msds sigmashield 825 base - SIGMA PAINTS

SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.SIGMASHIELD 825 BASEMSDS EU 01 / EN Version 1 Print Date 3/30/2007Revision date 16-03-07Viscosity, dynamic : 6,500 mPa.s at 23 °CFlow time : >= 60 sTransversal section: 6 mmMethod: ISO 2431 (EN 535) 6 mm CUP10. STABILITY AND REACTIVITYConditions to avoid : Avoid temperatures above 60°C (140 F), direct sunlight and contact withsources of heat.Hazardous reactions : Keep away from oxidising agents, strongly alkaline and strongly acidmaterials in order to avoid exothermic reactions.Hazardous decompositionproducts: In case of fire hazardous decomposition products may be produced such as:Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx),dense black smoke.11. TOXICOLOGICAL INFORMATIONAcute oral toxicity : May cause nausea, abdominal spasms and irritation of the mucousmembranes.Acute inhalation toxicity : Exposure to component solvent vapours concentration in excess of the statedoccupational exposure limit may result in adverse health effects. Such as:mucous membrane irritation, respiratory system irritation, adverse effects onkidney, liver and central nervous system. Symptoms and signs: headache,dizziness, fatigue, muscular weakness, drowsiness and in extreme cases lossof consciousness.Skin irritation : Repeated or prolonged contact with the preparation may cause removal ofnatural fat from the skin resulting in desiccation of the skin. The product maybe absorbed through the skin. Repeated skin contact may lead to irritationand to senitization, possible with cross-sensitization to other epoxies.Eye contact : Irritating to eyes.Further information : There is no data available for this product.Acute Toxicity Data for ComponentsTrizinc bis(orthophosphate)(7779-90-0)Acute oral toxicity : LD50: 552 mg/kg (mouse)12. ECOLOGICAL INFORMATIONFurther information : The preparation has been assessed following the conventional method of theDangerous Preparations Directive 1999/45/EC and is classified forecotoxicological properties accordingly. See sections 2 and 15 for details.13. DISPOSAL CONSIDERATIONSProduct : The product should not be allowed to enter drains, water courses or the soil.Disposal together with normal waste is not allowed. Special disposal requiredaccording to local regulations.5/8

SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.SIGMASHIELD 825 BASEMSDS EU 01 / EN Version 1 Print Date 3/30/2007Revision date 16-03-07Waste key for the unusedproduct: The European Waste Catalogue classification of this product, when disposedof as waste is:08 01 11 Waste paint and varnish containing organic solvents or otherdangerous substances.If this product is fully cured or mixed with other wastes, this code may nolonger apply. If mixed with other wastes, the appropriate code should beassigned. For further information contact your local waste authority14. TRANSPORT INFORMATIONTransport within user's premises: always transport in closed containers that are upright, labelled and secure. Ensure thatpersons transporting the product know what to do in the event of an accident or spillage.Transport to be in accordance with ADR for road, IMDG for sea and IATA for air transport:UN-No : 1263Proper shipping name : PAINTClass : 3Packing group : IIILabel : 3Proper shipping name (ADR) : PAINTMarine Pollutant (IMDG)(P,PP,-) : -EmS (IMDG) : F-E, S-ELimited quantity (ADR) : Max. per inner pack. : 5.00 LMax. per outer pack. : 30.00 KGLimited quantity (IMDG) : Max. per inner pack. : 5.00 LMax. per outer pack. : 30.00 KGNoteIf pack sizes less than 450L, under the terms of 2.2.3.1.5, this product is not subject to the provisions of ADR.If pack sizes up to and including 30L, under the terms of 2.3.2.5, this product is not subject to the packaging, labellingand marking requirements of the IMDG code, but both full documentation and placarding of cargo transport units isstill required.15. REGULATORY INFORMATIONThe product is classified and labelled in accordance with Directive 1999/45/EC.IrritantDangerous for theenvironmentHazardous components which must be listed on the label:• epoxy resin (MW

SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.SIGMASHIELD 825 BASEMSDS EU 01 / EN Version 1 Print Date 3/30/2007Revision date 16-03-07R-phrase(s) : R10 Flammable.R36/38 Irritating to eyes and skin.R43May cause sensitization by skin contact.R51/53 Toxic to aquatic organisms, may cause long-termadverse effects in the aquatic environment.S-phrase(s) : S23 Do not breathe spray.S36/37 Wear suitable protective clothing and gloves.S38In case of insufficient ventilation, wear suitablerespiratory equipment.S61Avoid release to the environment. Refer to specialinstructions/safety data sheets.P-phrase(s) : Contains epoxy constituents. See informationsupplied by the manufacturer.The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks, asrequired by other health and safety legislation. The provisions of the national health and safety at work regulationsapply to the use of this product at work.National legislation16. OTHER INFORMATIONExplanation of R-phrases mentioned in section 2xylene R10 Flammable.R20/21 Harmful by inhalation and in contact with skin.R38 Irritating to skin.iso-butanol R10 Flammable.R37/38 Irritating to respiratory system and skin.R41 Risk of serious damage to eyes.R67 Vapours may cause drowsiness and dizziness.ethylbenzene R11 Highly flammable.R20 Harmful by inhalation.epoxy resin (MW

SAFETY DATA SHEETThis safety data sheet is prepared in accordance with EU directive 91/155/EC amended by directive2001/58/EC.SIGMASHIELD 825 BASEMSDS EU 01 / EN Version 1 Print Date 3/30/2007Revision date 16-03-07Version: 1 Revision date 16.03.2007The information contained in this safety data sheet is based on the present state of knowledge and current European andNational legislation at the date of issue. The supplier reserves the right to modify data on the safety data sheet withoutfurther notice. Any change in data will normally be followed by the issue of a new safety data sheet. The user shouldcheck the date of issue and if more than 12 months have elapsed, then the data should only be used after checking withthe nearest sales office of the supplier to establish that the data is still valid. As the specific conditions of use of theproduct are outside the suppliers control, the supplier is not reponsible for the (negative) consequences of these specificconditions of use, which are outside of the suppliers. control and which are not compliant with the handling, storageand other instructions in this safety data sheet.After all component(s) stated on the relevant Technical Data Sheet have been mixed the safety precautions mentionedon each of the component(s) safety data sheets and labels should be used in assessing the safety precautions of themixed product.For further information see technical data sheet number: 77458/8