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3M DP 410 MSDS - AMI-CON

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<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural AdhesiveSafety Data SheetCopyright, 2012, <strong>3M</strong> Company All rights reserved. Copying and/or downloading of this information for the purpose ofproperly utilising <strong>3M</strong> products is allowed provided that: (1) the information is copied in full with no changes unless priorwritten agreement is obtained from <strong>3M</strong>, and (2) neither the copy nor the original is resold or otherwise distributed with theintention of earning a profit thereon.Document group: 18-9394-0 Version number: 9.03Revision date: 23/05/2012 Supersedes date: 19/12/2011Transportation version number: 3.00 (22/05/2012)This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THECOMPANY/UNDERTAKING1.1. Product identifier<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural AdhesiveProduct identification numbersFS-9100-2874-5 FS-9100-4027-81.2. Relevant identified uses of the substance or mixture and uses advised againstAdhesive1.3. Details of the supplier of the substance or mixtureAddress: <strong>3M</strong> United Kingdom PLC, <strong>3M</strong> Centre, Cain Road, Bracknell, Berkshire, RG12 8HT.E Mail:Website:tox.uk@mmm.comwww.<strong>3M</strong>.com/uk1.4. Emergency telephone number+44 (0)1344 858 000This product is a kit or a multipart product which consists of multiple, independently packaged components. A SafetyData Sheet for each of these components is included. Please do not separate the component Safety Data Sheets fromthis cover page. The document numbers of the <strong>MSDS</strong>s for components of this product are:18-9393-2, 07-7184-0TRANSPORTATION INFORMATIONFS-9100-2874-5, FS-9100-4027-8Component 1ADR/RID: UN3263, CORROSIVE SOLID, BASIC, ORGANIC, N.O.S., LIMITED QUANTITY, (3,3'-OXYBIS(ETHYLENEOXY)BIS(PROPYL<strong>AMI</strong>NE)), 8, II , (--), ADR Classification Code: C8.IMDG-CODE: UN3263, CORROSIVE SOLID,BASIC,ORGANIC,N.O.S., (3,3'-OXYBIS(ETHYLENEOXY)BIS(PROPYL<strong>AMI</strong>NE)), 8., II , IMDG-Code segregation code: 18- ALKALIS, LIMITEDQUANTITY, EMS: FA,SB.__________________________________________________________________________________________Page: 1 of 2


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural AdhesiveICAO/IATA: FORBIDDEN: IATA PRESSURE TEST ACC. 5.0.2.9 NOT PERFORMED ONPACKAGEComponent 2ADR/RID: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID,N.O.S.LIMITED QUANTITY,(LIQUID EPOXY RESIN), 9., III, (--), ADR Classification Code: M6.IMDG-CODE: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (LIQUID EPOXYRESIN), 9., III, LIMITED QUANTITY, Marine Pollutant, (LIQUID EPOXY RESIN), EMS: FA,SF.ICAO/IATA: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (LIQUID EPOXYRESIN), 9., III, fish and tree marking may be required (> 5kg/l), LIMITED QUANTITY.KIT LABEL2.2. Label elementsDangerous substances(67/548/EEC)/preparations(1999/45/EC) directiveSymbolsCNCorrosive.Dangerous to environment.Contains:Consult the component labels for disclosable ingredients.Risk phrasesR34Causes burns.R4<strong>3M</strong>ay cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.Safety phrasesS23AS24S36/37/39BS26S28CS45S29S61S2Do not breathe vapour.Avoid contact with skin.Wear suitable protective clothing, gloves, and eye and face protection.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of water for 15 minutes.In case of accident or if you feel unwell, seek medical advice immediately (show the label wherepossible).Do not empty into drains.Avoid release to the environment. Refer to special instructions/safety data sheets.Keep out of the reach of children.Special provisions concerning the labelling of certain substancesContains epoxy resins. See information supplied by manufacturer.Revision information:Revision Changes:Copyright was modified.__________________________________________________________________________________________Page: 2 of 2


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)Safety Data SheetCopyright, 2012, <strong>3M</strong> Company All rights reserved. Copying and/or downloading of this information for the purpose ofproperly utilising <strong>3M</strong> products is allowed provided that: (1) the information is copied in full with no changes unless priorwritten agreement is obtained from <strong>3M</strong>, and (2) neither the copy nor the original is resold or otherwise distributed with theintention of earning a profit thereon.Document group: 07-7184-0 Version number: 9.04Revision date: 23/05/2012 Supersedes date: 20/01/2012Transportation version number: 1.00 (26/09/2011)This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.SECTION 1: Identification of the substance/mixture and of thecompany/undertaking1.1. Product identifier<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)1.2. Relevant identified uses of the substance or mixture and uses advised againstIdentified usesAdhesive, Accelerator for two-part epoxy structural adhesive.1.3. Details of the supplier of the substance or mixtureAddress: <strong>3M</strong> United Kingdom PLC, <strong>3M</strong> Centre, Cain Road, Bracknell, Berkshire, RG12 8HT.E Mail:Website:tox.uk@mmm.comwww.<strong>3M</strong>.com/uk1.4. Emergency telephone number+44 (0)1344 858 000SECTION 2: Hazard identification2.1. Classification of the substance or mixtureDangerous substances(67/548/EEC)/preparations(1999/45/EC) directiveIndication of dangerCorrosive.Sensitising2.2. Label elementsDangerous substances(67/548/EEC)/preparations(1999/45/EC) directiveSymbolsCCorrosive.Contains:4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane; 3,3'-__________________________________________________________________________________________Page: 1 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)Oxybis(ethyleneoxy)bis(propylamine)Risk phrasesR34Causes burns.R4<strong>3M</strong>ay cause sensitisation by skin contact.R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.Safety phrasesS51Use only in well ventilated areas.S23ADo not breathe vapour.S22Do not breathe dust.S24/25 Avoid contact with the skin and eyes.S36/37/39B Wear suitable protective clothing, gloves, and eye and face protection.S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S28CAfter contact with skin, wash immediately with plenty of water for 15 minutes.S45In case of accident or if you feel unwell, seek medical advice immediately (show the label wherepossible).S61Avoid release to the environment. Refer to special instructions/safety data sheets.Special provisions concerning the labelling of certain substancesContains epoxy resins. See information supplied by manufacturer.2.3. Other hazardsMay cause chemical gastrointestinal burns.SECTION 3: Composition/information on ingredientsIngredient CAS Nbr EU Inventory % by Wt Classification3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 EINECS 224-207-240 - 70 C:R34; R52/53 (Self Classified)Skin Corr. 1B, H314; AquaticChronic 3, H412 (Self4,4'-Isopropylidenediphenol, oligomericreaction products with 1-chloro-2,3-epoxypropane25068-38-6 NLP 500-033-52,4,6-Tris(dimethylaminomethyl)phenol 90-72-2 EINECS 202-013-9Bis[(dimethylamino)methyl]phenol 71074-89-0 EINECS 275-162-0Classified)15 - 30 Xi:R36-38; N:R51/53; R43 (EU)Skin Irrit. 