Calypso 480 msds english.pdf - Bartlett.ca

Bayer CropScienceSafety Data SheetSDS Number: 102000008338CALYPSO® 480 SC INSECTICIDE SDS Version 1.2Potential EnvironmentalEffectToxic to aquatic organisms.SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSHazardous Component Name CAS-No. Average % by WeightThiacloprid 111988-49-9 40.40Glycerine 56-81-5 10.00SECTION 4. FIRST AID MEASURESGeneralEyeSkinIngestionInhalationNotes to physicianSigns andSymptomsTreatmentWhen possible, have the product container or label with you when calling apoison control center or doctor or going for treatment.Hold eye open and rinse slowly and gently with water for 15-20 minutes.Remove contact lenses, if present, after the first 5 minutes, then continue rinsingeye. Call a physician or poison control center immediately.Take off contaminated clothing and shoes immediately. Wash off immediatelywith plenty of water for at least 15 minutes. Call a physician or poison controlcenter immediately.Call a physician or poison control center immediately. Rinse out mouth and givewater in small sips to drink. DO NOT induce vomiting unless directed to do so bya physician or poison control center. Never give anything by mouth to anunconscious person. Do not leave victim unattended.Move to fresh air. If person is not breathing, call 911 or an ambulance, then giveartificial respiration, preferably mouth-to-mouth if possible. Call a physician orpoison control center immediately.To date no symptoms are known.Appropriate supportive and symptomatic treatment as indicated by the patient'scondition is recommended. There is no specific antidote.SECTION 5. FIRE FIGHTING MEASURESFlash point > 93.3 °C / > 199.9 °FAutoignition temperatureno data availablePage 2 of 9

Bayer CropScienceSafety Data SheetSDS Number: 102000008338CALYPSO® 480 SC INSECTICIDE SDS Version 1.2Lower FlammabilityLimitUpper Flammability LimitExplosivenessFire and ExplosionHazardsSuitable extinguishingmediaUnsuitable extinguishingmediaFire FightingInstructionsno data availableno data availablenot applicableIn the event of fire the following may be released:Hydrogen chloride (HCl)Carbon monoxide (CO)Nitrogen oxides (NOx)Hydrogen cyanide (hydrocyanic acid)Sulphur oxidesWater spray, Foam, Dry powder, Carbon dioxide (CO2), SandNone known.Avoid contact with spilled product or contaminated surfaces. Keep out of smoke.Fight fire from upwind position. Cool closed containers exposed to fire with waterspray. Do not allow run-off from fire fighting to enter drains or water courses.Firefighters should wear NIOSH approved self-contained breathing apparatusand full protective clothing.SECTION 6. ACCIDENTAL RELEASE MEASURESPersonal precautionsMethods for cleaning upAdditional adviceKeep unauthorized people away. Isolate hazard area. Avoid contact with spilledproduct or contaminated surfaces.Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universalbinder, sawdust). Collect and transfer the product into a properly labelled andtightly closed container. Contaminated soil may have to be removed anddisposed. Clean contaminated floors and objects thoroughly, observingenvironmental regulations.Use personal protective equipment. Do not allow to enter soil, waterways orwaste water canal.SECTION 7. HANDLING AND STORAGEHandling proceduresHandle and open container in a manner as to prevent spillage. Maintainexposure levels below the exposure limit through the use of general and localexhaust ventilation.Page 3 of 9

