TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
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PRES <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
PRES<br />
Presidential Event<br />
J. Francisco, ACS President,<br />
Program Chair<br />
SUNDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 210A<br />
Translational <strong>Chemical</strong> R&D: The Driving<br />
Force of Job Creation Cosponsored by CCR<br />
F. E. Walworth, Organizer<br />
1:30 Introductory Remarks. S. W. Synder,<br />
H. Semerjian<br />
1:40 Translational chemical R&D: The driving<br />
force of job creation. P. N. Confalone<br />
2:00 Translational chemical R&D: The driving<br />
force of job creation. C. A. Mirkin<br />
2:20 Translational chemical R&D: The driving<br />
force of job creation. M. Alger<br />
2:40 Question and Answer<br />
3:10 Translational chemical R&D: The driving<br />
force of job creation. M. G. Allen<br />
3:30 Translational chemical R&D: The driving<br />
force of job creation. E. D. Isaacs<br />
3:50 Translational chemical R&D: The driving<br />
force of job creation. C. W. Wessner<br />
4:10 Question and Answer<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 210B/C<br />
The Impact of Science and Technology on<br />
the Future of Global Healthcare<br />
D. Phillips, Organizer, Presiding<br />
2:00 Welcome. J. Francisco, ACS President<br />
2:10 Introductory Remarks. D. J. Phillips<br />
2:15 T.Z. and Irmgard Chu Distinguished<br />
Professor. C. R. Bertozzi<br />
3:00 Biotech 2010 Life Sciences: Adapting<br />
for success. S. Burrill<br />
3:45 A diet for health and longevity: How do<br />
we get there? B. N. Ames<br />
4:30 Biomaterials and biotechnology: From<br />
the discovery of angiogenesis inhibitors<br />
to the development of drug delivery systems<br />
and the foundation of tissue engineering.<br />
R. S. Langer<br />
5:15 Closing Remarks.<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 254A/B<br />
Astellas USA Foundation Award: Lectures<br />
in Research and Process Chemistry to<br />
Improve Human Health Symposium<br />
2–TECH<br />
F. E. Walworth, Organizer<br />
2:00 Introductory Remarks: J. Francisco,<br />
ACS President<br />
2:10 Introductory Remarks: K. Voorhees<br />
2:15 1. Chemistry of breathing: Lung surfactant<br />
and its role in the proper functioning<br />
of the lung. K. C. Lee<br />
2:55 Introductory Remarks: K. Voorhees<br />
3:00 2. Global arsenic crisis in drinking water:<br />
New findings for sustainable solution.<br />
A. K. SenGupta<br />
3:40 Introductory Remarks: K. Voorhees<br />
3:45 3. Synthesis and characterization of<br />
carotenoids and their metabolites in human<br />
serum and ocular tissues and their<br />
implication in the prevention of agerelated<br />
macular degeneration.<br />
F. Khachik<br />
‡ Cooperative Cosponsorship<br />
4:25 Concluding Remarks: K. Voorhees<br />
Connections to Germany and Europe:<br />
Education and Research Opportunities<br />
Sponsored by CHED, Cosponsored by CHED,<br />
IAC, PRES, SCTF, SOCED, WCC, and YCC<br />
MONDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 210A<br />
Sustainability Education<br />
F. E. Walworth, Organizer<br />
8:30 Introductory Remarks: J. S. Francisco,<br />
ACS President<br />
8:45 4. Sustainability education: A challenge<br />
to the engineering profession. B. Allenby<br />
9:15 5. Words into action: Sustainability.<br />
F. Wood-Black<br />
9:45 Break<br />
10:00 6. Youth encounters on sustainability:<br />
A new educational paradigm. R. Baud<br />
10:30 7. Sustainability: Matching our curriculum<br />
to our planet. C. Middlecamp<br />
11:00 Q&A/Discussion<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 210B/C<br />
Excellence in the Undergraduate Chemistry<br />
Curriculum: A Global Perspective<br />
Cosponsored by CPT and SOCED<br />
C. Larive, Organizer, Presiding<br />
8:50 Introductory Remarks<br />
9:00 8. Excellent chemistry students require<br />
excellent chemistry programs.<br />
C. G. Gutierrez<br />
9:30 9. Diversity equity is a figure of merit.<br />
R. Hernandez<br />
10:00 10. Using the 2008 ACS Guidelines to<br />
promote excellence and improve rigor in<br />
undergraduate chemistry education.<br />
W. F. Polik<br />
10:30 11. Post-Bologna process undergraduate<br />
chemistry curricula in Europe.<br />
A. K. Smith<br />
11:00 12. Atlantis: An international exchange<br />
program for undergraduates majoring<br />
in chemistry from the United<br />
States, Ireland and Germany.<br />
S. M. Lunte, C. E. Lunte, F. Regan,<br />
P. James, J. Aube, O. Reiser<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 210B/C<br />
Excellence in the Undergraduate Chemistry<br />
Curriculum: A Global Perspective<br />
Cosponsored by CPT and SOCED<br />
C. Larive, Organizer, Presiding<br />
1:20 Introductory Remarks<br />
1:30 13. America’s great idea: Advancing<br />
community college education in the US<br />
and abroad. J. V. Clevenger<br />
2:00 14. Improving student engagement in<br />
the laboratory: An initiative across all<br />
Australian universities. S. C. Barrie,<br />
M. A. Buntine, K. Burke da Silva, K. Lim,<br />
S. Pyke, M. Sharma, A. Yeung,<br />
S. H. Kable<br />
2:30 15. Integration of research and teaching<br />
in the classroom. J. M. Gentile<br />
3:00 16. Enriching undergraduate education<br />
in Chemistry to achieve global competitiveness:<br />
The value of an international<br />
REU program. L. E. Echegoyen<br />
3:30 17. Think globally: Study abroad opportunities<br />
for science undergraduates.<br />
M. Z. Hoffman<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 210A<br />
ACS/CEI Recognition of Exemplary Work in<br />
Incorporation of Sustainability into<br />
Chemistry Curriculum<br />
Cosponsored by CEI<br />
M. Fisher, Organizer, Presiding<br />
1:30 Introductory Remarks. C. A. Hunt<br />
1:45 2. Infusing sustainability / green chemistry<br />
across the undergraduate and graduate<br />
curricula, and beyond. M. Cann<br />
2:30 3. Sustainability as the organizing<br />
theme for a chemistry laboratory program.<br />
S. Sutheimer<br />
3:15 4. Expanding access to experimental<br />
science through green chemistry.<br />
K. M. Doxse<br />
4:00 5. Facilitating simpler, safer, and sustainable<br />
experimental chemistry education.<br />
J. G. Ibanez<br />
Section C<br />
Sheraton Boston<br />
Back Bay Ballroom C<br />
ACS Scholars Program Results: Stories<br />
Highlighting 15 Successful Years<br />
Cosponsored by CMA, CTA, CWD, PROF,<br />
WCC, and YCC Financially supported by PPG<br />
Industries Foundation<br />
L. Watkins, Organizer<br />
C. Gutierrez, Presiding<br />
2:00 Remarks by ACS President Joe Francisco<br />
2:05 Introductory Remarks<br />
2:10 18. ACS Scholars Program: From concept<br />
to fruition. C. G. Gutierrez<br />
2:30 19. ACS Scholar’s Journey: Erica<br />
Thorne. E. Thorne<br />
2:40 20. ACS Scholar’s Journey: Jacqueline<br />
Thomas. J. B. Thomas<br />
2:50 21. ACS Scholar’s Journey: Amy Paris.<br />
A. K. Paris<br />
3:00 22. ACS Scholar’s Journey: Bart Bartlett.<br />
B. Bartlett<br />
3:10 23. ACS Scholar’s Journey: Bernadette<br />
Hernandez-Sanchez.<br />
B. A. Hernandez-Sanchez<br />
3:20 24. ACS Scholar’s Journey: José Cintrón.J.<br />
M. Cintrón<br />
3:30 Panel Discussion<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
TUESDAY MORNING<br />
Section B<br />
Sheraton Boston<br />
Back Bay Ballroom B<br />
Women Chemists of Color (WCoC) Summit:<br />
Getting to the Table Cosponsored by CMA,<br />
JSD, PROF, and WCC<br />
G. Thomas, Z. Wilson, Organizers,<br />
Presiding<br />
8:15 Introductory Remarks<br />
8:25 25. Julia Chan: Louisiana State University.<br />
J. Chan<br />
8:35 26. Robyn Hannigan: University of<br />
Massachusetts at Boston. R. Hannigan<br />
8:45 27. Malika Jeffries-El: Iowa State University.<br />
M. Jeffries-El<br />
8:55 28. Linette Watkins: Texas State University<br />
- San Marcos. L. Watkins<br />
9:05 29. Kristala Jones Prather: Massachusetts<br />
Institute of Technology.<br />
K. J. Prather<br />
9:15 30. Shu Shu: Shell International Exploration<br />
and Production. S. Shu<br />
9:25 31. Sharon Kennedy: Colgate-Palmolive<br />
Company. S. L. Kennedy<br />
9:35 Panel Discussion<br />
9:55 Intermission<br />
10:10 Question and Answer Session<br />
11:10 Concluding Remarks<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 210A<br />
Encouraging Disadvantaged Students into<br />
Careers in the <strong>Chemical</strong> Sciences ACS<br />
Award Symposium in Honor of<br />
Robert L. Lichter<br />
C Gutierrez, F. E. Walworth, Organizers,<br />
Presiding<br />
8:30 Introductory Remarks. C. Gutierrez<br />
8:40 Arabs, Muslims, and diversity in <strong>American</strong><br />
science. N. B. Jackson<br />
9:10 Same as it ever was: the status of doctoral<br />
level underrepresented US racial<br />
and ethnic minorities in science and engineering.<br />
W. Pearson, Jr.<br />
9:40 The economics of diversity in the<br />
chemistry profession 1968-2009.<br />
S. J. Myers, Jr.<br />
10:10 Intermission.<br />
10:25 Encouraging diversity. T. Maldonaldo<br />
10:55 Encouraging diversity. J. Wyche<br />
11:25 Question and Answer.<br />
11:55 Closing Remarks. C. Gutierrez<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 210A<br />
Encouraging Disadvantaged Students into<br />
Careers in the <strong>Chemical</strong> Sciences ACS<br />
Award Symposium in Honor of<br />
Robert L. Lichter<br />
C Gutierrez, F. E. Walworth, Organizers,<br />
Presiding<br />
1:30 Introductory Comments and Introduction<br />
of Award Recipient. C. Gutierrez<br />
1:45 Award Address (ACS Award for Encouraging<br />
Disadvantaged Students into<br />
Careers in the <strong>Chemical</strong> Sciences Sponsored<br />
by The Camille and Henry Dreyfus<br />
Foundation, Inc.) Thank you for opening<br />
the doors to a beautiful career. R. L.<br />
Lichter<br />
2:20 Who so few? M. C. Adams<br />
2:50 Intermission.<br />
3:05 Encouraging diversity. T. Q. Gray<br />
3:35 Encouraging diversity. W. Harris<br />
4:05 Question and Answer.<br />
4:50 Closing Comments. C. Gutierrez<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 210B<br />
Laboratory Safety Cosponsored by CCS,<br />
CHAS, and financially supported by Board of<br />
<strong>Chemical</strong> Sciences and Technology of the<br />
National Research Council, and National<br />
Academies<br />
F. E. Walworth, Organizer<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
1:30 Introductory Remarks<br />
1:40 32. Prudent practices in the laboratory:<br />
Handling and management of chemical<br />
hazards. W. F. Carroll Jr., B. L. Foster,<br />
K. Hughes<br />
2:10 33. Development of chemical safety<br />
program at Chulalongkorn University.<br />
S. Tantayanon<br />
2:40 34. Promoting chemical laboratory<br />
safety and security in developing countries.<br />
C. P. Casey, T. M. Masciangioli<br />
3:20 35. The state of chemical safety in laboratories<br />
of African universities.<br />
T. Engida<br />
4:00 36. Safety in academic laboratories:<br />
The perspective of the US <strong>Chemical</strong><br />
Safety Board. J. Bresland<br />
Section C<br />
Sheraton Boston<br />
Back Bay Ballroom B<br />
Women Chemists of Color Summit: Staying<br />
at the Table Cosponsored by BMGT, CMA,<br />
COMSCI, JSD, PROF, and YCC<br />
A. Charlebois, J. Iriarte-Gross, R. Libby,<br />
I. Montes, Organizers<br />
J. Bryant, N. N. Bridges, Organizers,<br />
Presiding<br />
2:00 Introductory Remarks<br />
2:05 37. Hispanic women: How to rise<br />
above challenges and move forward?<br />
I. Montes<br />
2:15 38. Navigation of my career. E. Harris<br />
2:25 39. Where are the underrepresented<br />
minority women chemistry professors?<br />
D. Nelson<br />
2:35 40. Being the “only” one and making it<br />
work. N. Bridges<br />
2:45 Panel Discussion<br />
3:15 Concluding Remarks<br />
WEDNESDAY EVENING<br />
POLY/PMSE Plenary Lecture and Awards<br />
Reception Sponsored by POLY,<br />
Cosponsored by PMSE and PRES<br />
CPCD<br />
Chemistry for Preventing<br />
& Combating Disease<br />
J. Finley and K. A. Jacobson,<br />
Program Chairs<br />
SUNDAY AFTERNOON<br />
Job Growth in This Economy?: Clinical<br />
Supply Manufacture and Local Economies<br />
of Scale Sponsored by BMGT, Cosponsored<br />
by CPCD<br />
MONDAY MORNING<br />
Open-source Drug Discovery Sponsored by<br />
BMGT, Cosponsored by CPCD, MEDI<br />
MONDAY AFTERNOON<br />
Open-source Drug Discovery Sponsored by<br />
BMGT, Cosponsored by CPCD, MEDI<br />
AEI<br />
Academic Employment<br />
Initiative<br />
C. Kuniyoshi and J. Z. Sostaric,<br />
Program Chairs<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exposition Center<br />
Hall C<br />
Academic Employment Initiative<br />
C. Kuniyoshi, J. Z. Sostaric, Organizers<br />
8:00–10:00<br />
1. Allergens in propolis: Analytical problems<br />
and removal treatments. A. Aliboni<br />
2. Molecular beam study on nonthermal<br />
plasma treatment of air pollutants. L. He<br />
3. Histone modifications: Using chemical<br />
and biochemical techniques to explore<br />
the functions and regulatory enzymes of<br />
these complex and essential marks.<br />
E. M. Kolonko,J.M.Denu<br />
4. Translating the small molecule “languages”<br />
that regulate behavior in biological<br />
systems. A. G. Palmer<br />
5. Small molecule regulation of an algal-bacterial<br />
symbiosis. M. R. Seyedsayamdost,<br />
R. J. Case, R. Kolter, J. Clardy<br />
6. Designing, implementing, and evaluating<br />
research-based innovations in undergraduate<br />
chemistry courses: Giving students<br />
the foundation to succeed at all<br />
levels of chemistry. M. Barker<br />
7. Nano- and micron-sized particle design,<br />
functionalization, and patterning.<br />
E. M. Glogowski, J. S. Moore,<br />
J. A. Lewis<br />
8. Insights and applications of using various<br />
aryl-azido compounds for the inactivation<br />
of human immunodeficiency virus (HIV-1):<br />
Towards the generation of a novel inactivated<br />
vaccine strategy. J. M. Belanger,<br />
Y. Raviv, M. Viard, J. W. Bess,<br />
R. Blumenthal<br />
9. Withdrawn<br />
10. Oligophenylenaminones: Novel scaffold<br />
for helix mimicry. M. J. Adler,<br />
A. D. Hamilton<br />
11. Application of computational chemistry<br />
methods to biological systems and drug<br />
discovery. S. Zhong<br />
12. Collective behavior in biomimetic microcapsules.<br />
A. Bhattacharya<br />
13. Investigating the design of natural and<br />
artificial nanostructures and their applications<br />
to nanomedicine. A. Y. Koyfman<br />
14. Evaluating the Bruker SMART X2S<br />
bench-top system: A means to bringing<br />
X-ray crystallography into the undergraduate<br />
curriculum. U. I. Zakai, I. A. Guzei,<br />
N. J. Hill<br />
15. Multifunctional contrast agents for targeted<br />
and multimodal molecular imaging.<br />
C. Tu<br />
16. Interactions of Re(CO) 3 � based compounds<br />
with cells and proteins.<br />
S. L. Binkley, C. J. Ziegler, R. S. Herrick,<br />
R. S. Rowlett, A. Milsted<br />
17. Development of novel tools to probe biological<br />
functions. D. D. Young, A. Deiters,<br />
P. G. Schultz<br />
18. Probing cellular DNA/protein interactions<br />
using chromatin DNA rehybridization to<br />
identify transcription factors of oncogenes.<br />
H. Zhang, S. K. Morse,<br />
L. B. McGown<br />
19. Photobiogeochemistry of dissolved organic<br />
matter in natural waters.<br />
E. M. White<br />
20. Synthesis, characterization, and reactivity<br />
of electrophilic iridium and rhodium<br />
pincer complexes. M. Findlater,<br />
M. Brookhart<br />
21. Imaging and catalysis: Fluorescent sensors<br />
for metal ions, organocatalysis, and<br />
lanthanide-based catalysis. Y. Mei<br />
22. Enzymatic active site modeling and transition<br />
metal containing assemblies for industrial<br />
and medicinal applications.<br />
M. Kumar<br />
23. Learning from Nature: The design and<br />
application of bioinspired catalysts for<br />
oxidation chemistry. G. Xue, L. Que, Jr.<br />
24. Carbon nanotubes based solar energy<br />
collectors, a bioorganic DNA derivative<br />
skin cancer model, and synthetic methodology<br />
for pharmaceuticals for Alzheimer’s<br />
disease. J. Hahn<br />
25. Synthesis, chararacterization, and applications<br />
of polymeric materials.<br />
M. J. Nasrullah<br />
26. Main group organometallic chemistry<br />
and reactivity of carbonyl compounds.<br />
K. J. Kolonko, H. J. Reich<br />
27. Palladium and iron catalyzed direct arylation<br />
reactions. J. J. Mousseau,<br />
A. B. Charette<br />
28. Innovative technologies for natural products<br />
discovery. A. Y. Odendaal,<br />
D. J. Trader, E. E. Carlson<br />
29. Learn by doing: Creating an effective undergraduate<br />
experience through teaching<br />
and research. A. Moser<br />
30. Boronic acid end-functionalized polycaprolactone<br />
polymers as macromolecular<br />
reagents for the development of novel<br />
materials. A. L. Korich, P. M. Iovine<br />
31. First-principles based modeling of molecular<br />
electronic excitations in biological<br />
systems. D. Kosenkov, L. V. Slipchenko<br />
32. Improved solar systems based on selfassembled<br />
nanomaterials, and improved<br />
formulations of vaccines and protein<br />
drugs. V. Kayser<br />
33. Silicon-based nanomaterials for alternative<br />
energy and biocompatible luminescent<br />
imaging. E. A. McArthur<br />
34. Terahertz spectroscopy as an incisive<br />
tool to elucidate protein conformation<br />
and role of biological water in Alzheimer’s<br />
disease. Z. Ahmed, D. F. Plusquellic<br />
35. Zwitterionic/mixed-charge polymers as<br />
next-generation biomaterials. Z. Cao,<br />
S. Jiang<br />
36. First principles study of the photodynamics<br />
of oxidized silicon clusters.<br />
B. G. Levine<br />
37. Putting � bonds to work in organic electronics.<br />
S. A. Odom, J. E. Anthony,<br />
S. R. Marder, J. S. Moore<br />
38. Bioinspired design and synthesis of hierarchical,<br />
adaptive, dynamic architectures.<br />
P. Kim<br />
39. Modeling macromolecular structure, dynamics<br />
and energetics. J. L. Knight,<br />
C. L. Brooks<br />
40. Improving delivery of opioid peptides<br />
across blood-brain barrier by glycosylation.<br />
D. Muthu, C. M. Keyari, Y. Li, R. Polt<br />
41. Bridging homogeneous and heterogeneous<br />
chemistry to develop new catalysts,<br />
learn fundamentals of reactivity,<br />
and educate the next generation of scientists.<br />
D. R. Weinberg<br />
42. Isothermal-isobaric ab initio molecular<br />
dynamics: Application to water. Z. Ma,<br />
M. Tuckerman<br />
43. Electrochemical preparation of p-type<br />
ternary metal oxides for solar energy conversion.<br />
C. G. Read,K.Choi<br />
44. Materials with purpose: Designer materials<br />
for applications from every approach.<br />
A. P. Esser-Kahn, J. S. Moore<br />
45. Development of the first Lewis base catalyzed,<br />
enantioselective selenocyclization<br />
reaction and progress toward novel carbon-carbon<br />
bond forming technologies<br />
for carbon nanotube and graphitic surface<br />
functionalization. W. R. Collins,<br />
T. M. Swager, S. E. Denmark<br />
46. New format carbohydrate microarray: Its<br />
application for identification of multivalent<br />
inhibitors. Y. Zhang,Q.Li,<br />
L. G. Rodriguez, C. Campbell,<br />
D. Farnsworth, J. C. Gildersleeve<br />
47. Facilitating sustainable energy solutions<br />
with computational tools. Y. A. Kholod,<br />
M. S. Gordon<br />
PRES/CPCD/AEI<br />
48. Study of electron-transfer in transition<br />
metal complexes with valence resonant<br />
inelastic X-ray scattering. D. A. Meyer,<br />
K. J. Gaffney, U. Bergmann<br />
49. Photon and electron induced reaction<br />
dynamics at the vacuum-surface and<br />
buried interface of ice covered graphitic<br />
and silicate grains. H. L. Abbott,<br />
G. A. Grieves, M. Dawley, J. L. McLain,<br />
T. M. Orlando<br />
50. Synthesis and characterization of nanobuilding<br />
blocks for materials design.<br />
M. F. Roll<br />
51. Smart polymer-protein conjugates by<br />
RAFT polymerization: Potential applications<br />
in drug delivery. H. Li<br />
52. Using organometallic catalysts as oxidants<br />
for fuels and devices. J. F. Hull,<br />
T. J. Meyer, G. W. Brudvig, R. H. Crabtree<br />
53. Alterations in the serum metabolome induced<br />
by chronic inflammation.<br />
E. G. Prestwich, I. Babu, K. Taghizadeh,<br />
P. C. Dedon<br />
54. Exploring excitons and plasmons in single<br />
nanocrystals and nanostructures.<br />
J. Zhao, M. G. Bawendi<br />
55. Optical spectroscopy investigations of<br />
carbon-based nanomaterials for fundamental<br />
energy sciences research.<br />
J. R. Rocha, H. Zhou, M. J. Heben,<br />
L. J. Simpson, J. L. Blackburn<br />
56. Noble metal nanoparticles: Plasmon-mediated<br />
synthesis and assembly.<br />
J. Zhang,C.A.Mirkin<br />
57. Investigation of ring-size effect of cyclooctene-based<br />
oligomeric Co-salen<br />
catalysts on hydrolytic kinetic resolution<br />
of epoxides. Y. LIU,M.Weck<br />
58. Sugar-responsive organoboron block<br />
copolymers. J. N. Cambre,D.Roy,<br />
B. S. Sumerlin<br />
59. Reversible hydrogen storage and hydrogen<br />
multicenter bonds: Fundamental<br />
study on metal hybrid clusters.<br />
T. Dhilip Kumar<br />
60. Probing the assembly of the molybdenum-iron<br />
cofactor (FeMo-co) of nitrogenase<br />
using Mössbauer and EPR spectroscopies.<br />
Y. Guo, M. Demuez,<br />
L. M. Rubio<br />
61. Bioactive synthetic nanostructured extracellular<br />
matrices for biomedical applications.<br />
W. Suh, G. D. Stucky, M. Tirrell<br />
62. Stereodynamic tripodal ligand with three<br />
different coordinating arms: Synthesis<br />
and Zinc(II), Copper(I) complexation<br />
study. J. Liang,J.W.Canary<br />
63. QM/MM model and water splitting mechanism<br />
of the O 2-evolving complex of photosystem<br />
II. E. M. Sproviero,<br />
G. W. Brudvig, V. S. Batista<br />
64. Understanding structure-property relationships<br />
in the design of chemosensors,<br />
chromophores, and electronic devices.<br />
T. L. Andrew<br />
65. Confined laser IR resonance vibrational<br />
decomposition of molecular precursors:<br />
A new strategy for superhard materials<br />
syntheses and ceramic/polymer composite<br />
formation. bridging the gap between<br />
chemistry, physics, and materials science.<br />
B. L. Ivanov<br />
66. Fluorescent probes and switches based<br />
on the xanthene dyes rhodamine and fluorescein.<br />
C. J. Stephenson<br />
67. Finding new energy materials using computational<br />
chemistry and high-throughput<br />
screening. U. Das,W.H.Green<br />
68. Polycyclic aromatic hydrocarbons in science<br />
and technology. F. S. Ehrenhauser,<br />
M. J. Wornat, K. T. Valsaraj<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–3
AEI/AGFD <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
69. Stereoselective formation of N 2 -dG:<br />
N 2 -dG carbinolamine interstrand crosslinks<br />
arising from enal derived exocyclic<br />
1,N 2 -dG adducts. H. Huang,<br />
I. D. Kozekov, H. Wang, C. J. Rizzo,<br />
M. P. Stone<br />
70. Applying single chomophore spectroscopy<br />
to problems in nanoscience, biology,<br />
and medicine. L. F. Marshall,<br />
M. Bawendi<br />
71. Aerobic oxidation and reductive elimination<br />
from platinum and palladium organometallic<br />
complexes.<br />
J. R. Khusnutdinova<br />
72. Exploring the photoreduction of Au(III)<br />
complexes in the gas-phase.<br />
J. C. Marcum, S. H. Kaufman,<br />
J. M. Weber<br />
73. Deciphering the bioinorganic chemistry<br />
of life by using designed peptides and<br />
proteins as chemical tools to probe living<br />
systems. A. R. Reddi, V. C. Culotta,<br />
B. R. Gibney<br />
74. Progress towards integration of cobaltbased<br />
water oxidation catalyst with thin<br />
film cobalt anodes and low-bandgap<br />
semiconductor photoanodes.<br />
E. R. Young, V. Bulovic<br />
75. Green chemistry for a sustainable world:<br />
Biomimetic, organocatalytic, and transition<br />
metal catalyzed oxidations.<br />
F. G. Gelalcha<br />
76. Li � fluoroionophores comprised of coumarin<br />
derivatives substituted with crown<br />
ethers. D. L. Nutbrown, C. Stevens,<br />
J. Milligan, M. Perry<br />
77. Self-assembly of molecular architectures<br />
through metal coordination chemistry.<br />
L. A. Levine, M. E. Williams<br />
AGFD<br />
Division of Agricultural<br />
and Food Chemistry<br />
A. Mitchell, Program Chair<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Undergraduate Research Symposium<br />
4–TECH<br />
C. Brine, Organizer<br />
C. J. Brine, Presiding<br />
8:30 Introductory Remarks<br />
8:35 1. <strong>Chemical</strong> and mathematical approaches<br />
to promote the development of<br />
functional foods rich in natural antioxidants.<br />
J. Hao<br />
9:05 2. Investigating the effect of common<br />
antioxidants on the generation and fate of<br />
pyrazinium radicals in the Maillard reaction.<br />
Q. Bin, D. G. Peterson, R. J. Elias<br />
9:35 3. Stability of dietary polyphenolics under<br />
gastrointestinal conditions.<br />
M. A. Krook<br />
10:05 Intermission<br />
10:20 4. Starch retrogradation in gluten-free<br />
sorghum bread. E. Buckley<br />
10:50 5. Accumulation and toxicity of engineered<br />
nanoparticles to agricultural<br />
crops. J. Hawthorne<br />
11:20 6. Total polyphenol antioxidants in legumes:<br />
A major source of antioxidants.<br />
B. W. Redan, M. G. Coco, J. A. Vinson<br />
11:50 Concluding Remarks<br />
‡ Cooperative Cosponsorship<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
Agricultural and Food Derived Natural<br />
Products for Preventing and Combating<br />
Disease Purification and Characterization<br />
of Natural Compounds<br />
B. Patil, G. Jayaprakasha, K. Chidambara<br />
Murthy, N. P. Seeram, Organizers<br />
F. Pellati, G. Gowda, Presiding<br />
8:30 Introductory Remarks<br />
8:35 7. Comprehensive study of Digitalis<br />
Purpurea by selective ionization of cardiac<br />
glycosides using ESI-LC-QTrap.<br />
F. Shadkami, M. D. Celiz, A. D. Jones<br />
9:00 8. Rapid method for the separation of<br />
polymethoxyflavones using flash chromatography.<br />
R. M. Uckoo,<br />
G. K. Jayaprakasha, B. S. Patil<br />
9:25 9. Release of bound procyanidins from<br />
cranberry pomace by alkaline hydrolysis.<br />
B. L. White, L. R. Howard, R. L. Prior<br />
9:50 Intermission<br />
10:05 10. Correlating component variability<br />
of black raspberry (Rubus occidentalis L.)<br />
fruit extracts with chemical and biological<br />
responses using NMR data and multivariate<br />
statistical analysis. F. J. Wyzgoski,<br />
R. N. Reese, L. Paudel, P. L. Rinaldi,<br />
M. Ozgen, M. M. Giusti, J. Johnson,<br />
A. Z. Tulio, J. A. Bomser, J. K. Hardy,<br />
A. M. Chanon, J. C. Scheerens,<br />
A. R. Miller<br />
10:30 11. Metabolic profiling using isotope<br />
enhanced NMR spectroscopy methods<br />
for disease diagnostics. G. Gowda,<br />
D. Raftery<br />
10:55 12. Isolation and identification of polyphenolic<br />
compounds from Early Black<br />
Cranberry (Vaccinium macrocarpon), a<br />
pest-resistant cultivar. C. A. Dao,<br />
C. C. Neto, M. R. Salvas,<br />
J. E. Vanden Heuvel, B. T. Murphy<br />
11:20 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
160C<br />
General Papers<br />
A. Mitchell, Organizer<br />
A. Loaiza, N. Da Costa, Presiding<br />
8:30 Introductory Remarks<br />
8:35 13. Cranberry flavonol glycoside bioavailability<br />
in humans with type-2 diabetes.<br />
N. Vorsa, A. P. Singh, T. Wilson,<br />
V. Vorsa<br />
8:55 14. Selective separation of polyphenols<br />
using magnetic beads coated with hydrogen<br />
bonding ligands. T. Dong, Q. Zhou,<br />
X. Xiong, S. Chen<br />
9:15 15. Induction of HCT116 and HT29 colon<br />
cancer cell death by cranberry proanthocyanidins<br />
via mitogen activated protein<br />
kinase pathway. A. M. Liberty,<br />
T. P. Ferreira, C. C. Neto<br />
9:35 16. Resveratrol as a kcat type inhibitor<br />
of tyrosinase enzyme: Potentials as a<br />
melanogenesis inhibitor. H. Satooka,<br />
I. Kubo<br />
9:55 Intermission<br />
10:10 17. Content of nutritional substances<br />
in commercial tea beverages. S. Li,C.Lo,<br />
N. E. Rawson, P. Lucas-Schnarre, C. Ho<br />
10:10 18. Acrylamide in cereal products:<br />
Precursors, formation, and control measures.<br />
A. Mustafa<br />
10:30 19. Surface plasmon resonance (SPR)<br />
detection of staphylococcal enterotoxin A<br />
in food samples. M. B. Medina<br />
10:50 Concluding Remarks<br />
Nutritional Chemistry Symposium<br />
Sponsored by SOCED, Cosponsored by<br />
AGFD<br />
SUNDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
Agricultural and Food Derived Natural<br />
Products for Preventing and Combating<br />
Disease In Vitro Model<br />
B. Patil, G. Jayaprakasha, K. Chidambara<br />
Murthy, Organizers<br />
N. P. Seeram, Organizer, Presiding<br />
B. Neelwarne, Presiding<br />
1:00 Introductory Remarks<br />
1:05 20. Isolation, structure elucidation, synthesis<br />
and cytotoxic activity of polyacetylenes<br />
and polyenes from Echinacea pallida.<br />
F. Pellati, A. Chicca, B. Adinolfi,<br />
G. Orlandini, F. Prati, P. Nieri,<br />
S. Benvenuti<br />
1:30 21. Potential therapeutic applications<br />
of common agro-food byproducts and<br />
Chilean wild plants. J. S. Torres,<br />
M. N. Garcia, M. Rubilar, M. Cascante,<br />
E. Alvarez, M. Sanchez<br />
1:55 22. Compositional characteristics of<br />
fruits of hawthorn (Crataegus sp.) and<br />
emblic leafflower (Phyllanthus emblica).<br />
B. Yang, H. Kallio, P. Liu, M. Kortesniemi<br />
2:20 23. Natural pigments enhance stability<br />
of mRNAs of anti-oxidant enzymes in cultured<br />
mammalian cells. B. Neelwarne,<br />
J. M. Veigas<br />
2:45 Intermission<br />
3:00 24. Sugar maple (Acer saccharum)<br />
phytochemicals: Antioxidant, antibacterial,<br />
and cancer cell cytotoxicity properties.<br />
L. Li, N. P. Seeram<br />
3:25 25. Carrot bisacetylenic oxylipins: Phytochemicals<br />
behind the mask of the superfood.<br />
B. T. Metzger<br />
3:50 26. Beyond olive oil: Active components<br />
and health aspects of some less<br />
known Mediterranean plant products.<br />
N. Kalogeropoulos, A. Chiou,<br />
A. C. Kaliora, V. T. Karathanos,<br />
N. K. Andrikopoulos<br />
4:15 Concluding Remarks<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Young Scientist Award Symposium<br />
C. Brine, Organizer<br />
C. J. Brine, Presiding<br />
1:30 Introductory Remarks<br />
1:35 27. Bioactive secondary metabolites<br />
from agro-food industrial byproducts as<br />
source of dietary supplements.<br />
G. Jayaprakasha, B. S. Patil<br />
2:05 28. Bioavailability and delivery of nutraceuticals<br />
using nanotechnology.<br />
Q. Huang<br />
2:35 29. Rhizospheric signaling: From positive<br />
feedback to innate plant defense.<br />
H. Bais<br />
3:05 Intermission<br />
3:20 30. Stable isotope dilution assays for<br />
quantification of bioactives: Challenges<br />
and pitfalls. T. Stark<br />
3:50 31. Electrospun nanofibrous membranes:<br />
Novel materials for food technology<br />
applications. A. Arecchi<br />
4:20 32. Analytical techniques ensure performance<br />
and quality of encapsulates.<br />
D. DiNallo<br />
4:50 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 160C<br />
General Papers<br />
A. Mitchell, Organizer, Presiding<br />
N. Da Costa, K. Mahattanatawee,<br />
Presiding<br />
1:30 Introductory Remarks<br />
1:35 33. Enrichment of the antioxidant activity<br />
in potato tuber by ultrasound and electric<br />
treatments. K. Hironaka, T. Funato,<br />
H. Koaze<br />
1:55 34. Enhanced infusion of natural antioxidants<br />
into fruits using high hydrostatic<br />
pressure processing. S. Mahadevan,<br />
M. V. Karwe<br />
2:15 35. Pressurized hot ethanol extraction<br />
of carotenoids from carrot waste.<br />
A. Mustafa, C. Turner<br />
2:35 36. New paradigm for microwave extraction<br />
of essential oils and natural compounds.<br />
D. Gunn<br />
2:35 Intermission<br />
2:50 37. Food for thoughts: The potential for<br />
food patenting. K. B. Drake<br />
3:10 38. In vivo aroma release and sensory<br />
perception: The effect of HPMC concentration<br />
and viscosity. G. T. Eyres,<br />
D. C. Frank, U. Piyasiri, C. M. Delahunty<br />
3:30 39. GC-MS and sensory strawberry flavor<br />
changes at five maturity stages.<br />
X. Du, A. Plotto, E. Baldwin, R. Rouseff<br />
Careers in Chemistry<br />
What it’s Like in the Real World and How Do<br />
I Get the Job? Sponsored by SOCED,<br />
Cosponsored by AGFD<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Symposium Honoring Prof. Terry E. Acree<br />
on the Occasion of his 70th Year<br />
C. Brine, Organizer<br />
B. Halpern, C. J. Brine, Presiding<br />
8:00 Introductory Remarks<br />
8:05 40. Flavor chemistry and the perception<br />
of flavor. T. E. Acree<br />
8:45 41. Internet as a research tool for flavor<br />
chemistry: FlavorNet and beyond.<br />
D. D. Roberts<br />
9:15 42. Retronasal smelling: The roles of<br />
nasal cavity and oral cavity sensory systems.<br />
B. P. Halpern<br />
9:45 Intermission<br />
10:00 43. Unexpurgated CHARM of Terry<br />
Acree. J. V. Leland<br />
10:30 44. Phragrance and pharmacology.<br />
S. Firestein<br />
11:00 Award Presentation<br />
11:15 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 160C<br />
General Papers<br />
A. Mitchell, Organizer<br />
A. Rimando, K. Cadwallader,<br />
V. Acquarone, Presiding<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
8:00 Introductory Remarks<br />
8:05 45. Rapid screening method for the determination<br />
of rodenticide content of<br />
commercial bait formulations.<br />
D. A. Goldade, D. L. Griffin, D. T. Keller<br />
8:25 46. Multiresidue pesticide analysis of<br />
botanical dietary supplements by GC-<br />
MS/MS and LC-MS/MS. F. Shi,<br />
J. W. Wong, K. Zhang, D. G. Hayward,<br />
T. H. Begley<br />
8:45 47. Determination of diphacinone in<br />
kestrel and rat brain tissue. S. F. Volker,<br />
K. E. Horak, B. A. Rattner, D. A. Goldade<br />
9:05 48. Genetic makeup of native proteins<br />
changes the secondary structure features:<br />
A synchrotron FTIR study of Arabidopsis<br />
seed storage proteins.<br />
T. Sanjeewa, D. D. Hegedus, P. Yu,<br />
X. Qiu, T. C. McIntosh, T. May,<br />
J. P. Wanasundara<br />
9:25 Intermission<br />
9:40 49. Effect of novel cutinase CcCut1 in<br />
degrading potato suberin and berry cutin.<br />
R. Järvinen, U. Holopainen, A. Nyyssölä,<br />
A. Silvestre, A. Gil, P. Lehtinen,<br />
J. Buchert, H. Kallio<br />
10:00 50. Native and synthetic autoinducers<br />
regulate the virulence of the plant pathogens<br />
Pectobacterium carotovora and<br />
Pseudomonas syringae in host plants.<br />
A. G. Palmer, E. Streng, H. E. Blackwell<br />
10:20 51. Poly(lactic acid) and Osage orange<br />
wood fiber composites for agricultural<br />
mulch films. V. Finkenstadt,<br />
B. Tisserat<br />
10:40 52. Uptake of organochlorine pesticides<br />
by agricultural crops: Mechanistic<br />
studies. W. A. Berger, M. I. Mattina<br />
11:00 Concluding Remarks<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
Agricultural and Food Derived Natural<br />
Products for Preventing and Combating<br />
Disease In Vitro Model<br />
B. Patil, K. Chidambara Murthy,<br />
N. P. Seeram, Organizers<br />
G. Jayaprakasha, Organizer, Presiding<br />
H. Xiao, H. Humpf, Presiding<br />
8:30 Introductory Remarks<br />
8:35 53. Hydroxylated polymethoxyflavones<br />
from orange peel as novel cancer preventive<br />
agents. H. Xiao, P. Qiu, P. Dong,<br />
C. Ho, S. Li<br />
9:00 54. Anthocyanin-containing fruits and<br />
vegetables are functional foods with potential<br />
to ameliorate debilitating diseases.<br />
M. G. Nair<br />
9:25 55. Lipid accumulation and inflammation<br />
inhibition by Vaccinium floribundum<br />
proanthocyanidins. M. Schreckinger,<br />
J. Wang, G. Yousef, M. Lila,<br />
E. Gonzalez de Mejia<br />
9:50 56. Mediterranean wild plants: Endless<br />
source of natural food additives?<br />
A. Fiorentino, B. D’Abrosca, A. Esposito,<br />
M. Isidori, P. Monaco, S. Pacifico,<br />
S. Piccolella, A. Ricci, M. Scognamiglio<br />
10:15 Intermission<br />
10:30 57. Pig cecum model: A powerfull<br />
system to mimic the human intestinal metabolism<br />
of flavonoids. G. van ’t Slot,<br />
K. Rose, A. Engemann, H. Humpf<br />
10:55 58. Bioactive constituents from Formosan<br />
Kadsura and Schisandra. Y. Shen<br />
11:20 59. <strong>Chemical</strong> properties and antioxidant<br />
capacity of Chinese bay berry juice.<br />
X. Ye<br />
11:45 Concluding Remarks<br />
MONDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
Agricultural and Food Derived Natural<br />
Products for Preventing and Combating<br />
Disease In Vitro Model<br />
B. Patil, G. Jayaprakasha, K. Chidambara<br />
Murthy, N. P. Seeram, Organizers<br />
D. Klimis-Zacas, S. Poulose, Presiding<br />
1:00 Introductory Remarks<br />
1:05 60. Berry extracts and brain aging:<br />
Clearance of toxic protein accumulation<br />
in brain via induction of autophagy.<br />
S. M. Poulose, D. F. Bielinski,<br />
B. Shukitt-Hale, D. R. Fisher, J. A. Joseph<br />
1:30 61. Composition of fruit and vegetative<br />
cranberry phenolics with relation to antioxidant<br />
capacity. N. Vorsa, A. P. Singh,<br />
T. Wilson, M. R. Freeman, V. Vorsa<br />
1:55 62. Enhanced production of anticancer<br />
Camptothecins in Camptotheca. S. Li,<br />
Z. Zhang, P. Wang, W. Yuan<br />
2:20 63. <strong>Chemical</strong> constituents and biological<br />
activity of Taiwanese sugar cane extract.<br />
Y. Wu<br />
2:45 Intermission<br />
3:00 64. Inhibition of intestinal alpha-glucosidases<br />
and anti-postprandial hyperglycemic<br />
effect of grape seed extract.<br />
K. Zhou<br />
3:25 65. Wild Blueberries (Vaccinium angustifolium):<br />
Modulators of vascular function,<br />
structure and metabolism.<br />
D. Klimis-Zacas<br />
3:50 66. Distribution and biological activity<br />
of Citrus juices flavonoids. D. Barreca,<br />
E. Bellocco, C. Caristi, U. Leuzzi,<br />
G. Gattuso<br />
4:15 Concluding Remarks<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Symposium Honoring Prof. Terry E. Acree<br />
on the Occasion of his 70th Year Award<br />
Symposium<br />
C. Brine, Organizer<br />
A. Taylor, D. Roberts, Presiding<br />
1:30 Introductory Remarks<br />
1:35 67. Flavor of foods: The sound of an orchestra<br />
rather than that of a single instrument.<br />
P. H. Schieberle<br />
2:05 68. What do we taste, when we taste?<br />
T. Hofmann<br />
2:35 69. Aroma release, qualia and perceived<br />
flavour. A. J. Taylor<br />
3:05 Intermission<br />
3:20 70. Identification of new strawberry sulfur<br />
volatiles and changes during maturation.<br />
X. Du, M. Song, R. L. Rouseff<br />
3:50 71. Gas chromatography olfactometry<br />
applications to dairy products: A wonderful<br />
friendship. S. Carpino<br />
4:20 72. Integrating the culinary arts and<br />
sciences in Terry Acree’s flavor world.<br />
C. Loss<br />
4:50 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 160C<br />
Cardiovascular Disease and Diabetes<br />
J. Finley, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 73. Does lycopene have a role in the<br />
prevention of cardiovascular disease?<br />
H. D. Sesso<br />
2:05 74. Dietary fat and cardiovascular disease:<br />
Quantity or quality?<br />
A. Lichtenstien<br />
2:35 75. Polyunsaturated fatty acids and the<br />
endocannabinoid signalling system.<br />
B. A. Watkins<br />
3:05 Intermission<br />
3:10 76. Milk proteins in the regulation of<br />
food intake and metabolic syndrome.<br />
H. Anderson, B. Luhovyy, T. Akhavan,<br />
S. Panahi<br />
3:40 77. Cardiovascular health benefits of<br />
soy foods. J. W. Anderson<br />
4:10 Concluding Remarks<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 153C<br />
Chemistry and Nutrition for Better Health<br />
Plenary Lecture<br />
J. Finley, Organizer, Presiding<br />
4:00 78. Impact of early life nutrition on<br />
health and wellness. S. Roberts<br />
4:30 79. Optimum diets and natural products<br />
for disease prevention. B. N. Ames<br />
Undergraduate Research Posters<br />
Agricultural and Food Chemistry Sponsored<br />
by CHED, Cosponsored by AGFD and SOCED<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
N. Da Costa, Organizer<br />
8:00–10:00<br />
6. See previous listings.<br />
114, 118, 125, 126, 128, 131, 137, 138, 140,<br />
141, 142, 145, 151, 154, 155, 157, 160.<br />
See subsequent listings.<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Symposium Honoring Prof. Terry E. Acree<br />
on the Occasion of his 70th Year Award<br />
Symposium<br />
C. Brine, Organizer<br />
K. Cadwallader, R. Mcgorrin, Presiding<br />
8:00 Introductory Remarks<br />
8:05 80. Flavor chemistry of lemon-lime flavored<br />
carbonated beverages. B. Hausch,<br />
K. Cadwallader<br />
8:35 81. Perspectives on flavor analysis<br />
linked to chemosensory impact.<br />
R. J. McGorrin<br />
9:05 82. Zen and the art of chemosensory<br />
perception. J. F. Delwiche<br />
9:35 Intermission<br />
9:50 83. Playing with food: Flavor and food<br />
chemistry in the experimental restaurant<br />
kitchen. H. J. McGee<br />
10:20 84. Progression of the retronasal<br />
aroma simulator and flavor release sampling.<br />
K. D. Deibler<br />
10:50 85. Commercial consequences of<br />
Shallenberger and Acree’s AH,B theory of<br />
sweet taste. M. G. Lindley<br />
11:20 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 160C<br />
Nutrition and Brain Aging<br />
J. Finley, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 86. Behavioral and signaling effects of<br />
blueberries, strawberries, and walnuts:<br />
Quenching the fires of aging. J. Joseph,<br />
B. Shukitt-Hale, D. Fisher<br />
8:35 87. Application of calorie restriction<br />
and calorie restriction mimetics to attenuate<br />
brain aging. D. Ingram<br />
9:05 Intermission<br />
9:20 88. Role of an antioxidant diet and behavioral<br />
enrichment on cognition and<br />
neuropathology in the canine model of<br />
aging. E. Head<br />
9:50 89. Prevention approaches to Alzheimer<br />
disease: Omega-3 fatty acids and<br />
curcumin. G. M. Cole, Q. Ma, F. Yang,<br />
D. Gant, O. Ubeda, S. A. Frautschy<br />
10:20 Concluding Remarks<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
Agricultural and Food Derived Natural<br />
Products for Preventing and Combating<br />
Disease In Vitro Model<br />
B. Patil, G. Jayaprakasha, K. Chidambara<br />
Murthy, N. P. Seeram, Organizers<br />
B. Dayal, C. Erlanson-Albertsson,<br />
Presiding<br />
8:30 Introductory Remarks<br />
8:35 90. Methyl jasmonate: A plant stress<br />
hormone as an anticancer agent.<br />
E. Flescher<br />
9:00 91. Methyl nomilinate inhibits SW480<br />
colon cancer cells growth through modulation<br />
of cell cycle regulators. J. Kim,<br />
G. Jayaprakasha, A. Vikram, B. S. Patil<br />
9:25 92. Isolation and chemical characterization<br />
of limonoids from Azadirachta indica<br />
and Melia azaderach with biological<br />
activity. P. Caboni, N. Ntalli, C. E. Bueno,<br />
L. E. Alchè<br />
9:50 Intermission<br />
10:05 93. Characterization of bioactive compounds<br />
of selected (sub)tropical fruits<br />
and leaves grown in Jeju and their antiproliferative<br />
effects on human cancer<br />
cells through apoptosis. S. K. Cho<br />
10:30 94. Influence of the target molecule<br />
on the ORAC index. C. López-Alarcón<br />
10:55 95. Bioactive compounds from okra<br />
seeds: Potential treatments for diabetes-<br />
Type 2 and cardiovascular disease.<br />
B. Dayal, M. Lea, N. H. Ertel<br />
11:20 Concluding Remarks<br />
TUESDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
Agricultural and Food Derived Natural<br />
Products for Preventing and Combating<br />
Disease In Vivo Model<br />
B. Patil, G. Jayaprakasha, K. Chidambara<br />
Murthy, N. P. Seeram, Organizers<br />
K. Shetty, Y. Park, Presiding<br />
1:00 Introductory Remarks<br />
1:05 96. Citrus monoterpene induces apoptosis<br />
and inhibits angiogenesis in human<br />
colon cancer cells.<br />
K. N. Chidambara Murthy,<br />
G. K. Jayaprakasha, B. S. Patil<br />
1:30 97. Bioactives from a traditional herb<br />
collected from the tropical rainforest.<br />
C. Choo<br />
1:55 98. (-)-Epigallocatechin-3-gallate protects<br />
neonatal rat cardiomyocytes<br />
against oxidative stress induced by anoxia/reoxygenation<br />
injury. W. Li, S. Nie,<br />
M. Xie,S.Zhang,K.Zhu<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
AGFD<br />
TECH–5
AGFD <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
2:20 99. Conjugated fatty acids as a prevention<br />
tool for obesity and osteoporosis.<br />
Y. Park,Y.Park<br />
2:45 Intermission<br />
3:00 100. Phenolic antioxidant-enriched<br />
plant foods for prevention and management<br />
of type 2 diabetes and its complications.<br />
K. Shetty<br />
3:25 101. Bioactive constituents from Calamus<br />
quiquesetinervius and Astragalus<br />
membranaceus, and their evaluations in<br />
treating metabolic syndrome. Y. Kuo<br />
3:50 102. Protective effect of sesamol on<br />
stress-related mucosal disease in rats.<br />
D. Hsu, M. Liu<br />
4:15 Concluding Remarks<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Flavor Chemistry of Alcoholic Beverages<br />
T. Shellhammer, Organizer<br />
M. Qian, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 103. Spice up your life: Analysis of key<br />
aroma compounds in Shiraz.<br />
M. J. Herderich, T. Siebert, M. Parker,<br />
D. Capone, D. Jeffery<br />
2:00 104. Formation of carotenoid-derived<br />
aroma compounds in wine.<br />
P. Winterhalter,R.Goek<br />
2:25 105. Aroma composition of a native<br />
<strong>American</strong> grape species (Vitis cinerea)<br />
wine by SPME-GC/O/MS. Q. Sun,<br />
E. Lavin, T. E. Acree, G. L. Sacks<br />
2:50 Intermission<br />
3:10 106. Streamlined analysis of potent<br />
odorants in distilled alcoholic beverages.<br />
J. Lahne, K. Cadwallader<br />
3:35 107. (In)stability of the beer’s bitter<br />
taste: A molecular insight. T. Hofmann<br />
4:00 108. Analytical investigations to relate<br />
important wine odorant 3-mercaptohexan-1-ol<br />
to its precursors.<br />
D. L. Capone, M. A. Sefton, D. W. Jeffery<br />
4:25 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 160C<br />
Cardiovascular Disease and Diabetes<br />
J. Finley, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 109. Is the antioxidant activity of polyphenols<br />
relevant for protection against<br />
cardiovascular. P. C. Hollman<br />
2:00 110. Fine chemical structures of dietary<br />
polyphenols and their importance in understanding<br />
their role in the prevention of<br />
diseases. A. Scalbert, J. Perez-Jimenez,<br />
J. Rothwell, M. Touvier, L. Feuzeu,<br />
P. Galan<br />
2:25 111. Cardiovascular health effects of<br />
plant polyphenols. K. D. Croft<br />
2:50 Intermission<br />
3:05 112. Food synergy and nutritional research.<br />
D. R. Jacobs<br />
3:30 113. Berry intake ameliorates pro-inflammatory<br />
factors that increase risk of<br />
cardiovascular disease. P. E. Milbury,<br />
W. Kalt<br />
3:50 Concluding Remarks<br />
Section D<br />
Boston Convention & Exposition Center<br />
Hall C<br />
General Posters<br />
6–TECH<br />
N. Da Costa, Organizer<br />
‡ Cooperative Cosponsorship<br />
2:00–4:00<br />
114. Direct detection of microbial mRNA by<br />
rolling circle amplification. T. Kobori,<br />
H. Takahashi, A. Matsumoto,<br />
S. Sugiyama<br />
115. Post mortem changes in gene expression<br />
of fish muscle tissues. M. Saito,<br />
T. Higuchi, N. Uchida, H. Suzuki<br />
116. Tensile and solubility properties of calcium<br />
caseinate films cross-linked with<br />
genipin. P. M. Tomasula,P.Qi<br />
117. Effect of estradiol-17 � on embryos of<br />
the giant freshwater prawn, Macrobrachium<br />
rosenbergii(de Man).<br />
N. Pakdeenarong<br />
118. Determination of chitosan in aqueous<br />
solutions. S. Zivanovic, R. Davis,J.Li<br />
119. Diterpenoids from the cultured soft<br />
coral Klyxum simplex. B. Chen, Y. Lu,<br />
J. Sheu<br />
120. Synthesis and biological evaluation of<br />
novel acylphloroglucinols. C. Chang,<br />
C. Tang, J. Liu<br />
121. Antibacterial properties of Baicalin (Radix<br />
scutellariae) and Berberine (Rhizama<br />
coptidis) for Staphylococcus aureus,<br />
Escherichia coli and Bacillus atrophaeus.<br />
A. Shah,S.Cai<br />
122. Globospiramine, a new antituberculosis<br />
bisaspidospermidine indole alkaloid from<br />
Voacanga globosa. A. G. Macabeo,<br />
W. S. Vidar, M. Barbic, A. M. Aguinaldo,<br />
S. G. Franzblau, G. A. Cordell<br />
123. Studies of prenylflavonoids from the<br />
plant origin of Okinawan propolis.<br />
S. Kumazawa, N. Momose, M. Murase,<br />
T. Ohta, S. Fukumoto<br />
124. Preparation of bioactive peptides derived<br />
from wheat bran responsible for angiotensin<br />
I converting enzyme (ACE I) inhibition<br />
and nitric oxide (NO) produced<br />
acceleration and effects on hypertension.<br />
Y. Sauchi, M. Sakashita, M. Suga,<br />
M. Ochiai, T. Kon, K. Yamaguchi,<br />
Y. Ogihara<br />
125. Head space solid phase microextraction<br />
(HS-SPME) gas chromatography<br />
mass spectroscopy (GC/MS) analysis of<br />
volatile components of garlic.<br />
J. D. Williams, J. G. Clemente<br />
126. Flavor characteristics of Australian Botrytis<br />
Semillon. C. E. Hofmann,<br />
A. C. Clark, L. M. Schmitdke<br />
127. Enzymatic modification of wheat protein<br />
for the formation of pyrazines and<br />
other heterocyclic compounds through<br />
Maillard reaction. S. Lee,Y.Kim<br />
128. Determination of the levels of polycyclic<br />
aromatic hydrocarbons (PAH) in US and<br />
Swedish smokeless tobacco products.<br />
K. G. McAdam, A. Faizi, H. Kimpton,<br />
B. Rodu<br />
129. Cytotoxic terpenoids from Calocedrus<br />
macrolepis var. formosana. Y. Kuo<br />
130. Investigation on the flavor enhancing<br />
components in glutathione-Maillard reaction<br />
products using metabolomic approach.<br />
S. Lee, G. Kwon, K. Kim, Y. Kim<br />
131. Effect of hot-water extraction on noncarbohydrate<br />
components of hardwoods.<br />
M. J. Goundalkar, B. Bujanovic,<br />
T. E. Amidon<br />
132. Aroma profile comparisons of “Strawberry<br />
Festival” and “Florida Radiance”<br />
strawberries by GC-Olfactometry, odor<br />
activity values, and sensory evaluation.<br />
X. Du, A. Plotto, E. Baldwin, R. Rouseff<br />
133. Effect of short passage time on the polishing<br />
and storage temperature of milled<br />
and cooked rice quality. Y. Oh, W. Jeong,<br />
H. Jeong<br />
134. Metabolite profiling by gas chromatography-mass<br />
spectrometry (GC-MS) and<br />
principal component analysis (PCA) of<br />
Schizandra chinensis Baillon (omija fruits)<br />
according to their origins. H. Lee,I.Cho,<br />
Y. Kim<br />
135. Comparison of the volatile composition<br />
of pasteurized and unpasteurized makgeolli,<br />
a traditional Korean rice wine.<br />
H. Park,Y.Kim<br />
136. Determination and comparison of Saponins<br />
in Black Panax ginseng C.A.<br />
Mayer. S. H. Cho, O. Choi, C. Sung<br />
137. Insecticidal and antioxidant activities of<br />
abietane diterpeniods from Hyptis verticillata<br />
Jacq. R. B. Porter,D.A.Biggs,<br />
L. A. Williams<br />
138. Scopolamine-induced memory impairment<br />
in mice and antioxidant activities of<br />
aqueous antler extract. O. Choi,C.Sung,<br />
S. H. Cho<br />
139. Curcuminoids promote neuronal differentiation<br />
of PC12 cells through PKC-dependent<br />
phosphorylation of CREB protein.<br />
K. Liao, K. Lee, M. Wu, C. Ho,<br />
J. Yen<br />
140. Phytochemical composition and antifungal<br />
activity of extracts from cranberry<br />
cultivars (Vaccinium macrocarpon Ait.)<br />
that vary in resistance to plant pathogens.<br />
M. C. Nunnelley, J. L. Carpenter,<br />
C. C. Neto, F. L. Caruso<br />
141. Semi-continuous method for recovering<br />
anthocyanins and procyanidins from<br />
White Zinfandel (V. Vinifera) red grape<br />
pomace using subcritical water.<br />
J. Monrad, L. R. Howard, K. Srinivas,<br />
J. W. King, A. Mauromoustakos<br />
142. In vitro estimation of antioxidant activities<br />
in red and white cranberry extracts.<br />
A. Z. Tulio, Jr., I. Edirisinghe, C. Chang,<br />
J. E. Jablonski, R. K. Tadapaneni,<br />
B. Burton-Freeman, L. S. Jackson<br />
143. Phenolic content, antioxidant activity,<br />
and anti-proliferative property of coldpressed<br />
grape seed flours. L. A. Binzer,<br />
R. L. Brinsko, J. J. Cha, Z. Chen,<br />
S. E. Green, K. E. Grob, J. Hao,<br />
C. M. Hitz, L. J. Li, S. N. Swamy,<br />
M. Y. Wolf, M. Xu, M. C. Yanik<br />
144. <strong>Chemical</strong> composition and antioxidant<br />
properties of cold-pressed grape seed<br />
oils. L. A. Binzer, R. L. Brinsko,<br />
J. J. Cha, Z. Chen, S. E. Green,<br />
K. E. Grob, J. Hao, C. M. Hitz, L. J. Li,<br />
S. N. Swamy, M. Y. Wolf, M. Xu,<br />
M. C. Yanik<br />
145. Improved stability of blueberry juice anthocyanins<br />
by acidification and refrigeration.<br />
L. R. Howard, C. Brownmiller,<br />
R. L. Prior<br />
146. Salvia fruticosa mediates protection<br />
against H 2O 2-induced DNA damage in<br />
HEK293 cells. S. A. Bani hani<br />
147. Phytochemicals in winged sumac (Rhus<br />
copallinum) fruit. H. Ma,L.Li,<br />
N. P. Seeram<br />
148. Phytochemicals in Fraser’s Marsh St.<br />
John’s Wort (Triadenum fraseri). L. Li,<br />
D. Woolridge, J. Jennings, R. Saing,<br />
G. E. Henry, N. P. Seeram<br />
149. Phytochemicals in blueberry (Vaccinium<br />
corymbosum) stems and roots.<br />
A. Cirello, L. Li, L. R. Howard,<br />
N. P. Seeram<br />
150. Compounds from Eugenia jambolana<br />
(Jamun) berries beyond anthocyanins.<br />
R. Omar, L. Li, A. Cirello, N. P. Seeram<br />
151. Composition of flavonoids and other<br />
phenolics in foliage from cranberry cultivars<br />
(Vaccinium macrocarpon) that vary in<br />
susceptibility to cranberry tipworm and<br />
other pests. E. Yiantsidis,C.Dao,<br />
A. Averill, S. Tewari, F. Caruso, J. Hicks,<br />
K. Colson, K. B. Killday, C. Neto<br />
152. Pterocarpans and flavonoids from Derris<br />
laxiflora Benth. S. Chien<br />
153. Biocatalytically polymerized flavonoids<br />
with enhanced antioxidant activity.<br />
K. Daita, S. Tripathy, S. Nagarajan,<br />
R. Nagarajan, F. F. Bruno, L. Samuelson,<br />
J. Kumar<br />
154. Purification of homohexameric cruciferin<br />
from seeds of mutant Arabidopsis<br />
thaliana. T. Sanjeewa, D. D. Hegedus,<br />
X. Qiu, T. C. McIntosh,<br />
J. P. Wanasundara<br />
155. Methods of identification of adulterated<br />
food products based on carbohydrate<br />
profiles by UPLC. C. Hudalla, C. Boissel,<br />
P. Iraneta, D. Walsh, K. Wyndham<br />
156. Analysis of hormones and their conjugates<br />
in animal waste using QuEChERS<br />
method coupled with liquid chromatography-electrospray-tandem<br />
mass spectrometry.<br />
J. Kwon, K. L. Armbrust, K. Xia<br />
157. Photolysis of pesticides on alternate<br />
matrices compared to soil.<br />
M. C. McGuire, S. B. Hibler, L. R. Marks<br />
158. Fingerprint-based classification of a<br />
commercial odor database. A. B. Yongye,<br />
T. L. Peppard, J. L. Medina-Franco,<br />
K. Martinez-Mayorga<br />
159. Overview of sampling and analytical<br />
methodologies in the Food Safety and Inspection<br />
Service’s National Residue Program.<br />
D. Pagan-Rodriguez<br />
160. Increased air pressure substantially reduces<br />
the time required to remove raffinose-series<br />
oligosaccharides from legumes.<br />
R. Rakijian, J. L. Payne,<br />
S. Manzano, M. A. Payne<br />
161. Vitis labrusca L.: Antioxidant and antiproliferative<br />
properties of its components.<br />
M. Gallicchio, G. D’Angelo, S. Pacifico,<br />
A. Fiorentino, B. D’Abrosca, P. Monaco<br />
162. What can we learn from massive docking?<br />
K. T. Nguyen,M.M.Mysinger,<br />
B. K. Shoichet, J. J. Irwin<br />
163. Lanostane triterpenoids and a degraded<br />
steroid from Antrodia camphorata.<br />
H. Huang,Y.Kuo<br />
164. New mechanism for the generation of<br />
acyl radical in cigarette smoke. N. Hu,<br />
S. A. Green<br />
165. Determination the impact odorants of<br />
‘Hutai’ icewine from Hu county (China)<br />
using headspace solid-phase microextraction.<br />
H. Wang, L. Zhang, Y. Liang<br />
166. Detecting and predicting adulteration in<br />
Chinese garlic oil by gas chromatography<br />
analysis and chemometrics. D. Bolliet<br />
167. Withdrawn<br />
168. Constituents of maple syrup residue, a<br />
waste/by-product of the maple syrup industry.<br />
O. Ashorobi, L. Li, D. Worthen,<br />
N. Seeram<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Flavor Chemistry of Alcoholic Beverages<br />
T. Shellhammer, Organizer<br />
M. Qian, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 169. 1,1,6-Trimethyldihydronaphthalene:<br />
Effects of cluster light exposure timing<br />
and contribution to Riesling aroma.<br />
G. L. Sacks,T.E.Acree,<br />
J. E. Vanden Heuvel, M. T. Kwasniewski,<br />
L. Karoui<br />
8:30 170. Headspace solid-phase dynamic<br />
extraction (SPDE) and GC-MS for distinguishing<br />
a) styles of South African Chenin<br />
Blanc wines and b) types of pot-distilled<br />
brandies from regions around the world.<br />
V. A. Watts, I. Christ, J. Stadler,<br />
Z. Bellingan<br />
8:55 171. A little twist for wine aroma.<br />
M. C. Qian<br />
9:20 Intermission<br />
9:40 172. Fermentation and post-fermentation<br />
factors affecting accumulation and<br />
degradation of odour-active sulfur compounds<br />
during wine bottle storage.<br />
M. Ugliano, M. Kwiatkowski,<br />
P. A. Henshcke, E. J. Waters<br />
10:05 173. Impact of the oxgen exposure<br />
during bottling and oxygen barrier properties<br />
of different closures on wine quality<br />
during post-bottling. P. Lopes,<br />
M. A. Silva, M. Cabral, P. Darriet,<br />
P. Teissedre, D. Dubourdieu<br />
10:30 174. Assessing smoke taint in grapes<br />
and wine. K. L. Wilkinson, R. Ristic,<br />
K. Dungey, Y. Hayasaka<br />
10:55 175. Smoke taint aroma assessment<br />
in 2008 California grape harvest.<br />
H. Chong<br />
11:20 Concluding Remarks<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
Section C<br />
Boston Convention & Exhibition Center<br />
Room 159<br />
Antioxidant Analysis: Challenges and<br />
Critical Issues<br />
J. Finley, Organizer<br />
L. Howard, D. Luthria, Organizers,<br />
Presiding<br />
8:00 Introductory Remarks<br />
8:05 176. Significance of extraction and<br />
spectral fingerprinting methodology for<br />
the assay of bioactive phytochemicals.<br />
D. Luthria, J. Harnly<br />
8:30 177. Stability for extraction and analysis<br />
of acylated anthocyanins.<br />
H. Matsufuji<br />
8:55 178. Determination of extractable and<br />
nonextractable food polyphenols.<br />
L. R. Howard, B. L. White<br />
9:20 179. Revising and redirecting the<br />
chemistry of antioxidant (antiradical) activity<br />
assays. K. M. Schaich<br />
9:45 Intermission<br />
10:00 180. Luminescent molecular and nano<br />
probes for quantifying reactive oxygen<br />
species and the scavenging activity of dietary<br />
antioxidants. D. Huang<br />
10:25 181. Dietary modulation of oxidative<br />
stress in humans: Methodology, physiologycal<br />
meaning and value of the non<br />
enzymatic antioxidant capacity (NEAC).<br />
M. Serafini<br />
10:50 182. Assays for scavenging capacities<br />
against hydroxyl and DPPH radicals.<br />
L. Yu<br />
11:15 183. Challenges and issues with the<br />
ORAC assay. R. L. Prior<br />
11:40 184. Main and modified CUPRAC<br />
methods of antioxidant characterization.<br />
R. Apak,M.Özyürek, B. Bektas¸ogˇlu,<br />
K. Güçlü<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
Agricultural and Food Derived Natural<br />
Products for Preventing and Combating<br />
Disease Human Intervention Studies<br />
B. Patil, G. Jayaprakasha, N. P. Seeram,<br />
Organizers<br />
K. Chidambara Murthy, Organizer,<br />
Presiding<br />
C. Neto, J. Novotny, Presiding<br />
8:30 Introductory Remarks<br />
8:35 185. Cranberry phytochemicals: Potential<br />
benefits against disease and infection.<br />
C. C. Neto<br />
9:00 186. Queen Garnet plum, a new plum<br />
variety rich in antioxidant compounds:<br />
First results from a pilot study with<br />
healthy human subjects. M. Netzel,<br />
K. Fanning, G. Netzel, D. Zabaras,<br />
D. Russell, R. Stanley<br />
9:25 187. Anthocyanins: Disease preventing<br />
pigments with complex bioavailabilities.<br />
J. A. Novotny<br />
9:50 188. Food polyphenol consumption<br />
may reduce prevalence of hypertension in<br />
high cardiovascular risk population.<br />
R. M. Lamuela-Raventos,<br />
A. Medina-Remón, R. Estruch,<br />
C. Andres-Lacueva<br />
10:15 Intermission<br />
10:30 189. Oral consumption of cranberry<br />
juice inhibits cellular adhesion and biofilm<br />
formation of uropathogenic bacteria.<br />
Y. Tao, P. A. Pinzon, A. B. Howell,<br />
T. A. Camesano<br />
10:55 190. Effects of oral sea buckthorn<br />
(Hippophaë rhamnoides) oil on dry eye.<br />
P. S. Larmo,R.L.Järvinen, N. L. Setälä,<br />
B. Yang, M. H. Viitanen, J. R. Engblom,<br />
R. L. Tahvonen, H. P. Kallio<br />
11:20 191. Thylakoids promote satiety in<br />
healthy humans: Metabolic effects and<br />
mechanisms. C. Erlanson-Albertsson,<br />
P. Albertsson, R. Köhnke, M. Rayner,<br />
S. Emek, M. Landin-Olsson,, B. Weström,<br />
C. Montelius, K. Gustafsson,<br />
L. Svensson, I. Sjöholm<br />
11:45 Concluding Remarks<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Flavor Chemistry of Alcoholic Beverages<br />
T. Shellhammer, Organizer<br />
M. Qian, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 192. Evidence for demethylation of<br />
3-isobutyl-2-methoxypyrazine during<br />
maturation of bell pepper (Capsicum annum)<br />
and winegrapes (Vitis vinifera).<br />
I. Ryona, G. Sacks<br />
2:00 193. Free and potential aroma compounds<br />
and sensory profile in long-time<br />
grape skin macerated white wines.<br />
G. Versini, B. Fedrizzi, R. Ferrarini,<br />
F. Finato, E. Casarotti, G. Piubelli,<br />
M. Cipriani<br />
2:25 194. Assessing variability in the coopering<br />
process. T. S. Collins, S. E. Ebeler<br />
2:50 Intermission<br />
3:10 195. Bitter, twisted truth of the hop.<br />
P. L. Ting,D.Ryder<br />
3:35 196. On the flavor of Bourbon Whiskey:<br />
How the manufacturing process influences<br />
the concentrations of its key aroma<br />
molecules. P. H. Schieberle, M. Vocke<br />
4:00 197. Aroma characterization of Chinese<br />
liquor: Yanghe Daqu, Wuliangye, Jiannanchun<br />
and Maotai. M. C. Qian, W. Fan,<br />
Y. Xu<br />
4:25 198. Characteristic aroma compounds<br />
of Chinese rice wine by gas chromatography–olfactometry<br />
and quantitative<br />
analysis using headspace solid phase microextraction<br />
gas chromatography–mass<br />
spectrometry. W. Fan, Y. Xu<br />
4:50 Concluding Remarks<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
General Papers<br />
A. Mitchell, Organizer, Presiding<br />
N. Da Costa, Presiding<br />
1:30 Introductory Remarks<br />
1:35 199. Seed’s protein and oil content,<br />
fatty acid composition, and growing cycle<br />
length of a single genotype of chia (Salvia<br />
hispanica L.) as affected by environmental<br />
factors. R. Ayerza<br />
1:55 200. Extra virgin olive oil increases uncoupling<br />
protein 1 content in brown adipose<br />
tissue, and enhances noradrenaline<br />
and adrenaline secretions in rats.<br />
Y. Oi-Kano<br />
2:15 201. Inhibition of human NADPH oxidase<br />
by apocynin derived oligophenols.<br />
J. M. Mora Pale, S. Kwon, M. Weiwer,<br />
R. J. Linhardt, J. S. Dordick<br />
2:35 202. Antileishmanial, trypanocidal, antituberculosis<br />
and cytotoxic activities of<br />
targeted plant species from the Peruvian<br />
rain forest. Z. Jin, J. C. Aponte, V. A.,<br />
M. Sauvain, R. Gilman, G. Hammond<br />
2:55 Intermission<br />
3:10 203. Phytochemical analysis and antioxidant<br />
efficacy of fruits produced in Italy.<br />
N. Tsafantakis, S. Pacifico,<br />
M. Scognamiglio, S. Piccolella,<br />
B. D’Abrosca, A. Fiorentino<br />
3:30 204. Transcriptional control of alkaloid<br />
biosynthesis by methyl jasmonate in Catharanthus<br />
roseus hairy root cultures.<br />
S. Goklany, R. H. Loring, J. Glick,<br />
C. W. Lee-Parsons<br />
3:50 205. Molecular cloning and characterization<br />
of a novel down-regulated TOM20<br />
gene associated with the onset of tapping<br />
panel dryness (TPD) syndrome from the<br />
inner bark tissues of rubber tree (Hevea<br />
brasiliensis Muell. Arg.) by mRNA differential<br />
display. V. Perumal<br />
4:10 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 159<br />
New Perspectives on Antioxidants<br />
J. Finley, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 206. Relating in vitro research on the<br />
antioxidant impact of crucifer components<br />
to dietary redox regulation.<br />
E. Jeffery<br />
2:05 207. Too much of a good thing: Risk of<br />
over-antioxidation. X. Lei<br />
2:35 208. Regulation of the iron storage protein<br />
ferritin by the antioxidant responsive<br />
element. K. J. Hintze<br />
3:05 Intermission<br />
3:20 209. Antioxidant adaptation and signaling<br />
in response to physical exercise. L. Ji<br />
3:50 210. Dietary antioxidants: From activating<br />
Nrf2 signaling to genomics in prevention<br />
of cancer. A. Kong<br />
4:20 Concluding Remarks<br />
THURSDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Small Wonders: Peptides for Disease<br />
Control Cosponsored by BIOT<br />
K. Rajasekaran, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 211. Application of small molecule microarrays<br />
in high-throughput screening of<br />
protein targets. M. Uttamchandani<br />
9:05 212. Plant antimicrobial peptides: Thionins<br />
as nature’s invention for weapons<br />
of mass protection. S. Oard,<br />
T. Chouljenko, N. Maiti, F. Enright<br />
9:35 Intermission<br />
9:50 213. Results of a double blind randomized,<br />
multi-center phase-II clinical trial of<br />
genopep, a topical cream in the treatment<br />
of burn wounds. J. M. Jaynes,<br />
V. Reddy, P. Ramesh<br />
10:20 214. Effect of transgenic cotton plants<br />
transformed with antimicrobial synthetic<br />
peptide D4E1 on cotton seedling disease,<br />
soil microbial diversity, and enzymatic activity.<br />
L. J. Odom, R. O. Ankumah,<br />
J. Jaynes, C. Bonsi, J. W. Cary, M. Egnin,<br />
D. Mortley, L. Ogden, K. Rajasekaran<br />
10:50 215. Transformation of antimicrobial<br />
peptides from frog skin into therapeutically<br />
valuable anti-infective agents.<br />
J. Conlon<br />
11:20 Concluding Remarks<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
Caffeine and Other Natural Product<br />
Stimulants<br />
E. Demejia, Organizer<br />
J. Weil, Presiding<br />
8:30 Introductory Remarks<br />
8:40 216. Caffeine: Health benefits and<br />
safety concerns. E. Gonzalez de Mejia<br />
9:00 217. On the circumstances which modify<br />
the action of caffeine: The scope of<br />
science since Runge’s discovery until<br />
nowadays. J. G. Weil<br />
9:20 218. Energy drinks: An assessment of<br />
their ingredient profile and functionality.<br />
M. Heckman, E. Gonzalez de Mejia<br />
9:40 219. Rapid determination of pungent<br />
compounds of ginger by a combination of<br />
chromatography and vanilloid receptor<br />
(VR1) assay. Y. Yang, S. Liu, N. Mannava<br />
10:00 220. Natural components in yerba<br />
mate tea and coffee byproducts enhance<br />
antioxidant capacity, inhibit lipid synthesis,<br />
and suppress body fat and lipogenic<br />
genes. E. Gonzalez de Mejia,<br />
M. Heckman<br />
10:20 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 159<br />
Antioxidants and Health<br />
J. Finley, Organizer<br />
8:30 Introductory Remarks<br />
8:35 221. Antioxidants in black rice bran.<br />
Z. Xu, S. Jang, X. Yue<br />
9:05 222. Soybean antioxidant properties<br />
affected by food processing and in vitro<br />
digestion. K. Zhou<br />
9:35 223. Health effects of natural antioxidants<br />
from the selected edible botanical<br />
materials. L. Yu<br />
10:05 Intermission<br />
10:20 224. Catechin/Epicatechin metabolism<br />
and excretion in rats fed different<br />
berries. R. Khanal, S. E. Wilkes,<br />
T. J. Rogers, L. R. Howard, R. L. Prior<br />
10:50 225. Antioxidant activity of lutein and<br />
its protective effects on ischemia-hypoxia<br />
injury in cultured rat cortical neurons.<br />
M. Wang, R. Tsao<br />
11:20 226. Influence of extraction methodology<br />
on the assay of antioxidant phenolic<br />
compounds. D. Luthria<br />
11:50 Concluding Remarks<br />
THURSDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160A<br />
Small Wonders: Peptides for Disease<br />
Control Cosponsored by BIOT<br />
K. Rajasekaran, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 227. NMR structural insights on the<br />
function of antimicrobial peptides.<br />
A. Ramamoorthy<br />
2:05 228. Synthetic antimicrobial peptides<br />
as novel pesticides for plant disease control.<br />
E. Montesinos<br />
2:35 229. Antimicrobial and immunomodulatory<br />
peptides for combating infections.<br />
R. E. Hancock<br />
3:05 Intermission<br />
3:20 230. Transgenic expression of lytic<br />
peptides for elimination of mycotoxins in<br />
food and feed crops. K. Rajasekaran,<br />
J. W. Cary, J. M. Jaynes, D. Bhatnagar,<br />
T. E. Cleveland<br />
3:50 231. In vitro effects of two newly designed<br />
lytic peptides LHRH conjugates<br />
on prostate cancer. S. M. Sharp<br />
4:20 Concluding Remarks<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
AGFD<br />
TECH–7
AGFD/ANYL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 161<br />
General Papers<br />
A. Mitchell, Organizer<br />
N. Da Costa, Presiding<br />
1:30 Introductory Remarks<br />
1:35 232. Activation energy measurements<br />
of cheese. M. H. Tunick<br />
2:00 233. Impact of electrostatic deposition<br />
of anionic biopolymers on the stability of<br />
lactoferrin-coated oil droplets. T. Tokle,<br />
U. Lesmes, J. McClements<br />
2:25 234. Comparison of molecular and aggregation<br />
properties of soy proteins<br />
treated with various endopeptidases.<br />
M. J. Cho, D. Ryan, P. Ghosh<br />
2:50 Intermission<br />
3:05 235. Development of a sodium-free salt<br />
for food applications. D. L. Holliday,<br />
A. Prudente, J. W. Finley<br />
3:30 236. Foliage extracts of conifers as potential<br />
sources for isolation of shikimic<br />
and quinic acids, precursors to Tamiflu ® .<br />
L. Gedivinne Vithanage,B.J.Cole,<br />
R. C. Fort Jr., J. M. Genco, A. Shaffer,<br />
M. Rowe<br />
3:55 237. Efficacy of Ichthyophthirius vaccines<br />
in channel catfish against white<br />
spot disease. D. Xu, P. Klesius,<br />
C. Shoemaker<br />
4:20 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 159<br />
Antioxidants and Health<br />
J. Finley, Organizer<br />
1:30 Introductory Remarks<br />
1:35 238. Pterostilbene reduces colon tumor<br />
multiplicity and inflammatory markers in<br />
animal models of colon cancer.<br />
A. M. Rimando, S. Paul, N. Suh<br />
2:05 239. Multifunctional branched gold<br />
nanoparticle for prevention of cancer<br />
cells. P. C. Ray<br />
2:35 240. Chitosan grafted with phenolics to<br />
promote antioxidant activities.<br />
S. B. Schreiber, S. Zivanovic<br />
3:05 Intermission<br />
3:20 241. Bioassay-guided isolation and<br />
EPR-assisted antioxidant evaluation of<br />
two valuable compounds from mango<br />
peels. L. Jiang,S.He,Y.Pan<br />
3:50 242. Urinary excretion of phenolic acids<br />
in rats fed cranberry, blueberry, or<br />
black raspberry. R. Khanal, S. E. Wilkes,<br />
T. J. Rogers, L. R. Howard, R. L. Prior<br />
4:20 Concluding Remarks<br />
ANYL<br />
Division of Analytical<br />
Chemistry<br />
S. Lunte, Program Chair<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
Pharmaceutical Analysis Financially<br />
supported by Subdivision of Chromatography<br />
and Separations Chemistry<br />
8–TECH<br />
S. Lunte, Organizer, Presiding<br />
‡ Cooperative Cosponsorship<br />
8:15 1. Quantitative analysis of API crystallization<br />
by second harmonic generation<br />
microscopy. D. Wanapun, U. S. Kestur,<br />
L. S. Taylor, G. J. Simpson<br />
8:35 2. GPC-IR to characterize macromolecular<br />
excipients in pharmaceutical formulations.<br />
M. Zhou, W. Carson,<br />
S. Bourne, T. Kearney<br />
8:55 3. New fast online-SPE-LC-ESI-<br />
MS/MS approach for pharmacokinetic<br />
studies. N. H. Schebb, B. Inceoglu,<br />
B. D. Hammock<br />
9:15 4. Paracetamol crystal facets revisited:<br />
What does X-ray Photoelectron Spectroscopy<br />
(XPS) really reveal?<br />
S. L. Schroeder, H. M. Zaki,<br />
J. S. Stevens<br />
9:35 5. Characterization of polymeric excipients<br />
in drug formulations using advanced<br />
detection size-exclusion chromatography.<br />
J. Sanchez<br />
9:55 6. Electrospray ionization: Ion mobility<br />
spectrometer (ESI-IMS) for cleaning validation<br />
(CV) in pharmaceutical manufacturing.<br />
A. J. Midey, C. A. Krueger, C. Wu<br />
10:15 Intermission<br />
10:25 7. SPR sensing of drug molecules using<br />
a smart polymer film. R. B. Pernites,<br />
R. Ponnapati, M. Felipe, R. Advincula<br />
10:45 8. Protease analysis and the search<br />
for “protease-free” blocking proteins.<br />
J. Fishpaugh, K. Rupprecht<br />
11:05 9. Evaluation of the hemocompatibility<br />
of implantable device surfaces.<br />
S. A. Nielsen, K. M. Balss,<br />
C. A. Maryanoff<br />
11:25 10. Fabrication of uniform DNA-conjugated<br />
hydrogel microparticles via particle<br />
replication in nonwetting templates<br />
(PRINT) for facile nucleic acid hybridization<br />
assays. C. L. Lewis, C. Choi, Y. Lin,<br />
C. Lee, H. Yi<br />
11:45 11. High-throughput natural products<br />
chemistry: Is it possible?<br />
M. O’Neil-Johnson, G. Eldridge,<br />
J. Norcross, C. Milling, T. Peck<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
New Frontiers in Single Molecule Detection<br />
and Single Cell Analysis Cosponsored by<br />
BIOL ‡ and PHYS ‡<br />
X. Xu, Organizer, Presiding<br />
8:30 12. Single molecule imaging of biomolecules<br />
in nanopores. E. S. Yeung,C.Ma<br />
9:05 13. Single molecule studies of the synaptic<br />
vesicle. D. T. Chiu<br />
9:40 14. Molecules and methods for superresolution<br />
imaging in living cells.<br />
W. Moerner<br />
10:15 Intermission<br />
10:25 15. Wide-field LSPR imaging: Single<br />
nanoparticle spectroscopy, diffusional<br />
dynamics, and structural characterization.<br />
R. P. Van Duyne, J. M. Bingham,<br />
A. Henry, E. Ringe<br />
11:00 16. Design of photostable single molecule<br />
nanoparticle biosensors for real<br />
time probing single living cells. X. Xu,<br />
T. Huang, L. Browning, P. Nallathamby<br />
11:35 17. Life at the single molecule level.<br />
S. Xie<br />
Sustaining Water Quality<br />
Status and Trends Sponsored by ENVR,<br />
Cosponsored by ANYL<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
Spectroscopic Methods of Analysis<br />
S. Lunte, Organizer<br />
J. Anker, Organizer, Presiding<br />
1:30 18. Gold-coated aluminum oxide membranes<br />
(Au–AOM) as substrates for a new<br />
flow-through immunoassay with SERS<br />
readout. L. M. Siperko<br />
1:50 19. In situ polarized Raman spectroscopy<br />
and atomic force microscopy study<br />
of point defects, growth direction and<br />
mechanical properties in individual ZnO<br />
nanobelts. M. Lucas, Z. Wang, E. Riedo<br />
2:10 20. Selective detection from multianalyte<br />
mixtures using surface-enhanced Raman<br />
scattering. P. Pinkhasova,<br />
S. A. Sukhishvili, H. Du<br />
2:30 21. Effect of oxidation of silver on<br />
SERS enhancement. Y. Han,<br />
R. Lupitskyy, H. Du, S. Sukhishvili<br />
2:50 22. Time-resolved ATR spectroscopy<br />
on a planar waveguide for kinetic studies<br />
of supramolecular thin films.<br />
A. M. Simon, N. Marucci, S. S. Saavedra<br />
3:10 23. Large field of view LSPR imaging:<br />
Demonstrations of multiplexed, ensemble<br />
measurements. J. A. Ruemmele,<br />
P. W. Hall, R. P. Van Duyne<br />
3:30 Intermission<br />
3:40 24. Magnetically modulated fluorescent<br />
probes for detection in turbid media.<br />
Z. Yang, K. Nguyen, J. N. Anker<br />
4:00 25. Nanoscale infrared spectroscopic<br />
analysis of ABS-polycarbonate plastic<br />
blends. M. Lo, J. Ye, K. Kjoller, C. Prater<br />
4:20 26. Confocal Raman microscopy of<br />
transportan in live melanoma cells. J. Ye,<br />
A. C. Terentis<br />
4:40 27. In-situ electron energy-loss spectroscopy<br />
study of Co-based Fischer-<br />
Tropsch catalysts. Y. Zhao, T. Feltes,<br />
J. Regalbuto, R. Meyer, R. Klie<br />
5:00 28. Novel selective mercury sensors<br />
based on 7-nitrobenzo-2-oxa-1,3- diazolyl<br />
subunit(s): Efficient and simple colorimetric<br />
and fluorometric chemosensors.<br />
N. Wanichacheva,<br />
M. Siriprumpoonthum, A. Kamkaew,<br />
R. Sangsuwan, R. Teerasarun-yanon,<br />
K. Grudpan<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
New Frontiers in Single Molecule Detection<br />
and Single Cell Analysis Cosponsored by<br />
BIOL ‡ and PHYS ‡<br />
X. Xu, Organizer, Presiding<br />
1:30 29. Revealing bunching effects in single-molecule<br />
enzymatic conformational<br />
dynamics. H. Lu<br />
2:05 30. Droplet tracking for single molecule<br />
analysis. L. S. Goldner<br />
2:40 31. Single molecule studies of electronic<br />
energy transfer in semiconductor<br />
quantum dot clusters: Applications in solar<br />
energy and biological imaging.<br />
A. Van Orden, D. P. Shepherd,<br />
K. J. Whitcomb, P. M. Goodwin,<br />
M. P. Gelfand<br />
3:15 Intermission<br />
3:25 32. Single-molecule studies of protein -<br />
nucleic acid interactions in systems involved<br />
in gene-expression. X. Zhuang<br />
4:00 33. Optical microwell arrays for capturing<br />
and analyzing single cells. D. R. Walt,<br />
A. Phillips, R. Dragoey Whitaker<br />
4:35 34. Detection of single-molecule H2O2 signalling from epidermal growth factor<br />
receptor using fluorescent single-walled<br />
carbon nanotubes. J. Zhang<br />
Sustaining Water Quality<br />
Monitoring Various Contaminants<br />
Sponsored by ENVR, Cosponsored by ANYL<br />
MONDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
Innovations in Chromatography Financially<br />
supported by Subdivision of Chromatography<br />
and Separations Chemistry<br />
G. Roman, Organizer, Presiding<br />
8:00 35. Analytical column characterization<br />
for differential magnetic catch and release<br />
separation of magnetic nanoparticles.<br />
J. S. Beveridge, M. E. Williams<br />
8:20 36. Enhancing the sensitivity and specificity<br />
of HPLC analysis through post-column<br />
chemical and photochemical derivatization.<br />
H. Joshua<br />
8:40 37. Development of an ion-pairing reversed-phase<br />
liquid chromatography tandem<br />
mass spectrometry method for underivatized<br />
amino acid analyses of<br />
pediatric plasma and urine specimens.<br />
A. S. Ptolemy, Y. Li, S. Hossain,<br />
P. Karlsson, A. Shkreta, M. Kellogg<br />
9:00 38. New research in hybrid organic/inorganic<br />
chromatographic packing materials.<br />
K. D. Wyndham, P. C. Iraneta,<br />
D. P. Walsh, J. T. Cook, K. H. Glose,<br />
B. A. Alden, C. A. Boissel, J. E. Turner,<br />
C. Hudalla, S. McCall, T. H. Walter<br />
9:20 39. Separations of biomolecules by<br />
UPLC-SEC. E. S. Bouvier, S. Serpa,<br />
N. Brady, K. Wyndham, N. Lawrence,<br />
P. Hong, U. Neue, T. Walter<br />
9:40 40. Ultrafast separation of low molecular<br />
weight analytes on polymeric capillary<br />
columns. M. R. Buchmeiser, S. Lubbad<br />
10:00 Intermission<br />
10:15 41. Crown ethers as class I modifiers<br />
in micellar electrokinetic chromatography.<br />
R. Burks, D. Hage<br />
10:35 42. Characterization of solvatochromic<br />
shifts of dyes for use in micellar studies<br />
via linear solvation energy relationships<br />
(LSERs). M. F. Vitha,<br />
R. T. Johnson, R. M. Barkley,<br />
S. Nkrumah-Agyeefi, H. R. O’Brien,<br />
H. M. Liedl, C. E. Hurley, A. Marquez,<br />
C. Chavez, Z. Sarmiento<br />
10:55 43. Drainage experiments in micromodels<br />
of porous media: Influence of the<br />
wetting properties. C. Cottin,<br />
H. Bodiguel, A. Colin<br />
11:15 44. Duplicating the retention of cationic<br />
analytes obtained with ammonium<br />
formate mobile phases when switching to<br />
UV transparent mobile phase additives in<br />
RP-LC. E. Loeser, S. Babiak<br />
11:35 45. Analysis of inorganic As(III) in water<br />
at the low �gL -1 range by a colorimetric-solid<br />
phase extraction (C-SPE)<br />
method. L. M. Siperko, M. M. Bradley,<br />
M. D. Porter<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
ACS Award in Analytical Chemistry:<br />
Symposium in Honor of Richard Van Duyne<br />
K. Willets, Organizer, Presiding<br />
8:25 Introductory Remarks<br />
8:30 46. Award Address (ACS Award in<br />
Analytical Chemistry Sponsored by<br />
Battelle Memorial Institute). Single molecule<br />
and single particle SERS.<br />
R. P. Van Duyne<br />
9:15 47. Fabrication of plasmon-coupled<br />
gratings with nanowires, nanolines and<br />
nanoparticles for bioaffinity sensing.<br />
R. M. Corn, A. R. Halpern, D. Kim,<br />
Y. Chen<br />
9:45 48. Many-electron transfers of nanoparticles<br />
at electrodes. R. W. Murray<br />
10:15 Intermission<br />
10:30 49. Theories of the SERS effect: Top<br />
down meets bottom up. G. C. Schatz<br />
11:00 50. Sub-diffraction limited imaging of<br />
plasmonic hot spots. K. A. Willets,<br />
I. Kaplan-Ashiri, K. Koen, E. Titus,<br />
A. Campos<br />
11:30 51. Plasmonic and confinement effects<br />
of hollow plasmonic nanoparticles.<br />
M. El-Sayed<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
Sustaining Water Quality<br />
Remediation of Various Contaminants<br />
Sponsored by ENVR, Cosponsored by ANYL<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
Analytical Awards Symposium Financially<br />
supported by Subdivision of Chromatography<br />
and Separations Chemistry<br />
D. Phillips, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:45 52. High-performance microfluidic<br />
chemical and biochemical analysis systems.<br />
R. A. Mathies<br />
2:25 53. <strong>Chemical</strong> applications of synchrotron<br />
radiation spectroscopy.<br />
S. P. Cramer<br />
3:05 54. Electrochemistry and nano science.<br />
C. R. Martin<br />
3:45 Intermission<br />
4:00 55. Service and nanoparticles.<br />
R. W. Murray<br />
4:40 56. What do you say when they ask<br />
“should I go into college teaching”?<br />
L. W. Potts<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
Biomedical Applications of Mass<br />
Spectrometry<br />
S. Lunte, Organizer<br />
M. E. McComb, Organizer, Presiding<br />
1:30 57. Measuring in vivo glycation of a human<br />
IgG2 by mass spectrometry.<br />
Y. D. Liu, A. Goetze, G. C. Flynn<br />
1:50 58. Study of highly selective thiol derivatization<br />
using selenium reagents by<br />
mass spectrometry. K. Xu, Y. Zhang,<br />
B. Tang, J. Laskin, P. J. Roach, H. Chen<br />
2:10 59. Develop new mass spectrometry<br />
method to determine protein phosphorylation<br />
stoichiometry in large scale. R. Wu,<br />
N. Dephoure, w. Haas, S. Gygi<br />
2:30 60. Analysis of 1-deoxy-sphinginolipids<br />
using liquid chromatography coupled to<br />
electrospray ionization tandem mass<br />
spectrometry. H. Park, M. C. Sullards,<br />
A. H. Merrill, C. E. Costello<br />
2:50 61. Characterization of terpyridinebased<br />
metallomacrocycles using ion mobility<br />
mass spectrometry. X. Li,Y.Chan,<br />
G. Newkome, C. Wesdemiotis<br />
3:10 Intermission<br />
3:25 62. Potential clinical applications of<br />
top-down mass spectrometry: Transthyretin.<br />
R. Theberge, M. E. McComb,<br />
N. Leymarie, C. Lin, C. E. Costello<br />
3:45 63. Focused ion beam fabrication of<br />
solidified ferritin into nanoscale volumes<br />
for compositional analysis using time-offlight<br />
mass spectrometry methods.<br />
M. E. Greene, T. F. Kelly, D. J. Larson,<br />
T. J. Prosa<br />
4:05 64. Biomarkers and cardiovascular disease:<br />
Label-free MS and PTM characterization.<br />
M. E. McComb, D. H. Perlman,<br />
D. A. Siwik, V. N. Bhatia, R. A. Cohen,<br />
W. Colucci, C. A. Costello<br />
4:25 65. Method development for investigation<br />
of polar lipids in biological samples<br />
by reversed phase liquid chromatography<br />
coupled to mass spectrometry. Y. Zhou,<br />
J. Ollesch, H. Wille, D. S. Newburg,<br />
C. E. Costello<br />
4:45 66. Solid-phase thermodynamic interpretation<br />
of ion desorption in matrix-assisted<br />
laser desorption/ionization.<br />
Y. H. Lai, C. C. Wang, S. H. Lin,<br />
Y. S. Wang, Y. T. Lee<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
Undergraduate Research Posters<br />
Analytical Chemistry Sponsored by CHED,<br />
Cosponsored by ANYL and SOCED<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
S. Lunte, Organizer<br />
8:00–10:00<br />
219, 220, 221, 222, 223, 224, 225, 226, 227,<br />
228, 229, 230, 231, 232, 233, 234, 235,<br />
236, 237, 238, 239, 240, 241, 242, 243,<br />
244. See subsequent listings.<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
Frank H. Field and Joe L. Franklin Award for<br />
Outstanding Achievement in Mass<br />
Spectrometry: Symposium in Honor of<br />
Catherine Costello Cosponsored by WCC ‡<br />
S. Lunte, Organizer<br />
J. Zaia, Presiding<br />
8:25 Introductory Remarks<br />
8:35 67. Award Address (Frank H. Field<br />
and Joe L. Franklin Award for Outstanding<br />
Achievement in Mass Spectrometry<br />
Sponsored by Waters Corporation). Mass<br />
spectrometry: From fundamentals to the<br />
clinic. C. E. Costello<br />
9:10 68. History of MALDI mass spectrometry:<br />
The Muenster-Boston connection.<br />
F. Hillenkamp<br />
9:45 69. Isotopes, isobars, and isomers:<br />
Problems and opportunities for mass<br />
analysis of biomolecules. A. G. Marshall,<br />
M. R. Emmett, C. L. Hendrickson,<br />
G. T. Blakney<br />
10:20 Intermission<br />
10:30 70. Middle-down peptide analysis using<br />
an LTQ Orbitrap and ProSightPC 2.0.<br />
C. Fenselau<br />
11:05 71. Investigations into glycosaminoglycan<br />
detection and isomeric differentiation<br />
in human serum. J. A. Leary,<br />
W. W. Wei<br />
11:40 72. Environmental forensics using<br />
mass spectrometry. R. A. Hites<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
ACS Award in Chromatography:<br />
Symposium in Honor of Udo Brinkman<br />
Art of Separation: Hyphenation and<br />
Application Financially supported by<br />
Subdivision of Chromatography and<br />
Separations Chemistry<br />
G. De Jong, Organizer, Presiding<br />
8:25 Introductory Remarks<br />
8:30 73. Microchip electrophoresis as a tool<br />
for in vivo and in vitro monitoring of biological<br />
events. S. M. Lunte<br />
9:10 74. Hyphenation: All tied up beautifully.<br />
P. Schoenmakers<br />
9:50 75. Considerations on off- and on-line<br />
comprehensive fluid chromatography.<br />
P. Sandra<br />
10:30 Intermission<br />
10:50 76. Capillary electrophoresis – mass<br />
spectrometry: Art of separation and hyphenation.<br />
G. J. de Jong<br />
11:30 77. Award Address (ACS Award in<br />
Chromatography Sponsored by<br />
SUPELCO, Inc.). Art of separation: Comprehensive<br />
2D gas chromatography.<br />
U. A. Brinkman<br />
Oligonucleotide Therapeutics Sponsored by<br />
CARB, Cosponsored by ANYL, BIOL, MEDI,<br />
and ORGN<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
Frank H. Field and Joe L. Franklin Award for<br />
Outstanding Achievement in Mass<br />
Spectrometry: Symposium in Honor of<br />
Catherine Costello Cosponsored by WCC<br />
S. Lunte, Organizer<br />
J. Zaia, Presiding<br />
1:30 78. Advances in laser desorption timeof-flight<br />
mass spectrometry for biological<br />
applications. M. L. Vestal<br />
2:05 79. Ambient electrospray-assisted laser<br />
desorption Ionization (ELDI) for mass<br />
spectrometry characterization of proteins<br />
and glycoproteins. I. X. Peng,<br />
M. W. Little, R. R. Ogorzalek Loo,<br />
E. Margalith, J. A. Loo<br />
2:40 80. Monitoring DNA damage at the<br />
trace level by LC-MS: Challenges and implications.<br />
P. Vouros, J. Glick, H. Zarbl,<br />
Y. Zhang<br />
3:15 Intermission<br />
3:25 81. Advances in lipid mass spectrometric<br />
analysis: Biochemical pathways of<br />
arachidonic acid remodeling.<br />
R. C. Murphy<br />
4:00 82. Identification and new site assignments<br />
for protein O-GlcNAc by electron<br />
transfer dissociation (ETD) mass spectrometry.<br />
A. Burlingame, A. Ioanoviciu,<br />
A. Thalhammer, R. Schoepfer<br />
4:35 83. Progress toward a biomarker discovery-to-development<br />
pipeline in clinical<br />
proteomics. S. A. Carr<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
Microfluidics and Lab on a Chip Clinical and<br />
Diagnostic Applications of Labs on a Chip<br />
Methodologies Financially supported by<br />
Subdivision of Chromatography and<br />
Separations Chemistry<br />
G. Roman, Organizer, Presiding<br />
1:30 84. Resources and funding opportunities<br />
from the National Cancer Institute to<br />
support the development of your innovative<br />
analytical technology. M. D. Lim,<br />
C. C. Compton<br />
1:50 85. Development of fiber based microfluidic<br />
devices. F. Vatansever,<br />
R. Burtovyy, B. Zdyrko, T. Andrukh,<br />
S. Minko, K. G. Kornev, I. Luzinov<br />
2:10 86. Multidimensional analysis of the<br />
frequencies, dynamics, and rates of cytokine<br />
secretion from single cells by quantitative<br />
microengraving. Q. Han,<br />
E. Bradshaw, B. Nilsson, D. Hafler,<br />
J. Love<br />
2:30 87. Fluidic “Timers” for paper-based<br />
microfluidic devices. S. T. Phillips<br />
2:50 88. Microfluidic device for evaluation of<br />
gap junctional intercellular communication<br />
between single cells. N. Ye,<br />
C. Bathy, S. Hua<br />
3:10 89. Print-and-Peel microfluidic devices<br />
for space-domain lifetime measurements.<br />
V. Nunez, B. Millare, S. Shin,<br />
S. Upadhyayula, S. Gupta, V. I. Vullev<br />
3:30 Intermission<br />
3:45 90. Observation of shear-induced volume<br />
decrease in renal-epithelial cells using<br />
microfluidic cell volume sensor.<br />
J. Heo,S.z.Hua<br />
4:05 91. Rapid detection and quantitation of<br />
Botulinum Neurotoxin/A presence and<br />
enzymatic activity using a portable diagnostic<br />
platform. C. Koh, G. J. Sommer,<br />
B. Singh, A. K. Singh, A. V. Hatch<br />
4:25 92. Integrated microfluidic SAW sensor<br />
design for vapor sensing. S. Liu,H.Sun<br />
4:45 93. Spatially resolved functionalization<br />
of monolithic chips for on-line digestion<br />
and separation of analytes.<br />
M. R. Buchmeiser, C. Elsner, C. Ernst<br />
5:05 94. Capillary electrophoresis of segmented<br />
flow using a flow gate injector.<br />
G. Roman<br />
Oligonucleotide Therapeutics Sponsored by<br />
CARB, Cosponsored by ANYL, BIOL, MEDI,<br />
and ORGN<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Biological Assemblies Sponsored by PHYS,<br />
Cosponsored by ANYL<br />
TUESDAY EVENING<br />
Boston Convention & Exposition Center<br />
Hall C<br />
General Posters<br />
S. Lunte, Organizer<br />
7:00–9:00<br />
95. Multiwalled carbon nanotube (MWCNT)<br />
modified with Os(bipyridine) 2Cl]-co-ethylamine<br />
(POs-EA) for analysis of acetaminophen<br />
and ascorbic acid. A. Mugweru,<br />
P. Trihn<br />
96. Application of optical activity analysis on<br />
the differentitation of the origin of methamphetamine<br />
seizures in Taiwan.<br />
S. Chyueh,Y.Liu,C.Cheng,S.Hu<br />
97. Capillary electrophoretic analysis of<br />
postsynaptic density proteins.<br />
J. A. Stinson, R. Gilpin<br />
98. Characterizing molecular conjugation<br />
and aggregation of nanoscale particles<br />
using complementary physical measurement<br />
methods. D. Tsai, T. Cho,<br />
F. W. DelRio, R. I. MacCuspie,<br />
M. R. Zachariah, V. A. Hackley<br />
99. Chemometric optimization of a newly<br />
adopted SIA method for the assay of Ketoconazole<br />
in drug formulations.<br />
H. D. Dafalla<br />
100. Quantitation of imidazole by hydrophilic<br />
interaction liquid chromatography.<br />
B. Vemulapalli, J. Wang, S. Bilbulian,<br />
Z. Wei, P. Cash<br />
101. Very strong redox-dependent hydrogen<br />
bonding between a bis-dimethylaminophenylurea<br />
and a cyclic diamide.<br />
K. Kangas, J. E. Woods, A. L. Cooksy,<br />
D. K. Smith<br />
102. Capillary chromatography based on<br />
tube radial distribution of water-acetonitrile-ethyl<br />
acetate mixture carrier solvents<br />
under laminar flow conditions. N. Jinno,<br />
M. Hashimoto, K. Tsukagoshi<br />
103. Low-cost fluorimetric determination of<br />
radicals based on fluorogenic dimerization<br />
of the natural phenol sesamol.<br />
Y. Makino, S. Uchiyama,K.Ohno<br />
104. Ru(bpy) 2dppz 2� /DNA bilayer-modified<br />
glassy carbon electrode as a novel electrochemical<br />
biosensor for formaldehyde.<br />
W. PU,Q.Ding,J.Zhang<br />
105. General strategy in conducting biorelevant<br />
dissolution for basic compounds in<br />
supportive of early-phase formulation development.<br />
M. H. Wang,Y.Mao,<br />
W. Wasylaschuk, F. Kesisoglou,<br />
J. Broyles, J. Kuiper, D. Thompson,<br />
A. Mitra, M. McQuade, A. Lalloo<br />
106. Determination of FBP disulfide bonds<br />
by mass spectrometry. R. L. Campbell,<br />
C. W. Hutchins, J. R. Fishpaugh,<br />
K. R. Rupprecht, C. S. Ramsay<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ANYL<br />
TECH–9
ANYL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
107. Near infrared dye indocyanine green<br />
doped silica nanoparticles for biological<br />
imaging. B. Quan, Y. Kim, K. Kang,<br />
D. Chung<br />
108. Colloidal dogbone shaped gold nanoparticles<br />
as surface enhanced Raman<br />
spectroscopy (SERS) substrates for detection<br />
of thiram. B. Saute, R. Narayanan<br />
109. Facile formula weight analysis by diffusion-ordered<br />
NMR spectroscopy in physically<br />
separated diffusion systems. W. Li,<br />
G. Kagan, R. Hopson, P. Williard<br />
110. Study and characterization of crystalline<br />
hydrate and polymorph forms of a reverse<br />
transcriptase inhibitor by solid state<br />
NMR spectroscopy. N. C. Gonnella,<br />
S. Campbell, J. A. Smoliga,<br />
D. L. Norwood, C. A. Busacca,<br />
M. Cerreta, R. Varsolona<br />
111. Development and use of an innovative<br />
laboratory method for measuring arsenic<br />
in drinking water by gas chromatographymass<br />
spectrometry. J. DeFelice,<br />
S. H. Frisbie<br />
112. 1 H and 13 C NMR assignments and<br />
structural characterization of three isomeric<br />
o-fluoronaphthaldehydes and one<br />
o-fluorophenanthrene aldehyde.<br />
S. J. Campbell, N. Gonnella, C. Busacca,<br />
C. Senanayake<br />
113. Capillary electrophoresis analysis of<br />
peptides and proteins using a polyethyleneimine-coated<br />
capillary with UV and<br />
MS detection. R. G. Jayo, D. D. Chen<br />
114. New advances in the zeta potential<br />
measurements of proteins.<br />
J. T. Bodycomb, I. Herzberg, E. Farrell,<br />
B. Weiner<br />
115. Using uncertainty analysis to optimize<br />
GPC system performance.<br />
J. T. Bodycomb, I. Herzberg,<br />
J. McConville<br />
116. Systematic and phase appropriate approach<br />
to RP-HPLC method development<br />
for impurities analysis in active<br />
pharmaceutical ingredients via continuous<br />
manufacturing process understanding.<br />
S. Yang, Y. Li, T. Chen, A. Kord<br />
117. Thread as a matrix for biomedical assays.<br />
R. Dasgupta, M. Reches,<br />
G. M. Whitesides<br />
118. Quantifying and characterization of cellular<br />
internalization and localization of<br />
functionalized gold nanoparticles by oligomers.<br />
S. Hong, J. Park, S. Park, J. Yi<br />
119. Spectrometer design for highly efficient<br />
photon capture: Theoretical and practical<br />
limits. J. Hendrikse, A. R. Hajian,<br />
J. Meade, A. Cenko<br />
120. DNA-modified sieving polymers for<br />
metagenomic profiling in capillary electrophoresis.<br />
Y. Dong,L.B.McGown<br />
121. Novel detection method for total organic<br />
carbon (TOC) analysis for planetary<br />
science applications. S. T. Stroble,<br />
S. Kounaves<br />
122. Distinguishing among three luteolin glycoside<br />
isomers orientin/isoorientin/cynaroside<br />
by uUsing host-guest chemistry<br />
and LC-MS/MS. C. Ozer<br />
123. LC-MS/MS method development using<br />
host-guest chemistry to improve the detection<br />
limits for melamine and cyanuric<br />
acid. D. Ramanathan, R. Nardi<br />
124. Survey of the optical properties of the<br />
Equatorial Atlantic ocean waters.<br />
A. A. Andrew, N. V. Blough,<br />
R. Del Vecchio, A. Subramaniam<br />
125. On-line HPLC-FTIR and HPLC-DAD-<br />
UV-MS investigation of photodegradation.<br />
T. K. Chen<br />
126. Specific activity determination of I-124<br />
through chemical derivatization: The<br />
choice of iodination agent.<br />
A. I. Anzellotti,R.J.Ylimaki<br />
127. Spectroscopic characterization and absolute<br />
configuration determination of profenofos,<br />
an organophosphate compound.<br />
G. Proni, N. Capitali, A. Petrovic<br />
128. LC-IR hyphenated system for polymer<br />
characterization. M. Zhou, W. Carson,<br />
S. Bourne, T. Kearney<br />
10–TECH<br />
‡ Cooperative Cosponsorship<br />
129. Impact of the pharmaceuticals caffeine,<br />
erythromycin, and fluoxetine as environmental<br />
water pollutants to mammals.<br />
R. Pinhancos, D. Ramanathan,<br />
S. Weber, M. Gill, J. Yarfi<br />
130. Trifluoroacetic acid extraction for<br />
MALDI-TOF analysis of dyes and pigments.<br />
L. J. Soltzberg, E. R. Haglin,<br />
N. K. Le, B. K. Nguyen, K. A. Yee,<br />
R. Newman<br />
131. HPLC vs. VHPLC design space assessment<br />
for impurity profile methods.<br />
H. B. Fyfe, Y. D. Shi, B. L. Kleintop<br />
132. Spectroscopic study of the kinetics and<br />
the mechanism of the interaction of humic<br />
substances with biomembranes.<br />
L. M. Ojwang,R.L.Cook<br />
133. Environmental toxicity of mussel larvae<br />
determined by 31P NMR. C. L. Poche,<br />
B. D. Dubansky, F. Galvez, R. L. Cook<br />
134. Integrated bioanalytical system for<br />
ADME profiling. K. S. Kieltyka, M. Vath,<br />
J. Maloney, J. Stewart, J. Herbst,<br />
C. Conway, H. Weller, W. Shou, J. Zhang<br />
135. Mass spectrometric identification and<br />
characterization of novel kinase inhibitors<br />
that preferentially target the auto-inhibited<br />
conformation of the protein.<br />
E. Volckova, S. Eathiraj, K. Nguyen,<br />
S. Khanapurkar, M. Hirschi, M. A. Ashwell<br />
136. Determination of residual level of methanesulfonyl<br />
hydrazide in equipment<br />
cleaning for API production. J. Li,J.Yao,<br />
C. Wen<br />
137. Probing the stability of non-derivatized<br />
methyl hydrazine using gas chromatography.<br />
T. Chasse, S. Lloyd<br />
138. Development of chemical cross-linking<br />
and top-down mass spectrometry methodologies<br />
for investigation of protein conformation,<br />
folding disorders and aggregation.<br />
X. Xu, G. Infusini, N. Leymarie,<br />
R. Théberge, D. Perlman, M. E. Mccomb,<br />
C. E. Costello<br />
139. Generating narrowly distributed polymer<br />
using chromatographic fractionation<br />
and characterizing by light scattering and<br />
mass spectrometry. R. Xiang, X. Jia,<br />
F. Meng, H. Yuan, B. Mao<br />
140. Incorporating SPME and Spray Desorption<br />
Collection to evaluate the odor compounds<br />
associated with biodiesel feedstocks.<br />
J. G. Thompson, J. B. Miller,<br />
S. Bertman, A. K. Sarvestani, A. Venter<br />
141. Hexyl-substituted �-terthiophene carboxylic<br />
acids as fluorescence probes for<br />
pathogen detection. J. Hu, G. Jones<br />
142. InfoChemistry: Bioencrypted messages<br />
in arrays of E.coli by cytosolic expression<br />
of fluorescent proteins. M. A. Palacios,<br />
E. Benito-Peña, M. Manesse,<br />
A. D. Mazzeo, C. N. LaFratta,<br />
G. M. Whitesides, D. R. Walt<br />
143. Isobaric dipeptide tags for protein<br />
quantification using quadrupole ion trap.<br />
J. Seo, M. Suh, H. Lee, H. Yoon, S. Shin<br />
144. Implementation of near infrared (NIR)<br />
and microwave resonance (MR) sensors<br />
for moisture determination of powders<br />
and solid oral-dosage forms: A comparison<br />
vs. a Karl Fischer reference method.<br />
C. C. Corredor, D. Bu, D. Both<br />
145. New electrode for electrochemistry: AIS<br />
Snaptrode TM . D. B. Nuzzio<br />
146. Determination of fexofenadine in human<br />
plasma using ultra performance liquid<br />
chromatography. M. R. Amin,<br />
J. M. Amin, P. U. Patel, M. M. Patel,<br />
D. R. Patel<br />
147. Estimation of amiloride and furosemide<br />
in human plasma using high performance<br />
liquid chromatography. J. M. Amin,<br />
M. R. Amin, P. U. Patel, M. M. Patel,<br />
D. R. Patel<br />
148. Photophysical properties of thioglycosylaed<br />
chlorin, isobacteriochlorin, and<br />
bacteriochlorin conjugates. A. Aggarwal,<br />
S. Singh, C. M. Drain<br />
149. Effects of preparation conditions on the<br />
thermal phase transition of uncrosslinked<br />
N-isopropylacrylamide copolymers.<br />
J. R. Csoros, D. Silva,<br />
R. J. Sylvia, W. R. Seitz<br />
150. Multiplexed DNA detection using electrogenerated<br />
chemiluminescence from<br />
Ru (II) polypyridyl intercalators.<br />
E. Benito-Peña, M. A. Palacios,<br />
R. B. Hayman, C. N. LaFratta,<br />
G. Orellana, D. R. Walt<br />
151. Improving lab workflow and productivity<br />
by rapidly monitoring the organic synthesis<br />
reaction and separation with the<br />
atmospheric pressure solids analysis<br />
probe. P. J. Lee,B.P.Murphy,<br />
J. A. Burgess<br />
152. HT-NMR: A novel quality control tool for<br />
determining concentration and water<br />
content of pharmaceutical depository<br />
compounds. Y. Wang,S.Huang,<br />
S. Matson, M. Chartjee, M. Reily<br />
153. Isobaric N-acyl dipeptide tags for multiplexed<br />
protein quantification. M. Suh,<br />
H. Ham, J. Seo, H. Yoon, S. Shin<br />
154. Analysis of an anti-obesity OTC drug<br />
alli (orlistat) using a high-throughput reversed<br />
phase column. A. Chakrabarti,<br />
J. O’Donnell<br />
155. Development of a simple method for<br />
the simultaneous determination of a novel<br />
drug candidate and the biomarkers histamine,<br />
epinephrine, norepinephrine, and<br />
dopamine in rat plasma using LC-MS/<br />
MS. S. A. Pasas-Farmer,S.X.Peng,<br />
S. Dax, J. Mannion<br />
156. Comparative study of protein precipitation<br />
plates for the removal of phospholipids<br />
in plasma samples. X. Zhang,<br />
P. Iraneta, D. P. Walsh,<br />
F. J. Marszalkowski<br />
157. Investigation of selectivity for a new<br />
family of bonded phases. J. E. Turner,<br />
P. Iraneta, B. A. Alden, C. A. Boissel,<br />
S. McCall, T. H. Walter, K. D. Wyndham,<br />
D. P. Walsh, J. T. Cook, K. H. Glose<br />
158. Polymorph determination by mid-IR<br />
spectroscopy for potent active pharmaceutical<br />
ingredients (API’s).<br />
R. R. Shankar<br />
159. Cyclic voltammetry of non-aqueous<br />
phenylenediamines in the presence of<br />
bases. L. E. Rojas-Sligh, L. A. Clare,<br />
D. K. Smith<br />
160. Instrumental neutron activation analysis<br />
of gold in mouse tissues. R. P. Watson,<br />
G. Kramer-Marek, J. Capala<br />
161. Profiling biomass pretreatment hydrolysates<br />
by ultra performance liquid chromatography<br />
- ion mobility - high resolution<br />
mass spectrometry (UPLC-IM-<br />
HRMS). S. Munisamy, C. Becker,<br />
C. K. Chambliss<br />
162. Real-time measurement of cell signaling:<br />
A quartz crystal microbalance with<br />
dissipation (QCM-D) study. M. P. Garcia,<br />
M. Li, J. Chen, J. Xi<br />
163. Fabrication of allyl-silica hybrid monoliths<br />
in 530�m i.d. columns for liquid<br />
chromatography. W. Guo,L.A.Colon<br />
164. Novel biosensor capable of monitoring<br />
glucose in human serum. H. Yoon,<br />
D. Yoon, H. Bae, J. Lee<br />
165. Rapid biosensor capable of sensing tumor<br />
marker. J. R. Rho, T. D. Rho, H. Bae,<br />
J. Lee<br />
166. Advanced biosensor for the rapid quantification<br />
and monitoring of alkaline phosphatase<br />
in milk. L. Park, Y. Kim, H. Bae,<br />
J. Lee<br />
167. Competitive 1,1�-oxalyldiimidazole<br />
chemiluminescent enzyme immunoassay<br />
for the quantification of melamine.<br />
J. Choi, Y. Kim, J. Lee<br />
168. Quantification of acetylcholine in human<br />
serum and plasma using 1,1�-oxalyldiimidazole<br />
chemiluminescence detection.<br />
K. Kang, H. Kang, H. Bae, J. Lee<br />
169. Zirconia and hafnia monoliths for the<br />
electrokinetic pumping of methanol.<br />
I. M. Ferrer-Lassala,L.A.Colon<br />
170. Novel antibody-based nanostructured<br />
biosensors for glutathione oxidativestress<br />
biomarker. Z. Reed, N. Trombley,<br />
R. Wallace, M. Stobiecka, M. Hepel<br />
171. Coupling of electrochemical reduction<br />
and iron release in recombinant horse Hchain<br />
ferritin mutants. C. M. Lundblad,<br />
B. L. Scott, D. C. Zapien<br />
172. Fabrication of pH and magnesium ion<br />
sensors for magnesium implant. X. Guo,<br />
A. Doepke, W. R. Heineman<br />
173. DNA intercalation biosensors for studies<br />
of interactions of herbicides and pesticides<br />
with DNA. K. Coopersmith,<br />
A. Prance, M. Stobiecka, M. Hepel<br />
174. Phosphorodiamidate morpholino oligomers<br />
in DNA diagnostics. Y. Liu,<br />
D. Irving, R. Levicky<br />
175. Migration of substances from nylon 12<br />
and its copolymers. J. Lee, S. Choi,<br />
H. Kim, W. Kim, S. Kim, Y. Kim, S. Kim<br />
176. Surface-initiated polymerization of<br />
mixed brushes via the combination of<br />
controlled radical polymerization techniques<br />
and electrochemistry. M. R. Tria,<br />
R. C. Advincula<br />
177. Quantitative detection of benzene in energy<br />
drinks using GCMS. J. E. Spencer,<br />
S. Bremmer<br />
178. Development of on-line ICPMS methodology<br />
to study the interaction of particulate<br />
matter with biological media.<br />
D. Bérubé, T. Yapici, X. Liao<br />
179. Electrochemistry can be selective:<br />
Tryptamine and barbituric acid in a single-shot.<br />
B. Ebbert, S. M. Mitrovski<br />
180. Identification of analytical artifacts in<br />
the analysis of potency/related substances<br />
in reconstituted anti-cancer lyophilized<br />
solid drug product. Z. Li,<br />
R. Barnes<br />
181. LC-MS/MS method development using<br />
host-guest chemistry to improve the detection<br />
limits for melamine and cyanuric<br />
acid. R. A. Nardi<br />
182. Distinguishing among three luteolin glycoside<br />
isomers by using host-guest<br />
chemistry and LC-MS/MS. C. Ozer<br />
183. Characterization of homemade explosives<br />
(HMEs) by ion chromatography –<br />
tandem mass spectrometry (IC-MS/MS).<br />
J. A. Tokarz, J. M. Ginter, S. A. Ostazeski<br />
184. 2D NMR correlation experiments in the<br />
gas phase. A. A. Marchione<br />
185. Novel electrochemical DNA sensing<br />
strategy based on homogeneous solution<br />
phase hybridization and host-guest recognition.<br />
p. He,H.Fan,Y.Xu,Y.Fang<br />
186. Design and application of multiple polymer<br />
layered systems to facilitate<br />
waveguide sensor detection.<br />
J. M. Giammarco, B. Zdyrko, J. Hu,<br />
A. Agarwal, L. C. Kimerling, N. Carlie,<br />
L. Petit, K. Richardson, I. Luzinov<br />
187. Study of possibility to use zeolites for<br />
immobilization of proteins in conductometric<br />
and potentiometric biosensors.<br />
E. Soy, A. Sacco Jr., S. Dzyadevych,<br />
B. Akata Kurc<br />
188. Grating-coupled SPR for magnetic<br />
nanoparticle immunoassay. Y. Wang,<br />
J. Dostalek, W. Knoll<br />
189. Oxygen insensitive biosensors for real<br />
time detection of glutamate and glucose.<br />
C. R. Ispas, S. Andreescu<br />
190. Evaluation of GCxGC-TOF-MS as an<br />
advanced screening technique in support<br />
of the Organization for the Prohibition of<br />
<strong>Chemical</strong> Weapons (OPCW) proficiency<br />
testing. E. J. Bukowski, E. A. Jestel<br />
191. Fluorescent ratiomeric Cu(II) indicator<br />
based on poly(N-isopropylacrylamide) labelled<br />
with a donor, an acceptor, and a ligand.<br />
S. Yao, J. Du, W. R. Seitz,<br />
N. E. Bencivenga, R. P. Planalp,<br />
R. K. Jackson, D. P. Kennedy,<br />
S. C. Burdette<br />
192. Evaluation of the experimental parameters<br />
that affect the electron capture dissociation<br />
of oligosaccharides. X. Yu,<br />
C. Lin, Y. Huang, C. E. Costello<br />
193. New mass spectrometry based method<br />
to screen for �-amidated peptides from<br />
cell lines. Z. An, J. M. Koomen,<br />
D. J. Merkler<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
194. Photoresponsive ion-selective sensors<br />
for localized acid-base titration.<br />
V. Bychkova, A. Shvarev<br />
195. Real-time monitoring of protease activity<br />
by fluorescence resonance energy<br />
transfer through peptide-graphene conjugates.<br />
B. Ye,M.Zhang<br />
196. Environmental heavy metal contamination<br />
and pattern recognition in Kaduna,<br />
central northern Nigeria. S. O. Fakayode,<br />
E. F. Arhagba,, W. E. Stapleton,<br />
A. M. Taylor, M. McCoy, D. A. Pollard,<br />
M. Yakubu, A. K. Mohammed<br />
197. Nanoporous liposomes for chemical<br />
analysis. T. Hsin, G. Chellappan, K. Wu<br />
198. Azobenzene functionalized poly(dimethyl<br />
siloxane) coatings for explosive detection<br />
using a surface acoustic wave device.<br />
T. Ponrathnam, S. Liu, A. Kokil,<br />
J. Cho, H. Sun, R. Nagarajan, J. Kumar,<br />
P. Kurup<br />
199. Gas sensing in metal-organic frameworks<br />
via localized surface plasmon resonance<br />
spectroscopy. L. E. Kreno,<br />
J. T. Hupp, R. P. Van Duyne<br />
200. Structural characterizations of milk sugars<br />
by collision-induced dissociation<br />
(CID) and electron transfer dissociation<br />
(ETD) on an ion trap MS. L. Han,<br />
C. E. Costello<br />
201. Protein characterization using a combination<br />
of nonresonant CID and ECD in a<br />
Qh/FT-ICR hybrid mass spectrometer.<br />
S. Bourgoin-Voillard, N. Leymarie,<br />
C. E. Costello<br />
202. Mixed metal oxide nanowires and their<br />
sensing properties. X. Li, E. Chin, Q. Yan,<br />
H. Sun, P. U. Kurup, Z. Gu<br />
203. Extraction, concentration and decontamination<br />
of PCB’s and dioxins in food<br />
using small peptides on polyaniline matrix.<br />
N. N. Mateeva, E. Archibong,<br />
A. Foster, K. Warriner, S. Sreevatsan<br />
204. Ionic strength of supporting electrolyes<br />
change the response signals of a spectroelectrochemical<br />
sensor. E. E. Amba,<br />
L. K. Morrris, C. J. Seliskar,<br />
W. R. Heineman<br />
205. “Tail” of two detectors: Identification of<br />
avian influenza via fecal volatiles.<br />
B. A. Kimball, K. Yamazaki, D. Kohler,<br />
M. Opiekun, A. Faranda, J. P. Muth,<br />
R. Bowen, G. K. Beauchamp<br />
206. MiDA: An impartial and incontrovertible<br />
electroanalytical method to detect extraterrestrial<br />
microbial life. J. Wage,<br />
K. McElhoney, J. Maisano, S. Stroble,<br />
G. O’Neil, S. Kounaves<br />
207. Fluorescent sensing array based on<br />
grafted polymer layers.<br />
M. Chyasnavicyus, B. Zdyrko,<br />
V. Tsyalkovsky, V. Klep, I. Luzinov<br />
208. Organically wired gold monolayer protected<br />
clusters. B. N. Turner, D. E. Cliffel<br />
209. Photoacoustic effect generated in phononic<br />
structures. G. J. Diebold, B. Wu<br />
210. Hindered rolling and friction anisotropy<br />
in supported carbon nanotubes.<br />
M. Lucas, X. Zhang, I. Palaci, C. Klinke,<br />
E. Tosatti, E. Riedo<br />
211. Distance and wavelength dependent dielectric<br />
function of Au NPs by angleresolved<br />
SPRi. M. S. Golden,<br />
A. C. Bjonnes, R. M. Georgiadis<br />
212. Trace gas detection of nitrogen dioxide<br />
using cavity ring-down spectroscopy.<br />
J. Dudek<br />
213. Comparison of tandem GC-MS with<br />
tandem LC-MS for the determination of<br />
‚9-THC and its metabolites in biological<br />
fluids. M. S. Young, J. T. Martin<br />
214. Non-invasive NMR characterization and<br />
evaluation of conservation treatments of<br />
oil stains in works of art on paper.<br />
S. Centeno, C. Kehlet, P. Currier,<br />
D. Stockman, E. Del Federico<br />
215. Very high photon capture efficiency for<br />
Raman spectroscopy. A. R. Hajian,<br />
J. Hendrikse, O. Pawluczyk, A. Cenko,<br />
J. Meade<br />
216. Highly stable and sensitive cellular<br />
ELISA using potent enzymatic-inorganic<br />
cerium oxide nanoparticles (single reagent).<br />
A. Asati, C. Kaittanis, S. Santra,<br />
J. Perez<br />
217. Massively parallel detection of gene expression<br />
in single cells using subnanoliter<br />
wells and multiplexed RT-PCR. Y. Gong,<br />
J. C. Love<br />
218. Advances in potential-modulated attenuated<br />
total reflectance (PM-ATM) spectroscopy<br />
for characterization of transparent<br />
metal oxide/semiconductor interfaces<br />
relevant to solar energy conversion.<br />
J. L. Jenkins, Z. O. Araci,<br />
R. C. Shallcross, E. L. Ratcliff,<br />
S. S. Saavedra, N. R. Armstrong<br />
219. Effects of counter ions on solid phase<br />
analytical derivatizations. S. N. Atapattu,<br />
J. Rosenfeld, A. Liu, F. Cui<br />
220. Investigation of a dissolution failure<br />
where the root cause was determined to<br />
be trace level impurities in the API.<br />
P. Tattersall, E. Reiff, A. Bretnall,<br />
S. Brueggemeier, A. Dennis,<br />
R. Deshpande, W. Ding, L. Hobson,<br />
Z. Huang, M. Hubert, M. Leane,<br />
O. Lyngberg<br />
221. DNA aptamers for the diagnosis and<br />
characterization of ovarian cancer.<br />
D. Lopez-Colon,W.Tan<br />
222. Visual detection of pathogenic microorganisms<br />
using a protein conglomeration<br />
method. J. R. Carey,J.Chen<br />
223. New fluororescent sensors bearing two<br />
dansyl fluorophores for highly sensitive<br />
and selective detection of mercury (II)<br />
ions. N. Wanichacheva, A. Kamkaew,<br />
S. Watpathomsub, V. S. Lee, K. Grudpan<br />
224. Single-cell assays for measuring cytokine<br />
secretion and cytotoxicity of human<br />
natural killer cells. Y. J. Yamanaka,<br />
M. Sips, G. Alter, J. Love<br />
225. Maximizing chromatographic information<br />
obtained from complex improvised<br />
explosive device (IED) field samples by<br />
high-throughput GCxGC-TOF-MS.<br />
E. A. Jestel, E. J. Bukowski, T. F. Rusek<br />
226. Application of NMR and chemometrics<br />
in the quality control of biopharmaceutical<br />
drug substances. J. Y. Wei<br />
227. Single-cell analytic technology for the<br />
detailed characterization of human B cell<br />
repertoires. A. O. Ogunniyi,D.S.Kwon,<br />
N. Varadarajan, P. Poignard,<br />
D. R. Burton, B. D. Walker, J. Love<br />
228. Design and development of a beadbased<br />
mesofluidic system. B. Ye,S.Jin<br />
229. Improvement of tandem mass spectra<br />
of heparan sulfate by chemical modification<br />
and charge state manipulation.<br />
X. Shi, Y. Huang, J. Zaia, H. Yin,<br />
K. Killeen<br />
230. Simultaneous detection of multiplexed<br />
IgG proteins using giant magnetoresistive<br />
sensors. M. K. Vattipalli, M. C. Granger,<br />
R. L. Millen, M. D. Porter<br />
231. Simple and highly selective colorimetric<br />
detection method for gaseous formaldehyde.<br />
C. J. Musto, L. Feng, K. S. Suslick<br />
232. Colorimetric sensor array for vapor<br />
phase TATP detection. H. Lin,<br />
K. S. Suslick<br />
233. Carbon nanofilms on diamond for gas<br />
and temperature sensing applications.<br />
V. Kumar,A.A.Bergman,<br />
A. A. Gorokhovsky, A. M. Zaitsev<br />
234. Studying single enzyme kinetics: Correlations<br />
between size and activity.<br />
M. J. Rojek, H. H. Gorris, D. R. Walt<br />
235. Sensitive E-DNA sensor for trace bleomycins<br />
detection. B. Ye,B.Yin,D.Wu<br />
236. Monitoring anti-cancer drug metabolism<br />
with capillary electrophoresis.<br />
A. M. Jones, V. Subramaniam, A. J. Haes<br />
237. Optically trapped array of microbeads<br />
for biosensing applications. M. Manesse,<br />
C. N. Lafratta, M. A. Palacios,<br />
A. F. Phillips, D. R. Walt<br />
238. Neutron single-crystal diffraction instrument<br />
for structure studies in chemical<br />
and materials science. X. Wang,<br />
C. M. Hoffmann, M. J. Frost<br />
239. Fabrication of a folding-based electrochemical<br />
DNA sensor by “click” chemistry.<br />
S. P. Canete,R.Y.Lai<br />
240. Effects of surface charge on reversedphase<br />
liquid chromatographic stationary<br />
phases. B. A. Alden, J. E. Turner,<br />
P. Iraneta, C. A. Boissel, S. McCall,<br />
D. P. Walsh, J. T. Cook, K. H. Glose,<br />
K. D. Wyndham, T. H. Walter<br />
241. Single DNA molecule genotyping in an<br />
array of femtoliter-sized reaction vessels.<br />
A. F. Phillips,D.R.Walt<br />
242. Sensors for extraction and determination<br />
of PCBs and dioxins based on selective<br />
pentapeptides. E. Archibong,<br />
A. Foster, N. N. Mateeva, K. Warriner,<br />
S. Sreevatsan<br />
243. Evaporative packing of nano and microsphere<br />
masks on hydrophobic surfaces.<br />
D. E. Thompson, D. L. Williams,<br />
B. F. Dejene, D. C. Palm<br />
244. Investigating the use of multivariate fluorescence<br />
correlation spectroscopy for<br />
cross-correlation experiments.<br />
C. A. Roach,S.L.Neal<br />
WEDNESDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
ACS Award for Creative Invention:<br />
Symposium in Honor of David Walt<br />
T. Swager, Organizer, Presiding<br />
8:15 Introductory Remarks<br />
8:20 245. <strong>Chemical</strong> and biosensing with<br />
functionalized carbon nanotubes.<br />
T. M. Swager, Y. Weizmann,<br />
D. M. Chenoweth, F. Wang, J. Lim<br />
8:55 246. Nanoflares: A new modality in biodiagnostics<br />
and bioimaging. C. A. Mirkin<br />
9:30 247. Sensing chemical and biochemical<br />
compounds with optical nanostructures.<br />
M. J. Sailor<br />
10:05 Intermission<br />
10:25 248. Engineering better medicines.<br />
J. M. DeSimone<br />
11:00 249. Electrokinetic transport in brain<br />
tissue. S. G. Weber,Y.Guy,A.Hamsher,<br />
H. Xu, A. Faraji, K. Peters<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Analytical Science Cosponsored by ANYL<br />
and INOR Financially supported by University<br />
of North Carolina at Chapel Hill and Analytical<br />
Chemistry<br />
R. Wightman, R. McCarley, Organizers<br />
D. Rolison, Organizer, Presiding<br />
8:20 Introductory Remarks: Royce Murray’s<br />
50 years of excellence in research, education,<br />
and service to chemistry and science,<br />
Henry Blount<br />
8:30 250. Simple technologies for analysis.<br />
G. M. Whitesides, C. Mace, Z. Nie,<br />
F. Deiss, K. Mirica<br />
9:00 251. Applications of SERS to problems<br />
in bioanalytical chemistry and art conservation.<br />
R. P. Van Duyne<br />
9:30 252. Committed electron pusher trucks<br />
on. R. W. Murray<br />
10:00 Intermission<br />
10:30 253. Carbon electrodes for in vivo<br />
analysis. R. Wightman<br />
11:00 254. Nanopore analysis of DNA base<br />
modifications. H. S. White,C.J.Burrows,<br />
A. M. Fleming, N. An, Q. Chen, A. Schibel<br />
11:30 255. Quantitative electrochemical cytometry<br />
of nanometer transmitter vesicles.<br />
A. G. Ewing, D. Omiatek,<br />
L. Mellander, Y. Dong, M. Heien<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Technology Development Sponsored by<br />
PHYS, Cosponsored by ANYL<br />
WEDNESDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
ACS Award for Creative Invention:<br />
Symposium in Honor of David Walt<br />
T. Swager, Organizer, Presiding<br />
1:00 256. Biological mass spectrometry:<br />
Challenges and opportunities.<br />
L. M. Smith<br />
1:35 257. Ultrasensitive biosensing via optical<br />
diffraction with plasmons, nanowires,<br />
nanoparticles and surface enzyme chemistry.<br />
R. M. Corn, Y. Chen, A. R. Halpern,<br />
I. E. Sendroiu, W. Zhou, N. Hu<br />
2:10 258. Characterizing individual DNA<br />
molecules using nanofluidic devices.<br />
J. Ramsey<br />
2:45 Intermission<br />
2:55 259. Allosteric effectors of hemoglobin<br />
reduce the out-flux of apoptosis-inducing<br />
nitric oxide from tumors to blood.<br />
A. Heller<br />
3:30 260. Analysis on paper-based microfluidic<br />
systems. G. M. Whitesides<br />
4:05 Introductory Remarks<br />
4:10 261. Award Address (ACS Award for<br />
Creative Invention Sponsored by the ACS<br />
Corporation Associates). Studying single<br />
molecules and single cells using optical<br />
fiber arrays. D. R. Walt<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Materials Chemistry & Nanoscience<br />
Cosponsored by ANYL and INOR Financially<br />
supported by University of North Carolina at<br />
Chapel Hill and Analytical Chemistry<br />
D. Rolison, R. Wightman, Organizers<br />
R. McCarley, Organizer, Presiding<br />
1:30 262. Bonding in thiolated gold clusters<br />
and self-assembled monolayers: What<br />
happens when a “good metal” meets<br />
some “satisfied molecules”.<br />
R. L. Whetten<br />
2:00 263. Ligand-protected gold clusters as<br />
molecular metals. H. Häkkinen<br />
2:30 264. Some charge transport ideas, informed<br />
by Royce. M. Ratner<br />
3:00 Intermission<br />
3:30 265. Functional metal-organic framework<br />
materials. J. Hupp<br />
4:00 266. Optimizing electron and proton<br />
transfer in water splitting dye-sensitized<br />
solar cells. S. Lee, W. Youngblood,<br />
L. Blasdel, L. Jellison, D. Lentz,<br />
T. A. Moore, A. L. Moore, D. Gust,<br />
T. E. Mallouk<br />
4:30 267. Nanoparticulate ruthenium dioxide<br />
shells on optical substrate cores: An old<br />
material as a new TCO with broadband<br />
transparency and metallic conductivity.<br />
D. R. Rolison, C. N. Chervin, J. W. Long,<br />
J. C. Owrutsky, S. L. Brock,<br />
J. S. Melinger<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Structural Analysis & Filtration Sponsored<br />
by PHYS, Cosponsored by ANYL<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ANYL<br />
TECH–11
ANYL/BIOT/BIOL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
WEDNESDAY EVENING<br />
Sustaining Water Quality Sponsored by<br />
ENVR, Cosponsored by ANYL<br />
THURSDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
<strong>Chemical</strong> Sensors<br />
S. Lunte, Organizer<br />
J. Whitten, Organizer, Presiding<br />
8:00 268. Fabrication of Pd/TiO 2 nanofibers<br />
and their application in hydrogen sensing<br />
. W. Jia, L. Su, Y. Wang, Y. Lei<br />
8:20 269. Poly[meso-tetrakis(2-thienyl)porphyrin]<br />
for the sensitive electrochemical<br />
detection of explosives. W. Chen,<br />
Y. Wang,C.Brückner, C. Li, Y. Lei<br />
8:40 270. Surface plasmon resonance and<br />
quartz crystal microbalance sensing with<br />
nanopatterned colloidal film arrays.<br />
R. Advincula<br />
9:00 271. Nanometric ion sensing using<br />
near-field ratiometric fluorescence sensing.<br />
A. Lewis, E. Wajnryt, P. Hamra,<br />
C. Lewis<br />
9:20 272. Development of a mixed sensor<br />
system for the detection of hazardous<br />
chemicals and explosives. J. Im,<br />
S. K. Sengupta, M. F. Baruch,<br />
J. E. Whitten<br />
9:40 273. Microplasma detection of hazardous<br />
compounds. R. L. Vander Wal,<br />
J. Hitomi Fujiyama-Novak, B. Ward,<br />
D. Das, C. K. Gaddam, A. Mukerjee<br />
10:00 Intermission<br />
10:10 274. Schizophrenic molecules and<br />
materials with multiple personalities: How<br />
materials science could revolutionize<br />
chemical sensing. D. Diamond<br />
10:30 275. Watching the dynamics of photosensitive<br />
membrane proteins by fluorescence<br />
spectroscopy. H. Bayraktar,<br />
A. P. Fields, J. M. Kralj, J. L. Spudich,<br />
K. J. Rothschild, A. E. Cohen<br />
10:50 276. Ratiometric semiconductor<br />
nanocrystal sensors for toxins: Heavy<br />
metals and proteins. L. E. Page,<br />
X. Zhang, C. Tyrakowski, A. Ghai,<br />
J. Krooswyk, P. T. Snee<br />
11:10 277. Electrospun metal oxide nanofibers<br />
for sensitive glucose and H 2O 2 detection.<br />
Y. Ding,Y.Lei<br />
11:30 278. Direct electrochemistry and electrocatalysis<br />
of glucose oxidase on poly-<br />
[cobalt meso-tetrakis(2-thienyl)porphyrin]-SWNTs<br />
composites. W. Chen,<br />
Y. Ding, J. Akhigbe, C. Brückner, C. Li,<br />
Y. Lei<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Energy & Sustainability Cosponsored by<br />
ANYL and INOR Financially supported by<br />
University of North Carolina at Chapel Hill and<br />
Analytical Chemistry<br />
R. Wightman, R. McCarley, Organizers<br />
D. Rolison, Organizer, Presiding<br />
8:20 Introductory Remarks: Where would<br />
functional interfaces be without Royce<br />
Murray? Robert Nowak<br />
8:30 279. Electrochemistry at the nanoscale:<br />
Building blocks and techniques.<br />
H. D. Abruña<br />
12–TECH<br />
‡ Cooperative Cosponsorship<br />
9:00 280. In pursuit of a molecular view of<br />
low work function metal-organic interfaces<br />
in photonic devices.<br />
J. E. Pemberton<br />
9:30 281. Proton conduction in fluoroalkyl<br />
phosphonic and phosphinic acid electrolytes.<br />
S. Creager, D. DesMarteau,<br />
M. Herath, L. Jin<br />
10:00 Intermission<br />
10:30 282. Multifunctional carbon nanoarchitectures<br />
as designer platforms for<br />
electrochemical power sources.<br />
J. W. Long, M. B. Sassin, C. N. Chervin,<br />
J. M. Wallace, K. A. Pettigrew,<br />
J. L. Dysart, D. R. Rolison, A. N. Mansour<br />
11:00 283. Silver vanadium phosphorous<br />
oxide: Resistivity and morphology study.<br />
E. S. Takeuchi, Y. Kim, C. Lee,<br />
E. S. Kozarsky, M. K. Sharma, S. Zhu,<br />
A. C. Marschilok, K. J. Takeuchi<br />
11:30 284. So you think you’re an electrochemist,<br />
well say hello to my little friend.<br />
L. M. Tender, S. Strycharz, R. Snider<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Macromolecular Structures Sponsored by<br />
PHYS, Cosponsored by ANYL<br />
THURSDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 107C<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Look Where the Crossroads Led Us<br />
Cosponsored by ANYL and INOR Financially<br />
supported by University of North Carolina at<br />
Chapel Hill and Analytical Chemistry<br />
D. Rolison, R. McCarley, Organizers<br />
R. Wightman, Organizer, Presiding<br />
1:30 285. Spectroelectrochemical sensors:<br />
A strategy for improved selectivity.<br />
R. A. Wilson, S. E. Andria, C. J. Seliskar,<br />
W. R. Heineman<br />
2:00 286. Electrically conducting materials<br />
based on mixed-valent metal complexes.<br />
C. Elliott<br />
2:30 287. <strong>Chemical</strong> and nanostructural<br />
transformations during reactions of metal<br />
nanoparticles. J. B. Tracy<br />
3:00 Intermission<br />
3:30 288. Restarting the gold nanoparticle<br />
journey: Precursor Au–thiol studies.<br />
D. E. Cliffel, K. Harkness, C. Simpson,<br />
L. Deravi, B. Hixson<br />
4:00 289. Electrochemical DNA-based sensors:<br />
From benchtop to bedside.<br />
R. J. White, K. W. Plaxco<br />
4:30 290. Molecular delivery vehicles constructed<br />
from electron-transfer-active lipids.<br />
R. L. McCarley, N. H. Carrier,<br />
M. F. Mendoza, J. C. Forsythe,<br />
S. Balamurugan, W. C. Silvers<br />
5:00 Concluding Remarks<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 108<br />
Clinical Applications of Sensors<br />
S. Lunte, Organizer<br />
J. Dwyer, Organizer, Presiding<br />
1:30 291. Measurement of four cancer biomarker<br />
proteins in oral cancer using<br />
nanoparticle-based immunoelectrochemical<br />
arrays. R. Malhotra, V. Patel,<br />
J. S. Gutkind, J. F. Rusling<br />
1:50 292. Inexpensive, rapid, and portable<br />
bioassay for rapid detection of estrogenic<br />
activity. C. R. Ispas, S. Andreescu<br />
2:10 293. Particle-particle plasmonic interactions<br />
and their influence on surfaceenhanced<br />
Raman scattering sandwich<br />
immuonassays. E. J. Dufek,<br />
A. C. Crawford, M. D. Porter<br />
2:30 294. New microarray platforms for lipidomics<br />
studies with SPR imaging.<br />
M. J. Linman,Q.Cheng<br />
2:50 295. Synthetic nanopore force spectroscopy<br />
for clinical genotyping.<br />
J. R. Dwyer, V. Tabard-Cossa, D. Trivedi,<br />
M. Wiggin, N. N. Jetha, A. Marziali<br />
3:10 296. Biosensing systems for the detection<br />
of quorum sensing signaling molecules<br />
in clinical samples. N. G. Raut,<br />
P. Pasini, S. Harohalli,<br />
D. R. Auer Flomenhof, S. Daunert<br />
3:30 Intermission<br />
3:40 297. Digital enzyme-linked immunosorbent<br />
assays with subfemtomolar detection<br />
limits in serum. D. M. Rissin,<br />
C. W. Kan, T. G. Campbell, S. C. Howes,<br />
D. R. Fournier, L. Song, T. Piech,<br />
P. P. Patel, L. Chang, A. J. Rivnak,<br />
E. P. Ferrell, J. D. Randall,<br />
G. K. Provuncher, D. R. Walt, D. C. Duffy<br />
4:00 298. Zwitterionic-based antibody arrays<br />
with high sensitivity and specificity<br />
for early cancer diagnostics using SPR<br />
imaging. N. D. Brault, Q. Yu, S. Jiang<br />
4:20 299. Peptide-based electrochemical<br />
biosensor for the detection of HIV antibodies.<br />
J. Y. Gerasimov,R.Y.Lai<br />
4:40 300. Quartz crystal microbalance with<br />
dissipation for real-time characterization<br />
of ligand-induced cellular response.<br />
M. Li, M. Garcia, J. Xi<br />
5:00 301. Withdrawn<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Complex Samples Sponsored by PHYS,<br />
Cosponsored by ANYL<br />
BIOT<br />
Division of Biochemical<br />
Technology<br />
THURSDAY MORNING<br />
Small Wonders: Peptides for Disease<br />
Control Sponsored by AGFD, Cosponsored<br />
by BIOT<br />
BIOL<br />
Division of Biological<br />
Chemistry<br />
J. Bollinger and D. G. McCafferty<br />
Program Chairs<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Breakthroughs in Biochemistry<br />
J. Bollinger, Organizer, Presiding<br />
11:30 1. Shining light on anesthesia.<br />
I. J. Dmochowski, R. G. Eckenhoff<br />
11:50 2. Diphthamide biosynthesis requires<br />
an Fe-S enzyme-generated organic radical.<br />
H. Lin<br />
12:10 3. Mechanistic studies of syringolin A<br />
biosynthesis. W. M. Wuest,H.J.Imker,<br />
C. T. Walsh<br />
12:30 4. Discovery of new natural product<br />
gene clusters through proteomics. I. Ntai,<br />
B. S. Evans, S. B. Bumpus, J. C. Tran,<br />
Y. Chen, J. C. Albright, N. L. Kelleher<br />
12:50 5. Identification and characterization<br />
of small molecule RNA conjugates.<br />
A. M. Leconte,Y.G.Chen,<br />
W. E. Kowtoniuk, D. R. Liu<br />
1:10 6. Nitric oxide mediated signaling in<br />
bacteria. E. M. Boon<br />
1:30 7. Enzymes as nanomotors.<br />
S. Sengupta,H.S.Muddana,<br />
T. Tabouillot, T. E. Mallouk, P. J. Butler,<br />
A. Sen<br />
1:50 8. SIRT1 activation by small molecules<br />
- direct activation or artifact? Evidence<br />
for direct activation via allosteric modulation<br />
of catalysis. R. L. Stein,H.Dai,<br />
L. Kustigian, D. Careney, A. Case,<br />
T. Considine, T. V. Riera<br />
New Frontiers in Single Molecule Detection<br />
and Single Cell Analysis Sponsored by<br />
ANYL, Cosponsored by BIOL and PHYS<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Synthetic Chemistry for Biological Imaging,<br />
Quantitation, and Discovery Cosponsored<br />
by INOR<br />
D. G. McCafferty, Organizer, Presiding<br />
2:30 9. Small molecule probes of protease<br />
function: Applications to molecular imaging.<br />
M. Bogyo, G. Blum, L. Edgington,<br />
F. Yin, A. Berger, J. Lee, M. Terashima,<br />
H. Kosuge, M. McConnell<br />
3:10 10. Polyketide activity and biosynthesis<br />
studies using fluorescent and affinity<br />
tools. C. Perez-Reyes, W. Yu,<br />
B. D. Jones, M. Kang, J. J. La Clair,<br />
M. D. Burkart<br />
3:50 11. Genetically targeted sensors illuminate<br />
the distribution and dynamics of organelle<br />
transport of zinc in living cells.<br />
A. E. Palmer, P. J. Dittmer, Y. Qin,<br />
J. G. Miranda, C. Stoddard<br />
4:30 12. Novel sensors for imaging nitric oxide<br />
and nitroxyl: Selected applications to<br />
sensing biological NO. L. E. McQuade,<br />
M. D. Pluth, J. Rosenthal, S. J. Lippard<br />
New Frontiers in Single Molecule Detection<br />
and Single Cell Analysis Sponsored by<br />
ANYL, Cosponsored by BIOL and PHYS<br />
SUNDAY EVENING<br />
Section A<br />
Boston Convention & Exposition Center<br />
Hall C<br />
Advances in Biological Chemistry New<br />
Understanding<br />
J. Bollinger, Organizer<br />
5:30–7:30<br />
13. Using Cu(II) as a spectroscopic probe for<br />
metal coordination to Frataxin. L. Gentry,<br />
P. Veenam, M. Bowman, R. Timkovich,<br />
L. Busenlehner<br />
14. Ligand induced fit activation mechanism<br />
of GH5 endoglucanase: A molecular dynamics<br />
study. S. Badieyan, D. Bevan,<br />
M. Zhang<br />
15. 3D modeling of a conserved, tandem signaling<br />
GTPase. P. E. March, S. Patchett,<br />
C. Pinegar, M. A. Sellitto, F. Ryvkin<br />
16. Nonpolar isosteres of 8-OxoG expose<br />
recognition and catalysis of DNA repair<br />
glycosylases. P. L. McKibbin, A. Kobori,<br />
Y. Taniguchi, E. T. Kool, S. S. David<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
17. Crystal structures of calicheamicin natural<br />
product glycosyltransferases, CalG2<br />
and CalG4. A. Chang, S. Singh,<br />
C. A. Bingman, J. S. Thorson,<br />
G. N. Phillips, Jr.<br />
18. Boronate-based antioxidants as useful<br />
scavengers of hydrogen peroxide in neuronal<br />
cell culture. C. S. Peritore,<br />
S. E. Schaus<br />
19. X-ray structures of isopentenyl phosphate<br />
kinase. M. F. Mabanglo,<br />
H. L. Schubert, M. Chen, C. Poulter<br />
20. Mechanistic studies of two reductive dehydration<br />
reactions in the deoxyxylulose<br />
phosphate pathway. Y. Xiao,P.Liu<br />
21. Thermophilic bacterium capable of Poly-<br />
(vinyl alcohol) degradation. M. Kim,<br />
M. Yoon, Y. Yoon<br />
22. Geometric analysis of catalytic residues<br />
in the penicillin-binding proteins.<br />
W. G. Gutheil, S. Bobba<br />
23. Non-invasive fluorescence-based methods<br />
for measurements of integrin and<br />
lipid lateral organization in the membrane<br />
of cultured cells. S. Sander, N. Arora,<br />
D. Dibya, E. A. Smith<br />
24. Deoxyribonucleotide levels control genetic<br />
instability phenotypes in budding<br />
yeast. M. Fasullo, O. Tsaponina,<br />
A. Chabes, M. Sun<br />
25. Specific ion effects in coiled coil folding.<br />
A. F. Dexter<br />
26. Enzymatic activity of SIRT5 uncovers<br />
novel protein posttranslational modifications.<br />
H. Lin<br />
27. Zinc-substituted cytochrome P450cam:<br />
Characterization of protein conformers by<br />
photoinduced electron transfer.<br />
K. I. Jankowska,C.V.Pagba,<br />
P. Piotrowiak<br />
28. Vitamin K epoxide reductase employs intraprotein<br />
transfer of reducing power for<br />
continual formation of vitamin K hydroquinone.<br />
M. A. Rishavy, A. Usubalieva,<br />
K. W. Hallgren, K. W. Runge,<br />
K. L. Berkner<br />
29. DNA-catalyzed covalent modification of<br />
amino acid side chains. O. Wong,<br />
P. Pradeepkumar, S. K. Silverman<br />
30. Investigation of trinucleotide repeat<br />
structure in nucleosome core particles.<br />
C. B. Volle, S. Delaney<br />
31. Prenyl transferases involved in the biosynthesis<br />
of prenylated flavonoids exhibiting<br />
various biological activities.<br />
K. Yazaki<br />
32. Predicting protein resistance of molecular<br />
monolayers. P. Paramonov<br />
33. Mutual influences between �-synuclein<br />
and glutathione peroxidase and their<br />
physiological/pathological implications.<br />
H. Koo, J. Chun, D. Lee, S. Paik<br />
34. Investigating the interaction between the<br />
alpha subunit of DNA polymerase III and<br />
UmuD. M. C. Silva, E. Ronayne,<br />
P. J. Beuning<br />
35. 30K Protein originating from silkworm as<br />
an additive for stabilization of enzyme activity.<br />
J. Park, H. Park, T. Park<br />
36. Tale of two enzyme folds: Insights into<br />
catalysis by R67 and E. coli dihydrofolate<br />
reductase. G. Kamath, P. Agarwal<br />
37. Investigating the catalytic mechanism of<br />
the yeast palmitoyltransferase Akr1p.<br />
X. Guan, E. S. Simon, A. F. Roth,<br />
N. G. Davis, P. C. Andrews, C. A. Fierke<br />
38. Branching point of rebeccamycin and<br />
staurosporine aglycone biosynthesis:<br />
Roles of nonconserved residues in RebC<br />
and StaC. P. J. Goldman, K. S. Ryan,<br />
M. J. Hamill, S. J. Elliott, C. T. Walsh,<br />
C. L. Drennan<br />
39. Hairpin-hairpin interactions mediate conversion<br />
to duplex in trinucleotide repeat<br />
sequences. A. Ávila-Figueroa,<br />
S. Delaney<br />
40. Synthetic tools for the investigation and<br />
exploitation of polyketide biosynthesis.<br />
M. Tosin, P. F. Leadlay<br />
41. H 2O 2-mediated signal transduction: A<br />
possible role for peroxymonocarbonate.<br />
H. Zhou, Z. Parsons, S. Lewis,<br />
S. Bhattacharya, D. Seiner, J. N. LaButti,<br />
T. Reilly, K. S. Gates<br />
42. Engineering non-immunogenic and pharmacologically<br />
optimized enzymes for<br />
chemotherapeutic treatment of neuroblastomas.<br />
E. Stone, O. Paley, B. Ekerdt,<br />
S. Yang, G. Georgiou<br />
43. Impact of hydrogen bonding network: A<br />
closer look at the active site of FIH.<br />
E. Saban,M.J.Knapp<br />
44. Understanding the substrate specificity<br />
of DNA Pol III alpha through protein engineering.<br />
R. Parasuram, P. J. Beuning,<br />
M. Ondrechen<br />
45. Unfolding kinetics of Ferricytochrome c<br />
in the presence of phospholipid membranes<br />
with and without Cardiolipin.<br />
S. M. Greer, J. B. Soffer, A. Hagarman,<br />
R. Schweitzer-Stenner, J. Xi<br />
46. Iron storage of micro and macroalgae<br />
using Mossbauer spectroscopy.<br />
A. N. Romano<br />
47. Unexpected calcium inhibition towards<br />
porcine leukocyte 12-lipoxygenase.<br />
S. Xu, A. M. Sharp, M. O. Funk<br />
48. Investigating the role of lipids in cytokinesis.<br />
G. E. Atilla-Gokcumen, S. Sasse,<br />
U. Eggert<br />
49. Mechanistic investigations of new ribonucleotide<br />
reductase-inhibiting anticancer<br />
drugs. Y. Aye,J.Stubbe<br />
50. Studies on the formation of polyhydroxybutyrate<br />
granules in Ralstonia eutropha<br />
via characterization of granule precursors<br />
and fluorescence microscopy. M. Cho,<br />
C. J. Brigham, A. J. Sinskey, J. Stubbe<br />
51. Structural origins of fidelity in pri-miRNA<br />
maturation by the “microprocessor”.<br />
C. W. Wostenberg, K. A. Quarles,<br />
A. R. Bonny, S. A. Showalter<br />
52. Predictable transitive RNA interference<br />
induced by mRNA hairpins in C. elegans.<br />
T. M. Dwyer<br />
53. AGG interruptions in (CGG) n repeat<br />
tracts of DNA modulate the structure and<br />
thermodynamics of non-B conformations<br />
in vitro. D. A. Jarem, L. V. Huckaby,<br />
S. Delaney<br />
54. Switching a minimal riboswitch on/off:<br />
Experimental and computational approaches<br />
to PreQ1 riboswitch structural<br />
changes. A. Pomerantz, P. M. Petrone,<br />
J. Dewhurst, R. Tommasi, L. Whitehead<br />
55. Biosynthesis of azasugars. L. Clark,<br />
N. Horenstein<br />
56. Refined model for CD8, TCR, and MHC<br />
interactions at the immunological synapse.<br />
J. Hoerter, J. Casas, V. Rybakin,<br />
J. Ampudia, P. Yachi, J. Connolly,<br />
T. Hansen, K. Gould, N. Gascoigne<br />
57. Optimizing the expression of alkaline<br />
phytase in Pichia pastoris. M. Yang,<br />
S. C. Johnson, P. Murthy<br />
58. Influence of external stimuli on levels of<br />
human salivary immunoglobulin A (IgA).<br />
M. Doshi, J. Woloski, P. Huch,<br />
C. Charnetski, T. Wignot<br />
59. Hydroxymethylglutaryl-CoA lyase<br />
(HMGCL): Functional insights from structures<br />
of HMGCL-Mg �� -hydroxyglutaryl-<br />
CoA and HMGCL R41M-Mg �� -HMG-<br />
CoA ternary complexes. H. M. Miziorko,<br />
Z. Fu, J. A. Runquist, J. P. Kim<br />
60. Plausible molecular mechanism for H4-<br />
K16 acetylation triggered unfolding of<br />
chromatin. G. Arya,D.Yang<br />
61. Confirmation of a long range interaction<br />
in HIV-1 5�-UTR and its effect on dimerization.<br />
S. Barton, B. Dorjsuren,<br />
G. Kulandaivel, K. Lu, M. F. Summers<br />
62. Specific biological ability of trehalose<br />
and multivalent trehalose on A� aggregation.<br />
M. Wada, Y. Miyazawa, Y. Miura<br />
63. Spectroscopic, steady-state, and transient<br />
kinetic studies of a representative<br />
siderophore-associated monooxygenase.<br />
J. A. Mayfield, R. E. Frederick,<br />
B. R. Streit, T. A. Wencewicz,<br />
J. L. DuBois<br />
64. Analysis of trans-retinoic acid - induced<br />
neuronal differentiation of pluripotent embryonal<br />
carcinoma cells. H. E. Stansfield,<br />
B. Li, L. Gasimli, B. Yang, A. V. Nairn,<br />
K. W. Moremen, J. L. Paluh,<br />
R. J. Linhardt, J. S. Dordick<br />
65. Identification of the elusive metal binding<br />
sites the putative iron chaperone frataxin.<br />
L. E. Gentry, R. Timkovich,<br />
L. S. Busenlehner<br />
66. Proteomic profiling to determine the antineoplastic<br />
mechanism of silver carbenes.<br />
S. M. Bilinovich, M. J. Panzner,<br />
M. C. Deblock, W. J. Youngs,<br />
T. C. Leeper<br />
67. Comprehensive QM/MM studies of the<br />
proton transfer reaction in 4-oxalocrotonate<br />
tautomerase. P. Wu, X. Hu, W. Yang<br />
68. Catalytic activation of yeast acetyltransferase<br />
Rtt109 by the histone chaperone<br />
Vps75. E. M. Kolonko, B. N. Albaugh,<br />
S. E. Lindner, J. L. Keck, J. M. Denu<br />
69. Resonance Raman studies of the conformational<br />
transition in sol-gel encapsulated<br />
hemoglobin: Toward a structural<br />
basis for the tertiary two-state model of<br />
cooperativity. E. M. Jones,<br />
G. Balakrishnan, T. G. Spiro<br />
70. Discovery of an inhibitor of bacterial<br />
N-glycosylation. J. P. Morrison,<br />
D. Jimenez Teja, A. Ciulli, B. Imperiali<br />
71. Mechanistic exploration of small molecule<br />
inhibitors of O-GlcNAc transferase.<br />
J. Jiang, M. Lazarus, S. Walker<br />
72. Implication of OGG1 in onset of Huntington’s<br />
disease. K. M. Schermerhorn,<br />
N. Wilson, D. Jarem, S. Delaney<br />
73. Viral fusogenic peptides form transmembrane<br />
helical bundles: Implications for the<br />
mechanism of fusion. Y. Zhang,<br />
J. Donald, G. Fiorin, V. Carnevale,<br />
D. Slochower, M. L. Klein, W. F. DeGrado<br />
74. p-Thiotyrosine induced DNA cleavage<br />
and religation activity of vaccinia topoisomerase<br />
I. S. Chen,S.M.Hecht<br />
75. Spectroscopically determined pKa values<br />
of archaeal thioredoxins do not govern<br />
their electrochemical potential.<br />
