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BP201 - Awlgrip

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CAS No. Ingredient Name & % Source Exposure Data000100-41-4Ethyl benzene1.0 - 10% by WeightOSHA:100 ppm TWA; 435 mg/m3 TWA125 ppm STEL; 545 mg/m3 STELACGIH: 100 ppm TWA125 ppm STELNIOSH:100 ppm TWA; 435 mg/m3 TWA125 ppm STEL; 545 mg/m3STEL800 ppm IDLHSupplier: No Data Available100 ppm TWAEV; 435 mg/m3 TWAEV125 ppm STEV; 540 mg/m3OHSA, CAN:STEVMexico: 100 ppm TWA; 435 mg/m3 TWA125 ppm STEL; 545 mg/m3 STELBrazil: 78 ppm TWA; 340 mg/m3 TWASourceHealth DataNIOSH: Eye skinSourceOSHA:Select Carcinogen: NoCarcinogen DataNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: Yes; Group 3: No; Group 4: NoCAS No. Ingredient Name & % Source Exposure DataOSHA:No Data AvailableACGIH:No Data AvailableNIOSH:No Data AvailableSupplier:No Data AvailableOHSA, CAN: No Data Available001077-56-1Benzenesulfonamide, N-ethyl-2-methyl-1.0 - 10% by WeightMexico:Brazil:SourceNo Data AvailableNo Data AvailableHealth DataNIOSH:No Data AvailableSourceCarcinogen DataOSHA:Select Carcinogen: NoNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: No; Group 3: No; Group 4: NoCAS No. Ingredient Name & % Source Exposure DataOSHA:5 mg/m3 TWA (fume); 15 mg/m3 TWA (total dust); 5 mg/m3 TWA(respirable fraction)10 mg/m3 STEL (fume)ACGIH:2 mg/m3 TWA (respirable fraction)10 mg/m3 STEL (respirablefraction)NIOSH:5 mg/m3 TWA (dust and fume)10 mg/m3 STEL (fume)15 mg/m3Ceiling (dust)500 mg/m3 IDLHSupplier: No Data Available5 mg/m3 TWAEV (fume); 10 mg/m3 TWAEV (dust)10 mg/m3 STEVOHSA, CAN:(fume)001314-13-25 mg/m3 TWA (fume); 10 mg/m3 TWA (dust)10 mg/m3 STELZinc oxideMexico:(fume)1.0 - 10% by WeightBrazil: No Data AvailableSourceHealth DataNIOSH: Metal fume feverPage2 of 9


NIOSH:SourceOSHA:Metal fume feverSelect Carcinogen: NoCarcinogen DataNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: No; Group 3: No; Group 4: NoCAS No. Ingredient Name & % Source Exposure Data001317-39-1Copper(+1) oxide25 - 50% by WeightOSHA: No Data AvailableACGIH: No Data AvailableNIOSH: 1 mg/m3 TWA (as Cu)100 mg/m3 IDLH (dusts and mists, as Cu)Supplier: No Data AvailableOHSA, CAN: No Data AvailableMexico: No Data AvailableBrazil: No Data AvailableSourceHealth DataNIOSH: No Data AvailableSourceCarcinogen DataOSHA: Select Carcinogen: NoNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: No; Group 3: No; Group 4: NoCAS No. Ingredient Name & % Source Exposure Data001330-20-7Xylenes (o-, m-, p- isomers)10 - 25% by WeightOSHA:100 ppm TWA; 435 mg/m3 TWA150 ppm STEL; 655 mg/m3 STELACGIH: 100 ppm TWA150 ppm STELNIOSH: No Data AvailableSupplier: No Data Available100 ppm TWAEV; 435 mg/m3 TWAEV150 ppm STEV; 650 mg/m3OHSA, CAN:STEVMexico: 100 ppm TWA; 435 mg/m3 TWA150 ppm STEL; 655 mg/m3 STELBrazil: 78 ppm TWA; 340 mg/m3 TWASourceHealth DataNIOSH: Central nervous system depressant; respiratory and eye irritationSourceOSHA:Select Carcinogen: NoCarcinogen DataNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: No; Group 3: Yes; Group 4: NoCAS No. Ingredient Name & % Source Exposure DataPage3 of 9