2, H315; Eye Irrit. 2,H319; Skin Sens. 1, H317;Aquatic Chronic 2, H411 (CLP)7 - 13 Xn:R22; Xi:R36-38 (EU)Acute Tox. 4, H302; Skin Irrit.2, H315; Eye Irrit. 2, H319(CLP)0 - 0.9 C:R34 (Vendor)Xn:R22 (Self Classified)Skin Corr. 1B, H314 (Vendor)Acute Tox. 4, H302 (SelfClassified)Calcium Nitrate Tetrahydrate 13477-34-4 7 - 13 Xn:R22; Xi:R41 (SelfClassified)Acute Tox. 4, H302; Eye Dam.__________________________________________________________________________________________Page: 2 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)1, H318 (Self Classified)Please see section 16 for the full text of any R phrases and H statements referred to in this sectionPlease refer to section 15 for the any applicable Notas that have been applied to the above componentsFor information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDSSECTION 4: First aid measures4.1. Description of first aid measuresEye contactImmediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continuerinsing. Immediately get medical attention.Skin contactImmediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediatemedical attention. Wash clothing before reuse.InhalationRemove person to fresh air. If you feel unwell, get medical attention.If swallowedRinse mouth. Do not induce vomiting. Get immediate medical attention.4.2. Most important symptoms and effects, both acute and delayedSee Section 11.1 Information on toxicological effects4.3. Indication of any immediate medical attention and special treatment requiredNot applicableSECTION 5: Fire-fighting measures5.1. Extinguishing mediaIn case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.5.2. Special hazards arising from the substance or mixtureClosed containers exposed to heat from fire may build pressure and explode.Hazardous Decomposition or By-ProductsSubstanceAmine compounds.Carbon monoxide.Carbon dioxide.Oxides of nitrogen.ConditionDuring combustion.During combustion.During combustion.During combustion.5.3. Advice for fire-fightersWater may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool andprevent explosive rupture.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresKeep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Evacuate area. Ventilate__________________________________________________________________________________________Page: 3 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratoryprotection, ventilation, and personal protective equipment.6.2. Environmental precautionsAvoid release to the environment.6.3. Methods and material for containment and cleaning upWorking from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganicabsorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible usingnon-sparking tools. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air.Read and follow safety precautions on the solvent label and Safety Data Sheet. Place in a closed container approved fortransportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.6.4. Reference to other sectionsRefer to Section 8 and Section 13 for more informationSECTION 7: Handling and storage7.1. Precautions for safe handlingKeep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Donot get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Washcontaminated clothing before reuse. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoidcontact with oxidising agents (eg. chlorine, chromic acid etc.)7.2. Conditions for safe storage including any incompatibilitiesStore away from acids. Store away from oxidising agents. Store in a well-ventilated place. Keep cool.7.3. Specific end use(s)See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls andpersonal protection recommendations.SECTION 8: Exposure controls/personal protection8.1 Control parametersOccupational exposure limitsNo occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.Derived no effect level (DNEL)Ingredient4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropaneDegradationProductPopulationWorkerWorkerHuman exposurepatternDermal, Long-termexposure (8 hours),Systemic effectsDermal, Short-termexposure, SystemiceffectsDNEL8.3 mg/kg bw/d8.3 mg/kg4,4'- Worker Inhalation, Long-term 12.3 mg/m³__________________________________________________________________________________________Page: 4 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropaneWorkerexposure (8 hours),Systemic effectsInhalation, Short-termexposure, Systemiceffects12.3 mg/m³Predicted no effect concentrations (PNEC)IngredientDegradationProduct4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomeric reactionproducts with 1-chloro-2,3-epoxypropane8.2. Exposure controlsCompartmentFreshwaterFreshwater sedimentsIntermittent releases to waterMarine waterMarine water sedimentsSewage Treatment PlantPNEC0.003 mg/l0.5 mg/kg w.w.0.013 mg/l0.0003 mg/l0.5 mg/kg w.w.10 mg/l8.2.1. Engineering controlsUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant ExposureLimits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.8.2.2. Personal protective equipment (PPE)Eye/face protectionWear eye/face protection.__________________________________________________________________________________________Page: 5 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)The following eye protection(s) are recommended: Safety glasses with side shields.Indirect vented goggles.Skin/hand protectionWear protective gloves.Gloves made from the following material(s) are recommended: Polymer laminateRespiratory protectionSelect one of the following approved respirators based on airborne concentration of contaminants and in accordance withregulations:Half facepiece or full facepiece air-purifying respirator suitable for formaldehyde and particulatesHalf facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulatesSECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical stateLiquid.Specific Physical Form:PasteAppearance/OdourNon-sagging, off-white colour, typical epoxy resin odour.pHNot applicable.Boiling point/boiling rangeNot applicable.Melting pointNot applicable.Flammability (solid, gas) Flammable Liquid: Category 4.Explosive propertiesNot classifiedOxidising propertiesNot classifiedFlash point >=90 ºCAutoignition temperatureNot applicable.Flammable Limits(LEL)Not applicable.Flammable Limits(UEL)Not applicable.Vapour pressureNot applicable.Relative density± 1.09 g/mlWater solubilityNot applicable.Partition coefficient: n-octanol/waterEvaporation rateVapour densityViscosityDensityNo data available.No data available.Not applicable.No data available.1.09 g/ml9.2. Other informationVolatile organic compounds (VOC)No data available.Percent volatile


