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A numerical study of the rheological properties of suspensions of ...

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182 M. B. Mackaplow and E. S. G. ShaqfehComparison <strong>of</strong> our <strong>numerical</strong> simulations to experiments and <strong>the</strong>oretical predictionsfor steady state shear and extensional viscosities also support <strong>the</strong> conclusionthat <strong>the</strong> semi-dilute suspension screening length is independent <strong>of</strong> <strong>the</strong> fibre orientationdistribution in <strong>the</strong> suspension. This conclusion is powerful since it allows oneto convert knowledge <strong>of</strong> <strong>the</strong> transient fibre orientation distribution in a suspensionto <strong>the</strong> transient <strong>rheological</strong> <strong>properties</strong> <strong>of</strong> <strong>the</strong> suspension. This is particularly valuablein a rapidly changing flow field where steady-state conditions are not reached sincedirect measurement <strong>of</strong> transient <strong>rheological</strong> <strong>properties</strong> are difficult.Slender-body <strong>the</strong>ory will faithfully capture <strong>the</strong> effect <strong>of</strong> fibre-fibre interactionson <strong>the</strong> hydrodynamic stress in an isotropic suspension for concentrations up tox A/5, beyond which it underestimates <strong>the</strong>ir effect. Interestingly, although <strong>the</strong>average steady-state closest approach distance between fibres in shear flow is muchlarger than for those in an isotropic suspension, <strong>the</strong> few fibres that make <strong>the</strong> dominantcontribution to <strong>the</strong> suspension stress experience closest approach distances that areapproximately <strong>the</strong> same as those in an isotropic suspension. Consequently, in suchflows <strong>the</strong> same upper concentration limit for <strong>the</strong> ability <strong>of</strong> slender-body <strong>the</strong>ory tocapture <strong>the</strong> full effect <strong>of</strong> fibre-fibre interactions is observed. This limit is presumablymuch higher in aligned <strong>suspensions</strong>, since for a given suspension concentration <strong>the</strong>average closest approach distance is much larger.Our algorithm can easily be modified to determine <strong>the</strong> sedimentation characteristics<strong>of</strong> fibre <strong>suspensions</strong>. This is done by changing <strong>the</strong> right-hand side <strong>of</strong> (8) to specifythat <strong>the</strong> net force exerted by a fibre on <strong>the</strong> fluid is equal to <strong>the</strong> gravitational bodyforce exerted on <strong>the</strong> fibre. Monte Carlo and dynamic studies <strong>of</strong> fibre sedimentationare in progress.The authors would like to acknowledge support for this work from both a PresidentialYoung Investigator Award, Grant No. CTS-90557284, to ESGS, as well asa Merck Fellowship to MBM. Computer resources (CRAY C90) were supplied by agrant from <strong>the</strong> San Diego Supercomputer Center. This material is based on worksupported by Cornell University through <strong>the</strong> National Science Foundation Grant No.DDM-9212582.Appendix. Calculations <strong>of</strong> <strong>the</strong> correction to <strong>the</strong> effective viscosity <strong>of</strong> a fibresuspension for two-body interactionsA.l. General developmentA method for calculating expressions for <strong>the</strong> effective viscosity in a random dispersion<strong>of</strong> rigid fibres in a Newtonian fluid which accounts for multi-body interactions hasbeen carefully presented by Shaqfeh & Fredrickson (1990). We shall refer to thispublicaton for <strong>the</strong> details and only outline <strong>the</strong> ma<strong>the</strong>matical steps necessary to derive<strong>the</strong> results quoted in 54 - namely <strong>the</strong> first correction to <strong>the</strong> predicted effective viscosity<strong>of</strong> a fibre solution in <strong>the</strong> dilute limit which accounts for two-body interactions.The general <strong>the</strong>ory developed by Shaqfeh & Fredrickson (1990) for <strong>the</strong> wavenumberdependentpropagator, Gjk(q) in <strong>suspensions</strong> <strong>of</strong> randomly positioned fibres can besummarized in <strong>the</strong> following set <strong>of</strong> integral equations :

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