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Ident-No: HARDENER HY 4076 - AMI-CON

Ident-No: HARDENER HY 4076 - AMI-CON

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SAFETY DATA SHEETaccording to applicable EC directive<strong>Ident</strong>-<strong>No</strong>: <strong>HARDENER</strong> <strong>HY</strong> <strong>4076</strong>Version 1 Print Date 07.04.2009Revision Date 22.03.20091. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGProduct informationTrade name : <strong>HARDENER</strong> <strong>HY</strong> <strong>4076</strong>Use : Hardener for adhesive systemsCompany: Huntsman Advanced Materials (Europe)BVBAEverslaan 453078 Everberg / BelgiumTelephone : +41619661599Telefax : +41619661589Emergency telephone : +32 35 751 234 (in France ORFILA : +33(0)145425959)numberFor further Product EHS related questions concerning this document or its contents, pleasecontact:E-Mail: global_product_ehs_admat@huntsman.com2. HAZARDS IDENTIFICATIONCauses burns.Toxic in contact with skin.Harmful by inhalation.3. COMPOSITION/INFORMATION ON INGREDIENTSChemical natureAliphatic amine adductpreparationHazardous componentsChemical Name CAS-<strong>No</strong>. Symbol(s): R-phrase(s) Concentration [%]dioxadodecanediamine C,R34, R20EC-<strong>No</strong>.: 230-745-97300-34-7 C R20 R34 40.00 - 60.004. FIRST AID MEASURESInhalationEye contactSkin contactIngestion: Move to fresh air.Call a physician immediately.: Rinse immediately with plenty of water for at least 15 minutes.Call a physician immediately.: Wash off with soap and plenty of water.If skin irritation persists, call a physician.: Immediately give plenty of water (if possible charcoal slurry).Oxygen or artificial respiration if needed.1/7


SAFETY DATA SHEETaccording to applicable EC directive<strong>Ident</strong>-<strong>No</strong>: <strong>HARDENER</strong> <strong>HY</strong> <strong>4076</strong>Version 1 Print Date 07.04.2009Revision Date 22.03.2009Do not induce vomiting.Call a physician immediately.5. FIRE-FIGHTING MEASURESSuitable extinguishingmediaExtinguishing media whichmust not be used for safetyreasonsSpecial protectiveequipment for fire-fightersFurther information: Water spray.Carbon dioxide (CO2).Foam.Dry powder.: High volume water jet.: Wear self-contained breathing apparatus and protective suit.: Burning produces obnoxious and toxic fumes.Carbon oxides.Nitrogen oxides.6. ACCIDENTAL RELEASE MEASURESEnvironmental precautionsMethods for cleaning up: Do not allow material to contaminate ground water system.Prevent product from entering drains.: Soak up with inert absorbent material and dispose of ashazardous waste.7. HANDLING AND STORAGEHandlingAdvice on safe handling: Provide sufficient air exchange and/or exhaust in work rooms.Avoid formation of aerosol.Ensure adequate ventilation.Handle and open container with care.StorageFurther information onstorage conditionsStorage hazard classHuntsman AdvancedMaterials: Keep away from food, drink and animal feeding stuffs.Keep container tightly closed.Keep at temperatures between 2 and 40°C.: Storage class 8, Corrosive substances2/7


SAFETY DATA SHEETaccording to applicable EC directive<strong>Ident</strong>-<strong>No</strong>: <strong>HARDENER</strong> <strong>HY</strong> <strong>4076</strong>Version 1 Print Date 07.04.2009Revision Date 22.03.20098. EXPOSURE <strong>CON</strong>TROLS / PERSONAL PROTECTIONComponents with workplace control parametersComponents CAS-<strong>No</strong>. ControlparametersEngineering measures<strong>No</strong> special precautions required.UpdateBasisPersonal protective equipmentRespiratory protection: In case of insufficient ventilation wear suitable respiratoryequipment.Filter type AX-P3 (organic vapours, particles)Eye protectionHand protectionSkin and body protectionProtective measures: Tightly fitting safety goggles.Face-shield.: Material of gloves for long term application (BTT>480 min):Butyl rubberEthyl Vinyl Alcohol Laminate (EVAL)Material of gloves for short term/splash application (10min


SAFETY DATA SHEETaccording to applicable EC directive<strong>Ident</strong>-<strong>No</strong>: <strong>HARDENER</strong> <strong>HY</strong> <strong>4076</strong>Version 1 Print Date 07.04.2009Revision Date 22.03.2009Vapour pressureDensity: < 1 Paat 25 °C: 0.97 g/cm3at 25 °CWater solubility : at 20 °C<strong>No</strong>te: partly miscibleMiscibility with waterViscosity, dynamic: miscible: 1 - 2 Pa.sat 25 °C10. STABILITY AND REACTIVITYConditions to avoidMaterials to avoidHazardous decompositionproducts: <strong>No</strong>te: Take necessary action to avoid static electricitydischarge.: Strong acids and strong bases.Strong oxidizing agents.: Carbon oxides.11. TOXICOLOGICAL INFORMATIONAcute oral toxicityAcute inhalation toxicityAcute dermal toxicityEye irritationSkin irritation: LD50 ratDose: > 2,000 mg/kg: LC50 ratDose: approx. 3 mg/l: LD50 rabbitDose: < 400 mg/kg: Corrosiverabbit: Corrosiverabbitdermal12. ECOLOGICAL INFORMATIONEcotoxicity effectsFurther information on ecologyAdditional ecologicalinformation: Avoid subsoil penetration.Prevent product from entering drains.4/7