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)10.3 Possibility of hazardous reactionsHazardous polymerisation will not occur.10.4 Conditions to avoidHeat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature reaction(exothem) with production of intense heat and smoke.10.5 Incompatible materialsStrong oxidising agents.10.6 Hazardous decomposition productsSubstanceNone known.ConditionSECTION 11: Toxicological informationThe information below may not be consistent with the material classification in Section 2 if specific ingredientclassifications are mandated by a competent authority. In addition, toxicological data on ingredients may not bereflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may bepresent below the threshold for labelling, an ingredient may not be available for exposure, or the data may not berelevant to the material as a whole.11.1 Information on Toxicological effectsSigns and Symptoms of ExposureBased on test data and/or information on the components, this material may produce the following health effects:Eye contactCorrosive (eye burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,ulcerations, significantly impaired vision or complete loss of vision. Dust created by cutting, grinding, sanding, or machiningmay cause eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.Skin contactAllergic skin reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Corrosive(skin burns): Signs/symptoms may include localised redness, swelling, itching, intense pain, blistering, ulceration, and tissuedestruction.InhalationRespiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and noseand throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system:Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat pain.IngestionGastrointestinal corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, anddiarrhea; blood in the faeces and/or vomitus may also be seen. May be harmful if swallowed.Toxicological DataAcute ToxicityName Route Species ValueOverall product Ingestion No test data available; calculated ATE3,392__________________________________________________________________________________________Page: 7 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)3,3'-Oxybis(ethyleneoxy)bis(propylamine)3,3'-Oxybis(ethyleneoxy)bis(propylamine)4,4'-Isopropylidenediphenol,oligomeric reaction products with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomeric reaction products with 1-chloro-2,3-epoxypropane2,4,6-Tris(dimethylaminomethyl)phenol2,4,6-Tris(dimethylaminomethyl)phenolmg/kgDermal Rabbit LD50 2,500 mg/kgIngestion Rat LD50 3,160 mg/kgDermal Rat LD50 > 1,600 mg/kgIngestion Rat LD50 > 1,000 mg/kgDermal Rat LD50 1,280 mg/kgIngestion Rat LD50 1,000 mg/kgCalcium Nitrate TetrahydrateNo data availableBis[(dimethylamino)methyl]phenol Ingestion LD50 estimated to be 300 - 2,000 mg/kgATE = acute toxicity estimateSkin Corrosion/IrritationName Species Value3,3'-Oxybis(ethyleneoxy)bis(propylamine)Corrosive4,4'-Isopropylidenediphenol, oligomeric reactionMild irritantproducts with 1-chloro-2,3-epoxypropane2,4,6-Tris(dimethylaminomethyl)phenolIrritantCalcium Nitrate TetrahydrateNo data availableBis[(dimethylamino)methyl]phenolNo data availableSerious Eye Damage/IrritationName Species Value3,3'-Oxybis(ethyleneoxy)bis(propylamine)Corrosive4,4'-Isopropylidenediphenol, oligomeric reactionModerate irritantproducts with 1-chloro-2,3-epoxypropane2,4,6-Tris(dimethylaminomethyl)phenolSevere irritantCalcium Nitrate TetrahydrateNo data availableBis[(dimethylamino)methyl]phenolNo data availableSkin SensitisationName Species Value3,3'-Oxybis(ethyleneoxy)bis(propylamine)No data available4,4'-Isopropylidenediphenol, oligomeric reactionSensitisingproducts with 1-chloro-2,3-epoxypropane2,4,6-Tris(dimethylaminomethyl)phenolNot sensitizingCalcium Nitrate TetrahydrateNo data availableBis[(dimethylamino)methyl]phenolNo data availableRespiratory SensitisationName Species Value3,3'-Oxybis(ethyleneoxy)bis(propylamine)No data available4,4'-Isopropylidenediphenol, oligomeric reactionproducts with 1-chloro-2,3-epoxypropaneSome positive data exist, but the data are notsufficient for classification2,4,6-Tris(dimethylaminomethyl)phenolNo data availableCalcium Nitrate TetrahydrateNo data availableBis[(dimethylamino)methyl]phenolNo data availableGerm Cell MutagenicityName Route Value__________________________________________________________________________________________Page: 8 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)3,3'-Oxybis(ethyleneoxy)bis(propylamine)No data available4,4'-Isopropylidenediphenol, oligomeric reactionproducts with 1-chloro-2,3-epoxypropaneIn vivoSome positive data exist, but the data are notsufficient for classification2,4,6-Tris(dimethylaminomethyl)phenol In Vitro Not mutagenicCalcium Nitrate TetrahydrateNo data availableBis[(dimethylamino)methyl]phenolNo data availableCarcinogenicityName Route Species Value3,3'-No data availableOxybis(ethyleneoxy)bis(propylamine)4,4'-Isopropylidenediphenol,oligomeric reaction products with 1-DermalSome positive data exist, but the dataare not sufficient for classificationchloro-2,3-epoxypropane2,4,6-No data availableTris(dimethylaminomethyl)phenolCalcium Nitrate TetrahydrateNo data availableBis[(dimethylamino)methyl]phenolNo data availableReproductive ToxicityReproductive and/or Developmental EffectsName Route Value Species Test result Exposure Duration3,3'-No data availableOxybis(ethyleneoxy)bis(propylamine)4,4'-Isopropylidenediphenol, oligomericreaction productswith 1-chloro-2,3-epoxypropaneDermalNot toxic toreproduction and/ordevelopmentNOAEL 300mg/kg/day4,4'-Isopropylidenediphenol, oligomericreaction productswith 1-chloro-2,3-epoxypropane2,4,6-Tris(dimethylaminomethyl)phenolCalcium NitrateTetrahydrateBis[(dimethylamino)methyl]phenolTarget Organ(s)IngestionNot toxic toreproduction and/ordevelopmentNo data availableNo data availableNo data availableSpecific Target Organ Toxicity - single exposureName Route TargetOrgan(s)3,3'-Oxybis(ethyleneoxy)bis(propylamine)4,4'-Isopropylidenediphenol,InhalationInhalationrespiratoryirritationrespiratoryirritationNOAEL 750mg/kg/dayValue Species Test result ExposureDurationSome positiveIrritationdata exist, but thePositivedata are notsufficient forclassificationAll data arenegativeIrritationNegative__________________________________________________________________________________________Page: 9 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)oligomericreactionproducts