Page 1 of 8 perma-tec GmbH & Co. KG Safety data sheet in ...
Page 1 of 8 perma-tec GmbH & Co. KG Safety data sheet in ...
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<strong>perma</strong>-<strong>tec</strong> <strong>Page</strong> 1 <strong>of</strong> <strong>GmbH</strong> 8 & <strong>Co</strong>. <strong>KG</strong><br />
<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />
<strong>in</strong> accordance with 1907/2006 EC, Article 31<br />
Pr<strong>in</strong>t<strong>in</strong>g date: 27.02.2012 Revision: 27.02.2012<br />
1. Identification <strong>of</strong> the substance/mixture and <strong>of</strong> the company/undertak<strong>in</strong>g<br />
Product identifier<br />
Product name: SF 01 <strong>perma</strong> multi purpose grease<br />
Product description: Lubricat<strong>in</strong>g grease<br />
Manufacturer/supplier:<br />
Emergency number:<br />
<strong>perma</strong>-<strong>tec</strong> <strong>GmbH</strong> & <strong>Co</strong>. <strong>KG</strong><br />
Hammelburger Str. 21<br />
D-97717 Euerdorf<br />
Phone: 0049 (0) 9704-609-0<br />
Fax: 0049 (0) 9704-609-90<br />
Homepage: www.<strong>perma</strong>-<strong>tec</strong>.de<br />
E-mail: <strong>in</strong>fo@<strong>perma</strong>-<strong>tec</strong>.com<br />
0049 (0) 9704-609-99 (Mon - Thurs 8:00-16:30, Fri 8:00-12:00)<br />
2. Hazards identification<br />
This preparation is not classified as dangerous accord<strong>in</strong>g to Directive 1999/45/EEC <strong>in</strong> its amended and adapted version.<br />
Additional <strong>in</strong>formation about personal<br />
and environmental hazards:<br />
Possible harmful physical-chemical effects: None known<br />
Possible harmful effects on humans None known<br />
and possible symptoms:<br />
Possible harmful effects on the environment: None known<br />
Other hazards: None known<br />
3. <strong>Co</strong>mposition/<strong>in</strong>formation on <strong>in</strong>gredients<br />
3.1 Information about the preparation/mixture<br />
Description: M<strong>in</strong>eral oil product with highly ref<strong>in</strong>ed base oils and<br />
thickeners on a carboxylic acid basis, as well as<br />
selected additives.<br />
3.2 Hazardous substances:<br />
Substance name EC<br />
No.<br />
REACH<br />
No.<br />
Index<br />
No.<br />
CAS <strong>Co</strong>ntent<br />
No. %<br />
The World <strong>of</strong> Automatic Lubrication <strong>Page</strong> 1 <strong>of</strong> 8<br />
Classification <strong>in</strong> accordance with<br />
Regulation (EC) No. 1272/2008<br />
[CLP]<br />
Hazard classes /<br />
hazard categories<br />
Additive preparation - - - < 1% R 36/38<br />
R43<br />
Alkyl succ<strong>in</strong>ic acid half-ester 257-<br />
836-<br />
6<br />
Hazards<br />
<strong>in</strong>formation<br />
R 51/53<br />
< 1% R52 ; 53 N<br />
Classification <strong>in</strong><br />
accordance with<br />
67/548/EEC<br />
3.3 Note: Text <strong>of</strong> R-phrases and H-statements: See section 16.<br />
Xi,N
<strong>perma</strong>-<strong>tec</strong> <strong>Page</strong> 2 <strong>of</strong> <strong>GmbH</strong> 8 & <strong>Co</strong>. <strong>KG</strong><br />
<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />
<strong>in</strong> accordance with 1907/2006 EC, Article 31<br />
Pr<strong>in</strong>t<strong>in</strong>g date: 27.02.2012 Revision: 27.02.2012<br />
4. First-aid measures<br />
General <strong>in</strong>formation: Never give anyth<strong>in</strong>g by mouth to an<br />
unconscious person. <strong>Co</strong>nsult a physician if<br />
you feel unwell.<br />
After <strong>in</strong>halation: Not applicable<br />
After contact with the sk<strong>in</strong>: Wash the area <strong>of</strong> sk<strong>in</strong> affected with soap and<br />
copious amounts <strong>of</strong> water<br />
After contact with the eyes: R<strong>in</strong>se with copious amounts <strong>of</strong> water.<br />
<strong>Co</strong>nsult a physician.<br />