K. D. Bewley, S. Mitra, M. Dey,<br />
S. E. Chobot, C. L. Drennan, S. J. Elliott<br />
76. Structural and redox significance of flavin<br />
in E. coli adaptive response protein AidB.<br />
M. J. Hamill, C. Wong, C. L. Drennan,<br />
S. J. Elliott<br />
77. Advances in cyanobactin biosynthesis.<br />
J. A. McIntosh,E.W.Schmidt<br />
78. Discrimination against the fluorescent<br />
cytosine analog tC by E. coli polymerase<br />
IV DinB. J. M. Walsh, I. Bouamaied,<br />
L. Wilhelmsson, P. J. Beuning<br />
79. Withdrawn<br />
80. Creation, analysis and selective oxidation<br />
of modified replication related DNA<br />
architectures. N. J. Amato,T.J.Wang,<br />
A. J. Bryant-Friedrich, T. Mueser<br />
81. Probing N-linked glycosylation at the<br />
membrane interface with Nanodisc technology.<br />
M. D. Hartley, B. Imperiali<br />
82. Sequence-specific DNA phosphorothioate<br />
modification in bacterial kingdom.<br />
L. Wang, S. Chen, M. S. Demott,<br />
K. Taghizadeh, Z. Deng, P. C. Dedon<br />
83. Conformational characterization of the<br />
Escherichia coli DNA polymerase partner<br />
proteins UmuD and � sliding clamp.<br />
J. Fang, J. R. Engen, P. J. Beuning<br />
84. Characterization of an H-NOX regulated<br />
two-component signaling pathway in<br />
Pseudoalteromonas atlantica. D. Arora,<br />
E. Boon<br />
85. Viscosity effects on the rates of helical<br />
peptide conformational dynamics in neat<br />
alcohol solvents. M. A. Kubasik,<br />
C. Quinn<br />
86. Utilizing Taxus acyltransferases as biocatalysts:<br />
A handy way of producing<br />
modified paclitaxel compounds.<br />
I. N. Nawarathne, K. D. Walker<br />
87. Integrating microarray experimental and<br />
computational methods for improved<br />
drug target prediction. L. M. Christadore<br />
88. Prenylome profiling reveals farnesylation<br />
of an interferon-induced protein effector<br />
is crucial for host resistance to virus infection.<br />
G. Charron,L.K.Tsou,<br />
W. Maguire, H. C. Hang<br />
89. Probing the role of active site loops in E.<br />
coli Y family DNA damage bypass Polymerase<br />
V. L. A. Hawver, C. Gillooly,<br />
P. J. Beuning<br />
90. Protein folding dynamics in crowded environments<br />
and living cells. A. Dhar,<br />
S. Ebbinghaus, A. Samiotakis,<br />
M. S. Cheung, M. Gruebele<br />
91. Repair of DNA interstrand cross-links: Involvement<br />
of the cell cycle. T. M. Mason,<br />
M. Bender, J. Wikoff, P. Miller<br />
92. Kaposi sarcoma virus: Virus-host protein<br />
interactions. S. Wanamaker, D. Meine,<br />
T. Hao, D. Hill, M. Vidal,<br />
J. Roecklein-Canfield<br />
93. Novel small molecule allosterically activate<br />
Integrin Cd11b/Cd18 and reduce<br />
leukocyte migration. D. Maiguel,<br />
M. H. Faridi, V. Gupta<br />
94. Sequence-specific recognition of structured,<br />
pre-microRNA with conformationally-preorganized<br />
miniPEG-� peptide nucleic<br />
acids. M. J. Crawford,<br />
S. Rapireddy, B. Sahu, D. H. Ly<br />
95. E. coli UmuD conformational dynamics in<br />
response to DNA damage.<br />
J. N. Ollivierre, J. Sikora, A. Wallace,<br />
P. J. Beuning<br />
96. Determining the role of NO/HNOX in the<br />
quorum sensing pathway of Vibrio harveyi.<br />
B. M. Henares, E. Boon<br />
97. Analysis of isolated and purified Staphylococcus<br />
aureus type 5 capsular polysaccharide<br />
via monoclonal antibodies and<br />
NMR. J. M. Wells, T. Rudnicki,<br />
D. L. Fagan<br />
98. In vitro cytotoxicity and generation of oxidative<br />
stress by zinc oxide nanoparticles<br />
in human and rodent cells. Q. Xia,<br />
H. Chiang, H. Yu, J. Yin, F. P. Peter<br />
99. Role of polyamine biosynthesis and<br />
eIF5A hypusination in adipocyte differentiation.<br />
P. S. Tiwari, A. Gosslau, K. Chen,<br />
A. Liu<br />
100. Heat stress is associated with the loss<br />
of eukaryotic initiation factor 5A.<br />
R. Butler, A. Gosslau, A. Liu, K. Chen<br />
101. Characterization of a diguanylate cyclase<br />
from Shewanella woodyi with cyclase<br />
and phosphodiesterase activities.<br />
N. Liu<br />
102. pH-dependent structural and functional<br />
properties of hPRL and the extracellular<br />
domain of its receptor. M. Tettamanzi,<br />
C. Keeler, M. Kulkarni, S. Meshack,<br />
D. Myszka, M. Hodsdon<br />
103. Accumulation of tetrahedral intermediates<br />
in cholinesterase catalysis: A secondary<br />
isotope effect study. D. M. Quinn,<br />
J. R. Tormos, K. L. Wiley, F. Nachon,<br />
P. Masson, Y. Nicolet<br />
104. Genetic engineering of polyketide scaffolds<br />
for next generation antibiotics.<br />
L. S. Borketey, N. A. Schnarr<br />
105. Extracellular loop 2 and 3 of short<br />
wavelength cone opsins. D. J. Sandberg,<br />
M. Chen, K. R. Babu, J. Bubis, A. Surya,<br />
L. S. Ramos, H. J. Zapata, J. F. Galan,<br />
R. R. Birge, B. E. Knox<br />
106. Structure of peptides from mineralization-regulating<br />
proteins adsorbed onto<br />
hydroxyapatite. C. Vander Zanden,<br />
M. Wilson, E. Wilson<br />
107. Characterization of Bacillus subtillis<br />
QueE, a novel radical SAM enzyme that<br />
catalyzes a complex cyclization reaction<br />
in the the biosynthesis of 7-deazapurines.<br />
R. M. McCarty, V. Bandarian<br />
108. Effects of mutation of Lys192 and<br />
nearby residues on the substrate specificity<br />
and thermal stability of paraoxonase-1.<br />
C. K. Harsch, T. C. Otto,<br />
D. G. Mata, D. M. Cerasoli, D. E. Lenz,<br />
T. J. Magliery<br />
109. Unraveling amyloid assembly in phospholipids.<br />
J. A. Simmons,D.G.Lynn<br />
110. Kinetic studies of conformation<br />
changes associated with M2 proton<br />
channel activation from influenza A virus.<br />
J. X. Qiu, Y. Wu, W. F. DeGrado<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
BIOL<br />
TECH–13
BIOL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
111. His115 is a major determinant of the<br />
specificity of paraoxonase-1. D. G. Mata,<br />
T. C. Otto, C. K. Harsch, N. Bharwani,<br />
D. M. Cerasoli, D. E. Lenz, T. J. Magliery<br />
112. Directed evolution of bacteriorhodopsin<br />
for biomimetics. N. L. Wagner,<br />
E. E. Duffy, M. R. Gillespie, R. R. Birge<br />
113. Kinetic and structural insights into the<br />
mechanism of ampylation by VopS FIC<br />
domain. D. R. Tomchick,P.Luong,<br />
L. N. Kinch, C. A. Brautigam,<br />
N. V. Grishin, K. Orth<br />
114. Molecular mechanisms of action of Vernonia<br />
Amygdalina as anti-cancer in the<br />
management of breast cancer.<br />
C. G. Yedjou, P. B. Tchounwou,<br />
E. B. Izevbigie<br />
115. Quorum sensing-regulated antibiotic<br />
production from Burkholderia thailandensis.<br />
M. R. Seyedsayamdost,<br />
E. Greenberg, J. Clardy<br />
116. Proteomics of human lymph and<br />
plasma reveals a unique self peptidome<br />
associated with the lymph.<br />
C. C. Clement, L. Santambrogio<br />
117. Toward understanding an unusual His-<br />
Tyr ligated c-heme: X-ray crystal structures<br />
of MauG point mutants.<br />
L. M. Jensen, N. Abu Tarboush,<br />
V. L. Davidson, C. M. Wilmot<br />
118. Depletion of the negatively charged<br />
membrane lipid phosphatidyl glycerol<br />
leads to daptomycin resistance in Bacillus<br />
subtilis. A. G. Hachmann,<br />
J. D. Helmann<br />
119. Quorum quenching effects of PON 1 on<br />
pathogenic bacterial inhabitants of the<br />
human colon. L. M. Simons,<br />
K. Jankowski, Y. Harris<br />
120. Cholesterol transport in model-membrane<br />
systems studied by time resolve<br />
small angle neutron scattering. S. Garg,<br />
L. Porcar, U. Perez-Salas, P. Butler<br />
121. Chitosan treatment affects TGF-�2 expression<br />
in two ovarian cancer cell lines.<br />
E. C. Regisford, T. Taylor, J. Stone,<br />
R. Petrofes-Chapa, C. Johnson,<br />
M. Stewart, P. Traisawatwong,<br />
C. Kelly-Brown, L. E. Carson<br />
122. Understanding and modeling of therapeutic<br />
monoclonal antibody aggregation.<br />
V. Kayser, N. Chennamsetty, V. Voynov,<br />
B. Helk, K. Forrer, B. L. Trout<br />
123. Kindlin 2, its N-terminal structure and<br />
function. D. Perera, J. Yang, J. Qin<br />
124. Photon induced activation of archeal<br />
thioredoxin. M. Dey, S. J. Elliott,<br />
C. L. Drennan<br />
125. Investigating the noncooperative mechanism<br />
of a hyperthermophillic archaeal<br />
enzyme for drug development studies.<br />
L. Eligene, S. Mohamed, V. Curry,<br />
K. A. Stieglitz<br />
126. Refinement and analysis of the structure<br />
of a cobalamin-bound class II ribonucleotide<br />
reductase. M. A. Funk,<br />
M. D. Sintchak, N. Ando, J. Stubbe,<br />
C. Drennan<br />
127. Crystallographic study of a human DNA<br />
repair protein: Alkyladenine DNA glycosylase<br />
(AAG). J. W. Setser, G. M. Lingaraju,<br />
C. Davis, L. D. Samson, C. L. Drennan<br />
128. Probing the role of H-NOX proteins as<br />
sensors for small signaling molecules.<br />
Z. Dai,E.M.Boon<br />
129. Biosynthesis of polyhydroxybutyrate<br />
(PHB) in the Gram-negative aquatic bacterium<br />
Caulobacter crescentus.<br />
R. M. Buckley, J. Stubbe, K. N. Allen<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Repligen Award Symposium<br />
Four Corners of Biological Chemistry<br />
14–TECH<br />
R. T. Raines, Organizer, Presiding<br />
‡ Cooperative Cosponsorship<br />
8:30 130. Structure, function, and inhibition<br />
of human O-GlcNAc transferase.<br />
S. Walker<br />
9:10 131. <strong>Chemical</strong> approaches to sorting<br />
out protein acetylation. P. A. Cole<br />
9:50 132. Dicer and beyond: Mechanisms of<br />
regulatory RNA processing and targeting.<br />
J. Doudna<br />
10:30 133. Ribonuclease: From model system<br />
to the clinic. R. T. Raines<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Goodman Award Symposium<br />
Biogenesis of Enzyme Cofactors<br />
J. Bollinger, Organizer<br />
J. Stubbe, Organizer, Presiding<br />
11:20 134. In vivo and in vitro characterization<br />
of Fe-S cluster assembly by the<br />
stress-responsive Suf pathway.<br />
F. W. Outten<br />
11:55 135. In crystallo biosynthesis of the<br />
tryptophan tryptophylquinone cofactor of<br />
methylamine dehydrogenase by the enzyme<br />
MauG. C. M. Wilmot, L. M. Jensen,<br />
R. Sanishvili, V. L. Davidson<br />
12:30 136. Biosynthesis of the H-cluster of<br />
the [FeFe]-hydrogenase. J. B. Broderick,<br />
E. M. Shepard, B. R. Duffus,<br />
S. E. McGlynn, A. L. Bueling,<br />
C. S. Grady-Smith, S. J. George,<br />
S. P. Cramer, J. W. Peters<br />
1:05 137. Assembly of the diferric and dimanganese-tyrosyl<br />
radical cofactors in<br />
class Ia and Ib ribonucleotide reductases.<br />
J. Stubbe, J. A. Cotruvo, C. Shih,<br />
A. K. Boal, A. C. Rosenzweig<br />
1:40 138. Structural basis for activation of<br />
class Ib ribonucleotide reductase.<br />
A. K. Boal, J. A. Cotruvo, Jr., J. Stubbe,<br />
A. C. Rosenzweig<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
The Chemistry of Epigenetic Regulation<br />
Cosponsored by MEDI<br />
P. Cole, Organizer, Presiding<br />
2:45 139. Studies on the chemistry of oxygen<br />
dependent regulation of expression.<br />
C. J. Schofield<br />
3:25 140. Modulating the modulator: Epigenetic<br />
control beyond the histone code.<br />
M. Zhou<br />
4:05 141. Structural perspective of methylation<br />
mark-mediated epigenetic regulation.<br />
D. Patel<br />
4:45 142. Exploring the roles of epigenetic<br />
and chromatin regulatory proteins in<br />
mental retardation. Y. Shi<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
Undergraduate Research Posters<br />
Biochemistry Sponsored by CHED,<br />
Cosponsored by BIOL and SOCED<br />
Women at the Forefront of Preventing and<br />
Combating Disease Sponsored by WCC,<br />
Cosponsored by BIOL, MEDI, and PROF<br />
MONDAY EVENING<br />
Sci-Mix<br />
J. Bollinger, Organizer<br />
8:00–10:00<br />
26, 42, 54, 73, 81, 87, 116. See previous listings.<br />
171, 174, 177, 180, 182, 194, 195, 199, 202,<br />
205, 229, 242, 246. See subsequent listings.<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Pfizer Award Symposium<br />
V. Bandarian, Organizer, Presiding<br />
8:30 143. Radical-dependent mechanisms<br />
of post-translational modification.<br />
S. J. Booker<br />
9:10 144. Substrate and product analogs as<br />
suicide inactivators of ethanolamine ammonia-lyase.<br />
G. H. Reed, A. L. Menefee<br />
9:50 145. Genetic and molecular basis for<br />
sunscreen biosynthesis in cyanobacteria.<br />
C. T. Walsh, E. Balskus<br />
10:30 146. Uncovering the paradigm for biosynthesis<br />
of 7-deazapurine containing<br />
natural products. V. Bandarian<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Design, Discovery, and Directed Evolution<br />
of Enzyme Activities Cosponsored by COMP<br />
and POLY<br />
T. Magliery, Organizer, Presiding<br />
11:30 147. Elucidating specificity determinants<br />
in Bcl-2 family protein-peptide interactions.<br />
A. E. Keating, S. Dutta,<br />
S. Gulla, T. Chen, E. Fire, R. A. Grant<br />
12:10 148. Privileged scaffolds, “underlying”<br />
promiscuity, and convergence in the evolution<br />
of new enzyme functions.<br />
P. C. Babbitt<br />
12:50 149. Rational design of functional<br />
metalloenzymes. Y. Lu, N. Yeung,<br />
N. M. Marshall, K. D. Miner, S. New,<br />
A. Mukherjee<br />
1:30 150. Engineering proteins for stability<br />
and function with statistical and highthroughput<br />
approaches. T. J. Magliery<br />
Oligonucleotide Therapeutics Sponsored by<br />
CARB, Cosponsored by ANYL, BIOL, MEDI,<br />
and ORGN<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Natural Products Biosynthesis Cosponsored<br />
by MEDI and ORGN<br />
Y. Tang, Organizer, Presiding<br />
2:30 151. Biosynthesis of natural products<br />
in ascidians and their symbionts.<br />
E. W. Schmidt<br />
3:10 152. Expression of complete fungal<br />
biosynthetic gene clusters by promoter<br />
replacement in Aspergillus oryzae.<br />
R. J. Cox, L. M. Halo, M. N. Heneghan<br />
3:50 153. Posttranslational modifications in<br />
natural product biosynthesis.<br />
W. van der Donk<br />
4:30 154. Novel drug leads from natural<br />
products and their derivation from microbial<br />
and biosynthetic diversity.<br />
D. Sherman<br />
Oligonucleotide Therapeutics Sponsored by<br />
CARB, Cosponsored by ANYL, BIOL, MEDI,<br />
and ORGN<br />
TUESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Advances in Biological Chemistry<br />
New Methods<br />
J. Bollinger, Organizer<br />
5:30–7:30<br />
155. Codon scanning mutagenesis by asymmetric<br />
transposons. J. Liu,T.Cropp<br />
156. Genetically encoded photocaged N � -<br />
methyl-L-lysine. Y. Wang, B. Wu, W. Liu<br />
157. Increased functional expression of the<br />
biosynthetic enzymes responsible for the<br />
synthesis of Ramoplanin A2 using Streptomyces<br />
chaperones. A. J. Hoertz,<br />
J. B. Hamburger, D. M. Gooden,<br />
D. G. McCafferty<br />
158. Split-tetracysteine-FlAsH: A novel strategy<br />
for assessing transmembrane helix<br />
association. C. J. Pace, Q. Huang, J. Gao<br />
159. Shaken deepwell microplate screening<br />
to identify high yielding cell clones.<br />
F. B. Cataniag, J. Mendoza, J. Liu,<br />
P. Gilbert<br />
160. Engineering paraoxonase-1 for druglike<br />
properties, bacterial expression, and<br />
solubility. V. S. Shete, B. J. Competty,<br />
T. J. Magliery<br />
161. Improving lipid production from bagasse<br />
hydrolysate with Trichosporon fermentans<br />
using response surface methodology.<br />
R. Li, H. Wu, C. Huang, M. Zong<br />
162. New generation of antibody: Chicken<br />
antibody IgY. J. L. Chan<br />
163. NMR screening of competitive inhibitors<br />
for NHERF 1 and 2.<br />
J. M. Fitzpatrick, D. Mierke,<br />
M. Pellegrini, G. Gaidos<br />
164. Quantitative characterization of polymer<br />
– polymer and polymer – protein interaction<br />
via tracer sedimentation equilibrium.<br />
A. A. Fodeke,A.P.Minton<br />
165. Biodiesel production catalyzed by Rhizomucor<br />
miehei lipase-displaying Pichia<br />
pastoris whole-cell in an isooctane system.<br />
H. Shuangyan, H. Dengfeng,<br />
H. Zhenlin, L. Ying<br />
166. New method for determining the antibody<br />
affinities. M. A. Demchenko,<br />
S. A. Bobrovnik<br />
167. Liquid crystal state derived from �-casein<br />
amyloid fibrils. J. Chun,Y.Choi,<br />
S. Lee, S. Paik<br />
168. Photoelectric hybrid biomaterial prepared<br />
with amyloid fibrils of �-synuclein<br />
in the presence of iron and pthalocyanine<br />
tetrasulfonate. Y. Choi, H. Koo, D. Lee,<br />
S. Paik<br />
169. Energetic contributions of fluorinated<br />
aromatic amino acids to protein stability.<br />
H. Zheng,J.Gao<br />
170. Harnessing biosynthetic enzymes from<br />
Pseudomonas aeruginosa for the study of<br />
asparagine-linked glycosylation.<br />
A. Larkin, B. Imperiali<br />
171. Multiplexed and reiterative fluorescence<br />
labeling via DNA-circuitry. D. Y. Duose,<br />
R. M. Schweller, M. R. Diehl,<br />
W. N. Hittelman<br />
172. Photochemical and thermal stability of<br />
green and blue proteorhodopsins: Implications<br />
for protein-based bioelectronic<br />
devices. M. J. Ranaghan, S. Shima,<br />
L. Ramos, D. S. Poulin, G. Whited,<br />
S. Rajasekaran, J. A. Stuart, A. D. Albert,<br />
R. R. Birge<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
173. Synthetic sugars for cross-linking and<br />
identification of carbohydrate-binding<br />
proteins. R. A. Benedict,N.L.Pohl<br />
174. Controlling protein tyrosine phosphatase<br />
activity with small molecules.<br />
A. C. Bishop, Z. E. Walton, L. K. Harris,<br />
S. M. Frumm, J. Gallant<br />
175. Withdrawn<br />
176. Development of a new 2,4-dinitrotoluene-responsive<br />
riboswitch.<br />
M. E. Davidson, S. V. Harbaugh,<br />
Y. G. Chushak, N. Kelley-Loughnane,<br />
M. O. Stone<br />
177. Structure-activity relationship and<br />
mechanism of action studies for synthetic<br />
ligands that modulate quorum sensing in<br />
Gram-negative bacteria. C. E. McInnis,<br />
H. E. Blackwell<br />
178. Antigen targeted probe for imaging and<br />
delivery of siRNA to tumor cells.<br />
M. Kumar<br />
179. HPLC and MS analysis of modified nucleoside<br />
content in overexpressed tRNA.<br />
D. Pearson, T. Carell<br />
180. Small-molecule bromodomain inhibitors<br />
for cancer therapy. J. Qi,<br />
P. Filippakopoulos, S. Picaud, W. Smith,<br />
T. Keates, E. Morse, M. Philpott, K. Shaw,<br />
O. Fedorov, N. West, T. Heightman,<br />
C. French, S. Knapp, J. Bradner<br />
181. Rational design of cosolvents for inhibition<br />
of protein aggregation. D. Shukla,<br />
B. L. Trout<br />
182. Using peptide based combinatorial libraries<br />
to determine the substrate specificity<br />
of arginine modifying enzymes.<br />
K. L. Bicker, O. Obianyo, B. Knuckley,<br />
H. L. Rust, P. R. Thompson<br />
183. Biological oxidant-activated nanoagents<br />
for the detection and treatment of<br />
disease. M. R. Karver, P. Panizzi,<br />
R. Weissleder, J. R. McCarthy,<br />
S. A. Hilderbrand<br />
184. Contributions of second and third shell<br />
residues to the activity of alkaline phosphatase.<br />
N. A. DeLateur,<br />
S. Somarowthu, H. R. Brodkin,<br />
P. J. Beuning, M. Ondrechen<br />
185. Reengineering the nonribosomal peptide<br />
andrimid. B. S. Evans, Y. Chen,<br />
H. Zhao, N. L. Kelleher<br />
186. Fluorogenic tetrazine cycloadditions for<br />
cellular imaging and detection.<br />
N. K. Devaraj, S. A. Hilderbrand,<br />
R. Weissleder<br />
187. <strong>Chemical</strong> probes for PDZ domain-mediated<br />
interactions: Design, validation,<br />
and application to the study of Shank3<br />
PDZ domain dimerization.<br />
W. S. Iskenderian-Epps, B. Imperiali<br />
188. Tandem fluorescence imaging of dynamic<br />
S-acylation and protein turnover.<br />
M. M. Zhang, L. K. Tsou, G. Charron,<br />
A. S. Raghavan, H. C. Hang<br />
189. Predicting accessible target sites for<br />
trans-splicing ribozymes. D. Meluzzi,<br />
K. Olson, U. F. Muller, G. Arya<br />
190. Engineering of cutinase-hydrogenase<br />
chimera protein. D. M. Stallings<br />
191. Construction and expression of anti-Tnantigen<br />
(alpha GalNAc-Ser/Thr)-specific<br />
MLS128 single chain antibody (scFv)<br />
genes. H. Ogawa, N. Yuasa, Y. Kusada,<br />
H. Asanuma, A. Takasaki-Matsumoto,<br />
Y. Fujita-Yamaguchi<br />
192. In vitro production of anticarbohydrate<br />
antibodies: Purification of anti-T-antigen<br />
(beta Gal1-3GalNAc-Thr/Ser) single chain<br />
antibodies (scFvs) from inclusion bodies.<br />
A. Takasaki-Matsuoto, S. Yamaguchi,<br />
T. Koizumi, N. Yuasa,<br />
Y. Fujita-Yamaguchi<br />
193. Conformational change and ligand<br />
binding sites in allosteric enzymes.<br />
S. Mitternacht, I. N. Berezovsky<br />
194. Site-specific antibody-toxin conjugation<br />
through a genetically encoded p-acetylphenylalanine.<br />
J. A. Yin, B. M. Hutchins,<br />
S. A. Kazane, C. Kim, T. S. Young,<br />
K. M. Bajjuri, K. Staflin, J. S. Forsyth,<br />
B. Felding-Habermann, S. C. Sinha,<br />
V. V. Smider, P. G. Schultz<br />
195. Site-specific oligonucleotide conjugation:<br />
Therapeutic and diagnostic applications.<br />
S. A. Kazane, B. M. Hutchins,<br />
J. A. Yin, C. Kim, T. S. Young,<br />
V. M. Smider, P. G. Schultz<br />
196. Synthetic codon capture for incorporation<br />
of amino acid analogs in biomaterials.<br />
I. Wu, H. Carpenter Desai,<br />
V. P. Conticello<br />
197. SimCell technology: Solution to high<br />
throughput (HTP) bioprocess development.<br />
E. R. Wehling, E. Goel, S. Kumar,<br />
Y. Wen, Z. Xiao, J. LaPierre, S. Gorfien<br />
198. Two-photon phosphorescent nanoprobes<br />
for in vivo microscopy of oxygen.<br />
E. Roussakis, L. E. Sinks, S. Sakadzˇić,<br />
D. A. Boas, S. A. Vinogradov<br />
199. Orthogonal alkynyl-amino acid reporter<br />
for selective labeling of bacterial proteomes<br />
during infection. M. K. Grammel,<br />
M. M. Zhang, H. C. Hang<br />
200. Cytopathology by optical methods:<br />
Spectral cytopathology of mucosal tissue.<br />
K. Lenau, M. Diem, M. Miljkovic,<br />
B. Bird, J. Schubert<br />
201. Probing the divergent colchicine site on<br />
avian erythrocyte tubulin. M. Loew,<br />
A. R. Blanden, S. Bane<br />
202. Perceval2: Engineering an ATP:ADP ratio<br />
sensor for imaging mammalian cells.<br />
M. Tantama, Y. Hung, J. Berg, G. Yellen<br />
203. Multiplexed biochemical detection of<br />
the immunoresponse to dengue fever antigens.<br />
K. A. Murray, S. Ali, Q. Hanley<br />
204. Characterization of latent fluorophoreesterase<br />
pairs for enzymatic assays and<br />
biological imaging. R. Johnson,<br />
M. Hedge<br />
205. Correlated crystallographic and spectroscopic<br />
studies of metallo- and flavoproteins.<br />
D. Stoner-Ma, J. M. Skinner,<br />
A. Héroux, D. K. Schneider, R. M. Sweet,<br />
A. M. Orville<br />
206. Discovery of cyclic peptides that bind<br />
HIV-1 capsid. V. Dewan, T. Liu, K. Chen,<br />
H. Matsuo, D. Pei, K. Forsyth<br />
207. Polyoma virology: Potential drug<br />
screening model against BK virus associated<br />
nephropathy. C. O. Audu,<br />
M. Pellegrini, G. Gaidos, L. Wang,<br />
D. Mierke<br />
208. Fluorescently labeled prenylated peptides<br />
for the study of protein prenylation<br />
in live cells. J. D. Ochocki,<br />
M. D. Distefano, U. Igbavboa, W. Wood,<br />
E. V. Wattenberg, E. A. Arriaga<br />
209. Virus surface remodeling using non-canonical<br />
substrates. P. S. Banerjee,<br />
P. Hearing, I. S. Carrico<br />
210. High-affinity synthetic substrates for<br />
firefly luciferase with red-shifted light<br />
emission. R. R. Gadarla,<br />
W. C. Thompson, S. C. Miller<br />
211. Modification of DNA nucleosides by diethylpyrocarbonate.<br />
C. J. Yennie,S.Oh,<br />
S. Delaney<br />
212. Near-IR oxazine fluorophores for live<br />
cell imaging. S. Pauff, S. C. Miller<br />
213. Probing cellular DNA/protein interactions<br />
using chromatin DNA rehybridization<br />
to identify transcription factors of oncogenes.<br />
H. Zhang, S. K. Morse,<br />
L. B. McGown<br />
214. Delivery of sulfonated molecules into<br />
live cells using esterase-labile sulfonate<br />
protecting groups. L. Rusha, S. C. Miller<br />
215. Biomaterials design: Reflectin-mimetic<br />
protein polymers. H. E. Carpenter Desai,<br />
B. Young, R. Bartlett<br />
216. Progress in the application of GIC and<br />
related matrix/tensor decompositions in<br />
metabolomics and the exploration of protein/ligand<br />
interactions. D. A. Snyder,<br />
L. Alzapiedi, T. Short, P. Vekarya,<br />
C. Walcott, R. Brüschweiler<br />
217. Application of hydroxypropyl-�-cyclodextrin<br />
for the solubility improvement of<br />
microtubule-targeted drugs. T. I. Chio,<br />
M. Loew, S. Bane<br />
218. Developing tropism-modified adenoviral<br />
vectors using metabolic labeling and<br />
bioorthogonal conjugation. Y. Oum,<br />
I. S. Carrico<br />
219. Direct acylation of carrier proteins with<br />
functionalized �-lactones.<br />
J. W. Amoroso, L. S. Borketey,<br />
G. Prasad, N. A. Schnarr<br />
220. Synthesis and properties of DNA containing<br />
rigid nucleosides. H. Yueh,H.Yu,<br />
C. S. Theile, A. Pal, N. Greco,<br />
A. T. Horhota, L. W. McLaughlin<br />
221. Development of antisense agents to image<br />
iNOS expression. Y. Shen,<br />
J. A. Taylor<br />
222. Rapid creation and selection of macrocyclic<br />
libraries for the modulation of protein-protein<br />
interactions. W. H. Connors<br />
223. Introducing bioorthogonal functionalities<br />
onto lentiviral surface. Y. Chu,<br />
I. S. Carrico<br />
224. Computational techniques for generalized<br />
indirect covariance NMR as relates<br />
to protein dynamics. T. Short,<br />
C. Walcott, L. Alzapiedi, P. Vekariya,<br />
D. Snyder<br />
225. High-throughput screening assays for<br />
Pin1 WW and catalytic domains.<br />
A. Y. Mercedes-Camacho,X.R.Chen,<br />
F. A. Etzkorn<br />
226. Tunable carrier protein acylation with Nprotected<br />
�-Lactams. G. Prasad,<br />
J. W. Amoroso<br />
227. Enhanced functional potential of nucleic<br />
acid aptamer libraries patterned to increase<br />
secondary structure. K. M. Ruff,<br />
T. M. Snyder, D. R. Liu<br />
228. Design of a conditional E. coli auxotroph<br />
for functional selection of dual nucleoside<br />
kinase activity. Y. Liu,S.Lutz<br />
229. Identify the lysine acetylation targets of<br />
GCN5 by chemical proteomics with click<br />
chemistry. Z. Zhao<br />
230. Engineering non-immunogenic second<br />
generation L-Asparaginase for acute lymphoblastic<br />
leukemia therapy.<br />
J. R. Cantor, T. Yoo, E. Stone,<br />
G. Georgiou<br />
231. New synthesis of O 2 -POB-dT phosphoramidite<br />
for incorporation into DNA.<br />
M. R. Vargas<br />
232. New family of sensors for detection of<br />
Zn in biological media. B. Ghosh,<br />
S. Thyagarajan, A. Moore,<br />
S. A. Vinogradov<br />
233. Aromatic dithiols: Increasing the folding<br />
rate and yield of disulfide containing proteins.<br />
A. S. Patel,W.J.Lees<br />
234. Patterning of gene expression using<br />
light activated RNA interference (LARI).<br />
S. H. Friedman, P. K. Jain<br />
235. Hetero-bivalent ligand design for preventing<br />
allergic responses. B. Bilgicer<br />
236. Functionalization of thermoresponsive<br />
hydrogel particles with triazine-based<br />
molecules. T. N. Ha, A. Patanarut,<br />
M. Ramanan, B. Bishop<br />
237. Development of a novel double-diffusion<br />
gel electrophoresis system for the<br />
study of mineralization-regulating proteins.<br />
M. V. Wilson, G. Paulman,<br />
A. Exstrom, M. Martin, E. Doane,<br />
E. Wilson<br />
238. Development of a protein-based system<br />
for the detection of organophosphates<br />
using the pH-dependence of enhanced<br />
green fluorescent protein.<br />
J. D. Harris, M. Conway, C. M. Adams,<br />
B. Hounshell, L. G. Puckett<br />
239. Characterization and applications of<br />
Helicobacter pylori �1,3-fucosyltransferases.<br />
C. Besanceney,W.Wang,<br />
T. Zheng, P. Wu<br />
240. Melamine and cyanuric acid do not interfere<br />
with Bradford and Ninhydrin assays<br />
for protein determination. A. Field,<br />
J. Field<br />
241. Efficient syntheses of inducers of antibiotic<br />
production in Streptomyces bacteria.<br />
J. B. Morin, J. D. Bailey, J. K. Sello<br />
242. High throughput screen for small molecule<br />
haptens binding to an HIV-1 neutralizing<br />
antibody yields vaccine leads.<br />
M. J. Caulfield, V. Dudkin, E. A. Ottinger,<br />
K. L. Getty, P. D. Zuck, R. M. Kaufhold,<br />
R. W. Hepler, G. B. McGaughey,<br />
M. Citron, R. C. Hrin, Y. Wang,<br />
M. D. Miller, J. G. Joyce<br />
243. FRET-based investigations into poly-arginine<br />
CPP cellular uptake mechanisms.<br />
S. R. Emani, S. R. Adams, R. Y. Tsien<br />
244. Small molecule inhibitors of phosphatidylcholine<br />
transfer protein (PC-TP)/<br />
StarD2: Therapeutic implications for type<br />
2 diabetes. E. Y. Shishova, G. L. Stahl,<br />
G. D. Cuny, D. E. Cohen<br />
245. Strand-displacement activated fluorescent<br />
PNA probes for detecting iNOS<br />
mRNA expression. Z. Wang,Y.Shen,<br />
J. Taylor<br />
246. Carbon-detected NMR methods for the<br />
study of intrinsically disordered proteins.<br />
C. Lawrence, S. A. Showalter<br />
247. Improved thermoactivity and refoldability<br />
of fluorinated phosphotriesterase.<br />
P. J. Baker<br />
248. DOE approach to develop a cell culture<br />
process for live RSV vaccine. F. Chen<br />
249. Synthetic approach to stop codon<br />
scanning mutagenesis. L. Nie,<br />
T. J. Magliery<br />
250. Statistical approaches to elucidate the<br />
determinants of protein stability.<br />
B. J. Sullivan, V. Durani, T. Nguyen,<br />
T. J. Magliery<br />
251. Shot gun proteomics based identification<br />
of cell wall proteins in Aspergillus<br />
nidulans. N. Ramsubramaniam,<br />
M. R. Marten<br />
252. Design and synthesis of glycopolymers<br />
for exploring multivalent binding events.<br />
E. Lee<br />
253. Developing xenon biosensors for cancer<br />
imaging. Y. Bai, N. Khan, O. Taratula,<br />
P. Hill, G. Seward, I. J. Dmochowski<br />
254. Glycomics for probing O-GlcNAc modifications.<br />
L. Rajaram, I. S. Carrico<br />
255. Developing a cell based screen for<br />
functional mutants of the tumor suppressor<br />
protein p53 DNA binding domain.<br />
B. Ramasubramanian, T. J. Magliery<br />
256. <strong>Chemical</strong> modification of viral-host interactions.<br />
I. S. Carrico<br />
257. Mitochondrial sequestration of antineoplastic<br />
agents: Applications for cancer<br />
therapy and antimicrobial design.<br />
M. P. Pereira, S. B. Fonseca, S. O. Kelley<br />
258. Essential metabolites of M. tuberculosis<br />
and their molecular mimics.<br />
J. S. Freundlich, G. Lamichhane,<br />
S. Ekins, N. Wickramaratne, S. Nolan,<br />
W. R. Bishai<br />
259. Allosteric activators of enzymes.<br />
J. A. Wells, D. A. Wolan, J. A. Zorn,<br />
D. A. Datta, D. A. Gray, J. A. Sadowsky<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Lilly Award Symposium<br />
Molecular Imaging<br />
A. Ting, Organizer, Presiding<br />
8:30 260. How strong is too strong? Engineering<br />
ultrastable interactions to proteins<br />
for imaging and diagnosis.<br />
C. Chivers, B. Zakeri, L. Holm, C. Chu,<br />
E. Crozat, V. Moy, D. Sherratt,<br />
M. Howarth<br />
9:10 261. Designing quantum dots for biological<br />
applications. M. G. Bawendi<br />
9:50 262. Super-resolution fluorescence imaging<br />
reveals nanoscopic organization of<br />
subcellular structure. X. Zhuang<br />
10:30 263. Imaging molecular events at neuronal<br />
synapses using novel fluorescent<br />
reporters. A. Y. Ting<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
BIOL<br />
TECH–15
BIOL/BMGT/CARB <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Gordon Hammes ACS Biochemistry<br />
Lectureship<br />
Elucidations of Enzymatic Mechanisms:<br />
From Gold to Free Radicals<br />
J. Richard, Organizer, Presiding<br />
1:30 264. Elucidations of enzymatic mechanisms:<br />
From gold to free radicals.<br />
P. A. Frey<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Hammes Lectureship Symposium<br />
Enzymatic Reaction Mechanisms<br />
J. Richard, Organizer, Presiding<br />
2:40 265. Discovery and prediction of functions<br />
in the enolase superfamily.<br />
J. A. Gerlt<br />
3:20 266. Unusual enzymatic transformations<br />
during phosphonate biosynthesis.<br />
W. van der Donk<br />
4:00 267. Isopentenyl diphosphate isomerase:<br />
Mechanistic studies of the type-2<br />
enzyme. C. D. Poulter<br />
4:40 268. Mechanism for catalysis of enzyme-catalyzed<br />
proton transfer and decarboxylation<br />
reactions. J. P. Richard<br />
BMGT<br />
Division of Business<br />
Development and<br />
Management<br />
16–TECH<br />
M. Hurrey, Program Chair<br />
OTHER SYMPOSIA OF INTEREST:<br />
Best Practices in Identifying,<br />
Protecting, and Managing Your<br />
Intellectual Property Portfolio (see<br />
CHAL, Wed)<br />
Recent Developments in Intellectual<br />
Property Law: Patents, Trade<br />
Secrets, and Trademarks (see CHAL,<br />
Tue)<br />
Where’s the Good Stuff? Consumer<br />
Health Information Social<br />
Networking, Resources and Services<br />
(see CINF, Mon)<br />
ACS Scholars Program Results:<br />
Stories Highlighting 15 Successful<br />
Years (see PRES, Mon)<br />
Genesis of a <strong>Chemical</strong> Business (see<br />
PROF, Mon)<br />
Integrated Marketing for Small,<br />
Science-Focused Businesses (see<br />
SCHB, Wed)<br />
SOCIAL EVENTS:<br />
Knowledge Café and Networking<br />
Reception, 3:20-5:00 PM: Sun<br />
Membership Reception and Book<br />
Signing, 5:00-7:00 PM: Mon<br />
‡ Cooperative Cosponsorship<br />
BUSINESS MEETING:<br />
Open Meeting, 12:00-1:00 PM: Sun<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 208<br />
Job Growth in This Economy?: Clinical<br />
Supply Manufacture and Local Economies<br />
of Scale Cosponsored by CPCD and NESACS<br />
Financially supported by Vertex<br />
Pharmaceuticals<br />
M. Hurrey, Organizer, Presiding<br />
12:55 Introductory Remarks<br />
1:00 1. Pharmaceutical communities: Making<br />
drugs, protecting jobs, and building a<br />
local economy of scale. P. Connelly<br />
1:20 2. LOCAL vs. CENTRAL: A conundrum<br />
for CDMO’s. D. Mendenhall<br />
1:40 3. Importance of local communities in<br />
US job creation. M. Hurrey<br />
2:00 4. Continuous manufacturing of small<br />
molecule pharmaceuticals: The ultralean<br />
way of manufacturing. J. M. Evans,<br />
A. S. Myerson<br />
2:20 5. Special challenges in the outsourced<br />
manufacture of oncology drugs.<br />
M. J. Kaufman<br />
2:40 6. Navigating the critical path: Transferring<br />
technology to a contract manufacturing<br />
organization (CMO). E. Price<br />
3:00 7. Development of new technologies<br />
for contract chemistry providers: Addressing<br />
the chemistry complexity of the<br />
evolving NCE landscape. D. J. Coughlin<br />
3:20 Knowledge Cafe and Reception<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 254A/B<br />
Open-source Drug Discovery Cosponsored<br />
by CPCD, MEDI, and NESACS<br />
R. Harper, B. Munos, Organizers, Presiding<br />
8:30 Introductory Remarks<br />
8:35 8. Open innovation: A novel approach<br />
to collaborative research for global good.<br />
S. K. Brahmachari<br />
9:05 9. New ecology of collaborative pharmaceutical<br />
research. C. Austin<br />
9:35 10. Producing drug innovation on a<br />
shoestring: Innovation networks for neglected<br />
diseases. S. Nwaka<br />
10:05 Intermission<br />
10:20 11. GSK’s approach to open source<br />
malaria drug discovery. F. Gamo<br />
10:50 12. Innovating in drug innovation:<br />
What’s next? A. Bingham<br />
11:20 Panel Discussion<br />
Genesis of a <strong>Chemical</strong> Business Sponsored<br />
by PROF, Cosponsored by BMGT, SCHB, and<br />
YCC<br />
Sustaining a <strong>Chemical</strong> Business with<br />
Federal Grants & Contracts Sponsored by<br />
SCHB, Cosponsored by BMGT, PROF, and<br />
WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 254A/B<br />
Open-source Drug Discovery Cosponsored<br />
by CPCD, MEDI, and NESACS<br />
R. Harper, B. Munos, Organizers, Presiding<br />
1:30 Introductory Remarks<br />
1:35 13. Compelling economics of open innovation<br />
for drug R. B. Munos<br />
2:05 14. OSDD: Making open innovation<br />
work. Z. Thomas<br />
2:35 15. Lilly’s phenotypic drug discovery<br />
initiative. M. Pineiro-Nunez<br />
3:05 16. Distributed drug discovery (D3):<br />
Linking basic research and education to<br />
find drug leads for neglected diseases.<br />
W. Scott<br />
3:35 17. Collaborative drug discovery: A<br />
Platform for transforming neglected disease<br />
R&D and beyond. S. Ekins<br />
4:05 Panel Discussion<br />
TUESDAY MORNING<br />
Section A<br />
Sheraton Boston<br />
Republic Ballroom B<br />
Chemistry: The Future-proof Profession<br />
Cosponsored by CEPA, SCHB ‡ , SOCED, and<br />
WCC<br />
C. Duane, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:10 18. Once a chemist, always a chemist?<br />
N. R. Gray<br />
8:40 19. From chemistry to finance to philanthropy:<br />
An unplanned journey.<br />
S. C. Tang<br />
9:10 20. Love food as well as chemistry?<br />
Combining passions with chemistry for a<br />
successful career. C. Fisher<br />
9:40 21. Business development: A viable career<br />
path for chemists. B. Chaloner-Gill<br />
10:10 22. What sustainability means to me.<br />
M. A. Cavanaugh<br />
10:40 23. A chemist’s tale: Research to<br />
global environmental consulting.<br />
J. H. Exner<br />
11:10 24. Engineering and chemistry: Miscible,<br />
energetic, explosive? A. Lombard<br />
TUESDAY AFTERNOON<br />
Section A<br />
Sheraton Boston<br />
Republic Ballroom B<br />
Chemistry: The Future-proof Profession<br />
Cosponsored by CEPA, SCHB ‡ , SOCED, and<br />
WCC<br />
C. Duane, Organizer, Presiding<br />
2:00 Introductory Remarks<br />
2:05 25. A chemical education: Gaining<br />
common skills for uncommon opportunities!<br />
B. Lawlor<br />
2:35 26. A chemist ’s skills lead to success<br />
in the non-profit sector. J. Stoner<br />
3:05 27. Chemists without laboratory borders:<br />
Alternative careers in research administration.<br />
P. K. Dorhout<br />
3:35 28. Scientific publishing: The (not so)<br />
accidental profession. B. D. Crawford<br />
4:05 29. With a foundation of chemistry anything<br />
is possible! C. Martin<br />
4:35 Panel Discussion<br />
Women Chemists of Color Summit: Staying<br />
at the Table Sponsored by PRES,<br />
Cosponsored by BMGT, CMA, COMSCI, JSD,<br />
PROF, and YCC<br />
TUESDAY EVENING<br />
Town Hall Forum & Poster Session<br />
Sponsored by PROF, Cosponsored by BMGT,<br />
SCHB, and YCC<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 208<br />
Open Innovation: The New Paradigm for<br />
Competitive Advantage Cosponsored by<br />
NESACS Financially supported by BASF<br />
D. Daly, V. Bornemann, Organizers<br />
A. Loaiza, Presiding<br />
9:00 Introductory Remarks<br />
9:05 30. Implementing open innovation:<br />
Road warrior or road kill, it’s your choice.<br />
G. Slowinski<br />
9:45 31. Bringing sustainability to open innovation.<br />
M. Mascianica<br />
10:15 32. Manage your IP well to win the<br />
open innovation race. R. P. Taylor<br />
10:45 33. InnoCentive’s open innovation<br />
rapid adoption methods and practices<br />
(ONRAMP) program. G. Eichler<br />
11:15 34. Open innovation for long term<br />
projects. H. Guan<br />
11:45 35. Identifying disruptive opportunities<br />
in the materials marketplace: An example<br />
from the conformal barrier coatings<br />
market. E. M. Yokley, C. Hollinsed<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 208<br />
Open Innovation: The New Paradigm for<br />
Competitive Advantage Cosponsored by<br />
NESACS Financially supported by BASF<br />
D. Daly, V. Bornemann, Organizers<br />
A. Loaiza, Presiding<br />
2:00 36. Do organizations continually need<br />
to explore, test and experiment with new<br />
business models, in the same way they<br />
do with new products and technologies<br />
today? S. Kaplan<br />
2:25 37. Open innovation and the faculty entrepreneur:<br />
Opportunities and perils.<br />
R. D. Rogers, D. T. Daly, G. Gurau<br />
2:50 Panel Discussion<br />
CARB<br />
Division of Carbohydrate<br />
Chemistry<br />
T. Lowary, Program Chair<br />
SOCIAL EVENTS:<br />
Wolfrom-Isbell-New Investigator<br />
Award Dinner: Mon<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
Wolfrom-Isbell-New Investigator Award<br />
Symposium<br />
G. Eggleston, Organizer<br />
T. Lowary, Organizer, Presiding<br />
9:15 Introductory Remarks<br />
9:20 1. Developing an enzymatic approach<br />
to synthesize heparan sulfates. J. Liu<br />
10:00 2. Creating and implementing breakthrough<br />
medical technology.<br />
R. S. Langer<br />
10:40 3. Advances in heparin analysis and<br />
synthesis. R. J. Linhardt<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
Wolfrom-Isbell-New Investigator Award<br />
Symposium<br />
G. Eggleston, Organizer<br />
T. Lowary, Organizer, Presiding<br />
1:00 4. Development of a fully synthetic<br />
three-component carbohydrate-based<br />
cancer vaccine. G. Boons<br />
1:35 5. Chemoenzymatic synthesis and antibody<br />
recognition of HIV-1 V3 glycopeptides.<br />
L. Wang<br />
2:10 6. Entirely carbohydrate vaccine constructs<br />
and their application in probing<br />
glycoimmunology. P. R. Andreana<br />
2:45 Intermission<br />
3:00 7. Carbohydrate polymer assembly:<br />
How do mycobacteria do it?<br />
L. L. Kiessling<br />
3:35 8. Lipopolysaccharide transport and<br />
assembly in Escherichia coli. D. Kahne<br />
4:10 9. Arrays and automated oligosaccharide<br />
synthesis. N. L. Pohl<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
Synthetic Oligosaccharides and<br />
Glycoconjugates for Preventing and<br />
Combating Disease<br />
L. Wang, Organizer<br />
G. Boons, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 10. Bioactive N-linked glycopeptides<br />
and glycoprotein conjugates.<br />
T. J. Tolbert<br />
8:25 11. Efficient chemoenzymatic synthesis<br />
of sialyl Lewis antigens using sialyltransferase<br />
mutants. X. Chen, G. Sugiarto,<br />
K. Lau, L. Zhang, S. Huang<br />
9:00 12. Synthesis of saponin vaccine adjuvants<br />
for immunotherapy. D. Y. Gin<br />
9:35 13. Glycosylation engineering of human<br />
IgG-Fc for functional studies.<br />
L. Wang<br />
10:10 Intermission<br />
10:30 14. Chemoenzymatic synthesis of<br />
GPI-anchored proteins and glycoproteins.<br />
X. Guo, Z. Wu, Z. Guo<br />
10:50 15. Cancer relevant epitopes uncovered<br />
by synthetic mucin glycopeptides.<br />
S. Nishimura<br />
11:25 16. <strong>Chemical</strong> biology of O-GlcNAc<br />
processing enzymes. D. J. Vocadlo,<br />
T. M. Gloster, W. F. Zandberg,<br />
J. E. Heinonen, D. Shen, T. Clark,<br />
C. Martinez-Fleites, Y. He, G. J. Davies<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
Synthetic Oligosaccharides and<br />
Glycoconjugates for Preventing and<br />
Combating Disease<br />
G. Boons, Organizer<br />
L. Wang, Organizer, Presiding<br />
1:30 17. Synthesis of a single molecule Lrhamnose-containing<br />
three component<br />
vaccine and evaluation of antigenicity in<br />
the presence of anti L-rhamnose antibodies.<br />
S. Sarkar,R.S.Talan,<br />
S. A. Lombardo, K. A. Wall, S. J. Sucheck<br />
1:50 18. Design of glycoprotein vaccines<br />
against influenza and other viral diseases.<br />
C. Wong<br />
2:25 19. Modular synthesis of heparan sulfate<br />
oligosaccharides for array development.<br />
G. Boons<br />
3:00 Intermission<br />
3:15 20. New targets for antibiotics.<br />
S. Walker<br />
3:50 21. Challenges and opportunities in<br />
natural product glycosylation.<br />
J. S. Thorson<br />
4:25 22. Glycomimetic and non-carbohydrate<br />
inhibitors as probes of the lectin<br />
DC-SIGN. L. L. Kiessling<br />
5:00 Concluding Remarks<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
T. Lowary, Organizer<br />
8:00–10:00<br />
81, 82, 83, 85, 86, 87, 88, 89, 92, 93, 94, 96,<br />
97, 98, 100, 101, 102, 103, 104, 105, 106,<br />
107, 108, 110, 111, 113, 115. See subsequent<br />
listings.<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
Petite and Sweet: Glyconanotechnology as<br />
a Bridge to New Medicines<br />
X. Huang, Organizer<br />
J. Barchi, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 23. Toxicity and functional assessment<br />
using polysaccharide-based magnetic<br />
iron oxide nanoparticles for cell labeling<br />
in vivo and in vitro. Y. Miyamoto,<br />
Y. Koshidaka, H. Saito, Y. Kagami,<br />
K. Murase, N. Kaji, H. Yukawa,<br />
H. Noguchi, H. Iwata, Y. Baba, S. Hayashi<br />
9:05 24. Glycodendrimers for the mediation<br />
of cancer cellular aggregation processes.<br />
M. L. Wolfenden, J. J. Sprenger,<br />
M. P. Capp, P. Nangia-Makker, A. Raz,<br />
M. J. Cloninger<br />
9:35 25. Glyconanoparticles: Multibiofunctional<br />
nanomaterials for biomedical applications.<br />
S. Penades<br />
10:05 Intermission<br />
10:35 26. New glycopeptide-based nanoparticle<br />
constructions for anticancer therapy.<br />
J. J. Barchi, R. Brinas, A. Sundgren,<br />
P. Sahoo, A. Houghten, S. Morey,<br />
M. Sanford, H. Young<br />
11:05 27. Functionalized catanionic surfactant<br />
vesicles: A new approach to carbohydrate<br />
vaccines. J. Park, L. Rader,<br />
G. Thomas, D. English, L. Zimmerman,<br />
D. C. Stein, P. DeShong<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 252A<br />
Oligonucleotide Therapeutics Cosponsored<br />
by ANYL, BIOL, MEDI, and ORGN<br />
M. Manoharan, Organizer, Presiding<br />
R. Iyer, Presiding<br />
8:40 Introductory Remarks<br />
8:45 28. Novel synthesis of 2�-deoxynucleoside<br />
5�-triphosphates without nucleoside<br />
protection and DNA polymerase recognition.<br />
J. M. Caton-Williams, M. R. Smith,<br />
Z. Huang<br />
9:00 29. Activation of retinoic acid inducible<br />
gene (RIG-I) by short oligonucleotides.<br />
R. Iyer, J. Coughlin, S. Padmanabhan,<br />
B. Korba, S. Myong<br />
9:15 30. Solid-phase synthesis of 5�-di- and<br />
tri-phosphates and their modified analogs<br />
of DNA, RNA and chemically modified<br />
oligonucleotides. I. Zlatev,<br />
T. Lavergne, S. Takkellapati, R. Pandey,<br />
Y. Fan, M. Prhavc, K. Mills,<br />
G. Kallanthottathil, F. Debart, J. Vasseur,<br />
F. Morvana, M. Manoharan<br />
9:30 31. Drug discovery harnessing RNA interference.<br />
M. Manoharan<br />
9:45 32. Parallel high throughput synthesis<br />
of chemically modified 21-27mer siRNA<br />
sequences. J. Costigan, S. Kuchimanchi,<br />
S. Shaikh, K. Dufault, J. de Groot,<br />
R. Meyers<br />
10:00 33. New developments in the synthesis<br />
of oligoribonucleotides: Use of dimer/<br />
trimer blocks in combination with an<br />
“ionic tag” soluble support.<br />
M. R. Hassler, N. M. Reddy, T. Chan,<br />
M. J. Damha<br />
10:15 Break<br />
10:30 34. Advanced process of RNA synthesis.<br />
A. Mohan<br />
10:45 35. Novel method for the confirmation<br />
of siRNA sequence by LC-MS/MS.<br />
G. Lavine, M. Kretschmer, J. McArdle,<br />
S. Kuchimanchi, V. Murugaiah,<br />
M. Manoharan<br />
11:00 36. Evaluation of Canonical vs. Dicersubstrate<br />
siRNAs in vitro and in vivo.<br />
D. Foster, S. Elbashir, S. Kuchimanchi,<br />
G. Hinkle, W. Cantley, R. Duncan,<br />
G. Cole, C. Sherill, K. Mills, M. Broberg,<br />
J. Rollins, K. Charisse, M. Manoharan<br />
11:15 37. Modulation of thermal stability can<br />
enhance the potency of siRNA.<br />
H. Addepalli, M. Meena, C. Peng,<br />
G. Wang, Y. Fan, K. Charisse,<br />
K. Jayaprakash, G. Kallanthottathil,<br />
R. Pandey, G. Lavine, L. Zhang,<br />
K. Jahn-Hofmann, P. Hadwiger,<br />
M. Manoharan, M. Maier<br />
11:30 38. Carbohydrate conjugation to<br />
siRNA for tissue-specific delivery.<br />
G. Kallanthottathil, K. Jayaprakash,<br />
M. Frank-Kamenetsky, G. Wang, T. Lei,<br />
M. Severgnini, W. Querbes, J. Butler,<br />
A. Sehgal, T. Nakayama, K. Charrise,<br />
M. Maier, K. Fitzgerald, M. Manoharan<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
Petite and Sweet: Glyconanotechnology as<br />
a Bridge to New Medicines<br />
X. Huang, Organizer<br />
J. Barchi, Organizer, Presiding<br />
1:30 39. Sugar and proteins: Applications of<br />
bioconjugates. B. G. Davis<br />
2:00 40. Sialic acid recognition: Particles,<br />
chips, and cells. R. A. Field<br />
2:30 41. Functionalized nanoparticle for protein<br />
detection. C. Lin<br />
3:00 Intermission<br />
3:30 42. Nanotechnology-based tools for<br />
the glycomics revolution: Silicon nanophotonic<br />
carbohydrate biosensors.<br />
D. M. Ratner<br />
4:00 43. Targeted glyco-magnetic nanoprobes<br />
for detection and molecular imaging<br />
of atherosclerosis. K. El-Boubbou,<br />
M. Kamat, D. Zhu, R. Huang, G. Abela,<br />
X. Huang<br />
4:30 44. Carbohydrates on nanoparticles,<br />
surfaces and polymers: From basics to<br />
diagnostics applications.<br />
P. H. Seeberger<br />
5:00 Concluding Remarks<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 252A<br />
Oligonucleotide Therapeutics Cosponsored<br />
by ANYL, BIOL, MEDI, and ORGN<br />
M. Manoharan, Organizer, Presiding<br />
S. Srivastava, Presiding<br />
2:00 45. Efficient synthesis of siRNA-folic<br />
acid conjugates. R. Pandey,<br />
M. Jayaraman, A. Borodovsky, D. Butler,<br />
S. Matsuda, G. Wang, M. Maier, B. Peng,<br />
M. Solomon, S. Shulga-Morskoy,<br />
K. Charrise, D. Bumcrot, K. Yucius,<br />
V. Kotelianski, G. Kallanthottathil,<br />
M. Manoharan<br />
2:15 46. Combining 2�-TBDMS and 2�-ALE<br />
chemistry for on-column site specific<br />
modifications of RNA. J. G. Lackey,<br />
R. Johnsson, M. J. Damha<br />
2:30 47. Synthesis and evaluation of bicyclic<br />
ketal-based cationic lipids for the delivery<br />
of siRNA via lipid nanoparticle delivery<br />
systems. M. Jayaraman, D. Butler,<br />
L. Eltepu, M. Maier, T. Madden, M. Hope,<br />
Y. Tam, B. Mui, A. Sprague, A. Akinc,<br />
S. De, G. Kallanthottathil, M. Manoharan<br />
2:45 48. Development of a stability-indicating,<br />
ion-pair RP-HPLC method for separation<br />
and quantitative determination of<br />
two siRNA duplexes in a liposome.<br />
V. Murugaiah, W. Zedalis, G. Lavine,<br />
K. Charrise, M. Manoharan<br />
3:00 49. Novel applications of aerosolbased<br />
detectors for the analysis of nonchromophore,<br />
multi-lipid, drug delivery<br />
vehicles. W. Zedalis, M. Kretschmer,<br />
M. Manoharan<br />
3:15 Intermission<br />
3:30 50. Optimizing the LAL assay for detection<br />
of bacterial endotoxin in conjugated<br />
and formulated siRNAs.<br />
M. Broberg, K. Mills, K. Charisse,<br />
W. Zedalis, M. Manoharan<br />
3:45 51. Conjugation strategies for RNAs<br />
using copper-catalyzed click chemistry.<br />
C. Peng, T. Yamada, S. Matsuda,<br />
H. Addepalli, R. Alam, N. Jayaprakash,<br />
M. Jayaraman, D. Butler, R. Pandey,<br />
K. Mills, M. Maier, K. Charrise,<br />
G. Kallanthottathil, M. Manoharan<br />
4:00 52. Non-nucleoside building blocks for<br />
copper-assisted and copper-free click<br />
chemistry for synthesis of oligonucleotide<br />
conjugates. K. Jayaprakash,C.Peng,<br />
T. Yamada, D. Butler, G. Kallanthottathil,<br />
M. Maier, M. Manoharan<br />
4:15 53. Solid-support immobilized, reusable<br />
Cu (I) catalyst for “click reactions” of<br />
oligonucleotides with ligands. L. Eltepu,<br />
C. Peng, K. Jayaprakash, T. Yamada,<br />
M. Jayaraman, G. Kallanthottathil,<br />
M. Manoharan<br />
4:30 54. Synthesis of oligo spermine-containing<br />
oligonucleotides for siRNA delivery.<br />
S. Matsuda, G. Wang, L. Zhang,<br />
T. Lei, R. Alam, C. Pang, K. Jayaprakash,<br />
T. Yamada, D. Butler,<br />
M. Frank-Kamenetsky, M. Maier,<br />
K. Charrise, K. Fitzgerald,<br />
G. Kallanthottathil, M. Manoharan<br />
4:45 Concluding Remarks<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
Recognition of DNA: Recent Advances<br />
Cosponsored by MEDI<br />
D. Arya, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 55. Allosteric modulation of DNA by minor<br />
groove binding polyamides.<br />
D. M. Chenoweth, P. B. Dervan<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
CARB<br />
TECH–17
CARB <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
8:45 56. Strong and selective molecular recognition<br />
of the DNA minor groove: Compound<br />
and DNA chemistry and unusual<br />
conformational matching. W. Wilson,<br />
R. Nanjunda, A. Kumar, M. Munde, Y. Liu,<br />
R. Hunt, D. W. Boykin<br />
9:25 Intermission<br />
9:35 57. Toward DNA recognition by a Janus<br />
Wedge approach. L. W. McLaughlin,<br />
A. Pal, H. Chen, M. Meena<br />
10:15 58. Recognition of DNA major groove.<br />
D. P. Arya, L. Xue, S. Kumar<br />
10:55 59. Identification and cleavage site<br />
analysis of DNA sequences bound<br />
strongly by bleomycin. S. M. Hecht<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 252A<br />
General Papers Glycobiology<br />
T. Lowary, Organizer<br />
E. Cioffi, Presiding<br />
9:00 60. Synthesis and characterization of<br />
chain-end functionalizable glycopolymer<br />
and its oriented glyco-macroligand formation.<br />
S. Narla,X.Sun<br />
9:20 61. Separation and characterization of<br />
the glycosaminoglycan components of<br />
proteoglycans. M. Ly, T. N. Laremore,<br />
K. Solakyildirim, R. J. Linhardt<br />
9:40 62. Synthesis of nucleotide activated Lsugars<br />
from polyols via bioconversion.<br />
R. D. Woodyer<br />
10:00 Intermission<br />
10:15 63. Glycomorphology of the pulmonary<br />
vasculature: Endothelial cell glycocalyx<br />
and endothelial barrier function.<br />
E. Cioffi<br />
10:35 64. Multidimensional glycan arrays for<br />
enhanced lectin and antibody profiling.<br />
Y. Zhang, C. Campbell, Q. Li,<br />
J. Gildersleeve<br />
10:55 65. Peptide nucleic acids bind<br />
strongly and sequence selectively to double<br />
helical RNA. T. T. Zengeya,M.Li,<br />
E. Rozners<br />
11:15 66. Post surface function method for<br />
preparation of liposomal glyco-conjugates.<br />
H. Zhang, Y. Ma, X. Sun<br />
WEDNESDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 252A<br />
General Papers Glycobiology and<br />
Computation<br />
T. Lowary, Organizer<br />
S. Graham, Presiding<br />
1:00 67. Approach to study carbohydratecarbohydrate<br />
interactions involved in myelin<br />
using glycolipids assay in microtiter<br />
plate. J. Zhao,A.Basu<br />
1:20 68. Withdrawn<br />
1:40 69. Synthesis and characterization of<br />
protein glycopolymer conjugate.<br />
V. Gruzdys,X.Sun<br />
2:00 70. Robust analytical development for<br />
oligonucleotide manufacture.<br />
I. Roymoulik<br />
2:20 Intermission<br />
2:35 71. Glycomics studies on central nervous<br />
system. F. Zhang, Z. Liu,<br />
K. Solakyildirim, D. Pu, R. J. Linhardt<br />
2:55 72. Computational studies on the interactions<br />
of mannose with DOPC and<br />
POPC phospholipids. P. R,G.S<br />
3:15 73. Optimizatin of analysis of glycosaminoglycans<br />
in biological samples.<br />
B. Li, R. J. Linhardt<br />
3:35 74. Conformational analysis of nucleosides<br />
and nucleotides: PSEUROT 2010.<br />
S. M. Graham<br />
18–TECH<br />
‡ Cooperative Cosponsorship<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
Recognition of DNA: Recent Advances<br />
D. Arya, Organizer, Presiding<br />
1:30 75. Role of DNA topography in recognition<br />
by proteins and small molecules.<br />
T. D. Tullius<br />
2:10 76. Selective modulation of DNA polymerase<br />
activity by fixed-conformation nucleoside<br />
analogs. M. Egli, R. L. Eoff,<br />
V. E. Marquez, F. P. Guengerich<br />
2:50 77. Structural mechanisms underlying<br />
DNA replication and human DNA mismatch<br />
repair. L. S. Beese,<br />
E. McSweeney, P. L. Modrich, J. Orans,<br />
Q. Tseng, W. Wang<br />
3:30 Intermission<br />
3:45 78. Manipulating the electrostatic potential<br />
in the DNA grooves: Effect on thermodynamic<br />
stability, ion binding, hydration<br />
and structure. B. Gold<br />
4:25 79. Sequence-dependent recognition<br />
of minor groove width. B. Honig<br />
WEDNESDAY EVENING<br />
Section A<br />
Boston Convention & Exposition Center<br />
Hall C<br />
General Posters<br />
T. Lowary, Organizer<br />
8:00–10:00<br />
80. Glycosylation of substituted 4H-1,2,4triazole-3-thiol.<br />
E. H. El Ashry<br />
81. Expression and characterization of enzymes<br />
for bioenzymatic synthesis of heparin.<br />
P. Paul, W. Zhao, R. Linhardt,<br />
J. Dordick, J. Liu<br />
82. Catalytic conversion of biomass-derived<br />
carbohydrates to useful chemicals in one<br />
step. W. Yang,A.Sen<br />
83. Behaviour of polysaccharide aggregates<br />
in asymmetrical field-flow fractionation<br />
and size-exclusion chromatography.<br />
L. Pitkänen, M. Tenkanen, P. Tuomainen<br />
84. Key new observations in the synthesis of<br />
thiosialosides. I. F. Oliveira, G. R. Morais,<br />
B. R. Springett, R. A. Falconer<br />
85. Synthesis and structural optimization of<br />
antifungal kanamycin B analogs.<br />
M. Y. Fosso, Y. Kawasaki, S. Shrestha,<br />
J. Takemoto, T. C. Chang<br />
86. E. coli K5 heparosan production for bioengineered<br />
heparin. Z. Wang,M.Ly,<br />
F. Zhang, Z. Zhang, J. S. Dordick,<br />
R. J. Linhardt<br />
87. Stochastic simulation of lectin microarrays<br />
with nanosensor transducers: Potential<br />
platforms for optimal, high-throughput<br />
screening and profiling of glycoproteins.<br />
N. F. Reuel, J. Ahn, M. S. Strano<br />
88. Evaluation of different thioesters for glycocluster<br />
synthesis applying native<br />
chemical ligation. J. W. Wehner,<br />
T. K. Lindhorst<br />
89. NMR for structure elucidation of commercially<br />
available heparin polysaccharides.<br />
K. Solakyildirim, S. A. McCallum,<br />
R. J. Linhardt<br />
90. Syntheses of C-5-spirocyclic C-glycoside<br />
SGLT2 inhibitors. B. A. Thuma,<br />
V. Mascitti, R. P. Robinson, C. Préville,<br />
M. R. Reese, R. J. Maguire, C. L. Carr,<br />
M. T. Leininger, A. Lowe, C. M. Steppan<br />
91. Co-axial cellulose nanofibers for electrical<br />
applications. M. Miyauchi, J. Miao,<br />
T. J. Simmons, J. S. Dordick,<br />
R. J. Linhardt<br />
92. Study on the relative reactivity of glycosyl<br />
acceptors in the glycosylations of<br />
2-Azido-2-deoxy-galactosides.<br />
J. Kalikanda,Z.Li<br />
93. Synthesis of tailored glycoconjugates for<br />
the precise detection of pathogens.<br />
A. A. Kulkarni, S. S. Iyer<br />
94. Structure-activity studies of synthetic<br />
glycophosphatidylinositol anchored proteins.<br />
C. V. Christianson,<br />
P. H. Seeberger<br />
95. Chemoenzymatic synthesis of heparan<br />
sulfate. R. Liu, J. Liu, Y. Xu<br />
96. Synthesis of a fluorous-tagged disaccharide<br />
for the enzymatic preparation of heparin<br />
oligosaccharides. S. Masuko,<br />
S. Bera, R. J. Linhardt<br />
97. Preventing the transmission of Plasmodium<br />
falciparum through the inhibition of<br />
malaria protein binding to placental chondroitin<br />
sulfate A. J. M. Beaudet,<br />
L. J. Mansur, B. Yang, F. Zhang,<br />
R. J. Linhardt<br />
98. Real-time assessment of the morphological<br />
change of cellulose in response to<br />
enzymatic treatment. C. Nguyen<br />
99. Chemoselective glycosylation of hemoglobin<br />
as a potential oxygen therapeutic.<br />
T. J. Styslinger, N. Zhang, A. F. Palmer,<br />
P. G. Wang<br />
100. Immobilization of enzymes relevant to<br />
bioengineered heparin synthesis.<br />
E. R. Sterner, R. J. Linhardt,<br />
J. S. Dordick, J. Liu, F. Zhang, W. Zhao,<br />
P. Paul, J. Martin<br />
101. Analyses of anti Tn-antigen MLS128<br />
monoclonal antibody binding to two or<br />
three consecutive Tn-antigen clusters by<br />
surface plasmon resonance (SPR) and<br />
NMR. A. Takasaki-Matsumoto,<br />
S. Hanashima, A. Aoki, Y. Yamaguchi,<br />
R. Sato, H. Kawakami, M. Mizuno,<br />
Y. Fujita-Yamaguchi<br />
102. Modular glycoconjugate tool set for assembly<br />
and presentation of multivalent<br />
carbohydrate ligands on surfaces.<br />
I. Abia, B. Sanders, M. D. Best,<br />
D. C. Baker<br />
103. Analysis of the absorption of low molecular<br />
weight heparin in human umbilical<br />
cord tissue as a model for the prevention<br />
of cancer metastasis. A. M. Weyers,<br />
T. Sudha, B. Yang, B. Li, M. Takieddin,<br />
F. Zhang, S. A. Mousa, R. J. Linhardt<br />
104. Synthesis and biological evaluation of a<br />
Gal(�1-2)GalCer analog. Y. Liang,<br />
A. R. Howell<br />
105. Thiol-click chemistry approach to glycomimetics:<br />
Novel stereoselective synthesis<br />
of (1-3)-S-thiodisaccharides.<br />
Z. J. Witczak, I. Bak-Sypien<br />
106. High-throughput glycoarray for monitoring<br />
immune responses to a cancer<br />
vaccine. C. Campbell,Y.Zhang,<br />
O. Ludek, D. Farnsworth, J. Gildersleeve<br />
107. NMR spectroscopic studies of APF: A<br />
small glycopeptide possessing potent<br />
antiproliferative activity. K. M. Adams,<br />
P. Kaczmarek, S. K. Keay, J. J. Barchi, Jr<br />
108. Structural and quantitative analysis of<br />
disaccharides using CE with LIF detection.<br />
Y. Chang, T. Laremore, F. Zhang,<br />
R. J. Linhardt<br />
109. Development of a novel cancer vaccine<br />
based on multivalent presentation of tumor-associated<br />
carbohydrate antigens<br />
on gold nanoparticle scaffolds.<br />
R. P. Brinas, A. Sundgren, M. Maetani,<br />
O. Abbudayyeh, H. A. Young, M. Sanford,<br />
J. J. Barchi<br />
110. Carbon nanotubes and chitosan as<br />
possible scaffolds for bone tissue regeneration.<br />
J. Stone, Y. Olusanya, W. Jones,<br />
P. Traisawatwong, M. Stewart,<br />
C. Kelly-Brown, L. Carson, A. Oki,<br />
E. C. Regisford<br />
111. Biosynthesis of heparin by metabolic<br />
engineering of Chinese hamster ovary<br />
cells. L. Gasimli, J. Baik, S. Sharfstein,<br />
R. J. Linhardt<br />
112. Purification strategies for separation of<br />
capsular polysaccharide from fermentation<br />
broth. U. Bhaskar,Z.Wang,<br />
F. Zhang, J. S. Dordick, R. J. Linhardt<br />
113. Design, synthesis, and characterization<br />
of sulfated N-aryl aminoglycosides.<br />
A. M. Fenner,R.J.Kerns<br />
114. Photo-click immobilization of carbohydrates<br />
on polymeric surfaces: An effortless<br />
method to functionalize surfaces for<br />
biomolecular recognition studies.<br />
O. Norberg,L.Deng,M.Yan,<br />
O. Ramström<br />
115. On-line microflow high-performance liquid<br />
chromatography with nano-electrospray<br />
ionization mass spectrometry for<br />
heparan sulfate disaccharide analysis.<br />
B. Yang, K. Solakyildirim, J. G. Martin,<br />
T. Laremore, R. J. Linhardt<br />
THURSDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
General Papers Synthetic Chemistry<br />
T. Lowary, Organizer<br />
C. Marzabadi, Presiding<br />
8:45 116. De novo synthesis of a 2-acetamido-4-amino-2,4,6-trideoxy-D-galactose<br />
(AAT) building block for the preparation<br />
of the zwitterionic polysaccharide A1<br />
(PS A1) repeating subunit of Bacteroides<br />
fragilis. R. Pragani, P. H. Seeberger<br />
9:05 117. Automated solution-phase synthesis<br />
of alpha-galactosides.<br />
R. Roychoudhury,N.L.Pohl<br />
9:25 118. Study of the protecting group participation<br />
and stereoselectivity of<br />
2-azido-2-deoxygalactopyranosyl donors.<br />
Z. Li<br />
9:45 119. Reactions of glycals with orthosubstituted<br />
benzanilines.<br />
C. H. Marzabadi, K. Kochalski<br />
10:05 120. Novel glycolipids in CD1d-mediated<br />
immunity: Synthesis of new agonists<br />
for CD1d. J. Wojno, J. Jukes, P. Polzella,<br />
V. Cerundolo, L. R. Cox, G. S. Besra<br />
10:25 Intermission<br />
10:40 121. Automated synthesis of systematic<br />
di- and tri-saccharide libraries.<br />
X. Liu, B. Y. Collet, S. Tang,<br />
S. K. Nagappayya, R. Roychoudhury,<br />
X. Li, H. Edwards, N. L. Pohl<br />
11:00 122. Probe of activated glycoside<br />
building block stability for automated solution-phase<br />
synthesis of carbohydrate libraries.<br />
B. Y. Collet, X. Liu, S. Tang,<br />
H. Edwards, S. Nagappayya, L. Liu,<br />
N. L. Pohl<br />
11:20 123. Synthesis of unnatural glycosaminoglycans<br />
and evaluation of their interaction<br />
with proteins. S. Bera<br />
11:40 124. Grafting of cellulose esters by<br />
single electron transfer living radical polymerization<br />
Set-LrP. P. Vlcek,V.Raus,<br />
M. Janata, J. Kriz, P. Latalova, E. Cadova<br />
THURSDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 251<br />
General Papers<br />
Polysaccharides<br />
T. Lowary, Organizer<br />
R. Narain, Presiding<br />
1:00 125. Solvation and hydrolysis of cellulose<br />
with transition metal salts. V. Viner,<br />
B. G. Harvey, R. L. Quintana<br />
1:20 126. <strong>Chemical</strong> derivatization of glucan<br />
microparticles for targeted delivery.<br />
E. R. Soto, G. R. Ostroff<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
1:40 127. Degradation mechanism and crystal<br />
structure change of cellulose during<br />
TEMPO-NaOCl-NaBr selective oxidation<br />
and its biomedical application as hemostatics.<br />
B. Sun,W.Han,W.Wang,C.Gu,<br />
J. Ma, M. Zhu, B. Liang<br />
2:00 128. Temperature-dependent chaincollapse<br />
behavior of cellulose ethers in<br />
dilute solution. H. Shen, R. Sammler,<br />
D. Redwine, D. Meunier, M. Brackhagen<br />
2:20 129. Improving dyeability of nylon wiith<br />
nano-chitosan. H. Wong, H. Lui, L. Liu,<br />
Y. Szeto<br />
2:40 130. Modeling of Congo red adsorption<br />
on a surface of crystalline cellulose using<br />
molecular dynamics. M. Wyszomirski,<br />
K. Mazeau<br />
3:00 Intermission<br />
3:15 131. Evaluation of glycopolymers and<br />
glyconanoparticles for biosensing and<br />
gene delivery applications. R. Narain,<br />
M. Ahmed<br />
3:35 132. Application of data mining techniques<br />
to differentiate glucose-containing<br />
disaccharide ions fragmented via infrared-multiple<br />
photon dissociation using<br />
tunable lasers and Fourier transform ion<br />
cyclotron resonance mass spectrometry.<br />
S. Stefan, M. U. Ehsan, A. Aksenov,<br />
V. Boginksi, B. Bendiak, J. Eyler<br />
3:55 133. Influence of the structure of phosphoramidates<br />
on flame retardant properties<br />
of cellulose. V. Salimova, S. Gaan,<br />
J. Grützmacher<br />
4:15 134. High-flux thin-film nanofibrous<br />
composite ultrafiltration membranes containing<br />
cellulose barrier layer. H. Ma,<br />
B. S. Hsiao, B. Chu<br />
4:35 135. Discovery of 6-deoxy-D-altrose in<br />
nature. M. Tako, T. Yogi, K. Izumori,<br />
H. Ishida, M. Kiso<br />
CATL<br />
Division of Catalysis<br />
Science and Technology<br />
(Probationary)<br />
B. Zhou, Program Chair<br />
SOCIAL EVENTS:<br />
Luncheon: Mon<br />
Dinner: Tue<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Operando and In Situ Spectroscopy<br />
X-ray Methods Cosponsored by COLL,<br />
FUEL, and PETR<br />
P. Stair, Organizer, Presiding<br />
9:00 1. Recent developments in the application<br />
of in situ XAFS studies to catalysis<br />
characterization at UOP. S. R. Bare,<br />
S. D. Kelly, G. E. Mickelson, N. Greenlay,<br />
B. Ravel<br />
9:30 2. Liquid phase operando X-ray absorption<br />
spectroscopy (XAS): Glycerol reforming<br />
over a PtMo/C catalyst.<br />
B. R. Fingland, P. J. Dietrich,<br />
F. H. Ribeiro, N. Guo, J. A. Dumesic,<br />
J. T. Miller<br />
10:00 3. Reactivity of surface species<br />
probed by in situ X-ray absorption techniques.<br />
S. Bordiga, G. Agostini,<br />
D. Gianolio, E. Groppo, C. Lamberti<br />
10:30 4. Structural rearrangements of surface<br />
vanadia species during oxidative dehydrogenation<br />
of propane: In situ UV-vis<br />
and NEXAFS studies. G. Tzolova-Mueller,<br />
M. Haevecker, J. Kroehnert, P. Gruene,<br />
T. Wolfram, R. Schloegl, A. Trunschke<br />
11:00 5. In-situ spectroscopic investigation<br />
of the catalytic oxidative valorization of<br />
lignocellulosic biomass. J. Zakzeski,<br />
P. C. Bruijnincx, B. M. Weckhuysen<br />
11:20 6. Ambient pressure XPS for spatial<br />
and angular resolution of operational heterogeneous<br />
catalysts and electrochemical<br />
systems. M. E. Grass, P. G. Karlsson,<br />
C. Zhang, F. El Gabaly, A. H. McDaniel,<br />
S. H. DeCaluwe, F. Aksoy, B. S. Mun,<br />
G. S. Jackson, Z. Hussain, H. Bluhm,<br />
K. F. McCarty, B. Eichorn, Z. Liu<br />
11:40 7. In situ hard X-ray/infrared studies of<br />
the dynamic behviour of heterogeneous<br />
catalysts. M. A. Newton, M. Di Michiel,<br />
M. Fernandez-Garcia, P. J. Chupas,<br />
K. W. Chapman<br />
12:00 8. Evidence for the surface catalysed<br />
Suzuki-Miyaura reaction over Pd nanocatalysts:<br />
An operando XAS study.<br />
A. F. Lee, P. J. Ellis, I. J. Fairlamb,<br />
K. Wilson<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Operando and In Situ Spectroscopy<br />
Raman and Infrared Spectroscopy<br />
P. Stair, Organizer<br />
J. Miller, Presiding<br />
2:00 9. Operando and in situ Raman spectroscopy<br />
during catalytic reaction in the<br />
liquid phase and for solid-gas reactions.<br />
M. A. Bañares, V. Calvino-Casilda,<br />
E. Rojas-Garcia, R. Lopez-Medina,<br />
O. Guerrero-Perez<br />
2:30 10. Catalysts characterization using<br />
operando Raman spectroscopy. G. Li,<br />
D. Hu, G. Xia, C. Zhang, D. Kim,<br />
C. H. Peden<br />
2:50 11. Investigation of methane aromatization<br />
over Mo/ZSM-5 catalysts with<br />
operando spectroscopy and DFT calculations.<br />
Y. Dai, J. Jehng, S. G. Podkolzin,<br />
B. Modak, I. E. Wachs<br />
3:20 12. Ultraviolet-Raman studies of coke<br />
formation during hydrocarbon conversion<br />
over a zeolite catalyst. P. Allotta,<br />
B. Dunnington, P. C. Stair<br />
3:50 13. Surface dependence of defect sites<br />
on ceria nanocrystals probed by in situ vibrational<br />
spectroscopy. Z. Wu,M.Li,<br />
S. H. Overbury<br />
4:20 14. In-situ infrared absorption spectroscopy<br />
characterization of the adsorption<br />
properties of catalysts made using<br />
novel synthetic techniques. I. Lee,<br />
M. A. Albiter, J. Hong, Y. Yin, F. Zaera<br />
4:50 15. Revealing the zeolite synthesis<br />
mechanisms by in situ UV Raman spectroscopy.<br />
F. Fan, Z. Feng, C. Li<br />
5:10 16. Identification of hydroperoxy species<br />
as reaction intermediates in the electrochemical<br />
evolution of oxygen. B. Yeo,<br />
S. L. Klaus, P. N. Ross, R. A. Mathies,<br />
A. T. Bell<br />
Nanotech for Sustainable Energy and Fuels<br />
Catalyst and Nanomaterials Sponsored by<br />
FUEL, Cosponsored by CATL (probationary)<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Operando and In Situ Spectroscopy<br />
EPR and Others<br />
P. Stair, Organizer<br />
S. Bare, Presiding<br />
9:00 17. Advanced access to structure-reactivity<br />
relationships in vanadium containing<br />
oxidation catalysts by novel in-situ-EPR<br />
techniques. C. Janke, R. Stö�er,<br />
W. Herrmann, J. K. Jabor, A. Brückner<br />
9:30 18. EPR spectroscopy on model catalysts.<br />
T. Risse<br />
10:00 19. Mechanism and active site of the<br />
Phillips’ ethylene polymeirzation catalyst.<br />
A. E. Stiegman, C. Brown, A. Lita,<br />
M. Mileham, M. R. Crosswhite,<br />
J. Krystek, R. Fu<br />
10:30 20. In-situ time-resolved DXAFS and<br />
Raman spectroscopy for selective ethanol<br />
oxidation on supported vanadium<br />
catalysts. M. Tada, N. Ishiguro,<br />
D. Murakami, Y. Iwasawa<br />
10:50 21. In situ monitoring of reaction pathways<br />
on model catalyst surfaces by infrared<br />
spectroscopy: Vinyl acetate synthesis.<br />
W. Tysoe<br />
11:10 22. Withdrawn<br />
11:30 23. Correlation between structure,<br />
acidity and catalytic performance of<br />
WO x/Al 2O 3 catalysts. X. Chen, G. Clet,<br />
K. Thomas, M. Houalla<br />
11:50 24. Fe-containing micro- and mesoporous<br />
materials in heterogeneous catalysis:<br />
Elucidating the structure–activity<br />
relationship with in situ Raman spectroscopy.<br />
Z. Feng, H. Xia, J. Wang, C. Li<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Operando and In Situ Spectroscopy<br />
Imaging and Technique Development<br />
P. Stair, Organizer<br />
I. Wachs, Presiding<br />
2:00 25. Spatially resolved reactor profiles<br />
as novel tool for in situ catalysis research.<br />
R. Horn, O. Korup, S. Mavlyankariev,<br />
M. Geske, R. Schloegl<br />
2:30 26. Solutions to local structural problems<br />
in catalysis. P. J. Chupas<br />
3:00 27. Solving the structure of nanocatalysts<br />
with sub-second time resolution.<br />
A. I. Frenkel, J. C. Hanson<br />
3:30 28. Catalytic reactions on engineered<br />
nanoparticles studied by sum frequency<br />
generation vibrational spectroscopy and<br />
gas chromatography. C. Aliaga,<br />
G. Somorjai, C. Tsung, S. Alayoglu<br />
3:50 29. Combined diffraction and absorption<br />
tomography for catalyst body profiling<br />
during preparation and catalytic reaction.<br />
A. M. Beale, S. D. Jacques,<br />
M. G. O’Brien, L. Espinosa-Alonso,<br />
M. di’Michel, T. Sochi, P. Barnes,<br />
B. M. Weckhuysen<br />
4:10 30. Development of an operando transmission<br />
Fourier Transform Infrared (FTIR)<br />
catalysis reactor system and investigation<br />
of a steady state isotopic transient kinetic<br />
analysis on water gas shift (WGS) reaction.<br />
J. Wang, W. N. Delgass, F. H. Ribeiro<br />
4:30 31. <strong>Chemical</strong> imaging of catalytic reactions<br />
in zeolites with CARS microscopy.<br />
D. Mores, B. M. Weckhuysen,<br />
A. N. Parvulescu, G. Rago, K. F. Domke,<br />
J. P. Day, M. Bonn<br />
4:50 32. Relationship between trap states<br />
and photocatalytic performances of TiO2 studied by in-situ time-resolved photoluminescence<br />
spectroscopy. X. Wang,<br />
S. Shen, Z. Feng, C. Li<br />
AES Science and Technology<br />
Hydrogen as a Resource Sponsored by<br />
COMSCI, Cosponsored by CATL<br />
(probationary), FUEL, I&EC, INOR, and PMSE<br />
Heterogeneous Catalysis for Environmental<br />
and Sustainable Energy Applications<br />
General Environmental Catalysis Sponsored<br />
by ENVR, Cosponsored by CATL<br />
(probationary)<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
General Catalysis Cosponsored by COLL,<br />
FUEL, and PETR<br />
B. Zhou, Organizer<br />
CARB/CATL<br />
8:00–10:00<br />
33. Allenylidene complexes of group 10 transition<br />
metals: Synthesis and catalytic<br />
properties. E. Wuttke, F. Kessler,<br />
H. Fischer<br />
34. Tailored Pd nanocatalysts for the selective<br />
aerobic oxidation of allylic alcohols.<br />
C. V. Ellis, A. F. Lee, K. Wilson, T. H. Lim,<br />
M. A. Newton, C. M. Parlett<br />
35. Propane combustion characteristics over<br />
supporting platinum on zirconia-incorporated<br />
silica. K. Song,G.Seo,M.Kim<br />
36. Pd nanoparticle-doped mesoporous silicates<br />
for the selective aerobic oxidation<br />
of allylic alcohols. C. M. Parlett,<br />
A. F. Lee, K. Wilson, D. W. Bruce<br />
37. Environmentally benign chemical fixation<br />
of CO 2 under solvent-free conditions.<br />
L. He,A.Liu,J.Gao,Z.Yang,<br />
S. Chanfreau<br />
38. Synthesis and application of Platinum<br />
nanoparticles-coated polystyrene nanosphere<br />
catalysts in enantioselective hydrogenation.<br />
A. M. Kulkarni,B.Török,<br />
R. DeSousa, K. Satuluri, M. Török,<br />
G. K. Surya Prakash<br />
39. Au@SiO 2 core-shell nanoparticles for the<br />
selective aerobic oxidation of alcohols.<br />
A. F. Machado, A. F. Lee, K. Wilson<br />
40. Dinuclear zinc catalysts for the copolymerization<br />
of CO 2 and epoxides.<br />
M. W. Lehenmeier, C. Bruckmeier,<br />
P. Deglmann, A. Ott, B. Rieger<br />
41. Copper colloid based catalysts in methanol<br />
synthesis. S. Wang, J. Grunwaldt,<br />
C. Weidenthaler, O. Trapp, S. Vukojević,<br />
A. Kempter, F. Schüth<br />
42. Oxidation of alcohols catalyzed by heterogeneous<br />
polyoxometalate based organic–inorganic<br />
hybrid catalyst with hydrogen<br />
peroxide. Y. Ding, Z. Zhang, B. Ma<br />
43. Effect of prolonged exposure to organic<br />
solvents on the motion of a nitroxide spin<br />
label bound to the active-site of subtilisin<br />
Carlsberg. V. Bansal, Y. Delgado,<br />
M. Legault, G. Barletta<br />
44. Trapping a cubic tetramaganese cluster<br />
with both organic carboxylic acids and an<br />
inorganic polyoxometalate. J. Song,<br />
C. L. Hill, X. Fang<br />
45. Immobilization of platinum nanoparticles<br />
on spherical polyelectrolyte brushes and<br />
their high catalytic activity. S. Wu,<br />
T. Siepenkoetter, L. Li, X. Guo<br />
46. Atomic-scale investigations of catalyst<br />
core-shell nanoparticles using 3D atom<br />
probe. P. A. Bagot, T. Li, E. A. Marquis,<br />
E. S. Tsang, G. D. Smith<br />
47. Correlation of XRD, SAXS and electroactive<br />
surface area analyses with catalyst<br />
performance. M. Webber, L. Li, M. Bates,<br />
J. Bedard, E. S. Smotkin<br />
48. Microwave-assisted hydrothermal synthesis<br />
of cryptomelane-type octahedral<br />
molecular sieves (OMS-2) and their catalytic<br />
studies. H. Huang, S. Sithambaram,<br />
S. L. Suib<br />
49. Modeling selective CO oxidation over Pt<br />
based catalysts using modular neural<br />
network. M. Gunay, R. Yildirim<br />
50. Room-temperature synthesis of carbonsupported<br />
PtIr nanoparticles as direct liquid<br />
fuel anode catalysts. S. Hwang,<br />
S. Yoo, T. Lim, S. Kim<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–19
CATL/CHED <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
51. Synthesis of ternary Pt-Fe-Co alloy catalysts<br />
toward oxygen reduction reaction.<br />
S. Hwang,S.Yoo,T.Lim,S.Kim<br />
52. Catalytic nanobowls synthesized using<br />
atomic layer deposition. N. A. Ray,<br />
R. P. Van Duyne, P. C. Stair<br />
53. Kinetics of adsorption and reaction of hydrocarbon<br />
molecules on ordered Sn/<br />
Pt(111) alloy surfaces. L. A. Welch,<br />
B. E. Koel<br />
54. Synthesis, characterization, and catalytic<br />
applications of ruthenium(II) carbene-pincer<br />
complexes. O. V. Ozerov, R. Ramirez<br />
55. Improving cellulase compositions for<br />
lignocellulose hydrolysis. T. Shaghasi<br />
56. Synthesis of transition metal and transition<br />
metal alloy nanoparticles as catalysts.<br />
Y. Kang, C. B. Murray<br />
57. Oxidation of 2,3,6-trimethylphenol (TMP)<br />
using manganese oxide octahedral molecular<br />
sieves (OMS-2). N. N. Opembe,<br />
C. K. King’ondu, S. L. Suib<br />
58. Catalytic reactions of silica gel supported<br />
titanium oxide with aryl ketones.<br />
A. Apblett, R. Cannon<br />
59. In situ micro-spectroscopy study on the<br />
coke formation during the methanol-toolefin<br />
conversion on individual H-ZSM-5<br />
crystals. D. Mores, B. M. Weckhuysen<br />
60. Acid catalyzed synthesis of fatty acid<br />
methyl esters from waste greases.<br />
H. L. Ngo, H. Vanselous, W. Lin<br />
61. Influence of Nafion® on adsorption of<br />
carbon monoxide on platinum catalysts.<br />
A. P. Yakaboski, E. Smotkin<br />
62. High performance NH 3-SCR zeolite zatalysts<br />
for treatment of NOx in emissions<br />
from diesel engine. X. Yang, C. K. Narula<br />
63. Mono- and multilayer surface alloys as<br />
electrocatalysts. X. Yang, J. Fu, B. E. Koel<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Surface Science of Catalysis Cosponsored<br />
by COLL, FUEL, and PETR<br />
G. Bhargava, E. I. Altman, Organizers,<br />
Presiding<br />
9:00 Introductory Remarks<br />
9:05 64. Fine tuning modifier-substrate interactions<br />
in the asymmetric hydrogenation<br />
of ketoesters on chirally modified<br />
platinum. S. Lavoie,<br />
V. Demers-Carpentier, Y. Dong,<br />
J. Brunelle, G. Goubert, G. Mahieu,<br />
P. H. McBreen<br />
9:25 65. Density functional theory study of<br />
defects in magnetite. T. A. Manz,<br />
D. S. Sholl<br />
9:45 66. Inverse oxide/metal catalysts: Surface<br />
science models for fundamental<br />
studies in catalysis. J. Hrbek<br />
10:15 67. Interaction of oxygen adatom and<br />
carbon monoxide on TiO2(110) surface.<br />
J. Lee, Z. Zhang, X. Deng, D. Sorescu,<br />
J. T. Yates, C. Matranga<br />
10:35 68. Surface science models in catalysis:<br />
Thin oxide films as supports and reactive<br />
surfaces. M. Sterrer,<br />
S. Shaikhutdinov, H. Freund<br />
11:05 69. Size matters: Catalysis by gold.<br />
R. M. Lambert<br />
11:35 70. Atomic-scale view of metal alloy<br />
surface chemistry. C. Sykes<br />
12:05 71. Low-temperature hydrogenation<br />
catalysts: Theoretical predictions and experimental<br />
verification. J. G. Chen<br />
12:35 72. Atomic-scale engineering of Pt alloy<br />
catalyst surfaces using controlled oxidation-reduction<br />
cycles. T. Li, P. A. Bagot,<br />
E. A. Marquis, E. Tsang, G. D. Smith<br />
Fuel Cell Chemistry and Operation II<br />
Membranes Sponsored by FUEL,<br />
Cosponsored by CATL (probationary)<br />
20–TECH<br />
‡ Cooperative Cosponsorship<br />
Heterogeneous Catalysis for Environmental<br />
and Sustainable Energy Applications<br />
General Environmental Catalysis Sponsored<br />
by ENVR, Cosponsored by CATL<br />
(probationary)<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Surface Science of Catalysis<br />
E. I. Altman, Organizer<br />
G. Bhargava, Organizer, Presiding<br />
2:00 Introductory Remarks<br />
2:05 73. Single molecule imaging of manganese<br />
porphyrin oxidation reactions in a<br />
liquid-STM. D. den Boer, M. Li, T. Habets,<br />
P. Iavicoli, D. B. Amabilino, R. J. Nolte,<br />
A. E. Rowan, S. Speller, S. De Feyter,<br />
J. A. Elemans<br />
2:25 74. <strong>Chemical</strong> imaging and interaction<br />
quantification for catalytic materials using<br />
high-resolution atomic force microscopy.<br />
U. D. Schwarz, M. Z. Baykara,<br />
T. C. Schwendemann, H. Mönig,<br />
E. I. Altman<br />
2:55 75. Autocatalytic reduction of a Cu2O/ Cu(111) surface by CO: STM, XPS and<br />
DFT studies. F. Yang, Y. Choi, P. Liu,<br />
J. Hrbek, J. A. Rodriguez<br />
3:15 76. Chiral seeding in molecular surface<br />
assemblies studied by UHV-STM.<br />
F. Masini, N. Kalashnyk, M. M. Knudsen,<br />
K. V. Gothelf, F. Besenbacher,<br />
E. Lægsgaard, T. R. Linderoth<br />
3:35 77. Combined ambient pressure XPS,<br />
high pressure STM, and DFT study of the<br />
in situ oxidation of Pt(110) and the reaction<br />
of gas phase CO with two distinct<br />
surface oxygen species. M. E. Grass,<br />
D. Butcher, Z. Zeng, F. Aksoy, H. Bluhm,<br />
B. S. Mun, G. A. Somorjai, W. Li, Z. Liu<br />
3:55 78. Differential charging in XPS for<br />
nanomaterial and organic layer characterization.<br />
S. L. Bernasek<br />
4:25 79. Orientation and structure of hydrocarbon<br />
adsorbates at catalytically relevant<br />
vapor/oxide and liquid/oxide interfaces<br />
probed by sum frequency generation.<br />
A. M. Buchbinder, E. Weitz, F. M. Geiger<br />
4:45 Concluding Remarks<br />
Heterogeneous Catalysis for Environmental<br />
and Sustainable Energy Applications<br />
Photocatalysis Sponsored by ENVR,<br />
Cosponsored by CATL (probationary)<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Surface Science of Catalysis<br />
G. Bhargava, Organizer<br />
E. I. Altman, Organizer, Presiding<br />
9:00 80. Recent advances in the synthesis<br />
of Au-Pd colloids in the preparation of<br />
very active selective oxidation catalysts.<br />
J. A. Lopez-Sanchez, N. Dimitratos,<br />
J. M. Anthonykutty, A. F. Carley,<br />
R. C. Tiruvalam, A. A. Herzing, C. J. Kiely,<br />
D. W. Knight, G. J. Hutchings<br />
9:20 81. Vibrational spectroscopic study of<br />
low temperature CO oxidation over Au/ZnO<br />
nanoparticles. H. Noei, M. Muhler, Y. Wang<br />
9:40 82. Mechanistic studies on the nucleophilic<br />
coupling reactions on gold surface.<br />
B. Xu, R. J. Madix, C. M. Friend<br />
10:10 83. Atomic-level insight into nanogold<br />
catalysis viewed from the perspective of<br />
Au n superatoms. Y. Zhu<br />
10:30 84. First-Principles and experimental<br />
studies of the sub-nanomenter platinum<br />
atoms supported on �-alumina.<br />
C. K. Narula, X. Chen, M. G. Stocks,<br />
M. DeBusk, L. F. Allard<br />
10:50 85. Methanol reactions over metals<br />
(Pd, Pt and Au) doped ceria. N. Yi,R.Si,<br />
H. Saltsburg, M. Flytzani-Stephanopoulos<br />
11:10 86. Engineering and atomic-scale<br />
characterization of bimetallic Pd alloys for<br />
hydrogen dissociation. A. E. Baber,<br />
H. L. Tierney, J. R. Kitchin, E. H. Sykes<br />
11:30 87. Surface – subsurface interactions<br />
in hydrogen desorption from Pd.<br />
W. D. Michalak, M. Widom, J. B. Miller,<br />
D. Alfonso, B. Morreale, A. J. Gellman<br />
11:50 88. Surface structure of Pd 3Fe(111):<br />
Anomolous surface morphology and implications<br />
for electrocatalysis. X. Yang,<br />
B. E. Koel<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Surface Science of Catalysis<br />
E. I. Altman, G. Bhargava, Organizers<br />
2:00 89. High throughput study of the catalytic<br />
activity of CuPd alloys for hydrogen<br />
purification membranes. A. J. Gellman,<br />
J. B. Miller, P. Kondratyuk, S. Shukla,<br />
E. Broitman<br />
2:30 90. Heterogeneous catalysts need not<br />
be so heterogeneous: Size and shape selected<br />
transition metal nanocrystal fuel<br />
cell catalysts. C. B. Murray,Y.Kang,<br />
X. Ye, V. D. Nguyen<br />
3:00 91. Nature of excess electrons in TiO 2<br />
and their role in surface reactions.<br />
N. A. Deskins, R. Rousseau, M. Dupuis<br />
3:20 92. Solid-liquid interfacial hydrogen<br />
bond catalysis using nano structured materials<br />
metal oxides. W. Song,F.Niu<br />
3:40 93. Morphologies and reactivities of<br />
platinum and rhodium nanoparticles.<br />
D. W. Goodman, M. J. Lundwall,<br />
S. M. McClure, Z. Zhou, F. Yang<br />
4:10 94. Measuring and relating the electronic<br />
structure of alloys to their chemical<br />
and catalytic performance. S. Linic,<br />
N. Schweitzer, H. Xin, E. Nikolla<br />
4:30 95. Stark tuning of absorbed CO on<br />
fuel cell catalytic layers in operating fuel<br />
cells. I. Kendrick, E. Smotkin<br />
4:50 96. Immobilization of Mucor miehei<br />
lipase on titania mesoporous materials.<br />
Y. Martinez, M. Bellino, D. Kaplan,<br />
G. J. Soler-Illia, G. R. Castro<br />
5:10 Concluding Remarks<br />
WEDNESDAY EVENING<br />
Heterogeneous Catalysis for Environmental<br />
and Sustainable Energy Applications<br />
Sponsored by ENVR, Cosponsored by CATL<br />
(probationary)<br />
THURSDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 206B<br />
Catalyst for Energy Storage Cosponsored by<br />
FUEL and PETR<br />
J. Zheng, Organizer, Presiding<br />
9:00 97. Lithium-air battery. P. G. Bruce,<br />
S. A. Freunberger, L. J. Hardwick,<br />
Z. Q. Peng, Y. Chen<br />
9:45 98. Synthesis, characterization, and<br />
electrochemistry of high oxidation state<br />
cobalt hangman corroles for oxygen electrocatalysis.<br />
D. G. Nocera, D. D. Kiper<br />
10:15 99. Mechanistic study of water splitting<br />
catalyzed by a biomimetic dimanganese<br />
oxomanganese complex: A model<br />
for photosystem II. E. M. Sproviero,<br />
G. W. Brudvig, V. S. Batista<br />
10:45 100. Atomic simulations of heterogeneous<br />
fuel cracking catalysis.<br />
S. M. Opalka,T.H.Vanderspurt<br />
CHED<br />
Division of <strong>Chemical</strong><br />
Education<br />
C. Gauthier, J. Smist, and<br />
N. Snyder, Program Chairs<br />
OTHER SYMPOSIA OF INTEREST:<br />
Chemistry and the Environment Film<br />
Series (see CEI, Sun)<br />
The School <strong>Chemical</strong> Cleanout<br />
Campaign (SC3) Needs You (see<br />
CHAS, Mon)<br />
Formal and Informal Education<br />
Platforms for Sustainable Energy<br />
Systems (see COMSCI, Tue)<br />
Anna Jane Harrison: ACS President,<br />
Her Science and Her Legacy (see<br />
HIST, Mon)<br />
Excellence in the Undergraduate<br />
Chemistry Curriculum - A Global<br />
Perspective (see PRES, Mon)<br />
Sustainability Education (see PRES,<br />
Mon)<br />
SOCIAL EVENTS:<br />
High School – College Teachers<br />
Luncheon, 12:00 PM: Sun<br />
Reception, 5:30 PM: Sun<br />
SUNDAY MORNING<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom B<br />
High School Program<br />
S. Mitchell, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 1. Food and medicines of the future:<br />
The role of green chemistry. J. C. Warner<br />
9:20 2. Connecting candy to chemistry:<br />
Ready-to-use resources from the Journal<br />
of <strong>Chemical</strong> Education. E. K. Jacobsen,<br />
L. E. Slocum, N. J. Pienta<br />
9:55 Intermission<br />
10:10 3. ACS high school chem club program.<br />
A. LeFevre<br />
10:40 4. Chemistry of birds, carrots, oranges,<br />
pickles, and rhubarb. R. Perkins<br />
11:40 Concluding Remarks<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom B<br />
Using Technology to Enhance Learning in<br />
Organic Chemistry<br />
P. A. Janowicz, Organizer<br />
L. McClary, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 5. Turning a compressed video course<br />
into a “live” experience: Adding multimedia<br />
into organic chemistry. J. Kabrhel<br />
8:55 6. Using technology to the maximum in<br />
the teaching of chemistry. K. K. Bagga<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
9:15 7. Using personal response systems<br />
(clickers) to probe the structure-mechanism-reaction<br />
paradigm in organic chemistry.<br />
S. M. Graham<br />
9:35 Intermission<br />
9:50 8. Using web-based case studies to<br />
learn organic reaction mechanisms.<br />
K. Koenig, A. L. Smith<br />
10:10 9. “Molmodac”: A team project for the<br />
development of computational, informatics,<br />
and interpersonal skills in a secondsemester<br />
organic chemistry course.<br />
J. S. Moore, M. J. Evans<br />
10:30 Discussion<br />
10:50 Concluding Remarks<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Social Networking: The Next Generation<br />
Cosponsored by CINF and YCC<br />
L. Pence, H. Pence, Organizers<br />
L. Benedict, Presiding<br />
8:30 Introductory Remarks<br />
8:35 10. Construction of topical faculty<br />
learning communities by the Center for<br />
Workshops in the <strong>Chemical</strong> Sciences<br />
(CWCS) and the use of Drupal as a development<br />
platform. C. B. Russell,<br />
D. M. Collard<br />
8:55 11. Ebooks: A culture shift for academic<br />
libraries? B. A. Losoff<br />
9:15 12. Engaging student discussion: The<br />
role of a google jockey. L. E. Pence,<br />
E. R. Greene<br />
9:35 13. Rip-Mix-Learn (RML): Using Google<br />
Docs to create collaborative multimodal<br />
class notes. L. A. Benedict,H.E.Pence<br />
9:55 Intermission<br />
10:05 14. Smart phones, smart objects, and<br />
chemical education. H. E. Pence<br />
10:25 15. How community crowdsourcing<br />
and social networking is helping to build<br />
a quality online resource for chemists.<br />
A. J. Williams<br />
10:45 16. Chemistry of social media.<br />
S. Jensen<br />
SUNDAY AFTERNOON<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom B<br />
High School Program<br />
S. Mitchell, Organizer<br />
12:00 Introductory Remarks<br />
12:05 17. My experience (so far!) of trying to<br />
develop a drug for Alzheimer’s disease.<br />
P. Landsbury<br />
12:50 18. The curious cook: An experimental<br />
design approach to problem solving.<br />
H. McGee<br />
1:20 Intermission<br />
1:25 19. Play with your food, not your<br />
health. L. Hogue, A. Sarquis<br />
1:55 20. Spectroscopic applications for the<br />
high school chemistry classroom.<br />
D. McGraw<br />
2:25 21. Pop culture in the chemistry classroom.<br />
E. K. Mitchell<br />
2:30 Intermission<br />
2:40 22. Food science opportunties at Cornell<br />
University. R. Mitchell<br />
2:50 23. Research in the high school chemistry<br />
classroom. C. Larrabee<br />
2:55 24. FUNdamentals of food and packaging<br />
polymers can energize your chemistry<br />
teaching. L. Higgins, S. Rukes<br />
3:40 Intermission<br />
3:45 25. Trace metal elements in nutrition.<br />
A. P. Zipp<br />
4:15 Concluding Remarks<br />
Section D<br />
Seaport Hotel<br />
Constitution Room<br />
Connections to Germany and Europe:<br />
Education and Research Opportunities<br />
Cosponsored by CHED, IAC, PRES, SCTF,<br />
SOCED, WCC, and YCC<br />
M. Hoffman, Organizer, Presiding<br />
1:15 Introductory Remarks<br />
1:20 Welcome - John McKew<br />
1:25 Welcome - Michael Dröscher<br />
1:30 26. How we teach chemistry in high<br />
schools in Germany. J. Saborowski<br />
1:45 27. Ecologically benign and economically<br />
useful transformations: Research<br />
and education at the Georg-August-<br />
University Goettingen, Germany.<br />
N. Schützenmeister, L. F. Tietze<br />
2:00 28. <strong>Chemical</strong> experiments with pulsed<br />
atomic and molecular beams on the catalytic<br />
active surfaces of semiconductor<br />
heterosystems. K. Stella, D. Diesing,<br />
E. Hasselbrink<br />
2:15 29. Catalysis as a key technology for a<br />
sustainable development. S. Wang,<br />
F. Schüth<br />
2:30 Intermission<br />
2:40 Welcome - Joseph Francisco<br />
2:45 30. DAAD/RISE: Research internships<br />
in science and engineering. M. Hippchen<br />
3:00 31. ACS-IREU and Germany’s DAAD/<br />
RISE: A collaborative exchange program.<br />
L. E. Echegoyen<br />
3:15 32. Supporting chemistry research in<br />
Germany: The DFG’s funding strategy.<br />
B. Georg, M. Behnke<br />
3:30 33. Research funding opportunities in<br />
Germany for postdoctoral and experienced<br />
researchers. D. Kelly<br />
3:45 Intermission<br />
3:55 34. Developing the promise of young<br />
chemists: Projects of the German<br />
Younger Chemists’ Forum.<br />
C. Küchenthal<br />
4:10 35. NESACS/GDCh Exchange Program:<br />
Participation and organizational experiences.<br />
R. L. Napoleon<br />
4:25 36. Tenth anniversary of the German<br />
Exchange Program – personal experiences<br />
and impacts: Jens goes U.S.A.<br />
J. Breffke<br />
4:40 37. EYCN: The European Young<br />
Chemists Network. S. Toews, V. Fluxa,<br />
D. Dumitrescu, I. Vorotyntsev, H. Laavi<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom B<br />
High School Program<br />
S. Mitchell, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 38. Discrepant events workshop.<br />
S. Lantos<br />
2:10 39. Pharmacology Education Partnership:<br />
Military pharmacology. D. Krone,<br />
B. Howson<br />
2:45 40. Improve student learning with<br />
SmartPens in your classroom.<br />
A. D. Crosby<br />
3:05 Intermission<br />
3:20 41. Engaging your audience: Inspiring<br />
teachers to engage their audience<br />
through the use of multimedia and interactive<br />
demonstrations. J. Lull,<br />
J. Cucinotta<br />
3:45 42. Chemistry with vernier. J. Randall,<br />
D. Holmquist<br />
4:20 Concluding Remarks<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Social Networking: The Next Generation<br />
Cosponsored by CINF and YCC<br />
L. Pence, Organizer<br />
H. Pence, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 43. Communicating organic chemistry<br />
through the internet: Global learning<br />
communities. P. A. Janowicz<br />
1:55 44. Focusing CENtral Science: An<br />
overview of C&EN’s redesigned blog portal<br />
and its usefulness to educators.<br />
R. Pepling<br />
2:15 45. Chemistry blogging: From literature<br />
to controversy to community to. . .<br />
A. D. Finke<br />
2:35 46. Blogging: Ego trip, or sound science?<br />
Its role in chemical education and<br />
research. H. S. Rzepa<br />
2:55 Intermission<br />
3:05 47. Teaching scientific communication<br />
in pharmaceutical bioinformatics education.<br />
E. Willighagen<br />
3:25 48. Developments in chemistry resources<br />
on Wikipedia. M. A. Walker<br />
3:45 49. ChemEd DL WikiHyperGlossary.<br />
R. Belford, D. Berleant, M. Bauer,<br />
J. W. Moore, R. Hall<br />
4:05 50. Chempedia Lab: Group meeting on<br />
a global scale. R. L. Apodaca<br />
The Chemistry of Beer and Brewing<br />
Sponsored by YCC, Cosponsored by CHED,<br />
PROF, and SCHB<br />
SUNDAY EVENING<br />
Section A<br />
Seaport Hotel<br />
Lighthouse I<br />
General Posters<br />
I. Montes, Organizer<br />
7:00–9:00<br />
51. National Chemistry Week 2010: Behind<br />
the Scenes with Chemistry. A. H. Sowell,<br />
R. M. de Groot, M. Duerst, T. A. Halmi,<br />
C. Jaworek-Lopes, L. Hogue<br />
52. Chemists celebrate Earth Day 2010:<br />
“Plants: The Green Machines”. L. Avila,<br />
C. Harris, R. M. deGroot<br />
53. Join us to celebrate the International<br />
Year of Chemistry during 2011 through<br />
community outreach! I. Montes, T. Halmi,<br />
L. Hogue, C. Jaworek-Lopes,<br />
A. Jorgensen<br />
54. Communicating science: Public presentations<br />
by Science is Fun students.<br />
A. K. Turek, S. Wittkopp, R. Schreiner,<br />
B. Z. Shakhashiri<br />
55. Science in the city. S. Wittkopp,<br />
R. Schreiner, B. Z. Shakhashiri<br />
56. Chemistry as a community: Activities,<br />
outreach, and service of the Florida<br />
Southern College student affiliates chapter.<br />
M. J. Politis, J. C. Bruno,<br />
C. V. Gauthier<br />
57. ChemTeacher: An online resource for<br />
chemistry teachers from ChemEd DL.<br />
G. Bandos, J. M. Shorb, J. W. Moore<br />
58. Chemistry course for the common core<br />
on the “human journey” in a catholic university.<br />
D. A. Habboush<br />
59. Accessible chemistry to the non-science<br />
major. K. Thistle, M. Quigley,<br />
B. Datangel, A. Maffa<br />
60. Concert at chemistry: Linking science<br />
and the performing arts. J. F. Berry,<br />
B. Z. Shakhashiri, R. Schreiner<br />
61. Implementation and results of a laboratory<br />
practical examination in introductory<br />
college chemistry. S. J. Pilkenton,<br />
C. Dignam<br />
62. Pre- and post-assessment of general<br />
chemistry students. W. Burns,<br />
T. Kennon, M. Draganjac, M. Panigot,<br />
A. Ontko, H. Koizumi, R. Warby, S. Cron,<br />
B. Rougeau<br />
63. Effectiveness of guided inquiry on students’<br />
comprehension of chemistry concepts<br />
in a non-science majors’ course.<br />
A. Butler, W. Donovan<br />
64. Introduction of C4: A strategy for science<br />
laboratory instruction. C. A. Smith<br />
65. Impact of a teaching-assistant (TA) boot<br />
camp on first-year chemistry graduate<br />
students assigned to teach freshman<br />
chemistry recitation sections.<br />
R. Mitchell, E. M. Taylor, C. L. Drennan<br />
66. Teacher assistants in the chemistry lab.<br />
M. J. Anderson, K. Rugutt, J. Bulcholtz,<br />
O. Gonzalez<br />
67. ChemPRIME wiki-text: The chemistry<br />
behind your favorite subject. J. M. Shorb,<br />
E. Vitz, J. W. Moore<br />
68. Common biases in chemistry classroom<br />
teaching practices. N. J. Ronkainen<br />
69. Collaborative undergraduate research<br />
methods course. A. M. Schoffstall,<br />
S. Braun-Sand, R. M. Henry, D. J. Weiss,<br />
J. A. Canaria<br />
70. Using Independent Laboratory Access<br />
for the Blind (ILAB) tools as part of a summer<br />
science camp for students who are<br />
blind in the Caribbean. C. A. Supalo,<br />
T. E. Mallouk, H. D. Wohlers, R. A. Kreuter<br />
71. Increasing the diversity of the laboratory<br />
technician workforce through the inclusion<br />
of deaf and hard-of-hearing students.<br />
A. D. Ross, T. Pagano<br />
72. Active learning method for teaching enzyme<br />
kinetics to non-science majors.<br />
G. T. Hinckley<br />
73. Use of recyclable materials to build a<br />
groundwater tank model for classroom<br />
use. M. Larrousse, M. Watch<br />
74. Threefold representation in scientific<br />
models: Application in redox reaction.<br />
Z. Medina Torres, R. Barreto,<br />
E. L. Ortiz Nieves<br />
75. Preparation of zinc bromide using microwave<br />
technology: A simple stoichiometry<br />
experiment for the undergraduate general<br />
chemistry teaching laboratory.<br />
J. E. Horta, D. J. Foreman<br />
76. Interdisciplinary project based on the<br />
SEM-EDS analysis of iron, copper and<br />
brass artifacts excavated in southern<br />
New England. M. L. Parr, L. A. Tran,<br />
J. C. Gifford, A. H. Lehman,<br />
N. F. Bellantoni<br />
77. NO: Presenting real-world scientific research<br />
and problems in an artistic way.<br />
E. Victor, R. Schreiner, B. Z. Shakhashiri<br />
78. VIPEr: Virtual inorganic pedagogical<br />
electronic resource. E. R. Jamieson,<br />
E. Benatan, J. Dene, H. J. Eppley,<br />
M. J. Geselbracht, A. R. Johnson,<br />
B. A. Reisner, S. R. Smith, J. L. Stewart,<br />
L. A. Watson, B. Williams<br />
79. Turning X-ray vision on the “Gold Penny”<br />
activity. D. Collins, T. Narby,<br />
D. McCarthy<br />
80. Ruthenium tris-bipyridine: Laboratory experiments<br />
for instructing students in synthesis<br />
and chemical techniques.<br />
P. Rillema<br />
81. Carbon nanotube molecules effects on<br />
the crystallization and ordering behavior<br />
of liquid crystal molecules.<br />
G. Y. Georgiev, E. A. Gombos,<br />
M. B. McIntyre, P. Cebe<br />
82. Establishment of a center for the studies<br />
of curricula in chemistry and nanoscience<br />
(the “Chem Center”). A. K. Szeto<br />
83. Solubility rules and General Chemistry.<br />
P. DeGeorge, J. T. Moore, R. H. Langley,<br />
D. B. Dizon<br />
84. Analyzing pigments in tattoo inks by<br />
atomic absorption spectroscopy and thin<br />
layer chromatography. M. C. Salvi,<br />
R. E. Rose,P.M.Gordon,<br />
C. H. Jaworek-Lopes<br />
85. <strong>Chemical</strong> demonstrations: Color, light,<br />
vision, and perception.<br />
B. Z. Shakhashiri, R. Schreiner,<br />
J. A. Bell, S. Wittkopp<br />
86. Color revisited, I: Experiments and demonstrations<br />
on subtractive and additive<br />
colors of light. M. D. Duerst, K. Winter,<br />
R. J. Duerst, S. B. Duerst, R. W. Duerst<br />
87. Teaching organic chemistry using examples.<br />
C. H. Do<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
CHED<br />
TECH–21
CHED <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
88. Carbocation rearrangement in an electrophilic<br />
aromatic substitution discovery<br />
laboratory. V. Polito,C.S.Hamann,<br />
I. J. Rhile<br />
89. Introduction to multi-step synthesis in<br />
the advanced organic chemistry laboratory:<br />
The synthesis of racemic nicotine via<br />
ring closing metathesis. A. M. Hartel<br />
90. Representation of the Woodward UV<br />
Rules using a simple mathematical formula.<br />
Y. Kang,F.Kang<br />
91. Isochorismate synthase: From cloning to<br />
expression to characterization. Z. He<br />
92. Fostering learning in the undergraduate<br />
biochemistry laboratory: Supplementing<br />
experimentation with exercises that create<br />
a basis for inquiry and ignite peer discourse.<br />
M. L. Hall, D. Ulu-Vardar<br />
93. New PowerPoint materials for safety instruction<br />
in introductory laboratories.<br />
P. A. Redden<br />
94. Introducing the LEEDAR program, learning<br />
enhanced through experimental design<br />
and analysis with Rutgers: Giving<br />
high school students some insight into<br />
what it means to be a scientist.<br />
D. A. Laviska, S. M. Sparks,<br />
A. S. Goldman<br />
95. Explanation of a difference between covalent<br />
radii in hydrogen molecule and in<br />
heteroatomic hydrogen containing compounds.<br />
V. Y. Gankin, Y. V. Gankin<br />
96. Demystifying chemical bonding, chemical<br />
kinetics and catalysis. Y. Gankin,<br />
V. Gankin<br />
97. Withdrawn<br />
98. Symbiotic learning relationship: Apple<br />
iTouch connecting organic chemistry and<br />
software development students.<br />
M. Y. Tsoi, S. Dekhane<br />
Chemistry and the Environment Film Series<br />
Tara, Journey to the Heart of the Climate<br />
Machine Sponsored by CEI, Cosponsored by<br />
CHED and ENVR<br />
MONDAY MORNING<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom A<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Cosponsored by AGRO ‡ , ANYL ‡ ,<br />
BIOL ‡ , CCPA ‡ , CHAS ‡ , COLL ‡ , HIST ‡ , I&EC ‡ ,<br />
INOR ‡ , NUCL ‡ , ORGN ‡ , POLY ‡ , PRES ‡ ,<br />
SCHB ‡ , and WCC ‡ Financially supported by<br />
Graduate Student Symposium Planning<br />
Committee<br />
J. S. Silvia, J. Schnorr, Organizers,<br />
Presiding<br />
8:30 Introductory Remarks<br />
8:35 99. When science and politics meet.<br />
D. Goldston<br />
9:20 100. Engineering microbial metabolism<br />
for production of the anti-malarial drug<br />
artemisinin. J. D. Keasling<br />
10:05 Intermission<br />
10:20 101. Better things for better living<br />
through chemistry. J. B. Berkowitz<br />
11:05 102. LANL contributions to chemical<br />
research, public policy and national defense.<br />
W. S. Rees<br />
11:50 Concluding Remarks<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom B<br />
Undergraduate Research Oral<br />
Presentations<br />
22–TECH<br />
J. Miecznikowski, Organizer, Presiding<br />
‡ Cooperative Cosponsorship<br />
8:30 Introductory Remarks<br />
8:35 103. Oxidation and photochemical<br />
halogen elimination chemistry of a platinum-rhodium<br />
heterobimetallic core.<br />
T. R. Cook, B. D. McCarthy,<br />
D. A. Lutterman, D. G. Nocera<br />
8:55 104. Capillary action in a continuouslytapered<br />
narrow gap space. C. B. Kim,<br />
D. H. Waldeck, C. W. Borysenko<br />
9:15 105. Double diastereoselective, nucleophile<br />
catalyzed Aldol lactonizations<br />
(NCAL) leading to �-lactone fused carbocycles<br />
and tetrahydrofurans.<br />
K. M. Arendt, K. A. Morris, D. Romo<br />
9:35 Intermission<br />
9:50 106. Grazing angle incidence specular<br />
reflectance FT-IR characterization of the<br />
photocrosslinking of 4-vinylbenzyl thymine<br />
(VBT) and 4-vinylbenzyl trialkyl ammonium<br />
chloride (VBA) copolymers.<br />
K. Thomas, L. Searls, J. Bento,<br />
D. M. Martino, R. Gurney<br />
10:10 107. Synthesis of electrically conducting<br />
poly-2-ethylaniline microtubes having<br />
nanoscale morphology. N. Manohar,<br />
M. L. Lalli, S. P. Surwade, S. Agnihotra,<br />
S. K. Manohar<br />
10:30 108. Surface morphology and hydrophobicity<br />
of solution-cast films of polyaniline<br />
derivatives and its relationship to<br />
chain conformation in solution (solvatochromism).<br />
M. L. Lalli, N. Manohar,<br />
S. P. Surwade, S. K. Manohar<br />
10:50 Concluding Remarks<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Teaching Acid-Base Concepts in General<br />
and Organic Chemistry: Current<br />
Approaches to Improve Conceptual<br />
Understanding and Retention<br />
M. Asirvatham, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 109. Teaching acid base equlibrium in<br />
general chemistry without the Henderson–Hasselbalch<br />
equation.<br />
S. E. Van Bramer<br />
8:55 110. Melding molecular concepts of<br />
acid/base reactions with an algorithmic<br />
treatment of the data. J. C. Poe<br />
9:15 111. Misconceptions about acid-base<br />
reactions. J. D. Jensen, S. Lowery Bretz<br />
9:35 112. Pedagogical content knowledge<br />
of acids and bases of ten Mexican high<br />
school and college teachers.<br />
C. Alvarado, A. Garritz, V. Mellado<br />
9:55 Intermission<br />
10:05 113. Making the implicit explicit in acid-base<br />
instruction. J. Davenport,<br />
D. J. Yaron, M. Karabinos, J. Greeno<br />
10:25 114. Using multiple response clicker<br />
questions to improve student feedback.<br />
D. B. King<br />
10:45 115. Reinforcing acid-base concepts<br />
in organic chemistry using clickers and<br />
electronic homework. M. R. Asirvatham<br />
11:05 Intermission<br />
11:15 116. Bridging the gap: Design of interconnecting<br />
pH modules in the chemistry<br />
curriculum from general chemistry to biochemistry.<br />
S. M. Schelble, S. Bonetti,<br />
K. M. Elkins, D. Dillon<br />
11:35 117. How first-semester organic<br />
chemistry students use heuristics to employ<br />
mental models of acidity during a<br />
ranking task. L. McClary, V. Talanquer<br />
11:55 118. Assessing undergraduate students’<br />
acid-base chemistry conceptions.<br />
J. M. Duis, L. L. Jones<br />
MONDAY AFTERNOON<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom A<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Cosponsored by AGRO ‡ , ANYL ‡ ,<br />
CHAS ‡ , COLL ‡ , HIST ‡ , I&EC ‡ , INOR ‡ , NUCL ‡ ,<br />
ORGN ‡ , POLY ‡ , and PRES ‡ Financially<br />
supported by Graduate Student Symposium<br />
Planning Committee<br />
J. S. Silvia, J. Schnorr, Organizers,<br />
Presiding<br />
1:30 Introductory Remarks<br />
1:35 119. Scientist, politician, policy maker:<br />
A historical perspective. J. M. Hayes<br />
1:50 120. Federal public policy advocacy for<br />
chemists. J. Gavenonis<br />
2:35 121. A chemist in public service: From<br />
a government lab to the executive office<br />
and back. K. L. Beers<br />
3:20 Intermission<br />
3:35 122. Energy technology innovation.<br />
J. M. Deutch<br />
4:20 123. Innovation and entrepreneurship<br />
in chemistry. G. M. Whitesides,<br />
K. Mirica, C. Mace<br />
5:20 Concluding Remarks<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom B<br />
Successful Undergraduate Research<br />
Programs<br />
M. Fisher, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 124. Determination of the ionization<br />
constant of carboxylic acids using microscale<br />
freezing point depression measurements.<br />
P. Sharifi, G. Subramaniam,<br />
P. Irigoyen, P. Svoronos<br />
1:55 125. Successful undegraduate research<br />
in organic chemistry at a small liberal-arts<br />
college. M. J. D’Souza,<br />
J. L. Miller<br />
2:15 126. Undergraduate research in gasphase<br />
chemical kinetics. B. E. Holmes,<br />
G. L. Heard<br />
2:35 127. Computational Chemistry research<br />
in gas-phase reaction kinetics.<br />
G. L. Heard,B.E.Holmes<br />
2:55 Concluding Remarks<br />
3:00 128. Wilkes University Student Section:<br />
Outreach, service and fun! S. Anderson,<br />
D. Mencer<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Integrating Nanotechnology into the<br />
Chemistry Curriculum<br />
J. Montgomery, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 129. Design engineering tools for molecular<br />
gizmos: Explaining what makes<br />
“nano” different. K. Sohlberg<br />
1:55 130. Research and teaching in the<br />
nanoplasmonics. T. Seideman, L. Zhang,<br />
F. K. Amankona-Diawuo<br />
2:15 131. Hands-on nanotechnology education:<br />
An introduction to nanochemistry as<br />
part of the general chemistry curriculum.<br />
R. C. Holz, J. Ireland<br />
2:35 132. Many flavors of nano: Nanoscience<br />
for several audiences in chemistry.<br />
S. K. St. Angelo<br />
2:55 Intermission<br />
3:10 133. Introducing nanoscience concepts,<br />
techniques, and skills in the undergraduate<br />
curriculum. A. Mayol,<br />
M. Garcia, I. Rodriguez, E. Mosquera,<br />
A. Herrera, M. Gomez<br />
3:30 134. Nanotechnology experiments for<br />
general chemistry laboratory classes.<br />
D. A. Katz<br />
3:50 135. Preparation of electrically conductive<br />
polystyrene/carbon nanofiber nanocomposite<br />
films: An experiment for the<br />
undergraduate laboratory. L. Sun,H.Sue<br />
4:10 Concluding Remarks<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Agricultural and Food Chemistry<br />
Cosponsored by AGFD and SOCED<br />
N. Bakowski, Organizer<br />
2:30–4:30<br />
136. Laboratory analysis of vitamin C in prepared<br />
vegetables served in eldercare facilities.<br />
D. W. Konas, C. Garay,<br />
C. Feldman, B. Anand, J. Piemonte,<br />
E. Silverthorne, S. M. Wunderlich<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Analytical Chemistry Cosponsored by ANYL<br />
and SOCED<br />
N. Bakowski, S. Majorski, Organizers<br />
2:30–4:30<br />
137. Compositional studies of three low-FeO<br />
ordinary chondrite meteorites.<br />
J. Troiano, D. Rumble, M. L. Rivers,<br />
J. M. Friedrich<br />
138. Quantitative determination of gallic acid<br />
in tea beverages and juices using high<br />
pressure iquid chromatography.<br />
C. Casas, S. Svoronos, P. Irigoyen,<br />
P. Svoronos<br />
139. Spectrophotometric determination of<br />
the total phenol content in commercial<br />
beverages via the Folin-Ciocalteau micromethod.<br />
K. Lee, S. Svoronos, P. Irigoyen,<br />
P. Svoronos<br />
140. Probing UV-signaling pathways in<br />
plants: Identification of UV absorbing<br />
species in Arabidopsis thaliana and cucumber<br />
seedlings. C. L. Schardon,<br />
K. Meinhardt, J. R. Shinkle, M. M. Bushey<br />
141. Investigation of the binding mechanism<br />
of cysteine and homocysteine thiolactone<br />
with human serum albumin (HSA) using<br />
analytical spectroscopy. A. M. Taylor,<br />
S. O. Fakayode, W. E. Stapleton,<br />
E. F. Arhagba, M. McCoy, D. A. Pollard,<br />
A. K. Mohammed<br />
142. Conversion of secondary aliphatic<br />
amine moiety to ketone by Fe III —TAML<br />
system. A. J. Worth, D. Tshudy, L. Shen,<br />
T. J. Collins<br />
143. Liquid chromatography mass spectrometry<br />
analysis of FDA approved drugs<br />
that inhibited cancer cell growth.<br />
S. M. Mahmoud, D. M. Ramanathan<br />
144. Benzene production in commercial beverages.<br />
A. Rivera,C.A.Smith<br />
145. Contaminant analyses of commercial<br />
fish oils. E. A. Garza,C.A.Smith<br />
146. <strong>Chemical</strong> analysis of electronic cigarette<br />
smoke. G. Ayala,C.A.Smith<br />
147. Determination of acid ionization constants<br />
of cyanine dyes in water vs. methanol/water<br />
mixed solvent. S. Jeong,<br />
S. Patel, J. Miguel, Y. Shin,<br />
M. T. Mongelli<br />
148. Structure function studies of homocysteine<br />
thiolactone modified horse cytochrome<br />
c and horse myoglobin. A. Pan,<br />
E. M. Lawson, P. A. Mabrouk<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
149. Mobile NMR, FTIR and XRF of ancient<br />
roman wall paintings and mosaics at Herculaneum.<br />
B. Bluemich, A. Haber,<br />
V. Boardman, D. Souvorova, K. Ulrich,<br />
A. De Vita, B. Itin, E. Del Federico<br />
150. Semiquantitative analysis with paper<br />
analytical devices (PADs). T. Barstis,<br />
M. Parsons, C. Robakowski,<br />
M. Lieberman<br />
151. Effect of molecular characteristics on<br />
sugar recovery using in vitro microdialysis.<br />
D. O. Omire-Mayor, S. Wassink,<br />
A. Gray, W. R. LaCourse<br />
152. Determining solute concentration in<br />
shrinking microdroplets by refractive index.<br />
N. Florio, S. Lee, C. Morris,<br />
K. Giusto<br />
153. Characterization of TMOS:Acetone solgels.<br />
M. Yonz,M.B.Arnold,<br />
R. P. Crumpton, C. H. Lisse<br />
154. Analysis of metals in hookah tobacco.<br />
M. McEwan, W. E. Maelia, L. E. Maelia<br />
155. Semiconductor nanoparticle synthesis<br />
and assembly into thin films. T. Bein,<br />
H. Feckl, A. Haynes<br />
156. Detection of specific biomarkers within<br />
single cells using SERS and nanosensing.<br />
D. Graham, I. Larmour, E. Argueta<br />
157. Precipitation of nile red in aqueous solutions.<br />
B. Fox, P. Halling, C. Gillespie<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Biochemistry Cosponsored by BIOL and<br />
SOCED<br />
N. Bakowski, S. Majorski, Organizers<br />
2:30–4:30<br />
158. Metal ions binding properties of EfeO,<br />
an iron transport protein from Escherichia<br />
coli * . J. McNally,H.Yang,<br />
M. Rajasekaran, K. Watson, S. Andrews,<br />
F. Bou-Abdallah<br />
159. <strong>Chemical</strong> influences on the surface<br />
properties and life cycle characteristics of<br />
Bdellovibrio bacteriovorus. S. Bhaduri,<br />
M. Marone, M. Ferguson<br />
160. Cellular focus of the C. elegan bec-1<br />
autophagy gene. V. Young, A. Ruck,<br />
A. Melendez<br />
161. Elucidation of the estrogenicity and<br />
mechanism of action of lavender oil.<br />
B. C. Covington,M.K.Mann<br />
162. Characterization of esterase activity<br />
from the bacteria, Francisella tularensis,<br />
the causative agent of tularemia.<br />
L. A. Weston, R. J. Johnson<br />
163. Antibiotic resistance in bacteria from<br />
antibiotic-free poultry flocks.<br />
M. P. Labare, M. Labare, L. Takacs,<br />
H. Butler, E. Yess, C. Butler,<br />
D. E. Riegner<br />
164. Discovery of novel peptidic ligands for<br />
sickle cell hemoglobin. J. J. Henle,<br />
B. B. Brennan<br />
165. Role of AGG interruptions in modulating<br />
the rate of duplex formation in CGG/CCG<br />
trinucleotide repeat sequences. M. Wu,<br />
D. Jarem, S. Delaney<br />
166. Withdrawn<br />
167. Effects of trinucleotide repeat length on<br />
the mechanism of hairpin-duplex conversion.<br />
M. Griffin, A. Avila-Figueroa,<br />
S. Delaney<br />
168. Buffer and temperature dependence of<br />
alkaline phosphatase activation by trifluoroethanol.<br />
J. Kelly, L. Webb, E. Csuhai<br />
169. investigation into direct solar fuels from<br />
algae for Caribbean island communities.<br />
J. Ho, H. Kuar, A. Mahmut, D. Moscoso,<br />
W. Scherzinger, B. Teasdale,<br />
M. Mongelli<br />
170. Microwave assisted solid state<br />
polypeptide synthesis. C. Gemski,<br />
C. Soydara, J. C. Williams, Jr.<br />
171. Arylphosphonium salts conjugated to<br />
flourescent markers. A. Amer, J. Solares,<br />
S. Spinette, J. C. Williams, Jr., S. Spinette<br />
172. Withdrawn<br />
173. Synthesis and cross-linking of 3-thio-4hydroxybutanoic<br />
acid to develop anti-<br />
GHB ELISA. F. Wang, K. Bendinskas<br />
174. Search for synthesizable selective estrogen<br />
receptor modulators using<br />
eHits®Lightning on a Playstation-3.<br />
S. Morgan, J. C. Williams, Jr.<br />
175. pH-Dependent release kinetics of a<br />
PEGylated protein from a nano hydroxyapatite-coated<br />
poly(caprolactone fumarate)<br />
2D film. D. H. Kwak,H.H.Pham,<br />
S. Saurabh, J. Kim, J. O. Hollinger<br />
176. Determination of substrate specificity of<br />
two esterases from a thermally stable<br />
bacteria using fluorescence. M. Hedge,<br />
J. Johnson<br />
177. Evaluation of antioxidant properties of<br />
syringaldehyde-based tetra-phenolic antioxidant.<br />
K. S. Carlson, C. Y. Lee,<br />
A. Sharma, J. L. Nelson, S. K. Upadhaya,<br />
J. Cheong<br />
178. Protein sequence conservation in DNA<br />
repair protein Trex2. M. Valenciana,<br />
P. Hasty, S. M. Volk<br />
179. Metal ion-nucleotide interactions.<br />
B. D. Browne, B. P. Smith, W. Lahar<br />
180. Protoporphyrin IX and metallated protoporphyrin<br />
IX dose dependent effects on<br />
Leishmania. M. L. Beio, K. D. Droege,<br />
A. Carcu, V. H. Nguyen, J. D. Hooker,<br />
D. L. Cedeño, M. A. Jones<br />
181. Proteomic analysis of a NOS-knockout<br />
mutant of Bacillus subtilis.<br />
A. M. Pinkham, T. D. Kim<br />
182. Post-transcriptional modification of<br />
“rare” tRNAs. T. Riffelmacher,<br />
B. Addepalli, P. A. Limbach<br />
183. Detection of binding partners to pancreatic<br />
cancer biomarkers. G. A. Weiss,<br />
J. A. Arter, C. M. Overstreet, M. Fricke,<br />
R. M. Penner<br />
184. Biosynthesis of homocysteine from methionine<br />
to cysteine: Nuclear magnetic<br />
resonance studies. R. L. Blanchard,<br />
T. C. Brady, J. J. Mitnick<br />
185. Estradiol and its metabolites: Absorption<br />
and spectral studies lend insight into<br />
their role in breast cancer. C. M. Conroy,<br />
T. C. Brady, J. J. Mitnick<br />
186. Methylation of homocysteine to methionine<br />
by 5-methyltetrahydrofolate: Absorption<br />
spectral studies. M. P. Dziubina,<br />
T. C. Brady, J. J. Mitnick<br />
187. Growth inhibition of neoplastic breast<br />
cells by means of retinoids and tamoxifen.<br />
M. Lukaszewicz1,T.C.Brady,<br />
J. J. Mitnick<br />
188. Reduction of homocysteine levels by<br />
rapid conversion of homocysteine to methionine<br />
via methylation. B. R. Dempsey,<br />
T. C. Brady, J. J. Mitnick<br />
189. Analysis of complex formation in the E.<br />
coli mismatch repair system. N. Morante,<br />
I. Winkler, R. Heinz, A. Marx, P. Friedhoff<br />
190. Production and characterization of hapten<br />
modified DNA origami nano-scaffolds<br />
used as complex ligands in cell signaling.<br />
J. McCracken, D. Hautzinger,<br />
K. M. Müller<br />
191. Function of sialylation in the nervous<br />
system. T. Zimmermann, E. Repnikova,<br />
K. Koles, M. Nakamura, R. Islam,<br />
M. Altmyer, M. Zoran, V. Panin<br />
192. Probing the allosteric site of the<br />
Agrobacterium tumefaciens ADPGlucose<br />
pryrophosphorylase. N. Boehmer,<br />
B. Jacobson, M. Matsui, A. Orry,<br />
C. R. Meyer<br />
193. Sample preparation and matrix-assisted<br />
laser desorption/ionization mass<br />
spectrometry (MALDI-MS) measurement<br />
for intact protein profiling (IPP) of bacterial<br />
species. S. Laurer, D. Bozinovski,<br />
J. Seifert, M. von Bergen<br />
194. Rapid release of iron from ferritin by<br />
BHT chelate ligands. J. McNally,<br />
X. X. Liu, A. Melman, F. Bou-Abdallah<br />
195. Characterization of iron oxidation and<br />
mineral core formation in recombinant<br />
heteropolymer ferritins. B. Cooppe,<br />
J. McNally, P. Santambrogio, S. Levi,<br />
N. D. Dennis, F. Bou-Abdallah<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters <strong>Chemical</strong><br />
Education Cosponsored by SOCED<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
196. Undergraduate chemistry experiment: A<br />
study of the thermal properties of a binary/eutectic<br />
alloy of Sn-Pb using differential<br />
scanning calorimetry. D. Clark,<br />
R. P. D’Amelia, W. Nirode<br />
197. Refractive index of organic liquids measured<br />
at various temperature using a laser<br />
pointer. E. Yang, E. Choi, J. H. Shin<br />
198. Determination of acid and base concentrations<br />
using a laser pointer: Refractive<br />
index vs. concentration. R. Cho,<br />
E. Yang, J. H. Shin<br />
199. Determination of caffeine content in energy<br />
drinks by high pressure liquid chromatography.<br />
X. Ye,P.Irigoyen,T.Xu<br />
200. Isothermal titration calorimetry studies<br />
of Ca 2� and Mg 2� binding to EDTA.<br />
H. Root, L. C. O’Brien<br />
201. Developing an unknown Diels-Alder<br />
laboratory. L. E. Blair,C.Y.Chung,<br />
P. M. Gordon, C. H. Jaworek-Lopes<br />
202. DNA isolation and characterization experiments<br />
for the first-year organic chemistry<br />
laboratory. N. Sardar,<br />
B. Montalbano, J. Verdis<br />
203. Greening up the introductory chemistry<br />
lab: An undergraduate assessment and<br />
development project. M. L. Brulotte,<br />
E. J. Brush<br />
204. Evidence for a standard curriculum in<br />
undergraduate organic chemistry research.<br />
R. L. Miller, C. D. Street,<br />
P. A. Mabrouk<br />
205. “Did you smell that?”: Exploring students’<br />
predictions of perfume diffusion in<br />
air. M. Escriu-Sune, M. Stains, H. Sevian<br />
206. Temperature dependence of electrochemical<br />
cell EMF: An environmentally<br />
friendly physical chemistry laboratory experiment.<br />
E. Argueta,D.K.Lewis<br />
207. Potassium organotrifluoroborates: Useful<br />
reagents for Suzuki cross-coupling reactions<br />
that undergraduate students<br />
should know. J. K. Murray,C.N.Cipolla<br />
208. UPR-Cayey Chemistry Circle: Preventing<br />
and combating AH1N1.<br />
A. M. Suárez-Márquez,<br />
M. Y. Cortés-Cartagena,<br />
W. Resto-Otero<br />
209. Green chemistry laboratory activities:<br />
Comparative terrestrial ecotoxicology of<br />
road salts and common alcohols.<br />
T. A. Crocker, I. J. Levy,<br />
T. J. Swierzewski<br />
210. Partnerships between chemistry departments<br />
and the community: Green<br />
chemistry activities for homeschooled<br />
high school students. A. A. Demme,<br />
G. A. Eilers, I. J. Levy, C. Strnad<br />
211. Further studies on green crossed aldol<br />
condensation reactions of trans-cinnamaldehyde<br />
and derivatives. A. J. Belli,<br />
G. J. Molta,P.M.Gordon,<br />
C. H. Jaworek-Lopes<br />
212. Epoxy synthesis and strength testing in<br />
the first-year undergraduate laboratory.<br />
A. Fusco, P. Mabrouk<br />
213. Modeling biochemical pathways using<br />
Vensim ® : The Krebs tricycle.<br />
D. K. Otachliska, S. G. Desjardins<br />
214. Investigation of transition metal-catalyzed<br />
[2�2�2] cycloaddition reactions for<br />
the preparation of highly substituted benzenes:<br />
Useful teaching tools for undergraduate<br />
organic chemistry.<br />
J. K. Murray, E. Hewlett<br />
215. Total synthesis project in second semester<br />
organic chemistry laboratory.<br />
A. G. Burn, J. W. Baillargeon,<br />
S. J. Popham, M. R. O’Brien,<br />
M. C. Kittredge, K. W. Kittredge<br />
216. Inquiry-guided synthesis of novel anticancer<br />
chalcones. E. Cho, A. Abikoye,<br />
J. K. Rugutt, M. Anderson, M. Frazier<br />
217. Burning bridges in the biochemistry laboratory:<br />
Effects of reducing disulfide<br />
bonds on protein structure through HPLC<br />
analysis. J. G. Dickinson,<br />
A. F. Charlebois<br />
218. Mixing chemistry and adult-learners: A<br />
powerful reaction. A. Decatur,<br />
S. M. Schelble<br />
Section I<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Environmental Chemistry Cosponsored by<br />
ENVR and SOCED<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
219. Analysis of commercial discharges of<br />
various pollutants: A DEP industrial pretreatment<br />
program internship.<br />
G. Kouloumbes, P. Meleties, F. Jacques,<br />
P. Caroll, P. Svoronos<br />
220. Determination of the chlorine residual in<br />
water by the DPD. G. Song, P. Meleties,<br />
F. Jacques, P. Svoronos<br />
221. Summer internship at New York State’s<br />
Division of Environmental Protection: An<br />
application of what I learned in class to<br />
the real world. K. Lee, P. Meleties,<br />
F. Jacques, P. Svoronos<br />
222. Detection of nitrofuran metabolites in<br />
imported shrimp: An internship experience<br />
at the Food and Drug Administration.<br />
T. Fitzgerald, L. Graham, M. Fazio<br />
223. High pressure synthesis of water-splitting<br />
oxynitrides. P. Sharifi, W. Woerner,<br />
L. Ehm<br />
224. Effect of outdoor smoking on an indoor<br />
environment: A Brookhaven National<br />
Laboratory experience. C. Casas,<br />
J. Heiser<br />
225. Synthesis of imidazolium and pyrrolidinium<br />
ionic liquids for cellulose dissolution.<br />
F. Payen, S. Boursiquot,<br />
S. Lall-Ramnarine, M. Thomas,<br />
J. F. Wishart<br />
226. Synthesis and characterization of dialkylphosphate<br />
ionic liquids. M. Jalees,<br />
A. Castano, F. Payen, S. Boursiquot,<br />
T. Imtiaz, S. Lall-Ramnarine, M. Thomas,<br />
J. F. Wishart<br />
227. Effect of branched alkyl chains on the<br />
dynamical properties of ionic liquids.<br />
S. Ramati, K. Kerr, S. Lall-Ramnarine,<br />
J. F. Wishart<br />
228. Synthesis of eco-friendly plasticizers<br />
using curcumin di-esters. J. A. Saltos,<br />
K. Raja<br />
229. Ionic liquid based aqueous biphasic<br />
systems for the removal of dyes. M. Dilip,<br />
K. Dusoe<br />
230. Chemistry of “green” cleaners. M. Dilip,<br />
B. Spencer<br />
231. Comparative study of heavy metal ion<br />
adsoption by the ashes of local tree<br />
leaves: Oriental plane and common horse<br />
chestnut. E. Kaya, U. Erkirli,<br />
R. Celenligil Cetin, C. Z. Cermen<br />
232. Bacterial degradation of bisphenol A in<br />
the presence of various metal ions.<br />
A. Munis, R. Celenligil Cetin,<br />
C. Z. Cermen<br />
233. Analysis of microplastics in Corpus<br />
Christi’s marine environment. S. Garza,<br />
C. A. Smith<br />
234. Environmental implications and byproduct<br />
conversion of oil shale semicoke.<br />
B. A. Datangel, I. Kulaots, J. L. Goldfarb<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
CHED<br />
TECH–23
CHED <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
235. Phosphate source-sink dynamics in a<br />
tidal freshwater ecosystem.<br />
A. M. Cardamone, D. Vasudevan<br />
236. Non-linear sorption of aromatic amines<br />
to aluminosilicate clays. T. A. Arey,<br />
D. Vasudevan<br />
237. Investigation of the SHArK (Solar Hydrogen<br />
Activity Research Kit) printing<br />
pattern with handheld X-ray fluorescence<br />
spectrometer. S. Fields,<br />
J. Joshua Thomas, A. Fillinger<br />
Section J<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Geochemistry Cosponsored by GEOC and<br />
SOCED<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
238. Leaching of arsenic from CCA-treated<br />
wood in a suburban setting: Field and<br />
spectroscopic study. T. M. Beg, J. Wu,<br />
S. Tjiong, Y. Tang<br />
Section K<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Inorganic Chemistry Cosponsored by INOR<br />
and SOCED<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
239. Determination of the molecular weight<br />
of a solute using microscale freezing<br />
point depression measurements.<br />
S. Zhavian, G. Subramaniam, P. Irigoyen,<br />
P. Svoronos<br />
240. Synthesis, characterization, and ion-exchange<br />
properties of metal-doped silicotitanate<br />
materials. C. Alexander,<br />
N. Genovia, J. R. Houston<br />
241. Metal-containing molecular wire candidates:<br />
Synthesis and characterization.<br />
K. Kush, A. Brooks, C. R. de Denus<br />
242. Activation of molecular nitrogen using<br />
Mo complexes with tris(phosphino)silyl ligands.<br />
A. J. Ingram, H. Broda, F. Tuczek<br />
243. Towards nanostructured photovoltaic<br />
devices based on ordered valve metal<br />
oxide-nanotubes. X. Van Meerbeek,<br />
A. Birkel, D. Koll, W. Tremel<br />
244. Multicationic organometallic dendrimers:<br />
Synthesis and intra- and intermolecular<br />
NMR characterization. R. Cordero,<br />
G. Proni, C. Zuccaccia, A. Macchioni<br />
245. Real structure and phase change properties<br />
of thermoelectric chalcogenides.<br />
M. Schneider, O. Oekler, L. K. Sposato<br />
Section L<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Medicinal Chemistry Cosponsored by MEDI<br />
and SOCED<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
246. Repurposing FDA-approved drugs as<br />
novel cancer therapeutics. J. John,<br />
S. Mahmoud, W. Dong, K. Bednarz,<br />
L. Pettit, J. I. Fasick<br />
24–TECH<br />
‡ Cooperative Cosponsorship<br />
Section M<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Organic Chemistry<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
247. Studying low-temperature properties<br />
and energy content of new biodiesels derived<br />
from oils of plants growing in Northern<br />
Wisconsin and Minnesota.<br />
J. W. Lane, K. Hukriede, D. Koirala,<br />
A. Stewart, M. A. Waxman<br />
248. Synthesis of ketone-containing N-alkyl<br />
pyridones via gold(III)-catalysis.<br />
B. M. Klepser, N. A. Romero,<br />
C. E. Anderson<br />
249. Synthesis of �-iodo N-alkenyl pyridones<br />
bearing nitrogen substituents.<br />
G. S. Snapper, C. E. Anderson<br />
250. Synthesis of single geometric isomers<br />
of oxime ethers through palladium-catalyzed<br />
cross-coupling reactions.<br />
A. Bordelon, P. Flowers, J. Rhodus,<br />
A. Pandey, M. Lanier, J. Dinser,<br />
D. D. Dolliver, A. S. McKim<br />
251. Synthesis of N-alkoxyimidoyl tosylates.<br />
J. Rhodus, A. Pandey, A. Bordelon,<br />
P. Flowers, J. Dinser, M. Lanier,<br />
D. D. Dolliver, A. S. McKim<br />
252. Synthesis and characterization of blue<br />
light-emitting molecules for application in<br />
OLED technology. E. Bradic,C.Pharr<br />
253. Synthesis of carbazole-centered blue<br />
light-emitting organic molecules for use<br />
in organic light-emitting diodes. C. Nicka,<br />
C. Pharr<br />
254. Biocompatible boronic acid polymers<br />
prepared by atom transfer radical polymerization.<br />
Y. Lim, J. N. Cambre, D. Roy,<br />
B. S. Sumerlin<br />
255. Cyclooctyne modification of oligonucleotides<br />
for strain-promoted “click” bioconjugation.<br />
I. S. Marks, K. J. Landmark,<br />
J. Kang, T. Taton<br />
256. Reactivity of tris(trimethylsilyl)phosphite:<br />
Synthesis of bisphosphonate derivatives<br />
of �-alanine. A. Davalos, L. Vargas<br />
257. Computational studies of arsenate ester<br />
formation and hydrolysis in water and in<br />
aprotic solvents. S. Refua, J. Verdis<br />
258. Withdrawn<br />
259. Electroreductive cyclization of methyl<br />
cinnamate in the presence of nickel(II)<br />
salen: A mechanistic study.<br />
K. R. England, J. A. Miranda<br />
260. Withdrawn<br />
261. Computational and experimental studies<br />
of the reaction of chloroformates and<br />
chlorothioformates with tris(trimethylsilyl)phosphite.<br />
B. Shin, L. Vargas,<br />
J. Verdis<br />
262. Synthesis, colloidal, and anti-microbial<br />
studies on bicephalic (double-headed)<br />
amphiphiles. D. C. Warnock,<br />
K. L. Simmons, C. R. Schwantes,<br />
D. C. Flaherty, J. A. Willcox, R. W. Davis,<br />
J. E. Irby, K. P. Minbiole, K. Seifert,<br />
K. L. Caran<br />
263. Solid reduction of ketones using sodium<br />
borohydride/boric acid with chiral<br />
reagents. V. Liu, K. Thomas,<br />
D. Bourassa, U. Aleknaite, B. Yang,<br />
R. Gurney, N. Lee*<br />
264. Asymmetric [2�2] photodimerization<br />
crystal reactions. J. D. Wiseman,<br />
A. J. Bolokowicz, K. A. Wheeler<br />
265. Photoreactive crystalline cinnamoylsulfonamide<br />
racemates. A. E. Egan,<br />
S. A. Reeb, S. H. Malehorn, K. A. Wheeler<br />
266. Crystal reactions using self-assembled<br />
isocoumarin scaffolds. S. T. Karlson,<br />
K. A. Wheeler<br />
267. Kinetics of methylene blue release from<br />
weak polyelectrolyte multilayer films.<br />
R. T. Buckley, T. S. Durst,<br />
M. C. Kittredge, K. W. Kittredge<br />
268. Ring-contraction of benzazepine to<br />
quinoline. J. Baltonado, S. Karimi<br />
269. Electronic effects in the Kulinkovich hydroxycyclopropanation.<br />
T. Neuman,<br />
P. Pelphrey<br />
270. Microwave acceleration of trizaole synthesis<br />
by “click” chemistry. J. Hicks,<br />
J. C. Williams, Jr.<br />
271. Microwave polymerization to make antibiotic<br />
polymers. L. A. Crumbie,<br />
J. C. Williams, Jr., A. Amer<br />
272. Microwave acceleration of phosphonium<br />
salt synthesis and esterification reactions.<br />
A. Amer,L.A.Crumbie,<br />
J. C. Williams, Jr.<br />
273. Computational and experimental study<br />
of reductive amination of modified Ritter<br />
reaction products. D. Vasilchuk,<br />
C. Kellen-Yuen<br />
274. Efficient synthesis of (L)-4-fluorotryptophan.<br />
D. W. Konas, D. Seci, S. R. Tamimi<br />
275. Green synthesis of (E)-10,13-dimethyl-<br />
17-(6-methylheptan-2-yl)-2,3,4,7,8,9,10,<br />
11,12,13,14,15,16,17-tetradecahydro-<br />
1H-cyclopenta[a]phenanthren-3-yl 6-(4-<br />
(3-(4-methoxyphenyl)acryloyl)phenoxy)<br />
hexanoate. S. R. Malvaso,L.J.Tucker<br />
276. Investigations into the aza-conjugate<br />
addition of sulfonamides to 2-vinyl pyridine.<br />
R. T. Benning, D. L. Jacobs<br />
277. Design, synthesis, and evaluation of<br />
novel cyanoacrylamide polymers as<br />
drug-releasing bioadhesives.<br />
M. B. Elbaum,D.L.Jacobs<br />
278. Guided inquiry into the synthesis of bromo-chalcone<br />
analogs. E. Charobee<br />
279. Synthesis of symmetric ferrocene derivatives<br />
from 1,1�-diacetylferrocene.<br />
N. M. Lafontaine Vargas,<br />
M. R. Otano-Vega,<br />
R. Cardona-Couvertier,<br />
I. Montes-Gonzalez,<br />
A. Guadalupe-Quinones<br />
280. Organic synthesis of natural products:<br />
Lipoxin analogs. J. Pietruszka, A. Plate,<br />
S. Strong<br />
281. Polystyryl-BEMP as an efficient recoverable<br />
and reusable catalyst under solvent-free<br />
conditions. D. Lanari, J. Longo,<br />
L. Vaccaro<br />
282. Short C-C bonds. G. Markopoulos,<br />
M. Levin, H. Hopf<br />
283. Synthesis of photoswitchable N-heterocyclic<br />
carbenes. M. Stevens,<br />
E. O. Johnsen, S. Hecht<br />
284. Synthesis and biological studies of new<br />
gold(I) carbene complexes. K. Johnson,<br />
A. Meyer, I. Ott<br />
285. Magnetic nanoparticles with biofunctional<br />
shells. A. M. Schmidt, G. Marten,<br />
C. Ernst<br />
286. New routes to isoindolines by highly efficient<br />
palladium-catalysts. E. R. Jarvo,<br />
F. J. Williams, M. Dörr<br />
287. Total synthesis of attenol A. J. Colón,<br />
L. Tomas, D. Gueyrard, P. Goekjian<br />
288. Investigating the a-glucosidase inhibitory<br />
activity of some hydroxylated [13]macro-dilactones.<br />
D. Terwilliger,<br />
M. Martin, R. Ramsubhag, M. W. Peczuh<br />
289. Soft scorpionates of precious metals.<br />
L. Darby, J. Reglinski, M. Spicer<br />
290. Total synthesis of broussonetine H and<br />
N. J. Tom, B. Bourdon, L. Tomas,<br />
D. Gueyrard, P. Goekjian<br />
Section N<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Nanotechnology Cosponsored by SOCED<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
291. Antimicrobial activity of nano-silver in<br />
tris[3-(trimethoxysilyl)propyl] isocyanourate<br />
(TTPI) gels. M. Chauhan,<br />
M. Tawde, E. Kim, C. D. Echeverri,<br />
R. Lee<br />
292. Porous spheres of poly(o-toluidine) obtained<br />
by post-synthetic exposure to<br />
base. M. Murillo, D. M. Sarno<br />
293. Systematic study on the acid purification<br />
and functionalization of single-walled<br />
carbon nanotubes. E. Ahn,<br />
T. Hemraj-Benny<br />
294. Fabrication of p-n diodes using electrospun<br />
inorganic tin oxide nanofibers and<br />
organic semiconductors.<br />
K. V. Carrasquillo, N. J. Pinto, R. Agarwal<br />
295. Interaction of gold nanoparticles with<br />
nanofibers of polyaniline and sulfonic<br />
acid-substituted analogs. B. Persaud,<br />
M. M. Maye, D. M. Sarno<br />
296. Biosynthesis and characterization of<br />
colloidal metal nanoplates and nanoparticles.<br />
S. K. St. Angelo, E. L. Hartz<br />
297. Graphene growth using chemical vapor<br />
deposition. J. Fleming, M. Kelly, H. Xing<br />
298. Encapsulation of herbal components in<br />
glycodendrimers: Computational simulations<br />
and analyses. P. Chhetri<br />
299. Synthesis of large area graphene by<br />
chemical vapor deposition.<br />
N. Kawamoto, M. Berck, D. Singer,<br />
M. Chen, Z. Luo, A. Johnson<br />
300. Using FTIR to experimentally determine<br />
the mechanism of alcohol oxidation using<br />
Au, Pd, and bimetallic AuPd nanoparticle<br />
catalysts. R. Seepersad, A. Santa,<br />
J. M. Petroski<br />
301. Microchambers for microtubule assembly.<br />
R. Horvath, C. Breisch, M. Mahon,<br />
H. Goodson, M. Lieberman<br />
302. Synthesis of gold nano-shell by in situ<br />
generation of gold seeds on silica core.<br />
E. Grzincic, R. Wallen, B. Q. Li,<br />
K. Bandyopadhyay<br />
Section O<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Physical Chemistry Cosponsored by PHYS<br />
and SOCED<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
303. Intracavity laser absorption spectroscopy<br />
of platinum sulfide in the near infrared.<br />
K. Handler, L. C. O’Brien<br />
304. Using SERRS and visible extinction<br />
spectroscopy to study copper chlorophyllin.<br />
B. Karr, C. S. Schnitzer,<br />
P. G. House<br />
305. Formation energetics and reaction<br />
mechanisms of iron(II) and plutonium(IV)<br />
hydroxamate complexes. L. Kemp,<br />
J. L. Sonnenberg<br />
306. Formation energetics of uranyl hydroxamate<br />
complexes. B. Miller,<br />
J. L. Sonnenberg<br />
307. Kinetics of the thermal isomerization<br />
and decomposition reactions of gaseous<br />
ethylcyclopropane. H. Yi,D.K.Lewis,<br />
A. B. Campbell, E. R. Klein, B. L. Kalra<br />
308. Photochemistry of the liquid-vapor interface<br />
of saltwater. B. Ramos,<br />
J. Hasychak, H. Bluhm, M. J. Krisch<br />
309. Linear and cyclic molecular models of<br />
siloxanes: A DFT study of the Si-H bond<br />
activation. D. Sangobanwo, M. D. Bojin<br />
310. Arginine’s conformers in variable pH: A<br />
QM investigation. A. Esa,M.D.Bojin<br />
311. Exploration of the adsorption of<br />
K 6CoSiW 11O 39 to aminosilane-modified<br />
silica surfaces using EWCRDS.<br />
M. K. Robinson, M. A. Everest<br />
312. Preparation and characterization of silica<br />
functionalized with amino gradients.<br />
M. L. Cameron, M. A. Everest<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
313. Debundling and characterization of<br />
SWNT functionalized with Zn-phthalocyanine<br />
oligomers. K. Lawrence,<br />
J. Bartelmess, J. J. Cid, T. Torres,<br />
D. M. Guldi<br />
314. Quantum-mechanical evaluation of the<br />
dielectric properties of phosphonic-acid<br />
based self-assembled monolayer used as<br />
surface modifiers. F. Thöle,H.Li,<br />
V. Coropceanu, J. Brédas<br />
315. Nature of active oxygen stored on<br />
highly dispersed Au catalysts.<br />
D. Widmann, J. Behm, E. Hocking<br />
Section P<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Undergraduate Research Posters<br />
Polymer Chemistry Cosponsored by POLY<br />
and SOCED<br />
N. Bakowski, S. Majorski, B. Aronson,<br />
Organizers<br />
2:30–4:30<br />
316. Modeling a system of biomimetic microcapsules.<br />
J. Carpenter,<br />
A. Bhattacharya, A. C. Balazs<br />
317. Phenolic polymerization using Fe III -<br />
TAML system. K. E. Entwistle,<br />
D. Tshudy, T. J. Collins<br />
318. Alternative recycling of post-consumer<br />
PLA waste at a molecular level.<br />
C. Cacoq, A. E. Taylor, N. E. Lee,<br />
R. Gurney<br />
319. Hyperbranched perfluorinated polymers<br />
as proton exchange membrane materials.<br />
A. Mueller, S. K. Upadhaya<br />
320. Post-polymerization functionalization<br />
for the preparation of well-defined polymeric<br />
materials. P. Theato, P. Schattling,<br />
J. Schual-Berke<br />
Wheres the Good Stuff? Consumer Health<br />
Information, and Social Networking<br />
Resources and Services Sponsored by CINF,<br />
Cosponsored by CHED<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
J. Smist, Organizer<br />
8:00–10:00<br />
41, 51, 52, 53, 54, 55, 57, 59, 60, 63, 65, 72,<br />
74, 77, 78, 84, 85, 86, 92. See previous<br />
listings.<br />
348, 350, 371, 376, 377, 395, 409, 423. See<br />
subsequent listings.<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Successful Student Chapter Posters<br />
N. Bakowski, Organizer<br />
8:00–10:00<br />
56. See previous listings.<br />
TUESDAY MORNING<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom A<br />
Forensics Chemistry: Its Impact on the<br />
Education of Recent Generations of<br />
Undergraduate Students<br />
L. Kaplan, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 321. Forensic science: Its impact on<br />
the education of undergraduate science<br />
students. L. J. Kaplan<br />
8:55 322. Forensic chemistry education:<br />
What do crime laboratory directors want<br />
from universities graduating the next generation<br />
of forensic scientists?<br />
B. A. Fisher<br />
9:35 323. Forensic science and forensic<br />
chemistry programs at Sam Houston<br />
State University. P. A. Loeffler,<br />
D. L. Williams, J. C. Yu<br />
9:55 Intermission<br />
10:10 324. Tying together a multiple-discipline,<br />
team-taught forensic science<br />
course. M. B. Wells, J. Bartlett, T. Metz,<br />
C. Starita<br />
10:30 325. Making the next generation better:<br />
Emphasizing the “Chemistry” in forensic<br />
chemistry. S. Bell<br />
11:10 326. Forensic chemistry or instrumental<br />
analysis. D. D. Ensor, G. Mullins<br />
11:30 327. Some positive effects of forensic<br />
