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Xylan ®<br />

Xylan ®<br />

AUDI<br />

BMW<br />

CITROËN<br />

DAIMLERCHRYSLER<br />

FORD<br />

GENERAL MOTORS<br />

HONDA<br />

JAGUAR<br />

KARMANN<br />

LAND ROVER<br />

MERCEDES-BENZ<br />

NISSAN<br />

PEUGEOT<br />

PORSCHE<br />

ROVER<br />

SAAB<br />

SEAT<br />

SUZUKI<br />

TELCO<br />

TOYOTA<br />

VOLKSWAGEN<br />

flexible finishes:<br />

known by<br />

the companies they keep<br />

A QS-9000-approved supplier


Xylan: coatings born out of the<br />

problems of the automotive industry<br />

Xylan is a product of Whitford Worldwide,<br />

makers of the largest, most complete line of fluoropolymer<br />

coatings in the world.<br />

Some companies develop products in the<br />

abstract — and then bend problems to fit the<br />

products. Whitford takes the opposite point of<br />

view. We believe that the way to a better product<br />

is to start with a specific problem, then create<br />

a product designed to solve it.<br />

Xylan solved a glass-run abrasion<br />

problem for the Honda Civic.<br />

This approach<br />

led to<br />

automotive<br />

manufacturers<br />

looking<br />

for an alternative<br />

to traditionalmethods<br />

of post-<br />

treating elastomeric seals and mouldings.<br />

These traditional treatments involve the use of<br />

polyamide and polyester flocking agents, silicone<br />

solutions, fine particle chalks and specialist<br />

greases to reduce friction, suppress noise,<br />

avoid sticking and protect against weathering.<br />

Whitford’s research and development teams<br />

created a range of products to provide superior<br />

alternatives to these methods, often working<br />

hand in hand with sealing-system manufacturers<br />

and automotive companies. The end result<br />

is Xylan, a comprehensive range of coating<br />

solutions for automotive sealing systems which<br />

owe their unique effectiveness to a number of<br />

revolutionary technological advances pioneered<br />

by Whitford.<br />

Another benefit of the new Xylan coatings:<br />

rapid, yet effective processing techniques<br />

which have been developed in close cooperation<br />

with sealing-system manufacturers.<br />

Who’s using Xylan?<br />

Companies that are successfully using<br />

Xylan-coated sealing systems include:<br />

• Audi • BMW<br />

• Citroën • DaimlerChrysler<br />

• Ford • General Motors<br />

• Honda • Jaguar<br />

• Karmann • Land Rover<br />

• Mercedes-Benz • Nissan<br />

• Peugeot • Porsche<br />

• Rover • SAAB<br />

• SEAT • Suzuki<br />

• Telco • Toyota<br />

• Volkswagen<br />

QS-9000:<br />

The Automotive Seal of Quality<br />

Whitford is one of a select group of companies<br />

who have achieved the coveted status of<br />

being a QS-9000 rated supplier<br />

to the automotive industry.<br />

This commitment to the<br />

most exacting standards<br />

is maintained by quality<br />

assurance teams at each of<br />

Whitford’s worldwide facilities.<br />

Their sole task is to ensure that, as a supplier<br />

already rated to BS EN ISO 9001:1994, Certificate<br />

No. FM24177 and EAQF94 standards,<br />

continual improvement in quality is achieved.<br />

The popular Land<br />

Rover “Discovery”<br />

uses Xylan on the<br />

rear-door seal to<br />

provide excellent<br />

freeze-release as<br />

well as outstanding<br />

resistance to<br />

abrasion.


Xylan coatings and the many benefits<br />

they provide for sealing systems<br />

Xylan coatings offer a complete range of • Outstanding release properties.<br />

outstanding benefits to solve the problems of • Good aesthetic properties, including<br />

automotive sealing systems:<br />

clear coatings.<br />

• Low friction.<br />

• Colour-coordinated coatings (many<br />

• Excellent resistance to abrasion.<br />

colours to match the interior trim).<br />

• Elimination of noise from seal micromove- • Improved weathering and chemical resistment<br />

against the car body and glass.<br />

ance of sealing system compounds.<br />

• Soft touch (a velvet aspect<br />

for the cosmetic limbs of<br />

internal seals to match<br />

the interior trim velour).<br />

All Xylan coatings also provide<br />

significant benefits in processing:<br />

• Simple, easy-to-control,<br />

monitored applications.<br />

• Less likelihood of contamination<br />

than with alternative<br />

technologies.<br />

Volkswagen specified Xylan for application to the “A” pillar seal to reduce • Extremely cost-effective.<br />