001333-86-4Carbon black1.0 - 10% by WeightOSHA:3.5 mg/m3 TWAACGIH: 3.5 mg/m3 TWANIOSH:3.5 mg/m3 TWA; 0.1 mg/m3 TWA (as PAH, carbon black inpresence of polycyclic aromatic hydrocarb1750 mg/m3 IDLHSupplier: No Data AvailableOHSA, CAN: 3.5 mg/m3 TWAEVMexico: 3.5 mg/m3 TWA7 mg/m3 STELBrazil: No Data AvailableSourceHealth DataNIOSH: Lung cardiovascularSourceOSHA:Select Carcinogen: NoCarcinogen DataNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: Yes; Group 3: No; Group 4: NoCAS No. Ingredient Name & % Source Exposure DataOSHA:No Data AvailableACGIH:No Data AvailableNIOSH:No Data AvailableSupplier:No Data AvailableOHSA, CAN: No Data AvailableMexico:No Data Available008050-09-7Rosin1.0 - 10% by WeightBrazil:SourceNo Data AvailableHealth DataNIOSH:No Data AvailableSourceCarcinogen DataOSHA:Select Carcinogen: NoNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: No; Group 3: No; Group 4: NoCAS No. Ingredient Name & % Source Exposure DataOSHA:No Data AvailableACGIH:No Data AvailableNIOSH:No Data AvailableSupplier:No Data AvailableOHSA, CAN: No Data Available064742-95-6Petroleum naphtha, lightaromatic1.0 - 10% by WeightMexico:Brazil:SourceNo Data AvailableNo Data AvailableHealth DataNIOSH:No Data AvailableSourceCarcinogen DataOSHA:Select Carcinogen: NoNTP:IARCKnown Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Page4 of 9


IARC:Group 2b: No; Group 3: No; Group 4: NoCAS No. Ingredient Name & % Source Exposure Data065997-17-3Glass, oxide, chemicals1.0 - 10% by WeightOSHA:2 mg/m3 TWA (as Sn)ACGIH: 2 mg/m3 TWA (as Sn, except tin hydride)NIOSH:2 mg/m3 TWA (as Sn, except oxides)100 mg/m3 IDLH (as Sn,except oxides)Supplier: No Data AvailableOHSA, CAN: 2 mg/m3 TWAEV (except stannane, as Sn)Mexico: 2 mg/m3 TWA4 mg/m3 STEL (as Sn)Brazil: No Data AvailableSourceHealth DataNIOSH: No Data AvailableSourceOSHA:Select Carcinogen: NoCarcinogen DataNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: Yes; Group 3: No; Group 4: NoCAS No. Ingredient Name & % Source Exposure DataOSHA:No Data AvailableACGIH:No Data AvailableNIOSH:No Data AvailableSupplier:No Data AvailableOHSA, CAN: No Data AvailableMexico:No Data AvailableTS-RV0611Polymer1.0 - 10% by WeightBrazil:SourceNo Data AvailableHealth DataNIOSH:No Data AvailableSourceCarcinogen DataOSHA:Select Carcinogen: NoNTP:IARC:Known Carcinogen: No; Suspected Carcinogen: NoGroup 1: No; Group 2A: No;Group 2b: No; Group 3: No; Group 4: NoOverview:Inhalation:Eyes:Skin:Ingestion:Chronic Effects:3. HAZARD IDENTIFICATIONNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanentbrain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents maybe harmful or fatal. Avoid contact with eyes, skin and clothing. Contains 1,2,4-Trimethylbenzene which can causecentral nervous system depression, anemia and bronchitis.May be harmful or fatal if inhaled. Causes nose and throat irritation. Vapors may affect the brain or nervous systemcausing dizziness, headache or nausea.Causes severe eye irritation. Do not get in eyes.Causes skin irritation. May be harmful if absorbed through the skin.Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness.Contains an ingredient which can cause organ damage (See Section 2 and Section 15 for each ingredient).Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 2 andSection 15 for each ingredient). Risk of cancer depends on duration and level of exposure.Page5 of 9


