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SAFETY DATA SHEET AMBI-PUR 3VOLUTION ... - ScienceInTheBox

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<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><strong>AMBI</strong>-<strong>PUR</strong> <strong>3VOLUTION</strong> WINTER DREAMS - (Vanilla Treat)Bottle 3Benzyl alcoholLimoneneLinaloolCitronellol1-(1,2,3,4,6,7,8,8a-Octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-oneTetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans) 7-HydroxycitronellalCitronellyl acetateHabanolidealpha-Methyl-1,3-benzodioxole-5-propionaldehyde3-(p-Methoxyphenyl)-2-methylpropionaldehydealpha,alpha-Dimethylphenethyl butyrate(Z)-3-Hexenyl salicylateUndecan-4-olideHerbanateCoumarin2-Ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-olPin-2(3)-ene202-859-9205-341-0201-134-4203-375-0268-979-9405-040-6203-518-7205-775-0422-320-3214-881-6226-749-5233-221-8265-745-8203-225-4427-090-8202-086-7248-908-8201-291-95 - 72.5 - 53 - 52.5 - 52.5 - 51 - 31 - 31 - 2.50.25 - 2.50.1 - 2.50.1 - 10.1 - 2.50.1 - 2.50.1 - 2.50.1 - 10.1 - 10.1 - 0.250.1 - 0.25XnXi, NXiXi, NNXiXiXi, NNNX iNNNXi, NXnXi, NXn, NR20/22R10-38-43-50/53R38R38-43-51/53R51/53R36R36-43R38-51/53R50/53R51/53R43-52/53R51/53R51/53R51/53R43-51/53R22-43R38-50/53R10-43-50/53-65Reference is made to heading 16, where the full text of each relevant R phrase is listed.Occupational Exposure Limit(s), if relevant, are listed in section 8.4. FIRST AID MEASURESEffects and symptomsIngestionInhalationSkin contactEye contact: May cause drowsiness, headache and nausea.: Not applicable for normal use. The liquid may cause prickling ofrespiratory system.: May cause sensitisation by skin contact.: Not applicable for normal use. Liquid may cause prickling of eyes.First aid measuresIngestion :Inhalation :Skin contact :Eye contact :5. FIRE FIGHTING MEASURESExtinguishing mediaSuitable :Not suitable :Unusual fire/explosion:hazardsHazardous thermal:(de)composition productsProtection of fire-fighters :In case of ingestion do not induce vomiting. Rinse out mouth anddrink about one glass of water. Immediately get medical attention.Not applicable for normal use. In case of prickling of the respiratorysystem, remove to fresh air.Wash off with plenty of water and soap. Consult a doctor in event ofany complaints.Wash out with water with the eyelid held wide open for at least 15minutes. If prickling persists, consult a doctor.In case of fire, use alcohol resistant foam, water fog or dry chemical.Water jet.Not known.It decomposes into non harmful products in case of completecombustion.In case of insufficient ventilation, wear suitable respiratory equipment.Date of issue : 31/01/2011 UK SDS Ref : 1-107-01 Page 2 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><strong>AMBI</strong>-<strong>PUR</strong> <strong>3VOLUTION</strong> WINTER DREAMS - (Vanilla Treat)6. ACCIDENTAL RELEASE MEASURESPersonal precautions: Danger of slipping. Clean up spills immediately. Wear shoes withnon-slip soles. Avoid contact with skin and eyes. Wear suitablegloves. For details see chapter 8.Environmental precautions : Do not allow the undiluted product to enter the surface water orground water. In case of excess spillage, prevent contamination ofsoil and water.Methods for cleaning up : Collect spilled material in containers. Wash away remainder withwater and soap. Disposal in accordance with the local legislation.7. HANDLING AND STORAGEHandling: Handle in accordance with good occupational hygiene and safetypractices and only in well-ventilated areas. Avoid contact with skinand eyes. Wear suitable gloves.People suffering from perfume sensitivity should be cautious whenusing this product.Air Fresheners do not replace good hygiene practices.StoragePackaging materialsSuitable: Keep in a cool, dry, well-ventilated place.: Keep only in the original container.