SAFETY DATA SHEETaccording to applicable EC directive<strong>Ident</strong>-<strong>No</strong>: <strong>HARDENER</strong> <strong>HY</strong> <strong>4076</strong>Version 1 Print Date 07.04.2009Revision Date 22.03.2009Do not contaminate surface water.13. DISPOSAL <strong>CON</strong>SIDERATIONSProduct : Waste Key Number: 070204Must be incinerated, when in compliance with local regulations.Container: Empty containers can be landfilled after cleaning, when incompliance with the Environmental Protection (Duty of Care)Regulations 1991.14. TRANSPORT INFORMATIONLand transportADR:UN-<strong>No</strong>: 2922Class: 8Classification code: CT1Packaging group: IIRisk <strong>No</strong>.: 86ADR/RID-Labels: 8, 6.1Proper shipping name: CORROSIVE LIQUID, TOXIC, N.O.S.contains:DIOXADODECANE DI<strong>AMI</strong>NERID:UN-<strong>No</strong>: 2922Class: 8Packaging group: IIRisk <strong>No</strong>.: 86ADR/RID-Labels: 8, 6.1Proper shipping name: CORROSIVE LIQUID, TOXIC, N.O.S.contains:DIOXADODECANE DI<strong>AMI</strong>NESea transportIMDG:UN-<strong>No</strong>: 2922Class: 8Packaging group: IIADR/RID-Labels: 8, 6.1MFAG:EmS:F-A S-BProper shipping name: CORROSIVE LIQUID, TOXIC, N.O.S.contains:(DIOXADODECANE DI<strong>AMI</strong>NE)Air transportIATA-DGR:5/7


SAFETY DATA SHEETaccording to applicable EC directive<strong>Ident</strong>-<strong>No</strong>: <strong>HARDENER</strong> <strong>HY</strong> <strong>4076</strong>Version 1 Print Date 07.04.2009Revision Date 22.03.2009UN/ID <strong>No</strong>.: UN 2922Class: 8Packaging group: IIPacking instruction (cargo 812aircraft):Max. Qty/Pack.:30.00 L( 999.00 = <strong>No</strong> limit )Packing instruction 808(passenger aircraft):Max. Qty/Pack.:1.00 L( 999.00 = <strong>No</strong> limit )ADR/RID-Labels: 8, 6.1Proper shipping name: CORROSIVE LIQUID, TOXIC, N.O.S.contains:(DIOXADODECANE DI<strong>AMI</strong>NE)15. REGULATORY INFORMATIONLabelling according to EEC DirectiveLabelling requiredSymbol(s): : T ToxicR-phrase(s) : R34 Causes burns.R24Toxic in contact with skin.R20Harmful by inhalation.S-phrase(s) : S26 In case of contact with eyes, rinseimmediately with plenty of water and seekmedical advice.S36/37/39 Wear suitable protective clothing, glovesand eye/face protection.S28After contact with skin, wash immediatelywith plenty of soap and water.Hazardous componentswhich must be listed on thelabel: dioxadodecanediamine C, R34, R20EC-<strong>No</strong>.: 230-745-9National legislation<strong>No</strong>tification status: INV (CN) yes: EINECS not requiredPolymer6/7


SAFETY DATA SHEETaccording to applicable EC directive<strong>Ident</strong>-<strong>No</strong>: <strong>HARDENER</strong> <strong>HY</strong> <strong>4076</strong>Version 1 Print Date 07.04.2009Revision Date 22.03.2009: TSCA no16. OTHER INFORMATIONList of R-phrases (Section 3)R20R34Harmful by inhalation.Causes burns.The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognisedabbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an additionto the Health and Safety at Work Act 1974.Users of products supplied by Huntsman AdvancedMaterials should take appropriate measures to ensure working practices are in accordance with theControl of Substances Hazardous to Health Regulations (COSHH).All information is based on results gained from experience and tests and is believed to be accuratebut is given without acceptance of liability for loss or damage attributable to reliance thereon asconditions of use lie outside our control. Users should always carry out sufficient tests to establishthe suitability of any products for their intended applications. <strong>No</strong> statements shall be incorporated inany contract unless expressly agreed in writing nor construed as recommending the use of anyproduct in conflict of any patent. All goods are supplied subject to Huntsman Advanced MaterialsGeneral Conditions of Sale.7/7

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