HMIS Rating: Health: Unknown Flammability: Unknown Reactivity: UnknownGeneral:Inhalation:Eyes:Skin:Ingestion:4. FIRST AID MEASURESRemove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse.Thoroughly clean or destroy contaminated shoes.If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Getmedical attention immediately.In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attentionimmediately.In case of contact, immediately flush skin with soap and plenty of water. Get medical attention immediately.If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting unlessinstructed to do so by medical personnel. Never give anything by mouth to an unconscious person.5. PROTECTIVE EQUIPMENT AND CONTROL MEASURESSelect equipment to provide protection from the ingredients listed in Section 2 of this document. Ensure fresh airentry during application and drying. If you experience eye watering, headache or dizziness or if air monitoringdemonstrates dust, vapor, or mist levels are above applicable limits, wear an appropriate, properly fitted respirator(NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. FORRespiratory:USERS OF 3M RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational healthand safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243-4630, in Canada call 1-800-267-4414. Please do not contact these numbers regarding other manufacturer's respiratory protection products. 3Mdoes not endorse the accuracy of the information contained in this Material Safety Data Sheet.Do not get in eyes. Protective equipment should be selected to provide protection from exposure to the chemicalslisted in Section 2 of this document. Depending on the site-specific conditions of use, safety glasses, chemicalEyes:goggles, and/or head and face protection may be required to prevent contact. The equipment must be thoroughlycleaned, or discarded after each use.Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 2of this document. Depending on the site-specific conditions of use, protective gloves, apron, boots, head and faceSkin/Hand:protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded aftereach use.Engineering Controls:Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation.Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potentialexposure. Use good personal hygiene practices. Wash hands before eating, drinking, using toilet facilities, etc.Other Work Practices:Promptly remove soiled clothing and wash clothing thoroughly before reuse. Shower after work using plenty ofsoap and water.Flash Point: F: 80C: 276. FIRE AND EXPLOSION INFORMATIONLower Explosive Limit (LEL):Fire and Explosion Hazards:Fire Fighting Procedures:.6 (%vol in air) at Normal Atmospheric Temp and PressureFlammable liquid and vapor. FLAMMABLE/COMBUSTIBLE MATERIALS: Will be easily ignited by heat,sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignitionand flash back. Most vapors are heavier than air. They will spread along ground and collect in low orconfined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers maycreate fire or explosion hazard. Containers may explode when heated.Also Reference Emergency Response Guide Number: Not Determined7. PHYSICAL AND CHEMICAL PROPERTIESPhysical State:pH:LiquidNot DeterminedSpecific Gravity: 1.746197Boiling Point (F):115 ERROR!!!Page6 of 9


Vapor Density:VOC Content (lbs):Evaporation Rate:Heavier than airRefer to the Technical Data Sheet for this product.Slower than ether8. STABILITY AND REACTIVITY DATAGeneral:Incompatible Materials:HazardousDecompostion:This product is stable and hazardous polymerization will not occur.Strong oxidizing agents.May produce hazardous fumes when heated to decomposition as in welding. Fumes may produce CarbonDioxide and Carbon Monoxide.9. HANDLING AND STORAGEStorage Temperature:Handling and StoragePrecautions:Store between 32 and 120 FKeep away from heat, sparks and flame. Do not smoke. Extinguish all flames and pilot lights, and turn offstoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Vaporsmay cause flash fire or ignite explosively. Prevent build-up of vapors by opening all windows and doors toachieve cross-ventilation. Do not get in eyes, on skin or clothing. Close container after each use. Washthoroughly after handling.General:10. TOXICOLOGICAL DATANOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents withpermanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhalingthe contents may be harmful or fatal. No additional information provided for this product. See Section 2 forchemical specific data.11. ECOLOGICAL DATAGeneral:No additional information provided for this product. See Section 2 for chemical specific data.Spill ResponseProcedures:Public Safety:12. ACCIDENTAL RELEASE MEASURESELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in immediate area). Use onlynon-sparking equipment to handle spilled material and absorbent. Do not touch or walk through spilledmaterial. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confinedareas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, orother non-combustible material and transfer to containers. Use non-sparking tools to collect absorbedmaterial.CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or leak area immediately for atleast 25 to 50 meters (80 to 160 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keepout of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider initial downwindevacuation for at least 300 meters (1000 feet).Also, Reference Emergency Response Guide Number: Not DeterminedWaste Disposal:13. DISPOSAL CONSIDERATIONDispose of in accordance with local, state and federal regulations. (Also reference RCRA information inSection 15 if listed).Page7 of 9