science on chemistry students.<br />
H. A. Harris<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom B<br />
Advances in Teaching<br />
Analytical and Inorganic Chemistry<br />
A. Falke, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 328. Reinventing analytical chemistry<br />
instruction at a public primarily undergraduate<br />
university. D. A. Nivens,<br />
J. Smith, E. Werner, C. Padgett<br />
8:55 329. Using (nearly) real problems to<br />
teach the analytical process: Student<br />
feedback and perceptions. S. Burris<br />
9:15 330. ANA-POGIL: Bringing process oriented<br />
guided inquiry learning to analytical<br />
chemistry. J. M. Lantz,R.Cole<br />
9:35 331. POGIL in the Instrumental Analysis<br />
class. A. Falke<br />
9:55 Intermission<br />
10:10 332. Analysis of performance-enhancing<br />
drugs in sports. T. C. Werner<br />
10:30 333. Simple method to determine the<br />
effects of electrolytes on the critical micelle<br />
concentration of sodium-n-dodecylbenzenesulfonate.<br />
M. Levine, L. Avila,<br />
T. Gani<br />
10:50 334. Lake Nakuru: A web-based case<br />
study to introduce pesticide analysis and<br />
GC-MS in the analytical curriculum.<br />
A. G. Cavinato<br />
11:10 335. Making connections to inorganic<br />
chemistry: The integrated lab experience<br />
at Merrimack College. A. L. Fernandez,<br />
C. B. McGowan, K. C. Swallow<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Advances in Teaching<br />
Organic Chemistry<br />
M. Boucher, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 336. Innovative studio-based approach<br />
to teaching organic chemistry.<br />
C. Collison, J. A. Cody, C. Stanford<br />
8:55 337. Using relationship analogies in<br />
teaching organic chemistry. F. Damkaci<br />
9:15 338. Use of electron energies and the<br />
Toulmin Argumentation Model to help<br />
sophomore organic students develop understanding<br />
of concepts and effective explanations<br />
for their conclusions. R. Libby<br />
9:35 339. Engaging students in science<br />
courses by re-visiting the Thayer method.<br />
R. L. Pennington, D. P. Pursell,<br />
J. C. Sloop<br />
9:55 Intermission<br />
10:10 340. Guided research project for the<br />
organic chemistry lab. K. M. Specht<br />
10:30 341. Undergraduate laboratory renaissance<br />
for organic chemistry.<br />
R. Gurney, N. Lee<br />
10:50 342. Choose your own (TLC) adventure:<br />
Designing a chromatography laboratory<br />
for first-semester organic students.<br />
M. A. Boucher<br />
11:10 343. Essential oil laboratory: Introduction<br />
to distillation, GC, GC/MS, and refractometry.<br />
C. McCartha<br />
11:30 Intermission<br />
TUESDAY AFTERNOON<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom A<br />
Forensics Chemistry: Its Impact on the<br />
Education of Recent Generations of<br />
Undergraduate Students<br />
L. Kaplan, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 344. Forensic science at Fairfield University.<br />
A. S. Harper-Leatherman,<br />
J. R. Miecznikowski<br />
1:55 345. The National Academy of Sciences<br />
Forensic Sciences Report and forensic<br />
science education: Is a midcourse<br />
correction needed? J. A. Siegel<br />
2:35 346. Curricular and career changes<br />
catalyzed by a CWCS forensic science<br />
workshop. M. Goodman,P.J.Bush<br />
2:55 Intermission<br />
3:10 347. Seeing yellow: An activity on digital<br />
color documents. D. Tshudy<br />
3:30 348. Teaching forensic science: Bringing<br />
CSI into the classroom. R. Saferstein<br />
4:10 349. Using forensic science as a way to<br />
teach science to students of all ages.<br />
J. M. Petroski<br />
4:30 350. Chasing molecules in forensic undergraduate<br />
lab with CCD-based instrumentation.<br />
A. Y. Nazarenko<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom C<br />
Process Oriented Guided Inquiry Learning<br />
(POGIL)<br />
R. Moog, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 351. Introduction to POGIL and The<br />
POGIL Project. R. Moog<br />
1:55 352. Does size matter? A comparison<br />
of POGIL in small- and large-enrollment<br />
general chemistry courses. S. E. Shadle<br />
2:15 353. POGIL after the bell rings: What to<br />
do when time is up but the lesson isn’t.<br />
K. R. Woodrum<br />
2:35 Intermission<br />
2:50 354. Using POGIL in a predominantly<br />
pre-medical department. S. M. Lewis<br />
3:10 355. Assessment of student learning<br />
using POGIL in a biochemistry course.<br />
L. D. Frost<br />
3:30 356. Guided Inquiry in an OB course for<br />
pre-nursing students: A benefit to student<br />
learning. J. K. Abrahamson<br />
3:50 Intermission<br />
4:05 357. Discovering organic reaction<br />
mechanisms using POGIL and SWH,<br />
alone or in combination. F. J. Creegan<br />
4:25 358. POGIL and science writing heuristic<br />
hybrid experiments for sophomore organic<br />
laboratory. R. Libby<br />
4:45 359. Implementation of SWH as a laboratory<br />
instruction method in a large university:<br />
Facilitator training and program<br />
success. V. Lykourinou<br />
5:05 Panel Discussion<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Advances in Teaching<br />
Biochemistry and Physical Chemistry<br />
D. Vardar-Ulu, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 360. Math as a second language: A<br />
new approach to math in the biochemistry<br />
classroom. B. Sandler<br />
1:55 361. Using molecular structures from<br />
the PDB for a visual and exploratory<br />
learning experience in biochemistry.<br />
S. Dutta, H. Berman<br />
2:15 362. Enhancing active learning: An inquiry-based<br />
laboratory in biomolecular<br />
chemistry at Michigan Technological University.<br />
P. Murthy, M. Thompson,<br />
K. Hungwe<br />
2:35 363. Writing in chemistry: An introduction<br />
to the elements of grant writing for<br />
biochemistry students with limited content<br />
knowledge. F. Rossi<br />
2:55 364. SERRS and visible extinction<br />
spectroscopy of copper chlorophyllin: A<br />
physical chemistry experiment.<br />
C. S. Schnitzer, P. G. House, B. Karr<br />
3:15 Intermission<br />
3:30 365. Teaching physical chemistry<br />
based on the PHYS division symposia of<br />
a National ACS Meeting. T. Hopkins<br />
3:50 366. Quantum chemistry for the small,<br />
mixed-needs cohort: A tutorial approach.<br />
K. E. Downey<br />
4:10 367. Customized laboratory experience<br />
in physical chemistry. K. J. Castle,<br />
S. M. Rink<br />
4:30 368. Student designed laboratory procedures<br />
in physical chemistry. J. Dudek,<br />
R. Dudek<br />
4:50 369. Student centered classroom activities<br />
for learning physical chemistry.<br />
R. C. Dudek<br />
5:10 Concluding Remarks<br />
WEDNESDAY MORNING<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom A<br />
Research Ties between <strong>Chemical</strong><br />
Education and Other Disciplines<br />
M. Oliver-Hoyo, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 370. Educational research on the outcomes<br />
of activities supported by NSF<br />
STEP grant # 0622493, at New York City<br />
College of Technology - CUNY.<br />
P. A. Brown<br />
8:55 371. Chemistry new product development:<br />
An introductory chemistry course<br />
featuring science innovation and entrepreneurship.<br />
B. M. Comeau,D.I.Lewis,<br />
S. Bhatia<br />
9:15 372. Integrating green chemistry techniques<br />
into other disciplines: Minimizing<br />
art and biology department waste.<br />
A. J. Kabrhel, S. A. Hess, J. J. Becker<br />
9:35 373. Steady-state fluorescence applied<br />
to organized molecular systems: Aggregation<br />
number, polarity, and microenvironment<br />
viscosity of rhamnolipid aggregates.<br />
J. L. Jenkins, J. E. Pemberton,<br />
L. J. Begay, D. Belle-Oudry, R. M. Maier<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom C<br />
NSF Catalyzed Innovations in the<br />
Undergraduate Curriculum<br />
C. A. Burkhardt, Organizer<br />
R. Boggess, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:40 374. Innovative nanotechnology experiments<br />
for the undergraduate chemistry<br />
curriculum. B. Hillery, D. VanDorn,<br />
C. Wynter, S. Andreescu<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
CHED<br />
TECH–25
CHED <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
9:05 375. Interdisciplinary learning experience<br />
in biophotonics. A. Gericke,<br />
R. J. Twieg, J. T. Gleeson, J. R. Stalvey,<br />
D. kline<br />
9:30 376. Measuring the effect of an instrument-intensive<br />
curriculum on student<br />
critical thinking skills at Boise State University.<br />
S. E. Shadle, D. L. Warner,<br />
E. C. Brown, M. H. Towns<br />
9:55 Intermission<br />
10:05 377. BRAIDing together the science<br />
disciplines. R. Sweeder<br />
10:30 378. Five years of change in the<br />
MTSU general education STEM curriculum:<br />
Where we began, where we are now<br />
and where we are going.<br />
J. M. Iriarte-Gross, M. R. Weller,<br />
K. Greer<br />
10:55 Intermission<br />
11:05 379. ChemCompanion, a digital text<br />
for the first-year college chemistry<br />
course. S. Wood, L. Seawright, G. Trevor,<br />
D. Macfarlane, S. Stacey<br />
11:30 380. ChemQuery as a formative assessment<br />
instructional strategy for Chem<br />
1. K. Scalise, A. Stacy, M. Douskey<br />
11:55 Concluding Remarks<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Research in <strong>Chemical</strong> Education<br />
G. Bhattacharyya, Organizer<br />
S. Sandi-Urena, Presiding<br />
8:30 Introductory Remarks<br />
8:35 381. Efficacy of community college student<br />
participation in STEM research programs.<br />
C. J. Foley, N. A. Leonhardt<br />
8:55 382. Measuring student cognition during<br />
the learning of undergraduate organic<br />
chemistry. S. Schelble, K. Knaus<br />
9:15 383. Generating classroom cognition<br />
profiles during the assessment of learning<br />
of chemistry. K. Knaus, S. Schelble<br />
9:35 384. Representational competence in<br />
organic chemistry: Function to structure.<br />
H. Brinson, G. Bhattacharyya<br />
9:55 Intermission<br />
10:10 385. Interpretations of atomic representations:<br />
A comparative study of students<br />
and teachers. I. I. Salame,<br />
D. A. Krauss, S. Sarowar, S. Begum<br />
10:30 386. Results from Independent Laboratory<br />
Access for the Blind (ILAB) mainstream<br />
high school project years 1-3.<br />
C. A. Supalo, T. E. Mallouk,<br />
H. D. Wohlers, W. S. Carlsen<br />
10:50 387. Teachers’ perceptions of research-based<br />
labs in a high school<br />
chemistry curriculum. M. Pilarz,<br />
K. S. Kingery, G. C. Weaver<br />
11:10 388. Chemistry outreach programs:<br />
Can we tell if they help students learn?<br />
S. Burris, L. Pesterfield, E. Dumeyer<br />
Section D<br />
Seaport Hotel<br />
Seaport Ballroom B<br />
Where Goeth the Chemistry Textbook<br />
J. Reeves, Organizer<br />
D. Exton, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 389. Where goeth our textbooks.<br />
J. Reeves, D. Exton<br />
8:55 390. Choices for higher education publishers.<br />
K. A. Peterson<br />
9:15 391. Chemistry textbooks: Where have<br />
we been? Where are we going? J. Kotz<br />
9:35 Intermission<br />
9:50 392. Perspectives of a wheeler-dealer<br />
in the textbook world. P. Kelter<br />
26–TECH<br />
‡ Cooperative Cosponsorship<br />
10:10 393. One view of general chemistry<br />
textbook evolution and the textbook of<br />
the future. R. A. Pribush<br />
10:30 394. Chemistry, life, the universe and<br />
everything: A research-based general<br />
chemistry curriculum. M. Cooper,<br />
M. W. Klymkowsky<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom A<br />
Teaching Science to Elementary Teachers<br />
L. Hogue, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 395. Critical components of a college<br />
chemistry course for pre-elementary education<br />
majors: The evolution of a course.<br />
M. D. Duerst<br />
1:55 396. How do we teach elementary<br />
teachers. M. W. Moy<br />
2:15 397. Claims, evidence, and the scientific<br />
method. M. Sarquis, L. Hogue<br />
2:35 398. Professional development: Strategies<br />
and activities for pre-service and inservice<br />
teachers. D. A. Katz<br />
2:55 Intermission<br />
3:10 399. How a simple chemical analysis<br />
created a million jobs. D. Hicks<br />
3:30 400. Science in 3D: Drawing, dance,<br />
and drama. Z. M. Lerman<br />
3:50 401. Toys in the elementary classroom.<br />
J. L. Sarquis<br />
4:10 402. California mathematics and science<br />
partnership in Baldwin Park: Challenges<br />
and successes in sustainability<br />
and science educator professional development<br />
strategies. R. M. de Groot,<br />
C. Craney, A. Mazzeo<br />
4:30 403. Science integrated with children’s<br />
literature. L. Hogue<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom C<br />
NSF Catalyzed Innovations in the<br />
Undergraduate Curriculum<br />
R. Boggess, Organizer<br />
C. A. Burkhardt, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 404. Overview of NSF-DUE programs<br />
that support the education of STEM undergraduates.<br />
B. E. Holmes, E. Chang,<br />
S. Hixson, H. Sevian<br />
1:55 Panel Discussion<br />
2:30 Intermission<br />
2:40 405. Engaging students in chemistry<br />
courses: Lessons from the Arctic.<br />
L. K. Duffy, C. Middlecamp, A. Godduhn,<br />
L. Nicholas-Figueroa, C. Fabbri<br />
3:00 406. Incorporating a meaningful research<br />
experience into the general chemistry<br />
curriculum through implementation<br />
of equipment for materials characterization.<br />
T. R. Wagner<br />
3:20 407. NMR spectroscopy: A tool for infusing<br />
experiential investigation into the<br />
community college chemistry curriculum.<br />
P. A. Martino<br />
3:40 Intermission<br />
3:50 408. Isothermal titration calorimetry in<br />
physical chemistry and biochemistry laboratories.<br />
L. C. O’Brien,C.Wei,<br />
N. Shabestary, C. De Meo<br />
4:10 409. Fostering learner independence<br />
and skill mastery in a bioanalytical laboratory<br />
course through guided inquiry.<br />
L. D. Frost, C. M. McGibony<br />
4:30 410. Promoting student engagement in<br />
the analytical process: An instrumentation-based<br />
quantitative analysis laboratory.<br />
M. B. Jensen<br />
4:50 Concluding Remarks<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Research in <strong>Chemical</strong> Education<br />
G. Bhattacharyya, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 411. Assessment of the integration of<br />
online homework into general chemistry<br />
and its impact on student learning.<br />
I. I. Salame,S.A.Bacchus<br />
1:55 412. Form-based reflective journaling<br />
as a vehicle to facilitate self-direction in<br />
large lecture courses. P. A. Mabrouk<br />
2:15 413. Investigation into general chemistry<br />
student responses to a variety of<br />
teaching tools. G. A. Brown Wright<br />
2:35 Intermission<br />
2:50 414. Evaluation of peer-led team learning<br />
and the potential of the Human Constructivist<br />
learning theory. S. E. Lewis,<br />
J. L. Shaw<br />
3:10 415. Learning in the general chemistry<br />
laboratory: Student and TA gains in different<br />
instructional environments.<br />
S. Sandi-Urena, T. Gatlin, T. Eckart<br />
3:30 416. Design of an instrument for the assessment<br />
of college students’ epistemological<br />
sophistication. T. A. Gatlin,<br />
S. Sandi-Ureña<br />
3:50 Intermission<br />
4:05 417. General chemistry students’ understanding<br />
of nanoscience: A continuous<br />
study. A. K. Szeto, G. X. Ortiz<br />
4:25 418. The numeracy project: Analyzing<br />
the connection of quantitative literacy to<br />
achievement in general chemistry<br />
courses. T. L. Neal, C. Geary<br />
Section D<br />
Seaport Hotel<br />
Seaport Ballroom B<br />
Where Goeth the Chemistry Textbook<br />
D. Exton, Organizer<br />
J. Reeves, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 419. Fully assignable, interactive general<br />
chemistry textbook. W. J. Vining,<br />
S. Young, R. Day, B. Botch<br />
1:55 420. Options for reducing textbook<br />
costs for students. D. A. Katz,<br />
G. Buck-Rodriguez, K. Feuling,<br />
N. Lenihan, K. Meyers, S. Pritchett,<br />
R. Simpson<br />
2:15 421. Online textbooks are more than an<br />
online book: The development of ChemPaths<br />
online student portal. J. M. Shorb,<br />
J. W. Moore<br />
2:35 Intermission<br />
2:50 422. Print is dead: A year without textbooks<br />
in General and Organic Chemistry.<br />
D. M. Bartley, M. A. Benvenuto,<br />
J. E. Stevens, M. J. Mio<br />
3:10 423. Use of the Amazon Kindle DX in<br />
an introductory chemistry class.<br />
M. J. Kenney, M. Mentch<br />
3:30 Panel Discussion<br />
THURSDAY MORNING<br />
Section A<br />
Seaport Hotel<br />
Plaza Ballroom A<br />
General Papers<br />
C. Jaworek-Lopes, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 424. Teaching stereochemistry: Proposal<br />
for a terminology of chiral but not<br />
asymmetric chemical structures that<br />
would eliminate the existing confusion.<br />
J. Gal<br />
8:25 425. Chemistry, geometry and art:<br />
Constructing arbitrary fullerenes with<br />
beads. B. Jin, C. Chuang, C. Tsoo<br />
8:45 426. Inquiry-based learning in science<br />
camp for girls in Tanzania. I. I. Salame<br />
9:05 Intermission<br />
9:20 427. Implementing a new course on integrating<br />
science education research into<br />
secondary school science. I. I. Salame<br />
9:40 428. Promoting student learning<br />
through collaboration: Application to<br />
small and large classes. G. A. Crosby,<br />
J. L. Crosby, A. D. Crosby<br />
10:00 429. Development of a new class in<br />
energy and fuels. L. M. Pratt<br />
10:20 Intermission<br />
10:35 430. Energy science: Teaching chemistry<br />
and physics to non-science majors<br />
in a context relevant to their lives.<br />
C. R. Pharr, C. Chambers<br />
10:55 431. Mobile laboratory for the in-situ,<br />
non-destructive studies of works of art:<br />
Capturing students’ interest in chemistry<br />
at an Art and Design college.<br />
E. Del Federico<br />
11:15 432. Diversity among chemistry faculty:<br />
Implications for initiatives to revitalize<br />
chemistry. B. D. Barker<br />
Section B<br />
Seaport Hotel<br />
Seaport Ballroom C<br />
General Papers<br />
C. Jaworek-Lopes, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 433. Implementation and impact of a<br />
supplemental course taught in conjunction<br />
with general chemistry.<br />
S. Y. McGuire, E. Cook<br />
8:25 434. Helping General Chemistry students<br />
solve problems. D. B. Dizon,<br />
P.DeGeorge,J.T.Moore,R.H.Langley<br />
8:45 435. Effects of implementing a webbased<br />
math tutorial in a large lecturestyle<br />
general chemistry course: Re-<br />
MATCH positively affects student<br />
performance and attitudes in a two-year<br />
study. M. Barker, J. A. Heppert<br />
9:05 Intermission<br />
9:20 436. Spiral curricular approaches in<br />
General Chemistry: Increasing the conceptualization<br />
and the retention of knowledge<br />
for future applications.<br />
M. P. Masingale, J. D. Masingale<br />
9:40 437. Developing a scoring rubric for<br />
learning evaluation in an inquiry-based<br />
curriculum of chemistry laboratory.<br />
H. Chen,M.Chiu<br />
10:00 Intermission<br />
10:15 438. Analytical chemistry as an honors-level<br />
alternative to the traditional<br />
freshmen chemistry lab. B. Abrams<br />
10:35 439. Stoichiometry: Multi-tiered approaches<br />
to learning. H. Gendreau,<br />
B. Bridges<br />
10:55 440. Green chemistry in the high<br />
school laboratory. M. A. Walker,<br />
J. C. Proetta<br />
11:15 441. Chemistry II: From proposal to<br />
reality. S. Deratzou<br />
Section C<br />
Seaport Hotel<br />
Seaport Ballroom A<br />
Busted: Myths of a <strong>Chemical</strong> Nature<br />
Cosponsored by HIST<br />
C. Giunta, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 442. Inorganic myths in the freshman<br />
textbook. W. B. Jensen<br />
8:35 443. Metal-nonmetal dividing line in the<br />
periodic table: A chemical myth?<br />
G. S. Girolami<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
9:00 444. Fact and fiction of nitrogen-filled<br />
tires for enhanced automotive performance.<br />
S. C. Rasmussen,K.R.Radke<br />
9:25 Intermission<br />
9:40 445. Withdrawn<br />
10:05 446. Resonance structures: What they<br />
are and what they aren’t. C. J. Giunta<br />
10:30 447. “Death” of vitalism: Myth and<br />
reality. V. V. Mainz<br />
CHAS<br />
Division of <strong>Chemical</strong><br />
Health and Safety<br />
D. M. Decker, Program Chair<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 213<br />
Awards Symposium<br />
D. Walters, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 1. Reflections on fifteen years in health<br />
and safety in academia. D. M. Decker<br />
1:55 2. Laboratory safety at Princeton.<br />
R. M. Izzo<br />
2:15 3. Understanding the safe use and limitations<br />
of laboratory fume hoods, biological<br />
safety cabinets and ventilated balance<br />
enclosures. A. T. Chinni, J. R. Rizzo<br />
2:35 4. Laboratory ventilation: 2010 Revision<br />
of ANSI Z9.5. L. DiBerardinis<br />
2:55 5. Beyond ANSI/ASHRAE 110: Factoring<br />
turbulent intensity into the chemical<br />
fume hood test protocol. F. Memarzadeh<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 213<br />
Ask Dr. Safety: About Handling Air/Water<br />
Reactive and Pyrophoric Materials<br />
N. Langerman, Organizer, Presiding<br />
3:30 Introductory Remarks<br />
3:35 6. Nature of the pyrophoric beast: A review<br />
and comparison of safety approaches<br />
in academic, government, and<br />
industrial settings. D. Bunzow, R. Kelly<br />
3:55 7. Utilizing solvent recycling and other<br />
methods to reduce quantities of hazardous<br />
waste generated. S. Brehio<br />
4:15 8. ATOMICS in action: An injury-free<br />
career at Los Alamos National Lab.<br />
M. Montalvo<br />
4:35 Panel Discussion<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 213<br />
Considering the Human Element<br />
Hazards Analysis and Accident<br />
Investigation<br />
D. M. Decker, Organizer<br />
K. Jeskie, Organizer, Presiding<br />
9:00 Introductory Remarks<br />
9:05 9. Fundamentals of human performance<br />
improvement: Part I. M. McIntosh<br />
9:45 Intermission<br />
9:55 10. Fundamentals of human performance<br />
improvement: Part 2.<br />
M. McIntosh<br />
10:35 Intermission<br />
10:45 11. Using human performance fundamentals<br />
while investigating events in a<br />
fundamental chemistry research organization.<br />
M. Ross<br />
11:10 12. “They did what?!” Fighting our<br />
own human instincts so we can learn<br />
from minor laboratory accidents.<br />
K. Jeskie<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 213<br />
Considering the Human Element<br />
How we Prepare Chemists for Work<br />
D. M. Decker, Organizer<br />
K. Jeskie, Organizer, Presiding<br />
12:30 Introductory Remarks<br />
12:35 13. Human factors in accident prevention.<br />
R. Lippman<br />
1:00 14. Old hazards don’t change, but<br />
older researchers do. K. P. Fivizzani<br />
1:25 Intermission<br />
1:40 15. Training strategies for high<br />
throughput user facilities. J. M. Pickel<br />
2:05 16. Learning not to repeat someone<br />
else’s mistakes. K. Jeskie<br />
2:30 Panel Discussion<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 213<br />
The School <strong>Chemical</strong> Cleanout Campaign<br />
(SC3) Needs You<br />
R. Phifer, Organizer, Presiding<br />
3:00 Introductory Remarks<br />
3:05 17. Schools chemical cleanout campaign<br />
(SC3): ACS/EPA partnership.<br />
K. Meson<br />
3:25 18. <strong>Chemical</strong> management for the future:<br />
How universities can assist k-12<br />
schools with safe chemical management.<br />
S. Morin<br />
3:45 19. Keeping our schools safe: The importance<br />
of responsible chemical management<br />
from a k-12 teacher’s perspective.<br />
J. Miele<br />
4:05 20. How you can help your school district<br />
manage their chemicals. R. Phifer<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
D. M. Decker, Organizer<br />
8:00–10:00<br />
21. Did I really see that? Can you spot the<br />
hazard. F. K. Wood-Black<br />
22. Division of <strong>Chemical</strong> Health and Safety.<br />
D. M. Decker<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 213<br />
<strong>Chemical</strong> Life Cycle Management<br />
L. M. Stroud, Organizer, Presiding<br />
9:00 Introductory Remarks<br />
9:05 23. Web-based relational chemical and<br />
product database. G. R. Thompson<br />
9:25 24. State of chemical surplus sharing<br />
programs at colleges and universities.<br />
M. W. Weil<br />
9:45 25. “Green” criteria to support green<br />
principles. G. R. Thompson<br />
10:05 26. Web-based modules for assessment<br />
of “green” chemicals, products,<br />
processes and waste. G. R. Thompson<br />
10:25 Intermission<br />
10:40 27. Lean six sigma tools for a Glovebox<br />
Glove Integrity Program.<br />
M. E. Cournoyer<br />
11:00 28. Enhancing the shelf-life and safety<br />
of peroxide-forming solvents. A. Apblett,<br />
N. Materer, D. Bussan<br />
11:20 29. Shelf life and storage of chemicals:<br />
Applications for chemical inventory<br />
management. I. G. Cesa<br />
11:40 30. Full lifecycle approach to chemical<br />
safety management. K. Blake<br />
TUESDAY AFTERNOON<br />
Laboratory Safety Sponsored by PRES,<br />
Cosponsored by CCS, CHAS<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 213<br />
Chemistry in Preventing and Combating<br />
Disease<br />
R. Hill, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 31. Synthetic versions of cellular materials:<br />
Potential new therapies and risks.<br />
C. Mickelson<br />
8:55 32. Fighting global tuberculosis with<br />
chemistry. J. S. Baum<br />
9:15 33. Non-invasive means for estimating<br />
a smoker’s uptake of harmful chemicals.<br />
C. H. Watson<br />
9:35 34. Application of chemistry to end-of<br />
service life determination of personal protective<br />
equipment. J. L. Snyder<br />
9:55 Intermission<br />
10:10 35. Using soyscreen in an oil-based<br />
biopesticide formulation to protect Beauveria<br />
bassiana conidia from degradation<br />
by ultraviolet light energy. R. W. Behle,<br />
D. L. Compton, J. A. Laszlo<br />
10:30 36. Determination of �–amanitin in human<br />
urine by negative ion MRM and LC/<br />
MS/MS. C. Pittman, S. Lemire, L. Swaim,<br />
R. Johnson<br />
10:50 37. Ultra-trace determination of beryllium<br />
in occupational hygiene samples.<br />
K. Ashley<br />
11:10 38. Determination of total reactive isocyanate<br />
group (TRIG) using 1,8-diaminonaphthalene<br />
(DAN) as a derivatizing<br />
reagent. R. P. Streicher, D. Bello,<br />
F. Nourian, K. Ernst<br />
11:30 Concluding Remarks<br />
CINF<br />
Division of <strong>Chemical</strong><br />
Information<br />
R. Guha, Program Chair<br />
OTHER SYMPOSIA OF INTEREST:<br />
Data Analysis: Statistics on<br />
<strong>Chemical</strong>s (see COMP, Thu)<br />
The Journal of <strong>Chemical</strong> Information<br />
and Modeling’s 50th Anniversary<br />
Symposium (see COMP, Mon)<br />
Computer Modeling: The Wave of the<br />
Future and its Benefits for Small<br />
Business Owners (see SCHB, Thu)<br />
Drugging the Undruggable: Small<br />
Molecule Modulators of Protein-<br />
Protein Interactions (see MEDI, Mon)<br />
SOCIAL EVENTS:<br />
Luncheon, 12:00-1:30 PM: Tue<br />
CINF Welcoming Reception and<br />
Scholarship for Scientific Excellence<br />
Posters, 6:30-8:30 PM: Sun<br />
Harry’s Party, 5:30-8:00 PM: Mon<br />
Herman Skolnik Award Reception,<br />
6:30-8:30 PM: Tue<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
Semantic Web in Chemistry<br />
RDF & Computation Cosponsored by COMP<br />
M. Braendle, Organizer<br />
E. Willighagen, Organizer, Presiding<br />
8:45 Introductory Remarks<br />
8:55 1. Semantic envelopment of cheminformatics<br />
resources with SADI.<br />
L. L. Chepelev, E. Willighagen,<br />
M. Dumontier<br />
9:40 2. RESTful RDF web services for predictive<br />
toxicology. N. Jeliazkova<br />
10:10 Intermission<br />
10:25 3. Linking the resource description<br />
framework to cheminformatics and proteochemometrics.<br />
E. L. Willighagen,<br />
J. E. Wikberg<br />
10:55 4. <strong>Chemical</strong> e-Science Information<br />
Cloud (ChemCloud): A semantic web<br />
based eScience infrastructure.<br />
A. Paschke, S. Heineke<br />
11:25 5. Use of semantic web services to<br />
access small molecule ligand database.<br />
A. P. Tamhankar, A. S. Ausekar<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 155<br />
Assessing Collections & Information<br />
Resources in Science & Technology<br />
Financially sponsored by SLA CHEM<br />
E. Kajosalo, Organizer, Presiding<br />
CHED/CHAS/CINF<br />
9:00 Introductory Remarks<br />
9:05 6. Usage metrics: Tools for evaluating<br />
science monograph collections.<br />
M. M. Foss, V. Kisling, S. Haas<br />
9:30 7. Happily ever after or not: E-book collection<br />
usage analysis and assessment at<br />
USC Library. N. Xiao<br />
9:55 8. From <strong>Chemical</strong> Abstracts to<br />
SciFinder: Transitioning to SciFinder and<br />
assessing customer usage. S. Makar,<br />
S. Bruss<br />
10:20 Intermission<br />
10:35 9. Using Web of Knowledge to identify<br />
publishing and citation patterns of<br />
campus researchers at the University of<br />
Arkansas. L. Salisbury,J.S.Smith<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–27
CINF <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
11:00 10. Don’t forget the qualitative: Including<br />
focus groups in the collection assessment<br />
process. S. Shepherd,<br />
T. M. Vogel<br />
Social Networking: The Next Generation<br />
Sponsored by CHED, Cosponsored by CINF<br />
and YCC<br />
Tautomers and Biology<br />
Computer Handling of Tautomers<br />
Sponsored by COMP, Cosponsored by CINF,<br />
MEDI, and PHYS<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
Data-intensive Drug Design Cosponsored by<br />
COMP<br />
J. Van Drie, Organizer, Presiding<br />
1:45 Introductory Remarks<br />
1:50 11. Strategies for the identification and<br />
generation of informative compound sets.<br />
M. S. Lajiness<br />
2:15 12. Public-domain data resources at<br />
the European Bioinformatics Institute and<br />
their use in drug discovery. C. Steinbeck<br />
2:40 13. Decision making in the face of<br />
complicated drug discovery data using<br />
the Novartis system for virtual medicinal<br />
chemistry (FOCUS). D. Chin<br />
3:05 14. Integrating chemical and biological<br />
data: Insights from 10 years of VERDI.<br />
S. Roberts, W. P. Walters,<br />
R. McLoughlin, P. Gabriel, J. Willis,<br />
T. Kramer<br />
3:30 Intermission<br />
3:45 15. Collaborative database and computational<br />
models for tuberculosis drug<br />
discovery decision making. S. Ekins,<br />
J. Bradford, K. Dole, A. Spektor,<br />
K. Gregory, D. Blondeau, M. Hohman,<br />
B. A. Bunin<br />
4:10 16. Data drive life sciences: The Pyramids<br />
meet the Tower of Babel. R. Guha<br />
4:35 17. Design principles for diversity-oriented<br />
synthesis: Facilitating downstream<br />
discovery with upfront design.<br />
L. Marcaurelle<br />
5:00 18. Overview: Data-intensive drug design.<br />
J. H. Van Drie<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 155<br />
Assessing Collections & Information<br />
Resources in Science & Technology<br />
Financially supported by SLA CHEM<br />
E. Kajosalo, Organizer, Presiding<br />
2:00 19. Data-driven development: How<br />
ACS <strong>Publications</strong> uses data to enhance<br />
products and services, and respond to<br />
customer needs. M. Blaney, S. Rouhi<br />
2:25 20. Objective collections evaluation using<br />
statistics at the MIT Libraries.<br />
M. Willmott, E. Kajosalo<br />
2:50 21. Getting the biggest bang for your<br />
buck: Methods and strategies for managing<br />
journal collections. G. Baysinger<br />
3:15 22. Taking a collection down to its elements:<br />
Using various assessment techniques<br />
to revitalize a library. L. Solla<br />
3:40 Panel Discussion<br />
Scripting & Programming<br />
HPC on the Cheap Sponsored by COMP,<br />
Cosponsored by CINF<br />
Social Networking: The Next Generation<br />
Sponsored by CHED, Cosponsored by CINF<br />
and YCC<br />
Using Waters Explicitly in Drug Discovery<br />
Theory and Methods Sponsored by COMP,<br />
Cosponsored by CINF and MEDI<br />
28–TECH<br />
‡ Cooperative Cosponsorship<br />
SUNDAY EVENING<br />
Westin Boston Waterfront<br />
Harbor Ballroom I<br />
2010 CINF Scholarship for Scientific<br />
Excellence Financially supported by FIZ<br />
Chemie Berlin<br />
G. Grethe, Organizer<br />
6:30–9:30<br />
23. Predicting specific inhibition of cyclophilins<br />
A and B using docking, growing, and<br />
free energy perturbation calculations.<br />
S. V. Sambasivarao, O. Acevedo<br />
24. Using aggregative web services for drug<br />
discovery. Q. Zhu, M. S. Lajiness,<br />
D. J. Wild<br />
25. Semantifying polymer science using ontologies.<br />
E. O. Cannon, A. Nico,<br />
P. Murray-Rust<br />
26. Toxicity reference database (ToxRefDB)<br />
to develop predictive toxicity models and<br />
prioritize compounds for future toxicity<br />
testing. H. Tang, H. Zhu, L. Zhang,<br />
A. Sedykh, A. Richard, I. Rusyn,<br />
A. Tropsha<br />
27. OrbDB: A database of molecular orbital<br />
interactions. M. A. Kayala,<br />
C. A. Azencott, J. H. Chen, P. F. Baldi<br />
28. Novel approach to drug discovery integrating<br />
chemogenomics and QSAR modeling:<br />
Applications to anti-Alzheimer’s<br />
agents. R. Hajjo,S.Wang,B.L.Roth,<br />
A. Tropsha<br />
29. Cheminformatics improvements by combining<br />
semantic web technologies, cheminformatical<br />
representations, and chemometrics<br />
for statistical modeling and<br />
pattern recognition. E. L. Willighagen<br />
30. Prediction of consistent water networks<br />
in uncomplexed protein binding sites<br />
based on knowledge-based potentials.<br />
M. Betz, G. Neudert, G. Klebe<br />
31. Functional binders for non-specific binding:<br />
Evaluation of virtual screening methods<br />
for the elucidation of novel transthyretin<br />
amyloid inhibitors. C. J. Simões,<br />
T. Mukherjee, R. M. Jackson, R. M. Brito<br />
MONDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 155<br />
Semantic Web in Chemistry<br />
OWL <strong>Chemical</strong> Ontologies Cosponsored by<br />
COMP<br />
E. Willighagen, Organizer<br />
M. Braendle, Organizer, Presiding<br />
8:30 32. Using the oreChemexperiments ontology:<br />
Planning and enacting chemistry.<br />
J. G. Frey, M. I. Borkum, C. Lagoze,<br />
S. J. Coles<br />
9:15 33. CHEMINF: Community-developed<br />
ontology of chemical information and algorithms.<br />
L. L. Chepelev, J. Hastings,<br />
E. Willighagen, N. Adams, C. Steinbeck,<br />
P. Murray-Rust, M. Dumontier<br />
9:45 Intermission<br />
10:00 34. <strong>Chemical</strong> entity semantic specification:<br />
Knowledge representation for efficient<br />
semantic cheminformatics and facile<br />
data integration. L. L. Chepelev,<br />
M. Dumontier<br />
10:30 35. Semantic assistant for lipidomics<br />
researchers. A. Kouznetsov, R. Witte,<br />
C. J. Baker<br />
11:00 36. <strong>Chemical</strong>Tagger: A tool for semantic<br />
text-mining in chemistry.<br />
L. Hawizy, D. M. Jessop, P. Murray-Rust<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
The Journal of <strong>Chemical</strong> Information and<br />
Modeling’s 50th Anniversary Symposium<br />
Cosponsored by COMP<br />
W. Jorgensen, Organizer, Presiding<br />
8:45 Introductory Remarks<br />
8:55 37. From canonical numbering to the<br />
analysis of enzyme-catalyzed reactions:<br />
32 years of publishing in JCIM (JCICS).<br />
J. Gasteiger, J. Gasteiger<br />
9:25 38. Fifteen years of JCICS. G. W. Milne<br />
9:55 39. Fifteen years in chemical informatics:<br />
Lessons from the past, ideas for the<br />
future. D. Agrafiotis<br />
10:25 Intermission<br />
10:40 40. Applications of wavelets in virtual<br />
screening. V. Gillet, R. Martin,<br />
E. Gardiner, S. Senger<br />
11:10 41. Privileged substructures revisited:<br />
Target community-selective scaffolds.<br />
J. Bajorath<br />
11:40 42. Automated retrosynthetic analysis:<br />
An old flame rekindled. P. Johnson,<br />
A. P. Cook, J. Law, M. Mirzazadeh,<br />
A. Simon<br />
Tautomers and Biology<br />
Predictions of Tautomer Ratios Sponsored<br />
by COMP, Cosponsored by CINF, MEDI, and<br />
PHYS<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
MONDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 155<br />
Wheres the Good Stuff? Consumer Health<br />
Information, and Social Networking<br />
Resources and Services Cosponsored by<br />
CHED<br />
A. Twiss-Brooks, Organizer, Presiding<br />
1:00 43. Dietary supplements: Free evidence-based<br />
resources for the cautious<br />
consumer. B. Erb<br />
1:25 44. What lessons learned can we generalize<br />
from evaluation and usability of a<br />
health website designed for lower literacy<br />
consumers? M. J. Moore,R.G.Bias<br />
1:50 45. National Library of Medicine resources<br />
for consumer health information.<br />
M. Eberle<br />
2:15 46. Better prescription for information:<br />
Dietary supplements online.<br />
G. Y. Hendler<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
Semantic Web in Chemistry<br />
RDF/OWL Applications Cosponsored by<br />
COMP<br />
M. Braendle, Organizer<br />
E. Willighagen, Organizer, Presiding<br />
1:15 47. Overview of the linking open drug<br />
data task. E. Prudhommeaux,<br />
E. Willighagen, S. Stephens<br />
2:00 48. Control, monitoring, analysis and<br />
dissemination of laboratory physical<br />
chemistry experiments using semantic<br />
web and broker technologies. J. G. Frey,<br />
S. Wilson<br />
2:30 Intermission<br />
2:45 49. Semantic analysis of chemical patents.<br />
D. M. Jessop, L. Hawizy,<br />
P. Murray-Rust, R. C. Glen<br />
3:15 50. Data mining and querying of integrated<br />
chemical and biological information<br />
using Chem2Bio2RDF. D. J. Wild,<br />
B. Chen, Y. Ding, X. Dong, H. Wang,<br />
D. Jiao, Q. Zhu, M. Sankaranarayanan<br />
3:45 51. Mining and visualizing chemical<br />
compound-specific chemical-gene/disease/pathway/literature<br />
relationships.<br />
Q. Zhu, P. Purohit, J. Youl Choi, S. Bae,<br />
J. Qiu, Y. Ding, D. Wild<br />
4:15 Intermission<br />
4:20 CINF Open Meeting<br />
4:30 Open Meeting. Committees on <strong>Publications</strong><br />
and <strong>Chemical</strong> Abstracts Service<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 155<br />
CINFlash<br />
Can You Present Faster Than a<br />
Femtosecond Laser?<br />
R. Guha, Organizer, Presiding<br />
2:45 Panel Discussion<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
The Journal of <strong>Chemical</strong> Information and<br />
Modeling’s 50th Anniversary Symposium<br />
Sponsored by COMP, Cosponsored by CINF<br />
Using Waters Explicitly in Drug Discovery<br />
Characterization and Applications<br />
Sponsored by COMP, Cosponsored by CINF<br />
and MEDI<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
R. Guha, Organizer<br />
8:00–10:00<br />
2, 6, 20, 28, 31. See previous listings.<br />
78, 91. See subsequent listings.<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
Herman Skolnik Award Symposium<br />
The Marriage, or at Least Dating, of<br />
Molecular Simulation and Modeling with<br />
QSAR Analysis: Exploring Chemometric<br />
Methods<br />
E. X. Esposito, Organizer<br />
A. Hopfinger, Organizer, Presiding<br />
8:15 Introductory Remarks<br />
8:30 52. What makes polyphenols good antioxidants?<br />
Alton Brown, you should take<br />
notes. . . E. X. Esposito<br />
9:15 53. Engineering and 3D protein-ligand<br />
interaction scaling of 2D fingerprints.<br />
J. Bajorath<br />
10:00 Intermission<br />
10:15 54. In silico binary QSAR models<br />
based on 4D-fingerprints and MOE descriptors<br />
for prediction of hERG blockage.<br />
Y. Tseng<br />
11:00 55. Telling the good from the bad and<br />
the ugly: The challenge of evaluating<br />
pharmacophore model performance.<br />
R. D. Clark<br />
Tautomers and Biology<br />
Tautomers and Macromolecule-ligand<br />
Complexes Sponsored by COMP,<br />
Cosponsored by CINF, MEDI, and PHYS<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
Herman Skolnik Award Symposium<br />
The Marriage, or at Least Dating, of<br />
Molecular Simulation and Modeling with<br />
QSAR Analysis: Exploring <strong>Chemical</strong><br />
Systems<br />
A. Hopfinger, Organizer<br />
E. X. Esposito, Organizer, Presiding<br />
2:00 56. Creative application of ligandbased<br />
methods to solve structure-based<br />
problems: Using QSAR approaches to<br />
learn from protein crystal structures.<br />
C. M. Breneman, S. Das, M. Sundling,<br />
M. Krein, S. Cramer, K. P. Bennett,<br />
C. Bergeron, J. Zaretzki<br />
2:45 57. Computer-aided drug discovery.<br />
W. L. Jorgensen<br />
3:30 Intermission<br />
3:45 58. Structure-based discovery and<br />
QSAR methods: A marriage of convenience.<br />
J. S. Duca<br />
4:30 59. Extending the QSAR Paradigm using<br />
molecular modeling and simulation.<br />
A. J. Hopfinger<br />
5:15 Presentation of Award<br />
Using Waters Explicitly in Drug Discovery<br />
Hybrid Explicit/Implicit Methods Sponsored<br />
by COMP, Cosponsored by CINF and MEDI<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
The Emerging Concepts of Activity<br />
Landscapes and Activity Cliffs and their<br />
Role in Drug Research Cosponsored by<br />
COMP and MEDI<br />
G. Maggiora, M. Lajiness, Organizers<br />
J. Bajorath, Organizer, Presiding<br />
8:50 Introductory Remarks<br />
9:00 60. Overview of activity landscapes<br />
and activity cliffs: Prospects and problems.<br />
G. M. Maggiora<br />
9:30 61. Exploring and exploiting the potential<br />
of structure-activity cliffs.<br />
G. M. Maggiora, M. S. Lajiness<br />
10:00 62. What makes a good structure activity<br />
landscape? Network metrics and<br />
structure representations as a way of exploring<br />
activity landscapes. R. Guha<br />
10:30 Intermission<br />
10:45 63. Consensus model of activity landscapes<br />
and consensus activity cliffs.<br />
J. L. Medina-Franco,<br />
K. Martinez-Mayorga, F. Lopez-Vallejo<br />
11:15 64. R-Cliffs: Activity cliffs within a single<br />
analog series. D. Agrafiotis<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 155<br />
Recent Progress in <strong>Chemical</strong> Structure<br />
Representation<br />
Applications and Tools<br />
R. Apodaca, Organizer, Presiding<br />
9:00 Introductory Remarks<br />
9:05 65. <strong>Chemical</strong> structure representation<br />
in the DuPont <strong>Chemical</strong> Information Management<br />
Solutions database: Challenges<br />
posed by complex materials in a diversified<br />
science company. M. A. Andrews,<br />
E. S. Wilks<br />
9:35 66. From deposition to application:<br />
Technologies for storing and exploiting<br />
crystal structure data. C. R. Groom,<br />
J. Cole, S. Bowden, T. Olsson<br />
10:05 67. Recent IUPAC recommendations<br />
for chemical structure representation: An<br />
overview. J. Brecher<br />
10:35 Intermission<br />
10:50 68. Orbital development kit.<br />
E. L. Willighagen<br />
11:20 69. Line notations as unique identifiers.<br />
K. Boda<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
The Emerging Concepts of Activity<br />
Landscapes and Activity Cliffs and their<br />
Role in Drug Research Cosponsored by<br />
COMP and MEDI<br />
J. Bajorath, M. Lajiness, Organizers<br />
G. Maggiora, Organizer, Presiding<br />
2:00 70. Analysis of activity landscapes, activity<br />
cliffs, and selectivity cliffs.<br />
J. Bajorath<br />
2:30 71. Using Activity Cliff Information in<br />
structure-based design approaches.<br />
B. Seebeck, M. Wagener, M. Rarey<br />
3:00 72. Exploring activity cliffs using large<br />
scale semantic analysis of PubChem.<br />
D. J. Wild, B. Chen, Q. Zhu<br />
3:30 73. Quantifying the usefulness of a<br />
model of a structure-activity relationship:<br />
The SALI Curve Integral. J. H. Van Drie,<br />
R. Guha<br />
4:00 Concluding Remarks<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 155<br />
Recent Progress in <strong>Chemical</strong> Structure<br />
Representation<br />
File Formats and Line Notations<br />
R. Apodaca, Organizer, Presiding<br />
2:00 74. Status of the InChI and InChIKey algorithms.<br />
S. Heller<br />
2:30 75. Self-contained sequence representation<br />
(SCSR): Bridging the gap between<br />
bioinformatics and cheminformatics.<br />
K. T. Taylor, W. L. Chen, B. D. Christie,<br />
J. L. Durant, D. L. Grier, B. A. Leland,<br />
J. G. Nourse<br />
3:00 Intermission<br />
3:15 76. Representation of Markush structures:<br />
From molecules toward patents.<br />
S. Csepregi,N.Máté, R. Wágner,<br />
T. Csizmazia, S. Dóránt, E. Bíró,<br />
T. Dudgeon, A. Baharev, F. Csizmadia<br />
3:45 77. CSRML: A new markup language<br />
definition for chemical substructure representation.<br />
C. H. Schwab, B. Bienfait,<br />
J. Gasteiger, T. Kleinoeder, J. Marucszyk,<br />
O. Sacher, A. Tarkhov, L. Terfloth,<br />
C. Yang<br />
THURSDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
General Papers<br />
Characterization and Prediction<br />
R. Guha, Organizer, Presiding<br />
8:45 78. Prediction of solvent physical properties<br />
using the hierarchical clustering<br />
method. T. M. Martin,D.M.Young<br />
9:10 79. Scaffold diversity analysis using<br />
scaffold retrieval curves and an entropybased<br />
measure. J. L. Medina-Franco,<br />
K. Martinez-Mayorga, A. Bender, T. Scior<br />
9:35 80. Nonsubjective clustering scheme<br />
for multiconformer databases.<br />
A. B. Yongye,A.Bender,<br />
K. Martinez-Mayorga<br />
10:00 Intermission<br />
10:10 81. Finding drug discovery “rules of<br />
thumb” with bump hunting.<br />
T. Hashimoto, M. Segall<br />
10:35 82. Machine learning in discovery research:<br />
Polypharmacology predictions as<br />
a use case. N. Wale, K. McConnell,<br />
E. M. Gifford<br />
11:00 83. Interpretable correlation descriptors<br />
for quantitative structure-activity relationships.<br />
J. D. Hirst<br />
Computer Modeling: The Wave of the<br />
Future and its Benefits for Small Business<br />
Owners Sponsored by SCHB, Cosponsored<br />
by CINF, COMP, and PROF<br />
Targeting Gram-Negative Pathogens<br />
Sponsored by COMP, Cosponsored by CINF<br />
and MEDI<br />
THURSDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156A<br />
General Papers<br />
Extraction and Integration<br />
R. Guha, Organizer<br />
X. Wang, Presiding<br />
1:30 84. Chemistry in your hand: Using mobile<br />
devices to access public chemistry<br />
compound data. A. J. Williams,<br />
V. Tkachenko<br />
1:55 85. Feature analysis of ToxCast TM<br />
compounds. P. Volarath, S. Little,<br />
C. Yang, M. Martin, D. Reif, A. Richard<br />
2:20 86. Extracting information from the IU-<br />
PAC Green Book. J. G. Frey,<br />
M. I. Borkum<br />
2:45 87. Biologics and biosimilars: One and<br />
the same? R. Schenck<br />
3:10 Intermission<br />
3:20 88. Intelligent mining of drug information<br />
resources. R. Jain, A. Tamhankar,<br />
A. Ausekar, Y. Dixit<br />
3:45 89. Cheminformatics semantic grid for<br />
neglected diseases. P. J. Kowalczyk<br />
4:10 90. Extraction and integration of chemical<br />
information from documents.<br />
H. O. Villar, J. Betancort, M. R. Hansen<br />
4:35 91. SAR and the role of active-site waters<br />
in blood coagulating serine proteases:<br />
A thermodynamic analysis of ligand-protein<br />
binding. N. K. Salam,<br />
W. Sherman, R. Abel<br />
Data Analysis: Statistics on <strong>Chemical</strong>s<br />
Sponsored by COMP, Cosponsored by CINF<br />
Targeting Gram-Negative Pathogens<br />
Sponsored by COMP, Cosponsored by CINF<br />
and MEDI<br />
TOXI<br />
Division of <strong>Chemical</strong><br />
Toxicology<br />
K. Mitra, Program Chair<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
General Papers<br />
K. Mitra, Organizer, Presiding<br />
8:00 1. Structure and stability of duplex<br />
DNA bearing an aristolactam II-dA adduct:<br />
Insights into lesion mutagenesis<br />
and repair. M. Lukin, T. Zaliznyak,<br />
C. R. De los Santos<br />
8:20 2. Gold nanoparticles can reduce cell<br />
proliferation by altering plating surfaces.<br />
A. M. Keene,K.M.Tyner<br />
8:40 3. Formation and in-vivo replication<br />
studies of bulky DNA lesions induced by<br />
reactive oxygen species. Y. Wang,<br />
J. Wang, B. Yuan, C. Guerrero, J. Wang<br />
9:00 4. LASSO-ing potential pregnane X receptor<br />
agonists. S. Ekins, A. J. Williams,<br />
Z. Zsoldos, A. Simon, O. Ravitz,<br />
V. Tkachenko<br />
9:20 5. In vivo formation and repair of 1,3butadiene-induced<br />
DNA-DNA crosslinks.<br />
N. Tretyakova<br />
9:40 6. Find a needle in a haystack: Recent<br />
studies on drug-induced testicular toxicity.<br />
M. Song, N. Greene,<br />
R. E. Robert Chapin2<br />
10:00 Intermission<br />
10:20 7. Analysis of 4-hydroxy-1-(3-pyridyl)-<br />
1-butanone-releasing DNA adducts in<br />
human exfoliated oral mucosa cells by<br />
liquid chromatography-electrospray ionization-tandem<br />
mass spectrometry.<br />
I. Stepanov, J. Muzic, J. Jensen,<br />
D. Hatsukami, S. S. Hecht<br />
10:40 8. Prediction of mixture interactions<br />
via cellular stress response. J. W. Boyd,<br />
X. Gao, H. Williams, N. Rubenstein<br />
11:00 9. TP53 mutational signature of aristolochic<br />
acid. A. P. Grollman,<br />
B. Jelaković, M. Moriya<br />
11:20 10. Cytochrome P450 3A mediated<br />
thalidomide hydroxylation and formation<br />
of a glutathione conjugate.<br />
G. Chowdhury, N. Murayama, Y. Okada,<br />
Y. Uno, M. Shimizu, N. Shibata,<br />
F. P. Guengerich, H. Yamazaki<br />
11:40 11. Post-synthetic generation of FaPy<br />
lesions in oligonucleotides. M. A. Lukin,<br />
C. A. Minetti, D. P. Remeta, S. Attaluri,<br />
F. Johnson, K. J. Breslauer, d. Carlos<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
<strong>Chemical</strong> Mechanisms in Toxicology:<br />
Elucidating and Preventing Disease<br />
Founders’ Award Symposium<br />
R. Loeppky, Organizer, Presiding<br />
CINF/TOXI<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–29
TOXI <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
1:00 Founders’ Award Presentation<br />
1:10 12. Mechanisms in chemical toxicology:<br />
Letting the molecules point the way.<br />
R. N. Loeppky<br />
1:25 13. Recent studies on chemical mechanisms<br />
of carcinogenicity: N-Nitrosamines,<br />
aldehydes, and polycyclic aromatic<br />
hydrocarbons. S. S. Hecht,<br />
M. Wang, G. Cheng, Y. Zhong, S. Zhang,<br />
S. G. Carmella<br />
2:05 14. Alkylanilines: Complexities in<br />
chemistry, toxicity, mutagenicity, and<br />
carcinogenesis. S. R. Tannenbaum,<br />
P. L. Skipper, G. N. Wogan, C. Liang,<br />
L. Trudel, W. Ye<br />
2:45 Intermission<br />
3:05 15. Chemistry and biochemistry of biselectrophiles,<br />
thiols, and peptides related<br />
to DNA blockage and miscoding.<br />
F. P. Guengerich<br />
3:45 16. Reactive metabolites in the biotransformation<br />
of furan-containing molecules.<br />
L. A. Peterson<br />
4:25 17. Chemistry and biology of DNA<br />
damage by structurally interesting heterocyclic<br />
compounds. K. S. Gates<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
Young Investigators<br />
I. Stepanov, Organizer, Presiding<br />
8:15 18. Synthesis and quantitation of carboxymethylated<br />
DNA Lesions induced by<br />
diazoacetate. J. Wang,Y.Wang<br />
8:30 19. Differential expression of proteins<br />
in response to arsenic stress in Chlamydomonas<br />
reinhardtii.<br />
C. Walliwalagedara, H. van Keulen,<br />
B. Willard, R. Wei<br />
8:45 20. Nucleosome effect on deamination<br />
rate of 5-methyl cytosine in cyclobutane<br />
pyrimidine dimer DNA photoproduct.<br />
Q. Song, J. S. Taylor<br />
9:00 21. Small-molecule screening for suppressors<br />
of beta-cell apoptosis induced<br />
by inflammatory cytokines. D. Chou,<br />
P. W. Faloon, H. A. Carrinski,<br />
N. E. Bodycombe, P. A. Clemons,<br />
S. L. Schreiber, B. K. Wagner<br />
9:15 22. Exocyclic deoxyadenosine adducts<br />
of 1,2,3,4-diepoxybutane: Synthesis and<br />
effects on DNA structure.<br />
U. I. Seneviratne, N. Y. Tretyakova<br />
9:30 23. Analysis of r-7,t-8,9,c-10-tetrahydroxy-7,8,9,10-tetrahydrobenzo[a]pyrene<br />
in human urine: A biomarker for directly<br />
assessing carcinogenic polycyclic aromatic<br />
hydrocarbon metabolic activation.<br />
Y. Zhong, S. G. Carmella,<br />
J. B. Hochalter, S. S. Hecht<br />
9:45 24. Repair of the hydantoin lesions<br />
guanidinohydantoin (Gh) and spiroiminodihydantoin<br />
(Sp) by bacterial nucleotide<br />
excision repair. P. L. McKibbin,<br />
B. Van Houten, S. S. David<br />
10:00 Intermission<br />
10:20 25. Structural characterization of<br />
formaldehyde-induced DNA-protein<br />
cross-links. K. Lu, W. Ye, L. Zhou,<br />
L. B. Collins, X. Chen, A. Gold, L. M. Ball,<br />
J. A. Swenberg<br />
10:35 26. Reactive carbonyl species derived<br />
from omega-3 and omega-6 fatty acids.<br />
Y. Wang, J. S. Wishnok,<br />
S. R. Tannenbaum<br />
10:50 27. Beas2B cells as a model of polycyclic<br />
aromatic hydrocarbon metabolism<br />
in noncancerous human lung: Metabolic<br />
consequences of [ 3 H]-B[a]P and [ 3 H]-<br />
B[a]P-7,8-dihydrodiol treatment.<br />
M. E. Kushman, S. L. Gelhaus,<br />
T. M. Penning<br />
11:05 28. Effect of O 2 -arylated diazeniumdiolates<br />
on cellular glutathione status.<br />
R. J. Holland, J. E. Saavedra,<br />
L. K. Keefer, A. E. Maciag, H. Chakrapani<br />
30–TECH<br />
‡ Cooperative Cosponsorship<br />
11:20 29. Stereoselective formation of N 2 -<br />
dG:N 2 -dG carbinolamine interstrand<br />
cross-link arising from trans-4-Hydroxynonenal<br />
derived exocyclic<br />
(6S,8R,11S)1,N 2 -dG adduct. H. Huang,<br />
I. D. Kozekov, A. Kozekova, S. Banerjee,<br />
C. J. Rizzo, M. P. Stone<br />
11:35 30. Sequence-dependent oxidation of<br />
8-oxoguanine in DNA. K. Lim,L.Cui,<br />
K. Taghizadeh, J. S. Wishnok,<br />
S. R. Tannenbaum, P. C. Dedon<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
Protein Adducts and Stress Response<br />
Pathways<br />
D. Liebler, Organizer, Presiding<br />
1:15 31. Redox-dependent anti-inflammatory<br />
lipid mediator generation and actions.<br />
B. Freeman<br />
2:00 32. Identifying and quantifying cysteome<br />
modifications in response to NO<br />
donor and quinone donor drugs.<br />
G. R. Thatcher, R. E. Chandrasena,<br />
V. Sinha, G. T. Wijewickrama, T. Dunlap,<br />
S. C. Piyankarage, H. Xu, J. Bolton,<br />
I. T. Schiefer, P. D. Edirisinghe, Y. Wang<br />
2:45 Intermission<br />
3:05 33. Systems analysis of electrophileinduced<br />
gene expression: Role of HSF1affected<br />
genes in cellular viability.<br />
A. T. Jacobs<br />
3:50 34. Apoptosis signal-regulating kinase<br />
1 (ASK1), a sensor-trigger for proapoptotic<br />
signaling in electrophile stress.<br />
D. C. Liebler<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
Perspectives Lecture<br />
L. Peterson, Organizer, Presiding<br />
5:00 Introductory Remarks<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
Mechanisms of Food-Drug Interactions<br />
K. Myung, J. Manthey, S. Sturla,<br />
Organizers, Presiding<br />
8:30 35. Role of lipoproteins on the biological<br />
activity and pharmacokinetics of hydrophobic<br />
drugs. K. M. Wasan<br />
9:05 36. Interactions of dietary supplement<br />
mixtures and pure compounds on phase I<br />
drug metabolism. D. J. Kroll<br />
9:40 37. Impact of food on the function of<br />
oral drug delivery systems. R. L. Carrier<br />
10:15 Intermission<br />
10:35 38. Transporter-mediated drug-herb<br />
and drug-food interactions. M. E. Morris<br />
11:10 39. Mechanisms of cytochrome P450mediated<br />
food-drug interactions: Mechanism-based<br />
inactivators and the grapefruit<br />
juice effect. P. Hollenberg<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
Improving Drug Candidates by Design: A<br />
Focus on Physical Properties to Improve<br />
Disposition and Safety Cosponsored by<br />
MEDI<br />
N. Meanwell, F. Guengerich, Organizers,<br />
Presiding<br />
1:30 Introductory Remarks<br />
1:35 40. Physicochemical and pharmacological<br />
properties as predictors of drug<br />
safety and success. J. Empfield<br />
2:25 41. Aromatic ring count and compound<br />
developability. S. J. Macdonald,<br />
T. J. Ritchie, R. Young, A. Hill<br />
3:15 Intermission<br />
3:30 42. Molecular matched pairs derived<br />
QSAR for the optimization of ADMET<br />
properties. S. Johnson, M. Davis,<br />
S. Posy, B. Claus<br />
4:20 43. Moving beyond rules: The development<br />
of a central nervous system multiparameter<br />
optimization (CNS MPO) approach<br />
to enable alignment of drug-like<br />
properties. T. T. Wager,X.Hou,<br />
P. R. Verhoest, A. Villalobos<br />
TUESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 210A/B<br />
General Posters<br />
K. Mitra, Organizer<br />
6:30–8:30<br />
44. Affinity purification of kidney enzymes<br />
that bind mercapturic acids. E. Veldman,<br />
P. Josephy<br />
45. Translesion synthesis past the �-radiation-induced<br />
guanine- thymine intrastrand<br />
crosslink G[8,5-Me]T.<br />
P. Raychaudhury,A.K.Basu<br />
46. Structural studies of a repair-resistant<br />
dibenzo[a,l]pyrene-derived DNA adduct<br />
in a nucleosome. Y. Cai, N. E. Geacintov,<br />
S. Broyde<br />
47. Base flipping free energy profiles for<br />
damaged DNA. H. Zheng,Y.Cai,<br />
Y. Zhou, S. Wang, N. E. Geacintov,<br />
S. Broyde, Y. Zhang<br />
48. Experimental approach to enhance parent<br />
ion fragmentation for metabolite identification<br />
studies: Application of stepped<br />
CID and HCD in an Orbitrap-XL.<br />
J. L. Bushee, U. A. Argikar<br />
49. Effects of pharmaceutical excipients on<br />
4-methyl umbelliferone glucuronidation:<br />
An application for compounds with low<br />
solubility. U. A. Argikar, G. Liang,<br />
J. L. Bushee, V. Hosagrahara, W. Lee,<br />
L. Shah, S. Garad<br />
50. Translesion synthesis past the 2,6-diamino-4-hydroxy-N<br />
5 -(methyl)-formamidopyrimidine<br />
(MeFAPy-dG) adduct in oligonucleotides<br />
by DNA polymerases and<br />
selective incision of the �-anomer of Me-<br />
FAPy-dG by Escherichia coli Endo IV.<br />
P. P. Christov, C. J. Rizzo<br />
51. Quinone-enhanced reduction of nitric oxide<br />
by xanthine/xanthine oxidase.<br />
A. E. Alegria, P. Sanchez-Cruz<br />
52. Quantification of four oxidized guanine<br />
lesions from reaction of DNA with 3-morpholinosydnonimine.<br />
L. Cui,<br />
E. G. Prestwich, L. J. Trudel,<br />
J. S. Wishnok, P. C. Dedon,<br />
S. R. Tannenbaum<br />
53. Quantitative mapping of cysteome for<br />
the protein S-nitrosylation.<br />
R. P. Chandrasena, G. T. Wijewickrama,<br />
V. Sinha, H. Xu, G. R. Thatcher<br />
54. Proteomic analysis of protein covalent<br />
modification by quinone methide-releasing<br />
drugs. S. C. Piyankarage, T. Dunlap,<br />
R. P. Chandrasena, G. R. Thatcher<br />
55. Genotoxicity screening validation using<br />
electro-optical and magnetic bioreactor<br />
arrays. L. Zhao,S.Pan,<br />
J. B. Schenkman, J. F. Rusling<br />
56. Characterization of a deoxyguanosine-lysine<br />
crosslink induced by methylgyoxal.<br />
K. V. Petrova, A. D. Millsap, C. J. Rizzo<br />
57. Metabolic profiling of mitochondrial dysfunction.<br />
Q. Xu, H. Vu, W. H. Schaefer,<br />
L. Liu, J. Monroe, C. Chiu<br />
58. Evaluation of 9,12-dioxo-10(E)-dodecenoic<br />
acid and 4-oxo-2(E)-nonenal derived<br />
lysine adducts as potential biomarkers of<br />
inflammation. F. Li, E. Iffrig, C. Knutson,<br />
J. S. Wishnok, S. R. Tannenbaum<br />
59. Utility of hepatocyte bioreactor proteomics<br />
for identification of drug-induced liver<br />
toxicity. V. Brahmbhatt,A.Dash,<br />
S. W. Inman, L. Griffith,<br />
S. R. Tannenbaum<br />
60. Assembly and characterization of a system<br />
for delivering biologically relevant<br />
levels of nitric oxide and oxygen for studies<br />
of inflammation. V. Dendroulakis,<br />
B. S. Russell, C. E. Elmquist, L. J. Trudel,<br />
G. N. Wogan, P. C. Dedon, W. M. Deen<br />
61. Quantitative profiling of serum bile acids<br />
by LC/MRM during liver tumor promotion<br />
associated with chronic Helicobacter infection<br />
and nuclear receptor deficiency.<br />
Y. Zeng, A. Garcia, J. S. Wishnok,<br />
J. G. Fox, S. R. Tannenbaum<br />
62. Cytotoxicity study of nanomaterials<br />
based on bioimpedance analysis and<br />
confirmed by cellular uptake.<br />
K. Kandasamy, M. Marimuthu, S. Kim<br />
63. DNA-protein cross-links mediated by hydrogen<br />
peroxide. E. K. Hawkins,<br />
C. J. Rizzo<br />
64. Metabolism of benzo[a]pyrene-7,8-dione<br />
in human lung cells. M. Huang, X. Liu,<br />
I. A. Blair, T. M. Penning<br />
65. Effects of cytosine methylation on O 6 -alkylguanine<br />
DNA alkyltransferase repair of<br />
O 6 -(pyridyloxobutyl)guanine adducts in<br />
CG dinucleotides. D. Kotandeniya,<br />
A. E. Pegg, N. Y. Tretyakova<br />
66. Detoxification of structurally diverse PAH<br />
o-quinones by human recombinant<br />
COMT via o-methylation of PAH catechins.<br />
L. Zhang, S. Bhat, I. A. Blair,<br />
T. M. Penning<br />
67. Changes in the spectrum of tRNA secondary<br />
modifications as biomarker signatures<br />
of exposure to toxic stimuli.<br />
C. Chan, M. Dyavaiah, K. Taghizadeh,<br />
T. J. Begley, P. C. Dedon<br />
68. Inhibition of 4-aminobiphenyl-induced<br />
DNA damage by Sulforaphane and 5,6-<br />
Dihydrocyclopenta[c]-dithiole-3(4H)thione<br />
in bladder cells and tissues.<br />
K. L. Randall, Y. Ding, J. D. Paonessa,<br />
D. Argoti, R. Munday, Y. Zhang,<br />
P. Vouros<br />
69. Oxidative stress-induced protein modification:<br />
Application of clickable linoleic<br />
acid analogs. P. Slade, R. Aggeler,<br />
T. Nyberg, C. Pikens, U. Singh, B. Agnew<br />
70. Paradoxical down-regulation of benzo-<br />
[a]pyrene-mediated DNA-adduct formation<br />
and concurrent up-regulation of glutathione-adduct<br />
formation by 2,3,7,8tetrachlorodibenzo-p-dioxin<br />
in human<br />
lung cells. S. L. Gelhaus, T. M. Penning,<br />
I. A. Blair<br />
71. Stable isotope dilution HPLC-ESI - -<br />
MS/MS analysis of urinary butadiene metabolites<br />
as biomarkers of exposure to<br />
1,3-butadiene. S. Kotapati, B. A. Matter,<br />
D. Sangaraju, N. Y. Tretyakova<br />
72. Sensitive liquid chromatography/mass<br />
spectrometry method for the quantification<br />
of low levels of 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanol<br />
(NNAL) in<br />
urine of non-smokers. S. H. Bhat,<br />
S. L. Gelhaus, C. A. Mesaros, I. A. Blair<br />
73. Persistent ROS generation in H358 cells<br />
treated with PAH-o-quinones. S. S. Basu,<br />
S. L. Gelhaus, M. Huang, T. Penning,<br />
I. Blair<br />
74. Identification of tyrosine chlorination<br />
sites in human serum albumin for potential<br />
inflammatory disease biomarker discovery.<br />
P. Kang, Y. Zeng, J. S. Wishnok,<br />
S. R. Tannenbaum<br />
75. Total synthesis of Aristolochic acidsI&II<br />
and their derivatives. S. Attaluri,<br />
R. R. Bonala, F. Johnson<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
76. Quantification of the 2-deoxyribonolactone<br />
and nucleoside 5�-aldehyde products<br />
of 2-deoxyribose oxidation in DNA<br />
and cells by isotope-dilution gas chromatography<br />
mass spectrometry. W. Chan,<br />
P. Dedon<br />
77. Activity-based serum protease profiling<br />
for biomarkers of chronic inflammation.<br />
U. Sarkar, C. G. Knutson, J. S. Wishnok,<br />
S. R. Tannenbaum<br />
78. Mass spectrometric detection of hemoglobin<br />
adducts from the anti-HIV drug nevirapine<br />
and its metabolite 12-hydroxynevirapine<br />
in rats. M. Marques,<br />
A. L. Godinho, M. Oliveira, S. A. Pereira,<br />
E. C. Monteiro, F. A. Beland,<br />
A. M. Antunes<br />
79. Mechanistic studies on the biotransformation<br />
of BMS-690514, an ErbB/VEGF<br />
tyrosine kinase inhibitor, to metabolite<br />
M1. H. Hong, J. Caceres-Cortes, H. Su,<br />
X. Huang, S. Bonacorsi, Y. Hong, Y. Tian,<br />
R. A. Iyer, W. G. Humphreys,<br />
L. J. Christopher<br />
80. Systematic study of 2�-deoxyoxanosine<br />
formation during nitrosative deamination<br />
of 2�-deoxyguanosine under biologically<br />
relevant conditions. P. Lonkar,<br />
J. L. McFaline, P. C. Dedon<br />
81. NMR structure of duplex DNA having a<br />
�-carba-fapy-dG residue. T. Zaliznyak,<br />
M. Lukin, S. Attaluri, R. R. Bonala,<br />
F. Johnson, C. De los Santos<br />
82. New mass spectrometry based method<br />
for quantifying protein thiol modification<br />
in response to nitrosative and oxidative<br />
stress. V. Sinha, G. T. Wijewickrama,<br />
R. P. Chandrasena, I. T. Schiefer,<br />
G. R. Thatcher<br />
83. Conformational effects of C8-arylguanine<br />
substitution on B/Z-DNA in oligonucleotides<br />
with one modified base. B. C. Train,<br />
V. Vongsutilers, D. J. Phillips,<br />
P. M. Gannett<br />
84. Trapping of a catechol estrogen quinone<br />
by GSH is reversible and does not block<br />
estrogenic activity: Problematic detoxification<br />
of 4-hydroxyequilenin by GSH<br />
conjugate formation. K. Peng, M. Chang,<br />
Y. Wang, Z. Wang, Z. Qin, J. L. Bolton,<br />
G. R. Thatcher<br />
85. Fluorescent probe for direct detection of<br />
hypoxia. A. M. Rajapakse, U. Sarkar,<br />
K. S. Gates<br />
86. Estimating the interactions of signaling<br />
proteins in response to increasing dose.<br />
H. N. Williams, J. N. Rubenstein, X. Gao,<br />
A. C. Cook, J. W. Boyd<br />
87. Proteomic analysis of sera derived from<br />
patients with inflammatory bowel disease.<br />
C. G. Knutson, J. R. Korzenik,<br />
J. S. Wishnok, S. R. Tannenbaum<br />
88. Competitive removal of oxidatively generated<br />
guanine lesions in DNA by NER<br />
and BER in human cell extracts.<br />
K. Y. Kropachev, M. Kolbanovsky,<br />
V. Y. Shafirovich, N. E. Geacintov<br />
89. Human NER recognition mechanisms involving<br />
the undamaged strand of the<br />
double helix. Y. Chen, K. Y. Kropachev,<br />
Z. Liu, M. Kolbanovsky, N. E. Geacintov<br />
90. Solution conformations of the major (�)trans-anti-BPDE-N<br />
2 -guanine adduct opposite<br />
an abasic site in a DNA duplex.<br />
Z. Liu, C. Lin, L. Jia, S. Ding, A. Schwaid,<br />
S. Broyde, N. E. Geacintov<br />
91. Using Saenger sequencing to analyze<br />
base-sequence effects on in vitro translesion<br />
bypass catalyzed by a Y-family polymerase:<br />
Dpo4. Y. Lee, A. Kolbanovsky,<br />
S. Broyde, N. E. Geacintov<br />
92. DNA adducts formed from different metabolic<br />
pathways of 3,5-dimethylaniline.<br />
W. Ye, P. L. Skipper, L. Cui,<br />
J. S. Wishnok, S. R. Tannenbaum<br />
93. Lipoxygenase metabolites from cyclooxygenases.<br />
X. Liu, C. Mesaros,<br />
I. A. Blair<br />
94. Acetyl cysteine adducts of eicosatetraenoic<br />
acids: Synthesis, characterization,<br />
and identification in smoker’s urine.<br />
J. S. Arora, S. Zhang, I. A. Blair<br />
95. Quantification of urinary eicosanoids by<br />
liquid chromatography/mass spectrometry.<br />
C. A. Mesaros, I. A. Blair<br />
96. Nitrenium ion stability of aryl-amines.<br />
L. Whitehead, P. McCarren,<br />
G. Bebernitz, M. Grondine, L. Kirman,<br />
H. Schuster, J. Klickstein, S. Glowienke,<br />
P. Gedeck<br />
97. Quantitation of aristolochic acid adducts<br />
in murine DNA. K. A. Conlon,<br />
T. A. Rosenquist, C. R. Iden<br />
98. Sequence-context dependent recognition<br />
and repair of aristolochic acid-DNA<br />
adducts. J. Yeo, R. R. Bonala, S. Attaluri,<br />
I. Izaitseva, F. Johnson, C. R. Iden,<br />
O. D. Scharer<br />
99. Predicting mutagenicity of aromatic<br />
amines using hierarchical support vector<br />
regression approach. M. K. Leong,<br />
S. Lin, H. Chen<br />
100. Trapping reversible ortho-quinone methide<br />
- nucleoside adducts.<br />
M. P. McCrane, O. Ad, E. E. Weinert,<br />
Y. Ling, E. P. Mazzola, Y. Lam,<br />
S. E. Rokita<br />
101. Non-mutagenic bypass of a photodimer<br />
of T-methylC in DNA by yeast polymerase<br />
eta. Q. Song, J. Taylor<br />
102. Generation and investigation of the C3�deoxy-3�-thymidinyl<br />
radical in singlestranded<br />
oligonucleotides. B. Abdallah,<br />
A. Bryant-Friedrich<br />
103. Synthesis of a [3- 15 N]-5-methylcytosine<br />
cyclobutane pyrimidine dimer-containing<br />
DNA decamer for tautomerization and<br />
base pairing studies. R. E. Wang,<br />
J. L. Kao, J. Taylor<br />
104. Reactivity and stability of the 5�-aldehyde<br />
in DNA. S. A. Abdallah,<br />
A. C. Bryant-Friedrich<br />
105. Exploring the link between urban aerosols<br />
and DNA adducts using capillary<br />
nanoLC-ESI-MS/MS. J. J. Klaene,<br />
J. Glick, E. G. Stephanou, P. Vouros<br />
106. Biotransformation of epo-folate conjugate<br />
(BMS-753493). X. Gu, Y. Zhang,<br />
C. Darienzo, Y. Tian, Y. Hong,<br />
S. Bonacorsi, W. G. Humphreys,<br />
R. A. Iyer<br />
107. Structural studies of exocyclic deoxyadenosine<br />
adducts of 1,2,3,4-diepoxybutane.<br />
E. A. Kowal, U. Seneviratne,<br />
N. Tretyakova, M. P. Stone<br />
108. High-throughput screening of organophosphate<br />
antidotes in a zebrafish<br />
model. S. Jin, R. Peterson<br />
109. Phenotyping human livers for repair of<br />
O 6 -methylguanine and O 6 -[4-oxo-4-(3pyridyl)butyl]guanine<br />
adducts by O 6 -Alkylguanine-DNA<br />
alkyl-transferase.<br />
J. K. Warmka, Q. Fang, A. M. Urban,<br />
A. E. Pegg, L. A. Peterson<br />
110. Role of pyridyloxobutyl DNA adducts in<br />
nitrosamine-induced cancers.<br />
A. M. Urban, P. Upadhyaya,<br />
L. A. Peterson<br />
111. Investigation of cytotoxic and mutagenic<br />
effects of O 2 -methylthymine, a minor-groove<br />
DNA adduct. N. Andersen,<br />
J. Wang, Y. Wang<br />
112. Quantification of 8-5�-cyclo-2�-deoxyguanosine<br />
and 8-5�-cyclo-2�-deoxyadensosine<br />
in calf thymus DNA treated<br />
with Fenton Reagents. C. R. Guerrero,<br />
Y. Wang<br />
113. Role of carcinogen-induced conformational<br />
heterogeneity in translesion synthesis.<br />
B. P. Cho, V. Ganesan<br />
114. Spectroscopic and thermodynamic insights<br />
into sequence effects of<br />
2-acetylaminofluorene-induced conformational<br />
heterogeneity. B. P. Cho,<br />
S. Patnaik<br />
115. Long-range sequence effect on the<br />
arylamine-induced conformational heterogeneity.<br />
V. Jain, B. P. Cho, S. Patnaik,<br />
V. Ganesan, E. Darian, A. D. MacKerell<br />
116. Defining the role of RNA secondary<br />
modifications in the response of microbial<br />
pathogens to chemical mediators of inflammation.<br />
B. S. Russell, K. Lim,<br />
T. Chan, J. G. Fox, P. C. Dedon<br />
117. Alterations in the serum metabolome induced<br />
by chronic inflammation.<br />
E. G. Prestwich, I. Babu, K. Taghizadeh,<br />
P. C. Dedon<br />
118. Antioxidant activity of some wines produced<br />
in Moldova and their related ability<br />
to bind N-nitrosamine precursors.<br />
D. Porubin<br />
119. Differences in detailed chemistries<br />
among cigars and cigarettes and their<br />
potential relevance to the toxicological<br />
properties of mainstream cigar smoke.<br />
J. H. Lauterbach,D.A.Grimm<br />
120. Genetic toxicity of Fe3O4 nanoparticles.<br />
B. Wang, X. Meng, W. Yue, X. Bi<br />
121. Assessment of non-occupational exposure<br />
to polycyclic aromatic hydrocarbons<br />
through personal air sampling and urinary<br />
biomonitoring. Z. Li, J. A. Mulholland,<br />
L. C. Romanoff, E. N. Pittman,<br />
D. A. Trinidad, A. Sjodin<br />
122. Bridging health effects of chlorine exposures<br />
and therapy with chemistry: Toward<br />
a mechanism-oriented therapy for<br />
chlorine exposures. G. L. Squadrito,<br />
E. M. Postlethwait, S. Matalon<br />
123. Biological oxidant damage of engineered<br />
nanomaterials: Relationship with<br />
physicochemical properties. D. Bello,<br />
S. Hsieh, D. Schmidt, A. K. Pal, E. Rogers<br />
124. Biosimulation of acetaminophen-induced<br />
liver injury using the Entelos Physiolab<br />
platform. H. J. Clewell, B. Howell,<br />
S. Siler, R. Ho, A. Harrel, M. Andersen,<br />
P. Watkins<br />
125. Nuclear magnetic resonance- (NMR-)<br />
based study of post-mortem urines of<br />
opioid overdosed patients: Scope and<br />
limitations of the technique. G. Proni,<br />
N. Tan, D. K. Wilson, E. Champeil,<br />
B. S. Levine<br />
126. Role of lipid oxyl and peroxyl radicals in<br />
oxidative damage to guanine and 8-oxoguanine<br />
bases in DNA. J. Shao,<br />
N. E. Geacintov, V. Shafirovich<br />
127. Acute toxicity, biochemical responses<br />
and gene expression responses in Eisenia<br />
fetida exposed to polycyclic musks.<br />
C. Chen,Q.Zhou<br />
128. Investigation of the non-covalent binding<br />
mode of leinamycin with doublestranded<br />
DNA. M. I. Fekry, K. S. Gates<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
Inflammation Biomarkers and Interventions<br />
<strong>Chemical</strong> Mechanisms and Biomarkers<br />
P. Dedon, Organizer<br />
S. Tannenbaum, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:40 129. <strong>Chemical</strong> biology of NO in mechanisms<br />
of inflammation. D. Wink,<br />
C. Switzer, W. Flores-Santana, S. Glynn,<br />
L. Ridnour, R. Cheng<br />
9:10 130. Oxidation of DNA bases leading to<br />
mutagenic lesions. C. J. Burrows,<br />
A. M. Fleming, S. Kundu<br />
9:40 131. DNA damage and biomarkers of<br />
inflammation. A. R. Robinson, S. Gregg,<br />
J. S. Tilstra, P. Wipf, G. A. Garinis,<br />
P. D. Robbins, L. J. Niedernhofer<br />
10:10 Intermission<br />
10:30 132. Lipid oxidation and inflammation.<br />
I. Blair<br />
11:00 133. Chelation: The mechanism of action<br />
of AGE/ALE inhibitors. J. Baynes<br />
11:30 134. <strong>Chemical</strong> pathology of phagocyte<br />
activation. B. Shao, J. Heinecke<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 252B<br />
Inflammation Biomarkers and Interventions<br />
Translation and Intervention<br />
P. Dedon, S. Tannenbaum, Organizers,<br />
Presiding<br />
1:30 Introductory Remarks<br />
1:40 135. Proteomic analysis of inflammatory<br />
bowel disease. S. R. Tannenbaum,<br />
Y. Zeng, C. Knutson, A. Raczynski,<br />
J. S. Wishnok, J. Korzenik<br />
2:10 136. Hepatitis and liver disease.<br />
J. Groopman<br />
2:40 137. Inflammation and asbestos-associated<br />
diseases. B. Mossman,<br />
J. Hillegass, A. Shukla, M. MacPherson,<br />
S. Beuschel, S. Lathrop, T. Perkins,<br />
C. Steele<br />
3:10 Intermission<br />
3:30 138. Bioactive chlorinated lipids derived<br />
from plasmalemmal plasmalogens.<br />
D. Ford<br />
4:00 139. Cyclooxygenase-based anti-inflammatory<br />
drugs. L. Marnett,<br />
M. J. Uddin, B. C. Crews, P. J. Kingsley,<br />
A. L. Blobaum, D. W. Piston<br />
4:30 140. Nitric oxide-based drug development.<br />
L. Keefer<br />
CHAL<br />
Division of Chemistry<br />
and the Law<br />
J. Hasford, Program Chair<br />
SOCIAL EVENTS:<br />
Luncheon, 12:00-1:00 PM: Mon<br />
Reception, 5:00-8:00 PM: Mon<br />
BUSINESS MEETING:<br />
Executive Committee Meeting: Sun<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
Strengthening Your Patent Rights in Light<br />
of Recent Federal Circuit Court Decisions<br />
J. Hasford, Organizer<br />
10:00 Introductory Remarks<br />
10:05 1. Practitioners’ perspectives on 2010<br />
decisions from the U.S. courts.<br />
A. Ahmed, X. Pillai<br />
12:05 Panel Discussion<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
What Every Researcher Needs to Know<br />
About Patents: From Protecting Your<br />
Inventions to Careers in IP Law<br />
J. Hasford, Organizer<br />
J. Wager, A. Ahmed, Presiding<br />
TOXI/CHAL<br />
1:30 Introductory Remarks<br />
1:35 2. Best practices on protecting your invention.<br />
E. R. Gates<br />
2:20 3. Recent case law affecting chemical<br />
research. M. T. Siekman<br />
3:05 4. IP law career options for researchers.<br />
C. H. Baker<br />
3:50 Panel Discussion<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–31
CHAL/COLL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
Recent Trends in <strong>Chemical</strong> and<br />
Pharmaceutical Patent Law<br />
J. Hasford, Organizer<br />
S. P. Hasford, Presiding<br />
9:00 Introductory Remarks<br />
9:05 5. Hatch-Waxman: Interplay between<br />
drug development and lowering pharmaceutical<br />
costs. A. Ahmed<br />
9:35 6. Non-obviousness of chemical inventions.<br />
S. P. Hasford<br />
10:05 7. Defending against frivolous inequitable<br />
conduct allegations: Strategies for<br />
patent prosecution and litigation.<br />
J. J. Hasford<br />
10:35 8. “Written description” requirement<br />
after the Ariad case: What it is and what it<br />
means for pharmaceutical patent litigation.<br />
I. Poullaos<br />
11:05 9. Protecting against market erosion<br />
from generic entry: Authorized generics<br />
and reverse payments. J. T. Murata<br />
11:35 Panel Discussion<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
Identifying, Protecting and Enforcing<br />
Pharmaceutical Patent Rights in Solid<br />
Forms<br />
J. Hasford, Organizer<br />
1:00 10. Introduction to solid forms: What<br />
they are and why you should care.<br />
C. Bleczinski<br />
1:30 11. Problem solving with disordered<br />
solids: Latest developments with amorphous<br />
forms. I. Ivanisevic<br />
2:15 12. Problem solving with cocrystals:<br />
Primer and case studies. N. Schultheiss<br />
3:00 13. Patenting solid forms and protecting<br />
solutions to your solid form problems.<br />
E. Barash<br />
3:45 14. Litigating solid form patents: An expert’s<br />
tale. L. Chyall<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
H. Peters, S. Peters, J. Hasford, Organizers<br />
8:00–10:00<br />
15. Chocolate is the food of the gods — especially<br />
on Cunard’s Queen Mary 2.<br />
H. Peters, S. Peters<br />
16. National Inventors Hall of Fame.<br />
H. Peters, S. Peters<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
Recent Developments in Intellectual<br />
Property Law: Patents, Trade Secrets, and<br />
Trademarks<br />
32–TECH<br />
J. Hasford, Organizer, Presiding<br />
‡ Cooperative Cosponsorship<br />
9:30 Introductory Remarks<br />
9:35 17. Recent developments in U.S.<br />
Patent and Trademark Office patent practice.<br />
C. E. Van Horn<br />
10:05 18. Hot topics in chemical and pharmaceutical<br />
patent law. J. J. Hasford<br />
10:35 19. Recent developments in trade secret<br />
law. G. B. Price<br />
11:05 20. Trademark protection in the<br />
chemical, pharmaceutical and biotech industries.<br />
L. R. Robins<br />
11:35 Panel Discussion<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
The Lack of Legal and Forensic Suitability<br />
of Enzymatic Assaying for Blood Alcohol<br />
Concentrations in Prosecutions of Alleged<br />
Drunk Drivers<br />
J. Hasford, Organizer<br />
12:30 Introductory Remarks<br />
12:35 21. Enzymatic assaying: The indirect<br />
measurement that is non-specific to ethanol<br />
that is being misapplied from the clinical<br />
world into the forensic arena.<br />
J. McShane, A. Staubus, J. Citron<br />
2:05 Panel Discussion<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
Forensic Analysis: From Bench to<br />
Courtroom<br />
J. Hasford, Organizer<br />
R. Burks, Presiding<br />
3:00 Introductory Remarks<br />
3:05 22. The National Academy of Science<br />
report and forensic science education<br />
and research: Call to action. J. A. Siegel<br />
3:50 23. Communicating science in criminal<br />
court. C. Leonetti, R. Burks<br />
4:35 24. Crime laboratory vs. university research<br />
laboratory: Probing the differences<br />
in quality assurance programs.<br />
T. Reinholz<br />
5:20 Panel Discussion<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
Best Practices in Identifying, Protecting,<br />
and Managing Your Intellectual Property<br />
Portfolio<br />
J. Hasford, Organizer, Presiding<br />
9:00 Introductory Remarks<br />
9:05 25. Options for protecting your intellectual<br />
property. K. Bianco<br />
9:35 26. Identifying inventions — your own<br />
and others. M. Ali<br />
10:05 27. Protecting your intellectual property<br />
against third-party infringers and<br />
third-party patents. D. Main<br />
10:35 28. Managing your intellectual property.<br />
M. McGurk<br />
11:05 29. Maximizing the value of your intellectual<br />
property. I. Liu<br />
11:35 Panel Discussion<br />
A Small Business Guide to Intellectual<br />
Property Sponsored by SCHB, Cosponsored<br />
by CHAL and PROF<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
Developing and Losing Your Intellectual<br />
Property<br />
J. Hasford, Organizer<br />
1:30 Introductory Remarks<br />
1:35 30. What is patentable? How arguments<br />
on patentable subject matter affect<br />
anticipation and obviousness.<br />
J. T. Goodman<br />
2:20 31. Collaborations between industry<br />
and universities: Avoiding common —<br />
and often fatal — legal pitfalls.<br />
R. R. Micheletti<br />
3:05 32. Marked! Rising risks of false marking:<br />
Reducing your exposure.<br />
S. A. Brown<br />
3:50 33. IP perspectives: Discussion on developing<br />
and maintaining IP rights from<br />
corporate and academic perspectives.<br />
J. T. Goodman, R. R. Micheletti,<br />
S. A. Brown<br />
THURSDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
The Many Faces of CHAL: Where Chemistry<br />
Meets the Law<br />
J. Hasford, Organizer, Presiding<br />
9:30 Introductory Remarks<br />
9:35 34. Elements of patents. S. Martens<br />
10:05 35. Negotiating a patent: The art of<br />
Examiner interviews. S. Talapatra<br />
10:35 36. Nonobviousness of chemical inventions.<br />
B. C. Trinque<br />
11:05 37. IP due diligence: Who, what,<br />
where, when, and why? N. J. Uhlir<br />
11:35 Panel Discussion<br />
THURSDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 205C<br />
The Many Faces of CHAL: Where Chemistry<br />
Meets the Law<br />
J. Hasford, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 38. Inventorship issues in U.S. patent<br />
law. J. C. Lowe<br />
2:05 39. Importance of Markush structure<br />
searching for chemical entities.<br />
E. N. Cheeseman<br />
2:35 40. Withdrawn<br />
3:05 Panel Discussion<br />
COLL<br />
Division of Colloid and<br />
Surface Chemistry<br />
J. Texter, Program Chair<br />
SUNDAY MORNING<br />
Section A<br />
Westin Boston Waterfront<br />
Harbor Ballroom II<br />
Surface Chemistry and Environmental<br />
Applications of Nanoporous Materials<br />
W. Song, Organizer<br />
S. Larsen, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 1. Titanium dioxide nanotube photocatalysts<br />
for environmental remediation.<br />
K. J. Balkus, C. Ratanatawanate<br />
9:05 2. Nanostructured metal oxides’ fabrication<br />
and environmental applications.<br />
W. Li, C. Cao, S. Bian, L. Zhong,<br />
W. Song,L.Wan<br />
9:35 3. Dehydration, dehydroxylation, and<br />
rehydroxylation of single-walled aluminosilicate<br />
nanotubes. D. Kang,<br />
C. W. Jones, S. Nair<br />
9:50 4. Noble metal nanoflowers synthesized<br />
by novel approach based on pH dependent<br />
self assembly of surfactant and<br />
their extraordinary catalytic properties.<br />
A. Mohanty, N. Garg,R.Jin<br />
10:05 5. Degradation of azo dye in aqueous<br />
solution by novel catalysts of porous<br />
metal nanoparticles. Y. Sha,Q.Cui,<br />
J. Chen, Z. Gu<br />
10:20 Break<br />
10:40 6. Surface acidity of solid acid catalysts<br />
studied by solid-state NMR spectroscopy<br />
and theoretical DFT calculations.<br />
F. Deng<br />
11:10 7. Surface functionalization of zeolite<br />
nanostructures for renewable energy applications.<br />
G. Li, K. Dubois, E. Garcia,<br />
J. Agarwal, S. Bent<br />
11:40 8. Synthesis of nanocrystalline ZSM-5<br />
zeolite with controlled particle size and<br />
mesoporosity. A. Petushkov,<br />
S. C. Larsen<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterisla for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications Applications of Gold<br />
Nanoparticles<br />
R. Nagarajan, Organizer, Presiding<br />
8:30 9. Tagging single gold nanoparticles to<br />
lipids in living cell membranes.<br />
J. Rodríguez-Fernández,H.Ba,<br />
F. D. Stefani, J. Feldmann<br />
8:50 10. Competitive adsorption of thiolated<br />
polyethylene glycol and mercaptopropionic<br />
acid on gold nanoparticles probed<br />
by physical characterization methods:<br />
Application in targeted drug delivery.<br />
D. Tsai,F.W.DelRio,R.I.MacCuspie,<br />
T. Cho, M. R. Zachariah, V. A. Hackley<br />
9:10 11. Exploring the mechanism of formation<br />
of PAMAM – gold nanoparticle complexes.<br />
L. W. Hoffman,R.Knott,<br />
S. R. Clarke, N. H. Voelcker<br />
9:30 12. Kinetic studies of ligand exchange<br />
reactions on gold nanorods.<br />
R. D. Wampler, M. D. Porter<br />
9:50 13. Synthesis, characterization and<br />
properties of porous hollow Au nanoparticles.<br />
Y. Hao, C. Huang, J. Nyagilo,<br />
D. Dave, L. Xu, X. Sun<br />
10:10 14. Antibiotic mediated synthesis of<br />
gold nanoparticles with potent antimicrobial<br />
activity and their application in antimicrobial<br />
coatings. C. C. Perry,A.Rai,<br />
A. Prabhune<br />
10:30 15. Ultra-low fouling and functionalizable<br />
zwitterionic coatings onto gold and<br />
SiO 2 via a biomimetic adhesive group for<br />
sensing and detection in complex media.<br />
N. D. Brault, Q. Yu, S. Jiang<br />
10:50 16. Controlling the biochemistry of<br />
DNA functionalized gold nanoparticles for<br />
medical applications. A. E. Prigodich,<br />
C. A. Mirkin<br />
11:10 17. Supramolecular recognition-mediated<br />
control of gold nanoparticle toxicity<br />
inside the living cell using synthetic hostguest<br />
system. C. Kim, S. Agasti, Z. Zhu,<br />
L. Isaacs, V. Rotello<br />
11:30 18. Adsorption of water soluble thiols<br />
onto Au surfaces: Kinetics and applications.<br />
L. L. Rouhana, M. D. Moussallem,<br />
J. B. Schlenoff<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Formulation<br />
Formulating Nanoparticle and Structured<br />
Fluid Systems<br />
R. Y. Lochhead, Organizer<br />
M. W. Urban, Presiding<br />
8:30 Introductory Remarks<br />
8:40 19. Nanofluids for new materials and<br />
resins. J. Texter<br />
9:10 20. Pressure-driven assembly of spherical<br />
nanoparticles and formation of 1D<br />
nanostructure arrays. H. Wu,F.Bai,<br />
Z. Sun, R. E. Haddad, D. Boye, Z. Wang,<br />
H. Fan<br />
9:30 21. Tuning the dispersion of ligand-free<br />
ZnO quantum dots in solvents and polymers<br />
with electrostatically tethered nanoplatelets.<br />
D. Sun, W. Everett, H. Sue<br />
9:50 22. Coupling an oscillatory reaction to<br />
colloidal motion with diffusiophoresis:<br />
Swarm and disperse. M. E. Ibele,<br />
P. E. Lammert, T. E. Mallouk,<br />
V. H. Crespi, A. Sen<br />
10:10 23. Surfactant-free colloidal crystal<br />
based on ZnO quantum dots. X. Zhang,<br />
D. Sun, H. Sue<br />
10:30 24. Sonochemical formation of methyl<br />
hydroperoxide in polar aprotic solvents<br />
and its effect on single-walled carbon<br />
nanotube dispersion stability.<br />
M. W. Forney, J. C. Poler<br />
10:50 25. From spherical to asymmetric<br />
multi-phase colloidal nanoparticles and<br />
nanorods. D. Ramachandran,<br />
C. C. Corten, M. W. Urban<br />
11:10 26. Real time monitoring of the shape<br />
evolution and cancer therapeutic application<br />
of branched gold nanostructure.<br />
D. Senapati,A.K.Singh,P.C.Ray<br />
11:30 27. Influence of sensory perception<br />
on consumer perceptions of liking and<br />
performance. G. Civille<br />
11:50 28. Determination of the wetted surface<br />
area of suspensions of active pharmaceutical<br />
ingredients (API) using nuclear<br />
magnetic resonance. D. Fairhurst,<br />
T. Cosgrove<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal<br />
Interfaces and Adhsion<br />
H. Dodluk-Kenlg, R. Nagarajan, Organizers<br />
V. S. Gutowski, Organizer, Presiding<br />
8:30 Laudation<br />
8:40 Four Decades of Romance with Adhesion<br />
Science - K. L. Mittal<br />
9:10 29. Study of metal-polymer interfaces:<br />
Relevance to adhesion. J. F. Friedrich<br />
9:50 30. Measurement of lateral adhesion<br />
forces at the interface between a liquid<br />
drop and a substrate. R. Tadmor<br />
10:10 31. Girifalco: Good analysis of fluoroalkylated<br />
silicon-containing surfaces.<br />
S. S. Chhatre, J. O. Guardado,<br />
B. M. Moore, J. M. Mabry,<br />
G. H. McKinley, R. E. Cohen<br />
10:30 32. Characterizing surfactant distributions<br />
in pressure sensitive adhesive films<br />
using atomic force microscopy and confocal<br />
Raman microscopy. J. Zhang,<br />
H. Xu, J. Zhang, S. Severtson<br />
10:50 33. Ambient condition characterization<br />
of rock/fluids interactions for a GOM<br />
(Gulf of Mexico) deepwater offshore oil<br />
field. D. Saini, D. N. Rao<br />
11:10 34. Use of SPM in the study of particle<br />
adhesion in pharmaceutical systems:<br />
Adhesion mapping. F. M. Etzler<br />
11:30 35. Self-cleaning photovoltaic panels<br />
with integrated transparent electrodynamic<br />
screens: Dust adhesion and removal<br />
mechanism. M. K. Mazumder,<br />
M. N. Horenstein, D. Jackson, J. Stark,<br />
S. Blumenthal<br />
Section E<br />
Westin Boston Waterfront<br />
Lewis<br />
Nano Letters: The Next Ten Years<br />
Nanomaterials and Biology<br />
P. Alivisatos, C. Lieber, Organizers,<br />
Presiding<br />
P. A. Lewis, Presiding<br />
9:00 Introductory Remarks<br />
9:20 36. Future perspectives in nanotechnology.<br />
I. Willner<br />
10:00 37. Bioactive nanostructures for regeneration.<br />
S. I. Stupp<br />
10:40 38. Semiconductor nanomaterials for<br />
bio-integrated electronics. J. A. Rogers<br />
11:20 39. Towards a desktop fab: Polymer<br />
pen lithography and beam pen lithography.<br />
C. Mirkin<br />
Operando and In Situ Spectroscopy<br />
X-ray Methods Sponsored by CATL<br />
(probationary), Cosponsored by COLL, FUEL,<br />
and PETR<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Surface Characterization Techniques and<br />
Surface-Involved Reactions Sponsored by<br />
ENVR, Cosponsored by COLL and GEOC<br />
SUNDAY AFTERNOON<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
Detection of Biomolecules and Cells<br />
R. Nagarajan, Organizer, Presiding<br />
P. Ray, Presiding<br />
1:30 40. Real time detection of biomolecules<br />
using nanoparticle-based clusters.<br />
A. L. Stadler,C.Chi,O.Gang,<br />
D. van der Lelie<br />
1:50 41. <strong>Chemical</strong> approaches to glucose<br />
detection using the near-infrared fluorescence<br />
from single-walled carbon nanotubes.<br />
H. Yoon, P. W. Barone, J. Ahn,<br />
M. S. Strano<br />
2:10 42. Nanointerface modulation of singlewalled<br />
carbon nanotube for detection of<br />
ATP and nitric oxide in living cells. J. Kim,<br />
J. Ahn, P. W. Barone, J. Zhang,<br />
M. S. Strano<br />
2:30 43. Design of single plasmonic nanoparticle<br />
probes for study of multidrug<br />
membrane transporters of single living<br />
cells. X. Xu, P. Nallathamby, K. Lee,<br />
T. Huang<br />
2:50 44. Application of bioorthogonal tetrazine<br />
chemistry to nanoparticle based<br />
cell detection. N. K. Devaraj,J.B.Haun,<br />
R. Weissleder<br />
3:10 45. Surfactant self-assembling sol gel<br />
synthesis of zirconium dioxide as an effective<br />
electrode material for the detection<br />
of neurotransmitters. Y. Chen,<br />
Y. Song, S. K. Lunsford, D. D. Dionysiou<br />
3:30 46. Colorimetric bacteria sensing using<br />
a hybrid enzymatic nanocomposite biosensor.<br />
O. R. Miranda, X. Li, Z. Zhu,<br />
B. Yan, U. H. Bunz, V. M. Rotello<br />
3:50 47. Rapid identification and targeted<br />
photothermal lysis of salmonella bacteria<br />
using bioconjugated gold nanoparticle.<br />
P. C. Ray<br />
4:10 48. Array based sensing of proteins in<br />
human serum using nanoparticle-green<br />
fluorescent protein conjugates. S. Rana,<br />
M. De, O. R. Miranda, U. H. Bunz,<br />
V. M. Rotello<br />
4:30 49. Spatial addressing of neurotransmitters<br />
for G-protein coupled receptors.<br />
W. Liao, H. Cao, P. S. Weiss,<br />
A. M. Andrews<br />
4:50 50. Nanopatterned polymer film arrays<br />
with high surface area for peptide sensing.<br />
R. B. Pernites, R. Ponnapati,<br />
R. C. Advincula<br />
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Formulation<br />
Surfaces, Surfactants and Emulsions<br />
R. Y. Lochhead, Organizer<br />
A. J. Olenick, Presiding<br />
1:30 51. Photooxidation of nanopatterned<br />
poly(chloromethylstyrene): Direct formation<br />
of crosslinked aldehyde-functionalized<br />
films for chemical functionalization<br />
and bioconjugation. X. Yu, C. Subramani,<br />
X. Yang, C. Kim, V. M. Rotello<br />
1:50 52. Self-assembly monolayers of cysteamine<br />
on nanostructured Ag films for<br />
SERS sensing of perchlorate and its<br />
SERS enhancement mechanism. J. Hao,<br />
M. Han, Z. Xu, X. Meng<br />
2:10 53. Prospects for computational formulations<br />
design. J. Fraaije, S. McGrother,<br />
S. Nath<br />
2:30 54. Formulation and evaluation of multicomponent,<br />
multiphase systems by<br />
combinatorial liquid handling techniques.<br />
R. Y. Lochhead<br />
2:50 55. Formulating cleansers for sensitive<br />
skin: Creating a skin compatible cleanser<br />
with hydrophobically modified polymers.<br />
L. Gandolfi, R. Walters, N. Tierney,<br />
M. Fevola<br />
3:10 56. Relation of hair ellipticity to ethnicity<br />
and hair combing. A. N. Syed,<br />
T. Ventura, R. A. Khan, M. N. Syed<br />
3:30 57. Self-assembly of functional homopolymers.<br />
J. Kim,S.T.Nguyen<br />
3:50 58. Multidomain alkyl silicones in formulations.<br />
T. O’Lenick, T. O’Lenick<br />
4:10 59. Physical blends of silica sol and<br />
polymer latex: Effects on coating process<br />
and performance. G. Darr, E. W. Davis<br />
4:30 60. Impact of phase changes on emulsion<br />
phase inversion during emulsification<br />
and evaporation. Y. Liu, S. E. Friberg<br />
4:50 61. Efficient emulsification using<br />
poly(2-(dimethylamino)ethyl methacrylate)-grafted<br />
nanoparticles, poly(ethylene<br />
oxide) star polymers or their mixtures.<br />
T. Saigal, D. Kloss, P. L. Golas, H. Dong,<br />
K. Matyjaszewski, R. D. Tilton<br />
5:10 62. Suppressing non-specific interactions<br />
between solid surfaces used for single-molecule<br />
force measurements.<br />
S. Upadhyayula,S.Bishop,N.Johnson,<br />
S. Gupta, V. Vullev<br />
5:30 Concluding Remarks<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal Surface<br />
Modification<br />
H. Dodluk-Kenlg, V. S. Gutowski, R.<br />
Nagarajan, Organizers<br />
J. Friedrich, Presiding<br />
1:30 63. Controlled plasmachemical functionalization<br />
of polymer surfaces for adhesion<br />
and liquid repellency. J. S. Badyal<br />
2:10 64. Surface modification of ABS for<br />
electroless Cu plating without Cr-etching<br />
and Pd catalyst. N. Inagaki<br />
2:40 65. Achieving nanoscale surface structure<br />
on polyester film by atmospheric<br />
pressure plasma treatment. W. I. Tsoi,<br />
C. Kan,C.M.Yuen,T.Tang<br />
3:00 66. Surface modification of fibrous<br />
polymers using pulsed UV-laser radiation.<br />
T. Bahners, E. Schollmeyer<br />
3:20 67. Aerosol-based DBD–asimpleway<br />
to provide polymers with functional<br />
groups for adhesion promotion. R. Mix,<br />
H. Yin, J. Friedrich<br />
3:40 68. Surface modification of wheat gluten<br />
films for improved water resistance.<br />
K. S. Johansson, H. Chen,<br />
J. Lindqvist Hofmann, A. Swerin,<br />
M. S. Hedenqvist, M. Dubreuil,<br />
D. Vangeneugden, M. Gaellstedt<br />
4:00 69. Effect of atmospheric pressure<br />
plasma treatment on interfacial adhesion<br />
between carbon fibers and polyimide.<br />
Y. Qiu<br />
4:20 70. Kinetics and properties of new silane<br />
based anti-corrosion coatings.<br />
J. G. Matisons, R. Goreham<br />
4:40 71. Predicting performance of natural<br />
fibre composites using scanning probe<br />
microscopy. A. A. Kafi, K. Magneiz,<br />
B. L. Fox<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom B<br />
Surface Chemistry and Environmental<br />
Applications of Nanoporous Materials<br />
S. Larsen, W. Song, Organizers<br />
G. Li, Presiding<br />
2:00 72. Molecular modeling and design of<br />
metal-organic frameworks for CO 2 capture.<br />
A. O. Yazaydin, Y. Bae, D. Yu,<br />
R. Q. Snurr<br />
2:30 73. Atomistic simulations of CO 2 and<br />
N 2 within zeolites. D. Kohen,L.Madison,<br />
H. Heitzer, C. Russell, K. Deeg,<br />
D. Walters<br />
3:00 74. Combining modeling and experiments<br />
to develop metal-organic framework<br />
materials for efficient adsorptionand<br />
membrane-based chemical separations.<br />
D. Sholl, T. van Heest,<br />
E. Haldoupis, T. Watanabe, S. Nair,<br />
M. Allendorf, S. Meek, J. Perry,<br />
J. Greathouse<br />
3:30 Intermission<br />
3:50 75. Diffusive flux of nanoparticles<br />
through porous membranes.<br />
J. R. Stephens, M. E. Williams<br />
4:05 76. Strain and surface dependant bacterial<br />
attachment of Pseudomonas<br />
aeruginosa to contact lens materials.<br />
V. B. Tran,C.J.Radke<br />
4:20 77. Self-cleaning conducting polymer<br />
surfaces: Reversible superhydrophobicto-superhydrophillic<br />
surfaces with electrochromic<br />
properties. R. Advincula<br />
4:35 78. Nanoporous inverse opal films on<br />
curved surfaces by colloidal Co-assembly.<br />
B. Hatton, L. Mishchenko,<br />
J. Aizenberg<br />
4:50 79. Enhanced hydrodechlorination of<br />
trichloroethylene in aqueous solution by<br />
supported polysugar-stabilized Pd nanoparticles.<br />
D. Bacik, M. Zhang, D. Zhao,<br />
C. Roberts<br />
Section E<br />
Westin Boston Waterfront<br />
Lewis<br />
Nano Letters: The Next Ten Years<br />
Energy and Electronics<br />
P. Alivisatos, C. Lieber, Organizers,<br />
Presiding<br />
P. A. Lewis, Presiding<br />
2:00 80. Role of nanoscience in future generation<br />
solar photon conversion cells for<br />
electricity and fuels. A. J. Nozik<br />
2:40 81. Nanoscience for energy and novel<br />
materials. Y. Cui<br />
3:20 Intermission<br />
3:40 82. Graphene and carbon nanotubes:<br />
Advances and prospects in electronics<br />
and photonics. P. Avouris<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
COLL<br />
TECH–33
COLL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
4:20 83. Nanoscale electronic materials:<br />
Challenges and opportunities. A. Javey<br />
5:00 84. Perspectives on carbon nanostructures<br />
research. M. S. Dresselhaus<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Metals and Metal Oxides Sponsored by<br />
ENVR, Cosponsored by COLL and GEOC<br />
MONDAY MORNING<br />
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Novel Model Systems for Bilayer Lipid<br />
Membranes<br />
Supported Membranes<br />
J. Robertson, K. Hristova, Organizers<br />
I. Koeper, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 85. Detecting ligand-receptor interactions<br />
on supported membranes by pH<br />
modulation. P. S. Cremer<br />
9:05 86. Xerogel, steps, and ethanol control<br />
phase behavior of supported lipid bilayers.<br />
M. L. Longo<br />
9:25 87. Quartz crystal microbalance with<br />
dissipation monitoring (QCM-D) studies<br />
of nonionic polymeric surfactant adsorption<br />
onto phospholipid bilayers.<br />
A. R. Esker, Q. Xie, P. Huffstetler, L. Huh,<br />
J. S. Riffle, R. D. Gandour<br />
9:45 88. Calcinated thin silicate films on Au<br />
for SPR biosensing with supported lipid<br />
membranes. Q. J. Cheng<br />
10:15 89. Novel electrodes for redox-active<br />
membrane enzymes. L. J. Jeuken,<br />
S. A. Weiss, N. N. Daskalakis,<br />
P. J. Henderson, S. D. Evans,<br />
R. J. Bushby<br />
10:45 90. Electrically addressable, biologically<br />
relevant surface supported bilayers.<br />
J. Lin, J. Szymanski, P. Searson,<br />
K. Hristova<br />
11:05 91. Lysophospholipid hydrolysis by<br />
neuropathy target esterase and its influence<br />
on the fluidity of reconstituted bilayer<br />
lipid membranes. A. J. Greiner,<br />
R. J. Richardson, R. M. Worden,<br />
R. Y. Ofoli<br />
11:35 92. Electric field induced build-up and<br />
separation of charged species in patterned<br />
supported bilayer lipid membranes.<br />
M. R. Cheetham, J. P. Bramble,<br />
B. R. Johnson, X. Han, L. J. Jeuken,<br />
P. D. Olmsted, S. D. Evans<br />
Section E<br />
Westin Boston Waterfront<br />
Lewis<br />
Nano Letters: The Next Ten Years<br />
Functional Nanomaterials<br />
P. Alivisatos, C. Lieber, Organizers,<br />
Presiding<br />
P. A. Lewis, Presiding<br />
8:30 93. Selective nanocatalysis of organic<br />
transformation by metals. G. A. Somorjai<br />
9:10 94. Single-molecule nanocatalysis.<br />
P. Chen<br />
9:50 95. Hybrid nanoparticle architectures:<br />
What’s next? U. Banin<br />
10:30 96. Towards assembly engineering:<br />
Designing patchy particles for self-assembly<br />
propensity. S. C. Glotzer<br />
11:10 97. Excited state dynamics in semiconducting<br />
and metallic quantum dots: A<br />
time-domain ab initio perspective.<br />
O. Prezhdo<br />
34–TECH<br />
‡ Cooperative Cosponsorship<br />
Section A<br />
Westin Boston Waterfront<br />
Harbor Ballroom II<br />
Surface Chemistry and Environmental<br />
Applications of Nanoporous Materials<br />
S. Larsen, Organizer<br />
W. Song, Organizer, Presiding<br />
9:00 98. Biocompatible mesoporous silica<br />
nanoparticles for cell type selective membrane<br />
transport and intracellular delivery.<br />
V. S. Lin<br />
9:30 99. Studies on the adsorption, encapsulation,<br />
and release of enzymes using<br />
nanoporous particles. C. Landry,<br />
S. Livingston, A. Clemments, B. Miller<br />
10:00 100. Interactions of an anticancer<br />
drug with zeolites and mesoporous silica.<br />
A. Datt, N. A. Dhuna, S. C. Larsen<br />
10:15 101. Development of bifunctional<br />
nanozeolites for targeted imaging applications.<br />
N. Ndiege, R. Raidoo,<br />
S. C. Larsen, M. Scultz<br />
10:30 Intermission<br />
10:50 102. Engineering nanospaces: Designing<br />
organic-inorganic hybrid materials.<br />
D. F. Shantz<br />
11:20 103. Synthesis of ordered mesoporous<br />
silicas with ultra-large mesopores.<br />
L. Huang, L. Cao, M. Kruk<br />
11:35 104. Porous organosilicas for concentration<br />
and detection of nitroenergetic<br />
and organophosphate compounds.<br />
B. J. Melde, B. J. Johnson, P. T. Charles,<br />
I. A. Leska, M. A. Dinderman,<br />
J. R. Deschamps<br />
11:50 105. Multimodal nanoimprinted polyethyleneimine<br />
template for nanoparticle<br />
assembly and immobilization.<br />
c. Subramani, Y. Ofir, D. Patra,<br />
B. J. Jordan, I. W. Moran, M. -. Park,<br />
K. R. Carter, V. M. Rotello<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
Nanoparticle-cell Interactions<br />
R. Nagarajan, Organizer, Presiding<br />
K. Hamad-Schifferli, Presiding<br />
9:00 106. Engineering the nanoparticle-biology<br />
interface. K. Hamad-Schifferli<br />
9:20 107. Dual ligand-presenting surfaces<br />
that can dynamically modulate cell behavior<br />
in situ. A. Pulsipher, S. Park,<br />
M. N. Yousaf<br />
9:40 108. Comparison of bactericidal activity<br />
against Escherichia coli of silver nanoparticles<br />
with chemical disinfectants.<br />
K. R. Chamakura, R. P. Ballestero,<br />
S. Bashir, J. Liu<br />
10:00 109. Using quartz crystal microbalance<br />
with dissipation monitoring<br />
(QCM-D) to predict antimicrobial peptide<br />
action on membranes. K. F. Wang,<br />
R. Nagarajan, C. Mello, T. A. Camesano<br />
10:20 110. Bacteria pattern spontaneously<br />
on periodic nanoscale structures.<br />
A. I. Hochbaum, A. Epstein, J. Aizenberg<br />
10:40 111. Lipid bilayer-coated mesoporous<br />
silica nanoparticles (MSNs): Highly modular<br />
synthesis for affecting cellular uptake,<br />
drug release, and intracellular fate of<br />
MSNs. R. A. Roggers,V.Lin<br />
11:00 112. In vivo targeting of fluorescent<br />
silica nanoparticles to ischemia. J. Kim,<br />
L. Cao, D. J. Mooney<br />
11:20 113. Investigation of threonine based<br />
nanotubes for the development of new<br />
antioxidant materials. S. N. Barnaby,<br />
K. R. Fath, I. A. Banerjee<br />
11:40 114. Antiseptic single wall carbon<br />
nanotube bandages. T. J. Simmons,<br />
S. Lee, T. Park, D. P. Hashim,<br />
P. M. Ajayan, R. J. Linhardt<br />
12:00 115. Functionality of multivalent cell<br />
adhesion ligands on viruses. L. Lee,<br />
Q. Wang<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal<br />
Contact Angle, Wettability and Adhesion<br />
V. S. Gutowski, R. Nagarajan, Organizers<br />
H. Dodluk-Kenlg, Organizer, Presiding<br />
9:00 116. To wet or not to wet? Stability,<br />
metastability and instability of contact angles.<br />
A. Marmur<br />
9:40 117. Solvation pressure between molecularly<br />
rough surfaces. A. V. Neimark<br />
10:00 118. Effects of equilibrium vapor adsorption<br />
on capillary force. S. H. Kim,<br />
M. P. de Boer<br />
10:20 119. Wetting behaviors on viscoelastic<br />
coating surface. G. Pu, S. Severtson<br />
10:40 120. Interpretation of contact angle<br />
data to estimate drop adhesion onto solid<br />
surfaces. A. Amirfazli<br />
11:00 121. Mechano-chemical properties of<br />
precursor films in electrowetting by molecular<br />
dynamics simulation. Y. Zhao<br />
11:20 122. Adhesion characterization of<br />
large area narrow band filters deposited<br />
by ion beam sputtering and e-gun evaporation.<br />
S. Scaglione, I. Di Sarcina,<br />
M. Grilli, F. Menchini<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Sorption Processes: From Treatment to<br />
Fate and Transport Sponsored by ENVR,<br />
Cosponsored by COLL and GEOC<br />
MONDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Harbor Ballroom II<br />
Surface Chemistry of Chiral Interfaces<br />
A. Gellman, Organizer<br />
D. Sholl, Organizer, Presiding<br />
2:00 123. Controlling the adsorption of prochiral<br />
reagents at chirally modified metal<br />
surfaces. A. G. Trant, K. E. Wilson,<br />
T. E. Jones, C. J. Baddeley<br />
2:30 124. Understanding enantioselectivity<br />
on chirally modified surfaces in ultrahigh<br />
vacuum. W. Tysoe<br />
2:55 125. Chiral surface chemistry in the environment.<br />
F. M. Geiger<br />
3:20 126. Chiral self-assembly on achiral<br />
surfaces: Insights from theory. T. Popa,<br />
I. Paci<br />
3:45 127. Atomic-scale studies of chiral<br />
metal surfaces. T. J. Lawton,<br />
A. E. Baber, V. Pushkarev, A. J. Gellman,<br />
E. H. Sykes<br />
4:10 128. Molecular modeling of enantioselective<br />
adsorption in homochiral metal-organic<br />
frameworks. X. Bao,<br />
L. J. Broadbelt, R. Q. Snurr<br />
4:35 129. Mechanistic study of asymmetric<br />
hydrogenation on chirally modified platinum.<br />
V. Demers-Carpentier,<br />
G. Goubert, G. Mahieu, J. Brunelle,<br />
Y. Dong, S. Lavoie, P. H. McBreen<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
Applications of Magnetic Nanomaterials<br />
R. Nagarajan, Organizer, Presiding<br />
2:00 130. Nanomedicine: Magnetic nanomaterials<br />
and nanotube for controlled<br />
drug release. V. Varadan<br />
2:20 131. Recent developments in the synthesis<br />
of magnetic nanoparticles for biomedical<br />
applications. N. T. Thanh<br />
2:40 132. Magnetic virus-like particles:<br />
Novel materials for biomedical applications.<br />
L. Bronstein, X. Huang,<br />
A. Malyutin, J. Dyke, E. Gunn, B. Stein,<br />
B. Dragnea<br />
3:00 133. Block copolymer-coated magnetic<br />
nanoparticles as hybrid systems for<br />
imaging and therapeutic applications.<br />
S. Louguet, C. Schatz, R. Epherre,<br />
S. Mornet, E. Duguet, S. Lecommandoux<br />
3:20 134. Responsive magnetic nanoparticles<br />
modified with mixed polymer brush.<br />
B. Zdyrko, M. Motornov, D. Pippalla,<br />
M. K. Kinnan, G. Chumanov, S. Minko,<br />
I. Luzinov<br />
3:40 135. Magnetic glyco-nanoparticles: A<br />
new tool for cancer cell studies.<br />
X. Huang, K. El-boubbou, M. El-dakdouki<br />
4:00 136. Synthesis of magnetic micro-particles<br />
using stop flow lithography. S. Suh,<br />
K. P. Yuet, D. Hwang, P. S. Doyle,<br />
T. A. Hatton<br />
4:20 137. Kinetic processes in the synthesis<br />
of size tunable magnetite nanoparticles<br />
for biomedical applications. B. Qi,<br />
O. T. Mefford<br />
4:40 138. Use of magnetite nanoparticles for<br />
various therapeutic applications.<br />
S. L. Saville, M. House, B. Qi,<br />
O. T. Mefford<br />
5:00 139. Stealth and functionalizable zwitterionic<br />
magnetic nanoparticles prepared<br />
by a one-step method for image-guided<br />
targeting drug delivery. L. Zhang,H.Xue,<br />
S. Jiang<br />
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Novel Model Systems for Bilayer Lipid<br />
Membranes<br />
Structure and Function<br />
I. Koeper, J. Robertson, Organizers<br />
K. Hristova, Organizer, Presiding<br />
2:00 Introductory Remarks<br />
2:05 140. Neutron reflectometry and offspecular<br />
scattering investigations of lipid<br />
membranes on thermo-responsive polymer<br />
cushion. J. Majewski<br />
2:35 141. pH-response of tethered membranes<br />
obtained by stepwise functionalization:<br />
Insights from X-ray and neutron<br />
reflectometry. B. Nickel, S. Hertrich,<br />
J. Rädler<br />
3:05 142. Poly(lipid) supramolecular assemblies:<br />
Structure, function, and bioanalytical<br />
applications. S. Saavedra<br />
3:35 143. Lipid bilayers immobilized on<br />
polyelectrolyte multilayer cushions.<br />
R. Krastev, J. Chen, T. Gutberlet<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
4:05 144. Tethered bilayer lipid membranes<br />
used to probe membrane-protein interactions<br />
in food science. I. Koeper<br />
4:25 145. Influence of an electric field on oriented<br />
films of DMPC/gramicidin bilayers:<br />
A circular dichroism and PM IRRAS<br />
study. J. Lipkowski, J. Fiche, T. Laredo,<br />
O. Tanchak, J. R. Dutcher<br />
4:55 146. Spontaneous membrane asymmetry<br />
in supported membranes formed<br />
by vesicle fusion. H. P. Wacklin<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal<br />
Contact Angle, Wettability and Adhesion<br />
H. Dodluk-Kenlg, V. S. Gutowski,<br />
R. Nagarajan, Organizers<br />
A. Marmur, Presiding<br />
2:00 147. Effect of nanostructure and composition<br />
of solid surfaces on ice adhesion.<br />
H. Dodiuk,S.Kenig,F.Rios<br />
2:40 148. Toward self-healing super-repellent<br />
surfaces. W. Ming<br />
3:00 149. Control of water droplet adhesion<br />
on paper/cellulose surfaces for the design<br />
of lab on paper devices. B. Balu,<br />
V. Breedveld, D. W. Hess<br />
3:20 150. Build up superlyophobic surfaces<br />
from fluorine-containing conductive polymers.<br />
F. Guittard, T. Darmanin,<br />
E. Taffin de Givenchy, S. Amigoni<br />
3:40 151. From superhydrophobicity and<br />
water repellence to superhydrophilicity:<br />
Smart polymer-functionalized surfaces.<br />
S. H. Anastasiadis, E. Stratakis,<br />
M. Barberoglou, V. Zorba, A. Mateescu,<br />
D. S. Achilleos, M. Vamvakaki, C. Fotakis<br />
4:00 152. Relationships between water wettability<br />
and ice adhesion. A. J. Meuler,<br />
J. D. Smith, K. K. Varanasi, J. M. Mabry,<br />
G. H. McKinley, R. E. Cohen<br />
4:20 153. Diverse approaches for creation of<br />
surfaces with gradient wettability to<br />
achieve liquid droplet movement.<br />
A. Athanassiou,<br />
F. Villafiorita Monteleone, F. Spano,<br />
D. Fragouli, R. Cingolani<br />
4:40 154. One-step fabrication of superhydrophobic<br />
coatings. D. K. Sarkar,<br />
S. Noormohammed<br />
5:00 155. Adsorption of trisiloxane surfactants<br />
on a liquid-air interface.<br />
N. A. Ivanova, R. G. Rubio, V. M. Starov,<br />
V. B. V.B. Fainerman<br />
Section E<br />
Westin Boston Waterfront<br />
Lewis<br />
Nano Letters: The Next Ten Years<br />
Functional Nanomaterials<br />
P. Alivisatos, C. Lieber, Organizers,<br />
Presiding<br />
P. A. Lewis, Presiding<br />
2:00 156. Functional hybrid nanomaterials<br />
via directed self-assemblies. T. Xu<br />
2:40 157. Dislocation-driven nanomaterial<br />
growth: Nanowire trees, nanotubes, and<br />
beyond. S. Jin<br />
3:20 Intermission<br />
3:40 158. Colloidal inorganic nanocrystals:<br />
Shape and evolution. C. J. Murphy<br />
4:20 159. Drying-induced self assembly of<br />
nanorods. E. Rabani<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
MONDAY EVENING<br />
Section A<br />
Westin Boston Waterfront<br />
Galleria Room<br />
Fundamental Research in Colloid and<br />
Surface Science<br />
J. Texter, Organizer<br />
6:00–8:00<br />
160. Analytical characterization of gold<br />
nanoparticle primary particles, aggregates,<br />
agglomerates, and agglomerated<br />
aggregates. A. M. Keene, K. M. Tyner<br />
161. Morphological control over Titanium<br />
Oxide precipitates using a biomimetic approach.<br />
S. Filocamo, R. Stote<br />
162. Chemoselective patterning strategies to<br />
study biomolecular interactions on gold<br />
surfaces. A. Pulsipher, M. N. Yousaf,<br />
N. P. Pulsipher, D. Dutta<br />
163. Model lipid bilayers as a platform for<br />
enzymology and chemoselective ligand<br />
immobilization. D. Dutta, A. Pulsipher,<br />
M. N. Yousaf<br />
164. Synthesis of nanoislands for plasmonics-based<br />
subdiffraction-limited imaging:<br />
Applications to visualization of endocytotic<br />
internalization of adenovirus. K. Kim,<br />
J. Choi, K. Ma, C. Yoon, D. Kim<br />
165. Gently lifting gold’s herringbone reconstruction<br />
by tuning adsorbate chemistry.<br />
A. D. Jewell, H. L. Tierney, E. V. Iski,<br />
A. E. Baber, D. O. Bellisario, E. H. Sykes<br />
166. Electrochemistry and fluorescence of<br />
chromophore-functionalized quantum<br />
sized gold clusters. K. Kwak,<br />
M. Devadas, J. Park, J. Choi, C. Jun,<br />
R. Guda, D. Lee<br />
167. Anomalous Raman scattering of NaYF 4:<br />
Yb 3� ,Er 3� nanophosphors and dynamic<br />
proof of size dependent upconversion luminescence.<br />
J. Shan,Y.Ju<br />
168. Role of gold nanoparticles in the photocatalytic<br />
reactions of TiO 2/Au nanocomposites.<br />
M. Lee,D.Lee<br />
169. Coating from human albumin plastic on<br />
titanium orthopedic implants.<br />
F. Vatansever, B. Zdyrko, S. Sharma,<br />
X. Li, X. Wen, I. Luzinov<br />
170. Grafted enrichment polymer layer system<br />
for waveguide sensor.<br />
J. M. Giammarco, B. Zdyrko, J. Hu,<br />
A. Agarwal, L. C. Kimerling, N. Carlie,<br />
L. Petit, K. Richardson, I. Luzinov<br />
171. Investigation and preparation of hydrolytically<br />
stable aminosilane-derived layers<br />
on silica. M. Zhu,W.Chen<br />
172. Tuning fluorescent response of ultrathin<br />
film by polymer grafting.<br />
M. Chyasnavichyus, B. Zdyrko,<br />
V. Tsyalkovsky, V. Klep, C. Hubert,<br />
L. Khulordava, I. Luzinov<br />
173. Morphological and spectral changes of<br />
anisotropic Ag nanoparticles induced by<br />
localized surface plasmon resonance.<br />
E. Kazuma, N. Sakai, T. Tatsuma<br />
174. Surface modification of nickel nanofibers<br />
with polymer grafting.<br />
Y. D. Galabura, R. Burtovyy, B. Zdyrko,<br />
A. Grigoryev, I. Tokarev, Y. Roiter,<br />
S. Minko, K. Kornev, I. Luzinov<br />
175. Identification and isolation of<br />
Au 40(SR) 24 from the core mass 8kDa gold<br />
nanoclusters. H. Qian,R.Jin<br />
176. Nano material based two-photon Rayleigh<br />
scattering probe for ultrasensitive<br />
and highly selective detection of Alzheimer’s<br />
disease biomarker. A. K. Singh,<br />
D. Senapati, P. C. Ray<br />
177. Optoelectronic property of 1D self-assembled<br />
�-conjugated oligopeptide<br />
nanostructure. Y. Sun, F. Boey, X. Chen<br />
178. 1D arrangement of Au nanoparticles<br />
with tunable interparticle distance.<br />
L. Jiang, J. Ma, F. Boey, X. Chen<br />
179. Hydrolytic and polymerization activities<br />
of engineered Endoglucanase immobilized<br />
on gold. I. Nakamura, Y. Horikawa,<br />
A. Makino, M. Ohmae, J. Sugiyama,<br />
S. Kimura<br />
180. Studying interactions of nanorodaptamer<br />
conjugates with proteins.<br />
H. de Puig Guixé,S.H.Baxamusa,<br />
M. Balcells, K. Hamad-Schifferli<br />
181. Functionalization of ferromagnetic cobalt<br />
nanoparticles via ligand exchange<br />
with polymeric ligands. H. Yoo,<br />
M. M. Bull, W. Chung, J. Pyun<br />
182. Stimuli-responsive gold nanoparticles/<br />
polymer assemblies. Z. Zhu,<br />
S. Sukhishvili<br />
183. Clay-containing responsive multilayers.<br />
A. Zhuk, S. Sukhishvili<br />
184. Surface-enhanced Raman spectroscopy<br />
at single sub-micron silver particles<br />
from shape-controlled synthesis.<br />
H. J. Bing<br />
185. Specific ion effects in emulsion coalescence.<br />
A. F. Dexter<br />
186. Solid-phase PCR using graft-copolymer-stabilized<br />
Au nanoparticles as primer<br />
supports. J. Kang, I. S. Marks,<br />
T. A. Taton<br />
187. Fluorescence resonance energy transfer<br />
between functionalized Coumarin<br />
dyes and gold nanoparticles.<br />
K. Coopersmith, M. Stobiecka, M. Hepel<br />
188. Detection of homocysteine based on<br />
gold nanoparticle plasmonic coupling<br />
monitored by elastic light scattering.<br />
M. Stobiecka, J. Deeb, M. Hepel<br />
189. Study of unique behavior of miscible<br />
and partially miscible systems using a<br />
spinning drop tensiometer. G. Viner,<br />
J. A. Pojman<br />
190. Peptide-surface biointerfaces.<br />
J. L. Kulp III, K. P. Fears,<br />
D. Y. Petrovykh, T. D. Clark<br />
191. Structural and NO x uptake properties of<br />
Fe-promoted NO x storage materials.<br />
E. Ozensoy, E. Kayhan, S. Andonova,<br />
G. Senturk<br />
192. New amphiphilic invertible polyesters:<br />
Synthesis and characterization. A. Kohut,<br />
I. Hevus, A. Voronov<br />
193. Preparation and properties of ZnO<br />
nanorods decorated with colloidal gold<br />
nanoparticles. J. Im,J.Singh,<br />
J. W. Soares, D. M. Steeves, J. E. Whitten<br />
194. Preparation and evaluation of pH dualresponsive<br />
nanoparticles. E. Mahmoud,<br />
J. Sankaranarayanan, D. Choi, E. Wang,<br />
G. Kim, A. Almutairi<br />
195. Fluorescent scaffold based on vaterite<br />
and water-soluble semiconductor quantum<br />
dots with potential for biosensing applications.<br />
R. Krishna Pai, M. Cotlet<br />
196. Spherical glycosurface assembling<br />
based on chemoselective and biocompatible<br />
immobilization and modification of<br />
intact liposome. Y. Ma, H. Zhang, X. Sun<br />
197. Surface-initiated ring-opening metathesis<br />
polymerization of low strain cyclic<br />
monomers for new materials synthesis.<br />
M. Z. Lerum,W.Chen<br />
198. Silica-based Janus nanoparticles simulated<br />
at the water-decane interface: Evidence<br />
of emergent behavior. H. Fan,<br />
A. Striolo<br />
199. Carbon dioxide and water corrosion of<br />
a single ZnO nanowire detected using<br />
second harmonic generation microscopy.<br />
K. A. Cimatu, K. A. Meyer, K. C. Ng,<br />
W. B. Whitten, R. W. Shaw<br />
200. Structure and orientation of hydrocarbon<br />
adsorbates at �-Al 2O 3 surfaces:<br />
Comparisons among vapor, liquid, and<br />
solvated interfaces studied by sum frequency<br />
generation. A. M. Buchbinder,<br />
E. Weitz, F. M. Geiger<br />
201. Stabilization of gold nanoparticles in solution<br />
by poly(vinyl alcohol) adsorption.<br />
L. Zhang,W.Chen<br />
202. Surface-initiated ring-opening metathesis<br />
polymerization (SiROMP) of cyclooctadiene<br />
(COD) and subsequent hydroxylation.<br />
M. N. Hang, M. F. Lerum,<br />
W. Chen<br />
203. Direct determination of the Tolman<br />
length from the bulk pressures of liquid<br />
drops via Molecular Dynamics simulations.<br />
A. E. van Giessen,E.M.Blokhuis<br />
204. Poly(vinyl alcohol) hydrogels as reaction<br />
matrices for diffusion-controlled reduction<br />
of tetrachloroauric acid.<br />
A. S. Erlwanger,W.Chen<br />
205. Withdrawn<br />
206. Glycosyl-nucleoside amphiphiles as<br />
components of nanostructured hydrogels<br />
with nucleic acid delivery capabilities.<br />
G. D. Godeau, J. Kaplan,<br />
P. A. Barthélémy, M. W. Grinstaff<br />
207. Smart functionalized polymer dispersions<br />
for selective adsorption to metal<br />
oxide surfaces: New concepts for corrosion<br />
protection. S. Toews, W. Bremser<br />
208. Investigating the adhesion forces and<br />
morphology of polyelectrolyte multilayers<br />
by atomic force microscopy. S. Ada,<br />
T. A. Camesano, S. A. Marcott, B. Nair,<br />
R. Nagarajan<br />
209. Friction of polyaromatic thiol self-assembled<br />
monolayers measured with friction<br />
force microscopy and the surface<br />
forces apparatus. Y. Yang,M.Ruths<br />
210. Atomic scale view of cobalt’s chemistry<br />
in alloys. E. A. Lewis,A.D.Jewell,<br />
H. L. Tierney, E. V. Iski, E. H. Sykes<br />
211. Magnetically vectored delivery of cancer<br />
drugs using remotely on-off switchable<br />
nanospheres. S. Kong, J. Lee,<br />
W. Zhang, M. Karin, S. Jin<br />
212. Polymerization powered microspheres.<br />
R. A. Pavlick, S. Sengupta,<br />
T. McFadden, A. Sen<br />
213. Hierarchical co-assembly of inverse<br />
photonic crystals. L. Mishchenko,<br />
B. Hatton, J. Aizenberg<br />
214. Structure and function of a membraneassociated<br />
biosurfactant produced by B.<br />
bacteriovorus. M. A. Ferguson,<br />
M. Wengen, E. M. Spain, M. E. Nunez<br />
215. Detection of pathogenic bacteria using<br />
siderophore patterned gold surfaces.<br />
W. A. Henne, D. D. Doorneweerd,<br />
R. G. Reifenberger, P. S. Low<br />
216. Water-induced superhydrophobicity<br />
with responsive polymer brushes on<br />
nanostructured surface. X. Wang,<br />
G. Qing, T. Sun<br />
217. Electrospun fibers assembled with multilayered<br />
TiO 2 nanoparticles for photochemical<br />
water remediation. J. Lee,<br />
Y. Nam, G. C. Rutledge, P. T. Hammond<br />
218. Heterostructured colloidal monolayers<br />
and hollow silica spheres: Nanoparticles<br />
as a versatile templating platform.<br />
M. Retsch, U. Jonas, E. L. Thomas<br />
219. Active chemotaxis of microparticles in<br />
response to ion gradients. A. Chertok,<br />
S. Sengupta, A. Sen<br />
220. Effect of specific anion on templated<br />
crystal nucleation at the liquid-liquid interface.<br />
P. Sanstead, S. Lee, J. Wiener,<br />
R. Bebawee, A. Hilario<br />
221. New porous reaction layer for developing<br />
addressable molecular libraries.<br />
L. Hu, K. D. Moeller<br />
222. Catalytic isomerization of allyl alcohols<br />
using ligand-stabilized Pd nanoparticles.<br />
E. Sadeghmoghaddam, Y. S. Shon<br />
223. Synthesis, characterization and Au surface<br />
tethering of Ti 16-oxo-alkoxy cages.<br />
S. Eslava, A. C. Papageorgiou,<br />
S. K. Beaumont, G. Kyriakou,<br />
D. S. Wright, R. M. Lambert<br />
224. Suspension microarray based on silica<br />
nanotube coded with quantum dots.<br />
Q. Fang, Y. Zhang, I. Hong, W. Yoon,<br />
H. Ju, S. Son<br />
225. Dual thermo- and pH-stimuli responsive<br />
copolymers based on acrylate monomers.<br />
M. A. Dergunov, S. A. Dergunov,<br />
O. Guven, E. Pinkhassik, G. A. Mun<br />
226. Partitioning of charged solutes supporting<br />
Overton’s rule: The wandering ion.<br />
P. B. Chatterjee, A. M. Trujillo,<br />
N. E. Levinger, D. C. Crans<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
COLL<br />
TECH–35
COLL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
227. Biologically catalyzed synthesis of zinc<br />
oxide nanoparticles in aqueous medium.<br />
J. Samson, A. Yampolsky,<br />
P. C. Nahirney, I. Piscopo, C. M. Drain<br />
228. Biomimetic fabrication of non-fluorinatedsuperhydrophobic-to-superhydrophillic<br />
conducting polymer surface<br />
with reversible wettability and electrochromic<br />
properties. R. B. Pernites,<br />
R. Ponnapati, R. C. Advincula<br />
229. Immobilized Cytochrome P450 enzymes:<br />
A construct to better predict invivo<br />
in-vitro correlation. L. Wollenberg,<br />
J. Kabulski, J. Jett, N. Wu, T. Tracy,<br />
P. M. Gannett<br />
230. AFM studies on Ag(I) complexes of G2<br />
PAMAM dendrimers. A. Jankovich,<br />
M. Chai<br />
231. Oxidative template for conducting polymer<br />
nanoclips. X. Zhang, Z. Liu,<br />
S. Poyraz, S. P. Surwade, S. K. Manohar<br />
232. Spherical polyelectrolyte brushes grafting<br />
from colloical polybutadiene particles<br />
by photoemulsion polymerization.<br />
S. Zhao, G. Li, J. Xu, X. Guo<br />
233. Solubilizing functionalized SWCNTs in<br />
water using hyper-branched PEI polymers.<br />
D. Holycross, M. Chai, L. Rakesh<br />
234. Characterization and tracking of monolayer-protected<br />
nanoparticles in biological<br />
systems using mass spectrometry.<br />
Z. Zhu, B. Yan, O. R. Miranda,<br />
R. W. Vachet, V. M. Rotello<br />
235. Interactions among spherical polyelectrolyte<br />
brushes observed by rheology and<br />
small angle X-ray scattering. F. Chu,<br />
W. Wang, L. Li, J. Xu, S. Wu, X. Guo<br />
236. Nanotemplates from porous molecular<br />
monolayers self-assembled at solid-liquid<br />
interfaces. M. Ai,S.Gröper, W. Zhuang,<br />
X. Feng, K. Müllen, J. Rabe<br />
237. Correlation between adhesion response,<br />
surface wettability and charge on<br />
biocompatible thermoresponsive<br />
brushes. E. Svetushkina, K. Grundke,<br />
M. Stamm, C. Bellmann, A. Förster,<br />
A. Synytska<br />
238. Synthesis and characterization of intelligent<br />
poly(methacrylic acid) hydrogels.<br />
H. Cheng, J. Xu, L. Li, X. Guo<br />
239. Electron tunneling through monolayers<br />
self-assembled on a hanging mercury<br />
drop electrode in the presence of aliphatic<br />
alcohols. E. Adaligil, K. Slowinski<br />
240. Thrombus-targeted theranostic nanoagents<br />
for fibrinolysis. J. R. McCarthy,<br />
I. Y. Sazonova, R. Weissleder, G. L. Reed,<br />
F. A. Jaffer<br />
241. Controlled aggregation of superparamagnetic<br />
iron oxide by electrostatic complexation.<br />
S. P. Nair, J. Dinglasan,<br />
D. J. Anderson<br />
242. Protein adsorption and exchange at the<br />
solid/liquid interface: A neutron reflectivity<br />
study. E. G. Latter,R.K.Thomas,<br />
J. Penfold<br />
243. Arsenic encapsulation in iron nanoparticles:<br />
Evidence of intraparticle reactions.<br />
W. Yan, M. A. Valencia Ramos,<br />
B. E. Koel, W. Zhang<br />
244. Role of cranberry juice cocktail on inhibition<br />
of urinary tract infections.<br />
Y. Zhang, Y. Tao, P. A. Pinzon-Arango,<br />
T. A. Camesano<br />
245. Stability of colloidal lipid nanosystems.<br />
S. Savarala, M. A. IIies, S. L. Wunder<br />
246. Disassembly of aggregated amphiphilic<br />
small molecule surfactant by phosphatase.<br />
N. Sekar, S. Thayumanavan<br />
247. Initial steps of biofilm formation of Listeria<br />
monocytogenes EGDe. F. P. Gordesli,<br />
N. I. Abu-Lail<br />
248. Fabricating Ag clusters on PVA films<br />
through fern-like crystalline templating.<br />
Y. Chan, W. Lin, J. Lin<br />
249. Reversible phase transition of polymer<br />
brushes prepared from dual-head initiator<br />
ATRP grafting poly(N-isopropylacrylamide)<br />
on silicate platelets. B. Hsieh,<br />
Y. Su, H. Lin, Y. Lan, Y. Chen, Y. Sheng,<br />
Y. Sheng, J. Lin, J. Lin<br />
36–TECH<br />
‡ Cooperative Cosponsorship<br />
250. Towards surface design to control crystallization:<br />
Understanding the roles of surface<br />
chemistry and morphology in heterogeneous<br />
nucleation. Y. Diao,<br />
A. Myerson, T. A. Hatton, B. Trout<br />
251. Effects of electropolymerized poly(3,4ethylenedioxythiophene)<br />
(PEDOT) film<br />
with porous structure as a hole collecting<br />
layer on bulk heterojunction photovoltaic<br />
cells. J. Park, J. J. Peterson,<br />
N. Hendricks, K. R. Carter<br />
252. Synthesis of silver nanocomposite films<br />
of enhanced antimicrobial activity.<br />
T. Radhakrishnan, M. K. Georges,<br />
V. Djoković<br />
253. Lipid bilayer membrane array and automated<br />
membrane formation. J. Park,<br />
Y. Baek, T. Jeon<br />
254. Self-assemblies of diblock copolymers<br />
for nanostructured carbon and inorganic<br />
materials. S. Kim, S. Jeon, H. Kim,<br />
Y. Lee, B. Sohn<br />
255. STM study of solvent effects in the<br />
asymmetric hydrogenation of trifluoroacetophenone<br />
on chirally modified platinum.<br />
J. Brunelle, G. Mahieu,<br />
V. Demers-Carpentier, S. Lavoie,<br />
P. H. McBreen<br />
256. Antibacterial activity of cubic boron nitride<br />
(cBN) coatings on stainless steel<br />
grade 316 (316L). E. Uzunoglu, K. Derici,<br />
D. Biriken, B. Kaftanoglu, M. Sengonul<br />
257. Synthesis of core-shell quantum dots<br />
via MAPS. H. Han, P. Lutz, M. M. Maye<br />
258. Modular phase transfer and ligand exchange<br />
protocol for quantum dots.<br />
J. Zylstra, N. Miska, M. Maye<br />
259. Mechanical properties of glycosyl-nucleoside-lipid<br />
hydrogels. J. A. Kaplan,<br />
G. Godeau, P. Barthélémy,<br />
M. W. Grinstaff<br />
260. Unidirectional self-assembly of colloidal<br />
crystals under centrifugal force field.<br />
S. Lee, G. Yi, W. Jeong, S. Yang,<br />
K. F. Jensen, J. Baek<br />
261. Crystal growth of CuS on structured<br />
surfaces. Y. Vasquez, E. M. Fenton,<br />
V. Chernow, J. Aizenberg<br />
262. Organic oxygenates on titania: A<br />
thermo- and photochemical study.<br />
P. Clawin, K. Al-Shamery, C. M. Friend<br />
263. Evaluation method for the interaction<br />
between endocrine disrupting chemicals<br />
(EDCs) and model biomembrane liposome.<br />
Y. Nakane,I.Kubo<br />
264. Surface modification to control biomaterial-adherent<br />
macrophage activation.<br />
K. R. Park, J. D. Bryers<br />
265. How the solid surface affects the velocity<br />
of liquid at an interface. A. Ponjavic,<br />
J. Wong<br />
266. Quantification of protein adsorption<br />
onto alkylsilane monolayers using Whispering<br />
Gallery Mode resonance biosensing<br />
in optical microcavities. K. A. Wilson,<br />
C. C. Finch, F. Vollmer, P. Anderson,<br />
J. J. Hickman<br />
267. Smart surfaces based on mixed polymer<br />
brushes: A combined layer-by-layer<br />
(LbL) and surface-initiated polymerization<br />
(SIP) approach. N. C. Estillore,<br />
R. C. Advincula<br />
268. STM studies of adsorbate-induced surface<br />
restructuring of Pt(100) in ethylene<br />
adsorption, hydrogenation, and poisoningbyCO.D.<br />
R. Butcher,<br />
M. B. Salmeron, G. A. Somorjai<br />
269. In situ monitoring platform for nanolithography<br />
by combining conducting<br />
probe atomic force microscopy and tipenhanced<br />
Raman spectroscopy techniques.<br />
C. Chang, J. D. Batteas<br />
270. Nanoparticle stabilized capsules for encapsulation<br />
and delivery. Y. Jeong,<br />
V. M. Rotello, B. Samata, S. Agasti,<br />
X. Yang<br />
271. Statistical modeling of particle interactions<br />
with nano-featured surfaces in flow.<br />
M. Bendersky, J. M. Davis,<br />
M. M. Santore<br />
272. Surface-enhanced Raman scattering<br />
analysis of perchlorate using silver nanofilms<br />
deposited on copper foils. J. Hao,<br />
Z. Xu, M. Han, S. Xu, X. Meng<br />
273. Tuning the encapsulation stability of<br />
nanoparticles for drug delivery containers.<br />
S. Jiwpanich, J. Ryu, S. Bickerton,<br />
S. Thayumanavan<br />
274. Intracellular delivery of anticancer drugs<br />
within a monolayer of gold nanoparticles.<br />
C. Kim, Z. Zhu, V. Rotello<br />
275. <strong>Chemical</strong>ly directed immobilization of<br />
nanoparticles on gold substrates and orthogonal<br />
assembly using dithiocarbamate<br />
bond formation. M. Park,X.Duan,<br />
B. Creran, J. Huskens, V. M. Rotello<br />
276. Biomimetic high density lipoprotein<br />
nanoparticles for the treatment of heart<br />
disease. A. J. Luthi, D. Kim, W. L. Daniel,<br />
H. Zhang, D. A. Giljohann, C. Thaxton,<br />
C. A. Mirkin<br />
277. Nanoparticle-immunolabeling of hepatocellular<br />
carcinoma. D. Rand, V. Ortiz,<br />
Z. Derdak, J. R. Wands, C. Rose-Petruck<br />
278. Molecular tweezer: SWNT supramolecular<br />
complexes. J. R. Alston,<br />
M. Etzkorn, J. C. Poler,J.C.Timmerman<br />
279. Competitive interactions in surfactant<br />
solutions: A neutron scattering investigation.<br />
A. Fajalia, M. Tsianou<br />
280. Arsenate detection by surface-enhanced<br />
Raman scattering using Ag nanofilms<br />
deposited on glass slides. M. Han,<br />
J. Hao, X. Meng<br />
281. Small angle X-ray scattering as universal<br />
tool for investigating the nucleation<br />
and growth processes of nanoparticles.<br />
J. Polte, R. Kraehnert, A. Thuenemann,<br />
F. Emmerling<br />
282. Selective detection of chemical and biological<br />
toxins using gold nanoparticle<br />
based two-photon scattering assay.<br />
S. Banerjee,P.Ray<br />
283. Naturally derived surface active polymers<br />
based on Chitosan. R. M. Bouldin,<br />
S. Shingi, R. Nagarajan<br />
284. Characterization of acid-base and redox<br />
properties of metal oxide nanoparticles<br />
in water using probe-molecule FTIR<br />
spectroscopy. S. Ponnurangam,<br />
I. Chernyshova, P. Somasundaran<br />
285. Effect of substrate on the structure and<br />
properties of mesoporous silica thin films.<br />
J. M. Allen, M. G. Bakker, R. Schad,<br />
X. Li, D. Lee, J. Wang<br />
286. Effect of temperature and incubation<br />
time on the in situ synthesis of gold nanoparticle<br />
assemblies. M. Kerrigan,<br />
T. Chase, A. Bonday, K. Bandyopadhyay<br />
287. Measuring surface potential of mixed<br />
surfactant micelles using indicator dyes.<br />
G. F. Kirton, A. Arveschoug,K.Kimura<br />
288. Electrochemical and hydrogen peroxide-driven<br />
oxidation of N G -hydroxy-L-arginine<br />
by films containing oxygenase domain<br />
of inducible nitric oxide synthase.<br />
M. So, M. Bayachou<br />
289. Size, shape, and color tunable copper<br />
nanoparticles: Photochemical syntheses<br />
and growth mechanisms for particles.<br />
J. J. Determan, S. Marpu, A. K. Wilson,<br />
M. A. Omary<br />
290. 2D assembly of disk-like molecules.<br />
I. P. Hamilton,L.Li<br />
291. Synthesis and structure of bicelle-templated<br />
periodic mesoporous silicas.<br />
P. Mohanty, J. Lee, K. Glover,<br />
K. Landskron<br />
292. Retention of colloids on calcite and<br />
limestone as a function of surface topography<br />
and roughness. G. K. Darbha,<br />
T. Schäfer, A. Lüttge, C. Fischer<br />
Section B<br />
Westin Boston Waterfront<br />
Galleria Room<br />
Fundamental Research in Colloid and<br />
Surface Science<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
J. Texter, R. Nagarajan, Organizers<br />
6:00–8:00<br />
293. Nanoconjugation alters dynamics, localization<br />
and mechanism of receptor internalization.<br />
S. Bhattacharyya<br />
294. Conformation of antimicrobial peptide<br />
Cecropin P1 C immobilized on silica surface<br />
using Molecular Dynamics Simulation.<br />
H. Chang, X. Wu, C. Mello,<br />
R. Nagarajan, G. Narsimhan<br />
295. Antiangiogenic properties of gold nanoparticles:<br />
Effect of size and surface<br />
charge. R. R. Arvizo,O.R.Miranda,<br />
R. Bhattacharya, V. M. Rotello,<br />
P. Mukherjee<br />
296. Facile synthesis, silanization and biodistribution<br />
of biocompatible quantum<br />
dots. N. Ma, A. F. Marshall, S. Gambhir,<br />
J. Rao<br />
297. Viral nanostructures: In vitro self-assembly<br />
of Parvovirus B19-like particles.<br />
S. P. Sanchez-Rodriguez,<br />
J. M. Mora-Pale, J. S. Dordick,<br />
I. Bustos-Jaimes<br />
298. Surface mineralization of Ti6Al4V with<br />
calcium apatite for retention/delivery of<br />
rhBMP-2. J. Smits, D. Ayers, J. Song<br />
299. Study of mesoscopic structures in<br />
aqueous solutions using light scattering.<br />
D. Subramanian,M.A.Anisimov,<br />
I. K. Yudin<br />
300. Role of macropinocytosis in DNA transfections<br />
with charge-reversal amphiphiles.<br />
X. Zhang, P. Allen, M. W. Grinstaff<br />
301. Directing molecular self-assembly: An<br />
AFM study. J. Yu<br />
302. Effective elasticity of a flexible filament<br />
bound to a deformable cylindrical surface.<br />
A. Saric, J. C. Pamies, A. Cacciuto<br />
303. Surface charge determines functional<br />
interactions between nanoparticles and<br />
cells. R. R. Arvizo, P. Mukherjee,<br />
Y. Prakash, M. A. Thompson,<br />
O. R. Miranda, J. D. Robertson,<br />
V. M. Rotello<br />
304. Retention of colloids at rough rock and<br />
mineral surfaces as a function of size,<br />
charge, and polydispersity: An analog<br />
study. G. K. Darbha, A. Michler,<br />
T. Schäfer, A. Lüttge, C. Fischer<br />
305. Stable suspension of mixed iron oxide/<br />
cobalt oxide nanoparticles in aqueous<br />
surfactant solutions and their use for<br />
mixer studies in liquids feeds.<br />
N. N. Barashkov, D. Eisenberg,<br />
S. Eisenberg, I. S. Irgibaeva, A. Mantel,<br />
T. S. Novikova<br />
306. Self-assembled fluorescent organic<br />
nanotubes for selective surface recognition<br />
as biosensory platform. C. Kim,<br />
J. Lee<br />
Section C<br />
Westin Boston Waterfront<br />
Galleria Room<br />
Fundamental Research in Colloid and<br />
Surface Science<br />
Nano Letters: The Next Ten Years<br />
C. Lieber, J. Texter, P. Alivisatos,<br />
Organizers<br />
6:00–8:00<br />
307. Microemulsion synthesis of Buffer stable<br />
Chitosan-PGA hybrid nanoparticles<br />
for biomedical applications. A. Malhotra<br />
308. Probing nanoscale redox transitions at<br />
molecular junctions using conductive<br />
probe atomic force microscopy.<br />
L. R. Ditzler, A. V. Tivanski<br />
309. Antimicrobial studies of biocompatible<br />
colloidal silver nanoparticles with tunable<br />
visible to near-infrared plasmonic absorptions.<br />
S. Marpu, S. Kolailat,<br />
R. Charturvedi, J. Shah, Z. Hu,<br />
M. A. Omary<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
310. Growth kinetics of nanoparticles: Investigating<br />
the effect of sacrificial nanoparticles<br />
to produce size focusing (quantized<br />
Ostwald ripening). P. Dagtepe, V. Chikan<br />
311. Nanowire nanoelectronics: Building interfaces<br />
with cell and tissue at the natural<br />
scale of biology. T. Cohen-Karni,<br />
B. P. Timko, Q. Qing, B. Tian,<br />
C. M. Lieber<br />
312. Wave front velocity oscillations of carbon<br />
nanotube-guided thermopower<br />
waves: Nanoscale alternating current<br />
sources. M. S. Strano,<br />
J. T. Abrahamson, W. Choi, J. Han,<br />
K. Kalantar-zadeh<br />
313. Understanding protein binding triggered<br />
disassembly of micellar nanostructures<br />
formed by amphiphilic macromolecules.<br />
D. F. Amado Torres,<br />
M. A. Azagarsamy, S. Thayumanavan<br />
314. Rationally designed peptide conjugates<br />
for directing the simultaneous synthesis<br />
and assembly of complex nanoparticle<br />
superstructures. N. L. Rosi, L. Hwang,<br />
C. Song, C. Chen, P. Zhang<br />
315. Synthesis of magnetic nanoparticles in<br />
spherical polyelectrolyte brush as nanoreactor.<br />
Y. Zhu, K. Chen, L. Li, X. Guo<br />
General Catalysis Sponsored by CATL<br />
(probationary), Cosponsored by COLL, FUEL,<br />
and PETR<br />
TUESDAY MORNING<br />
Section A<br />
Westin Boston Waterfront<br />
Harbor Ballroom II<br />
Surface Chemistry of Chiral Interfaces<br />
D. Sholl, Organizer<br />
A. Gellman, Organizer, Presiding<br />
8:30 316. Bestowing chirality on solid surfaces.<br />
Z. Ma, I. Lee, J. Lai, L. Mueller,<br />
F. Zaera<br />
8:55 317. Transmission of molecular chirality<br />
through multiple length scales.<br />
E. V. Iski, A. D. Jewell, H. L. Tierney,<br />
E. H. Sykes<br />
9:20 318. Chiral evolution on Cu(100).<br />
G. Contini, P. Gori, F. Ronci, N. Zema,<br />
S. Colonna, M. Aschi, A. Palma,<br />
S. Turchini, D. Catone, A. Cricenti,<br />
T. Prosperi<br />
9:45 319. Chiral effects in the adsorption of<br />
amino acids on metals and minerals.<br />
D. Sholl,J.Han<br />
10:10 320. Mirror symmetry breaking at the<br />
single molecule level. H. L. Tierney,<br />
A. D. Jewell, E. V. Iski, A. E. Baber,<br />
E. H. Sykes<br />
10:35 321. Chiral gold nanoparticles: Synthesis,<br />
chiroptical properties and ligand<br />
exchange reactions. S. Knoppe,T.Bürgi<br />
11:00 322. Unravelling chiral ligand-capped<br />
gold nanoparticle chirality and exploiting<br />
their use as chiral dopants for liquid crystal<br />
applications. H. Qi, J. D. O’Neil,<br />
T. Hegmann<br />
11:25 323. Enantioselective chiral nanoparticles.<br />
A. J. Gellman, N. Shukla, M. Bartel<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
Polymer Nanomaterials for Drug Delivery<br />
R. Nagarajan, Organizer, Presiding<br />
E. Davis, Presiding<br />
8:30 324. Electrically triggered release of a<br />
small molecule therapeutic from a polyelectrolyte<br />
multilayer thin film.<br />
D. J. Schmidt, J. S. Moskowitz,<br />
P. T. Hammond<br />
8:50 325. Layer-by-layer films for triggered<br />
release of antibacterial agents.<br />
S. V. Pavlukhina, A. Patimetha,<br />
S. Sukhishvili, M. Libera<br />
9:10 326. Surface modification with NIPAM<br />
containing nanogels. M. J. Seeber,<br />
R. Burtovyy, B. Zdyrko, C. Tsai,<br />
K. G. Kornev, I. Luzinov<br />
9:30 327. Halloysite: Polymer composite<br />
films for controlled release applications.<br />
C. J. Ward, S. Song, E. W. Davis<br />
9:50 328. Slow release and magnetic resonance<br />
imaging of anti-cancer drug molecules<br />
carried by poly(propylene fumarate)<br />
scaffolds. J. Choi,K.Kim,T.Kim,G.Liu,<br />
T. Hyeon, M. T. McMahon, J. W. Bulte,<br />
J. P. Fisher, A. A. Gilad<br />
10:10 329. Drug delivery nanoparticles from<br />
Amphiphilic polymers with sharp hydrophobic/hydrophilic<br />
contrast. Z. Cao,<br />
S. Jiang<br />
10:30 330. Modulated supramolecular release<br />
of drugs from dendrimer-nanoparticle<br />
composite films. M. Park,<br />
V. M. Rotello<br />
10:50 331. Encapsulation of nanoparticles<br />
within glucan microparticles for drug delivery.<br />
E. R. Soto, C. Mueller, G. Gao,<br />
G. R. Ostroff<br />
11:10 332. Development of a block copolymer<br />
for delivery of novel anti-inflammatory<br />
agents for severe asthmatics.<br />
M. Scionti, N. K. Comolli, R. A. Panettieri<br />
11:30 333. Morphogenesis of calcium biominerals<br />
effected by polyelectrolytes.<br />
M. China, M. Tsianou<br />
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Novel Model Systems for Bilayer Lipid<br />
Membranes<br />
Suspended Membranes and Vesicles<br />
I. Koeper, J. Robertson, Organizers<br />
K. Hristova, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 334. High throughput ion channel measurement<br />
platforms using artificial lipid<br />
membranes. J. Schmidt<br />
9:05 335. Highly stabilized polymeric suspended<br />
lipid bilayers with enhanced fluidity<br />
for ion channel recordings. B. A. Heitz,<br />
T. J. Comi, R. P. Cordero,<br />
