Storm Secure MSDS - Pest Control Management - BASF

Safety data sheetPage: 1/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014SECTION 1: Identification of the substance/mixture and of thecompany/undertaking1.1. Product identifierSTORM SECURE1.2. Relevant identified uses of the substance or mixture and uses advised againstRelevant identified uses: rodenticide, biocide1.3. Details of the supplier of the safety data sheetCompany:BASF SE67056 LudwigshafenGERMANYContact address:BASF plcPO Box 4, Earl Road, Cheadle Hulme,Cheadle, CheshireSK8 6QG, UNITED KINGDOMTelephone: +44 161 485-6222E-mail address: product-safety-north@basf.com1.4. Emergency telephone numberInternational emergency number:Telephone: +49 180 2273-112SECTION 2: Hazards Identification2.1. Classification of the substance or mixtureAccording to Regulation (EC) No 1272/2008 [CLP]No need for classification according to GHS criteria for this product.According to Directive 67/548/EEC or 1999/45/EC

Page: 2/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014Possible Hazards:No specific dangers known, if the regulations/notes for storage and handling are considered.2.2. Label elementsGlobally Harmonized System (GHS) in accordance with UK regulations.Precautionary Statement:P101If medical advice is needed, have product container or label at hand.P102Keep out of reach of children.Precautionary Statements (Prevention):P270Do not eat, drink or smoke when using this product.P273Avoid release to the environment.According to Directive 67/548/EEC or 1999/45/ECClassification/labelling in accordance with UK regulations.S-phrase(s)S1Keep locked up.S2Keep out of the reach of children.S7Keep container tightly closed.S13Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.S44If you feel unwell, seek medical advice (show the label where possible)S49Keep only in the original container.S57Use appropriate container to avoid environmental contamination.S60This material and its container must be disposed of as hazardouswaste.2.3. Other hazardsAccording to Regulation (EC) No 1272/2008 [CLP]See section 12 - Results of PBT and vPvB assessment.This product is hazardous to mammals, including domesticated animals, and birds. Exposure of nontargetanimals should be prevented.SECTION 3: Composition/Information on Ingredients3.1. SubstancesNot applicable

Page: 3/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.20143.2. MixturesChemical naturerodenticide, Bait, biocideContains: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1 ,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin (Content (W/W): 0.005 %)Hazardous ingredients (GHS)according to Regulation (EC) No. 1272/2008Paraffin waxes and Hydrocarbon waxesContent (W/W): < 30 %CAS Number: 8002-74-2EC-Number: 232-315-6REACH registration number: 01-2119488076-30Hazardous ingredientsaccording to Directive 1999/45/ECParaffin waxes and Hydrocarbon waxesContent (W/W): < 30 %CAS Number: 8002-74-2EC-Number: 232-315-6REACH registration number: 01-2119488076-30SECTION 4: First-Aid Measures4.1. Description of first aid measuresRemove contaminated clothing.If inhaled:Keep patient calm, remove to fresh air.On skin contact:Wash thoroughly with soap and water.On contact with eyes:Wash affected eyes for at least 15 minutes under running water with eyelids held open.On ingestion:If swallowed, seek medical advice immediately and show this container or label. Do not inducevomiting.Rinse mouth and then drink plenty of water.

Page: 4/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.20144.2. Most important symptoms and effects, both acute and delayedSymptoms: coagulation disordersIncreased tendency to bleed.In severe cases, massive bleeding from internal organs may result in circulatory shock, which couldprove fatal.The onset of symptoms is delayed for up to 4 days after uptake.Hazards: The substance / product is an anticoagulant rodenticide with a coumarin-type mode ofaction.4.3. Indication of any immediate medical attention and special treatment neededTreatment: Symptomatic treatment (decontamination, vital functions).SECTION 5: Fire-Fighting Measures5.1. Extinguishing mediaSuitable extinguishing media:dry powder, foam, water sprayUnsuitable extinguishing media for safety reasons:carbon dioxide5.2. Special hazards arising from the substance or mixturecarbon monoxide, hydrogen fluoride, Carbon dioxide, nitrogen oxides, toxic gasThe substances/groups of substances mentioned can be released in case of fire.5.3. Advice for fire-fightersSpecial protective equipment:Wear self-contained breathing apparatus and chemical-protective clothing.Further information:In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water ifexposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewageor effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance withofficial regulations.SECTION 6: Accidental Release Measures6.1. Personal precautions, protective equipment and emergency proceduresUse personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dustformation.

Page: 6/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014SECTION 8: Exposure Controls/Personal Protection8.1. Control parametersComponents with occupational exposure limitsNo occupational exposure limits known.Refer to the current edition of HSE Guidance Note EH40 Occupational Exposure Limits (UnitedKingdom). For normal use and handling refer to the product label/leaflet. In all other cases thefollowing apply.8.2. Exposure controlsPersonal protective equipmentRespiratory protection:Respiratory protection not required.Hand protection:Protective gloves (EN 374) are required for the safe handling of this product and are alsorecommended for protection against rodent-borne diseases.e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and otherManufacturer's directions for use should be observed because of great diversity of types.Eye protection:Required when there is a risk of eye contact., Safety glasses with side-shields (frame goggles) (e.g.EN 166)Body protection:Body protection must be chosen depending on activity and possible exposure, e.g. apron, protectingboots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in caseof dust).General safety and hygiene measuresHandle in accordance with good industrial hygiene and safety practice. Wearing of closed workclothing is recommended. Store work clothing separately. Keep away from food, drink and animalfeeding stuffs.SECTION 9: Physical and Chemical Properties9.1. Information on basic physical and chemical propertiesForm:Colour:Odour:Odour threshold:solid, blocksbluealmost odourless, faint odour, fresh cut grassNot determined due to potentialhealth hazard by inhalation.

Page: 7/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014pH value: approx. 4 - 7(20 °C)Melting point: >= 64 °CThe statements are based on theproperties of the individualcomponents.Boiling point: > 300 °CThe statements are based on theproperties of the individualcomponents.Flash point:not applicable, the product is a solidEvaporation rate:not applicableFlammability: not flammable (Directive 92/69/EEC, A.10)Lower explosion limit:As a result of our experience with thisproduct and our knowledge of itscomposition we do not expect anyhazard as long as the product is usedappropriately and in accordance withthe intended use.Upper explosion limit:As a result of our experience with thisproduct and our knowledge of itscomposition we do not expect anyhazard as long as the product is usedappropriately and in accordance withthe intended use.Vapour pressure:not applicableDensity:approx. 1.27 g/cm3(OECD Guideline 109)(20 °C)Relative vapour density (air):not applicableSolubility in water: insolubleInformation on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinPartitioning coefficient n-octanol/water (log Kow): 6.12(pH value: 7)----------------------------------Self ignition: Temperature: 267 °C(OECD Guideline 107)Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.Viscosity, dynamic:not applicable, the product is a solidExplosion hazard: Based on the chemical structurethere is no indicating of explosiveproperties.(Directive 84/449/EEC, A.14)

Page: 8/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014Fire promoting properties: Based on its structural propertiesthe product is not classified asoxidizing.9.2. Other informationOther Information:If necessary, information on other physical and chemical parameters is indicated in this section.SECTION 10: Stability and Reactivity10.1. ReactivityNo hazardous reactions if stored and handled as prescribed/indicated.10.2. Chemical stabilityThe product is stable if stored and handled as prescribed/indicated.10.3. Possibility of hazardous reactionsNo hazardous reactions if stored and handled as prescribed/indicated.10.4. Conditions to avoidSee MSDS section 7 - Handling and storage.10.5. Incompatible materialsSubstances to avoid:strong acids, strong bases, strong oxidizing agents10.6. Hazardous decomposition productsHazardous decomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.SECTION 11: Toxicological Information11.1. Information on toxicological effectsAcute toxicityAssessment of acute toxicity:The product has not been tested. The statement has been derived from substances/products of asimilar structure or composition. Virtually nontoxic after a single ingestion. Virtually nontoxic after asingle skin contact. Inhalation is not likely in the available physical form.Experimental/calculated data:LD50 rat (oral): > 5,000 mg/kg

Page: 9/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014LC50 (by inhalation):Not inhalable due to the physico-chemical properties of the product.LD50 rat (dermal): > 5,000 mg/kgIrritationAssessment of irritating effects:The product has not been tested. The statement has been derived from substances/products of asimilar structure or composition. Not irritating to the eyes. Not irritating to the skin.Experimental/calculated data:Skin corrosion/irritation rabbit: non-irritantSerious eye damage/irritation rabbit: non-irritantRespiratory/Skin sensitizationAssessment of sensitization:The product has not been tested. The statement has been derived from substances/products of asimilar structure or composition. There is no evidence of a skin-sensitizing potential.Experimental/calculated data:modified Buehler test guinea pig: Skin sensitizing effects were not observed in animal studies.Germ cell mutagenicityAssessment of mutagenicity:The product has not been tested. The statement has been derived from the properties of theindividual components. Mutagenicity tests revealed no genotoxic potential.CarcinogenicityAssessment of carcinogenicity:The product has not been tested. The statement has been derived from the properties of theindividual components. The results of various animal studies gave no indication of a carcinogeniceffect.Reproductive toxicityAssessment of reproduction toxicity:The product has not been tested. The statement has been derived from the properties of theindividual components. The results of animal studies gave no indication of a fertility impairing effect.Developmental toxicityAssessment of teratogenicity:The product has not been tested. The statement has been derived from the properties of theindividual components. Animal studies gave no indication of a developmental toxic effect at dosesthat were not toxic to the parental animals.

Page: 10/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014Repeated dose toxicity and Specific target organ toxicity (repeated exposure)Assessment of repeated dose toxicity:The product has not been tested. The statement has been derived from the properties of theindividual components.Information on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinAssessment of repeated dose toxicity:Repeated exposure to small quantities may affect certain organs. Damages the coagulation system.----------------------------------Other relevant toxicity informationMisuse can be harmful to health.SECTION 12: Ecological Information12.1. ToxicityAssessment of aquatic toxicity:There is a high probability that the product is not acutely harmful to aquatic organisms. The producthas not been tested. The statement has been derived from the properties of the individualcomponents.Information on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinToxicity to fish:LC50 (96 h) 0.071 mg/l, Oncorhynchus mykiss (OECD Guideline 203)----------------------------------Information on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinAquatic invertebrates:EC50 (48 h) 0.17 mg/l, Daphnia magna (OECD Guideline 202, part 1)----------------------------------Information on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinAquatic plants:EC50 (72 h) > 18.2 mg/l, Pseudokirchneriella subcapitata (OECD Guideline 201)----------------------------------12.2. Persistence and degradability

Page: 11/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014Assessment biodegradation and elimination (H2O):The product has not been tested. The statement has been derived from the properties of theindividual components.Information on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinAssessment biodegradation and elimination (H2O):Not readily biodegradable (by OECD criteria).----------------------------------12.3. Bioaccumulative potentialAssessment bioaccumulation potential:The product has not been tested. The statement has been derived from the properties of theindividual components.Information on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinBioaccumulation potential:Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms ispossible.----------------------------------12.4. Mobility in soilAssessment transport between environmental compartments:Adsorption in soil: The product has not been tested. The statement has been derived from theproperties of the individual components.Information on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinAssessment transport between environmental compartments:Adsorption in soil: Following exposure to soil, adsorption to solid soil particles is probable, thereforecontamination of groundwater is not expected.----------------------------------12.5. Results of PBT and vPvB assessmentThe product contains a potential PBT substance.Information on: a mixture of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarinAccording to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,Authorisation and Restriction of Chemicals (REACH): Fulfills the criteria for PBT and vPvB----------------------------------

Page: 12/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.201412.6. Other adverse effectsThe product does not contain substances that are listed in Regulation (EC) 1005/2009 onsubstances that deplete the ozone layer.12.7. Additional informationOther ecotoxicological advice:Must not be discharged into the environment.SECTION 13: Disposal Considerations13.1. Waste treatment methodsMust be disposed of or incinerated in accordance with local regulations.The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted(United Kingdom).Contaminated packaging:Contaminated packaging should be emptied as far as possible and disposed of in the same manneras the substance/product.SECTION 14: Transport InformationLand transportADRNot classified as a dangerous good under transport regulationsUN number:Not applicableUN proper shipping name: Not applicableTransport hazard class(es): Not applicablePacking group:Not applicableEnvironmental hazards: Not applicableSpecial precautions for None knownuserRIDNot classified as a dangerous good under transport regulationsUN number:Not applicableUN proper shipping name: Not applicableTransport hazard class(es): Not applicablePacking group:Not applicableEnvironmental hazards: Not applicableSpecial precautions for None known

Page: 13/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014userInland waterway transportADNNot classified as a dangerous good under transport regulationsUN number:Not applicableUN proper shipping name: Not applicableTransport hazard class(es): Not applicablePacking group:Not applicableEnvironmental hazards: Not applicableSpecial precautions for None knownuserTransport in inland Not evaluatedwaterway vessel:Sea transportIMDGNot classified as a dangerous good under transport regulationsUN number:Not applicableUN proper shipping name: Not applicableTransport hazard class(es): Not applicablePacking group:Not applicableEnvironmental hazards: Not applicableSpecial precautions for None knownuserAir transportIATA/ICAONot classified as a dangerous good under transport regulationsUN number:Not applicableUN proper shipping name: Not applicableTransport hazard class(es): Not applicablePacking group:Not applicableEnvironmental hazards: Not applicableSpecial precautions for None knownuser14.1. UN numberSee corresponding entries for “UN number” for the respective regulations in the tables above.14.2. UN proper shipping name

Page: 14/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014See corresponding entries for “UN proper shipping name” for the respective regulations in the tablesabove.14.3. Transport hazard class(es)See corresponding entries for “Transport hazard class(es)” for the respective regulations in thetables above.14.4. Packing groupSee corresponding entries for “Packing group” for the respective regulations in the tables above.14.5. Environmental hazardsSee corresponding entries for “Environmental hazards” for the respective regulations in the tablesabove.14.6. Special precautions for userSee corresponding entries for “Special precautions for user” for the respective regulations in thetables above.14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC CodeRegulation:Not evaluatedShipment approved: Not evaluatedPollution name:Not evaluatedPollution category: Not evaluatedShip Type:Not evaluatedSECTION 15: Regulatory Information15.1. Safety, health and environmental regulations/legislation specific for thesubstance or mixtureIf other regulatory information applies that is not already provided elsewhere in this safety datasheet, then it is described in this subsection.Keep in a safe placeHarmful to wildlifeAvoid all contact by mouthFor indoor use onlyPrevent access to the bait by children, birds and other animals, particulary dogs, cats, pigs andpoultry.Do not place bait where food, feed or water could become contaminated (except when used insewers)Wash hands and exposed skin before meals and after work.Search for and remove rodent bodies at frequent* intervals during treatment (unless used in sewers).Collect and dispose of the remains of bait and any remaining rodent bodies after treatment (unlessused in sewers). You must ensure that you comply with legislation regarding the correct disposal ofwaste. For further guidance, contact the Environment Agency or your local Scottish EnvironmentProtection Agency (SEPA) office.

Page: 15/15BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.Date / Revised: 22.12.2014 Version: 8.0Product: STORM SECURE(ID no. 58595254/SDS_GEN_GB/EN)Date of print 23.12.2014(*Intervals will vary depending on formulation and treatment regime; therefore the user should referto and comply with the manufacturer’s guidelines).The data should be considered when making any assessment under the Control of SubstancesHazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials'(United Kingdom).15.2. Chemical Safety AssessmentAdvice on product handling can be found in sections 7 and 8 of this safety data sheet.SECTION 16: Other InformationIf you have any queries relating to this MSDS, it's contents or any other product safety related questions,please write to the following e-mail address: product-safety-north@basf.comThe data contained in this safety data sheet are based on our current knowledge and experience anddescribe the product only with regard to safety requirements. The data do not describe the product'sproperties (product specification). Neither should any agreed property nor the suitability of the product forany specific purpose be deduced from the data contained in the safety data sheet. It is the responsibilityof the recipient of the product to ensure any proprietary rights and existing laws and legislation areobserved.Vertical lines in the left hand margin indicate an amendment from the previous version.