with1-chloro-2,3-epoxypropane2,4,6-Tris(dimethylaminomethyl)phenolCalciumNitrateTetrahydrateBis[(dimethylamino)methyl]phenolInhalationrespiratoryirritationSome positivedata exist, but thedata are notsufficient forclassificationNo data availableNo data availableIrritationPositiveSpecific Target Organ Toxicity - repeated exposureName Route TargetOrgan(s)Value Species Test result ExposureDuration3,3'-No data availableOxybis(ethyleneoxy)bis(propylamine)4,4'-Isopropylidenediphenol,oligomericreactionproducts with1-chloro-2,3-epoxypropaneDermal liver Some positivedata exist, but thedata are notsufficient forclassificationNOEL 1mg/kg/day4,4'-Isopropylidenediphenol,oligomericreactionproducts with1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomericreactionproducts with1-chloro-2,3-epoxypropane2,4,6-Tris(dimethylaminomethyl)phenol2,4,6-Tris(dimethylaminomethyl)phenol2,4,6-Tris(dimethylaminomethyl)Dermal nervous system All data arenegativeIngestionDermalauditory system| heart |endocrinesystem | blood |hematopoieticsystem | liver |eyes | kidneyand/or bladderskin | nervoussystemAll data arenegativeSome positivedata exist, but thedata are notsufficient forclassificationDermal liver Some positivedata exist, but thedata are notsufficient forclassificationDermalauditory system| hematopoieticsystem | eyesAll data arenegativeNOAEL 1,000mg/kg/dayNOAEL 1,000mg/kg/dayNOEL 5mg/kg/dayNOEL 25mg/kg/dayNOAEL 125mg/kg/day__________________________________________________________________________________________Page: 10 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)phenolCalciumNitrateTetrahydrateBis[(dimethylamino)methyl]phenolNo data availableNo data availableAspiration HazardName3,3'-Oxybis(ethyleneoxy)bis(propylamine)4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane2,4,6-Tris(dimethylaminomethyl)phenolCalcium Nitrate TetrahydrateBis[(dimethylamino)methyl]phenolValueNot an aspiration hazardNot an aspiration hazardNot an aspiration hazardNot an aspiration hazardNot an aspiration hazardPlease contact the address or phone number listed on the first page of the SDS for additional toxicological informationon this material and/or its components.SECTION 12: Ecological informationThe information below may not be consistent with the material classification in Section 2 if specific ingredient classificationsare mandated by a competent authority. Additional information leading to material classification in Section 2 is availableupon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because aningredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the datais considered not relevant to the material as a whole.12.1. ToxicityAcute aquatic hazard:GHS Acute 3: Harmful to aquatic life.Chronic aquatic hazard:GHS Chronic 3: Harmful to aquatic life with long lasting effects.No product test data available.No component test data available.12.2. Persistence and degradabilityNo test data available.12.3 : Bioaccumulative potentialNo test data available.12.4. Mobility in soilPlease contact manufacturer for more details12.5. Results of the PBT and vPvB assessmentNo information available at this time, contact manufacturer for more details12.6. Other adverse effectsNo information available.SECTION 13: Disposal considerations__________________________________________________________________________________________Page: 11 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)13.1 Waste treatment methodsDispose of contents/ container in accordance with the local/regional/national/international regulationsIncinerate uncured product in a permitted waste incineration facility. Dispose of completely cured (or polymerised) materialin a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incinerationfacility. If no other disposal options are available, waste product that has been completely cured or polymerised may beplaced in a landfill properly designed for industrial waste.The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of<strong>3M</strong>, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC - 2000/532/ECand amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations arecomplied with and always use a licensed waste contractor.EU waste code (product as sold)08 04 09* Waste adhesives and sealants containing organic solvents or other dangerous substances20 01 27* Paint, inks, adhesives and resins containing dangerous substancesSECTION 14: Transportation informationADR: UN3263; Corrosive solid, basic, organic, N.O.S., limited quantity, (3,3'-oxybis(ethyleneoxy)bis(propylamine)); 8; II;C8.IMDG: UN3263; Corrosive solid, basic, organic, N.O.S., (3,3'-oxybis(ethyleneoxy)bis(propylamine)); 8; II; EmS FA,SB.IATA: Forbidden - IATA pressure test ACC. 5.0.2.9 not performed on packageSECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureGlobal inventory statusContact <strong>3M</strong> for more information. The components of this material are in compliance with the provisions of the KoreanToxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. Thecomponents of this material are in compliance with the provisions of Australia National Industrial Chemical Notification andAssessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. Thecomponents of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certainrestrictions may apply. Contact the selling division for additional information. The components of this material are incompliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the sellingdivision for additional information. The components of this product are in compliance with the new substance notificationrequirements of CEPA. The components of this product are in compliance with the chemical notification requirements ofTSCA.15.2. Chemical Safety AssessmentNot applicableSECTION 16: Other informationList of relevant H statementsH302H314H315H317H318H319Harmful if swallowed.Causes severe skin burns and eye damage.Causes skin irritation.May cause an allergic skin reaction.Causes serious eye damage.Causes serious eye irritation.