Show your physician the safety <strong>data</strong> <strong>sheet</strong>.<br />
After swallow<strong>in</strong>g: Do not <strong>in</strong>duce vomit<strong>in</strong>g unless expressly<br />
<strong>in</strong>structed to do so by a medical pr<strong>of</strong>essional.<br />
<strong>Co</strong>nsult a physician. Show your physician the<br />
safety <strong>data</strong> <strong>sheet</strong>.<br />
Self-pro<strong>tec</strong>tion for the first-aider: After oral contam<strong>in</strong>ation, do not perform<br />
mouth-to-mouth resuscitation on the victim.<br />
Information for physicians (symptoms, hazards, treatment)<br />
Symptoms: Nausea, drows<strong>in</strong>ess.<br />
Hazards: None known.<br />
Treatment: If feel<strong>in</strong>g unwell, observation for 24 hours<br />
5. Firefight<strong>in</strong>g measures<br />
Suitable ext<strong>in</strong>guish<strong>in</strong>g media: Foam, dry powder, spray<br />
Unsuitable ext<strong>in</strong>guish<strong>in</strong>g media Water jet full<br />
due to safety reasons:<br />
Particular hazard posed by the substance Carbon monoxide, sulfur oxides, nitrogen oxides<br />
or product itself, its products <strong>of</strong><br />
combustion or resultant gases:<br />
Special fire-fight<strong>in</strong>g pro<strong>tec</strong>tive equipment: Respirator mask<br />
6. Accidental release measures<br />
Personal precautions: Avoid contact with sk<strong>in</strong> and eyes.<br />
Remove any ignition sources.<br />
Provide adequate ventilation.<br />
Environmental precautions: Prevent from enter<strong>in</strong>g sewers. If the<br />
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<strong>perma</strong>-<strong>tec</strong> <strong>Page</strong> 3 <strong>of</strong> <strong>GmbH</strong> 8 & <strong>Co</strong>. <strong>KG</strong><br />
<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />
<strong>in</strong> accordance with 1907/2006 EC, Article 31<br />
Pr<strong>in</strong>t<strong>in</strong>g date: 27.02.2012 Revision: 27.02.2012<br />
The World <strong>of</strong> Automatic Lubrication <strong>Page</strong> 3 <strong>of</strong> 8<br />
product gets <strong>in</strong>to surface or ground water or <strong>in</strong>to the ground,<br />
possibly alert the neighborhood.<br />
Clean-up methods: Use absorbent materials (cellulose cloths, universal b<strong>in</strong>d<strong>in</strong>g<br />
agents, sawdust)<br />
Additional <strong>in</strong>formation: None.<br />
7. Handl<strong>in</strong>g and storage<br />
Handl<strong>in</strong>g: Store the product <strong>in</strong> a sealed conta<strong>in</strong>er<br />
<strong>in</strong> a cool, dry place. Pro<strong>tec</strong>t aga<strong>in</strong>st<br />
frost and high temperatures.<br />
Information for safe handl<strong>in</strong>g:<br />
Precautions: No special precautions required.<br />
Technical measures: Store <strong>in</strong> ventilated areas.<br />
Precautions to prevent aerosol Not applicable.<br />
and dust formation:<br />
Environmental precautions: Do not allow to enter sewers.<br />
Specific requirements or Store <strong>in</strong> sealed conta<strong>in</strong>ers <strong>in</strong>tended for<br />
handl<strong>in</strong>g regulations: this purpose.<br />
Information about fire and Keep away from ignition sources.<br />
explosion precautions:<br />
Further <strong>in</strong>formation: None.<br />
Storage:<br />
Technical measures and<br />
storage conditions<br />
Packag<strong>in</strong>g materials: Store only <strong>in</strong> conta<strong>in</strong>ers <strong>in</strong>tended for<br />
this purpose.<br />
Storage area Storage areas should be ventilated.<br />
and conta<strong>in</strong>er requirements: Ensure that the conta<strong>in</strong>ers are sealed<br />
dur<strong>in</strong>g storage.<br />
Information about storage with other products: Do not store with oxidiz<strong>in</strong>g substances<br />
or strong oxidants.