noise generated through wind resistance in the Golf.<br />

Xylan works, whatever the application<br />

Xylan coating materials have proved highly<br />

successful in many different automotive applications.<br />

In glass-run channels, for instance,<br />

Xylan’s remarkable abrasion resistance<br />

ensures long-lasting, smooth, silent window<br />

operation combined with consistently low levels<br />

of friction. When used on boot<br />

(trunk) seals, this versatile material<br />

provides excellent release even in<br />

the most adverse conditions.<br />

In addition to excellent release,<br />

Xylan provides outstanding appearance,<br />

door-slam resistance and<br />

protection against weathering to<br />

main door seals, body seals and<br />

drip rails. Xylan greatly enhances<br />

the weather resistance and appearance<br />

of door pillars and exterior<br />

window seals. Xylan coatings also<br />

combat the effect of “stick-slip”, thus reducing<br />

squeak and noise associated with the micromovement<br />

of seals against body panels and<br />

glass.<br />

Variety of Substrates<br />

Xylan coatings are not limited to applica-<br />

The Rover 25 uses Xylan on its glass-run channels to reduce friction and<br />

resist abrasion, making operation of windows quiet and effortless.


tions with EPDM. They<br />

have also been successfully<br />

applied to NBR, PVC,<br />

ASA, acrylics, ABS and<br />

polyester, sometimes in<br />

combination with Whitfordprovided<br />

or approved<br />

primer systems.<br />

In anticipation of new<br />

market trends, Whitford<br />

has carried out extensive<br />

development in the formulation<br />

of Xylan coating<br />

variations for specific use<br />

on TPE (TPV/TPO) substrates.<br />

Pretreatment<br />

In many cases, a clean,<br />

contamination-free surface<br />

is all that is required to<br />

achieve a good bond of Xylan to the sealingsystem<br />

surface.<br />

In other situations, depending on the type of<br />

substrate and the required end application,<br />

pretreatment is necessary. Such pretreatment<br />

can take the form of physical methods such as<br />

corona discharge or flaming techniques, both<br />

of which are easy to control and environmentally<br />

friendly. Recently developed oxygen-plasma<br />

techniques represent excellent physical pretreatment<br />

methods for preparing rubber and<br />

plastic surfaces<br />

for the application<br />

of Xylan.<br />

In many off-line<br />

situations in<br />

which this is<br />

unsuitable, a<br />

range of primers<br />

available from<br />

Whitford can be<br />

used.<br />

Ease of<br />

Application<br />

Xylan coatings<br />

have been de-<br />

Xylan is applied on the glass-run channels of the Peugeot 406 Series to reduce friction<br />

and to provide resistance to abrasion and protection for the seal against environmental<br />

attack, assuring a long, trouble-free service life.<br />

signed to ensure maximum convenience and<br />

ease of application for the extruder or fabricator.<br />

In virtually all cases, the coatings can be<br />

applied using one of two methods:<br />

1.As part of an integral on-line extrusion<br />

process, applied directly after extrusion<br />

and processed with the substrate, or, if<br />

preferred, at a later stage, possibly after<br />

partial cure or “blowing” of the profile<br />

compound in question.<br />

The Mercedes-Benz M-Class uses Xylan on seals to provide outstanding<br />

abrasion resistance for the life of the vehicle.<br />

2. As a post-fabricating/extrusion operation,<br />

the coatings can<br />

be applied to a<br />

finished part and<br />

cured separately.<br />

Usually, Xylan<br />

is applied by<br />

spray techniques,<br />

but<br />

grades are available<br />

that have<br />

been specially<br />

formulated for<br />

easy application<br />

by wiping or<br />

brushing.


