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msds sigmaguard csf 575 base - SIGMA PAINTS

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SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.<strong>SIGMA</strong>GUARD CSF <strong>575</strong> (<strong>SIGMA</strong>GUARD CSF 75) BASEMSDS EU 01 / EN Version 1 Print Date 3/27/2007Revision date 16-03-07Advice on protection againstfire and explosion: Prevent the creation of flammable or explosive concentrations of vapour inair and avoid vapour concentration higher than the occupational exposurelimits. When transferring from one container to another apply earthingmeasures and use conductive hose material. No sparking tools should beused. Take necessary action to avoid static electricity discharge (which mightcause ignition of organic vapours). The product should only be used in areasfrom which all naked lights and other sources of ignition have been excluded.No smoking. The accumulation of contaminated rags and dry overspray,particularly in spray booth filters, may result in spontaneous combustion.Good housekeeping standards, regular safe removal of waste materials andregular maintenance of spray booth filters will minimise the risks ofspontaneous combustion and other fire hazards.StorageRequirements for storage areasand containers: Observe label precautions. Prevent unauthorized access. Containers whichare opened must be carefully resealed and kept upright to prevent leakage.Store between 5 and 25°C (41 - 77 F) in a dry, well ventilated place awayfrom sources of heat, ignition and direct sunlight. Solvent vapours are heavierthan air and may spread along floors. Vapours may form explosive mixtureswith air. Electrical installations / working materials must comply with thetechnological safety standards. Keep away from sources of ignition - Nosmoking. Store in accordance with the particular national regulations (seesection 15).Advice on common storage : Keep away from oxidising agents and strongly acid or alkaline materials.8. EXPOSURE CONTROLS / PERSONAL PROTECTIONTO REACH 10 % LEL : not applicableComponents on the national list and/or the European TLV list (98/24/EC):Components CAS-No. Value[mg/m 3 ]Value[ppm]BasisPersonal protective equipmentGeneral adviceRespiratory protection : When operators, whether spraying or not, have to work inside the spraybooth, ventilation is unlikly to be sufficient to control particulates and solventvapour in all cases. In such circumstances they should wear a compressed airfedrespirator during the spraying process and until such time as theparticulates and solvent vapour concentration has fallen below the exposurelimits.3/7


SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.<strong>SIGMA</strong>GUARD CSF <strong>575</strong> (<strong>SIGMA</strong>GUARD CSF 75) BASEMSDS EU 01 / EN Version 1 Print Date 3/27/2007Revision date 16-03-07Hand protection : For prolonged or repeated contact use protective gloves.Barrier creams may help to protect the exposed areas of skin, they shouldhowever not be applied once exposure has occurred.Skin should be washed after contact.Use chemical resistant gloves classified under Standard EN 374: Protectivegloves against chemicals and micro-organisms.Recommended gloves: butyl-rubberMinimum breakthrough time: 480 minWhen prolonged or frequently repeated contact may occur, a glove with aprotection class of 6 (breakthrough time greater than 480 minutes accordingto EN 374) is recommended. When only brief contact is expected, a glovewith a protection class of 2 or higher (breakthrough time greater than 30minutes according to EN 374) is recommended.NOTICE: The selection of a specific glove for a particular application andduration of use in a workplace should also take into account all relevantworkplace factors such as, but not limited to: Other chemicals which may behandled, physicalrequirements (cut/puncture protection, dexterity, thermalprotection), potential body reactions toglovematerials, as wellas theinstructions/specifications provided by the glove supplier.Eye protection : Chemical resistant goggles must be worn.Skin and body protection : Personnel should wear protective clothing. Skin should be washed aftercontact. Working clothes must not consist of textiles, which show adangerous melting behaviour in case of fire. Workers should wear antistaticfootwear.Additional adviceEnvironmental protection : Refer to national regulations in chapter 15 for regulations on environmentalprotection.Personal protectionProtective equipment : Eye protection and safety glovesPlease contact your personal protection equipment supplier for further advice9. PHYSICAL AND CHEMICAL PROPERTIESForm : viscousColour : variousOdour : characteristicFlash point :Note: not applicableAutoignition temperature :Note: not applicableUpper explosion limit :Note: not applicableLower explosion limit :Note: not applicableDensity : 1.4 g/cm3at 20 °CWater solubility : immisciblepH :Viscosity, dynamic : 7,500 mPa.s at 23 °CFlow time : >= 60 sTransversal section: 6 mmMethod: ISO 2431 (EN 535) 6 mm CUP4/7


SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.<strong>SIGMA</strong>GUARD CSF <strong>575</strong> (<strong>SIGMA</strong>GUARD CSF 75) BASEMSDS EU 01 / EN Version 1 Print Date 3/27/2007Revision date 16-03-0710. STABILITY AND REACTIVITYConditions to avoid : Avoid temperatures above 60°C (140 F), direct sunlight and contact withsources of heat.Hazardous reactions : Keep away from oxidising agents, strongly alkaline and strongly acidmaterials in order to avoid exothermic reactions.Hazardous decompositionproducts: In case of fire hazardous decomposition products may be produced such as:Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx),dense black smoke.11. TOXICOLOGICAL INFORMATIONAcute oral toxicity : May cause nausea, abdominal spasms and irritation of the mucousmembranes.Acute inhalation toxicity : Exposure to component solvent vapours concentration in excess of the statedoccupational exposure limit may result in adverse health effects. Such as:mucous membrane irritation, respiratory system irritation, adverse effects onkidney, liver and central nervous system. Symptoms and signs: headache,dizziness, fatigue, muscular weakness, drowsiness and in extreme cases lossof consciousness.Skin irritation : Repeated or prolonged contact with the preparation may cause removal ofnatural fat from the skin resulting in desiccation of the skin. The product maybe absorbed through the skin. Repeated skin contact may lead to irritationand to senitization, possible with cross-sensitization to other epoxies.Eye contact : Irritating to eyes.Further information : Based on the properties of epoxy constituent(s) and considering toxicologicaldata on similar preparations, this preparation may be a skin sensitiser and asevere irritant. It contains epoxy <strong>base</strong>d reactive diluents wich are moderate toseverely irritating to eyes, mucous membrane and skin and are strongsensitisers. Repeated skin contact may lead to irritation and to hypersensitivity,possible with cross-sensitisation to other epoxies. Single oralexposure to doses of epoxy <strong>base</strong>d reactive diluents at or close to the lethaldose has been shown to cause transient neurotoxic effects in animals.Prolonged exposure to high concentration may cause adverse effects in targetorgans such as liver and kidney.Acute Toxicity Data for Components12. ECOLOGICAL INFORMATIONFurther information : The preparation has been assessed following the conventional method of theDangerous Preparations Directive 1999/45/EC and is classified forecotoxicological properties accordingly. See sections 2 and 15 for details.13. DISPOSAL CONSIDERATIONSProduct : The product should not be allowed to enter drains, water courses or the soil.Disposal together with normal waste is not allowed. Special disposal requiredaccording to local regulations.5/7


SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.<strong>SIGMA</strong>GUARD CSF <strong>575</strong> (<strong>SIGMA</strong>GUARD CSF 75) BASEMSDS EU 01 / EN Version 1 Print Date 3/27/2007Revision date 16-03-07Waste key for the unusedproduct: The European Waste Catalogue classification of this product, when disposedof as waste is:08 01 11 Waste paint and varnish containing organic solvents or otherdangerous substances.If this product is fully cured or mixed with other wastes, this code may nolonger apply. If mixed with other wastes, the appropriate code should beassigned. For further information contact your local waste authority14. TRANSPORT INFORMATIONTransport within user's premises: always transport in closed containers that are upright, labelled and secure. Ensure thatpersons transporting the product know what to do in the event of an accident or spillage.Transport to be in accordance with ADR for road, IMDG for sea and IATA for air transport:UN-No : 3082Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.Class : 9Packing group : IIILabel : 9Proper shipping name (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.Technical name 1 : epoxy resin (Mw


SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.<strong>SIGMA</strong>GUARD CSF <strong>575</strong> (<strong>SIGMA</strong>GUARD CSF 75) BASEMSDS EU 01 / EN Version 1 Print Date 3/27/2007Revision date 16-03-07S-phrase(s) : S23 Do not breathe spray.S36/37 Wear suitable protective clothing and gloves.S38In case of insufficient ventilation, wear suitablerespiratory equipment.S61Avoid release to the environment. Refer to specialinstructions/safety data sheets.P-phrase(s) : Contains epoxy constituents. See informationsupplied by the manufacturer.The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks, asrequired by other health and safety legislation. The provisions of the national health and safety at work regulationsapply to the use of this product at work.National legislation16. OTHER INFORMATIONExplanation of R-phrases mentioned in section 22,3-Epoxypropyl neodecanoate R43 May cause sensitization by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.epoxy resin (MW

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