C. A. Aspinwall, S. S. Saavedra<br />
9:25 336. Nanopore-based single molecule<br />
determination of polymer-cation binding<br />
and membrane protein dynamics.<br />
J. E. Reiner, J. J. Kasianowicz,<br />
J. W. Robertson<br />
9:55 337. Interactions of phospholipid bilayers<br />
with several classes of amphiphilic ahelical<br />
peptides: Insights from coarsegrained<br />
molecular dynamics simulations.<br />
P. Gkeka, L. Sarkisov<br />
10:15 338. Selective tethering of ligands and<br />
proteins to a microfluidic patterned electroactive<br />
fluid lipid bilayer array.<br />
M. N. Yousaf<br />
10:35 339. Controlled loading of organic<br />
molecules into self-assembled bilayers.<br />
S. A. Dergunov,S.C.Schaub,<br />
A. Richter, E. Pinkhassik<br />
10:55 340. DNA mediated artificial cell functionalization<br />
in the microfluidic environment.<br />
J. Xu, P. A. Beales, T. K. Vanderlick<br />
11:15 341. Liposomes for orthogonal highthroughput<br />
selection of cell penetrating<br />
peptides. J. R. Marks, W. C. Wimley<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal<br />
Nanomaterials and Polymer<br />
Nanocomposites<br />
H. Dodluk-Kenlg, V. S. Gutowski,<br />
R. Nagarajan, Organizers<br />
E. Maeder, Presiding<br />
8:30 342. Polymer matrix nanocomposites<br />
for highly enhanced electrical conduction<br />
and improved mechanical properties.<br />
S. Bandyopadhyay, M. R. Mada,<br />
D. R. Saha<br />
9:10 343. Nanostructured fibre sizings for<br />
interphase modification in composites.<br />
E. Maeder<br />
9:40 344. Nanoparticle deposition on packaging<br />
materials by the liquid flame spray.<br />
M. Tuominen<br />
10:00 345. Surface modification of multiwalled<br />
carbon nanotubes with oxygen<br />
and chlorine atoms. L. Oliveira, T. Debies,<br />
G. A. Takacs<br />
10:20 346. Cyanate ester/multiwalled carbon<br />
nanotube nanocomposites: Synthesis<br />
and characterization including adhesive<br />
properties. M. N. Sarojadevi,<br />
M. N. Rakesh<br />
10:40 347. Electrostatic adhesion mediated<br />
by ions helps making multicomponent<br />
nanostructured materials. F. Galembeck,<br />
L. Valadares, M. M. Rippel<br />
11:00 348. Exploiting adhesion forces to<br />
form superplastic nanowires of common<br />
salt. N. W. Moore,J.Luo,J.Y.Huang,<br />
S. X. Mao, J. E. Houston<br />
11:20 349. Effective elastic properties of<br />
biopolymer composites with imperfect<br />
adhesion between constituents analysed<br />
using hybrid identification strategy.<br />
S. Guessasma, D. Bassir<br />
11:40 350. Fiber-reinforced composites: Expanding<br />
minimal invasive applications in<br />
dentistry. M. Özcan<br />
Section E<br />
Westin Boston Waterfront<br />
Lewis<br />
Nano Letters: The Next Ten Years<br />
Photonics and Plasmonics<br />
P. Alivisatos, C. Lieber, Organizers,<br />
Presiding<br />
P. A. Lewis, Presiding<br />
9:00 351. Breaking the diffraction limit of<br />
light microscopy: Nanoscopic imaging<br />
with STORM. X. Zhuang<br />
9:40 352. Nonlinear coherent optical imaging<br />
for biology and medicine: The quest<br />
for ultimate sensitivity. X. Xie<br />
10:20 Intermission<br />
10:40 353. Single molecules as nanoscopic<br />
probes of 3D structure and metallic nanoantennas.<br />
W. Moerner<br />
11:20 354. Plasmonics – the next ten years.<br />
H. A. Atwater<br />
Surface Science of Catalysis Sponsored by<br />
CATL (probationary), Cosponsored by COLL,<br />
FUEL, and PETR<br />
TUESDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom B<br />
Langmuir Award Lectures<br />
W. Tysoe, Organizer, Presiding<br />
2:00 355. Catalytic chemistry and self-assembly<br />
on metal surfaces.<br />
R. M. Lambert<br />
2:20 356. Engineering the nanoparticle interface<br />
for materials and biological applications.<br />
V. M. Rotello<br />
WEDNESDAY MORNING<br />
Section A<br />
Westin Boston Waterfront<br />
Harbor Ballroom II<br />
Symposium in Honor of Richard Lambert<br />
C. Sykes, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:40 357. Surface reaction pathways on<br />
model palladium catalyst surfaces.<br />
W. T. Tysoe<br />
9:05 358. Nanostructured materials from the<br />
electrochemical reduction of lyotropic liquid<br />
crystalline phases. D. J. Watson,<br />
K. A. Asghar, J. M. Elliott<br />
9:30 359. Phosphine coordination materials<br />
as hybrid catalysts. S. M. Humphrey,<br />
A. J. Nunez, S. Won<br />
9:55 360. Heterogeneously-catalyzed C-C<br />
and C-N bond forming reactions on<br />
Au(111) and gold catalysts. G. Kyriakou,<br />
S. K. Beaumont, V. K. Kanuru,<br />
A. C. Papageorgiou, D. J. Watson,<br />
S. M. Hamphrey, R. M. Lambert<br />
10:20 361. Influence of N and Sn doping on<br />
electronic structure and photocatalytic<br />
activity of TiO 2. R. G. Egdell<br />
10:45 362. Cleaning of multilayer mirrors<br />
used in EUV photolithography and synchrotron<br />
light sources: A surface science<br />
approach. R. B. Grant, D. j. Davis,<br />
A. Keen, G. Kyriakou, A. V. Stevens,<br />
M. Tikhov, R. M. Lambert<br />
11:10 363. Tuning the catalytic properties of<br />
Au nanoparticles. F. Illas<br />
11:35 364. Plasma assisted catalysis applied<br />
to environmental chemistry and energy<br />
conversion processes. J. L. Hueso,<br />
V. J. Rico, J. Cotrino,<br />
A. R. Gonzalez-Elipe<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
Applications of Biomolecules<br />
R. Nagarajan, Organizer, Presiding<br />
R. Narain, Presiding<br />
8:30 365. Applications of nanocrystal labeled-high<br />
density lipoproteins for multimodality<br />
imaging of cardiovascular disease.<br />
D. P. Cormode, T. Skajaa,<br />
E. Roessl, A. Thran, R. Proksa,<br />
E. A. Fisher, Z. A. Fayad, W. J. Mulder<br />
8:50 366. Peptides as salt-resistant emulsifiers.<br />
A. F. Dexter<br />
9:10 367. Doxorubicin-loaded and antibodyconjugated<br />
liposome-QD hybrid vesicles<br />
for targeted cancer therapy and imaging.<br />
B. Tian, W. T. Al-Jamal,<br />
J. Van den Bossche, M. Stuart,<br />
J. G. Raynes, K. Kostarelos<br />
9:30 368. Peptide-based surface coatings<br />
for the inhibition of pathogenic biofilms<br />
on titanium. X. Khoo,G.O’Toole,<br />
D. Kenan, M. Grinstaff<br />
9:50 369. Self assemblies of liquid crystalline<br />
lipid A-phosphates. H. H. Paradies,<br />
C. A. Faunce<br />
10:10 370. Cationic glyconanoparticles as<br />
efficient gene delivery systems.<br />
R. Narain,M.Ahmed<br />
10:30 371. Lectin-conjugated fluorescent<br />
silica nanoparticles for quantitative histopathology<br />
evaluations of tissue biopsies.<br />
Y. Wang, M. Zimmt, D. Gnepp,<br />
J. Gildersleeve<br />
10:50 372. Synthetic zwitterlation of enzymatic<br />
proteins for functional stability.<br />
A. Keefe<br />
11:10 373. Surface properties of amyloid<br />
beta (1-42) mixed or conjugated to quantum<br />
dots. G. Thakur, R. M. Leblanc,<br />
M. Micic<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
COLL<br />
TECH–37
COLL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
11:30 374. Bio-inspired synthesis and coating<br />
of nanoparticles for biological applications.<br />
Y. Zheng, J. Xie, J. Jiang,<br />
J. Y. Ying<br />
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Inorganic-Organic Solar Cells<br />
L. Chen, Organizer<br />
G. Meyer, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 375. What makes dye cells tick, or kick<br />
the bucket? Injection, regeneration, and<br />
collection efficiencies in new, old, dry,<br />
and wet dye sensitized solar cells.<br />
B. C. O’Regan, P. R. Barnes, C. Law,<br />
A. Y. Anderson, A. Listorti, J. R. Durrant,<br />
T. Ghaddar, R. Humphry-Baker<br />
9:05 376. Nanostructured photoelectrodes<br />
for light to electrical energy conversion.<br />
J. Hupp<br />
9:30 377. Electric field effects in dye sensitized<br />
solar cells. G. Meyer,S.Ardo,<br />
J. Rowley<br />
9:55 378. Ruthenium “star” complexes as<br />
sensitizing dyes. E. Galoppini,Y.Zhang,<br />
P. Johansson, G. J. Meyer<br />
10:20 Intermission<br />
10:35 379. Quantum dot sensitized solar<br />
cells: Mapping photoinduced charge<br />
transfer processes. P. V. Kamat<br />
11:00 380. Studies of oxomanganese complexes<br />
for natural and artificial photosynthesis.<br />
V. S. Batista<br />
11:25 381. Dye sensitized solar cells and organic<br />
photovoltaics: Alternatives to the<br />
usual. C. M. Elliott, D. J. Bates,<br />
C. B. Moss, L. N. Ashbrook,<br />
C. A. Bignozzi, S. Cazzanti<br />
11:50 382. Funneling solar energy and<br />
charge at sensitized mesoporous films.<br />
S. Ardo, G. J. Meyer<br />
12:05 383. <strong>Chemical</strong> modification of III-V<br />
semiconductor photoelectrodes for photoelectrochemical<br />
energy conversion and<br />
storage. S. Maldonado<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal<br />
Wood and Paper Adhesion<br />
H. Dodluk-Kenlg, V. S. Gutowski,<br />
R. Nagarajan, Organizers<br />
C. Frihart, Presiding<br />
9:00 384. Wood joints adhesion and performance<br />
in mechanical friction welding of<br />
wood without adhesives. A. Pizzi<br />
9:40 385. Challenges in measuring the adhesion<br />
properties and surface energy of<br />
cellulose nanofibrils. D. J. Gardner<br />
10:00 386. Silane coupling agents as wet<br />
end aids for papermaking process.<br />
O. Paquet, E. Zeno, M. Brochier-Salon,<br />
N. M. Belgacem<br />
10:20 387. Challenges in understanding the<br />
performance of wood adhesives.<br />
C. R. Frihart<br />
10:40 388. Withdrawn<br />
11:00 389. Effect of soy protein modifications<br />
and fiber surface treatments on their<br />
impact on interfacial shear strength with<br />
cellulose fibers. A. N. Netravali<br />
11:20 390. Proteins as wood adhesives.<br />
C. R. Frihart, C. G. Hunt, M. J. Birkeland<br />
11:40 391. Withdrawn<br />
38–TECH<br />
‡ Cooperative Cosponsorship<br />
Section E<br />
Westin Boston Waterfront<br />
Lewis<br />
Nanoscale Characterization of Microbes<br />
and Cells<br />
Nanoscale Characterization of Microbes<br />
N. Abu Lail, M. Nunez, Organizers<br />
T. Camesano, Organizer, Presiding<br />
9:00 Introductory Remarks<br />
9:05 392. Immunoimmobilization and<br />
nanoscale manipulation of living bacteria.<br />
Z. Suo, M. Deliorman, X. Yang,<br />
L. Loetterle, R. Avci<br />
9:25 393. Nanoscale adhesion of Listeria<br />
monocytogenes EGDe to silicon nitride as<br />
a function of growth temperatures.<br />
F. P. Gordesli, N. I. Abu-Lail<br />
9:45 394. Trypanosoma brucei flagellum reveals<br />
unique and dynamic structures of a<br />
nanomachine. A. Y. Koyfman,<br />
M. F. Schmid, L. Gheiratmand,<br />
H. A. Khant, C. J. Fu, C. Y. He, W. Chiu<br />
10:05 395. Anti-sporal activity of antimicrobial<br />
peptides against Bacillus anthracis.<br />
P. A. Pinzon-Arango, R. Nagarajan,<br />
T. A. Camesano<br />
10:25 396. Surface adhesion profile change<br />
of uropathogenic E. coli in urine after oral<br />
consumption of cranberry juice cocktail.<br />
Y. Tao, P. A. Pinzon, A. B. Howell,<br />
T. A. Camesano<br />
10:45 397. Nanoscale comparisons of the<br />
adhesion strength measured between silicon<br />
nitride and L. monocytogenes’<br />
strains of environmental or epidemic origin<br />
under fixed environmental conditions.<br />
A. Eskhan, N. Abu-Lail<br />
11:05 398. Nanomaterial - cell interaction<br />
measurement platforms. E. Mansfield,<br />
S. Hooker<br />
11:25 399. Probing the interaction forces<br />
between bacterial biofilms and surfaces<br />
with atomic force microscopy.<br />
A. E. Murdaugh, K. Aidala, M. Nunez<br />
11:45 400. Listeria monocytogenes: Mucin<br />
interactions in gastrointestinal infections.<br />
N. Yurt-Beyenal, N. Abu-Lail<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Harbor Ballroom II<br />
Symposium in Honor of Richard Lambert<br />
C. Sykes, Organizer<br />
C. Baddeley, Presiding<br />
1:30 Introductory Remarks<br />
1:35 401. Conversion of waste biogas over<br />
supported nickel catalysts and solid oxide<br />
fuel cell anodes: Carbon deposition,<br />
sulphur poisoning and characterisation of<br />
hydrocarbonaceous overlayers formed<br />
during reforming. R. M. Ormerod,<br />
C. J. Laycock, J. Z. Staniforth,<br />
A. L. Hopkin, G. J. Moore,<br />
I. P. Silverwood, N. G. Hamilton,<br />
D. Lennon, C. D. Frost, S. F. Parker<br />
2:00 402. X-ray studies of catalytic clean<br />
technologies. A. F. Lee<br />
2:25 403. Electrochemical promotion of catalysis.<br />
C. G. Vayenas<br />
2:50 404. Tuneable solid acid catalysts for<br />
clean chemical technologies. K. Wilson<br />
3:15 405. Particle size and support effects in<br />
electrocatalysis. B. Hayden<br />
3:40 406. RML inspired research in surface<br />
chemistry. F. J. Williams<br />
4:05 407. Towards a surface science of molecular<br />
crystals: Studies with soft X-ray<br />
spectroscopies. S. L. Schroeder,<br />
J. S. Stevens, H. M. Zaki, A. M. Booth<br />
4:30 408. Combining catalysts and light: Environmental<br />
applications of nanoparticles<br />
and nanostructures. A. Orlov<br />
4:55 409. Deciphering the mechanism for<br />
covalent alkyl monolayers on silicon.<br />
M. V. Lee, T. M. Willey, J. R. Lee,<br />
D. E. Brehmer, D. Enders, T. Nagao,<br />
M. R. Linford, K. Ariga<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
Nanoparticles Synthesis and Properties<br />
R. Nagarajan, Organizer, Presiding<br />
I. Sokolov, Presiding<br />
1:30 410. Synthesis and surface modification<br />
of colloidal Yb 3� ,Er 3� codoped<br />
NaYF 4 upconversion nanophosphors for<br />
photodynamic therapy. J. Shan,<br />
S. J. Budijono, R. K. Prud’homme, Y. Ju<br />
1:50 411. High yield synthesis and optical<br />
properties of Ag 10 clusters. A. Mohanty,<br />
N. Garg, R. Jin<br />
2:10 412. Withdrawn<br />
2:30 413. Large-scale synthesis of uniformsized<br />
nanocrystals and their designed assembly<br />
for multifunctional biomedical applications.<br />
T. Hyeon, B. Kim, M. Park,<br />
J. Lee<br />
2:50 414. Plasmonic copper selenide<br />
nanocrystals for photothermal therapy.<br />
C. M. Hessel, V. Pattani, M. Rasch,<br />
J. L. Hueso, J. W. Tunnell, B. A. Korgel<br />
3:10 415. Ultrabright fluorescent mesoporous<br />
silica particles, both nano and micro.<br />
D. O. Volkov, E. Cho, I. Sokolov<br />
3:30 416. Engineered SERS substrates with<br />
multiscale signal enhancement: Nanoparticle<br />
cluster arrays. B. Yan, B. Reinhard<br />
3:50 417. Nucleation and growth studies as<br />
essential basis for manipulating the properties<br />
of nanomaterials. J. Polte,<br />
R. Kraehnert, A. Thuenemann,<br />
F. Emmerling<br />
4:10 418. Small-angle X-ray scattering study<br />
of readily controllable palladium nanoparticle<br />
formation on viral nanotemplates.<br />
A. K. Manocchi, B. Lee, H. Yi<br />
4:30 419. Biomimic approach for Visible-<br />
NIR water soluble colloidal quantum dots.<br />
Q. Song,X.Ai<br />
4:50 420. Tuning the spectral properties of<br />
cyanine based near infrared fluorescent<br />
nanoparticles. S. Das, D. Bwambok,<br />
B. El-Zahab, J. D. Monk, S. L. de Rooy,<br />
F. Hung, G. Baker, I. M. Warner<br />
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Inorganic-Organic Solar Cells<br />
G. Meyer, Organizer<br />
M. D. McGehee, Presiding<br />
L. Chen, Organizer, Presiding<br />
2:00 421. Engineering interfacial layers and<br />
compatible polymers for organic photovoltaics.<br />
T. Marks<br />
2:30 422. Using time-resolved THz spectroscopy<br />
to study carrier dynamics in<br />
TiO 2 nanotubes. C. Richter,<br />
C. Schmuttenmaer<br />
2:55 423. Progress in development of new<br />
semiconducting polymers for highly efficient<br />
organic solar cells. L. Yu<br />
3:20 Intermission<br />
3:35 424. Increasing light harvesting with<br />
energy transfer in organic-inorganic solar<br />
cells. M. D. McGehee<br />
4:00 425. Long-range energy transfer between<br />
conjugated polymers and<br />
fullerenes: Implications for bilayer plastic<br />
solar cells. B. J. Schwartz,A.L.Ayzner,<br />
S. Doan, B. Tremolet de Villers,<br />
S. H. Tolbert<br />
4:25 426. Structure, dynamics and power<br />
conversion efficiency correlations in new<br />
low bandgap polymer:PCBM solar cells.<br />
L. X. Chen, J. Guo, J. M. Szarko,<br />
Y. Liang, B. S. Rolczynski, B. Lee, H. Son,<br />
L. Yu<br />
4:50 427. Energetics and structure of metal/<br />
semiconducting polymer interfaces.<br />
C. T. Campbell, J. A. Farmer, J. Sharp,<br />
J. M. Gottfried, J. Zhu<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal<br />
Adhesion Mechanism and Testing<br />
H. Dodluk-Kenlg, V. S. Gutowski,<br />
R. Nagarajan, Organizers<br />
S. Bandyopadhyay, Presiding<br />
2:00 428. Adhesion control through engineered<br />
macromolecular interphases.<br />
W. S. Gutowski, S. Li, G. Toikka<br />
2:40 429. Predictions of solid film properties<br />
derived from thermochemical kinetic<br />
analysis of raw resin formulations.<br />
A. Kandelbauer, G. Wuzella,<br />
A. R. Mahendran, I. Taudes, P. Widsten<br />
3:00 430. Recent research trends in high<br />
performance pressure-sensitive adhesives.<br />
H. Hyun-Joong Kim,<br />
S. Sumin Kim<br />
3:20 431. Latest developments in the<br />
scratch test for adhesion measurement of<br />
thin films and coatings. N. Randall<br />
3:40 432. Estimation of the adhesion<br />
strength of particles/residues and gate<br />
structures for calculating the damage<br />
threshold of patterned silicon wafers during<br />
physical force assisted cleans.<br />
S. Halder, T. Kim, A. Pacco, K. Kenis,<br />
M. Claes, R. Vos, S. De Gendt,<br />
P. Mertens<br />
4:00 433. Fundamental studies of clathrate<br />
hydrate adhesion. J. D. Smith,<br />
A. J. Meuler, Y. Cui, R. E. Cohen,<br />
G. H. McKinley, K. K. Varanasi<br />
Section E<br />
Westin Boston Waterfront<br />
Lewis<br />
Nanoscale Characterization of Microbes<br />
and Cells<br />
Nanoscale Characterization of Mammalian<br />
and Microbial Cells<br />
T. Camesano, M. Nunez, Organizers<br />
N. Abu Lail, Organizer, Presiding<br />
2:00 434. AFM study of epithelial cells: Towards<br />
“physical markers” of cancer.<br />
I. Sokolov, M. E. Dokukin, N. V. Guz,<br />
S. Iyer, R. M. Gaikwad, C. D. Woodworth<br />
2:40 435. <strong>Chemical</strong> imaging of lipid distribution<br />
within cell membranes with high-resolution<br />
secondary ion mass spectrometry.<br />
M. L. Kraft, K. Lou, J. F. Frisz,<br />
P. K. Weber, K. J. Carpenter,<br />
W. P. Hanafin, I. D. Hutcheon<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
3:00 436. Role of extracellular mechanical<br />
stress in cancer metastasis.<br />
S. Muralidharan, C. B. Mudianselege,<br />
K. Dorrance, N. Srividya, N. Abu-Lail<br />
3:20 437. Cellular crystallography: Generation<br />
and detection of 2D membrane protein<br />
crystals in living cells. E. Gualtieri,<br />
F. Guo, J. Jose, M. Zhalnina, W. Cramer,<br />
R. Kuhn, W. Jiang, G. Simpson<br />
3:40 438. Mechanical stress induced phosphatidyl<br />
serine translocation in cancer<br />
cells. S. Muralidharan, T. Gay, S. Patel<br />
4:00 439. Single-cell analytic technology to<br />
measure dynamic antigen-specific responses<br />
of human CD4 � T cells. J. Choi,<br />
E. M. Bradshaw, Q. Han, S. C. Kent,<br />
D. A. Hafler, J. Love<br />
4:20 440. Examining the lipopolysaccharide<br />
layer conformation and bacterial adhesion<br />
to human airway epithelial cells under<br />
various genetic mutations.<br />
I. E. Ivanov, T. A. Camesano, E. Kintz,<br />
J. B. Goldberg<br />
4:40 441. Modeling of naphthalene biodegradation<br />
by Paenibacillus naphthalenovorans.<br />
S. Aliyeva, J. N. Petersen,<br />
N. I. Abu-Lail<br />
5:00 Concluding Remarks<br />
WEDNESDAY EVENING<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes Sponsored by<br />
ENVR, Cosponsored by COLL and GEOC<br />
THURSDAY MORNING<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal<br />
Mechanics Aspects of Adhesion<br />
H. Dodluk-Kenlg, V. S. Gutowski,<br />
R. Nagarajan, Organizers<br />
E. Sancaktar, Presiding<br />
8:00 442. Roles of adhesion in tribology of<br />
microsystems. S. K. Sinha<br />
8:40 443. Adhesion controlled by multiscale<br />
interface residual stresses. K. Kim<br />
9:10 444. Physical-chemical mechanics of<br />
contact adhesion. E. D. Shchukin<br />
9:40 445. Adhesion and boundary friction of<br />
aromatic monolayers. M. Ruths,Y.Yang<br />
10:00 446. Improved approaches to analyse<br />
the non-linear behaviour of adhesives in<br />
bonded assemblies. J. Cognard,<br />
R. Creac’hcadec, J. Maurice, L. Sohier,<br />
P. Davies<br />
10:20 447. Study of the deformation of a<br />
cantilever beam caused by an asymmetric<br />
liquid bridge. T. Chowdhury,<br />
A. Amirfazli, T. Tang<br />
10:40 448. Stress interference in double adhesive<br />
layer scarf and butt joints.<br />
E. Sancaktar,S.Teli<br />
11:00 449. Interlaminar stresses and adhesive<br />
layer stresses in single lap and<br />
socket tubular adhesively bonded joints<br />
with a delaminated composite adherend.<br />
R. A. Esmaeel, F. Taheri<br />
Section A<br />
Westin Boston Waterfront<br />
Harbor Ballroom II<br />
Symposium in Honor of Richard Lambert<br />
C. Sykes, Organizer<br />
A. Lee, Presiding<br />
8:30 Introductory Remarks<br />
8:35 450. Plasmachemical tailoring of solid<br />
surfaces. J. S. Badyal<br />
9:00 451. Interstitial mediated coupling of<br />
benzaldehyde on reduced TiO 2(110).<br />
S. Jensen, J. Haubrich, L. Benz<br />
9:25 452. UV and visible photoactivity of titania:<br />
Nature of reduced and doped TiO 2.<br />
G. Pacchioni<br />
9:50 453. Structural, compositional and<br />
electrochemical characterization of platinum-cobalt<br />
oxygen-reduction catalysts.<br />
S. Axnanda, K. D. Cummins, Z. Zhou,<br />
M. P. Soriaga, D. W. Goodman<br />
10:15 454. Carbon deposits on Pd catalysts<br />
modeled by nanoparticles.<br />
K. M. NEYMAN<br />
10:40 455. Adsorbate induced roughening<br />
in Si(100). C. M. Aldao, D. A. Mirabella<br />
11:05 456. Out of ultra high vacuum and into<br />
the real world. R. M. Lambert<br />
11:30 457. Selective amine acylation on metallic<br />
silver and gold single crystal surfaces.<br />
C. G. Freyschlag, B. Xu, L. Zhou,<br />
C. M. Friend, R. J. Madix<br />
11:55 458. Synthesis and photobehavior of<br />
Titania thin-films prepared by anodic oxidation.<br />
S. Perathoner, G. Centi,<br />
C. Ampelli, R. Passalacqua<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
Nanomaterials for Biomedicine<br />
R. Nagarajan, Organizer, Presiding<br />
A. Dragulescu-Andrasi, Presiding<br />
8:30 459. Switching blood coagulation on<br />
and off by gold nanorod excitation.<br />
S. H. Baxamusa, H. de Puig Guixe,<br />
M. Balcells, K. Hamad-Schifferli<br />
8:50 460. Light-activated amphiphiles for<br />
gene delivery. C. M. LaManna, H. Lusic,<br />
J. H. Feng, M. W. Grinstaff<br />
9:10 461. Second-order kinetic surface processes:<br />
A case study from surface hybridization.<br />
Y. Liu, R. Levicky<br />
9:30 462. Integrated microfluidic neurotransmitter-modified<br />
substrates. H. Cao,<br />
W. Liao, P. S. Weiss, A. M. Andrews<br />
9:50 463. Self assembly of TMAO at hydrophobic<br />
interfaces and its effect on protein<br />
adsorption: Insights from experiments<br />
and simulations. G. Anand,<br />
S. N. Jamadagni, S. Garde, G. Belfort<br />
10:10 464. Contrasting emulsions:<br />
Nanovectors for MRI. S. Chadel,<br />
V. Schmitt, F. Leal Calderon, C. Robic,<br />
M. Port<br />
10:30 465. Surface modification of tissueengineered<br />
cartilage grafts for enhanced<br />
osteochondral integration.<br />
A. Dragulescu-Andrasi, T. Wong,<br />
J. Song<br />
10:50 466. DNA oligonucleotide length controls<br />
the efficient assembly of DNA-based<br />
nanomaterials: Molecualr dynamics<br />
study. Y. G. Yingling, A. Singh<br />
11:10 467. Phthalocyanine nanoballs.<br />
K. Baek, R. Hota, G. Yun, Y. Kim,<br />
H. Jung, K. Park, E. Yoon, T. Joo,<br />
J. Kang, C. Park, S. Bae, W. Ahn, K. Kim<br />
11:30 468. Laser-induced rupture of infrared<br />
dye-doped liposomes. H. Suzuki,<br />
I. S. Lee, T. Sakai<br />
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Inorganic-Organic Solar Cells<br />
G. Meyer, L. Chen, Organizers<br />
B. Parkinson, O. Prezhdo, Presiding<br />
8:30 469. Third generation solar photon<br />
conversion to electricity and fuel: Multiple<br />
exciton generation in colloidal quantum<br />
dots, quantum dot arrays, and solar sells.<br />
A. J. Nozik, M. C. Hanna, M. C. Beard,<br />
J. E. Luther, J. Gao<br />
9:00 470. Electron transfer at quantum dot-<br />
TiO 2 interfaces prepared by linker-assisted<br />
assembly. R. S. Dibbell,<br />
J. S. Nevins, D. G. Youker,<br />
K. M. Coughlin, D. F. Watson<br />
9:25 471. Electrochemical and photoelectrochemical<br />
investigations of outersphere<br />
redox shuttles in dye-sensitized solar<br />
cells. T. Hamann, J. Ondersma, B. Klahr<br />
9:50 472. New heteroleptic Ru(II) and Os(II)<br />
sensitizers for dye-sensitized solar cells<br />
based on titania materials.<br />
F. N. Castellano<br />
10:15 Intermission<br />
10:30 473. Quantum dot sensitization of single<br />
crystal TiO 2 electrodes: Surface<br />
chemistry, stability, and collection of multiple<br />
electrons per photon. J. Sambur,<br />
B. A. Parkinson<br />
10:55 474. Time-domain ab initio studies of<br />
quantum dots and molecule-bulk interfaces<br />
for solar energy harvesting.<br />
O. Prezhdo<br />
11:20 475. Relaxation of exciton confinement<br />
in CdSe quantum dots by modification<br />
with a conjugated dithiocarbamate ligand.<br />
E. A. Weiss, M. T. Frederick<br />
11:45 476. Charge carrier resolved relaxation<br />
of the first excitonic state in CdSe<br />
quantum dots probed with near-infrared<br />
transient absorption spectroscopy.<br />
E. A. McArthur, A. J. Morris-Cohen,<br />
K. E. Knowles, E. A. Weiss<br />
12:00 477. Size-dependent molecular order<br />
of n-octylphosphonate ligands on CdSe<br />
quantum dots probed by vibrational sum<br />
frequency generation. J. L. Achtyl,<br />
M. T. Frederick, E. A. Weiss, F. M. Geiger<br />
THURSDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Harbor Ballroom II<br />
Symposium in Honor of Richard Lambert<br />
C. Sykes, Organizer<br />
F. Williams, K. Wilson, Presiding<br />
1:30 Introductory Remarks<br />
1:35 478. Electrochemical and spectroscopic<br />
investigations of enantioselectivity<br />
at platinum surfaces. G. A. Attard<br />
2:00 479. Heterogeneous asymmetric C�C<br />
hydrogenation: Critical influence of the<br />
hydrogenation substrate.<br />
S. K. Beaumont, G. Kyriakou,<br />
D. J. Watson, R. B. Jesudason,<br />
O. P. Vaughan, A. Papageorgiou,<br />
J. W. Burton, R. M. Lambert<br />
2:25 480. Design of selective catalysts with<br />
well-defined shapes. I. Lee, F. Delbecq,<br />
F. Zaera<br />
2:50 481. Molecular rotors, motors, and<br />
chirality. C. Sykes<br />
3:15 482. Enantioselective explosions on<br />
chiral surfaces. A. J. Gellman<br />
3:40 483. Understanding the surface chemistry<br />
of enantioselective �-ketoester hydrogenation<br />
reactions over amino acidmodified<br />
Ni catalysts. K. E. Wilson,<br />
A. G. Trant, C. J. Baddeley<br />
4:00 484. Assembly of functionalized molecular<br />
networks at surfaces.<br />
C. J. Baddeley, H. A. Fruchtl,<br />
J. Greenwood, S. Jensen, T. E. Jones<br />
4:25 485. Surface modification of poly(dimethylsiloxane)<br />
with perfluorinated alkoxysilanes:<br />
Zeta potential and the adsorption<br />
of perfluoro-tagged proteins and<br />
peptides. H. Horton<br />
Section B<br />
Westin Boston Waterfront<br />
Alcott<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications<br />
Applications of Polymer Based<br />
Nanostructures<br />
R. Nagarajan, Organizer, Presiding<br />
1:30 486. Nano-patterned brushes with selective<br />
protein and cell adhesion. S. Gon,<br />
M. M. Santore<br />
1:50 487. Fluorescent nanoscale assemblies<br />
of anionic poly(phenylene vinylene) with<br />
lipid vesicles and silica beads. A. T. Ngo,<br />
P. Karam, K. L. Lau, M. Burger,<br />
J. Quesnel, R. Aboukhalil, G. Cosa<br />
2:10 488. Real-time analysis of RSV RNAprotein<br />
interactions at the single RNA<br />
molecule level. L. R. Skewis,C.Zack,<br />
R. Djang, R. Fearns, B. M. Reinhard<br />
2:30 489. Dynamics of surface bound nucleic<br />
acids: Capturing DNA in motion.<br />
K. Williams<br />
2:50 490. Protein adsorption resistance of<br />
thermoresponsive PEG-co-PNIPAm microgels.<br />
T. Trongsatitkul, B. Budhlall<br />
3:10 491. Development of a nucleic acid<br />
vector based on noncovalent assembly of<br />
bioresponsive amino-b-cyclodextrin:<br />
poly(ethylene glycol)-poly(vinyl alcohol)adamantanate<br />
complexes. W. Deng,<br />
K. Aditya, E. Trisha, D. H. Thompson<br />
3:30 492. Synthesis, characterization, and<br />
supramolecular assembly of PEGylated<br />
and electropolymerizable Janus type<br />
dendrimers. M. L. Felipe, R. Pernites,<br />
R. Advincula<br />
3:50 493. Preparation and characterization<br />
of polymer brushes via electrochemistry<br />
and surface-initiated RAFT polymerization<br />
for biomedical applications.<br />
M. R. Tria,R.C.Advincula<br />
4:10 494. Alkyl passivation and amphiphilic<br />
polymer coating of silicon nanocrystals<br />
for diagnostic imaging. C. M. Hessel,<br />
M. Rasch, J. L. Hueso,<br />
P. Puvanakrishnan, J. W. Tunnel,<br />
B. A. Korgel<br />
4:30 495. Nanoscale amphiphilic macromolecules<br />
to biostabilize white-light emitting<br />
CdSe nanocrystals. S. M. Sparks,<br />
M. A. Schreuder, F. R. Haselton,<br />
S. J. Rosenthal, K. E. Uhrich<br />
Section D<br />
Westin Boston Waterfront<br />
Carlton<br />
Symposium in Honor of Kash Mittal<br />
Dental and Medical Adhesion<br />
V. S. Gutowski, H. Dodluk-Kenlg,<br />
R. Nagarajan, Organizers<br />
S. Neogi, Presiding<br />
1:30 496. Adhesion aspects in dentistry:<br />
Resin zirconia bonding. J. P. Matinlinna<br />
2:10 497. Controlling biomaterial-tissue interfacial<br />
interactions for implantable device<br />
performance. A. J. Coury<br />
2:40 498. Piezoelectric inkjet printing of<br />
medical adhesives and sealants.<br />
R. J. Narayan, A. Doraiswamy,<br />
T. M. Dunaway, J. J. Wilker, R. Crombez,<br />
W. Shen, Y. Lee<br />
3:00 499. Bacterial surface properties and<br />
adhesion and transport. G. Chen<br />
3:20 500. Enhanced cell adhesion and<br />
transfection on the nanostructured surfaces.<br />
P. Chen<br />
3:40 501. Evaluation of biocompatibility and<br />
blood compatibility of polycarbonate<br />
treated with argon plasma. N. gomathi,<br />
S. Neogi<br />
4:00 502. Effect of surface mechanics on<br />
cell function and dynamics.<br />
M. Rafailovich, Z. Pan, Y. Liu, K. Ghosh,<br />
M. Simon, V. Jurukovsky, R. Clark,<br />
G. Prestwich<br />
4:20 503. Study of primer systems for adhesion<br />
to dentin. J. M. Antonucci,<br />
G. E. Schumacher<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
COLL<br />
TECH–39
COLL/COMP <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section C<br />
Westin Boston Waterfront<br />
Burroughs<br />
Inorganic-Organic Solar Cells<br />
G. Meyer, L. Chen, Organizers<br />
D. Guldi, S. Marder, Presiding<br />
2:00 504. Electronic and geometric structure<br />
of conducting oxide/organic interfaces<br />
in organic solar cells. J. Bredas<br />
2:30 505. Applications of rylene diimide<br />
containing materials for organic solar cell<br />
applications. Z. An, S. Barlow,<br />
T. M. Clarke, B. Domercq, J. R. Durrant,<br />
C. Huang, B. Kippelen, Y. Li, S. Shoaee,<br />
Z. Tan, X. Wang, X. Zhan, X. Zhang,<br />
E. Zhou, S. R. Marder<br />
2:55 506. Structure-function-property relationships<br />
in Diketopyrrolopyrrole-based<br />
materials for solar cell applications.<br />
T. Nguyen,X.Dang,C.Kim<br />
3:20 Intermission<br />
3:35 507. Nanoscale carbon materials for<br />
solar energy conversion. D. Guldi<br />
4:00 508. Hybrid solar cells based on<br />
poly(3-hexylthiophene) and colloidally<br />
prepared semiconductor nanocrystals.<br />
H. Borchert, N. Radychev, F. Witt,<br />
M. Kruszynska, I. Lokteva,<br />
J. Kolny-Olesiak, J. Parisi<br />
4:25 509. Spectra and level widths for ultrafast<br />
photoinduced heterogeneous electron<br />
transfer (PHET) at room temperature<br />
and very low temperature. L. Gundlach,<br />
V. May, F. Willig<br />
4:50 510. Photoelectrochemical complexes<br />
for solar energy conversion that chemically<br />
and autonomously regenerate.<br />
A. A. Boghossian,M.Ham,J.Choi,<br />
M. S. Strano<br />
COMP<br />
Division of Computers in<br />
Chemistry<br />
E. X. Esposito and J. D. Madura,<br />
Program Chairs<br />
SUNDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
Proteins<br />
E. X. Esposito, Organizer<br />
V. Somisetti, Presiding<br />
8:30 1. Probing the �-helical structural stability<br />
of stapled p53 peptides: Molecular<br />
dynamics simulations and analysis.<br />
Z. Guo, U. Mohanty, J. Noehre,<br />
T. Sawyer, W. Sherman, G. Krilov<br />
9:00 2. Density functional theory calculations<br />
on matrix metalloproteinases and<br />
inhibitors. M. A. Ferron, N. Dimakis,<br />
R. Castillo, I. Leal, R. Espinoza,<br />
N. Navarro<br />
9:30 3. Efficient data mining of the human<br />
kinome. J. Maier<br />
10:00 Intermission<br />
10:15 4. Methemoglobinemia caused by<br />
8-aminoquinoline drugs: DFT calculations<br />
suggest an analogy to H4B’s role in nitric<br />
oxide synthase. H. Liu, L. A. Walker,<br />
N. Nanayakara, R. J. Doerksen<br />
10:45 5. Evaluation and ranking of enzyme<br />
designs. G. Kiss, D. Rothlisberger,<br />
D. Baker, K. N. Houk<br />
40–TECH<br />
‡ Cooperative Cosponsorship<br />
11:15 6. Thermodynamic contributions to<br />
PDZ binding affinities: A theoretical and<br />
experimental case study. L. Vogt,<br />
E. Karp, A. Aspuru-Guzik, G. MacBeath<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Colloids: Gels, Sols, and Emulsions. You<br />
Know...Goo<br />
E. X. Esposito, Organizer<br />
K. Armacost, Presiding<br />
8:30 7. Aggregation dynamics of partially<br />
sticky and structured colloidal spheres<br />
under shear stresses. M. C. Hagy,<br />
A. V. Popov, R. Hernandez<br />
9:00 8. Molecular simulations of electric field<br />
effects in condensed phase systems.<br />
A. Luzar, C. Daub, D. Bratko<br />
9:30 9. Theories of molecular fluids confined<br />
in disordered porous materials.<br />
L. Sarkisov<br />
10:00 Intermission<br />
10:15 10. Self-consistent treatment of polarization<br />
in condensed-phase QM/MM calculations.<br />
L. D. Jacobson, C. F. Williams,<br />
J. M. Herbert<br />
10:45 11. Developed the potential function<br />
of electrostatic interactions for quadrupolar<br />
fluid on the basis of consider the<br />
atomic charges as variables values for<br />
calculation of structure and thermodynamic<br />
properties by RISM.<br />
S. V. Keshtova, F. Keshtova<br />
11:15 12. Brownian motion in nonequilibrium<br />
colloidal suspensions: Dynamics of<br />
a stationary solution and swelling colloids.<br />
A. V. Popov, R. Hernandez<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
Tautomers and Biology<br />
Computer Handling of Tautomers<br />
Cosponsored by CINF, MEDI, and PHYS<br />
Y. Martin, Organizer<br />
T. Stouch, Organizer, Presiding<br />
8:30 13. Tautomerism in chemical information<br />
management systems. W. A. Warr<br />
9:00 14. Tautomerism in large databases.<br />
M. Sitzmann, W. Ihlenfeldt,<br />
M. C. Nicklaus<br />
9:30 15. Tautomerism in drug discovery.<br />
B. M. El-Gendy, A. R. Katritzky, C. Hall,<br />
B. Draghici<br />
10:00 Intermission<br />
10:15 16. Quantitative forecasts of biological<br />
potency of molecules that can tautomerize.<br />
Y. C. Martin<br />
10:45 17. New questions about tautomerism<br />
in cytosine: Quantum chemical and matrix<br />
isolation spectroscopic studies.<br />
G. Fogarasi, G. Bazso, P. G. Szalay,<br />
G. Tarczay<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 157B<br />
Methodology for Small Systems<br />
E. X. Esposito, Organizer<br />
V. Pakkala, Presiding<br />
8:30 18. Muonic molecules control in intense<br />
laser field. Q. Wang<br />
9:00 19. Exploring the free energy landscapes<br />
of chemical reactions. B. Ensing<br />
9:30 20. Three-body interactions in condensed<br />
phases of helium. R. J. Hinde<br />
10:00 Intermission<br />
10:15 21. Activation of the CO bond in CO 2<br />
by Ta and Nb mono and dications.<br />
E. Hull, T. Windus<br />
10:45 22. <strong>Chemical</strong> potential from particle<br />
removal and insertion: Upper and lower<br />
bounds and accurate estimates from<br />
computer simulations. J. C. Rasaiah,<br />
G. Feng, G. Hummer<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Drug Discovery<br />
Strike a Pose! But no Vogue-ing Please<br />
S. Wildman, Y. Tseng, Organizers<br />
Z. Yang, Presiding<br />
8:30 23. DOCK Blaster: Automatic docking<br />
with self-asessment. J. J. Irwin,<br />
B. K. Shoichet, K. T. Nguyen,<br />
M. M. Mysinger<br />
9:00 24. Key directions of mastering docking<br />
and scoring approaches. G. Chilov,<br />
O. Stroganov, F. Novikov, V. Stroylov,<br />
V. Kulkov<br />
9:30 25. How eHiTS solves the docking and<br />
scoring problems. Z. Zsoldos, O. Ravitz<br />
10:00 Intermission<br />
10:15 26. Combining atom-based and residue-based<br />
scoring functions in proteinprotein<br />
docking. T. Vreven, H. Hwang,<br />
Z. Weng<br />
10:45 27. SHAPEFIT: Pose prediction with<br />
shape and chemistry. B. P. Kelley,<br />
S. P. Brown<br />
11:15 28. Efficient protein-ligand docking including<br />
full receptor flexibility. I. Antes<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 153C<br />
Novel Is So Passé Just Say NEW Methods<br />
E. X. Esposito, Organizer<br />
S. Kim, Presiding<br />
8:30 29. (kSP) fluctuating charge method<br />
based on the consider polarization effects<br />
and anisotropy steric van der Waals<br />
radiuses of atoms in molecule.<br />
F. Keshtova, S. V. Keshtova<br />
9:00 30. Acidity constants and solvation<br />
structures of amino acids via DFTMD.<br />
M. Mangold, L. Rolland, F. Costanzo,<br />
M. Sprik, M. Sulpizi, J. Blumberger<br />
9:30 31. Variational formulation of the polarizable<br />
continuum model. G. Scalmani,<br />
F. Lipparini, B. Mennucci, E. Cances,<br />
M. Caricato, M. J. Frisch<br />
10:00 32. Going beyond the Frozen Core<br />
Approximation with a coordinate-dependent<br />
pseudopotential. A. Kahros,<br />
B. J. Schwartz<br />
10:30 Intermission<br />
10:45 33. Coupled cluster calculations in<br />
solution with the polarizable continuum<br />
model of solvation. M. Caricato,<br />
G. W. Trucks, M. J. Frisch<br />
11:15 34. Modeling molecular charge density<br />
with Gaussian multipoles.<br />
D. M. Elking, L. Perera, R. Duke,<br />
L. G. Pedersen<br />
11:45 35. Dispersion in combined ab initio/<br />
effective fragment potential systems.<br />
T. Smith, L. Slipchenko, M. S. Gordon<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Molecular Dynamics and Monte Carlo-<br />
Models and Algorithms Cosponsored by<br />
PHYS<br />
G. Voth, J. Straub, Organizers<br />
M. Tuckerman, Organizer, Presiding<br />
9:00 36. Statistical mechanical basis of<br />
coarse graining. A. Das, H. C. Andersen<br />
9:30 37. Well tempered-ensemble.<br />
M. Parrinello<br />
10:00 38. Molecular simulation: Five decades<br />
and counting. M. L. Klein<br />
10:30 Intermission<br />
10:45 39. <strong>Chemical</strong> dynamics at metal surfaces:<br />
The role of electronic excitations.<br />
N. Shenvi, S. Roy, J. Tully<br />
11:15 40. Coupling Quantum Monte Carlo<br />
for electrons with Monte Carlo for Ions.<br />
D. Ceperley<br />
11:45 41. Novel molecular dynamics based<br />
techniques for enhancing conformational<br />
sampling in systems described by rough<br />
energy landscapes. M. E. Tuckerman<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units (GP-<br />
GPUs)<br />
GPU Computing in Chemistry Sponsored by<br />
PHYS, Cosponsored by COMP<br />
Semantic Web in Chemistry<br />
RDF & Computation Sponsored by CINF,<br />
Cosponsored by COMP<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Hydrophobic Effect and Solvation<br />
Phenomena Cosponsored by PHYS<br />
G. Voth, J. Straub, M. Tuckerman,<br />
Organizers<br />
P. Rossky, Presiding<br />
1:30 42. Hard and soft interfaces of water.<br />
D. Chandler<br />
2:00 43. Effects of molecular-scale density<br />
fluctuations and surface roughness on<br />
hydrophobic hydration. J. Mittal,<br />
G. Hummer<br />
2:30 44. Excited state dynamics of conjugated<br />
polymers. P. J. Rossky<br />
3:00 Intermission<br />
3:15 45. Local molecular field analysis of hydrogen<br />
bonding patterns for water at hydrophilic<br />
and hydrophobic silica surfaces.<br />
R. C. Remsing, J. D. Weeks<br />
3:45 46. From water structure and fluctuations<br />
to hydrophobicity of proteins and<br />
interfaces. S. Garde<br />
4:15 47. Statistical thermodynamics of real<br />
liquids: Molecular quasi-chemical theory<br />
applied to liquid water. L. R. Pratt<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
Proteins<br />
E. X. Esposito, Organizer<br />
H. Liu, Presiding<br />
1:30 48. Investigating molecular mechanisms<br />
of specificity in regulation of the<br />
HER2 and HER4 tyrosine kinases.<br />
S. E. Telesco, R. Vadigepalli,<br />
R. Radhakrishnan<br />
2:00 49. Riboswitches in motion: Computational<br />
and experimental approaches.<br />
P. M. Petrone, A. Pomerantz,<br />
J. Dewhurst, R. Tommasi, L. Whitehead<br />
2:30 50. Differential dynamics coupling of<br />
plexin GTPase complexes in MD Simulations.<br />
L. Zhang, M. Buck<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
3:00 51. Computational study of the ammonium<br />
transport mechanism in AmtB: NH 3<br />
permeation vs. NH 3/H � Co-transport.<br />
S. Wang, G. Lamoureux<br />
3:30 Intermission<br />
3:45 52. Atomistic perspective of metabolite<br />
specificity in the SAM-II riboswitch.<br />
J. M. Kelley, D. Hamelberg<br />
4:15 53. Linear interaction energy method<br />
for the prediction of protein stability<br />
changes upon mutation. L. Wickstrom,<br />
E. Gallicchio, R. Levy<br />
4:45 54. Molecular mechanics and the evolution<br />
of enzyme activity. M. K. Singh,<br />
A. R. Brice, C. Stanton, B. N. Dominy<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Scripting & Programming<br />
HPC on the Cheap Cosponsored by CINF<br />
R. Guha, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 55. FPGA implementation of cheminformatics<br />
and computational chemistry<br />
algorithms and its cost/performance<br />
comparison with GPGPU, cloud computing<br />
and SIMD implementations.<br />
A. Berces, B. Feher, P. Szanto,<br />
I. Pechan, L. Lajko, Z. Runyo, P. Laczko,<br />
J. Lazanyi<br />
2:05 56. Technologies for desktop HPC: Application<br />
developer’s perspective.<br />
V. Kindratenko,G.Shi<br />
2:35 57. Faster, cheaper, and better science:<br />
Molecular modeling on GPUs.<br />
J. E. Stone<br />
3:05 58. Folding@home: Petaflops on the<br />
cheap today, exaflops soon? V. Pande<br />
3:35 Intermission<br />
3:50 59. Protein-ligand docking on the<br />
Cell/BE processor with eHiTS Lightning.<br />
Z. Zsoldos, O. Ravitz<br />
4:20 60. Fragment-based druggable hot<br />
spot identification in proteins and proteinprotein<br />
interactions using HPC.<br />
G. Chuang, R. Brenke, D. R. Hall,<br />
D. Beglov, D. Kozakov,S.Vajda<br />
4:50 61. GPUs: What is all the fuss about?<br />
B. Cole, B. Tolbert, A. Nicholls<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
The PDB and Chemistry<br />
T. Stouch, Organizer, Presiding<br />
1:30 62. wwPDB: An organization that provides<br />
macromolecular structural data to<br />
the global community. H. M. Berman,<br />
G. J. Kleywegt, H. Nakamura,<br />
J. L. Markley<br />
2:00 63. wwPDB common annotation and<br />
deposition tool project. M. Quesada,<br />
J. Westbrook, T. Oldfield, J. Young,<br />
J. Swaminathan, Z. Feng, S. Velankar,<br />
M. Zhuravleva, G. Sahni, C. Shao,<br />
T. Matsuura, E. Ulrich, S. Madding<br />
2:30 64. Small molecule resources and<br />
search tools at the PDB.<br />
D. Dimitropoulos, J. Westbrook<br />
3:00 65. Remediation of PDB entries containing<br />
molecules with antibiotic and inhibitory<br />
pharmacological properties.<br />
M. Hirshberg, S. Dutta, K. Henrick<br />
3:30 Intermission<br />
3:45 66. Synergies of the PDB and the CSD.<br />
T. S. Olsson, J. C. Cole, S. Bowden,<br />
C. R. Groom<br />
4:15 67. Iridium: Prepping PDB data for use<br />
in computation chemistry software development.<br />
G. L. Warren,T.Do,<br />
S. D. Warren<br />
4:45 68. Challenges in positioning, validation,<br />
annotation and visualization of<br />
chemical compounds bound to proteins.<br />
R. Abagyan<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 157B<br />
Drug Discovery<br />
Docking<br />
S. Wildman, Y. Tseng, Organizers<br />
P. Mukherjee, Presiding<br />
1:30 69. Understanding of drug-target interactions<br />
and substrate binding to neuraminidase<br />
of influenza A virus subtypes<br />
H5N1 and H1N1-2009. M. Malaisree,<br />
T. Rungrotmongkol, N. Nantaboot,<br />
A. Mulholland, S. Hannongbua<br />
2:00 70. Structure-based lead optimization<br />
of small molecule Aurora A and CDK1 inhibitors.<br />
D. Wang, L. Zhang,<br />
J. l. Brazidec, L. Silvian, D. Marcotte,<br />
J. Fan, J. Chong, M. Teng, S. Zhao,<br />
K. Nguyen, A. Pasis, B. Tam, C. Boykin,<br />
G. Claassen, K. Lundgren, J. Chao,<br />
A. Lugovskoy<br />
2:30 71. Structure-based drug design of inhibitors<br />
of TNF-� converting enzyme<br />
(TACE). Z. Guo<br />
3:00 Intermission<br />
3:15 72. Evaluation of DOCK6 for pose prediction<br />
and enrichment. S. Mukherjee,<br />
T. E. Balius, R. C. Rizzo<br />
3:45 73. Binding of the macrocyclic noncovalent<br />
inhibitor TMC435 to its HCV NS3/<br />
NS4A protease target. M. D. Cummings,<br />
J. Lindberg, T. Lin, H. de Kock, O. Lenz,<br />
E. Lilja, S. Fellander, V. Baraznenok,<br />
S. Nystrom, M. Nilsson, L. Vrang,<br />
M. Edlund, A. Rosenquist,<br />
B. Samuelsson, P. Raboisson, K. Simmen<br />
4:15 74. Molecular modeling of the aryl hydrocarbon<br />
receptor and its interaction<br />
with ligands. A. S. Jogalekar, S. Reiling,<br />
R. J. Vaz<br />
4:45 75. Methodological advancements to<br />
improve the accuracy of induced-fit<br />
docking. Z. Zhou, R. Farid, W. Sherman<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Using Waters Explicitly in Drug Discovery<br />
Theory and Methods Cosponsored by CINF<br />
and MEDI<br />
V. Shanmugasundaram, Organizer<br />
W. Sherman, Organizer, Presiding<br />
1:30 Introductory Remarks - Woody Sherman<br />
1:35 76. Water in protein binding sites: Consequences<br />
for ligand optimization.<br />
J. Michel, J. Tirado-Rives, J. Luccarelli,<br />
W. L. Jorgensen<br />
2:15 77. Efficient method for computing the<br />
free energies of active site waters: Application<br />
to drug discovery. J. Zou,<br />
S. Meshkat, Z. Konteatis, A. Klon,<br />
C. H. Reynolds<br />
2:45 78. Using explicit solvent implicitly.<br />
C. J. Fennell, C. W. Kehoe, K. A. Dill<br />
3:15 Coffee Break<br />
3:30 79. Role of solvent in protein-ligand<br />
binding. R. Abel, N. Salam, T. Beuming,<br />
W. Sherman, R. Farid<br />
4:00 80. Compute the contribution of protein-pocket<br />
solvation to ligand-binding<br />
affinity by explicit water simulations.<br />
M. Hao, I. Muegge<br />
4:30 81. All-atom explicit-solvent fragmentbased<br />
drug discovery: SILCS (“Site Identification<br />
by Ligand Competitive Saturation”)<br />
molecular dynamics simulations<br />
applied to IL-2. O. Guvench<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 153C<br />
We Were Promised Jet Packs. They Found<br />
Out About These on the Way<br />
E. X. Esposito, Organizer<br />
Z. Cournia, Presiding<br />
1:30 82. Past, present, and future of<br />
semiempirical methods. J. J. Stewart<br />
2:00 83. Monte Carlo study of the axial nextnearest-neighbor<br />
Ising model and other<br />
microphase forming systems. K. Zhang,<br />
P. Charbonneau<br />
2:30 84. B2GP-PLYP and friends: Robust,<br />
generally applicable, double-hybrid functionals<br />
for thermochemistry, thermochemical<br />
kinetics, and weak interactions.<br />
J. M. Martin<br />
3:00 85. Exploring formation, spectroscopy,<br />
and outcome of disulfide radical anions<br />
by QM/MM approaches: Insights into a<br />
molecular rheostat. E. Dumont,<br />
A. D. Laurent, P. Loos, X. Assfeld<br />
3:30 Intermission<br />
3:45 86. Accelerating self-consistent field<br />
convergence with the augmented<br />
Roothaan–Hall energy function. X. Hu,<br />
W. Yang<br />
4:15 87. Computer algorithm development<br />
for modeling of biological macromolecules.<br />
D. Janezic<br />
4:45 88. Common catalytic features among<br />
cofactor independent racemases and<br />
epimerases: A computational perspective.<br />
M. Stenta, P. Altoè, M. Dal Peraro,<br />
M. Garavelli, A. Bottoni<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units (GP-<br />
GPUs)<br />
Molecular Dynamics on GPUs Sponsored by<br />
PHYS, Cosponsored by COMP<br />
Data-intensive Drug Design Sponsored by<br />
CINF, Cosponsored by COMP<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Quantum Effects in Thermodynamics and<br />
Dynamics Cosponsored by PHYS<br />
G. Voth, J. Straub, M. Tuckerman,<br />
Organizers<br />
J. Cao, Presiding<br />
8:30 89. Signature of quantum coherent effects.<br />
J. Cao<br />
9:00 90. Quantum dynamics of excitation<br />
energy transfer in nanostructured environments.<br />
D. F. Coker, P. Huo, T. Rivera,<br />
D. Montemayor<br />
9:30 91. Can impact excitation explain carrier<br />
multiplication in carbon nanotube<br />
photodiodes? E. Rabani<br />
10:00 Intermission<br />
10:15 92. Electronically non-adiabatic dynamics<br />
via semiclassical initial value<br />
methods. W. H. Miller<br />
10:45 93. Very accurate semiclassical surface<br />
hopping calculations. M. F. Herman<br />
11:15 94. <strong>Chemical</strong> reaction rates from ring<br />
polymer molecular dynamics.<br />
D. E. Manolopoulos<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
An Emerging Challenge in Multiscale<br />
Modeling and Simulation: Mechanistic<br />
Understandings<br />
Multiscale Simulation Methods<br />
H. Guo, Organizer<br />
J. Chu, Organizer, Presiding<br />
8:30 95. Multiscale models from molecules<br />
to life. Y. N. Kaznessis<br />
9:00 96. Many-scale and multi-scale modeling<br />
in computational nanoscience.<br />
P. T. Cummings<br />
9:30 97. Coarse-grained and multiscale<br />
models of bulk liquids and macromolecules.<br />
T. Head-Gordon<br />
10:00 Intermission<br />
10:15 98. Examining methods for general<br />
multi-scale modeling using CHARMM.<br />
B. R. Brooks<br />
10:45 99. ErbB receptor mediated oncogenic<br />
signaling: Molecular systems biology<br />
through multiscale modeling and<br />
high-performance computing.<br />
R. Radhakrishnan<br />
11:15 100. Coarse grained molecular dynamics<br />
of biological and soft matter systems.<br />
R. H. DeVane, W. Shinoda,<br />
M. L. Klein<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
Tautomers and Biology<br />
Predictions of Tautomer Ratios<br />
Cosponsored by CINF, MEDI, and PHYS<br />
T. Stouch, Organizer<br />
Y. Martin, Organizer, Presiding<br />
8:30 101. Predicting tautomer preference:<br />
Simple rules and unforeseen complexities.<br />
P. W. Kenny, P. J. Taylor<br />
9:00 102. Methods for robust and efficient<br />
tautomer enumeration, tautomer searching<br />
and tautomer duplicate filtering.<br />
J. Szegezdi, Z. Mohácsi, T. Csizmazia,<br />
S. Dóránt, &. Papp, G. Pirok,<br />
S. Csepregi, F. Csizmadia<br />
9:30 103. Tautomerization approach for<br />
drug-like molecules. J. C. Shelley,<br />
A. P. Sullivan, D. Calkins,<br />
J. R. Greenwood<br />
10:00 Intermission<br />
10:15 104. Acid/base ionization vs. prototropic<br />
tautomerism. R. Fraczkiewicz,<br />
M. Waldman, R. D. Clark, W. S. Woltosz,<br />
M. B. Bolger<br />
10:45 105. Combinatorial-computationalchemoinformatics<br />
approach to finding<br />
and analyzing low-energy tautomers.<br />
M. Haranczyk, M. Gutowski<br />
11:15 106. Comparison of pattern-based<br />
and algorithm-based approaches to tautomer<br />
informatics. B. Ellingson,<br />
R. Tolbert, A. Skillman<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
COMP<br />
TECH–41
COMP <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Drug Discovery<br />
High Throughput Screening: Robots Ruling<br />
the Plates<br />
S. Wildman, Y. Tseng, Organizers<br />
S. Natesan, Presiding<br />
8:30 107. Sticking to kinases: Scaffold selectivity<br />
and implications for focused library<br />
design. S. L. Posy, S. R. Johnson,<br />
D. Loughney, M. Hermsmeier,<br />
W. Vaccaro, G. Trainor, K. Ott<br />
9:00 108. Novel classification of proteases<br />
in the peptide substrate space reveals<br />
cross-family substrate similarities with<br />
applications to lead discovery.<br />
S. K. Sukuru, F. Nigsch, J. Quancard,<br />
M. Renatus, R. Chopra, N. Brooijmans,<br />
D. Mikhailov, Z. Deng, A. Cornett,<br />
J. L. Jenkins, U. Hommel, J. W. Davies,<br />
M. Glick<br />
9:30 109. Profile-QSAR and surrogate autoshim:<br />
Utilizing chemogenomic relationships<br />
for drug discovery applications.<br />
P. Mukherjee, E. Martin<br />
10:00 Intermission<br />
10:15 110. Introduction of an interpretation<br />
layer to link unsupervised and supervised<br />
methods for classification of chemicals in<br />
biological effects space. J. Rathman,<br />
C. Yang<br />
10:45 111. Creating reaction schemes to<br />
generate an arbitrary number of linked<br />
and conjugated polymers.<br />
R. Olivares-Amaya, S. Atahan,<br />
A. Aspuru-Guzik, C. A. Bedolla<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 153C<br />
Waters: Feisty Little Molecules<br />
E. X. Esposito, Organizer<br />
K. Immadisetty, Presiding<br />
8:30 112. Quantitative rate calculations from<br />
simulations: The Ru 2� -Ru 3� electron<br />
self-exchange reaction in water.<br />
H. Oberhofer, J. Blumberger<br />
9:00 113. “On water” reactivity and solvent<br />
effects for Claisen rearrangements from<br />
QM/MM simulations. O. Acevedo,<br />
K. Armacost<br />
9:30 114. Effect of hydrogen bonding on the<br />
dynamical stability of water clusters.<br />
J. R. Green, T. S. Hofer, D. J. Wales<br />
10:00 Intermission<br />
10:15 115. DFT geometry optimization and<br />
vibrational frequencies of the quaternary<br />
ammonium cation-water [N (CH 3) 4 � OH - /<br />
(H 2O) n] clusters. D. Kumari,<br />
E. S. Smotkin, N. Dimakis<br />
10:45 116. Computational study of vibrational<br />
spectra of some water containing<br />
complexes of atmospheric interest.<br />
E. Sälli, T. Salmi, L. Halonen<br />
11:15 117. Using a vibrational averaging<br />
technique to understand the role of water<br />
dimers in atmospheric absorption.<br />
R. E. Kelly, M. J. Barber, J. Tennyson,<br />
G. C. Groenenboom, A. van der Avoird<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Challenges in Industrial Computational<br />
Methods<br />
42–TECH<br />
A. Nicholls, E. Sourial, Organizers<br />
C. Lemmen, C. Groom, Presiding<br />
‡ Cooperative Cosponsorship<br />
9:00 118. Modeling for the masses: The philosphers’<br />
stone of CAMD software.<br />
A. C. Good<br />
10:00 119. Lightning-fast 3D-shape and feature-based<br />
virtual screening. C. Lemmen<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 157B<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Cosponsored by BIOL, CINF, and MEDI<br />
H. Carlson, Organizer, Presiding<br />
9:00 Introductory Remarks<br />
9:05 120. Community structure-activity resource:<br />
Collecting, curating, and generating<br />
protein-ligand data to improve docking<br />
and scoring. J. B. Dunbar,<br />
H. A. Carlson<br />
9:35 121. Results of CSAR’s 2010 Benchmark<br />
Exercise. J. B. Dunbar, R. D. Smith,<br />
H. A. Carlson<br />
10:05 122. Scoring performance of eHiTS<br />
on the CSAR dataset. Z. Zsoldos,<br />
O. Ravitz<br />
10:35 Intermission<br />
10:50 123. Hydrophobic complementarity: A<br />
dominant term in affinity and binding<br />
mode prediction. L. A. Kuhn,<br />
M. E. Tonero<br />
11:20 124. Docking and scoring for 2010<br />
CSAR benchmark using an improved iterative<br />
knowledge-based scoring function<br />
with MDock. S. Huang, X. Zou<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units (GP-<br />
GPUs)<br />
Electronic Structure Calculations on GPUs<br />
Sponsored by PHYS, Cosponsored by COMP<br />
Semantic Web in Chemistry<br />
OWL <strong>Chemical</strong> Ontologies Sponsored by<br />
CINF, Cosponsored by COMP<br />
The Journal of <strong>Chemical</strong> Information and<br />
Modeling’s 50th Anniversary Symposium<br />
Sponsored by CINF, Cosponsored by COMP<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Thermodynamics and Dynamics of<br />
Complex Systems Cosponsored by PHYS<br />
G. Voth, J. Straub, M. Tuckerman,<br />
Organizers<br />
R. Silbey, Presiding<br />
1:30 125. Quantum glass. D. Reichman<br />
2:00 126. Energy transfer, coherence, and<br />
decoherence in molecular aggregates.<br />
R. J. Silbey<br />
2:30 127. Local solvent environment dependent<br />
electron transfer reactions in roomtemperature<br />
ionic-liquids. C. J. Margulis<br />
3:00 Intermission<br />
3:15 128. Crystallization of hard aspherical<br />
particles. A. Cacciuto<br />
3:45 129. Fluctuations and the second law<br />
of thermodynamics: What do we know<br />
that Maxwell, Boltzmann and Gibbs did<br />
not know? C. Jarzynski<br />
4:15 130. Microscopic kinetic model exhibiting<br />
chiral symmetry breaking.<br />
F. H. Stillinger<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
An Emerging Challenge in Multiscale<br />
Modeling and Simulation: Mechanistic<br />
Understandings<br />
New Developments in Coarse-grain Theory<br />
H. Guo, J. Chu, Organizers<br />
M. Hagan, Presiding<br />
1:30 131. Getting the right answer for the<br />
right reason: Accurate and transferable<br />
coarse-grained models from structural information.<br />
W. G. Noid, W. Mullinax<br />
2:00 132. Improved lattice models of the hydrophobic<br />
effect. P. Varilly, A. J. Patel,<br />
D. Chandler<br />
2:30 133. Dissecting force interactions between<br />
cellulose and ionic liquids by using<br />
the iterative-YGB method. H. Cho,J.Chu<br />
3:00 Intermission<br />
3:15 134. Fluctuations, slow dynamics, and<br />
ordering across length and time scales in<br />
nanoparticle self-assembly.<br />
P. L. Geissler, M. Gruenwald,<br />
A. Widmer-Cooper<br />
3:45 135. Generalized mean field theory of<br />
coarse-graining. V. Krishna, L. Larini<br />
4:15 136. Statistics in multiresolution modeling:<br />
An application of Bayesian interference<br />
in multiscale coarse-graining. P. Liu<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Challenges in Industrial Computational<br />
Methods<br />
A. Nicholls, E. Sourial, Organizers<br />
C. Lemmen, C. Groom, Presiding<br />
1:30 137. Risk assessment of chemicals and<br />
prediction of metabolism. J. Gasteiger,<br />
T. Kleinoeder, J. Marucszyk,<br />
C. H. Schwab, A. Tarkhov, L. Terfloth<br />
2:30 138. Considering protein structural<br />
variations in molecular docking: Ensemble<br />
docking with GOLD. J. Cole,<br />
C. Groom<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
The Journal of <strong>Chemical</strong> Information and<br />
Modeling’s 50th Anniversary Symposium<br />
Cosponsored by CINF<br />
W. Jorgensen, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:40 139. Configurational entropy and mechanical<br />
stress in molecular recognition.<br />
M. K. Gilson<br />
2:10 140. Advancing anthrax toxin countermeasures<br />
using topomeric searching and<br />
virtual screening methodologies.<br />
E. A. Amin, T. Chiu, D. J. Hook,<br />
M. A. Walters, B. C. Finzel, J. Solberg,<br />
S. Patil, T. W. Geders, S. Rangarajan,<br />
R. Francis, X. Zhang<br />
2:40 141. Model-free drug-like filters.<br />
O.Ursu,C.G.Bologa,T. I. Oprea<br />
3:10 Intermission<br />
3:25 142. Chemocentric informatics: Enabling<br />
bioactive compound discovery<br />
through structural hypothesis fusion.<br />
A. Tropsha<br />
3:55 143. Computers and drug discovery:<br />
From duds to $5B drugs. R. C. Glen<br />
4:25 144. Weighting and fusion methods for<br />
similarity-based virtual screening.<br />
P. Willett, S. Arif, J. Holliday, N. Malim,<br />
C. Mueller<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 157B<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Cosponsored by BIOL, CINF, and MEDI<br />
H. Carlson, Organizer<br />
J. Dunbar, Presiding<br />
1:30 145. Lead Finder in the CSAR scoring<br />
challenge. V. Stroylov, G. Chilov,<br />
O. Stroganov, F. Novikov, V. Kulkov<br />
2:00 146. Benchmark of solvated interaction<br />
energy (SIE) scoring function on the<br />
CSAR-2010 dataset. T. Sulea,Q.Cui,<br />
H. Hogues, C. R. Corbeil, E. O. Purisima<br />
2:30 147. Protonation states and scoring receptor-ligand<br />
poses: It’s always the details.<br />
E. X. Esposito<br />
3:00 Intermission<br />
3:15 148. Role of active-site solvent in protein-ligand<br />
binding affinity calculations.<br />
Y. Che, V. Shanmugasundaram<br />
3:45 149. Flexible docking using a stochastic<br />
rotamer library of ligands. F. Ding,<br />
S. Yin, N. V. Dokholyan<br />
4:15 150. Cheminformatics meets molecular<br />
mechanics: A combined application of<br />
knowledge based pose scoring and<br />
physical force field-based hit scoring<br />
functions improves the accuracy of virtual<br />
screening. J. Hsieh, S. Yin, X. S. Wang,<br />
S. Liu, N. V. Dokholyan, A. Tropsha<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Using Waters Explicitly in Drug Discovery<br />
Characterization and Applications<br />
Cosponsored by CINF and MEDI<br />
W. Sherman, Organizer<br />
V. Shanmugasundaram, Organizer,<br />
Presiding<br />
1:30 Introductory Remarks - Veer Shanmugasundaram<br />
1:35 151. Application of free energy methods<br />
to water molecules in protein binding<br />
sites. J. W. Essex, C. Barillari,<br />
M. Bodnarchuk, R. Viner<br />
2:15 152. Which waters are important and<br />
how do we identify them? S. Bowden,<br />
J. C. Cole, O. Korb, T. Olsson,<br />
J. Liebescheutz, C. Groom<br />
2:45 153. Free energies and entropies of<br />
water molecules at protein-ligand interfaces.<br />
S. W. Rick,H.Yu<br />
3:15 Coffee Break<br />
3:30 154. Role of water molecules in docking<br />
studies of Cytochromes P450.<br />
C. Oostenbrink<br />
4:00 155. Modeling explicit waters in docking<br />
and scoring. N. Huang<br />
4:30 156. Desolvation/resolvation: A revolving<br />
door that controls the rates of association/dissociation<br />
of protein-ligand complexes?<br />
Analysis of PCSK9-EGF-A<br />
binding kinetics using WaterMap.<br />
R. A. Pearlstein, Q. Hu, J. Zhou,<br />
D. Yowe, J. Levell, B. Dale, V. Kaushik,<br />
D. Daniels, S. Hanrahan, W. Sherman,<br />
R. Abel<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
5:00 157. Biophysics-based library design:<br />
Discovery of “non-acid” inhibitors of S1<br />
DHFR. V. Shanmugasundaram,<br />
K. Borzilleri, J. Chang, B. Chrunyk,<br />
M. E. Flanagan, S. Han, M. Harris,<br />
B. Lacey, R. Miller, P. Sahasrabudhe,<br />
R. Sarver, H. Soutter, J. Withka<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units (GP-<br />
GPUs)<br />
GPU Computing in Chemistry Sponsored by<br />
PHYS, Cosponsored by COMP<br />
Semantic Web in Chemistry<br />
RDF/OWL Applications Sponsored by CINF,<br />
Cosponsored by COMP<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
E. X. Esposito, Organizer<br />
8:00–10:00<br />
233, 237, 242, 243, 249, 255, 256, 257, 266,<br />
268, 271, 288, 296, 302, 307. See subsequent<br />
listings.<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Force Field Development Cosponsored by<br />
PHYS<br />
G. Voth, J. Straub, M. Tuckerman,<br />
Organizers<br />
H. Stern, Presiding<br />
8:30 158. WaterMap: A new approach to<br />
mapping water structure, energetics, and<br />
free energies of displacement by ligands<br />
in protein active sites. R. A. Friesner<br />
9:00 159. QM/MM simulations of organic<br />
and enzymatic reactions.<br />
W. L. Jorgensen<br />
9:30 160. Recent advances in the development<br />
of a polarizable force field for simulations<br />
of complex biomolecular systems.<br />
B. Roux, W. Jiang, D. Hardy, J. Phillips,<br />
A. D. MacKerell, K. Schulten, E. Harder,<br />
J. Chowdhary, X. Zhu, P. Lopes, J. Shim,<br />
C. Baker, H. Yu, A. Lau<br />
10:00 Intermission<br />
10:15 161. Estimating protein-ligand binding<br />
affinities using a fluctuating charge<br />
model. H. A. Stern<br />
10:45 162. Applications of variable timestep<br />
integrators and polarizable potentials in<br />
condensed phase simulations.<br />
S. J. Stuart<br />
11:15 163. Efficient methods for replica exchange<br />
and charge transfer models for<br />
liquid simulation. S. W. Rick,A.J.Lee<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
An Emerging Challenge in Multiscale<br />
Modeling and Simulation: Mechanistic<br />
Understandings<br />
Reaction Pathways of Biomolecules<br />
H. Guo, Organizer<br />
J. Chu, Organizer, Presiding<br />
8:30 164. Modeling co-translational folding<br />
of ribosome-nascent chain using AFM<br />
probe and computer simulations.<br />
X. Zeng, W. Lee, H. Zhou, V. Bennett,<br />
W. Yang, P. E. Marszalek<br />
9:00 165. Multi-scaled explorations of binding<br />
induced folding of intrinsically disordered<br />
protein inhibitor IA3 to its target enzyme.<br />
J. Wang<br />
9:30 166. Ligand binding, hinge strain, and<br />
local unfolding: Driving forces of conformational<br />
change in adenylate kinase.<br />
J. Brokaw<br />
10:00 Intermission<br />
10:15 167. Systematic identification of order<br />
parameters in biophysical systems.<br />
A. L. Ferguson, P. G. Debenedetti,<br />
I. G. Kevrekidis, A. Z. Panagiotopoulos<br />
10:45 168. Ab initio QM/MM minimum free<br />
energy path for simulating chemical reaction<br />
and redox processes in solution and<br />
in enzymes. W. Yang<br />
11:15 169. Development and application of<br />
the string method to characterize conformational<br />
transition pathways in complex<br />
biomolecular systems. B. Roux,W.Gan,<br />
L. Maragliano<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
Tautomers and Biology<br />
Tautomers and Macromolecule-ligand<br />
Complexes Cosponsored by CINF, MEDI, and<br />
PHYS<br />
T. Stouch, Organizer<br />
Y. Martin, Organizer, Presiding<br />
8:30 170. Computational evaluation of tautomers<br />
and zwitterions of D-amino acid<br />
oxidase (DAAO) inhibitors. S. Mente<br />
9:00 171. Defining states of ionization and<br />
tautomerization of thiamin diphosphate at<br />
individual reaction intermediates on enzymes:<br />
Enzymes that use a rare tautomeric<br />
form. F. Jordan, N. S. Nemeria,<br />
A. Balakrishnan, S. Paramasivam,<br />
T. Polenova<br />
9:30 Intermission<br />
9:45 172. Do tautomers matter in calculating<br />
molecular similarity? S. W. Muchmore,<br />
I. Haight, S. Brown<br />
10:15 173. Automated prediction of tautomeric<br />
states in protein-ligand complexes.<br />
S. Urbaczek, S. Bietz, M. Rarey<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 157B<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Cosponsored by BIOL, CINF, and MEDI<br />
H. Carlson, Organizer, Presiding<br />
8:30 174. Predicting relative binding affinities<br />
in the CSAR Scoring Challenge.<br />
M. P. Jacobson, C. Kalyanaraman<br />
9:00 175. Surflex: Docking and scoring on<br />
CSAR. A. N. Jain<br />
9:30 176. What we can learn from very large<br />
panel docking screens. K. T. Nguyen,<br />
J. J. Irwin, B. K. Shoichet,<br />
M. M. Mysinger<br />
10:00 Community Discussion: Evaluation<br />
Criteria<br />
10:30 Intermission<br />
10:45 177. Docking and scoring of fragments.<br />
M. L. Verdonk<br />
11:15 Community Discussion: Dataset<br />
Criteria<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Drug Discovery<br />
Using the Receptor Against Itself<br />
S. Wildman, Y. Tseng, Organizers<br />
R. Baron, Presiding<br />
8:30 178. Dynamical investigation of autoinhibitory<br />
mechanism of AMP-activated<br />
protein kinase. C. Peng, T. Head-Gordon<br />
9:00 179. Accounting for ligand conformational<br />
restriction in calculations of protein-ligand<br />
binding affinities. H. A. Stern<br />
9:30 180. Assessment of factors determining<br />
successful potency prediction in lead<br />
optimization: A case study with dual Abl/<br />
Src kinase inhibitors. A. Kohlmann,<br />
X. Zhu, T. Zhou, L. Commodore, L. Xue,<br />
Y. Wang, W. Huang, S. Liu, M. Thomas,<br />
Q. Xu, J. Keats, V. M. Rivera,<br />
C. A. Metcalf, T. K. Sawyer, T. Clackson,<br />
W. C. Shakespeare, D. C. Dalgarno<br />
10:00 181. Accelerated MD simulation study<br />
of the maltose-binding protein.<br />
D. Bucher,A.J.McCammon,<br />
P. Markwick, B. Grant<br />
10:30 Intermission<br />
10:45 182. Changes of human receptor<br />
binding affinity of H1N1 hemagglutinins:<br />
Insights from molecular dynamics simulation.<br />
N. Nunthaboot, T. Rungrotmongkol,<br />
M. Malaisree, N. Kaiyawet, P. Decha,<br />
P. Sompornpisut, Y. Poovorawan,<br />
S. Hannongbua<br />
11:15 183. Benchmark set for validating and<br />
testing free energy methods in molecular<br />
design. H. Paliwal, M. R. Shirts<br />
11:45 184. Reaction network analysis and<br />
the application of structure-based<br />
screening methods for the butanoate<br />
metabolic pathways. Q. Wang,D.Wu,<br />
R. Assary, L. J. Broadbelt, G. Krilov<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 155<br />
Quantum Chemistry<br />
E. X. Esposito, Organizer<br />
J. Sanders, Presiding<br />
8:30 185. Importance of solvent and dynamics<br />
on the dehydrogenation of ammonia<br />
borane. P. M. Zimmerman, Z. Zhang,<br />
C. B. Musgrave<br />
9:00 186. pKa predictions of some organic<br />
amine solvents. M. Elanany<br />
9:30 187. Simulated back proton transfer in<br />
3-Hydroxyflavone. Y. Tambouret,<br />
D. Coker<br />
10:00 188. Ab initio study of hydrogen<br />
bonding cooperativity in arylamide.<br />
J. A. Geer, J. Galan, Z. Liu, V. Pophristic<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Challenges in Industrial Computational<br />
Methods<br />
A. Nicholls, E. Sourial, Organizers<br />
C. Lemmen, C. Groom, Presiding<br />
9:00 189. Drug discovery technology: The<br />
past, the present, and the future.<br />
C. Lipinski<br />
10:00 190. Generating novel compounds via<br />
rule-based molecular transformations.<br />
J. Leonard, A. Clark<br />
Design, Discovery, and Directed Evolution<br />
of Enzyme Activities Sponsored by BIOL,<br />
Cosponsored by COMP and POLY<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Reaction Rate Theory, Vibrational<br />
Relaxation, and Simulation Methods<br />
Cosponsored by PHYS<br />
G. Voth, J. Straub, M. Tuckerman,<br />
Organizers<br />
J. Skinner, Presiding<br />
1:30 191. Vibrational spectroscopy of water<br />
and ice. J. Skinner<br />
2:00 192. Rates of reactions activated by<br />
non-Gaussian noise. H. Grabert,<br />
D. F. Urban<br />
2:30 193. Dynamics of photoinduced proton-coupled<br />
electron transfer reactions.<br />
S. Hammes-Schiffer<br />
3:00 Intermission<br />
3:15 194. Theory of rainbow scattering from<br />
surfaces. E. Pollak<br />
3:45 195. Heat transfer, heating and cooling<br />
in molecular conduction junctions.<br />
A. Nitzan<br />
4:15 196. Sorting out electrostatic polarization,<br />
dispersion, and hydrogen bonding in<br />
solvatochromic shifts. A. V. Marenich,<br />
C. J. Cramer, D. G. Truhlar<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
An Emerging Challenge in Multiscale<br />
Modeling and Simulation: Mechanistic<br />
Understandings<br />
Self-assembled Systems<br />
H. Guo, J. Chu, Organizers<br />
W. Noid, Presiding<br />
1:30 197. Multiscale simulation of membrane<br />
remodeling by proteins. G. A. Voth<br />
2:00 198. Self-limited self-assembly of chiral<br />
filaments. Y. Yang, R. Meyer, M. Hagan<br />
2:30 199. Combining theory, computation,<br />
and experiment for studying protein aggregation.<br />
R. V. Pappu<br />
3:00 Intermission<br />
3:15 200. Understanding the effect of cholesterol<br />
on the properties of membranes.<br />
B. Smit, F. de Meyer, J. M. Rodgers,<br />
A. Benjamini<br />
3:45 201. Capsid assembly around RNA and<br />
other polyelectrolytes: Multiple roles of<br />
the polymeric cargo. O. M. Elrad,<br />
M. Perkett, M. F. Hagan<br />
4:15 202. Intrinsic bending states of tubulin<br />
dimers and protofilaments.<br />
A. Grafmueller,G.A.Voth<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Challenges in Industrial<br />
Computational Methods<br />
A. Nicholls, E. Sourial, Organizers<br />
C. Lemmen, C. Groom, Presiding<br />
1:30 203. Are the laws of chemistry and<br />
physics sufficient for the discovery of<br />
new drugs? G. Maggiora<br />
2:30 204. How should the world of molecular<br />
modeling be organized? Thoughts and<br />
speculations. A. Nicholls<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
Insane in the Membrane<br />
E. X. Esposito, Organizer<br />
S. Manepalli, Presiding<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
COMP<br />
TECH–43
COMP <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
1:30 205. Peptide partitioning properties<br />
from direct water-to-membrane insertion<br />
studies. J. P. Ulmschneider<br />
2:00 206. Understanding interactions of propylene<br />
glycol and skin lipids using molecular<br />
dynamics simulation. J. Ghosh,<br />
B. Michniak-Kohn<br />
2:30 207. Conformational prediction of the<br />
HIV-1 gp41 membrane-spanning domain.<br />
V. K. Gangupomu,C.F.Abrams<br />
3:00 208. Computing dynamics, electrostatics<br />
and spectroscopy at membrane-water<br />
interfaces. J. D. Hirst, D. Robinson,<br />
N. A. Besley, P. O’Shea<br />
3:30 Intermission<br />
3:45 209. Lipid10: A comprehensive phospholipid<br />
force field for AMBER.<br />
R. C. Walker, A. Skjevik, K. Teigen<br />
4:15 210. Adaptive multiscale modeling of<br />
bilayer systems. P. B. Moore, V. Perez,<br />
S. O. Nielsen, B. Ensing<br />
4:45 211. Effect of spherical fullerenes on<br />
pulmonary lipid monolayers: Molecular<br />
dynamics simulations. S. O. Nielsen,<br />
C. Chiu, P. B. Moore, R. DeVane,<br />
M. L. Klein, W. Shinoda<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 157B<br />
Docking & Scoring: What Have We Learned<br />
and Where Are We Now?<br />
Computational Approaches for Fragment<br />
Screening<br />
N. Nevins, G. Warren, Organizers<br />
G. McGaughey, Organizer, Presiding<br />
1:30 212. Fragment docking in BACE: Retrospective<br />
survey of loop sampling and<br />
docking. J. H. Voigt, P. Orth, Y. Wang,<br />
D. Wyss, S. Babu, J. Caldwell,<br />
S. Chackalamannil, X. Che, J. Cumming,<br />
M. Czarniecki, J. Duo, J. Durkin, H. Gu,<br />
T. Guo, R. Hunter, U. Iserloh,<br />
M. E. Kennedy, R. Kuvelkar, L. Thuy,<br />
V. Madison, R. D. Mazzola,<br />
B. A. McKittrick, T. Meng, J. Misiaszek,<br />
T. Nechuta, J. Pan, E. Parker, G. Qian,<br />
K. Saionz, M. Senior, E. M. Smith, Z. Sun,<br />
D. Tadesse, L. Wang, J. Wong, Y. Wu,<br />
Y. Xia, Y. Ye, J. Zhao, Z. Zhu,<br />
A. Stamford, W. Greenlee, C. Strickland<br />
2:00 213. Accurate pose prediction and improved<br />
structure-based virtual screening<br />
for fragments. W. Sherman<br />
2:30 214. Fragment screening paradigm for<br />
drug discovery. D. Joseph-McCarthy<br />
3:00 Intermission<br />
3:15 215. Fragment-based druggability<br />
measures in drug targets. D. R. Hall,<br />
C. Ngan, B. Zerbe, D. Kozakov, S. Vajda<br />
3:45 216. FragVLib: Fragment-based virtual<br />
screening library using geometric and<br />
chemical patterns of interactions at interface<br />
of ligand-receptor complex crystal<br />
structures. R. S. Khashan, W. Zheng<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Using Waters Explicitly in Drug Discovery<br />
Hybrid Explicit/Implicit Methods<br />
Cosponsored by CINF and MEDI<br />
V. Shanmugasundaram, Organizer<br />
W. Sherman, Organizer, Presiding<br />
1:30 Introductory Remarks - Woody Sherman<br />
1:35 217. Molecular dynamics studies of<br />
water-protein interactions. G. Hummer,<br />
J. C. Rasaiah, H. Yin, G. Feng<br />
44–TECH<br />
‡ Cooperative Cosponsorship<br />
2:15 218. Addressing limitations with the<br />
MM-GB/SA scoring procedure using the<br />
WaterMap method and free-energy perturbation<br />
calculations. C. R. Guimaraes<br />
2:45 219. Prediction of potency of protease<br />
inhibitors by GBSA simulations with polarizable<br />
quantum mechanics-based ligand<br />
charges and a hybrid water model.<br />
D. Das, H. Mitsuya, Y. Koh, Y. Tojo,<br />
A. Ghosh<br />
3:15 Coffee Break<br />
3:30 220. Continuum theory and the analysis<br />
of active sites. A. Nicholls,M.Word<br />
4:00 221. Prediction of consistent water networks<br />
in uncomplexed protein binding<br />
sites based on knowledge-based potentials.<br />
M. Betz, G. Neudert, G. Klebe<br />
4:30 222. Explicit-water modeling of a<br />
model protein-ligand binding site predicts<br />
the non-classical hydrophobic effect.<br />
D. T. Moustakas,P.W.Snyder,<br />
W. Sherman, G. M. Whitesides<br />
5:00 223. New coarse-grained model for<br />
water: The importance of electrostatic interactions.<br />
Z. Wu, Q. Cui, A. Yethiraj<br />
TUESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
<strong>Chemical</strong> Computing Group Excellence<br />
Award Financially supported by <strong>Chemical</strong><br />
Computing Group, Inc<br />
C. Simmerling, Organizer<br />
6:00 224. Virtual screening targeting the<br />
PhoP response regulator to inhibit bacterial<br />
virulence. Y. T. Tang, E. A. Groisman,<br />
J. J. Havranek, G. R. Marshall<br />
6:20 225. Computational investigation of the<br />
transport mechanism for monoamine<br />
transporters. B. A. Merchant,<br />
J. D. Madura<br />
6:40 226. Quantum chemistry calculations<br />
for arbitrarily complex electrostatic environments:<br />
Benzene anion stabilization.<br />
R. Olivares-Amaya, M. Stopa,<br />
A. Aspuru-Guzik<br />
7:00 227. Biomolecular dynamics simulations<br />
based on the finite-difference Poisson-Boltzmann<br />
method. Q. Cai,X.Ye,<br />
J. Wang, M. Hsieh, R. Luo<br />
7:20 228. Filtering and ranking enzyme designs<br />
using EDGE. S. A. Johnson,<br />
K. N. Houk<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
Hewlett-Packard Outstanding Junior<br />
Faculty Award Financially supported by<br />
Hewlett-Packard Development Company, L.P.<br />
C. Simmerling, Organizer<br />
6:00 229. Quantum information and quantum<br />
computation for chemistry.<br />
A. Aspuru-Guzik<br />
6:20 230. Excited-state quantum chemistry<br />
for macromolecules and condensed<br />
phases. J. M. Herbert<br />
6:40 231. Mimicking coarse-grained simulations<br />
without coarse-graining: Enhanced<br />
sampling by damping short-range interactions.<br />
F. Wang<br />
7:00 232. Information flow in biomolecules.<br />
A. van der Vaart<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 052A/B<br />
Poster Session<br />
E. X. Esposito, Organizer<br />
6:00–8:00<br />
233. Predicting the structure and the binding<br />
site of rimonabant for the cannabinoid<br />
CB1 receptor. C. E. Scott, R. Abrol,<br />
W. A. Goddard<br />
234. Theoretical studies of hydrogen spillover<br />
mechanism for developing next generation<br />
automobile catalyst: A quantum<br />
chemical molecular dynamics study.<br />
F. Ahmed, R. Muira, A. Suzuki, H. Tsuboi,<br />
N. Hatakeyama, A. Endou, H. Takaba,<br />
M. Kubo, A. Miyamoto<br />
235. Crystallization of polydisperse systems<br />
of aspherical particles. W. L. Miller,<br />
A. Cacciuto<br />
236. Dependent of structural and thermodynamic<br />
characteristics of supercritical carbon<br />
dioxide fluid from atomic charges in<br />
molecule in region of critical point calculated<br />
by RISM theory. S. V. Keshtova,<br />
F. Keshtova<br />
237. Application of structure and ligand<br />
based methods for the investigation of<br />
the flexibility of loop regions within a cyclin-dependent<br />
kinase (CDK) and the prediction<br />
of a possible binding mode of<br />
highly selective inhibitors. C. Jäger,<br />
M. Buchholz, W. Brandt, L. Zeitlmann,<br />
A. Niestroj, H. Demuth, U. Heiser<br />
238. Molecular simulation of the nucleation<br />
and growth of C60 nanoparticles from the<br />
supersaturated vapor and from the undercooled<br />
liquid. K. Ngale,<br />
C. Desgranges, J. Delhommelle<br />
239. Phase equilibria of polyaromatic hydrocarbons<br />
by hybrid Monte Carlo Wang-<br />
Landau simulations. A. Magness,<br />
C. Desgranges, J. Delhommelle, J. Hicks<br />
240. Molecular simulation of the formation of<br />
Fe-Pt nanomaterials for ultrahigh-density<br />
magnetic data storage. J. Persson,<br />
C. Desgranges, J. Delhommelle<br />
241. Enhanced sampling in folding simulations<br />
of Ala5 peptide by DSRI method.<br />
D. Wei,F.Wang<br />
242. Monte Carlo statistical analysis of the<br />
uncertainty of enrichment metrics for ensemble<br />
docking. I. Tubert-Brohman<br />
243. Docking studies of propafenone derivatives<br />
into a homology model of the hERG<br />
channel in the open state. A. Schiesaro,<br />
A. Windisch, E. Eugen Timin, S. Hering,<br />
G. F. Ecker<br />
244. QSAR, ligand efficiency (LE) and lipophilic<br />
efficiency (LipE) studies of a series<br />
of benzophenone-type inhibitors of<br />
the multidrug transporter P-glycoprotein.<br />
I. Jabeen, Z. Parveen, U. Rinner,<br />
P. Chiba, G. F. Ecker<br />
245. Molecular insight into FabH-inhibitor interactions<br />
using molecular dynamics simulations<br />
and free energy calculations to<br />
identify novel scaffolds for inhibition by<br />
pharmacophore-based virtual screening.<br />
A. Mittal, M. E. Johnson<br />
246. Molecular origin of the interaction between<br />
PB1 and PB2 subunit in RNA polymerase<br />
of influenza virus. J. Park,W.Jo<br />
247. Development of minimal pharmacophore<br />
hypotheses by molecular dynamics<br />
simulation and spatial restriction for<br />
screening N5-CAIR mutase fragment-like<br />
inhibitors. T. Zhu, D. Mulhearn,<br />
M. E. Johnson<br />
248. Computational modeling study of anthranilate<br />
synthase from Streptomyces<br />
venezuelae for the developing new antimicrobial<br />
agents. J. Z. Hu, M. Ashenafi,<br />
W. M. Byrnes, W. W. Southerland<br />
249. Machine learning application for the<br />
high-performance prediction of functional<br />
sites in proteins of unknown function.<br />
S. Somarowthu,Y.Wang,<br />
A. Michaelson, H. Yang, M. Ondrechen<br />
250. Identification of functional subclasses in<br />
the ribulose-phosphate binding barrel superfamily<br />
using computational tools.<br />
J. S. Lee, S. Somarowthu, M. Ondrechen<br />
251. Comparison of the performance of different<br />
scoring functions in docking of antidepressants<br />
to serotonin transporter.<br />
S. G. Manepalli, J. D. Madura, C. Surratt<br />
252. Novel scaffold replacement methodology<br />
applied to the discovery of P38 MAP<br />
kinase inhibitors. J. Leonard,<br />
N. Thorsteinson<br />
253. Insights into the cross-reaction between<br />
trypanosoma cruzi antibodies and<br />
human beta-1 adrenergic receptor.<br />
C. F. de Oliveira, A. J. McCammon<br />
254. Molecular orbital study of keto-enol tautomerism<br />
of salvinorin A models. I. Vinar,<br />
W. J. Skawinski, C. A. Venanzi<br />
255. Ligand-steered modeling of the cannabinoid<br />
receptor 2: Successful applications<br />
to rationalize SAR data of selective<br />
CB2 inverse agonist and agonist compounds.<br />
S. S. Phatak, P. Diaz, J. Xu,<br />
F. Astruc-Diaz, M. Naguib,<br />
C. N. Cavasotto<br />
256. Development of property-encoded<br />
shape distribution descriptors for the robust<br />
prediction of polymer glass transition<br />
temperatures. M. P. Krein,S.Das,<br />
M. J. Embrechts, B. Natarajan,<br />
L. Schadler, C. M. Breneman<br />
257. Molecular dynamics studies of amphiphathic<br />
peptides embedded within a<br />
lipid bilayer. T. T. Nguyen, Z. Liu,<br />
P. B. Moore<br />
258. Structural basis of pregnane X receptor<br />
binding promiscuity. C. Ngan, D. Beglov,<br />
A. N. Rudnitskaya, D. Kozakov,<br />
D. J. Waxman, S. Vajda<br />
259. Coarse-grained modeling of antibody<br />
self-association. A. Chaudhri,<br />
T. Kamerzell, G. A. Voth<br />
260. An N log N generalize Born approximation.<br />
R. Anandakrishnan, A. V. Onufriev<br />
261. Development of internal potentials for a<br />
protein coarse-grain forcefield.<br />
K. Nguyen, J. Galan, Z. Liu, R. DeVane,<br />
P. Moore<br />
262. Interaction of 12c4 with alkali metal cation<br />
in aqueous solution: Theoretical investigation<br />
using polarized continuum<br />
model. T. Arora, H. Ali, W. A. Burns,<br />
H. Koizumi<br />
263. LowModeMD: Conformational search<br />
of small molecules, macrocycles, and<br />
protein loops. E. Sourial,P.Labute<br />
264. Parameterization of small drug-Like ligands<br />
using CHARMM General Force<br />
Field. K. C. Immadisetty, J. Gibbons,<br />
J. Brancho, J. D. Madura<br />
265. Glycogen phosphorylase inhibitor identification<br />
targeting the inhibitor binding<br />
site using virtual screening and experimental<br />
validation. S. Zhong, K. Alexacou,<br />
M. A. Charavgi, C. Tiraidis,<br />
S. E. Zographos, D. D. Leonidas,<br />
E. D. Chrysina, N. G. Oikonomakos,<br />
A. D. MacKerell, Jr.<br />
266. Structure refinement by J-coupling constants<br />
restraining using local elevation.<br />
D. Steiner, W. F. van Gunsteren<br />
267. First-principles design of conductance<br />
switching in functionalized carbon nanotubes.<br />
E. Y. Li, N. Poilvert, N. Marzari<br />
268. Binding free energy of cocaine and citalopram<br />
to the serotonin transporter using<br />
molecular dynamics. J. J. Brancho,<br />
K. Immadisetty, J. Gibbons, J. D. Madura<br />
269. Prediction of Lapatinib selectivity with<br />
kinases in the ErbB family. Y. Huang<br />
270. Correcting for errors in one-body and<br />
two-body interactions of small molecules<br />
in DFT with empirical potential forms parameterized<br />
through force matching.<br />
Y. Song,F.Wang<br />
271. Identification of novel non-hydroxamate<br />
anthrax toxin lethal factor inhibitor scaffolds<br />
using in silico and in vitro highthroughput<br />
screening methodologies.<br />
T. Chiu, J. Solberg, S. Patil,<br />
T. W. Geders, X. Zhang, S. Rangarajan,<br />
R. Francis, B. C. Finzel, M. A. Walters,<br />
D. J. Hook, E. A. Amin<br />
272. HS-PHARM-GEN: An automated tool<br />
for generating receptor-based pharmacophores<br />
from ligand-free protein structures.<br />
G. Chuang, C. Barillari, D. Rognan<br />
273. Molecular interaction footprints: A<br />
docking rescoring method. T. E. Balius,<br />
S. Mukherjee, R. C. Rizzo<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
274. Structural characterization of layered<br />
perovskite niobates using projector augmented<br />
wave (PAW) method of density<br />
functional theory (DFT). J. Adhikari,<br />
L. J. Smith<br />
275. Fragment based design and biophores<br />
using geometric and chemical patterns of<br />
interactions at interface of ligand-receptor<br />
complex crystal structures.<br />
R. Khashan, W. Zheng, a. Tropsha<br />
276. Withdrawn<br />
277. Cryptic adaptive pockets: What can we<br />
learn from protein sequence and structure<br />
regarding new pocket formation?<br />
V. Chandrasekaran, C. Paris, A. Keating<br />
278. Folding mechanism of BBL. J. Fan,<br />
M. Duan, L. Han, S. Huo<br />
279. Engineering intein-modified cell walldegrading<br />
enzymes: Prediction of nonnative<br />
intein insertion sites with nativelike<br />
properties. J. R. Apgar, B. Shen,<br />
X. Zuo, X. Sun, P. Lessard, S. Dohle,<br />
J. Emery, G. Lazar, H. de la Vega,<br />
M. Ross, D. Sturtevant, T. Shilling,<br />
R. Raab<br />
280. SZMAP: Mapping solvent thermodynamics<br />
in binding sites. J. M. Word,<br />
M. T. Geballe, A. Nicholls<br />
281. Improvement of an implicit solvent<br />
model. H. Nguyen,D.R.Roe,<br />
L. Wickstrom, C. Simmerling<br />
282. Hydrated or not? The factors affecting<br />
the hydration of a protein cavity. H. Yu,<br />
S. W. Rick<br />
283. Multi-scale modeling of coarse grained<br />
protein interactions: A CHARMMing implementation.<br />
F. C. Pickard, B. T. Miller,<br />
H. L. Woodcock, H. F. Schaefer,<br />
B. R. Brooks<br />
284. Charge transfer model for simulation of<br />
water and aqueous solutions. A. J. Lee,<br />
S. W. Rick<br />
285. Statistical analysis of scoring relative to<br />
experimental affinities (CSAR 2010<br />
Benchmark Exercise). R. D. Smith,<br />
J. B. Dunbar, H. A. Carlson<br />
286. Hydration and confinement effects on<br />
helix formation in a 23-residue polypeptide.<br />
S. Samaratunga, D. Suvlu,<br />
J. C. Rasaiah, D. Thirumalai<br />
287. Assessment and optimization of docking-based<br />
virtual screening for GPCR ligands:<br />
Not only crystal structures but<br />
also homology models. S. Costanzi,<br />
S. Vilar, G. Ferino, S. S. Phatak, B. Berk,<br />
C. N. Cavasotto<br />
288. Identification of binding hot spots in<br />
protein-macrocycle interactions.<br />
E. A. Villar, D. Kozakov, A. Whitty,<br />
S. Vajda<br />
289. Molecular modeling and simulation of<br />
the HER3/ErbB3 pseudo-kinase domain.<br />
S. E. Telesco, Y. Liu, R. Radhakrishnan<br />
290. Can vibrational spectra distinguish anionic<br />
from neutral radicals derived from<br />
ubiquinone cofactors in electron transfer<br />
proteins? R. A. Wheeler, S. E. Boesch<br />
291. Computational study of the effects of<br />
water molecules on sulfur oxide reactions.<br />
J. M. Standard, M. C. Cafarelli,<br />
P. Gorczynski, R. A. Craigmile<br />
292. Eyring: A computer program for computing<br />
gas-phase bimolecular chemical<br />
reaction rates of polyatomic species.<br />
C. Zavala-Oseguera, A. Galano,<br />
A. Ramírez-Manzanares, G. Merino<br />
293. Conformational sampling of macrocycles<br />
using Monte Carlo search techniques.<br />
C. Weigelt, R. Kimura,<br />
A. J. Tebben<br />
294. Computational studies on interaction of<br />
antioxidant dendrimers with plasmid<br />
DNA, pBR322. L. Rakesh, C. Y. Lee,<br />
P. Chhetri<br />
295. Designing enzymes with ROSETTA:<br />
Challenges and solutions. S. Kim,<br />
G. Kiss, R. S. Paton, S. A. Johnson,<br />
G. Nosrati, K. N. Houk<br />
296. QSAR modeling of GPCR receptor families,<br />
model application for virtual screening,<br />
and experimental validation of computational<br />
hits. R. Hajjo, S. Wang,<br />
B. L. Roth, A. Tropsha<br />
297. Parallel virtual screening for novel antimigraine<br />
therapeutics acting on 5-HT1B,<br />
5-HT1D and 5-HT1F serotonin receptors.<br />
T. L. Moda, X. S. Wang,<br />
A. D. Andricopulo, T. I. Oprea, A. Tropsha<br />
298. Development of semi-empirical models<br />
for zinc metalloenzymes. S. Wang,<br />
G. Lamoureux<br />
299. Allosterism in MutS proteins during<br />
DNA mismatch recognition and repair<br />
signaling. S. N. Pieniazek,<br />
M. M. Hingorani, D. L. Beveridge<br />
300. Computational investigation of the Nitrogen-Boron<br />
interaction in o-(N,N-dialkylaminomethyl)arylboronate<br />
systems.<br />
J. D. Larkin, J. S. Fossey, T. D. James,<br />
B. R. Brooks, C. W. Bock<br />
301. Analysis of amino acid sidechain Chi1,<br />
Chi2 conformational properties using<br />
quantum mechanical and experimental<br />
data. X. Zhu, P. Lopes, J. Shim,<br />
A. D. MacKerell, Jr.<br />
302. Structure-based fragment hopping ligand<br />
design using predocked fragment<br />
database. F. Lin, Y. Tseng<br />
303. Fragment-based de-novo design for<br />
VEGFR2/3 inhibitors. Y. Huang,B.Su,<br />
Y. Tseng<br />
304. 4D-Fingerprints clustering based scaffold<br />
hopping. Y. Tu, B. Su, Y. Tseng<br />
305. Simulation-informed predictions of interfacial<br />
phenomena: A generalized<br />
model for the electric double layer.<br />
A. Striolo<br />
306. Pose accuracy using DOCK: Database<br />
construction and protocol evaluation.<br />
S. Mukherjee, T. E. Balius, R. C. Rizzo<br />
307. Withdrawn<br />
308. Conceptual QSAR models for cellbased<br />
assays combining QM/MM linear<br />
response approach and disposition function.<br />
S. Natesan, S. Balaz<br />
309. Charge transfer excited states for large<br />
donor-acceptor molecular systems.<br />
T. Baruah, M. Olguin, R. R. Zope<br />
310. Withdrawn<br />
311. Quantitative conformational sampling of<br />
glucokinase using second-order orthogonal<br />
space random walk. W. Harris,<br />
W. Yang<br />
312. Interplay of AAA� molecular machines,<br />
DNA repair enzymes and sliding clamps<br />
at the replication fork: A multiscale approach<br />
to modeling replisome assembly<br />
and function. I. Ivanov, J. McCammon,<br />
J. A. Tainer<br />
313. High-quality ligand-steered modeling<br />
and docking evaluation of classAGprotein-coupled<br />
receptors. S. S. Phatak,<br />
C. N. Cavasotto<br />
314. Multiple land simultaneous docking<br />
(MLSD): Orchestrated dancing of ligands<br />
in binding sites of protein. H. Li, C. Li<br />
315. Ligand effects on geometric and electronic<br />
structure of the Au 25(SR) 18 - nanoparticle.<br />
C. M. Aikens<br />
316. Flipping process of 8oxoG in Fpg studied<br />
by mutagenesis in silico and umbrella<br />
sampling simulation. F. Lin,<br />
A. J. Campbell, C. Bergonzo,<br />
A. Grollman, C. Simmerling<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Applications to Nanoscale and<br />
Biomolecular Systems Cosponsored by<br />
PHYS<br />
G. Voth, M. Tuckerman, Organizers<br />
J. Straub, Organizer, Presiding<br />
8:30 317. Protein folding/unfolding under<br />
force. J. M. Fernandez, R. Berkovich,<br />
T. Kuo, S. Garcia-Manyes, J. Li, I. Barel,<br />
H. Lu, B. J. Berne, M. Urbakh, J. Klafter<br />
9:00 318. Multiscale experimental and computational<br />
studies of cadherin-mediated<br />
cell adhesion: From molecule to cell.<br />
B. Honig<br />
9:30 319. Link between folding landscapes<br />
of riboswitches and control of gene expression.<br />
D. Thirumalai<br />
10:00 Intermission<br />
10:15 320. Urea’s action on hydrophobic interactions<br />
in both physical and biological<br />
systems. R. Zhou<br />
10:45 321. Simulations of protein aggregation<br />
in the cellular milieu. J. Shea<br />
11:15 322. Exploring the earliest stages of<br />
the amyloid � protein aggregation pathway.<br />
J. E. Straub<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
An Emerging Challenge in Multiscale<br />
Modeling and Simulation: Mechanistic<br />
Understandings<br />
Free Energy Simulation and Enhanced<br />
Sampling<br />
H. Guo, J. Chu, Organizers<br />
P. Liu, Presiding<br />
8:30 323. Reconstructing the energy landscape<br />
of single molecules and complexes<br />
from force measurements. G. Arya<br />
9:00 324. Protein-ligand binding free energy<br />
calculations for pharmaceutical targets<br />
with the binding energy distribution analysis<br />
method (BEDAM). L. Mauro,<br />
E. Gallicchio, R. M. Levy<br />
9:30 325. New algorithms for enhanced<br />
sampling and applications to protein folding<br />
in explicit solvent. J. Ma<br />
10:00 Intermission<br />
10:15 326. High-order generalized ensemble<br />
theory to achieve long timescale sampling<br />
of complex biomolecules. W. Yang<br />
10:45 327. Target-blind conformational<br />
sampling in all-atom protein simulations<br />
with temperature-accelerated molecular<br />
dynamics. H. Vashisth, C. F. Abrams<br />
11:15 328. Q-dynamics: A transition state<br />
theory based strategy for modeling rare<br />
event dynamics. C. Lu, G. Henkelman<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
Success Stories in Computer-Guided<br />
Chemistry<br />
A. Parrill, Organizer, Presiding<br />
8:30 329. Computer-guided discovery of<br />
autotaxin inhibitors. A. L. Parrill,<br />
E. J. North, A. Hoeglund, H. Bostic,<br />
M. D. Best, D. L. Baker<br />
9:00 330. Probing hydrophilic domains and<br />
interdomain bridges in selected morphological<br />
models of hydrated Nafion using<br />
large-scale molecular dynamics simulations.<br />
C. K. Knox,G.A.Voth<br />
9:30 331. Computational design of organometallic<br />
photochromic systems with chelating,<br />
bifunctional tethered side-chains.<br />
C. E. Webster, K. R. Ruddick,<br />
K. L. Mosley, J. O. Johnson, P. P. Lubet,<br />
T. J. Burkey<br />
10:00 Intermission<br />
10:15 332. Modeling detailed chemical kinetics<br />
of JP-10 combustion using automated<br />
reaction mechanism generation.<br />
G. R. Magoon, W. H. Green,<br />
O. O. Oluwole, H. Wong, S. E. Albo,<br />
D. K. Lewis<br />
10:45 333. Computational (re)design and<br />
engineering of lipases: Toward a “Diels-<br />
Alderase”. M. Linder, T. Brinck<br />
11:15 334. Dynamic modeling and optimization<br />
of alcoholic fermentation of a grape.<br />
H. Ait Haddou<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 157B<br />
Docking & Scoring: What Have We Learned<br />
and Where Are We Now?<br />
Computational Approaches for Fragment<br />
Screening<br />
G. Warren, N. Nevins, Organizers<br />
G. McGaughey, Organizer, Presiding<br />
8:30 335. Recent advances in computational<br />
fragment-based lead discovery.<br />
C. Detering, H. Claussen, M. Gastreich,<br />
M. Lilienthal, C. Lemmen<br />
9:00 336. Let Gibbs be your guide: Free energy<br />
simulations in fragment-based drug<br />
design. Z. Konteatis, A. Klon, S. Meshkat,<br />
J. Zou, C. H. Reynolds<br />
9:30 337. Fragment-to-lead and peptide mimetic<br />
design using Fragment Molecular<br />
Orbital QM calculations. R. J. Law,<br />
O. Ichihara, M. Mazanetz, M. Szeto,<br />
S. Pal, M. Whittaker, D. Hallett<br />
10:00 Intermission<br />
10:15 338. Fragment based screening by<br />
free energy computer simulations: A critical<br />
assessment. J. W. Essex,<br />
M. Bodnarchuk, R. Viner<br />
10:45 339. Quantum mechanical pair-wise<br />
decomposition analysis of protein kinase<br />
B inhibitors: Validating a new tool for<br />
fragment-based drug design.<br />
A. C. Gibbs, X. Zhang, C. H. Reynolds,<br />
M. B. Peters, L. M. Westerhoff<br />
11:15 340. Fragment based drug design using<br />
differential chemical shift perturbation<br />
induced upon binding. L. Westerhoff,<br />
J. Liu, S. Brown, A. M. Petros, B. Wang,<br />
K. M. Merz<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Drug Discovery<br />
FBDD and LBDD<br />
S. Wildman, Y. Tseng, Organizers<br />
A. Patny, Presiding<br />
8:30 341. Flexible alignment in 3D and its<br />
applications. A. Kalaszi,G.Imre,<br />
O. Farkas, M. Vargyas, F. Csizmadia<br />
9:00 342. Template-constrained fragment<br />
alignment (TCFA). R. D. Cramer<br />
9:30 343. <strong>Chemical</strong> fragments that hydrogen<br />
bond to Asp, Glu, Arg, and His side<br />
chains in protein binding sites. E. Chan,<br />
R. Laskowski, D. Selwood<br />
10:00 Intermission<br />
10:15 344. Designing FBS libraries for drug<br />
discovery: Capturing fragment potential.<br />
J. M. Jansen, P. Mukherjee,<br />
M. K. Lindvall, Y. Xu, T. J. Hoeffel,<br />
R. W. Thompson, J. Kondracki,<br />
E. J. Martin<br />
10:45 345. CADD methodologies for lead<br />
optimization: Recent advances.<br />
R. D. Cramer<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
COMP<br />
TECH–45
COMP <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Challenges in Industrial Computational<br />
Methods<br />
A. Nicholls, E. Sourial, Organizers<br />
C. Lemmen, C. Groom, Presiding<br />
9:00 346. Software for drug discovery: Are<br />
we solving the most relevant problems?<br />
W. Walters<br />
Simulation of Hybrid Interfaces and Multi-<br />
Component Polymeric Materials<br />
Biointerfaces Sponsored by PMSE,<br />
Cosponsored by COMP<br />
The Emerging Concepts of Activity<br />
Landscapes and Activity Cliffs and their<br />
Role in Drug Research Sponsored by CINF,<br />
Cosponsored by COMP and MEDI<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Applications to Nanoscale and<br />
Biomolecular Systems Cosponsored by<br />
PHYS<br />
J. Straub, M. Tuckerman, Organizers<br />
G. Voth, Organizer, Presiding<br />
1:30 347. Base-by-base ratcheting of single<br />
stranded DNA through a solid-state<br />
nanopore: The DNA transistor. H. Peng,<br />
B. Luan, S. Harrer, S. Polonsky,<br />
S. Rossnagel, G. Martyna, G. Stolovitzky<br />
2:00 348. Exploring landscapes for protein<br />
allostery, binding, and folding: Effective<br />
potentials, replica exchange dynamics,<br />
and kinetic network models. R. Levy,<br />
M. Andrec, E. Gallicchio, W. Zheng<br />
2:30 349. Aging: Rejuvenation and the ultimate<br />
fate of supercooled liquids.<br />
P. G. Wolynes<br />
3:00 Intermission<br />
3:15 350. Millisecond-long molecular dynamics<br />
simulations of proteins on a special-purpose<br />
machine. D. E. Shaw<br />
3:45 351. Application of Markov State Models<br />
to dramatically enhance sampling of<br />
complex biomolecular simulations.<br />
V. Pande<br />
4:15 352. Multiscale theory and simulation<br />
of biomolecular systems. G. A. Voth<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
An Emerging Challenge in Multiscale<br />
Modeling and Simulation: Mechanistic<br />
Understandings<br />
Protein Dynamics<br />
J. Chu, Organizer<br />
H. Guo, Organizer, Presiding<br />
1:30 353. Multi-scale simulation methods<br />
for modeling two-step ligand-protein<br />
binding processes. M. Kang, C. A. Chang<br />
2:00 354. Multiscale simulations of F1-AT-<br />
Pase. J. Pu, M. Karplus<br />
2:30 355. Constructing a mechanistic model<br />
for a processive cellulose-degrading enzyme<br />
from molecular simulation.<br />
G. T. Beckham, J. F. Matthews,<br />
Y. J. Bomble, L. Bu, W. S. Adney,<br />
M. E. Himmel, M. R. Nimlos,<br />
M. F. Crowley<br />
46–TECH<br />
‡ Cooperative Cosponsorship<br />
3:00 Intermission<br />
3:15 356. Allostery of protein as determined<br />
by dynamics fluctuations and correlations.<br />
M. Liu<br />
3:45 357. Investigating conformational<br />
changes of biological macromolecules<br />
using multi-resolution Markov State Models.<br />
X. Huang<br />
4:15 358. Discovering conformational substates<br />
essential to protein function: A<br />
multi-scale approach. A. Ramanathan,<br />
C. J. Langmead, C. S. Chennubhotla,<br />
P. K. Agarwal<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Challenges in Industrial Computational<br />
Methods<br />
A. Nicholls, E. Sourial, Organizers<br />
C. Lemmen, C. Groom, Presiding<br />
1:30 Panel Discussion<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
Scripting & Programming<br />
Cross Pharma Collaboration in High<br />
Performance Computing Financially<br />
supported by Intel Corporation and Dell<br />
Incorporated<br />
E. Fluder, Z. Yang, Organizers<br />
1:30 359. Introduction to cross pharma high<br />
performance computing forum.<br />
J. C. Morris,Z.Yang<br />
2:00 360. Applications and use of cloud<br />
computing in the pharmaceutical industry.<br />
M. D. Miller, D. M. Powers,<br />
G. Stiegler, J. M. M<br />
2:30 361. Current trends of high performance<br />
computing in Pharma. S. Litster,<br />
J. Martin<br />
3:00 362. Challenges of HPC and collaboration<br />
opportunities in Pharma.<br />
R. Stansfield, M. D. Miller<br />
3:30 Intermission<br />
3:45 Open Panel Discussion<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 157B<br />
Docking & Scoring: What Have We Learned<br />
and Where Are We Now?<br />
Learnings from Docking and Scoring<br />
Evaluations with a Pharmaceutically<br />
Relevant Data Set<br />
N. Nevins, G. Warren, G. McGaughey,<br />
Organizers<br />
1:30 Introductory Remarks<br />
1:35 363. Importance of pharmaceutically<br />
relevant benchmark data. C. Lemmen,<br />
M. Gastreich, C. Detering, P. Oledzki<br />
2:05 364. Insights from “real world” docking<br />
with RosettaLigand. I. W. Davis<br />
2:35 365. Recent experiences with molecular<br />
docking in MOE. C. Williams,<br />
P. Labute<br />
3:05 Intermission<br />
3:20 366. Advances in induced-fit docking:<br />
What we have learned (and not learned)<br />
from the GSK dataset. D. Shivakumar,<br />
W. Sherman<br />
3:50 367. Surflex-Dock and the GSK Dataset:<br />
A retrospective. E. Metwally<br />
4:20 368. How to build a better mousetrap:<br />
Experiences with docking/scoring benchmarks<br />
– including the GlaxoSmithKline<br />
set – and what has been learned.<br />
L. M. Westerhoff<br />
4:50 Concluding Remarks<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Emerging Technologies in Computational<br />
Chemistry<br />
Award Symposium Financially supported by<br />
Schrödinger, Inc.<br />
C. Breneman, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 369. Pocket similarity: Are alpha carbons<br />
enough? H. Feldman<br />
2:05 370. <strong>Chemical</strong>ly meaningful net atomic<br />
charges and atomic multipole moments<br />
that reproduce the electrostatic potential<br />
in periodic and nonperiodic materials.<br />
T. A. Manz, D. S. Sholl<br />
2:35 371. Ultrafast electrostatic similarity:<br />
The sound of inevitability?<br />
P. C. Hawkins, A. Nicholls<br />
3:05 372. Bringing GPUs to mainstream molecular<br />
dynamics packages, acceleration<br />
of AMBER molecular dynamics simulations<br />
using NVIDIA GPUs: Achieving high<br />
performance without sacrificing accuracy.<br />
R. C. Walker<br />
3:35 Intermission<br />
3:50 373. Quantum polarized fluctuating<br />
charge (QPFC) model: A practical method<br />
to include quantum mechanical ligand<br />
polarizability in force-field-based molecular<br />
simulation. S. Kimura, R. Rajamani,<br />
D. R. Langley<br />
4:20 374. Status of the ReaxFF reactive<br />
forcefield: Development and applications.<br />
A. C. van Duin, M. Russo, K. Joshi,<br />
S. Kim, S. Agrawalla, A. Kamat,<br />
A. Bharati, J. D. Kubicki<br />
4:50 375. Parametrization of site-specific<br />
force fields for computational enzymology.<br />
G. Lamoureux<br />
5:20 Judgement and Award<br />
Simulation of Hybrid Interfaces and Multi-<br />
Component Polymeric Materials<br />
Multiscale Simulation of Polymeric<br />
Materials Sponsored by PMSE, Cosponsored<br />
by COMP<br />
The Emerging Concepts of Activity<br />
Landscapes and Activity Cliffs and their<br />
Role in Drug Research Sponsored by CINF,<br />
Cosponsored by COMP and MEDI<br />
THURSDAY MORNING<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Targeting Gram-Negative Pathogens<br />
Cosponsored by CINF and MEDI<br />
J. Starr, Organizer<br />
V. Shanmugasundaram, Organizer,<br />
Presiding<br />
8:00 Introductory Remarks - Veer Shanmugasundaram<br />
8:05 376. Approaches to the treatment of<br />
multidrug resistant gram negative infections.<br />
M. C. Noe, S. J. Brickner, T. Gootz,<br />
M. Huband, M. E. Flanagan, J. Mueller<br />
8:45 377. Physicochemical property space<br />
of antibiotics. H. E. Moser<br />
9:15 378. Physicochemical properties correlated<br />
with Gram-negative antibacterial<br />
activity of compounds in the Pfizer corporate<br />
library. J. T. Starr, R. Gupta,<br />
V. Shanmugasundaram<br />
9:45 379. Combining lessons from computational<br />
design of gram positive antibacterials<br />
with datamining to aid the design<br />
of novel gram negative antibacterials.<br />
C. J. Eyermann<br />
10:15 Intermission<br />
10:30 380. Targeting gram-negative pathogens:<br />
Drug design to improve antibiotics<br />
permeation? E. Hajjar, A. Kumar,<br />
P. Ruggerone, M. Ceccarelli<br />
11:00 381. Structure-based lead optimization<br />
of novel bacterial type II topoisomerase<br />
inhibitors. N. D. Pearson,Z.Yang,<br />
B. D. Bax, M. N. Gwynn<br />
11:30 382. Fragment-based development of<br />
tetrazole inhibitors against class A betalactamase.<br />
Y. Chen<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Materials, Polymers, and Nano-stuff<br />
Materials Are Soooooo Much Cooler Than<br />
the Twilight Saga<br />
E. X. Esposito, Organizer<br />
J. Kelley, Presiding<br />
8:30 383. Elucidating the molecular mechanisms<br />
underlying the nucleation and<br />
growth of nanoparticles. K. D. Watson,<br />
J. Persson, C. Desgranges,<br />
J. Delhommelle<br />
9:00 384. Molecular and mesoscale mechanisms<br />
of Brittle Bone Disease (Osteogenesis<br />
imperfecta): A computational materiomics<br />
study. M. J. Buehler, M. Buehler<br />
9:30 385. Mimicking coarse-grained simulations<br />
without coarse-graining: Enhanced<br />
sampling by damping short-range interactions.<br />
F. Wang,D.Wei<br />
10:00 Intermission<br />
10:15 386. Mechanism of sliding clamp<br />
opening by the clamp loader RFC: Insight<br />
from atomistic simulations. I. Ivanov,<br />
J. McCammon, J. A. Tainer<br />
10:45 387. Spatial hetererogeneity in the<br />
temperature of a rectangular nanorod<br />
dragged across a surface. A. V. Popov,<br />
R. Hernandez<br />
11:15 388. Molecular dynamics simulations<br />
of nanoparticles and surfactants at oil/<br />
water interfaces: Chemisorption vs. physisorption.<br />
S. O. Nielsen,C.T.Nguyen,<br />
U. Ranatunga<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
An Emerging Challenge in Multiscale<br />
Modeling and Simulation: Mechanistic<br />
Understandings<br />
Biological Membranes and Nanosystems<br />
J. Chu, Organizer<br />
H. Guo, Organizer, Presiding<br />
8:30 389. Aggregation dynamics of spherically-symmetric<br />
reactive colloidal particles.<br />
M. C. Hagy,S.J.Fitzwater,<br />
T. H. Pierce, M. Schure, A. V. Popov,<br />
R. Hernandez<br />
9:00 390. Coarse-grained models for processes<br />
that involve large-scale membrane<br />
deformation. Q. Cui<br />
9:30 391. Coarse-graining electrostatics in<br />
multiscale molecular simulations.<br />
D. Alemani, F. Collu, E. Spiga,<br />
M. Cascella, M. Dal Peraro<br />
10:00 Intermission<br />
10:15 392. Understanding the cellulosome<br />
and its assembly with coarse-grain modeling:<br />
Toward improving the CBP process.<br />
M. Crowley, Y. J. Bomble,<br />
M. R. Nimlos, M. E. Himmel<br />
10:45 393. Developing multiscale simulation<br />
models to study aggregation in peptidebased<br />
materials. C. Peter<br />
11:15 394. Recent progress in multiscale<br />
molecular dynamics simulation of soft<br />
matter. B. Ensing,P.B.Moore,<br />
S. O. Nielsen<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
Peter McWilliams said, ‘Life is Not a<br />
Struggle. It’s a Wiggle.’<br />
MD Methodology<br />
E. X. Esposito, Organizer<br />
D. Xu, Presiding<br />
8:30 395. Monte Carlo simulations of biophysical<br />
systems: The importance of<br />
quality of random number generators.<br />
G. Kaminski<br />
9:00 396. Developing multisite �-dynamics<br />
for structure-based drug design.<br />
J. L. Knight,C.L.Brooks<br />
9:30 397. A new computational method for<br />
modeling the solvation at interfaces:<br />
Bridging fluctuating hydrodynamics and<br />
molecular dynamics simulations.<br />
N. Voulgarakis, B. Shang, J. Chu<br />
10:00 398. Novel method to control pressure<br />
in molecular dynamics simulations.<br />
D. V. Perez, P. B. Moore, S. O. Nielsen<br />
10:30 Intermission<br />
10:45 399. Hydration effects on protein dynamics<br />
and function: A microscopic perspective.<br />
Q. Johnson, U. Doshi,<br />
D. Hamelberg<br />
11:15 400. Lambda hopping: An efficient<br />
replica exchange-based sampling<br />
method for free energy perturbation calculations.<br />
Y. Wu, T. Lin, J. C. Shelley,<br />
W. Sherman<br />
11:45 401. Improving umbrella sampling<br />
with knowledge. D. J. Sindhikara,<br />
Y. Okamoto<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Drug Discovery<br />
Energy<br />
S. Wildman, Y. Tseng, Organizers<br />
J. Jansen, Presiding<br />
8:30 408. Application of free energy perturbation<br />
to drug discovery research: What<br />
have we learnt so far, and whats next?<br />
D. Shivakumar, W. Sherman<br />
9:00 409. Binding site water in relative free<br />
energy calculations for drug-like compounds.<br />
J. C. Shelley, D. Calkins,<br />
A. P. Sullivan, Y. Wu, T. Lin, B. Kim,<br />
M. Y. Shelley, R. J. Abel<br />
9:30 410. Optimal �-stacking interaction energies<br />
in parallel-displaced aryl/aryl<br />
dimers are predicted by the dimer heavy<br />
atom count. J. M. Sanders<br />
10:00 411. Computational alanine scanning<br />
with linear scaling semi-empirical quantum<br />
mechanical methods. D. J. Diller,<br />
X. Zhang, L. M. Westerhoff<br />
10:30 Intermission<br />
10:45 412. Computational insight into the<br />
specific inhibition of cyclophilins A and B.<br />
O. Acevedo, S. V. Sambasivarao<br />
11:15 413. Structural promiscuity of human<br />
cytochromes P450: Understanding drugdrug<br />
interactions and metabolism via in<br />
silico fragment mapping. C. Ngan,<br />
R. L. Napoleon, D. Kozakov, S. Vajda<br />
11:45 414. GeoIsosteres: Structure-based<br />
approach to finding bioisosters using<br />
geometric and chemical patterns of interacting<br />
atoms at receptor-ligand interfaces.<br />
R. S. Khashan, W. Zheng,<br />
A. Tropsha<br />
Computer Modeling: The Wave of the<br />
Future and its Benefits for Small Business<br />
Owners Sponsored by SCHB, Cosponsored<br />
by CINF, COMP, and PROF<br />
Simulation of Hybrid Interfaces and Multi-<br />
Component Polymeric Materials<br />
Polymers, Fibers and Nanocomposites<br />
Sponsored by PMSE, Cosponsored by COMP<br />
THURSDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 156B<br />
An Emerging Challenge in Multiscale<br />
Modeling and Simulation: Mechanistic<br />
Understandings<br />
<strong>Chemical</strong> Reactions in Condensed Phase<br />
H. Guo, J. Chu, Organizers<br />
X. Huang, Presiding<br />
1:00 415. Energy triplets for writing epigenetic<br />
marks: QM/MM free energy simulations<br />
of protein lysine methyltransferases.<br />
H. Guo<br />
1:30 416. Multiscale quantum modeling of<br />
mechanisms of ribozyme catalysis.<br />
D. M. York<br />
2:00 417. Nanoscale effects on heterojunction<br />
electron gases in core/shell nanowires.<br />
B. M. Wong, F. Leonard<br />
2:30 418. Simulations of highly reactive<br />
complex chemical processes via an<br />
adaptive, multilevel QM/MM technique.<br />
M. R. Salazar<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 157A<br />
Targeting Gram-Negative Pathogens<br />
Cosponsored by CINF and MEDI<br />
V. Shanmugasundaram, Organizer<br />
J. Starr, Organizer, Presiding<br />
1:00 Introductory Remarks<br />
1:05 419. Utilizing organic syntheses and<br />
microbial iron assimilation processes for<br />
the development of new antibiotics.<br />
M. J. Miller<br />
1:45 420. Utilization of bacterial iron transport<br />
systems for drug delivery.<br />
U. Moellmann, L. Heinisch<br />
2:15 421. Activity of BAL30072, a novel siderophore<br />
sulfactam. M. G. Page<br />
2:45 422. Targeting bacterial multidrug efflux<br />
pumps. O. Lomovskaya, S. Hecker<br />
3:15 Intermission<br />
3:30 423. Interaction of �-peptides with<br />
membranes. J. Mondal,X.Zhu,Q.Cui,<br />
A. Yethiraj<br />
4:00 424. Molecular modeling of beta-lactamase<br />
inhibitors. S. Ha, T. Blizzard,<br />
H. Chen, S. Kim, J. Wu, K. Young,<br />
Y. Park, A. Ogawa, S. Raghoobar,<br />
R. Painter, N. Hairston, S. Lee, A. Misura,<br />
T. Felcetto, P. Fitzgerald, N. Sharma,<br />
J. Lu, E. Hickey, J. Hermes, M. Hammond<br />
4:30 425. Assembly and function of large<br />
Gram-negative bacterial machines studied<br />
by molecular simulation integrated<br />
with experimental data. M. Dal Peraro<br />
5:00 426. Design of potent, broad-spectrum<br />
AccC inhibitors. L. Xiao, C. Cheng,<br />
G. W. Shipps, A. Soriano, P. Orth,<br />
T. Black<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 156C<br />
Materials, Polymers, and Nano-stuff<br />
Honey, I Shrunk the Materials<br />
E. X. Esposito, Organizer<br />
R. Paton, Presiding<br />
1:30 427. Application of the Nudged Elastic<br />
Band method to the Su-Schrieffer-Heeger<br />
model reveals a new conduction<br />
mechanism in trans-polyacetylene.<br />
A. L. Botelho, M. Li, X. Lin<br />
2:00 428. Computational high-throughput<br />
screening of sorbents for reversible CO 2<br />
capture at high temperature. U. Das,<br />
W. H. Green<br />
2:30 429. Excited-state properties of dyesensitized<br />
solar cells and light-harvesting<br />
molecules. B. M. Wong,J.G.Cordaro<br />
3:00 430. Computational study of electronic<br />
states of monomer units of epoxy polymers.<br />
U. T. Novakovski,<br />
S. L. Richardson, S. Christensen<br />
3:30 Intermission<br />
3:45 431. Migration mechanism of self-localized<br />
defects in conductive polymers.<br />
Y. Shin,X.Lin<br />
4:15 432. Asymmetric deposition of Pt electrodes<br />
on (001) ferroelectric surfaces.<br />
M. A. Méndez Polanco, I. Grinberg,<br />
A. M. Rappe<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 157C<br />
Data Analysis: Statistics on <strong>Chemical</strong>s<br />
Cosponsored by CINF<br />
E. X. Esposito, Organizer<br />
A. Abebe, Presiding<br />
1:30 433. Exploring protein conformational<br />
changes with accelerated molecular dynamics<br />
in NAMD. Y. Wang,<br />
J. McCammon<br />
2:00 434. Pseudo-chair conformation of carboxyphosphate.<br />
V. S. Pakkala,<br />
S. M. Firestine, J. D. Evanseck<br />
2:30 435. Analysis of vibrational spectra of<br />
polypeptides in terms of localized vibrations.<br />
C. R. Jacob, M. Reiher<br />
3:00 Intermission<br />
3:15 436. Conformational coupling between<br />
LOV and kinase domains in phototropins:<br />
A computational perspective. M. Stenta,<br />
M. Dal Peraro<br />
3:45 437. Conformational sampling of macrocycles<br />
through accelerated molecular<br />
dynamics simulation. S. Kimura<br />
4:15 438. Withdrawn<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 154<br />
Drug Discovery<br />
Proteins: The BIG Phings the Drugs Stick<br />
To<br />
S. Wildman, Y. Tseng, Organizers<br />
R. Napoleon, Presiding<br />
1:30 446. Tackling difficult protein targets<br />
for novel anti-cancer treatments. I. Chen<br />
2:00 447. Pose grading for docking applications.<br />
S. A. Wildman, J. Penzotti<br />
2:30 448. Alignment of protein surfaces using<br />
shape and chemical features: Application<br />
to detect local similarity among<br />
protein-ligand binding sites. B. K. Rai,<br />
G. A. Bakken, W. J. Howe<br />
3:00 Intermission<br />
3:15 449. Ligand-steered homology modeling<br />
and high-throughput docking: Successful<br />
evaluation in aminergic GPCRs.<br />
C. N. Cavasotto, S. S. Phatak<br />
3:45 450. More better charges for metalloproteins.<br />
A. Cho<br />
Simulation of Hybrid Interfaces and Multi-<br />
Component Polymeric Materials<br />
Inorganic Interfaces and Biomaterials<br />
Sponsored by PMSE, Cosponsored by COMP<br />
ENVR<br />
Division of<br />
Environmental<br />
Chemistry<br />
D. Dionysiou, Program Chair<br />
OTHER SYMPOSIA OF INTEREST:<br />
<strong>Chemical</strong> Sensors (see ANYL, Thu)<br />
Frank H. Field and Joe L. Franklin<br />
Award for Outstanding Achievement<br />
in Mass Spectrometry: Symposium in<br />
Honor of Catherine Costello (see<br />
ANYL, Tue)<br />
Pharmaceutical Analysis (see ANYL,<br />
Sun)<br />
Surface Chemistry and<br />
Environmental Applications of<br />
Nanoporous Materials (see COLL, Sun<br />
& Mon)<br />
Coal-, Gas-, Biomass- and Waste-to-<br />
Liquids Conversion (see FUEL, Wed)<br />
Environmental Aspects of Inorganic<br />
Chemistry (see INOR, Sun)<br />
SOCIAL EVENTS:<br />
Social Hour, 6:30 PM: Tue<br />
Dinner, 7:00 PM: Tue<br />
BUSINESS MEETING:<br />
Program Planning Meeting, 2:00 PM:<br />
Sun<br />
Long Range Planning, 3:00 PM: Sun<br />
Executive Committee Meeting, 7:00<br />
PM: Sun<br />
SUNDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Chemistry of AOP Radicals During Water<br />
and Wastewater Treatment<br />
D. Dionysiou, F. Rosario, Organizers<br />
S. Mezyk, Organizer, Presiding<br />
COMP/ENVR<br />
8:30 Introductory Remarks<br />
8:35 1. Evaluation of the reactivity of hydroxyl<br />
radical towards effluent organic<br />
matter. F. L. Rosario-Ortiz,M.Dong,<br />
S. Mezyk<br />
9:05 2. Removing estrogenic steroids from<br />
waters by advanced oxidative and reductive<br />
chemistry. E. M. Abud,<br />
K. L. Swancutt, K. A. Rickman,<br />
S. P. Mezyk<br />
9:25 3. Supported bismuth catalysts for<br />
degradation of organic contaminants.<br />
J. Virkutyte,R.S.Varma<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–47
ENVR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
9:45 4. Ionizing radiation techniques for hydroxyl<br />
radical efficiency determinations of<br />
organic contaminant mixtures in treated<br />
wastewater matrices. J. R. Peller,<br />
S. P. Mezyk<br />
10:05 Intermission<br />
10:20 5. Effect of photocatalytic degradation<br />
and adsorption processes on the removal<br />
of phenolic compounds from agroindustrial<br />
effluent. K. Baransi,<br />
Y. Dubowski, I. Sabbah<br />
10:40 6. Advanced oxidation processes for<br />
the removal of antidepressant compounds<br />
from water: Photochemical fate<br />
studies. H. Santoke,W.Song,<br />
W. J. Cooper<br />
11:00 7. Reductive dechlorination of carbon<br />
tetrachloride in modified Fenton reaction<br />
by Fe(II) chelated with cross-linked chitosan.<br />
Y. Lee, S. Bae,W.Lee<br />
11:20 8. Degradation of phenolic compounds<br />
and antibiotics in the presence of<br />
free radicals. X. He, M. Yalılı Kılıç,<br />
K. Kestiogˇ lu, S. Mezyk, D. D. Dionysiou<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Surface Characterization Techniques and<br />
Surface-Involved Reactions Cosponsored by<br />
COLL and GEOC<br />
H. Zhang, T. Strathmann, J. Brandes,<br />
J. Texter, Organizers<br />
E. Weber, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 9. First-principles investigation of catalytic<br />
reduction of nitrogen oxides for environmental<br />
applications. W. F. Schneider,<br />
D. McCalman<br />
9:05 10. Depth resolved characterization of<br />
model and ambient atmospheric particles<br />
using high-resolution secondary ion mass<br />
spectrometry. S. Ghosal<br />
9:25 11. Nonionic surfactant interaction with<br />
biofilm in surfactant enhanced biofiltration<br />
systems. V. R. Sendamangalam,<br />
W. Zongsu, G. Sorial, Y. Seo<br />
9:45 12. Deposition of inorganic minerals at<br />
the water-metal interface: Role of surface<br />
conditioning by anti-deposition polymers.<br />
H. Li,R.Vidic<br />
10:05 Intermission<br />
10:20 13. Unexpected role of activated carbon<br />
in promoting transformation of secondary<br />
amines to N-nitrosamines.<br />
C. Huang<br />
10:50 14. Revision of oxidative catalytic reaction<br />
mechanism of hematite nanoparticles<br />
and related size-effects.<br />
I. Chernyshova, S. Ponnurangam,<br />
P. Somasundaran<br />
11:10 15. Interactions between metal oxides<br />
and the impact on the redox transformation<br />
of organic contaminants. H. Zhang,<br />
S. Taujale, F. J. Murrillo, P. Bick<br />
11:30 16. Uranyl at fused silica/aqueous interfaces<br />
studied by resonantly enhanced<br />
second harmonic generation and the<br />
Eisenthal chi(3) method. F. M. Geiger<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Sustaining Water Quality<br />
Status and Trends Cosponsored by ANYL<br />
Financially supported by Global Innovation<br />
Imperatives<br />
M. Larsen, W. Cooper, Organizers<br />
S. Ahuja, Organizer, Presiding<br />
48–TECH<br />
8:30 Introductory Remarks<br />
‡ Cooperative Cosponsorship<br />
8:35 17. Water quality status and trends in<br />
the United States. M. C. Larsen,<br />
P. A. Hamilton, D. N. Myers<br />
9:05 18. Water quality issues in India due to<br />
environmental pollution. R. K. Sharma<br />
9:35 19. Rivers in Africa are in jeopardy and<br />
there is need for rivers’ restoration.<br />
S. O. Wandiga<br />
10:05 20. Quantitative structure activity relationships<br />
(QSAR) for determining the mobility<br />
and toxicity of quaternary ammonium<br />
compounds. U. Tezel,<br />
S. G. Pavlostathis<br />
10:35 Intermission<br />
10:50 21. Understanding temporal trends in<br />
the chemistry of halides and dissolved organic<br />
matter. K. M. Walker, T. Boyer,<br />
C. Overdevest<br />
11:20 22. Monitoring from source to tap:<br />
The new paradigm for ensuring water security<br />
and quality. D. Kroll<br />
11:50 23. Beyond water sustainability.<br />
S. Ahuja<br />
SUNDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Chemistry of AOP Radicals During Water<br />
and Wastewater Treatment<br />
D. Dionysiou, S. Mezyk, Organizers<br />
F. Rosario, Organizer, Presiding<br />
1:30 24. Absolute kinetics and reaction efficiencies<br />
of hydroxyl radical-induced degradation<br />
of methyl isothiocyanate (MITC)<br />
in different quality waters. S. P. Mezyk,<br />
K. L. Swancutt, M. K. Dail, K. P. Ishida<br />
2:00 25. Degradation of DNOC with nanomagnetite<br />
and cathodic Fenton generation<br />
of hydrogen peroxide. A. T. Lemley,<br />
X. Zeng, K. Hanna<br />
2:20 26. Effects of hydroxyl radical mediated<br />
oxidation on N-acylhomoserine lactones<br />
used in microbial signaling: Rates,<br />
products, and effects on signaling activity.<br />
J. L. Ferry, R. L. Frey, A. W. Decho<br />
2:40 27. Linear free energy relationship<br />
(LFER) for the aqueous phase hydroxyl<br />
radical (HO●) reactions with ionized species:<br />
Experimental and theoretical studies.<br />
D. Minakata, J. C. Crittenden<br />
3:00 Intermission<br />
3:15 28. Sonocatalytic elimination of diclofenac<br />
in water. N. H. Ince, A. Ziylan<br />
3:35 29. Characterization of performance<br />
and wear mechanism of diamond electrodes<br />
used for electrochemical oxidation<br />
of TCE. B. P. Chaplin, J. Farrell,<br />
J. Carlisle, H. Zeng<br />
3:55 30. Removing contaminant pharmaceuticals<br />
from waters using sulfate radicals.<br />
K. A. Rickman, G. McKay,<br />
S. P. Mezyk<br />
4:15 31. Effects of pH, phosphate, chloride,<br />
bromide, carbonate, Fe(II) and natural organic<br />
matter on the yield of HO from a<br />
modified Udenfriend process: A multifactorial<br />
study. J. M. Burns, J. L. Ferry,<br />
T. J. Shaw<br />
4:35 32. Effect of copper on zerovalent ironbased<br />
oxidation for the degradation of trichloroethylene.<br />
K. Choi,W.Lee<br />
4:55 Concluding Remarks<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Metals and Metal Oxides Cosponsored by<br />
COLL and GEOC<br />
E. Weber, H. Zhang, T. Strathmann,<br />
Organizers<br />
Y. Jun, Presiding<br />
1:30 Introductory Remarks<br />
1:35 33. Evaluating prediction uncertainty in<br />
reactive transport models of uranium in<br />
groundwater. G. P. Curtis,M.Ye,<br />
M. Kohler, P. Fox, J. Davis<br />
2:05 34. Uranium attenuation in subsurface<br />
systems under NH 3 gas induced alkaline<br />
conditions. N. P. Qafoku, J. E. Szecsody,<br />
M. J. Truex, L. Zhong<br />
2:25 35. Removal of low levels of As, Se, Cu<br />
and Cr from waste ion exchange brine by<br />
in situ ferric hydroxide precipitation.<br />
J. E. Tobiason, Y. Larsen, M. Pham<br />
2:45 Intermission<br />
3:00 36. Multifactorial modeling of the effects<br />
of precipitating agents and common<br />
ions on Fe(II) oxidation in the presence of<br />
natural organic matter. J. L. Ferry,<br />
J. M. Burns, T. J. Shaw<br />
3:30 37. CO 2-H 2O-PbS interfacial reactions:<br />
Implications for CO 2 leakage from geologic<br />
sequestration. K. O’Malley, Y. Jun<br />
3:50 38. Sequestration of 99 Tc by goethite.<br />
W. UM, R. Serne, N. P. Qafoku,<br />
J. H. Westsik<br />
4:10 39. Initial concentration effect: Inherent<br />
limitations of classical adsorption theories.<br />
G. Pan<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Sustaining Water Quality<br />
Monitoring Various Contaminants<br />
Cosponsored by ANYL Financially supported<br />
by Global Innovation Imperatives<br />
S. Ahuja, W. Cooper, Organizers<br />
M. Larsen, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 40. Forensic water quality investigations:<br />
Identifying pollution sources and<br />
polluters. S. Ahuja, L. B. Cahoon,<br />
R. H. Cutting<br />
1:55 41. Septic systems in the coastal environment:<br />
Multiple water quality problems<br />
in multiple areas. M. A. Mallin<br />
2:15 42. Analytical chemical measurements<br />
to improve non-point pollution assessment<br />
in Indiana’s Lake Michigan Watershed.<br />
J. R. Peller, E. Argyilan<br />
2:35 43. Kinetics and mechanism of the<br />
sensitized photodegradation of trimethoprim<br />
in aqueous environment.<br />
W. Song, H. Xu, W. J. Cooper<br />
2:55 44. Factors controlling the regional distribution<br />
of Vanadium in California<br />
groundwater. M. T. Wright, K. Belitz<br />
3:15 Intermission<br />
3:30 45. Measuring redox potential in situ<br />
using a fiber optic sensor. W. Chudyk,<br />
C. Sotolongo, E. Mueller<br />
3:50 46. Interaction between mercury and<br />
marine organic matter. A. B. Schartup,<br />
R. P. Mason<br />
4:10 47. Atmospheric mercury deposition in<br />
Bermuda. S. Gichuki, M. Andersson,<br />
R. Mason, A. Peters<br />
4:30 48. Streamwater dissolved nitrate<br />
trends in the Mississippi-Atchafalaya<br />
River Basin using windowed regressions<br />
on time, discharge, and season.<br />
B. T. Aulenbach, R. M. Hirsch<br />
4:50 49. Removing chemical contaminants<br />
from water using radical reactions.<br />
S. P. Mezyk<br />
SUNDAY EVENING<br />
Chemistry and the Environment Film Series<br />
Tara, Journey to the Heart of the Climate<br />
Machine Sponsored by CEI, Cosponsored by<br />
CHED and ENVR<br />
MONDAY MORNING<br />
Section C<br />
Renaissance Boston Waterfront<br />
Brewster<br />
Sustaining Water Quality<br />
Remediation of Various Contaminants<br />
Cosponsored by ANYL Financially supported<br />
by Global Innovation Imperatives<br />
S. Ahuja, W. Cooper, M. Larsen,<br />
Organizers, Presiding<br />
8:00 Introductory Remarks<br />
8:05 50. Arsenic in groundwater and its impact<br />
on community health. K. J. Nath<br />
8:30 51. Withdrawn<br />
8:55 52. Arsenic sorption dynamics on composite<br />
iron matrix for efficient arsenic water<br />
filter design. A. Hussam, S. Ahamed<br />
9:20 53. First community based sustainable<br />
arsenic removal system in Cambodia.<br />
D. Uy,V.Huy,A.K.SenGupta<br />
9:40 54. Arsenic removal from drinking water<br />
and ion exchange brine using polysaccharide-bridged<br />
iron-based nanoparticles.<br />
Q. Liang, B. An, D. Zhao<br />
10:00 Intermission<br />
10:15 55. Evaluation of environmentally sustainable<br />
strategies to address challenges<br />
associated with water quality and water<br />
shortage. T. F. Marhaba, R. Duvil<br />
10:35 56. Discovery of metal binding peptides<br />
in the blood of the blue mussel,<br />
Mytilus edulis and their potential role as a<br />
biomarker for metal contamination.<br />
R. S. Manmode, C. Malepati, D. K. Ryan<br />
10:55 57. Horseradish peroxidase mediated<br />
stabilization of 2,4-dichlorophenol in a<br />
model SOM-free soil. M. Paloma,<br />
A. Bhandari<br />
11:15 58. Mechanistic studies on the interaction<br />
of cactus mucilage with arsenic.<br />
D. I. Fox, T. Pichler, D. H. Yeh,<br />
N. A. Alcantar<br />
11:35 59. Transforming arsenic crisis into an<br />
economic enterprise: Example from Indian<br />
villages. S. Sarkar, A. Gupta,<br />
A. K. SenGupta<br />
11:55 Concluding Remarks<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Environmental Applications and<br />
Implications of Nanotechnology<br />
Environmental Applications Financially<br />
supported by Q-Sense, Division of Biolin<br />
Scientific<br />
C. Vecitis, Y. Jun, A. Gu, Organizers<br />
K. Chen, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 60. Photocatalytic nanoparticles for<br />
water and surface disinfection. J. Kim<br />
9:15 61. Virus inactivation by photocatalytic<br />
nanoparticles. M. V. Liga, H. R. Jafry,<br />
C. Yu, E. L. Bryant, A. R. Barron,<br />
V. L. Colvin, Q. Li<br />
9:35 62. Role of filter surfaces in the removal<br />
of water contaminants by silver nanoparticles.<br />
S. A. Hooker, E. Mansfield,<br />
M. Stewart<br />
9:55 63. Reactive activated carbon impregnated<br />
with Fe/Pd nanoparticles: Innovative<br />
material development and PCB<br />
cleanup strategy. H. Choi,S.R.Al-Abed<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
10:15 Intermission<br />
10:25 64. Label-free, ultrasensitive and selective<br />
detection of Trinitrotoluene (TNT)<br />
using NLO properties of L-Cysteine modified<br />
gold nanoparticle. S. S. Dasary,<br />
D. Senapati, A. Singh, A. Yerramilli, H. Yu,<br />
P. C. Ray<br />
10:45 65. Carbon nanotubes promote hydroxyl<br />
radical formation during ozonation.<br />
R. L. Oulton, M. Nalbandian,<br />
D. M. Cwiertny<br />
11:05 66. Converting visible light into UVC:<br />
Lanthanide upconversion nano-phosphors<br />
for light-activated biocidal surfaces.<br />
E. L. Cates,M.Cho,J.Kim<br />
11:25 67. Selective reduction of nitrate to dinitrogen<br />
in water utilizing photocatalytic<br />
nanocomposites. K. W. Doudrick,<br />
P. Westerhoff<br />
11:45 68. Carbon nanotube-based nanobiosensor<br />
for detection of pathogen DNA in<br />
the environment. C. Gao, Y. Liu, X. Li,<br />
A. Gu<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Sorption Processes: From Treatment to<br />
Fate and Transport Cosponsored by COLL<br />
and GEOC<br />
E. Weber, T. Strathmann, J. Brandes,<br />
J. Texter, Organizers<br />
H. Zhang, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 69. Influence of surface chemistry on<br />
the behavior of mutli-walled carbon nanotubes<br />
in aquatic environments.<br />
H. Fairbrother, B. Smith, K. Wepasnick,<br />
W. P. Ball<br />
9:05 70. Effects of oxide nanoparticles on<br />
bacterial surface biomolecules. W. Jiang,<br />
R. W. Vachet, B. Xing<br />
9:25 71. Influence of geochemical variables<br />
on nanoscale zerovalent iron (nZVI) longevity:<br />
Implications of particle aging for<br />
treatment applications. Y. Xie,<br />
D. M. Cwiertny<br />
9:45 72. Aggregation kinetics of fullerenesingle-walled<br />
carbon nanotube hybrids.<br />
N. Aich, N. B. Saleh<br />
10:05 Intermission<br />
10:20 73. Adsorption of organic compounds<br />
by engineered carbon nanoparticles.<br />
K. Yang, B. Xing<br />
10:50 74. Adsorption of benzene and<br />
phenanthrene on carbonaceous geosorbents.<br />
Y. Ran<br />
11:10 75. Partition of endosulfan and chlorpyrifos<br />
onto soil organic matter.<br />
M. K. Tiwari,S.Guha<br />
11:30 76. Sorption properties of tylosin on<br />
soil minerals. Q. Zhang, C. Yang,<br />
W. Huang, Z. Dang<br />
MONDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Environmental Applications and<br />
Implications of Nanotechnology<br />
Fate and Transport Financially supported by<br />
Q-Sense, Division of Biolin Scientific<br />
A. Gu, C. Vecitis, K. Chen, Organizers<br />
Y. Jun, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 77. Integrated approach toward understanding<br />
the environmental fate, transport,<br />
toxicity and occupational health<br />
hazards of metal and metal oxide nanoparticles.<br />
V. H. Grassian<br />
2:15 78. Investigation of health relevant<br />
physical and chemical properties of select<br />
engineered carbon nanomaterials.<br />
M. Lu, R. E. Agnew, M. E. Birch<br />
2:35 79. UV-induced surface modifications<br />
of silver nanoparticles in atmospheric and<br />
aqueous conditions. J. M. Gorham,<br />
R. I. MacCuspie, D. H. Fairbrother,<br />
R. D. Holbrook<br />
2:55 80. Evaluation of nano copper removal<br />
and toxicity in wastewaters. J. Smeraldi,<br />
G. Rajagopalan, T. Hosseini, L. Khatib,<br />
B. H. Olson, D. Rosso<br />
3:15 Intermission<br />
3:25 81. Impacts of water chemistry on<br />
nanoparticle stability and bioavailability<br />
for freshwater bacteria and algae.<br />
V. C. Reyes, C. Marambio-Jones, M. Li,<br />
E. M. Hoek, S. Mahendra<br />
3:45 82. Microscopic recognition of engineered<br />
nanomaterials using Kelvin probe<br />
force microscopy. Q. Yu,C.Na<br />
4:05 83. Environmental transformation of<br />
14 C-labeled multi-walled carbon nanotubes.<br />
L. Zhang, Q. Huang<br />
4:25 84. Influence of oxygen-containing<br />
functional groups and graphenic carbon<br />
on Zn[II] sorption by multiwall carbon<br />
nanotubes: Application of Two-Site Langmuir<br />
model. H. Cho, J. Yang, W. P. Ball<br />
4:45 85. Sorption of engineered nanomaterials<br />
to soils. K. D. Hristovski, E. Mousset,<br />
H. Luque, P. K. Westerhoff, J. D. Posner<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Heterogeneous Catalysis for Environmental<br />
and Sustainable Energy Applications<br />
General Environmental Catalysis<br />
Cosponsored by CATL (probationary)<br />
M. Castaldi, M. Bekbolet, B. Wilhite,<br />
B. Zhou, Organizers<br />
A. Orlov, M. Flytzani-Stephanopoulos,<br />
Organizers, Presiding<br />
1:30 Introductory Remarks<br />
1:35 86. Applications of photocatalysis and<br />
photovoltaic electrocatalysis for energy<br />
and environmental sustainability.<br />
M. R. Hoffmann<br />
2:20 Intermission<br />
2:40 87. Scanning tunneling microscopy/<br />
spectroscopy study of the water-gasshift<br />
reaction on iron oxide supported<br />
gold nanoparticles. K. Rim,D.Eom,<br />
J. Raitano, S. Chan,<br />
M. Flytzani-Stephanopoulos, G. W. Flynn<br />
3:05 88. Model biomass conversion reactions<br />
on oxide surface: Ethylene glycol on<br />
CeO 2(111). T. Chen, F. C. Calaza,<br />
S. H. Overbury, D. R. Mullins<br />
3:30 89. Hierarchical porous catalysts tailored<br />
for biodiesel production.<br />
J. Dacquin, A. F. Lee, K. Wilson<br />
3:55 Intermission<br />
4:10 90. Catalyst deactivation and regeneration<br />
studies reforming ethanol/gasoline<br />
blends containing sulfur. A. Simson,<br />
M. Castaldi, R. Farrauto<br />
4:35 91. Controlling the surface dispersion<br />
ofBaOdomainsonNO x storage materials<br />
via TiO 2 anchoring sites. E. Ozensoy,<br />
S. Andonova, G. Senturk<br />
5:00 92. Computational design of multifunctional<br />
catalysts for efficient carbon dioxide<br />
and methane utilization.<br />
B. J. Sherman, N. A. Fine, C. S. Lo<br />
Section C<br />
Renaissance Boston Waterfront<br />
Brewster<br />
Drinking Water Chemistry, Disease<br />
Prevention and Health Promotion Financially<br />
supported by Association of Environmental<br />
Engineering and Science Professors<br />
A. Dietrich, Organizer<br />
M. Edwards, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 93. Nutritional and off-flavor aspects of<br />
metals in drinking water. A. M. Dietrich,<br />
P. Omur-Ozbek<br />
2:00 94. Drinking more water: An effective<br />
strategy for the prevention and treatment<br />
of obesity? B. M. Davy, E. A. Dennis,<br />
V. E. Hedrick, P. A. Estabrooks,<br />
A. M. Dietrich<br />
2:25 95. Effect of water chemistry on the release<br />
of lead and other contaminants<br />
from lead corrosion products to drinking<br />
water. E. Kim, J. E. Herrera<br />
2:50 96. Bromate formation during drinking<br />
water treatment using a hybrid ceramic<br />
membrane filtration – ozonation.<br />
M. Moslemi, S. H. Davies, S. J. Masten<br />
3:15 Intermission<br />
3:25 97. Metallic flavor perception and the<br />
effects of cancer therapies. S. Mirlohi,<br />
A. M. Dietrich, S. E. Duncan, G. J. Lesser<br />
3:50 98. Emotional and sensory response to<br />
iron in water using facial recognition and<br />
sensory evaluation methods.<br />
S. E. Duncan, L. S. Hightower, S. L. Fong<br />
4:15 99. Susceptibility of biofilm to disinfectants<br />
in the presence of disinfectant-demanding<br />
substrate. Z. Xue,Z.Wang,<br />
Y. Seo<br />
4:40 100. Impacts of heating on disinfection<br />
byproducts in municipal drinking water<br />
systems. D. A. Reckhow,B.Liu<br />
Undergraduate Research Posters<br />
Environmental Chemistry Sponsored by<br />
CHED, Cosponsored by ENVR and SOCED<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
D. Dionysiou, Organizer<br />
8:00–10:00<br />
209, 210, 211, 215, 216, 217, 218, 219, 229,<br />
230, 232, 234, 235, 236, 237, 238, 239,<br />
240, 241, 243, 244, 246, 247, 249, 251,<br />
252, 253, 254, 255, 256, 257, 259, 260,<br />
262, 263, 266, 267, 268, 269, 270, 272,<br />
274, 275, 276, 277, 279, 280, 282, 285,<br />
287, 289, 290, 291, 292, 295. See subsequent<br />
listings.<br />
TUESDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Environmental Applications and<br />
Implications of Nanotechnology<br />
Fate and Transport Financially supported by<br />
Q-Sense, Division of Biolin Scientific<br />
A. Gu, C. Vecitis, K. Chen, Organizers<br />
Y. Jun, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 101. Aggregation of titanium dioxide<br />
nanoparticles: The role of environmentally-relevant<br />
surface coatings.<br />
R. D. Holbrook,K.K.Vu<br />
8:55 102. Aggregation and sedimentation of<br />
titanium dioxide nanoparticles in aqueous<br />
environment: Effects of crystallinity and<br />
morphology. X. Liu,G.Chen,C.Su<br />
9:15 103. Transport and retention of TiO 2<br />
nanoparticles in saturated porous media:<br />
Role of ionic strength, valence, and humic<br />
acid. G. Chen, X. Liu, C. Su<br />
9:35 104. Aggregation kinetics of silver nanoparticles<br />
in monovalent and divalent electrolyte<br />
solutions: Implications for environmental<br />
fate and transport. K. Huynh,<br />
K. Chen<br />
9:55 105. Transport of MWCNTs in porous<br />
media and their effect on Ni(II) transport.<br />
J. Yang, J. L. Bitter, H. Fairbrother,<br />
W. P. Ball<br />
10:15 106. Coated nanoparticle transport:<br />
Does the underlying particle play a role?<br />
E. M. Hotze,S.Lin,S.Chae,<br />
M. R. Wiesner, G. V. Lowry<br />
10:35 Intermission<br />
10:45 107. Gold nanoparticle interactions<br />
with humic acid: Role of nanoparticle<br />
core size effects. V. L. Pallem,<br />
H. A. Stretz, M. J. Wells, X. Ma,<br />
D. Bouchard<br />
11:05 108. Effect of attached-phase NOM<br />
and solution chemistry on the deposition<br />
rate of nC60. C. P. McNew,<br />
E. J. LeBoeuf, Y. Li<br />
11:25 109. Filtration of anisotropic and hybrid<br />
nanomaterials. N. B. Saleh,<br />
N.Afrooz,N.Aich,I.A.Khan<br />
11:45 110. Aggregation and transport of<br />
carboxymethyl cellulose-modified zerovalent<br />
iron nanoparticles in porous media.<br />
T. Raychoudhury, N. Tufenkji,<br />
S. Ghoshal<br />
12:05 111. Stabilization and size control of<br />
zerovalent iron nanoparticles using carboxyl-<br />
and phosphate-functionalized<br />