VW chooses chooses Xylan Xylan<br />

Toyota chooses Xylan<br />

The Whitford Test Matrix:<br />

Meeting Performance Specifications<br />

Test Specification Rating Requirement<br />

Adhesion ASTM D-3359 or No adhesion loss 5 tape pulls<br />

“Popsicle stick” No adhesion loss 180˚ bend<br />

Xenon arc SAE J1960 Minimum 4 2000 hours<br />

(Ford) AATCC and visual 2500kJ<br />

Xenon arc SAE J1960 Minimum 4 1250kJ<br />

(GM) AATCC and visual<br />

Xenon arc SAE J1960 Minimum 4 2500kJ<br />

(Whitford) AATCC and visual<br />

Ice release SP-TP 102 No ice sticking Record force<br />

Toluene: SP-TP 88 # rubs to damage 100 double rubs<br />

double rubs film (after 24 hours)<br />

Glass Chisel 1 kg on dense No break in 20,000 cycles<br />

(Honda, GM) coating<br />

Glass Chisel 3 kgs on dense No break in 10,000 cycles<br />

(Toyota) TSM 1708G coating<br />

Crocking: dry Mercedes DBL No wear through in 500 cycles; record<br />

(Mercedes- 5578.30 coating min 4.5 actual<br />

Benz) 500g load DIN 54002<br />

Crocking: Ford- WSB- No break in 500 cycles; record<br />

wet M2D49A2<br />

900 gm load<br />

coating actual<br />

70˚C Water SPS 105 No delamination 1 day: record results.<br />

immersion or damage to Repeat DBL 5578.30<br />

coating dry abrasion test<br />

Humidity Whitford test or No blistering or 7 days/38˚C, 95% or<br />

“Cataplasm” adhesion loss 14 days<br />

Oven aging Whitford test No cracking, 72 hrs @80˚C. Testing<br />

tackiness or according to matrix<br />

adhesion loss procedure previously<br />

indicated<br />

CoF ASTM D1894 Static: 1.1 Record actual<br />

(Ford) Dynamic: 0.9<br />

CoF PSA D41 or Static: >0.5 Refer to part<br />

(Whitford) ASTM D1894 Dynamic: >0.5 drawing<br />

Glass Mitsubishi ESX- Measure force Refer to part<br />

adhesion 60058, 4:8 drawing<br />

Cold flex DBL 5578.30 No cracks or<br />

loss of adhesion<br />

Record actual<br />

Muddy water TSM 1708G 3000 cycles, no Record actual<br />

abrasion test break in coating,<br />

minimum rating 4<br />

Honda<br />

chooses Xylan<br />

Mercedes-Benz<br />

chooses Xylan<br />

Nissan chooses<br />

Xylan<br />

Rover chooses<br />

Xylan


How Xylan coatings solve problems<br />

such as friction, freeze-release and stick-slip<br />

Each flexible finish of Xylan has been engineered<br />

to offer specific characteristics to solve<br />

different problems.<br />

Coefficient of friction<br />

The following illustrations demonstrate how<br />

1.2<br />

1.0<br />

0.8<br />

0.6<br />

0.4<br />

0.2<br />

Coefficients of friction for coated and uncoated<br />

EPDM rubber measured against glass<br />

UNCOATED<br />

COATED WITH XYLAN<br />

0 20 40 60 80 100 120 140<br />

Extension (mm)<br />

Problem: Freeze-Release<br />

The chart at the right shows the<br />

significant decrease in force<br />

required in a freeze-release test to<br />

separate a rubber profile coated<br />

with Xylan from a car body panel<br />

compared with the force required<br />

to separate the same substrate<br />

but uncoated.<br />

TYPICAL URETHANE:<br />

Maximum load (N) Mean load (N)<br />

9.012 4.935<br />

XYLAN 2020:<br />

Maximum load (N) Mean load (N)<br />

2.301 2.068<br />

160<br />

COATED WITH<br />

XYLAN<br />

Xylan solves three of the most common problems<br />

in sealing systems: high coefficient of friction,<br />

limited release in freezing conditions, and<br />

the noise generated by stick-slip.<br />

Problem: Friction<br />

The chart at the left shows the results of<br />

a friction test conducted to compare the<br />

coefficients of friction of uncoated rubber<br />

profile with the same profile coated with<br />

Xylan. Both the static coefficient of friction<br />

illustrated by the initial peak in the<br />

curve and the dynamic coefficient of friction<br />

represented by the stable continuum<br />

of the graph are significantly reduced in<br />

the coated example.<br />

Freeze-release characteristics<br />

of coated and uncoated rubber samples<br />

UNCOATED<br />

0 2 4 6 8 10 12<br />

Force required to pull samples from surface (N)<br />

Problem: Noise Generation through Stick-Slip<br />

These traces show the difference in “stick-slip” of<br />

rubber coated with typical urethane coatings vs.<br />

rubber coated with a Xylan Weatherstrip material.<br />

They indicate the amount of force required to move<br />

the rubber test-piece across a glass or painted surface<br />

at constant speed. The oscillating trace of the<br />

urethane-coated sample represents its tendency to<br />

“stick”. The peak force values (spikes in the trace)<br />

indicate the extra force needed to move the urethane-coated<br />

piece (causing it to “slip”). This “stickslip”<br />

phenomenon often leads to itch and squeak<br />

noises generated by seals moving against car bodies<br />

when vehicles are in motion.


