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A numerical study of the rheological properties of suspensions of ...

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156fibre suspension can be writtenM. B. Mackaplow and E. S. G. Shaqfeh(8) = 2,u (e) + n (s) (1)where ,u is <strong>the</strong> viscosity <strong>of</strong> <strong>the</strong> suspending fluid, e is <strong>the</strong> volume-averaged fluid rate <strong>of</strong>strain tensor, n is <strong>the</strong> particle number density, and (S) is <strong>the</strong> average particle ‘stresslet’.The latter is a symmetric, traceless tensor that is a function <strong>of</strong> particle shapes, sizes,orientations, and centre-<strong>of</strong>-mass distributions. It will be discussed in more detail in$2. In general, for orientable particles, (S) will not have <strong>the</strong> same tensorial form as(e). Therefore, <strong>the</strong> volume-averaged deviatoric stress tensor <strong>of</strong> <strong>the</strong> suspension cannotbe written merely as 2peff(e), where ,ueff is referred to as <strong>the</strong> effective viscosity <strong>of</strong> <strong>the</strong>suspension.In addition, <strong>the</strong> <strong>rheological</strong> <strong>properties</strong> <strong>of</strong> fibre <strong>suspensions</strong> may change dramaticallyduring startup. This is because <strong>the</strong> instantaneous suspension <strong>properties</strong> are a strongfunction <strong>of</strong> <strong>the</strong> fibre orientation distribution. The orientation distribution evolvesover time as particles rotate in <strong>the</strong> mean flow and interact with each o<strong>the</strong>r until asteady-state distribution is reached. This has been observed experimentally by Bibbo(1987). In industrial applications, such as <strong>the</strong> injection moulding <strong>of</strong> <strong>suspensions</strong>, it ispossible that <strong>the</strong> suspension will experience a rapidly changing flow field such thata steady-state orientation distribution will never be reached. Thus, it is importantto understand both <strong>the</strong> development <strong>of</strong> <strong>the</strong> orientation distribution and how <strong>the</strong><strong>rheological</strong> <strong>properties</strong> vary as a function <strong>of</strong> it. We note that <strong>the</strong> effect <strong>of</strong> <strong>the</strong> particleorientation distribution on <strong>the</strong> <strong>rheological</strong> <strong>properties</strong> <strong>of</strong> <strong>the</strong> suspension is particularlyimportant for large particle aspect ratios, as indicated by equation (11) below.The reason that small volume fractions <strong>of</strong> fibres can have such large effects on<strong>the</strong> <strong>rheological</strong> <strong>properties</strong> <strong>of</strong> a suspension can be understood by examining <strong>the</strong><strong>the</strong>oretical results <strong>of</strong> Batchelor (1970) for isolated fibres, henceforth referred to as<strong>the</strong> dilute <strong>the</strong>ory. These show that <strong>the</strong> disturbance to <strong>the</strong> flow field created by a fibre<strong>of</strong> aspect ratio A is only llln(2A) weaker than a sphere having <strong>the</strong> same diameteras <strong>the</strong> fibre length. Moreover, <strong>the</strong> disturbance extends over <strong>the</strong> same fluid volume.Thus, <strong>the</strong> disturbance per unit particle volume created by a fibre relative to that <strong>of</strong> asphere is O(A*/ln(A)), which can be quite large even with fibres <strong>of</strong> moderate aspectratio. However, only <strong>the</strong> governing equations for <strong>suspensions</strong> where <strong>the</strong> fibres arenot interacting with each o<strong>the</strong>r are analytically tractable. Since, as shown by <strong>the</strong>dilute <strong>the</strong>ory, <strong>the</strong> interaction length <strong>of</strong> a fibre is determined by its physical length,21, fibre interactions can only be neglected when n13

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