compounds. L. F. Greenlee<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Heterogeneous Catalysis for Environmental<br />
and Sustainable Energy Applications<br />
General Environmental Catalysis<br />
Cosponsored by CATL (probationary)<br />
A. Orlov, M. Flytzani-Stephanopoulos,<br />
M. Bekbolet, B. Zhou, Organizers<br />
M. Castaldi, B. Wilhite, Organizers,<br />
Presiding<br />
8:30 Introductory Remarks<br />
8:35 112. Heterogeneous catalysis for sustainable<br />
energy. S. Perathoner, G. Centi,<br />
P. Lanzafame<br />
9:20 113. Dispersed calcium oxide as a reversible<br />
CO 2 sorbent at intermediate temperatures<br />
for sorption enhanced H 2-production.<br />
P. Gruene, R. J. Farrauto,<br />
M. J. Castaldi<br />
9:45 114. Design of nanostructured Au/<br />
Fe 3O 4 catalysts with high stability and<br />
activity for hydrogen production.<br />
S. Goergen, B. Ricks, P. Wu,<br />
M. Flytzani-Stephanopoulos<br />
10:10 Intermission<br />
10:30 115. Preferential oxidation of CO on<br />
Pt: Regimes of operation. F. Barrai,<br />
M. J. Castaldi<br />
10:55 116. Surface oxygen promoted reactions<br />
of methanol over gold supported on<br />
ZnO and CeO 2 “nano-shapes”.<br />
M. B. Boucher, N. Yi, B. Zugic, R. Si,<br />
H. Saltsburg,<br />
M. Flytzani-Stephanopoulos<br />
11:20 117. Autothermal reforming of JP8:<br />
Catalyst aging and impacts of sulfur on<br />
catalyst activity. N. Klinghoffer,<br />
M. J. Castaldi<br />
11:45 118. Catalytic decarboxylation of butyric<br />
acid to propane. B. Zugic,<br />
M. Flytzani-Stephanopoulos<br />
12:10 119. Facile approaches for controlled<br />
assembly of viral-templated palladium<br />
nanocatalysts for dichromate reduction.<br />
C. Yang, A. K. Manocchi, B. Lee, H. Yi<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ENVR<br />
TECH–49
ENVR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section C<br />
Renaissance Boston Waterfront<br />
Brewster<br />
Mining Waste: Geochemistry, Treatment,<br />
and Beneficial Reuse<br />
S. Al-Abed, Organizer<br />
R. Brennan, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 120. Oxic and anoxic tailings slurry aging<br />
studies at the Hope Bay Project, Nunavut.<br />
T. Wildeman, C. Bucknam,<br />
K. Murphey<br />
8:55 121. Use of acid mine drainage in management<br />
of flowback water from Marcellus<br />
shale hydrofracturing. E. Barbot,<br />
M. Li, M. Henrikson, J. Peng, K. Gregory,<br />
R. D. Vidic<br />
9:15 122. Use of mine water as alternative<br />
makeup water in cooling systems: Issues<br />
with excessive mineral scaling. H. Li,<br />
D. Dzombak, R. Vidic<br />
9:35 123. Modified humidity cell testing program<br />
for the prediction of acid rock drainage.<br />
S. P. Sunkavalli, E. M. Trujillo,<br />
P. Evans, D. Garcia, S. Kaiser<br />
9:55 124. Remedial technologies for mine<br />
wastes: An ITRC web-based guidance.<br />
P. Eger, C. Baysinger, S. Hill<br />
10:15 Intermission<br />
10:25 125. Silver mining, ore beneficiation<br />
and recycling, and land reclamation.<br />
J. R. Ellis<br />
10:45 126. Electrode-based remediation of<br />
U(VI)-contaminated acidic subsurfaces.<br />
J. Peng,K.B.Gregory<br />
11:05 127. Utilization of a sustainable resource<br />
to remediate high-strength mineimpacted<br />
water from a local abandoned<br />
mine: Crab-shell column study.<br />
J. A. Grembi, B. A. Sick, R. A. Brennan<br />
11:25 128. Activated iron solids treatment of<br />
mine drainage: A heterogeneous ferrous<br />
iron oxidation process. J. M. Dietz<br />
11:45 129. Heavy metal removal from mine<br />
impacted water using chitin. P. X. Pinto,<br />
S. Al-Abed, D. Reisman<br />
TUESDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Environmental Applications and<br />
Implications of Nanotechnology<br />
Biological Interactions Financially supported<br />
by Q-Sense, Division of Biolin Scientific<br />
A. Gu, C. Vecitis, Y. Jun, Organizers<br />
K. Chen, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 130. Sulfidation eliminates bactericidal<br />
effects of silver nanoparticles to Escherichia<br />
coli. Z. Li, B. C. Reinsch, R. Ma,<br />
K. B. Gregory, G. V. Lowry<br />
1:55 131. Role of nanoparticle geometry on<br />
nano-bio interaction: A quest to separate<br />
physics from chemistry. A. Afrooz,<br />
Q. Zaib, A. W. Decho, N. B. Saleh<br />
2:15 132. Is NMs uptake by algae possible?<br />
Evidence of titanium dioxide nanomaterials<br />
uptake by the cyanobacteria<br />
Anabaena variabilis. C. Cherchi,A.Z.Gu<br />
2:35 133. Antimicrobial effect of silver nanoparticles<br />
on bacterial biofilms. H. Park,<br />
E. Bae, J. Yi, J. Yoon<br />
2:55 134. Synthesis, properties, and antimicrobial<br />
activities of manganese oxide<br />
nanoparticles. A. Rutz, Y. Jun<br />
3:15 Intermission<br />
50–TECH<br />
‡ Cooperative Cosponsorship<br />
3:25 135. Ohshima’s soft particle analysis<br />
for estimating thickness of lipopolysaccharide<br />
and peptidoglycan on bacteria<br />
cell walls. T. Phenrat, A. Karamalidis,<br />
R. D. Tilton, G. V. Lowry<br />
3:45 136. Interaction of nanoparticles with<br />
biofilms. E. Sahle-Demessie, H. Tadesse<br />
4:05 137. Uptake and transport of quantum<br />
dots by protozoa in the presence and absence<br />
of bacteria. S. G. Berk,<br />
J. T. Payne, M. J. Wells<br />
4:25 138. MS2 coliphage inactivation by<br />
nanoparticulate zero-valent iron and ferrous<br />
ion. J. Kim, C. Lee, D. C. Love,<br />
D. L. Sedlak, K. L. Nelson, J. Yoon<br />
4:45 139. Toxicity mechanism of carbon<br />
nanomaterials. N. Gou,<br />
A. Onnis-Hayden, A. Z. Gu<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Heterogeneous Catalysis for Environmental<br />
and Sustainable Energy Applications<br />
Photocatalysis Cosponsored by CATL<br />
(probationary)<br />
A. Orlov, B. Wilhite, B. Zhou, M. Castaldi,<br />
M. Flytzani-Stephanopoulos, Organizers<br />
M. Bekbolet, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 140. Effect of molecular structure on<br />
the photocatalytic oxidation of multicomponent<br />
gas-phase mixtures.<br />
M. E. Zorn, S. O. Hay, M. A. Anderson<br />
1:55 141. Visible light photoreduction of<br />
CO 2 using CdSe/Pt/TiO 2 heterostructured<br />
catalysts. C. Wang, R. Thompson,<br />
J. Baltrus, C. Matranga<br />
2:15 142. Photocatalytic destruction of<br />
methyl t-butyl ether (MTBE) and 1,4-dioxane<br />
and other water soluble ethers using<br />
visible light. R. D. Barreto,D.Wood<br />
2:35 143. Air pollution removal by photocatalytic<br />
process. O. Zahraa<br />
2:55 144. Environmental photocatalysis: Exploring<br />
nanonometer and sub-nanometer<br />
particles to enhance the activity.<br />
A. Orlov, S. Zhao, G. Ramakrishnan,<br />
P. Shen, W. Han<br />
3:15 Intermission<br />
3:30 145. Highly efficient nanocrystalline<br />
visible light-activated TiO 2 films by modified<br />
sol-gel methods for sustainable<br />
“green” applications. M. Pelaez,<br />
P. Falaras, V. Likodimos, A. G. Kontos,<br />
A. A. de la Cruz, D. D. Dionysiou<br />
3:50 146. Hybrid adsorption-photocatalysis<br />
of organic pollutants with bifunctional<br />
TiO 2/AC composite under solar light: Prospective<br />
applications in water treatment<br />
and reclamation. T. Lim, P. Yap, M. Lim,<br />
S. Madhavi<br />
4:10 147. Absorption spectra of visiblelight-active<br />
TiO 2 specimens in the visible<br />
spectral domain. A. Emeline,<br />
V. N. Kuznetsov, V. K. Ryabchuk,<br />
N. Serpone<br />
4:30 148. Degradation C.I. Direct Yellow 9<br />
by heterogeneous oxidation processes<br />
using UV irradiation and ultrasound.<br />
Z. Eren, N. H. Inceb, F. N. Acarc<br />
4:50 149. Quantification of photoreactivity in<br />
nanostructured TiO 2 using EPR spin trap<br />
methods. S. S. Watson, I. Tseng,<br />
B. Pellegrin<br />
5:10 Concluding Remarks<br />
Section C<br />
Renaissance Boston Waterfront<br />
Brewster<br />
C. Ellen Gonter Environmental Chemistry<br />
Awards Symposium<br />
T. Anderson, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 150. Toxic metal sensing through pH<br />
changes using a novel hybrid sorbent<br />
material. P. K. Chatterjee,<br />
A. K. SenGupta<br />
2:00 151. Reduction rate constants for nitroaromatic<br />
compounds estimated from<br />
one-electron reduction potentials.<br />
K. L. Phillips, P. C. Chiu, S. I. Sandler<br />
2:25 152. Monitoring of 14 C-estradiol to determine<br />
the role of abiotic processes in<br />
the removal of estrogens during wastewater<br />
treatment. R. Marfil-Vega,<br />
M. T. Suidan, M. A. Mills<br />
2:50 153. Chlorine monoxide (Cl 2O) and molecular<br />
chlorine (Cl 2) as active chlorinating<br />
agents in reaction of dimethenamid with<br />
aqueous free chlorine. J. D. Sivey,<br />
C. E. McCullough, A. L. Roberts<br />
3:15 Intermission<br />
3:35 154. Fate of PCB congeners in an industrial<br />
harbor of Lake Michigan.<br />
A. Martinez, K. Wang, K. C. Hornbuckle<br />
4:00 155. Factors affecting stereoselective<br />
biotransformation of chiral polychlorinated<br />
biphenyls (PCBs) by cytochrome<br />
P-450 enzymes. Z. Lu, C. S. Wong<br />
4:25 156. Mechanisms of interaction between<br />
humic acid and hydrophobic CdSe<br />
quantum dots facilitating the partitioning<br />
into aqueous phase. D. G. Navarro,<br />
D. S. Aga, S. Banerjee, D. F. Watson<br />
WEDNESDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Environmental Applications and<br />
Implications of Nanotechnology<br />
Biological Interactions Financially supported<br />
by Q-Sense, Division of Biolin Scientific<br />
C. Vecitis, K. Chen, Y. Jun, Organizers<br />
A. Gu, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 157. Aggregation behavior of carbonbased<br />
nanomaterials in aquatic environments:<br />
Implications for transport and<br />
bacterial cytotoxicity. M. Elimelech<br />
9:15 158. Palladium nanoparticle formation<br />
by Citrobacter: Effective catalysts for diatrizoate<br />
removal. T. Hennebel,<br />
S. De Corte, D. Van der Lelie, J. Fitts,<br />
N. Boon, W. Verstraete<br />
9:35 159. Production of Au(0)-nanoparticles<br />
by Shewanella oneidensis after fast biosorption<br />
and slow reduction of Au(III).<br />
S. De Corte, T. Hennebel, S. Verschuere,<br />
C. Cuvelier, W. Verstraete, N. Boon<br />
9:55 160. Bioaccumulation of 14 C 60 by the<br />
earthworm Eisenia foetida. D. Li,<br />
C. Chen, D. R. Johnson, P. J. Alvarez<br />
10:15 Intermission<br />
10:25 161. New nanotoxicity assessment index<br />
links multidimensional toxicogenomics<br />
to regulatory ecotoxicology. N. Gou,<br />
A. Onnis-Hayden, A. Z. Gu<br />
10:45 162. Copper oxide nanoparticles<br />
(CuO NPs) induce oxidative DNA damage<br />
in plants. D. H. Atha, H. Wang,<br />
E. Petersen, A. Dillon, B. Xing, P. Jaruga,<br />
M. Dizdaroglu, B. C. Nelson<br />
11:05 163. Influence of phenotypic variation<br />
of bacteria on the toxicity of titanium dioxide.<br />
C. Hessler,Y.Seo<br />
11:25 164. Effects of surface charge on the<br />
partitioning of gold nanorods in saline estuarine<br />
mesocosms. J. L. Ferry,<br />
R. L. Frey, J. M. Burns, T. J. Shaw,<br />
C. J. Murphy, P. Sisco, A. W. Decho,<br />
G. T. Chandler, P. Pennington, M. Fulton<br />
11:45 165. Effect of titanium dioxide nanomaterials<br />
on nitrogen fixation rate and on<br />
N-storage dynamics of the blue-green algae<br />
Anabaena variabilis. C. Cherchi,<br />
A. Z. Gu<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy<br />
Probing Black Carbon Structure, Reactivity,<br />
and Sorptivity Cosponsored by GEOC<br />
J. Brandes, Organizer<br />
S. Uchimiya, J. Pignatello, J. Lehmann,<br />
Organizers, Presiding<br />
8:30 Introductory Remarks<br />
8:35 166. Complexity of aromatic carbon in<br />
biomass-derived black carbon (biochar):<br />
Implications for molecular structure and<br />
sorptive interactions. M. Keiluweit,<br />
P. S. Nico, M. G. Johnson, M. Kleber<br />
9:05 167. Characterization of charcoal using<br />
advanced solid-state NMR. J. Mao,<br />
J. J. Pignatello, J. Lehmann, M. Chappell<br />
9:35 168. Concentration dependency of<br />
PAH sorption in sediment-water systems:<br />
Enhanced sorption at low sorbate levels<br />
or physical occlusion? D. T. Kuo,<br />
P. M. Gschwend<br />
9:55 Intermission<br />
10:25 169. Sorption of bisphenol A, 17�ethinyl<br />
estradiol and phenanthrene by<br />
biochars obtained by thermal and hydrothermal<br />
methods. K. Sun,K.S.Ro,<br />
M. Guo, B. Xing<br />
10:45 170. Sorption properties of 1,3,5-trichlorobenznene<br />
on geosorbents.<br />
C. Yang, W. Huang, Z. Dang<br />
11:05 171. Unexpected adsorption behavior<br />
of a polar ionizable compound (sulfamethazine)<br />
on black carbon (biochar).<br />
J. J. Pignatello, M. Teixido-Planes,<br />
M. Granados, J. L. Peccia<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Emerging Applications in Membrane<br />
Science and Technology<br />
Innovations in Materials Development and<br />
Gas Separations<br />
I. Escobar, Organizer<br />
B. Van der Bruggen, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 172. Acceleration of materials design of<br />
hydrogen separation membrane alloys.<br />
R. Hu, M. Gao, &. Dogan, B. Howard,<br />
B. Morreale<br />
8:50 173. On tailoring the size and charge<br />
selectivity of thin film composite nanofiltration<br />
membranes based on PAN-g-PEO<br />
comb copolymers. N. Lovell,A.Mayes<br />
9:05 174. Organic membranes from painted<br />
latex films. J. Texter<br />
9:20 175. Functional nanotube membranes<br />
for hydrophobicity-based separations by<br />
initiated chemical vapor deposition<br />
(iCVD). A. Asatekin,K.K.Gleason<br />
9:35 176. Influence of fermentation by-products<br />
on the isolation of ethanol from fermentation<br />
broths using pervaporation.<br />
S. Chovau, B. Van der Bruggen,<br />
A. J. Straathof, S. Gaykawad<br />
9:50 177. Ionic liquid membranes for CO 2<br />
separation. C. R. Myers,D.R.Luebke,<br />
K. J. Champagne, D. Sorescu, C. Tang,<br />
W. Shi<br />
10:05 Intermission<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
10:20 178. Solubility and diffusivity of small<br />
molecules in thermally rearranged orthofunctional<br />
polyimides for gas separations.<br />
Z. P. Smith, D. Sanders, C. Ribeiro,<br />
B. D. Freeman, D. Paul<br />
10:35 179. Perfluorocyclobutyl (PFCB) polymers:<br />
Basolite ® Z1200 Mixed-Matrix<br />
Membranes (MMMs) for gas separation<br />
applications. G. D. Kalaw, K. J. Balkus,<br />
I. H. Musselman, J. P. Ferraris<br />
10:50 180. Carbon dioxide sorption properties<br />
of octahedral molecular sieves with<br />
manganese based framework composition.<br />
L. Espinal, C. R. Snyder, C. Chiu,<br />
L. A. Bendersky, W. Wong-Ng,<br />
M. L. Green, A. E. Espinal, H. F. Garces,<br />
S. L. Suib<br />
11:05 181. Hollow fiber membranes for carbon<br />
dioxide separation from flue gas and<br />
landfill gas: Experimental and modeling<br />
studies. J. R. Du, G. J. Francisco,<br />
P. Kundu, A. Chakma, X. Feng<br />
11:20 182. Pre-combustion fuel decarbonization<br />
with high temperature H 2 separation<br />
membranes. E. Engwall,<br />
J. Saukaitis, A. Del Paggio<br />
11:35 183. Grafting monomers for improved<br />
protein resistance with high throughput<br />
atmospheric plasma. M. Gu, J. C. Kilduff,<br />
G. Belfort<br />
11:50 Concluding Remarks<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Environmental Applications and<br />
Implications of Nanotechnology<br />
Fate and Transport Financially supported by<br />
Q-Sense, Division of Biolin Scientific<br />
A. Gu, K. Chen, Y. Jun, Organizers<br />
C. Vecitis, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 184. Oxidation of carbon nanotubes:<br />
Influence on interparticle forces and release<br />
rates. H. Fairbrother,<br />
K. Wepasnick, B. Smith, M. Bevan,<br />
S. Eichmann<br />
2:15 185. Systematic change in chirality affects<br />
aggregation kinetics of singlewalled<br />
carbon nanotubes. I. A. Khan,<br />
P. L. Ferguson, T. Sabo-Attwood,<br />
N. B. Saleh<br />
2:35 186. Influence of solution chemistry on<br />
the deposition kinetics of oxidized multiwalled<br />
carbon nanotubes on silica surfaces.<br />
P. Yi, K. Wepasnick, B. Smith,<br />
H. Fairbrother, K. Chen<br />
2:55 187. Phase distribution of 14 C-labeled<br />
multi-walled carbon nanotubes in aqueous<br />
systems containing model solids.<br />
L. Zhang, Q. Huang<br />
3:15 188. Alkyne-assisted carbon nanotube<br />
synthesis improves growth rate, yield,<br />
and quality while reducing costs and environmental<br />
impacts. D. L. Plata,<br />
E. R. Meshot, C. M. Reddy, A. Hart,<br />
P. M. Gschwend<br />
3:35 Intermission<br />
3:45 189. Occurrence and fate of engineered<br />
nanomaterials in wastewater<br />
treatment plants. M. A. Kiser,<br />
P. K. Westerhoff, H. Ryu, T. Benn<br />
4:05 190. Characterization of drinking water<br />
for naturally occurring and synthetic<br />
nanoparticles. E. A. Abdalla,G.Gagnon<br />
4:25 191. Effects of natural organic matter<br />
on stability, transport and deposition of<br />
engineered nanoparticles in porous media.<br />
E. Sahle-Demessie, Z. Li, G. Sorial<br />
4:45 192. Water-nanoparticle interactions:<br />
Effects of solution chemistry on n-Ag in<br />
aquatic systems. J. McLaughlin,<br />
T. H. Boyer, K. Powers, J. J. Bonzongo<br />
5:05 193. Impact of sunlight and humic acid<br />
on the aggregation kinetics of nC 60.<br />
X. Qu, Y. Hwang, Q. Li<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy<br />
Probing Black Carbon Structure, Reactivity,<br />
and Sorptivity Cosponsored by GEOC<br />
J. Lehmann, J. Pignatello, S. Uchimiya,<br />
J. Brandes, Organizers<br />
G. Cornelissen, Presiding<br />
1:30 Introductory Remarks<br />
1:35 194. Deciphering the chemical properties<br />
of pyrogenic carbon: Exposing a<br />
range of biochars to a range of characterization<br />
methods. A. R. Zimmerman,<br />
G. N. Kasozi, A. Mukherjee<br />
2:05 195. Sorption of pyrene to biologically,<br />
chemically and physically altered black<br />
carbons with and without soil. S. Hale,<br />
H. Arp, M. Elmquist, T. Henriksen,<br />
T. Hartnik, J. Lehmann, K. Hanley,<br />
G. Cornelissen<br />
2:35 196. Greenhouse gas sink or health<br />
risk? Assessing the fate of polycyclic aromatic<br />
hydrocarbons (PAHs) in biochar<br />
within the plant-soil system.<br />
S. Rangecroft, T. DeLuca, B. Emmett,<br />
D. Jones<br />
2:55 Intermission<br />
3:25 197. Comparison of nonpolar organic<br />
compounds and divalent metallic ions<br />
sorption with carbonaceous materials.<br />
H. Cho, J. Yang, W. P. Ball<br />
3:45 198. Metal interactions at the biocharwater<br />
interface: Energetics and composition-sorption<br />
relationship elucidated by<br />
flow adsorption micro-calorimetry.<br />
O. R. Harvey, B. E. Herbert, R. D. Rhue,<br />
L. Kuo<br />
4:05 199. Black carbon mediates reductive<br />
dehalogenation and nitro reduction reactions.<br />
S. Oh, J. Son, P. C. Chiu<br />
4:25 200. Black-carbon mediated destruction<br />
of nitroglycerin and RDX by hydrogen<br />
sulfide: Relevance to in situ remediation.<br />
W. Xu, K. Dana, W. Mitch<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Emerging Applications in Membrane<br />
Science and Technology<br />
Session in Honor of Benny D. Freeman<br />
B. Van der Bruggen, I. Escobar, Organizers<br />
G. Lipscomb, Presiding<br />
1:30 201. Hollow fiber membrane spinning.<br />
G. Lipscomb<br />
2:00 202. Temperature effects on solubilityselective<br />
membranes. X. Wang,<br />
T. C. Merkel, B. D. Freeman,<br />
I. C. Sanchez<br />
2:30 203. Polymer membrane design with<br />
high internal free volume for gas separation.<br />
H. Park,Y.Cho<br />
3:00 204. Separation of aromatic/aliphatic<br />
mixtures by pervaporation using orthofunctionalized<br />
polyimide membranes.<br />
C. P. Ribeiro, B. D. Freeman<br />
3:30 205. Understand the real upper bound<br />
for CO 2/CH 4 separation. H. Lin,<br />
A. Serbanescu-Martin, M. Zhou,<br />
T. Merkel<br />
4:00 206. Understanding the effect of ion<br />
exchange on water and salt transport<br />
properties of a highly-charged sulfonated<br />
pentablock copolymer. G. M. Geise,<br />
B. D. Freeman, D. R. Paul<br />
4:30 207. Advances in polymer membranes<br />
for water purification. B. D. Freeman<br />
5:20 Discussion<br />
WEDNESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
General Posters<br />
D. Dionysiou, Organizer<br />
6:00–8:00<br />
208. Ambient levels of persistent and emerging<br />
air contaminants at Acadia National<br />
Park. J. J. Pagano, C. M. Alexander<br />
209. Imprinted polymers for the removal of<br />
hydrophilic arsenic complexes from water.<br />
R. T. Perera, A. Mueller<br />
210. Experimental study of concentrated<br />
brine in SO 2 removal. X. Li<br />
211. Levels of selected heavy metals in New<br />
Jersey sanitary biosolids that are used as<br />
fertilizer. T. Tongesayi, P. Dasilva,<br />
K. Dilger, T. Hollingsworth<br />
212. Investigation on the enhanced stability<br />
of CO 2 hydrate in Ulleung-basin sediment<br />
suspension. K. Lee,W.Lee<br />
213. Tar reforming with catalyst and plasma.<br />
S. Roh, D. Lee, J. Lee, S. Keel,W.Kim<br />
214. Preparation of carbon and sulfur doped<br />
TiO 2 by sol-gel method for drinking water<br />
treatment under visible light. C. Han,<br />
M. Pelaez, V. Likodimos, A. G. Kontos,<br />
P. Falaras, D. D. Dionysiou<br />
215. New instrument for biogeochemical<br />
monitoring: AIS Micro-Observatory.<br />
D. B. Nuzzio<br />
216. Effects of air pollutants on the environmental<br />
health risk assessment of Gyeongju<br />
and Pohang in South Korea.<br />
J. Jung,B.Shon,K.Yoo<br />
217. Real-time simultaneous measurement<br />
of diesel vehicle exhaust with laser ionization<br />
mass spectroscopy. H. Yamada<br />
218. Enhanced solubilization and biodegradation<br />
of hexane by nonionic surfactant.<br />
Z. Wei, C. M. Hessler, G. Sorial, Y. Seo<br />
219. Size estimation and kinetics of formation<br />
for nanoparticles of sulfide with copper<br />
and zinc. R. Braczyk, S. M. Theberge<br />
220. Enhanced crystallinity of a carbon<br />
nanotube-based biosensor for monitoring<br />
microcystin-LR. C. Han, A. Doepke,<br />
W. Cho, A. D. de la Cruz,<br />
W. R. Heineman, H. B. Halsall,<br />
V. N. Shanov, M. J. Schulz, V. Likodimos,<br />
P. Falaras, D. D. Dionysiou<br />
221. Surface characterization of fouled PVDF<br />
based hollow fiber membranes used in<br />
drinking water treatment. J. E. Tobiason,<br />
A. Nguyen<br />
222. Characteristics and applications of controlled<br />
release permanganate gel for<br />
groundwater remediation. P. R. Olson,<br />
E. Lee, U. Solpuker, F. W. Schwartz,<br />
Y. Kim<br />
223. Influence of bacterial extracellular polymeric<br />
substances (EPS) on biosorption of<br />
natural organic matter in water distribution<br />
system. Z. Wang, Z. Xue, Y. Seo<br />
224. Development of degradation agent and<br />
field test assessment for oil contaminated<br />
soil using modified peat moss and organic<br />
sludge. J. H. Suh, J. Y. Lee,<br />
C. H. Lee<br />
225. Determination of organochlorine pesticides<br />
and polychlorinated biphenyls in<br />
sediment slurry using GC-ECD and GC-<br />
EI-MS after the hollow fibre-liquid phase<br />
microextraction. T. A. Msagati<br />
226. Basic characteristics of in-furnace<br />
deSOx in oxy-PC combustion field.<br />
J. Yun, S. Keel, T. Min,J.Lee<br />
227. Inactivation of E. coli endotoxin by softhydrothermal<br />
processing. T. Miyamoto,<br />
N. Kasai, S. Okano<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy Cosponsored<br />
by GEOC<br />
J. Brandes, S. Uchimiya, J. Pignatello,<br />
J. Lehmann, Organizers<br />
6:00–8:00<br />
228. Role of black carbon on the sorption of<br />
dioxins and furans in sediments from<br />
Newark Bay, New Jersey.<br />
M. K. Lambert, C. Friedman, J. Sullivan,<br />
R. Lohmann<br />
229. Reduction of Cr(VI) by chars derived<br />
from cellulose and lignin. S. Wang,<br />
Y. Chang, J. Lee<br />
230. Remediation of heavy metal contaminated<br />
soil with activated carbon.<br />
D. Rehrah<br />
231. Comparison of volatile chlorinated organic<br />
chemical sorption to black carbon<br />
and black shale. S. Choung,<br />
R. M. Allen-King<br />
232. Simple index for assessing the potential<br />
environmental stability of plant-derived<br />
biochars. O. R. Harvey<br />
233. Biochar soil amendment: Impact of soil<br />
types on heavy metal sorption-desorption<br />
behaviors and repeated nutrient leaching.<br />
M. Uchimiya, I. M. Lima, K. T. Klasson,<br />
L. H. Wartelle<br />
234. Characterization of solvent-extractable<br />
PAHs isolated from biochar produced<br />
from wood and grass over a range of pyrolysis<br />
temperatures. F. G. Prahl,<br />
M. Keiluweit, M. A. Sparrow, M. Kleber<br />
235. Reactive activated carbon impregnated<br />
with iron nanoparticles as a new environmental<br />
risk management option for contaminated<br />
sites. H. Choi, S. R. Al-Abed<br />
236. Black carbon and sorption of PAHs in<br />
natural fire-impacted sediments from Oriole<br />
Lake (CA). J. Sullivan, R. Lohmann,<br />
K. Bollinger, J. King, M. Cantwell, T. Caprio<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Chemistry of AOP Radicals During Water<br />
and Wastewater Treatment<br />
F. Rosario, D. Dionysiou, S. Mezyk,<br />
Organizers<br />
6:00–8:00<br />
237. Degradation of Reactive Red 195 azo<br />
dye by advanced oxidation processes.<br />
G. Genc<br />
238. Treatment of statin pharmaceuticals by<br />
advanced oxidation processes: Kinetic<br />
considerations and destruction mechanism.<br />
W. J. Cooper, B. Razavi, W. Song<br />
239. Removal of musk ketone and musk xylene<br />
from reclaimed wastewater using<br />
radical reactions. C. M. Hirsch,<br />
S. P. Mezyk<br />
240. Radical chemistry of chloramine in waters<br />
intended for reuse. G. McKay,<br />
S. P. Mezyk<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ENVR<br />
TECH–51
ENVR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section D<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Drinking Water Chemistry, Disease<br />
Prevention and Health Promotion Financially<br />
supported by Association of Environmental<br />
Engineering and Science Professors<br />
A. Dietrich, Organizer<br />
6:00–8:00<br />
241. Monitoring of biofilm by conducting<br />
polymer based sensor. T. Kim,J.Kang,<br />
K. Shin, J. Jang, J. Yoon, J. Choi<br />
242. Mechanistic insights into the inactivation<br />
of influenza viruses by antimicrobial<br />
hydrophobic polycationic coatings.<br />
B. B. Hsu, A. M. Klibanov<br />
243. Preventing and controlling pollution of<br />
electrolytic manganese industries and establishing<br />
a human healthy society.<br />
N. Duan, L. Jiang<br />
244. MST by using qRT-PCR to appraise the<br />
potential exposure to waterborne pathogens.<br />
M. O. Ryan,C.N.Haas<br />
245. Inactivation of microorganisms by Fenton’s<br />
reagent. J. Y. Kim, C. Lee,<br />
D. L. Sedlak, K. L. Nelson, J. Yoon<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Emerging Applications in Membrane<br />
Science and Technology<br />
I. Escobar, B. Van der Bruggen, Organizers<br />
6:00–8:00<br />
246. Fouling-tolerant membrane surface engineering<br />
for water purification and desalination<br />
applications. Y. Cho, H. Park,<br />
J. Shim<br />
247. Theoretical study for the integration of<br />
the Pd-based water gas shift membrane<br />
reactors into the IGCC plants. R. Koc,<br />
N. K. Kazantzis, Y. H. Ma<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Environmental Applications and<br />
Implications of Nanotechnology Financially<br />
supported by Q-Sense, Division of Biolin<br />
Scientific<br />
C. Vecitis, K. Chen, Y. Jun, A. Gu,<br />
Organizers<br />
6:00–8:00<br />
248. Size distribution and concentration signatures<br />
of nanoparticles and associated<br />
metals in indoor air. J. Niu,<br />
P. E. Rasmussen, B. G. Fraser<br />
249. Dissolution-accompanied aggregation<br />
kinetics of silver nanoparticles. X. Li,<br />
J. J. Lenhart, H. W. Walker<br />
250. Effect of humic acid on the stability of<br />
TiO 2 and ZnO nanoparticles in water.<br />
Y. Tseng, Y. Shih,S.Wu<br />
251. Fate and transport of zinc oxide nanoparticles<br />
in porous media in the presence<br />
of naturally occurring organic ligands.<br />
E. H. Jones,C.Su<br />
252. Effects of abiotic factors on silver nanoparticle<br />
uptake into Escherichia coli:Humic<br />
acid and salinity. E. Bae, H. Park,<br />
J. Yoon, J. Yi<br />
253. Elimination of the toxicity of singlewalled<br />
carbon nanotubes on a model<br />
aquatic organism through the manipulation<br />
of suspension preparation methods.<br />
S. Youn, K. J. Ziegler, J. J. Bonzongo<br />
254. Interactions between bacteria and silver<br />
nanoparticles with biodegradable coatings.<br />
D. M. Aruguete,B.Kim,Y.Cheng,<br />
J. Liu, M. F. Hochella<br />
52–TECH<br />
‡ Cooperative Cosponsorship<br />
255. Influence of stabilized magnetite nanoparticles<br />
on bacterial survival and growth<br />
in natural waters. K. F. Starr, Y. Feng,<br />
Q. Liang, D. Zhao<br />
256. Stabilization of nanoscale zerovalent<br />
iron (nZVI) with green tea. B. Jung,<br />
B. E. Sleep, D. M. O’Carroll<br />
257. Aqueous suspension methods of carbon-based<br />
nanomaterials and biological<br />
effects on model aquatic organisms.<br />
V. Llaneza, J. Gao, J. McLaughlin,<br />
K. Ziegler, J. J. Bonzongo<br />
258. Sorption of non-polar organic vapors on<br />
silica- and carbon-based engineered<br />
nanomaterials. D. Ramirez,<br />
N. Facundo Torres<br />
259. Nitrogenation of multi-walled carbon<br />
nanotubes. J. L. Bitter, H. Fairbrother<br />
260. Effect of water chemistry on disinfection<br />
performance of silver nanoparticles.<br />
H. Zhang, V. O. Craver<br />
261. Inhibition and gene expression of Nitrosomonas<br />
europaea cells exposed to silver<br />
nanoparticles in various aqueous chemistries.<br />
T. S. Radniecki, D. Stankus,<br />
J. Nason, L. Semprini<br />
262. Development of fumed-silica-supported<br />
nanostructured sorbent for CO 2 capture.<br />
E. Peduzzi, X. Ma, C. Song<br />
263. Separation and quantification of E. coli<br />
O157:H7 using magnetic bead-quantum<br />
dot nanoparticles. A. Son,G.Kim<br />
264. Temperature stability in quartz crystal<br />
microbalance studies. G. Coimbatore,<br />
M. Smith, A. Hoffarth, A. Gibson,<br />
G. Austin, S. Presley, G. P. Cobb<br />
265. Liquid phase deposition of nanostructured<br />
TiO 2 hybrid films as functionalized<br />
semiconducting electrodes. C. Yang,<br />
J. Zhang<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Environmental Health Volatiles and<br />
Aerosols: Novel Direct Measurement<br />
Methods Relevant to Lung Disease<br />
B. Holmen, J. Hill, J. Peccia, Organizers<br />
6:00–8:00<br />
266. Chemistry in the earth’s atmosphere:<br />
Investigating ester formation in secondary<br />
organic aerosols by mass spectrometry.<br />
J. Delius,L.Müller, M. Reinnig,<br />
T. Hoffmann<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Heterogeneous Catalysis for Environmental<br />
and Sustainable Energy Applications<br />
Cosponsored by CATL (probationary)<br />
A. Orlov, M. Castaldi, M. Bekbolet, B.<br />
Wilhite, M. Flytzani-Stephanopoulos,<br />
B. Zhou, Organizers<br />
6:00–8:00<br />
267. New solid base catalysts for biodiesel<br />
synthesis. J. M. Montero, K. Wilson,<br />
A. F. Lee<br />
268. Hierarchical nanoporous solid base catalysts<br />
for biofuels. J. Woodford,<br />
A. F. Lee, K. Wilson, J. Dacquin<br />
269. Continuous-flow gas-phase photocatalytic<br />
oxidation of acrylonitrile on sulphated<br />
TiO 2 and transient study of acrylonitrile<br />
photocatalytic degradation.<br />
S. Jõks, M. Kritsevskaja, S. Preis<br />
270. Catalytic reduction of nitric oxide with<br />
hydrogen by Pd/PVP in water. K. Kelley,<br />
J. R. Shapley<br />
271. Simultaneous observation of gas phase<br />
and surface species in photocatalytic reactions:<br />
The next generation of DRIFTS<br />
applications. G. Ramakrishnan, S. Zhao,<br />
A. Orlov<br />
272. Heterogeneous perchlorate reduction<br />
by a Mo-Pd/C catalyst. Y. Zhang,<br />
J. R. Shapley<br />
273. Preparation of characterization of highly<br />
active Ni catalyst supported on �-Al 2O 3<br />
for the steam reforming of glycerol.<br />
Y. Choi,N.Kim,J.Baek,J.Yi<br />
274. Novel applications of sub-nanometer<br />
noble metal particles for photocatalysis.<br />
S. Zhao, G. Ramakrishnan, P. Shen,<br />
W. Han, A. Orlov<br />
275. Thermogravimetric study of propane<br />
and propene steam reforming over NiO<br />
and PtRh catalysts. M. P. Kohn,<br />
M. J. Castaldi, R. J. Farrauto<br />
276. Rare earth oxysulfides as sulfur-tolerant<br />
catalysts for the high-temperature watergas<br />
shift reaction. I. Valsamakis,<br />
M. Flytzani-Stephanopoulos<br />
Section I<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Mining Waste: Geochemistry, Treatment,<br />
and Beneficial Reuse<br />
R. Brennan, S. Al-Abed, Organizers<br />
6:00–8:00<br />
277. Geochemical distribution of trace element<br />
concentrations in the vicinity of Boroo<br />
Gold Mine, Mongolia. E. Inam,<br />
S. Khantotong, K. Kim,<br />
B. Tumendemberel, S. Erdenetsetseg,<br />
T. Puntsag<br />
278. Remediation of manganese-bearing<br />
mine-impacted water using crab-shell<br />
chitin: Isolating the abiotic mechanisms<br />
of sorption and precipitation.<br />
M. Robinson-Lora, R. A. Brennan<br />
Section J<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes Cosponsored by<br />
COLL and GEOC<br />
E. Weber, T. Strathmann, J. Brandes,<br />
J. Texter, H. Zhang, Organizers<br />
6:00–8:00<br />
279. Spectroscopic and microscopic studies<br />
of weathering and decay in historic magnesian<br />
limestone. R. A. Walker,<br />
K. F. Giles, A. F. Lee, K. Wilson<br />
280. Bifunctional resin-supported Fe/Ni<br />
composites for catalytic elimination of trichloroethylene<br />
by simultaneous dechlorination<br />
and adsorption. W. Zhang<br />
281. Novel environmentally friendly approach<br />
to paint strippers based in interfacial<br />
mechanistic studies. J. H. Wynne,<br />
K. E. Watson, J. G. Lundin,<br />
J. P. Yesinowski<br />
282. Photochemistry of adsorbed nitrate on<br />
aluminum oxide particle surfaces.<br />
G. R. Rubasinghege, V. H. Grassian<br />
283. Episodic hydrogeochemical controls on<br />
lead and arsenic mobility at a former fertilizer<br />
manufacturing facility, New Jersey.<br />
J. L. deLemos, B. C. Bostick,<br />
W. D. Brady, G. O. Cadwalader,<br />
J. E. Vidumsky, M. F. DeFlaun<br />
284. Reactions involving dissolved Al and<br />
SiO 2: A comparison between amorphous<br />
silica and crystalline quartz. H. Van Atta,<br />
R. S. Maxwell, S. A. Carroll,<br />
J. R. Houston<br />
285. Polymer-based zirconium phosphate<br />
nanoparticles for lead retention: Effect of<br />
polymeric functional groups. Q. Zhang,<br />
B. Pan, W. Zhang, L. Lv, Q. Zhang<br />
286. Abiotic transformation of hormones exposed<br />
to Fe(III)-montmorillonite and nitrite.<br />
K. Xia,K.Verma<br />
Section K<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sustaining Water Quality Cosponsored by<br />
ANYL Financially supported by Global<br />
Innovation Imperatives<br />
S. Ahuja, M. Larsen, W. Cooper,<br />
Organizers<br />
6:00–8:00<br />
287. New ocean contamination derived from<br />
marine debris plastics. F. Shionoya,<br />
H. Sato, Y. Kodera, S. Chung, O. Abe,<br />
N. Ogawa, Q. Che, K. Miyashita, T. Kusui,<br />
K. Saido<br />
288. Molecular detection and quantification<br />
of swine fecal contamination in the northeast<br />
Cape Fear River and Black River.<br />
A. Arfken, M. I. Haltom, M. A. Mallin,<br />
L. Cahoon, B. Song<br />
289. Dielectric barrier discharges plasma inactivation<br />
of Microcystis aeruginosa: Effects<br />
and mechanisms. G. Wang<br />
290. Effect of heavy metals on mineral surfaces<br />
and bacterial attachment.<br />
H. Zhang, M. Olson<br />
291. Drinking water: New adsorbentia for the<br />
removal and detection of polar organic<br />
chemicals. P. S. Bauerlein, T. L. ter Laak,<br />
P. de Voogt, B. van der Gaag,<br />
A. van Wezel<br />
292. Biogeochemical factors affecting mercury<br />
speciation in Long Island Sound.<br />
A. B. Schartup, P. Balcom, R. P. Mason,<br />
A. Hutchins<br />
293. Source water quality in the Monongahela<br />
River Basin. J. M. Wilson,<br />
J. M. VanBriesen<br />
294. Impact of CSO on water quality in urban<br />
streams. J. Bushey, A. Aragon-Jose,<br />
C. Perkins, M. Mendes, G. Ulatowski<br />
295. Statistical analysis of water chemistry<br />
parameters, land use patterns, and geology<br />
in the Kayaderosseras Creek watershed.<br />
J. A. Halstead, S. Kliman,<br />
D. de la Puente-Ranea, A. Cock-Esteb,<br />
A. Chaucer, K. Connolly, K. Marsella,<br />
C. W. Berheide<br />
296. Adsorption characteristics of copper<br />
ion with zeolite synthesized by coal fly<br />
ash. J. Y. Lee, J. H. Suh,C.H.Lee<br />
297. Influence of biofilm formation on pathogen<br />
removal in the riverbank filtration system.<br />
E. Boff,Y.Seo<br />
THURSDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Environmental Applications and<br />
Implications of Nanotechnology<br />
Environmental Applications Financially<br />
supported by Q-Sense, Division of Biolin<br />
Scientific<br />
A. Gu, K. Chen, Y. Jun, Organizers<br />
C. Vecitis, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 298. Photochemistry and photophysics<br />
of semiconductor quantum dots: Effects<br />
of quantum confinement, defect states,<br />
doping, shape and morphology.<br />
M. R. Hoffmann<br />
9:15 299. Withdrawn<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
9:35 300. Organic nanoparticles of metalloporphyrins<br />
as efficient catalysts for the<br />
selective oxidation of olefins under ambient<br />
conditions. A. Aggarwal,C.M.Drain<br />
9:55 301. Effect of cations on the reduction<br />
of pentachlorophenol by zerovalent bimetallic<br />
nanoparticles. Y. Su, M. Chen,<br />
Y. Shih<br />
10:15 Intermission<br />
10:25 302. Nanocomposites for removal of<br />
pollutants. A. K. Das, D. Norton,<br />
J. Dinglasan, N. Loukine, D. Anderson<br />
10:45 303. Application of nano-zerovalent<br />
iron (NZVI) for adsorption of antimony in<br />
shooting range soils: Characterization<br />
and Sb adsorption properties of NZVI.<br />
D. Amarasiriwardena, P. Dorjee, B. Xing<br />
11:05 304. Mercury removal from aqueous<br />
effluents using zerovalent iron: Effect of<br />
particle size and implications for wastewater<br />
treatment. J. Vernon, J. Bonzongo<br />
11:25 305. Iron oxide coated multiwall carbon<br />
nanotubes for the removal of arsenic<br />
from water. S. Addo Ntim, S. Mitra<br />
11:45 306. Development of silica-gel-supported<br />
polyethylenimine sorbent for CO 2<br />
capture. Z. Zhang, X. Ma, C. Song,<br />
Y. Wang<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy<br />
Utilization of Black Carbon Products in<br />
Agriculture, Environmental Remediation,<br />
and Other Applications Cosponsored by<br />
GEOC<br />
S. Uchimiya, J. Pignatello, J. Lehmann,<br />
Organizers, Presiding<br />
8:30 Introductory Remarks<br />
8:35 307. In situ sequestration of organics,<br />
metals, and carbon in contaminated sediments.<br />
U. Ghosh<br />
9:05 308. Modeling the mass transfer of hydrophobic<br />
organic pollutants in sediment<br />
after amendment with activated carbon.<br />
D. Werner,S.E.Hale<br />
9:25 309. Simultaneous removal of mercury(II)<br />
and PCBs by polysulfide-rubber(PSR)-coated<br />
activated carbon.<br />
E. Kim, R. G. Luthy<br />
9:45 Intermission<br />
10:15 310. Charcoal production: The state<br />
of the art. M. J. Antal, Jr<br />
10:45 311. Oil shale semicoke as a carbon<br />
source: Sorbent capacity, reactivity and<br />
entrained compounds as functions of pyrolysis<br />
temperature and shale origin.<br />
J. L. Goldfarb, B. Datangel, I. Kulaots<br />
11:05 312. Evaluation of chitosan coated<br />
granular activated carbon for treatment of<br />
perchlorate-contaminated munitions<br />
wastewater. V. M. Boddu,<br />
S. W. Maloney, D. S. Viswanath,<br />
T. K. Ghoash, S. M. Uchimiya<br />
11:25 313. Aqueous nanodispersions of hydrothermal<br />
carbon for environmentally<br />
friendly and sustainable combustion processes.<br />
J. Texter, R. Crombez, M. Titrici,<br />
F. Perez-Caballero, M. Antonietti<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Emerging Applications in Membrane<br />
Science and Technology<br />
Advances in Membrane Materials and<br />
Liquid Separations<br />
I. Escobar, Organizer<br />
B. Van der Bruggen, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 314. Preparation of biofouling-resistant<br />
RO membranes by the attachment of ceragenins.<br />
M. Hibbs, S. Altman,<br />
L. McGrath, H. Jones, Y. Feng, P. Savage<br />
8:50 315. Development of copper and silver<br />
charged polypropylene feed spacers for<br />
biofouling control. R. Hausman,<br />
T. Gullinkala, I. Escobar<br />
9:05 316. Quantitative emerging materials<br />
characterization techniques to anticipate<br />
membrane biofouling. A. M. Zaky<br />
9:20 317. N-isopropylacrylamide (NIPAAM)<br />
modified ultrafiltration membranes.<br />
C. Gorey, I. Escobar, G. Bothun<br />
9:35 318. Adsorptive fouling resistance of<br />
carbon nanotube blended polyethersulfone<br />
membranes. E. Celik, H. Choi<br />
9:50 319. Study of nanoparticle rejection using<br />
a tailor-made ultrafiltration polysulfone<br />
membrane. S. Hakim Elahi,<br />
I. C. Escobar<br />
10:05 Intermission<br />
10:15 320. Grafting binary monomers and<br />
solvent effects for improved protein resistance.<br />
Y. S. Ho, M. Gu, C. Kilduff,<br />
G. Belfort<br />
10:30 321. Hydrophilization of thin film composite<br />
membrane support layers for engineered<br />
osmosis applications.<br />
J. McCutcheon, J. Arena, N. Bui<br />
10:45 322. Surface functionalization of polybenzimidizole<br />
membranes to increase hydrophilicity<br />
and charge. B. Digman,<br />
I. C. Escobar, R. Hausman, M. Coleman,<br />
T. Chung<br />
11:00 323. Chiral signatures in passive samplers<br />
support a better understanding of<br />
transformation of contaminants in water.<br />
V. D. Dang,C.M.Lee<br />
11:15 324. Imprinted polymers and membranes<br />
for Cd 2� and Zn 2� removal from<br />
water. S. A. Ashraf, A. Mueller<br />
11:30 325. Reversible cation exchangemembrane<br />
(RCIX-MEM) process for scaling<br />
free, energy efficient desalination of<br />
seawater. S. Sarkar,A.K.SenGupta<br />
11:45 Concluding Remarks<br />
THURSDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 1<br />
Environmental Applications and<br />
Implications of Nanotechnology<br />
General Papers Financially supported by<br />
Q-Sense, Division of Biolin Scientific<br />
C. Vecitis, K. Chen, Y. Jun, Organizers<br />
A. Gu, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 326. <strong>Chemical</strong> reduction of hexabromocyclododecane<br />
by zerovalent iron<br />
nanoparticles. C. Tso, Y. Shih, C. Lin<br />
1:55 327. Removal of atrazine and trimethoprim<br />
by iron oxide nanoparticle-impregnated<br />
mesoporous carbon. Y. Kim<br />
2:15 328. Spectroscopic investigations of<br />
arsenic redox transformations by<br />
nanoscale zero-valent iron (nZVI).<br />
W. Yan, M. A. Ramos, X. Li, B. E. Koel,<br />
W. Zhang<br />
2:35 329. Transport of polysaccharide-stabilized<br />
iron nanoparticles in porous media:<br />
Effect of surface and solution chemistry.<br />
M. Zhang,D.Zhao<br />
2:55 330. Sequestration of malodorous sulfides<br />
with zero-valent iron nanoparticles.<br />
X. Li<br />
3:15 Intermission<br />
3:25 331. Effect of natural organic matter on<br />
the stability and mobility of polymercoated<br />
iron nanoparticles. B. Jung,<br />
B. E. Sleep, D. M. O’Carroll<br />
3:45 332. Development of carbon-based<br />
“molecular basket” sorbent for CO 2 capture<br />
from flue gas. D. Wang, C. Shalaby,<br />
X. Ma, C. Song<br />
4:05 333. Stability and mobility of metal oxide<br />
nanoparticles in porous media.<br />
C. Contreras, J. George, K. Paredes,<br />
H. J. Shipley<br />
4:25 334. Gold nanoparticle-based selective<br />
and ultrasensitive detection of iodide by<br />
SERS. S. S. Dasary, D. Senapati,<br />
A. Singh, T. Arbneshi, H. Yu, P. C. Ray<br />
4:45 335. Utilization of polymer cross-linkers<br />
to improve the thermal stability of “molecular-basket”<br />
sorbents. E. P. Fillerup,<br />
X. Wang, X. Ma, C. Song<br />
5:05 Best Graduate Student Presentation<br />
Awards<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom A/B<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy<br />
Fate and Function of Black Carbon in Soil<br />
and Sediment Cosponsored by GEOC<br />
S. Uchimiya, J. Pignatello, J. Lehmann,<br />
Organizers, Presiding<br />
1:30 Introductory Remarks<br />
1:35 336. Rapid screening of biochar products<br />
for soil functional attributes.<br />
S. P. Sohi, A. Cross, M. Borlinghaus<br />
2:05 337. Impacts of biochar additions on<br />
soil microbial processes and nitrogen cycling.<br />
K. A. Spokas<br />
2:35 338. Biochar: Mother Nature’s nanotechnology.<br />
R. S. Stein, H. S. McLaughlin<br />
2:55 Intermission<br />
3:25 339. Pyrogenic matter dynamics in the<br />
soil: Characterization, stabilization processes,<br />
C budget and effects on soil<br />
properties. S. Abiven, M. Schneider,<br />
N. Singh, B. Maestrini, M. Schmidt<br />
3:55 340. Biomass plant fly ash as a source<br />
of black carbon for amending agricultural<br />
soils. A. F. Carpenter<br />
4:15 341. Interactions of engineered soot to<br />
natural organic matter and extracellular<br />
polymeric substances: Resulting surface<br />
modification and field application.<br />
J. Lohwacharin, K. Oguma, S. Takizawa<br />
4:35 342. Biochar as a soil amendment: Soil<br />
Survey considerations for future management<br />
directions. C. A. Stiles, L. T. West,<br />
C. W. Smith, J. Gaskin<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Environmental Health Volatiles and<br />
Aerosols: Novel Direct Measurement<br />
Methods Relevant to Lung Disease<br />
J. Hill, J. Peccia, Organizers<br />
B. Holmen, Organizer, Presiding<br />
1:30 343. Rapid detection of tobramycin impacts<br />
on Pseudomonas aeruginosa volatile<br />
organic compound production by<br />
SESI-MS. Y. Kuo,J.Hill<br />
1:50 Discussion<br />
1:55 344. Volatile signature of P. aeruginosa<br />
adaptation to the cystic fibrosis lung.<br />
H. D. Bean, Y. Kuo, J. Zhu, J. E. Hill<br />
2:15 Discussion<br />
2:20 345. Next-generation DNA sequencing<br />
reveals viral diversity in biosolids.<br />
K. J. Bibby, E. J. Viau, J. Peccia<br />
2:40 Discussion<br />
2:45 Intermission<br />
2:55 346. Airport air: What are we breathing?<br />
R. L. Vander Wal, V. M. Bryg,<br />
C. Hunag<br />
3:15 Discussion<br />
3:20 347. Preliminary investigation of traffic<br />
emissions in the vicinity of an inner city<br />
elementary school. B. Albrinck, M. Lu,<br />
J. Hu, C. Chaiwatpongsakorn,<br />
V. K. Nemalapuri, H. Wei<br />
3:40 Discussion<br />
3:45 348. Quantitative estimates of the volatility<br />
of ambient organic aerosol.<br />
C. D. Cappa, J. L. Jimenez<br />
4:05 Discussion<br />
4:10 349. Organic aerosol composition using<br />
a combined thermal desorption aerosol<br />
gas chromatograph (TAG) - high resolution<br />
time-of-flight aerosol mass<br />
spectrometer (HR-ToF-AMS). B. Williams,<br />
A. Lambe, J. Jayne, D. Worsnop,<br />
N. L. Ng, M. Canagaratna, L. Williams,<br />
J. Kimmel, D. Sueper, N. Kreisberg,<br />
S. Herring, D. Worton, A. Goldstein<br />
4:30 Discussion<br />
FUEL<br />
Division of Fuel<br />
Chemistry<br />
C. Liu, Program Chair<br />
SOCIAL EVENTS:<br />
Dinner, 6:30 PM: Tue<br />
BUSINESS MEETING:<br />
Program Meeting, 2:00 PM: Sun<br />
Executive Council Meeting, 4:00 PM:<br />
Sun<br />
Business Meeting, 12:00 PM: Mon<br />
SUNDAY MORNING<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom E<br />
Ionic Liquids in Sustainable Energy and<br />
Fuels<br />
CO2 Capture, Gas Absorption and<br />
Separations Cosponsored by I&EC<br />
W. Henderson, Organizer<br />
E. Maginn, Organizer, Presiding<br />
ENVR/FUEL<br />
8:30 Introductory Remarks<br />
8:40 1. Synthesis, characterization and performance<br />
of single-component CO 2binding<br />
organic liquids (CO 2BOLs) for<br />
post combustion CO 2 capture.<br />
P. K. Koech, D. J. Heldebrant,<br />
J. E. Rainbolt, F. Zheng, T. Smurthwaite<br />
9:00 2. Ab initio description of CO 2 interactions<br />
with anions in ionic liquids.<br />
J. A. Steckel,W.Shi<br />
9:20 3. Predicting CO 2 complexation in ionic<br />
liquids using reaction ensemble Monte<br />
Carlo. T. W. Rosch,E.J.Maginn<br />
9:40 4. Ionic liquid gas absorption of NO X,<br />
CO X and SO X. S. Saravanamurugan,<br />
J. Due-Hansen, S. Kegnæs,<br />
T. Grétarsdóttir, A. Riisager,<br />
R. Fehrmann<br />
10:00 Intermission<br />
10:10 5. Ionic liquids with aprotic heterocyclic<br />
anions for post-combustion CO2<br />
capture. B. Goodrich, S. Seo, L. Wilson,<br />
L. Ficke, M. Massel, D. Zadigian,<br />
J. F. Brennecke<br />
10:45 6. Origin of products in homogeneous<br />
CO hydrogenation reactions. J. H. Blank,<br />
D. J. Cole-Hamilton<br />
11:20 7. Separation of ethanol from water<br />
using phosphonium-based ionic liquids.<br />
C. M. Neves, M. G. Freire, J. A. Coutinho<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–53
FUEL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section C<br />
Renaissance Boston Waterfront<br />
Brewster<br />
Non-thermal Plasma Assisted Fuel<br />
Conversion for Green Chemistry<br />
General Future Fuel Issues<br />
A. Gutsol, T. Nozaki, Organizers, Presiding<br />
8:30 Introductory Remarks<br />
8:35 8. Acidity analysis of HZSM-5 zeolite<br />
prepared using plasma template removal<br />
via dielectric barrier discharges. Y. Liu,<br />
P. Kuai, P. Huo, C. Liu<br />
8:55 9. Low temperature plasma assisted<br />
dissociation of hydrogen sulfide.<br />
K. Gutsol, T. Nunnally, A. Rabinovich,<br />
A. Starikovskiy, A. Fridman, A. Gutsol,<br />
A. Kemoun<br />
9:15 10. Effect of plasma assisted pretreatment<br />
of wheat straw on enzymatic hydrolysis,<br />
and ethanol fermentation.<br />
N. Schultz-Jensen, Z. Kadar, F. Leipold<br />
9:35 11. <strong>Chemical</strong> intermediate detection<br />
following corona discharge on volatile organic<br />
compounds: General method using<br />
molecular beam techniques. L. He,<br />
M. Sulkes<br />
9:55 12. Current-voltage characteristics of<br />
in-liquid plasma. S. Nomura, S. Mukasa,<br />
H. Toyota, M. Kageura<br />
10:15 Intermission<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
Nanotech for Sustainable Energy and Fuels<br />
Solar Energy and Photocatalysis<br />
C. Liu, F. Besenbacher, Z. Wang,<br />
Organizers<br />
E. Kadossov, Presiding<br />
U. Burghaus, Organizer, Presiding<br />
9:00 Introductory Remarks<br />
9:05 13. CuO x /TiO 2 nanostructure for photocatalytic<br />
hydrogen production.<br />
V. Gombac, T. Montini, L. Sordelli,<br />
M. Cargnello, P. Fornasiero<br />
9:25 14. Design considerations for nanowire<br />
heterojunctions in solar energy conversion/storage<br />
applications.<br />
K. V. Hagedorn, C. Forgacs, S. Collins,<br />
S. Maldonado<br />
9:45 15. Synthesis and characterization of<br />
TiO 2 nanotube films via pulsed laser deposition<br />
for solar cell applications.<br />
S. D. Perera, K. J. Balkus<br />
10:05 Intermission<br />
10:15 16. Synthesis of fullerene tethered<br />
double-cable diblock copolymers based<br />
on P3HT and its application in polymer<br />
solar cells. D. Lee, J. P. Ferraris<br />
10:35 17. Enhancing photochemical activity<br />
of semiconductor nanoparticles with optically<br />
active metallic nanostructures: Photochemistry<br />
mediated by surface plasmons.<br />
S. Linic, P. Chrisotpher,<br />
D. B. Ingram<br />
10:55 18. High efficiency water photolysis<br />
by titanium dioxide nanowire thin films.<br />
M. Liu,N.d.Snapp,H.Park<br />
11:15 19. Porphyrin sensitized solar cell:<br />
Synthesis, photophysics, and photovoltaics.<br />
H. He, V. Pogula, M. Shrestha,<br />
M. Dubey, Y. Zhong, M. Yan, X. Yan<br />
54–TECH<br />
‡ Cooperative Cosponsorship<br />
Section C<br />
Renaissance Boston Waterfront<br />
Brewster<br />
Non-thermal Plasma Assisted Fuel<br />
Conversion for Green Chemistry<br />
Stationary Plasma Fuel and CO2 Conversion<br />
A. Gutsol, T. Nozaki, Organizers, Presiding<br />
10:35 20. Plasma fuel reforming.<br />
A. Fridman, A. Rabinovich, A. Gutsol<br />
11:05 21. Decomposition of CO2 by large<br />
flow atmospheric microwave plasma<br />
(LAMP). S. Parajulee, S. Ikezawa,<br />
M. Hayakawa<br />
11:25 22. Dissociation of CO2 in low current<br />
gliding arc plasmatron. T. P. Nunnally,<br />
K. Gutsol, A. Rabinovich, A. Fridman,<br />
A. Starikovskii, A. Gutsol, A. Kemoun<br />
11:45 23. Non-thermal plasma-chemical<br />
CO2 utilization: COx polymer formation.<br />
R. Geiger, D. Staack<br />
12:05 24. Dry reforming of methane using a<br />
dielectric barrier plasma reactor.<br />
J. C. Whitehead, H. J. Gallon, X. Tu,<br />
M. V. Twigg<br />
Operando and In Situ Spectroscopy<br />
X-ray Methods Sponsored by CATL<br />
(probationary), Cosponsored by COLL, FUEL,<br />
and PETR<br />
SUNDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
Nanotech for Sustainable Energy and Fuels<br />
Catalyst and Nanomaterials Cosponsored by<br />
CATL (probationary)<br />
C. Liu, F. Besenbacher, Z. Wang,<br />
Organizers<br />
U. Burghaus, Organizer, Presiding<br />
R. Tenne, Presiding<br />
1:25 Introductory Remarks<br />
1:30 25. Catalytic model systems studied by<br />
high-resolution, video-rate scanning tunneling<br />
microscopy. F. Besenbacher<br />
2:05 26. Core-shell catalysts and bimodal<br />
catalysts for Fischer-Tropsch synthesis.<br />
N. Tsubaki<br />
2:40 27. Effect of surface oxygen containing<br />
groups on carbon nanotube supported<br />
catalyst. X. Wang, N. Li, L. D. Pfefferle,<br />
G. L. Haller<br />
3:00 28. Bond activation in thiophene and<br />
catalyst poisoning: Nanosize Mo clusters<br />
supported on silica for desulfurization catalysis.<br />
E. Kadossov, M. Komarneni,<br />
J. Justin, U. Burghaus<br />
3:20 29. Free-standing palladium/polyamide<br />
6 nanofibers for electrooxidation of alcohols<br />
in alkaline medium. L. Su, W. Jia,<br />
Y. Lei<br />
3:40 Intermission<br />
3:50 30. Routes for core-shell inorganic<br />
nanotubes. R. Kreizman, S. Y. Hong,<br />
F. L. Deepak, A. N. Enyashin,<br />
R. Popovitz-Biro, A. Albu-Yaron,<br />
G. Seifert, R. Tenne<br />
4:25 31. Reversible nanoconfined chemical<br />
reaction. T. K. Nielsen,U.Bösenberg,<br />
R. Gosalawit, M. Dornheim, Y. Cerenius,<br />
T. Jensen, F. Besenbacher<br />
4:45 32. How geometry relaxation in metallic<br />
nanoparticle affects the oxygen reduction<br />
reaction. C. Lu, G. Henkelman<br />
5:05 33. Correlation between preparation<br />
methods and surface carbon formed in<br />
CH 4 and CO 2 dry reforming on Ni-based<br />
catalysts. L. Guczi, A. Kiennemann,<br />
G. Stefler<br />
5:25 34. Promotion effect of nano Ga 2O 3<br />
particles on CO 2 adsorption and conversion.<br />
Y. Pan, P. Kuai, Y. Liu, C. Liu<br />
5:45 35. Palladium/titanium dioxide nanofibers<br />
for glycerol electrooxidation in alkaline<br />
medium. L. Su, W. Jia, Y. Lei<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom E<br />
Ionic Liquids in Sustainable Energy and<br />
Fuels<br />
Extraction and Separation<br />
E. Maginn, W. Henderson, Organizers<br />
P. Wasserscheid, Presiding<br />
2:00 36. Ionic liquids in catalytic conversion<br />
and separation processes for the production<br />
of clean and sustainable fuels.<br />
P. Wasserscheid<br />
2:35 37. Ionic liquids as sustainable solvents<br />
in petrochemicals extraction.<br />
W. Meindersma,F.S.Onink,<br />
A. R. Hansmeier, A. B. de Haan<br />
3:10 38. Developing inexpensive eutectic<br />
ionic liquids for biodiesel synthesis.<br />
H. Zhao, S. Holmes<br />
3:45 Intermission<br />
4:00 39. Towards in situ extraction of biofuels<br />
from fermentations with ionic liquids:<br />
Partitioning and bacterial toxicology.<br />
S. A. Gangu, L. R. Weatherley,<br />
A. M. Scurto<br />
4:20 40. Extraction of lipids and biodiesel<br />
from biomass using co-solvent mixtures<br />
of ionic liquids and polar covalent molecules.<br />
G. Young, M. J. Cooney<br />
4:40 41. Ionic liquid pretreatment of poplar<br />
wood at room temperature: Swelling and<br />
incorporation of nanoparticles. M. Lucas,<br />
B. A. Macdonald, G. L. Wagner,<br />
S. A. Joyce, K. D. Rector<br />
5:00 42. Dissolution of polyaromatics in<br />
ionic liquids. W. Henderson, M. Gebbie<br />
Section C<br />
Renaissance Boston Waterfront<br />
Brewster<br />
Non-thermal Plasma Assisted Fuel<br />
Conversion for Green Chemistry<br />
On-Board Plasma Fuel and Methane<br />
Conversion<br />
A. Gutsol, T. Nozaki, Organizers, Presiding<br />
2:00 43. Plasma reforming of E85 for hydrogen<br />
rich gas production. X. Zhu,<br />
T. Hoang, L. Lobban, R. Mallinson<br />
2:30 44. Single step methane conversion<br />
into liquid oxygenates using multiphase<br />
flow, microplasma reactor. T. Nozaki,<br />
A. Agiral, S. Yuzawa,<br />
H. J. Gardeniers, k. 0kazaki<br />
2:50 45. Oxidation of carbon particle by lattice<br />
oxygen on/in oxide catalyst with an<br />
application of electrical discharge.<br />
Y. Sekine, H. Koyama, M. Matsukata,<br />
E. Kikuchi<br />
3:10 46. Plasma-catalytic hybrid system using<br />
spouted bed with gliding arc discharge.<br />
H. Lee, H. Sekiguchi<br />
3:30 47. Oxidation of methane in a DBD-catalyst<br />
system with rare gas dilution.<br />
A. Janeco, N. Pinhão, A. Ferreira,<br />
J. Branco<br />
3:50 Intermission<br />
4:05 48. Effect of discharge properties on<br />
conversion of methane using pulsed DC<br />
discharge field. M. Okada, R. Hattori,<br />
Y. Kuwayama, S. Furukawa, T. Hiaki<br />
4:25 49. Non thermal plasma reforming of<br />
hydrocarbon fuels with gliding arc discharge.<br />
F. Odeyemi, M. Gallagher,<br />
A. Rabinovich, A. Fridman<br />
4:45 50. Methane conversion to higher hydrocarbons<br />
using warm non-equilibrium<br />
microplasma glow discharge. S. Parimi,<br />
D. Staack<br />
5:05 51. Coke free dry reforming of n-dodecane<br />
by low energy pulsed electric discharge<br />
at low temperature.<br />
Y. Sekine, n. furukawa, M. Matsukata,<br />
E. Kikuchi<br />
5:25 Concluding Remarks<br />
MONDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
Nanotech for Sustainable Energy and Fuels<br />
Energy Storage<br />
C. Liu, F. Besenbacher, U. Burghaus,<br />
Z. Wang, Organizers<br />
E. Kadossov, M. Liu, Presiding<br />
8:30 52. Metal oxide/carbon nanotubes<br />
nano-hybrid materials for energy storage<br />
applications. S. Ma, J. Kim, H. Kim,<br />
H. Choi, K. Kim<br />
8:50 53. High lithiation capacity and rate capability<br />
observed with amorphous MoO 2<br />
electrodes for lithium-ion batteries. S. Oh,<br />
J. Ku, J. Ryu<br />
9:10 54. Virus templated lithium ion battery<br />
materials: New cathodes for higher energy<br />
and capacity. M. A. Allen,<br />
R. Kolesnikov-Lindsey, A. M. Belcher<br />
9:30 55. Defects enhanced Li-ion intercalation<br />
properties in nanostructured electrodes<br />
for lithium ion batteries. D. Liu,<br />
D. Yu, G. Cao<br />
10:05 Intermission<br />
10:15 56. Multiscale synthesis of functional<br />
nanostructured materials for energy applications.<br />
J. Liu<br />
10:50 57. Effect of anion substitution in<br />
metal borohydrides. L. H. Rude,<br />
Y. Filinchuk, M. Sørby, B. Hauback,<br />
T. Jensen<br />
11:10 58. Energy materials under extreme<br />
conditions: Electro-thermo-mechanical<br />
coupling in TEM. R. Shahbazian Yassar,<br />
H. Ghassemi, A. Asthana, Y. K. Yap<br />
11:30 59. Coaxial electrospun PEG/PVDF-<br />
(core/sheath) composite non-woven mats<br />
as energy storage material. J. Park,<br />
T. Nguyen<br />
11:50 60. Catalytic activation of CO 2 into<br />
useful carbonates products over metallic<br />
nanocatalysts supported on metal organic<br />
frameworks. V. Abdelsayed,<br />
Y. Fan, T. Gardner<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom E<br />
Ionic Liquids in Sustainable Energy and<br />
Fuels<br />
Biomass Processing<br />
E. Maginn, Organizer<br />
W. Henderson, Organizer, Presiding<br />
8:30 61. How can we improve the dissolution<br />
and recovery of biopolymers from<br />
biomass in ionic liquids specifically for<br />
biofuels applications? W. Li, N. Sun,<br />
R. D. Rogers<br />
9:05 62. From cellulose to fermentable sugars.<br />
R. Rinaldi, P. Engel, J. Büchs,<br />
A. C. Spiess, F. Schüth<br />
9:25 63. Enzymatic hydrolysis of lignocellulose<br />
in ionic liquid-aqueous systems.<br />
P. W. Wolski, K. Shill, H. W. Blanch,<br />
D. S. Clark<br />
9:45 64. Fermentable sugars by chemical<br />
hydrolysis of biomass in an ionic liquid.<br />
R. T. Raines<br />
10:05 Intermission<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
10:15 65. Application of ionic liquids for the<br />
conversion of cellulosic biomass into usable<br />
fuels. P. C. Trulove, W. M. Reichert,<br />
M. P. Foley, W. B. McIlvaine,<br />
D. W. O’Sullivan, H. C. De Long<br />
10:50 66. Conversion of biomass to fuels in<br />
ionic liquids. A. T. Bell<br />
11:25 67. Glucose activation by transient<br />
CR 2� dimers. E. J. Hensen,E.A.Pidko,<br />
V. Degirmenci<br />
11:45 68. Pretreatment of cellulosic biomass<br />
with ionic liquids for biofuels production.<br />
W. Henderson,E.Brown<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Hydrogen Production and Application<br />
Reforming, WGS, or Gasification<br />
Cosponsored by COMSCI<br />
X. Wang, Organizer<br />
J. Yang, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 69. In-situ studies of active sites and<br />
mechanism for the water-gas shift reaction<br />
on meta/oxide catalysts.<br />
J. A. Rodriguez, J. C. Hanson, P. Liu,<br />
J. Hrbek<br />
9:15 70. Methanol steam reforming over a<br />
stabilized ceria supported PdZn catalyst<br />
for hydrogen production. Q. Zhang,<br />
R. J. Farrauto<br />
9:35 71. Environmentally benign energy<br />
technologies. M. J. Castaldi<br />
10:15 Intermission<br />
10:25 72. Pt-Re interaction in Pt-Re/C catalysts<br />
under hydrothermal environment for<br />
production of hydrogen and biofuels<br />
through aqueous phase reforming.<br />
L. Zhang, A. Karim, G. Xia, Y. Yang,<br />
D. Heldebrant, D. L. King, Y. Wang<br />
11:05 73. Novel Pt/Mg(In)(Al)O catalysts for<br />
alkane dehydrogenation. P. Sun,<br />
G. Siddiqi, A. T. Bell<br />
11:25 74. Power type rate law of propane<br />
ATR over Pt-Ni/Al 2O 3 catalyst.<br />
F. Gökaliler,Z.Önsan, A. Aksoylu<br />
11:45 75. Reaction pathways from CH 4 to<br />
H 2 - UBI-QEP evaluation of transition<br />
metals. B. Enger, R. Lødeng, A. Holmen<br />
MONDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
New Energy Technologies<br />
Solar Cell and Solar Fuels<br />
C. Liu, J. Chen, J. Wang, Organizers<br />
J. Wu, L. Wang, Presiding<br />
1:30 Introductory Remarks<br />
1:35 76. Ultrafast studies of charge carrier<br />
dynamics in novel nanocomposite materials<br />
for solar energy conversion applications.<br />
J. Z. Zhang, J. Hensel<br />
2:05 77. Multiple electron excitations and<br />
transfers in the dyes of coal solar cells.<br />
L. Wang<br />
2:35 78. Designing nanomaterials, devices,<br />
and processings for next generation of<br />
solar cells. Y. Cui<br />
3:05 79. Nanotubes from rutile TiO2 (110)<br />
sheets: Formation and properties.<br />
J. Wang<br />
3:35 Intermission<br />
3:50 80. Optimizing bulk and nanoscale architecture<br />
for improved performance in<br />
semiconducting polymer based photovoltaics.<br />
C. Tassone, A. L. Ayzner, A. Clark,<br />
C. Shi, Y. Rubin, B. Schwartz, S. Tolbert<br />
4:20 81. Leaf-like materials capable of energy<br />
conversion and CO 2 assimilation.<br />
B. Su<br />
4:50 82. Renewable fuel from CO 2 photoreduction<br />
using illuminated monolith reactor.<br />
P. Liou, S. Chen, J. C. Wu, D. Liu,<br />
S. Mackintosh, M. Maroto-Valer,<br />
R. Linforth<br />
5:20 83. Water oxidation by ruthenium complexes<br />
with tris(2-pyridylmethyl)amine derivatives.<br />
X. Zhao, R. Grudzien, J. A. Ivie,<br />
K. R. Ruddick, C. E. Webster<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Hydrogen Production and Application<br />
Reforming and H2 Storage Cosponsored by<br />
COMSCI<br />
X. Wang, Organizer<br />
J. Yang, Organizer, Presiding<br />
1:30 84. Tuning structures and hydrogen<br />
adsorption properties of microporous<br />
metal organicframework (MMOF) materials.<br />
J. Li, H. Wu, Y. Zhao,<br />
M. Padmanabhan<br />
2:10 85. Development of integrated reformer<br />
system for syngas production.<br />
C. Junaedi, S. Vilekar, D. Walsh,<br />
R. Mastanduno, S. Roychoudhury<br />
2:30 86. Steam methane reforming over Ni<br />
and Ni/Ag catalysts: Gaining mechanistic<br />
insight through experiment and computation.<br />
D. W. Blaylock, H. Wang,<br />
A. H. Dam, Y. Zhu, U. Das, W. H. Green,<br />
A. Holmen, D. Chen<br />
2:50 87. Opportunities and challenges of<br />
Li-N based materials for hydrogen fuels.<br />
Y. Hu<br />
3:30 Intermission<br />
3:40 88. Advanced chemical hydrides for<br />
hydrogen storage. J. Holladay,<br />
A. Karkakamkar, D. Neiner, M. Bowden,<br />
D. Heldebrandt, J. Linehan, E. Ronnebro,<br />
C. Sorensen, R. Zheng, D. Matson,<br />
J. Birnbaum, T. Smurthwaite,<br />
D. Camaioni, T. Autrey<br />
4:20 89. Ni-substituted hexaaluminates as<br />
efficient partial oxidation catalysts.<br />
T. H. Gardner, E. Kugler, V. Abdelsayed,<br />
Y. Fan, J. Spivey<br />
4:40 90. Noble-metal based catalysts for<br />
biomass-derived tar cracking and methane<br />
reforming. R. A. Dagle,M.A.Gerber,<br />
Y. Su, M. Flake, D. L. King, J. F. White<br />
5:00 91. Catalytic partial oxidation of methane<br />
on autothermally operated Pt catalysts:<br />
Reaction pathways, zoning effects,<br />
and impact of mass and heat transport.<br />
O. Korup, M. Geske, S. Mavlyankariev,<br />
R. Schlögl, R. Horn<br />
5:20 92. Fundamental understanding of the<br />
role of K on the activity of Pt/CeO 2 catalyst<br />
for hydrogen production from ethanol<br />
and ethylene glycol. Z. He,X.Wang<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom E<br />
Ionic Liquids in Sustainable Energy and<br />
Fuels<br />
Electrochemistry, Energy Storage and<br />
Propulsion<br />
E. Maginn, W. Henderson, Organizers<br />
P. Trulove, Presiding<br />
2:00 93. Imidazole-based ionic liquids for<br />
use in PEMFCs: Proton conductivity<br />
studies. C. Gorman, L. Dyers,<br />
M. Gervais, J. B. Kerr<br />
2:35 94. Simulation study of nanoporous<br />
carbon supercapacitors in a room-temperature<br />
ionic liquid. H. J. Kim,Y.Shim<br />
3:10 95. Ionic liquid-based electrolytes for<br />
lithium batteries: Thermal phase behavior<br />
and ionic interactions. W. Henderson,<br />
Q. Zhou<br />
3:30 96. Thermal and corrosion properties<br />
of nanoparticle enhanced ionic liquids<br />
(NEILs). E. B. Fox, A. E. Visser,<br />
N. J. Bridges, J. R. Gray<br />
3:50 Intermission<br />
4:00 97. Vacuum electrospray ionization of<br />
ionic liquids. Y. Chiu, B. W. Ticknor,<br />
B. D. Prince<br />
4:35 98. Substituting hazardous rocket propellants.<br />
S. Schneider, T. Hawkins,<br />
M. Rosander, Y. Ahmed, J. Mills<br />
5:10 99. AHA! Computational design of<br />
aprotic heterocyclic anions for ionic-liquid-based<br />
CO2 separations.<br />
W. Schneider, E. Mindrup<br />
5:30 100. Dicyanoborate-based ionic liquids<br />
as hypergolic fluids. Y. Zhang,Y.Joo,<br />
J. M. Shreeve<br />
AES Science and Technology<br />
Hydrogen as a Resource Sponsored by<br />
COMSCI, Cosponsored by CATL<br />
(probationary), FUEL, I&EC, INOR, and PMSE<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Advances in Fuel Science and Technology<br />
C. Liu, X. Ma, Organizers<br />
8:00–10:00<br />
101. Advances in polymer electrolyte membranes<br />
reinforced by electrospun nanofiber<br />
porous substrates for fuel cells.<br />
S. Yun, J. Woo, S. Seo, S. Oh, S. Moon<br />
102. Synthesis and characterization of new<br />
biodiesels derived from oils of plants<br />
growing in northern Wisconsin and Minnesota.<br />
J. W. Lane, K. Hukriede,<br />
D. Koirala, D. Levings, A. Stewart,<br />
M. A. Waxman<br />
103. Development of oil recovery methods:<br />
Facing up to the challenge of heavy oil resources.<br />
A. Duan, R. Li, B. Zheng,<br />
A. Duan<br />
104. Heterocyclic based ILs having alkyl hydrazine<br />
tether: Synthesis and physiochemical<br />
properties. Y. O. Ahmed,<br />
S. Schneider, M. Rosander,<br />
T. W. Hawkins<br />
105. Effect of acidity of zeolite on sythesis of<br />
dimethyl carbonate via methyl nitrite.<br />
C. Hao, S. Wang,H.Chen,Y.Ge,Z. Li,<br />
X. Ma<br />
106. Hydrogenation of CO 2 to formic acid on<br />
ruthenium hydroxide catalysts. S. Wang,<br />
C. Hao, M. Li, L. Kang, P. Na, X. Ma<br />
107. Surface-modified polyethylene separators<br />
for lithium-ion polymer battery via<br />
plasma-induced coating process. J. Kim,<br />
D. Lim<br />
108. Plasma modification of polyethylene<br />
separator for lithium-ion battery. G. An,<br />
J. Kim, D. Lim<br />
109. Catalytic behavior of ash derived from<br />
biomass gasification. N. Klinghoffer,<br />
M. J. Castaldi, A. Nzihou<br />
110. Catalyst center at the Advanced Photon<br />
Source beamline 9-BM. T. Bolin<br />
111. Simulating Fischer-Tropsch synthesis<br />
phase behavior in nonconventional reaction<br />
media. N. O. Elbashir<br />
112. Adsorption characteristics of lignosulfonates<br />
on self-assembly multilayers.<br />
Y. Deng, Y. Wu, X. Ouyang, D. Yang,<br />
X. Qiu<br />
113. Prediction of liquid-liquid equilibria of<br />
(ionic liquid � hydrocarbon) systems by<br />
COSMO-RS. A. R. Ferreira, M. G. Freire,<br />
J. G. Crespo, J. A. Coutinho<br />
114. <strong>Chemical</strong> durability studies of imidazoles<br />
and their ionic mixtures (with triflic<br />
acid) under mimic fuel cell conditions.<br />
L. Dyers, M. Gervais, J. B. Kerr<br />
115. Characterization of unsaturated hydrocarbon<br />
content from light and middle petroleum<br />
distillates using desorption electrospray<br />
ionization (DESI) mass<br />
spectrometry. E. Sokol, A. U. Jackson,<br />
T. Shum, R. Cooks<br />
116. Green methods for improving enzymatic<br />
saccharification of plant based biomass<br />
for cellulosic ethanol by using<br />
oxalic acid pretreatments.<br />
D. W. Berke-Schlessel,S.Das,<br />
R. Wexler, Y. Wei<br />
117. Xylose production with Thermobacillus<br />
composti immobilized on a porous gel<br />
carrier. Y. Nakane, K. Watanabe,<br />
K. Nakagawa, T. Sakaguchi<br />
118. Mono- and multilayer surface alloys as<br />
electrocatalysts. X. Yang,J.Fu,<br />
B. E. Koel<br />
119. Adsorption, dissociation of H 2 molecules<br />
on Ni(001) surface of Ni/YSZ slab: A<br />
DFT study. H. Chen,J.Chang,J.Lu<br />
120. Gas phase decomposition of methyl<br />
formate. S. Dooley, T. Farouk, F. L. Dryer<br />
121. Comparison of kinetic pathways in oxidation<br />
of 1,3,5-trimethylbenzene and propylbenzene.<br />
S. Jahangirian, S. Dooley,<br />
F. L. Dryer<br />
122. CO2 sequestration and coal gasification<br />
using the Versatile Atmospheric dielectric<br />
barrier Discharge ExpeRiment (VADER).<br />
M. A. Lindon, E. Scime, D. Shekhawat,<br />
M. Gallagher, D. Berry<br />
123. Green heterogeneous catalytic conversion<br />
of bioethanol into n- and branched<br />
butanol on hydroxyapatites. L. Carreno,<br />
K. P. Ibarra, D. J. Portillo<br />
124. Gas phase decomposition of the most<br />
basic methyl ester, methyl formate.<br />
S. Dooley, T. Farouk, F. Dryer<br />
125. Selective sulfur removal from JP-8 jet<br />
fuel. M. Timko, L. Gonzalez, L. Shafer,<br />
J. Tester, P. Kracke, W. Green<br />
126. Preparation and characterization of a<br />
RuNi catalyst for biomass conversion to<br />
advanced alcohols. L. Song,J.Chen<br />
127. Diffusion coefficient-formula weight<br />
correlation analysis via DOSY NMR to examine<br />
acylglyceride mixtures and biodiesel<br />
production. G. L. Kagan,<br />
A. M. Socha, W. Li, R. Hopson,<br />
J. K. Sello, P. G. Williard<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Chemistry for Energy: Student Posters<br />
C. Burgess, Y. Alvarez Rojas, M. Hill,<br />
Organizers<br />
8:00–10:00<br />
128. In-reactor production of esterified biooil<br />
via methanol injection.<br />
P. Bhattacharya, P. Steele, E. Hassan,<br />
L. Ingram<br />
129. Performance degradation and recovery<br />
effect of direct formic acid fuel cells using<br />
a palladium anode catalyst. S. Baek,<br />
Y. Kwon, J. Han, J. Kim<br />
130. Carbon nanotube supported Pt and<br />
Pt-Co bimetallic catalyst: Structure and<br />
aqueous phase reforming activity.<br />
X. Wang, N. Li, L. D. Pfefferle, G. L. Haller<br />
131. New phosphonic acid based copolymer<br />
membrane for fuel cell applications.<br />
G. J. Schlichting, A. M. Herring<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
C. Liu, Organizer<br />
8:00–10:00<br />
2, 3, 11, 15, 18, 23, 34, 40, 41, 54, 74, 75,<br />
101. See previous listings.<br />
158, 180, 210, 217, 218, 226, 236, 247, 252,<br />
253, 265. See subsequent listings.<br />
General Catalysis Sponsored by CATL<br />
(probationary), Cosponsored by COLL, FUEL,<br />
and PETR<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
FUEL<br />
TECH–55
FUEL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
TUESDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
New Energy Technologies<br />
Catalyst and Nanostructured Materials for<br />
New Energy Applications<br />
C. Liu, J. Chen, J. Wang, Organizers<br />
D. Wang, Y. Hu, Presiding<br />
8:30 132. New nanocatalysts for cleaner energy<br />
provisions. S. Tsang, C. Wu<br />
9:00 133. Nanoengineering catalysts in size,<br />
shape, and composition for fuel cells.<br />
C. Zhong, B. Fang, B. Wanjala,<br />
R. Loukrakpam, J. Yin, J. Luo<br />
9:30 134. Metal-organic frameworks for energy<br />
applications. Y. Hu<br />
10:00 Intermission<br />
10:10 135. Enhancing electrocatalytic activity<br />
by tuning nanoparticle surface structure<br />
and composition. S. Lee, S. Chen,<br />
Y. Shao-Horn<br />
10:40 136. Self-assembled nanostructured<br />
materials for energy storage. D. Wang<br />
11:10 137. Architecture of nanoparticle<br />
structures at nanoscale for energy conversion<br />
applications. C. Wang<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom E<br />
Storch Award: Symposium in Honor of<br />
Chunshan Song<br />
Fuel Science<br />
C. Song, Organizer<br />
H. Schobert, M. Gray, Presiding<br />
8:30 Introductory Remarks<br />
8:35 138. Characteristics of optimal chain<br />
transfer solvents for heavy hydrocarbon<br />
conversion. M. T. Klein, C. LaMarca<br />
9:10 139. Asphaltene reactions and aggregation:<br />
Insights at the molecular level.<br />
M. R. Gray<br />
9:45 140. Conversion of low-rank coals into<br />
upgraded coals and extracts having similar<br />
chemical and physical properties using<br />
degradative solvent extraction.<br />
L. Xian, Y. Hasegawa, M. Moromoto,<br />
R. Ashida, K. Miura<br />
10:20 Intermission<br />
10:35 141. Experimental and theoretical investigations<br />
of the pyrolysis of lignin<br />
model compounds. P. F. Britt,<br />
A. Buchanan, M. K. Kidder, A. Beste,<br />
B. G. Sumpter<br />
11:10 142. Ultra low sulfur fuels: Impacts of<br />
advanced HDS strategies on automotive<br />
emissions, fuel economy, and energy security.<br />
A. L. Boehman<br />
11:45 143. Advanced simulation tools for<br />
accelerating the development, and deployment<br />
of carbon capture technologies.<br />
A. Cugini, M. Syamlal, B. Morreale<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Hydrogen Production and Application<br />
Membrane Technology and H2 Application<br />
Cosponsored by COMSCI<br />
56–TECH<br />
J. Yang, Organizer<br />
X. Wang, Organizer, Presiding<br />
8:30 144. Dry reforming of methane cannot<br />
be used to produce hydrogen.<br />
T. S. Oyama<br />
‡ Cooperative Cosponsorship<br />
9:10 145. Thin-film membranes downstream<br />
to the reactor for novel energy-efficient<br />
processes in H 2 production. G. Centi,<br />
S. Perathoner, S. Abate, G. Iaquaniello<br />
9:30 146. Parameterizations of force constants<br />
in depend on change of induced<br />
local electrostatic field by change of environment<br />
in cluster model and approximate<br />
to bulk model at modeling of ionomer<br />
membrane. F. Keshtova,<br />
S. V. Keshtova<br />
9:50 147. Synthesis and application of micro-mesoporous<br />
material in the catalysts<br />
for the hydrotreating of transport fuels.<br />
Z. Zhao, D. Zhang, Q. Huo, A. Duan,<br />
J. Liu, G. Jiang, H. Pan, T. Dou<br />
10:30 Intermission<br />
10:40 148. Catalysis for the 21st century.<br />
r. J. Farrauto<br />
11:20 149. Use of nuclear energy for future<br />
transportation fuels. J. Herring,<br />
C. Stoots, J. O’Brien<br />
12:00 150. Regenerable adsorbent for liquid<br />
phase JP-8 fuel: A case study of gold/silica<br />
based adsorbent at room temperature.<br />
D. T. Tran, Z. W. Dunbar, D. Chu<br />
Section D<br />
Renaissance Boston Waterfront<br />
Caspian<br />
Fuel Cell Chemistry and Operation II<br />
Membranes Cosponsored by CATL<br />
(probationary)<br />
S. Hamrock, Organizer<br />
A. Herring, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 151. FTIR study of perfluorinated ionomer<br />
membranes and model compounds.<br />
S. Schlick, L. Lin, M. Danilczuk,<br />
S. J. Hamrock, M. S. Schaberg<br />
9:00 152. Polystyrene-based superacidic<br />
fluoroalkyl sulfonated ionomers for fuel<br />
cell applications. Y. Chang,<br />
L. V. Brownell, T. Jo, C. Bae<br />
9:25 153. Hybrid inorganic/polymer ionomers<br />
for low RH fuel cell operation.<br />
A. M. Herring, J. L. Horan, M. Kuo,<br />
G. J. Schlichting, Z. Ziegler, F. Zhang,<br />
J. Jessop, S. Nelson<br />
9:50 154. Molecular dynamics simulation<br />
study of hydrated sulfonated poly (ether<br />
ether ketone) for application to polymer<br />
electrolyte membrane fuel cells in comparison<br />
with sulfonated polystyrene.<br />
G. F. Brunello, B. Watson, J. Fuller,<br />
S. Lee, S. Jang<br />
10:15 Intermission<br />
10:25 155. Inorganic sol-gel modified solution<br />
cast Nafion ® membranes for optimum<br />
performance and durability in fuel<br />
cells. S. Kulkarni, K. Mauritz<br />
10:50 156. Selective transport properties<br />
and water binding in proton exchange<br />
membranes. H. Xie, T. Saito, K. Xu,<br />
Q. Wang, M. A. Hickner<br />
11:15 157. Broadband dielectric spectroscopy<br />
studies of instrument - in situ annealed<br />
poly (2,5- benzimidazole) membrane<br />
materials. A. Nalawade,<br />
M. K. Hassan, K. A. Mauritz, M. H. Litt<br />
11:40 158. Design of triazole bearing sol-gel<br />
membranes as water free proton exchange<br />
membranes for hydrogen fuel<br />
cells, effect of crosslink density, and heterocycle<br />
content on membrane performance.<br />
S. Granados-Focil,<br />
J. R. Conway, Y. Meng, L. Smith<br />
Surface Science of Catalysis Sponsored by<br />
CATL (probationary), Cosponsored by COLL,<br />
FUEL, and PETR<br />
TUESDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
New Energy Technologies<br />
Catalyst and Nanostructured Materials for<br />
New Energy Applications<br />
C. Liu, J. Chen, J. Wang, Organizers<br />
C. Sykes, Q. Ge, Presiding<br />
1:30 159. Tungsten carbides as alternative<br />
electrocatalysts: From surface science<br />
studies to fuel cell evaluation. J. G. Chen<br />
2:00 160. Catalyzing the catalyst: Hydrogen<br />
dissociation and spillover on individual<br />
isolated palladium atoms. H. Tierney,<br />
A. Baber, J. Kitchin, C. Sykes<br />
2:30 161. Understanding and designing hydrogen<br />
storage materials based on first<br />
principle computational analysis. Q. Ge<br />
3:00 162. Thermally reversible hydrino catalyst<br />
systems as a new power source.<br />
R. Mills, G. Zhao, K. Akhtar, Z. Chang,<br />
J. He, X. Hu, G. Wu, J. Lotoski, G. Chu<br />
3:30 Intermission<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom E<br />
Storch Award: Symposium in Honor of<br />
Chunshan Song<br />
Future Fuels and CO2 C. Song, Organizer<br />
C. Burgess, S. Oyama, Presiding<br />
1:30 Introductory Remarks<br />
1:35 163. Development of coal-based jet<br />
fuel: From JP-900 to JP-8 and Jet-A.<br />
H. Schobert<br />
2:10 164. From catalytic coal liquefaction to<br />
CO 2 capture and conversion towards fuels<br />
of the future. C. Song<br />
3:00 Intermission<br />
3:20 165. Discovery of the benefits produced<br />
when carbon dioxide is used in<br />
chemical, biological or technological applications.<br />
M. Aresta<br />
3:55 166. Development of highly functional<br />
TiO2 thin film materials by a RF magnetron<br />
sputtering method and their applications<br />
in the production of H2 from H2O<br />
and dye-sensitizer-free thin film solar<br />
cells. M. Anpo<br />
4:30 167. Mesoporous carbon and carbonbased<br />
nanocomposites as catalyst support<br />
for celluose conversion into polyols.<br />
A. Wang, Y. Zhang, J. Xu, J. Pang,<br />
M. Zheng, Y. Huang, T. Zhang<br />
Section C<br />
Renaissance Boston Waterfront<br />
Atlantic Ballroom 2/3<br />
Hydrogen Production and Application<br />
Biological and Solar Methods Cosponsored<br />
by COMSCI<br />
J. Yang, Organizer<br />
X. Wang, Organizer, Presiding<br />
1:30 168. Hydrogen production in Clostridium<br />
thermocellum via dark fermentation<br />
of lignocellulosic biomass. J. Jo,<br />
L. Magnusson, S. Thammannagowda,<br />
G. Pennington, P. Maness<br />
2:10 169. Synthesis and characterizaton of<br />
silver gallium selenide thin film for photoelectrochemical<br />
application. L. Chen,<br />
H. Tang, S. Shet, H. Wang, Y. Yan,<br />
J. Turner, M. Al-Jassim<br />
2:30 170. Photocatalytic hydrogen generation<br />
through water splitting on nano-crystalline<br />
LaFeO 3 perovskite. S. N. Tijare,<br />
M. M. Joshi, S. S. Rayalu,<br />
N. K. Labhasetwar<br />
2:50 171. Visible light induced photoreduction<br />
of water by N- doped mesoporous titania.<br />
M. M. Joshi, P. A. Mangrulkar,<br />
S. N. Tijare, S. Metkar, N. K. Labhsetwar,<br />
S. S. Rayalu<br />
3:10 172. Photoproduction of H 2 from water<br />
and biowastes using titania-based catalysts.<br />
G. Centi, R. Passalacqua,<br />
P. Fornasiero, C. Ampelli, S. Perathoner<br />
3:30 Intermission<br />
3:40 173. Photosynthetic hydrogen production<br />
from water splitting in the model organism<br />
Chlamydomonas reinhardtii.<br />
P. King, K. Ratcliff, M. Ghirardi<br />
4:20 174. Nano cobalt oxide for photocatalytic<br />
hydrogen production.<br />
P. A. Mangrulkar,M.V.Joshi,<br />
N. K. Labhsetwar, V. Polshettiwar,<br />
S. S. Rayalu<br />
4:40 175. Cadmium stannates as model<br />
photocatalytic systems for water decomposition<br />
and pollution abatement.<br />
B. Viswanathan, R. Viswanath,<br />
T. varadarajan, G. Magesh<br />
5:00 176. Effect of borate in photocatalysis.<br />
L. Gongxuan, J. Zhiliang<br />
5:20 177. Dissociation of H 2S in low current<br />
gliding arc tornado discharge.<br />
T. P. Nunnally, K. Gutsol, A. Rabinovich,<br />
A. Fridman, A. Starikovskii, A. Gutsol,<br />
A. Kemoun<br />
Section D<br />
Renaissance Boston Waterfront<br />
Caspian<br />
Fuel Cell Chemistry and Operation II<br />
Membranes and Fuel Cell Operation<br />
A. Herring, Organizer<br />
S. Hamrock, Organizer, Presiding<br />
1:30 178. New fuel cell membrane development<br />
at 3M. M. Schaberg, J. Abulu,<br />
M. Emery, G. Haugen, P. Xiong,<br />
S. Hamrock<br />
1:55 179. Thin film quartenary ammonium<br />
and phosphonium based anion exchange<br />
membranes. C. Arges, S. Kulkarni,<br />
A. Baranek, K. Pan, M. Jung, D. Patton,<br />
K. Mauritz, V. Ramani<br />
2:20 180. Anion exchange membranes<br />
based on highly fluorinated poly (arylene<br />
ether). J. Yan,B.L.Chaloux,<br />
M. A. Hickner<br />
2:45 181. Durability studies on performance<br />
degradation of catalysts and Nafion®<br />
membrane in direct methanol fuel cells.<br />
D. Kumari, E. S. Smotkin, C. Grice<br />
3:10 Intermission<br />
3:30 182. Perfluorocyclobutyl (PFCB) polymers<br />
for proton exchange membrane fuel<br />
cell (PEMFC) applications. G. D. Kalaw,<br />
J. N. Wahome, K. J. Balkus,<br />
I. H. Musselman, D. Yang, J. P. Ferraris<br />
3:55 183. RoleofCeO 2 addition to TiO 2based<br />
adsorbent in adsorptive desulfurization:<br />
A DFT study. J. Guo, S. Watanabe,<br />
M. Janik, C. Song<br />
4:20 184. Synthesis and comparative electrocatalytic<br />
study of Pt 3Ni nanoctahedra<br />
and nanocubes. J. Zhang, H. Yang,<br />
S. Zou, J. Fang<br />
4:45 185. Characterization of flow-through<br />
microbial fuel cells. S. Higgins,<br />
S. Minteer, M. Cooney<br />
5:10 186. Diesel fuel desulfurization for use<br />
in fuel cells. A. Jayaraman, G. Alptekin,<br />
J. Monroe, M. Dubovik<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
New Energy Technologies<br />
Solar Cell and Solar Fuels<br />
C. Liu, J. Chen, J. Wang, Organizers<br />
G. Lu, J. Wang, Presiding<br />
3:50 187. Roles of nanocavities and alternate<br />
structures structural on TiO2 nanoribbon<br />
for visible-light induced photocatalytic<br />
H2 evolution. G. Lu<br />
4:20 188. Improving bulk heterojunction solar<br />
cells through controlling their nanostructure.<br />
N. C. Cates, G. F. Burkhard,<br />
R. Gysel, Z. Beiley, E. T. Hoke,<br />
S. R. Scully, C. E. Miller, M. F. Toney,<br />
M. Heeney, I. McCulloch,<br />
M. D. McGehee<br />
4:50 189. Artificial photosynthesis by bacteria-templated<br />
micro/nanostructures.<br />
T. Fan, H. Zhou, D. Zhang<br />
5:20 190. I-Doped titanium dioxide nanocrystalline<br />
films: Preparation, characterization,<br />
and application for dye sensitized<br />
solar cells. Q. Hou, X. Tao, J. Chen<br />
WEDNESDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
New Energy Technologies<br />
Catalysis and Biomass Conversion<br />
C. Liu, J. Chen, J. Wang, Organizers<br />
J. Wang, M. Maroto Valer, Presiding<br />
8:30 191. Reliable fabrication of highly b-oriented<br />
pure silica and hetero-atom MFI<br />
zeolite membranes for ethanol recovery<br />
from dilute aqueous solution. L. Lang,<br />
X. Liu, X. Liu, B. Zhang<br />
9:00 192. Novel catalytic methods for the<br />
conversion of methane and biomass to<br />
alternative energy sources. K. Yoo,<br />
P. Pullanikat, J. Lee, J. Olsen, R. Giles,<br />
K. Jung<br />
9:30 193. Novel pH-swing process using<br />
ammonium salts for CO 2 mineralization.<br />
M. Maroto-Valer,X.Wang<br />
10:00 194. Catalysis of lignin depolymerization<br />
in ionic liquids. S. Jia, B. Cox,<br />
X. Guo, Z. Zhang, J. Ekerdt<br />
10:30 Intermission<br />
10:40 195. Second generation biodiesel:<br />
From cellulose to 5-HMF derivates.<br />
G. Centi, S. Perathoner, P. Lanzafame,<br />
D. Temi, A. Macario, G. Giordano<br />
11:10 196. Catalytic active sites for H 2 production<br />
from bio-alcohols over transition<br />
metal oxide nanoparticles. Z. He,<br />
X. Wang<br />
11:40 197. Direct catalytic conversion of<br />
biomass into glycols using tungstenbased<br />
catalysts. A. Wang, M. Zheng,<br />
N. Ji, Y. Zhang, Y. Huang, T. Zhang<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom E<br />
Storch Award: Symposium in Honor of<br />
Chunshan Song<br />
Catalytic Fuel Processing<br />
C. Song, Organizer<br />
J. Miller, M. Klein, Presiding<br />
8:30 Introductory Remarks<br />
8:35 198. Hydrotreating catalysis: Structure<br />
sensitivity and inhibition effects.<br />
H. Topsøe<br />
9:10 199. Active phase of a nickel phosphide<br />
(Ni 2P) catalyst supported on KUSY<br />
zeolite for the hydrodesulfurization of 4,6-<br />
DMDBT. T. S. Oyama,Y.Lee,<br />
K. Asakura, K. K. Bando, Y. Yoshimura<br />
9:45 200. Hydrodesulfurization performance<br />
of transition metal phosphides prepared<br />
by hydrogen plasma reduction. M. Qin,<br />
Z. Wang, Y. Wang, X. Li, A. Wang,Y.Hu<br />
10:20 Intermission<br />
10:35 201. Catalysis for hydrogen production<br />
and fuel cell applications.<br />
R. J. Farrauto<br />
11:10 202. Distillate-fuel desulfurization and<br />
reforming for SOFC and HTPEM fuel<br />
cells: From science to system integration.<br />
M. Namazian<br />
11:45 203. Using in-situ Fe and Mn K-edge<br />
XANES to study a Mn-promoted Fe/Cu/<br />
SiO 2 catalyst during H 2 reduction and<br />
during the Fischer-Tropsch synthesis.<br />
A. Campos, N. Lohitharn, A. Roy,<br />
J. Goodwin, Jr., J. Spivey<br />
Section C<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
Coal-, Gas-, Biomass- and Waste-to-<br />
Liquids Conversion<br />
A. De Klerk, D. King, Organizers, Presiding<br />
8:30 Introductory Remarks<br />
8:35 204. Catalytic conversion of small oxygenates<br />
from bio-oil to alkylaromatics on<br />
zeolites. D. E. Resasco,X.Zhu,<br />
L. L. Lobban, R. G. Mallinson, T. Hoang<br />
9:10 205. Optimization of zeolites for pyrolytic<br />
conversion of glucose to aromatic<br />
hydrocarbons. A. J. Foster, J. Jae,<br />
G. W. Huber, R. F. Lobo<br />
9:30 206. Examination of hydrothermal lignin<br />
conversion using carbon monoxide.<br />
M. Hill Bembenic, C. Burgess Clifford<br />
9:50 207. Preliminary study of methyl<br />
okeate’s oxidation (biodiesel) in a tubular<br />
reactor. M. Lu,M.Chai<br />
10:10 Intermission<br />
10:25 208. Indirect liquefaction carbon efficiency.<br />
A. de Klerk<br />
10:45 209. Supercritical deoxygenation of<br />
model bio-oil oxygenates. J. W. Ford,<br />
H. Wan, R. V. Chaudhari,<br />
B. Subramaniam<br />
11:05 210. Hydrodeoxygenation of glycerol<br />
into bio-crude. M. Tymchyshyn,<br />
A. Parmar, C. C. Xu<br />
11:25 211. Impact of solvent type and conditions<br />
on the yields and compositions of<br />
oils from thermolytic extraction of biomass.<br />
C. E. Snape,H.Deng,<br />
W. Meredith, C. Uguna<br />
11:45 212. Production of upgraded biofuels:<br />
HDO of phenol over Ni-W/C catalysts.<br />
S. Echeandia Medina,<br />
P. L. Arias Ergueta, B. T. Pawelec,<br />
J. L. Garcia Fierro<br />
Section D<br />
Renaissance Boston Waterfront<br />
Caspian<br />
Chemistry, Production, and Use of Green<br />
Fuels<br />
Chemistry and Use of Green Fuels<br />
S. Minteer, M. Cooney, Organizers,<br />
Presiding<br />
9:00 Introductory Remarks<br />
9:05 213. Synthesis and characterization of<br />
multiblock hydrophobic partially fluorinated<br />
(polyarylene ether ketone) -hydrophilic<br />
(disulfonated polyarylene ether sulfone)<br />
copolymers for proton exchange<br />
membranes. Y. Chen, C. Lee, O. Lane,<br />
J. E. McGrath<br />
9:25 214. Developing a complete oxidation<br />
direct electron transfer glucose biofuel<br />
cell. S. Xu, S. Minteer<br />
9:45 215. Fuel cells that use mitochondria<br />
as energy conversion matrices to generate<br />
electricity from biofuels.<br />
R. Arechederra, S. D. Minteer<br />
10:05 216. GM’s powertrain diversity strategy.<br />
L. Bednarova<br />
10:25 Intermission<br />
10:40 217. Bimettalic - doped ZnO sorbents<br />
for simultaneous H 2S removal and COS<br />
hydrolysis from reformate streams.<br />
P. P. Dhage, A. Samokhvalov,<br />
B. J. Tatarchuk, D. Repala<br />
11:00 218. Alkane-capped aluminum nanoparticles.<br />
S. W. Buckner, P. A. Jelliss,<br />
D. W. Hammerstroem, C. E. Bunker,<br />
E. A. Guliants, S. E. Hayes, K. M. Wentz<br />
11:20 219. Reaction mechanisms without<br />
borders: Combustion of the butanol isomers<br />
from ��0.25 to ���. M. R. Harper,<br />
K. M. Van Geem, G. B. Marin,<br />
W. H. Green<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
New Energy Technologies<br />
Biofuel, CO2 and Resources<br />
J. Chen, J. Wang, Organizers<br />
Y. Wang, Presiding<br />
C. Liu, Organizer, Presiding<br />
1:30 220. One step conversion of bio-ethanoltoisobuteneonZn<br />
xZr yO z mixed oxides<br />
with balanced acid-base pairs.<br />
J. Sun, K. Zhu, L. Zhang, J. Liu, Y. Wang<br />
2:00 221. Green process for dimethyl carbonate<br />
synthesis starting from carbon dioxide.<br />
L. He, Z. Yang, A. Liu, J. Gao,<br />
S. Chanfreau<br />
2:30 222. Synthesis of nanoscale HZSM-5<br />
zeolite and its application in alkylation,<br />
dehydration of bio-ethanol and upgrading<br />
of FCC gasoline. X. Guo, H. Long,<br />
Y. Zhao, X. Cheng, L. Sun, J. Bi, X. Wang<br />
3:00 223. Alternative approach to synthesizing<br />
highly active desulfurization catalysts.<br />
Q. Guan, W. Li<br />
3:30 Intermission<br />
3:45 224. Upgrading and refining of Canadian<br />
bitumen and heavy oil. J. Chen,<br />
E. Little<br />
4:15 225. Hydrothermal conversion of biomass<br />
and carbon dioxide into chemicals<br />
and fuels: A potentially useful technology<br />
for improving global carbon cycle by<br />
mimicking nature. F. Jin,Z.Huo,J.Cao,<br />
B. Wu, H. Enomoto<br />
4:45 226. Simultaneous reclamation of derelict<br />
acid mine drainage land and sustainable<br />
energy production using switchgrass.<br />
D. M. Kargbo,S.Al-Abed<br />
5:15 227. Effect of ethanol/water blend fumigated<br />
on combustion process of diesel<br />
engine. C. Yao, X. Chen, Q. Xia, X. Yang,<br />
L. Wei, J. Liu, Y. Xu<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom E<br />
Storch Award: Symposium in Honor of<br />
Chunshan Song <strong>Chemical</strong>s, Fuels and<br />
Materials<br />
C. Song, Organizer<br />
C. Marshall, J. Spivey, Presiding<br />
1:30 Introductory Remarks<br />
1:35 228. Molecular design and commercial<br />
application of highly selective zeolite catalysts<br />
for alkylaromatics production.<br />
T. F. Degnan,J.S.Beck<br />
2:10 229. Sustainable catalysis for fuels and<br />
chemicals with gas-expanded liquids.<br />
B. Subramaniam<br />
2:45 230. Influence of size and adsorbates<br />
on the L 3,L 2 and L 1 xanes of Pt catalysts.<br />
J. T. Miller, Y. Lei, J. Jelic, H. Liang,<br />
S. Linic, R. Meyer<br />
3:20 Intermission<br />
3:35 231. Biomass to fuels: A European perspective.<br />
A. Sanna, L. Porcu,<br />
J. M. Andresen<br />
4:10 232. Chemistry of carbonaceous mesophase<br />
development and petroleum<br />
coke texture. S. Eser, G. Wang,<br />
R. T. Wincek<br />
4:45 233. Selective catalytic production of<br />
clean hydrocarbon fuels from fossil and<br />
non-fossil resources by removing sulfur<br />
compounds. K. Sakanishi<br />
5:20 234. Shape-selective methylation of aromatics<br />
for environmentally friendly synthesis<br />
of specialty chemicals over zeolite<br />
catalysts. X. Guo, C. Zhang, Y. Zhao,<br />
A. Zhang, M. Liu, X. Wang, C. Song<br />
5:55 Concluding Remarks<br />
Section C<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
Coal-, Gas-, Biomass- and Waste-to-<br />
Liquids Conversion<br />
A. De Klerk, D. King, Organizers, Presiding<br />
1:30 235. Hydrocracking different Fischer-<br />
Tropsch waxes: Model simulations.<br />
C. Gambaro,V.Calemma<br />
1:50 236. Oligomerization of light olefin to<br />
produce jet fuel. J. Zhu,S.K.Saha,<br />
X. Ma, C. Song<br />
2:10 237. Improving the utility of large-scale<br />
coal molecular models by simplifying the<br />
view: 3D models to reactive lattice grids.<br />
Y. E. Alvarez, J. K. Watson,<br />
J. P. Mathews<br />
2:30 238. Evaluating matrix effects on trace<br />
element partitioning during coal combustion<br />
using novel in situ/direct method.<br />
A. A. Raeva, E. I. Kozliak, D. T. Pierce,<br />
W. S. Seames<br />
2:50 239. S-XANES analysis of sulfur forms<br />
in Argonne Premium Coals. T. Bolin<br />
3:10 240. Hexadecane hydrotreating as a<br />
surrogate for Fischer-Tropsch upgrading<br />
to aviation fuel using a Co/MoO 3/silicaalumina<br />
catalyst. H. J. Robota, J. Jones,<br />
A. Stewart, M. Luo<br />
3:30 Intermission<br />
3:45 241. Sequential combination of organic<br />
acid and base treatments for converting<br />
lignocellulosic biomass and cellulose.<br />
Y. Noda, U. Wongsiriwan,<br />
P. Prasassarakich, Y. Yeboah, C. Song<br />
4:05 242. Catalytic conversions of biomassderived<br />
polyols to value added chemicals<br />
and fuels. A. Rahman<br />
4:25 243. Transforming municipal solid<br />
waste (MSW) into fuel via the gasification/<br />
pyrolysis process. E. Kwon,<br />
M. J. Castaldi<br />
4:45 244. DFT evaluation of sodium effects<br />
on the gasification mechanisms of carbonaceous<br />
materials with carbon dioxide.<br />
J. F. Espinal, L. A. Calderón,<br />
F. Mondragón<br />
5:05 245. Gasification of salmon wastes and<br />
small diameter alder. J. A. Soria,<br />
S. Freitas<br />
Section D<br />
Renaissance Boston Waterfront<br />
Caspian<br />
Chemistry, Production, and Use of Green<br />
Fuels<br />
Production of Green Fuels<br />
S. Minteer, M. Cooney, Organizers,<br />
Presiding<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
FUEL<br />
TECH–57
FUEL/GEOC <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
1:30 246. Biofuels and products from microalgae<br />
and seaweeds. F. B. Metting,<br />
M. Huesemann, G. Roesjadi,<br />
J. Benemann<br />
2:05 247. Bio-oil from microalgae: Review of<br />
existing methods, challenges, milestones<br />
and governmental role needed to develop<br />
algal biofuels. R. Pate, G. Young,<br />
M. J. Cooney<br />
2:25 248. Comparison of hydroprocessed<br />
bio-oil gasoline, diesel and jet fuel fractions<br />
characteristics to ASTM standards<br />
for drop-in fuels. P. H. Steele,<br />
S. K. Gajjela, E. M. Hassan<br />
2:45 249. Lifecycle energy and carbon footrpint<br />
for an algae-based ethanol production<br />
process. Z. Hu, D. Luo, D. Choi,<br />
V. M. Thomas, M. Realff, R. Chance<br />
3:05 250. Maximizing the yield of biodiesel<br />
from waste cooking oil hydroprocessing<br />
by cut-point optimization. D. Karonis,<br />
S. Bezergianni, D. Chilari, E. Kelesidis<br />
3:25 Intermission<br />
3:35 251. Combined anaerobic-aerobic digestion<br />
of wastewater on biocarbons as<br />
immobilization material. M. J. Cooney,<br />
M. J. Antal<br />
3:55 252. Ab initio study of polypyrrole<br />
doped with sulfonated ions for pervaporation<br />
of ethanol-water mixtures.<br />
A. L. Botelho,X.Lin<br />
4:15 253. Cloning, expression, and characterization<br />
of the sucrose synthesizing asf<br />
gene product from Synechococcus elongatus<br />
PCC 7942. R. J. Turner,<br />
V. Sershon, J. Aikens<br />
4:35 254. Jet fuel from biologically-derived<br />
triacylglycerol oils. D. Derr<br />
4:55 255. Using gold catalysts for upgrading<br />
glycerol from biodiesel production: Selective<br />
oxidation and synthesis of glycerol<br />
carbonate. J. A. Lopez-Sanchez,<br />
N. Dimitratos, C. Hammond,<br />
M. Ab Rahim, J. M. Anthonykutty,<br />
A. F. Carley, R. C. Tiruvalam, C. J. Kiely,<br />
D. W. Knight, G. J. Hutchings<br />
5:15 Concluding Remarks<br />
THURSDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom D<br />
Heavy Hydrocarbon Resources:<br />
Characterization Upgrading and Utilization<br />
O. Koseoglu, D. Espinat, A. Al Hajji,<br />
Organizers, Presiding<br />
8:25 Introductory Remarks<br />
8:30 256. Petroleomics: Composition/structure<br />
relation to properties/performance of<br />
petroleum and its fractions. C. Hsu,<br />
R. Rodgers, A. McKenna, A. Marshall<br />
9:10 257. Structural characterization and<br />
quantitative analysis of petroleum macromolecules.<br />
W. A. Burgess,<br />
S. U. Kulkarni,M.C.Thies<br />
9:30 258. Continuum of petroleum composition<br />
and its implication for asphaltene<br />
composition examined by FT-ICR mass<br />
spectrometry. A. M. McKenna,<br />
R. P. Rodgers, W. K. Robbins, C. S. Hsu,<br />
M. Mapolelo, B. Ehrmann, A. G. Marshall<br />
9:50 259. Insight into asphaltene nano-aggregate<br />
structure inferred by small angle<br />
neutron and X-ray scattering.<br />
J. Eyssautier, P. Levitz, D. Espinat,<br />
J. Jestin, J. Gummel, I. Grillo, L. Barré<br />
10:10 260. Study of catalyst-coke recycle<br />
during bitumen hydroconversion in a<br />
semi-batch, slurry-phase reactor.<br />
H. Rezaei, S. Jooya Ardakani, K. J. Smith<br />
10:30 Intermission<br />
10:40 261. Compositional analysis of unprocesses<br />
and processed heavy oils with<br />
high resolution mass spectrometry.<br />
H. Wang, S. C. Houdek, D. B. Galloway,<br />
G. Yokomizo<br />
58–TECH<br />
‡ Cooperative Cosponsorship<br />
11:00 262. Analytics driving kinetics: Thermochemical<br />
conversion of heavy petroleum<br />
fractions. S. P. Pyl,<br />
K. M. Van Geem, M. Reyniers,<br />
G. B. Marin<br />
11:20 263. Characterization of asphaltenes<br />
and petroleum by mass spectrometry.<br />
A. E. Pomerantz, O. C. Mullins,<br />
M. R. Gray, R. N. Zare<br />
11:40 264. Supercritical water mediated upgrading<br />
of heavy oil. K. Choi<br />
12:00 265. Three-tier methodology for<br />
quantification and characterization of<br />
naphthenic acids in aqueous solutions.<br />
U. Tezel, T. Misiti, D. Bostwick,<br />
C. Sullards, S. Pavlostathis<br />
Section C<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
Coal-, Gas-, Biomass- and Waste-to-<br />
Liquids Conversion<br />
A. De Klerk, Organizer<br />
D. King, Organizer, Presiding<br />
8:30 266. Hydrocracking of Fischer-Tropsch<br />
wax: Effect of feed composition.<br />
V. Calemma,C.Gambaro<br />
9:05 267. Kinetics study of Fischer-Tropsch<br />
synthesis over a 15%Co/Al2O3 catalyst.<br />
W. MA, G. Jacobs, D. Sparks, C. Yen,<br />
J. Klettlinger, T. Tomsik, B. Davis<br />
9:25 268. Preparing low temperature iron<br />
Fischer-Tropsch catalysts: Strategies that<br />
work and those that do not.<br />
P. J. Pretorius<br />
9:45 269. Fischer-Tropsch synthesis over<br />
promoted Mo carbide catalysts: Time-onstream<br />
behaviour. D. N. Vo, T. Nguyen,<br />
A. A. Adesina<br />
10:05 Intermission<br />
10:20 270. What can vanadium chemistry<br />
teach us about Fischer-Tropsch synthesis?<br />
G. Beran,Y.Luo<br />
10:40 271. Deutero-1-pentene tracer studies<br />
for iron and cobalt Fischer-Tropsch<br />
synthesis. M. Gnanamani,R.A.Keogh,<br />
W. D. Shafer, B. H. Davis<br />
11:00 272. Mixed metal xerogels and aerogels<br />
for Fischer-Tropsch synthesis of alternative<br />
fuels. S. Bali, E. L. Moulding,<br />
G. S. Bali, F. E. Huggins, G. P. Huffman,<br />
R. D. Ernst, R. J. Pugmire, E. M. Eyring<br />
11:20 273. Electrical capacitance tomography<br />
(ECT) study of carbon monoxide hydrogenation<br />
in a slurry reactor.<br />
B. Abdullah, C. Dave, C. G. Cooper,<br />
T. Nguyen, A. A. Adesina<br />
Catalyst for Energy Storage Sponsored by<br />
CATL (probationary), Cosponsored by FUEL<br />
and PETR<br />
GEOC<br />
Division of Geochemistry<br />
J. Brandes, Program Chair<br />
SOCIAL EVENTS:<br />
Social Hour, 5:00 PM: Mon<br />
SUNDAY MORNING<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Surface Characterization Techniques and<br />
Surface-Involved Reactions Sponsored by<br />
ENVR, Cosponsored by COLL and GEOC<br />
SUNDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Mediterranean<br />
Geochemistry of Soils and Sediments<br />
J. Brandes, Organizer, Presiding<br />
1:00 Introductory Remarks<br />
1:05 1. Systematic characterization of soil<br />
and sediment organic matter using advanced<br />
solid-state nuclear magnetic resonance.<br />
J. Mao<br />
1:25 2. Quantitative determination of oil and<br />
water saturation in porous media using<br />
NMR chemical shift imaging. Y. Zhao<br />
1:45 3. Role of hematite in carbon sequestration<br />
conditions. R. T. Murphy,<br />
K. Lammers, A. Smirnov,<br />
M. A. Schoonen, D. R. Strongin<br />
2:05 4. Coal mine refuse stabilization using<br />
an alkaline clay by-product.<br />
T. E. Kovalchuk, J. Fu, D. Fulmer,<br />
P. Koranchie-Boah<br />
2:25 5. Statistical exploration of reservoir<br />
sediment chemistry. P. Waldo<br />
2:45 6. Geochemical controls and grainscale<br />
modeling of U(VI) mass-transfer in<br />
the Hanford 300-Area Aquifer.<br />
D. L. Stoliker, D. B. Kent, J. Yin,<br />
R. Haggerty, M. B. Hay, J. A. Davis,<br />
J. M. Zachara<br />
3:05 Intermission<br />
3:15 7. Withdrawn<br />
3:35 8. Estimation of formation constants of<br />
metal complexes: Bidentate binding to<br />
oxygen and nitrogen donor atoms.<br />
R. F. Carbonaro, Y. B. Atalay,<br />
D. M. Di Toro<br />
3:55 9. In situ ATR-FTIR, XAS, and quantum<br />
chemical study of chromate bonding<br />
mechanisms on goethite.<br />
C. P. Johnston, M. Chrysochoou<br />
4:15 10. Selective uptake and allocation of<br />
elements for shoot and grain of paddy in<br />
plain of Eastern China. X. Yuan,J.Li,<br />
M. Ge<br />
4:35 11. <strong>Chemical</strong> and geochemical similarities<br />
and differences between Re and Tc:<br />
The specific case of reduction and incorporation<br />
into goethite. N. P. Qafoku,<br />
W. Um, S. C. Smith, R. Serne,<br />
J. M. Westsik<br />
4:55 12. Adsorption of nitrate on kaolinite<br />
surfaces: A theoretical study. L. Tribe,<br />
J. D. Kubicki<br />
5:15 13. Reduction of nitrite and nitrate on<br />
iron sulfide mineral surfaces: Implications<br />
for the origin of life. S. Singireddy,<br />
A. D. Gordon, A. Smirnov, D. R. Strongin,<br />
M. A. Schoonen<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Metals and Metal Oxides Sponsored by<br />
ENVR, Cosponsored by COLL and GEOC<br />
MONDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Mediterranean<br />
General Geochemistry Papers<br />
J. Brandes, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 14. Measurement of pore structure and<br />
fluid flow in porous media by MRI.<br />
L. Jiang<br />
8:25 15. Molecular dynamics investigation<br />
of MgO-CaO-SiO2 melts: Influence of<br />
pressure and composition on density and<br />
transport properties. L. Zhang,<br />
J. Van Orman, D. Lacks<br />
8:45 16. CO 2 sequestration through mineral<br />
carbonation of iron oxyhydroxides.<br />
K. Lammers, D. R. Strongin,<br />
A. Riendeau, R. Murphy, A. Smirnov,<br />
M. A. Schoonen<br />
9:05 17. Management of ORP and pH for in<br />
situ remediation of arsenic in groundwater.<br />
M. F. de Flaun,W.D.Brady,<br />
B. L. Petty, H. B. Kerfoot<br />
9:25 18. Studying the interactions of trivalent<br />
metal ions with the silica/water interface<br />
using second harmonic generation.<br />
D. S. Jordan, J. N. Malin, F. M. Geiger<br />
9:45 Intermission<br />
10:00 19. Study on variation of fluoride concentration<br />
in shallow and deep aquifers.<br />
A. Tewari<br />
10:20 20. Aluminum-induced calcium deficiency<br />
syndrome in a spruce-pine forest<br />
in NW Russia. W. C. Shortle,K.T.Smith,<br />
G. B. Lawrence<br />
10:40 21. Surfactant-aided mobilization of<br />
contaminants in soil: Toward a realistic<br />
approach. M. Hernandez-Soriano,<br />
A. Pena, M. Mingorance<br />
11:00 22. Comparing carbon dioxide solubility<br />
models for the suitability for use in<br />
carbon sequestration resource estimates.<br />
A. K. Karamalidis, D. Allen, A. Goodman,<br />
J. Hakala<br />
11:20 23. Study on variation in anion concentration<br />
and nitrogen and oxygen stable<br />
isotope ratio regarding intense rain fall<br />
in Singapore. H. Katsura,M.Yoh,<br />
K. Koba, R. Balasubramanian, J. He<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes<br />
Sorption Processes: From Treatment to<br />
Fate and Transport Sponsored by ENVR,<br />
Cosponsored by COLL and GEOC<br />
MONDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Mediterranean<br />
General Geochemistry Papers<br />
J. Brandes, Organizer, Presiding<br />
1:00 24. Insight into chemical structures and<br />
potential sources of marine and coastal<br />
dissolved organic matter by advanced<br />
solid-state NMR. J. Mao, X. Kong,<br />
K. Schmidt-Rohr, E. Perdue<br />
1:20 25. Examination of the factors controlling<br />
mercury methylation in coastal marine<br />
ecosystems. R. P. Mason,<br />
T. A. Hollweg, C. C. Gilmour<br />
1:40 26. Plankton propagation possibly contributed<br />
by natural diffusion from subterranean<br />
offshore petroleum deposits.<br />
S. Mori<br />
2:00 27. New global contamination derived<br />
from debris plastics. K. Saido, H. Sato,<br />
A. Okabe, Y. Kodera, S. Chung, O. Abe,<br />
N. Ogawa, K. Amamiya, T. Kusui<br />
2:20 28. Fluxes of soot black carbon to<br />
South Atlantic sediments. K. Pohl,<br />
J. Sullivan, R. Lohmann, K. Bollinger,<br />
M. Cantwell, J. Feichter, I. Fischer-Bruns,<br />
M. Zabel<br />
2:40 29. Burning earth: Evaluation of 750 o C<br />
temperatures in an active landslide.<br />
H. B. Kerfoot, K. H. Kondru, S. Siciliano,<br />
E. D. Smalstig<br />
Undergraduate Research Posters<br />
Geochemistry Sponsored by CHED,<br />
Cosponsored by GEOC and SOCED<br />
WEDNESDAY MORNING<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy<br />
Probing Black Carbon Structure, Reactivity,<br />
and Sorptivity Sponsored by ENVR,<br />
Cosponsored by GEOC<br />
WEDNESDAY AFTERNOON<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy<br />
Probing Black Carbon Structure, Reactivity,<br />
and Sorptivity Sponsored by ENVR,<br />
Cosponsored by GEOC<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
WEDNESDAY EVENING<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy Sponsored<br />
by ENVR, Cosponsored by GEOC<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes Sponsored by<br />
ENVR, Cosponsored by COLL and GEOC<br />
THURSDAY MORNING<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy<br />
Utilization of Black Carbon Products in<br />
Agriculture, Environmental Remediation,<br />
and Other Applications Sponsored by ENVR,<br />
Cosponsored by GEOC<br />
THURSDAY AFTERNOON<br />
Black Carbon as Geosorbent and Beyond:<br />
Contaminant Sorption, Soil Fertilization,<br />
and Carbon-Negative Strategy<br />
Fate and Function of Black Carbon in Soil<br />
and Sediment Sponsored by ENVR,<br />
Cosponsored by GEOC<br />
HIST<br />
Division of the History of<br />
Chemistry<br />
S. C. Rasmussen, Program Chair<br />
SUNDAY AFTERNOON<br />
Section A<br />
Seaport Hotel<br />
Flagship Room A<br />
General Papers<br />
S. C. Rasmussen, Organizer, Presiding<br />
1:30 1. On the trail of a Thomas Thomson<br />
work published in Philadelphia.<br />
B. Charton, B. N. Charton<br />
2:00 2. Charles Darwin and chemistry.<br />
M. D. Saltzman<br />
2:30 3. Dawn of biological activity prediction.<br />
M. Charton<br />
3:00 Intermission<br />
3:15 4. Did John Frederick William Herschel<br />
discover molecular chirality before Louis<br />
Pasteur? J. Gal<br />
3:45 5. Robert L. Alldredge, chemical engineer,<br />
inventor, entrepreneur, developer of<br />
Octolig®. D. F. Martin<br />
4:15 6. Hydrogen to Copernicium: An elemental<br />
history of the periodic table.<br />
D. Rabinovich<br />
MONDAY MORNING<br />
Section A<br />
Seaport Hotel<br />
Constitution Room<br />
Anna Jane Harrison: ACS President, Her<br />
Science and Her Legacy Cosponsored by<br />
WCC<br />
J. Hayes, Organizer, Presiding<br />
8:15 Introductory Remarks<br />
8:25 7. Anna J. Harrison: Teacher and<br />
leader. L. P. Eubanks<br />
8:55 8. Anna Jane Harrison at Mount<br />
Holyoke College. M. Campbell<br />
9:25 9. From toxic smoke to the structure<br />
and reactions of organic compounds: The<br />
chemical research of Anna Jane Harrison.<br />
J. M. Hayes<br />
9:55 Intermission<br />
10:15 10. Anna Jane Harrison: First woman<br />
elected as ACS President. H. M. Free,<br />
J. M. Hayes<br />
10:45 11. Anna Jane Harrison: Policy leader.<br />
M. L. Good, M. A. Cavanaugh<br />
11:15 12. Anna Jane Harrison from afar.<br />
M. F. Singleton<br />
11:45 Panel Discussion<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Seaport Hotel<br />
Constitution Room<br />
Classic Books in Chemistry VII: Physical<br />
Chemistry Books from New England<br />
Financially supported by Bolton <strong>Society</strong><br />
N. Heindel, Organizer<br />
G. Patterson, Organizer, Presiding<br />
1:30 13. Physical chemistry before Ostwald:<br />
The textbooks of Josiah Parsons Cooke.<br />
W. B. Jensen<br />
2:10 14. Henry Adams and the application<br />
of thermodynamics to history.<br />
R. A. Egolf, P. A. Khoury<br />
2:40 15. Measures of the spread: The influence<br />
of statistics on J. Willard Gibbs and<br />
the influence of Gibbs on statistics.<br />
C. Cobb<br />
3:10 Intermission<br />
3:30 16. Richards the First. P. J. Karol<br />
4:00 17. “<strong>Chemical</strong> Thermodynamics”, by<br />
Kirkwood and Oppenheim. T. Keyes<br />
4:30 18. MIT and the physical chemistry laboratory:<br />
Charles Kraus and “The Properties<br />
of Electrically Conducting Systems”.<br />
G. D. Patterson<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
S. C. Rasmussen, Organizer<br />
8:00–10:00<br />
14. See previous listings.<br />
THURSDAY MORNING<br />
Busted: Myths of a <strong>Chemical</strong> Nature<br />
Sponsored by CHED, Cosponsored by HIST<br />
I&EC<br />
Division of Industrial and<br />
Engineering Chemistry<br />
J. T. Ciszewski, Program Chair<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
Green Synthesis and Materials Processing<br />
using Tunable Fluids Financially supported<br />
by Novel Chemistry with Industrial<br />
Applications subdivision of I&EC<br />
C. Kitchens, C. Roberts, Organizers,<br />
Presiding<br />
8:00 Introductory Remarks<br />
8:05 1. Supercritical carbon dioxide expanded<br />
polymerization of methyl methacrylate.<br />
J. Li, J. El Harfi, S. M. Howdle,<br />
D. J. Irvine<br />
8:25 2. Microwave-assisted polymerization<br />
of �-caprolactone using stannous 2-ethylhexanoate<br />
and purposely added alcohol.<br />
N. T. Nguyen, M. J. Kamaruddin,<br />
S. M. Howdle, S. W. Kingman,<br />
J. P. Robinson, D. J. Irvine<br />
8:45 3. Designer reversible ionic liquids for<br />
CO2 capture. R. Jha, A. Fadhel,<br />
V. Blasucci, R. Hart, P. Pollet, C. L. Liotta,<br />
C. A. Eckert<br />
9:05 4. Combining homogeneous reactions<br />
with heterogeneous separations for hydroformylation<br />
reactions using tunable<br />
solvents. A. Z. Fadhel,J.Ford,<br />
V. Llopis-Mestre, P. Pollet, C. L. Liotta,<br />
C. A. Eckert<br />
9:25 Intermission<br />
9:40 5. Precipitation and fractionation of<br />
nanoparticles using gas-expanded mixtures<br />
as tunable solvents.<br />
S. R. Saunders, C. B. Roberts<br />
10:00 6. Immobilized nanoparticle coatings<br />
deposited via gas-expanded liquids for<br />
improved microtribology control.<br />
K. M. Hurst, N. Ansari, C. B. Roberts,<br />
W. Ashurst<br />
10:20 7. Small angle neutron scattering of<br />
alkanethiol stabilized nanoparticles in gas<br />
expanded liquids. G. V. White,<br />
C. L. Kitchens<br />
10:40 8. Reversible reactions of CO2 with<br />
amino-terminated SAM’s employing a<br />
protection/deprotection mechanism for<br />
smart surfaces. F. Mohammed,<br />
C. L. Kitchens<br />
11:00 Concluding Remarks<br />
Ionic Liquids in Sustainable Energy and<br />
Fuels<br />
CO2 Capture, Gas Absorption and<br />
Separations Sponsored by FUEL,<br />
Cosponsored by I&EC<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
Green Chemistry for Drugs that Make a<br />
Difference Financially supported by Green<br />
Chemistry Engineering subdivision of I&EC<br />
J. Manley, D. Hughes, Organizers,<br />
Presiding<br />
1:00 Introductory Remarks<br />
1:05 9. How green chemistry can contribute<br />
to pharmaceutical industry sustainability:<br />
Accomplishments and opportunites.<br />
B. W. Cue<br />
1:25 10. Laropiprant (Tredaptive): Development<br />
toward an efficient and green<br />
manufacturing process. G. R. Humphrey<br />
1:45 11. Green biocatalytic chemistry for<br />
drug manufacture. J. Grate<br />
2:05 Intermission<br />
2:20 12. Greening up the Grignard reaction<br />
in the pharmaceutical industry: Development<br />
of continuous stirred tank reactor<br />
(CSTR) processes. M. E. Kopach,<br />
J. Groh McClary, M. D. Johnson<br />
2:40 13. Enabling green chemistry through<br />
process research: Development of large<br />
scale process for a LFA-1 inhibitor.<br />
D. Krishnamurthy, X. Wang, R. Frutos,<br />
L. Nummy, T. Wirth, L. Zhang, Y. Xu,<br />
X. Sun, D. Reeves, C. H. Senanayake<br />
3:00 14. Pharmaceutical green chemistry at<br />
Amgen. J. L. Tucker<br />
3:20 Concluding Remarks<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
Hydrocarbons from Biomass (HyBi):<br />
Emerging Research Financially supported by<br />
National Science Foundation<br />
S. Morton, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 15. Hydrocarbons from biomassemerging<br />
frontier programs funded by the<br />
National Science Foundation. G. J. Antos<br />
9:00 16. EFRI-HyBi: Algal oils to “drop-in”<br />
replacements for petroleum transportation<br />
fuels. H. H. Lamb, J. Burkholder,<br />
W. L. Roberts, H. W. Sederoff,<br />
L. F. Strikeleather<br />
9:35 17. Bioengineering a system for the direct<br />
production of biological hydrocarbons<br />
for biofuels. J. V. Shanks,<br />
B. J. Nikolau, T. A. Bobik, G. S. Nadathur,<br />
G. V. Wolfe<br />
10:10 18. Autothermal conversion of biomass<br />
compounds to transportation fuels<br />
using multifunctional stratified reactors.<br />
M. Skinner, A. Bhan, L. Schmidt,<br />
M. Tsapatsis<br />
10:45 19. Fungal processes for direct bioconversion<br />
of cellulose to hydrocarbons.<br />
B. A. Peyton, N. D. Mallette,<br />
R. P. Carlson<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
Hydrocarbons from Biomass (HyBi):<br />
Emerging Research Financially supported by<br />
National Science Foundation<br />
S. Morton, Organizer, Presiding<br />
GEOC/HIST/I&EC<br />
1:00 20. Maximizing conversion of biomass<br />
carbon to liquid fuel. F. H. Ribeiro,<br />
M. M. Abu-Omar, R. Agrawal,<br />
N. C. Carpita, W. Delgass, M. C. McCann<br />
1:35 21. Lignin deconstruction for the production<br />
of liquid fuels. R. Andrews,<br />
M. Crocker, S. DeBolt, M. Meier,<br />
S. A. Morton<br />
2:10 22. Hydrothermal liquefaction of microalgae<br />
to make crude bio-oils.<br />
P. Savage<br />
2:45 23. Green aromatics by catalytic fast<br />
pyrolysis of lignocellulosic biomass.<br />
G. W. Huber, J. Cho, T. Carlson,<br />
R. Coolman, V. Agarwal, S. Almalkie,<br />
Y. Lin, S. Auerbach, S. de Bruyn Kops,<br />
T. J. Mountziaris, W. C. Conner,<br />
J. M. Davis, P. Dauenhauer<br />
3:20 Moderator’s Remarks<br />
3:25 24. Biodiesel production potential of algal<br />
lipids extracted with supercritical carbon<br />
dioxide. L. Soh, J. Zimmerman<br />
3:50 25. Intrinsic kinetics and heats of reactions<br />
for cellulose pyrolysis and char formation.<br />
J. Cho, Y. Lin, J. M. Davis,<br />
G. W. Huber<br />
AES Science and Technology<br />
Hydrogen as a Resource Sponsored by<br />
COMSCI, Cosponsored by CATL<br />
(probationary), FUEL, I&EC, INOR, and PMSE<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–59
I&EC/INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
Fragrance Design: A Creative Challenge<br />
Cosponsored by CTA ‡ , and WCC ‡<br />
Financially supported by Applied <strong>Chemical</strong><br />
Technology subdivision of I&EC<br />
M. Moore, Organizer, Presiding<br />
1:00 26. Fragrance design: A creative challenge.<br />
M. Papas, J. Conlon<br />
TUESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
General Posters<br />
J. T. Ciszewski, Organizer<br />
7:00–9:00<br />
27. Improvement of device performance on<br />
membrane dialysis with ultrafiltration operation.<br />
C. Ho,J.Tu<br />
28. Novel triazine phosphonates derivatives<br />
as economic flame retardant for cotton.<br />
T. Duong Nguyen, S. Chang, B. Condon,<br />
E. Graves, J. Smith<br />
29. Kinetic study of synthesizing 1-(3-phenylpropyl)-pyrrolidine-2,5-dione<br />
under<br />
solid-liquid phase transfer catalytic condition<br />
assisted by microwave irradiation.<br />
M. Wang,C.Chen<br />
30. Pyrolysis characteristics and gasification<br />
of pine and oak trees in a fluidized bed<br />
reactor. S. Kim, Y. Park, J. Kim, W. Cho,<br />
Y. Baek<br />
31. Effect of operational parameters on fast<br />
pyrolysis of palm kernel cake using fluidized<br />
bed reactor. T. Ngo, Y. Seo,J.Kim,<br />
S. Kim<br />
32. Bio-oil and bio-char production from<br />
palm by-products in a fluidized bed reactor.<br />
Y. Park,T.Ngo,J.Kim,S. Kim<br />
33. Synthesis, characterization and photocatalytic<br />
activity of doped TiO 2 under visible<br />
light. J. Virkutyte,R.S.Varma<br />
34. Model-based optimization of preparative<br />
batch HPLC for pharmaceutical development.<br />
N. de Mas, O. K. Lyngberg,<br />
G. Stroehlein, D. C. Chen<br />
35. Numerical investigation of the gas production<br />
behavior of natural gas hydrates<br />
in porous sediments. X. Ruan, Y. Song,<br />
H. Liang<br />
36. Methoxycarbonylation of aliphatic diamines<br />
promoted by in situ generated hydroxide<br />
ion. D. Kim, Y. Shim, D. Nguyen,<br />
H. Kim, M. Cheong<br />
37. Preparation and characterization of mesoporous<br />
ceria-based catalysts for the<br />
production of propylene from CO 2 and<br />
propane. J. Baek,N.Kim,Y.Choi,J.Yi<br />
38. Combustion characteristics of biomass<br />
wastes in a bubbling fluidized bed reactor.<br />
K. Yoo, M. Jang, s. Park, S. Kim,<br />
J. Jung<br />
39. Optimization of operating Parameters of<br />
the hybrid SNCR-SCR process in a pilot<br />
scale flow reactor. S. Kim, K. Yoo,<br />
M. Jang, s. Park, W. Eom<br />
40. Ionic liquid as extractant for the separation<br />
of aromatic compounds and aliphatic<br />
hydrocarbons. D. Kim,H.Kim,<br />
M. Cheong, J. Kim, B. Ahn<br />
41. Zinc naphthenate effects evaluation over<br />
epoxy-based systems applied on insulation<br />
composites. C. S. Goncalves,<br />
T. Koreeda, A. D. Polo<br />
42. Scale up of a continuous pharmaceutical<br />
process. W. R. Perrault, D. J. Knoechel,<br />
D. Erdman, A. Fabian, R. Jackson,<br />
J. Deering, T. Fox, S. Mancini,<br />
E. K. Moreno, C. Rossman<br />
60–TECH<br />
‡ Cooperative Cosponsorship<br />
43. Potentials for utilizing the solubility parameters<br />
in the design of single and<br />
mixed solvents for recycling used lubricating<br />
oils. N. O. Elbashir<br />
44. Removal of sulfur compounds from solvent<br />
extracts of low rank coal. K. Yi,<br />
I. Kim, C. Ko, S. Han, J. Kim<br />
45. Determination of UV filters contained in<br />
sunscreen cosmetic products by highperformance<br />
liquid chromatography.<br />
Y. Zuo, Y. Yang<br />
46. Removal of sulfones in commercial and<br />
model diesel by silica adsorbents: Effect<br />
of oxidant concentration and side products.<br />
C. Ko, S. Han, S. Lim, J. Park,<br />
J. Kim, J. Ryu, Y. Chu, Y. Kim, S. Park,<br />
K. Yi, J. Park, J. Kim<br />
47. Automatic DockOmatic: Ligand and receptor<br />
screening made easy.<br />
R. B. Jacob, C. Bullock<br />
48. Development of environmentally friendly<br />
organometallic catalysis for drug discovery.<br />
N. Hoshiya, S. Shuto, M. Arisawa<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
Applied Metal Ion Separation Chemistry<br />
Financially supported by Separation Science<br />
and Technology subdivision of I&EC<br />
G. Fugate, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 49. New approach for third phase investigation.<br />
M. Borkowski<br />
8:30 50. Novel use of ESI-IM-TOFMS for the<br />
analysis of inorganic uranyl compounds.<br />
H. H. Hill, Jr., C. L. Crawford,<br />
G. A. Fugate, P. R. Cable-Dunlap,<br />
N. A. Wall<br />
8:55 51. Understanding the electrochemical<br />
behavior of actinides to aid in their separation.<br />
A. E. Visser, N. J. Bridges<br />
9:20 Intermission<br />
9:40 52. Separations using inorganic and<br />
hybrid ion-exchange materials.<br />
D. T. Hobbs, K. M. Taylor-Pashow,<br />
M. C. Elvington, M. D. Nyman,<br />
A. Clearfield, J. Burns<br />
10:05 53. Understanding the role of kinetics<br />
in f element solvent extraction systems.<br />
L. R. Martin, P. R. Zalupski,<br />
R. D. Tillotson<br />
10:30 End of Session Remarks<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
Applied Metal Ion Separation Chemistry<br />
Financially supported by Separation Science<br />
and Technology subdivision of I&EC<br />
G. Fugate, Organizer, Presiding<br />
1:00 Start of Session Remarks<br />
1:05 54. Role of the kinetics of lanthanide<br />
aminopolycarboxylate complexation in<br />
lanthanide/actinide separations.<br />
K. L. Nash, A. Martin, T. Shehee<br />
1:25 55. Toward a better understanding of<br />
the role of lactic acid in the TALSPEAK<br />
process. C. Marie, K. L. Nash, K. Uruga,<br />
T. S. Grimes<br />
1:45 Intermission<br />
2:00 56. Recent advances in extraction<br />
chromatography for separation of actinides<br />
and lanthanides. J. Sulakova,<br />
J. Braley, K. L. Nash<br />
2:20 57. Contributing to the recent discussions<br />
of the fundamentals of TALSPEAK<br />
chemistry. P. Zalupski, L. Martin<br />
2:40 Concluding Remarks<br />
THURSDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
General Papers<br />
J. T. Ciszewski, Organizer, Presiding<br />
8:00 Introductory Remarks<br />
8:05 58. Poisoning of mixed matrix membranes<br />
for fuel ethanol production from<br />
fermentation broths. R. D. Offeman,<br />
C. N. Ludvik<br />
8:25 59. Synthesis of novel flame retardant<br />
organophosphorus compounds for the<br />
application to cotton textile.<br />
M. Yoshioka-Tarver,M.W.Easson,<br />
B. D. Condon<br />
8:45 60. Multiple linear regression analysis<br />
of NOx and PM10 emissions from plasma<br />
cutting operations. R. U. Edgehill<br />
9:05 61. Comparison of post-stress responses<br />
of various porous carbon electrodes<br />
in supercapacitors. G. Gourdin,<br />
T. Jiang, P. Smith, D. Qu<br />
9:25 Intermission<br />
9:45 62. Survivability of Bacillus anthracis<br />
(Sterne strain) in processed liquid eggs.<br />
S. A. Khan, K. Sung, M. S. Nawaz,<br />
C. E. Cerniglia, M. L. Tamplin,<br />
R. W. Phillips, L. C. Kelley<br />
10:05 63. Microwave-assisted polymerization<br />
of �-Caprolactone using Stannous<br />
2-Ethylhexanoate and purposely added<br />
alcohol. N. T. Nguyen, M. J. Kamaruddin,<br />
S. M. Howdle, S. W. Kingman,<br />
J. P. Robinson, D. J. Irvine<br />
10:25 64. Withdrawn<br />
THURSDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 160B<br />
General Papers<br />
J. T. Ciszewski, Organizer, Presiding<br />
1:00 Introductory Remarks<br />
1:05 65. Toward zero emission of sulfur species:<br />
Using alumina nanofiber-based adsorbent<br />
for Claus tail gas processing.<br />
P. D. Clark, R. Sui<br />
1:25 66. Green synthesis of highly crystalline<br />
and visible-light sensitive C-, N- and Scodoped<br />
with Ag TiO 2 nanocatalysts.<br />
J. Virkutyte,R.S.Varma<br />
1:45 67. FCC selectivity studied in lab-scale<br />
units and pilot plants. G. M. Bollas,<br />
D. Orlicki, H. Ma<br />
2:05 Intermission<br />
2:25 68. Nanosized Ti doped �-Fe 2O 3:A<br />
novel magnetic sorbent for the removal of<br />
gaseous elemental mercury from flue gas.<br />
S. Yang, N. Yan,H.He,D.Wu,Q.Zhou<br />
2:45 69. Direct synthesis of hydrogen peroxide<br />
based on microreactor technology.<br />
T. Inoue, K. Ohtaki, Y. Kikutani, K. Sato,<br />
M. Nishioka, S. Hamakawa, K. Mawatari,<br />
A. Hibara, F. Mizukami, T. Kitamori<br />
3:05 70. DSC-like thermal analysis of large<br />
(gram-sized) materials used in processing,<br />
agriculture, building and food industries.<br />
P. Ralbovsky, J. L. Ralbovsky<br />
3:25 71. Hydrothermal synthesis of construction<br />
materials from river sediment<br />
and loess. Z. Jing, F. Jin, L. Lu, X. Pan,<br />
H. Ishida<br />
INOR<br />
Division of Inorganic<br />
Chemistry<br />
B. Donovan-Merkert and<br />
M. Millar, Program Chairs<br />
SUNDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Organometallic Chemistry Catalysis<br />
N. Radu, Organizer<br />
O. Ozerov, Presiding<br />
8:30 1. Competitive C-H/C-O oxidative addition<br />
reactions at pincer-supported Rh<br />
centers and implications for catalysis.<br />
O. V. Ozerov, Y. Zhu, D. E. Herbert<br />
8:50 2. Catalytic carbene transfer reactions<br />
with iridium(III) porphyrins. B. J. Anding,<br />
L. K. Woo<br />
9:10 3. Comparison of the reactivities of a<br />
terminal alkene and an internal alkyne in<br />
platinum-catalyzed hydrosilylation reactions.<br />
M. K. Kolel-Veetil, T. M. Keller<br />
9:30 4. Catalytic H/D exchange and acetoxylation<br />
of aromatic compounds using<br />
novel Pt and Pd complexes.<br />
M. H. Emmert,M.S.Sanford<br />
9:50 5. Factors affecting the oxidative addition<br />
of N-H and C-H bonds to iridium<br />
complexes. D. Y. Wang, Y. Choliy,<br />
K. Krogh-Jespersen, J. F. Hartwig,<br />
A. S. Goldman<br />
10:10 6. Study of ethylene hydrophenylation<br />
catalyzed by cationic Pt(II) complexes.<br />
T. B. Gunnoe, B. A. McKeown,<br />
M. R. Friedfeld, T. R. Cundari, M. Sabat<br />
10:30 Intermission<br />
10:35 7. Electrophilic Ir(III) catalyzed 1,2-hydride<br />
shift/Friedel-Crafts alkylation sequence<br />
of heteroaryl enones. T. Vaidya,<br />
A. J. Frontier, R. Eisenberg<br />
10:55 8. Are formyl complexes intermediates<br />
in CO2 reduction catalysis? A computational<br />
and experimental study.<br />
J. G. Andino,M.Baik<br />
11:15 9. Oxidative addition of sp 3 -C-F and<br />
sp 3 -C-O bonds by pincer-ligated iridium<br />
complexes. J. Choi, T. J. Emge,<br />
K. Krogh-Jespersen, A. S. Goldman<br />
11:35 10. Insights into the iridium-catalyzed<br />
water oxidation mechanism from a DFT<br />
study. D. Balcells, O. Eisenstein,<br />
R. H. Crabtree, A. Lledos<br />
11:55 11. Metal oxo complexes for the catalytic<br />
activation of syn gas. E. A. Ison,<br />
J. L. Smeltz, P. D. Boyle<br />
12:15 12. Experimental and theoretical studies<br />
on the mechanism of hydrogenation<br />
by � 6 -arene �-diketiminato -ruthenium<br />
and -osmium complexes. A. D. Phillips,<br />
D. Schreiber, P. J. Dyson<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Coordination Chemistry<br />
Characterization and Applications<br />
D. Crans, Organizer<br />
M. Guo, Presiding<br />
8:30 13. Fe 8-based contrast agents for MRI:<br />
Targeting ovarian cancer cells.<br />
K. A. Parga, I. Chakraborty, R. G. Raptis<br />
8:50 14. Synthetic strategies for the development<br />
of novel Pt anticancer compounds.<br />
J. J. Wilson, J. Fedoce Lopes,<br />
S. J. Lippard<br />
9:10 15. Cobalt(III)-cyclophosphate complexes<br />
in aqueous solutions. M. Montag,<br />
C. R. Clough, P. Mueller, C. C. Cummins<br />
9:30 16. Insights into the interaction of thiolate-bound<br />
Zn 2� with nitric oxide and Snitrosothiols.<br />
J. Kozhukh, S. J. Lippard<br />
9:50 17. Rhodamine B lactam-based sensors<br />
for detecting biologically important<br />
zinc ions. P. Du, S. J. Lippard<br />
10:10 18. Mystery behind monomeric<br />
square-planar cobalt(II) acetylacetonate.<br />
E. V. Dikarev, J. Yang, V. D. Vreshch,<br />
A. S. Filatov, H. Zhang<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
10:30 19. Studies on biologically important<br />
binary complexes in solution: The systems<br />
beryllium (II) and cobalt (II)- homoserine.<br />
B. B. Tewari, B. B. Tewari<br />
10:50 20. Zn(II) and Cu(II) detection with<br />
simple Schiff base systems. S. Khatua,<br />
J. Kang, K. Kim, H. Park, D. G. Churchill<br />
11:10 21. Development of triggereable chelating<br />
agents as probes for metal-induced<br />
oxidative stress. L. M. Hyman,<br />
K. J. Franz<br />
11:30 22. Further studies of bis(carboxylato)<br />
platinum(IV) compounds: Correlation between,<br />
liphoilicity, reduction potential,<br />
cellular accumulation and cytotoxicity.<br />
M. R. Reithofer, A. Bytzek,<br />
S. M. Valiahdi, C. R. Kowol, M. Groessl,<br />
M. Galanski, C. G. Hartinger,<br />
M. A. Jakupec, B. K. Keppler<br />
11:50 23. Anti-Fenton chemistry and detecting<br />
oxidative stress induced by metal and<br />
H 2O 2 in living cells. Y. Wei, Y. Zhang,<br />
Z. Liu, M. Guo<br />
12:30 24. Access to well-defined Ru(I) and<br />
Os(I) metalloradicals. A. Takaoka,<br />
L. C. Gerber, J. C. Peters<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
General Inorganic Chemistry<br />
B. Donovan-Merkert, Organizer<br />
F. Beckford, Presiding<br />
8:30 25. Single-walled metal–organic nanotubes.<br />
K. Lu, H. Wu, Y. Jao, T. Tseng,<br />
S. Peng<br />
8:50 26. Magnificent FOX-7 can be tamed.<br />
S. Garg, H. Gao, B. Twamley,<br />
J. M. Shreeve<br />
9:10 27. Investigations of transition metalthiosemicarbazone<br />
complexes as medicinal<br />
agents. F. Beckford<br />
9:30 28. Mechanistic studies on the inhibition<br />
of enzymes and zinc finger transcription<br />
factors with cobalt(III) Schiff base<br />
complexes. T. A. Atesin,T.J.Meade<br />
9:50 29. Common fixatives used in the preservation<br />
of biological tissues.<br />
S. S. Mantravadi<br />
10:10 30. Copper cross-linked palindromic<br />
bipyridine substituted artificial tripeptides<br />
and the effects of anions on structure.<br />
J. A. Gallagher, L. A. Levine,<br />
M. E. Williams*<br />
10:30 31. Aminoethylglycine-modified ruthenium<br />
complexes: Scaffolds for photocatalysts.<br />
C. P. Myers, M. E. Williams*<br />
10:50 32. Duplex formation of ligand substituted<br />
aminoethylglycine di- and tri-peptides<br />
with Cu �2 . M. B. Coppock,<br />
J. Miller, M. E. Williams*<br />
11:10 33. Photophysical properties, DNA<br />
photocleavage, and photocytotoxicity of<br />
a series of dppn dirhodium (II,II) complexes.<br />
L. E. Joyce, J. Aguirre,<br />
A. M. Angeles-Boza, A. Chouai,<br />
P. K. Fu-Giles, K. R. Dunbar, C. Turro<br />
11:30 34. Photodynamic therapy for skin<br />
carcinomas. R. A. Khanke,P.K.Fu<br />
11:50 35. Impact of triarylboron on the luminescence<br />
of Pt(II) acetylides: Enhanced<br />
phosphorescence and chemical sensing.<br />
C. Sun, Z. M. Hudson, S. Wang<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Chemistry of Materials<br />
Structure and Properties<br />
B. Donovan-Merkert, D. Nelson,<br />
Organizers<br />
P. Dinolfo, Presiding<br />
8:30 36. Studying protein-inorganic nanoparticle<br />
interactions in ferritin model systems.<br />
L. Zhang, D. Liu, J. Cheung-Lau,<br />
J. Swift, C. Butts, I. J. Dmochowski<br />
8:50 37. Perfluorographane: Synthesis and<br />
measurement of electrical and mechanical<br />
properties. J. S. Burgess,<br />
J. T. Robinson, M. Zalalutdinov,<br />
K. Perkins, P. Campbell, E. S. Snow,<br />
B. H. Houston, J. W. Baldwin<br />
9:10 38. Layer-by-layer formation of molecular<br />
multilayers using “click” chemistry:<br />
Synthetic versatility and thin-film characterization.<br />
P. H. Dinolfo, P. K. Palomaki,<br />
A. Krawicz<br />
9:30 39. Synthesis, electronic structure, and<br />
alignment of graphene thin films. V. Lee,<br />
R. V. Dennis, C. Jaye, D. A. Fischer,<br />
S. Banerjee<br />
9:50 40. Synthesis, reaction, characterization,<br />
and properties of high density energetic<br />
alkoxynitroiminotetrazoles. Y. Joo,<br />
J. M. Shreeve<br />
10:10 41. Microemulsion strategy for the<br />
synthesis of nano-LiFePO 4/C composites.<br />
S. Jheng, J. R. Carey, J. Chen<br />
10:30 Intermission<br />
10:50 42. Theoretical studies and investigations<br />
of a proposed new allotrope of carbon.<br />
P. J. Bonk<br />
11:10 43. High power oscillating thermoelectric<br />
waves from exothermic reactions<br />
around nanoscale thermal conduits.<br />
M. S. Strano, J. T. Abrahamson,<br />
W. Choi, J. Han, K. Kalantar-zadeh<br />
11:30 44. Electrostatic charging of fumed<br />
silica particles: Effect of surface treatment<br />
with alkylfluorosilanes. J. Liu,<br />
J. K. Floess, H. Tu, D. Fomitchev<br />
11:50 45. Catalytic activity of aggregated<br />
gold nanoparticles upon irradiation of<br />
light. J. Kim, B. W. Lavin<br />
12:10 46. <strong>Chemical</strong> processing of ferroelectric<br />
nanostructures with variable architectural<br />
complexity. G. Caruntu,<br />
S. Adireddy, A. Yourdkhani, C. Lin<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Properties and Applications<br />
S. Wong, Organizer<br />
D. Dudis, Presiding<br />
8:30 47. Dynamic thin film fabrication of Palladium<br />
nanomaterials for application in<br />
hydrogen gas sensing. J. Zou, S. Iyer,<br />
C. Raston<br />
8:50 48. Graphene and nanowire transistors<br />
for cellular interfaces and electrical recording.<br />
T. Cohen-Karni, Q. Qing,<br />
L. Qiang, Y. Fang, C. M. Lieber<br />
9:10 49. Size-dependant magnetism in lanthanide<br />
chalcogenide nanomaterials.<br />
W. L. Boncher, S. L. Stoll<br />
9:30 50. Energy generation in carbon nanotube<br />
induced by the chemical reaction:<br />
Thermopower waves. W. Choi,S.Hong,<br />
J. Abrahamson, J. Han, C. Song, N. Nair,<br />
S. Baik, M. Strano<br />
9:50 51. Fullerene-based Superatom thermoelectric<br />
materials. D. S. Dudis,<br />
M. Check, H. A. Seibel, J. B. Ferguson,<br />
B. Elliott, J. Gengler, M. Leamy<br />
10:20 Intermission<br />
10:40 52. Effect of surfactant and surfactant<br />
content on electrical conductivity of single<br />
walled carbon nanotubes thin films.<br />
J. Hahn<br />
11:10 53. Novel, lanthanide-based nanoparticles<br />
for NIR to UV energy conversion.<br />
J. A. Ayres, I. N. Stanton, M. J. Therien<br />
11:30 54. Engineering nanoparticle catalysis<br />
via a multimetallic core/shell structure.<br />
V. Mazumder,S.Sun<br />
11:50 55. Withdrawn<br />
12:10 56. Enhanced solar energy conversion<br />
at quantum dot sensitized TiO 2 photonic<br />
crystals and disordered films by slow<br />
light effects. M. El Harakeh, S. Bayram,<br />
S. Jaber, L. Halaoui<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Organometallic Chemistry<br />
Applications to Materials and Polymer<br />
Science<br />
N. Radu, Organizer<br />
E. Chen, Presiding<br />
9:00 57. Chiroptical and stereoregular polymers<br />
from achiral polar vinyl monomers<br />
by chiral metallocenium catalysts.<br />
E. Y. Chen<br />
9:20 58. “Click” synthesis of heteroleptic cyclometalated<br />
iridium(III) and platinum(II)<br />
complexes. S. Liu,T.M.Swager<br />
9:40 59. Tuning of electronic bandgap in<br />
conjugated polymers by chlorotricarbonyl<br />
rhenium(I) complexes. C. S. Mak,<br />
W. Cheung, Q. Leung, W. Chan<br />
10:00 60. Structure and catalysis of oxidesupported<br />
Ir-dimer catalysts for transfer<br />
hydrogenation. S. Muratsugu,<br />
Y. Kushida, H. Nakai, K. Isobe, T. Sasaki,<br />
M. Tada<br />
10:20 Intermission<br />
10:25 61. Isocyanate- and isothiocyanatederived<br />
Grubbs-Hoveyda type catalysts:<br />
Synthesis, structure, and activity.<br />
M. R. Buchmeiser, S. Kumar, I. Ahmad<br />
10:45 62. Ring-opening metathesis polymerization-based<br />
pore-size-selective<br />
functionalization of glycidyl methacrylatebased<br />
monolithic media: Access to sizestable<br />
nanoparticles for ligand-free metal<br />
catalysis. M. R. Buchmeiser, R. Bandari,<br />
T. Hoeche, K. Dirnberger, A. Prager<br />
11:05 63. Cobalt catalysts for the copolymerization<br />
of epoxides and carbon dioxide.<br />
M. R. Kember, C. K. Williams<br />
11:25 64. Hybrid polyoxometalates embedded<br />
in porous polymeric materials as heterogeneous<br />
catalytic systems.<br />
M. Carraro, M. Gardan, M. Bonchio,<br />
A. Sartorel, G. Scorrano<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Main Group Chemistry<br />
B. Donovan-Merkert, Organizer<br />
F. Gabbai, Presiding<br />
9:00 65. Dimethyl sulfide adduct of 9,10-dihydro-9,10-diboraanthracene:<br />
A powerful<br />
ditopic reagent for hydroboration and<br />
other transformations. A. Lorbach,<br />
M. Bolte, H. Lerner, M. Wagner<br />
9:20 66. Approaches to a novel boronbased<br />
cationic Lewis acid. A. Schnurr,<br />
M. Bolte, M. Wagner<br />
9:40 67. Synthesis of oligotopic arylborohydrides:<br />
Coordination chemistry and hydroboration<br />
reactivity. D. Franz,<br />
M. Wagner, M. Bolte<br />
10:00 68. Chiral organoborane derivatives<br />
based on the 1,2-ferrocenyl framework.<br />
J. Chen, T. Pakkarisamy,<br />
K. Venkatasubbaiah, F. Jäkle<br />
10:20 69. Carbene-stabilization of unusual<br />
main group molecules. Y. Wang,<br />
M. Abraham, P. V. Schleyer,<br />
G. H. Robinson<br />
10:40 Intermission<br />
10:50 70. Predicting the observed effect of<br />
force on S N2 cleavage kinetics of C–O,<br />
Si–O, and P–O bonds. T. J. Kucharski,<br />
Q. Yang, S. Akbulatov, Z. Huang,<br />
R. Boulatov<br />
11:10 71. Protonated clusters of M@Sn 9H 3and<br />
their relationships to the fused deltahedral<br />
clusters. F. S. Kocak, P. Y. Zavalij,<br />
B. W. Eichhorn<br />
11:30 72. Synthesis and anion-binding<br />
properties of a telluronium borane.<br />
H. Zhao,F.P.Gabbaï<br />
SUNDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Young Investigator Symposium<br />
F. Walker, Organizer, Presiding<br />
1:30 73. Mechanochromic luminescence of<br />
difluoroboron �-diketonate molecular solids.<br />
G. Zhang, J. Lu, M. Sabat,<br />
C. L. Fraser<br />
2:00 74. Magnetic resonance imaging<br />
agents for selective copper detection.<br />
E. L. Que,C.J.Chang<br />
2:30 75. Carbon monoxide-induced cleavage<br />
of dinitrogen promoted by group 4<br />
metallocene compounds.<br />
D. J. Knobloch, E. Lobkovsky,<br />
P. J. Chirik<br />
3:00 76. Synthesis and anion binding properties<br />
of cationic main group Lewis acids.<br />
Y. Kim,F.P.Gabbaï<br />
3:30 Intermission<br />
3:40 77. Synthetic and mechanistic studies<br />
of the ring-opening and denitrogenation<br />
of pyridine and picolines by a Ti-C multiple<br />
bond. A. R. Fout, B. C. Bailey,<br />
D. M. Buck, H. Fan, J. C. Huffman,<br />
M. Baik, D. J. Mindiola<br />
4:10 78. Pathways of hydrogen evolution<br />
catalyzed by cobalt(II) diglyoxime complexes.<br />
J. L. Dempsey, J. R. Winkler,<br />
H. B. Gray<br />
4:40 79. Optical resonances in semiconductor<br />
nanowires. L. Cao, M. L. Brongersma<br />
5:10 80. Chalcogels: Novel porous metalchalcogenide<br />
aerogels. S. Bag,<br />
M. G. Kanatzidis<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Bioinorganic Chemistry<br />
Enzymes and Coenzymes<br />
M. Millar, Organizer<br />
E. Rybak-Akimova, Presiding<br />
1:30 81. Nature of the ferryl heme species in<br />
Compounds I and II. E. Raven,<br />
A. Gumiero, P. C. Moody<br />
1:50 82. Open conformational states of<br />
P450cam and a detailed pathway for<br />
opening of the substrate access channel.<br />
D. B. Goodin, Y. Lee, E. C. Glazer,<br />
R. F. Wilson, I. Rupniewski<br />
2:10 83. Using myoglobin as a model to<br />
study electron transfer in cytochromes<br />
P450 on the single molecule level.<br />
J. E. Jett, D. Li, D. Lederman,<br />
P. M. Gannett<br />
2:30 84. N 2 and H 2 activation by �-diketiminato<br />