DOT (Domestic Surface Transportation)DOT Proper Shipping Name:CONSUMER COMMODITY, ORM-D14. TRANSPORTATION INFORMATIONIMO / IMDG (Ocean Transportation)IMDG Proper Shipping Name:CONSUMER COMMODITY, ORM-DDOT Hazard Class: NR IMDG Hazard Class: Not RegulatedUN / NA Number: Not Regulated UN Number: Not RegulatedDOT Packing Group: Not Regulated IMDG Packing Group: Not RegulatedCERCLA/DOT RQ:50 gal. / 734 lbs.System ReferenceCode:5Regulatory Overview:WHMIS Classification:Regulatory ListDOT Marine Pollutants (10%):(No Product Ingredients Listed)DOT Severe Marine Pollutants (1%):(No Product Ingredients Listed)EPCRA 311/312 Chemicals and RQs(>.1%) :007440-50-815. REGULATORY INFORMATIONThe regulatory data in Section 15 is not intended to be all-inclusive, only selected regulationsare represented. All ingredients of this product are listed on the TSCA (Toxic SubstanceControl Act) Inventory or are not required to be listed on the TSCA Inventory.Note: Any chemical ingredients listed in Section 15, that do not also appear in Section 2, arecontained in the product at a concentration below the applicable OSHA threshold level of 1%or 0.1%.Not DeterminedProduct Ingredients on ListCopper : 5000 lb final RQ (no reporting of releases of this hazardous substance is required ifthe diame000100-41-4 Ethyl benzene : 1000 lb final RQ; 454 kg final RQ001330-20-7 Xylenes (o-, m-, p- isomers) : 100 lb final RQ; 45.4 kg final RQEPCRA 302 Extremely Hazardous (>.1%):(No Product Ingredients Listed)EPCRA 313 Toxic Chemicals (>.1%) :007440-50-8 Copper001317-38-0 Copper oxide001317-39-1 Copper(+1) oxide000100-41-4 Ethyl benzene065997-17-3 Glass, oxide, chemicals000095-63-6 Pseudocumene001330-20-7 Xylenes (o-, m-, p- isomers)001314-13-2 Zinc oxideMass RTK Substances (>1%) :001333-86-4 Carbon black000100-41-4 Ethyl benzene000095-63-6 Pseudocumene001330-20-7 Xylenes (o-, m-, p- isomers)001314-13-2 Zinc oxideMass Extraordinarily Haz Sub (>.01%) :014808-60-7 QuartzPenn RTK Substances (>1%) :001333-86-4 Carbon black000100-41-4 Ethyl benzene000095-63-6 Pseudocumene001330-20-7 Xylenes (o-, m-, p- isomers)001314-13-2 Zinc oxidePenn Special Hazardous Substances(>.01%) :001333-86-4 Carbon blackRhode Island Hazardous Substances(>.1%) :Page8 of 9


001333-86-4 Carbon black007440-50-8 Copper000100-41-4 Ethyl benzene001330-20-7 Xylenes (o-, m-, p- isomers)001314-13-2 Zinc oxideRCRA Status (>.01%) :(No Product Ingredients Listed)N.J. RTK Substances (>1%) :001333-86-4 Carbon black000100-41-4 Ethyl benzene000095-63-6 Pseudocumene001330-20-7 Xylenes (o-, m-, p- isomers)001314-13-2 Zinc oxideN.J. Special Hazardous Substances(>.01%) :000100-41-4 Ethyl benzene001330-20-7 Xylenes (o-, m-, p- isomers)N.J. Env. Hazardous Substances (>.1%) :007440-50-8 Copper001317-38-0 Copper oxide001317-39-1 Copper(+1) oxide000100-41-4 Ethyl benzene065997-17-3 Glass, oxide, chemicals000095-63-6 Pseudocumene001330-20-7 Xylenes (o-, m-, p- isomers)001314-13-2 Zinc oxideProposition 65 - Carcinogens (>0%):007440-43-9 Cadmium001333-86-4 Carbon black007439-92-1 Lead014808-60-7 QuartzProposition 65 - Female Repro Toxins(>0%):007439-92-1 LeadProposition 65 - Male Repro Toxins(>0%):007440-43-9 Cadmium007439-92-1 LeadProposition 65 - Developmental Toxins(>0%):007440-43-9 Cadmium007439-92-1 Lead16. OTHER INFORMATIONThe information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warrantyof any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim allliability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with allapplicable health and safety laws, regulations, and orders.End Of DocumentPage9 of 9

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