__________________________________________________________________________________________Page: 12 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part A)H411H412Toxic to aquatic life with long lasting effects.Harmful to aquatic life with long lasting effects.List of relevant R-phrasesR22Harmful if swallowed.R34Causes burns.R36Irritating to eyes.R38Irritating to skin.R41Risk of serious damage to eyes.R4<strong>3M</strong>ay cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.Revision information:Revision Changes:Section 8: Respiratory protection - recommended respirators information was modified.Section 14: Transportation classification was modified.Aspiration Hazard Table was modified.Section 11: Acute Toxicity table was modified.Carcinogenicity Table was modified.Serious Eye Damage/Irritation Table was modified.Germ Cell Mutagenicity Table was modified.Skin Sensitisation Table was modified.Respiratory Sensitisation Table was modified.Reproductive Toxicity Table was modified.Skin Corrosion/Irritation Table was modified.Target Organs - Repeated Table was modified.Target Organs - Single Table was modified.Section 8: 8.1. Derived no effect level (DNEL) table heading was added.Section 8: 8.1. Predicted no effect concentrations (PNEC) table heading was added.Section 8: 8.1. Derived no effect level (DNEL) table ingredient column heading was added.Section 8: 8.1. Derived no effect level (DNEL) table population column heading was added.Section 8: 8.1. Derived no effect level (DNEL) table human exposure pattern column heading was added.Section 8: 8.1. Derived no effect level (DNEL) table DNEL column heading was added.Section 8: DNEL table row was added.Section 8: 8.1. Predicted no effect concentrations (PNEC) table ingredient column heading was added.Section 8: 8.1. Predicted no effect concentrations (PNEC) table compartment column heading was added.Section 8: 8.1. Predicted no effect concentrations (PNEC) table PNEC column heading was added.Section 8: PNEC table row was added.Section 8: 8.1. Derived no effect level (DNEL) table Degradation Product column heading was added.Section 8: 8.1. Predicted no effect concentrations (PNEC) table Degradation Product column heading was added.Section 11: UN GHS Classification table heading was deleted.DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of ourknowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of theproduct in combination with other materials. For these reasons, it is important that customers carry out their own test tosatisfy themselves as to the suitability of the product for their own intended applications.<strong>3M</strong> United Kingdom <strong>MSDS</strong>s are available at www.<strong>3M</strong>.com/uk__________________________________________________________________________________________Page: 13 of 13


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)Safety Data SheetCopyright, 2011, <strong>3M</strong> Company All rights reserved. Copying and/or downloading of this information for the purpose ofproperly utilising <strong>3M</strong> products is allowed provided that: (1) the information is copied in full with no changes unless priorwritten agreement is obtained from <strong>3M</strong>, and (2) neither the copy nor the original is resold or otherwise distributed with theintention of earning a profit thereon.Document group: 18-9393-2 Version number: 8.02Revision date: 19/12/2011 Supersedes date: 26/09/2011Transportation version number: 1.00 (26/09/2011)This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.SECTION 1: Identification of the substance/mixture and of thecompany/undertaking1.1. Product identifier<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)1.2. Relevant identified uses of the substance or mixture and uses advised againstIdentified usesAdhesive, Base for two-part epoxy adhesive.1.3. Details of the supplier of the substance or mixtureAddress: <strong>3M</strong> United Kingdom PLC, <strong>3M</strong> Centre, Cain Road, Bracknell, Berkshire, RG12 8HT.E Mail:Website:tox.uk@mmm.comwww.<strong>3M</strong>.com/uk1.4. Emergency telephone number+44 (0)1344 858 000SECTION 2: Hazard identification2.1. Classification of the substance or mixtureDangerous substances(67/548/EEC)/preparations(1999/45/EC) directiveIndication of dangerDangerous to environment.Irritant.Sensitising2.2. Label elementsDangerous substances(67/548/EEC)/preparations(1999/45/EC) directiveSymbolsXiNIrritant.Dangerous to environment.__________________________________________________________________________________________Page: 1 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)Contains:2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxirane; 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropaneRisk phrasesR36/38 Irritating to eyes and skin.R4<strong>3M</strong>ay cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.Safety phrasesS24S37S61Avoid contact with skin.Wear suitable gloves.Avoid release to the environment. Refer to special instructions/safety data sheets.Special provisions concerning the labelling of certain substancesContains epoxy resins. See information supplied by manufacturer.2.3. Other hazardsNone known.SECTION 3: Composition/information on ingredientsIngredient CAS Nbr EU Inventory % by Wt Classification4,4'-Isopropylidenediphenol, oligomericreaction products with 1-chloro-2,3-epoxypropane25068-38-6 NLP 500-033-560 - 100 Xi:R36-38; N:R51/53; R43 (EU)Skin Irrit. 2, H315; Eye Irrit. 2,H319; Skin Sens. 1, H317;2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene - styrenepolymerDimethyl siloxane, reaction product withsilica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane71033-08-4 EINECS 275-143-725053-09-2 7 - 1367762-90-7 1 - 52530-83-8 EINECS 219-784-2Aquatic Chronic 2, H411 (CLP)10 - 20 Xi:R36-38; R43 (Vendor)Skin Irrit. 2, H315; Eye Irrit. 2,H319; Skin Sens. 1, H317(Vendor)0.5 - 1.5 Xi:R38-41 (Self Classified)Skin Irrit. 2, H315; Eye Dam. 1,H318 (Self Classified)Please see section 16 for the full text of any R phrases and H statements referred to in this sectionPlease refer to section 15 for the any applicable Notas that have been applied to the above componentsFor information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDSSECTION 4: First aid measures4.1. Description of first aid measuresEye contactImmediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medicalattention.__________________________________________________________________________________________Page: 2 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)Skin contactImmediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,get medical attention.InhalationRemove person to fresh air. If you feel unwell, get medical attention.If swallowedRinse mouth. If you feel unwell, get medical attention.4.2. Most important symptoms and effects, both acute and delayedSee Section 11.1 Information on toxicological effects4.3. Indication of any immediate medical attention and special treatment requiredNot applicableSECTION 5: Fire-fighting measures5.1. Extinguishing mediaIn case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.5.2. Special hazards arising from the substance or mixtureClosed containers exposed to heat from fire may build pressure and explode.Hazardous Decomposition or By-ProductsSubstanceAldehydes.Carbon monoxide.Carbon dioxide.ConditionDuring combustion.During combustion.During combustion.5.3. Advice for fire-fightersWater may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool andprevent explosive rupture.