Nickel(I) complexes and hydrogenase<br />
activity of resulting hydrides.<br />
C. Limberg, S. Pfirrmann, R. Stößer,<br />
B. Braun, C. Herwig<br />
2:50 85. ONIOM Study on a missing piece in<br />
our understanding of heme chemistry:<br />
Bacterial tryptophan 2,3-dioxygenase<br />
(TDO) with dual oxidants. L. Chung,X.Li,<br />
K. Morokuma<br />
3:10 86. Studying the mechanism of NO reduction<br />
in flavodiiron proteins with a flavin-free<br />
enzyme. T. Hayashi, J. Caranto,<br />
D. A. Wampler, D. M. Kurtz, Jr,<br />
P. T. Moenne-Loccoz<br />
3:30 Intermission<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–61
INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
3:40 87. NMR solution studies on NikR and<br />
UreE: Proteins involved in the biochemistry<br />
of nickel. S. Ciurli<br />
4:00 88. Carboxylic acids enhance the activity<br />
of biomimetic 3d-metal complexes in<br />
hydrogen peroxide activation reactions.<br />
E. V. Rybak-Akimova, O. V. Makhlynets,<br />
V. G. Organo, T. D. Palluccio<br />
4:20 89. Ligand and metal effects on the formation<br />
of O 2-reactive divalent metal enolate<br />
complexes: Evaluation of the influence<br />
of water. K. Grubel, K. Rudzka,<br />
C. Read, A. Fuller, L. M. Berreau,<br />
A. M. Arif<br />
4:40 90. Synthesis and stability of the clusters<br />
[Fe 4S 4(SR) 4] 2- in aqueous and partially<br />
aqueous media. W. Lo,T.A.Scott,<br />
R. H. Holm<br />
5:00 91. Site-differentiated iron-sulfur single<br />
cubanes as possible building blocks in<br />
the synthesis of higher-nuclearity clusters.<br />
A. Majumdar,L.Deng,R.H.Holm<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Coordination Chemistry<br />
Synthesis<br />
D. Crans, Organizer<br />
J. Scott, Presiding<br />
1:30 92. Zeolitic boron imidazolate frameworks.<br />
T. Wu, J. Zhang, C. Zhou,<br />
L. Wang, X. Bu, P. Feng<br />
1:50 93. Rational design of a porous metal<br />
organic framework and its gas absorption<br />
properties. X. Zhao,T.Wu,X.Bu,<br />
P. Feng<br />
2:10 94. Different ferroelectricity in two isostructural<br />
1D coordination polymers.<br />
L. Long<br />
2:30 95. Clathrochelate frameworks as the<br />
promising molecular scaffolds for new<br />
nanosized (photo)electronic devices and<br />
(radio)pharmaceuticals. Y. Z. Voloshin,<br />
O. A. Varzatskii, S. V. Shul’ga,<br />
A. S. Belov, I. G. Makarenko,<br />
K. Y. Zhizhin, N. T. Kuznetsov,<br />
Y. N. Bubnov<br />
2:50 96. Construction of high-nuclearity silver<br />
alkynyl clusters with anion templates.<br />
Q. Wang<br />
3:10 97. Magnetic chain compounds incorporating<br />
[ReCl 4(CN) 2] 2- . T. D. Harris,<br />
M. V. Bennett, R. Clerac, J. R. Long<br />
3:30 Intermission<br />
3:40 98. Using tripodal amine ligands to<br />
synthesize Cu-Gd bimetallic complexes.<br />
C. A. Barta, J. Post, B. Hervert, J. Kranz<br />
4:00 99. Synthesis of biorelevant zinc and<br />
copper complexes by utilizing bulky<br />
Tris(3-R-5-R�-1,2,4-triazolyl)borate<br />
(Ttz R,R� ) ligands. M. Kumar, E. T. Papish,<br />
M. Zeller<br />
4:20 100. New reactivity of anionic niobium<br />
phosphide complexes: Activation of P 4<br />
and generation of diatomic PN. D. Tofan,<br />
C. C. Cummins<br />
4:40 101. Design and development of reactive<br />
metal-ligand systems. C. C. Lu<br />
5:00 102. Trinuclear manganese clusters assembled<br />
with a novel tripodal tacn-based<br />
ligand. R. Cao, S. J. Lippard<br />
5:20 103. Synthesis and characterization of<br />
transition metal complexes supported by<br />
triazine-based ligands. K. D. Chisholm,<br />
J. Cull, J. Scott<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Electrochemistry<br />
62–TECH<br />
B. Donovan-Merkert, Organizer<br />
Y. Hao, Presiding<br />
‡ Cooperative Cosponsorship<br />
1:30 104. Development of non-flammable<br />
electrolytes for lithium ion batteries.<br />
S. Dalavi, M. Xu, B. Ravdel, B. L. Lucht<br />
1:50 105. Inhibition of electrolyte oxidation<br />
in lithium ion batteries with electrolyte additives.<br />
T. Markmaitree,L.Yang,<br />
B. Lucht<br />
2:10 106. Electrochemical reduction of dinitrogen<br />
to ammonia using the<br />
[HIPTN 3N]Mo catalyst. T. Munisamy,<br />
R. R. Schrock<br />
2:30 107. Oxygen evolution mediated by a<br />
cobalt based thin film electrocatalyst.<br />
Y. Surendranath, D. G. Nocera<br />
2:50 108. Investigation of photocatalytic hydrogen<br />
generation by light-initiated chronoamperometry.<br />
J. I. Goldsmith<br />
3:10 Intermission<br />
3:20 109. Electrocatalysis of oxygen evolution<br />
reaction in Li-air batteries for energy<br />
storage application. Y. Lu,<br />
H. A. Gasteiger, Y. Shao-Horn<br />
3:40 110. Remarkable reactivity of ruthenium<br />
catalyst for C-H activation: A case<br />
study of alcohol oxidation. A. Paul,<br />
J. Hull, Z. Chen, T. J. Meyer<br />
4:00 111. Electron transfer on vertically<br />
aligned carbon nanofibers. E. C. Landis,<br />
R. J. Hamers<br />
4:20 112. Effect of cationic species on the<br />
oxygen reduction reaction (ORR) activity<br />
of perovskite transition metal oxides in<br />
the alkaline environment: Elucidating the<br />
charge transfer mechanism on model oxide<br />
surfaces. J. Suntivich, N. Yabuuchi,<br />
H. A. Gasteiger, Y. Shao-horn<br />
4:40 113. Formation of Au nanoparticles<br />
through reduction of Na 3Au(SO 3) 2 by<br />
electrochemically evolved hydrogen.<br />
Y. Hao, Y. Li, C. Huang, C. Muangphat<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Chemistry of Materials<br />
Novel Applications<br />
D. Nelson, Organizer<br />
P. Kim, Presiding<br />
1:30 114. Employing permanganate oxidations<br />
in organic chemistry as a synthetic<br />
route toward LiMn 2O 4 spinel, a Li-ion<br />
battery cathode material. B. M. Bartlett,<br />
B. J. Liddle, B. P. Clifford<br />
1:50 115. Cobalt-based catalyst deposited<br />
on low-bandgap semiconductor photoanodes<br />
for visible-light induced water oxidation.<br />
R. Costi, E. R. Young, V. Bulovic,<br />
D. G. Nocera<br />
2:10 116. Hafnium (IV) and zirconium (IV)<br />
porphyrinato and phthalocyaninato diacetate<br />
complexes as new dyes for solar<br />
cell devices. I. Radivojevic, C. M. Drain,<br />
M. Sfeir, C. T. Black, B. P. Burton-Pye<br />
2:30 117. New Tantalum (oxy)nitride photocatalysts<br />
designed for overall water splitting<br />
under visible light. C. Ho,<br />
M. J. Randall, P. T. Snee, K. Low<br />
2:50 118. Role of inorganic anions in crystal<br />
engineering of novel materials for nonlinear<br />
optics based on hydrogen bonded<br />
salts of polarizable organic molecules.<br />
I. Nemec, I. Matulkova, M. Fridrichova,<br />
I. Cisarova, R. Gyepes, P. Nemec<br />
3:10 119. Hierarchical self-assembly of<br />
nanoparticles and nanofibers: Toward<br />
photocatalysis. F. O. Ochanda,<br />
M. R. Barnett<br />
3:30 Intermission<br />
3:50 120. Development of thin film cobalt<br />
metal anode as scaffold and Co 2� source<br />
for formation of cobalt-based water oxidation<br />
catalyst. E. R. Young, V. Bulovic<br />
4:10 121. Facile size-tuning of gold nanoparticles<br />
onto thiol functionalized carbon<br />
nanotubes and their electrocatalytic activity<br />
for oxygen reduction reaction.<br />
J. Kim, S. Lee, S. Chen, Y. Shao-Horn<br />
4:30 122. Phthalocyanines for thermoelectric<br />
applications. D. S. Dudis,<br />
J. Shumaker, C. Chen, J. B. Ferguson,<br />
J. E. Schmidt, E. Kemp, A. V. Fratini<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Zero-dimensional Structures<br />
S. Wong, Organizer<br />
J. Pettibone, Presiding<br />
1:30 123. AuPt nanoparticles with a Pt-rich<br />
surface layer. Z. Xu, J. Suntivich, J. Kim,<br />
C. Carlton, H. Gasteiger, Y. Shao-Horn,<br />
K. Hamad-Schifferli<br />
1:50 124. Pd 0 ,Ag 0 , and Au 0 nanoparticles<br />
supported on porous, thermally stable<br />
M IV phosphonate frameworks.<br />
H. P. Perry, J. Law, A. Clearfield<br />
2:10 125. Synthesis and shape control of Pt<br />
and Pt-based alloy nanocrystals.<br />
Y. Kang, X. Ye, C. B. Murray<br />
2:30 126. Nanocomposite materials: A simple<br />
route toward effective supported<br />
nanocatalysts. S. E. Hunyadi Murph,<br />
E. B. Fox, S. Serkiz, H. Colon-Mercado,<br />
L. Sexton, R. D. Torres, M. Siegfried<br />
2:50 127. Growth and formation of tunable,<br />
monodisperse phosphine-protected gold<br />
clusters. J. M. Pettibone, J. W. Hudgens<br />
3:20 Intermission<br />
3:30 128. Shape controlled colloidal synthesis<br />
of rock-salt lead selenide nanocrystals.<br />
A. M. Jawaid, D. Asunskis,<br />
L. Hanley, P. T. Snee<br />
4:00 129. Quantitative and size-tunable<br />
quantum growth using sec-phosphine<br />
chalcogenide anion sources.<br />
C. M. Evans<br />
4:20 130. Rational synthesis of heterostructured<br />
nanoparticles with shape control.<br />
C. Wang, V. R. Stamenkovic,<br />
N. M. Markovic<br />
4:40 131. Generalized strategy for the photochemical<br />
synthesis of group II-VI nanoparticles.<br />
T. Warwick, W. Thornley,<br />
T. E. bitterwolf<br />
5:00 132. Simple synthesis of Pd-Fe3O4<br />
heterodimer nanocrystals and their applications<br />
to magnetically recyclable catalyst<br />
for Suzuki cross-coupling reactions.<br />
Y. Jang,T.Hyeon<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Commemoration of the Founding of the<br />
ACS Journal Organometallics<br />
Reminiscences, Catalysis, Main Group,<br />
Organosilicon<br />
D. Lichtenberger, Organizer<br />
M. Bochmann, Presiding<br />
1:50 Introductory Remarks<br />
2:00 133. Third generation: Thousands of<br />
new catalysts for olefin metathesis.<br />
R. R. Schrock, A. J. King, S. Marinescu,<br />
Y. Zhao, A. Lichtscheidl, M. Flook,<br />
L. Gerber<br />
2:30 134. Dietmar Seyferth’s favorites: The<br />
elements of group 14. H. W. Roesky<br />
3:00 135. Researches on unusual molecular<br />
organic compounds of the lanthanides.<br />
M. F. Lappert<br />
3:30 Intermission<br />
3:45 136. New pathways in metal-mediated<br />
transformations of organosilicon compounds.<br />
D. Tilley<br />
4:15 137. Stoichiometric and catalytic reactions<br />
of the (pentamethylcyclopentadienyl)silicon(II)<br />
cation. P. Jutzi,<br />
K. Leszczynska, A. Mix, B. Rummel<br />
4:45 138. Heteroallenes E�C�E� (E, E��<br />
group 14 and 15 elements). J. Escudie<br />
5:15 139. Changing pathways by replacing<br />
carbon by silicon: Examples in d and f<br />
transition metal compounds.<br />
O. Eisenstein<br />
Synthetic Chemistry for Biological Imaging,<br />
Quantitation, and Discovery Sponsored by<br />
BIOL, Cosponsored by INOR<br />
SUNDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Bioinorganic Chemistry<br />
M. Millar, Organizer<br />
7:00–9:00<br />
140. New chiral dinuclear platinum(II) complexes<br />
bridged by tartrate: Unique diastereoselective<br />
effect on antitumor growth<br />
inhibition. S. Kaizaki<br />
141. Analysis of DNA mismatches and potassium<br />
ions using an aptamer probe and<br />
light switch complex. J. Kim<br />
142. Detection of small molecules and ions<br />
using conformational changes of DNA<br />
aptamers. J. Kim, B. N. Oh,M.Cha<br />
143. Near-stoichiometric conversion of hydrogen<br />
peroxide to oxoiron(IV) intermediates<br />
at nonheme iron centers. F. Li,<br />
J. England, L. Que<br />
144. Olefin cis-dihydroxylation with bio-inspired<br />
iron catalysts containing facial N,<br />
N, O-ligands that mimic the active site of<br />
Rieske dioxygenases. Y. Feng,<br />
P. D. Oldenburg, L. Que<br />
145. Reaction paths in Mg(II) and Ca(II) catalyzed<br />
transesterification of an RNA model<br />
phosphodiester. D. O. Corona-Martínez,<br />
A. K. Yatsimirsky<br />
146. Reactivity of thiolate dinitrosyl iron<br />
complexes with dioxygen. H. Kalyvas,<br />
E. Kim<br />
147. Synthesis and dioxygen reactivity of Nbound<br />
dinitrosyl iron complexes.<br />
K. M. Skodje,N.Tran,E.Kim<br />
148. Investigating the NO reduction mechanism<br />
in terminal oxidases by low temperature<br />
photolysis studies. T. Hayashi,<br />
P. T. Moenne-Loccoz<br />
149. Active site of carbon monoxide dehydrogenase:<br />
Electronic structure studies of<br />
bridged molybdenum-copper complexes.<br />
A. Dinescu,J.Ash<br />
150. Investigating the nickel- and cobaltspecific<br />
response in the E. coli transcriptional<br />
derepressor, RcnR. K. A. Higgins,<br />
M. J. Maroney<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
General Inorganic Chemistry<br />
B. Donovan-Merkert, M. Millar, Organizers<br />
7:00–9:00<br />
151. Transition metal-salicylaldehyde complexes:<br />
Photophysical properties and applications.<br />
J. E. Bates, J. E. McGarrah<br />
152. Novel hydrogen-bonded host lattice<br />
built of 1-(diaminomethylene)thiourea and<br />
its derivative of 3-amino-1,2,4-thiadiazole-5-carbamate<br />
anion. J. Zhang, Q. Li<br />
153. Synthesis, luminescent and electrical<br />
characterization of two ruthenium complexes.<br />
S. Manickam, S. Sivasankaran,<br />
B. Varghese, R. Ramanathan<br />
154. Characterization of proton coupled<br />
electron transfer in a biomimetic oxomanganese<br />
complex: Evaluation of the DFT<br />
B3LYP level of theory. T. Wang,<br />
G. Brudvig, V. Batista<br />
155. New class of chiral ligands for the aqueous,<br />
lanthanide-catalyzed carbon–carbon<br />
bond-forming reactions. Y. Mei,<br />
P. Dissanayake, M. J. Allen<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
156. Correlation of Lewis acidity with halogen<br />
substitution of triphenyl borate: Acceptor<br />
number determinations from 31 P<br />
NMR data of Et 3PO-B(OAr) 3 adducts.<br />
D. C. Wilson, R. Potter,<br />
T. D. Smurthwaite, D. M. Camaioni,<br />
J. C. Linehan, T. Autrey, D. M. Schubert<br />
157. Attachment of tris(pyrazolyl)borate ligands<br />
to synthesis beads. R. M. Tarkka,<br />
P. J. Desrochers, B. Bowlin, A. Roller<br />
158. Effect of sintering conditions on micro<br />
structure and chemical properties of<br />
polyphenylcarbosilane. W. Kwon,S.Kim,<br />
Y. Lee, Y. Kim, R. R. Bhave<br />
159. Transition metal isomorphous substitution<br />
in vanadosilicate AM-6 framework.<br />
M. N. Ismail, D. Shea, J. Warzywoda,<br />
A. Sacco, Jr.<br />
160. Effects of chirality on Shiff base ligands<br />
and complexes. M. A. O’Connor,<br />
A. W. Addison<br />
161. Heterometallic metal-titanium(IV) oxo<br />
cages: Key building blocks for hybrid materials.<br />
S. Eslava, F. Hengesbach,<br />
M. McPartlin, D. S. Wright<br />
162. Magneli phases from ilmenite and rutile<br />
at lower temperature. S. Sivasankaran,<br />
S. B, R. Ramanathan<br />
163. Synthesis and characterization of aminoaryl<br />
substituted cyclic and polymeric<br />
phosphazenes. C. Kumas, P. Devulapalli,<br />
P. Wisian-Neilson<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Nanoscience<br />
Novel Nanostructures<br />
S. Wong, Organizer<br />
7:00–9:00<br />
164. Structures, spectra, reaction energies<br />
and oxidation trends of NH 4Cl nanocrystallites.<br />
R. Q. Topper, W. V. Feldmann,<br />
I. Markus<br />
165. Investigation of laser-induced fabrication<br />
of free-standing, 3D metal microstructures.<br />
D. W. Bemis, S. Converse,<br />
M. Amos, R. A. Farrer<br />
166. Organometallic, light-harvesting building<br />
blocks for double salt complexes.<br />
V. Phillips, L. H. Doerrer<br />
167. On the expanding role for ionic liquids<br />
in nanomaterials synthesis.<br />
J. D. Woodward, G. A. Baker, S. Dai,<br />
S. N. Baker, A. J. Rondinone, P. Fulvio,<br />
H. Zhao<br />
168. Single molecule super-resolution imaging<br />
of surface enhancement hotspot.<br />
H. Cang, X. Zhang<br />
169. Growth and density control of nanometric<br />
FeNi cyanide-bridged objects on functionalized<br />
Si(100) surface. S. Tricard,<br />
B. Fleury, F. Volatron,<br />
C. Costa-Coquelard, S. Mazerat, V. Huc,<br />
C. David, F. Brisset, F. Miserque,<br />
P. Jegou, S. Palacin, T. Mallah<br />
170. Exploring formation and magnetic behavior<br />
of metal co-ordinated<br />
pyrogallol[4]arene capsules. H. Kumari,<br />
C. Dennis, A. Mossine, J. L. Atwood<br />
171. Chlorination for retrieving non-IPR<br />
fullerene[78]. S. Xie, L. Zheng, R. Huang<br />
172. Preparation of highly conductive and<br />
transparent thin films from single-walled<br />
carbon nanotubes via spin coating process.<br />
J. Jo, J. Jung, J. Lee, W. Jo<br />
173. Noncovalent functionalisation of purified<br />
and filled carbon nanotubes by fluorescent<br />
and biocompatible hosts for molecular<br />
imaging applications. Z. Hu,<br />
R. Arrowsmith, R. M. Tyrrell, S. I. Pascu<br />
174. Electrocatalytic activity of nitrogendoped<br />
carbon nanotube cups. Y. Tang,<br />
B. L. Allen, D. R. Kauffman, A. Star<br />
175. Kinetic Monte Carlo model predicting<br />
the short-circuit current of a P3HT-SWNT<br />
planar heterojunction solar cell.<br />
G. L. Paulus, M. Ham, M. S. Strano<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Chemistry of Materials<br />
D. Nelson, M. Millar, Organizers<br />
7:00–9:00<br />
176. Identification of DNA structural motifs<br />
for hydroxyapatite binding and biomineralization.<br />
S. Ngourn, S. Landry,<br />
J. Anderson, A. E. Gerdon<br />
177. Spin lattice model of vanado-alkyldiphosphonate<br />
determined by electronic<br />
structure calculations. H. Koo<br />
178. Antimicrobial-modified mesoporous<br />
particles as functional carriers for hygienic<br />
paper. J. Snow, Z. Ziaee, H. Xiao<br />
179. New ALD and MOCVD metal precursors<br />
for transparent oxide thin films.<br />
T. Chung, C. G. Kim, I. Jung, B. K. Park<br />
180. Growing superconducting ironoxypnictide<br />
nanowires. P. Sood, M. Nath,<br />
S. Patil, E. S. Hallstrom<br />
181. Preparation and characterization of mesoporous<br />
tin oxide thin film. Y. Kim,<br />
E. Jung, S. Kim, W. Seo, Y. Lim<br />
182. Novel germanium complexes as promising<br />
precursors for nonvolatile memory<br />
Ge 2Sb 2Te 5 (GST) device. T. Chung,<br />
C. G. Kim, B. K. Park, Y. Lee<br />
183. Modified TiO 2: Visible light responding<br />
photocatalyst. F. Zuo, L. Wang, T. Wu,<br />
D. Borchardt, P. Feng<br />
184. Assembly of supertetrahedral T5 copper-indium-sulfide<br />
clusters into super-supertetrahedron<br />
of infinite order. L. Wang,<br />
F. Zuo, T. Wu, X. Zhao, X. Bu, J. Wu,<br />
P. Feng<br />
185. Solid solubility limit of manganese in<br />
AgInSe 2 chalcopyrites. J. D. Lucas,<br />
K. Balamurugan, J. Yao, J. A. Aitken<br />
186. Proximity effect in Pt and CoFe 2O 4<br />
nanoparticles confined within the mesoporous<br />
shell of a silica microsphere.<br />
D. Kang, M. Eum, K. Lee, H. Lim, N. Hur<br />
187. Making molecular multilayers using<br />
“click” chemistry: Growth and thin film<br />
characterization. P. K. Palomaki,<br />
P. H. Dinolfo<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Coordination Chemistry<br />
Characterization and Applications<br />
D. Crans, M. Millar, Organizers<br />
7:00–9:00<br />
188. Syntheses, structures, and properties of<br />
Co(II)-based ionic liquids. T. Peppel,<br />
M. Köckerling<br />
189. Reversible 2D-3D framework transformation<br />
within a prototype metal-organic<br />
framework. Z. Chen, S. Xiang, D. Zhao,<br />
B. Chen<br />
190. Selective gas adsorption within a fiveconnected<br />
porous metal-organic framework.<br />
M. Xue, Z. Zhang, S. Xiang,<br />
C. Liang, Z. Jin, G. Zhu, S. Qiu, B. Chen<br />
191. Reactivity of a reduced zirconium-heterobimetallic<br />
toward small molecule activation.<br />
B. P. Greenwood,G.T.Rowe,<br />
C. M. Thomas<br />
192. Comparison of the reactivity of zirconium-cobalt<br />
complexes with small molecules.<br />
J. W. Napoline, B. P. Greenwood,<br />
C. M. Thomas<br />
193. Speciation of Hg2� and Zn2� in the<br />
presence of tridentate N,N,S ligand: An<br />
electrospray ionization mass spectrometry<br />
study. M. Nestor, D. Bebout<br />
194. Luminescent nitrogen and sulfur adducts<br />
of copper(I) salts. R. D. Pike,<br />
S. M. McCullough, J. P. Safko,<br />
L. E. Dunaway, M. D. Dembo,<br />
H. H. Patterson, C. A. Bayse<br />
195. Ground and excited-state coordination<br />
of Ru(bpy) 2(ppz) 2� (ppz-4�7�-phenathrolino-5�6�:5,6-pyrazine).<br />
A. Perri,<br />
H. D. Gafney, J. Kolombogias, N. Alper,<br />
S. Chow, G. Iberrola<br />
196. Comproportionation reactions as a<br />
route to new high oxidation state manganese<br />
clusters and single-molecule magnets.<br />
S. Mukherjee, K. A. Abboud,<br />
W. Wernsdorfer, G. Christou<br />
197. Precursor Chemistry for MOCVD of<br />
functional metal oxides of Zn and Co.<br />
D. Bekermann, M. G. Walawalkar,<br />
A. Devi, R. A. Fischer<br />
198. Octahedral hexanuclear transition metal<br />
clusters: Novel small molecule transformations.<br />
L. Szczepura<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Coordination Chemistry<br />
Synthesis<br />
D. Crans, M. Millar, Organizers<br />
7:00–9:00<br />
199. Stereogenic nitrogen centers with specific<br />
configuration: Coordination of chiral<br />
diamines to transition metals.<br />
P. K. Eckert, G. Dropalla, V. H. Gessner,<br />
C. Strohmann<br />
200. Study of ferrocene and ruthenocene<br />
based dipyrromethene ligands and their<br />
metal complexes. M. R. Malachowski,<br />
M. F. Grau, J. Thomas, A. B. Dru,<br />
L. Margerum<br />
201. Synthesis of new N-functionalized<br />
1,4,7-triazacyclononane (TACN) ligands<br />
and their Copper(II) coordination chemistry.<br />
E. Garcia, G. R. Weisman,<br />
E. H. Wong, C. Moore, J. A. Golen,<br />
A. L. Rheingold<br />
202. Coordinatively unsaturated polynuclear<br />
mixed-valent oxo-centered tin carboxylates.<br />
A. V. Zabula, A. S. Filatov,<br />
M. A. Petrukhina<br />
203. Tetranuclear copper(I) carboxylates:<br />
The effect of a stepwise increase in Lewis<br />
acidity on solid state structures and photoluminescence.<br />
O. Hietsoi, C. Dubceac,<br />
A. S. Filatov, M. A. Petrukhina<br />
204. Energy transfer in highly-ordered multilayer<br />
thin films of CdSe quantum dots<br />
and Au nanoparticles. T. M. Dansereau,<br />
S. K. Panda, M. A. Petrukhina<br />
205. First palladium �-complex of corannulene.<br />
S. N. Spisak, A. S. Filatov,<br />
M. A. Petrukhina<br />
206. Dirhodium paddlewheels with functionalized<br />
carboxylate bridges: Self-Assembly<br />
and catalytic properties. M. Napier,<br />
K. D. Kumar, A. S. Filatov, E. V. Dikarev,<br />
M. A. Petrukhina<br />
207. Structure and reactivity of gold(III) terpyridine<br />
complexes. M. C. Hardwick,<br />
V. Gomez, C. Hahn<br />
208. Synthesis and characterization of Ag(I)<br />
and Pd(II) complexes with pyridine substituted<br />
N-heterocyclic carbene ligands.<br />
G. Y. Kim, H. J. JUng, G. Park, D. Lee<br />
209. Mixed-valence tri- and octanuclear iron<br />
oxo pyrazolate complexes: Effect of terminal<br />
substitutions on electronic delocalization<br />
probed by various spectroscopic<br />
analyses. I. Chakraborty, D. M. Pinero,<br />
Y. Sanakis, R. G. Raptis<br />
210. Heterometallic mixed-ligand alkoxide/<br />
beta-diketonate complexes of tin and<br />
transition metals. C. M. Lieberman,<br />
V. D. Vreshch, E. V. Dikarev<br />
211. <strong>Chemical</strong> and thermal stability, and<br />
gaseous catalytic and sensing behaviors<br />
of ZnO/(La,Sr)CoO 3 composite nanowire<br />
arrays. A. Cai<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Electrochemistry<br />
B. Donovan-Merkert, Organizer<br />
7:00–9:00<br />
212. Synthesis, electrochemistry and chemical<br />
oxidation of ferrocenyl(phenyl)phosphine<br />
chalcogenides. R. U. Kirss,<br />
M. J. Verschoor-Kirss, R. Conry,<br />
C. M. Verschoor, O. Hendricks<br />
213. Investigation of novel electrolytes for<br />
lithium ion batteries. L. Zhou,M.Xu,<br />
B. L. Lucht<br />
214. Suppression of internal pressure in Li<br />
ion battery containing oxygen gas from<br />
lithium rich layered oxide. D. Lee,D.Im,<br />
Y. Ryu, V. Roev, S. Lee, J. Yoon, W. Choi,<br />
J. Lee, C. Back, I. Jung, S. Lee, S. Doo<br />
215. Surface proton-couple electron transfer:<br />
Effects of diversified factors. Z. Chen,<br />
J. J. Concepcion, J. W. Jurss, T. J. Meyer<br />
216. Interlocking electrodes fabricated by RF<br />
magnetron sputtering for lithium thin film<br />
batteries. Y. Chung,H.Kim,S.Yu,<br />
K. Kim, Y. Sung<br />
217. Structural improvement of cathode catalyst<br />
layer in direct methanol fuel cell.<br />
N. Jung,Y.Cho,J.Lim,M.Ahn,Y.Kang,<br />
D. Chung, Y. Sung<br />
218. Electrocatalytic reduction of nitric oxide<br />
(NO) mediated by the inducible nitric oxide<br />
synthase oxygenase domain (iN-<br />
OSoxy). J. Boutros, M. Bayachou<br />
219. Composite electrode for improved oxygen<br />
reduction. A. C. Marschilok, S. Lee,<br />
S. Zhu, C. Lee, C. Milleville, P. Chen,<br />
E. S. Takeuchi, K. J. Takeuchi<br />
220. New synthetic strategies towards lower<br />
cost, sustainable energy materials.<br />
K. J. Takeuchi, S. Zhu, A. C. Marschilok,<br />
E. S. Takeuchi<br />
221. Vanadium based cathodes for use in<br />
lithium based batteries: Opportunities for<br />
multiple electron transfer. E. S. Takeuchi,<br />
C. Lee, Y. Kim, A. Subramanian,<br />
A. C. Marschilok, K. J. Takeuchi<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Inorganic Catalysts<br />
B. Donovan-Merkert, Organizer<br />
7:00–9:00<br />
222. Hydrogen generation from the sodium<br />
borohydride hydrolysis reaction using<br />
hollow nanoparticles as catalysts. Q. Cui,<br />
Y. Sha, J. Pelealuw, J. Chen, Z. Gu<br />
223. Substituent effects in<br />
[Ni(P 2 R N2 R� )2](BF 4) 2 proton reduction<br />
electrocatalysts. U. J. Kilgore,<br />
D. H. Pool, J. A. Roberts, A. M. Appel,<br />
D. L. DuBois, R. M. Bullock<br />
224. Modifying the oxide composition of carbon<br />
supported PtRu-M ternary nanoparticles<br />
via pH control for methanol oxidation<br />
reaction. K. Choi, T. Jeon, H. Park,<br />
N. Jung, Y. Chung, Y. Sung<br />
225. Development of chiral diketiminate type<br />
ligands for asymmetric catalysis. G. Du,<br />
S. Abbina, Z. Lu, P. I. Binda<br />
226. Niobium-based oxide semiconductor<br />
nanowires possessing superior photocatalytic<br />
properties. K. Saito,A.Kudo<br />
227. Structural and dynamics studies of catalytic<br />
intermediates of hydrogen oxidation<br />
catalysts containing proton relays.<br />
M. J. O’Hagan,J.Y.Yang,W.J.Shaw,<br />
R. Bullock, D. L. DuBois<br />
228. New ligands for dimeric transfer hydrogenation<br />
catalysts. E. Macintosh,<br />
S. Muhia, B. Avitia, E. Kelson<br />
229. Preparation of nickel and palladium<br />
electrocatalysts for the reduction of CO 2.<br />
B. J. Boro, M. Bullock, D. L. DuBois<br />
230. Microwave-assisted synthesis of manganese<br />
oxide octahedral molecular<br />
sieves: Effects of flow rates, power delivery,<br />
and solvent system. N. N. Opembe,<br />
C. K. King’ondu, S. L. Suib<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–63
INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
231. Biotransformation using artificial cofactors<br />
photogenerated by metal complexes.<br />
J. Kim,J.A.Kim<br />
232. Synthesis and structure of intermediates<br />
in copper-catalyzed alkylation of diphenylphosphine.<br />
M. F. Cain,<br />
R. P. Hughes, D. S. Glueck, J. A. Golen,<br />
C. E. Moore, A. L. Rheingold<br />
Section I<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Organometallic Chemistry<br />
Catalysis<br />
N. Radu, Organizer<br />
7:00–9:00<br />
233. Synthesis, characterization and reactivity<br />
of a novel arylspiroboronate ester.<br />
G. M. Lee, C. M. Vogels, A. Decken,<br />
S. A. Westcott<br />
234. Approaches to the synthesis of C 3symmetric<br />
P-stereogenic triphosphine ligands.<br />
M. F. Cain, D. S. Glueck<br />
235. Platinum (II) catalysts for the hydroarylation<br />
of olefins: Effect of ligand donor<br />
strength on catalytic activity.<br />
M. R. Friedfeld,B.A.McKeown,<br />
M. Sabat, T. B. Gunnoe<br />
236. Transformation of bridging methylene<br />
to methyl in complexes of Rh/Os and Ru/<br />
Ir. R. L. DeKock, B. J. Burkhart,<br />
B. M. Brandsen<br />
237. Double activation of the geminal<br />
carbon�hydrogen bonds in 1,3-butadiene<br />
by a diiridium complex.<br />
B. J. Burkhart,R.L.DeKock<br />
238. Formation of methyl acrylate from CO 2<br />
and ethylene via methylation of nickelalactones.<br />
C. Bruckmeier,<br />
M. W. Lehenmeier, R. Reichardt,<br />
S. Vagin, B. Rieger<br />
239. Visible light-driven hydrogen production<br />
catalyzed by nickel and cobalt catalysts<br />
containing cyclic phosphine ligands with<br />
pendant bases. M. P. McLaughlin,<br />
T. M. McCormick, R. S. Eisenberg,<br />
P. L. Holland<br />
240. Catalytic epoxidation of alkenes using<br />
tripodal titanium polyhedral oligomeric<br />
silsesquioxane (Ti-POSS). E. H. Aish,<br />
M. Crocker, F. T. Ladipo<br />
241. Palladium-catalyzed synthesis of carbazoles<br />
via C-C cleavage. S. L. Rogers,<br />
A. R. Chianese<br />
242. Synthesis, characterization, and catalytic<br />
activity of iridium-CCC-pincer complexes.<br />
A. Mo, A. R. Chianese<br />
243. Rigid, sterically diverse N-heterocyclic<br />
carbene-pyridine chelates: Synthesis,<br />
mild palladation, and palladium-catalyzed<br />
allylic substitution. P. T. Bremer,<br />
A. R. Chianese<br />
244. Preparation of ruthenium carbene complexes<br />
based on a novel NHCP ligand for<br />
ROMP reactions. H. Salem, M. Schmitt,<br />
U. Blumbach, P. Hofmann<br />
245. Cationic Pt and Pd complexes for C—H<br />
bond functionalization. M. H. Emmert,<br />
M. S. Sanford<br />
246. Theoretical studies of the activation of<br />
carbon dioxide using transition metal<br />
�-diketiminato complexes. C. Liu,<br />
T. Cundari, A. Wilson<br />
247. How might intermediate Q of methane<br />
monooxygenase oxidize strong C-H<br />
bonds: Mechanistic insights from studying<br />
synthetic models. G. Xue,R.DeHont,<br />
E. Münck, L. Que, Jr.<br />
248. Search for the catalytic allylic CH-amination<br />
of alkenes by Pd(II) and Pt(II) complexes<br />
supported by bis-(di-t-butylphosphino)methane<br />
(dtbpm). M. Ferreira,<br />
P. Hofmann, V. B. Romakh, C. Jokisch<br />
249. Novel dinuclear Ru-complex for water<br />
oxidation. E. V. Johnston, E. A. Karlsson,<br />
M. D. Kärkäs, B. Lee, B. Åkermark<br />
64–TECH<br />
‡ Cooperative Cosponsorship<br />
Section J<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Environmental Aspects of Inorganic<br />
Chemistry<br />
B. Donovan-Merkert, Organizer<br />
7:00–9:00<br />
250. DFT calculations leading to multiscale<br />
modeling of CO 2 solutions.<br />
O. A. Olatunji-Ojo, T. R. Cundari,<br />
S. K. Boetcher<br />
251. Comparison between acid aerosol exposure<br />
of asthmatic schoolchildren and<br />
traffic density in metropolitan Taipei.<br />
C. Lin,I.Mao,Y.Chen,F.Sung,M.Chen<br />
252. Characterization and carbon dioxide reactivity<br />
of dinuclear molybdenum complexes.<br />
C. T. Tran,E.Kim<br />
253. Activation of CO 2 by bis(dithiolene-<br />
)tungsten complexes relevant to DMSO<br />
reductase. J. Seo,E.Kim<br />
254. Rhodamine based sensor for nerve gas<br />
mimics: Crystal structures and structure<br />
function relationship. A. J. Weerasinghe,<br />
C. S. Schmiesing, E. Sinn<br />
MONDAY MORNING<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Organometallic Chemistry<br />
Synthesis and Characterization<br />
N. Radu, Organizer<br />
C. Thomas, M. Buchmeiser, Presiding<br />
8:30 255. Alkyne chemistry of low valent Cr<br />
complexes supported by �-diimine ligands.<br />
J. Shen,G.P.Yap,<br />
K. H. Theopold<br />
8:50 256. Coordination of a novel family of<br />
tridentate bis-aryloxide-NHC chelating ligands<br />
to Ti(IV) and Zr(IV): Synthesis,<br />
structure, reactivity and use of the derived<br />
complexes in the controlled ROP of<br />
rac-lactide. S. Dagorne,<br />
S. Bellemin-Laponnaz, C. Romain<br />
9:10 257. Electronic factors affecting metalmetal<br />
interactions in early/late heterobimetallics:<br />
Substituent effects in Pt/Zr<br />
bis(phosphinoamide) complexes.<br />
B. G. Cooper,C.M.Thomas,<br />
C. M. Fafard<br />
9:30 258. Unique primary carbon-nitrogen<br />
bond scission across a W-W multiple<br />
bond and methyl dehydrogenation.<br />
S. Sarkar, J. A. Culver, A. R. Peloquin,<br />
I. Giviriga, K. A. Abboud, A. S. Veige<br />
9:50 Intermission<br />
9:55 259. Amidinate-supported tungsten(VI)<br />
silyl complexes. M. E. Fasulo, T. D. Tilley<br />
10:15 260. Synthesis, interconversion, and<br />
reactivity of titanaaziridines and titanaoxiranes.<br />
L. Li, K. E. Kristian, J. R. Norton<br />
10:35 261. Carbon dioxide reduction by<br />
low-valent molybdenum complexes.<br />
W. H. Bernskoetter, B. Tyler<br />
10:55 262. When “dispersion” means “cohesion”:<br />
The crucial role of London force<br />
in bimetallic systems. J. Djukic,<br />
S. Grimme, T. Schwabe, I. Hyla-Kryspin<br />
11:15 263. Mid-valent early transition metal<br />
chemistry with derivatives of the bicyclic<br />
guanidinate hpp — (hexahydropyrimidopyrimidinate).<br />
L. Messerle<br />
11:35 264. Polymer-supported, CO 2-protected<br />
N-heterocyclic carbenes: Synthesis<br />
and application in organo- and organometallic<br />
catalysis. M. R. Buchmeiser,<br />
G. M. Pawar<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Luminescence and Magnetism of<br />
Lanthanide-Containing Materials<br />
A. De Bettencourt Dias, Organizer<br />
C. Cahill, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 265. Luminescent Eu(III) complexes incorporated<br />
into bulge-like structures in<br />
DNA selectively bind small molecules.<br />
J. R. Morrow, J. J. Kim, M. G. Frith,<br />
R. Haner<br />
9:05 266. Synthesis, crystal chemistry and<br />
magnetic properties of RE 5–xMg xGe 4<br />
(RE � Gd-Lu and Y) and RE 5–xLi xGe 4<br />
(RE � Nd, Sm, Gd). S. Bobev<br />
9:35 267. Controlling and exploiting energy<br />
transfer pathways in luminescent lanthanide<br />
complexes. S. Faulkner<br />
10:05 Intermission<br />
10:15 268. Benefits from polarized luminescence<br />
of Ln(III)-containing systems.<br />
G. Muller<br />
10:45 269. Lanthanide-based hybrid nanoparticles<br />
for biomedical imaging. W. Lin<br />
11:15 270. Naphthalimide sensitized lanthanide(III)<br />
luminescence. A. H. Shelton,<br />
D. Sykes, M. D. Ward<br />
11:35 271. Room temperature colloidal synthesis<br />
of magnetic EuTe nanoparticles.<br />
W. He, S. Somarajan, D. Koktysh,<br />
J. Dickerson<br />
11:55 Concluding Remarks<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Inorganic Chemistry<br />
M. Millar, S. Koch, Organizers<br />
J. Protasiewicz, W. Armstrong, Presiding<br />
8:30 272. Inorganic physiology: Remodeling<br />
of the cellular metallome in infectious disease<br />
and mammalian development.<br />
T. V. O’Halloran<br />
9:10 273. Facile photochemical release of<br />
NO from a rhodium nitrosyl complex.<br />
A. Bakac, W. Song, K. Kristian<br />
9:30 274. Electroactive cages and their linear<br />
conjugates: Inorganic-organic hybrid<br />
platforms for chemical sensing and electron<br />
transport. D. Lee<br />
9:50 275. Structural chemistry and properties<br />
of metal organic frameworks based<br />
on polyazaheteroaromatic ligands.<br />
W. Ouellette, A. V. Prosvirin,<br />
K. R. Dunbar, J. A. Zubieta<br />
10:10 276. Platinum in molecules and platinum<br />
in chains. L. H. Doerrer<br />
10:30 277. Postsynthetic modification of<br />
aluminum-based metal-organic frameworks.<br />
S. M. Cohen<br />
10:50 278. Synthesis and reactivity of metal<br />
ion clusters. S. Banerjee, X. Zhang,<br />
W. Lo, S. Vaddypally, W. H. Armstrong<br />
11:10 279. Synthesis and iron chemistry of<br />
novel biomimetic triptycene-based ligands.<br />
Y. Li, S. J. Lippard<br />
11:30 280. Phosphorus as a carbon-copy<br />
and as a photo-copy. J. D. Protasiewicz,<br />
M. P. Washington, V. B. Gudimetla<br />
11:50 281. Selective aerobic oxidation reactions<br />
involving organometallic C-H activation<br />
pathways. S. S. Stahl<br />
12:10 282. Catalytic, selective C-H bond<br />
functionalizations with main group reagents.<br />
J. F. Hartwig, D. W. Robbins,<br />
C. W. Liskey, E. M. Simmons<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Chemistry of Materials<br />
Magnetism and Electronic Effects<br />
D. Nelson, Organizer<br />
G. Halder, I. Bersuker, Presiding<br />
8:30 283. Single-molecule magnetic and dipolar<br />
bistability induced by the Jahn-<br />
Teller effect. I. B. Bersuker,<br />
P. Garcia-Fernandez<br />
8:50 284. Cobalt coordination and clustering<br />
in �-Co(OH) 2: Tuning magnetic properties<br />
with kinetically controlled hydrolysis.<br />
J. R. Neilson, J. A. Kurzman,<br />
B. C. Melot, D. P. Shoemaker,<br />
R. Seshadri, D. E. Morse<br />
9:10 285. Catalysts supported on magnetic<br />
mesocellular foams for versatile organic<br />
transformations. S. Lee,S.N.Riduan,<br />
N. Erathodiyil, J. Lim, Y. Han, J. Y. Ying<br />
9:30 286. Magnetic and structural studies of<br />
the frustrated kagomé antiferromagnet<br />
Herbertsmithite, ZnCu 3(OH) 6Cl 2 and its<br />
structural analogs. D. E. Freedman,<br />
T. McQueen, R. Chisnell, T. Han,<br />
Y. S. Lee, D. G. Nocera<br />
9:50 287. Pressure-induced sequential orbital<br />
reorientation in a magnetic framework<br />
material. G. J. Halder,<br />
K. W. Chapman, J. A. Schlueter,<br />
J. L. Manson<br />
10:10 Intermission<br />
10:30 288. Phase controlled synthesis of<br />
iron silicide (Fe 3Si and FeSi 2) nanoparticles<br />
in solution. V. Chikan, N. Dahal<br />
10:50 289. Synthesis, electronic structure,<br />
and phase transitions of M xV 2O 5 nanostructures.<br />
C. J. Patridge, S. Banerjee<br />
11:10 290. Efficient charge transfer antenna<br />
tetrathiafulvalene ligand for the sensitization<br />
of Yb(III) luminescence. L. Ouahab,<br />
F. Pointillart, T. Cauchy, O. Cador,<br />
S. Golhen, O. Maury<br />
11:30 291. Solvation effects on spin-crossover<br />
complexes. J. Tao<br />
11:50 292. True-Blue Alq 3: Combined substituent<br />
effect in 8-hydroxyquinoline ligands<br />
on emission color and triplet energy<br />
tuning. P. Anzenbacher,<br />
C. Pérez-Bolívar, S. Takizawa,<br />
G. Nishimura, V. A. Montes<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
One-dimensional Structures<br />
S. Wong, Organizer<br />
B. Wiley, Presiding<br />
8:30 293. Gallium functionalization of nitrogen-doped<br />
carbon nanotubes to form<br />
gallium nitride carbon nanotube hybrid<br />
material. T. J. Simmons,<br />
M. Bravo Sanchez, E. Lopez Luna,<br />
M. A. Vidal Borbolla,<br />
H. Navarro Contreras<br />
8:50 294. Fabrication and physical properties<br />
of ZnO/CuO heterostructured nanowires.<br />
K. Liao, P. Shimpi, P. Gao<br />
9:10 295. Synthesis of single-crystalline 1D<br />
LiNbO 3 nanorods. A. C. Santulli,<br />
H. Zhou, S. Berweger, M. B. Raschke,<br />
E. Sutter, S. S. Wong<br />
9:30 296. Nonaqueous synthesis of molybdenum<br />
dioxide nanorodes: Comprehensive<br />
study of growth of nanoparticles, insitu<br />
EXAFS monitoring of inorganic<br />
reaction mechanism and their electrochemical<br />
properties. D. Koziej,<br />
A. Hintennach, J. Grunwaldt,<br />
M. D. Rossell, P. Novak, M. Niederberger<br />
9:50 297. Exfoliation of boron nitride nanotubes<br />
prepared from a solid gas chemical<br />
reaction. C. Hung, J. Hurst<br />
10:10 Intermission<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
10:30 298. Growth mechanism of copper<br />
nanowires and their properties in flexible,<br />
transparent conducting films.<br />
A. R. Rathmell, S. M. Bergin, Y. Hua,<br />
Z. Li, B. J. Wiley<br />
11:00 299. Effects of salt selection on the<br />
rapid synthesis of silver nanowires.<br />
S. Nandikonda, E. W. Davis<br />
11:20 300. Synthesis of Ni and FeNi coreshell<br />
nanorods. N. Shukla, J. B. Miller,<br />
E. Coletta, A. Ondeck, J. Chung Lee,<br />
A. J. Gellman<br />
11:40 301. One-pot hydrothermal synthesis<br />
of silver nanowires via citrate reduction.<br />
Z. Yang, H. Qian, H. Chen, J. N. Anker<br />
12:00 302. Boron nitride nanotubes from<br />
graphene sheets. S. Xie, R. Huang,<br />
L. Zheng<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Commemoration of the Founding of the<br />
ACS Journal Organometallics<br />
Synthesis and Catalysis<br />
D. Lichtenberger, Organizer<br />
L. Liebeskind, Presiding<br />
9:00 303. Synthesis and chemistry of electrophilic<br />
iridium and rhodium pincer complexes.<br />
M. Brookhart,<br />
W. H. Bernskoetter, M. Findlater,<br />
C. Schauer, M. D. Walter<br />
9:30 304. Reductive coupling of carbon<br />
monoxide in Re and Mn carbonyl complexes<br />
with pendant Lewis acids.<br />
J. E. Bercaw, N. West, J. A. Labinger,<br />
S. Yu, A. Hazari, A. J. Miller<br />
10:00 305. Organometallic chemistry of synthetic<br />
methods. J. F. Hartwig<br />
10:30 Intermission<br />
10:45 306. From 5-membered metallacyclo-cumulenes,<br />
–pentynes and –allenes<br />
to 4-membered metalla-dihetero-cycloallenes<br />
and its complexes. O. Theilmann,<br />
A. Villinger, A. Schulz, M. Lamac,<br />
K. Kaleta, T. Beweries, P. Arndt,<br />
W. Baumann, A. Spannenberg,<br />
U. Rosenthal<br />
11:15 307. Unique chemical properties of<br />
non-traditional metal-carbon bonds.<br />
Z. Xie<br />
11:45 308. Methane activation and functionalization<br />
by a transient titanium alkylidyne.<br />
D. J. Mindiola, J. A. Flores,<br />
D. M. Buck, G. Chen, J. E. Bercaw,<br />
J. G. Andino<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Inorganic Materials: Electrochemistry and<br />
Battery Applications<br />
A. Marschilok, K. Takeuchi, Organizers<br />
E. Takeuchi, Organizer, Presiding<br />
9:00 309. Opportunities for multiple electron<br />
transfer in cathode materials.<br />
E. S. Takeuchi, C. Lee, Y. Kim,<br />
A. Subramanian, A. C. Marschilok,<br />
K. J. Takeuchi<br />
9:30 310. Electrochemistry-materials interactions<br />
and impact on battery design.<br />
Y. Chiang<br />
10:00 311. Aqueous electrolyte energy storage:<br />
Materials and devices. J. Whitacre<br />
10:30 312. Li-diffusion mechanisms and the<br />
role of coherency strains during twophase<br />
reactions in titanate electrodes for<br />
Li batteries. A. Van der Ven,<br />
J. Bhattacharya, A. Dalton, Y. Wang<br />
11:00 313. Development and application of<br />
nanophosphate batteries. B. Riley<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
MONDAY AFTERNOON<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Ligand Design and Metal Behavior<br />
L. Doerrer, M. Millar, Organizers<br />
S. Koch, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 314. Catalytic reduction of dinitrogen<br />
to ammonia with molybdenum under mild<br />
conditions. R. R. Schrock, B. Hanna,<br />
J. Chin, M. Reithofer<br />
2:15 315. Designing polymetallic reaction<br />
sites: Ligand control of M-M interactions.<br />
T. Betley<br />
2:45 316. Building bulkier �-diketiminate ligands<br />
for applications in bioinorganic<br />
chemistry and catalysis. P. L. Holland,<br />
T. R. Dugan, B. R. Dible,<br />
W. W. Brennessel<br />
3:15 Intermission<br />
3:25 317. Ligand effects on copper-oxygen<br />
reactivity. W. B. Tolman<br />
3:55 318. Nickel catalysts for hydrogen oxidation<br />
and production containing diphosphine<br />
ligands with pendant amine bases.<br />
M. Rakowski-DuBois, D. DuBois,<br />
R. M. Bullock<br />
4:25 319. Regulating the primary and secondary<br />
coordination sphere within transition<br />
metal complexes through ligand design.<br />
A. Borovik<br />
4:55 320. Ligand effects on the chemistry of<br />
O 2-reactive divalent metal enolate and<br />
enediolate complexes. L. M. Berreau<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Luminescence and Magnetism of<br />
Lanthanide-Containing Materials<br />
C. Cahill, Organizer<br />
A. De Bettencourt Dias, Organizer,<br />
Presiding<br />
1:30 Introductory Remarks<br />
1:35 321. All oxygen donor ligands as efficient<br />
antennae for lanthanide luminescence.<br />
K. N. Raymond<br />
2:05 322. Structure-relaxivity relationships<br />
among macrocyclic gadolinium(III) complexes.<br />
V. Jacques, S. Dumas,<br />
M. T. Greenfield, W. Sun, J. S. Troughton,<br />
P. Caravan<br />
2:35 323. Interaction of luminescent lanthanide-functionalized<br />
gold nanoparticles<br />
with bovine serum albumin (BSA).<br />
S. Comby, T. Gunnlaugsson<br />
3:05 Intermission<br />
3:15 324. Developing lanthanide-based responsive<br />
complexes. S. Pope,<br />
M. Andrews, J. Jones<br />
3:45 325. Gd-labeled porous silica microparticles<br />
with large relaxivities studied in<br />
vivo by MRI. C. Landry, J. Steinbacher,<br />
S. Lathrop, J. Hillegass, B. Mossman<br />
4:15 326. Lanthanide complexes utilizing<br />
bis(pyrazolyl)pyridine and beta-diketonate<br />
ligands to efficiently sensitize lanthanide<br />
luminescence. J. M. Stanley,<br />
B. J. Holliday<br />
4:35 327. Buckyball maracas: <strong>Chemical</strong> and<br />
electrochemical properties of trimetallic<br />
nitride endohedral fullerenes.<br />
L. Echegoyen, N. Chen, J. Pinzin<br />
4:55 328. Physical properties of PbEuS<br />
nanocrystals. S. Somarajan,W.He,<br />
D. Koktysh, J. Dickerson<br />
5:15 Concluding Remarks<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Bioinorganic Chemistry<br />
DNA, RNA and Enzymes<br />
M. Millar, Organizer<br />
C. Goldsmith, Presiding<br />
1:30 329. Silver and its roles in combating<br />
diseases. J. R. Ellis<br />
1:50 330. Photo-enhanced oxidative DNA<br />
cleavage with non-heme iron complexes.<br />
Q. Li, G. Roelfes<br />
2:10 331. Two metals are better than one:<br />
Interactions between dinuclear metal<br />
complexes and quadruplex DNA.<br />
R. Vilar, K. Suntharalingam<br />
2:30 332. Computational study of the<br />
nucleobase electronic structure dynamics:<br />
How to do a fast but accurate job.<br />
S. Keinan, R. Venkatramani, A. Balaeff,<br />
D. N. Beratan<br />
2:50 333. Hydrolysis of plasmid DNA by<br />
metal complexes of modified cyclen.<br />
I. O. Kady<br />
3:10 334. Turning genes on and off with<br />
light. B. Ruble, J. L. Richards, X. Tang,<br />
J. Griepenburg, I. J. Dmochowski<br />
3:30 Intermission<br />
3:40 335. Mechanism of assembly of the dimanganese(III)-tyrosyl<br />
radical cofactor of<br />
Escherichia coli class Ib ribonucleotide<br />
reductase. J. A. Cotruvo,J.Stubbe<br />
4:00 336. Site-specific incorporation of 3-nitrotyrosine<br />
as a probe of pK a perturbation<br />
of redox-active tyrosines in ribonucleotide<br />
reductase. K. Yokoyama, U. Uhlin,<br />
J. Stubbe<br />
4:20 337. Characterization of radical intermediates<br />
on the PCET pathway in aminotyrosine-substituted<br />
ribonucleotide reductases.<br />
E. C. Minnihan,<br />
M. R. Seyedsayamdost, J. Stubbe<br />
4:40 338. Identification of a radical intermediate<br />
in the catalytic cycle of methyl-coenzyme<br />
M reductase. M. Dey,X.Li,<br />
J. Telser, G. Gerfen, B. M. Hoffman,<br />
S. W. Ragsdale<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
PUI/Community College Nanoscience<br />
S. Wong, Organizer, Presiding<br />
1:30 339. Unusual phenomena at nanometer-sized<br />
electrochemical interfaces.<br />
M. V. Mirkin, J. Velmurugan<br />
2:00 340. Nanostructured 3D architectures<br />
incorporating bioactivity.<br />
A. S. Harper-Leatherman, M. Iftikhar,<br />
A. Ndoi, S. J. Scappaticci<br />
2:30 341. Immobilization of inorganic nanoparticles<br />
into smart polymer nanogels for<br />
integration of sensing, cell imaging, and<br />
controlled drug delivery. W. Wu,J.Shen,<br />
P. Banerjee, S. Zhou<br />
3:00 Intermission<br />
3:20 342. Directed self-assembly within laponite<br />
nanoscaffolds. M. E. Hagerman<br />
3:50 343. Silver nanoparticle thin films: Factors<br />
influencing formation and stability.<br />
N. T. Flynn,M.I.Vara<br />
4:20 344. Formation of Tris(trimethoxysilylpropyl)<br />
Isocynurate (TTPI) capped palladium<br />
nanoparticles onto single-walled<br />
carbon nanotubes. T. Hemraj-Benny,<br />
M. Chauhan, C. Wong, E. Kim<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Commemoration of the Founding of the<br />
ACS Journal Organometallics<br />
Synthesis, Devices, Hydrogen, Catalysis<br />
D. Lichtenberger, Organizer<br />
T. Marks, Presiding<br />
2:00 345. Luminescent organometallics:<br />
From design to assembly and functions.<br />
V. W. Yam<br />
2:30 346. Activation of dihydrogen by pentaarylboroles.<br />
W. Piers,C.Fan,<br />
L. Mercier, A. Houghton, M. Parvez<br />
3:00 347. Molecular catalysts for oxidation<br />
of hydrogen and production of hydrogen:<br />
Shoving protons around with pendant<br />
amines. R. M. Bullock,J.Y.Yang,<br />
E. S. Wiedner, K. D. Welch, D. L. DuBois<br />
3:30 Intermission<br />
3:45 348. Reactivity studies on M(� 5 -<br />
C 5Me 5) complexes (M � Rh, Ir) of a cyclometalated<br />
aryl phosphine ligand.<br />
E. Carmona<br />
4:15 349. PSiP-Pincer palladium complexes<br />
for innovative catalytic reactions.<br />
N. Iwasawa<br />
4:45 350. Molecular magnesium(I) complexes:<br />
From chemical landmarks to versatile<br />
reagents. C. Jones<br />
5:15 351. Carbene-stabilization of highly reactive<br />
diatomic molecules.<br />
G. H. Robinson<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Inorganic Materials: Electrochemistry and<br />
Battery Applications<br />
A. Marschilok, E. Takeuchi, Organizers<br />
K. Takeuchi, Organizer, Presiding<br />
2:00 352. Synthesis, characterization and<br />
electrochemical properties of silver hollandite<br />
(Ag xMn 8O 16). K. J. Takeuchi,<br />
S. Zhu, A. C. Marschilok, E. S. Takeuchi<br />
2:30 353. Materials challenges and opportunities<br />
of lithium-ion battery technology.<br />
A. Manthiram<br />
3:00 354. Science and practical performance<br />
of metal fluoride nanocomposites<br />
for advanced energy storage. F. Badway,<br />
N. Pereira, A. Gmitter, I. Plitz, L. Wu,<br />
G. G. Amatucci<br />
3:30 355. Advanced Li-ion battery cathode<br />
materials for vehicle technologies.<br />
M. M. Doeff, T. Conry, K. Kam, A. Chern<br />
4:00 356. Targeting new materials.<br />
K. R. Poeppelmeier<br />
4:30 357. Synthesis, characterization and<br />
electrochemical properties of magnetite<br />
(Fe 3O 4). S. Zhu, A. C. Marschilok,<br />
E. S. Takeuchi, K. J. Takeuchi<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Inorganic Spectroscopy and<br />
Electrochemistry<br />
S. Ronco, Organizer<br />
H. Patterson, Presiding<br />
2:00 358. Spectroscopic study of heterometallic<br />
d 8 -d 10 and d 10 -d 10 exciplex nanoclusters<br />
doped in alkali halide single crystals.<br />
H. H. Patterson, F. Baril-Robert,<br />
X. Li, D. A. Welch, C. L. Larochelle<br />
2:20 359. Spectroscopic and electronic<br />
structure studies of copper (II) binding to<br />
His111 in the human prion protein fragment<br />
106-115: Evaluating the role of protons<br />
and methionine residues.<br />
L. Rivillas-Acevedo, R. Grande-Aztatzi,<br />
I. Lomelí, E. Barrios, S. Teloxa, J. García,<br />
A. Vela, L. Quintanar<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–65
INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
2:40 360. Influence of morpholgy and processing<br />
on X-ray photoelectron spectroscopic<br />
characterization of SrO-CaO-<br />
ZnO-SiO2 bioglass. F. R. Laffir,<br />
A. W. Wren, M. R. Towler<br />
3:00 Intermission<br />
3:10 361. Identification and quantification of<br />
oxygen containing surface functional<br />
groups on carbon materials by X-ray absorption<br />
near edge structure (XANES)<br />
spectroscopy. Y. Chen,K.Kim,P.Zhu<br />
3:30 362. Developing turn-on fluorescent<br />
sensors for iron imaging in live neuronal<br />
cells. Y. Wei, Z. Aydin, Y. Zhang, Z. Liu,<br />
M. Guo<br />
3:50 363. Na-ion cathode electrodes for grid<br />
scale energy storage. Y. Fan, T. Gardner,<br />
V. Abdelsayed<br />
4:10 364. Electrogenerated chemiluminescence<br />
of Pt(II) complexes and corresponding<br />
metallopolymers. X. Chen,<br />
X. Yang, B. J. Holliday<br />
4:30 365. Non-noble metal catalysts impregnated<br />
in chemically reduced graphene<br />
for oxygen reduction reaction.<br />
H. Byon, J. Suntivich, S. Yang<br />
AES Science and Technology<br />
Hydrogen as a Resource Sponsored by<br />
COMSCI, Cosponsored by CATL<br />
(probationary), FUEL, I&EC, INOR, and PMSE<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
Undergraduate Research Posters<br />
Inorganic Chemistry Sponsored by CHED,<br />
Cosponsored by INOR and SOCED<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
B. Donovan-Merkert, M. Millar, Organizers<br />
8:00–10:00<br />
140, 142, 150, 154, 155, 160, 161, 168, 187,<br />
188, 191, 194, 195, 196, 199, 203, 205,<br />
207, 209, 212, 213, 215, 223, 227, 228,<br />
229, 230, 231, 234, 235, 239, 245, 248,<br />
250, 252, 253, 254. See previous listings.<br />
484, 487, 492, 494, 502, 503, 521, 524, 529,<br />
531, 534, 538, 539, 550, 556, 674, 734,<br />
736, 737, 744, 745, 751, 753, 754, 761,<br />
764, 766, 767, 770, 772, 775, 779, 782,<br />
791, 795. See subsequent listings.<br />
TUESDAY MORNING<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Ligand Design and Metal Behavior<br />
L. Doerrer, M. Millar, S. Koch, Organizers<br />
T. Agapie, Presiding<br />
8:30 366. Multinuclear metal complexes<br />
supported by diphenylbenzene and triphenylbenzene<br />
frameworks decorated<br />
with P, N, and O donors. T. Agapie,<br />
A. Velian, S. Lin, E. Tsui, J. Kanady<br />
9:00 367. Masked three-coordinate vanadium(II)<br />
complexes. B. L. Tran, M. Pink,<br />
D. J. Mindiola<br />
9:30 368. Small molecule activation at reactive<br />
iron and uranium centers: Control of<br />
reactivity via molecular architecture.<br />
K. Meyer<br />
10:00 Intermission<br />
10:10 369. Tuning metal ligands for specific<br />
songs. K. N. Raymond<br />
66–TECH<br />
‡ Cooperative Cosponsorship<br />
10:50 370. Exploring the feasibility of N 2 fixation<br />
at single and multiple iron sites.<br />
J. C. Peters<br />
11:20 371. Iron–TAML activators: Designing<br />
ligands to achieve peroxidase mimics.<br />
T. J. Collins<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Bioinorganic Chemistry<br />
M. Millar, S. Koch, Organizers<br />
A. Barrios, K. Franz, Presiding<br />
8:30 372. Targeting DNA mismatches with<br />
metalloinsertors. J. K. Barton<br />
9:10 373. X-ray structure and mechanism of<br />
RNA polymerase II stalled by a monofunctional<br />
antineoplastic agent. D. Wang,<br />
G. Zhu, X. Huang, S. J. Lippard<br />
9:30 374. Probing the outer reaches of the<br />
folding funnel of c-type cytochromes.<br />
B. E. Bowler, T. A. Dar, F. O. Tzul,<br />
M. L. Finnegan, K. A. Khan,<br />
T. A. Danielson<br />
9:50 375. Molecular probes put tyrosine<br />
phosphorylation in the spotlight.<br />
A. M. Barrios<br />
10:10 376. Nickel binding and release by<br />
Escherichia coli hydrogenase biosynthetic<br />
proteins. D. B. Zamble,<br />
H. Kaluarachchi, K. C. Chan Chung,<br />
F. Cai<br />
10:30 Intermission<br />
10:40 377. Cu(II) complexes of (oligo)nucleotides:<br />
Structure determination with the<br />
help of pulsed EPR spectroscopy.<br />
M. Santangelo, P. M. Antoni,<br />
A. Medina-Molner, G. Mitrikas,<br />
G. Jeschke, B. Spingler<br />
11:00 378. Evolutionary constraint on DNA<br />
structure in the human genome.<br />
T. D. Tullius, S. C. Parker,<br />
E. H. Margulies<br />
11:20 379. Insights into the role of histidine<br />
in Ctr1-dependent copper uptake.<br />
K. J. Franz,K.L.Haas<br />
11:40 380. Judicious placement of a methylene<br />
or methyl group on a ligand for copper:<br />
Subsequent copper complex redox<br />
behavior or dioxygen chemistry.<br />
K. D. Karlin<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Inorganic Catalysts<br />
B. Donovan-Merkert, Organizer<br />
C. Berlinguette, Presiding<br />
8:30 381. Design of a molecularly-imprinted<br />
Ru-complex catalyst for regio- and<br />
shape-selective limonene epoxidation.<br />
S. Muratsugu, Y. Yang, M. Kinoshita,<br />
M. Tada<br />
8:50 382. Electrocatalytic oxygen reduction<br />
mediated by metalo-hangman-xantheneporphyrin<br />
and –corrole complexes.<br />
R. McGuire, D. K. Dogutan,<br />
Y. Shao-Horn, D. G. Nocera<br />
9:10 383. New visible light photocatalyst,<br />
ZnBiGaO 4 for photocatalytic solar hydrogen<br />
production. J. Baeg,S.Moon,<br />
K. Kong<br />
9:30 384. Electrocatalytic C-H bond activation<br />
with Ru: Transferring reactivity from<br />
homogeneous solution to nanomaterial<br />
electrode surfaces. J. F. Hull,Z.Chen,<br />
T. J. Meyer<br />
9:50 385. Self-healing oxygen-evolving catalyst.<br />
D. A. Lutterman, Y. Surendranath,<br />
D. G. Nocera<br />
10:10 Intermission<br />
10:20 386. Critical examination of catalytic<br />
water oxidation by mononuclear complexes.<br />
C. P. Berlinguette<br />
10:40 387. Preparation of supported intermetallic<br />
AuCu and AuCu 3 nanoparticle<br />
catalyst for CO oxidation. J. C. Bauer,<br />
D. Mullins, S. H. Overbury, S. Dai<br />
11:00 388. Tailoring Pt-bimetallic alloy<br />
nanoparticles for electrocatalytic reduction<br />
of oxygen. C. Wang,<br />
V. R. Stamenkovic, N. M. Markovic<br />
11:20 389. From surface-inspired oxovanadium<br />
silsesquioxane models to active<br />
catalysts for the oxidation of alcohols<br />
with O 2: The cinnamic acid/metavanadate<br />
system. C. Limberg,C.Ohde<br />
11:40 390. Aerobic alcohol oxidation catalyzed<br />
by vanadium(V) complexes.<br />
S. K. Hanson, R. T. Baker, J. C. Gordon,<br />
B. L. Scott, L. A. Silks, D. L. Thorn, R. Wu<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Commemoration of the Founding of the<br />
ACS Journal Organometallics<br />
Synthesis and Catalysis<br />
D. Lichtenberger, Organizer<br />
D. Sweigart, Presiding<br />
9:00 391. Homogeneous and biocatalysis in<br />
concert: Hybrids of ECE-pincer organometallics<br />
and lipases. G. van Koten<br />
9:30 392. Direct �-alkylation of amines: Catalytic<br />
hydroaminoalkylation with amidate<br />
complexes. L. L. Schafer<br />
10:00 393. F-block complexes with labile Nheterocyclic<br />
carbenes: Small molecule<br />
activation and unusual new bonding motifs.<br />
P. L. Arnold, Z. R. Turner,<br />
A. I. Germeroth, S. Zlatogorsky,<br />
S. M. Mansell, B. F. Perandones,<br />
R. M. Bellabarba, R. P. Tooze<br />
10:30 Intermission<br />
10:45 394. Pursuit of a terminal uranium nitride<br />
using mixed-ligand frameworks.<br />
J. L. Kiplinger<br />
11:15 395. Subtleties in organometallic<br />
bond activation. W. D. Jones<br />
11:45 396. Reactions of frustrated Lewis<br />
pairs with alkenes and alkynes.<br />
C. Mömming, C. Chen, P. Feldhaus,<br />
O. Ekkert, T. Voss, G. Kehr, R. Fröhlich,<br />
G. Erker<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Inorganic Materials: Electrochemistry and<br />
Battery Applications<br />
E. Takeuchi, K. Takeuchi, Organizers<br />
A. Marschilok, Organizer, Presiding<br />
9:00 397. Novel composite air cathodes for<br />
energy storage. A. C. Marschilok,S.Lee,<br />
S. Zhu, C. Milleville, C. Lee, P. Chen,<br />
E. S. Takeuchi, K. J. Takeuchi<br />
9:30 398. Using disorder and architectural<br />
design to improve electrical energy storage<br />
devices. J. W. Long, B. P. Hahn,<br />
M. B. Sassin, J. Wallace, K. A. Pettigrew,<br />
M. Osofsky, A. N. Mansour,<br />
D. R. Rolison<br />
10:00 399. Electrodeposition as a key tool<br />
for the fabrication of 3D lithium-ion rechargeable<br />
batteries. A. L. Prieto,<br />
T. S. Arthur, D. C. Johnson, J. M. Mosby<br />
10:30 400. Lithium phosphorus oxynitride<br />
solid electrolyte: Applications beyond thin<br />
film batteries. N. J. Dudney,Y.Kim,<br />
W. Tenhaeff, E. Herbert, G. Veith<br />
11:00 401. Catalysis studies and electrode<br />
design considerations for Lithium-air batteries.<br />
Y. Lu, J. R. Harding, Y. Tsukada,<br />
H. A. Gasteiger, Y. Shao-Horn<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
ACS Inorganic Nanoscience Award:<br />
Symposium in Honor of Frank Osterloh<br />
D. Nelson, Organizer, Presiding<br />
9:00 History of Nanoscience Award and Introduction<br />
of Dr. Frank Osterloh<br />
9:10 402. Making fuel from sunshine: Inorganic<br />
nanomaterials for photocatalytic<br />
hydrogen production. F. E. Osterloh<br />
9:55 403. New functional materials from topochemical<br />
reactions of layer perovskites.<br />
C. N. Henderson, S. Kannan,<br />
E. C. Sklute, M. Eguchi, Y. Kobayashi,<br />
J. Kwak, T. E. Mallouk<br />
10:25 Intermission<br />
10:40 404. Applications of coordination<br />
chemistry in the synthesis of single-molecule<br />
magnets. J. D. Rinehart, T. Harris,<br />
D. E. Freedman, J. M. Zadrozny,<br />
K. R. Meihaus, X. Feng,<br />
P. Dechambenoit, B. Bechlars,<br />
D. M. Jenkins, D. M. D’Alessandro,<br />
J. R. Long<br />
11:10 405. New strategies for improving<br />
photoresponse for solar energy conversion<br />
using nanocomposites. J. Z. Zhang<br />
11:40 406. Pathway from a molecular precursor<br />
to silver nanoparticles: The prominent<br />
role of aggregative growth.<br />
V. N. Richards, N. P. Rath, W. E. Buhro<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Organometallic Chemistry<br />
Applications to Organic Transformations<br />
N. Radu, Organizer<br />
D. Balcells, Presiding<br />
9:00 407. Development of one-pot, single<br />
solvent processes for aromatic C-H borylation/Suzuki-Miyaura<br />
cross-coupling sequences.<br />
P. Harrisson, J. Morris,<br />
P. G. Steel, T. B. Marder<br />
9:20 408. Oxidation of olefins with hydrogen<br />
peroxide and polyoxometalates in ionic<br />
liquids and fluorinated alcohols as “magic<br />
solvents”. M. Carraro, S. Berardi,<br />
M. Gardan, M. Bonchio, G. Scorrano,<br />
A. Sartorel<br />
9:40 409. Ionic liquids in transition metal catalysis:<br />
An efficient route to valuable compounds.<br />
P. S. Bauerlein,T.L.terLaak,<br />
P. de Voogt, C. Müller, D. Vogt,<br />
I. J. Fairlamb, J. M. Slattery,<br />
A. C. Whitwood, A. F. Lee<br />
10:00 Intermission<br />
10:05 410. Chiral SPAN ligands: A new toolbox<br />
of ligands for asymmetric catalysis.<br />
N. D. Clément, O. Jacquet,<br />
P. W. van Leeuwen<br />
10:25 411. C-H oxidation by Mn porphyrins:<br />
A DFT study on the nature of the active<br />
species and the reaction mechanism.<br />
D. Balcells, C. Raynaud, O. Eisenstein,<br />
R. H. Crabtree<br />
10:45 412. Rational design approach toward<br />
developing chiral diNHC ligands: New<br />
Pd(NHC) complexes and their use in enantioseletive<br />
cross coupling reactions.<br />
M. S. Jeletic, I. Ghiviriga, K. A. Abboud,<br />
A. S. Veige<br />
11:05 413. Carbenes by elimination of �-halosilanes<br />
under mild conditions.<br />
C. M. Loeschel, N. T. Allison<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
TUESDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
ExxonMobil Solid State Chemistry Faculty<br />
Fellow Award<br />
Symposium in Honor of Sarbajit Banerjee<br />
S. Brock, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:40 414. Understanding the influence of finite<br />
size on the phase transitions and<br />
phase stabilities of early transition metal<br />
oxides. S. Banerjee, L. Whittaker,<br />
C. J. Patridge, S. W. Depner,<br />
J. M. Velazquez, K. R. Kort<br />
2:10 415. Nanomaterials for energy storage.<br />
M. Whittingham<br />
2:40 416. <strong>Chemical</strong> strategies in nanoscience.<br />
S. S. Wong<br />
3:10 Intermission<br />
3:25 417. Using local structural probes to<br />
understand and optimize the functioning<br />
of lithium ion battery materials. B. Key,<br />
R. Bhattacharyya, N. Trease, C. P. Grey<br />
3:55 418. Nanomaterials composed of<br />
nanocomponents: Nanoparticle supercrystals<br />
and hybrids. I. P. Herman<br />
4:25 419. Discovery and characterization of<br />
novel materials for electrical energy generation<br />
and storage: Fuel cells, batteries<br />
and super-caps. H. D. Abruña<br />
4:55 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Ligand Design and Metal Behavior<br />
M. Millar, S. Koch, Organizers<br />
L. Doerrer, Organizer, Presiding<br />
1:30 420. Monobridged, binuclear metallacycles<br />
supported by third generation<br />
bis(1-pyrazolyl)methane ligands: Unusual<br />
magnetic properties. D. L. Reger,<br />
E. A. Foley, R. P. Watson, A. E. Pascui,<br />
M. D. Smith<br />
2:00 421. Design of phosphine ligands for<br />
electrocatalytic carbon dioxide reduction<br />
and formate oxidation. D. DuBois,<br />
B. Boro, J. Linehan, J. Roberts, B. Galan,<br />
J. Schoffel, C. Kubiak<br />
2:30 422. Bimetallic cooperativity in catalysis<br />
based on a binuclating tetraphosphine<br />
ligand. G. G. Stanley, D. Polakova,<br />
A. R. Barnum, C. T. Alexander,<br />
Z. S. Wilson, M. A. Peterson<br />
3:00 Intermission<br />
3:10 423. Evolution from TMPA (� TPA) in<br />
copper-dioxygen and heme-copper-dioxygen<br />
coordination chemistry.<br />
K. D. Karlin<br />
3:50 424. Construction and properties of<br />
binuclear Ni-Fe complexes in relation to<br />
the active site of Ni-Fe-S carbon monoxide<br />
dehydrogenase. D. Huang,<br />
R. H. Holm<br />
4:20 425. Coordination chemistry with trisphenolate,<br />
thiolate, and selenolate amine<br />
and phosphine tripod ligands. S. A. Koch<br />
4:50 426. Ligand design elements that promote<br />
generation of high-valent nonheme<br />
iron-oxo species. L. Que, Jr.<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Bioinorganic Chemistry<br />
M. Millar, S. Koch, Organizers<br />
A. Valentine, J. Wilker, Presiding<br />
1:30 427. Active site of particulate methane<br />
monooxygenase. R. Balasubramanian,<br />
S. M. Smith, M. A. Culpepper, S. Rawat,<br />
L. A. Yatsunyk, T. L. Stemmler,<br />
A. Rosenzweig<br />
2:10 428. Bioinorganic approaches to renewable<br />
energy catalysis. C. J. Chang<br />
2:30 429. Synthesis and reactivity of manganese<br />
and iron complexes with methylated<br />
derivatives of bis(2-pyridylmethyl)-<br />
1,2-ethanediamine (bispicen).<br />
C. M. Coates, K. Hagan, C. A. Mitchell,<br />
C. R. Goldsmith<br />
2:50 430. Titanium in the environment: Siderophore<br />
coordination and photoreactivity.<br />
K. L. Batchler, K. E. Cole,<br />
A. M. Valentine<br />
3:10 431. Development of multifunctional<br />
small molecules as chemical tools and<br />
potential therapeutics for Alzheimer’s disease.<br />
M. Lim<br />
3:30 432. Escaping the octopus-like grasp<br />
of iron-oxygen chemistry: Studies on marine<br />
biological materials. J. D. White,<br />
C. R. Matos-Perez, J. R. Burkett,<br />
A. O. Mattes, T. W. McCarthy,<br />
J. J. Wilker<br />
3:50 433. Recognition of Zn 2� by the conjugates<br />
of calixarenes and carbohydrates<br />
and the role of the corresponding complex<br />
in biorelevant systems. C. P. Rao<br />
4:10 434. Development of caged-complexes<br />
for studying signaling and homeostasis of<br />
metal ions. S. C. Burdette<br />
4:30 435. Comparison of the reactivity<br />
chemistry of mononuclear and binuclear<br />
non-heme ferrous complexes with oxygen,<br />
peroxides, and oxygen atom donor<br />
molecules. J. P. Caradonna<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Inorganic Catalysts<br />
B. Donovan-Merkert, Organizer<br />
N. Abrams, Presiding<br />
1:30 436. Studies of the effects of hydrogen<br />
with the hopes of improving the catalytic<br />
reduction of dinitrogen to ammonia at a<br />
single molybdenum center. B. S. Hanna,<br />
R. R. Schrock<br />
1:50 437. Cross-coupling with tricarbonylchromium-coordinated<br />
benzyllithiums: A<br />
new approach to polyarylmethane derivatives.<br />
G. I. McGrew, J. Temaismithi,<br />
P. J. Carroll, P. J. Walsh<br />
2:10 438. One-pot synthesis of catalytically<br />
stable and active nanoreactors: Encapsulation<br />
of size-controlled nanoparticles<br />
within a hierarchically macroporous core<br />
@ordered mesoporous shell system.<br />
B. Su,X.Yang<br />
2:30 439. Investigation of nanostructured<br />
mixed monolayer protected nanoparticles<br />
as catalytic platforms. A. Ghosh,<br />
S. Basak, B. H. Wunsch, R. Kumar,<br />
F. Stellacci<br />
2:50 440. Spinel-type cobalt-manganesebased<br />
mixed oxide as sacrificial catalyst<br />
for the high yield synthesis of homogeneous<br />
carbon nanotubes. J. Tessonnier,<br />
M. Becker, W. Xia, F. Girgsdies,<br />
R. Blume, L. Yao, D. Su, M. Muhler,<br />
R. Schlögl<br />
3:10 441. Structures and reaction mechanisms<br />
of propene oxide isomerization to<br />
propanal on H-FER zeolite: A theoretical<br />
study using the newly developed density<br />
functional theory. B. Boekfa, T. Maihom,<br />
S. Wannakao, K. Bobuatong,<br />
J. Limtrakul<br />
3:30 442. Reaction mechanisms of ethene<br />
formation via ethanol dehydration catalyzed<br />
by Fe-ZSM-5 zeolite: An ONIOM<br />
study with an M06-L functional.<br />
T. Maihom, B. Boekfa, S. Wannakao,<br />
J. Limtrakul<br />
3:50 443. Spinel ferrite nanoparticles as selective<br />
microwave absorbers for heterogeneous<br />
oxidation catalysis.<br />
M. Thompson, P. Chem,<br />
L. J. van de Burgt, A. E. Stiegman<br />
4:10 444. Novel oxynitride compounds from<br />
cellulose biotemplates. A. Levine,<br />
J. M. MCEnaney, N. M. Abrams<br />
4:30 445. Synthesis of different CeO 2 structures<br />
on mesoporous silica and characterization<br />
of the reduction properties and<br />
the catalytic behavior. J. Strunk,<br />
W. C. Vining, A. T. Bell<br />
4:50 446. Investigation on the contradictory<br />
gas sensing behaviors of semiconducting<br />
ZnO and Zn 2SnO 4 single crystalline<br />
nanowires arrays. A. Cai<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Optoelectronic Characterization<br />
S. Wong, Organizer<br />
S. Lee, Presiding<br />
1:30 447. Photo-induced electron transfer in<br />
chromophore-functionalized quantum<br />
sized gold clusters. K. Kwak,<br />
M. Devadas, H. Lee, G. Ramakrishna,<br />
D. Lee<br />
1:50 448. Fluorophore functionalized metal<br />
clusters. M. Devadas, D. Lee, E. Sinn<br />
2:10 449. Upconversion luminescence and<br />
X-ray-excited optical luminescence<br />
(XEOL) of lanthanide doped Yttrium oxide<br />
nanocrystals. I. N. Stanton, J. A. Ayres,<br />
M. J. Therien<br />
2:30 450. Ab initio study of multiple exiton<br />
generation (MEG) in quantum dots.<br />
Z. Zhang, P. Zimmerman, C. Musgrave<br />
2:50 451. Surface-enhanced Raman spectroscopy<br />
with silver nanocube dimers:<br />
Experiment and calculation. S. Lee,<br />
G. S. Lang, L. Hung, J. E. Cornett,<br />
I. D. Mayergoyz, O. Rabin<br />
3:20 Intermission<br />
3:40 452. Solar energy conversion with selforganized<br />
regular arrays of S-doped TiO 2<br />
nanotubes. Y. Shin, S. Lee<br />
4:10 453. Probing dynamics of photoinduced<br />
charge transfer in heterodimers<br />
composed of CdSe/ZnS quantum dots<br />
and fullerene derivatives by single molecule<br />
spectroscopy. M. Cotlet,Z.Xu<br />
4:30 454. Single-molecule optical detection<br />
of nitroaromatic compounds by carbon<br />
nanotubes. D. A. Heller, G. W. Pratt,<br />
J. Zhang, N. Nair, A. J. Hansborough,<br />
A. A. Boghossian, N. F. Reuel,<br />
P. W. Barone, M. S. Strano<br />
4:50 455. Exciton antennae and concentrators<br />
from core-shell and corrugated carbon<br />
nanotube filaments of homogeneous<br />
composition. J. Han, G. L. Paulus,<br />
R. Maruyama, D. A. Heller, W. Kim,<br />
P. W. Barone, C. Lee, J. Choi, M. Ham,<br />
C. Song, C. Fantini, M. S. Strano<br />
5:10 456. Anomalously large reactivity of<br />
single graphene layers and edges toward<br />
electron transfer chemistries. R. Sharma,<br />
J. Baik, C. Perera, M. S. Strano<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Commemoration of the Founding of the<br />
ACS Journal Organometallics<br />
Synthesis and Catalysis<br />
D. Lichtenberger, Organizer, Presiding<br />
2:00 457. Efficient iron catalyst for the chemoselective<br />
hydrogenation of aldehydes<br />
and ketones. C. P. Casey,H.Guan,<br />
A. C. Atesin<br />
2:30 458. Multiheterometallic transition<br />
metal complexes: Going for records.<br />
H. Lang<br />
3:00 459. Custom polyethylene by molecular<br />
design. J. C. Stevens<br />
3:30 460. Some memories and then some<br />
new chemistry of single walled carbon<br />
nanotubes. M. L. Green<br />
4:00 Close of symposium D. Seyferth,<br />
J. Gladysz<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Main Group Chemistry<br />
B. Donovan-Merkert, Organizer<br />
J. J. Weigand, Presiding<br />
2:00 461. Lewis acidic properties of a bifunctional<br />
stibonium/borane. C. R. Wade,<br />
F. P. Gabbaï<br />
2:20 462. Use of group 6 carbonyl reagents<br />
to stabilize phosphonium and siliconium<br />
cationic species. J. M. Beres,<br />
A. M. Leigh, M. J. Panzner, V. Scionti,<br />
B. D. Wright, C. Wesdimiotis,<br />
W. J. Youngs, C. A. Tessier<br />
2:40 463. Phosphorus-containing<br />
calix[5]arene metal complexes: Catalysis<br />
and a rare � 6 palladium geometry.<br />
B. Rios, M. Lattman<br />
3:00 Intermission<br />
3:10 464. Heavy atom effects in thienyl<br />
BODIPY systems. K. Kim, T. Jun,<br />
S. Khatua, S. Choi, D. G. Churchill<br />
3:30 465. Capturing In � monomers in a neutral<br />
weakly coordinating environment.<br />
T. Jurca, S. I. Gorelsky, I. Korobkov,<br />
G. P. Yap, D. S. Richeson<br />
3:50 466. Transition metal-like behavior of<br />
mercury in a dinuclear complex featuring<br />
a mercury3antimony interaction. T. Lin,<br />
C. R. Wade, F. P. Gabbaï<br />
4:10 467. Formation of cationic phosphorus<br />
clusters by insertion of phosphenium cations<br />
into P-P bonds of the P 4 tetrahedron.<br />
J. J. Weigand, M. H. Holthausen<br />
TUESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Inorganic Chemistry<br />
M. Millar, Organizer<br />
7:00–9:00<br />
468. Synthesis of biologically relevant manganese<br />
clusters by reductive aggregation.<br />
W. Lo, S. Vaddypally, P. Müller,<br />
W. H. Armstrong<br />
469. Trinuclear manganese complexes relevant<br />
to Photosystem II. S. Vaddypally,<br />
W. Lo, L. Greb, W. H. Armstrong<br />
470. Influence of platinum-based anticancer<br />
agents on nucleosome mobility. G. Zhu,<br />
S. J. Lippard<br />
471. Elucidation of the reactivity of nitric oxide<br />
with polypyrridyl copper(II) complexes.<br />
J. Rosenthal, J. Kozhukh,<br />
S. J. Lippard<br />
472. Visualization of endogenous nitric oxide<br />
in live cells using cell-trappable fluorescent<br />
probes. M. D. Pluth, L. E. McQuade,<br />
S. J. Lippard<br />
473. Pt(IV) encapsulated PLGA-PEG nanoparticles<br />
for targeting integrins in tumors.<br />
N. J. Graf, N. Kolishetti, D. R. Bielenberg,<br />
O. C. Farokhzad, S. J. Lippard<br />
474. Thermodynamic studies of DNA duplexes<br />
containing the spiroiminodihydantoin<br />
lesion. E. R. Jamieson,<br />
F. Chinyengetere, M. Dwarakanath,<br />
M. Ng, M. Thida, C. Gao, M. Martei<br />
475. Solid state coordination chemistry: Organic-inorganic<br />
hybrid materials constructed<br />
from copper 5-(4�-pyridyl)tetrazole<br />
networks with embedded molybdate<br />
clusters. S. Jones,H.Liu,<br />
C. C. O’Connor, J. Zubieta<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–67
INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
476. Ratiometric detection of mercury ion in<br />
water: Accelerated response kinetics of<br />
azo chromophores having ethynyl ligand<br />
tethers. H. Lee, J. Jo, H. Park, D. Lee<br />
477. Phenylalanine complex of glucosyl-C2salicilylimino<br />
conjugate: Nanofiber formation<br />
and its applications by spectroscopy,<br />
microscopy, and coputational modeling.<br />
C. P. Rao<br />
478. Biologically relevant multinuclear manganese<br />
complexes. X. Zhang,W.Lo,<br />
S. Vaddypally, W. H. Armstrong<br />
479. Structural investigations into the oxometalate<br />
organodiarsonate system of organic/inorganic<br />
hybrid materials.<br />
K. Darling, E. Burkholder, J. Zubieta<br />
480. Rapid bio-orthogonal inverse electron<br />
demand cycloadditions for biological imaging.<br />
S. A. Hilderbrand, N. K. Devaraj,<br />
M. R. Karver, R. Weissleder<br />
481. Reactions of cobalt(ii) and nickel(ii)<br />
complexes containing binucleating macrocyclic<br />
and pyridine ligands: Structural<br />
and spectroscopic studies. J. M. Kamm,<br />
T. M. Buetow, P. E. Fanwick, H. C. Prusi,<br />
T. J. Smith<br />
482. Solid-state simulation of the vibrational<br />
modes and intensities of simple vanadium<br />
phosphates. S. L. Pellizzeri,<br />
T. Korter, J. Zubieta<br />
483. Steric influences on the chemical and<br />
spectroscopic behavior of copper<br />
phenanthrolines. S. P. Watton<br />
484. Activation of dinitrogen by multinuclear<br />
vanadium complexes at room temperature.<br />
S. Banerjee, W. H. Armstrong<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
General Inorganic Chemistry<br />
B. Donovan-Merkert, M. Millar, Organizers<br />
7:00–9:00<br />
485. Palladium catalyzed hydration of nitriles<br />
in water: Synthesis and characterization<br />
of palladium(II) complexes of 4-cyanopyridine<br />
and 4-pyridinecarboxamide.<br />
R. A. Adrian, N. Sanchez, D. R. Powell,<br />
J. A. Walmsley<br />
486. Synthesis and properties of nitrogen<br />
containing metalloles. L. Emerson,<br />
N. Benfaremo, J. R. Ford, J. L. Mullin,<br />
C. K. Prudente, H. J. Tracy<br />
487. Reactions of gold(III) complexes with<br />
olefins in aqueous media. C. Rezsnyak,<br />
J. D. Atwood<br />
488. Progress towards the synthesis of<br />
group 14 metallole-based immunosensors.<br />
N. Mahoney, N. Benfaremo,<br />
J. R. Ford, J. L. Mullin, C. K. Prudenté,<br />
H. J. Tracy<br />
489. Progress on the fabrication of group 14<br />
metallole optoelectronic devices.<br />
A. L. Szendrei, N. Benfaremo, J. R. Ford,<br />
J. L. Mullin, C. K. Prudenté,H. J. Tracy<br />
490. Synthesis of novel group 14 metalloles.<br />
D. Lane, N. Benfaremo, J. R. Ford,<br />
J. L. Mullin, C. K. Prudenté,H. J. Tracy<br />
491. Comparison between density functional<br />
calculations and experimental measurements<br />
of group 14 metalloles.<br />
A. Blanchard, N. Benfaremo, J. R. Ford,<br />
J. L. Mullin, C. K. Prudenté,H. J. Tracy<br />
492. Using copper(I)-catalyzed azide-alkyne<br />
cycloaddition in the creation of triazole<br />
linked multi-porphyrin arrays.<br />
M. J. Leonardi, P. K. Palomaki,<br />
P. H. Dinolfo<br />
493. Investigation into the mechanism of enhanced<br />
reactivity in a film-shear reactor.<br />
B. R. Fox, K. Wiggins, T. Hudnall,<br />
C. W. Bielawski, D. R. Tyler<br />
494. Solvent dielectric effect on metal assisted<br />
thiolate-disulfide exchange: No<br />
free thiolate. A. Chandrasoma,<br />
A. E. Bruce, M. R. Bruce<br />
68–TECH<br />
‡ Cooperative Cosponsorship<br />
495. Optical detection of anions with chromogenic<br />
triorganotin(IV) complexes.<br />
R. Villamil-Ramos, V. Barba,<br />
A. K. Yatsimirsky<br />
496. Synthesis and characterization of ruthenium<br />
aqua complexes self assembled on<br />
electrode surfaces. J. Rochford,<br />
D. A. Walsh<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Nanoscience<br />
Non-Carbon One-dimensional Structures<br />
S. Wong, Organizer<br />
7:00–9:00<br />
497. Synthesis of monodisperse PbSe nanorods:<br />
A case for oriented attachment.<br />
W. Koh, C. B. Murray, A. C. Bartnik,<br />
F. W. Wise<br />
498. Production of functional inorganic<br />
nanowire arrays on patterned substrates<br />
for use in electronic devices. S. Patil,<br />
M. Nath<br />
499. Fabrication of multifunctional silica<br />
nanotube by stacking preformed functional<br />
nanoparticles. Y. Zhang, Q. Fang,<br />
I. Hong, E. Lee, S. Seo, S. Son<br />
500. Synthesis and characterization of chromium<br />
oxide nanowires. A. C. Santulli,<br />
M. Feygenson, M. C. Aronson,<br />
S. S. Wong<br />
501. Spatial-controlled growth of zinc oxide<br />
nanowire arrays on surface-modified<br />
seed pattern by inkjet. S. Kim,J.W.Cho<br />
502. Chalcopyrite nanostructures for solar<br />
cells: Fabrication and characterization of<br />
copper indium diselenide (CuInSe 2) nananowires.<br />
E. A. Hernandez, T. E. Mallouk<br />
503. 1D rutile TiO 2 nanorod arrays decorated<br />
with CdSe for solar energy conversion.<br />
J. Bang,P.V.Kamat<br />
504. Dye sensitized TiO 2 nanotube solar<br />
cells with markedly enhanced performance<br />
via rational surface engineering.<br />
J. Wang,Z.Lin<br />
505. Fabrication of 3D ordered arrays of mesoporous<br />
titania spheres. L. Xu,Z.Hua,<br />
Y. Yan, A. A. Zakhidov, R. H. Baughman,<br />
J. Chen<br />
506. Alternate route for large scale synthesis<br />
of boron nitride nanotubes.<br />
A. Chakrabarti, J. Price, J. A. Maguire,<br />
N. S. Hosmane<br />
507. Use of ferric chloride as a solvent to purify<br />
boron nitride nanotube. C. Hung,<br />
J. Hurst<br />
508. Water soluble boron nanorods.<br />
A. Chakrabarti, K. N. Boblak, Y. Liang,<br />
L. M. Kuta, K. J. Krise, J. A. Maguire,<br />
N. S. Hosmane<br />
509. Electronic structure modification of<br />
electrospun titania by Rhodium nanoparaticles.<br />
E. Obuya, W. Harrigan,<br />
W. E. Jones<br />
510. Metal-filled scroll alkoxy and organosilicon<br />
nanopolymers. P. Vassilaras,<br />
M. E. Kenney<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Chemistry of Materials<br />
D. Nelson, M. Millar, Organizers<br />
7:00–9:00<br />
511. Electrochemical oxidation of graphite in<br />
1-ethyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate<br />
(EMI<br />
FAP) / nitromethane electrolyte.<br />
B. Ozmen-Monkul, M. M. Lerner<br />
512. Electrocatalytic carbon dioxide reduction<br />
at thin polymeric films containing either<br />
Pd(0) or Rh(0) particles.<br />
D. R. Weinberg, Z. Chen, A. J. Shearer,<br />
T. J. Meyer<br />
513. Exploring the S � 1 ⁄2 triangular lattice:<br />
Synthesis and properties of<br />
BaAg 2Cu[VO 4] 2. N. E. Amuneke,<br />
D. E. Gheorghe, A. Moeller<br />
514. Thin film optical amplifiers: A highthroughput<br />
approach to synthesis, optical<br />
screening, and crystallization studies.<br />
K. E. Downey, R. B. van Dover<br />
515. Controlling band gap energies in cluster-assembled<br />
materials. S. Mandal,<br />
A. Sen, A. C. Reber, M. Qian,<br />
H. M. Saavedra, P. S. Weiss,<br />
S. N. Khanna<br />
516. Layer-by-layer assembly of molecular<br />
multilayers on electrode surfaces.<br />
A. Krawicz,P.H.Dinolfo<br />
517. Carboxylic acid-functionalized layered<br />
M IV phosphonates: Intercalation, exfoliation,<br />
and applications. H. P. Perry,<br />
J. Law, J. Grunlan, A. Clearfield<br />
518. Effects of an ionically functionalized ligand<br />
on exciton recombination in PbS<br />
nanoparticles. J. M. Zemke, D. R. Tyler<br />
519. Conducting polythiophene fibers grown<br />
from CdTe quantum dot surface.<br />
V. A. Strong, M. Battson, R. B. Kaner<br />
520. Electrochemical oxygen reduction reaction<br />
on different morphology of gold<br />
nanoclusters. J. Kim, N. Sinha,<br />
H. A. Gasteiger, C. Carlton,<br />
K. Hamad-Schifferli, Y. Shao-Horn<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Coordination Chemistry<br />
Characterization and Applications<br />
D. Crans, M. Millar, Organizers<br />
7:00–9:00<br />
521. Application of fluorinated heterometallic<br />
beta-diketonates for the synthesis of<br />
mixed-metal fluorides. A. Navulla,<br />
Z. Wei, J. Yang, H. Zhang, E. V. Dikarev<br />
522. Using nickel(II)-vinylimidazole complex<br />
ions as templates for biologically inspired<br />
“active-sites” in hydrogel networks.<br />
M. R. Bukowski<br />
523. Fluorescent sensors for Zn 2� based on<br />
�-extended dipyrrins: Synthesis and<br />
spectroscopic characterization.<br />
S. Thyagarajan, B. Ghosh,<br />
A. V. Cheprakov, A. Moore,<br />
S. A. Vinogradov<br />
524. Single and two-photon excitation fluorescence<br />
imaging of new zinc(II), copper(II),<br />
gallium(III) and indium(III) bis(thiosemicarbazonato)<br />
complexes for<br />
multimodal imaging of cancer.<br />
R. L. Arrowsmith,J.Zhong,<br />
G. Kociok-Köhn, P. A. Waghorn,<br />
P. Burgos, J. R. Dilworth,<br />
S. W. Botchway, F. I. Aigbirhio,<br />
R. M. Tyrrell, S. I. Pascu<br />
525. Supramolecular architectures and coordination<br />
polymers based on metallacrown<br />
complexes: Magnetic and sorption<br />
properties. A. V. Pavlishchuk,<br />
S. V. Kolotilov, M. Zeller, L. K. Thompson,<br />
I. O. Fritsky, A. W. Addison,A.D.Hunter<br />
526. Computational study of tridentate SNSpincer<br />
complexes: Toward an understanding<br />
of the liver alcohol dehydrogenase<br />
active site. M. A. Lynn,<br />
J. R. Miecznikowski, W. Lo,<br />
A. P. DiMarzio, K. M. Foley, L. C. Keilich,<br />
B. E. O’Loughlin<br />
527. Mechanistic studies of nitrile binding to<br />
Mo and V tris-anilide complexes involved<br />
in N 2 splitting. M. E. Germain,<br />
A. Castonguay, J. J. Curley, J. S. Silvia,<br />
M. Temprado, C. C. Cummins, C. D. Hoff,<br />
E. V. Rybak-Akimova<br />
528. Preparation and properties of<br />
{RuCl 2(NO)[PPh 2(CH 2) n-P(O)Ph 2] 2} � ,n�<br />
1or2.S. E. Knight, L. R. Walton,<br />
D. S. Amenta, J. W. Gilje, G. P. Yap<br />
529. Synthesis, characterization and coordination<br />
chemistry of a novel class of electroneutral<br />
phosphines. M. Choate,<br />
G. Peters, L. Tvedte, R. Baughman<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Coordination Chemistry<br />
Synthesis<br />
D. Crans, M. Millar, Organizers<br />
7:00–9:00<br />
530. Syntheses and characterization of<br />
dimeric metal complexes of 3,5-bis[bis(N-<br />
6-pivalamido-2-pyridylmethyl)aminomethyl]-1H-pyrazole<br />
containing intramolecular<br />
hydrogen bonding networks.<br />
K. Ng, J. W. Ziller, A. S. Borovik<br />
531. Aromatic crown ether/4,4�-bipyridinium<br />
pseudorotaxanes as a building block for<br />
metal organic rotaxane frameworks.<br />
I. R. Fernando, S. Bairu, C. Ziegler,<br />
R. Guda, G. Mezei*<br />
532. Iron and cobalt(II) clathrochelates with<br />
second fluorine-containing hydrophobic<br />
shell: Synthesis, X-ray structure, spectral<br />
and electrochemical properties.<br />
I. G. Makarenko, Y. Z. Voloshin,<br />
A. S. Belov, Z. A. Starikova, Y. N. Bubnov<br />
533. Mixed lanthanide/transition-metal clusters<br />
from polyoxometalate chemistry.<br />
J. R. Galan-Mascaros,S.Reinoso<br />
534. Chemistry of the fac-[Fe(CN) x(CO) 3I (3-x)] -<br />
Series (x � 1 – 3). O. Azran, A. Stock,<br />
J. Solaimanzadeh, J. Jiang<br />
535. Synthetic analogs of methanobactin.<br />
D. Rabinovich<br />
536. Synthesis and structural characterization<br />
of platinum(IV)-� 3 -terpyridine complexes.<br />
F. G. Baddour,M.I.Kahn,<br />
L. H. Doerrer<br />
537. Secondary coordination sphere effects<br />
on dicopper O 2 complexes. C. S. Letko,<br />
M. A. Thorseth, A. A. Gewirth,<br />
T. B. Rauchfuss<br />
538. Synthesis and characterization of rigid<br />
�2and�3 heteroleptic binuclear ruthenium<br />
coordination complexes.<br />
J. R. Alston,J.C.Poler<br />
539. Tris(guanidinato) complexes of iridium(III)<br />
and iridium(IV): Synthesis, characterization<br />
and reactivity. W. Lee, J. Rohde<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Lanthanide and Actinide Chemistry<br />
B. Donovan-Merkert, M. Millar, Organizers<br />
7:00–9:00<br />
540. Magnetic studies of bimetallic Gd(III)<br />
complexes. J. D. Moore,M.J.Allen<br />
541. Increasing the oxidative stability of<br />
aqueous Eu(II) complexes.<br />
N. H. Gamage, Y. Mei, J. Garcia,<br />
M. J. Allen<br />
542. Morphology controlled colloidal synthesis<br />
of LnOCl nanocrystals and integration<br />
into thin films. K. R. Kort, S. Banerjee<br />
543. Extraction efficiencies of neodymium<br />
and europium trivalent ions using derivatives<br />
of the tripodal ligand tris(2-hydroxy-<br />
3,5-dimethylbenzyl)amine. R. Copeland,<br />
J. Drader, N. Elbers, G. Llerena, J. Friese,<br />
S. Friese<br />
544. Synthesis, spectroscopy and redox behaviour<br />
of ferrocene appended lanthanide<br />
complexes. S. Faulkner,<br />
M. Tropiano<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
545. Developing novel nanoparticulated imaging<br />
system using luminescence enhancement<br />
of Eu(III) and Tb(III) by singlestrand<br />
DNA. D. A. Corcoran,<br />
D. L. Harms, P. K. Fu<br />
546. MRI contrast enhancement using<br />
Gd(III)-nanodiamond conjugates.<br />
L. M. Manus, D. J. Mastarone, X. Zhang,<br />
E. A. Waters, K. W. MacRenaris,<br />
G. Parigi, C. Luchinat, D. Ho, T. J. Meade<br />
547. Development of triphenoxymethane<br />
based ligands for the liquid-liquid extraction<br />
of lanthanides and actinides.<br />
G. L. Guillet, P. Hillesheim, M. J. Scott<br />
548. Computational and synthetic development<br />
of ligands for the selective binding<br />
of lanthanides and actinides. I. D. Hyatt,<br />
C. A. Rienas, M. J. Scott<br />
549. Synthesis and characterization of Gd 3�<br />
conjugated-hyperbranched polyglycerols<br />
for use as MR vascular imaging agents.<br />
C. A. Barta, N. A. Rossi, S. Horte,<br />
B. F. Lai, J. N. Kizhakkedathu<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Inorganic Catalysts<br />
B. Donovan-Merkert, Organizer<br />
7:00–9:00<br />
550. Synthesis and reactivity of Ir III CCC-<br />
NHC pincer complexes. K. M. Schultz,<br />
W. Kaminsky, K. I. Goldberg, D. Heinekey<br />
551. Methane to methanol: A DFT study of<br />
the oxy-functionalization of metal alkyls.<br />
T. R. Cundari, B. M. Prince, T. M. Figg<br />
552. Production of poly(lactide) using aluminium<br />
and zinc complexes.<br />
O. Karroonnirun, D. J. Darensbourg<br />
553. N-doped SiO 2/TiO 2 core/shell nanoparticles<br />
as highly efficient visible light photocatalyst:<br />
Application in decomposition<br />
of water pollutant. C. Kim, J. Jang<br />
554. Preparation and characterization of<br />
supported binuclear copper complexes<br />
on Cab-O-Sil and their catalytic activity.<br />
S. A. Ranaweera, W. P. Henry,<br />
M. D. Rowe, K. B. Walters, M. G. White,<br />
J. M. Rodriguez<br />
555. Asymmetric reaction rates in terpolymers<br />
produced from CO 2 and epoxides.<br />
R. R. Poland, D. J. Darensbourg<br />
556. Novel metal nitride catalysts supported<br />
on magnetic silica microspheres for click<br />
reactions. S. Han, B. Lee, M. Yi, S. Chu,<br />
J. Lee, H. Kwon, K. Lee, D. Kang, D. Chi,<br />
N. Hur<br />
557. Carbon dioxide reduction with biomimetic<br />
molybdenum catalysts. A. Aron,<br />
J. Seo, E. Kim<br />
Section I<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Organometallic Chemistry<br />
Synthesis and Characterization<br />
N. Radu, Organizer<br />
7:00–9:00<br />
558. Organometallic furan derivatives for solar<br />
energy capture. N. C. Tice,<br />
A. Z. Preston, C. A. Snyder<br />
559. Preparation and structural characterization<br />
of bimetallic Iron�Nickel carbido<br />
cluster complexes. S. Saha,L.Zhu,<br />
B. Captain<br />
560. Synthesis and structure of gold and<br />
platinum menthyl complexes.<br />
A. A. Zuzek, S. C. Reynolds, J. A. Golen,<br />
A. L. Rheingold, D. S. Glueck<br />
561. Synthesis, structure, and spectroscopic<br />
properties of 2,3-bis(diphenylphosphino-<br />
)quinoxaline (dppQx) Cu(I) complexes.<br />
M. F. Cain, S. C. Reynolds, D. S. Glueck,<br />
J. A. Golen, A. L. Rheingold<br />
562. Formation of group 4 metallacyclopentanes<br />
from metallacyclopropenes: Investigation<br />
of the reactions with ethylene by<br />
in situ NMR and UV/vis spectroscopy.<br />
T. Beweries, C. Fischer, S. Peitz,<br />
V. V. Burlakov, P. Arndt, W. Baumann,<br />
A. Spannenberg, D. Heller, U. Rosenthal<br />
563. �-Coordinated chromium and manganese<br />
DBCOT complexes. N. Bandara,<br />
D. J. Beard, S. R. Gwaltney, W. P. Henry<br />
564. Oxidative addition and cleavage of sp 3<br />
C-F Bond by pincer iridium complexes.<br />
J. Choi,A.S.Goldman<br />
565. New PNP pincer ligand motifs as mechanistic<br />
probes into metal-ligand cooperation<br />
catalysis at ruthenium. E. Khaskin,<br />
M. A. Iron, D. Milstein<br />
566. Mononuclear guanidinato and amidinato<br />
complexes of iridium(I) and rhodium(I).<br />
M. R. Kelley,J.Rohde<br />
567. Synthesis of new photochromic organometallics<br />
based on a linkage isomerization.<br />
K. L. Mosley, K. R. Ruddick,<br />
J. O. Johnson, C. E. Webster,<br />
T. J. Burkey<br />
568. Investigation into the effects of halide<br />
substitution on the structures and N-CH 3<br />
oxidative addition reaction occurring in<br />
[PN(Me)P]RhX complexes.<br />
A. L. Fernandez, B. M. Foxman,<br />
O. V. Ozerov<br />
569. Reaction of O 2 with alkyl amide imide<br />
Ta(�NSiMe 3)[N(SiMe 3) 2](CH 2Bu t ) 2.<br />
mechanistic study of the formation of<br />
Ta(�NSiMe 3)[N(SiMe 3) 2](OCH 2Bu t ) 2.<br />
S. Chen, S. C. Hunter, X. Wang, Z. Xue<br />
570. Direct synthesis of (eta6-aniline) manganese<br />
tricarbonyl cation. W. Dai,S.Kim,<br />
P. D. Robert, D. A. Sweigart<br />
571. Synthesis, structures and reactivity of<br />
some azaferrocene boron-Lewis Acid donor-acceptor<br />
complexes. T. J. Brunker,<br />
B. T. Roembke, A. L. Rheingold, J. Golen<br />
572. Investigation of new imido ligands and<br />
their application to olefin metathesis.<br />
A. G. Lichtscheidl, R. R. Schrock<br />
573. Synthesis and characterization of ruthenium-glycals<br />
containing BINAP and 1,1�-<br />
Bis(diphenylphosphino)ferrocene.<br />
V. D. Reddy<br />
574. Synthesis and characterization of oxygenous<br />
ligands and their relevance to water<br />
oxydation. R. Huacuja, O. V. Ozerov,<br />
D. Graham, B. M. Foxman, C. Chen<br />
575. Withdrawn<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Organometallic Chemistry<br />
Catalysis<br />
N. Radu, Organizer<br />
A. Wenzel, J. Soper, Presiding<br />
8:30 576. Ruthenium metallacycles derived<br />
from 14- and 16-electron complexes:<br />
New methods for metallacycle preparation,<br />
and the insights gained from the<br />
study of these metathesis intermediates.<br />
A. G. Wenzel, R. H. Grubbs, G. Blake<br />
8:50 577. Influence of electronically and<br />
sterically tunable olefin-ligands on the<br />
properties of group 10 d 10 metal-complexes<br />
and correlation with reactivity.<br />
M. R. Buchner, K. Ruhland<br />
9:10 578. Platinum and nickel metal complexes<br />
containing bulky tin ligands.<br />
V. Yempally, L. Zhu, D. Isrow, B. Captain<br />
9:30 579. Palladium alkyl complexes with<br />
chelating N-heterocyclic carbene-sulfonate<br />
ligand. X. Zhou,R.F.Jordan<br />
9:50 580. Enhanced phosphorescence in<br />
cyclometalated Pt(II) complexes facilitated<br />
by triarylboron. Z. M. Hudson,<br />
C. Sun, H. Amarne, S. Wang<br />
10:10 Intermission<br />
10:15 581. Gilded organometallics: Recent<br />
developments. T. G. Gray, D. V. Partyka,<br />
L. Gao, T. J. Robilotto, N. Deligonul<br />
10:35 582. Novel bis(2-pyridyl)borato platinum(II)<br />
complexes for alkane C-H bond<br />
functionalization. S. Pal, A. N. Vedernikov<br />
10:55 583. Luminescent Au(I)/Cu(I) alkynyl<br />
clusters of ethynyl steroids and related aliphatic<br />
acetylides. G. Manbeck,<br />
W. Brennessel, R. Stockland,<br />
R. Eisenberg<br />
11:15 584. Redox-active ligand-mediated<br />
coupling reactions at square planar manganese,<br />
iron and cobalt centers.<br />
J. D. Soper<br />
11:35 585. Paramagnetic multinuclear complexes<br />
bridged by alkynyl-type ligands.<br />
M. P. Shores, W. A. Hoffert, B. S. Newell,<br />
A. K. Rappe<br />
11:55 586. C-H and C-CN bond activation<br />
of acetonitrile with [Cp*Rh(PMe 3)]: An experimental<br />
and theoretical investigation.<br />
M. E. Evans, T. Li, W. D. Jones<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Organometallic Chemistry<br />
Synthesis and Characterization<br />
N. Radu, Organizer<br />
L. Mirica, Presiding<br />
8:30 587. Oxidative addition and reductive<br />
elimination of C-H bonds of aryl halides<br />
by a pincer-ligated iridium complex.<br />
D. A. Laviska,D.Y.Wang,<br />
K. Krogh-Jespersen, A. S. Goldman<br />
8:50 588. Complexes of pincer ligands with<br />
a central silylene donor. O. V. Ozerov,<br />
W. Gu, J. R. Walensky<br />
9:10 589. Activation of NH bonds by ruthenium<br />
via metal-ligand cooperation.<br />
E. Khaskin, M. A. Iron, L. J. Shimon,<br />
D. Milstein<br />
9:30 590. Four-coordinate Ru(II) amdio<br />
PNP-pincer complexes. B. Askevold,<br />
J. Meiners, M. Khusniyarov,<br />
E. Herdtweck, S. Schneider<br />
9:50 591. Studies of oxygenous ligands and<br />
their relevance to transiton metal-catalyzed<br />
water oxidation. R. Huacuja,<br />
O. Ozerov, D. Graham, B. Foxman,<br />
C. Chen<br />
10:10 592. Effect of mono- and dianionic ligands<br />
on the reactivity of monoalkylplatinum(II)<br />
complexes toward O 2 in water.<br />
A. Sberegaeva, A. Vedernikov<br />
10:30 593. Reactivity of Pt and Rh hydrocarbyl<br />
complexes with oxidants. J. R. Webb,<br />
T. Gunnoe<br />
10:50 Intermission<br />
10:55 594. O-Ligated monoaryl palladium(IV)<br />
complexes: Experimental and<br />
computational study of direct C(sp 2 )-O<br />
reductive elimination from Pd IV center.<br />
A. N. Vedernikov,W.Oloo<br />
11:15 595. Mononuclear alkyl and aryl Pd(III)<br />
complexes and their reactivity in C-C and<br />
C-X bond formation. L. M. Mirica,<br />
J. R. Khusnutdinova<br />
11:35 596. Synthesis, characterization and<br />
electrochemical studies of Pd(III) complexes<br />
stabilized by polydentate N-donor<br />
ligands. J. R. Khusnutdinova,<br />
L. M. Mirica<br />
11:55 597. Chemistry and electrochemistry<br />
of fluorinated rhodium acyl diphosphine<br />
complexes, Rh(COR)(P-P)X 2.<br />
B. D. Panthi, S. L. Gipson, A. Franken<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Coordination Chemistry<br />
Synthesis<br />
D. Crans, Organizer<br />
J. Rohde, Presiding<br />
8:30 598. Synthesis, spectroscopic and<br />
electrochemical characterizations, density<br />
functional theory calculations, and<br />
activity screening of tridentate SNS zinc<br />
pincer complexes. J. R. Miecznikowski,<br />
W. Lo, M. A. Lynn, N. F. Kloczko,<br />
B. E. O’Loughlin, A. P. DiMarzio,<br />
L. C. Keilich, K. M. Foley<br />
8:50 599. Mixed-valence models for [NiFe]<br />
hydrogenase: Synthesis and reactivity.<br />
D. Schilter, B. E. Barton, M. J. Nilges,<br />
T. B. Rauchfuss<br />
9:10 600. Family of new Mn/Ln (Ln � lanthanide)<br />
single-molecule magnets with<br />
record magnetization reversal barriers for<br />
3d-4f SMMs. C. Papatriantafyllopoulou,<br />
K. A. Abboud, W. Wernsdorfer,<br />
G. Christou<br />
9:30 601. Pseudo-tetrahedral metal-oxo<br />
complexes supported by bulky alkoxides.<br />
M. B. Chambers, S. Groysman,<br />
D. G. Nocera<br />
9:50 602. Synthesis, structure, and spectroscopy<br />
of an iron(I)-sulfide complex.<br />
M. M. Clark, B. D. Stubbert,<br />
W. W. Brennessel, E. Bill, P. L. Holland<br />
10:10 603. Synthesis, electrochemistry, and<br />
magnetic properties of a binuclear bis(�-<br />
OMe) Co(II)Co(III) mixed-valent complex.<br />
J. Luo, L. M. Mirica<br />
10:30 604. Binucleating ligands: Control of<br />
the M-M distance in transition metal<br />
complexes. F. Tang, L. Mirica<br />
10:50 605. New aspects of chirality and molecular<br />
sensing in metallocorrole chemistry.<br />
O. A. Egorova, O. G. Tsay, K. Kim,<br />
D. G. Churchill<br />
11:10 606. Dialkyldiarylguanidinato(1–) ligands<br />
and their iridium(I), iridium(III) and<br />
iridium(IV) complexes. J. Rohde, W. Lee,<br />
M. R. Kelley<br />
11:30 607. Outer vs. inner-sphere redox<br />
chemistry of 3d transition metal tris(pyrrolide)ethane<br />
complexes. G. T. Sazama,<br />
T. A. Betley<br />
11:50 608. Dipyrromethene supported lowcoordinate<br />
high-spin iron complexes and<br />
their reactivity as platforms for C-H functionalization<br />
via oxidative group transfer.<br />
E. R. King, T. A. Betley<br />
12:10 609. Rational design and synthesis of<br />
polynuclear clusters to control M-M interactions.<br />
A. R. Fout,T.A.Betley<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Chemistry of Materials<br />
Polymer-related Research<br />
D. Nelson, Organizer<br />
J. Burgess, N. Kariuki, Presiding<br />
8:30 610. Palladium alloys for oxygen reduction<br />
in polymer electrolyte fuel cells.<br />
N. N. Kariuki, X. Xiaoping, S. Niyogi,<br />
D. J. Myers, T. Hofmann, Y. Zhang,<br />
C. Heske, W. A. Goddard, III,, B. Merinov,<br />
T. Yu<br />
8:50 611. N-benzylazole and hydroxypyridine<br />
substituted polyphosphazenes to be<br />
used as proton exchange membranes in<br />
fuel cells. S. K. Ekanayake, S. Moolsin,<br />
M. J. Panzner, C. A. Tessier*,<br />
W. J. Youngs*<br />
9:10 612. Polymer microblades in srtificial<br />
muscles: Toward bio-inspired adaptive<br />
optics and self-sustaining propulsion.<br />
P. Kim, J. M. Epstein, L. D. Zarzar,<br />
M. Aizenberg, J. Aizenberg<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–69
INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
9:30 613. Lanthanide-containing conducting<br />
metallopolymers for near-infrared lightemitting<br />
materials. X. Chen,Y.Yin,<br />
X. Yang, B. J. Holliday<br />
9:50 614. Nanostructured SiOC low dielectric<br />
film derived from inorganic polymer.<br />
Y. Kim, J. Kim, Y. Lee, W. Kwon, S. Kim,<br />
D. Choi<br />
10:10 Intermission<br />
10:30 615. Nanoscopic patterned materials<br />
with tunable dimensions via atomic layer<br />
deposition on block copolymers.<br />
Q. Peng, Y. Tseng, S. B. Darling,<br />
J. W. Elam<br />
10:50 616. Non-hydrolytic synthesis, characterization,<br />
and electronic structure of<br />
colloidal early transition metal oxide<br />
nanocrystals. S. W. Depner, K. R. Kort,<br />
C. Jaye, H. Zhang, D. A. Fischer,<br />
S. Banerjee<br />
11:10 617. Synthesis and characterization of<br />
amorphous pyrophosphates and their<br />
use in brushite bone cements. C. Slater,<br />
A. J. Wright, L. M. Grover, V. Burnell,<br />
D. Laurencin, J. A. Hriljac, M. E. Smith<br />
11:30 618. Hybrid polyoxometalates, from<br />
molecular catalysts to functional materials.<br />
M. Carraro, G. Modugno, A. Sartorel,<br />
M. Bonchio, G. Scorrano<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Growth and Design<br />
S. Wong, Organizer<br />
I. Hakem, K. Balkus, Presiding<br />
8:30 619. Large scale ZnO nanodendrites<br />
converted by an in-situ carbothermal<br />
method and their application as gas sensors.<br />
P. Shimpi,P.Gao<br />
8:50 620. Thermal behavior study of<br />
�-Fe 2 O 3 and �-FeOOH nanocapsules<br />
structures. Y. Kim, R. Yu, J. Pee, K. Kim<br />
9:10 621. Tuning the metal-insulator phase<br />
transition in VO 2 nanostructures.<br />
L. Whittaker, T. Wu, C. Jaye, D. Fischer,<br />
S. Ganapathy, S. Banerjee<br />
9:30 622. Nanostructured vanadium oxides<br />
by chemical vapor transport and hydrothermal<br />
methods. J. M. Velazquez,<br />
C. Jaye, D. A. Fischer, S. Banerjee<br />
9:50 623. Vanadium oxide nanotube films<br />
prepared via pulsed laser ablation.<br />
K. Balkus, S. D. Perera, J. Bonso,<br />
J. Ferraris<br />
10:20 Intermission<br />
10:40 624. Experimental and theoretical<br />
evaluation of the distribution of functionality<br />
of surface modified nanoparticles.<br />
I. F. Hakem, J. Walker, A. Leech,<br />
J. Johnson, S. Donahue,<br />
M. R. Bockstaller<br />
11:10 625. Nanoclusters of dicyanocuprate<br />
(I) ions doped in different alkali halides.<br />
X. Li, D. A. Welch, F. Baril-Robert,<br />
H. H. Patterson<br />
11:30 626. Efficient assemby of photochromic<br />
spiropyran molecules on zeolite<br />
nanostructures. K. Dubois, E. Garcia,<br />
S. Bent, G. Li<br />
11:50 627. Controlling ice formation on<br />
nanostructured superhydrophobic surfaces.<br />
L. Mishchenko,B.Hatton,<br />
J. Taylor, V. Bahadur, T. Krupenkin,<br />
J. Aizenberg<br />
12:10 628. Large-scale soft colloidal template<br />
synthesis of 1.4 nm-thick CdSe<br />
nanosheets. J. Son, T. Hyeon<br />
70–TECH<br />
‡ Cooperative Cosponsorship<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Ligand Design and Metal Behavior<br />
L. Doerrer, S. Koch, Organizers<br />
M. Millar, Organizer, Presiding<br />
9:00 629. Coordination chemistry of bidentate<br />
and tridentate N-aryl-substituted imino-N-heterocyclic<br />
carbene ligands.<br />
G. G. Lavoie, S. Dastgir, A. C. Badaj,<br />
T. G. Larocque<br />
9:30 630. Ligands which provide hydrogen<br />
bonds near and far from the metal center.<br />
E. T. Papish, M. Kumar, I. Nieto,<br />
S. W. Shim, S. N. Oseback, N. A. Dixon,<br />
M. Zeller<br />
10:00 631. Ligands designed for mimicking<br />
the diiron centers of bacterial monooxygenases.<br />
L. Do, Y. Li, S. J. Lippard<br />
10:40 Intermission<br />
10:50 632. Fluorinated ligands vs. fluorine<br />
as a ligand. L. H. Doerrer<br />
11:20 633. Designing ligands to enforce<br />
multielectron excited state chemistry.<br />
D. G. Nocera<br />
12:00 634. On the use of various thiolate ligands<br />
to replicate the chemistry of metalcysteine<br />
centers in nature. M. Millar<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Lanthanide and Actinide Chemistry<br />
B. Donovan-Merkert, A. De Bettencourt<br />
Dias, Organizers<br />
S. Bart, Presiding<br />
9:00 635. Interaction between CMPO and<br />
HDEHP in combined TRUEX-TALSPEAK<br />
extraction process. P. Tkac,<br />
G. F. Vandegrift, G. Lumetta, A. Gelis<br />
9:20 636. Placement of lanthanide and actinide<br />
elements in the Periodic Table.<br />
G. Katz<br />
9:40 637. Metal-loaded liquid scintillator for<br />
neutrino experiment. S. Hans,M.Yeh,<br />
R. Hahn, L. Hu<br />
10:00 638. Synthesis and reactivity of uranium<br />
compounds containing redox-active<br />
�-diimine ligands. S. J. Kraft,<br />
P. E. Fanwick, S. C. Bart<br />
10:20 639. Encapsulation of the uranyl dication.<br />
O. B. Berryman, S. Beer, D. Ajami,<br />
J. Rebek Jr.<br />
10:40 Intermission<br />
10:50 640. Organometallic chemistry of lowvalent<br />
uranium complexes with hydrotris(pyrazolyl)borate<br />
ligands. S. C. Bart,<br />
E. M. Matson, P. E. Fanwick<br />
11:10 641. Transformation and curvature in<br />
uranyl diphosphonate system: Synthesis<br />
and structural characterization from single<br />
X-ray crystallography. P. O. Adelani,<br />
T. E. Albrecht-Schmitt<br />
11:30 642. Controllable optical properties of<br />
luminescent core-shell rare-earth ion<br />
doped nanoparticles. J. Dorman,<br />
J. P. Chang<br />
11:50 643. Novel lanthanide complexes as<br />
potential photodynamic therapeutic<br />
agents. S. Gangula, A. Blinder, P. K. Fu<br />
12:10 644. Strong ytterbium (III)-induced<br />
near-infrared emission by a BODIPYmodified<br />
bidentate ligand. H. He,<br />
Y. Zhong, A. Sykes<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Analytical Science Sponsored by ANYL,<br />
Cosponsored by INOR<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Organometallic Chemistry<br />
Synthesis and Characterization<br />
N. Radu, Organizer<br />
T. Betley, Presiding<br />
1:30 645. Photochemical reaction of 1-ferrocenyl-4-phenyl-1,3-butadiyne<br />
and<br />
Fe(CO) 5 in presence of CS 2 and S 8-powder.<br />
R. S. Ji, P. Mathur<br />
1:50 646. Metal complexes containing redox<br />
noninnocent aryldithiolate N-heterocyclic<br />
carbene ligands. B. Pan,C.M.Thomas<br />
2:10 647. Lithium dimethylcuprate and thiocarbonyl<br />
compounds: Observation, characterization<br />
and reactions of pi complexes.<br />
A. A. Thomas, Y. Moazami,<br />
J. D. Richter, S. H. Bertz, M. D. Murphy,<br />
C. A. Ogle<br />
2:30 648. Low energy solar neutrino spectrometer<br />
(LES). L. Hu, S. Rountree,<br />
R. Raghavan, S. Hans, M. Yeh,<br />
R. L. Hahn<br />
2:50 649. Deprotonation of N-alkylimidazole<br />
ligands: New reactivity patterns.<br />
J. Perez, L. Riera, M. A. Huertos<br />
3:10 650. Bimetallic carbon-halogen bond<br />
oxidative addition at Co(0). D. Zhu,<br />
P. H. Budzelaar<br />
3:30 Intermission<br />
3:35 651. Increasing the sensitivity of NMR<br />
spectroscopy: Iridium catalysts for polarisation<br />
transfer from para-hydrogen.<br />
M. J. Cowley, S. B. Duckett, G. Green<br />
3:55 652. Photochromic cyclopentadiene<br />
manganese tricarbonyl derivatives: Participation<br />
of imine group during linkage<br />
isomerization. T. J. Burkey, K. L. Mosley,<br />
C. E. Webster, K. R. Ruddick, P. P. Lubet,<br />
J. O. Johnson, E. J. Heilweil<br />
4:15 653. Role of Lewis acids in the reductive<br />
coupling of CO in Re and Mn cations:<br />
Intermolecular metal-free cleavage of dihydrogen<br />
and intramolecular facilitation<br />
of C-C bond formation. A. J. Miller,<br />
J. A. Labinger, J. E. Bercaw<br />
4:35 654. Catalytic, iron-mediated C-H<br />
bond functionalization chemistry.<br />
T. Betley, E. Hennessy, E. King,<br />
G. Edouard<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Organometallic Chemistry Catalysis<br />
N. Radu, Organizer<br />
A. Sadow, R. Waterman, Presiding<br />
1:30 655. Novel Chromium-based catalyst<br />
system for the highly selective trimerization<br />
of ethylene to 1-hexene. S. Peitz,<br />
N. Peulecke, B. R. Aluri, B. H. Müller,<br />
U. Rosenthal,A.Wöhl, W. Müller,<br />
M. H. Al-Hazmi, F. M. Mousa<br />
1:50 656. Synthesis, reactivity and mechanistic<br />
studies of Molybdenum pyrrolide<br />
alkylidene species supported by chiral<br />
bulky alkoxides. S. C. Marinescu,<br />
R. R. Schrock, P. Müller, J. H. Simpson,<br />
A. H. Hoveyda<br />
2:10 657. Mechanistic studies of ring-opening<br />
metathesis polymerization with molybdenum<br />
monoaryloxide monopyrrolide<br />
catalysts. L. Gerber, R. R. Schrock<br />
2:30 658. New catalysts for C-N bond formation<br />
involving hydroamination and related<br />
mechanistic investigations.<br />
A. D. Sadow<br />
2:50 659. Scope and mechanism of cis- and<br />
syndio-selective ring opening metathesis<br />
polymerization with molybdenum imido<br />
alkylidene complexes. M. M. Flook,<br />
R. R. Schrock<br />
3:10 660. Catalytic C–H bond amination and<br />
aziridination using organoazides from a<br />
ferrous dipyrromethene platform.<br />
E. T. Hennessy, T. Betley<br />
3:30 661. SiH bond activation reactions involving<br />
a coordinatively saturated zinc(II)<br />
center. D. Mukherjee, A. Ellern,<br />
A. D. Sadow<br />
3:50 662. Zirconium-mediated and -catalyzed<br />
P–C bond-forming reactions.<br />
A. J. Roering, S. E. Leshinski,<br />
R. Waterman<br />
4:10 663. Advances in phosphine dehydrocoupling<br />
and applications. M. Ghebreab,<br />
R. Waterman<br />
4:30 664. Indenyl Co(I) complexes: Synthesis,<br />
structure, and reactivity.<br />
F. Hung-Low, C. A. Bradley<br />
4:50 665. Synthesis and reactivity of iron<br />
pincer complexes. P. Bhattacharya,<br />
J. A. Krause, H. Guan<br />
5:10 666. Unusual activation of silanes resulting<br />
from � 3 -coordination to<br />
[PhBP3]RuH. M. C. Lipke, T. Tilley<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
General Inorganic Chemistry<br />
B. Donovan-Merkert, Organizer<br />
C. Murillo, Presiding<br />
1:30 667. Matrix photochemistry of<br />
PdL 2(N 3)X derivatives. W. A. Thornley,<br />
T. E. Bitterwolf<br />
1:50 668. High valent transition metals featuring<br />
siloxide ligands. M. P. Marshak,<br />
D. G. Nocera<br />
2:10 669. Combined ligand �/metal � and ligand<br />
p�/metal-d� interactions indicated<br />
by magnetic and structural data.<br />
C. A. Murillo, G. M. Chiarella,<br />
D. Villagran, X. Wang<br />
2:30 670. Dioxygen activation by low valent<br />
chromium compounds. F. Dai,<br />
L. MacAdams, G. P. Yap, K. Theopold<br />
2:50 671. Synthesis and crystal structure of<br />
(benzo[1,2-c:3,4-c�:5,6-c�]trithiophene)2(7,7,8,8-tetracyano-p-quinodimethane)<br />
a possible 1D thermoelectric<br />
material. J. E. Schmidt, D. S. Dudis,<br />
A. V. Fratini<br />
3:10 672. Incorporation of main group elements<br />
into phosphorus-rich compounds<br />
via M[P 3Nb(ODipp) 3] platforms. A. Velian,<br />
C. C. Cummins<br />
3:30 673. Enhanced oxidative desulfurization<br />
of fuels using a film shear reactor.<br />
B. R. Fox, J. L. Male, D. R. Tyler<br />
3:50 674. Dimetal nitride chemistry and new<br />
insight into dirhodium catalyzed aminations.<br />
A. K. Long, J. F. Berry<br />
4:10 675. Luminescent rhenium(I) complexes<br />
incorporating a thiophene-functionalized<br />
bis(pyrazolyl) pyridine ligand.<br />
L. A. Lytwak, B. J. Holliday<br />
4:30 676. Comparing metal assisted thiolate<br />
disulfide exchange reactions (M�Au, Zn).<br />
G. S. Garusinghe,M.R.Bruce,<br />
A. E. Bruce<br />
4:50 677. Stopped flow ultra rapid IR studies<br />
of ClNO with metal complexes.<br />
M. L. Reback, T. E. Bitterwolf,<br />
P. R. Griffiths<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Coordination Chemistry<br />
Characterization and Applications<br />
D. Crans, Organizer<br />
C. Lu, Presiding<br />
1:30 678. Controlling the polymerization of<br />
2,6-hexadiyne-diole in 1D metal-organic<br />
frameworks (MOFs) like [Al(OH)(terephthalate)]<br />
n: Structural investigations and<br />
possible properties. M. Meilikhov,<br />
K. Yusenko, R. A. Fischer<br />
1:50 679. Reactivity of early/late heterobimetallic<br />
complexes featuring metal-metal<br />
multiple bonds: Small molecule activation<br />
and catalytic applications.<br />
C. M. Thomas,G.T.Rowe,<br />
B. P. Greenwood, J. W. Napoline,<br />
W. Zhou, D. J. Graham, B. M. Foxman<br />
2:10 680. Orotate complexes of cobalt: Solid-state<br />
phase transition and metalloligand<br />
behavior toward silver and thallium.<br />
L. R. Falvello,M.Tomás, G. Martínez,<br />
N. Mushale<br />
2:30 681. Double bond between metals in<br />
the H 2Os 3(CO) 10 and H 2Ru 3(CO) 10 clusters?<br />
R. J. Alvarez-Mendez,<br />
O. Reyes-Lopez, M. J. Rosales-Hoz,<br />
A. Vela<br />
2:50 682. Synthesis, reactivity, and photochemistry<br />
of heterobimetallic rhodiumgold<br />
halide and hydride complexes.<br />
T. S. Teets, M. P. Neumann,<br />
D. G. Nocera<br />
3:10 683. Pseudorotaxanes as ligands for<br />
the construction of metal-organic molecular<br />
devices. G. Mezei, I. R. Fernando,<br />
S. Bairu, R. Guda, C. J. Ziegler<br />
3:30 684. Using molybdenum tetracarbonyl<br />
complexes to investigate photoinduced<br />
ligand field switching in photochromic<br />
spirooxazine ligands. M. M. Paquette,<br />
B. O. Patrick, N. L. Frank<br />
3:50 685. Withdrawn<br />
4:10 686. Copolymerizable ligands, and<br />
their incorporation in polymer based<br />
Cu 2� sensors. J. Massing,<br />
N. Bencivenga, J. Du, R. Ding, S. Yao,<br />
R. Planalp, R. Seitz, J. Reddel<br />
4:30 687. Reactivity of pseudotetrahedral<br />
nickel(II) arylthiolate complexes.<br />
M. Jensen, S. Chattopadhyay, T. Deb,<br />
V. G. Young, Jr.<br />
4:50 688. Characterization of high-spin triiron<br />
complexes with variable metal-metal<br />
interaction. E. V. Eames, T. A. Betley,<br />
Q. Zhao<br />
5:10 689. Reaction mechanism in the synthesis<br />
of (PNP)Rh�O using N2O.<br />
J. G. Andino,K.G.Caulton<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Inorganic Chemistry<br />
M. Millar, S. Koch, Organizers<br />
J. Caradonna, L. Doerrer, Presiding<br />
1:30 690. Discrete Cu(I) and dioxygen reactivity<br />
without N-donor ligands. J. S. Lum,<br />
L. H. Doerrer<br />
1:50 691. Fluorinated cobalt alkoxide complexes.<br />
S. A. Cantalupo, L. H. Doerrer<br />
2:10 692. Preparation and characterization<br />
of a reactive synthetic model complex to<br />
mimic the chemistry of TauD.<br />
P. C. Tarves, P. J. Cappillino,<br />
J. P. Caradonna<br />
2:30 693. Density functional theory (DFT)<br />
study of a series of Fe II/III nonheme iron<br />
oxygenase model compounds.<br />
J. S. McNally, P. J. Cappillino, F. Wang,<br />
J. P. Caradonna<br />
2:50 694. Reactivity studies of a functional<br />
non-heme iron enzyme model complex<br />
using stopped-flow UV/vis spectroscopy.<br />
L. C. Gregor,G.T.Rowe,<br />
E. V. Rybak-Akimova, J. P. Caradonna<br />
3:10 695. Studies toward understanding the<br />
mechanism of allosteric activation in phenylalanine<br />
hydroxylase. S. R. Soltau,<br />
G. Anarat, R. Napoleon, D. Kozakov,<br />
S. Vajda, J. P. Caradonna<br />
3:30 696. Investigation into the kinetic<br />
mechanisms and characterization of the<br />
active sites of truncated and full-length<br />
phenylalanine hydroxylases.<br />
B. J. Salsbery, G. Anarat,<br />
J. P. Caradonna<br />
3:50 697. Differential studies of the kinetics,<br />
mechanisms, and active site structures of<br />
truncated and full length phenylalanine<br />
hydroxylase. J. P. Caradonna<br />
4:10 698. Membrane permeable and impermeable<br />
sensors for the visualization and<br />
quantification of mobile zinc.<br />
D. Buccella,S.J.Lippard<br />
4:30 699. New synthetic platforms that<br />
mimic the structure and function of diiron<br />
monooxygenases. L. H. Do,S.J.Lippard<br />
4:50 700. Dioxygen activation in T201 variants<br />
of toluene/o-xylene monooxygenase<br />
hydroxylase from Pseudomonas sp. OX1.<br />
W. Song,S.J.Lippard<br />
5:10 701. Mechanistic studies of dioxygen<br />
activation in soluble methane monooxygenase.<br />
C. E. Tinberg,S.J.Lippard<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Chemistry of Materials<br />
Metal Organic Frameworks and Porous<br />
Surfaces<br />
D. Nelson, Organizer<br />
D. Knight, K. Chapman, Presiding<br />
1:30 702. Exceptionally high acetylene uptake<br />
in a microporous metal-organic<br />
framework with open metal sites.<br />
S. Xiang, W. Zhou, Y. Liu, B. Chen<br />
1:50 703. Novel monovalent metal organophosphates.<br />
T. L. Kinnibrugh,<br />
N. Jimenez Garcia, A. Clearfield<br />
2:10 704. Effects of crystal structure and<br />
linker on MOF luminescent properties.<br />
S. T. Meek, P. L. Feng, J. J. Perry,<br />
P. Doty, M. D. Allendorf<br />
2:30 705. Pressure-induced pore modification<br />
and amorphization in a metal-organic<br />
framework. K. W. Chapman,<br />
G. J. Halder, P. J. Chupas<br />
2:50 706. Metals supported on covalent organic<br />
frameworks as heterogeneous catalysts.<br />
C. E. Chan-Thaw, M. Bojdys,<br />
P. Katekomol, K. Kailasam, R. Palkovits,<br />
F. Schüth, A. Villa, L. Prati, A. Thomas<br />
3:10 Intermission<br />
3:30 707. Novel hydrogen storage materials<br />
obtained via the stabilization of aluminum<br />
borohydride. D. A. Knight, R. Zidan,<br />
R. Lascola, T. Motyka,<br />
P. Simvasubramanian, R. Mohtadi<br />
3:50 708. Chemistry of trimethylaluminium:<br />
A spontaneous route to thermally stable<br />
3D crystalline macroporous alumina<br />
foams with a hierarchy of pore sizes.<br />
B. Su, Y. Li, X. Yang<br />
4:10 709. Dry water: Can we still make<br />
waves? B. O. Carter, J. V. Weaver,<br />
D. J. Adams, A. I. Cooper, W. Wang,<br />
D. G. Spiller<br />
4:30 710. ZnO nanostructures with outstanding<br />
gas sensing performance.<br />
D. Bekermann, D. Barreca, E. Comini,<br />
A. Gasparotto, C. Maccato, R. A. Fischer,<br />
A. Devi<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Biology<br />
S. Wong, Organizer<br />
S. Pascu, Presiding<br />
1:30 711. Nanotubes as radiopharmaceuticals<br />
for cancer imaging and therapy.<br />
Y. Mackeyev, J. Sims-Mourtada,<br />
L. Wilson, I. Tworowska<br />
1:50 712. Synthesis, characterization, and<br />
computed tomography imaging of a tantalum<br />
oxide nanoparticle imaging agent.<br />
P. J. Bonitatibus Jr, A. S. Torres,<br />
G. D. Goddard, P. F. FitzGerald,<br />
A. M. Kulkarni<br />
2:10 713. Synthetic extracellular matrices<br />
and nanostructures for biomedical applications.<br />
W. Suh, G. Stucky, M. Tirrell<br />
2:30 714. Production of zeolite including microfluidic<br />
channels: Applications in biosensors.<br />
S. K. Kirdeciler,<br />
B. Ozansoy Kasap, B. Akata, S. Öztürk<br />
2:50 715. Design, synthesis, and characterization<br />
of functional carbon nanomaterials<br />
for bioimaging applications: Toward<br />
healthcare for the modern age.<br />
S. I. Pascu<br />
3:20 Intermission<br />
3:30 716. Novel approach to nanoscale materials<br />
assembly using bioengineered spider<br />
silk fusion proteins and chemically<br />
generated fusion proteins- application to<br />
the synthesis of a range of nanosized<br />
metal and oxide particles. C. C. Perry,<br />
O. Deschaume, H. A. Currie, D. L. Kaplan,<br />
E. Boix-Lopez, L. Canabady-Rochelle,<br />
D. J. Belton<br />
4:00 717. DNA-mediated assembly of<br />
nanocubes. F. Lu, Y. Zhang,<br />
D. van der Lelie, O. Gang<br />
4:20 718. Dephosphorylation of biologically<br />
relevant molecules by cerium oxide nanoparticles<br />
(CNP). M. H. Kuchma, J. Colon,<br />
B. Alvarado, C. H. Baker, A. Teblum,<br />
A. Masonov<br />
4:40 719. Design of intracellular pH sensitive<br />
nanovalve on mesoporous silica nanoparticle.<br />
M. Xue,H.Meng,T.Xia,<br />
Y. Zhao, J. F. Stoddart, A. E. Nel,<br />
J. I. Zink<br />
5:00 720. Noninvasive release of drugs by<br />
magnetic actuation of mechanized nanoparticles.<br />
C. R. Thomas, D. P. Ferris,<br />
J. Lee, J. Cheon, J. I. Zink<br />
5:20 721. Effect of surface chemistry on uptake,<br />
distribution and excretion of nanomaterials<br />
by Japanese medaka. Z. Zhu,<br />
R. Carboni, M. Quercio, B. Yan,<br />
O. R. Miranda, K. F. Arcaro, R. W. Vachet,<br />
V. M. Rotello<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Materials Chemistry & Nanoscience<br />
Sponsored by ANYL, Cosponsored by INOR<br />
WEDNESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Bioinorganic Chemistry<br />
M. Millar, Organizer<br />
7:00–9:00<br />
722. High yield flash-quench method to<br />
probe long-range electron transfer. P. Lin<br />
723. Bioinspired small molecule activation<br />
with monofunctionalized aminopyridine<br />
macrocyclic complexes of iron.<br />
T. Palluccio, V. Organo, W. Ye,<br />
E. Rybak-Akimova<br />
724. Interface probing with 2,6-pyridinedicarboxylic<br />
acid: CTAB micelles and reverse<br />
micelles. E. Gaidamauskas,<br />
D. Cleaver, P. B. Chatterjee, D. C. Crans<br />
725. Aromatic hydroxylation at nonheme iron<br />
model complexes: Kinetics and insights<br />
into the nature of the active species.<br />
O. Makhlynets, P. Das, L. Que Jr.,<br />
E. Rybak-Akimova<br />
726. Role of the [Fe-S] protein YfaE in the<br />
biosynthesis of the diferric-tyrosyl radical<br />
cofactor of class Ia ribonucleotide reductase.<br />
C. Shih, C. Wu, W. Jiang, C. Krebs,<br />
J. Stubbe<br />
727. Development of heme fusion tags for<br />
protein affinity purification, for protein<br />
quantitation, and for monitoring protein<br />
folding. W. B. Asher,T.D.Krauss,<br />
K. L. Bren<br />
728. Kinetic studies of formation and reactivity<br />
of peroxo- and Fe III Fe IV intermediates<br />
with tris-picolylamine ligands. X. Sun,<br />
S. V. Kryatov, E. V. Rybak-Akimova<br />
729. Spectroscopic and computational investigations<br />
into the mechanism of oxalate<br />
decarboxylase. A. M. Glass,<br />
T. A. Jackson<br />
730. Immobilization of Cellobiase enzyme in<br />
mesoporous silica and its application in<br />
saccharification of biomass. S. Das,<br />
D. Berke-Schlessel, Y. Wei<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
General Inorganic Chemistry<br />
B. Donovan-Merkert, M. Millar, Organizers<br />
7:00–9:00<br />
731. Self-assembled monolayers of heteroleptic<br />
ruthenium complexes incorporating<br />
redox-active ligand architectures.<br />
J. P. Harney, D. A. Walsh, J. Rochford<br />
732. Kinetic studies of labile olefins of platinum(II)<br />
complexes. J. A. Dudziak,<br />
J. D. Atwood<br />
733. Electronic perturbations of iron dipyrromethene<br />
complexes by variations in the<br />
ligand periphery. A. B. Scharf,<br />
T. A. Betley<br />
734. Oxidation of alcohols by a tetra-ruthenium<br />
polyoxometalate complex: Kinetics<br />
and mechanism. G. Zhu,C.Besson,<br />
Y. V. Geletii, P. Zhuk, D. G. Musaev,<br />
C. L. Hill<br />
735. Elctron transfer in [Ru(bpy) 2(5,5�dabpy-(phe-A)<br />
2)] 2� dyad. I. Hsu<br />
736. Synthesis, characterization, and metalation<br />
of phthalocyanine analogs with<br />
phenol and resorcinol units. R. S. Costa,<br />
C. J. Ziegler<br />
737. Contrasting magnetic dimensionality<br />
and other properties of nickel dibromide<br />
dihydrate and monohydrate.<br />
G. C. DeFotis,A.S.Hampton,<br />
J. M. Pothen, C. M. Davis, C. L. DeSanto<br />
738. Contrasting magnetic dimensionality<br />
and other properties of manganese dibromide<br />
dihydrate and monohydrate.<br />
G. C. DeFotis,A.S.Hampton,<br />
J. M. Pothen<br />
739. Detection via coumarin-based sensors<br />
for sensing metal ions and nerve gas<br />
agents. E. Sinn,F.A.Abebe<br />
740. Land-use and land cover effects on<br />
stream physical and chemical parameters<br />
of the Neponset River Watershed.<br />
N. D. Henderson, A. D. Christian,<br />
R. E. Hannigan<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–71
INOR/MEDI <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section C<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Nanoscience<br />
Zero-dimensional Structures<br />
S. Wong, Organizer<br />
7:00–9:00<br />
741. Synthesis and characterization of perovskite<br />
PbTiO 3 nanoparticles with solution<br />
processibility. J. Wang,Z.Lin<br />
742. Shape-controlled synthesis of ferroelectric<br />
BaTiO 3 nanocrystals via nonaqueous<br />
thermal decomposition. Z. Lin,<br />
J. Wang<br />
743. Surface modification of CuInS 2 nanoparticles.<br />
Y. Kim,H.Yang,H.Kim,K.Kim<br />
744. Synthesis via green chemistry and characterization<br />
of metal and mixed metal<br />
nanoparticles. S. K. St. Angelo,<br />
E. L. Hartz, K. A. Cohen, M. C. Kyper<br />
745. Structural host effects on the nature of<br />
mixed-metal interactions in nanoclusters<br />
of dicyanoargentate(I) and dicyanoaurate(I)<br />
ions doped in different alkali halides.<br />
H. H. Patterson, D. A. Welch,<br />
F. Baril-Robert, X. Li<br />
746. Highly massive synthesis of gold nanoparticles<br />
using polymeric reduction and<br />
capping agent of polyethyleneimine.<br />
R. Kim,W.Kim,J.Yi<br />
747. Integrated synthetic methodology for<br />
surface passivation and kinetic stabilization<br />
of aluminum nanoparticles with polymerizable<br />
capping agents. B. J. Thomas,<br />
S. W. Buckner, M. A. Burgers,<br />
S. W. Chung, D. W. Hammerstroem,<br />
P. A. Jelliss, C. D. Oberle, C. E. Bunker,<br />
E. A. Guliants, S. E. Hayes, K. Wentz<br />
748. Structural and optical properties of<br />
transition-metal nanoparticles in nanoporous<br />
silica matrices. P. Jagassar,<br />
J. C. Colis, S. Dehipawala,<br />
D. S. Amarasinghe, H. D. Gafney<br />
749. Step-by-step heteroepitaxial growth of<br />
Pd@Au@Pd@Au and Au@Pd@Au@Pd<br />
core-multishell nanocrystals. F. Wang,<br />
J. Wang<br />
750. Experimental validation of a chemomechanical<br />
model: Bridging the �m–nm<br />
gap. T. J. Kucharski, Z. Huang, Q. Yang,<br />
S. Akbulatov, Y. Tian<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Chemistry of Materials<br />
D. Nelson, M. Millar, Organizers<br />
7:00–9:00<br />
751. Development of a materials chemistry<br />
process for solution fabricated amorphous<br />
metal oxide thin film transistors.<br />
K. K. Banger, R. L. Peterson, K. Mori,<br />
Y. Yamashita, T. Leedham, H. Sirringhaus<br />
752. Preparation and characterization of silver<br />
chloride/silver nanostructures for<br />
plasmonic photocatalyst. K. Shin, J. Jang<br />
753. Development of a simple preparation<br />
method of multimetallic oxides related to<br />
the SHArK project. K. J. Watkins,<br />
L. M. Breindel, M. D. Dallas, D. V. Tryon,<br />
C. C. Raymond<br />
754. From single molecule to nanoscopically<br />
structured materials: Rational reversible<br />
self assembly of metal chalcogenide/<br />
metal oxide nanostructures based on<br />
Pearson’s hardness. J. K. Sahoo,<br />
M. N. Tahir, A. Yella, T. Schladt,<br />
W. Tremel<br />
755. Synthesis and characterization of cobalt<br />
doped ZnO. L. A. Smith, T. Fereday,<br />
J. Harris, A. Thurber, J. Brotherton,<br />
W. B. Knowlton, A. Punnoose, B. J. Frost<br />
72–TECH<br />
‡ Cooperative Cosponsorship<br />
756. <strong>Chemical</strong> vapor deposition of vanadium<br />
(V) oxide using two different precursors:<br />
Effects of precursor chemistry on film<br />
morphology. H. Leonard, T. Moersch,<br />
C. Taylor<br />
757. Dye-sensitization of europium chalcogenide<br />
semiconductors. S. Kar,<br />
M. W. Megra, S. L. Stoll<br />
758. Surface interactions of boron nitride on<br />
ruthenium (0001) surfaces. G. R. Morello,<br />
T. R. Cundari, J. A. Kelber, B. Chilukuri,<br />
C. Bjelkevig, M. Zhou<br />
759. Biomimetic cross-linking polymers inspired<br />
by mussel adhesive proteins.<br />
C. R. Matos-Pérez, J. D. White,<br />
J. J. Wilker<br />
760. Colloidal crystals and inverse patterned<br />
colloidal crystals of well-ordered nano/<br />
microstructured array of conducting polymer<br />
films. R. B. Pernites, M. Felipe,<br />
R. C. Advincula<br />
761. Targeted synthesis of novel porous organic<br />
framework that store gas. T. Ben,<br />
S. Qiu<br />
762. Microporous luminescent metal-organic<br />
framework for highly selective and sensitive<br />
sensing of Cu 2� in aqueous solution.<br />
Y. Xiao, Y. Cui, Q. Zheng, S. Xiang,<br />
G. Qian, B. Chen<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Coordination Chemistry<br />
Characterization and Applications<br />
D. Crans, M. Millar, Organizers<br />
7:00–9:00<br />
763. Synthesis, characterization, magnetic<br />
properties and 120 K crystal structure of<br />
[Cu(phen) 2(ONO 2)][NO 3].HDCI: Further insights<br />
into structural pathways involving<br />
nitrato copper(II) complexes. B. Murphy<br />
764. Kumada coupling reactions catalyzed<br />
by Cobalt-zirconium heterobimetallic<br />
complexes. W. Zhou, C. M. Thomas<br />
765. Synthesis and characterization of symmetrical<br />
and unsymmetrical imidoylamidines<br />
promoted by coordinatively unsaturated<br />
bis-nickel (II)-hydroxy complex.<br />
C. R. Guifarro Calona, J. P. Wikstrom,<br />
A. S. Filatov, E. V. Rybak-Akimova<br />
766. Bridging the world of chemistry and the<br />
world of electricity: Synthesis, characterization<br />
and redox properties of salan diolates<br />
of titanium(IV). M. Quiroz-Guzman,<br />
S. N. Brown<br />
767. Characterization of stability and protonation<br />
constants of novel bifunctional ligands<br />
for use in a copper sensor.<br />
J. C. Reddel, N. E. Bencivenga,<br />
J. Massing, R. Ding, W. R. Seitz,<br />
R. P. Planalp<br />
768. Aggregation studies of amyloid beta<br />
peptide in the presence of metal cations<br />
and metal binding-compounds.<br />
N. Hawco, L. M. Mirica<br />
769. Development and validation of a HPLC<br />
method for simultaneous determination<br />
of a nytrosil ruthenium complex and PpIX,<br />
used in association in PDT. A. R. Carollo,<br />
C. A. Carollo, R. S. da Silva,<br />
M. L. Bentley<br />
770. Enantioselective axial corrdination of<br />
�-amino acids in chiral zinc porphyrin assembly.<br />
H. Jintoku, S. Shimoda,<br />
T. Sagawa, M. Takafuji, H. Ihara<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Coordination Chemistry<br />
Synthesis<br />
D. Crans, M. Millar, Organizers<br />
7:00–9:00<br />
771. Dipyrrinato complexes of platinum(II).<br />
S. M. Matlosz, M. M. Olmstead,<br />
J. R. Stork<br />
772. Mixed metal/lithium metal-organic<br />
frameworks. P. J. Calderone,<br />
D. Banerjee, L. A. Borkowski, J. B. Parise<br />
773. Supramolecular nanotubes based on<br />
Ln(III) ions and tptz ligands: Gas sorption<br />
and single crystal X-ray studies of<br />
[Ln(tptz)(HCOO) 3]�2.5H 2O(Ln� Pr, Sm).<br />
N. Lopez, H. Zhao, D. Zhao, H. Zhou,<br />
K. R. Dunbar<br />
774. Ionothermal synthesis of divalent metal<br />
phosphonates. K. J. Gagnon, Z. J. Beal,<br />
A. Clearfield<br />
775. Synthesis, reactivity and characterization<br />
of polymetallic complexes.<br />
D. J. Xiao, A. R. Fout, T. A. Betley<br />
776. Precursor Pt-Co complexes for heterobimetallic<br />
nanoparticles catalysts.<br />
G. Suliman, H. N. Miras, R. G. Raptis<br />
777. Synthesis, characterization, and reactivity<br />
of tri-iron clusters. T. Agee,<br />
T. Betley<br />
778. Lanthanide clusters for structural and<br />
reduction studies. S. L. Dempsey,<br />
T. Hughbanks<br />
779. Design and synthesis of a transchelating<br />
phosphine ligand and its metal complexes.<br />
K. Ding,C.C.Lu<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Main Group Chemistry<br />
B. Donovan-Merkert, Organizer<br />
7:00–9:00<br />
780. Using force as a molecular ruler: Insights<br />
into substitutions at phosphorus.<br />
R. Boulatov, T. J. Kucharski,<br />
S. Akbulatov<br />
781. Sequential formation of the endohedral,<br />
substituted clusters: Pd@Sn 9SnCy 3 3- ,<br />
Pd@Sn 9PdSnCy 3 3- . F. S. Kocak,<br />
P. Y. Zavalij, B. W. Eichhorn<br />
782. Reactions of [PCl 2N] 3 with electrophiles.<br />
Z. Tun, M. J. Panzner,<br />
D. A. Medvetz, B. D. Wright, L. Li,<br />
D. Savant, V. Scionti, C. Wesdemiotis,<br />
P. L. Rinaldi, W. J. Youngs, C. A. Tessier<br />
783. Investigation of the byproducts of the<br />
ring opening polymerization of [PNCl 2] 3.<br />
D. J. Bowers, J. Baughman, V. Scionti,<br />
M. J. Panzner, C. Wesdimiotis, M. Espe,<br />
W. J. Youngs, C. A. Tessier<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Inorganic Spectroscopy<br />
S. Ronco, Organizer<br />
7:00–9:00<br />
784. Structural characterization of copper(II)<br />
binding to the high affinity site in alphasynuclein<br />
by electron paramagnetic resonance.<br />
E. E. Rodriguez,A.Binolfi,<br />
C. O. Fernandez, L. Quintanar<br />
785. Withdrawn<br />
786. Spectroscopic evaluation of copper (II)<br />
binding to alpha and beta-peptide fragments<br />
of the human prion protein.<br />
L. Rivillas-Acevedo, L. Blancas,<br />
J. E. García, E. Juaristi, L. Quintanar<br />
787. 93 Nb solid state NMR study of Dion-Jacobson<br />
type layered niobates XLaNb 2O 7<br />
(X�Cs, Rb, K, H). T. Liu,H.Yang,<br />
L. J. Smith<br />
788. Characterization of the HypA nickel trafficking<br />
protein from Helicobacter pylori.<br />
V. Martin-Diaconescu,M.J.Maroney<br />
789. Series of vibrational circular dichroism<br />
of �-SAPR-8-tetrakis((�)-heptafluorobutyrylcamphorato)lanthanide(III)complexes<br />
with an encapsulated cesium ion,<br />
Cs[Ln((�)-hfbc) 4]: Correlation with the<br />
ground state orbital parity. S. Kaizaki,<br />
D. Shirotani, K. Yamanari, H. Sato<br />
790. Colorimetric fluoride ion sensor based<br />
on ruthenium complex having hydroxyl<br />
groups. Y. Tsai,I.Chang<br />
Section I<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Organometallic Chemistry Applications to<br />
Organic Transformations<br />
N. Radu, Organizer<br />
7:00–9:00<br />
791. Synthesis of ruthenium quinone methide<br />
complexes. H. Yang, D. Morgan,<br />
C. Cai, W. Dai, R. D. Pike, W. C. Trenkle,<br />
D. A. Sweigart<br />
792. Ligand enabled oxidation of monoary-<br />
Pd II complexes with aqueous H 2O 2 to<br />
stable monoaryl Pd IV complexes and<br />
consecutive C-O reductive elimination<br />
studies. W. N. Oloo,A.N.Vedernikov<br />
793. Reactions of dicationic platinum(II)<br />
alkyne complexes with arenes.<br />
M. Miranda, C. Hahn<br />
794. Preferential binding of an iridium(III) porphyrin<br />
with methoxide and methanol in<br />
competition with hydroxide and water in<br />
aqueous solution. S. Bhagan,<br />
B. B. Wayland<br />
795. Simultaneous degenerate proton and<br />
methanol ligand exchange processes for<br />
[(TMP)Rh-OCH 3(CH 3OH)] in methanol/<br />
benzene media. S. Sarkar,S.Li,<br />
B. B. Wayland<br />
796. Study of oxidatively-induced reductive<br />
elimination of carbon-halogen bonds<br />
from nickel. A. Higgs, M. Sanford<br />
THURSDAY MORNING<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Energy & Sustainability Sponsored by ANYL,<br />
Cosponsored by INOR<br />
THURSDAY AFTERNOON<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Look Where the Crossroads Led Us<br />
Sponsored by ANYL, Cosponsored by INOR<br />
MEDI<br />
Division of Medicinal<br />
Chemistry<br />
J. Zablocki, Program Chair<br />
SOCIAL EVENTS:<br />
Social Hour, 7:00 PM: Sun<br />
Social Hour, 7:00 PM: Wed<br />
SUNDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
General Oral Session<br />
J. Zablocki, Organizer, Presiding<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
8:30 1. 2-Aminothiazoles derivatives as potent<br />
�-secretase modulators. S. Cheng,<br />
D. Comer, L. Mao, D. Pleynet, C. Yu,<br />
M. Z. Kounnas, C. Tyree, A. D. Danks,<br />
S. L. Wagner, W. T. Comer<br />
8:50 2. New aminohydantoins as BACE1 inhibitors.<br />
M. S. Malamas, A. Robichaud,<br />
J. Erdei, D. Quagliato, W. Fobare,<br />
A. Porte, J. Kim, W. Solvibile, P. Zhou,<br />
R. McDevitt, K. Morris, S. Antane,<br />
J. Turner, E. Wagner, K. Fan, J. Bard,<br />
S. Jacobsen, P. Reinhart, M. Pangalos,<br />
D. Riddell<br />
9:10 3. New potent and selective PDE10A<br />
inhibitors for the treatment of schizophrenia.<br />
M. S. Malamas, Y. Ni, J. Erdei,<br />
K. Fan, N. Hoefgen, H. Stange,<br />
R. Schindler, C. Grunwald, U. Egerland,<br />
B. Langen, T. Hage, T. Kronbach,<br />
S. Grauer, B. Harrison, A. Robichaud,<br />
K. Marquis, T. Comery, J. Dunlop,<br />
M. Pangalos, N. Brandon<br />
9:30 4. Amino imidazoles as �-secretase inhibitors<br />
for treatment of Alzheimer’s disease.<br />
M. Brodney, K. Borzilleri,<br />
S. Capetta, L. Chenard, K. Coffman,<br />
P. Dorf, J. Dutra, I. Efremov, C. Helal,<br />
G. Kauffman, L. Lanyon, D. Liston, J. Liu,<br />
F. Nelson, C. Oborski, B. O’Neill,<br />
T. O’Sullivan, B. Sahagan, F. Vajdos,<br />
M. Wessel, J. Withka, T. N. O’Connell,<br />
H. Wang<br />
9:50 5. Development of TRPM8 selective<br />
antagonists for the treatment of inflammatory<br />
and neuropathic pain.<br />
H. Monenschein, Y. Bo, J. Clarine,<br />
C. Davis, H. Deng, V. Gore, D. Horne,<br />
M. Horner, M. Kaller, S. Lehto, V. Ma,<br />
K. Nagapudi, T. Nguyen, N. Nishimura,<br />
M. Norman, N. Tamayo, J. Treanor,<br />
Y. Wang, T. Wang, W. Wang, K. Wild,<br />
B. Youngblood, M. Zhang, W. Zhong,<br />
D. Zhu, N. Gavva<br />
10:10 6. Discovery of new high-affinity<br />
PDE10 inhibitors using fragment based<br />
lead generation and knowledge-based<br />
design. J. S. Albert, D. Aharony,<br />
T. Akerud, U. Bauer, N. Dekker, J. Forst,<br />
S. Geschwindner, C. Holmquist,<br />
P. Johansson, C. Scott, L. Spadola,<br />
N. Spear, G. Tian, X. Wang, D. Wilkins,<br />
M. Wood, E. Back, P. Hillertz,<br />
R. Horsefield, A. Tigerstrom<br />
10:30 7. Discovery of potent and orally bioavailable<br />
phthalazinone Bradykinin B1 receptor<br />
antagonists for chronic pain.<br />
K. Biswas, T. A. Peterkin, M. C. Bryan,<br />
L. Arik, S. G. Lehto, H. Sun, F. Hsieh,<br />
C. Xu, R. T. Fremeau, J. R. Allen<br />
10:50 8. Rational design, synthesis and<br />
structure-activity relationships of novel<br />
bicyclic azole-amines as negative allosteric<br />
modulators of Metabotropic Glutamate<br />
Receptor 5. D. F. Burdi, R. Hunt,<br />
L. Fan, T. Hu, J. Wang, Z. Guo, Z. Huang,<br />
C. Wu, L. Hardy, M. Detheux,<br />
M. A. Orsini, M. S. Quinton, R. Lew,<br />
K. Spear<br />
11:10 9. Activation of retinoic acid inducible<br />
gene (RIG-I) by nucleotide analogs: A potential<br />
novel mechanism for antiviral discovery.<br />
R. P. Iyer, J. E. Coughlin,<br />
S. Padmanabhan, B. Korba, S. Myong<br />
11:30 10. Discovery of the 1,7-diazacarbazole<br />
class of inhibitors of checkpoint kinase<br />
1. L. J. Gazzard<br />
11:50 11. Rapid discovery of a DP1 antagonist<br />
series with good developability characteristics.<br />
S. Peace, M. Foster,<br />
S. Campos, M. Crawford, G. Inglis,<br />
J. Pritchard, J. Redmond, D. Tape,<br />
A. Craven, I. Campbell, S. Keeling,<br />
R. Wheeler, Y. Solanke, L. Butterfield,<br />
C. Edwards, N. Lindsay<br />
12:10 12. Discovery and optimization of<br />
benzylphenoxyethyluracil to yield non-nucleoside<br />
inhibitors of HIV-1 reverse transcriptase<br />
using virtual screening and freeenergy<br />
calculations. V. V. Thakur,<br />
R. A. Domaoal, S. E. Nichols,<br />
K. S. Anderson, W. L. Jorgensen<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom West<br />
60 Years of <strong>Chemical</strong> Research at the<br />
National Institute of Diabetes & Digestive &<br />
Kidney Diseases<br />
K. A. Jacobson, J. Hanover, Organizers,<br />
Presiding<br />
9:00 13. Medicinal chemistry in opioid research:<br />
Looking back. K. C. Rice<br />
9:45 14. Targeting O-GlcNAc cycling: Impact<br />
on the epigenetics of diabesity and<br />
immunity. J. A. Hanover<br />
10:20 15. Membrane trafficking complexes<br />
of the ESCRT pathway. J. H. Hurley<br />
10:55 16. G Protein-coupled receptor signaling<br />
pathways in pancreatic beta-cells.<br />
J. Wess<br />
11:30 17. New frontiers for selective agonists<br />
and antagonists of adenosine and<br />
P2Y receptors. K. A. Jacobson<br />
Tautomers and Biology<br />
Computer Handling of Tautomers<br />
Sponsored by COMP, Cosponsored by CINF,<br />
MEDI, and PHYS<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom West<br />
First Time Disclosure of Clinical Candidate<br />
Financially supported by Lundbeck Research,<br />
USA<br />
A. J. Robichaud, Organizer, Presiding<br />
2:00 18. First disclosure of PF-03715455:<br />
An inhaled p38 inhibitor for the treatment<br />
of chronic obstructive pulmonary disease.<br />
D. Millan, M. Bunnage, K. Butcher,<br />
P. Dodd, T. Evans, D. Fairman,<br />
S. Hughes, I. Kilty, A. Lemaitre,<br />
R. Lewthwaite, J. Mathias, C. Phillips,<br />
R. Smith, M. Stefaniak, M. Yeadon<br />
2:30 19. Discovery of PSI-352938 and PSI-<br />
353661: Purine nucleotide prodrugs for<br />
the treatment of HCV. M. J. Sofia,<br />
D. Bao, W. Chang, B. Chun, J. Du,<br />
D. Nagarathnam, S. Rachakonda,<br />
P. G. Reddy, B. S. Ross, H. Zhang,<br />
S. Bansal, H. Bao, C. L. Espiritu,<br />
M. Keilman, A. M. Lam, E. Murakami,<br />
C. Niu, H. M. Steuer, T. Tolstykh,<br />
V. Zennou, P. A. Furman, M. J. Otto<br />
3:00 20. Discovery and early development<br />
of ALKS-33, an opioid modulator for<br />
treatment of reward disorders.<br />
&. Almarsson, D. R. Deaver,<br />
R. Z. Turncliff, M. Wentland, E. Ehrich<br />
3:30 21. Discovery of a new class of SGLT2<br />
inhibitors. V. Mascitti<br />
4:00 22. INS115644 (latrunculin B): A potential<br />
new treatment for glaucoma.<br />
P. S. Watson, W. Peterson, J. Vittitow,<br />
J. Lampe, J. She, L. Trevino, L. Richards,<br />
R. Krishnamoorthy<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
General Oral Session<br />
J. Zablocki, Organizer, Presiding<br />
2:00 23. Making agonists from antagonists:<br />
SAR106881, a breakthrough in FGFRs<br />
activation and a potential treatment to improve<br />
peripheral revascularization and reduce<br />
neuropathic pain. N. Guillo<br />