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering measures: Use only in well-ventilated areas.Hygienic measures: When handling do not eat, drink or smoke.Date of issue : 31/01/2011 UK SDS Ref : 1-107-01 Page 3 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><strong>AMBI</strong>-<strong>PUR</strong> <strong>3VOLUTION</strong> WINTER DREAMS - (Vanilla Treat)Occupational ExposureLimitsChemical name"MAC" (Netherlands): No occupational exposure limits are known on the product, but someare available on the hazardous ingredients defined in section 3.: (2-Methoxymethylethoxy)propanol: TWA - 8 hours: 300 mg/m3 (50 ppm)Personal protectiveequipmentRespiratory system : In case of excess spillage wear: filter mask, type A.Hands: Wear suitable gloves: butyl rubber gloves or PVA (polyvinylalcohol)gloves.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state : 3 liquids ( Electrical diffuser with a glass bottle ).Colour: CharacteristicOdour: CharacteristicBoiling point: Not established.Specific gravity (H 2O=1) : 0.8 - 1.0 kg/lpH: Not applicableSolubility in water: ImmiscibleFat solubility: Not established.Partition coefficient: n-: Not established.octanol/waterVapour pressure: Not established.Vapour density: Not established.Evaporation rate: Not established.Viscosity: Not established.Flammability: Not flammable.Flash point : > 61°CExplosive properties : Not established.Oxidising properties : Not oxidizing.10. STABILITY AND REACTIVITY11.Stability :Conditions to avoid :Materials to avoid :Hazardous decomposition :productsTOXICOLOGICAL INFORMATIONStable under normal conditions.Not applicable.Keep away from oxidizing substances.None.Date of issue : 31/01/2011 UK SDS Ref : 1-107-01 Page 4 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><strong>AMBI</strong>-<strong>PUR</strong> <strong>3VOLUTION</strong> WINTER DREAMS - (Vanilla Treat)No toxicological research on the product has been performed. Based on the composition as indicatedin chapter 3, the following risk phrase(s) apply for this product:May cause sensitisation by skin contact.Specific effects of raw material(s) indicated in chapter 3 are given further on in this chapter.Toxicologic effects and symptoms:Eye contactIngestionInhalationSkin contactChemical nameAcute toxicityOralSkin irritationSensitization: Not applicable for normal use. Liquid may cause prickling of eyes.: May cause drowsiness, headache and nausea.: Not applicable for normal use. The liquid may cause prickling ofrespiratory system.: May cause sensitisation by skin contact.: Limonene: LD 50( mouse ) 5.6 - 6.6 g/kg: Irritating to skin.: May cause sensitisation by skin contact.Chemical name :Acute toxicitySkin irritation :Sensitization :CitronellolIrritating to skin.May cause sensitisation by skin contact.Chemical name :Acute toxicityOral :Dermal :Inhalation :Skin irritation :Sensitization :7-HydroxycitronellalLD 50( rat ) : 3600 mg/kgLD 50( rabbit ) : > 5000 mg/kgLC 50( mouse ) : 4000 mg/kgIrritating to skin.May cause sensitisation by skin contact.Chemical nameAcute toxicityOralSensitizationChemical nameAcute toxicityOralEye irritationSensitization: Coumarin: Harmful if swallowed.: LD 50( guinea-pig ): 202 mg/kgLD 50(rat ): 293 mg/kg: May cause sensitisation by skin contact.: Eugenol: LD 50( rat ): 1930 mg/kg: Irritating to eyes.: May cause sensitisation by skin contact.12. ECOLOGICAL INFORMATIONDate of issue : 31/01/2011 UK SDS Ref : 1-107-01 Page 5 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><strong>AMBI</strong>-<strong>PUR</strong> <strong>3VOLUTION</strong> WINTER DREAMS - (Vanilla Treat)Toxic to aquatic organisms, may cause long-term effects in the aquatic environment.The following ingredient(s) as indicated in chapter 3 are classified as being dangerous to theenvironment:Chemical name: LimonenePersistence/degradability : The substance is poorly biodegradable.Bioaccumulative potential : log Pow: 4.23Ecotoxicity: Very toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.EC 