Bayer CropScienceSafety Data SheetSDS Number: 102000008338CALYPSO® 480 SC INSECTICIDE SDS Version 1.2Storing ProceduresStore in a cool, dry place and in such a manner as to prevent crosscontamination with other crop protection products, fertilizers, food, and feed.Store in original container and out of the reach of children, preferably in a lockedstorage area.Work/HygienicProceduresWash hands thoroughly with soap and water after handling and before eating,drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.Remove Personal Protective Equipment (PPE) immediately after handling thisproduct. Before removing gloves clean them with soap and water. Removesoiled clothing immediately and clean thoroughly before using again. Washthoroughly and put on clean clothing.SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTIONGeneral ProtectionEye/Face ProtectionHand protectionBody ProtectionRespiratory protectionFollow manufacturer's instructions for cleaning/maintaining PPE. If no suchinstructions for washables, use detergent and warm/tepid water. Keep and washPPE separately from other laundry.Safety glasses with side-shieldsChemical resistant nitrile rubber glovesWear long-sleeved shirt and long pants and shoes plus socks.When respirators are required, select NIOSH approved equipment based onactual or potential airborne concentrations and in accordance with theappropriate regulatory standards and/or industry recommendations.Exposure LimitsGlycerine 56-81-5 CAD AB OEL TWA 10 mg/m3CAD BC OEL TWA 3 mg/m3CAD BC OEL TWA 10 mg/m3CAD ON OEL TWAEV 10 mg/m3CAD SK OEL 8 HR ACL 10 mg/m3CAD SK OEL 15 MIN ACL 20 mg/m3OEL (QUE) TWA 10 mg/m3SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESAppearancePhysical StateOdorwhite to beigeviscous Liquidvery faintPage 4 of 9

Bayer CropScienceSafety Data SheetSDS Number: 102000008338CALYPSO® 480 SC INSECTICIDE SDS Version 1.2pH 7 - 9 (5 %) at 23 °Cdispersion in waterVapor PressureVapor Density (Air = 1)no data availableno data availableDensity 1.18 g/cm³ at 20 °CEvapouration rateBoiling PointMelting / Freezing PointWater solubilityMinimum Ignition EnergyDecompositiontemperaturePartition coefficient: n-octanol/waterno data availableno data availableno data availabledispersiblenot applicablenot applicableno data availableViscosity 1,000 - 1,200 mPa.s at 20 °CSECTION 10. STABILITY AND REACTIVITYConditions to avoidIncompatibilityHazardousDecomposition ProductsHazardous reactionsfreezingno data availableNo decomposition products expected under normal conditions of use.No dangerous reaction known under conditions of normal use.SECTION 11. TOXICOLOGICAL INFORMATIONOnly acute studies have been performed on this product as formulated. The non-acute information pertains tothe technical-grade active ingredient, thiacloprid.Acute oral toxicityAcute dermal toxicityrat: LD50: > 300 - < 500 mg/kgrat: LD50: > 4,000 mg/kgPage 5 of 9

Bayer CropScienceSafety Data SheetSDS Number: 102000008338CALYPSO® 480 SC INSECTICIDE SDS Version 1.2Acute inhalation toxicityfemale rat: LC50: > 1.0 - < 2.2 mg/lExposure time: 4 hDetermined in the form of liquid aerosol.female rat: LC50: > 4.0 - < 8.8 mg/lExposure time: 1 hDetermined in the form of liquid aerosol.Extrapolated from the 4 hr LC50.male rat: LC50: > 2.2 mg/lExposure time: 4 hDetermined in the form of liquid aerosol.male rat: LC50: > 8.8 mg/lExposure time: 1 hDetermined in the form of liquid aerosol.Extrapolated from the 4 hr LC50.Skin irritationEye irritationSensitisationChronic toxicityrabbit: No skin irritationrabbit: No eye irritationguinea pig: SensitisingOECD Test Guideline 406, Magnusson & Kligman testThiacloprid did not cause specific target organ toxicity in experimental animalstudies.Assessment CarcinogenicityThiacloprid caused at high dose levels an increased incidence of tumours in rats in the following organ(s):uterus, thyroid.Thiacloprid caused at high dose levels an increased incidence of tumours in mice in the following organ(s):ovaries. The tumours seen with Thiacloprid were caused through a non-genotoxic mechanism, which is notrelevant at low doses. The mechanism that triggers tumours in rodents is not relevant for the lowexposures encountered under normal use conditions.ACGIHNone.NTPNone.IARCNone.OSHANone.Reproductive toxicityThiacloprid caused reproduction toxicity in a two-generation study in rats only atdose levels also toxic to the parent animals. Thiacloprid caused difficulties inparturition in rats. The mechanism of action for this effect is not considered to berelevant to man.Page 6 of 9

