HEADLAND TRICURE PELLETS - Headland Amenity

PRODUCT SAFETY DATA SHEETHEADLAND TRICURE PELLETS1. Identification of the substance/mixture and of the company/undertaking:1.1 Product identifier:Headland Tricure Pellets1.2 Relevant identified uses of the substance or mixture and uses advised against:A wetting agent pellet for use on amenity turf1.3 Details of the supplier of the safety data sheet:Headland Amenity Ltd,1010 Cambourne Business Park,CambourneCambridgeshireCB23 6DPTel : +44 (0) 1223 597834Fax - +44 (0) 1223 598052e-mail info@headlandamenity.com1.4 Emergency telephone number:Tel : +44 (0) 1223 597834 during office hours (9am-5pm, Monday-Friday)2. Hazards Identification:2.1 Classification of the substance or mixture;Classification according to Directive 1999/45/EC and statutory instrument No.716 2009 Chemicals (HazardInformation and Packaging) regulation)Xi, R36/38Date of MSDS completion: 25-02-2011Version: 2Supersedes MSDS dated: 04-2008Page 1

2.2 Label elements:Headland Tricure GranularIRRITANTRisk Phrases:R36/38: Irritating to eyes and skinSafety Phrases:S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS36/37/39: Wear suitable protective clothingS45: In case of accident or if you feel unwell seek medical advice immediately (show the label wherepossible)2.3 Other hazards:None Known3: Composition/information on ingredients:3.2 MixturesA pelleted concentrate containing a blend of non-ionic surfactants4. First Aid Measures:4.1 Description of first aid measures:Eyes:Skin:Ingestion:Inhalation:Irrigate with clean water for at least 15 minutes, remove contact lenses if present andeasy to do so after 5 minutes. Seek medical attention if any irritation or rednesspersists.Wash thoroughly with soap and water. Seek medical advice if any irritation persists ordevelops later.If swallowed, wash out mouth with water. DO NOT induce vomiting. Obtain medicaladvice if patient feels unwell. May cause irritation to the gastro-intestinal tract.Remove from source of exposure into fresh air. Seek medical advice if irritation persistsor develops later.4.2 Most important symptoms and effects, both acute and delayed:No further information available4.3 Indication of any immediate medical attention and special treatment needed:No further information available5. Fire Fighting Measures:5.1 Extinguishing MediaMixture is not classed as flammable. Use extinguishing media as appropriate for surrounding materials.Contain any material used in fire fighting.Page 2

5.2 Special hazards arising from the substance or mixtureCombustion gases may cause irritation. Prevent entry of the product or fire fighting water intowatercourses, ditches or drains.5.3 Advice for fire-fighters:Suitable protective clothing and breathing apparatus.6. Accidental Release Measures:6.1 Personal precautions, protective equipment and emergency procedures:Prevent contact with skin or eyes. Use coveralls and chemical resistant gloves with eye protection asnecessary.6.2 Environmental precautions:DO NOT wash excessive spillages into water courses. If this product enters water course or sewer(including via contaminated soil and vegetation)in large quantities, contact local agency and/or policeimmediately.DO NOT burn.6.3 Methods and material for containment and cleaning up:Sweep / shovel avoiding generating dust, place in suitably labelled containers for re-use or disposalaccording to local regulations6.4 Reference to other sections:No reference7. Handling and storage:7.1 Precautions for safe handling:Wash hands and exposed skin before meals and after work. Ensure good ventilation and avoid contact withwater or humidity. Open container to avoid generating dust7.2 Conditions for safe storage, including any incompatibilities:Store in a cool, dry atmosphere in original, labelled containers.DO NOT allow to freeze – store above 5 o CKeep away from food, drink and animal feeding stuffs.Keep away from children. Refer to manufacturer for maximum safe stacking height.7.3 Specific end use(s):No further information available8. Exposure controls/personal protection:8.1 Control ParametersNo exposure limits determined for mixture. Ensure suitable engineering controls for measuring andhandling of product8.2 Exposure ControlsPrimary Hazard considered handling as concentrate.Wear suitable protective clothing, protective gloves and face-shield when handling the concentratedproduct. Avoid breathing in any dust created from measuring or spreading product.Page 3