2:20 24. Using irreversibility to achieve enhanced<br />
potency and selectivity against<br />
the HCV protease. D. Niu, M. Hagel,<br />
L. Qiao, T. St. Martin, M. P. Sheets,<br />
Z. Zhu, M. T. Labenski, P. Chaturvedi,<br />
M. Nacht, W. F. Westlin, R. C. Petter,<br />
J. Singh<br />
2:40 25. <strong>Chemical</strong> biology of chromatin regulation:<br />
The first small molecule antagonists<br />
of MBT domains. J. Herold,<br />
T. J. Wigle, C. Gao, D. B. Kireev,<br />
W. P. Janzen, S. V. Frye<br />
3:00 26. PXR agonism and drug-drug interactions:<br />
Structure based design to eliminate<br />
PXR mediated CYP induction.<br />
J. Ramanjulu, L. Casillas, A. Charnley,<br />
M. DeMartino, X. Dong, P. Harris,<br />
J. Jeong, Y. Lan, A. Rahman,<br />
S. P. Williams, A. Lakdawala, L. Dare,<br />
S. Hoffman, M. Schaeffer, S. Kumar,<br />
R. Marquis<br />
3:20 27. Discovery of CRM1-mediated nuclear<br />
transport inhibitors as novel modulators<br />
of epigenetic enzymes.<br />
V. Sandanayaka, R. Nir, S. Shechter,<br />
M. Kauffman, S. Shacham<br />
3:40 28. Identification of the pharmacophore<br />
of 4EGI-1, an inhibitor of translation initiation<br />
with anti-cancer activity.<br />
E. Y. Kabha,Y.Wang,L.Chen,<br />
N. Zhang, R. Rodriguez,<br />
E. Papadopoulos, G. Wagner,<br />
B. H. Aktas, J. A. Halperin, M. Chorev<br />
4:00 29. High-affinity binding of small-molecules<br />
to the intrinsically disordered c-Myc<br />
oncoprotein. A. Viacava Follis, H. Wang,<br />
D. I. Hammoudeh, E. V. Prochownik,<br />
S. J. Metallo<br />
4:20 30. Design and synthesis of HDAC inhibitors<br />
for property based optimization.<br />
E. Choi,J.Park,J.Seo,G.Han<br />
4:40 31. Identification of the b-amyloid PET<br />
ligand candidate MK-3328.<br />
S. T. Harrison, J. C. Barrow, J. J. Cook,<br />
J. C. Culberson, H. Fan, G. D. Hartman,<br />
E. Hostetler, P. J. Miller, J. J. Mulhearn,<br />
S. S. O’Malley, C. Ryan, S. Sanabria,<br />
C. Sur, S. E. Wolkenberg, D. L. Williams,<br />
Z. Zeng<br />
5:00 32. Long-residence time kinase inhibitors:<br />
Binding kinetics in fragment-based<br />
design. G. Mueller, P. C. Sennhenn,<br />
L. Neumann<br />
5:20 33. Novel and efficient inhibitors of<br />
peptidyl-prolyl-cis/trans-isomerases Pin1<br />
and cyclophilin. M. Braun<br />
Using Waters Explicitly in Drug Discovery<br />
Theory and Methods Sponsored by COMP,<br />
Cosponsored by CINF and MEDI<br />
SUNDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Poster Session and Social Hour<br />
J. Zablocki, Organizer<br />
7:00–9:00<br />
34. Spirocyclic sulfamides as �-secretase inhibitors<br />
for treatment of Alzheimer’s disease.<br />
M. Brodney, C. Ambroise, F. Bian,<br />
K. Borzilleri, H. Coffey, K. Coffman,<br />
C. Christoffersen, I. Efremov,<br />
E. Hajos-Korcsok, D. Hannah, C. Helal,<br />
G. Kauffman, L. Lanyon, D. Liston, J. Liu,<br />
Y. Lu, L. Martinez-Alsina, J. Murray,<br />
F. Nelson, S. Noell, C. Nolan, C. Oborski,<br />
B. O’Neill, K. Ogilvie, B. Sahagan,<br />
J. Tuttle, F. Vajdos, J. Withka<br />
35. Amyloid beta aggregates as intrinsic<br />
platforms for assembling a non-conjugated<br />
non-bioengineered FRET pair.<br />
C. Ran, A. Moore<br />
36. Curcumin analogs as “turn-on” fluorescent<br />
probes for a wide variety of amyloid<br />
beta species and in vivo imaging with<br />
transgenic mice. C. Ran, A. Moore<br />
37. Structure-activity relationship of dual target<br />
inhibitors of amyloid-beta self-assembly.<br />
A. Sood, A. Kulkarni, D. Borkin,<br />
S. Bag, S. Dasgupta, H. LeVine III,<br />
B. Torok, M. Torok<br />
38. Development of hydantoin spiropiperidines<br />
as potent BACE1 inhibitors.<br />
J. M. Wai, M. Egbertson, D. Perlow,<br />
C. Coburn, L. Neilson, S. Pitzenberger,<br />
G. McGaughey, D. Colussi,<br />
S. Haugabook, K. Tugusheva, J. Chang,<br />
C. Fandozzi, T. Allison, M. Dancho,<br />
M. Michener, D. Posavec, N. Pudvah,<br />
J. Vacca, S. Graham<br />
39. Evaluation of virtual screening methods<br />
towards the discovery of new functional<br />
transthyretin amyloid inhibitors.<br />
C. J. Simões, T. Mukherjee,<br />
R. M. Jackson, R. M. Brito<br />
40. Novel amides and ureas as �-secretase<br />
modulators. H. Zhou, C. Fischer,<br />
L. Surdi, S. Zultanski, P. Tempest,<br />
B. Hughes, R. Middleton, N. Smotrov,<br />
N. Bays, S. Shah, B. Munoz,<br />
M. Shearman<br />
41. Novel iminopyrimidinone �-secretase<br />
(BACE) inhibitors: P1-thiophenes.<br />
J. D. Scott, S. W. Li, E. J. Gilbert,<br />
C. Huang, J. Cumming, U. Iserloh,<br />
R. D. Mazzola, S. Babu, J. Caldwell,<br />
X. Chen, K. Cox, M. Czarniecki, J. Durkin,<br />
L. Favreau, T. Gu, W. J. Greenlee,<br />
R. Hodgson, Y. Huang, L. Hyde, Q. Jiang,<br />
M. Kennedy, R. Kuvelkar, G. Li,<br />
V. Madison, B. McKittrick, M. W. Miller,<br />
P. Orth, J. Pan, E. Parker, P. Pasetto,<br />
A. W. Stamford, C. Strickland, Z. Sun,<br />
D. Tadesse, J. Voight, L. Wang,<br />
B. Werner, J. Wong, Y. Wu, L. Zhang,<br />
Q. Zhang, Z. Zhu<br />
42. Tetracyclic sulfones as gamma secretase<br />
inhibitors. T. K. Sasikumar<br />
43. Novel inhibitors of AHCY for the treatment<br />
of Alzheimer’s disease.<br />
T. J. Hartingh, A. Converso, M. E. Fraley,<br />
E. J. Brnardic, R. M. Garbaccio,<br />
G. D. Hartman, S. Y. Huang, E. S. Tasber,<br />
S. D. Young, L. H. Gold, J. M. Majercak,<br />
A. McCampbell, S. Na, W. J. Ray,<br />
M. J. Savage, Y. Yu, C. Fandozzi,<br />
R. White, S. Yeh, S. M. Galloway,<br />
J. G. DeLuca, V. Reddy, K. Holloway,<br />
T. Allison, S. Munshi, K. Rickert<br />
44. Design and synthesis of neuroprotective<br />
NO chimeras with GABA A potentiating<br />
activity as Alzheimer’s disease therapeutics.<br />
Z. Qin, J. Luo, L. VandeVrede,<br />
G. R. Thatcher<br />
45. Common antibiotics used in the treatment<br />
of gram negative infectious diseases.<br />
S. S. Mantravadi<br />
46. Evidence for the production of novel<br />
macrocyclic antibiotics from the marine<br />
bacterium Pseudovibrio denitrificans.<br />
M. I. Vizcaino, P. J. Morris, P. D. Moeller<br />
47. Design and synthesis of dual CDK2 and<br />
CDK7 inhibitors. E. Meschini,<br />
J. A. Endicott, B. T. Golding,<br />
I. R. Hardcastle, D. R. Newell,<br />
M. E. Noble, L. Wang, R. J. Griffin<br />
48. Synthesis of novel carboxypeptidase ligands<br />
for tumor imaging.<br />
C. Kuechenthal, W. Maison<br />
49. Synthesis and anticancer activity of fatty<br />
acid derivatives of cytarabine.<br />
B. S. Chhikara, D. Mandal, k. Parang<br />
50. Application of in silico design and highthroughput<br />
chemistry platform in the lead<br />
optimization of selective and potent mutant-B-RAF<br />
inhibitors. C. J. Brassard,<br />
J. Lapierre, R. Nicewonger, J. Ring,<br />
K. Bresciano, T. Hall, J. Szwaya, C. Chen,<br />
D. France, M. A. Ashwell<br />
51. Discovery and optimization of a potent<br />
and selective triazolopyridinone series of<br />
c-Met inhibitors. C. M. Bode,<br />
A. A. Boezio, B. K. Albrecht, S. F. Bellon,<br />
M. Broome, D. Choquette, M. Lin, K. Rex,<br />
J. Harmange<br />
52. Discovery of water soluble N,2-dimethyl-<br />
N-substituted phenyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-amines<br />
as antimitotic<br />
agents that circumvent taxol<br />
resistance. A. Gangjee, Y. Zhao,<br />
S. Mooberry<br />
53. Discovery of substituted pyrrolo[2,3d]pyrimidines<br />
as water soluble antitubulin<br />
antitumor agents. A. Gangjee, L. Lin,<br />
S. L. Mooberry, E. Hamel<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
MEDI<br />
TECH–73
MEDI <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
54. Novel tumor-targeting anticancer drug<br />
conjugate bearing a taxoid and a topotecan.<br />
E. S. Zuniga,I.Ojima<br />
55. Synthesis and biological evaluation of<br />
novel carbocycle-containing combretastatin<br />
A-4 analogs. R. Fürst,<br />
C. Nowikow, A. Berenyi, G. F. Ecker,<br />
W. Schmid, I. Zupko, U. Rinner<br />
56. Design of potent guanase inhibitors<br />
based on azepinomycin skeleton.<br />
S. Chakraborty, R. Hosmane<br />
57. Blocking the nuclear translocation of signal<br />
transducer and activator of transcription<br />
3 (STAT3) protein via membrane anchorage.<br />
M. Avadisian, S. Fletcher,<br />
B. Liu, W. Xu, P. Yue, A. D. Schimmer,<br />
J. Turkson, C. Gradinaru, P. T. Gunning*<br />
58. Development of PET and SPECT radiotracers<br />
for the imaging of cancers overexpressing<br />
the ErbB family of growth factor<br />
receptors. E. B. Corcoran, H. T. Pham,<br />
R. N. Hanson<br />
59. Development of a second-generation antiandrogen<br />
for treatment of castration-resistant<br />
prostate cancer (CRPC). D. Yoo,<br />
S. Ouk, C. Chen, C. Tran, J. Wongvipat,<br />
C. L. Sawyers, M. E. Jung<br />
60. Targeting the interaction of mixed lineage<br />
leukemia 1 (MLL1) and wd repeat<br />
domain 5 (WDR5) for new anticancer drug<br />
design. H. Karatas, E. Townsend,<br />
D. Bernard, Y. Dou, S. Wang<br />
61. Rational design and evaluation of small<br />
molecule DNA ligase inhibitors as potential<br />
cancer chemotherapeutics.<br />
G. E. Greco,X.Chen,L.A.Tobin,<br />
R. A. Lapidus, M. Sadowska, A. J. Yang,<br />
N. N. Nemieboka, A. D. MacKerell,<br />
S. Zhong, F. V. Rassool, A. E. Tomkinson<br />
62. Design, synthesis and evaluation of<br />
dibenzo[c,h][1,6]naphthyridines as Top1<br />
inhibitors and potential anticancer<br />
agents. E. Kiselev, T. Dexhemier,<br />
Y. Pommier, M. Cushman<br />
63. Design and synthesis of ezrin inhibitors<br />
for metastatic osteosarcoma.<br />
G. W. Kosturko, G. Bulut, V. Rodriguez,<br />
E. Glasgow, S. Hong, C. Khanna,<br />
M. Brown, M. Paige, A. Üren<br />
64. Small molecule prostate specific membrane<br />
antigen inhibitors with Re/Tc for<br />
the diagnosis and staging of prostate<br />
cancer. G. Lu, K. P. Maresca,<br />
S. M. Hillier, J. C. Marquis,<br />
C. N. Zimmerman, W. C. Eckelman,<br />
J. L. Joyal, J. W. Babich<br />
65. Structure-based design, synthesis, and<br />
evaluation of a new class of potent Bcl-2/<br />
Bcl-X L inhibitors. H. Zhou, J. Chen,<br />
A. Aguilar, X. Cong, L. Liu, L. Bai,<br />
D. McEachern, C. Yang, H. Yi,<br />
J. Meagher, J. A. Stuckey, X. Li, D. Sun,<br />
S. Wang<br />
66. Novel VEGFR2 inhibitors: Pyridylmethylthio<br />
derivatives with intramolecular nonbonded<br />
S-O interaction. H. Tajima,<br />
T. Honda, K. Kawashima, Y. Sasabuchi,<br />
M. Yamamoto, M. Ban, K. Okamoto,<br />
K. Inoue, T. Inaba, Y. Takeno, H. Aono,<br />
T. Tsuboi, A. Tonouchi<br />
67. Design, synthesis and evaluation of<br />
Smac mimetics as selective cIAP-1 and<br />
cIAP-2 inhibitors. H. Sun, J. Lu, L. Liu,<br />
C. Yang, H. Yi, S. Wang<br />
68. DNA methyltransferase inhibitors: Molecular<br />
modeling and virtual screening.<br />
J. L. Medina-Franco, N. Singh,<br />
F. Lopez-Vallejo, D. Kuck, F. Lyko,<br />
A. Dueñas-Gonzalez, G. Sbardella<br />
69. Apoptosis triggers targeting selectively<br />
resistant tumours. E. Genoux,<br />
D. Lorendeau, H. Cortay, A. Di Pietro,<br />
A. Boumendjel<br />
70. 2-Aryl-benzimidazole-4-carboxamides<br />
as novel SIRT1 activators. J. S. Disch,<br />
C. B. Vu, L. McPherson, P. Ng,<br />
J. E. Bemis, D. P. Carney, A. V. Lynch,<br />
C. Loh, S. Ribich, P. Romero, J. J. Smith,<br />
J. Song, D. J. Gagne, A. Cote, M. Davis,<br />
E. Lainez, R. B. Perni<br />
74–TECH<br />
‡ Cooperative Cosponsorship<br />
71. Synthesis and SAR of tricyclic isoquinoline<br />
derivatives as HCV NS3 protease inhibitors.<br />
J. Chen, L. Sun, F. Yu, G. Zhai,<br />
D. Hernandez, A. K. Sheaffer, J. Friborg,<br />
D. Barry, H. Mulherin, M. S. Lee,<br />
F. McPhee, J. O. Knipe, K. Mosure,<br />
N. A. Meanwell, P. M. Scola<br />
72. In vitro and in vivo biological annotation<br />
of a novel B-RAF inhibitor amenable for<br />
clinical evaluation against B-RAF(V600E)harboring<br />
human tumors. J. Lapierre,<br />
C. Chen, Y. Liu, J. Szwaya, E. Chiesa,<br />
C. Bull, E. Chang, C. Waghorne, J. Mao,<br />
D. Lowe, K. Nguyen, E. Volckova,<br />
Y. Wang, T. Hall, R. Savage, D. France,<br />
M. A. Ashwell<br />
73. Design and synthesis of simplified paclitaxel<br />
analogs based on the T-taxol bioactive<br />
conformation. J. Zhao,S.Bane,<br />
K. Mukherjee, J. P. Snyder, H. Hu,<br />
D. G. Kingston<br />
74. Discovery of novel 2,4,6-trisubstituted<br />
pyrimidine and pyridine based SIRT1 activators.<br />
K. J. Koppetsch, C. J. Oalmann,<br />
B. Szczepankiewicz, C. B. Vu,<br />
G. Gualtieri, R. L. Casaubon, J. S. Disch,<br />
A. V. Lynch, J. Song, D. J. Gagne,<br />
A. Cote, M. Davis, E. Lainez, R. B. Perni<br />
75. Discovery of a new class of selective<br />
Chk1 “diazacarbazoles”. J. Drobnick,<br />
B. Appleton, L. Axford, M. Beresini,<br />
B. Burton, H. Chen, D. Clark, K. Clark,<br />
P. Crackett, C. Ellwood, E. Gancia,<br />
A. Ganguli, M. Gill, J. Goldstein,<br />
S. Goodacre, J. Hewitt, D. Hurst, S. Kintz,<br />
P. Lockey, J. Lyssikatos, S. Major,<br />
C. McLeod, D. McNair, G. Medard,<br />
R. Narukulla, R. Newman, S. Sideris,<br />
C. Weismann, H. Hunt, K. Williams,<br />
S. Malek, L. Gazzard<br />
76. Phthalazinone pyrazoles as potent, selective<br />
and orally bio-available inhibitors<br />
of Aurora-A kinase. M. Prime,<br />
F. Brookfield, S. Courtney, G. Georges,<br />
B. Goller, A. Limberg, R. Marston,<br />
P. Rueger, M. Rueth, W. von der Saal<br />
77. Synthesis of novel osteogenic oxysterol<br />
activators of the Hedgehog signaling<br />
pathway. M. Epperson,W.Xiao,<br />
F. Stappenbeck, F. Farouz<br />
78. Putative exosite targeting for optimization<br />
of 4EGI-1, a PPI inhibitor and a potent<br />
anti-cancer agent. K. Takrouri,<br />
Y. Wang, L. Chen, N. Zhang, B. H. Aktas,<br />
G. Wagner, J. A. Halperin, M. Chorev<br />
79. Structure-based computational design of<br />
selective, small molecule PRMT5 inhibitors<br />
for experimental therapeutics of cancer:<br />
Protein modeling, virtual screening<br />
and lead validation. K. V. Mahasenan,<br />
F. Yan, R. Baiocchi, C. Li<br />
80. In vitro and in vivo studies on the effectiveness<br />
of free drug and nanoparticle encapsulated<br />
silver carbene complexes on<br />
H460 lung cancer. M. C. Deblock,<br />
N. Robishaw, A. Knapp, M. J. Panzner,<br />
A. Gupta, W. J. Youngs<br />
81. Design, synthesis, and pharmacological<br />
evaluation of multireceptor modulating<br />
agents as potential atypical antipsychotics.<br />
K. Peprah, S. V. Eyunni,<br />
J. R. Etukala, V. Setola, B. L. Roth,<br />
S. Y. Abblodeppey<br />
82. Selective small molecules targeting<br />
G-protein interactions to combat cancer<br />
metastasis. M. J. Koyack,<br />
R. V. Rajnarayanan<br />
83. Synthetic strategies for developing multivalent<br />
nitric oxide donors.<br />
R. S. Nandurdikar,S.Y.Hong,<br />
O. A. Oladeinde, A. E. Maciag,<br />
J. E. Saavedra, L. K. Keefer<br />
84. Synthesis of carbon-11-labeled casimiroin<br />
analogs as new potential PET agents<br />
for imaging of quinone reductase 2 and<br />
aromatase expression in cancer.<br />
M. Wang, M. Gao, G. D. Hutchins,<br />
Q. Zheng<br />
85. Property based optimization of lactam<br />
based histone deacetylase (HDAC) inhibitors.<br />
M. Cho, D. Song<br />
86. Discovery of potent imidazo[1,2-a]pyrazine<br />
Aurora kinase inhibitors.<br />
D. B. Belanger, P. J. Curran, A. Hruza,<br />
J. Voigt, Z. Meng, A. K. Mandal,<br />
M. A. Siddiqui, A. D. Basso, K. Gray<br />
87. Design, synthesis and biological evaluation<br />
of pemetrexed(PMX) homologs for<br />
folate receptor targeting multiple enzyme<br />
antifolates. A. Gangjee, Y. Wang,<br />
S. K. Desmoulin, C. Cherian,<br />
L. H. Matherly, R. L. Kisliuk<br />
88. Design, synthesis, and testing of orthoamido<br />
diphenylamines as inhibitors of<br />
MEK5. P. T. Flaherty, I. Chopra,<br />
A. Diwan, D. A. Monlish, J. E. Cavanaugh<br />
89. 2-Desamino and 2-methyl-6-substituted<br />
pyrrolo[2,3-d]pyrimidine classical antifolates<br />
as selective folate receptor substrates,<br />
glycinamide ribonucleotide<br />
formyltransferase inhibitors and antitumor<br />
agents. A. Gangjee, S. Zhao, C. Cherian,<br />
S. K. Desmoulin, L. H. Matherly,<br />
R. L. Kisliuk<br />
90. Synthesis and SAR of diaminopyrimidines<br />
as c-Met inhibitors.<br />
L. R. Weinberg, M. S. Albom,<br />
T. S. Angeles, J. L. Diebold, J. Husten,<br />
J. G. Lisko, K. L. Milkiewicz, S. Murthy,<br />
G. R. Ott, B. A. Ruggeri, J. P. Theroff,<br />
T. L. Underiner, B. D. Dorsey<br />
91. Identification of potential proteins targets<br />
of quercetin inhibition of HSP-70 induction<br />
with a biotin-quercetin photoaffinity<br />
agent. R. E. Wang, C. R. Hunt, J. Taylor<br />
92. Development of polyamides as gene inhibitors<br />
of heat shock protein 70 expression.<br />
R. E. Wang, R. Pandita, C. R. Hunt,<br />
J. Taylor<br />
93. Rational design of disubstituted triazole<br />
conjugated acridines with high selectivity<br />
for the human parallel telomeric quadruplex.<br />
S. Sparapani,S.M.Haider,<br />
F. Doria, M. Gunaratnam, S. Neidle<br />
94. Synthesis and characterization of rigidified<br />
4EGI-1 mimetics that block proteinprotein<br />
interaction, inhibit translation initiation,<br />
and have anticancer activity.<br />
R. Yefidoff-Freedman,Y.Wang,<br />
L. Chen, N. Zhang, B. H. Aktas,<br />
G. Wagner, J. A. Halperin, M. Chorev<br />
95. Novel fluorescently labeled omega-3<br />
fatty acid-taxiod conjugates.<br />
W. T. Berger, E. Zuniga, J. D. Seitz,<br />
L. V. Kuznetsova, I. Ojima<br />
96. Discovery of TAK-700, a naphthylmethylimidazole<br />
derivative, as a highly selective,<br />
orally active 17, 20 lyase inhibitor for<br />
prostate cancer. T. Kaku, T. Hitaka,<br />
A. Ojida, N. Matsunaga, N. Terauchi,<br />
F. Itoh, T. Tanaka, T. Hara, M. Yamaoka,<br />
M. Kusaka, T. Okuda, S. Asahi, S. Furuya,<br />
A. Tasaka<br />
97. Structural requirements of histone<br />
deacetylase (HDAC) inhibitors: Suberoyl<br />
anilide hydroxamic acid (SAHA) analogs<br />
modified at the C3 position. S. Choi,<br />
S. V. Weerasinghe, M. H. Pflum<br />
98. Antagonism of the Bak–Bcl-xL complex<br />
by �-helix mimetics of varying curvatures.<br />
S. Fletcher<br />
99. Anticancer properties of gold(I)-N-heterocyclic<br />
carbene complexes and their<br />
silver(I) precursors. T. J. Siciliano,<br />
M. C. Deblock, K. M. Hindi, S. Durmus,<br />
M. J. Panzner, C. A. Tessier,<br />
W. J. Youngs<br />
100. Development of small molecule protein<br />
lysine methyltransferase G9a inhibitors.<br />
J. M. Yost, F. Liu, X. Chen,<br />
A. Allali-Hassani, A. M. Quinn, T. J. Wigle,<br />
D. Barsyte, G. A. Wasney, A. Dong,<br />
I. Kozieradzki, G. Senisterra, I. Chau,<br />
A. Siarheyeva, A. Van Deusen,<br />
D. B. Kireev, A. Jadhav, J. M. Herold,<br />
S. V. Frye, C. H. Arrowsmith,<br />
W. P. Janzen, P. J. Brown, A. Simeonov,<br />
M. Vedadi, J. Jin<br />
101. From isothiazole to thiophene and thiazole:<br />
A bioisosteric approach to the discovery<br />
of potent imidazo[1,2-a]pyrazines<br />
as Aurora kinase inhibitors. Z. Meng,<br />
B. A. Kulkarni, A. D. Kerekes, J. Voigt,<br />
A. K. Mandal, S. J. Esposite,<br />
D. B. Belanger, P. P. Reddy, A. D. Basso,<br />
K. Gray, S. Tevar, J. Jones, E. Smith,<br />
M. A. Siddiqui, R. Doll<br />
102. SAR of various Aurora selective chemotypes.<br />
Z. Ji, Y. Dai, D. H. Albert,<br />
J. J. Bouska, K. B. Glaser,<br />
T. J. Magoc, k. D. Stewart, P. Tapang,<br />
R. Wei, M. Michaelides<br />
103. Development of oxazolidinone and oxazolobenzimidazole<br />
positive allosteric<br />
modulators for the treatment of Schizophrenia.<br />
E. J. Brnardic, R. M. Garbaccio,<br />
M. E. Fraley, M. E. Layton, G. D. Hartman,<br />
M. A. Jacobson, B. C. Magliaro,<br />
S. L. Huszar, P. H. Hutson, J. A. O’Brien,<br />
J. M. Uslaner, K. L. Fillgrove, C. Tang,<br />
Y. Kuo, S. M. Sur<br />
104. 2-Substituted benzimidazoles as<br />
metabotropic glutamate receptor-2 positive<br />
allosteric modulators: A hit to lead<br />
evaluation. C. Chen, U. Topiwala,<br />
H. Jimenez, H. Chen, M. Uberti, K. Jones,<br />
S. Topiol, M. Marzabadi, D. Doller<br />
105. Structure activity relationship studies of<br />
4-((((3S,6S)-6-benzhydryltetrahydro-2Hpyran-3-yl)amino)methyl)phenol<br />
and its<br />
analogs: Development of novel triple uptake<br />
inhibitors as new generation antidepressants.<br />
B. Gopishetty, S. Santra,<br />
S. Ali, M. Reith, a. dutta<br />
106. Probing S1� site of caspase-3: A new<br />
hope for mechanism based treatment of<br />
neurological disorders. A. K. Sharma<br />
107. SAR evaluation of fused heterocyclic<br />
quinolone carboxylic acid M1 positive allosteric<br />
modulators. C. N. Di Marco,<br />
V. Cofre, W. J. Ray, L. Ma, M. Wittmann,<br />
M. A. Seager, K. A. Koeplinger,<br />
C. D. Thompson, G. D. Hartman,<br />
M. T. Bilodeau, S. D. Kuduk<br />
108. New aryl sulfonamides compounds as<br />
potent and selective 5-ht 6 receptor ligands.<br />
A. Shinde, V. Reballi,<br />
V. Tiriveedhi, P. Gudla, L. Kota,<br />
A. Chindhe, N. Rambabu,<br />
R. Kambhampati, R. Nirogi<br />
109. Structure-activity relationships of 2,4diphenyl-1H-imidazole<br />
analogs as CB2<br />
receptor agonists for the treatment of<br />
chronic pain. S. Yang, J. Smotryski,<br />
J. Matasi, G. Ho, D. Tulshian,<br />
W. J. Greenlee, R. Brusa, M. Beltramo,<br />
K. Cox<br />
110. High affinity ligands for opioid receptors<br />
in the picomolar K i range: N-(2-[1,1�-biphenyl]-4-ylethyl)<br />
analogs of 8-CAC.<br />
J. M. Bidlack, D. J. Cohen,<br />
J. M. Gargano, X. Jia, S. Jo,<br />
M. A. VanAlstine, M. P. Wentland<br />
111. Novel series of CB2 selective antagonists<br />
for the treatment of autoimmune<br />
disorders: Synthesis, functional evaluation<br />
and ligand-steered modeling.<br />
S. S. Phatak, R. R. Petrov,<br />
F. Astruc-Diaz, C. N. Cavasotto,P.Diaz<br />
112. 7-Hydroxy-benzopyran-4-one derivatives:<br />
Discovery and structure-activity relationships<br />
of PPAR � and -� (PPAR� and<br />
�) dual agonists. N. Gavande, A. Matin,<br />
M. S. Kim, N. K. Salam, J. R. Hanrahan,<br />
R. H. Roubin, D. E. Hibbs<br />
113. Synthesis and structure-activity relationships<br />
of 3-aminopyridazine derivatives<br />
of �-aminobutyric acid acting as<br />
GABA C (�) antagonists. N. Gavande,<br />
G. A. Johnston, J. R. Hanrahan,<br />
M. Chebib<br />
114. Design, synthesis and pharmacological<br />
evaluation of fluorescent GABA C probes<br />
for receptor visualization and localization<br />
studies. N. Gavande, G. A. Johnston,<br />
J. R. Hanrahan, M. Chebib<br />
115. Design, synthesis, and pharmacological<br />
evaluation of novel, selective �-aminobutyric<br />
acid � (GABA C) receptor antagonists.<br />
N. Gavande, K. Mewett,<br />
G. A. Johnston, J. R. Hanrahan,<br />
M. Chebib<br />
116. Hepatitis C protease inhibitors based<br />
on 2(1H)-pyrazinones. J. Gising,<br />
A. Belfrage,P.Örtqvist, M. Larhed,<br />
U. Danielson, A. Sandström<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
117. Synthesis and SAR studies on novel<br />
heteroaryl fused tetracyclic indole-diamide<br />
compounds: Potent allosteric inhibitors<br />
of the hepatitis C virus NS5B polymerase<br />
enzyme. M. Ding,F.He,<br />
X. Zheng, T. W. Hudyma, M. A. Poss,<br />
J. F. Kadow, K. L. Rigat, Y. Wang,<br />
R. Fridell, D. Qiu, M. Liu, S. Boss, M. Gao,<br />
S. B. Roberts, R. G. Gentles<br />
118. Synthesis and biological evaluation of<br />
the selective inverse agonist PWZ-029 for<br />
alpha 5 Bzr/GABA aergic receptor subtypes:<br />
This ligand enhances cognition in<br />
rhesus monkeys. S. K. Rallapalli,<br />
C. Moran, J. K. Rowlett, J. M. Cook<br />
119. Highly potent inhibitors of HCV NS3<br />
protease. B. Venables, N. Sin, A. Wang,<br />
L. Sun, D. Hernandez, A. Sheaffer,<br />
M. Lee, D. Barry, J. Friborg, F. Yu,<br />
J. Knipe, J. Sandquist, A. C. Good,<br />
F. Mcphee, N. A. Meanwell, P. M. Scola<br />
120. Design and synthesis of deuterated boceprevir<br />
analogs with enhanced pharmacokinetic<br />
properties. A. J. Morgan,<br />
C. E. Masse, S. Nguyen, V. Uttamsingh,<br />
R. Tung, S. Harbeson<br />
121. Rational design, virtual screening, synthesis<br />
and biological activity of donepezil-based<br />
new acetylcholinesterase inhibitors.<br />
S. Datta, D. Borkin, A. Rudnitskaya,<br />
M. Torok, B. Torok<br />
122. Application of small heterocyclic P3<br />
caps in HCV NS3 protease inhibitors.<br />
N. Sin, B. L. Venables, L. Sun,<br />
A. X. Wang, S. Sit, Y. Chen, J. Chen,<br />
Y. Han, A. C. Good, J. Friborg, D. Barry,<br />
F. Yu, D. Hernandez, A. Sheaffer,<br />
J. Knipe, F. McPhee, N. A. Meanwell,<br />
P. M. Scola<br />
123. Cyclic phosphate prodrugs of 2�deoxy-2�-fluoro-2�-C-methyl<br />
nucleoside<br />
analogs as inhibitors of HCV NS5B polymerase.<br />
P. Reddy, D. Bao, W. Chang,<br />
B. Chun, J. Du, D. Nagarathnam,<br />
S. Rachakonda, B. S. Ross, H. Zhang,<br />
S. Bansal, C. L. Espiritu, M. Keilman,<br />
A. M. Lam, C. Niu, H. M. Steuer,<br />
P. A. Furman, M. J. Otto, M. J. Sofia<br />
124. Discovery of PSI-353661: A novel purine<br />
nucleotide prodrug with improved in<br />
vitro potency for the treatment of HCV infection.<br />
W. Chang, D. Bao, B. Chun,<br />
D. Nagarathnam, S. Rachakonda,<br />
P. Reddy, B. S. Ross, H. Zhang,<br />
S. Bansal, C. L. Espiritu, M. Keilman,<br />
A. M. Lam, C. Niu, H. M. Steuer,<br />
P. A. Furman, M. J. Otto, M. J. Sofia<br />
125. Synthesis of novel, fluorinated P1 NS3<br />
protease inhibitors of HCV. Y. Chen,<br />
S. Sit, J. Chen, L. Sun, S. V. D’Andrea,<br />
Z. Zheng, A. X. Wang, S. Hiebert,<br />
M. Bowsher, A. Cocuzza, Q. Zhao,<br />
D. Bilder, N. Sin, B. L. Venables,<br />
D. Carini, B. Johnson, E. Mull,<br />
D. Hernandez, A. K. Sheaffer,<br />
H. Mulherin, F. Yu, J. O. Knipe,<br />
K. Mosure, A. C. Good, R. Rajamani,<br />
H. Klei, J. Friborg, V. Arora, Y. Shu,<br />
X. Huang, L. Levesque, D. Li, J. Zhu,<br />
S. Adam, F. McPhee, N. Meanwell,<br />
P. M. Scola<br />
126. Synthesis and SAR studies on highly<br />
potent, novel, N,1-C2- phenyl-bridged<br />
2-phenyl-indole-6-carboxamide based<br />
hepatitis C virus NS5B inhibitors.<br />
X. Zheng, T. W. Hudyma, M. Ding, F. He,<br />
M. A. Poss, J. F. Kadow,<br />
C. Chang, c. wan, M. R. Witmer, P. Morin,<br />
D. M. Camac, S. Sheriff, B. R. Beno,<br />
K. Rigat, Y. Wang, R. Fridell, J. Lemm,<br />
D. Qiu, P. Liu, S. Voss, S. B. Roberts,<br />
M. Gao, J. Knipe, R. G. Gentles<br />
127. Isoquinoline tripeptides as HCV NS3<br />
protease inhibitors. Z. B. Zheng,<br />
A. X. Wang, D. Carini, A. Cocuzza,<br />
S. Hiebert, M. Bowsher, Y. Chen, S. Sit,<br />
L. Sun, F. Mcphee, J. Friborg, D. Barry,<br />
F. Yu, D. Hernandez, J. Knipe,<br />
R. Rajaman, H. Klei, A. Ng, B. Ma,<br />
Q. Gao, N. A. Meanwell, P. M. Scola,<br />
S. D’Andrea<br />
128. SAR and mode of binding studies on a<br />
series of N-benzyl-4-heteroaryl-1-(phenylsulfonyl)piperazine-2-carboxamides:<br />
Potent inhibitors of the polymerase enzyme<br />
(NS5B) of the hepatitis C virus.<br />
R. G. Gentles, M. Ding, X. Zheng,<br />
L. Chupak, M. A. Poss, C. Chang,<br />
C. Wan, M. R. Witmer, P. Morin,<br />
D. M. Camac, S. Sheriff, B. R. Beno,<br />
K. Rigat, S. B. Roberts, M. Gao,<br />
J. F. Kadow, J. Lemm, S. Voss, M. Liu,<br />
L. Pelosi, Y. Wang<br />
129. Development of novel carbohydrate<br />
binding agents: A new class of potent antiviral<br />
therapeutics. P. C. Trippier,<br />
J. Balzarini, C. McGuigan<br />
130. Synthesis and HIV-1 integrase inhibitory<br />
activity of C2-C-linked heterocyclic-5-hydroxy-6-oxo-dihydropyrimidine-4-carboxamides.<br />
B. Naidu, M. E. Sorenson,<br />
M. Patel, Y. Ueda, J. Banville,<br />
F. Beaulieu, S. Bollini, I. Dicker, H. Higley,<br />
Z. Lin, L. Pajor, D. D. Parker, B. Terry,<br />
M. Zheng, A. Martel, N. A. Meanwell,<br />
M. Krystal, M. A. Walker<br />
131. Design, synthesis and HIV-1 integrase<br />
inhibitory activity associated with spirocycle-fused5-hydroxy-6-oxo-dihydropyrimidine-4-carboxamides.<br />
B. Naidu,<br />
M. E. Sorenson, J. D. Matiskella, Y. Ueda,<br />
S. Bollini, I. Dicker, H. Higley, Z. Lin,<br />
D. Wu, L. Pajor, D. D. Parker, B. Terry,<br />
M. Zheng, N. A. Meanwell, M. Krystal,<br />
M. A. Walker<br />
132. Synthesis and evaluation of novel phosphoramidates<br />
of acyclic nucleosides in<br />
the bypass of the first phosphorylation<br />
step mediated by the thymidine kinase.<br />
D. Carta, C. McGuigan, C. Vanpouille,<br />
L. Margolis, J. Balzarini<br />
133. Study of C2-N-linked heterocyclic pyrimidin-6-oxa-5-hydroxy-4-carboxamide<br />
derivatives as HIV integrase inhibitors.<br />
M. Sorenson, B. Naidu, J. Matiskella,<br />
T. Connolly, Y. Ueda, N. Meanwell,<br />
S. Bollini, H. Samanta, B. Terry, Z. Lin,<br />
I. Dicker, D. Parker, L. Pajor, M. Zheng,<br />
M. Krystal, M. Walker<br />
134. Design, synthesis and SAR study of<br />
novel spiro aza-pyrimidinone HIV integrase<br />
inhibitors. c. li, M. A. Walker,<br />
Y. Ueda, J. Matiskella, Z. Lin, I. Dicker,<br />
H. Samanta, B. Terry, H. Higley, S. Bollini,<br />
M. Krystal, N. A. Meanwell<br />
135. Discovery and preclinical evaluation of<br />
the HIV integrase inhibitor BMS-727740.<br />
M. A. Walker, J. Banville, B. Naidu,<br />
M. Sorenson, R. Remillard, A. Martel,<br />
Y. Ueda, T. Connolly, J. Weiss, C. Li,<br />
A. Trehan, H. Wong, Z. Lin, I. Dicker,<br />
H. Samanta, B. Terry, H. Scarnati,<br />
C. Deminie, S. Bollini, M. Zheng,<br />
A. Chimalakonda, L. Pajor, T. Philip,<br />
D. Parker, M. Krystal, N. A. Meanwell<br />
136. Towards the synthesis of novel boronates<br />
as potential HIV-1 protease inhibitors.<br />
J. L. Nye, D. R. Clayton,<br />
M. S. McCammant, L. Fabry-Asztalos<br />
137. Novel spirocyclobutyl- and spirocyclooxetanyl-pyrimidin-6-oxa-5-hydroxy-<br />
4-carboxybenzylamides as potent HIV-1<br />
integrase inhibitors. T. P. Connolly,<br />
I. Dicker, M. Krystal, Z. Lin, J. Matiskella,<br />
N. A. Meanwell, B. Naidu, L. Pajor,<br />
M. Sorenson, B. Terry, Y. Ueda,<br />
M. A. Walker, M. Zheng<br />
138. Design, synthesis and structure-activity<br />
relationships of novel dicamphanoyl-<br />
2�,2�-dimethyldihydropyranochromone<br />
(DCP) analogs as potent anti-HIV agents.<br />
T. Zhou, C. Chen, Q. Shi, L. Huang,<br />
P. Ho, K. Lee<br />
139. HIV-1 protease inhibitors with a tertiaryalcohol-containing<br />
transition-state mimic<br />
and various P2/P1� substituents.<br />
P. Öhrngren, X. Wu, J. K. Ekegren,<br />
T. Unge, &. Rosenquist, B. Samuelsson,<br />
M. Larhed<br />
140. Design and synthesis of novel isatin derivatives<br />
as potent anti-HIV agents.<br />
R. K. Singh, G. Kumari, M. Yadav<br />
141. Small molecules to target Mycobacterium<br />
tuberculosis 1-Deoxy-D-xylulose-5phosphate<br />
reducto-isomerase (MtbDxr).<br />
E. R. Jackson, K. Kehn-Hall,<br />
F. Kashanchi, H. I. Boshoff, C. S. Dowd<br />
142. Synthesis and in silico studies of altered<br />
DNA substrates as HIV RT inhibitors.<br />
M. Yadav, G. Kumari, R. K. Singh<br />
143. Synthesis of new antimalarial bi-drug<br />
molecules. A. Jonet,<br />
A. Dassonville-Klimpt, P. Sonnet<br />
144. Motualevic acid analogs: Synthesis, antimicrobial<br />
activity, and structure�activity<br />
relationship (SAR) studies. P. Cheruku,<br />
J. L. Keffer, C. A. Bewley<br />
145. New bicyclic peptidomimetic inhibitors<br />
of secreted aspartic proteinase 2 (SAP2)<br />
for the treatment of drug-resistant Candida<br />
albicans infections. A. Trabocchi,<br />
C. Calugi, A. Cassone, R. Cauda,<br />
A. Guarna<br />
146. Quinolonimines as novel antimalarial<br />
leads. T. Rodrigues, J. Gut,<br />
P. J. Rosenthal, R. Moreira, R. Guedes,<br />
D. Santos, F. Lopes<br />
147. Discovery and development of the covalent<br />
hydrates of trifluoromethylated<br />
pyrazoles as riboflavin synthase inhibitors<br />
with antitubercular activity. A. Talukdar,<br />
A. Bacher, B. Illarionov, M. Fischer,<br />
S. G. Franzblau, B. Wan, M. Cushman<br />
148. Hybrid compounds targeting both liver<br />
and blood stages of malaria parasites.<br />
F. Lopes, R. Capela, R. Moreira,<br />
P. J. Rosenthal, J. Gut, G. Cabal,<br />
M. Prudêncio, M. Mota<br />
149. Synthesis and antiviral activity of a second<br />
generation of measles virus RNA-dependent<br />
RNA polymerase activity inhibitors.<br />
J. M. Ndungu, S. A. Krumm, A. Sun,<br />
R. K. Plemper, J. P. Snyder<br />
150. Design and synthesis of a sixteen million<br />
member DNA-encoded library (DEL)<br />
and discovery of potent Mycobacterium<br />
tuberculosis (Mtb) InhA inhibitors.<br />
C. P. Davie, P. A. Centrella,<br />
G. K. O’Donovan, G. Evindar, H. O’Keefe,<br />
A. M. Patel, M. A. Clark<br />
151. Cell-based optimization of imidazolopiperazines<br />
as new antimalarials. T. Wu,<br />
A. Nagle, K. Kuhen, K. Henson,<br />
R. Borboa, C. Francek, Z. Chen,<br />
D. Plouffe, J. Chang, C. Li, T. Tuntland,<br />
J. Isbell, M. Rottmann, E. Winzeler,<br />
R. Glynne, D. C. Tully, A. K. Chatterjee<br />
152. Modeling trypanosomal TOR kinase domains:<br />
Implications for the design of antiparasitic<br />
drugs. Z. Wang, C. E. Hubbard,<br />
M. Ondrechen, M. P. Pollastri<br />
153. High-speed synthesis of 3,6-disubstituted<br />
pyrazolo[1,5-a]pyrimidines applied<br />
to bone morphogenetic protein signaling<br />
inhibitors. J. Liu,G.D.Cuny,P.B.Yu,<br />
X. Xing, K. D. Bloch, R. T. Peterson<br />
154. Total synthesis of YM-181741 for the<br />
preparation of natural product-like<br />
STAT3:STAT3 inhibitors. A. Misale,<br />
D. Antonow, D. E. Thurston, G. Zinzalla<br />
155. Tetrapodal Stat3 inhibitors offer potent<br />
disruption of Stat3 in vitro and in whole<br />
cell assays. B. D. Page, A. Schimmer,<br />
J. Turkson, P. T. Gunning<br />
156. NO-NSAIDs: Nitric oxide-releasing prodrugs<br />
of non-steroidal anti-inflammatory<br />
drugs with gastric-sparing properties.<br />
K. V. Nemmani, N. Borhade, A. R. Pathan,<br />
S. V. Mali, M. Karwa, S. S. P.,<br />
V. Pamidiboina, M. Gund,<br />
N. J. Deshmukh, P. Gaikwad, A. K. Jain,<br />
J. J. Deshattiwar, S. Halder, D. C. Desai,<br />
J. Mudgal, M. Dhiman, A. U. Burhan,<br />
A. Sharma, N. P. Dubash, N. K. Mangu,<br />
M. Dutta, G. Thakre, S. Goud,<br />
D. Pacharne, L. Babu, S. Deshpande,<br />
V. Nadar, S. Sharma, A. Satyam<br />
157. Inhibition of CuZnSOD by low MW natural<br />
products. J. S. Summers,<br />
M. E. Arrington, M. R. Yost, J. Markley,<br />
E. Parris, B. Hickman, J. Schmitt<br />
158. Thiobenzimidazole-1-acetic acids as<br />
CRTH2 antagonists. J. Pothier,<br />
A. Fecher, M. Gude, K. Hilpert,<br />
M. A. Riederer, X. Leroy, O. Peter,<br />
H. Kletzl, C. Gnerre, R. Bravo,<br />
S. Delahaye, L. Piali, F. Sylvie, H. Fretz<br />
159. Development of SH2 domain proteomimetics<br />
as potent disruptors of oncogenic<br />
Stat3:Stat3 dimerization. J. A. Drewry,<br />
P. T. Gunning<br />
160. 1,3,6-substituted-4-aminopyrazolopyrimidines,<br />
new potent inhibitors for phopholipase<br />
D. J. Baffoe, A. M. Kulkarni,<br />
V. Curry, B. Török, K. Stieglitz<br />
161. Development of potent and selective<br />
MMP inhibitors with a triazole zinc binding<br />
group. J. Haas,A.M.Fryer,<br />
S. W. Andrews, L. Huang, J. A. Josey,<br />
S. Kragerud, Y. Marsh, J. P. Rizzi,<br />
F. Sullivan<br />
162. Reduction of hERG activity in (4,5,6,7tetrahydro-1H-indazolyl)ethanamines,<br />
a<br />
novel series of potent and selective S1P1<br />
selective agonists. N. Aguilar,<br />
M. Carrascal, M. Erra, S. Fonquerna,<br />
L. Taboada, J. Alonso, B. Vidal,<br />
N. Godessart, G. Tarrasón, T. Domenech,<br />
C. Armengol, M. Córdoba, M. Sabaté,<br />
D. Casals, M. Domínguez<br />
163. Structure-activity relationship studies of<br />
sphingosine kinase inhibitors. M. R. Raje,<br />
Y. Kharel, K. R. Lynch, W. L. Santos<br />
164. Amido-1,3,4-thiadiazole derivatives as<br />
novel S1P1 selective agonists: From an<br />
HTS hit to a sub-nanomolar, orally active<br />
advanced lead. N. Aguilar, M. Mir,<br />
P. Grima, M. López, N. Godessart,<br />
G. Tarrasón, T. Domenech, D. Vilella,<br />
C. Armengol, M. Córdoba, M. Sabaté,<br />
D. Casals, M. Domínguez<br />
165. Structure-based design of potent, conformationally<br />
constrained, cell-permeable<br />
STAT3 inhibitors. J. Chen,L.Bai,<br />
Y. Zhao, D. Bernard,<br />
Z. Nikolovska-Coleska, C. Gomez,<br />
J. Zhang, H. Yi, S. Wang<br />
166. Structure and activity relationships of<br />
tartrate-based TACE inhibitors. D. Li,<br />
J. V. Popovici-Muller, D. B. Belanger,<br />
J. Caldwell, C. Dai, M. David,<br />
V. M. Girijavallabhan, Z. Guo,<br />
J. A. Kozlowski, B. J. Lavey, D. J. Lundell,<br />
J. F. Lee, Z. Liu, R. Mazzola,<br />
B. McKittrick, X. Niu, P. Orth, V. Madison,<br />
J. Piwinski, R. Rizvi, K. E. Rosner,<br />
B. Shankar, N. Shih, G. W. Shipps,<br />
M. Siddiqui, J. Spitler, C. O. Strickland,<br />
J. Sun, P. C. Ting, S. Chen, H. Vaccaro,<br />
W. Yu, G. Zhou, Z. Zhu<br />
167. New nNOS PDZ domain ligands and<br />
their biological evaluation.<br />
A. M. Perez-Lopez,<br />
J. M. Cardenas-Maestre,<br />
R. Salto-Gonzalez, M. Giron-Gonzalez,<br />
J. Martinez-Lopez, T. de la Rubia-Nieto,<br />
J. F. Dominguez-Seglar,<br />
R. Sanchez-Martin, J. A. Gomez-Vidal<br />
168. Synthesis of a series of nonpeptidic<br />
thiochromanone-based thiosemicarbazone<br />
analogs as inhibitors of cathepsin L.<br />
J. Song, L. M. Jones,<br />
K. Gaddale Devanna, E. S. Conner,<br />
G. E. Chavarria, A. K. Charlton-Sevcik,<br />
M. L. Trawick, B. G. Siim, D. J. Chaplin,<br />
K. G. Pinney<br />
169. Thiosemicarbazone derivatives of functionalized<br />
tetralone, indanone, chromanone,<br />
and 2,3-dihydroquinolinone<br />
scaffolds as inhibitors of cathepsins L<br />
and B. L. M. Jones,J.Song,<br />
A. L. Johansen, A. K. Jantz,<br />
G. E. Chavarria, A. K. Charlton-Sevcik,<br />
M. Trawick, B. G. Siim, D. J. Chaplin,<br />
K. G. Pinney<br />
170. Rigidified 2-aminopyrimidines as histamine<br />
H 4 receptor antagonists: Effects of<br />
substitution about the rigidifying ring.<br />
J. R. Koenig, H. Liu, I. Drizin, D. G. Witte,<br />
T. L. Carr, A. M. Manelli, I. Milicic,<br />
M. I. Strakhova, T. R. Miller,<br />
T. A. Esbenshade, J. D. Brioni, M. Cowart<br />
171. Design and synthesis of 3-alkylsulfonylmethylcyclohexylaminobenzamide-derived<br />
inhibitors of CC chemokine receptor<br />
2 (CCR2). M. G. Yang,D.G.Batt,<br />
R. J. Cherney, S. Mandlekar, M. Cvijic,<br />
Q. Zhao, J. C. Barrish, P. H. Carter<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
MEDI<br />
TECH–75
MEDI <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
172. Synthesis and development of multimeric<br />
molecules to mimic the pro-apoptotic<br />
ligand TRAIL, a member of the TNF<br />
superfamily. M. Lechner, J. Beyrath,<br />
V. Pavet, C. Pardin, A. Morizot,<br />
M. Wendland, W. Maison, O. Micheau,<br />
H. Gronemeyer, S. Fournel, G. Guichard<br />
173. Utilizing a pharmacophore model for<br />
the development of potent small molecule<br />
inhibitors of STAT3 function.<br />
V. M. Shahani, S. Fletcher, P. Yue,<br />
D. P. Luu, S. Sharmeen, A. D. Schimmer,<br />
J. Turkson, P. T. Gunning*<br />
174. Design and synthesis of substituted<br />
6-arylquinazolin-4-amines as potent and<br />
selective inhibitors of members of the<br />
CLK and DYRK kinase families.<br />
A. S. Rosenthal, C. Tanega, M. Shen,<br />
B. T. Mott, D. S. Auld, J. Inglese,<br />
C. P. Austin, D. J. Maloney, C. J. Thomas<br />
175. Design, synthesis and structure-activity<br />
relationships of potent B-RAF inhibitors.<br />
N. Namdev, J. Lapierre, Y. Liu, H. Wu,<br />
C. Brassard, N. Westlund, M. Tandon,<br />
J. Link, D. Kizer, R. Nicewonger,<br />
K. Bresciano, T. Hall, J. Szwaya, C. Chen,<br />
D. France, M. A. Ashwell<br />
176. Discovery of pyrazol-3-yl and thiazol-<br />
2-yl amino pyrazines as novel JAK2 inhibitors.<br />
L. Almeida, S. Ioannidis,<br />
M. L. Lamb, A. M. Davies, M. Su,<br />
B. Peng, H. Guan, G. Bebernitz, M. Ye,<br />
K. Bell, M. Alimzhanov, M. Zinda<br />
177. Utilization of 1,3,5-triazine as a pyrimidine<br />
surrogate for the evaluation of PDK1<br />
inhibitors. M. Bobko, K. Evans, J. Axten,<br />
J. Medina, L. Shuster, C. Blackledge,<br />
S. Grant, A. Shu, C. Becker,<br />
S. Rabindran, C. Gardiner, H. Xiang<br />
178. Design, synthesis and biological evaluation<br />
of novel quinoxaline derivatives as<br />
PI3K inhibitors. P. Wu, Y. Su, L. Zhang,<br />
S. Y. Wen, J. C. Xu, B. Yang, Q. J. He,<br />
Y. Z. Hu<br />
179. Structure-based discovery and optimization<br />
of a novel protein kinase B (AKT)<br />
inhibitor. F. Lopez-Vallejo,<br />
A. Hernandez-Campos,<br />
I. Velazquez-Martinez, R. Castillo, Y. Yu,<br />
N. Singh, M. Giulianotti,<br />
J. Medina-Franco<br />
180. Design and synthesis of a novel, potent,<br />
and selective class of type II p38 inhibitors.<br />
D. V. Nguyen, R. Shetty,<br />
N. Jayasuriya, E. L. Michelotti,<br />
F. Machrouhi, J. Gaboury, W. Evans,<br />
H. V. Namboodiri, M. Bukhtiyarova,<br />
S. Mardirosian, M. Guo, T. Fujimoto<br />
181. Development of a gene family targeted<br />
workflow for the identification of inhibitors<br />
of kinase targets. P. D. Kane,<br />
J. A. Foster, R. J. Foster, J. Swanson,<br />
M. S. Lawless<br />
182. Novel approaches to CDK2 modulation:<br />
Hit identification, characterization, and<br />
optimization. Y. Deng, G. W. Shipps,<br />
P. J. Curran, L. Zhao, M. A. Siddiqui,<br />
J. Popovici-Muller, J. S. Duca,<br />
A. W. Hruza, T. O. Fischmann,<br />
V. S. Madison, R. Zhang,<br />
C. W. McNemar, T. W. Mayhood,<br />
E. M. Lees, D. A. Parry, W. T. Windsor<br />
183. Design, synthesis and in vitro characterization<br />
of phosphate pro-drugs of mutant-B-RAF<br />
inhibitors. Y. Liu, J. Lapierre,<br />
M. Tandon, N. Namdev, H. Wu,<br />
C. Brassard, E. Volckova, J. Szwaya,<br />
C. Chen, D. France, M. A. Ashwell<br />
184. Design and synthesis of 4-subtituted<br />
thiazoles as AKT inhibitors. X. Wang,<br />
Q. Zeng, M. Bourbeau, M. Lee, G. Yao,<br />
S. Tadesse, F. Hong, C. Yuan, X. Huang,<br />
B. Han, E. Wohlhieter, J. Allen, S. Zhang,<br />
J. Lofgren, X. Zhang, D. Freeman,<br />
J. Bready, C. Davis, C. Fotsch,<br />
R. Hungate, R. Kendall<br />
185. Design and synthesis of novel heterocyclic<br />
scaffolds as protein kinase inhibitor.<br />
L. Wei, S. V. Malhotra<br />
76–TECH<br />
‡ Cooperative Cosponsorship<br />
186. Discovery of orally bioavailable Aurora<br />
kinase inhibitors. D. B. Belanger,<br />
M. J. Williams, Z. Meng, T. Yu,<br />
A. K. Mandal, P. J. Curran, M. P. Rainka,<br />
N. Shih, M. A. Siddiqui, A. D. Basso,<br />
D. Prelusky, M. Liu, S. Lee, B. Yaremko,<br />
K. Gray, S. Tevar, J. Jones, E. B. Smith<br />
187. Discovery of pyrrolo[2,1-f][1,2,4]triazine<br />
C6-ketones as potent, orally active p38�<br />
MAP kinase inhibitors. A. J. Dyckman,<br />
T. Li, G. Schieven, S. Pitt, R. Zhang,<br />
D. Shen, M. McKinnon, K. McIntyre,<br />
K. Gillooly, D. Shuster, A. Doweyko,<br />
J. Sack, H. Zhang, P. Marathe, J. Barrish,<br />
J. Dodd, K. Leftheris<br />
188. Discovery of 2-aminophenyl quinazolines<br />
as potent and selective PDK1 inhibitors.<br />
X. Lin, M. Aikawa, P. Amiri,<br />
S. Basham, J. Chan, R. Jain, S. Lin,<br />
T. Machajewsky, W. McCrea,<br />
D. Menezes, J. Murray, S. Ng, K. Pfister,<br />
A. C. Rico, S. Ramurthy, W. Shu,<br />
S. Subramanian, J. Sutton,<br />
E. Venetsanakos, M. X. Wang, B. Warne,<br />
Y. Xu, R. Zang, Y. Zhou<br />
189. SAR of a new series of Stearoyl-CoA<br />
desaturase inhibitors. J. Leclerc,<br />
C. Chan, J. Falgueyret, J. Guay, S. Guiral,<br />
Z. Huang, N. Lachance, C. Li, R. Oballa,<br />
Y. K. Ramtohul, L. Zhang<br />
190. Synthesis of pyrazolospiroketone ACC<br />
inhibitors. C. Limberakis, S. Bader,<br />
L. M. Buzon, S. B. Coffey, B. G. Conway,<br />
J. W. Corbett, K. D. Freeman-Cook,<br />
K. E. Henegar, C. S. Jones, K. L. Nelson,<br />
W. Song, J. D. Weaver, Z. Zhao,<br />
D. P. Phillion<br />
191. Discovery of a potent small molecule inhibitor<br />
of IGF-1R. D. Frennesson,<br />
M. Wittman, M. Saulnier, J. Carboni,<br />
R. Attar, P. Balimane, C. Chang, C. Chen,<br />
L. Discenza, M. Gottardis, A. Greer,<br />
W. Hurlburt, W. Johnson, D. Langley,<br />
F. Lee, A. Li, P. Liu, H. Mastalerz,<br />
A. Mathur, K. Menard, K. Patel, J. Sack,<br />
X. Sang, S. Traeger, G. Trainor,<br />
U. Velaparthi, Z. Yang, G. Zhang,<br />
K. Zimmermann, D. Vyas<br />
192. Novel dual agonists of the GPR40 and<br />
PPAR� receptors. E. Marsault,<br />
H. Tremblay, F. Chagnon, A. Beauregard,<br />
A. Émond, P. Boulais, M. Langlois,<br />
R. Leduc<br />
193. Novel cambinol analogs as sirtuin inhibitors:<br />
Synthesis, biological evaluation and<br />
rationalisation of activity. F. Medda,<br />
L. Pirrie, S. Poupart, R. J. Russell,<br />
M. Higgins, A. R. McCarthy, J. Campbell,<br />
A. M. Slawin, D. P. Lane, S. Lain,<br />
N. J. Westwood<br />
194. Metabolism-guided design of amino alcohol<br />
acids as orally active, short-acting<br />
calcium-sensing receptor antagonists.<br />
G. Balan, Y. Zhang,J.N.Bauman,<br />
T. A. Brown, G. Fate, D. R. Healy,<br />
M. Herr, P. Humphries, A. S. Kalgutkar,<br />
B. Kapinos, M. Li, T. S. Maurer, C. Neagu,<br />
R. Oliver, V. M. Paralkar, D. A. Price,<br />
K. A. Riccardi, J. Sagal, J. A. Southers,<br />
S. Spath, I. A. Stock<br />
195. Synthesis of possible calcimimetic derivatives<br />
from enantiopure primary<br />
amines. S. Espinosa-Diaz, J. L. Alvarez,<br />
K. M. Santiago<br />
196. Discovery of TAK-875: A potent, selective,<br />
and orally bioavailable GPR40 agonist.<br />
N. Negoro, S. Sasaki, S. Mikami,<br />
M. Ito, M. Suzuki, Y. Tsujihata, R. Ito,<br />
A. Harada, K. Takeuchi, N. Suzuki,<br />
J. Miyazaki, T. Santou, N. Kanzaki,<br />
S. Satou, T. Odani, J. Sakamoto,<br />
M. Funami, T. Tanaka, A. Kogame,<br />
S. Matsunaga, T. Yasuma, Y. Momose<br />
197. Investigation of functionally liver selective<br />
glucokinase activators.<br />
H. F. Schuster,L.C.Kirman,<br />
G. R. Bebernitz, M. S. Grondine,<br />
A. Duttaroy, S. L. Caplan, P. M. Taslimi,<br />
B. A. Dale, J. Gao, R. Deacon,<br />
V. Beaulieu, W. M. Maniara, T. Stams,<br />
B. Vash, R. C. Gupta, S. Munshi,<br />
S. S. Nadkarni<br />
198. Glucokinase activators with improved<br />
physicochemical properties and off target<br />
effects. L. C. Kirman, H. F. Schuster,<br />
M. S. Grondine, G. R. Bebernitz,<br />
S. L. Caplan, A. Duttaroy, P. M. Taslimi,<br />
B. A. Dale, J. Gao, J. Liang, V. Beaulieu,<br />
R. Deacon<br />
199. Investigation of chiral sulfoxide GPR119<br />
agonists for type 2 diabetes.<br />
G. E. Peckham<br />
200. Rearrangement of the SSTR5 agonist<br />
L-817,818 under physiological conditions<br />
affords an alternate SSTR5 agonist that<br />
elevates plasma glucose excursion during<br />
OGTT. M. Reiter, J. Terebetski,<br />
D. Shen, B. Murphy, J. L. Duffy<br />
201. Design, synthesis and evaluation of<br />
novel (4-piperidinyl)-piperazine class as<br />
acetyl-CoA carboxylase 1/2 non-selective<br />
inhibitors. T. Chonan, D. Wakasugi,<br />
D. Yamamoto, M. Yashiro, T. Oi,<br />
H. Tanaka, A. Ohoka-Sugita, F. Io,<br />
H. Koretsune, A. Hiratate<br />
202. Discovery of O-spiroketal C-arylglucosides<br />
as novel and selective sodiumdependent<br />
glucose cotransporter 2<br />
(SGLT2) inhibitor for the treatment of type<br />
2 diabetes. T. Sato, T. Kobayashi,<br />
M. Nishimoto, N. Taka, Y. Ohtake,<br />
K. Takano, K. Yamamoto, M. Ohmori,<br />
M. Yamaguchi, K. Takami, S. Yeu,<br />
K. Ahn, H. Matsuoka, M. Suzuki,<br />
H. Hagita, K. Ozawa, K. Yamaguchi,<br />
M. Kato, S. Ikeda<br />
203. Synthesis and evaluation of a series of<br />
piperazinylpyridines as GPR119 agonists.<br />
Y. Wu, J. D. Kuntz, A. Carpenter<br />
204. Structure-based Virtual Screening for<br />
the discovery of potential P2Y14 receptor<br />
ligands. F. Deflorian, A. Szabo,<br />
K. A. Jacobson<br />
205. Exploring structural scaffolds as a strategy<br />
to design selective ligands.<br />
A. B. Yongye, Y. Li, M. A. Giulianotti,<br />
Y. Yu, R. A. Houghten, A. Nefzi,<br />
L. Chaker, K. Martinez-Mayorga<br />
206. Optimization of phenylmethylene hydantoins<br />
as prostate cancer migration inhibitors:<br />
SAR-directed design, synthesis,<br />
and pharmacophore modeling. M. Mudit,<br />
K. A. El Sayed<br />
207. Art of crystallization and application of<br />
single crystal X-ray diffraction to support<br />
solid-state characterization of pharmaceuticals.<br />
N. Tsou, A. Mckeown, R. Ball,<br />
M. McNevin, C. Maguire, A. Chen, A. Bak<br />
208. Estrogen receptor antagonist-functionalized<br />
gold nanoparticles for breast cancer<br />
drug delivery and imaging systems.<br />
K. D. Dao, R. N. Hanson, R. Sawant,<br />
V. Torchilin<br />
209. Bipolar biphenyl proteomimetics as estrogen<br />
receptor � and androgen receptor<br />
coactivator binding inhibitors.<br />
P. T. Weiser, A. B. Williams,<br />
R. N. Hanson<br />
210. Identification of a novel series of [2.2.1]oxabicyclo<br />
lactam-based androgen receptor<br />
antagonists. J. F. Austin,<br />
L. S. Sharma, A. J. Balog, W. Shan,<br />
A. J. Nation, D. S. Nirschl, A. V. Miller III,<br />
G. D. Vite, C. A. Rizzo, M. Gottardis,<br />
J. Dell-John, L. Zhang, R. Attar,<br />
L. Schweizer, M. T. Obermeier,<br />
M. N. Jure-Kunkel, T. E. Spires,<br />
A. V. Gavai<br />
211. Development and application of the<br />
pharmacophore model of pregnane X receptor.<br />
J. Ramanjulu, A. S. Lakdawala,<br />
S. Williams, R. Marquis<br />
212. Synthesis and evaluation of fluorinated<br />
�1-adrenoreceptor selective ligands.<br />
H. S. Radeke, A. Purohit, T. D. Harris,<br />
K. Hanson, M. Broekema, C. Hu,<br />
R. Jones, M. Azure, M. Cdebaca,<br />
P. Yalamanchili, M. Kavosi, M. Yu,<br />
M. Guaraldi, J. McDonald, M. Kagan,<br />
S. Robinson, D. Casebier<br />
213. Tetra-aryl cyclobutanes as direct inhibitors<br />
of the nuclear receptor/coactivator<br />
interaction. A. A. Parent, J. R. Gunther,<br />
J. A. Katzenellenbogen<br />
214. Identification of allosteric potentiators<br />
of the prostaglandin receptor EP2.<br />
T. Ganesh,J.Jiang,Y.Du,R.Shaw,<br />
P. Thepchatri, R. Dingledine<br />
215. Design, synthesis, and evaluation of<br />
isoquinoline urea derivatives of A-425619<br />
as TRPV1 antagonists. N. A. Gujarati,<br />
B. J. Undem, V. L. Korlipara<br />
216. Conformationally constrained analogs<br />
of BAY 59-3074, a CB1 cannabinoid receptor<br />
partial agonist. H. Teng,<br />
G. Thakur, A. Makriyannis<br />
217. Arylguanidines as analgesic adjuvants:<br />
Graphics modeling studies. G. S. Alley,<br />
P. D. Mosier, M. Dukat<br />
218. Novel peptidyl boronic acid based inhibitors<br />
of PSA. M. B. Kostova,<br />
D. M. Rosen, S. R. Denmead<br />
219. Amino aryl sulfonamides as novel and<br />
potent 5-ht 6 receptor ligands. R. Nirogi,<br />
R. Kambhampati, T. Bandyala, J. Konda,<br />
S. Arepalli, V. Reballi, P. Kothmirkar,<br />
N. Pamuleti, A. Shinde<br />
220. Strategy for conjugation of “clickable”<br />
agonists of the A 3 adenosine receptor to<br />
polyamidoamine (PAMAM) dendrimers.<br />
D. K. Tosh,L.S.Yoo,M.Chinn,Z.Gao,<br />
K. A. Jacobson<br />
221. Structure-activity relationship of (N)methanocarba<br />
phosphonate analogs of<br />
5�-AMP as cardioprotective agents acting<br />
through a cardiac P2X receptor.<br />
S. Thatikonda, S. Zhou, B. V. Joshi,<br />
R. Balasubramanian, T. Yang, B. T. Liang,<br />
K. A. Jacobson<br />
222. <strong>Chemical</strong> enhancement for skin drug<br />
delivery using gemini surfactants.<br />
S. Silva, J. Sousa, A. Pais,<br />
B. Michniak-Kohn<br />
223. Development of small molecular weight<br />
non-aminoglucosides for compound-induced<br />
readthrough of premature termination<br />
codons caused by nonsense mutations.<br />
J. Ku, L. Du, R. Damoiseaux,<br />
H. Hu, C. Bertoni, R. A. Gatti, M. E. Jung<br />
224. Characterizations of diastereoisomers<br />
of polyamine analogs with oxime functionalites.<br />
H. Shin, E. Rawls,<br />
H. Whitehead, J. Lee, S. Kim<br />
225. Development and evaluation of a novel<br />
radiogallium labeled peptide as a bone<br />
imaging agent for PET. K. Ogawa,<br />
K. Takai, T. Kiwada, Y. Kitamura,<br />
K. Shiba, A. Odani<br />
226. Fluorescence-labeled celecoxib derivatives<br />
as novel pharmacological tools.<br />
A. P. Lill, S. Schiffmann, S. Groesch,<br />
E. Proschak, H. Stark<br />
227. Design and optimization of a potent series<br />
of eIF4E inhibitors. D. Kopecky,<br />
X. Chen, J. Mihalic, J. Heath, J. Deignan,<br />
F. Kayser, S. Jeffries, Z. Wang,<br />
S. Johnstone, X. Min, M. Cardozo,<br />
S. Shen, M. Lo<br />
228. Discovery of a pyrimidinone-based antagonist<br />
of calcium sensing receptor.<br />
J. Ramanjulu, L. Casillas, A. Charnley,<br />
M. DeMartino, X. Dong, P. Harris,<br />
J. Jeong, Y. Lan, A. Rahman, L. Dare,<br />
M. Schaeffer, S. Hoffman, S. Kumar,<br />
R. Marquis<br />
229. Dimeric modulators of ENaC for the<br />
treatment of cystic fibrosis. U. Baettig,<br />
R. Butler, N. Smith, E. Stanley, P. Oakley,<br />
S. Collingwood, H. Danahay, K. Coote,<br />
H. Atherton, D. Paisley, R. Lock<br />
230. Conformationally constrained peptides<br />
as the Src SH3 domain binding ligands.<br />
R. Tiwari, A. Brown, S. Narramaneni,<br />
G. Sun, K. Parang<br />
231. Discovery of novel 4-oxo-2-thioxo-7quinazoline<br />
carboxamides and derivatives<br />
as prolyl hydroxylase inhibitors.<br />
M. J. Schulz,G.L.Adams,<br />
J. A. Brackley, H. Yu, J. M. Ghergurovich,<br />
R. M. Sanchez, J. Qu, G. Burton, Y. Wang<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
232. Bisphosphonate analogs of geranyl and<br />
farnesyl pyrophosphate as potential inhibitors<br />
of prenyl synthases.<br />
M. A. Maalouf, B. M. Wasko, R. J. Hohl,<br />
D. F. Wiemer<br />
233. Design and synthesis of folate conjugates<br />
of Rapamycin and Everolimus.<br />
I. R. Vlahov, P. J. Kleindl,<br />
H. R. Santhapuram, J. F. Vaughn,<br />
S. J. Han, F. You, Y. Wang, C. P. Leamon<br />
234. Discovery of TAK-438: Synthesis and<br />
biological evaluation of novel pyrrole derivatives<br />
as potassium-competitive acid<br />
blockers (P-CABs). Y. Arikawa,<br />
H. Nishida, A. Hasuoka, O. Kurasawa,<br />
K. Hirase, N. Inatomi, Y. Hori,<br />
J. Matsukawa, N. Tarui, A. Imanishi,<br />
M. Kondo, Y. N. Imai, M. Kajino<br />
235. Series of non-covalent inhibitors of the<br />
human 20S Proteasome derived from<br />
N-�-neopentyl asparagine with unprecedented<br />
potency and selectivity.<br />
C. Blackburn, C. Barrett, N. Bump,<br />
F. Bruzzese, L. Dick, P. Fleming,<br />
K. Garcia, K. Gigstad, P. Hales,<br />
L. Herman, M. Jones, J. Liu, D. Sappal,<br />
M. Sintchak, C. Tsu, J. Blank<br />
236. Total synthesis of racemic and natural<br />
glyceollin II. A. Luniwal, P. W. Erhardt<br />
237. Genomics guided medicinal chemistry.<br />
E. Beausoleil, T. Taverne,<br />
C. Chauvignac, B. Leblond, D. Pallares,<br />
M. Brenner, M. Pando<br />
238. De-convolution of medicinal citrus<br />
products. S. Li,N.E.Rawson,C.Ho<br />
239. Utilization of DNA-encoded libraries for<br />
the identification of novel inhibitors of<br />
prolyl hydroxylases. D. T. Fosbenner,<br />
B. W. King, K. K. Brown, P. Keller,<br />
K. McKenzie, B. Siegfried, L. Mitchell,<br />
A. Smallwood, N. Concha, L. Miller,<br />
Y. Xue, G. J. Franklin, P. A. Centrella,<br />
J. Svendsen, S. Mataruse, M. A. Clark<br />
240. Oxyphors R3 and G3 — new phosphorescent<br />
probes for tissue oxygen measurements:<br />
Synthesis and characterization.<br />
T. V. Esipova, S. A. Vinogradov<br />
241. Synthesis of rosmarinic acid analogs.<br />
G. A. Kraus, G. R. Pollock III<br />
242. Overexpression, isolation, and oral delivery<br />
of the appetite suppressant peptide<br />
PYY. C. H. Fazen,R.P.Doyle<br />
243. Using haptocorrin and intrinsic factor as<br />
oral delivery agents. D. Valentin,<br />
R. P. Doyle<br />
244. Benzo[d]imidazole/indole inhibitors of<br />
coactivator associated arginine methyltransferase<br />
1 (CARM1). H. Wan,<br />
T. Huynh, S. Pang, J. Geng, T. Bandiera,<br />
S. Bindi, P. Vianello, F. Roletto,<br />
S. Thieffine, A. Galvani, W. Vaccaro,<br />
M. A. Poss, G. L. Trainor, M. V. Lorenzi,<br />
M. Gottardis, L. Jayaraman,<br />
A. V. Purandare<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom West<br />
G-Quadruplexes as Targets for Drug<br />
Discovery and Development<br />
L. Hurley, D. Yang, Organizers, Presiding<br />
8:30 245. Quadruplex nucleic acids as functional<br />
elements and therapeutic targets.<br />
S. Balasubramanian<br />
9:10 246. Overview of G-quadruplexes, their<br />
biological role, and G-quadruplex structures.<br />
D. Yang<br />
9:50 247. Structure-based design and evaluation<br />
of small molecules with selectivity<br />
for telomeric quadruplex nucleic acids.<br />
M. Gunaratnam, S. Hempel, G. Collie,<br />
S. Sparapani, N. Campbell, G. Parkinson,<br />
M. de la Fuente, A. Schatzlein, S. Neidle<br />
10:30 248. Drug targeting of the c-Myc<br />
G-quadruplex and associated proteins to<br />
inhibit gene transcription. L. H. Hurley<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
Effects of Free Drug on In Vivo Efficacy<br />
J. Butera, Organizer<br />
L. Di, E. Kerns, Organizers, Presiding<br />
8:30 249. Free fraction, free drug concentration<br />
and in vitro to in vivo extrapolation-no<br />
common consensus on a common<br />
problem. D. A. Smith<br />
9:05 250. Considerations of protein binding<br />
in CNS drug design. X. Liu,C.E.Hop<br />
9:40 251. Determinants of drug disposition<br />
in tumors. J. M. Gallo<br />
10:15 252. Managing plasma protein binding.<br />
G. L. Trainor<br />
10:50 253. Changes in protein binding:<br />
When can they be clinically relevant?<br />
L. Z. Benet<br />
11:25 Panel Discussion<br />
Open-source Drug Discovery Sponsored by<br />
BMGT, Cosponsored by CPCD, MEDI, and<br />
NESACS<br />
Tautomers and Biology<br />
Predictions of Tautomer Ratios Sponsored<br />
by COMP, Cosponsored by CINF, MEDI, and<br />
PHYS<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom West<br />
Recent Developments in Investigational<br />
Therapies for HCV<br />
A. Palani, A. Arasappan, A. Stamford,<br />
W. Kazmierski, Organizers, Presiding<br />
2:00 254. Discovery of telaprevir. A. Grillot<br />
2:30 255. Novel noncovalent inhibitors of<br />
the HCV serine protease. P. J. Edwards,<br />
M. D. Bailey, P. K. Bhardwaj, M. Bös,<br />
M. G. Cordingley, P. Forgione,<br />
N. Goudreau, C. Lemke, P. W. White,<br />
M. Llinàs-Brunet<br />
3:00 256. Discovery of potent HCV inhibitors<br />
targeting the NS5A protein. M. Belema,<br />
V. N. Nguyen, J. L. Romine,<br />
D. R. St. Laurent, M. H. Serrano-Wu,<br />
L. B. Snyder, M. S. Deshpande,<br />
R. A. Fridell, D. R. O’Boyle II, J. A. Lemm,<br />
J. E. Leet, J. O. Knipe, D. R. Langley,<br />
R. E. Nettles, C. Chien, R. J. Colonno,<br />
D. M. Grasela, N. A. Meanwell,<br />
L. G. Hamann, M. Gao<br />
3:30 257. HCV NS4A antagonists.<br />
A. Phadke, X. Wang, D. Chen,<br />
V. Gadhachanda, A. Hashimoto,<br />
M. Deshpande, M. Huang<br />
4:00 258. Benzofuran inhibitors of HCV<br />
NS5b polymerase: An in-depth look at<br />
SAR and pre-clinical characteristics that<br />
let to the advancement of HCV-796 into<br />
human clinical studies. A. K. Saha<br />
4:30 259. Discovery and development of 2�-<br />
F-2�-C-methyl nucleosides and nucleotides<br />
for the treatment of HCV.<br />
M. J. Sofia<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
Drugging the Undruggable: Small Molecule<br />
Modulators of Protein-Protein Interactions<br />
D. Hertzog, E. Velthuisen, Organizers,<br />
Presiding<br />
2:00 260. Principles of protein-protein interactions:<br />
What is the preferred way for<br />
proteins to interact? R. Nussinov<br />
2:30 261. Synthesis and evaluation of libraries<br />
designed to modulate protein-protein<br />
and protein-DNA interactions.<br />
D. L. Boger<br />
3:00 262. Protein-protein interaction inhibitors<br />
of transcription factors and kinases.<br />
T. Berg<br />
3:30 263. Drugging the undruggable using<br />
stapled peptides. G. L. Verdine<br />
4:00 264. Small molecule inhibitors of protein-protein<br />
interactions: Targeting Bcl-2<br />
family proteins to treat cancer.<br />
S. W. Elmore<br />
Open-source Drug Discovery Sponsored by<br />
BMGT, Cosponsored by CPCD, MEDI, and<br />
NESACS<br />
The Chemistry of Epigenetic Regulation<br />
Sponsored by BIOL, Cosponsored by MEDI<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
Undergraduate Research Posters<br />
Medicinal Chemistry Sponsored by CHED,<br />
Cosponsored by MEDI and SOCED<br />
Using Waters Explicitly in Drug Discovery<br />
Characterization and Applications<br />
Sponsored by COMP, Cosponsored by CINF<br />
and MEDI<br />
Women at the Forefront of Preventing and<br />
Combating Disease Sponsored by WCC,<br />
Cosponsored by BIOL,MEDI, and PROF<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
J. Zablocki, Organizer<br />
8:00–10:00<br />
37, 39, 41, 42, 48, 60, 64, 65, 67, 68, 72, 75,<br />
76, 77, 78, 91, 93, 96, 98, 116, 117, 118,<br />
119, 120, 121, 122, 123, 124, 129, 130,<br />
131, 135, 153, 195, 208, 209, 220, 221,<br />
226. See previous listings.<br />
484. See subsequent listings.<br />
TUESDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
MEDI Awards Symposium<br />
L. Hurley, J. Mc Carthy, Organizers<br />
P. Woster, Presiding<br />
8:00 265. JANUVIA® and beyond: Selective<br />
dipeptidyl peptidase IV inhibitors for the<br />
treatment of type 2 diabetes. A. E. Weber<br />
8:40 266. Bioorganic studies on recognition<br />
of soluble amyloid oligomers using small<br />
molecules. N. W. Smith, S. V. Dzyuba<br />
8:55 267. Application of aminoglycoside-Nacetyltransferases<br />
in the development of<br />
novel N-acylated aminoglycoside antibiotics.<br />
J. L. Houghton,<br />
S. Garneau-Tsodikova, M. Fridman,<br />
K. Green, W. Chen<br />
9:10 268. Designing attenuated Michael acceptors<br />
as experimental redox chemotherapeutics<br />
targeting skin cancer.<br />
C. M. Cabello, G. T. Wondrak<br />
9:25 269. Small molecule glycosaminoglycan<br />
mimics. A. M. Fenner,R.J.Kerns<br />
9:40 270. Discovery of a pharmacophore for<br />
inhibition of poly(ADP-ribose) glycohydrolase.<br />
J. D. Steffen, L. Steffen,<br />
D. Coyle, M. K. Jacobson<br />
9:55 271. Exploring Alphanapthoflavone<br />
heterotropic allosteric regulation of Cytochrome<br />
P450 3A4. C. M. Woods,<br />
W. M. Atkins, C. Fernandez<br />
10:10 272. Rational design of Tubastatin A:<br />
An immunosuppressant HDAC6 inhibitor<br />
with unprecedented selectivity. K. Butler,<br />
J. Kalin, C. Brochier, B. Langley,<br />
W. Hancock, G. Vistoli, A. Kozikowski<br />
10:25 273. Evaluation of a direct procaspase<br />
activating compound in pet<br />
dogs with lymphoma. Q. P. Peterson,<br />
D. C. West, D. C. Hsu, T. M. Fan,<br />
P. J. Hergenrother<br />
10:40 274. Heterocyclization in cyanobactin<br />
biosynthesis. J. A. McIntosh<br />
10:55 275. Discovery of novel BACE1 inhibitors<br />
for the treatment of Alzheimer’s disease.<br />
A. W. Stamford<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom West<br />
Process Chemistry: The Role of Organic<br />
Synthesis in Early Clinical Drug<br />
Development Cosponsored by ORGN ‡<br />
A. Abdel-Magid, Organizer<br />
R. A. Singer, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 276. Development of a scalable process<br />
for p38 inhibitor VX-702. S. Roeper<br />
9:15 277. Continuing process development<br />
for existing HIV/AIDS drugs: Improving<br />
access to medicines in the developing<br />
world. D. S. Teager, D. H. Ripin,<br />
R. Stringham, J. Fortunak<br />
9:55 278. Discovery and development of<br />
scalable routes to prepare AMG-221.<br />
K. B. Hansen<br />
10:35 279. Development of a scaleable process<br />
for the production of a small molecule<br />
clinical candidate. S. H. Wagaw<br />
11:15 280. Catalytic asymmetric reactions in<br />
the synthesis of complex drug targets.<br />
A. Klapars,K.R.Campos,<br />
J. H. Waldman, C. Chen<br />
Oligonucleotide Therapeutics Sponsored by<br />
CARB, Cosponsored by ANYL, BIOL, MEDI,<br />
and ORGN<br />
Tautomers and Biology<br />
Tautomers and Macromolecule-ligand<br />
Complexes Sponsored by COMP,<br />
Cosponsored by CINF, MEDI, and PHYS<br />
The Community Structure-Activity<br />
Resource (CSAR) Scoring Challenge<br />
Sponsored by COMP, Cosponsored by BIOL,<br />
CINF, and MEDI<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 153A/B/C<br />
Lunch and Learn Case Study: Chemistry<br />
and Pharmaceutical Blogging<br />
An Important Means of Non-Traditional<br />
Scientific Communication<br />
T. Bannister, C. Drahl, Organizers,<br />
Presiding<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
An Update on the War on Obesity<br />
J. Macor, W. Ewing, Organizers, Presiding<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
MEDI<br />
TECH–77
MEDI <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
2:00 281. Combination strategies to treat<br />
obesity: Overview of peripheral and central<br />
pathways modulating energy homeostasis.<br />
M. A. Pelleymounter<br />
2:30 282. Discovery of Lorcaserin: A selective<br />
5-HT 2C receptor agonist for the treatment<br />
of obesity. B. M. Smith<br />
3:00 283. MCH R1 antagonists: Problems<br />
and solutions. D. L. Hertzog,<br />
K. A. Al-Barazanji, K. K. Barvian,<br />
E. Bigham, M. J. Bishop, C. S. Britt,<br />
D. L. Carlton, A. J. Carpenter,<br />
J. P. Cooper, D. M. Garrido, A. S. Goetz,<br />
G. M. Green, M. K. Grizzle, Y. C. Guo,<br />
A. L. Handlon, C. E. Hyman, D. M. Ignar,<br />
D. G. Lang, R. O. Morgan, A. J. Peat,<br />
G. E. Peckham, A. J. Reisinger,<br />
J. D. Speake, W. R. Swain, F. X. Tavares,<br />
H. Zhou<br />
3:30 284. Discovery of S-2367 (velneperit): A<br />
potent and selective NPY Y5 antagonist<br />
for the treatment of obesity. T. Okuno,<br />
H. Takenaka, Y. Aoyama, Y. Kanda,<br />
Y. Yoshida, T. Okada, H. Hashizume,<br />
M. Sakagami, T. Nakatani, K. Hattori,<br />
T. Ichihashi, T. Yoshikawa, H. Yukioka,<br />
K. Hanasaki, Y. Kawanishi<br />
4:00 285. Anti-obesity potential of SGLT2<br />
inhibitors in development for treatment of<br />
diabetes. W. N. Washburn<br />
4:30 286. Discovery of pramilitide and peptide<br />
approaches to treating obesity.<br />
S. S. Ghosh<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom West<br />
General Oral Session Financially supported<br />
by Gilead Sciences, Inc.<br />
J. Zablocki, Organizer, Presiding<br />
2:05 287. Isoquinucline-based GlyT1 inhibitors<br />
for schizophrenia: Discovery, optimization,<br />
synthesis, and in vivo pharmacology.<br />
J. S. Albert, C. Alhambra, D. Brott,<br />
T. Brugel, M. Chopra, G. E. Ernst,<br />
J. Forst, F. Gharahdaghi, D. Gryte,<br />
A. Gupta, C. Holmquist, J. Jonak,<br />
G. Koether, J. Liu, J. Milano, T. E. Norris,<br />
W. M. Potts, G. Smaggin, D. Song,<br />
S. Sydserff, M. Sylvester, G. Tian,<br />
J. G. Varnes, C. A. Veale, X. Wang,<br />
D. Widzowski, D. Wilkins, M. Wood,<br />
H. Xiong, S. Zukin<br />
2:35 288. From fragment-based lead generation<br />
to 2-aminoquinolines as potent beta-secretase<br />
inhibitors that are efficacious<br />
in vivo. Y. Cheng, K. Ashton,<br />
M. Bartberger, J. Brown, C. Bryan,<br />
K. Chen, J. Esmay, R. T. Fremeau Jr.,<br />
J. Golden, S. Harried, D. Hickman,<br />
S. A. Hitchcock, M. Huang, B. Jordan,<br />
T. Judd, P. Lopez, S. W. Louie, Y. Luo,<br />
S. Mercede, K. Michelsen, T. Nixey,<br />
N. A. Paras, S. Poon, T. S. Powers,<br />
A. Sickmier, D. St. Jean, C. Tegley,<br />
W. Zhong, P. Wen, R. C. Wahl, S. Wood,<br />
M. Xue, B. Yang<br />
3:05 289. From discovery to clinic:<br />
GSK962040, the first oral, small molecule<br />
motilin receptor agonist for treatment of<br />
conditions associated with impaired gastric<br />
motility. S. M. Westaway,<br />
G. J. Sanger, G. Dukes<br />
3:35 290. Discovery of BMS-582949, a clinical<br />
p38a MAP kinase inhibitor for the<br />
treatment of inflammatory diseases.<br />
C. Liu, J. Lin, S. T. Wrobleski, S. Lin,<br />
J. Hynes, Jr., H. Wu, A. J. Dyckman, T. Li,<br />
J. Wityak, K. M. Gillooly, S. Pitt, D. Shen,<br />
R. F. Zhang, K. W. McIntyre,<br />
L. Salter-Cid, D. J. Shuster, H. Zhang,<br />
P. H. Marathe, A. M. Doweyko,<br />
J. S. Sack, L. Gao, J. Wang, R. R. Latek,<br />
U. Thienel, S. Kaul, M. McKinnon,<br />
J. H. Dodd, J. C. Barrish, G. L. Schieven,<br />
K. Leftheris<br />
78–TECH<br />
‡ Cooperative Cosponsorship<br />
4:05 291. Development of an oxazolobenzimidazole<br />
class of positive allosteric<br />
modulators of mGluR2 for the treatment<br />
of schizophrenia. R. M. Garbaccio,<br />
E. J. Brnardic, M. E. Fraley, M. E. Layton,<br />
G. D. Hartman, M. A. Jacobson,<br />
B. C. Magliaro, P. H. Hutson,<br />
J. A. O’Brien, S. L. Huszar, J. M. Uslaner,<br />
K. L. Fillgrove, C. Tang, Y. Kuo, S. M. Sur<br />
4:35 292. Substituted biaryl pyrazoles as sodium<br />
channel blockers for the treatment<br />
of neuropathic pain. S. Tyagarajan,<br />
P. K. Chakravarty, B. Zhou, B. Taylor,<br />
W. H. Parsons, M. H. Fisher,<br />
M. J. Wyvratt, K. Lyons, T. Klatt, X. Li,<br />
S. Kumar, B. Williams, J. Felix,<br />
B. T. Priest, R. M. Brochu, V. Warren,<br />
M. Smith, M. Garcia, G. J. Kaczorowski,<br />
W. J. Martin, C. Abbadie, E. McGowan,<br />
N. Jochnowitz, A. Weber, J. L. Duffy<br />
Improving Drug Candidates by Design: A<br />
Focus on Physical Properties to Improve<br />
Disposition and Safety Sponsored by TOXI,<br />
Cosponsored by MEDI<br />
Natural Products Biosynthesis Sponsored<br />
by BIOL, Cosponsored by MEDI and ORGN<br />
Oligonucleotide Therapeutics Sponsored by<br />
CARB, Cosponsored by ANYL, BIOL, MEDI,<br />
and ORGN<br />
Using Waters Explicitly in Drug Discovery<br />
Hybrid Explicit/Implicit Methods Sponsored<br />
by COMP, Cosponsored by CINF and MEDI<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom West<br />
JAK Kinase Inhibitors for Cancer and<br />
Myeloproliferative Disease<br />
S. Ioannidis, Organizer<br />
M. Lamb, Organizer, Presiding<br />
8:30 293. Molecular pathogenesis and therapy<br />
of myeloproliferative neoplasms.<br />
P. Koppikar, O. Abdel-Wahab,<br />
S. Marubayashi, O. Kilpivaara, N. Kucine,<br />
R. L. Levine<br />
9:10 294. Identification of AZD1480 as a<br />
novel JAK2 inhibitor. S. Ioannidis<br />
9:50 295. Discovery of CYT387: A potent<br />
and selective dual inhibitor of JAK1 and<br />
JAK2. C. J. Burns<br />
10:30 296. Discovery of polycyclic azaindoles<br />
and deazapurines as potent JAK2<br />
inhibitors. M. W. Ledeboer<br />
11:10 297. Discovery of INCB018424: A potent<br />
and selective JAK1/JAK2 inhibitor for<br />
the treatment of myeloproliferative neoplasms.<br />
J. D. Rodgers, J. S. Fridman,<br />
S. Shepard, T. P. Maduskuie,<br />
A. G. Arvanitis, H. Wang, L. Shao,<br />
B. Folmer, N. Falahatpisheh, M. Rafalski,<br />
L. Storace, R. K. Jalluri, K. Vaddi,<br />
P. J. Haley, T. C. Burn, M. Rupar,<br />
P. C. Liu, M. B. Covington, E. Caulder,<br />
J. Li, P. Waeltz, A. Margulis, R. Wynn,<br />
M. Becker-Pasha, Y. Li, Y. Lo,<br />
B. Thomas, G. Hollis, M. F. Favata,<br />
X. Wen, J. Kelly, K. Solomon,<br />
P. A. Scherle, J. Shi, S. Yeleswaram,<br />
R. C. Newton, S. M. Friedman, B. Metcalf<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
Opioid Receptors as Targets for Drug<br />
Discovery<br />
M. Lamb, T. Prisinzano, Organizers<br />
T. Brugel, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 298. Opioid receptors: Past, present,<br />
and future. T. E. Prisinzano<br />
9:20 299. Strategies employed and outcomes<br />
of the multiparameter optimization<br />
of 4-piperidin-4-ylidenemethyl-benzamides<br />
as potent and selective �-opioid<br />
receptor agonists. C. L. Dantzman,<br />
M. M. King, S. Wesolowski, G. E. Ernst,<br />
X. Wang, J. McCauley, K. Brush,<br />
W. E. Palmer, W. Frietze, V. Hoesch,<br />
D. W. Andisik, T. J. Hudzik, K. H. Bui,<br />
J. Liu, N. Spear<br />
10:05 300. Discovery of carboxamide bioisosteres<br />
of the phenolic-OH of opioids.<br />
M. P. Wentland, J. M. Bidlack, Y. Bu,<br />
C. L. Cioffi, D. J. Cohen,<br />
C. M. Dehnhardt, W. Duan, R. Ganorkar,<br />
J. Gargano, C. Guo, J. Jaber, J. Jin,<br />
X. Jia, S. Jo, B. I. Knapp, R. Kucejko,<br />
R. Lou, Q. Lu, A. L. Parkhill,<br />
G. P. Richardson, X. Sun,<br />
M. A. VanAlstine, G. Xu, Y. Ye, H. Zhang,<br />
S. Zhang, Q. Zhou<br />
10:50 301. Discovery and characterization<br />
of a new kappa selective opioid receptor<br />
antagonist. C. H. Mitch, S. Quimby,<br />
J. Matt, N. Diaz, C. Pedregal,<br />
M. De La Torre, Q. Shi, E. Canada,<br />
D. McKinzie, M. Statnick<br />
11:35 302. Potential of opioid receptor antagonists<br />
to manage L-DOPA-induced<br />
dyskinesia in Parkinson’s disease.<br />
R. E. Dolle, A. Goodman,<br />
B. Le Bourdonnec, P. J. Little,<br />
J. M. Brotchie, T. H. Johnston,<br />
J. B. Koprich, S. H. Fox<br />
Process Chemistry: Role of Organic<br />
Chemistry in Early Clinical Drug<br />
Development V Sponsored by ORGN,<br />
Cosponsored by MEDI<br />
Recognition of DNA: Recent Advances<br />
Sponsored by CARB, Cosponsored by MEDI<br />
The Emerging Concepts of Activity<br />
Landscapes and Activity Cliffs and their<br />
Role in Drug Research Sponsored by CINF,<br />
Cosponsored by COMP and MEDI<br />
WEDNESDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
New Therapeutic Approaches for Major<br />
Ocular Diseases<br />
T. Bannister, R. Fecik, Organizers,<br />
Presiding<br />
1:30 303. Multifunctional antioxidants for<br />
the treatment of age-related eye diseases.<br />
P. F. Kador, J. Randazzo,<br />
H. Kawada, H. Jin<br />
1:55 304. Aldose reductase inhibitors for the<br />
treatment of diabetic cataracts and retinopathy.<br />
P. F. Kador, M. Wyman,<br />
K. Blessing<br />
2:15 305. KDR kinase inhibitors for retinal<br />
disease: The design and investigation of<br />
small molecules for topical and intravitreal<br />
dosing. M. T. Bilodeau,<br />
A. L. Webber, L. A. Hettrick,<br />
A. C. Hughes, J. W. Maxwell, Y. Kim,<br />
R. L. Peiffer, W. O. Cook, S. Mittal, B. Ma,<br />
X. Mao, K. A. Thomas, C. J. Thut<br />
2:45 306. Recent investigations of prostaglandin<br />
receptor agonist analogs as novel<br />
ocular hypotensive agents in glaucoma<br />
management. R. M. Burk<br />
3:15 307. Discovery and in vitro SAR of AR-<br />
12286, a potent kinase inhibitor for the<br />
treatment of glaucoma. M. A. deLong,<br />
J. M. Sturdivant, S. M. Royalty,<br />
G. R. Heintzelman, J. D. Yingling,<br />
C. L. Laethem, B. W. Sherman,<br />
C. C. Kopczynski<br />
3:45 308. Development of Rho kinase inhibitors<br />
for the treatment of glaucoma.<br />
Y. Feng, P. LoGrasso, Y. Yin, Y. Chen,<br />
X. Fang, S. Chowdhury, T. D. Bannister,<br />
A. Weiser, J. Pocas, W. Grant,<br />
T. Schroeter, M. D. Cameron, L. Lin,<br />
C. Ruiz, S. Khan, A. Pachori, T. Inoue,<br />
V. Rao<br />
4:15 309. Palomid 529, a dual TORC1/<br />
TORC2 inhibitor of the PI3K/Akt/mTOR<br />
pathway as a therapeutic approach to ocular<br />
diseases of retinal neovascularization.<br />
D. Sherris<br />
4:45 310. Activation of the serotonin 5-HT1A<br />
receptor protects the retina from severe<br />
photo-oxidative stress. R. J. Collier<br />
5:15 311. Rho kinase inhibitors: A potential<br />
new treatment for glaucoma. D. J. Slade,<br />
N. Pelz, J. Lampe, P. Watson,<br />
W. Peterson, A. Brown, E. Glaub,<br />
C. Crean, R. Verhoeven, J. Vittitow<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom West<br />
Drug Discovery for Epigenetic Targets<br />
D. Hertzog, Organizer<br />
R. Trump, Organizer, Presiding<br />
2:00 312. Epigenetic reprogramming of cancer<br />
cells by targeting DNA methylation<br />
dynamics. D. J. Bearss,D.A.Jones,<br />
B. R. Cairns, S. Sharma<br />
2:30 313. Modulating the epigenetic code<br />
readout in transcription. M. Zhou<br />
3:00 314. Discovery of epigenetic chemical<br />
probes. H. Ouyang, C. Arrowsmith,<br />
P. J. Brown<br />
3:30 315. Structure and mechanism guided<br />
identification of histone demethylase inhibitors.<br />
C. J. Schofield<br />
4:00 316. Discovery of chemical probes for<br />
protein lysine methyltransferase G9a.<br />
F. Liu, X. Chen, A. Allali-Hassani,<br />
A. M. Quinn, T. J. Wigle, D. Barsyte,<br />
J. M. Yost, G. A. Wasney, A. Dong,<br />
I. Kozieradzki, G. Senisterra, I. Chau,<br />
A. Siarheyeva, A. Van Deusen,<br />
D. B. Kireev, A. Jadhav, M. Herold,<br />
S. V. Frye, C. H. Arrowsmith,<br />
W. P. Janzen, P. J. Brown, A. Simeonov,<br />
M. Vedadi, J. Jin<br />
4:30 317. Identification of potent and selective<br />
small molecule inhibitors of the BET<br />
family bromodomains demonstrate the<br />
tractability of a new class of epigenetic<br />
targets for drug discovery. C. Chung<br />
The Emerging Concepts of Activity<br />
Landscapes and Activity Cliffs and their<br />
Role in Drug Research Sponsored by CINF,<br />
Cosponsored by COMP and MEDI<br />
WEDNESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 153ABC<br />
General Poster Session<br />
J. Zablocki, Organizer<br />
7:00–9:00<br />
318. Asymmetric synthesis of the estrogen<br />
receptor � ligand, S-2,3-bis(p-hydroxyphenyl)propionitrile<br />
(S-DPN).<br />
V. M. Carroll, J. A. Katzenellenbogen<br />
319. Synthesis and structural optimization of<br />
multiple H-bonding region of diarylalkyl<br />
(thio)amides as novel TRPV1 antagonists.<br />
F. Li, J. Jang, N. Kim, Y. Jeong, S. Kim,<br />
Y. Park, Y. Suh<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
320. Active-site probes of serine beta-lactamases:<br />
Hydrogen-bond analogs of C-6<br />
substituted hydroxymethyl, synthesis,<br />
and structure-activity relationships.<br />
M. Nottingham, S. R. Pagadala,<br />
C. R. Bethel, E. Harry, R. A. Bonomo,<br />
J. D. Buynak<br />
321. In vitro effects of C-7 aryl fluoroquinolones<br />
on DNA gyrase and DNA.<br />
H. A. Schwanz, J. D. Rosen, R. J. Kerns<br />
322. “Trojan horse” strategy: An efficient<br />
therapy against multidrug resistance bacteria.<br />
S. Fardeau, A. Jonet,<br />
A. Dassonville-Klimpt, N. Audic,<br />
P. Sonnet<br />
323. Polyacetylene natural products as potential<br />
antibiotic agents: Total synthesis,<br />
biological evaluation, and analog studies.<br />
J. H. Hoody, T. Lanoue, E. S. Bolstad,<br />
N. D. Priestley, D. B. Bolstad<br />
324. Benzothiophenesulfonylamidophosphonates:<br />
Novel inhibitors of<br />
Class A and C Beta-lactamases.<br />
K. D. Dykstra,S.Kim,Q.Tan,<br />
F. DiNinno, M. L. Hammond, Y. Park,,<br />
A. Ogawa, S. Raghoobar, R. E. Painter,<br />
D. Wisniewski,, T. Guine, C. Yang,<br />
A. Bansal, M. Proctor, Z. Zhang, W. Tang,<br />
N. Hairston, S. Lee, A. Misura,<br />
T. Felcetto, P. Fitzgerald, N. Sharma,<br />
J. Lu, S. Ha, E. Hickey, K. Young,<br />
J. Hermes, S. Raeppel, M. Stephane,<br />
N. Z. Zhou, F. Gaudette, A. Vaisburg,<br />
J. M. Besterman, J. Rahil,<br />
N. Georgopapadakou, R. Gabi<br />
325. Influence of a C-2 thioether moiety on<br />
the activity of fluoroquinolone antibiotics.<br />
K. R. Marks, R. J. Kerns<br />
326. Membrane and self-association studies<br />
of benzophenone based antibiotic.<br />
M. B. Dewal, S. K. Vooturi,<br />
S. M. Firestine<br />
327. Concise synthesis and antibacterial<br />
evaluation of 2-hydroxy-1-(indol-3-yl)-4methylpentan-3-one,<br />
a natural product<br />
from Xenorhabdus nematophilus, and its<br />
analogs. S. T. Nguyen, N. P. Peet,<br />
M. M. Butler<br />
328. Discovery of 5-(arenethynyl) monocyclic<br />
derivatives as potent inhibitors of native<br />
BCR-ABL including the T315I gatekeeper<br />
mutant. M. Thomas,W.Huang,D.Wen,<br />
X. Zhu, Y. Wang, C. A. Metcalf, S. Liu,<br />
I. Chen, J. Romero, Z. Dong, F. Li, J. Qi,<br />
Q. Xu, J. Keats, F. Wang, S. Wardwell,<br />
Y. Ning, J. T. Snodgrass, M. I. Broudy,<br />
K. Russian, J. Iuliucci, V. M. Rivera,<br />
T. K. Sawyer, D. Dalgarno, T. Clackson,<br />
W. C. Shakespeare<br />
329. Discovery and optimization of potent<br />
and selective B-RAF kinase inhibitors.<br />
H. Wu, J. Lapierre, N. Namdev,<br />
P. Hutchins, M. Moussa, M. Tandon,<br />
J. Hill, Y. Liu, J. Link, D. Kizer, C. Bruseo,<br />
J. Szwaya, C. Chen, D. France,<br />
M. A. Ashwell<br />
330. Novel semisynthetic pentacyclic triterpenoids<br />
with cytotoxic activity.<br />
A. S. Leal, R. C. Santos, M. Cascante,<br />
J. A. Salvador<br />
331. Aminothiazole analogs as CDK5 inhibitors.<br />
P. Jain, D. Shah, P. Flaherty,<br />
J. Madura, L. Meijer<br />
332. Lead optimization of furanopyrimidine<br />
Aurora kinase inhibitors: Development of<br />
in vivo active agents in tumor xenograft<br />
models. H. Hsieh, C. Chu, M. S. Coumar,<br />
W.Lin,C.Chen,T.Hsu,S.Wu,Y.Chao<br />
333. Synthesis and biological evaluation of<br />
novel and highly potent taxoids for tumor-targeted<br />
drug delivery. J. D. Seitz,<br />
E. S. Zuniga, I. Ojima<br />
334. Anthraquinone-type anticancer compounds:<br />
Derivatives of hydramycin (NSC-<br />
698410). C. Njiojob, M. Bahta,<br />
S. S. Headrick, A. Dervishi, D. C. Baker<br />
335. Development and optimization of fluorescence<br />
polarization and mitochondrial<br />
function assays for potent B-Cell Lymphocyte/Leukemia-2<br />
family proteins inhibitors.<br />
L. Liu, H. Zhou, J. Chen,<br />
A. Aguilar, J. Long,<br />
Z. Nikolovska-Coleska, J. Meagher,<br />
J. Stuckey, H. Yi, S. Wang<br />
336. Antileishmanial activities of new histone<br />
deacetylase inhibitors.<br />
M. Tabraue-Chavez, V. Corpas-Lopez,<br />
S. Panadero-Fajardo, F. Franco A. L.,<br />
F. Morillas-Marquez,<br />
J. F. Dominguez-Seglar,<br />
J. Martin-Sanchez, J. A. Gomez-Vidal<br />
337. Design, synthesis and screening of<br />
novel bis-benzimidazole derivatives as<br />
cytotoxic agents. R. J. Shah,N.R.Modi,<br />
L. J. Patel<br />
338. 5a-Carba-b-D-glucopyranose derivatives<br />
as novel sodium-dependent glucose<br />
cotransporter 2 (SGLT2) inhibitors for the<br />
treatment of type 2 diabetes. Y. Ohtake,<br />
T. Sato, M. Nishimoto, N. Taka,<br />
K. Takano, K. Yamamoto, M. Ohmori,<br />
T. Higuchi, M. Murakata, T. Kobayashi,<br />
H. Matsuoka, N. Shinma, M. Suzuki,<br />
H. Hagita, K. Ozawa, K. Yamaguchi,<br />
M. Kato, S. Ikeda<br />
339. Efficient synthesis of pyrazolopyrimidine<br />
libraries which exhibit anaplastic<br />
lymphoma kinase (ALK) inhibition.<br />
P. J. Slavish, J. E. Price,<br />
P. B. Hanumesh, Q. Jiang, X. Cui,<br />
V. A. Boyd, S. W. Morris, T. R. Webb<br />
340. Synthesis, biological evaluation and<br />
structure-activity relationships of 4-substituted<br />
methoxybenzoyl aryl thiazole<br />
(SMART) as anticancer agents. Y. Lu,<br />
C. Li, Z. Wang, J. Chen, J. T. Dalton,<br />
W. Li, D. D. Miller<br />
341. Chemoenzymatic approach to the synthesis<br />
of bioactive tripeptide mimetics for<br />
treatment of cancer. R. Ostaszewski,<br />
M. Mroczkiewicz, S. Kłossowski<br />
342. 5,5�-Substituted indirubin-3�-oxime derivatives<br />
as potent cyclin-dependent kinase<br />
inhibitors with anticancer activity.<br />
S. Choi, J. Lee, S. Jeong, I. Im, S. Lee,<br />
E. Lee, S. Lee, S. Kwon, S. Ahn, J. Yoon,<br />
S. Han, J. Kim, Y. Kim<br />
343. Indirubin derivatives as potent FLT3 inhibitors<br />
with anti-proliferative activity of<br />
acute myleoid leukemic cells. S. Choi,<br />
J. Lee, S. Lee, S. Choi, S. Han, Y. Kim<br />
344. Synthesis and selective tumor targeting<br />
properties of some asymmetric porphyrins.<br />
R. Socoteanu, R. Boscencu,<br />
A. Hirtopeanu, C. Deleanu, C. Constantin,<br />
A. Oliveira, L. Vieira Ferreira<br />
345. Design of potent ATP-competitive<br />
MEK1 inhibitors. C. C. Cheng,<br />
M. P. Richards, X. Huang, G. W. Shipps,<br />
P. Spacciapoli, C. E. Whitehurst,<br />
R. Zhang, T. Fischmann, L. Xiao, D. Carr,<br />
D. Rindgen, C. K. Smith<br />
346. Exploration of novel benzimidazole core<br />
as selective CDK5/p25 inhibitors. P. Jain,<br />
S. Yi, P. T. Flaherty, J. D. Madura,<br />
L. Meijer<br />
347. Total synthesis and anticancer activity<br />
of novel glycolipid derivatives. M. Kim,<br />
Y. Lee, H. Moon, M. Jung, H. Kim, T. Yun,<br />
J. Ricci<br />
348. Synthesis and biological activity of a series<br />
of ring-expanded heterocyclic bases<br />
containing the 5:7-fused imidazo[4,5e][1,3]diazepine<br />
ring system as potent anti-cancer<br />
agents. M. Xie,<br />
H. S. Ramanchandra<br />
349. Discovery and SAR study of antagonists<br />
towards both 5-HT2C and 5-HT6 receptors.<br />
C. Park,S.Kim,W.Park<br />
350. Facile synthesis of octahydrobenzo-<br />
[h]isoquinolines, a new class of potent<br />
and selective D 1 dopamine agonists.<br />
L. A. Bonner, B. R. Chemel, V. J. Watts,<br />
D. E. Nichols<br />
351. HPLC study of distribution of two acetylcholinesterase<br />
inhibitors: Tacrine and<br />
7-MEOTA after oral administration in rats.<br />
J. Zdarova Karasova, M. Hroch,<br />
M. Pohanka, L. Novotny, K. Kuca<br />
352. Monoamine releasers as potential treatments<br />
for stimulant addictions.<br />
A. M. Decker, B. E. Blough, J. S. Partilla,<br />
A. Landavazo, R. B. Rothman<br />
353. Structure activity relationship study of<br />
BAY 59-3074, a partial agonist of the CB1<br />
cannabinoid receptor. H. Teng,<br />
G. Thakur, A. Makriyannis<br />
354. Novel CB2 selective bicyclic cannabinoids.<br />
G. A. Thakur, V. Shukla, S. Bajaj,<br />
A. Makriyannis<br />
355. Synthesis and biological studies of androgen<br />
receptor ligands: Towards mutation-resistant<br />
nonsteroidal antagonism.<br />
C. B. Duke, A. Jones, C. Bohl,<br />
J. T. Dalton, D. D. Miller<br />
356. Discovery of 2,2-difluoro-2-phenylethylpiperidines<br />
as NR2B-subtype selective<br />
NMDA receptor antagonists.<br />
M. J. Kelly III, M. Layton, D. Armstrong,<br />
J. Butcher, C. Claiborne, D. Claremon,<br />
G. Hartman, B. Libby, N. Liverton,<br />
J. McCauley, C. McIntyre, P. Munson,<br />
K. Nguyen, B. Phillips, K. Rodzinak,<br />
J. Romano, P. Sanderson, J. Schreier,<br />
W. Thompson, M. Yaroschak, S. Young,<br />
B. Bednar, R. Bednar, K. Chapman,<br />
M. Cunningham, A. DiLella, S. Gaul,<br />
S. Kane, K. Koblan, Y. Leonard, A. Liang,<br />
E. Lyle, J. Lynch, S. Mosser, D. Reiss,<br />
G. Stump, H. Sun, H. Wang, M. Xia,<br />
C. Addy, C. Shadle, J. Stone, M. Stroh,<br />
C. Fandozzi, J. Ellis, R. Gundersdorf,<br />
N. Trainor, J. Yergey<br />
357. Bifunctional dopamine D3 selective agonist<br />
as novel antiparkinsonian agents:<br />
Evaluation of selected compounds in Parkinson’s<br />
disease animal model.<br />
B. Ghosh, T. Antonio, M. Reith, a. dutta<br />
358. Non-covalent interactions of quaternary<br />
heteroaromatic compounds with cholinesterases:<br />
Analogs of SAD-128.<br />
K. Musilek, J. Roder, O. Holas,<br />
A. Horova, M. Pohanka, V. Opletalova,<br />
K. Kuca<br />
359. Design, synthesis and biological activity<br />
of novel �,�-unsaturated carbonyl compounds<br />
as acetylcholinesterase inhibitors.<br />
S. Bag, S. Datta, T. Achildiev,<br />
A. Rudnitskaya, M. Török,B.Török<br />
360. Withdrawn<br />
361. Synthesis and evaluation of a homologous<br />
series of 3,5-trisubstituted gammabutyrolactones<br />
as potential muscarinic ligands.<br />
R. Gao,D.J.Canney<br />
362. Synthesis, nicotinic acetylcholine receptors<br />
binding and antinociceptive<br />
properties of 3�-(substituted pyridine)epibatidine<br />
analogs. P. W. Ondachi,<br />
F. Carroll<br />
363. Synthesis, nicotinic acetylcholine receptors<br />
binding and antinociceptive<br />
properties of 2�-fluoro-3�-(substituted<br />
pyridine)deschloroepibatidine analogs.<br />
P. W. Ondachi, F. Carroll<br />
364. Adventures in pyridyl azabicycloalkenes:<br />
In search of dual affinity nicotinic ligands.<br />
S. R. Breining, B. S. Bhatti,<br />
M. S. Melvin<br />
365. 1-Acyl-4-sulfonylpiperazines as a new<br />
class of selective cannabinoid 1 receptor<br />
(CB1R) inverse agonists for the treatment<br />
of obesity: Correlation between peripherally<br />
vs. CNS-expressed CB1R and efficacy.<br />
P. Vachal, J. M. Fletcher,<br />
T. M. Fong, C. C. Huang, J. Lao,<br />
J. C. Xiao, C. Shen, S. Ha, A. Strack,<br />
L. Shearman, S. Stribling, R. Z. Chen,<br />
A. Frasseto, X. Tong, J. Wang,<br />
J. Achanfuo-Yeboah, R. G. Ball,<br />
N. N. Tsou, G. J. Hickey, D. F. Thompson,<br />
T. D. Faidley, S. Nicolich, D. F. Hora,<br />
J. J. Hale, W. K. Hagmann<br />
366. Development of N-aryl piperazines as<br />
selective mGluR 5 potentiators. Y. Zhou,<br />
J. T. Manka, A. L. Rodriguez, D. Weaver,<br />
E. J. Hermann, C. J. Jones, J. P. Conn,<br />
C. W. Lindsley, S. R. Stauffer<br />
367. Design and synthesis of tryptaminebased<br />
5HT2C agonists for the treatment<br />
of certain CNS disorders. S. Leit,<br />
A. Elder, D. Wilson, R. Hunt, B. Li,<br />
K. Wiig, J. Song, H. P. Sard, B. Roth,<br />
C. Morency, G. Kumaran, L. Xu, J. Li,<br />
Y. Zhang, R. Reddy, D. Gerber,<br />
G. Harriman<br />
368. Synthesis and SAR of piperazinyl and<br />
homopiperazinyl analogs as positive allosteric<br />
modulators of mGluR4. Y. Cheung,<br />
C. R. Hopkins, C. Niswender,<br />
C. W. Lindsley, P. Conn<br />
369. Corticotropin releasing factor receptor-1<br />
(CRF1) antagonists: Synthesis and<br />
structure-activity relationship studies of<br />
pyrazinones with carbamate and etherbased<br />
substituents. V. T. Ahuja,<br />
R. A. Hartz, G. K. Mattson, T. F. Molski,<br />
S. Lelas, Y. Li, J. E. Grace, K. A. Lentz,<br />
R. J. Mattson, J. J. Bronson, J. E. Macor<br />
370. Hybrid adamantyl cannabinoids.<br />
S. Bajaj, G. A. Thakur, R. Tichkule,<br />
A. Makriyannis<br />
371. Fused oxacyclic-thiazolylidines as a<br />
novel series of potent CB 2 agonists.<br />
S. Peddi, A. Perez-Medrano, J. M. Frost,<br />
M. J. Dart, A. V. Daza, L. Li,<br />
G. K. Grayson, Y. Fan, B. A. Hooker,<br />
L. N. Miller, T. R. Garrison,<br />
O. F. El-Kouhen, B. Yao, G. C. Hseih,<br />
W. A. Carroll, M. D. Meyer<br />
372. Parachute strategy for drug discovery:<br />
Design and synthesis of trypanosomal<br />
phosphodiesterase inhibitors towards African<br />
sleeping sickness therapeutics.<br />
C. Wang, R. K. Campbell, A. Gustafson,<br />
N. D. Bland, C. Tallman, M. Russo,<br />
M. P. Pollastri<br />
373. Selective and potent benzoxazole inhibitors<br />
of Cryptosporidium parvum inosine<br />
5�-monophosphate dehydrogenase.<br />
M. Kavitha, S. K. Gorla, M. Zhang, X. Liu,<br />
L. Sharling, D. R. Gollapall, B. Striepen,<br />
G. Cuny, L. Hedstrom<br />
374. Synthesis of small molecule inhibitors of<br />
Mtb Dxr from Mycobacterium tuberculosis.<br />
G. San Jose, K. Kehn-Hall,<br />
F. Kashanchi, H. I. Boshoff, C. S. Dowd<br />
375. Parachute strategy for drug discovery:<br />
Design and synthesis of trypanosomal<br />
histone deacetylase inhibitors towards<br />
trypanosomal disease therapeutics.<br />
C. M. Snedeker, J. E. Bradner, G. Estiu,<br />
D. Horn, J. Qi, O. Wiest, Q. Wang,<br />
M. P. Pollastri<br />
376. Isolation of leishmania amastigote protein<br />
fractions which induced lymphocyte<br />
stimulation and remission of psoriasis.<br />
J. A. O’Daly<br />
377. Biological evaluation of novel antitubercular<br />
trisubstituted benzimidazoles on<br />
Mtb-FtsZ: Discovery of novel mechanism<br />
of action. D. Awasthi, K. Kumar,<br />
B. Ruzsicska, P. J. Tonge, R. A. Slayden,<br />
I. Ojima<br />
378. Design, synthesis and in-vitro antibacterial<br />
and antifungal activities of some<br />
novel spiro[azetidine-2, 3�-indole]-2,<br />
4(1�H)-dione. R. J. Shah, N. R. Modi,<br />
M. J. Patel, L. J. Patel<br />
379. Discovery of novel hit compounds for<br />
Trypanosoma cruzi sterol 14�-demethylase<br />
through structure-based virtual<br />
screening. R. C. Braga, J. R. Sabino,<br />
V. de Oliveira, C. H. Andrade<br />
380. Inhibitors of trypanosomal Aurora kinases<br />
as an approach for treatments of<br />
African sleeping sickness. S. O. Ochiana,<br />
L. Ruben, J. G. Hubbard,<br />
M. J. Ondrechen, M. P. Pollastri<br />
381. Synthesis, characterization, and antimicrobial<br />
properties of silver carbene complexes<br />
encapsulated in polyethylene glycol-polylactic<br />
acid micelles. A. R. Knapp,<br />
M. J. Panzner, W. J. Youngs,<br />
C. L. Cannon, J. G. Leid<br />
382. Synthesis and structural studies of the<br />
antimicrobial action of some amphipathic<br />
cyclopeptides. M. Ngu-Schwemlein,<br />
T. Stevens, J. Brooks<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
MEDI<br />
TECH–79
MEDI <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
383. Identification and structure-activity relationships<br />
of 2,6-disubstituted pyrazines<br />
as antituberculosis agents. Y. Sun,<br />
V. Petukhova, R. S. Giri, L. L. Klein,<br />
Y. Song, N. Zhang, K. Peng, B. Wan,<br />
Y. Wang, S. G. Franzblau<br />
384. Highly potent and selective inhibitors<br />
for Cryptosporidium parvum inosine 5�monophosphate<br />
dehydrogenase: SAR<br />
and anticryptosporidial activity.<br />
S. K. Gorla, M. Kavitha, M. Zhang, X. Liu,<br />
L. Sharling, I. S. MacPherson,<br />
D. R. Gollapalli, B. Striepen, G. Cuny,<br />
L. Hedstrom<br />
385. Antifungal agents from multivalent antimicrobial<br />
peptides design. A. Young,<br />
S. Safir, C. Zhou, N. Kallenbach<br />
386. Synthesis of pyridone-based glucokinase<br />
activators. K. J. Filipski,<br />
C. S. Jones, M. L. Minich, S. W. Wright,<br />
J. Li, A. Guzman-Perez, J. A. Pfefferkorn<br />
387. Development of diaryl ether-based ligands<br />
for estrogen-related receptor � as<br />
potential anti-diabetic agents.<br />
R. J. Patch, L. L. Searle, A. J. Kim, D. De,<br />
X. Zhu, H. B. Askari, J. C. O’Neill,<br />
M. C. Abad, D. Rentzeperis, J. G. Geisler,<br />
J. M. Lenhard, M. R. Player, M. D. Gaul<br />
388. Pyrimidine carboxamides as potent and<br />
selective CCK1R agonists. L. Wang,<br />
Z. Chen, T. G. Holt, J. A. Hubert,<br />
B. V. Karanam, S. J. Lee, J. Pan, S. Qian,<br />
V. B. Reddy, M. L. Reitman, A. M. Strack,<br />
V. Tong, D. T. Weingarth, M. S. Wolff,<br />
D. J. MacNeil, A. E. Weber,<br />
S. D. Edmondson<br />
389. Discovery of new phenylthiazolyl<br />
PPARa/d selective agonists.<br />
M. Dubernet, J. Delhomel,<br />
A. Rubenstrunk, R. Walczak,<br />
K. Bertrand-Caumont, D. W. Hum<br />
390. Discovery of a potent, proteolytically<br />
stable, and cell permeable human SIRT1<br />
and SIRT2 peptidomimetic inhibitor containing<br />
N e -thioacetyl-lysine.<br />
B. M. Hirsch, C. A. Gallo, Z. Du, Z. Wang,<br />
W. Zheng<br />
391. Antileishmanial activities of new histone<br />
deacetylase inhibitors.<br />
C. Erlanson-Albertsson<br />
392. Discovery of aminopyrimidine derivatives<br />
as novel GPR119 receptor agonists.<br />
Y. Yonetoku, K. Negoro, K. Onda,<br />
M. Hayakawa, D. Sasuga, T. Nigawara,<br />
K. Iikubo, K. Yonezawa, H. Moritomo,<br />
T. Matsui, S. Yoshida, H. Tanaka,<br />
T. Ohishi, H. Kayakiri, M. Ohta,<br />
M. Takeuchi<br />
393. 6-Amino-4-(pyrimidin-4-yl)pyridones:<br />
Novel glycogen synthase kinase-3b inhibitors.<br />
K. Coffman, M. Brodney,<br />
J. Cook, L. Lanyon, J. Pandit, S. Sakya,<br />
J. Schachter, E. Tseng-Lovering,<br />
M. Wessel<br />
394. Strategy to control hERG activity of<br />
brain penetrant Melanin-concentrating<br />
hormone 1 receptor (MCH1r) antagonists.<br />
Y. Jiang, B. Chen, S. Hong,<br />
E. M. Eldemenky, K. Lu, M. R. Marzabadi,<br />
B. Li, H. Zhang, K. A. Jones, A. D. White,<br />
M. Labelle<br />
395. Diamine template as novel Melaninconcentrating<br />
hormone 1 receptor<br />
(MCH1r) antagonists with improved cardiovascular<br />
safety. Y. Jiang, C. Chen,<br />
B. Chen, E. M. Eldemenky, C. G. Mazza,<br />
N. Ray, M. R. Marzabadi, C. Forray, B. Li,<br />
H. Zhang, K. A. Jones, D. Dong,<br />
G. Chandrasena, D. A. Craig, X. Ping,<br />
K. Andersen<br />
396. Design and synthesis of fluorescent<br />
compounds as a new class of antagonists<br />
targeting PPAR�. Y. Liu,A.Wang,<br />
Y. A. Tomita, S. Dakshanamurth,<br />
R. I. Glazer, M. L. Brown, Y. Kong<br />
397. Design, synthesis and QSAR study of<br />
novel 2-(2, 3-dioxo-2, 3-dihydro-1H-indol-1-yl)-N-phenylacetamide<br />
derivatives<br />
as cytotoxic agents. R. J. Shah,<br />
N. R. Modi, L. J. Patel<br />
398. Extraction of chemical information from<br />
documents. H. O. Villar, J. Betancort,<br />
M. R. Hansen<br />
80–TECH<br />
‡ Cooperative Cosponsorship<br />
399. Application of the interligand Overhauser<br />
effect to fragment linking and<br />
screening. P. Sledz,A.W.Hung,<br />
H. L. Silvestre, S. Wen, A. Ciulli,<br />
T. L. Blundell, C. Abell<br />
400. Covalent inhibitor design: Quantum mechanical<br />
calculation of electrophilicity for<br />
optimization of bond-forming functional<br />
groups. z. Zhu, K. N. Houk, E. Krenske,<br />
J. Singh, M. Labenski, K. Lee,<br />
R. C. Petter<br />
401. CoMFA analysis of pyrrolo[2,3-d]pyrimidines<br />
and furo[2,3-d]pyrimidines as multiple<br />
receptor tyrosine kinase inhibitors.<br />
A. Gangjee, S. Raghavan<br />
402. Trainable QSAR model of plasma protein<br />
binding and its application for predicting<br />
volume of distribution.<br />
K. Lanevskij, R. Didziapetris, P. Japertas<br />
403. Approach to quick lead optimization including<br />
physicochemical and ADME profiling.<br />
P. Japertas, A. Sazonovas,<br />
K. Lanevskij, K. Kassam<br />
404. How internal data marries public information<br />
in chemical and biological universes<br />
in drug discovery. P. Liu,<br />
D. Rassokhin, D. K. Agrafiotis<br />
405. Using open source descriptors and algorithms<br />
for modeling ADME properties.<br />
R. R. Gupta, E. M. Gifford, T. Liston,<br />
C. Waller, B. Bunin, S. Ekins<br />
406. Design and synthesis of deuterated erlotinib<br />
analogs with enhanced pharmacokinetic<br />
properties. C. E. Masse,<br />
R. Gallegos, V. Uttamsingh,<br />
A. J. Morales, S. Harbeson, R. Tung<br />
407. Third-generation synthetic inhibitors of<br />
plasminogen activator inhibitor-1.<br />
C. G. Vaghela, J. M. Lisi,<br />
N. C. El-Ayache, P. R. North,<br />
K. L. Sanders, M. Warnock, S. Li,<br />
D. A. Lawrence, C. D. Emal<br />
408. Design, synthesis, structure-activity relationships<br />
and biological evaluation of<br />
phenolic inhibitors of plasminogen activator<br />
inhibitor-1. K. L. Sanders,<br />
H. Y. Saraha, G. A. Abernathy,<br />
N. C. El-Ayache, S. Li, M. Warnock,<br />
D. A. Lawrence, C. D. Emal<br />
409. Discovery of new lead tetrapeptides reversible<br />
inhibitors of thrombin using 2Dtransferred<br />
NOESY NMR. C. C. Clement,<br />
M. Philipp<br />
410. Chemoenzymatic route to uncommon<br />
sugar nucleotides. L. Cai, W. Guan,<br />
P. G. Wang<br />
411. Triarylcarboxylic acid derivatives as<br />
novel xanthine oxidase inhibitors.<br />
J. Miyata, H. Kubota, K. Hattori,<br />
T. Asano, J. Watanabe, R. Munakata,<br />
A. Kamikawa, M. Kageyama, R. Naito,<br />
M. Kawakami, M. Takeuchi, M. Ohta<br />
412. Synthesis of carbon-11-labeled cholesterol-based<br />
cationic lipids as new potential<br />
PET probes for imaging of gene delivery.<br />
M. Gao, M. Wang, G. D. Hutchins,<br />
Q. Zheng<br />
413. Automating gradient method development<br />
in flash chromatography for greater<br />
productivity and minimizing solvent use.<br />
A. Lesniowski, D. McCreary,<br />
S. Anderson, K. Lawrence<br />
414. Biosensor detection of early onset septicemia.<br />
S. K. Hasan, S. Ammu,<br />
S. K. Manohar<br />
415. Synthesis and biological evaluation of<br />
nitroxide-functionalized silica nanoparticles.<br />
M. M. Sprachman, A. H. Faraji,<br />
W. Feng, V. Kagan, P. Wipf<br />
416. Synthesis and evaluation of fluorine<br />
substituted CGRP receptor antagonists<br />
for the development of an 18 F PET imaging<br />
agent. J. J. Kim,M.R.Wood,<br />
K. M. Schirripa, E. Hostetler, S. Sanabria,<br />
C. Sur, D. L. Williams, Z. Zeng,<br />
L. L. Gammage, M. Williams, J. J. Cook,<br />
E. L. Moore, M. S. Michener, J. F. Fay,<br />
S. D. Mosser, R. B. White, J. G. Bruno,<br />
C. A. Salvatore, S. A. Kane, H. G. Selnick,<br />
S. L. Graham<br />
417. RevealX technology improves isolation<br />
and purification of natural products<br />
by flash chromatography. R. Bose,<br />
S. Anderson, K. Lawrence<br />
418. RevealX technology improves purification<br />
of lead generation compounds by<br />
flash chromatography. R. Bose,<br />
S. Anderson, K. Lawrence<br />
419. Development of an analytical method<br />
for the production and measurement of<br />
singlet oxygen. S. L. Pena, L. Rivera,<br />
O. Perales, S. Singh<br />
420. Discovery of dihydroindolyl azetidine<br />
derivatives as potent MCH antagonists<br />
with low PgP efflux. S. Hong,<br />
G. Chandrasena, B. Chen, E. Eldemenky,<br />
A. Husain, Y. Jiang, K. Jones, M. Labelle,<br />
B. Li, K. Lu, G. Ma, M. Marzabadi,<br />
C. Mazza, S. Miller, M. Packiarajan,<br />
M. Sabio, D. Smith, A. D. White, L. Wu<br />
421. Novel ammonium prodrug: Synthesis,<br />
pharmacokinetics, mechanism of release<br />
and scope. A. Regueiro-Ren,<br />
S. M. Jenkins, S. Kim, K. Mosure,<br />
S. Rahematpura, J. Simmermacher,<br />
M. Sinz, M. Zheng, K. Johnson,<br />
N. A. Meanwell, J. F. Kadow<br />
422. Hydrolytic properties of thymidine �-Pboranophosphate<br />
analogs. Z. Xu,<br />
B. R. Shaw<br />
423. Synthesis of sulfonyl curcumin mimics<br />
exerting a vasodilatation effect on the<br />
basilar artery of rabbits. C. Ahn,B.Park,<br />
H. Woo, J. Ham, W. Shin, S. Lee<br />
424. Computed tomography (CT) contrast<br />
agents for determining cartilage health.<br />
R. C. Stewart, P. N. Bansal, N. S. Joshi,<br />
V. Entezari, B. C. Malone, B. D. Snyder,<br />
M. W. Grinstaff<br />
425. Design and optimization of benzimidazole-containing<br />
cold menthol receptor<br />
(TRPM8) antagonists. D. J. Parks,<br />
R. R. Calvo, W. H. Parsons, S. Meegalla,<br />
S. K. Ballentine, J. Chen, C. R. Illig,<br />
D. J. Stone, N. Qin, T. L. Hutchinson,<br />
M. Lubin, Y. Liu, J. Baker, R. W. Colburn,<br />
C. M. Flores, M. R. Player<br />
426. Dendrimer based CT contrast agents<br />
for GAG quantification. S. E. Stidham,<br />
M. W. Grinstaff<br />
427. Synthesis, functionalization and photo-<br />
Bergman chemistry of enediyne bioconjugates.<br />
K. M. Wager,G.B.Jones<br />
428. Discovery, synthesis and biological<br />
evaluation of pyrrole derivatives as novel<br />
and highly selective potassium-competitive<br />
acid blockers (P-CABs). H. Nishida,<br />
A. Hasuoka, Y. Arikawa, O. Kurasawa,<br />
K. Hirase, N. Inatomi, Y. Hori, F. Sato,<br />
N. Tarui, A. Imanishi, M. Kondo, S. Endo,<br />
T. Takagi, M. Kajino<br />
429. Drug-like properties of macrocyclic<br />
molecules derived from DNA-programmed<br />
combinatorial libraries.<br />
B. Seigal, F. Favaloro Jr., T. F. Briggs,<br />
R. Sandberg-Diment, J. Furr, S. Hale,<br />
N. Terrett<br />
430. Optimization of affinity and relaxity of<br />
peptide-based fibrin-targeted MRI contrast<br />
agents via N-terminal PNA modification.<br />
Z. Zhang, M. Greenfield,<br />
A. Kolodziej, P. Caravan<br />
431. Electrochemical reactivity and interactions<br />
of quercetin with DNA in the presence<br />
of Cu(II) ions. S. Cutler,<br />
M. Stobiecka, M. Hepel<br />
432. Crystal structures and hydrogen bonding<br />
patterns in some Schiff Bases of<br />
pharmacological importance.<br />
J. P. Jasinski, R. J. Butcher,<br />
A. N. Mayekar, H. S. Yathirajan,<br />
B. Narayna<br />
433. Synthesis of new hybrid materials designed<br />
for iron selective electrodes based<br />
on selective amino spacer organizations.<br />
P. Rouge, M. Becuwe,<br />
A. Dassonville-Klimpt, A. Jonet,<br />
M. Benazza, C. Guery, E. Baudrin,<br />
P. Sonnet<br />
434. Crystal structures and hydrogen bonding<br />
patterns in picrate salts of pharmacologically<br />
active compounds-I.<br />
J. P. Jasinski, R. J. Butcher,<br />
Q. Hakim Al-arique, H. S. Yathirajan,<br />
B. Narayana<br />
435. Crystal structures and hydrogen bonding<br />
patterns in picrates salts of pharmacologically<br />
active compounds-II.<br />
J. P. Jasinski, R. J. Butcher,<br />
H. S. Yathirajan, B. Narayana,<br />
K. Prakash Kamath<br />
436. Effect of molecular charge in computed<br />
tomography imaging agents. H. Lusic,<br />
N. S. Joshi, R. C. Stewart, P. N. Bansal,<br />
B. D. Snyder, M. W. Grinstaff<br />
437. Structural characterization and biological<br />
activities of various soluble beta-1,3/<br />
1,6-glucans. N. Bose, A. S. Chan,<br />
M. E. Danielson,C.M.Dudney,<br />
N. Elmasry, K. B. Gorden, F. O. Guerrero,<br />
R. R. Langeslay, A. S. Magee,<br />
C. M. Maristany, J. P. Vasilakos,<br />
R. M. Walsh, P. M. Will, L. R. Wurst<br />
438. Annonacin isolated from Asimina triloba<br />
fruit pulp is toxic to rat primary cortical<br />
neurons. L. F. Potts, F. A. Luzzio,<br />
I. Litvan, M. Hetman<br />
439. Identification of piperazine-bisamide<br />
GHSR antagonists for the treatment of<br />
obesity: Transformation from agonist to<br />
antagonist. M. Yu, M. Lizarzaburu,<br />
H. Beckmann, R. Connors, K. Dai, C. Li,<br />
L. Liang, M. Wanska, L. Li, J. C. Medina<br />
440. Withdrawn<br />
441. N-oxyde aurones as new, potent and<br />
non-toxic tyrosinase inhibitors.<br />
R. Haudecoeur, C. Dubois,<br />
A. Boumendjel, C. Belle, M. Réglier<br />
442. Synthesis and photophysical characterization<br />
of novel lanthanide-ion based luminescent<br />
probes for ultrasensitive detection<br />
of biopolymers. L. A. Wirpsza,<br />
S. A. Marras, M. Kozlov, L. Krasnoperov,<br />
A. Mustaev<br />
443. Oral delivery of insulin through the vitamin<br />
B 12 uptake pathway. S. M. Clardy,<br />
T. J. Fairchild, R. P. Doyle<br />
444. Novel prodrug strategy for intracellular<br />
delivery of bisphosphonates.<br />
M. R. Webster, C. Hann, C. Freel Meyers<br />
445. Synthesis and characterization of a new<br />
generation of �-galactosidase-activated<br />
MRI contrast agents. S. G. Byker,<br />
D. M. Ballweg, A. S. Harney, E. A. Waters,<br />
K. W. MacRenaris, K. Lakhoo, J. Krimmel,<br />
T. J. Meade<br />
446. Novel synthesis of prostamide analogs<br />
for use in the physiological characterization<br />
of a specific target receptor.<br />
E. L. Shelnut, A. Makriyannis<br />
447. Design and synthesis of sortase binding<br />
peptide analogs and an SAR study of<br />
small molecule sortase A inhibitors. S. Yi,<br />
A. Chan, N. Suree, R. T. Clubb,<br />
M. E. Jung<br />
448. Quantitation of prechafuroside A, Isovitexin<br />
2”-sulfate and Isovitexin in teas and<br />
fresh tea leaves from spring to autumn.<br />
H. Ishida, T. Usami, T. Wakimoto,<br />
H. Nukaya<br />
449. Synthesis of folate and siRNA conjugates<br />
derived from a water soluble melittin.<br />
I. R. Vlahov, H. R. Santhapuram,<br />
P. J. Kleindl, J. F. Vaughn, L. Qi,<br />
J. A. Reddy, C. P. Leamon<br />
450. Trainable in-silico screening filter for<br />
various human cytochrome P450 isoforms<br />
inhibition liability. R. Didziapetris,<br />
J. Dapkunas, A. Sazonovas, P. Japertas<br />
451. Screening for inhibitors of superoxide<br />
dismutase and characterization of inhibition<br />
using NMR. M. E. Arrington,<br />
J. S. Summers, J. D. Schmitt, J. Markley,<br />
M. R. Yost, E. Parris<br />
452. Pyrrolo[1,2-a]quinoxalin-4(5H)-ones as<br />
novel adenosine A3 antagonists.<br />
S. MAYER, S. Gardan, S. Schann,<br />
P. Neuville<br />
453. Effect of novel pp60 c-src inhibitors on<br />
mammalian glutathione S-transferase activity.<br />
B. S. I˙s¸gör,Y.G.I˙s¸gör, Z. Kılıç-Kurt,<br />
S. Ölgen<br />
454. Inhibitors of adenosine deaminase containing<br />
5:8-fused imidazo[4,5f][1,4]diazocine<br />
ring system.<br />
S. Tantravedi<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
455. Solid phase synthesis of dendritic prodrugs<br />
of salicylic acid. D. Cater, M. Chai,<br />
G. Lu<br />
456. Synthesis of water-soluble salicylic acid<br />
analogs by sugar-conjugation.<br />
D. MacHue, J. Rowlett, M. Chai<br />
457. Improved synthesis of the epoxy isoprostane<br />
phospholipid PEIPC and its analogs.<br />
W. Zhong, J. Springstead,<br />
J. A. Berliner, M. E. Jung<br />
458. Design and synthesis of new derivatives<br />
of YK-4-279 as inhibitors of EWS-FLI1.<br />
P. N. Tosso, L. Jacobwitz, J. A. Toretsky,<br />
M. L. Brown, Y. Kong<br />
459. Design and synthesis of homodinuclear<br />
cyclen-based SH2 domain proteomimetics.<br />
S. Haftchenary,<br />
S. Fletcher, J. A. Drewry, J. Turkson,<br />
P. T. Gunning*<br />
460. Discovery of potent and selective inhibitors<br />
for ADAMTS-4 through encoded library<br />
technology (ELT). Y. Ding,<br />
H. O’Keefe, J. L. Svendsen,<br />
G. J. Franklin, P. A. Centrella, M. A. Clark,<br />
R. A. Acharya, F. Li, J. A. Messer,<br />
C. H. Chiu, R. E. Matico,<br />
M. F. Murray-Thompson, S. R. Skinner,<br />
S. L. Belyanskaya, D. I. Israel,<br />
J. W. Cuozzo, C. C. Arico-Muendel,<br />
B. A. Morgan<br />
461. Novel chemical probes for p300 HAT inhibition.<br />
C. Mukherjee, D. J. Meyers,<br />
E. M. Bowers, P. A. Cole<br />
462. Studies of ciprofloxacin encapsulation<br />
on biogels in organic solvent mixtures.<br />
V. E. Bosio, G. A. Islan, D. Kaplan,<br />
G. R. Castro<br />
463. New and efficient synthesis of regiospecifically<br />
deuterated covalent probes for<br />
cannabinoid receptors. G. A. Thakur,<br />
R. Sharma, A. Makriyannis<br />
464. Design and synthesis of a biotinylated<br />
derivative of the tylophorine analog DCB-<br />
3503. S. Francis, D. C. Baker,<br />
J. Gutierrez, Y. Cheng, X. Wang<br />
465. Optimization of alkyl amine renin inhibitors.<br />
C. M. Tice, R. D. Simpson, J. Yuan,<br />
Z. Xu, W. Zhao, L. Jia, S. Cacatian,<br />
P. T. Flaherty, J. Guo, A. Ishchenko,<br />
S. B. Singh, Z. Wu, B. M. McKeever,<br />
B. B. Scott, Y. Bukhtiyarov, J. Berbaum,<br />
R. Panemangalore, C. P. Doe,<br />
R. N. Willette, R. K. Harrison,<br />
G. M. McGeehan, L. W. Dillard,<br />
J. J. Baldwin, D. A. Claremon<br />
466. Effects of lead and mercury on the<br />
blood proteome of children.<br />
K. Bendinskas, R. Birdsall, M. Kiley,<br />
J. A. MacKenzie<br />
467. Helping build better pre-clinical drug<br />
candidates: Pharmaceutical development<br />
programs at the discovery-development<br />
interface. J. D. Higgins, A. Templeton,<br />
E. Kwong<br />
468. Correlative microscopy: Concurrent<br />
SEM and optical imaging of cells in an<br />
open system. D. Guarrera, H. Nishiyama,<br />
M. Suga, C. Sato<br />
469. Active targeting with controlled delivery<br />
of therapeutic agents to bone using versatile,<br />
bifunctional bisphosphonates.<br />
J. Yewle, D. Puleo, L. Bachas<br />
470. Design and synthesis of Mycobacterial<br />
proteasome inhibitors. G. V. Clements,<br />
H. I. Boshoff, C. S. Dowd<br />
471. New and facile way to Flustramine analogs<br />
through radical cyclization.<br />
G. A. Kraus, J. Beasley<br />
472. Fundamental oxidation and reduction<br />
chemistry of isoniazid and its reactive intermediates.<br />
K. A. Rickman, S. P. Mezyk,<br />
J. J. Kiddle<br />
473. Capture compound mass spectrometry:<br />
A novel chemical proteomics approach to<br />
profile small molecule-protein interactions<br />
for drug target discovery and offtarget<br />
binding-induced toxicity.<br />
M. Sefkow, S. Michaelis, C. Dalhoff,<br />
J. J. Fischer, O. Y. Graebner, F. Kroll,<br />
M. Glinski, M. Dreger, H. Koester<br />
474. Pyrrolopyrimidine-based P2X3 antagonists<br />
for the treatment of pain. L. Cantin,<br />
M. Bayrakdarian, C. Buon, Y. Hu,<br />
V. Kennedy, M. Laplante, C. Leung,<br />
X. Luo, N. Popovic, O. René,<br />
V. Santhakumar, J. Butterworth,<br />
C. Godbout, M. Gosselin, E. Grazzini,<br />
J. Labrecque, M. Paré, D. Projean,<br />
X. Hong Yu, M. J. Tomaszewski<br />
475. Drug discovery: Natural herbal formulation.<br />
J. L. Chan<br />
476. Synthesis and preliminary biological<br />
evaluation of 20-epi-eldecalcitol [20-Epi-<br />
1alfa,25-dihydroxy-2beta-(3-hydroxypropoxy)vitamin<br />
D3: 20-Epi-ED-71].<br />
S. Hatakeyama, M. Yoshino, K. Eto,<br />
K. Takahashi, J. Ishihara, Y. Ono,<br />
H. Saito, N. Kubodera<br />
477. Investigation of preparative HPLC applications<br />
performed at both acidic and basic<br />
pH. J. W. Benedict<br />
478. Novel lacZ responsive enhanced Gdbased<br />
1 H MRI agents. J. Yu,<br />
J. Magnusson, R. P. Mason<br />
479. Synthesis of tetralene- and chromenebased<br />
4EGI-1 mimetics as inhibitors of<br />
eIF4E/eIF4G interaction. P. Mahalingam,<br />
Y. Wang, L. Chen, N. Zhang, J. J. Levy,<br />
E. Papadopoulos, B. H. Aktas,<br />
G. Wagner, J. A. Halperin, M. Chorev<br />
480. Spiro-benzamides as ENT-1 inhibitors.<br />
D. Berthelot, S. Pieters, M. De Cleyn,<br />
J. Bosmans, S. Pype, T. Meert<br />
481. Depth dependent swelling and mechanical<br />
behavior of cartilage. F. Horkay,<br />
I. Horkayne-Szakaly, E. K. Dimitriadis,<br />
C. Silva, P. J. Basser<br />
482. Evaluation of select fractions of mineral<br />
oil in vaccine preparation. R. S. Stahl,<br />
J. M. kemp, L. A. Miller<br />
483. Loading the dice by integrating lead optimization.<br />
R. D. Clark, D. Miller,<br />
R. Fraczkiewicz, M. Waldman,<br />
M. B. Bolger, W. S. Woltosz<br />
484. Withdrawn<br />
THURSDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
General Oral Session<br />
J. Zablocki, Organizer<br />
X. Wang, Presiding<br />
8:30 485. Multicomponent reactions for the<br />
discovery of p53-Mdm2 antagonists:<br />
Synthesis, chemoinformatics and biological<br />
evaluations. Y. Huang,A.Dömling<br />
8:50 486. Discovery of novel macrolide antibiotics:<br />
Synthesis and biological evaluation<br />
of 4,8,10-tridesmethyl telithromycin.<br />
V. Velvadapu, T. Paul, B. S. Wagh,<br />
R. B. Andrade<br />
9:10 487. Engineered immunity: Development<br />
of multivalent artificial opsonins for<br />
the treatment of nosocomial infections.<br />
K. N. Katzenmeyer, J. D. Bryers<br />
9:30 488. Identification and SAR of novel furan-free<br />
imidazopyridine ligands as selective<br />
adenosine A2A-antagonists for Parkinson<br />
disease. S. Schann, S. Mayer,<br />
L. Cardona, S. Gardan, N. Hubert,<br />
A. Haberkorn, E. Steinberg, L. Baron,<br />
C. Franchet, P. Neuville<br />
9:50 489. Discovery of BKM120, a pan class<br />
I PI3 kinase inhibitor in phase I/II clinical<br />
trials. M. T. Burger, S. Pecchi,<br />
A. Wagman, Z. Ni, M. Knapp, G. Atallah,<br />
K. Pfister, S. Ng, A. Smith, T. Pick,<br />
K. Frazier, J. Verhagen, Y. Zhang,<br />
S. Bartulis, T. Hendricksen, E. Iwanowicz,<br />
J. Hazenadar, K. Huh, A. Ashash, X. Xin,<br />
D. Menezes, H. Merritt, M. Wiesmann,<br />
C. Voliva<br />
10:10 490. Design and synthesis of dual<br />
adenosine A 2A/A 1 antagonists for the<br />
treatment of Parkinson’s disease.<br />
B. C. Shook<br />
10:30 491. Synthesis and biological activity<br />
of 2H-quinolizin-2-one based p38-a MAP<br />
kinase inhibitors. R. M. Tynebor,<br />
M. Chen, S. R. Natarajan, E. A. O’Neill,<br />
J. E. Thompson, C. E. Fitzgerald,<br />
S. J. O’Keefe, J. B. Doherty<br />
10:50 492. Evaluation of 4-cyano-4-arylpiperidine<br />
quinolizidinone carboxylic acid<br />
selective M 1 positive allosteric receptor<br />
modulators. S. D. Kuduk,R.K.Chang,<br />
C. N. Di Marco, D. R. Pitts, W. J. Ray,<br />
L. Ma, M. Wittmann, M. A. Seager,<br />
K. A. Koeplinger, C. D. Thompson,<br />
G. D. Hartman, M. T. Bilodeau<br />
11:10 493. Discovery of the potent PI3K/<br />
mTOR dual inhibitor PF-04979064.<br />
H. Cheng, S. Bagrodia, S. Bailey,<br />
S. M. Baxi, L. Goulet, L. Guo, J. Hoffman,<br />
T. O. Johnson, T. W. Johnson, C. Li, J. Li,<br />
K. Liu, Z. Liu, M. A. Marx, G. Paderes,<br />
S. Sun, M. Walls, P. A. Wells, A. Yang,<br />
M. Yin, J. Zhu<br />
11:30 494. Identification of PKI-179 as a potent<br />
and orally efficacious PI3 kinase inhibitor<br />
for the treatment of cancer.<br />
Z. Chen, A. M. Venkatesan<br />
11:50 495. Design and synthesis of tricyclic<br />
sulfones as g-secretase inhibitors with<br />
greatly reduced Notch toxicity. R. Xu,<br />
D. Cole, T. Asberom, T. Bara, C. Bennett,<br />
D. A. Burnett, J. Clader, M. Domalski,<br />
W. Greenlee, L. Hyde, H. Josien, H. Li,<br />
M. McBriar, B. McKittrick, A. T. McPhail,<br />
D. Pissarnitski, L. Qiang, M. Rajagopalan,<br />
T. Sasikumar, J. Su, H. Tang, W. Wu,<br />
L. Zhang, Z. Zhao<br />
12:10 496. Discovery of PPIs using chemical<br />
feature-based pharmacophore models.<br />
T. Langer<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 253A/B<br />
Pharmacological Manipulation of<br />
Endocannabinoid Degradation<br />
J. Breitenbucher, S. McAlpine, Organizers,<br />
Presiding<br />
8:30 Introductory Remarks<br />
8:40 497. Targeting endogenous cannabinoid<br />
catabolic enzymes in preclinical<br />
models of pain. A. H. Lichtman<br />
9:20 498. Discovery of a novel series of potent,<br />
non-covalent fatty acid amide hydrolase<br />
(FAAH) inhibitors through rational<br />
design. D. J. Gustin,Z.Ma,Y.Li,<br />
C. Hedberg, X. Min, C. Guimaraes,<br />
Z. Wang, N. Walker, M. Lindstrom,<br />
R. Connors, A. C. Porter,<br />
D. Lester-Zeiner, F. Kayser<br />
10:00 499. Inhibitors of fatty acid amide hydrolase<br />
(FAAH): SAR and results in preclinical<br />
pain models. M. S. Tichenor,<br />
J. M. Keith, R. L. Apodaca, W. Xiao,<br />
W. Jones, A. L. Chambers, M. Seierstad,<br />
J. Pierce, J. A. Palmer, M. Webb,<br />
M. J. Karbarz, L. Chang, S. J. Wilson,<br />
L. Luo, M. L. Wennerholm, S. M. Brown,<br />
M. Rizzolio, R. Rynberg, B. P. Scott,<br />
J. Breitenbucher, S. R. Chaplan<br />
10:40 500. Discovery of PF-04457845, an irreversible<br />
FAAH inhibitor with exquisite<br />
selectivity. D. S. Johnson<br />
11:20 501. Discovery and development of<br />
inhibitors of fatty acid amide hydrolase<br />
(FAAH). D. L. Boger<br />
Targeting Gram-Negative Pathogens<br />
Sponsored by COMP, Cosponsored by CINF<br />
and MEDI<br />
THURSDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
General Oral Session<br />
J. Zablocki, Organizer, Presiding<br />
1:30 502. Nicotinamide derivatives as novel,<br />
potent and orally active mGlu5 receptor<br />
antagonists. R. Glatthar, I. Vranesic,<br />
C. Spanka, D. Orain, S. Desrayaud,<br />
M. Fendt, D. Hoyer, Y. P. Auberson,<br />
K. H. McAllister, M. T. Wyss, A. Buck<br />
1:45 503. Development of long term manufacturing<br />
process for MK-0633 (Setileuton).<br />
H. Li, J. Balsells-padros,<br />
G. Humphrey, C. Chen, B. Cohen,<br />
D. J. Kumke, F. Gosselin, C. Nadeau,<br />
S. Dolman, P. O’Shea<br />
2:00 504. Apolipoprotein B-100: A 3-iodothyronamine<br />
(T1AM) binding protein.<br />
G. Roy, T. Scanlan<br />
2:15 505. Resorcinol-class HSP90 inhibitors<br />
for oral treatment in oncology.<br />
H. Eggenweiler, C. Sirrenberg,<br />
H. Buchstaller, M. Wolf, U. Grädler,<br />
J. März, D. Musil, E. Hoppe,<br />
A. Zimmermann, C. Amendt,<br />
H. Schwartz, J. Bomke, A. Wegener,<br />
T. Mohr, H. Bauer, M. Brändle,<br />
M. Braendle, J. Gleitz, N. Huebler,<br />
T. Selzer<br />
2:30 506. Design and synthesis of potent,<br />
dual action p53/MDM2/MDMX antagonists<br />
for the treatment of cancer.<br />
K. Wang, W. Wang, G. M. Popowicz,<br />
A. Czarna, S. Wolf, D. Alexander,<br />
T. A. Holak<br />
2:45 507. Synthesis and evaluation of hadacidin<br />
analogs. N. Tibrewal, G. I. Elliott<br />
3:00 508. Trypanosomal target of rapamycin:<br />
Repurposing of mammalian TOR inhibitors<br />
for neglected disease drug discovery.<br />
C. E. Hubbard, S. M. Beverley,<br />
R. Diaz, L. Madeira da Silva, M. Navarro,<br />
M. J. Ondrechen, Z. Wang, M. P. Pollastri<br />
3:15 509. Discovery of a fluorescent cyclindependant<br />
kinase inhibitor with potent<br />
antiproliferative activity in human breast<br />
cancer cells. V. M. Yenugonda,<br />
T. B. Deb, S. C. Grindrod,<br />
S. Dakshanamurthy, Y. Yang, M. Paige,<br />
M. L. Brown<br />
3:30 510. Discovery of phenoxy thiophene<br />
sulfonamides as new potentiators of<br />
Nerve Growth Factor (NGF)-induced neurite<br />
outgrowth. A. L. Williams,<br />
S. R. Dandepally, N. Gilyazova,<br />
S. M. Witherspoon, G. Ibeanu<br />
3:45 511. Synthesis, SAR and biological<br />
evaluation of novel benzimidazoles targeting<br />
FtsZ for drug discovery of efficacious<br />
antitubercular agents. K. Kumar,<br />
D. Awasthi, B. Ruzsicska, P. J. Tonge,<br />
R. A. Slayden, I. Ojima<br />
4:00 512. De novo purine biosynthesis as a<br />
novel antibiotic target. H. Paritala,<br />
J. B. Thoden, H. M. Holden,<br />
S. M. Firestine<br />
4:15 513. Imaging of amyloid beta species<br />
by using spectral unmixing with a “smart”<br />
fluorescence probe. C. Ran,A.Moore<br />
4:30 514. New potential drug against obesity:<br />
Design and synthesis of ghrelin receptor<br />
antagonists. A. Blayo, J. Martinez,<br />
J. Fehrentz<br />
4:45 515. Inhibitors of protein-amyloid interactions<br />
protect cells from �-amyloid-induced<br />
oxidative stress and toxicity.<br />
L. K. Habib, J. Yang<br />
Targeting Gram-Negative Pathogens<br />
Sponsored by COMP, Cosponsored by CINF<br />
and MEDI<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
MEDI<br />
TECH–81
NUCL <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
NUCL<br />
Division of Nuclear<br />
Chemistry and<br />
Technology<br />
S. Jurisson, Program Chair<br />
SOCIAL EVENTS:<br />
Social Hour, 5:30 PM: Mon<br />
BUSINESS MEETING:<br />
Business Meeting, 5:00 PM: Mon<br />
Executive Committee Meeting, 6:00<br />
PM: Sun<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
Radiochemistry at the Facility for Rare<br />
Isotope Beams<br />
Science and Production of Rare Isotopes<br />
M. Stoyer, Organizer<br />
P. Mantica, Organizer, Presiding<br />
8:00 1. Overview of the Facility for Rare Isotope<br />
Beams. B. Sherrill<br />
8:30 2. Computing atomic nuclei.<br />
W. Nazarewicz<br />
9:00 3. Current and future needs for isotopes<br />
critical to research and industry.<br />
W. Runde<br />
9:30 Intermission<br />
9:45 4. Isotope production at high energy:<br />
Lessons for FRIB. L. F. Mausner<br />
10:15 5. Isotope production at the Los<br />
Alamos Isotope Production Facility.<br />
K. John<br />
10:45 6. Current and future use of radionuclides<br />
produced from nuclear reactors for<br />
medical applications. C. S. Cutler,<br />
A. R. Ketring<br />
11:15 7. Transuranium target based Superheavy<br />
Element research at GSI.<br />
C. E. Duellmann<br />
11:45 Panel Discussion<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 109B<br />
Graduate Student Symposium in Nuclear<br />
and Radiochemistry<br />
P. Benny, Organizer<br />
J. Robertson, Organizer, Presiding<br />
8:00 8. Applicability of intrinsic dosimetry to<br />
waste management and nuclear forensics.<br />
R. A. Clark, S. D. Miller,<br />
J. D. Robertson, J. M. Schwantes<br />
8:25 9. Assessing thermochromatography<br />
as a separations method for nuclear forensics:<br />
Current capability vis-à-vis forensic<br />
requirements. D. E. Hanson,<br />
J. R. Garrison, H. L. Hall<br />
8:50 10. Neutron-capture gamma-ray studies<br />
for levels in 75,77 Ge and 81,83 Se.<br />
N. E. Sharp, C. J. Chiara, W. B. Walters,<br />
R. T. Bindel, R. L. Paul<br />
9:15 11. Cathodoluminescent signatures of<br />
neutron irradiation. D. K. Silletti,<br />
J. D. Borycz, S. A. Brokus,<br />
P. A. DeYoung, J. Buscaglia,<br />
G. F. Peaslee<br />
82–TECH<br />
‡ Cooperative Cosponsorship<br />
9:40 12. Monte Carlo analysis of thermochromatography<br />
for nuclear forensics applicability.<br />
J. R. Garrison,D.E.Hanson,<br />
H. L. Hall<br />
10:05 Intermission<br />
10:20 13. Azimuthal anisotropy of unidentified<br />
charged hadrons at forward rapidity<br />
in PHENIX at RHIC. E. Richardson<br />
10:45 14. Development of a gas stopping<br />
cell for heavy element chemistry research<br />
at the Texas A&M Cyclotron Institute.<br />
M. C. Alfonso, C. M. Folden<br />
11:10 15. Experimental study of partitioning<br />
and reactive transport of uranium through<br />
a graphite matrix. G. Schmidt,<br />
G. Cerefice<br />
11:35 16. Extractive chromatography for the<br />
treatment of used nuclear fuel.<br />
M. D. Gott, D. D. Ensor<br />
12:00 17. Determination of Tc-99 concentration<br />
in water, soil, and vegetation samples<br />
at Savannah River National Lab.<br />
J. McCormick, S. Jurisson, D. Beals,<br />
G. Fugate, H. Brandt<br />
SUNDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 109B<br />
New Directions in Isotope Production,<br />
Nuclear Forensics and Radiochemistry<br />
Nuclear Forensics Education Award<br />
Program Financially supported by U.S.<br />
Department of Energy<br />
C. Williamson, Organizer<br />
M. Walsh, Presiding<br />
1:00 Introductory Remarks<br />
1:05 18. The Nuclear Forensics Education<br />
Award Program. S. Kentis, T. Black,<br />
D. Velaquez<br />
1:25 19. Defense Threat Reduction Agency<br />
radiochemical needs. M. A. Walsh,<br />
D. L. Velaquez<br />
1:45 Intermission<br />
2:00 20. Master’s-level certificate program<br />
in nuclear forensics at Texas A&M University.<br />
C. M. Folden, W. S. Charlton,<br />
D. G. Ford, P. Kuchment, W. Rundell,<br />
R. E. Tribble<br />
2:20 21. NFEAP at the University of Missouri-<br />
Columbia. J. D. Robertson,<br />
S. S. Jurisson, S. Z. Lever<br />
2:30 22. NFEAP at the University of Texas-<br />
Austin. S. Landsberger, S. Biegalski,<br />
L. Sentis<br />
2:40 23. Radiochemistry and nuclear forensics<br />
education at Washington State University.<br />
S. B. Clark<br />
2:50 Intermission<br />
3:05 24. Nuclear forensics student activities<br />
at the Savannah River National Laboratory.<br />
D. Beals<br />
3:15 25. Nuclear and radiological forensics<br />
at Argonne National Laboratory.<br />
M. Goldberg<br />
3:25 26. Nuclear forensics at Idaho National<br />
Laboratory. M. Finck<br />
3:35 27. Nuclear forensics at Lawrence Livermore<br />
National Laboratory. A. Kersting<br />
3:45 28. Nuclear forensics at Oak Ridge National<br />
Laboratory. B. D. Patton<br />
3:55 29. Nuclear forensics at Pacific Northwest<br />
National Laboratory. J. Schwantes<br />
4:05 30. Nuclear forensics at Los Alamos<br />
National Laboratory. C. Burns<br />
4:15 Intermission<br />
4:30 31. Nuclear Forensics Graduate Fellowship<br />
Program at Penn State University.<br />
J. H. Rim<br />
4:40 32. Nuclear Forensics Graduate Fellowship<br />
Program at TAMU. J. C. Miller<br />
4:50 33. Nuclear Forensics Graduate Fellowship<br />
Program at Georgia Institute of<br />
Technology. J. L. Steeb<br />
5:00 34. Nuclear Forensics Graduate Fellowship<br />
Program at the University of<br />
Texas. C. J. Weaver<br />
5:10 Panel Discussion<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
New Directions in Isotope Production,<br />
Nuclear Forensics and Radiochemistry<br />
Radiochemistry Financially supported by U.S.<br />
Department of Energy<br />
M. Welch, P. Srivastava, Organizers,<br />
Presiding<br />
1:30 Introductory Remarks<br />
1:35 35. Radiotracer chemistry and molecular<br />
imaging with carbon-11 and fluorine-18.<br />
J. S. Fowler<br />
2:05 36. Solid-phase approach for radioiodination<br />
of aromatic biomolecules from organotin<br />
precursors. A. N. Gifford,<br />
C. Shea, J. S. Fowler<br />
2:20 37. Preparation of anhydrous 18 F-fluoride.<br />
T. Tewson<br />
2:35 38. Novel ways to study defense-induced<br />
carbon allocation and metabolic<br />
partitioning in plants using 2-[ 18 F]fluoro-<br />
2-deoxy-D-glucose. A. Ferrieri, M. Best,<br />
H. Appel, J. Schultz, R. A. Ferrieri<br />
2:50 39. Silicon-fluoride functionalized small<br />
molecule hormones: Prospects for PET<br />
imaging of estrogen receptors with<br />
Si-F-18 labeled ligands. S. Kim,<br />
V. M. Carroll, J. A. Katzenellenbogen,<br />
M. J. Welch, C. Dence, D. Zhou<br />
3:05 Intermission<br />
3:20 40. Estrogen-dendrimer conjugate labeled<br />
with fluorine-18 for PET imaging.<br />
S. Kim, V. M. Carroll,<br />
J. A. Katzenellenbogen, M. J. Welch,<br />
C. Dence, D. Zhou<br />
3:35 41. Isotope incorporation using solid<br />
state boron reagents. G. W. Kabalka,<br />
L. Yong, M. Yao<br />
3:50 42. PET imaging of thin objects: Measuring<br />
the effects of positron range and<br />
partial volume averaging in the leaf of<br />
Nicotiana tabacum. D. Alexoff, S. Dewey,<br />
P. Vaska, S. Krishnamoorthy, R. Ferrieri,<br />
M. Schueller, D. J. Schlyer, J. Fowler<br />
4:05 43. Improved synthesis of 2�-deoxy-2�-<br />
[ 18 F]fluoro-5-methyl-1-�-D-arabinofuranosyluracil<br />
( 18 F-FMAU). Z. Li,H.Cai,<br />
P. S. Conti<br />
4:20 44. New uses of carbon-11 synthons:<br />
11 CO2,H 2 11 CO, and H 11 CN.<br />
J. M. Hooker<br />
4:35 45. Training for the development of<br />
novel radiotracers for interrogations of biological<br />
systems. S. S. Jurisson,<br />
S. Z. Lever, J. D. Robertson, R. Ferrieri,<br />
C. Cutler, T. Glass, M. Harmata, T. Quinn,<br />
L. Song, P. Cavins, R. Sun<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
Radiochemistry at the Facility for Rare<br />
Isotope Beams<br />
Surrogates and Targets<br />
P. Mantica, Organizer<br />
M. Stoyer, Organizer, Presiding<br />
8:00 46. Role of radioactive beams in stockpile<br />
stewardship science. E. Hartouni<br />
8:30 47. Is there a surrogate for neutron<br />
capture? J. A. Cizewski<br />
9:00 48. Surrogate ratio method measurements<br />
in the actinide region.<br />
C. W. Beausang<br />
9:30 Intermission<br />
9:45 49. Cross section measurements using<br />
direct reactions at FRIB. J. T. Burke,<br />
N. D. Scielzo, J. J. Ressler, J. E. Escher,<br />
I. J. Thompson, R. A. Henderson,<br />
D. L. Bleuel, R. J. Casperson,<br />
L. A. Bernstein, M. Wiedeking,<br />
L. W. Phair, S. Basunia, R. Hatarik,<br />
E. B. Norman, J. Munson,<br />
B. F. Lyles-Goldblum, C. Beausang,<br />
T. Ross, R. Hughes, S. Paschalis, M. Petri<br />
10:15 50. Reaction measurements on and<br />
with radioactive isotopes for nuclear astrophysics.<br />
R. Reifarth<br />
10:45 51. FRIB isotope production for rare<br />
targets. J. Ressler<br />
11:15 52. Uranium carbide targets for radioactive<br />
ion beams: Review and new developments.<br />
T. Stora<br />
11:45 Panel Discussion<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 109B<br />
Graduate Student Symposium in Nuclear<br />
and Radiochemistry<br />
J. Robertson, Organizer<br />
P. Benny, Organizer, Presiding<br />
8:30 53. Effect of radiolysis on the yield of<br />
Mo from the Cintichem process.<br />
M. F. McLaughlin, J. D. Robertson<br />
8:55 54. 64 Cu-labeled somatostatin analogs<br />
as diagnostic and therapeutic agents.<br />
K. Nguyen, J. Parry, A. Chang,<br />
A. Zheleznyak, C. Sherman, B. E. Rogers,<br />
C. J. Anderson<br />
9:20 55. N2S2 ligands (ligands with two nitrogen<br />
donors and two sulfur donors) for<br />
chelating oxorhenium(V): Successes and<br />
failures. D. W. Demoin,T.J.Hoffman,<br />
S. S. Jurisson<br />
9:45 56. Optimization of the synthesis of binary<br />
technetium halides.<br />
E. V. Johnstone, F. Poineau,<br />
K. R. Czerwinski, A. Sattelberger<br />
10:10 Intermission<br />
10:25 57. Development of a tetrathioether<br />
bifunctional chelate system for 105 Rh.<br />
V. N. Carroll, T. Hoffman, S. Jurisson<br />
10:50 58. Investigation of the radiation effects<br />
and redox stability of M(CO)3 (M �<br />
Re, Tc-99m) amino acid complexes in<br />
aqueous solution. K. M. Johnstron,<br />
S. Mezyk, A. Wemple, C. M. Jewett,<br />
P. D. Benny<br />
11:15 59. Measurement of trace elements<br />
during the development and immune response<br />
of Heliothis virescens larvae.<br />
R. Sun, H. R. Popham, K. S. Shelby,<br />
J. D. Robertson<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
New Directions in Isotope Production,<br />
Nuclear Forensics and Radiochemistry<br />
Radiochemistry Financially supported by U.S.<br />
Department of Energy<br />
M. Welch, Organizer<br />
P. Srivastava, Organizer, Presiding<br />
J. Fowler, Presiding<br />
1:30 Introductory Remarks<br />
1:35 60. Radiochemistry and applications of<br />
nonstandard positron emitting radionuclides.<br />
M. J. Welch<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
2:05 61. Applications of PET imaging toward<br />
bioremediation and geochemical studies.<br />
N. T. Vandehey, S. E. Taylor, J. P. O’Neil<br />
2:20 62. Digital microfluidics: Toward a<br />
bench-top platform for on-demand radiosynthesis<br />
of diverse PET tracers.<br />
P. Y. Keng, H. Ding, S. Chen, S. Sadeghi,<br />
G. J. Shah, M. E. Phelps, N. Satyamurthy,<br />
C. Kim, R. M. van Dam<br />
2:35 63. Design and synthesis of molecular<br />
and nanoparticulate probes: A training<br />
program in radiochemistry and radiotracer<br />
development. R. N. Hanson<br />
2:50 64. In-vitro stability measurement of<br />
Cu-64 complexes of bifunctional chelators.<br />
V. Maheshwari, J. Dearling,<br />
T. S. Treves, A. B. Packard<br />
3:05 Intermission<br />
3:20 65. Microfluidic radiometal labeling<br />
systems for biomolecules. D. Zeng,<br />
D. E. Reichert, T. Wheeler, A. Desai,<br />
P. J. Kenis<br />
3:35 66. Preparation of a copper-64 labeled<br />
somatostatin analog using a phosphonic<br />
acid derivative of cross-bridge cyclam as<br />
the chelator. Y. Guo, R. Ferdani,<br />
C. J. Anderson<br />
3:50 67. Preparation and biological evaluation<br />
of 64 Cu labeled AmBaSar-RGD peptide<br />
for improved microPET imaging of integrin<br />
�v�3 expression. H. Cai, Z. Li,<br />
C. Huang, R. Park, A. Shahinian,<br />
P. S. Conti<br />
4:05 68. Novel bifunctional chelators for<br />
Cu-64 radiolabeling and PET imaging.<br />
S. Jain, X. Sun, H. A. Song, S. E. Lapi,<br />
M. J. Welch, H. Chong, B. E. Rogers<br />
4:20 69. Synthesis and chemical stability of<br />
actinium-fullerenes. J. Mwakisege,<br />
G. Schweitzer, R. Boll, S. Mirzadeh<br />
4:35 70. Optimization of solid-phase approaches<br />
for radiolabeled peptides.<br />
S. H. Hausner, R. D. Carpenter,<br />
J. B. White, J. L. Sutcliffe<br />
4:50 71. New approaches for reduction of<br />
99<br />
Tc pertechnetate: Potential applications<br />
in environmental remediation and<br />
extension to reduction of 188 Re perrhenate<br />
for radiopharmaceutical applications.<br />
D. McGregor, B. P. Burton-Pye,<br />
I. M. Mbomekalle, W. W. Lukens,<br />
L. C. Francesconi<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
Radiochemistry at the Facility for Rare<br />
Isotope Beams<br />
Applications<br />
M. Stoyer, P. Mantica, Organizers<br />
B. Sherrill, Presiding<br />
8:00 72. Neptunium and plutonium borates.<br />
T. E. Albrecht-Schmitt<br />
8:30 73. Aqueous chemistry of technetium-99<br />
polyoxometalates: Understanding<br />
fundamental chemistry of technetium-99<br />
incorporated into metal oxide<br />
matrices. B. P. Burton-Pye, D. McGregor,<br />
I. M. Mbomekalle, W. W. Lukens,<br />
F. Poineau, E. Mausolf,<br />
L. C. Francesconi<br />
9:00 74. Radioistopes in plant science:<br />
Meeting global challenges in sustainability.<br />
R. A. Ferrieri<br />
9:30 Intermission<br />
9:45 75. Opportunities for the production of<br />
medical isotopes with FRIB. S. E. Lapi,<br />
M. J. Welch<br />
10:15 76. Accelerator mass spectrometry:<br />
Current status, new developments, and<br />
opportunities with FRIB. P. Collon<br />
10:45 77. Beta-NMR facility at TRIUMF:<br />
New tools for materials science at the<br />
nanoscale. M. Andrew, G. Morris<br />
11:15 78. 7-Be implantation in plastics for<br />
prosthesis wear studies. U. Greife,<br />
L. Erikson, N. Patel, M. Wimmer,<br />
Y. Dwiwedi, M. Laurent, K. Chipps,<br />
J. Blackmon, R. Kozub, D. Bardayan,<br />
C. Gross, D. Stracener, M. Smith,<br />
C. Nesaraya, E. Rehm, I. Ahmad,<br />
J. Greene<br />
11:45 Panel Discussion<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 109B<br />
Graduate Student Symposium in Nuclear<br />
and Radiochemistry<br />
J. Robertson, Organizer<br />
P. Benny, Organizer, Presiding<br />
8:00 79. Investigation of actinide solubility in<br />
brines using XAFS. D. Olive,D.Reed,<br />
J. Terry<br />
8:25 80. Using polymer ligand films for rapid<br />
radiochemical sample preparation for alpha<br />
spectrometry. C. L. Tulley,<br />
E. R. Gonzales, C. E. Armenta,<br />
J. A. Hererra, D. S. Peterson<br />
8:50 81. U(VI) and Sr(II) speciation at the<br />
silica/water interface determined by second<br />
harmonic generation. J. N. Malin,<br />
F. M. Geiger<br />
9:15 82. Lanthanide and actinide extraction<br />
from carboxylic acid media by Cyanex®<br />
923. J. H. Hines,K.L.Nash<br />
9:40 83. Calorimetric and time resolved fluorescence<br />
spectroscopy of Eu(III) complexation<br />
with �-hydroxyisobutyric acid in a<br />
mixed 1, 4-dioxane/water media.<br />
M. R. Kriz, Z. Wang, K. L. Nash<br />
10:05 Intermission<br />
10:20 84. Radiolytic behavior of neptunium<br />
in nitric acid in the presence of HNO 2<br />
scavengers. M. Precek, A. Paulenova<br />
10:45 85. Synthesis and structural characterization<br />
of actinide phosphonate compounds:<br />
A comparative study of Th(IV)<br />
and U(VI) complexes. P. O. Adelani,<br />
T. E. Albrecht-Schmitt<br />
11:10 86. Determination of plutonium interactions<br />
with aluminum-substituted goethite<br />
using X-ray absorption spectroscopy.<br />
D. L. Wang,Y.Hu,<br />
L. K. Schwaiger, H. Nitsche<br />
11:35 87. Chromatographic materials for the<br />
separation of actinides and lanthanides.<br />
K. F. York, D. D. Ensor<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
New Directions in Isotope Production,<br />
Nuclear Forensics and Radiochemistry<br />
Science and Technology for Making<br />
Isotopes Financially supported by U.S.<br />
Department of Energy<br />
D. Phillips, Organizer<br />
D. Wilbur, R. Atcher, Presiding<br />
1:30 Introductory Remarks<br />
1:35 88. The National Isotope Development<br />
Center. R. Atcher<br />
1:50 89. Production of thorium-229 in a proton<br />
accelerator. M. A. Garland,<br />
D. W. Stracener, R. A. Boll,<br />
S. L. Holbrook, S. Mirzadeh, J. R. Beene<br />
2:05 90. Alternate method for production of<br />
Ac-225. J. Harvey, J. A. Nolan, T. Kroc,<br />
I. Gomes, P. Horwitz, D. McAlister<br />
2:20 91. Accelerator-based production of<br />
the therapy isotope 225 Ac. F. M. Nortier,<br />
J. W. Weidner, H. T. Bach, K. D. John,<br />
A. Couture, J. L. Ullmann,<br />
M. E. Fassbender, G. S. Goff, W. Taylor,<br />
F. Valdez, L. E. Wolfsberg, M. Cisneros,<br />
D. Dry, M. Gallegos, R. Gritzo,<br />
L. J. Bitteker, S. Wender, R. S. Baty<br />
2:35 92. LaPO 4 nanoparticles doped with<br />
Actinium-225 that partially sequester<br />
daughter radionuclides.<br />
J. D. Woodward, S. J. Kennel,<br />
A. Stuckey, D. Osborne, J. Wall,<br />
A. J. Rondinone, R. F. Standaert,<br />
S. Mirzadeh<br />
2:50 93. Recovery of actinium-227 from legacy<br />
actinium-beryllium neutron sources.<br />
M. Du, C. W. Alexander, R. A. Boll<br />
3:05 Intermission<br />
3:20 94. Ionic liquids as solvents for improved<br />
production of radioisotopes.<br />
H. Luo, J. R. Bell, R. A. Boll,<br />
D. W. Depaoli, S. Dai<br />
3:35 95. Assessing the wet chemistry approach<br />
for isolation of astatine-211 from<br />
irradiated bismuth targets. D. Wilbur,<br />
D. K. Hamlin, M. Chyan, D. Dadachov<br />
3:50 96. Accelerator production of Astatine-<br />
211 from molten metallic Bismuth targets.<br />
M. C. Lagunas-Solar<br />
4:05 97. Production of alpha-particle emitting<br />
At-211 at the Texas A&M Cyclotron<br />
Institute. V. Bhakta, G. Akabani,<br />
A. Alharbi, R. Tribble<br />
4:20 98. Production of 64 Cu from irradiated<br />
64 Ni. J. Robertson, A. Y. Garnov,<br />
L. A. Saale, M. D. Weichelt<br />
4:35 99. Production of radioisotope Cu 67<br />
with high specific activity at Brookhaven<br />
Linac Isotope Producer.<br />
D. G. Medvedev, L. F. Mausner,<br />
C. J. Dodge<br />
4:50 100. Improved purification process for<br />
production of gadolinium-153.<br />
A. M. Johnson, C. Z. Soderquist,<br />
B. K. McNamara, D. R. Fisher<br />
WEDNESDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 109B<br />
Aqueous Chemistry and Thermodynamics<br />
of Actinides and Fission Products: A Tribute<br />
to Volker Neck<br />
H. Nitsche, H. Geckeis, Organizers<br />
T. Fanghänel (Fanghaenel), Organizer,<br />
Presiding<br />
A. Seibert, Presiding<br />
8:00 Introductory Remarks<br />
8:05 101. Aqueous chemistry and thermodynamics<br />
of plutonium. T. Fanghänel,<br />
V. Neck, M. Altmaier<br />
8:35 102. Actinide chemistry in aqueous<br />
systems at high ionic strength.<br />
M. Altmaier<br />
9:05 103. High ionic-strength subsurface<br />
chemistry of actinides. D. T. Reed,<br />
M. Borkowski, M. K. Richmann,<br />
J. Lucchini, J. Swanson, D. Ams,<br />
H. Khaing<br />
9:35 Intermission<br />
9:50 104. Hydrolysis of Pu(VI) at elevated<br />
temperatures. L. Rao, G. Tian,<br />
P. Di Bernardo, P. Zanonato<br />
10:20 105. Thermodynamic approach for<br />
predicting actinide concentrations in<br />
leachates from radioactive waste glasses.<br />
D. Rai,M.Yui<br />
10:50 106. Speciation of polynuclear An(IV)<br />
complexes by electrospray mass-spectrometry.<br />
C. Walther<br />
11:20 107. Hydration of gas phase ytterbium<br />
ion complexes studied by experiment<br />
and theory. P. X. Rutkowski,<br />
M. Michelini, T. H. Bray, J. Marçalo,<br />
J. K. Gibson<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
Applications of Radionuclides in Imaging<br />
and Therapy<br />
Fluorine-18 and Carbon-11<br />
A. Packard, M. Lewis, Organizers,<br />
Presiding<br />
8:30 108. Engineered antibody fragments<br />
for immunoPET: Optimization of F-18 labeled<br />
diabodies. E. J. Lepin, K. Liu,<br />
M. W. Wang, S. J. Sirk, R. M. Van Dam,<br />
C. K. Shen, A. M. Wu<br />
8:50 109. Biodistribution and radiation dosimetry<br />
of amyloid � plaque imaging<br />
agent 18F-W372 measured in healthy<br />
volunteers. J. Q. Yu,M.Doss,<br />
R. K. Alpaugh, J. C. Walsh, Z. Zhu,<br />
A. Chaudhary, H. Kolb, T. Morrison<br />
9:10 110. Design, synthesis and structure<br />
dependence of 18-[ 18 F]fluoro-thia-fatty<br />
acids as myocardial fatty acid oxidation<br />
probes. M. K. Pandey,A.P.Belanger,<br />
S. Wang, T. R. DeGrado<br />
9:30 111. F-18 radiolabeled rhodamine derivatives<br />
as potential myocardial perfusion<br />
tracers for positron emission tomography.<br />
M. D. Bartholomä,<br />
V. Gottumukkala, A. Baker, P. Dunning,<br />
F. H. Fahey, S. T. Treves, A. B. Packard<br />
9:50 Intermission<br />
10:10 112. Microwave-assisted [ 18 F]fluorination<br />
of fatty acid analog PET probes.<br />
A. P. Belanger, M. Pandey,<br />
T. R. DeGrado<br />
10:30 113. Rapid 11 C-methylation of sluggishly<br />
reactive arylamines, pyrroles, and<br />
amides with [ 11 C]methyl iodide under the<br />
influence of solid bases and ultrasound.<br />
L. Cai, R. Xu, S. Guo, V. W. Pike<br />
10:50 114. Synthesis and positron emission<br />
tomography studies of three C-11 labeled<br />
carboxylic acid drugs, [ 11 C]butyric acid,<br />
[ 11 C]valporic acid, [ 11 C]4-phenylbutyric<br />
acid. S. Kim, J. M. Hooker, D. Alexoff,<br />
N. Otto, K. Win, N. Volkow, J. S. Fowler<br />
11:10 115. HDAC imaging probes for<br />
positron emission tomography.<br />
H. V. Diyabalanage,J.M.Hooker<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
