272856-Cropcare-Alliance-20L-MSDS - Agsure

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Material Safety Data SheetCS: 1.4.93Page: 2of6Infosafe No 3NU76 Issue Date : June 2010 ISSUED by CRPCAREProduct Name ALLIANCE® HerbicideSkinEyeFirst Aid FacilitiesAdvice to DoctorFirst AidClassified as hazardous(Aust). Make every effort to prevent vomit from entering the lungs by carefulplacement of the patient.The above first aid instructions are mandated by the Commonwealth Departmentof Health and Ageing via the National Drugs and Poisons Schedule. Theseinstructions are suitable for ingestion of spray solution and small amounts ofconcentrate; however, if SUBSTANTIAL AMOUNTS of the concentrate have beenswallowed (more than about about 5ml) AND if medical assistance is more than30 minutes away, the induction of vomiting should be CONSIDERED, preferablybased on MEDICAL ADVICE if a physician can be contacted by phone. All caremust be taken to prevent vomit from being inhaled. Do not give anything bymouth to a semi-conscious or unconscious person.Immediately transfer patient to nearest hospital or medical centre, warning bytelephone of the estimated time of arrival so that the start of treatment isnot delayed.Contact of the concentrate with abraded skin or skin with cuts must beavoided.Wash affected areas thoroughly with soap and water.Remove contaminated clothing and launder before re-use.Seek medical advice, but only after the exposed skin has been thoroughlywashed.If in eyes, hold eyelids open and wash with copious amounts of water for atleast 15 minutes.Seek medical advice immediately.If poisoning occurs, contact a doctor or the Poisons Information Centre(Australia) on 13 11 26.Rapid treatment for Paraquat poisoning is essential.Evacuation of the stomach and stomach washout should be carried out as quicklyas possible.A booklet entitled 'Paraquat Poisoning, a practical guide to diagnosis, firstaid and hospital treatment' (prepared by Syngenta) or 'The Treatment ofParaquat Poisoning: a guide for doctors' (prepared by ORICA Australia) isavailable at major hospitals or Poisons Information Centres, or contact theemergency number at the end of this <strong>MSDS</strong>.TREATMENT: Wash out stomach and test urine and gastric aspirate (if clear)for presence of paraquat. Give up to 1 litre of 15% aqueous suspension ofFuller's Earth orally or via gastric tube, together with a suitable purgative(200ml of an aqueous solution of mannitol). A 7% suspension of bentonite in10% glycerol in water should be used if Fuller's Earth is unavailable. Repeatadministration of absorbent plus purgative until absorbent is seen in thestools. This should normally take between 4 and 6 hours after the start oftreatment. Do not use supplemental oxygen.OBTAIN IMMEDIATE MEDICAL ATTENTION.SPEED IS ESSENTIAL.5. FIRE FIGHTING MEASURESSuitableIf involved in a fire, the product will not burn. Choose extinguishing mediaExtinguishing Media to suit the burning material.Hazards from Non-combustible.Combustion If involved in a fire, the dehydrated components may emit oxides of carbon,Productsoxides of nitrogen and hydrogen chloride.Special ProtectiveEquipment for firefightersHazchem CodeBreathable air apparatus must be worn when fighting a fire in which thisproduct is involved.2X6. ACCIDENTAL RELEASE MEASURESSpills & Disposal Contain spill and absorb with clay, sand, soil or proprietary absorbent (suchas vermiculite).Collect spilled material and waste in sealable open-top type containers fordisposal.On-site disposal of concentrate is not acceptable.If possible, ring 1800 033 498 for specialist advice.Print Date: 1/06/2010 CS: 1.4.93
Material Safety Data SheetCS: 1.4.93Page: 3of6Infosafe No 3NU76 Issue Date : June 2010 ISSUED by CRPCAREProduct Name ALLIANCE® HerbicidePersonal ProtectionClean-up Methods -Large SpillagesEnvironmentalPrecautions7. HANDLING AND STORAGEPrecautions for SafeHandlingConditions for SafeStorageTank CleaningOther InformationClassified as hazardousWear specified PPE to decontaminate personnel and equipment, or to handlebroken packages or containers.Wear eye protection, chemically resistant gloves, boots and overalls.Decontaminate emergency personnel with soap and water before leaving theemergency area.If large liquid spills occur, attempt to recover as much spilt material fromsumps and bunded areas before absorbing remaining material into vermiculite orother absorbent.Use earthen bunds or absorbent bunding to prevent spreading of spillage.Prevent from entering into drains, ditches, rivers or the sea. This product isa herbicide and spills can damage crops, pastures and desirable vegetation.Do not work in spray mist. Do not continue to use if skin irritation or nosebleed occurs. This may be caused by exposure to spray mist as the result ofincorrect use of equipment or adverse climatic conditions. Stop and reviewhandling and spraying techniques before further spraying. If symptoms persistseek medical advice.For use by licensed pest control operators or primary producers only.Store in the closed, original container in a cool, well ventilated area.Do not store for prolonged periods in direct sunlight.Store in a locked enclosure.For use by licensed pest-control operators or primary producers only.Thoroughly flush all spray equipment with water following the use of thisproduct and before use with other products.Always read the label and any attached leaflet before use.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONNational ExposureStandardsEngineeringControlsRespiratoryProtectionPersonal ProtectiveEquipmentNo exposure standard for this product has been set, however, an exposurestandard has been set for paraquat (respirable sizes) at 0.1 mg/m3.NOHSC has set the following exposure standard for amitrole : TLV (TWA) 0.2mg/m3, STEL -.No special requirements.Ensure workplace is well ventilated.Some people who are extremely sensitive to the product may develop nose bleedswhen handling the concentrate. If possible, these people should not handlethe material; if they must, provide effective local ventilation.If exposure to vapour, spray or dusts from dried product is expected, wear ahigh efficiency particulate respirator covering nose and mouth.When opening the container, preparing spray and using the prepared spray wearcotton overalls buttoned to the neck and wrist and a washable hat,elbow-length PVC gloves and face shield or goggles.Re-entry period: Do not enter treated area until spray has dried.When there is a risk of exposure to spray mist wear waterproof footwear andwaterproof protective clothing, impervious gauntlet length gloves (rubber orPVC), goggles and a face mask and respirator covering nose and mouth andcapable of filtering spray droplets. A high efficiency type particulaterespirator is recommended, but in any event use a respirator which complieswith the requirements of AS1716 (Standards Association of Australia). Furtheradvice on safety equipment should be obtained from a safety equipmentmanufacturer.Avoid contacting vegetation wet with spray, but if necesary to do so, wearwaterproof footwear and waterproof protective clothing and gloves.Hygiene Measures After use and before eating, drinking or smoking, wash hands, arms and facethoroughly with soap and water.After each day's use, wash contaminated clothing and safety equipment.9. PHYSICAL AND CHEMICAL PROPERTIESFormLiquidAppearance Clear dark green liquidOdourObnoxious odourPrint Date: 1/06/2010 CS: 1.4.93
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272856-Cropcare-Alliance-20L-MSDS - Agsure

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