<strong>perma</strong>-<strong>tec</strong> <strong>Page</strong> 4 <strong>of</strong> <strong>GmbH</strong> 8 & <strong>Co</strong>. <strong>KG</strong><br />
<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />
<strong>in</strong> accordance with 1907/2006 EC, Article 31<br />
Pr<strong>in</strong>t<strong>in</strong>g date: 27.02.2012 Revision: 27.02.2012<br />
Further <strong>in</strong>formation about<br />
storage conditions:<br />
Storage temperature: 5 °C - 40 °C<br />
Relative air humidity {%): Not specified<br />
Storage stability: No special <strong>in</strong>formation required.<br />
Maximum storage period: 24 months<br />
Storage class: None<br />
Intended use:<br />
Recommendations: Use as a lubricant at open and closed<br />
lubrication po<strong>in</strong>ts.<br />
Branch solutions: No separate <strong>in</strong>formation.<br />
8. Exposure controls/personal pro<strong>tec</strong>tion<br />
Exposure limits:<br />
Ingredients with Base oil<br />
workplace limits or<br />
biological limits to be monitored<br />
Workplace limits: -<br />
Additional exposure limits 5 mg/m 3 ACGIH (TLV)<br />
under process<strong>in</strong>g conditions: 5 mg/m 3 OSHA (PEL)<br />
10mg/m 3 ACGIH (STEL)<br />
DN EL.DM EL and PNEC values: -<br />
Exposure controls and monitor<strong>in</strong>g: -<br />
Workplace exposure controls and monitor<strong>in</strong>g:<br />
Product-based measures for Use <strong>in</strong> closed lubrication po<strong>in</strong>ts to<br />
prevent<strong>in</strong>g exposure: prevent release.<br />
Instructions for Wear personal pro<strong>tec</strong>tive equipment.<br />
prevent<strong>in</strong>g exposure:<br />
Organizational measures for Tra<strong>in</strong> personnel <strong>in</strong> the use <strong>of</strong> personal<br />
prevent<strong>in</strong>g exposure: pro<strong>tec</strong>tive equipment.<br />
Technical measures for Install extraction equipment, <strong>in</strong> order to<br />
prevent<strong>in</strong>g exposure: reduce air pollution.<br />
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<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />
<strong>in</strong> accordance with 1907/2006 EC, Article 31<br />
Pr<strong>in</strong>t<strong>in</strong>g date: 27.02.2012 Revision: 27.02.2012<br />
Personal pro<strong>tec</strong>tive equipment:<br />
Respiratory pro<strong>tec</strong>tion: Not required when product is used properly.<br />
Hand pro<strong>tec</strong>tion: Wear suitable pro<strong>tec</strong>tive gloves <strong>in</strong> accordance with<br />
DIN EN 374. Please ask your manufacturer for<br />
<strong>in</strong>formation.<br />
Eye pro<strong>tec</strong>tion: When there is a risk <strong>of</strong> potential eye contact, comply with<br />
the guidel<strong>in</strong>es provided by BGR 192 (e.g. wear<strong>in</strong>g goggles).<br />
Body pro<strong>tec</strong>tion: When there is a risk <strong>of</strong> potential contact with the body, wear<br />
suitable pro<strong>tec</strong>tive cloth<strong>in</strong>g <strong>in</strong> accordance with the <strong>in</strong>formation<br />
<strong>in</strong> BGR 189.<br />
Environmental exposure<br />
controls and monitor<strong>in</strong>g:<br />
Product-based measures for prevent<strong>in</strong>g Use product only <strong>in</strong> accordance with its <strong>in</strong>tended<br />
exposure: purpose.<br />
Instructions for prevent<strong>in</strong>g exposure: Instruct personnel <strong>in</strong> the use <strong>of</strong> pro<strong>tec</strong>tive cloth<strong>in</strong>g<br />
.<br />
Technical measures for prevent<strong>in</strong>g exposure: Provide adequate ventilation.<br />
<strong>Co</strong>nsumer exposure<br />
controls and monitor<strong>in</strong>g:<br />
Measures relat<strong>in</strong>g to the use <strong>of</strong> the substance None<br />
(<strong>in</strong> its orig<strong>in</strong>al form or <strong>in</strong> preparations)<br />
by the consumer:<br />
Measures relat<strong>in</strong>g to the use <strong>of</strong> the substance None<br />
<strong>in</strong> items:<br />
9. Physical and chemical properties<br />
General <strong>in</strong>formation<br />
Appearance <strong>Co</strong>lor: Brown (light)<br />
Smell: M<strong>in</strong>eral oil<br />
Aggregate state: Solid<br />
Important <strong>in</strong>formation about Do not allow to enter sewers. Do not allow to enter<br />
health and environmental pro<strong>tec</strong>tion ground water.<br />
and safety:<br />
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<strong>perma</strong>-<strong>tec</strong> <strong>Page</strong> 6 <strong>of</strong> <strong>GmbH</strong> 8 & <strong>Co</strong>. <strong>KG</strong><br />
<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />
<strong>in</strong> accordance with 1907/2006 EC, Article 31<br />
Pr<strong>in</strong>t<strong>in</strong>g date: 27.02.2012 Revision: 27.02.2012<br />
Basic safety-related <strong>data</strong>:<br />
Drop po<strong>in</strong>t (°C): Value Method Note<br />
> 150 DIN ISO 2176 -<br />
Density (g/cm3): 950 DIN EN ISO 12185 -<br />
Water solubility Non-soluble - -<br />
(20° <strong>in</strong> g/l):<br />
Other <strong>in</strong>formation: None<br />
10. Stability and reactivity<br />
<strong>Co</strong>nditions to avoid: Intense heat <strong>in</strong> excess <strong>of</strong> 200 °C.<br />
Substances to avoid: Strong oxidants. Oxidiz<strong>in</strong>g substances.<br />
Hazardous decomposition products: Carbon oxides, sulfur oxides, nitrogen oxides.<br />
11. Toxicological <strong>in</strong>formation<br />
Toxicok<strong>in</strong>etics, metabolism and distribution<br />
Non-human-toxicological <strong>data</strong>:<br />
Method:<br />
Dose: > 5000 mg/kg<br />
Mode <strong>of</strong> adm<strong>in</strong>istration: Oral<br />
Results: LD50<br />
Human toxicological <strong>data</strong>: None known.<br />
Acute effects (toxicological tests)<br />
12. Ecological <strong>in</strong>formation<br />
Ecological toxicity:<br />
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None available.<br />
Mobility: Penetration <strong>in</strong>to ground water is improbable,
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<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />
<strong>in</strong> accordance with 1907/2006 EC, Article 31<br />
Pr<strong>in</strong>t<strong>in</strong>g date: 27.02.2012 Revision: 27.02.2012<br />
Other harmful effects: None known.<br />
Other ecological <strong>in</strong>formation: None.<br />
13. Disposal considerations<br />
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s<strong>in</strong>ce the product is practically <strong>in</strong>soluble <strong>in</strong><br />
water.<br />
Disposal / waste (product): Must be disposed <strong>of</strong> by authorized waste<br />
disposal contractor.<br />
EWC/AVV (German waste catalog<br />
ord<strong>in</strong>ance) waste disposal code: 12 01 12* used waxes and greases.<br />
Additional <strong>in</strong>formation: None.<br />
14. Transport <strong>in</strong>formation<br />
Not a hazardous substance under transport regulations.<br />
Land transport (ADR RID GGVSE<br />
(ord<strong>in</strong>ance on the carriage <strong>of</strong><br />
hazardous goods by road and rail)): -<br />
Mar<strong>in</strong>e transport (IMDG <strong>Co</strong>de/GGVSee<br />
(ord<strong>in</strong>ance on the carriage <strong>of</strong> hazardous<br />
goods by sea): -<br />
Air transport (ICAO-IATA/DGR): -<br />
15. Regulatory <strong>in</strong>formation<br />
15.1 EU regulations Classification and designation have been carried<br />
out <strong>in</strong> accordance with the ECDirectives 1995/45/EC<br />
and 67/54S/EEC <strong>in</strong> their amended and adapted versions<br />
Designation (67/543/EEC or 1999/45/EC) -<br />
Hazard symbols and hazard designations<br />
for hazardous substances and preparations: -<br />
Hazardous components to be listed<br />
on the label: -<br />
R-phrases: -
<strong>perma</strong>-<strong>tec</strong> <strong>Page</strong> 8 <strong>of</strong> <strong>GmbH</strong> 8 & <strong>Co</strong>. <strong>KG</strong><br />
<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />
<strong>in</strong> accordance with 1907/2006 EC, Article 31<br />
Pr<strong>in</strong>t<strong>in</strong>g date: 27.02.2012 Revision: 27.02.2012<br />
S-phrases: -<br />
Note: -<br />
Special designation <strong>of</strong> certa<strong>in</strong> preparations: -<br />
Approvals and/or restrictions <strong>of</strong> use: -<br />
Other EU regulations -<br />
National regulations (Germany)<br />
Water hazard class (VwVwS) 1<br />
16. Other <strong>in</strong>formation<br />
Text <strong>of</strong> R-phrases and H-statements: -<br />
Tra<strong>in</strong><strong>in</strong>g <strong>in</strong>formation: -<br />
Recommended restrictions <strong>of</strong> use: Only use <strong>in</strong> accordance with the <strong>in</strong>tended purpose.<br />
Categories <strong>of</strong> use and exposure (overview): -<br />
Additional <strong>in</strong>formation: -<br />
Data sources:<br />
EC Directive 67/548/EEC <strong>in</strong> the applicable version.<br />
EC Directive 1999/45/EC <strong>in</strong> the applicable version.<br />
EC Directive 1907/2006/EC <strong>in</strong> the applicable version.<br />
Notice 220 <strong>in</strong> the applicable version.<br />
Transport regulations <strong>in</strong> accordance with ADR, RID, IMDG. IATA <strong>in</strong> the applicable version.<br />
Important <strong>in</strong>formation:<br />
All <strong>in</strong>formation is based on our current knowledge. The purpose <strong>of</strong> the safety <strong>data</strong> <strong>sheet</strong> is to provide the ma<strong>in</strong> physical,<br />
safety-related, toxicological and ecological <strong>data</strong> for the handl<strong>in</strong>g <strong>of</strong> chemical substances and preparations, together<br />
with recommendations for safe storage, usage and transportation. The aim is to provide correct <strong>in</strong>formation for<br />
personal and environmental pro<strong>tec</strong>tion. These specialist <strong>in</strong>dustrial safety statements are <strong>in</strong>tended for use by safety<br />
<strong>of</strong>ficers, experts and eng<strong>in</strong>eers, as well as occupational health physicians, toxicologists and state supervisory bodies.<br />
Please pass on this <strong>in</strong>formation to the relevant departments and authorities.<br />
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