations, 1994and amendments., EH 40, Occupational Exposure Limits, HSE. Revisedannually., HS(G) 53, Respiratory Protective Equipment - A Practical Guidefor Users, HSE., HS(G) 97, A Step by Step guide to COSHH Regulations,HSE., EH 173, Monitoring Strategies for Toxic Substances, HSE., EH 16,Isocyantes: toxic hazards and precautions, HSE.16. OTHER INFORMATIONExplanation of R-phrases mentioned in section 27/8

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