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresKeep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Evacuate area. Ventilatethe area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratoryprotection, ventilation, and personal protective equipment.6.2. Environmental precautionsAvoid release to the environment.6.3. Methods and material for containment and cleaning upWorking from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganicabsorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible usingnon-sparking tools. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air.Read and follow safety precautions on the solvent label and Safety Data Sheet. Place in a closed container approved fortransportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.6.4. Reference to other sections__________________________________________________________________________________________Page: 3 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)Refer to Section 8 and Section 13 for more informationSECTION 7: Handling and storage7.1. Precautions for safe handlingAvoid eye contact. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathingdust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using thisproduct. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoidrelease to the environment. Wash contaminated clothing before reuse. Avoid breathing of dust created by cutting, sanding,grinding or machining. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)7.2. Conditions for safe storage including any incompatibilitiesStore away from acids. Store away from oxidising agents. Store in a well-ventilated place. Keep cool.7.3. Specific end use(s)See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls andpersonal protection recommendations.SECTION 8: Exposure controls/personal protection8.1 Control parametersOccupational exposure limitsNo occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.8.2. Exposure controls8.2.1. Engineering controlsUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant ExposureLimits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.8.2.2. Personal protective equipment (PPE)Eye/face protectionWear eye/face protection.The following eye protection(s) are recommended: Safety glasses with side shields.Indirect vented goggles.Skin/hand protectionWear protective gloves.Gloves made from the following material(s) are recommended: Polymer laminateRespiratory protectionSelect one of the following approved respirators based on airborne concentration of contaminants and in accordance withregulations:Half facepiece or fullface air-purifying respirator with formaldehyde cartridges and P3 particulate prefilters.Half facepiece or fullface air-purifying respirator with formaldehyde cartridges and P2 particulate prefilters.Half facepiece or fullface air-purifying respirator with organic vapour cartridges and P2 particulate prefilters.SECTION 9: Physical and chemical properties__________________________________________________________________________________________Page: 4 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)9.1. Information on basic physical and chemical propertiesPhysical stateLiquid.Specific Physical Form:PasteAppearance/OdourNon-sagging, off-white colour, typical epoxy resin odour.pHNot applicable.Boiling point/boiling rangeNot applicable.Melting pointNot applicable.Flammability (solid, gas) Flammable Liquid: Category 4.Explosive propertiesNot classifiedOxidising propertiesNot classifiedFlash point >=90 ºCAutoignition temperatureNot applicable.Flammable Limits(LEL)Not applicable.Flammable Limits(UEL)Not applicable.Vapour pressureNot applicable.Relative density± 1.15 g/mlWater solubilityNot applicable.Partition coefficient: n-octanol/waterEvaporation rateVapour densityViscosityDensityNo data available.No data available.Not applicable.No data available.1.15 g/ml9.2. Other informationVolatile organic compounds (VOC)No data available.Percent volatile


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)SECTION 11: Toxicological informationThe information below may not be consistent with the material classification in Section 2 if specific ingredientclassifications are mandated by a competent authority. In addition, toxicological data on ingredients may not bereflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may bepresent below the threshold for labelling, an ingredient may not be available for exposure, or the data may not berelevant to the material as a whole.11.1 Information on Toxicological effectsSigns and Symptoms of ExposureBased on test data and/or information on the components, this material may produce the following health effects:Eye contactSevere eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of thecornea, and impaired vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation:Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.Skin contactAllergic skin reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. SkinIrritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.InhalationVapours released during curing may cause irritation of the respiratory system: Signs/symptoms may include cough, sneezing,nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining maycause irritation of the respiratory system: Signs/symptoms may include cough, sneezing, nasal discharge, headache,hoarseness, nose and throat pain.IngestionGastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.Toxicological DataAcute ToxicityName Route Species Value UN GHS ClassificationOverall product Ingestion No test data available;calculated ATE >5,000Not classified(12.66% unknown)mg/kg4,4'-Isopropylidenediphenol, Dermal Rat LD50 > 1,600 mg/kg Not classifiedoligomeric reaction products with 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol, Ingestion Rat LD50 > 1,000 mg/kg Not classifiedoligomeric reaction products with 1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-No data availablephenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene - Dermal Rabbit LD50 >= 5,000 mg/kg Not classifiedstyrene polymerMethyl methacrylate - butadiene - Ingestion Rat LD50 >= 5,000 mg/kg Not classifiedstyrene polymerDimethyl siloxane, reaction product Dermal Rabbit LD50 > 5,000 mg/kg Not classifiedwith silicaDimethyl siloxane, reaction productwith silicaInhalation-Dust/Mist (4Rat LC50 > 0.691 mg/l Category5__________________________________________________________________________________________Page: 6 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)Dimethyl siloxane, reaction productwith silica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneATE = acute toxicity estimatehours)Ingestion Rat LD50 > 5,110 mg/kg Not classifiedDermal Rabbit LD50 4,000 mg/kg Category5Inhalation-Dust/Mist (4hours)Rat LC50 > 5 mg/l Category5Ingestion Rat LD50 7,010 mg/kg Not classifiedSkin Corrosion/IrritationName Species Value UN GHS ClassificationOverall productNo test data available; Category 2calculated to be irritant4,4'-Isopropylidenediphenol, oligomericMild irritant Category 3reaction products with 1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-No data availablephenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene - styreneMinimal irritationNot classifiedpolymerDimethyl siloxane, reaction product with Rabbit No significant irritation Not classifiedsilica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneMild irritant Category 3Serious Eye Damage/IrritationName Species Value UN GHS ClassificationOverall productNo test data available; Category 2Acalculated to be severe irritant4,4'-Isopropylidenediphenol, oligomericModerate irritantCategory 2Breaction products with 1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-No data availablephenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene - styreneMild irritantNot classifiedpolymerDimethyl siloxane, reaction product with Rabbit No significant irritation Not classifiedsilica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneCorrosive Category 1Skin SensitisationName Species Value UN GHS ClassificationOverall product No test data available. Category 1 based on componentdata4,4'-Isopropylidenediphenol, oligomericSensitising Category 1reaction products with 1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-No data availablephenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene - styreneNo data available__________________________________________________________________________________________Page: 7 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)polymerDimethyl siloxane, reaction product withsilica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneHuman andanimalNot sensitizingSome positive data exist, butthe data are not sufficient forclassificationNot classifiedNot classifiedRespiratory SensitisationName Species Value UN GHS ClassificationOverall product No test data available. Not classified based oncomponent data4,4'-Isopropylidenediphenol, oligomericreaction products with 1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene - styrenepolymerDimethyl siloxane, reaction product withsilica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneSome positive data exist, butthe data are not sufficient forclassificationNo data availableNo data availableNo data availableNo data availableNot classifiedGerm Cell MutagenicityName Route Value UN GHS ClassificationOverall product No data available Overall Germ Cell Mutagenicityclassification Not classifiedOverall product4,4'-Isopropylidenediphenol, oligomericreaction products with 1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene - styrenepolymerDimethyl siloxane, reaction product withsilica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneIn vivoNo test data available.Some positive data exist, butthe data are not sufficient forclassificationNo data availableNo data availableNot classifiedIn Vitro Not mutagenic Not classifiedIn vivoSome positive data exist, butthe data are not sufficient forclassificationNot classifiedCarcinogenicityName Route Species Value UN GHS ClassificationOverall product No test data available. Not classified based oncomponent data4,4'-Isopropylidenediphenol,oligomeric reaction products with 1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene -styrene polymerDermalSome positive dataexist, but the data arenot sufficient forclassificationNo data availableNo data availableNot classifiedDimethyl siloxane, reaction product Not specified. Mouse Some positive data Not classified__________________________________________________________________________________________Page: 8 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)with silica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneexist, but the data arenot sufficient forclassificationDermal Not carcinogenic Not classifiedReproductive ToxicityReproductive and/or Developmental EffectsName Route Value Species Test result ExposureDurationOverall productNo test dataavailable.4,4'-Isopropylidenediphenol, oligomericreaction productswith 1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol, oligomericreaction productswith 1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate- butadiene - styrenepolymerDimethyl siloxane,reaction product withsilicaDimethyl siloxane,reaction product withsilicaDimethyl siloxane,reaction product withsilica[3-(2,3-Epoxypropoxy)propyl] trimethoxysilaneDermalIngestionIngestionIngestionIngestionIngestionNot toxic toreproduction and/ordevelopmentNot toxic toreproduction and/ordevelopmentNo data availableNo data availableNot toxic to femalereproductionNot toxic to malereproductionNot toxic todevelopmentNot toxic toreproduction and/ordevelopmentRatRatRatNOAEL300mg/kg/dayNOAEL750mg/kg/dayNOAEL509mg/kg/dayNOAEL497mg/kg/dayNOAEL1,350mg/kg/dayNOAEL1,500mg/kg/day1 generation1 generationduringorganogenesisUN GHSClassificationNot classifiedbased oncomponent dataTarget Organ(s)Specific Target Organ Toxicity - single exposureName Route TargetOrgan(s)Value Species Test result ExposureDurationOverallNo test dataproductavailable.4,4'-Isopropylidenediphenol,oligomericInhalationrespiratoryirritationAll data arenegativeIrritationNegativeUN GHSClassificationNot classifiedbased oncomponent dataNot classified__________________________________________________________________________________________Page: 9 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)reactionproducts with1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethylmethacrylate -butadiene -styrenepolymerDimethylsiloxane,reactionproduct withsilica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneInhalationrespiratoryirritationNo dataavailableNo dataavailableNo dataavailableAll data arenegativeIrritationNegativeNot classifiedSpecific Target Organ Toxicity - repeated exposureName Route TargetOrgan(s)Value Species Test result ExposureDurationOverallNo test dataproductavailable.4,4'-Isopropylidenediphenol,oligomericreactionproducts with1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomericreactionproducts with1-chloro-2,3-epoxypropane4,4'-Isopropylidenediphenol,oligomericreactionproducts with1-chloro-2,3-epoxypropaneDermal liver Some positive dataexist, but the dataare not sufficientfor classificationDermalIngestionnervoussystemauditorysystem |heart |endocrinesystem |blood |hematopoietic system |liver | eyes| kidneyAll data arenegativeAll data arenegativeNOEL 1mg/kg/dayNOAEL1,000mg/kg/dayNOAEL1,000mg/kg/dayUN GHSClassificationNot classifiedbased oncomponent dataNot classifiedNot classifiedNot classified__________________________________________________________________________________________Page: 10 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethylmethacrylate -butadiene -styrenepolymerDimethylsiloxane,reactionproduct withsilica[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneInhalationand/orbladderrespiratorysystem |silicosisIngestion heart |endocrinesystem |bone, teeth,nails,and/or hair|hematopoietic system |liver |immunesystem |nervoussystem |kidneyand/orbladder |respiratorysystemNo data availableNo data availableAll data arenegativeAll data arenegativeHumanNOAELNotavailableNOAEL1,000mg/kg/dayoccupationalexposureNot classifiedNot classifiedAspiration HazardName Value UN GHS ClassificationOverall product No test data available. Not classified based oncomponent and/or viscositydata4,4'-Isopropylidenediphenol, oligomeric reaction products with Not an aspiration hazard Not classified1-chloro-2,3-epoxypropane2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1-Not an aspiration hazard Not classified(butoxymethyl)ethylene]oxymethylene]]bisoxiraneMethyl methacrylate - butadiene - styrene polymer Not an aspiration hazard Not classifiedDimethyl siloxane, reaction product with silica Not an aspiration hazard Not classified[3-(2,3-Epoxypropoxy)propyl] trimethoxysilane Not an aspiration hazard Not classifiedPlease contact the address or phone number listed on the first page of the SDS for additional toxicological informationon this material and/or its components.SECTION 12: Ecological informationThe information below may not be consistent with the material classification in Section 2 if specific ingredient classifications__________________________________________________________________________________________Page: 11 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)are mandated by a competent authority. Additional information leading to material classification in Section 2 is availableupon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because aningredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the datais considered not relevant to the material as a whole.12.1. ToxicityAcute aquatic hazard:GHS Acute 3: Harmful to aquatic life.Chronic aquatic hazard:Not chronically toxic to aquatic life by GHS criteria.No product test data available.No component test data available.12.2. Persistence and degradabilityNo test data available.12.3 : Bioaccumulative potentialNo test data available.12.4. Mobility in soilPlease contact manufacturer for more details12.5. Results of the PBT and vPvB assessmentNo information available at this time, contact manufacturer for more details12.6. Other adverse effectsNo information available.SECTION 13: Disposal considerations13.1 Waste treatment methodsDispose of contents/ container in accordance with the local/regional/national/international regulationsIncinerate uncured product in a permitted waste incineration facility. Dispose of completely cured (or polymerised) materialin a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incinerationfacility. If no other disposal options are available, waste product that has been completely cured or polymerised may beplaced in a landfill properly designed for industrial waste.The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of<strong>3M</strong>, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC - 2000/532/ECand amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations arecomplied with and always use a licensed waste contractor.EU waste code (product as sold)08 04 09* Waste adhesives and sealants containing organic solvents or other dangerous substances20 01 27* Paint, inks, adhesives and resins containing dangerous substancesSECTION 14: Transportation informationADR: UN3082; Environmentally hazardous substance, liquid, N.O.S., limited quantity, (liquid epoxy resin); 9; III; M6.IMDG: UN3082; Environmentally hazardous substance, liquid, N.O.S., (liquid epoxy resin); 9; III; EmS FA,SF.__________________________________________________________________________________________Page: 12 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)IATA: UN3082; Environmentally hazardous substance, liquid, N.O.S., (liquid epoxy resin); 9; III.SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureGlobal inventory statusContact <strong>3M</strong> for more information. The components of this material are in compliance with the provisions of the KoreanToxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. Thecomponents of this material are in compliance with the provisions of Australia National Industrial Chemical Notification andAssessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. Thecomponents of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certainrestrictions may apply. Contact the selling division for additional information. The components of this material are incompliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the sellingdivision for additional information. The components of this product are in compliance with the new substance notificationrequirements of CEPA. The components of this product are in compliance with the chemical notification requirements ofTSCA.15.2. Chemical Safety AssessmentNot applicableSECTION 16: Other informationList of relevant H statementsH315H317H318H319H411Causes skin irritation.May cause an allergic skin reaction.Causes serious eye damage.Causes serious eye irritation.Toxic to aquatic life with long lasting effects.List of relevant R-phrasesR36Irritating to eyes.R38Irritating to skin.R41Risk of serious damage to eyes.R4<strong>3M</strong>ay cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.Revision information:Revision Changes:Germ Cell Mutagenicity Table was modified.Section 11: Health Effects - Skin information was modified.Section 6: Accidental release personal information was modified.Section 6: Accidental release clean-up information was modified.Section 7: Precautions safe handling information was modified.Section 13: Standard Phrase Category Waste GHS was modified.Section 14: Transportation classification was added.DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of ourknowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of theproduct in combination with other materials. For these reasons, it is important that customers carry out their own test tosatisfy themselves as to the suitability of the product for their own intended applications.<strong>3M</strong> United Kingdom <strong>MSDS</strong>s are available at www.<strong>3M</strong>.com/uk__________________________________________________________________________________________Page: 13 of 14


<strong>3M</strong> Scotch-Weld <strong>DP</strong>-<strong>410</strong> NS Epoxy Structural Adhesive (Part B)__________________________________________________________________________________________Page: 14 of 14

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