9. Physical and Chemical Properties:9.01 Appearance:9.02 Odour:9.03 pH:9.04 Melting point / Range9.05 Flash Point / Flammability:9.06 Explosive Properties:9.07 Oxidising Properties:9.08 Vapour Pressure:9.09 Relative Density:9.10 Solubility:9.11 Partition Coefficient:9.12 Viscosity:9.13 Vapour Density:9.14 Evaporation Rate:Blue coloured solid cylinder shaped tabletsBland, musty odourInformation not available>130 o CAuto ignition 220 o C / Not classed as flammableNot classified as explosiveNot Classified as oxidisingInformation not availableInformation not availableInformation not availableInformation not availableInformation not availableInformation not availableInformation not available9.2 Other InformationNo other relevant information available10. Stability and Reactivity:10.1 Reactivity:Not known.10.2 Chemical Stability:Stable under normal conditions.10.3 Possibility of hazardous reactions:None known.10.4 Conditions to avoidExtremes of temperature.10.5 Incompatible materialsAvoid contact with acid10.6 Hazardous decomposition productsIrritant fumes may be evolved upon decompositionPage 4

11. Toxicological Information:11.1 Information on toxicological effects:Acute Oral LD50:Acute Dermal LD50:Skin Irritancy:Eye Irritancy:No Information availableNo Information availableIrritating to skinIrritating to eyesNo evidence of mutagenicity. No evidence of reproductive toxicity12. Ecological Information12.1 Toxicity:Not classified as harmful to the environment in accordance with the CHIP regulations 2009 and1999/45/EC.12.2 Persistence and Degradability:Readily disperses in water12.3 Bioaccumulative potential:Unlikely to bio-accumulate.12.4 Mobility in soil:No information available12.5 Results of PBT and vPvB assessment:Mixture not assessed12.6 Other adverse effects:No other adverse effects known13. Disposal Considerations:13.1 Waste treatment methods:Disposal of Used Preparation:Dispose of at an appropriate disposal facility or via specialised waste contractor.Disposal of Packaging:An empty container can contain product residue and should not be re-used. Use specialist waste contractorin accordance with local regulations.Page 5

14. Transport Information:Road and Rail/Sea/AirInformation not required as mixture not regulated for carriage.UN number:UN proper shipping name:Transport hazard class(es):Packing group:Environmental hazards:Special precautions for user:Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC code:15. Regulatory Information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:This mixture is classified and labelled in accordance with Directive 1999/45/EC, Regulation 1272/2008, thestatutory instrument No.716 2009 Chemicals (Hazard Information and Packaging) regulations..15.2 Chemical Safety Assessment:CSA not undertaken for this mixture.16. Other InformationThe above information is intended to give health and safety guidance on the storage and transportof the substance or product to which it relates. It is not intended to apply to the use of the product,for which purpose the product label and any appropriate technical usage literature available shouldbe consulted and any relevant licences, consents or approvals complied with. The requirements orrecommendations of any relevant site or working procedure, system or policy in force or arisingfrom any risk assessment involving the substance or product should take precedence over any ofthe guidance contained in this safety data sheet where there is a difference in the informationgiven. The information provided in this safety data sheet is accurate to the best of the issuer’savailable knowledge at the date of publication, and will be updated as and when appropriate. Noliability will be accepted for any loss or damage resulting from any failure to take account ofinformation or advice contained in this safety data sheet.Reason For Update:MSDS has been re-written to reflect the new format given in Annex I of the REACH regulation453/2010Headland is a registered trademark of Headland AgrochemicalsTri-cure is a trademark of Mitchell Products, Millville, New Jersey, USA.End of Safety Data SheetPage 6