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Aqueous Geochemistry in Mineral Exploration - ADIMB

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1<strong>Aqueous</strong> <strong>Geochemistry</strong> <strong>in</strong> M<strong>in</strong>eral <strong>Exploration</strong>Matthew I. Leybourne, GNS Science, Avalon, Lower Hutt, New Zealand


Outl<strong>in</strong>e• Why aqueous geochemistry <strong>in</strong> m<strong>in</strong>eral exploration?• Field analyses - importance of pH and Eh• Major species• Trace metals and metalloids• Stable isotopes• Radiogenic isotopes• Insights ga<strong>in</strong>ed from water chemistry• Seawater exploration for SMSGNS Science


Utility of groundwater geochemistry• Significant challenge for m<strong>in</strong>eral exploration is to f<strong>in</strong>dnew and deeper deposits, particularly <strong>in</strong> areas whereeither thick cover exists• Where past exploration has already discovered shallowm<strong>in</strong>eralization and exploration must extend to greaterdepth• Groundwater recharges to depth, result<strong>in</strong>g <strong>in</strong> greaterlikelihood of <strong>in</strong>teract<strong>in</strong>g with buried m<strong>in</strong>eralizationcompared to surficial geochemical methods, thusprovid<strong>in</strong>g a three dimensional perspective• <strong>Aqueous</strong> geochemistry can provide <strong>in</strong>sights <strong>in</strong>to othersample media and dispersion processes, secondarym<strong>in</strong>eral formationGNS Science


Natural waters vs AMDGNS Science


Field based analyses- pH and redoxKZK (Yukon)Spence (Chile)GNS Science


Major species: Monturaqui, Salar de Punta Negraand Hamburgo Bas<strong>in</strong>GNS Science


Major species: Kirkland Lake,OntarioGNS Science


Trace metals and metalloidsGNS Science


Trace elements - Spence, ChileGNS Science


Trace elements - Spence, ChileGNS Science


Trace elements - KZK, YukonGNS Science


Trace elements - Bathurst Camp, NBGNS Science


Trace elements - Bathurst Camp, NBGNS Science


Filtration versus non-filtrationGNS Science


Stable Isotopes - Spence, ChileGNS Science


Stable isotopesGNS Science


Stable isotopes - KZK, YukonLayton-Matthews and Leybourne (unpublished data)GNS Science


F<strong>in</strong>gerpr<strong>in</strong>t<strong>in</strong>g trace metal sourcesde Caritat, P. and Kirste, D., (2005)GNS Science


Radiogenic isotopes - Pb• Pb has low solubility <strong>in</strong> waters• Dist<strong>in</strong>guish<strong>in</strong>g true from false anomalies (organic, Mn or Fe oxideaccumulation of metals)GNS Science


Radiogenic isotopesGNS Science


Integration of geochemical model<strong>in</strong>g with realworldexamples• Enhanced understand<strong>in</strong>g of critical processes• Application to metallurgical processes, remediation studies, supergenem<strong>in</strong>eralizationGNS Science


Formation of atacamiteGNS Science


Formation of soil anomaliesGNS Science


GNS Science


<strong>Aqueous</strong>Geochemical<strong>Exploration</strong>: TheOceansGNS Science


GNS Science


GNS Science


Plume Hunt<strong>in</strong>gGNS Science


GNS Science


GNS Science


GNS Science


GNS Science


GNS Science


GNS Science


1.01.41.8GNS Science


GNS Science


GNS Science


GNS Science


Sometimes the water comes to you…GNS Science


26 th International Applied <strong>Geochemistry</strong> SymposiumIncorporat<strong>in</strong>g the New Zealand Geothermal Workshop18-21 November, 2013, Rotorua, New Zealandwww.gns.cri.nz/iags

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