50( fish ) < 1 mg/lChemical nameEcotoxicity: Habanolide: Very toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.LD 50( fish ): 2.0 mg/lEC 50( Daphnia magna ): 0.48 mg/lChemical name: 2-Ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-olBioaccumulative potential : log Pow: 5.14Ecotoxicity: Very toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.EC 50( Daphnia magna ): 0.63 mg/lChemical name: CitronellolBioaccumulative potential : log Pow: 3.91Ecotoxicity: Toxic to aquatic organisms, may cause long-term effects in theaquatic environment.Chemical namePersistence/degradabilityEcotoxicity: 1-(1,2,3,4,6,7,8,8a-Octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one: May cause long-term adverse effects in the aquatic environment.: Toxic to aquatic organisms.13. DISPOSAL CONSIDERATIONSMethods of disposalWaste residues: Disposal in accordance with the local legislation.14. TRANSPORT INFORMATIONDate of issue : 31/01/2011 UK SDS Ref : 1-107-01 Page 6 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><strong>AMBI</strong>-<strong>PUR</strong> <strong>3VOLUTION</strong> WINTER DREAMS - (Vanilla Treat)UN number : 3082Proper shipping nameENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S (limonene )Land - Road/RailwayADR Class : 9Classification Code : M6ADR Packaging Group : IIIInland waterways: Not availableSeaIMDG Class : 9IMDG Packaging Group : IIIEmS Code: F - A / S - FMarine pollutant: NoAir: Not available.National transportregulations15. REGULATORY INFORMATIONEC RegulationsEC Classification(67/548/EC-99/45/EC) andother relevant regulations: Not available.Hazard symbol(s) : X i, N IRRITANT DANGEROUS FORTHE ENVIRONMENTRisk phrasesR43: May cause sensitisation by skin contact.R51/53: Toxic to aquatic organisms, may cause long-term effects in the aquatic environment.Date of issue : 31/01/2011 UK SDS Ref : 1-107-01 Page 7 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><strong>AMBI</strong>-<strong>PUR</strong> <strong>3VOLUTION</strong> WINTER DREAMS - (Vanilla Treat)Safety phrasesS2 : Keep out of reach of children.S24: Avoid contact with skin.S29: Do not empty into drains.S37: Wear suitable gloves.S46: If swallowed, seek medical advice immediately and show this container or label.Contains limonene, citronellol, hydroxycitronellal, coumarin, eugenol and cinnamyl alcohol.National regulations16. OTHER INFORMATIONFull text of indicated R-phrases for the ingredients mentioned in chapter 3R10: Flammable.R20/22: Harmful by inhalation and if swallowed.R22: Harmful if swallowed.R36: Irritating to eyes.R38: Irritating to skin.R41: Risk of serious damage to eyes.R43: May cause sensitisation by skin contact.R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.R51/53: Toxic to aquatic organisms, may cause long-term effects in the aquatic environment.R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.R62: Possible risk of impaired fertility.R65: Harmful; may cause lung damage if swallowed.Regulation (EC) 1907/2006:From the raw materials as used in this preparation no safety reports are registered with respect toregulation 1907/2006 (EC) at the moment of preparing this safety data sheet.This sheet conforms to the Regulation (EC) 1907/2006 dated 18 December 2006. The informationcontained in this sheet is to the best of our knowledge true and accurate but all data, instructions,recommendations and/or suggestions are made without guarantee.Date of issue : 31/01/2011 UK SDS Ref : 1-107-01 Page 8 of 9


<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><strong>AMBI</strong>-<strong>PUR</strong> <strong>3VOLUTION</strong> WINTER DREAMS - (Vanilla Treat)HISTORYDate first issue :Date previous SDS :Date of issue:12-04-200623-04-200931/01/2011Revisions : The contents of the following chapters are changed: 3 and 16.Date of issue : 31/01/2011 UK SDS Ref : 1-107-01 Page 9 of 9

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