Bayer CropScienceSafety Data SheetSDS Number: 102000008338CALYPSO® 480 SC INSECTICIDE SDS Version 1.2Developmental ToxicityMutagenicityThiacloprid caused developmental toxicity only at dose levels toxic to the dams.The developmental effects seen with Thiacloprid are related to maternal toxicity.Thiacloprid was not mutagenic or genotoxic in a battery of in vitro and in vivotests.SECTION 12. ECOLOGICAL INFORMATIONToxicity to fishToxicity to aquatic plantsLepomis macrochirus (Bluegill sunfish)LC50: 80.7 mg/lExposure time: 96 hDesmodesmus subspicatusIC50: 96.7 mg/lExposure time: 72 hSelenastrum capricornutumIC50: > 100 mg/lExposure time: 72 hAcute Toxicity to AquaticInvertebratesEnvironmentalprecautionsDaphniaEC50: >= 85.1 mg/lExposure time: 48 hDo not apply directly to water, to areas where surface water is present or tointertidal areas below the mean high water mark. Do not contaminate surface orground water by cleaning equipment or disposal of wastes, including equipmentwash water. Drift and runoff from treated areas may be hazardous to aquaticorganisms in adjacent sites. Apply this product as specified on the label.SECTION 13. DISPOSAL CONSIDERATIONSGeneral DisposalGuidanceContainer DisposalDo not contaminate water, food, or feed by disposal. Follow container labelinstructions for disposal of wastes generated during use in compliance with theproduct label.Do not re-use empty containers. Triple rinse containers. Puncture container toavoid re-use. Dispose of empty container in a sanitary landfill or by incineration,or, if allowed by State/Provincial and local authorities, by burning. If burned, stayout of smoke. Follow advice on product label and/or leaflet.SECTION 14. TRANSPORT INFORMATIONAccording to national and international transport regulations this material is not classified as dangerousgoods / hazardous material.Page 7 of 9

Bayer CropScienceSafety Data SheetSDS Number: 102000008338CALYPSO® 480 SC INSECTICIDE SDS Version 1.2Freight Classification:INSECTICIDES OR FUNGICIDES, N.O.I., POISON, OTHER THANGASES THAT ARE POISONOUS BY INHALATIONSECTION 15. REGULATORY INFORMATIONPCP Registration No. 28429US Federal RegulationsTSCA listGlycerine 56-81-5US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)None.SARA Title III - Section 302 - Notification and InformationNone.SARA Title III - Section 313 - Toxic Chemical Release ReportingNone.US States Regulatory ReportingCA Prop65This product does not contain any substances known to the State of California to cause cancer.This product does not contain any substances known to the State of California to cause reproductiveharm.US State Right-To-Know IngredientsGlycerine 56-81-5 MNCanadian RegulationsCanadian Domestic Substance ListGlycerine 56-81-5EnvironmentalCERCLANone.Clean Water Section 307 Priority PollutantsNone.Safe Drinking Water Act Maximum Contaminant LevelsNone.International RegulationsEuropean Inventory of Existing Commercial Substances (EINECS)Glycerine 56-81-5Page 8 of 9

Bayer CropScienceSafety Data SheetSDS Number: 102000008338CALYPSO® 480 SC INSECTICIDE SDS Version 1.2SECTION 16. OTHER INFORMATIONNFPA 704 (National Fire Protection Association):Health - 2 Flammability - 1 Instability - 1 Others - noneHMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide)Health - 2 Flammability - 1 Physical Hazard - 1 PPE -0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazardReason for Revision: Reviewed and updated for general editorial purposes.Prepared by the HSE Department of Bayer CropScience Inc. (306)-721-0310.Revision Date: 03/10/2014This information is provided in good faith but without express or implied warranty. The customer assumes allresponsibility for safety and use not in accordance with label instructions. The product names are registeredtrademarks of Bayer.Page 9 of 9