2b. Noise suppression:<br />

Xylan eliminates itch<br />

and squeak from<br />

micromovement.<br />

Which Xylan coating is best<br />

for your sealing-system problem?<br />

1. Glass run: Xylan’s excellent<br />

abrasion resistance offers<br />

years of extra wear.<br />

All the new Xylan coatings have been formulated<br />

to solve specific problems on varied substrates.<br />

This guide indicates which coating is<br />

best suited for each individual application.<br />

1. Glass-Run Applications<br />

These applications refer to the coating of<br />

window seals in which automotive glass<br />

moves during opening and closing operations.<br />

The coatings have high abrasion resistance,<br />

low consistent-friction values and low operational-noise<br />

qualities, all major advantages<br />

over traditional flock technologies.<br />

◆ Solvent-borne option:<br />

• 2321 Series (two-component system).<br />

◆ Waterborne option:<br />

• 2121 Series (two-component system).<br />

2. Weatherstrip Applications<br />

These applications refer to the coating of<br />

primary and secondary door seals, boot<br />

(trunk) seals and bonnet (hood) seals. The<br />

reasons for using a coating include provision<br />

for freeze (ice)-release and noise suppression<br />

properties associated with the micromovement<br />

of seals against a painted surface.<br />

◆ Solvent-borne options:<br />

• 2320 Series (two-component system).<br />

2a. Freeze release:<br />

Prevents sticky seals in<br />

all weather conditions.<br />

3. Appearance: Xylan comes in an<br />

unlimited range of colors and textures.<br />

It resists weathering, maintaining its<br />

sheen for years of service.<br />

◆ Waterborne options:<br />

• 2020 Series (single component system).<br />

3. Appearance Applications<br />

These are the coating of sealing systems<br />

for decorative effect. By inference, the coatings<br />

are often required to have excellent<br />

resistance to environmental weathering. This<br />

group of applications includes coloured and<br />

textured coatings.<br />

◆ Solvent-borne option:<br />

• 2322 Series (two-component system).<br />

◆ Waterborne options:<br />

• 2222 Series (one-component system).<br />

• 2330 Series (one-component system).<br />

Thanks to Xylan, the absence of itch and squeak lets the<br />

beauty of nature speak in its own quiet way.


Abrasion...friction...<br />

squeaking...colour...<br />

freeze-release...weathering.<br />

Whatever your sealing system<br />

problems, Whitford will work<br />

closely with you to develop<br />

the perfect solution.<br />

How to contact Whitford<br />

Whitford manufactures in 8 countries, has employees in 6 more and agents<br />

in an additional 25. To find the office nearest you, please contact:<br />

Asia-Pacific<br />

Whitford Ltd.<br />

22nd Floor, Oterprise Square<br />

26 Nathan Road, Kowloon, Hong Kong<br />

• Tel: +852 2559-3833<br />

• Fax: +852 2857-7911<br />

• Email: sales@whitfordww.com.hk<br />

North America<br />

Whitford Corporation<br />

33 Sproul Road<br />

Frazer, PA 19355<br />

• Tel: +1 (610) 296-3200<br />

• Fax: +1 (610) 647-4849<br />

• Email: sales@whitfordww.com<br />

Europe<br />

Whitford Plastics Ltd.<br />

Christleton Court, Manor Park<br />

Runcorn, Cheshire, WA7 1ST England<br />

• Tel: +44 (0) 1928 571000<br />

• Fax: +44 (0) 1928 571010<br />

• Email: sales@whitfordww.co.uk<br />

South America<br />

Whitford Comercio e Industria Ltda.<br />

Avenida Sao Carlos 620, 1 Distrito Industrial<br />

Americo Brasiliense, SP, CEP 14820-000<br />

Brazil<br />

• Tel/Fax: +55 (16 ) 3392 6885<br />

• Email: sales@whitfordww.com.br<br />

Visit us at www.whitfordww.com or Email us at sales@whitfordww.com<br />

Xylan is a registered trademark of Whitford.<br />

NON-WARRANTY: THE INFORMATION PRESENTED IN THIS PUBLICATION IS BASED UPON THE RESEARCH AND EXPERIENCE OF WHITFORD. NO<br />

REPRESENTATION OR WARRANTY IS MADE, HOWEVER, CONCERNING THE ACCURACY OR COMPLETENESS OF THE INFORMATION<br />

PRESENTED IN THIS PUBLICATION. WHITFORD MAKES NO WARRANTY OR REPRESENTATION OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING<br />

WITHOUT LIMITATION ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE, AND NO WARRANTY OR REPRE-<br />

SENTATION SHALL BE IMPLIED BY LAW OR OTHERWISE. ANY PRODUCTS SOLD BY WHITFORD ARE NOT WARRANTED AS SUITABLE FOR ANY<br />

PARTICULAR PURPOSE TO THE BUYER. THE SUITABILITY OF ANY PRODUCTS FOR ANY PURPOSE PARTICULAR TO THE BUYER IS FOR THE<br />

BUYER TO DETERMINE. WHITFORD ASSUMES NO RESPONSIBILITY FOR THE SELECTION OF PRODUCTS SUITABLE TO THE PARTICULAR PUR-<br />

POSES OF ANY PARTICULAR BUYER. WHITFORD SHALL IN NO EVENT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES.<br />

WC9/03

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