New Directions in Isotope Production,<br />
Nuclear Forensics and Radiochemistry<br />
Isotope Production Financially supported by<br />
U.S. Department of Energy<br />
D. Phillips, Organizer, Presiding<br />
M. Lagunas-Solar, S. Mirzadeh, Presiding<br />
1:30 Introductory Remarks<br />
1:35 116. Development of high specific activity<br />
radionuclides. S. S. Jurisson,<br />
C. Cutler, A. Ketring, F. M. Nortier,<br />
J. Kitten, W. Taylor, K. John,<br />
M. Fassbender<br />
1:50 117. New research program for medical<br />
radioisotope production at the Cyclotron<br />
Institute, Texas A&M University.<br />
A. A. Alharbi, M. McCleskey, A. Spiridon,<br />
B. Roeder, E. Simmons, A. Azzam,<br />
A. Banu, G. Tabacaru, V. Goldberg,<br />
L. Trache, R. E. Tribble<br />
2:05 118. Development of innovative radioactive<br />
isotope production techniques at<br />
the Pennsylvania State University Radiation<br />
Science and Engineering Center.<br />
K. Ünlü, B. Heidrich<br />
2:20 119. Burn-up cross-sections of reactor<br />
produced medical and industrial radioisotopes.<br />
S. Mirzadeh, M. Garland, R. Boll,<br />
R. Knapp<br />
2:35 120. Recovery and purification of zirconium-93<br />
from special high-burnup targets.<br />
M. Du, C. W. Alexander<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
NUCL<br />
TECH–83
NUCL/ORGN <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
2:50 121. Reactor-based fission production<br />
of Molybdenum-99 from LEU solution targets.<br />
M. C. Lagunas-Solar<br />
3:05 Intermission<br />
3:20 122. Subcritical hybrid intense neutron<br />
emitter (SHINE): An innovative method to<br />
produce 99 Mo. G. R. Piefer<br />
3:35 123. 122 Xe/ 122 I Generator development:<br />
Short-lived PET isotope availability.<br />
J. P. O’Neil, T. F. Buddinger<br />
3:50 124. Compact, low-cost radioisotope<br />
production with electromagnetic particle<br />
accelerators. G. B. Rieker,<br />
F. Poehlmann, M. Cappelli<br />
4:05 125. Isotope production for medical<br />
usage Fast neutron reactions in JAEA.<br />
Y. Hatsukawa<br />
4:20 126. Novel nucleosynthesis for medical<br />
isotopes. C. Tahan<br />
4:35 127. Electromagnetic systems for production<br />
of stable isotopes. A. Wong,<br />
G. Paskalov, R. McCaughey, R. Wang,<br />
J. Chen<br />
THURSDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 109B<br />
Aqueous Chemistry and Thermodynamics<br />
of Actinides and Fission Products: A Tribute<br />
to Volker Neck<br />
H. Nitsche, H. Geckeis, T. Fanghänel<br />
(Fanghaenel), Organizers<br />
A. Felmy, M. Altmaier, Presiding<br />
8:00 128. Solubility, surface charge, ion adsorption<br />
and dissolution/precipitation kinetics<br />
of oxides in hydrothermal solutions.<br />
D. J. Wesolowski<br />
8:30 129. Redox transformations of PuO 2�x<br />
induced by Fe(II): Importance of the Fe(III)<br />
reaction product. A. R. Felmy,<br />
S. D. Conradson, E. S. Ilton<br />
9:00 130. Radiation assisted reactions at a<br />
PuO 2 - water interface. A. Seibert,<br />
T. Gouder, F. Huber<br />
9:30 131. Radiation effects on the separation<br />
of technetium-99 by macrocompounds.<br />
A. Roman, K. Campbell,<br />
E. Brown, A. Nunez, a. Espartero,<br />
P. Paviet-Hartmann<br />
9:50 132. Withdrawn<br />
10:10 133. Nitric acid radiation effects on<br />
solvent extraction chemistry.<br />
T. D. Cullen, S. P. Mezyk, G. Elias,<br />
B. J. Mincher<br />
10:30 Intermission<br />
10:45 134. Some reflections and thoughts<br />
after 25 years developing thermodynamic<br />
data bases for nuclear waste management<br />
and other environmental applications.<br />
J. Bruno,L.Duro<br />
11:15 135. THEREDA: The thermodynamic<br />
reference database for nuclear waste disposal<br />
in Germany. H. C. Moog,<br />
H. Herbert, V. Brendler, A. Richter,<br />
M. Altmaier, C. Marquardt, W. Voigt,<br />
S. Wilhelm<br />
11:35 136. Investigation of the radiolytic stability<br />
of DTPA under TALSPEAK conditions.<br />
D. K. Gaskins, S. P. Mezyk,<br />
L. R. Martin<br />
11:55 137. Mixed-ligands complexes of<br />
trivalent Am 3� ,Cm 3� and Eu 3� with<br />
HEDTA�NTA-complexation thermodynamics<br />
and structural aspects.<br />
P. Thakur, G. R. Choppin, J. L. Conca<br />
12:15 Concluding Remarks<br />
84–TECH<br />
‡ Cooperative Cosponsorship<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
Applications of Radionuclides in Imaging<br />
and Therapy<br />
Multimodality, Therapy, and Other<br />
A. Packard, M. Lewis, Organizers,<br />
Presiding<br />
9:00 138. Multimodal imaging probes for fibrin.<br />
R. Uppal, P. Caravan<br />
9:20 139. Radiolabeled Sonic Hedgehog as<br />
a ligand targeting cancer stem cells.<br />
I. Tworowska, J. Sims-Mourtada<br />
9:40 140. Selection of small pretargeting<br />
molecules with affinity for radiochelates.<br />
N. Sisay, S. S. Jurisson, G. P. Smith<br />
10:00 Intermission<br />
10:15 141. In vitro and in vivo evaluations of<br />
177 Lu antisense radiotherapy in B-cell<br />
non-Hodgkin’s lymphoma. E. R. Balkin,<br />
F. Jia, W. H. Miller, M. R. Lewis<br />
10:35 142. Radioiodinated maleimide derivatives<br />
targeting peripheral and membrane<br />
sulfhydryl groups for in vitro cell labeling.<br />
J. K. Amartey<br />
10:55 143. Successful multimodality nuclear<br />
and fluorescent tumor imaging in mice<br />
using a streptavidin nanoparticle.<br />
d. j. hnatowich, M. Liang, X. Liu,<br />
D. Cheng, G. Liu, S. Dou, Y. Wang,<br />
M. Rusckowski<br />
THURSDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 109A<br />
Applications of Radionuclides in Imaging<br />
and Therapy<br />
Radiometals: Imaging<br />
A. Packard, M. Lewis, Organizers,<br />
Presiding<br />
1:00 144. Radiolabeled peptides for PET imaging:<br />
The impact of the bifunctional chelator.<br />
C. L. Ferreira, D. T. Yapp, R. Gill,<br />
C. Bensimon, P. Jurek, G. Kiefer<br />
1:20 145. microPET imaging of integrin � 2� 1<br />
expression using 64 Cu-labeled DGEA<br />
peptides. C. Huang, Z. Li,H.Cai,<br />
K. Chen, R. Park, T. Shahinian,<br />
P. S. Conti<br />
1:40 146. Comparative study of 64 Cu and<br />
67 Ga-bombesin antagonists as potential<br />
agents for prostate cancer imaging.<br />
P. K. Nanda, U. Pandey, B. N. Bottenus,<br />
S. R. Lane, T. L. Rold, G. L. Sieckman,<br />
T. J. Hoffman, C. J. Smith<br />
2:00 Intermission<br />
2:20 147. Highly stable functionalizable chelator<br />
for gallium isotopes. E. Boros,<br />
C. L. Ferreira, J. F. Cawthray, E. W. Price,<br />
D. W. Wester, M. J. Adam, C. Orvig<br />
2:40 148. Human islet cell imaging in mice<br />
by pretargeting using a DNA analog<br />
(MORF) conjugated antibody and a radiolabeled<br />
cMORF. G. Liu,S.Dou,<br />
D. Cheng, J. Leif, M. Rusckowski,<br />
P. Streeter, L. D. Shultz, D. L. Greiner,<br />
D. J. Hnatowich<br />
3:00 149. Targeting the prostate specific<br />
membrane antigen in prostate cancer<br />
with Tc-99m phosphoramidate inhibitors.<br />
P. D. Benny, J. Byers, M. Jabbes,<br />
C. Berkman, J. N. Bryan<br />
3:20 150. One-pot synthesis of trifunctional<br />
Tc-99m radioconjugates by click chemistry.<br />
T. L. Mindt, H. Struthers, B. Spingler,<br />
E. Garcia-Garayoa, D. Tourwé, R. Schibli<br />
ORGN<br />
Division of Organic<br />
Chemistry<br />
A. Abdel-Magid and S. Sieburth,<br />
Program Chairs<br />
OTHER SYMPOSIA OF INTEREST:<br />
Academic Employment Initiative (see<br />
AEI, Mon)<br />
Synthetic Chemistry for Biological<br />
Imaging, Quantitation, and Discovery<br />
(see BIOL, Sun)<br />
Natural Products Biosynthesis (see<br />
BIOL, Tue)<br />
Advances in Teaching Organic<br />
Chemistry (see CHED, Tue)<br />
Chemistry and Policy: Solving<br />
Problems at the Interface (see CHED,<br />
Mon)<br />
Undergraduate Research Posters:<br />
Organic Chemistry (see CHED, Mon)<br />
SOCIAL EVENTS:<br />
Social Hour, 8:00 PM: Sun<br />
Organic & Medicinal Chemistry<br />
Divisions Joint Poster Session &<br />
Social Event, 7:00 PM: Wed<br />
Tetrahedron Award Reception, 5:30<br />
PM: Mon<br />
Arthur C. Cope Award & Arthur C.<br />
Cope Scholars’ Awards Reception,<br />
5:30 PM: Tue<br />
BUSINESS MEETING:<br />
Business Meeting, 5:00 PM: Sun<br />
SUNDAY MORNING<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 206A<br />
New Reactions and Methodology<br />
S. Sieburth, Organizer<br />
L. Anderson, Presiding<br />
8:00 1. Hydroxyl group directed copper/<br />
selectfluor-activated C-H bond amination.<br />
Z. Jin, J. C. Aponte, B. Xu,<br />
G. B. Hammond<br />
8:20 2. Recent advances in organic synthesis<br />
using real-time in situ FTIR (fourier<br />
transform infrared spectroscopy).<br />
D. Hebrault<br />
8:40 3. Multidimensional screening and<br />
methodology development of condensations<br />
involving complex 1,2-diketones.<br />
J. R. Goodell, A. B. Beeler, J. A. Porco,<br />
Jr.<br />
9:00 4. Water overcomes methyl group directing<br />
effects in endo-selective epoxideopening<br />
cascades. C. J. Morten,<br />
T. F. Jamison<br />
9:20 5. Preactivated unsymmetrical diboron:<br />
Catalytic regioselective boration of �,�unsaturated<br />
conjugated compounds.<br />
W. L. Santos,G.Ming,S.B.Thorpe<br />
9:40 6. TEMPO-coated Fe 3O 4 superparamagnetic<br />
nanoparticles: A recyclable catalyst<br />
for selective oxidation of alcohols.<br />
A. K. Tucker-Schwartz, R. L. Garrell<br />
10:00 7. N-triflylphosphoramides: From synthesis<br />
and applications in organocatalysis<br />
towards combined metal-Brønsted acid<br />
catalysis. R. M. Koenigs, M. Rueping<br />
10:20 8. C-H bonds as ubiquitous functionality:<br />
A general approach to complex imidazoles<br />
via regioselective sequential<br />
arylation of all three C-H bonds and regioselective<br />
N-alkylation of SEM-imidazoles.<br />
J. Joo, B. Touré, D. Sames<br />
10:40 9. Halogenation of hydrocarbon substrates<br />
with peracetic acid and halide<br />
salts. Y. He, C. R. Goldsmith<br />
11:00 10. Oxidative coupling reactions: New<br />
methods for the synthesis of carbogenic<br />
molecules. L. C. Konkol,R.J.Thomson<br />
11:20 11. Metal-free syn-dihydroxylation of<br />
alkenes. S. Picon,N.C.Tomkinson<br />
11:40 12. Greater than 99% site-isolation of<br />
phosphines and Pd using polydicyclopentadiene<br />
membranes. A. Gupta,<br />
N. B. Bowden<br />
12:00 13. Using catalytic scaffolding ligands<br />
for regio- and enantioselective hydroformylation.<br />
A. Worthy,C.Joe,K.Tan<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 203<br />
Peptides, Proteins and Amino Acids<br />
S. Sieburth, Organizer<br />
J. Gao, Presiding<br />
8:00 14. Iterative elongation of small peptides<br />
for developing capture agents via<br />
reliable screening. J. Lim, J. Cha, S. Tan,<br />
Y. Zheng, Y. Ang, S. Lee<br />
8:20 15. Lanthanide sensitization and fluorescent<br />
sensing of A/T-rich DNA sequences<br />
and oncogenic bZIP transcription<br />
factors. E. Pazos, M. I. Sánchez,<br />
J. Mosquera, C. Penas, J. L. Mascareñas,<br />
M. Vázquez<br />
8:40 16. High throughput screening of cyclic<br />
peptides library to identify inhibitors<br />
against calcineurin/NFAT interaction.<br />
T. Liu,D.Pei<br />
9:00 17. Use of triazole-stapled BCL9/B9L<br />
�-helical peptides to target �-catenin and<br />
inhibit Wnt signaling. S. A. Kawamoto,<br />
A. Coleska, X. Ran, H. Yi, C. Yang,<br />
S. Wang<br />
9:20 18. Peptide-surface interactions.<br />
J. L. Kulp III, K. P. Fears,<br />
D. Y. Petrovykh, T. D. Clark<br />
9:40 19. Rationally designed cyclic sulfopeptides<br />
for HIV-1 entry inhibition.<br />
J. G. Rudick, M. M. Laakso, R. W. Doms,<br />
W. F. DeGrado<br />
10:00 20. Translocating membrane-impermeable<br />
toxins into cancer cells: pHLIPmediated<br />
delivery of phalloidin inhibits<br />
cell proliferation. M. An, D. Wijesinghe,<br />
O. A. Andreev, Y. K. Reshetnyak,<br />
D. M. Engelman<br />
10:20 21. Evolved aminoacyl-tRNA synthetases<br />
with unusual polyspecificities.<br />
D. D. Young, T. S. Young, I. Ahmad,<br />
P. G. Schultz<br />
10:40 22. Using NMR to characterize small<br />
selectively thionated pseudopeptides.<br />
W. M. Vizcaino, S. M. Schelble<br />
11:00 23. Application of thioacids in the<br />
chemical ligation of peptides. I. Sharma,<br />
D. Crich<br />
11:20 24. Formation of the 5,6-dihydrouridin-6-yl<br />
radical in RNA results in direct<br />
strand scission. M. J. Resendiz,<br />
A. C. Jacobs, M. M. Greenberg*<br />
11:40 25. Studying peptide aggregation with<br />
a series of phosphopeptide variants.<br />
N. M. Valette, S. E. Radford, S. A. Harris,<br />
S. L. Warriner<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
12:00 26. Semisynthesis of chemically modified<br />
antibody fragments and glycoproteins<br />
with multiple N-linked glycosylation<br />
sites. T. J. Tolbert<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 204B<br />
Asymmetric Reactions and Syntheses<br />
S. Sieburth, Organizer<br />
M. Bergdahl, Presiding<br />
8:00 27. Isothiourea-mediated stereoselective<br />
C-acylation of silyl ketene acetals.<br />
P. A. Woods, R. A. Bragg, A. D. Smith<br />
8:20 28. Tertiary amine-Lewis acid cooperative<br />
asymmetric catalysis. D. J. Dixon,<br />
F. Sladojevich, T. Yang, A. Ferrali<br />
8:40 29. Asymmetric synthesis of substituted<br />
homotropinone alkaloids from acyclic<br />
N-sulfinyl �-amino ketone ketals.<br />
F. A. Davis, R. Edupuganti<br />
9:00 30. Determination of the relative importance<br />
of Lewis-acid and Lewis-base catalysis<br />
in asymmetric catalysis using bifunctional<br />
catalysts. M. North,<br />
M. Omedes-Pujol, C. Williamson<br />
9:20 31. Asymmetric �-methoxyallylboration<br />
of ketones with the B-[(Z)-g-methoxyallyl]-10-phenyl-9-borabicyclo[3.3.2]<br />
decanes. L. A. Seda, J. A. Soderquist<br />
9:40 32. Reagent control in asymmetric allenylboration<br />
of nonracemic �-amino aldehydes<br />
with the 10-TMS-9-borabicyclo<br />
[3.3.2]decanes. J. M. Guzman,<br />
J. A. Soderquist<br />
10:00 33. Scaffolding ligands: A method for<br />
controlling regio- and stereochemistry in<br />
hydroformylation. K. Tan<br />
10:20 34. Synthesis of enantiomerically pure<br />
1,3-aminoalcohols through organo-, organometallic,<br />
and enzymatic catalysis.<br />
A. M. Träff, R. Millet, M. L. Petrus,<br />
J. Bäckvall<br />
10:40 35. Development of an asymmetric<br />
Michael-Benzoin cascade for the synthesis<br />
of functionalized cyclopentanones.<br />
K. E. Ozboya, T. Rovis<br />
11:00 36. Highly enantioselective phase<br />
transfer reactions with new cinchonium<br />
salts. B. A. Provencher,L.Deng<br />
11:20 37. Efficient preparation of chiral<br />
N-aryl �-amino acids. P. Hermsen,<br />
G. Busscher, L. Lefort, A. de Vries,<br />
H. de Vries<br />
11:40 38. Catalytic methods for enantioselective<br />
C–F bond formation with fluoride<br />
sources. A. Doyle<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 204A<br />
Total Synthesis of Complex Molecules<br />
S. Sieburth, Organizer<br />
G. Florence, Presiding<br />
8:20 39. Development of a unified synthetic<br />
strategy to the polyprenylated acylphloroglucinols.<br />
Q. Zhang, J. A. Porco<br />
8:40 40. Total synthesis of the Lycopodium<br />
alkaloid (�)-sieboldine A. S. M. Canham,<br />
D. J. France, L. E. Overman<br />
9:00 41. Piperazic acids in natural products:<br />
Synthetic studies towards chloptosin and<br />
lydiamycin. A. J. Oelke, D. J. France,<br />
G. Wuitschik, T. Hofmann, S. V. Ley<br />
9:20 42. Toward the total synthesis of the<br />
brasilinolides. C. J. Cordier,<br />
M. P. Housden, P. M. Burton,<br />
F. A. Mühlthau, O. Loiseleur, I. Paterson<br />
9:40 43. Total synthesis of (-)-virginiamycin<br />
M 2 using atom-economical and chemoselective<br />
approaches. J. Wu<br />
10:00 44. Studies toward the total synthesis<br />
of dideoxy lomaiviticinone.<br />
A. Baranczak, G. A. Sulikowski<br />
10:20 45. Asymmetric catalytic formal synthesis<br />
of the anti-angiogenic polyketide<br />
(–)-Borrelidin. A. V. Madduri,<br />
A. J. Minnaard<br />
10:40 46. Progress toward the synthesis of<br />
the parnafungins. Q. Zhou,B.B.Snider<br />
11:00 47. Total synthesis of (�)-SCH<br />
351448. K. Zhu<br />
11:20 48. Synthesis, characterisation, and in<br />
vitro cytotoxic activitiy of some Ru(II)<br />
complexes. S. Thota, s. s. karki,<br />
E. d. clercq, j. balzarini<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 207<br />
Physical Organic Chemistry: Calculations,<br />
Mechanisms, Photochemistry and High-<br />
Energy Species<br />
S. Sieburth, Organizer<br />
R. McCulla, Presiding<br />
8:20 49. 2-Anthryltriazolyl-containing multidentate<br />
ligands: Zinc-coordination mediated<br />
photophysical processes and thier<br />
potential application in live-cell imaging.<br />
H. A. Michaels,L.Zhu<br />
8:40 50. How solvent modulates hydroxyl<br />
radical reactivity in hydrogen atom abstractions.<br />
S. Mitroka, S. Zimmeck,<br />
D. Troya, J. M. Tanko<br />
9:00 51. Challenges posed to bornyl diphosphate<br />
synthase: Diverging reaction mechanisms<br />
in monoterpenes. D. T. Major,<br />
M. Weitman<br />
9:20 52. Insights into the formation and<br />
isomerization of the benzene metabolite<br />
muconaldehyde and related molecules:<br />
Comparison of computational and experimental<br />
studies of simple, benzo-annelated,<br />
and bridged 2,3-epoxyoxepins.<br />
J. P. Morgan, A. Greenberg<br />
9:40 53. Inverse isotope effect in the Co catalyzed<br />
synthesis of hydrocarbons from<br />
CO and H 2. B. Shi,C.Jin<br />
10:00 54. Computational approach to predicting<br />
gas diffusion in organic cages.<br />
D. Holden, A. Trewin, A. Cooper<br />
10:20 55. Isomerization of cis-1,2-dimethylcyclohexane<br />
in shock tube experiments.<br />
C. M. Rosado-Reyes, W. Tsang<br />
10:40 56. Fluorinated acid amplifiers improve<br />
high resolution imaging.<br />
S. A. Kruger, C. Higgins, B. Cardineau,<br />
R. L. Brainard<br />
11:00 57. Modeling the localization of excitations<br />
in poly-phenylacetylene based<br />
dendrimers. Y. Shin,X.Lin<br />
11:20 58. Marcus theory for hydride transfer<br />
reactions between heteroaromatic compounds.<br />
I. H. Lee<br />
11:40 59. Development and synthesis of<br />
corannulene-based organic light emitters.<br />
D. R. Jones,J.Mack<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 205A/B<br />
Young Investigators<br />
D. Huryn, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 60. Efficient and practical synthesis of<br />
GSK812397, an HIV drug candidate.<br />
V. I. Elitzin<br />
8:55 61. Synthesis and evaluation of NO donor<br />
containing carbonic anhydrase inhibitors.<br />
Q. Huang,M.Cobbs,D.M.Dinh,<br />
H. Gukasyan, J. A. Lafontaine, S. Mehta,<br />
B. D. Patterson, P. F. Richardson,<br />
E. Y. Rui<br />
9:15 62. DNA-programmed chemistry approaches<br />
to macrocyclic lead compounds.<br />
A. W. Fraley<br />
9:35 63. Synthesis of pyridyl amine ligands<br />
for catalyzed ethylene oligomerization.<br />
C. A. Faler<br />
9:55 64. Design and synthesis of novel<br />
�-secretase (BACE) inhibitors.<br />
R. D. Mazzola Jr., S. Babu, J. Caldwell,<br />
X. Chen, J. Cumming, M. Czarniecki,<br />
J. Duo, J. Durkin, W. J. Greenlee, H. Gu,<br />
T. Guo, R. Hunter, U. Iserloh,<br />
M. E. Kennedy, J. Kong, R. Kuvelkar,<br />
L. Hyde, P. Leach, V. Madison,<br />
B. A. Mckittrick, T. Le, T. Meng,<br />
J. Misiaszek, J. Pan, E. Parker, G. Qian,<br />
K. Saionz, A. Stamford, C. Strickland,<br />
D. Tadesse, J. Voigt, L. Wang, J. Wong,<br />
Y. Wu, J. Zhao, Z. Zhu, G. Li, Y. Huang,<br />
Y. Ye, K. Cox, L. Favreau, D. Wyss,<br />
Y. Wang, Z. Sun<br />
10:15 Intermission<br />
10:25 65. Development of an efficient palladium-catalyzed<br />
intramolecular carbometalation<br />
reaction for the synthesis of a<br />
dibenzoxapine-containing tetrasubstituted<br />
exocyclic alkene. H. Yu,<br />
R. N. Richey<br />
10:45 66. Peptide mimetics disrupting protein-protein<br />
interactions discovered by<br />
post-solid phase modifications. F. Liu,<br />
A. G. Stephen, A. A. Waheed, J. Park,<br />
R. J. Fisher, K. S. Lee, E. O. Freed,<br />
T. R. Burke<br />
11:05 67. Asymmetric hydrogenation of unprotected<br />
N-H ketoimines. F. Gosselin<br />
11:25 68. Synthetic ligands (synbodies):<br />
Synthetic alternatives to antibodies.<br />
N. Gupta, P. E. Belcher, M. Shah,<br />
P. Stafford, C. W. Diehnelt,<br />
J. J. Rajasekaran, S. A. Johnston<br />
11:45 69. Practial arene metallation chemistry.<br />
M. M. Bio<br />
12:05 Concluding Remarks<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom East<br />
Symposium in Memory of Keith Fagnou<br />
T. Rovis, Organizer<br />
G. Hughes, Organizer, Presiding<br />
8:50 Introductory Remarks<br />
8:55 70. Mechanistic aspects of cross-coupling<br />
reactions that form C-C bonds.<br />
J. F. Hartwig, B. P. Carrow, Z. Huang,<br />
Y. Tan<br />
9:40 71. High oxidation state palladium in<br />
catalysis. M. Sanford<br />
10:25 72. Pd(II)/Pd(0) catalysis: A promising<br />
platform for versatileC-Hfunctionalizations.<br />
J. Yu<br />
11:10 73. Mechanism of the hydrolytic kinetic<br />
resolution reaction. E. N. Jacobsen<br />
SUNDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 205A/B<br />
Chemistry for Preventing and Combating<br />
Disease<br />
S. Sieburth, Organizer<br />
X. Qian, Presiding<br />
1:00 74. Insights and applications of using<br />
various aryl-azido compounds for the inactivation<br />
of human immunodeficiency virus<br />
(HIV-1): Towards the generation of a<br />
novel inactivated vaccine strategy.<br />
J. M. Belanger, Y. Raviv, M. Viard,<br />
J. W. Bess, R. Blumenthal<br />
1:20 75. Enhanced radical scavenging activities<br />
of catechin derivatives incorporating<br />
basic amino acids. K. Fukuhara,<br />
I. Nakanishi, K. Imai, A. Ohno, K. Ohkubo,<br />
S. Fukuzumi, A. Nakamura, K. Anzai,<br />
N. Miyata, H. Okuda<br />
1:40 76. Nitric oxide releasing nanoparticles:<br />
A topical therapeutic strategy for the<br />
treatment of superficial and deep soft tissue<br />
infections. A. Friedman,G.Han,<br />
L. Martinez, M. Mihu, J. Nosanchuk,<br />
J. Friedman<br />
2:00 77. Therapeutic strategies based on<br />
siderophores: Iron out Pseudomonas<br />
aeruginosa infections with synthetic<br />
pyochelin? S. Noël, F. Rivault, L. Guillon,<br />
F. Hoegy, V. Gasser, D. Rognan,<br />
I. J. Schalk, G. L. Mislin<br />
2:20 78. Multifuntional porphyrinoids for simultanious<br />
breast cancer detection, imaging,<br />
and therapy. C. M. Drain<br />
2:40 79. Anti-parasitic activity of a bisphosphonamidate<br />
clodronate prodrug.<br />
C. L. Freel Meyers, M. Webster, S. Tang,<br />
T. Shapiro<br />
3:00 80. Chiral surfaces that resist biofouling.<br />
D. Bandyopadhyay, P. Sejwal,<br />
D. Prashar, Y. Y. Luk<br />
3:20 81. Fiber optic device for targeted singlet<br />
oxygen delivery for potential application<br />
in human diseases such as brain tumors.<br />
M. Zamadar, G. Ghosh,<br />
D. Aebisher, M. Alqaim, A. Greer<br />
3:40 82. NMR studies on the mutagenic<br />
nucleosides that can cause viral decay<br />
acceleration of HIV. D. Li,<br />
J. M. Essigmann<br />
4:00 83. New routes to functional adenosine<br />
A 2A receptor antagonists. R. Thomas,<br />
M. Sitkovsky, G. B. Jones<br />
4:20 84. Enantioselective synthesis of a<br />
drug for a low price using open science.<br />
M. Wölfle,M.H.Todd<br />
4:40 85. Converting C-H to C-C bonds: Synthesis<br />
of veratramine. D. F. Taber,<br />
J. F. Berry, P. W. DeMatteo<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 206A<br />
New Reactions and Methodology<br />
S. Sieburth, Organizer<br />
N. Bowden, Presiding<br />
1:00 86. Vinylogous aldol products from<br />
chiral crotylsilanes obtained by carbenoid<br />
Si-H insertion. J. Wu<br />
1:20 87. (E)-Enolate equivalents from<br />
alkynes using tandem catalysis: Development<br />
of an anti-selective aldol reaction.<br />
L. K. Chan,M.J.Gaunt<br />
1:40 88. Aqueous Wittig reactions: Highly<br />
stereoselective, chemoselective, organic<br />
solvent and protecting group-free synthesis<br />
of functionalized alkenes. P. Das,<br />
J. McNulty<br />
2:00 89. Di-fluorous tagging strategy for the<br />
automated solution-phase synthesis of<br />
plant oligosaccharides.<br />
S. K. Nagappayya, H. Edwards,<br />
N. L. Pohl<br />
2:20 90. Gold catalyzed cyclization of<br />
propargylic esters with enones to give<br />
Rauhut-Currier type products.<br />
J. W. Cran, M. E. Krafft<br />
2:40 91. Strecker and Mannich reactions of<br />
�-amido p-tolylsulfones. S. T. Kadam,<br />
S. Kim<br />
3:00 92. Pyrazolidin-3-ones as a new scaffold<br />
for iminium ion organocatalysis.<br />
E. R. Gould, A. D. Smith, M. Reid<br />
3:20 93. Iterative metal-catalyzed C-H bond<br />
functionalization for complex natural<br />
product synthesis. L. McMurray,<br />
E. M. Beck, M. J. Gaunt<br />
3:40 94. Nickel-catalyzed stereoselective<br />
formation of 1,2-cis-2-amino-2-deoxy<br />
glucosides and galactosides.<br />
E. A. Mensah, H. M. Nguyen<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ORGN<br />
TECH–85
ORGN <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
4:00 95. Catalytic enantioselective dearomatization:<br />
A strategy for the rapid generation<br />
of non-racemic complex molecular<br />
architecture. A. E. Williamson,<br />
M. J. Gaunt<br />
4:20 96. Copper-catalyzed meta-selective<br />
direct arylation of �-arylacetamides.<br />
R. E. Gilligan, H. A. Duong, M. J. Gaunt<br />
4:40 97. Two-carbon homologation of ketones<br />
to 3-methyl unsaturated aldehydes.<br />
R. J. Petroski, K. Vermillion<br />
5:00 98. Intermolecular aryne insertion into<br />
the C-O bonds of carboxylic acids.<br />
A. V. Dubrovskiy, R. C. Larock<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 203<br />
Peptides, Proteins and Amino Acids<br />
S. Sieburth, Organizer<br />
T. Tolbert, Presiding<br />
1:00 99. Staudinger reactions with unsymmetrical<br />
phosphites: Applications to the<br />
synthesis of phosphoramidate-linked glycopeptides<br />
and the functionalization of<br />
proteins. C. P. Hackenberger<br />
1:20 100. Rational design of functional macromolecular<br />
bis-peptides.<br />
C. E. Schafmeister, Z. Brown, M. Parker,<br />
K. Akula, M. Jackson<br />
1:40 101. Synthesis and application of porphyrin-peptide-conjugates<br />
in photodynamic<br />
inactivation of bacteria. E. Feese,<br />
R. A. Ghiladi<br />
2:00 102. Targeted photodynamic therapy<br />
of leukemia T cells using dual-surface<br />
modified virus capsids.<br />
N. Stephanopoulos,G.J.Tong,<br />
S. C. Hsiao, M. B. Francis<br />
2:20 103. Genome-free viral capsids as multivalent<br />
carriers for taxol delivery. W. Wu,<br />
S. C. Hsiao, K. Wai, M. B. Francis<br />
2:40 104. Protein modification for enhanced<br />
activities and targeted drug delivery.<br />
D. Prashar, D. Cui, Y. Shi,<br />
D. Bandyopadhyay, J. Dabrowiak,<br />
Y. Y. Luk<br />
3:00 105. Water-driven reactions for protein<br />
modification without side products.<br />
Y. Y. Luk, D. Cui, D. Prashar<br />
3:20 106. Exon-encoded polypeptides as<br />
primordial enzymes. Y. Ivanova,<br />
D. Pamuk, K. Kumar<br />
3:40 107. Self-assembly of cyclic peptides<br />
and potential application as molecular<br />
transporters. D. Mandal, K. Parang<br />
4:00 108. Energetic contribution of fluorinated<br />
aromatics to protein stability.<br />
J. Gao, H. Zheng, C. Pace<br />
4:20 109. Protein core packing by dynamic<br />
combinatorial chemistry. M. A. Case,<br />
L. Roy<br />
4:40 110. Structure and compositional analysis<br />
of polymeric active ingredients for<br />
drug delivery applications using advanced<br />
detection size-exclusion chromatography.<br />
J. Sanchez<br />
5:00 111. Comparison study of cyclic and<br />
linear peptoid libraries for high throughput<br />
screening. Y. Gao, T. Kodadek<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 204A<br />
Total Synthesis of Complex Molecules<br />
86–TECH<br />
S. Sieburth, Organizer<br />
S. Rasapalli, Presiding<br />
1:00 112. Intramolecular alpha–glucosaminidation:<br />
Synthesis of mycothiol.<br />
S. Knapp, K. Ajayi, V. V. Thakur,<br />
R. C. Lapo<br />
‡ Cooperative Cosponsorship<br />
1:20 113. Structural assignment and total<br />
synthesis of Gephyronic acid. L. Nicolas,<br />
T. Anderl, L. Sabine, R. E. Taylor<br />
1:40 114. Defining the stereochemical configuration<br />
of chamuvarinin via synthesis.<br />
G. J. Florence<br />
2:00 115. Progress toward the total synthesis<br />
of Sch 47554. B. W. Slafer,<br />
A. G. Barrett, M. Espensen, O. Niemeier<br />
2:20 116. Efforts toward the total synthesis<br />
of leiodelide A. M. F. Chellat, N. Proust,<br />
M. G. Lauer, J. P. Stambuli<br />
2:40 117. Bromonium-initiated epoxideopening<br />
cascades and its application for<br />
the total synthesis of ent-dioxepandehydrothyrsiferol.<br />
J. Tanuwidjaja,S.Ng,<br />
T. F. Jamison<br />
3:00 118. Towards the total synthesis of<br />
Agariblazeispirol C. L. C. Paterson,<br />
W. J. Kerr, A. Sutherland<br />
3:20 119. Highlights on the way to the first<br />
total synthesis of Pl-3. C. R. Lentsch,<br />
R. Fürst, U. Rinner<br />
3:40 120. Toward the first total synthesis of<br />
Pl-4 – a jatrophane dipterpene with remarkable<br />
multidrug resistant reversal<br />
(MDR) effect. R. Fürst, U. Rinner<br />
4:00 121. Synthesis of (�)-eusynstyelamide<br />
A. O. V. Barykina,B.B.Snider<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 204B<br />
Asymmetric Reactions and Syntheses<br />
S. Sieburth, Organizer<br />
S. Singh, Presiding<br />
1:00 122. Synthesis of stereochemically diverse<br />
2-pyrrolines through a novel Ag<br />
catalyzed [3�2] cycloaddition.<br />
J. A. Bishop, S. E. Schaus<br />
1:20 123. Copper-catalyzed regio- and enantioselective<br />
formal conjugate addition<br />
of Grignard reagents to �,�-unsaturated<br />
aldehydes. M. Fañanás Mastral,<br />
B. L. Feringa<br />
1:40 124. Investigation of the scope and<br />
mechanism of the palladium-catalyzed<br />
synthesis of enantioenriched allylic esters<br />
from prochiral (Z)-allylic alcohols.<br />
J. S. Cannon, S. F. Kirsch,<br />
L. E. Overman, H. F. Sneddon<br />
2:00 125. Catalytic enantioselective Saucey<br />
Marbet Claisen rearrangement of heterocyclic<br />
substrates. T. Cao,<br />
M. C. Kozlowski<br />
2:20 126. Asymmetric organocatalytic allylation<br />
of acetals. R. M. Gleixner,L.R.Cox<br />
2:40 127. Discovery and development of the<br />
Sc(III)-catalyzed homologation of cycloalkanones<br />
with substituted diazomethanes.<br />
D. C. Moebius, V. L. Rendina,<br />
J. S. Kingsbury<br />
3:00 128. Asymmetric Diels-Alder reaction<br />
with a new bifunctional cinchona alkaloid<br />
catalyst. K. J. Bartelson, R. P. Singh,<br />
L. Deng<br />
3:20 129. (E)-2-Boryl-1,3-butadiene derivatives<br />
of the 10-TMS-9-BBDs: Highly selective<br />
reagents for the asymmetric synthesis<br />
of anti-1,2-disubstituted 3,4pentadien-1-amines.<br />
J. R. Gonzalez,<br />
J. A. Soderquist<br />
3:40 130. Asymmetric allylic alkylations with<br />
preformed ketone and lactone enolates<br />
and doubly deprotonated carboxylic acids.<br />
M. Braun, P. Meletis<br />
4:00 131. Chiral boronate derivatives via<br />
catalytic enantioselective conjugate addition<br />
of Grignard reagents on 3-boronyl<br />
unsaturated esters and thioesters.<br />
J. C. Lee,D.G.Hall<br />
4:20 132. Override of substrate reactivity in<br />
highly enantioselective regiodivergent<br />
ring opening reactions of [2.2.1] oxabicyclic<br />
alkenes: Applications to practical API<br />
synthesis. R. Webster, N. Nguyen,<br />
A. Boyer, C. Boeing, M. Lautens<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 207<br />
Physical Organic Chemistry: Calculations,<br />
Mechanisms, Photochemistry and High-<br />
Energy Species<br />
S. Sieburth, Organizer<br />
W. Dichtel, Presiding<br />
1:00 133. Molecular force probes for studying<br />
reaction kinetics under force.<br />
R. Boulatov, T. J. Kucharski<br />
1:20 134. Mechanistic large scale industrial<br />
catalysis: Regioselectivity control in arene<br />
substitution. C. Kring, F. Windlin,<br />
P. Hofmann<br />
1:40 135. Mechanistic investigations into<br />
the role of water in regioselective epoxy<br />
alcohol cyclizations in aqueous media.<br />
J. A. Byers, T. F. Jamison<br />
2:00 136. Quantum chemical studies on the<br />
photochemistry of nitro-aromatic explosives.<br />
J. Quenneville, D. S. Moore<br />
2:20 137. Mechanistic studies of lithium<br />
enolates: Enolate generation and reactivity.<br />
K. J. Kolonko, H. J. Reich<br />
2:40 138. Reaction mechanism of imidazole<br />
formation from glyoxal and amines: A<br />
computational study. J. Kua, H. Krizner<br />
3:00 139. Intermolecular influences on radical<br />
reactions. A. K. Croft,C.J.Cadman,<br />
A. Garcia Cabellero, H. M. Howard-Jones,<br />
S. M. Nalli, C. C. Wood<br />
3:20 140. Brownian dynamic simulations of<br />
the excited-state reversible proton transfer<br />
in the zwitterion-proton pair.<br />
A. V. Popov, K. M. Solntsev, E. Bartolo,<br />
L. M. Tolbert, R. Hernandez<br />
3:40 141. Insights into the catalytic mechanism<br />
of GH97 enzyme from the MD and<br />
QM/MM-MFEP simulations. G. Cui,<br />
W. Yang<br />
4:00 142. Novel off-on fluorescent probes<br />
for visualizing reactive oxygen species in<br />
lipid membranes. K. Krumova,G.Cosa<br />
4:20 143. Mechanism of the �,�-diphenylprolinol<br />
trimethylsilyl ether-catalyzed aza-<br />
Michael reaction. C. Wong<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom East<br />
JOC: Defining the Frontiers of Organic<br />
Chemistry for 75 Years<br />
C. Burrows, Organizer<br />
R. Boeckman, Organizer, Presiding<br />
1:30 Introductory Remarks by C. D. Poulter<br />
1:40 144. Evolution of anion relay chemistry<br />
(ARC): Construction of architecturally<br />
complex natural and unnatural products.<br />
A. B. Smith, III<br />
2:20 145. Catalytic organometallic carbonheteroatom<br />
bond formation.<br />
J. F. Hartwig<br />
3:00 146. Strategies for the rational chemical<br />
synthesis of fullerenes and carbon<br />
nanotubes. L. T. Scott<br />
3:40 147. Bioactive compounds: A driving<br />
force for the discovery of methods.<br />
J. Cossy<br />
4:20 148. <strong>Chemical</strong> synthesis in the context<br />
of pharma discovery. S. J. Danishefsky<br />
SUNDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Heterocycles and Aromatics, Metal-<br />
Mediated Reactions & Syntheses,<br />
Molecular Recognition & Self-Assembly<br />
and Physical Organic Chemistry:<br />
Calculations, Mechanisms, Photochemistry<br />
& High-Energy Species<br />
A. Abdel-Magid, Organizer<br />
8:00–10:00<br />
149. Novel syntheses of some 1, 2, 4-triazoles<br />
as potent bacteriocidal agents.<br />
J. R. Patel<br />
150. Radioiodination of functionalized indoles.<br />
A. B. Williams,R.N.Hanson<br />
151. Reverse NO 2 reactivity in the oxidation<br />
of syringyl lignin model compounds in<br />
acetonitrile. S. S. Mustakim, M. R. Karim<br />
152. Novel and efficient synthesis of bendamustine<br />
hydrochloride, the active ingredient<br />
in Treanda®. J. Chen,<br />
K. Przyuski Mowrey, R. Roemmele<br />
153. Sulfonamidophenyl porphyrinic macrocycles<br />
as thiol-activatable photosensitizers<br />
for biological applications.<br />
J. Bhaumik, K. M. Bardon,<br />
R. Weissleder, J. R. McCarthy<br />
154. Modulation of regioselectivity in the<br />
condensation 3-amino-5-methylpyrazole<br />
with unsymmetrical ketones: Applications<br />
to the synthesis of pyrazolo[1,5-�]pyrimidines.<br />
J. R. Rizzo, T. Y. Zhang, M. Jia,<br />
H. Ping<br />
155. p-Iodination and p-bromination of activated<br />
arenes in hydrocarbon media.<br />
D. W. Slocum, P. E. Whitley,B.Fouzia<br />
156. Synthesis of nitrogen- and sulfur-containing<br />
heterocycles from cyclopropanol<br />
fragmentation. G. T. Stoyanov,<br />
K. L. George, K. P. Minbiole<br />
157. Synthesis of a coumarin/phenanthridine-fused<br />
heterocycle: A potential organocatalytic<br />
oxidizing agent. D. Yang,<br />
J. Chen<br />
158. One-step, multicomponent reaction for<br />
the synthesis of fully substituted 5-amino-1,3-thiazole-4-carboxamides.<br />
K. K. Childers, A. M. Haidle,<br />
M. R. Machacek, J. P. Rogers, E. Romeo<br />
159. Carbon-Carbon bond formation under<br />
mild conditions using cyclic ketene<br />
acetals: Reactions of substituted oxazoles<br />
and thiazoles with acid chlorides and isocyanates.<br />
S. Chatterjee, G. Ye, Y. Song,<br />
B. L. Barker, C. U. Pittman, Jr.<br />
160. Asymmetric synthesis of Pyrrolodinopyridine<br />
based CXCR4. R. Zhou, C. Bi,<br />
M. He, R. Hoffman, M. Jalaie, J. Kath,<br />
S. Kupchinsky, T. Ling, J. Lu, M. Marx,<br />
P. Richardson, N. Sach, K. Tran,<br />
N. Barbour, S. Cho-Schultz<br />
161. Tandem Henry-Michael route to the<br />
1,3-disubstituted-1,3-dihydrobenzo[c]furan<br />
system. F. A. Luzzio,J.Chen<br />
162. Fluorous benzaldehyde-based synthesis<br />
of heterocyclic systems. A. Kadam,<br />
S. Ding, R. Fitzgerald, M. Le-Nguyen,<br />
W. Zhang<br />
163. Enhancing the solubility of polycyclic<br />
aromatic hydrocarbons: Advancements<br />
in the total synthesis of a [6,6] carbon<br />
nanotube end cap. A. K. Greene,<br />
F. Liquido, L. T. Scott<br />
164. N-2 aryltriazole as a new fluorophore<br />
with tunible photo reactivity. X. Shi,<br />
W. Yan<br />
165. Development of triazole based proline<br />
as new catalyst in chemistry synthesis.<br />
X. Shi, X. YE<br />
166. Iron catalyzed 1,2,3-triazole propargylation:<br />
A practical route for the preparation<br />
of bis-1,2,3-triazole. Q. Wang,X.Shi<br />
167. Direct copper C-arylation for synthesis<br />
of thiazolyl–pyrazolopyrimidines.<br />
S. K. Boini, J. R. Rizzo, R. K. Vaid,<br />
B. Dominguez, M. Groarke<br />
168. Synthesis of thieno[2,3-b]furans and<br />
furo[2,3-b]furans using a modification of<br />
the Jacobi bis-heteroannulation method.<br />
S. F. McCann, Y. Hu, M. Hendrixson,<br />
R. A. Coats<br />
169. New approaches to the synthesis of indolequinones<br />
as bioreductive anticancer<br />
agents. M. Inman, C. J. Moody<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
170. Convenient one-pot synthesis of 4-substituted-2,6-dihalopyridines:<br />
Valuable<br />
building blocks for medicinally active heterocycles.<br />
V. Neelagiri, P. Salgaonkar,<br />
D. Sethumadhavan, M. Neelagiri,<br />
V. Rajur, H. Kim, R. Rajur, R. Reddy,<br />
K. Vines, S. Gadamasetty, C. Moon<br />
171. Intermolecular aza Diels-Alder reactions<br />
of iminoacetonitriles.A[4� 2 ] cycloaddition<br />
route to substituted tetrahydropyridines.<br />
S. Tumidajski, K. M. Maloney,<br />
R. L. Danheiser<br />
172. Toward [8]circulene. R. Bhola,<br />
B. T. King<br />
173. Short synthesis of benzo[1,2,5]triazepin-<br />
4-ones via intramolecular S NAr substitution.<br />
S. Jin, O. St-Jean, V. Santhakumar,<br />
M. J. Tomaszewski<br />
174. X-ray, NMR, FTIR and DFT structural<br />
study of enaminketone derivatives of the<br />
Fisher base. O. F. Vazquez-Vuelvas,<br />
D. Morales-Morales, Z. Gomez-Sandoval,<br />
M. Tlenkopatchev, A. Pineda-Contreras<br />
175. New photolabile linkers for the solidphase<br />
synthesis of NH-1,2,3-triazoles,<br />
homoserine lactones, and other heterocycles.<br />
K. Qvortrup, T. E. Nielsen<br />
176. Microwave-assisted soluble polymer<br />
supported synthesis of quinoxalines,<br />
benzodiazepines, and benzimidazoles.<br />
F. S. Fouad<br />
177. Total synthesis of cyclooroidin and<br />
studies towards some oroidin dimers.<br />
S. Mukherjee, C. J. Lovely<br />
178. Modified synthesis and direct borylation<br />
of corannulene. M. N. Eliseeva,<br />
L. T. Scott<br />
179. Peculiarities of the reaction between<br />
sodium hydroxide and syn- and anti-isomers<br />
of 5-substituted 2-(4-chlorobutyryl)aminobenzophenones<br />
oximes.<br />
O. V. Kulikov, L. K. Minacheva,<br />
A. V. Mazepa<br />
180. Interactions of �-conjugated chains in<br />
stacked oligo(phenylene ethynylene)s.<br />
S. P. Jagtap, G. Brizius, W. Komorner,<br />
D. M. Collard<br />
181. Mild and efficient �-alkynylation of<br />
butenolides: Short synthesis of fugomycins.<br />
N. Bruneau-Latour, J. Boukouvalas<br />
182. Diels-Alder strategy for constructing<br />
�-benzoyl-�-arylbutenolides: Expedient<br />
synthesis of cadiolides. C. Thibault,<br />
J. Boukouvalas<br />
183. Troubleshooting a synthesis: Optimization<br />
of a synthetic route to cyclic hydroxamic<br />
acids. B. M. Bechle,A.B.Dounay,<br />
X. Gan, S. Ghosh, J. Kim, L. McAllister,<br />
V. Parikh, J. Tuttle, P. Verhoest<br />
184. Reactivity and regioselectivity of nitroalkenes<br />
with unsymmetrical münchnones.<br />
J. M. Lopchuk,G.W.Gribble<br />
185. Progress toward the asymmetric synthesis<br />
of cyclic hydroxamic acids: Route<br />
design and optimization. S. Ghosh,<br />
A. B. Dounay, X. Gan, B. M. Bechle,<br />
J. Kim, L. McAllister, V. Parikh,<br />
J. B. Tuttle, P. R. Verhoest<br />
186. Formal olefination and acylaziridination<br />
of imidazolones. X. Dai, M. W. Miller,<br />
A. W. Stamford<br />
187. Picolinamide derivatives as ligand in<br />
aryl-aryl Ullmann type couplings at RT.<br />
F. Damkaci, E. Altay<br />
188. Synthesis and characterization of 1,8dithia-4,11-diazacyclotetradecane.<br />
T. L. Walker, M. J. Taschner, W. Malasi,<br />
S. Bhide, T. Parker<br />
189. Synthesis and alkali metal reduction of<br />
cyclooctatetraenyl isocyanate. J. R. Klen,<br />
S. J. Peters<br />
190. Superelectrophilic chemistry of nitriles.<br />
D. A. Klumpp,E.K.Raja<br />
191. Direct continuous flow synthesis of<br />
highly substituted pyrrole-3-carboxylic<br />
acids via in situ hydrolysis of tert-butyl<br />
esters. A. Herath,N.D.Cosford<br />
192. Rapid multistep continuous flow synthesis<br />
of novel 3,4-dihydropyrimidin-<br />
2(1H)-ones (DHPMs): Tandem heterocycle<br />
formation/three component reaction<br />
in a single continuous microreactor sequence.<br />
N. Pagano, A. Herath,<br />
N. D. Cosford<br />
193. Charge migration across aryl groups in<br />
superelectrophiles. D. A. Klumpp,<br />
R. R. Naredia, K. J. Boblak,<br />
M. J. O’Connor<br />
194. New methods for the quaternization of<br />
benzothiazoles. L. Chen<br />
195. Protio-defluorination chemistry.<br />
D. A. Klumpp, A. Kethe<br />
196. Synthesis of chiral amino acid based<br />
pyrrolidine thioethers. A. M. Lineberry,<br />
M. J. Taschner<br />
197. Synthesis and conjugation of chlorins to<br />
iron oxide nanoparticles for diagnoses<br />
and treatment of atherosclerotic vascular<br />
disease. S. Erdem, R. Weissleder,<br />
J. McCarthy*<br />
198. Synthesis of novel 6,12-disubstituted<br />
derivatives of Tröger’s base. E. Ascic,<br />
J. Artacho, K. Månsson, J. Karlsson,<br />
M. Harmata, V. Snieckus, K. Wärnmark<br />
199. Withdrawn<br />
200. Direct aziridination of 1,3-dioxenones:<br />
Applications in the synthesis �-amino<br />
acids. M. Fletcher, J. Falla,<br />
E. C. McLaughlin<br />
201. Application of hetero-Michael pathways<br />
for the synthesis of sultam libraries.<br />
Q. Zang, S. Javed, P. K. Maity,<br />
J. J. Hasting, P. R. Hanson<br />
202. Design and synthesis of a Lewis acid<br />
functionalized room-temperature ionic<br />
liquid for use as a gas capture material.<br />
B. R. Wiesenauer, J. E. Bara,<br />
R. D. Noble, D. L. Gin<br />
203. Synthesis and biological evaluation of<br />
macrocyclic bifunctional ligands for cancer<br />
therapy. X. Sun, H. Song, M. Dadwal,<br />
C. Kang, A. Dai, H. Chong<br />
204. Synthesis of �-substituted porpholactones<br />
as novel chromophores for optical<br />
high pH sensing. J. Worlinsky, G. Zarate,<br />
P. Daddario, M. Ghandehari, G. Khalil,<br />
C. Brückner<br />
205. Synthesis of (�)-2-aryl- and (�)-2-alkylsubstituted2,3-dihydro-4(1H)-quinazolinones<br />
from 2-nitro- and 2-aminobenzamide.<br />
R. A. Bunce, B. Nammalwar<br />
206. [Azeteochlorinato]Ni(II), a pyrrole ringcontracted<br />
chlorin analog. M. A. Hyland,<br />
S. Banerjee, C. Brückner<br />
207. Oxazolochlorins: Stable chlorin-type<br />
chromophores. J. Ogikubo,<br />
L. Samankumara, C. Brückner<br />
208. Formation of bridged and fused bicyclic<br />
diazenium salts from aryl hydrazone precursors.<br />
J. Wyman, M. I. Javed,<br />
M. Brewer<br />
209. Reactions of 2-alkynylcarboxylic acids<br />
and terminal alkynes. D. E. Mendes,<br />
A. M. Schoffstall<br />
210. Investigations of heterocyclic sulfones<br />
as medicinal compounds. K. N. Barrett,<br />
J. McKee, M. Zanger<br />
211. Toward a library-optimized approach to<br />
synthetic ergolines. M. A. Parker,<br />
J. Hwang, D. Schmit, J. Almazan,<br />
M. Farmer, J. Duensing, M. B. Bergdahl<br />
212. Solid state aldol synthesis of novel anticancer<br />
chalcones. J. K. Rugutt<br />
213. Gold(I)-catalyzed intermolecular amination<br />
of allylic alcohols with cyclic ureas<br />
and related nucleophiles. P. Mukherjee,<br />
R. A. Widenhoefer<br />
214. Synthesis of pyrroles and furans via<br />
Au(I)-catalyzed Claisen rearrangement.<br />
A. Saito, T. Konishi, Y. Hanzawa<br />
215. TiCl 4-activated selective nucleophilic<br />
substitutions of t-butyl alcohol and benzyl<br />
alcohols with pi-donating substituents.<br />
C. Tsai, R. Sung, K. Sung<br />
216. Copper-catalyzed formations of sulfurnitrogen<br />
bonds using thiols. N. Taniguchi<br />
217. Highly chemoselective nickel-catalyzed<br />
three-component cross-trimerization of<br />
three distinct alkynes leading to 1,3-dien-<br />
5-ynes. K. Ogata, Y. Atsuumi,<br />
S. Fukuzawa<br />
218. Pd(II)-catalyzed arylation of cyclic<br />
enaminones using boronic acids via C–H<br />
functionalization. Y. KIM, G. I. Georg<br />
219. Zirconium mediated three component<br />
reaction with carbon dioxide. D. Castillo,<br />
J. Padilla,S.Oda,S.Mito<br />
220. Highly diastereoselective synthesis of<br />
both (E)-and (Z)-trisubstituted alkenes via<br />
organoboranes. N. G. Bhat, L. Reyna<br />
221. Novel diastereoselective synthesis of<br />
(Z)-disubstituted alkenes containing a<br />
4-methylbenzyl moiety via organoboranes.<br />
N. G. Bhat, R. Cavazos<br />
222. Tandem catalysis: Highly functionalized<br />
lactones through a ruthenium-catalyzed<br />
ring closing metathesis/hetero-Pauson-<br />
Khand reaction sequence.<br />
D. F. Finnegan,M.L.Snapper<br />
223. Development of a new generation of<br />
C-C bond forming reactions through C-H<br />
activation. M. Wasa<br />
224. Synthesis of oxindoles using copper<br />
mediated radical cyclisation. H. Parekh<br />
225. Intramolecular C-C formation via oxidative<br />
coupling reactions. K. C. Pereira,<br />
A. Kantak, B. DeBoef<br />
226. Csp 3 -Csp 3 bond formation by nickelcatalyzed<br />
reductive coupling of alkyl halides.<br />
M. R. Prinsell,D.J.Weix<br />
227. Isolated polyacetylene chains in a urea<br />
inclusion complex. A. Lashua,<br />
B. S. Hudson, M. B. Sponsler<br />
228. Pd-Pd bridged complexes: Synthesis<br />
and reactivity. R. Rios, M. Viciano,<br />
A. Moyano<br />
229. Rh(I)-catalyzed diasterselective and<br />
enantioselecive diboration of internal<br />
alkenes. M. Tsai<br />
230. Synthesis of new radiopharmaceuticals<br />
for PET imaging by “click chemistry”.<br />
J. Sims-Mourtada, I. Tworowska<br />
231. In search of a universal Suzuki-Miyaura<br />
reaction. C. Stanciu, S. Berritt,<br />
S. D. Dreher<br />
232. Synthesis of 5-7-5 fused tricyclic lactones<br />
via Rh(I)-catalyzed [2�2�2�1] cycloaddition<br />
of enediynes with carbon<br />
monoxide. J. J. Kaloko,G.Y.Teng,<br />
S. Pavel, I. Ojima, A. A. Athan<br />
233. Rh-catalyzed intramolecular cycloadditions<br />
of 1,6-diene-11-ynes and 6-ene-<br />
1,11-diynes. A. A. Athan,J.J.Kaloko,<br />
G. Y. Teng, I. Ojima<br />
234. Rh(I)-catalyzed [2�2�2�1] cycloaddition<br />
of triynes for rapid access to cholchicinoids.<br />
G. Y. Teng,J.Kaloko,I.Ojima<br />
235. Transition metal-catalyzed addition reactions<br />
of arylboronic acids with alkyl<br />
2-formylbenzoates: Efficient access to<br />
chiral 3-substituted phthalides. Y. Liao,<br />
C. Xing, P. He, Q. Hu<br />
236. Formation of novel 5-7-5-5 fused tetracyclic<br />
skeletons through Rh(I)-catalyzed<br />
[2�2�2�1] cycloaddition of cyclopentene-diynes<br />
with carbon monoxide.<br />
J. J. Kaloko, G. Y. Teng, A. A. Athan,<br />
I. Ojima<br />
237. Oxidative addition of malonates to tetrahydrofurans<br />
via ferrocenium hexafluorophosphate.<br />
C. R. Stephenson,<br />
B. S. Matsuura<br />
238. Selective reduction of �, �-unsaturated<br />
carbonyl compounds using Bu 3SnH.<br />
D. V. Vidhani, M. E. Krafft, J. W. Cran<br />
239. Mechanistic studies of a Pd-catalyzed<br />
olefin dioxygenation. S. R. Neufeldt,<br />
M. S. Sanford<br />
240. Development of a palladium-catalyzed<br />
arylfunctionalization of alkenes.<br />
A. Kubota, A. D. Satterfield,<br />
M. S. Sanford<br />
241. Development of novel cationic Diels-Alder<br />
dienophiles stabilized by cobaltalkyne<br />
complexes. M. Torres,K.M.Shea<br />
242. Diels-Alder dienes activated by cobaltcomplexed<br />
alkynes. S. J. Perlmutter,<br />
K. M. Shea<br />
243. Group 4 metal mediated reactions with<br />
carbon dioxide. S. Oda,S.Mito<br />
244. Lithium 2-pyridyltrihydroxyborate salts:<br />
Stable, isolable, and scalable boronates<br />
for Suzuki-Miyaura coupling reactions.<br />
K. Chen, R. Peterson, S. K. Math,<br />
J. LaMunyon, C. Testa<br />
245. Hydrogen-bonding scaffolds and their<br />
application to Henry reactions in nitrosugar<br />
syntheses. A. J. Metrano,<br />
B. R. Linton<br />
246. New fluorescent gelators derived from<br />
1,3,5-benzenetricarboxamide: Synthesis<br />
and gel preparation. Y. Chen, C. Huang,<br />
P. P. Lee, Y. Wang, H. Wang, J. H. Xin,<br />
K. K. Cheuk<br />
247. Study on self-assembly of novel 1,3,5benzenetricarboxamide-basedorganogel.<br />
Y. Chen, C. Huang, P. P. Lee,<br />
Y. Wang, H. Wang, J. H. Xin, K. K. Cheuk<br />
248. Low molecular weight organogel based<br />
on pyrene derivative. C. Huang, Y. Chen,<br />
P. P. Lee, Y. Wang, H. Wang, J. H. Xin,<br />
K. K. Cheuk<br />
249. Towards lanthanide-based responsive<br />
luminescent probes for the detection of<br />
reactive oxygen species. J. Laakso,<br />
K. E. Borbas<br />
250. Disassembly of amphiphilic macromolecules<br />
based-nanocontainers with enzyme<br />
as stimulus. F. Wang,<br />
M. A. Azagarsamy, S. Thayumanavan<br />
251. Resolution of pharmaceuticals via crystallization<br />
self-assembled monolayers.<br />
P. S. Navare, J. C. MacDonald<br />
252. Crystal engineering of sulfoxides: A<br />
multiple synthon approach in the formation<br />
of sulfa drug-based co-crystals.<br />
E. Elacqua, D. Bucar, R. F. Henry,<br />
G. G. Zhang, L. R. MacGillivray<br />
253. Localization of self-assembled molecular<br />
nanofiber on endoplasmic reticulum<br />
inside live cells. Y. Gao, Y. Kuang, B. Xu<br />
254. N-alkyl-DABCOnium trihalozincates:<br />
Privileged scaffolds for the preparation of<br />
noncentrosymmetric solids. A. D. Finke,<br />
D. L. Gray, J. S. Moore<br />
255. Effects of halogenation on the self-assembly<br />
and hydrogelation of a small molecule.<br />
D. M. Ryan, S. B. Anderson,<br />
B. L. Nilsson<br />
256. Synthesis and characterization of novel<br />
macrocycles based on chenodeoxycholic<br />
acid (CDCA) as potent drug delivery system.<br />
X. Bai, X. Chen, J. R. Dias<br />
257. Sugar-responsive organoboron block<br />
copolymers. J. N. Cambre,D.Roy,<br />
B. S. Sumerlin<br />
258. Colorimetric detection of iodide ions.<br />
I. Ahn, J. Choi, D. Cho<br />
259. Encapsulation and isolation of flavin–<br />
polymer conjugates using dendritic guest<br />
moieties via molecular recognition.<br />
C. Subramani, G. Yesilbag, B. J. Jordan,<br />
X. Li, G. Cooke, A. Sanyal, V. M. Rotello<br />
260. Cell-surface and lysate based identification<br />
of cell types and cancer states using<br />
gold nanoparticle-GFP supramolecular<br />
complexes. S. Rana, A. Bajaj,<br />
O. R. Miranda, J. C. Yawe, D. J. Jerry,<br />
U. H. Bunz<br />
261. Semiconductor co-crystals based on<br />
carboxylic acids. K. M. Kester,<br />
J. C. Sumrak, L. R. MacGillivray<br />
262. Design of ruthenium and osmium containing<br />
coiled-coil peptide dimers: Studies<br />
in energy transfer. D. J. Wilger,<br />
M. L. Waters<br />
263. Synthesis and self-assembly of membrane-active<br />
cationic molecules.<br />
M. J. Razumov, J. S. Carter, H. Patel,<br />
G. J. Gabriel<br />
264. Aqueous self-assembly of porphyrin<br />
nanowires: Synthesis, characterization<br />
and energy transfer studies. M. Fathalla,<br />
A. Neuberger, S. Li, R. Schmehl,<br />
U. Diebold, J. Jayawickramarajah<br />
265. Coordination-driven selective self-assembly<br />
of multicomponent supramolecules.<br />
Y. Zheng, M. Wang, Z. Zhao,<br />
J. B. Pollock, K. Ghosh<br />
266. Tripodal binding groups for the noncovalent<br />
functionalization of graphene<br />
sheets. J. A. Mann,W.R.Dichtel<br />
267. Synthesis and studies of assembled<br />
structures of porphyrins bearing rigid hydrogen<br />
bonding motifs. S. Singh,<br />
C. M. Drain<br />
268. Traveling wave ion mobility mass spectrometry<br />
analysis of self-assembled terpyridine-based<br />
Ru(II)-Fe(II) macrocycles.<br />
X. Li, Y. Chan, G. Newkome,<br />
C. Wesdemiotis<br />
269. Enhancing molecular gelation using<br />
functionalized polymers for sensing applications.<br />
Y. Adhia,T.H.Lent,J.Chen,<br />
M. T. Perez, A. J. McNeil<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ORGN<br />
TECH–87
ORGN <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
270. Design, synthesis, and topochemical<br />
polymerization of diacetylene macrocyclic<br />
systems. T. Hsu, F. W. Fowler,<br />
J. W. Lauher<br />
271. Probing early events in peptide self-assembly<br />
with nonnatural amino acids.<br />
T. M. Doran, A. J. Kamens, N. K. Byrnes,<br />
B. L. Nilsson<br />
272. Withdrawn<br />
273. Exploring the effect of linker topology<br />
on the binding affinity of donor acceptor<br />
hetero-duplexes. S. A. Samuel,<br />
B. Iverson<br />
274. Thermal reaction of a columnar assembled<br />
diacetylene macrocycle. Y. Xu,<br />
L. S. Shimizu<br />
275. Dan-Ndi liquid crystals: Tunable mesophases<br />
and potential photovoltaic applications.<br />
P. M. Alvey, B. Iverson<br />
276. Concentric cyclic assembly of watersoluble<br />
aedamers. C. R. Martinez,<br />
B. L. Iverson<br />
277. 3-Halodiazirinyl anion: A complex of<br />
diazirinylidene and halide ion. T. Martinu,<br />
E. Hanzlova<br />
278. Dynamics of spin-labels in solvent inclusions<br />
in potassium hydrogen phtalate<br />
and phtalic acid single crystals.<br />
L. Ryzhkov<br />
279. Asymmetric Diels-Alder reaction using<br />
benzoin as a photoremovable chiral auxiliary.<br />
V. B. Kammath,P.Sˇ ebej,<br />
T. Slanina, P. Klán<br />
280. Study of 1-naphthyl N-methylcarbamate<br />
� OH radical gas-phase reaction:<br />
Mechanism, kinetics, and branching ratios.<br />
C. Zavala-Oseguera, A. Galano,<br />
G. Merino<br />
281. Computational studies on the structure<br />
and photophysical properties of photochromic<br />
oligothienoacene derivatives.<br />
W. Lam,C.Ko,V.Yam<br />
282. Changing reaction mechanisms with<br />
force. T. J. Kucharski, Q. Yang, Y. Tian,<br />
N. C. Rubin, R. Boulatov<br />
283. p-Hydroxyphenacyl as a photoremovable<br />
protecting group for amines and<br />
amino acids. I. Bownik, J. Literák,<br />
R. S. Givens, P. Klán<br />
284. Slow rearrangement of a sterically hindered<br />
nitrocyclohexadienone and the absence<br />
of phenol oxidation by NO.<br />
S. J. Peters, M. E. Kassabaum,<br />
T. M. Blood<br />
285. Dynamics of 1,3-dipolar cycloadditions<br />
and carbene cycloadditions. L. Xu,<br />
D. E. Charles, K. N. Houk, R. A. Moss<br />
286. Planar and nearly planar trialkylamines.<br />
D. S. Makhanu,A.N.Alsobrook,<br />
A. D. Nelson, T. E. Albrecht-Schmitt,<br />
P. D. Livant<br />
287. Symmetry of N-X-N halogen bonds in<br />
solution. A. C. Carlsson, M. Erdelyi<br />
288. New carbazole, indole, and diphenylamine<br />
based emissive compounds:<br />
Synthesis, photophysical properties, and<br />
formation of nanoparticles. K. Panthi,<br />
T. H. Kinstle<br />
289. Mechanistic insights into the copper(II)promoted<br />
aminooxygenation of alkenes.<br />
M. C. Paderes, J. B. Keister,<br />
S. R. Chemler<br />
290. Elucidating the relative importance of<br />
various photochemically produced reactive<br />
intermediates in the photodegradation<br />
of endocrine-disrupting pollutants.<br />
K. E. Daumit,C.M.Whidbey,<br />
C. N. Goodwin, J. L. Gray, D. E. Latch<br />
291. Using the photo-Fries reaction as a<br />
photochemical probe to quantify the cage<br />
effects of ionic liquids. A. Zablowsky,<br />
A. E. Keirstead<br />
292. N-(�-Aminoalkyl)tetrazoles: Synthesis<br />
and NMR study of the tautomeric equilibria.<br />
B. M. El-Gendy, B. Draghici, C. Hall,<br />
P. J. Steel<br />
293. Experimental and computational investigations<br />
of the thermochemical decomposition<br />
of aryl ether lignin model compounds.<br />
M. K. Kidder, A. Beste,<br />
A. Buchanan<br />
88–TECH<br />
‡ Cooperative Cosponsorship<br />
294. Molecular torsion balance for evaluation<br />
of halogen bonding in polar and nonpolar<br />
solvents. S. K. Keyser, C. S. Wilcox<br />
295. Mechanism for the fragmentation of<br />
aryltrialkylstannane cation radicals.<br />
P. Luo, J. P. Dinnocenzo<br />
296. Bottom-up synthesis of graphene nanoribbons.<br />
J. Kintigh, G. P. Miller<br />
297. X-ray crystal structures of organothiosubstituted<br />
pentacenes. J. B. Briggs,<br />
I. Kaur, G. P. Miller<br />
298. Synthesis and study of substituted starphenes.<br />
R. P. Kopreski, G. P. Miller<br />
299. Intramolecular enyne-pyridone photocycloaddition.<br />
S. Kulyk, S. M. Sieburth<br />
300. Synthesis of unusual bicyclic amino<br />
acid from D-Glucose and its use in the<br />
synthesis of natural product analogs.<br />
N. Goyal,G.Wang<br />
301. Efficient ligand-free copper catalyzed<br />
N-arylation of sulfonamides.<br />
T. Yong-Chua,F.Yong<br />
302. Manganese-catalyzed cross-coupling<br />
reactions of nitrogen nucleophiles with<br />
aryl halides in water. Y. Teo, F. Yong,<br />
C. Poh, Y. Yan, G. Chua<br />
303. Highly enantioselective 1,3-dipolar addition<br />
of azomethine ylide with unsaturated<br />
ketones, esters, and amides.<br />
K. Shimizu, K. Ogata, S. Fukuzawa<br />
MONDAY MORNING<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 205A/B<br />
Robert Burns Woodward Memorial<br />
Symposium<br />
R. Williams, W. Greenlee, Organizers<br />
L. T. Scott, Organizer, Presiding<br />
8:00 Introductory Remarks by Roald Hoffmann<br />
8:10 304. Natural product synthesis.<br />
Y. Kishi<br />
9:10 305. Topics in discovery and process<br />
chemistry from pharmaceutical and crop<br />
protection R&D. P. N. Confalone<br />
10:00 Intermission<br />
10:20 306. Design of bifunctional allylboron<br />
reagents via allene hydroboration reactions<br />
and applications to the synthesis of<br />
natural products. W. R. Roush<br />
11:10 307. Synthetic studies on selective<br />
phosphatidylinositol 3-kinase inhibitors.<br />
P. A. Jacobi, E. Onyango, T. Konekamp<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 206A<br />
New Reactions and Methodology<br />
S. Sieburth, Organizer<br />
C. Stephenson, Presiding<br />
8:00 308. Concise approach to the synthesis<br />
of vinigrol using electrocyclic cyclization.<br />
D. Wang,W.E.Crowe<br />
8:20 309. Novel cascade ether synthesis<br />
through the [3,3] sigmatropic rearrangement<br />
of N-allylhydrazones. K. E. Lutz,<br />
R. J. Thomson, D. A. Mundal<br />
8:40 310. Discovery of silver-N-heterocylic<br />
carbenes as novel promoters for O-glycosidation<br />
reactions. I. J. Talisman,<br />
V. Kumar, S. V. Malhotra<br />
9:00 311. Electron transfer-initiated Diels-Alder<br />
cycloadditions of 2�-hydroxychalcones.<br />
H. Cong, J. A. Porco<br />
9:20 312. Highly efficient, three-component,<br />
one-pot, microwave-assisted synthesis<br />
of 2,3-disubstituted benzofurans under<br />
Sonogashira conditions. N. A. Markina,<br />
Y. Chen, R. C. Larock<br />
9:40 313. Copper-catalyzed [4�1] cycloaddition<br />
of 1,3-dienes and nitrene precursors.<br />
J. Zhou<br />
10:00 314. Synthesis of amines, aldehydes,<br />
and imines: Exceeding chemoselectivity<br />
in secondary amide reductions.<br />
G. Pelletier, W. S. Bechara,<br />
A. B. Charette<br />
10:20 315. Bayer-Villiger oxidation of 2-acylcyclic<br />
ketones: A novel approach for the<br />
synthesis of acyl substituted alpha-hydroxy<br />
and alpha-beta unsaturated long<br />
chain acids. V. R. Neelagiri<br />
10:40 316. Boronic acid catalysis for mild<br />
and selective cycloadditions of unsaturated<br />
carboxylic acids. H. Zheng,<br />
O. Marion, D. G. Hall<br />
11:00 317. Sequenced Brook and Ireland-<br />
Claisen rearrangements of allylic silyl<br />
glyoxylates. D. C. Schmitt,J.S.Johnson<br />
11:20 318. Novel expedient synthesis of<br />
18 O-labelled allyl alcohol. S. Purser,<br />
G. J. Owen-Smith, G. C. Lloyd-Jones<br />
11:40 319. Electrophilic aromatic selenylation.<br />
S. Knapp,M.Abdo<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 203<br />
Biologically-Related Molecules &<br />
Processes<br />
S. Sieburth, Organizer<br />
C. Meyers, Presiding<br />
8:00 320. Chemistry of thyroxine and dissociation<br />
of arylglyoxylic acids. R. Reddy<br />
8:20 321. <strong>Chemical</strong> communication within<br />
and between species. M. M. Meijler<br />
8:40 322. Natural product isolation from<br />
some marine-derived fungi.<br />
D. K. Fearon, P. B. Reese<br />
9:00 323. Simple synthesis, anti-breast cancer<br />
activity of novel coumarin-based sulfonamides:<br />
A coumestrol derivative and<br />
related molecules. G. Zeng,W.Mao,<br />
H. Zeng, T. Wang, Z. Zhu, S. Liu<br />
9:20 324. Molecular imaging approaches to<br />
understanding hydrogen peroxide biology<br />
in stress and development.<br />
B. C. Dickinson,C.J.Chang<br />
9:40 325. Synthetic scale-up and process<br />
optimization of glyceollin I, a novel natural<br />
product that displays interesting anticancer<br />
activity. A. Luniwal, M. El-Dakdouki,<br />
L. Fang, R. Khuspe, J. Liu, M. Reese,<br />
P. W. Erhardt<br />
10:00 326. Fungal biotransformation of<br />
Ferutinin and Tschimganin to afford bioactive<br />
products. A. Azarpira,<br />
M. I. Choudhary, S. A. Sattar, A. Rahman<br />
10:20 327. Synthesis of affinity tags for the<br />
proteomic profiling of cysteine sulfenic<br />
acids and S-nitrosothiols. E. Bechtold,<br />
J. Qian, K. J. Nelson, L. B. Poole,<br />
C. M. Furdui, S. B. King<br />
10:40 328. Mutasynthesis of novel thiopeptide<br />
natural product antibiotics.<br />
M. G. Acker, A. A. Bowers, A. Koglin,<br />
C. T. Walsh<br />
11:00 329. Development of fluorescent substrates<br />
for vesicular monoamine transporter<br />
2 (VMAT2) and their application in<br />
high throughput screening of VMAT2 inhibitors.<br />
G. Hu,D.Sames<br />
11:20 330. Synthesis and screening of PI3K<br />
inhibitor prodrugs for prostate cancer<br />
treatment. T. A. Pinder, M. Welker,<br />
G. Kulik<br />
11:40 331. Diversity-oriented synthesis of<br />
macrocyclic peptidomimetic scaffolds.<br />
A. Isidro-Llobet, P. Bello, T. Murillo,<br />
D. R. Spring<br />
12:00 332. Synthesis of vitamin D analogs<br />
as ligands for mutant human vitamin D receptor<br />
(Arg274Leu). S. Honzawa,<br />
N. Takahashi, A. Yamashita, T. Sugiura,<br />
M. A. Arai, S. Kato, M. Kurihara,<br />
A. Kittaka<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 204A<br />
Total Synthesis of Complex Molecules<br />
S. Sieburth, Organizer<br />
A. Doyle, Presiding<br />
8:00 333. Concise racemic and asymmetric<br />
total synthesese of strychnos alkaloids:<br />
Akuammicine, strychnine. G. Sirasani,<br />
T. Paul, R. B. Andrade<br />
8:20 334. Progress towards total synthesis<br />
of Ammocidin D. S. T. Chau,J.A.Teske,<br />
Q. Liu, G. A. Sulikowski<br />
8:40 335. Progress towards the total synthesis<br />
of Pectenotoxin 4. R. Sharma,<br />
L. J. Williams<br />
9:00 336. Efficient total synthesis of (-)-1<br />
(10),5-germacradien-4-ol from Pinus strobus.<br />
J. J. Kiddle, J. M. Smith,<br />
A. M. Vermeersch, T. Lim<br />
9:20 337. Convergent synthesis of the natural<br />
product DC-45-A2, the parent aglycone<br />
of the trioxacarcins. N. Hill,<br />
J. Svenda, A. G. Myers<br />
9:40 338. Six-step synthesis of strychnine.<br />
D. B. Martin, C. D. Vanderwal<br />
10:00 339. Total synthesis of (�)-nakadomarin<br />
A. P. Jakubec,<br />
D. M. Cockfield, D. J. Dixon<br />
10:20 340. Studies toward the synthesis of<br />
sanggenol-type natural products.<br />
Y. Xiong,J.A.Porco<br />
10:40 341. Concise total syntheses of Lycopodium<br />
and Aspidosperma alkaloids.<br />
S. P. Waters,X.Cheng<br />
11:00 342. Studies directed toward the total<br />
synthesis of isatisine A. J. Lee,<br />
J. S. Panek<br />
11:20 343. Synthetic access to members of<br />
the Aeruginosin family of natural products<br />
relying upon a novel oxabicyclic building<br />
block. C. S. Schindler, E. M. Carreira<br />
11:40 344. Synthesis and biological evaluation<br />
of the macrolide 4,8,10-tridesmethyl<br />
cethromycin, an effort towards overcoming<br />
antibiotic resistance. B. S. Wagh,<br />
V. Velvadapu, T. Paul, R. B. Andrade<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 204B<br />
Asymmetric Reactions and Syntheses<br />
S. Sieburth, Organizer<br />
D. Coltart, Presiding<br />
8:00 345. Novel camphor-based amino alcohols<br />
and diols for selected asymmetric<br />
synthesis. O. B. Olubanwo,J.A.Golen,<br />
V. Nevalainen<br />
8:20 346. Computationally inspired diastereo-<br />
and enantioselective rhodium-catalyzed<br />
Pauson-Khand reaction at room<br />
temperature. P. Ricci, P. Evans, M. Baik<br />
8:40 347. Enantioenriched allenylsilanes as<br />
building blocks for stereocontrol in organic<br />
synthesis. R. A. Brawn,J.S.Panek<br />
9:00 348. Design and synthesis of cobalt(II)<br />
porphyrin catalysts for stereoselective intro-molecular<br />
cyclopropanation. X. Xu,<br />
H. Lu, R. Joshua, P. Zhang<br />
9:20 349. Asymmetric total synthesis of (�)clusianone<br />
via N-amino cyclic carbamate<br />
hydrazones. M. R. Garnsey,D.Lim,<br />
J. Yost, D. M. Coltart<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
9:40 350. Probing tubulin interactions with<br />
14-methyl epothilone D analogs.<br />
E. M. Daly, R. E. Taylor<br />
10:00 351. Triazole-gold catalysed synthesis<br />
of �, � Unsaturated compounds from<br />
propargyl acetate. L. S. Gautam,<br />
D.Wang,X.M.Shi<br />
10:20 352. Pyrimidine-Mannich base hybrids<br />
as antitubercular agents: Facile synthesis<br />
with ZnBF 4 in THF/water biphasic<br />
system. M. S. Chorghade,<br />
A. M. Rahatgaonkar, N. K. Longadge<br />
10:40 353. Catalytic stereoselective allene<br />
oxidation: Reagent controlled spirodiepoxide<br />
formation. G. Hu, M. A. Drahl,<br />
L. J. Williams<br />
11:00 354. Asymmetric reduction by chiral<br />
reagents. M. S. Chorghade,<br />
R. S. CHORGHADE,R.H.Grubbs,<br />
C. S. Daeffler<br />
11:20 355. Organocatalytic synthesis of<br />
spiro compounds. R. Rios,<br />
X. Companyó, A. R. Alba, A. Moyano<br />
11:40 356. Organocatalytic oxazolone addition<br />
to 1,2-bisphenylsulfonylethene.<br />
R. Rios, N. Bravo, A. R. Alba, G. Valero,<br />
X. Companyó, A. Moyano<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom East<br />
JOC: Defining the Frontiers of Organic<br />
Chemistry for 75 Years<br />
R. Boeckman, Organizer<br />
C. Burrows, Organizer, Presiding<br />
8:30 357. Organotrifluoroborates: Organoboron<br />
reagents for the 21st century.<br />
G. Molander<br />
9:10 358. Fluorescent tools for chemical biology.<br />
B. Imperiali<br />
9:50 359. Explorations of organic chemistry<br />
with catalytic amino acids and peptides.<br />
S. J. Miller<br />
10:30 360. Art of building small.<br />
B. L. Feringa<br />
11:10 361. Complex alkaloid total synthesis.<br />
M. Movassaghi<br />
11:50 Concluding Remarks (C. J. Burrows)<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 207<br />
Physical Organic Chemistry: Calculations,<br />
Mechanisms, Photochemistry and High-<br />
Energy Species<br />
S. Sieburth, Organizer<br />
B. Shi, Presiding<br />
8:40 362. Reactivity of photochemically<br />
generated atomic oxygen in aqueous media.<br />
R. D. McCulla<br />
9:00 363. Gas-phase nucleophilic and elimination<br />
reactions in simple alkyl nitrates.<br />
J. M. Riveros, T. C. Correra<br />
9:20 364. Mechanisms of lithium cuprate<br />
coupling reactions: A computational<br />
study. L. M. Pratt<br />
9:40 365. Fiber-optic singlet-oxygen [ 1 O 2<br />
( 1 ‚ g)] generator device serving as a point<br />
selective sterilizer. D. Aebisher,<br />
M. Zamadar, A. Mahendran, G. Ghosh,<br />
C. McEntee, A. Greer<br />
10:00 366. Exciton transfer rate between<br />
conjugated polymer chains. Q. Lu,M.Li,<br />
X. Lin<br />
10:20 367. QM/MM molecular dynamics<br />
simulations provide insight into the photoisomerization<br />
mechanism of retinal in<br />
rhodopsin and an artificial molecular<br />
switch. I. Schapiro, M. Olivucci<br />
10:40 368. Test to evaluate the performance<br />
of aromaticity descriptors in all-metal and<br />
semimetal clusters: An appraisal of electronic<br />
and magnetic indicators of aromaticity.<br />
J. Poater, F. Feixas,<br />
J. Jimenez-Halla, E. Matito, M. Solà<br />
11:00 369. The Thorpe-Ingold effect on<br />
the Bergman cyclization of an elevencarbon<br />
monocyclic enediyne: Theoretical<br />
studies. E. M. Greer, O. Lavinda<br />
11:20 370. Ab initio study of cerium(III) trapping<br />
by the Schiff-base complex N,N�bis[2-(salicylideneamino)ethyl]ethane-<br />
1,2-diamine for sensing applications.<br />
A. L. Botelho, S. Gopalan, X. Lin<br />
11:40 371. Functionalization of multilayer<br />
fullerenes (carbon nanoonions) using diazonium<br />
compounds and click chemistry.<br />
K. Flavin, M. Chaur, L. Echegoyen,<br />
S. Giordani<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom East<br />
Tetrahedron Prize for Creativity in Organic<br />
Chemistry<br />
Contemporary Methods in Organic<br />
Synthesis<br />
S. Hall, D. Francissen, Organizers<br />
S. Martin, Presiding<br />
1:00 Introductory Remarks: Stephen F. Martin,<br />
Presiding<br />
1:05 372. New catalytic strategies for chemical<br />
synthesis. M. J. Gaunt<br />
2:00 373. Catalysis and cascades in complex<br />
alkaloid natural product synthesis.<br />
D. J. Dixon<br />
2:55 374. Exocyclic and acyclic stereocontrol<br />
in catalyzed reactions of ethylene:<br />
Asymmetric hydrovinylation reactions in<br />
natural product synthesis. T. RajanBabu<br />
3:50 Intermission<br />
3:55 Award Presentation: H. Waldmann & D.<br />
Francissen<br />
4:05 375. Award Address (Tetrahedron<br />
Prize for Creativity in Organic Chemistry,<br />
sponsored by Elsevier). Changing face of<br />
organic synthesis. S. V. Ley<br />
5:05 Concluding Remarks: S. F. Martin<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 206A<br />
New Reactions and Methodology<br />
S. Sieburth, Organizer<br />
C. Larsen, Presiding<br />
1:00 376. Organocatalytic amination of allenyl<br />
esters and subsequent cyclization to<br />
form azaproline derivatives. P. Maity,<br />
S. D. Lepore<br />
1:20 377. Enhanced hydrogen bond donor<br />
catalysis. A. E. Mattson,S.S.So,<br />
J. A. Burkett<br />
1:40 378. Synthesis and fast Diels-Alder/<br />
cross coupling reactions of boron substituted<br />
1,3-dienes. L. Wang, M. E. Welker,<br />
M. W. Wright, C. Day<br />
2:00 379. Skeletal diversity via cationic rearrangements<br />
of substituted dihydropyrans.<br />
M. R. Medeiros, R. S. Narayan,<br />
S. E. Schaus, J. A. Porco, Jr<br />
2:20 380. Rhodium-catalyzed transformations<br />
of non-sulfonyl 1,2,3-triazoles.<br />
M. Zibinsky, V. Fokin<br />
2:40 381. Attoreactors: <strong>Chemical</strong> reactions<br />
carried out on a zeptomol (10 -21 mol)<br />
scale. P. Anzenbacher, M. A. Palacios<br />
3:00 382. XtalFluor-salts: Selective fluorination<br />
reagents with enhanced thermal stability<br />
and ease of handling. A. L’Heureux,<br />
M. Couturier, F. Beaulieu, C. Bennett,<br />
D. Bill, S. Clayton, F. LaFlamme,<br />
M. Mirmehrabi, S. Tadayon, D. Tovell<br />
3:20 383. Zinc-mediated chain extension as<br />
an approach for the synthesis of papyracillic<br />
acid C. J. R. Mazzone,<br />
C. K. Zercher<br />
3:40 384. Carbon-carbon bond formation<br />
and pyrrole synthesis via the [3,3] sigmatropic<br />
rearrangement of O-vinyl oxime<br />
ethers. L. L. Anderson,H.Wang,<br />
D. S. Mueller, R. Sachwani,<br />
H. N. Londino, A. Papirnyak<br />
4:00 385. Investigation onto the use of silica-supported<br />
amines within packed-bed<br />
and microstructured catalytic flow reactors.<br />
L. Soldi, R. Maggi, G. Sartori,<br />
S. Loebbecke<br />
4:20 386. Para-selective direct arylation of<br />
anisoles and aniline derivatives.<br />
J. R. Brandt, C. Ciana, F. M. Meyer,<br />
R. J. Phipps, M. J. Gaunt<br />
4:40 387. Synthetic studies of a regiospecific<br />
trisubstituted aziridine ring opening<br />
reaction. B. Kelley, M. M. Joullie<br />
5:00 388. Palladium-catalyzed intramolecular<br />
carboesterification of olefin. Y. Li,<br />
D. Song, D. M. Vy<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 203<br />
Biologically-Related Molecules &<br />
Processes<br />
S. Sieburth, Organizer<br />
K. Wang, Presiding<br />
1:00 389. Synthesis of Pin1 WW domain libraries<br />
via solid-phase phosphorylation.<br />
X. R. Chen, A. Y. Mercedes-Camacho,<br />
F. A. Etzkorn<br />
1:20 390. Chemoselective Staudinger-phosphite<br />
reactions: Applications to the phosphorylation<br />
and PEGylation of proteins.<br />
C. P. Hackenberger<br />
1:40 391. Design of a continuous flow system<br />
for the iterative cross aldol condensation<br />
of aldehydes. S. A. France<br />
2:00 392. Development of gadolinium and<br />
xenon-based probes for MR molecular<br />
imaging. B. DeBoef<br />
2:20 393. Derivatives of ganglioside G M1 to<br />
facilitate imaging and functional studies.<br />
Z. Liu, K. Kumar<br />
2:40 394. Novel inhibitors of fibroblast<br />
growth factor receptor 1 kinase: Lead optimization<br />
of thienopyrimidinones by<br />
structure-based design. A. R. Ekkati,<br />
K. P. Ravindranathan, V. Mandiyan,<br />
J. H. Bae, J. Schlessinger,<br />
W. L. Jorgensen<br />
3:00 395. Synthesis and biological evaluation<br />
of 3, 5-disubstituted isoxazolines as<br />
potential antitumor agents.<br />
M. S. Chorghae, A. M. Rahatgaonkar,<br />
K. R. Lanjewar, B. D. Saraf<br />
3:20 396. Pyrimidine derivatives as COX-1<br />
and COX -2 inhibitors. M. S. Chorghade,<br />
R. P. Dhankar, A. M. Rahatgaonkar<br />
3:40 397. Mtb Bla-specific fluorescent<br />
probes for tuberculosis detection and imaging.<br />
H. Xie, J. Rao, J. Mire,<br />
J. C. Sacchettini, Y. Kong, J. D. Cirillo<br />
4:00 398. Discovery and synthetic development<br />
of novel sterols as antileishmanial<br />
agents. D. Abdelhamid,L.Pan,<br />
A. Kinghorn, C. M. Lezama-Davila,<br />
A. Satoskar, J. R. Fuchs<br />
4:20 399. De novo asymmetric synthesis of<br />
�-6-deoxyidopyranoside via Wharton rearrangement.<br />
H. Wang,G.A.O’Doherty<br />
4:40 400. Synthesis of a highly branched oligosaccharide.<br />
G. A. O’Doherty, S. Kang<br />
5:00 401. Protein cage polymer hybrid as a<br />
potential MRI contrast agent.<br />
M. J. Abedin, L. Liepold, M. Young,<br />
T. Douglas<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 204A<br />
Total Synthesis of Complex Molecules<br />
S. Sieburth, Organizer<br />
S. Waters, Presiding<br />
1:00 402. Total synthesis of reserpine: Using<br />
C-3 as an element for stereocontrol.<br />
G. A. Barcan, O. Kwon<br />
1:20 403. Electron transfer photoredox catalysis:<br />
Applications in complex molecule<br />
synthesis. J. M. Narayanam,<br />
S. Diethelm, L. Furst, C. R. Stephenson<br />
1:40 404. Convergent total synthesis of dinophysistoxin-2.<br />
Y. Pang, C. J. Forsyth<br />
2:00 405. Enantioselective formal total synthesis<br />
of (�)-aspergillide C.<br />
J. D. Panarese, S. P. Waters<br />
2:20 406. Progress toward the total synthesis<br />
of stemocurtisine utilizing an asymmetric<br />
Stetter reaction. D. M. Rubush,<br />
T. Rovis<br />
2:40 407. Progress towards a total synthesis<br />
of the selective cytotoxic natural product<br />
maoecrystal V. D. D. McLeod,<br />
W. J. Chain, M. Naylor, C. S. Jeffrey,<br />
E. J. Sorensen<br />
3:00 408. Approaches to the synthesis of<br />
auxofuran. R. P. Loach, J. Boukouvalas<br />
3:20 409. Total synthesis of Celogentin C via<br />
stereoselective C-H activation. Y. Feng,<br />
G. Chen<br />
3:40 410. Studies toward the total synthesis<br />
of acremoxanthones. A. J. Little,<br />
J. A. Porco<br />
4:00 411. Continued progress toward the<br />
expedient syntheses of cephalostatin<br />
“North 1” analogs. D. P. Jamieson,<br />
P. L. Fuchs<br />
4:20 412. De novo asymmetric synthesis of<br />
Aspergillide. Y. Xing, G. A. O’Doherty<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 204B<br />
Asymmetric Reactions and Syntheses<br />
S. Sieburth, Organizer<br />
S. Kulyk, Presiding<br />
1:00 413. Enantioselective rhodium(II)-catalyzed<br />
cyclopropanation of alkenes with<br />
�-EWG diazoacetophenones: PMP-ketones<br />
as stereoselectivity controllers.<br />
V. N. Lindsay, A. B. Charette<br />
1:20 414. Synthetic utility of W-alkylidene<br />
monopyrrolide alkoxide complexes in olefin<br />
metathesis. Y. Zhao, A. H. Hoveyda,<br />
R. R. Schrock<br />
1:40 415. Asymmetric arylhalogenation of<br />
terminal olefins. A. Kubota,<br />
M. S. Sanford<br />
2:00 416. Asymmetric intramolecular alkene<br />
cyanoamidation via carbon–carbon<br />
sigma bond activation: Total synthesis of<br />
(–)-Quebrachamine. V. J. Reddy,<br />
C. J. Douglas<br />
2:20 417. Asymmetric �-alkylation of ketones<br />
via activated hydrazones.<br />
D. M. Coltart<br />
2:40 418. Toward the total synthesis of 20deoxyapoptolidinone.<br />
V. M. Lombardo<br />
3:00 419. New applications of asymmetric<br />
dienamine catalysis. M. Christmann,<br />
J. Stiller, E. Marques-Lopez, R. P. Herrera<br />
3:20 420. Work toward the total synthesis of<br />
pycnanthuquinone A via an asymmetric<br />
Morita-Baylis-Hillman reaction.<br />
A. M. Wensley, S. E. Schaus<br />
3:40 421. Design and development of novel<br />
chiral ligands for metal and organo catalysis.<br />
S. Rasapalli,V.Kumbam,M.Yu<br />
4:00 422. Development of the asymmetric<br />
intermolecular Stetter reaction catalyzed<br />
by N-heterocyclic carbenes. D. DiRocco<br />
4:20 423. <strong>Chemical</strong> synthesis of micromide.<br />
M. B. Bergdahl, I. Nevchas, M. Parker,<br />
L. Wang, J. Duensing<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ORGN<br />
TECH–89
ORGN <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
4:40 424. Practical large scale synthesis of<br />
(4R,5R)-(-)-4,5-O-isoproylidene-2-cyclopentanone.<br />
V. R. Neelagiri, C. Moon,<br />
M. Neelagiri, K. Vines,H.Kim,R.Rajur<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 207<br />
Physical Organic Chemistry: Calculations,<br />
Mechanisms, Photochemistry and High-<br />
Energy Species<br />
S. Sieburth, Organizer<br />
E. Greer, Presiding<br />
1:00 425. Synthesis and characterization of<br />
the first nonacene derivative. I. Kaur,<br />
G. P. Miller<br />
1:20 426. Rational design of pentacene derivatives<br />
with truly exceptional photooxidative<br />
resistances. I. Kaur, G. P. Miller<br />
1:40 427. Ionic liquid impact on reaction<br />
outcomes: A rational mechanism-based<br />
approach. A. K. Croft,J.B.Harper,<br />
H. Yau, S. G. Jones, S. A. Barnes,<br />
J. M. Hook<br />
2:00 428. Computational studies on site-selective<br />
C-H oxidation. R. S. Paton,<br />
K. N. Houk<br />
2:20 429. Perylenediimide as base-pair surrogates<br />
in DNA hairpins: Effect of the<br />
number of base-pairs separating two PDI<br />
chromophores on stability and spectroscopic<br />
properties. T. A. Zeidan,<br />
F. D. Lewis<br />
2:40 430. Theoretical study of the groundstate<br />
electronics of acenes and substituted<br />
acenes including organothio substituted<br />
pentacenes, heptacenes, and<br />
nonacenes. R. P. Kopreski, G. P. Miller<br />
3:00 431. Probing CH – � interactions by<br />
dynamic NMR studies of substituted<br />
o-quinodimethane [60]fullerene Diels-Alder<br />
adducts. R. P. Kopreski,J.B.Briggs,<br />
G. P. Miller<br />
3:20 432. Bis-Peptide scaffolds as designed<br />
probes for electron transfer phenomena.<br />
M. F. Parker, C. E. Schafmeister,<br />
D. H. Waldeck<br />
3:40 433. Reduction of 4-tertbutylcyclohexanone<br />
with complex metalhydrides.<br />
S. Narayan, W. Diehl, J. Townsend<br />
4:00 434. pH-responsive particles for anticancer<br />
drug delivery. B. Gordon, D. Lim,<br />
E. Achinivu, C. Luckett, S. Ehrman,<br />
D. English<br />
4:20 435. Regio-selective radiofluorination<br />
of diaryliodonium salts. Y. Lee,<br />
M. Hodoscek, J. Chun, V. W. Pike<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 205A/B<br />
Robert Burns Woodward Memorial<br />
Symposium<br />
R. Williams, L. T. Scott, Organizers<br />
W. Greenlee, Organizer, Presiding<br />
1:30 436. Looking back: Linkage through<br />
structure, symmetry, synthesis, spectroscopy,<br />
and mechanism. T. R. Hoye<br />
2:20 437. Quinine! A story of chemistry, history,<br />
personalities, and ethics.<br />
R. M. Williams,A.C.Smith<br />
3:10 Coffee Break<br />
3:30 438. Was plagiarism involved in the development<br />
of the Woodward—Hoffmann<br />
rules? J. I. Seeman<br />
4:20 439. Towards linking tumor genomic<br />
signatures to cancer therapeutics.<br />
S. L. Schreiber<br />
90–TECH<br />
‡ Cooperative Cosponsorship<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
A. Abdel-Magid, Organizer<br />
8:00–10:00<br />
155, 156, 163, 188, 198, 202, 204, 210, 216,<br />
223, 227, 229, 231, 252, 254, 271, 299.<br />
See previous listings.<br />
583, 588, 590, 592, 595, 603, 615, 616, 624,<br />
631, 638, 641, 657, 658, 662, 666, 672,<br />
702, 708, 724, 740, 742, 744, 932, 934,<br />
936, 939, 940, 948, 949, 950, 959, 981,<br />
987, 988, 993, 997, 1008, 1021, 1023,<br />
1039, 1070, 1082, 1085, 1091, 1092. See<br />
subsequent listings.<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom East<br />
Arthur C. Cope and Arthur C. Cope<br />
Scholars Award Symposium<br />
S. Sieburth, Organizer<br />
G. Molander, Presiding<br />
8:00 440. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). Orotidine 5�monophosphate<br />
decarboxylase: Mechanism<br />
and intrinsic binding energy.<br />
J. A. Gerlt<br />
8:40 441. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). Molecular reporters<br />
for cellular imaging based on synthetic<br />
fluorophores and enzymatic ligases.<br />
A. Y. Ting<br />
9:20 442. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). Molecular imaging<br />
approaches to understanding chemistry<br />
in the brain. C. J. Chang<br />
10:00 443. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). Organic synthesis<br />
and molecular design in today’s medicine.<br />
A. K. Ghosh<br />
10:40 444. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). <strong>Chemical</strong> intervention<br />
into bacterial cell-cell signaling.<br />
H. E. Blackwell<br />
11:20 445. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). Imaging of single<br />
organic molecules in motion.<br />
E. Nakamura<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 205A/B<br />
Young Academic Investigators<br />
L. McElwee-White, H. Davies, Organizers,<br />
Presiding<br />
8:00 446. Strong CH hydrogen bonds and<br />
the photodriven regulation of anions.<br />
A. H. Flood, Y. Hua, K. P. McDonald,<br />
S. Lee<br />
8:30 447. <strong>Chemical</strong> insights from molecular<br />
force probes. R. Boulatov<br />
9:00 448. Cyclopropenones and cyclopropenium<br />
ions: Reaction, design, and catalysis.<br />
T. Lambert<br />
9:30 449. Developing the basic science and<br />
applications of boron(B)-nitrogen(N)-containing<br />
heterocycles. A. J. Marwitz,<br />
E. R. Abbey, P. G. Campbell, A. N. Lamm,<br />
S. Liu<br />
10:00 450. Enantioselective approach to<br />
lactones: Design, scope, and mechanism.<br />
V. M. Dong<br />
10:30 451. Metallonitrene/alkyne metathesis<br />
and beyond: Transition metal catalyzed<br />
oxidative amination for organic synthesis.<br />
S. B. Blakey<br />
11:00 452. Design and development of catalytic<br />
reactions involving organometallic<br />
nucleophiles. E. R. Jarvo<br />
11:30 453. Transition-metal catalyzed fluorination.<br />
T. Ritter<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 206A<br />
New Reactions and Methodology<br />
S. Sieburth, Organizer<br />
T. Driver, Presiding<br />
8:00 454. Rapid synthetic organic reaction<br />
analysis using ion mobility spectrometry.<br />
C. A. Krueger, C. Wu, A. J. Midey,<br />
S. X. Li, F. J. Antosz, Z. Zhang, G. Goetz<br />
8:20 455. Nucleophilic catalysis by anilines<br />
in reactions of reducing carbohydrates.<br />
M. B. Thygesen, H. Munch, K. J. Jensen<br />
8:40 456. Diversity-oriented synthesis of<br />
Gewald thiophene scaffolds via isocyanide-based<br />
multicomponent reactions.<br />
Y. Huang,A.Dömling<br />
9:00 457. Spiropiperidine and fused ring<br />
systems from pyridine dearomatization.<br />
S. G. Parameswarappa,F.C.Pigge<br />
9:20 458. Allylic C—H amination for the<br />
preparation of syn-1,3-amino alcohol motifs.<br />
G. T. Rice, M. White<br />
9:40 459. Novel approach to the synthesis<br />
of omeprazole: An anti-peptic ulcer<br />
agent. R. Bandichhor<br />
10:00 460. Ru-catalyzed ring-closing metathesis-isomerization<br />
cascade reactions.<br />
T. E. Nielsen, E. Ascic, J. F. Jensen<br />
10:20 461. Bismuth-initiated reactions toward<br />
stereoselective syntheses of tetrahydropyrans<br />
and dihydropyrans.<br />
R. J. Hinkle, R. F. Lambert,<br />
S. E. Ammann, L. C. Speight, J. Liu,<br />
Y. Lian<br />
10:40 462. Pyridine elaboration through direct<br />
functionalization reactions.<br />
J. J. Mousseau, A. B. Charette<br />
11:00 463. Palladium-catalyzed functionalization<br />
of alkenes via C-H activation using<br />
hypervalent iodine reagents.<br />
L. T. Pilarski, N. Selander, D. Böse,<br />
K. J. Szabó<br />
11:20 464. Asymmetric addition of organoindium<br />
and organobismuth reagents<br />
to electrophilic carbons.<br />
N. Balasubramanian, G. R. Cook,<br />
A. J. Ostlund<br />
11:40 465. Metal-free alkene dioxygenations<br />
using hydroxamic acids. V. A. Schmidt,<br />
E. J. Alexanian<br />
12:00 466. Formal [2 � 2 � 2] cycloaddition<br />
strategy based on an intramolecular<br />
propargylic ene reaction/Diels-Alder cycloaddition<br />
cascade.<br />
J. M. Robinson-Surry, T. Sakai,<br />
R. L. Danheiser<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 203<br />
Heterocycles and Aromatics<br />
S. Sieburth, Organizer<br />
W. Zhang, Presiding<br />
8:00 467. Patterns of �-electron delocalization<br />
in aromatic and antiaromatic organic<br />
compounds in the light of the Hückel’s<br />
4n�2 rule. J. Poater, F. Feixas, E. Matito,<br />
M. Solà<br />
8:20 468. Multicomponent reaction of cyanoacetamides:<br />
One starting material and<br />
many scaffolds. K. Wang, A. Doemling<br />
8:40 469. Convenient approach for the synthesis<br />
of isoxazoles and application to<br />
nucleoside and oligonucleotide conjugation.<br />
A. M. Jawalekar, F. P. Rutjes,<br />
F. L. van Delft<br />
9:00 470. Selective C-H arylation and alkenylation<br />
of free-(NH2) adenines and related<br />
heterocycles: Rapid access to potent<br />
Hsp90 inhibitors. S. Sahnoun,<br />
S. Messaoudi, J. Peyrat, J. Brion,<br />
M. Alami<br />
9:20 471. Isolation and characterization of<br />
an unusual N-alkenyl pyridone.<br />
C. E. Anderson<br />
9:40 472. Reactivity of tethered diyne-�,�unsaturated<br />
carbonyl compounds in<br />
[2�2�2] cyclizations: Synthesis and diversification<br />
of densely functionalized<br />
heterocyclic scaffolds. A. L. Jones,<br />
J. K. Snyder<br />
10:00 473. 2D adapted Su-Schrieffer-Heeger<br />
model for conducting polymer polypyrrole.<br />
M. Li,X.Lin<br />
10:20 474. Efficient synthesis of a thioglycosylated<br />
chlorins and isobacteriochlorins<br />
for bioimaging and diagnostics. S. Singh,<br />
J. P. Tome, M. Vinodu, C. M. Drain<br />
10:40 475. Rhodium-catalyzed cycloaddition<br />
of benzamides and alkynes via C-H/<br />
N-H activation. T. K. Hyster,T.Rovis<br />
11:00 476. Preparation and evaluation of<br />
steroid-porphyrin conjugates as photodynamic<br />
therapy agents. S. Sadler,R.Ray,<br />
G. B. Jones<br />
11:20 477. Aromaticity indices of thiophene<br />
and furan based on the NMR spectroscopic<br />
studies of 1-aryl-3-heteroarylpropen-1-ones.<br />
C. Lee<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 204B<br />
Metal-Mediated Reactions and Syntheses<br />
S. Sieburth, Organizer<br />
C. Douglas, Presiding<br />
8:00 478. Relating catalyst structure to reactivity:<br />
A rationally-designed NHC-Pd catalyst<br />
for amination and sulfination.<br />
M. G. Organ<br />
8:20 479. Development of a Pd(II)-catalyzed<br />
3-step cascade sequence to produce<br />
1-aryl-3-vinyl-isoindolines. F. J. Williams,<br />
E. Jarvo<br />
8:40 480. Novel and rapid access to Lysergic<br />
acid: A remarkable triple tandem<br />
domino reaction. A. Boyer, T. Gilles,<br />
M. Lautens<br />
9:00 481. Silylene transfer to allylic sulfides:<br />
Episulfonium ion formation to afford substituted<br />
silacyclobutanes. B. J. Ager,<br />
L. E. Bourque, K. M. Buchner,<br />
K. A. Woerpel<br />
9:20 482. Palladium-NHC catalyzed cyclopentannulation<br />
of diazabicyclic alkenes:<br />
Direct access to cyclopenta[b]benzofuran<br />
derivatives. B. Bhanu Prasad,<br />
A. E. Buechele, S. R. Gilbertson<br />
9:40 483. Nickel-catalyzed reductive crosscoupling<br />
of aryl halides with alkyl halides.<br />
D. A. Everson,D.J.Weix<br />
10:00 484. Apparent copper(II) catalyzed<br />
azide-alkyne cycloaddition.<br />
W. S. Brotherton,L.Zhu<br />
10:20 485. Systematic investigation into the<br />
nature of Au (I) catalysts using propargyl<br />
Claisen rearrangements. D. V. Vidhani,<br />
M. E. Krafft, J. W. Cran, M. Mariappan<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
10:40 486. Utilization of Stille cross coupling<br />
protocol for the synthesis of series of biaryl-8-oxabicyclo[3.2.1]octane-2-carboxylic<br />
acid methyl esters. L. Torun,<br />
P. C. Meltzer<br />
11:00 487. Palladium-catalyzed propargylic<br />
substitution with phosphorus nucleophiles.<br />
M. Kalek, M. Jezowska,<br />
J. Stawinski<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 207<br />
Material, Devices and Switches<br />
S. Sieburth, Organizer<br />
E. Bauer, Presiding<br />
8:00 488. Luminescent phosphonium-bearing<br />
polyelectrolytes. E. G. Tennyson,<br />
T. Maltais, R. C. Smith<br />
8:20 489. Novel crosslinking agents for the<br />
control of inter-pi-system interactions in<br />
organic semiconducting polymers.<br />
A. Mangalum, R. C. Smith<br />
8:40 490. High performance organic field effect<br />
transistors from an organic single<br />
crystal micro-ribbons by solution process.<br />
Y. Zhou, T. Lei, J. Pei, J. Wang<br />
9:00 491. Corannulene based blue emitters.<br />
P. Bachawala,J.Mack<br />
9:20 492. Easy access to a family of polymer<br />
catalysts from modular star polymers.<br />
V. O. Rodionov, H. Gao, S. Scroggins,<br />
D. A. Unruh, A. Avestro, J. M. Fréchet<br />
9:40 493. <strong>Chemical</strong> vapor detection using<br />
reduced graphene oxide. S. K. Manohar<br />
10:00 494. Boolean solid-state porosity<br />
switching in a molecular organic solid.<br />
J. T. Jones, T. Mitra, T. Hasell,<br />
D. Holden, J. Bacsa, A. Steiner,<br />
A. Trewin, A. I. Cooper<br />
10:20 495. Supramolecular coupling agents<br />
for adhesion promotion at interfaces.<br />
C. A. Anderson, D. W. Kuykendall,<br />
E. M. Briggs, S. C. Zimmerman<br />
10:40 496. Redox active mesoporous hybrid<br />
materials by incooperation of (oligo)phenothiazines<br />
into structured silica phases.<br />
A. W. Franz<br />
11:00 497. Functionalizable boron-incorporating<br />
polycyclic aromatics built upon the<br />
seven-membered borepin ring structure.<br />
A. Caruso Jr., M. A. Siegler, J. D. Tovar<br />
11:20 498. Sub-ppm nerve agent detection<br />
with chemically functionalized silicon<br />
nanoribbon field-effect transistors.<br />
A. Carella, S. Clavaguera, C. Celle,<br />
L. Caillier, S. Lenfant, D. Vuillaume,<br />
J. Simonato<br />
11:40 499. Synthesis and characterization of<br />
sulfated, dextran coated iron oxide nanoparticles<br />
for MRI of macrophages. C. Tu,<br />
A. Louie<br />
12:00 500. Expansile polymeric nanoparticles<br />
for the treatment of breast cancer.<br />
K. V. Zubris, A. P. Griset, R. Liu,<br />
Y. L. Colson, M. W. Grinstaff<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 204A<br />
Total Synthesis of Complex Molecules<br />
S. Sieburth, Organizer<br />
S. Wiskur, Presiding<br />
8:20 501. Synthetic studies on muraymycin<br />
A1. M. Kurosu, K. Li, C. Schneider<br />
8:40 502. Spirodiepoxide-based domino sequences<br />
in total synthesis. L. J. Williams<br />
9:00 503. Concise access to Xenicane diterpenes<br />
and close biogenetic relatives.<br />
L. J. Williams<br />
9:20 504. Fused bicyclo[2.2.2]octanes: Toward<br />
the core of atropurpuran.<br />
M. J. Smith, J. A. Malona, E. J. Sorensen<br />
9:40 505. Enantioselective synthesis of (�)isolysergol<br />
via ring closing metathesis.<br />
J. A. Deck, S. F. Martin<br />
10:00 506. Synthetic efforts mediate a<br />
structural reassigment of the M. tuberculosis-produced<br />
natural product, Edaxadiene.<br />
J. E. Spangler, C. A. Carson,<br />
E. J. Sorensen<br />
10:20 507. De novo asymmetric synthesis of<br />
several cleistriosides and cleistetrosides.<br />
B. Wu, M. Li, G. A. O’Doherty<br />
10:40 508. Evaluation of an oxidative BDring<br />
formation from a Diels-Alder derived<br />
pyrrole-imidazole intermediate en route<br />
to the polyheterocyclic core of<br />
palau’amine. T. Doundoulakis,<br />
C. J. Lovely<br />
11:00 509. Fragment-based domain shuffling:<br />
An approach facilitating downstream<br />
drug discovery. E. Comer,<br />
A. Clabault, H. Liu, L. A. Marcaurelle<br />
11:20 510. Total synthesis of jadomycin A<br />
and cyclitol analog of jadomycin B.<br />
E. U. Sharif, G. A. O’Doherty<br />
11:40 511. Enantioselective synthesis of indole<br />
alkaloids of the ervatamine-silicine<br />
group. B. Checa, N. Llor, M. Amat,<br />
J. Bosch<br />
Oligonucleotide Therapeutics Sponsored by<br />
CARB, Cosponsored by ANYL, BIOL, MEDI,<br />
and ORGN<br />
Process Chemistry: The Role of Organic<br />
Synthesis in Early Clinical Drug<br />
Development Sponsored by MEDI,<br />
Cosponsored by ORGN<br />
TUESDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 205A/B<br />
Young Academic Investigators<br />
L. McElwee-White, H. Davies, Organizers,<br />
Presiding<br />
1:00 512. Stimuli-responsive polymer-protein<br />
conjugates and “sweet-tooth” micelles.<br />
B. S. Sumerlin<br />
1:30 513. <strong>Chemical</strong> tools for mapping protein<br />
S-nitrosation. M. Xian<br />
2:00 514. Engineering Streptomyces bacteria<br />
as lignocellulosic biorefineries.<br />
J. K. Sello<br />
2:30 515. Painting the cysteine chapel: New<br />
tools to probe oxidation biology.<br />
K. S. Carroll<br />
3:00 516. Studying the bacterial cytoskeleton<br />
using a chemical biological approach<br />
provides new opportunities for antibiotic<br />
development. D. B. Weibel,Y.Eun,<br />
M. Foss<br />
3:30 517. <strong>Chemical</strong> approaches to the investigation<br />
of protein-membrane binding<br />
interactions using synthetic lipid probes.<br />
M. D. Best, M. D. Smith, D. Gong,<br />
M. M. Rowland, H. E. Bostic, E. A. Losey<br />
4:00 518. New unnatural products by harnessing<br />
biosynthesis. R. J. Goss<br />
4:30 519. Development and application of<br />
carbon–carbon bond forming reactions<br />
for organic synthesis. R. J. Thomson<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 206A<br />
New Technologies to Expedite Research in<br />
Organic Chemistry<br />
C. Welch, Organizer, Presiding<br />
1:00 520. New tools and technologies for<br />
supporting drug development.<br />
J. M. Hawkins<br />
1:30 521. Reaction discovery approaches to<br />
chemical diversity. J. A. Porco<br />
2:00 522. Low-barrier high-throughput experimentation<br />
tools for efficient chemistry<br />
development. S. D. Dreher<br />
2:30 523. Automation for enabling high<br />
throughput reaction discovery.<br />
J. C. Conrad, D. W. MacMillan<br />
3:00 524. Implementation of a flexible strategy<br />
for automating decision-enabling<br />
process development workflows.<br />
E. Rubin, T. Kudla, M. Liu, J. Qiu,<br />
V. Rosso, V. Vydra, R. Waltermire<br />
3:30 525. Automation and robotics in an academic<br />
organometallic chemistry research.<br />
S. C. Virgil,K.M.Kuhn,<br />
J. B. Matson, S. R. Golisz, N. Hazari,<br />
R. H. Grubbs, J. E. Bercaw, B. M. Stoltz<br />
4:00 526. Current state and future prospects<br />
for high throughput mass directed purification<br />
technologies. J. W. Eschelbach,<br />
G. Bi, L. Miller, W. Goetzinger<br />
4:30 527. Micro- and mesoscale flow synthesis<br />
promoted by microwave irradiation:<br />
Is it a sustainable technology?<br />
M. G. Organ<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 203<br />
Heterocycles and Aromatics<br />
S. Sieburth, Organizer<br />
D. Klumpp, Presiding<br />
1:00 528. Novel monomers and polymerization<br />
strategies for organic semiconducting<br />
polymers. R. C. Smith<br />
1:20 529. Steric coordination control in conducting<br />
metallopolymers: Photophysics<br />
and electrochemistry. R. C. Smith,S.He<br />
1:40 530. N-heteroacenes: Promising materials<br />
for organic electronic devices.<br />
A. L. Appleton,U.H.Bunz<br />
2:00 531. Construction of protected hydroxylated<br />
pyrrolidines using nitrogencentered<br />
radical cyclizations.<br />
M. Zlotorzynska, H. Zhai, G. Sammis<br />
2:20 532. Fluorous linker facilitated synthesis<br />
of heterocyclic systems. W. Zhang<br />
2:40 533. Process development of a Corticotropin-Releasing<br />
Factor 1 (CRF1) receptor<br />
antagonist. C. Sfouggatakis,<br />
S. Broxer, M. Fitzgerald, J. P. Sherbine<br />
3:00 534. Exploring the barriers to metalfree<br />
carbon nanotube growth. E. H. Fort,<br />
L. T. Scott<br />
3:20 535. Solid-phase synthesis of cleavable<br />
fluorescently labeled nucleotides for<br />
DNA sequencing. K. Ko, E. Roller,<br />
X. Huang<br />
3:40 536. New synthetic route to benzannulated<br />
corannulenes. N. J. Smith,<br />
L. T. Scott<br />
4:00 537. Design, synthesis and characterization<br />
of a diverse pyrazolopyrrolidinone<br />
library. L. E. Brown,S.E.Schaus<br />
4:20 538. Progress toward a [10,10] carbon<br />
nanotube end-cap. J. M. Quimby,<br />
L. T. Scott<br />
4:40 539. Resolution and racemization kinetics<br />
of cross-bridged cyclam.<br />
A. Y. Odendaal, B. T. Li, G. R. Weisman,<br />
E. H. Wong, J. A. Golen, A. L. Rheingold<br />
5:00 540. Synthesis of Lavendamycin analogs<br />
via cycloisomerization reactions of<br />
propargylamides. G. Verniest,<br />
D. England, X. Wang, N. De Kimpe,<br />
A. Padwa<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 204A<br />
Molecular Recognition and Self-Assembly<br />
S. Sieburth, Organizer<br />
Y. Luk, Presiding<br />
1:00 541. Noncovalent chemistry of �-extended<br />
tetrathiafulvalene derivatives and<br />
fullerenes. E. M. Perez, H. Isla,<br />
M. Gallego, N. Martin<br />
1:20 542. Cucurbit[n]uril – metal nanoparticle<br />
composites: Synthesis, self-assembly,<br />
and applications. T. Lee,S.Jones,<br />
R. Coulston, O. A. Scherman<br />
1:40 543. Triply interpenetrated covalent organic<br />
cages. T. Hasell,X.Wu,<br />
J. T. Jones, J. Bacsa, A. Steiner, T. Mitra,<br />
A. Trewin, D. J. Adams, A. I. Cooper<br />
2:00 544. Novel method for synthesizing<br />
self-assembled porous organic cages.<br />
S. Jiang, D. Adams, A. Trewin, A. Cooper<br />
2:20 545. Anionic amphiphilic dendrimers as<br />
broad spectrum antimicrobial agents.<br />
M. A. Mintzer, M. W. Grinstaff<br />
2:40 546. Coordination vs. hydrogen bonddriven<br />
self-assembly: A directed stereospecific<br />
single crystal – single crystal<br />
(SCSC) solid-state photodimerization of a<br />
trisubstituted olefin. E. Elacqua,<br />
J. C. Sumrak, L. R. MacGillivray<br />
3:00 547. Pharmaceutical co-crystals of<br />
chiral APIs: Crystal engineering and solidstate<br />
properties. E. Elacqua, S. Chen,<br />
R. F. Henry, G. G. Zhang,<br />
L. R. MacGillivray<br />
3:20 548. Turn-on fluorescence: Utilizing the<br />
principles of dynamic combinatorial<br />
chemistry for developing molecular sensors.<br />
M. V. Maddipatla, A. M. Roland,<br />
M. L. Waters, M. R. Gagné<br />
3:40 549. Preparation of [3]pseudorotaxanes<br />
and pseudorotaxane-type non-covalent<br />
polymers based on bis(meta-phenylene)-32-crown-10<br />
cryptand. Z. Niu,<br />
H. W. Gibson<br />
4:00 550. Self-assembly of dendronized triphenylenes<br />
into helical pyramidal columns<br />
and chiral supramolecular spheres.<br />
M. R. Imam, V. Percec<br />
4:20 551. Supramolecular polymeric nanowires<br />
with tunable colors: Nucleation<br />
growth and direct functionalization.<br />
T. Lei, C. Cheng, C. Zheng, Y. Zhou,<br />
D. Liang, J. Pei<br />
4:40 552. Assembly of phthalocyanines into<br />
stacked columns within 2D covalent organic<br />
frameworks. E. L. Spitler,<br />
W. R. Dichtel<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 204B<br />
Metal-Mediated Reactions and Syntheses<br />
S. Sieburth, Organizer<br />
E. Alexanian, Presiding<br />
1:00 553. C-C Bond formation via double<br />
C-H functionalization. B. DeBoef<br />
1:20 554. Diastereoselective rhodium-catalyzed<br />
ene-cycloisomerization of alkenylidenecyclopropanes:<br />
Application to the<br />
total synthesis of (–)-�-kainic acid.<br />
P. A. Inglesby,P.A.Evans<br />
1:40 555. Gold-catalyzed Claisen rearrangement<br />
of allenyl vinyl ethers: Synthesis of<br />
substituted 1,3-dienes. M. E. Krafft,<br />
K. M. Hallal<br />
2:00 556. Addressing synthetic challenges<br />
via iridium-catalyzed C-H borylation.<br />
D. W. Robbins, J. F. Hartwig<br />
2:20 557. How to make a gold catalyst “immortal”.<br />
T. Graf, N. B. Bowden<br />
2:40 558. Iron-catalyzed 1,4-additions to<br />
1,3-dienes. J. Wu, T. Ritter<br />
3:00 559. Building molecular complexity by<br />
carbon-carbon bond activation and related<br />
catalytic processes. C. J. Douglas<br />
3:20 560. Kinetic studies of metal promoted<br />
cyclizations of aromatic enynes.<br />
A. Franklin<br />
3:40 561. Nickel-catalyzed direct synthesis<br />
of 1,4-difunctionalized compounds.<br />
S. K. Rodrigo,H.Guan<br />
4:00 562. Efficient synthesis of �-hydroxy<br />
ketones and �-amino ketones from allylic<br />
alcohols by catalytic formation of ruthenium<br />
enolates. A. Bartoszewicz,<br />
M. Jezowska, K. Laymand,<br />
B. Martín-Matute<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ORGN<br />
TECH–91
ORGN <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
4:20 563. Catalysis by metal nanoparticles.<br />
B. C. Ranu<br />
4:40 564. New iron complexes and their catalytic<br />
activity in C-C and C-O bond forming<br />
reactions. E. B. Bauer, M. Lenze,<br />
P. Shejwalkar<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 207<br />
Material, Devices and Switches<br />
S. Sieburth, Organizer<br />
I. Aprahamian, Presiding<br />
1:00 565. Solution processable high band<br />
gap hosts based on carbazole functionalized<br />
cyclic phosphazene cores for application<br />
in organic light-emitting diodes.<br />
M. Soh, S. Santamaria, H. Bolink,<br />
A. Sellinger<br />
1:20 566. Synthesis of phenylene-containing<br />
acenoid structures. R. R. Parkhurst,<br />
T. M. Swager<br />
1:40 567. Photochemically triggered radical<br />
reactions on graphitic carbons. L. Soldi,<br />
R. J. Cullen, D. Jayasundara, D. Murphy,<br />
E. Scanlan, S. Giordani, P. E. Colavita<br />
2:00 568. Optimization of OLED power efficiency<br />
by chemical structure modification.<br />
A. B. Padmaperuma, P. K. Koech,<br />
L. Cosimbescu, E. Polikarpov,<br />
A. Von Ruden, J. E. Rainbolt,<br />
J. S. Swensen, L. Wang, J. T. Darsell,<br />
D. J. Gaspar<br />
2:20 569. Development and utility of a lightresponsive<br />
MRI T2 agent. E. A. Osborne,<br />
A. Y. Louie<br />
2:40 570. C 3-symmetric conjugation supported<br />
by tris(hydrazone) platform: Elucidation<br />
of tautomeric state and application<br />
to amine vapor sensing. H. Lee,X.Song,<br />
H. Park, D. Lee<br />
3:00 571. Connecting metal centers in solution<br />
with water soluble multi-walled carbon<br />
nanotubes. J. M. Schnorr,<br />
T. M. Swager<br />
3:20 572. N, N�-dicarbazolyl-4,4�-biphenyl<br />
(CBP) isomers with high triplet energies<br />
as hosts for blue phosphorescence: Synthesis,<br />
spectroscopy, and OLEDs.<br />
P. Anzenbacher, G. V. Zyryanov,<br />
C. Pérez-Bolívar, S. Takizawa<br />
3:40 573. Gilch and Horner-Wittig Routes to<br />
poly(p-phenylene vinylene) derivatives incorporating<br />
monoalkyl defect-free 9,9-dialkyl-1,4-fluorenylene<br />
units.<br />
B. J. Laughlin,R.C.Smith<br />
4:00 574. Poly(p-phenylenevinylene) derivatives<br />
with defined conjugation segments<br />
and post-polymerization modification<br />
with chromophores. A. A. Buelt,<br />
R. C. Smith<br />
4:20 575. Wound healing modulation and<br />
acceleration with novel nitric oxide releasing<br />
hybrid nanoparticles.<br />
A. Friedman, G. Han, L. Martinez,<br />
J. Nosanchuk, J. Friedman<br />
4:40 576. Nanoparticles as a novel topical<br />
delivery vehicle for therapeutics targeting<br />
erectile dysfunction. A. Friedman,<br />
G. Han, M. Tar, A. Melman, K. Davies,<br />
J. Friedman<br />
5:00 577. Mimicry of amyloid �-sheets.<br />
P. Cheng,J.S.Nowick<br />
92–TECH<br />
‡ Cooperative Cosponsorship<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom East<br />
Arthur C. Cope and Arthur C. Cope<br />
Scholars Award Symposium<br />
S. Sieburth, Organizer<br />
P. A. Evans, Presiding<br />
1:20 578. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). C—H Oxidation in<br />
organic synthesis. M. White<br />
2:00 579. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). Complexity building<br />
reactions: Recent case studies.<br />
J. Johnson<br />
2:40 580. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). Palladium-catalyzed<br />
oxidation reactions for organic synthesis.<br />
M. S. Sigman<br />
3:20 581. Award Address (Arthur C. Cope<br />
Scholar Award (CSM) Sponsored by<br />
Arthur C. Cope Fund). Carbon dichloride:<br />
Dihalocarbenes sixty years after Hine.<br />
R. A. Moss<br />
4:00 582. Award Address (Arthur C. Cope<br />
Award Sponsored by Arthur C. Cope<br />
Fund). Pericyclic reactions: Reactivity,<br />
mechanisms, and dynamics. K. N. Houk<br />
Natural Products Biosynthesis Sponsored<br />
by BIOL, Cosponsored by MEDI and ORGN<br />
Oligonucleotide Therapeutics Sponsored by<br />
CARB, Cosponsored by ANYL, BIOL, MEDI,<br />
and ORGN<br />
TUESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Asymmetric Reactions and Syntheses,<br />
Biologically-Related Molecules &<br />
Processes, Material, Devices & Switches<br />
and Peptides, Proteins & Amino Acids<br />
A. Abdel-Magid, Organizer<br />
8:00–10:00<br />
583. Phosphine-catalyzed enantioselective<br />
formation of �-arylthio �,�-unsaturated<br />
esters from activated allenes.<br />
Y. Fujiwara, J. Sun, G. C. Fu<br />
584. Asymmetric aldol addition to cyclopentylpropynone<br />
gives key intermediate to<br />
antiviral drug candidate. J. Sieser,<br />
R. A. Singer, P. Bowles, D. Lafrance<br />
585. Enantioselective total synthesis of<br />
streptorubin B. D. X. Hu, M. D. Clift,<br />
R. J. Thomson<br />
586. Enantioselective bromolactonization of<br />
conjugated enynes. W. Zhang, S. Zheng,<br />
N. Liu, J. B. Werness, W. Tang<br />
587. Organocatalytic enantioselective hydroxyalkylation<br />
of indoles with trifluoroacetaldehyde<br />
hemiacetal catalyzed by<br />
cinchona alkaloids. D. Borkin,S.Landge,<br />
B. Torok<br />
588. Enantioselective Friedel-Crafts alkylation<br />
of indoles with chiral �-phenyl benzylic<br />
cations: Asymmetric synthesis of<br />
anti-1,1,2-triarylalkanes. J. Y. Chung,<br />
D. Mancheno, P. G. Dormer, R. G. Ball,<br />
N. N. Tsou<br />
589. Sulfinimine-mediated asymmetric synthesis<br />
of anti-a-alkyl b-amino Weinreb<br />
amides and ketones. P. Xu, F. A. Davis<br />
590. Asymmetric transfer hydrogenation of<br />
quinolines using tethered Ru (II) catalysts.<br />
V. Parekh, I. Lennon, J. Ramsden,<br />
M. Wills<br />
591. Highly active water-soluble and recyclable<br />
organocatalyst for the asymmetric<br />
1,4-conjugate addition of carbanion to<br />
�,�-unsaturated aldehydes. B. Ni,<br />
S. Ghosh, K. Dhungana, A. D. Headley<br />
592. Stereoselective copper-catalyzed synthesis<br />
of chiral 1,2- hydroxyalkyl moieties.<br />
M. Fañanás Mastral, B. L. Feringa<br />
593. Highly efficient synthesis of chiral epoxides<br />
via borane reduction of 2-haloketones<br />
catalyzed by spiroborate ester:<br />
Application to the synthesis of optically<br />
pure 1,2-hydroxy ethers and 1,2-azido alcohols.<br />
M. Ortiz-Marciales, K. Huang,<br />
H. Wang, M. De Jesús, C. Torruellas,<br />
W. Correa, V. Stepanenko<br />
594. Facile synthesis of [1,2,4]-triazolo[4,3-<br />
A]-pyridine and related derivatives. J. Liu,<br />
X. Lin, E. Liu<br />
595. Origin of stereoselectivity induced by<br />
Evans’ oxazolidinones in furan–oxyallyl<br />
(4�3) cycloadditions. E. H. Krenske,<br />
K. Houk, A. G. Lohse, J. E. Antoline,<br />
R. P. Hsung<br />
596. First asymmetric total synthesis of 3,3�biflavanone.<br />
B. Ma<br />
597. Highly selective organocatalytic<br />
Michael-Michael cascade reaction gives<br />
fused carbocycles. P. G. McGarraugh,<br />
S. E. Brenner<br />
598. Novel applications of BINOL-phosphates<br />
in asymmetric catalysis.<br />
A. Zamfir, C. Baudequin, S. B. Tsogoeva<br />
599. Asymmetric ketone and imine reductions<br />
using ruthenium catalysts.<br />
J. Hopewell, M. Wills, J. E. Martins<br />
600. Catalytic asymmetric synthesis of highly<br />
functionalized cis-aziridines via a general<br />
method for versatile diazoketones.<br />
H. Ren,W.D.Wulff<br />
601. Asymmetric synthesis of di- and trisubstituted<br />
cyclopropanes through an intramolecular<br />
ring closure.<br />
M. M. Mulhern, J. M. Kallemeyn, Y. Ku<br />
602. Synthetic strategies towards the synthesis<br />
of enantiopure diamines predicted<br />
to be a hundred million fold more basic<br />
than the original proton sponge.<br />
S. Purser, R. W. Alder, C. P. Butts,<br />
G. C. Lloyd-Jones<br />
603. Asymmetric organocatalysis using<br />
DPEN and proline derivatives.<br />
C. V. Manville, M. Wills, G. Docherty,<br />
G. Woodwood, R. Padda<br />
604. Recyclable fluorous organocatalysts for<br />
asymmetric synthesis. Z. Zhang,<br />
L. Wang, H. Zeng, W. Zhang<br />
605. Double stereodifferentiation in the imine<br />
substituent in aziridinations with diazoesters.<br />
L. Huang, Y. Zhang,<br />
W. D. Wulff<br />
606. CB-1 receptor antagonist process development.<br />
E. Reiff, L. Hobson,<br />
S. Brueggemeier, R. Deshpande,<br />
L. Greene, S. Kim, J. Li, L. Li, D. Lin,<br />
O. Lyngberg, M. Mahoney, G. Powers,<br />
X. Qian, B. Remy, V. Rosso, M. Sandoval,<br />
E. Tang, P. Tattersall, K. TenHuisen,<br />
C. Wei<br />
607. Donor-acceptor cyclopropanes as<br />
building blocks in (3�2) annulation reactions.<br />
A. T. Parsons, A. G. Smith,<br />
J. S. Johnson<br />
608. Practical stereoselective synthesis of<br />
(�)-polyoxamic acid via enatioselective<br />
phase-transfer catalytic Michael reaction<br />
and diastereoselective dihydroxylation.<br />
Y. Lee,S.Jew,H.Park<br />
609. Synthesis of microsclerodermins F, G,<br />
H&I.A. H. Rathi, T. J. Donohoe<br />
610. Development of a practical and efficient<br />
synthesis of chloromethyl 2-ethoxy-2methylpropanoate.<br />
W. Cai,<br />
R. Colon-Cruz, N. D. Ide, Z. Peng,<br />
J. A. Ragan, B. C. Vanderplas<br />
611. Design and synthesis of VANOL and<br />
VAPOL derivatives as new ligands.<br />
Y. Guan,W.D.Wulff<br />
612. Sample loading techniques for large<br />
scale flash chromatography. J. E. Silver,<br />
O. Mneimne, R. Pipes, M. Drooby<br />
613. Asymmetric electrocyclization induced<br />
by chiral oxazoline auxiliaries. K. Kim,<br />
K. A. Parker<br />
614. Vinylogous Mukaiyama approaches towards<br />
the stereoselective synthesis of<br />
bielschowskysin and norsecurinines.<br />
A. G. Macabeo, O. Reiser<br />
615. Organocatalytic addition of oxindoles to<br />
nitrosobenzene. R. Rios, X. Companyó,<br />
A. Moyano<br />
616. Regiocontrolled asymmetric �,�-bisand<br />
�,�,��,��-tetraalkylation of ketones<br />
via N-amino cyclic carbamate chiral auxiliaries.<br />
S. E. Wengryniuk,D.Lim,<br />
D. M. Coltart<br />
617. Design and synthesis of Cobalt(II) porphyrin<br />
catalysts for stereoselective interand<br />
intro-molecular cyclopropanation.<br />
X. Xu, S. Zhu, X. Cui, H. Lu, R. Joshua,<br />
P. Zhang<br />
618. Synthesis of functionalized cyclopentenones<br />
via Diels-Alder reaction of anthracene.<br />
G. Eaksinitkun,<br />
W. Phutdhawong, W. Phutdhawong<br />
619. Enantioselective synthesis of 1-vinyltetrahydroisoquinolines<br />
via Pd-catalyzed intramolecular<br />
allylic amination using novel<br />
diphosphonites and its application for the<br />
formal total syntheses of Schulzeines<br />
A-C. C. Lin,I.Ojima<br />
620. Enantioselective synthesis of 1-vinyltetrahydroisoquinolines<br />
through Pd-catalyzed<br />
intramolecular asymmetric allylic<br />
amination using novel monophosphoramidite<br />
ligands. C. Chien,I.Ojima<br />
621. Optically active 2-aryl cycloalkanones<br />
by catalytic asymmetric carbon insertion.<br />
V. L. Rendina,D.C.Moebius,<br />
J. S. Kingsbury<br />
622. Structure enantioselectivity relationship<br />
studies involving cinchona alkaloid<br />
dimers for the the stereoselective organocatalytic<br />
chlorolactonization.<br />
S. E. Marshall, R. Yousefi,<br />
A. Jaganathan, B. Borhan<br />
623. Recent developments in the Pauson<br />
Khand reaction of allenol-acetates.<br />
S. Majumder, K. M. Brummond<br />
624. Asymmetric synthesis of cyclic cis-�amino<br />
acid derivatives using sulfinimines<br />
and prochiral Weinreb amide enolates.<br />
N. Theddu, F. Davis<br />
625. Synthesis of novel Spiroaminoborates<br />
esters derived from nonracemic 1,2-Aminoalcohols.<br />
M. De Jesús, M. M. Padilla,<br />
V. Stepanenko, M. Ortiz<br />
626. Catalytic enantioselective synthesis of<br />
chiral allylboronates. J. E. Schultz,<br />
G. R. Cook<br />
627. Asymmetric [4 � 3] cycloaddition applied<br />
to the synthesis of barekoxide and<br />
barekol. Y. Lian, L. Miller, R. Sarpong,<br />
H. M. Davies<br />
628. Highly enantioselective rhodium-catalyzed<br />
cyclopropenation of terminal<br />
alkynes with styryldiazoacetates.<br />
J. F. Briones<br />
629. Chiral promoters to control the stereochemical<br />
outcome of glycosylation reactions.<br />
D. Liu, S. Sarrafpour, W. Guo,<br />
B. M. Goulart, C. S. Bennett<br />
630. Toward the asymmetric total synthesis<br />
of antascomicin B via an asymmetric<br />
transfer hydrogenation, an Ireland-<br />
Claisen (ICR), and an allylic diazene (ADR)<br />
rearrangement sequence. D. R. Clay,<br />
M. C. McIntosh<br />
631. Studies toward the enantioselective<br />
syntheses of 3-hydroxy-2-oxindole containing<br />
natural products. A. J. Ostlund,<br />
B. Narayanaganesh, G. R. Cook<br />
632. Ring opening of aziridinium ions: Synthesis<br />
of enantiomerically pure amines<br />
and substituted trans-allyl amines.<br />
X. Sun, Y. Chen, H. Song, I. Sin,<br />
M. Dadwal, H. Chong<br />
633. Synthesis and enantioselective and regioselective<br />
ring opening of aziridinium<br />
ions. Y. Chen, H. Song, X. Sun,<br />
W. Sawyer, I. Sin, M. Dadwal, H. Chong<br />
634. Rate accelerated Wittig reactions using<br />
water as a medium employing stabilized<br />
ylides and aldehydes. M. B. Bergdahl,<br />
A. El-Batta, C. Jiang, A. L. Cooksy<br />
635. Double stereo-differentiation of chiral<br />
imines in catalytic asymmetric aziridination<br />
reaction. M. Mukherjee,<br />
V. R. Pulgam, W. D. Wulff<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
636. Unique multicomponent catalytic asymmetric<br />
aziridination reaction via substrate<br />
induced catalyst formation. A. K. Gupta,<br />
M. Mukherjee, G. Hu, W. D. Wulff<br />
637. Iridium-catalyzed asymmetric hydrogenation<br />
of N-aryl imines and N-H imines.<br />
W. Li, G. Hou, X. Zhang<br />
638. Catalytic enantio- and regioselective<br />
additions of silyl ketene acetals into<br />
diketones. T. Luanphaisarnnont,<br />
D. A. Evans<br />
639. Demonstration of the octant rule using a<br />
simple CA3D molecular modeling.<br />
Y. Kang<br />
640. Probes for narcotic receptor mediated<br />
phenomena: Synthesis of C8-substituted<br />
5-(3-hydroxyphenyl)-N-phenylethylmorphans.<br />
Y. Peng, A. E. Jacobson,<br />
K. C. Rice<br />
641. Biodegradable hybrid polymers for regenerative<br />
medicine. M. Beyer,<br />
R. Houbertz, T. Stichel, G. Sextl<br />
642. Activity-based chemical profiling of Mycobacterium<br />
tuberculosis H37Rv,<br />
CDC1551, and HN878. L. M. Smith,<br />
R. D. Smith, A. T. Wright, C. D. Nicora<br />
643. Synthesis and biochemistry of novel fluorogenic<br />
substrates for �-lactamase detection.<br />
A. Rukavishnikov, H. Kang,<br />
K. R. Gee, S. Corry<br />
644. Substituted biaryls as alpha-helix mimetics.<br />
A. B. Williams, R. N. Hanson<br />
645. New fluorescent dibenzocyclooctyne<br />
analogs for live-cell studies using copper<br />
free click chemistry. A. Chen, H. Engel,<br />
Y. Hu, J. Liu, A. Rukavishnikov,<br />
T. Schwenger, Y. Wu, R. Aggler,<br />
B. Agnew, K. Gee, H. Kang<br />
646. Dual bioresponsive polymeric nanoparticles.<br />
J. Sankaranarayanan,<br />
E. Mahmoud, G. Kim, A. Almutairi<br />
647. Synthesis and electrophysiological<br />
characterization of a tetherable ligand<br />
specific for GABA A receptors.<br />
M. Feliciano,J.J.Chambers<br />
648. Fluorescein derivatives functionalized<br />
silsesquioxnae/ bridged silsesquioxane<br />
nanoparticles: Synthesis, characterization,<br />
and particle morphology.<br />
C. J. Simouth, J. Binion,<br />
H. P. Rathnayake<br />
649. Synthesis of deuterated enantiomer of<br />
CP55,940, d 6-(-)-CP55,940. K. Cheng,<br />
T. Kimura, K. Gawrisch, A. E. Jacobson,<br />
K. C. Rice<br />
650. Fluorescent detection and proteomic<br />
profiling of acetylated proteins using<br />
bioorthogonal chemical reporters.<br />
Y. Yang, J. M. Ascano, H. C. Hang<br />
651. Optimization of the preparation of 4-<br />
(methoxycarbonyl)bicyclo[2.2.1]heptane-<br />
1-carboxylic acid. X. Qian, A. Ramirez,<br />
M. Y. Wong, K. Yamamoto, F. Rita,<br />
Z. Guo, A. Goswami, B. Patel,<br />
R. O. Cann, R. P. Deshpande<br />
652. Novel bitriazoyl nucleosides with antiviral<br />
and anticancer activity. Y. Xu,F.Qu<br />
653. Synthesis of photocleavable peptide<br />
conjugates using click chemistry.<br />
F. Rossi, J. A. Baccile, C. L. Barnes,<br />
D. L. Drew, M. J. Houghton<br />
654. Synthesis of phosphatidic acid mimetics<br />
for competitive binding with the receptor<br />
AFAP-110 in a pathway relevant to<br />
breast and ovarian cancer.<br />
M. Cuccarese, G. A. O’Doherty,<br />
R. Vemula, D. Flynn<br />
655. Synthesis of benzaldehydes possessing<br />
aminoethyl substitutents and their use in<br />
the production of curcumins and 1,5diarylpent-1,4-dien-3-ones.<br />
S. Helmy,<br />
R. Tincher, P. D. Hampton<br />
656. Diversity-oriented synthesis utilizing a<br />
two-directional macrocyclisation approach.<br />
K. M. O’Connell, H. T. Horsley,<br />
D. R. Spring<br />
657. SAR and protein binding studies of<br />
Marpin, a recently discovered synthetic<br />
Chk1-phosphorylation inhibitor.<br />
B. Manteau, K. Brummond, P. Nghiem,<br />
M. Kawasumi<br />
658. Aqueous phosphine-mediated ligations<br />
of nitroxyl (HNO): Kinetic analysis and detection<br />
of enzyme-generated HNO.<br />
J. A. Reisz, E. Bechtold, M. W. Wright,<br />
S. King<br />
659. Fundamental amidine diazeniumdiolate<br />
chemistry: Applications in the bio-medical<br />
realm. D. Biswas, F. DeRosa,<br />
M. Kibbe, M. L. Citro, L. K. Keefer,<br />
J. A. Hrabie<br />
660. Nucleophilic catalysis expands repertoire<br />
for hydrazine-based bioorthogonal<br />
labeling of �-tubulin C-terminus.<br />
A. R. Blanden, O. Dilek, K. Mukherjee,<br />
M. Loew, R. Kuperman, S. L. Bane<br />
661. Novel approach for detection of lacZ<br />
using 1 H MRI agents. J. Yu,<br />
J. Magnusson<br />
662. Reactivity-dependent PCR: One-step<br />
amplification and in vitro selection.<br />
D. J. Gorin, A. Kamlet, L. McGregor,<br />
D. R. Liu<br />
663. Novel method to covalently-label native<br />
neurotransmitter receptors.<br />
A. M. Hussey, R. E. Combs-Bachmann,<br />
D. Vytla, I. Hafez, J. J. Chambers<br />
664. One-pot procedures for the preparation<br />
of fully protected carbohydrates.<br />
L. Chen, N. Kaila, P. Thakker<br />
665. Fused bicyclic ring systems with nitrogen<br />
bridgehead: Synthesis and biological<br />
evaluation. A. Pepe,Y.S.Kim,<br />
J. B. Trepel, S. V. Malhotra<br />
666. Sulfamide based inhibitors of tyrosyl-<br />
DNA phosphodiesterase 1 (Tdp1). J. Jun,<br />
T. S. Dexheimer, I. E. Weidlich,<br />
M. C. Nicklaus, Y. Pommier,<br />
S. V. Malhotra<br />
667. Employment of DNA-programmed<br />
chemistry for rapid reaction of macrocyclic<br />
lead compounds. D. Yan<br />
668. Photochromic effectors for native<br />
GABA-ergic signaling. D. Vytla,<br />
K. A. Medeiros, J. J. Chambers<br />
669. Studies towards the synthesis of the Cglycoside<br />
analog of antitumor antibiotic<br />
Bleomycin A 5. I. Sharma, D. Crich<br />
670. Solanesol-derived scaffold for multimerization<br />
of bioactive peptides.<br />
R. Alleti, V. Rao, L. Xu, R. J. Gillies,<br />
E. A. Mash<br />
671. Redoxchemistry of 8-oxopurine nucleosides<br />
and their potential role in mitigating<br />
photochemical damage in DNA.<br />
K. V. Nguyen, J. G. Muller, C. J. Burrows<br />
672. Development of a practical and convergent<br />
process for the preparation of sulopenem<br />
antibacterial CP-70,429.<br />
D. Nadkarni, J. Nelson, S. Brenek,<br />
T. Braish, S. Caron, M. Drexler, M. Ewing,<br />
R. Handfield, N. Ide, H. Perfect,<br />
J. Phillips, J. Teixeira, C. Wager,<br />
R. Weekly<br />
673. Reaction of pyrrolizidine alkaloid reactive<br />
metabolits with deoxyguanosine.<br />
Y. Zhao,P.P.Fu<br />
674. Solvent effects on the rate of photodimerization<br />
of orotic acid. J. Hahn<br />
675. Innovative technologies for natural<br />
products discovery. A. Y. Odendaal,<br />
D. J. Trader, E. E. Carlson<br />
676. Modulation of the phenyl substituents<br />
on the 1,1-diphenyl-hexahydro-oxazolo[3,4-a]pyrazin-3-one<br />
scaffold: Investigating<br />
the structural features necessary<br />
for antagonist activity toward the neuropeptide<br />
S receptor. J. A. Brinck,<br />
S. A. Habay, R. K. Reinscheid<br />
677. Kinetic and product analysis of the reactions<br />
of acyloxy nitroso compounds, a<br />
new class of HNO donors, with thiols.<br />
M. E. Shoman,J.DuMond,S.B.King<br />
678. Adventures in diversity-oriented synthesis.<br />
W. R. Galloway, D. R. Spring<br />
679. Cyclooctyne-modified oligonucleotide<br />
primers for post-PCR, strain-promoted<br />
“click” chemistry on DNA. I. S. Marks,<br />
K. J. Landmark, J. Kang, T. Taton<br />
680. Synthesis of the capture ligand, ethyl<br />
(4-nitrophenyl)[11-[(1,3-diazole)carbamate]undecyl]phosphonate.<br />
D. Stallings,<br />
B. Coleman, S. Contigiani, M. Moser,<br />
J. Boyd, J. Gardner<br />
681. Identification of pyrimidine adducts<br />
formed from the carcinogen N-nitrosomorpholine.<br />
N. H. Shah, J. C. Fishbein<br />
682. Effects of pyridine on the silylation of<br />
17�-ethinylestradiol and other steroidal<br />
hormones. Y. Zuo,Y.Lin<br />
683. Reactions of acyloxy nitroso compounds<br />
with thiols and aldehyde dehydrogenase.<br />
J. F. DuMond,S.King<br />
684. Two photon degradable hydrogels.<br />
G. Kim, J. Sankaranarayanan,<br />
E. Mahmoud, C. McFearin<br />
685. Oxidation of vitamin K: A free radical<br />
mechanism. D. E. Lewis<br />
686. Largazole analogs with modified zinc<br />
interacting moiety. P. R. Bhansali,<br />
L. Tillekeratne<br />
687. G-Quadruplex formation from lipophilic<br />
guanine derivatives. J. E. McCallum,<br />
J. McSweeney, S. Amare<br />
688. Ester and aza analogs of open-chain<br />
epothilones. S. R. Fedorka,<br />
L. Tillekeratne<br />
689. Total synthesis and biological activity of<br />
18(R)-HEPE. V. Krishnamurthy,<br />
E. L. Chaikof<br />
690. Library synthesis utilizing regioselective<br />
urea-based condensations with complex<br />
1,2-diketones toward the synthesis of cycloheptanes.<br />
B. Leng, J. Godell,<br />
A. Beeler, J. Porco<br />
691. Evaluation of diarylureas for activity<br />
against Plasmodium falciparum.<br />
Y. Zhang, M. Anderson, J. L. Weisman,<br />
M. Lu, C. J. Choy, V. A. Boyd, J. Price,<br />
M. Sigal, J. Clark, M. Connelly, F. Zhu,<br />
W. A. Guiguemde, A. P. Liou, T. R. Webb,<br />
J. L. DeRisi, R. K. Guy<br />
692. New nine-membered lactam libraries<br />
via ring-closing metathesis. L. Maina,<br />
J. A. DeCapo, N. Brown, K. R. Buszek<br />
693. Mechanistic degradation of high density<br />
polyethylene potable water materials.<br />
S. Mitroka, A. Whelton, T. Smiley,<br />
A. Dietrich, J. Tanko<br />
694. FRET based pattern recognition of isogenic<br />
cells differing in cell surface glycans.<br />
O. R. Miranda, A. Bajaj, S. G. Elci,<br />
S. Rana, K. Saha, R. L. Phillips,<br />
J. J. Bryant, I. Kim, D. Jerry, U. H. Bunz,<br />
V. M. Rotello<br />
695. Systematic control of the lactam/amide<br />
equilibrium in rhodamine amide derivatives.<br />
C. J. Stephenson,K.D.Shimizu,<br />
K. Yehl<br />
696. Highly-reversible electrochromic polycarbenes<br />
for photovoltaic applications.<br />
A. B. Powell,A.H.Cowley<br />
697. Synthesis and application of novel porphyrins<br />
for use in solar cells. M. Jurow<br />
698. New methods for phthalocyanine/naphthalocyanine<br />
synthesis. C. Lu, X. Chen,<br />
D. V. McGrath<br />
699. Dendronized thiopyrylium cyanines for<br />
photonic applications. A. Nantalaksakul,<br />
J. M. Hales, A. Scarpaci, J. D. Matichak,<br />
S. Barlow, J. W. Perry, S. R. Marder<br />
700. Thiophene based copolymer for organic<br />
solar cells. R. Anandakathir,<br />
S. Satapathi, J. Kumar<br />
701. Light-triggered release from and degradation<br />
of polymeric nanoparticles.<br />
N. Fomina, M. Sermsakdi, O. Edigin,<br />
A. Almutairi<br />
702. Cycloparaphenylenes with a twist.<br />
L. M. Gaworski, R. Jasti<br />
703. Computational design of multifunctional<br />
emitters. A. B. Padmaperuma,<br />
P. K. Koech<br />
704. Lanthanide metal-organic frameworks:<br />
Catalytic activity and structural changes<br />
during activation and catalysis.<br />
M. Gustafsson, A. Bartoszewicz,<br />
B. Martín-Matute, J. Sun, J. Grins,<br />
T. Zhao, Z. Li, G. Zhu, X. Zou<br />
705. Synthesis and characterization of polylactide-polybutadiene-polylactide<br />
triblock<br />
copolymers. N. Kim,J.Lee,<br />
C. Choochottiros, I. Chin<br />
706. Free radical copolymerization of 2-hydroxyethyl<br />
methacrylate terminated<br />
poly(L-lactide) with butyl acrylate. J. Lee,<br />
N. Kim, I. Chin<br />
707. Cyclacene and the organic synthesis of<br />
zigzag carbon nanotubes. P. J. Evans,<br />
R. Jasti<br />
708. Switching mechanism of a pH activated,<br />
hydrazone-based, configurational<br />
switch: Rotation vs. lateral inversion.<br />
S. M. Landge, I. Aprahamian<br />
709. Rigidly dendronized ions. D. Türp,<br />
K. Müllen<br />
710. Studies towards the rational synthesis<br />
of carbon nanotube junctions. E. Hirst,<br />
R. Jasti<br />
711. Synthesis and properties of new type of<br />
liquid crystal containing polycation tails in<br />
place of n-alkyl tails. M. Reynolds,<br />
A. LaFrate, C. Gabriel, D. Gin<br />
712. Synthesis, structure and performance<br />
of liquid-crystalline proton conductors.<br />
D. Basak, S. K. Surampudi,<br />
S. Christensen, C. Versek, D. Toscano,<br />
J. Harvey, S. M. Auerbach,<br />
M. T. Tuominen, R. Hayward,<br />
D. Venkataraman<br />
713. Approach for the synthesis of selectively<br />
deuterated methyl acrylate.<br />
J. Yang, P. V. Bonnesen, M. S. Kilbey,<br />
K. Hong<br />
714. Design of porous sp 2 -hybridized carbon<br />
nanomaterials. H. Xiao, R. Jasti<br />
715. Optical properties of cyclic dimers of a<br />
pentamethine dye: Moving beyond exciton<br />
theory. C. A. Liberko, J. Valenstein,<br />
J. Shanata<br />
716. Donor-acceptor cross conjugated macrocycles.<br />
W. C. Leu, C. Hartley<br />
717. Zinc(II)-controlled configurational rotary<br />
switch based on a hydrazone backbone.<br />
X. Su, I. Aprahamian<br />
718. Benzothiadiazole-based donor-acceptor<br />
alternating polymer sensitizers for<br />
dye-sensitized solar cells. Z. Fang,<br />
A. Eshbough, K. S. Schanze<br />
719. Liquid crystalline tetrabenzo[18]cyclynes.<br />
A. N. Scioneaux, A. Wilson, S. Hartley<br />
720. Stilbene tethered porphyrin jaw: Synthesis,<br />
characterization, and fullerene<br />
binding studies. M. Fathalla,<br />
J. Jayawickramarajah<br />
721. Bottom-up synthesis of oligo(orthophenylenes).<br />
J. He, J. L. Crase, C. Hartley<br />
722. Syntheses of aryleneethynylene dendrimers<br />
with D 3horC 2v symmetry with<br />
electrooptical applications. G. K. Joshi,<br />
K. N. Fuhr, W. F. Schnatter,<br />
N. Matsunaga, J. Chao, A. Khan<br />
723. New non-planar push-pull chromophores:<br />
Synthesis and characterization.<br />
M. Chiu, M. Kivala, S. Kato,<br />
F. Diederich<br />
724. Conducting azepine polymers. C. Song,<br />
D. B. Walker,T.M.Swager<br />
725. Controlling contact electrification with<br />
photoreactive polymers. S. W. Thomas,<br />
S. Friedle<br />
726. Functional polymeric blends for sensing<br />
applications. J. M. Lobez,T.M.Swager<br />
727. Fluorescence resonance energy transfer<br />
as a new tool for the identification of<br />
mechanically-induced chemical reactions.<br />
M. J. Kryger,S.A.Odom,<br />
H. Enozawa, J. S. Moore<br />
728. Dicyanofulvenes as effective electronaccepting<br />
moieties: Toward the synthesis<br />
of n-type conducting polymers.<br />
T. L. Andrew, T. M. Swager, J. R. Cox<br />
729. Synthesis and fabrication of nanoporous<br />
thin-films based on the polymerization<br />
of a gemini ammonium amphiphile<br />
for molecular-size filtration applications.<br />
B. R. Wiesenauer, E. S. Hatakeyama,<br />
M. Zhou, R. D. Noble, B. J. Elliott,<br />
D. L. Gin<br />
730. Preparation of semiconducting nanoparticles.<br />
Y. Li, Y. Xu, G. P. Miller<br />
731. Synthesis of air-stable, moisture-resistant,<br />
and tunable perfluoroalkylated<br />
arenes for optoelectronics. H. Sun,<br />
A. Putta, J. Kloster<br />
732. Effect of side chains on the electron<br />
transfer rates in Donor-Bridge-Acceptor<br />
dyads. A. Bheemaraju,T.L.Benanti,<br />
S. K. Surampudi, M. Pourmand,<br />
M. Achermann, D. Venkataraman<br />
733. Click-BODIPY dyes as fluorescent<br />
probes for amyloidogenic biomolecules.<br />
N. W. Smith, B. B. Polenz, E. L. Deal,<br />
C. B. Boyd, S. R. Vempati, S. V. Dzyuba<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ORGN<br />
TECH–93
ORGN <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
734. Efficient synthesis of protected aminoxyacyl<br />
sterols and terpenes.<br />
B. Draghici, B. El-Dien M. El-Gendy<br />
735. Encapsulation and release of Histagged<br />
proteins from collagen microflorettes.<br />
D. Ernenwein, M. M. Pires,<br />
J. Chmielewski<br />
736. <strong>Chemical</strong> tools for investigating cell migration:<br />
Semisynthesis of photoactivated<br />
myosin regulatory light chain. B. Goguen,<br />
B. Imperiali<br />
737. Total synthesis of tubulysins. T. Shibue,<br />
M. Yamazaki, H. Ebisu, T. Hirai,<br />
I. Okamoto, N. Morita, O. Tamura<br />
738. Design and synthesis of novel peptidomimetic-AApeptide.<br />
Y. Hu, J. Cai<br />
739. Chirality control in peptide-metal complexes.<br />
M. Vázquez,G.Rama,<br />
J. M. Blanco, H. Ishida,<br />
M. Vázquez-López<br />
740. New fullerene array based on peptide<br />
nanotubes. C. Reiriz, R. J. Brea,<br />
J. R. Granja<br />
741. Controlled protein trans-splicing by using<br />
photo-labile protecting group.<br />
Y. Kwon<br />
742. Stitching �-helical peptides by tandem<br />
ring-closing metathesis. Y. Kim,<br />
P. S. Kutchukian, C. M. Crenshaw,<br />
S. S. Stanton, A. Chang, G. L. Verdine<br />
743. Tag-assisted solution-phase peptide<br />
synthesis featuring multistep process.<br />
M. Sugai, T. Gegen, S. Kim, K. Chiba<br />
744. Origin of conformational organization of<br />
�-peptide nucleic acids (PNAs).<br />
M. J. Crawford, R. Gil, D. H. Ly<br />
745. Synthesis and structure-activity relationship<br />
(SAR) of tetrapeptides with Phe<br />
analogs reversible inhibitors of thrombin.<br />
C. C. Clement, M. Philipp<br />
746. Thioester-based strategy for synthesis<br />
of linear and cyclic peptide libraries.<br />
S. Santra, M. E. Bucks, S. N. Savinov<br />
747. Bioactive synthetic nanostructured extracellular<br />
matrices for biomedical applications.<br />
W. Suh, G. D. Stucky, M. Tirrell<br />
748. Withdrawn<br />
749. Evidence for the utilization of formate as<br />
a substrate by carbamoyl phosphate synthetase.<br />
L. Lund, H. J. Williams,<br />
F. M. Raushel<br />
750. <strong>Chemical</strong> ligations of S-acyl isopeptides.<br />
S. R. Tala, N. E. Abo-Dya,<br />
A. R. Katritzky<br />
751. Modifying proteins with kosmotropes<br />
for enhanced activities and targeted drug<br />
delivery. D. Prashar,D.Cui,Y.Shi,<br />
D. Bandyopadhyay, J. Dabrowiak,<br />
Y. Y. Luk<br />
752. Polyvinylimidazoles/pyridoxamines with<br />
hydrophobic chains as enzymes/co-enzymes<br />
mimics for the catalysis of the<br />
transamination reaction in water.<br />
R. Skouta, S. Wei, R. Breslow<br />
753. On the design and synthesis of activatable<br />
dsDNA-binding peptides.<br />
A. Jiménez, B. Martínez, O. Vázquez,<br />
M. E. Vázquez, J. L. Mascareñas<br />
754. Proteins for imaging applications.<br />
P. D. Garimella, M. B. Francis<br />
755. i,i�3 Stapling: Highly stereospecific<br />
ring-closing metathesis on �-helices.<br />
Y. Kim, S. Shim, M. J. Kolar,<br />
P. S. Kutchukian, G. L. Verdine<br />
756. Targeting proteins with iron-based oxidants.<br />
J. Prakash, J. J. Kodanko<br />
757. Strand invasion of extended, mixed-sequence<br />
B-DNA by �PNAs (�-peptide nucleic<br />
acids). G. He, S. Rapireddy,<br />
R. Bahal, B. Sahu, D. H. Ly<br />
758. Design and synthesis of highly functionalized<br />
and complex Bis-Peptide macromolecules.<br />
M. F. Parker,<br />
C. E. Schafmeister<br />
759. Catalytic asymmetric intramolecular hydrosilylation<br />
of 2-alkyl allyl silyl ethers.<br />
S. Singh, S. M. Sieburth<br />
760. Unprecedented cross coupling reaction<br />
of allyltrifluroborate and benzoyl halides.<br />
K. Liu, M. Al-Masum<br />
94–TECH<br />
‡ Cooperative Cosponsorship<br />
761. Palladium-catalyzed microwave irradiated<br />
direct coupling of potassium arylvinyltrifluoroborates<br />
and benzoyl chlorides.<br />
E. Ng, M. Wai, M. Al-Masum<br />
762. Chiral synthesis of novel anticancer<br />
�-lactams. S. Mukherje, I. Banik,<br />
S. Samajdar, F. F. Becker, B. K. Banik<br />
763. Diasteroselectivity of �-lactam formation<br />
with polyaromatic imines: Synthesis<br />
of novel anticancer agents.<br />
D. Bandyopadhyay, L. C. Turrubiartes,<br />
F. F. Becker, B. K. Banik<br />
764. Synthetic aspects and photochemical<br />
studies of deoxy-adenosine analogs.<br />
B. Saha, M. S. Platz<br />
765. Synthesis and NMR studies of imidazole-2-carboxamides<br />
as DNA bases<br />
reader. F. Liang, S. Lindsay, P. Zhang<br />
766. Synthesis and characterization of functionalized<br />
graphite nanofibers.<br />
T. Pellenbarg, J. A. Hull, A. Tuladhar,<br />
H. Yoo, E. Assenmacher, R. Giuliano<br />
767. Hydroarylation of 2-azabicyclo[2.2.1]<br />
hept-5-en-3-one followed by ring opening<br />
as a facile and stereodefined synthesis<br />
of trisubstituted cyclopentanes.<br />
J. Polivkova, D. W. Piotrowski<br />
768. New methodology for the stereoselective<br />
synthesis of unnatural a-amino acids.<br />
L. J. Drummond, A. Sutherland<br />
769. Solution synthesis of peptides using<br />
solid phase reagents and microwave<br />
heating. R. Lundin, P. Ioannidis<br />
770. Total synthesis of erythronolides.<br />
K. Liu, L. J. Williams, H. Kim<br />
771. Cyclodextrin/dextran based drug carriers<br />
for a controlled release of hydrophobic<br />
drugs in zebrafish embryos. K. Peng,<br />
I. Tomatsu, A. Kros<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom East<br />
Technical Achievements in Organic<br />
Chemistry Award Symposium<br />
J. Cohen, C. Welch, Organizers<br />
P. Mahaney, Presiding<br />
8:00 Introductory Remarks<br />
8:05 772. Identification and optimization of<br />
1,5-diarylpyrazoles as CCK-1 receptor<br />
antagonists. K. McClure,<br />
J. G. Breitenbucher, L. Gomez, C. Sehon,<br />
M. Morton, T. D. Barrett, J. M. Friedman,<br />
C. E. Prendergast, V. Moreno, J. Pyati,<br />
K. Figueroa, L. Li, N. P. Shankley<br />
8:30 773. Overcoming synthetic challenges<br />
to prepare novel gamma-secretase inhibitors.<br />
C. M. Semko<br />
8:55 774. Discovery of PF-610355: An inhaled<br />
once-daily Beta-2 adrenoceptor<br />
agonist for asthma and COPD.<br />
P. A. Glossop<br />
9:20 775. Development of processes supporting<br />
the manufacture of 5-amino-3bromo-4-pyridinyl<br />
substituted isothiazoles.<br />
P. C. Heath, D. S. Coffey,<br />
M. K. Hawk, J. F. Mick<br />
9:45 776. Use of organic rheology control<br />
agents in water-borne and solvent-borne<br />
paint systems and ring opening polymerization<br />
(ROP) of macrocyclics.<br />
M. W. Cobb<br />
10:10 777. Discovery of 5-(6-[(3R)-1-<br />
Azabicyclo[2.2.2]oct-3-yloxy]pyridazin-3yl)-1H-indole<br />
as a novel a7 neuronal nicotinic<br />
receptor (NNR) agonist. T. Li<br />
10:35 778. <strong>Chemical</strong> development of an<br />
NHE3 inhibitor for the treatment of sleep<br />
apnea. A. Hillegass, J. J. Shay, N. Choy,<br />
T. A. Ayers, H. Gill<br />
11:00 779. Identification of novel HCV NS3<br />
protease inhibitors. J. A. O’Meara<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 206A<br />
New Reactions and Methodology<br />
S. Sieburth, Organizer<br />
C. Goldsmith, Presiding<br />
8:00 780. Mechanisms of palladium-catalyzed<br />
processes for the formation of fluorine-containing<br />
aromatic compounds.<br />
T. Kinzel,S.L.Buchwald<br />
8:20 781. Stereochemical and skeletal diversity<br />
by coupling Petasis reaction to intramolecular<br />
1,3-dipolar cycloaddition reactions.<br />
G. Muncipinto, T. Kaya,<br />
P. A. Clemons, N. Kumagai,<br />
S. L. Schreiber<br />
8:40 782. Photoredox catalysis: Enabling<br />
chemical synthesis with visible light.<br />
C. R. Stephenson<br />
9:00 783. Bidirectional synthesis of ketones<br />
from monomeric formaldehyde by catalytic<br />
C-H insertion with diazoalkanes.<br />
A. J. Wommack,J.S.Kingsbury<br />
9:20 784. Fluoride-promoted cross-coupling<br />
of chloro(mono-, di-, or triphenyl)germanes<br />
with aryl halides in “moist” toluene.<br />
J. Pitteloud, Z. Zhang, L. Cabrera,<br />
Y. Liang, M. Toribio, S. F. Wnuk<br />
9:40 785. Gold (I) catalysed reactions wth<br />
cyclopropenes. M. S. Hadfield<br />
10:00 786. New reactivity of esters: An intramolecular<br />
oxy–acylation reaction of<br />
alkenes initiated by rhodium catalyzed<br />
acyl C–O bond activation. G. T. Hoang,<br />
C. J. Douglas<br />
10:20 787. Preparation of peptide isosteres<br />
through a one-pot tandem homologationcyclopropanation-lactonization<br />
of betaketo<br />
imides. I. S. Taschner, C. K. Zercher<br />
10:40 788. Selective dioxygenation of<br />
alkenes using Pd catalysis.<br />
S. R. Neufeldt,M.S.Sanford<br />
11:00 789. Synthesis of the tetracyclic core<br />
of mulberrofuran G via a chromene<br />
dimerization approach. Y. Luan,<br />
S. E. Schaus<br />
11:20 790. Macrocyclic ring closing metathesis<br />
of vinylsiloxanes and its application.<br />
Y. Wang, A. S. Hansen, E. Raiber,<br />
D. W. Young, S. L. Schreiber<br />
11:40 791. Kinetic resolution of secondary<br />
alcohols through enantioselective silylation.<br />
S. L. Wiskur<br />
12:00 792. Direct carbon–carbon bond formation<br />
via soft enolization of thioesters.<br />
D. M. Coltart<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 203<br />
Heterocycles and Aromatics<br />
S. Sieburth, Organizer<br />
M. G. Kociolek, Presiding<br />
8:00 793. New reactivities from bistriazole<br />
metal catalysts. X. Shi, W. Yan<br />
8:20 794. 1, 2, 3 Triazole-Au complex catalyzed<br />
alkynes activation. X. Shi, X. YE,<br />
D. Wang<br />
8:40 795. Development of new transition<br />
metal catalyst from bis-1,2,3-triazole ligands.<br />
Q. Wang<br />
9:00 796. Enantioselective [4 � 2] cycloadditions<br />
of iminoacetonitriles: Application<br />
to the total synthesis of quinolizidine<br />
207I. S. D. Fontaine,M.K.Virdi,<br />
R. L. Danheiser<br />
9:20 797. Anti-Markovnikov additions to vinylpyrimidines,<br />
quinoxalines, quinazolines,<br />
and other heterocycles.<br />
D. A. Klumpp, M. A. Sheets, Y. Zhang<br />
9:40 798. Radical-mediated indole functionalization<br />
and application in natural product<br />
synthesis. L. Furst, B. S. Matsuura,<br />
C. R. Stephenson<br />
10:00 799. Synthesis, characterization,<br />
mechanism of decomposition, and antiproliferative<br />
activity of a new class of<br />
PEGylated benzopolysulfanes with enhanced<br />
water solubility. A. Mahendran,<br />
A. Vuong, D. Aebisher, Y. Gong,<br />
R. Bittman, G. Arthur, A. Kawamura,<br />
A. Greer<br />
10:20 800. Microwave accelerated fluorination<br />
and fluoroalkylation methods.<br />
M. S. Placzek, P. LaBeaume,<br />
G. B. Jones<br />
10:40 801. Reaction of nitrile-oxide precursors<br />
with heterocyclic enamines.<br />
C. Altug, Y. Durust, M. C. Elliott,<br />
B. M. Kariuki<br />
11:00 802. New approach to �-carbolines<br />
via inverse electron demand Diels-Alder<br />
reaction. Z. