ERG 2012 - Guide 131 - CAMEO Chemicals

GUIDE131fLaMMabLe LiqUids - toxiCERG2012POTENTIAL HAZARDSHEALTH• TOXIC; may be fatal if inhaled, ingested or absorbed through skin.• Inhalation or contact with some of these materials will irritate or burn skin and eyes.• Fire will produce irritating, corrosive and/or toxic gases.• Vapors may cause dizziness or suffocation.• Runoff from fire control or dilution water may cause pollution.FIRE OR EXPLOSION• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.• Vapors may form explosive mixtures with air.• Vapors may travel to source of ignition and flash back.• Most vapors are heavier than air. They will spread along ground and collect in low or confined areas(sewers, basements, tanks).• Vapor explosion and poison hazard indoors, outdoors or in sewers.• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.• Runoff to sewer may create fire or explosion hazard.• Containers may explode when heated.• Many liquids are lighter than water.PUBLIC SAFETY• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper notavailable or no answer, refer to appropriate telephone number listed on the inside back cover.• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in alldirections.• Keep unauthorized personnel away.• Stay upwind.• Keep out of low areas.• Ventilate closed spaces before entering.PROTECTIVE CLOTHING• Wear positive pressure self-contained breathing apparatus (SCBA).• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may providelittle or no thermal protection.• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is noteffective in spill situations where direct contact with the substance is possible.EVACUATIONSpill• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For nonhighlightedmaterials, increase, in the downwind direction, as necessary, the isolation distance shownunder “PUBLIC SAFETY”.Fire• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also,consider initial evacuation for 800 meters (1/2 mile) in all directions.Page 200

ERG2012 fLaMMabLe LiqUids - toxiCGUIDE131EMERGENCY RESPONSEFIRECAUTION: All these products have a very low flash point: Use of water spray when fighting fire maybe inefficient.Small Fire• Dry chemical, CO 2, water spray or alcohol-resistant foam.Large Fire• Water spray, fog or alcohol-resistant foam.• Move containers from fire area if you can do it without risk.• Dike fire-control water for later disposal; do not scatter the material.• Use water spray or fog; do not use straight streams.Fire involving Tanks or Car/Trailer Loads• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.• Cool containers with flooding quantities of water until well after fire is out.• Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.• ALWAYS stay away from tanks engulfed in fire.• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw fromarea and let fire burn.SPILL OR LEAK• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).• All equipment used when handling the product must be grounded.• Do not touch or walk through spilled material.• Stop leak if you can do it without risk.• Prevent entry into waterways, sewers, basements or confined areas.• A vapor suppressing foam may be used to reduce vapors.• Small Spill •Absorb with earth, sand or other non-combustible material and transfer to containers forlater disposal.• Use clean non-sparking tools to collect absorbed material.• Large Spill • Dike far ahead of liquid spill for later disposal.• Water spray may reduce vapor; but may not prevent ignition in closed spaces.FIRST AID• Move victim to fresh air. • Call 911 or emergency medical service.• Give artificial respiration if victim is not breathing.• Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificialrespiration with the aid of a pocket mask equipped with a one-way valve or other properrespiratory medical device.• Administer oxygen if breathing is difficult.• Remove and isolate contaminated clothing and shoes.• In case of contact with substance, immediately flush skin or eyes with running water for at least 20minutes.• Wash skin with soap and water.• In case of burns, immediately cool affected skin for as long as possible with cold water.Do not remove clothing if adhering to skin. • Keep victim warm and quiet.• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.• Ensure that medical personnel are aware of the material(s) involved and take precautionsto protect themselves.Page 201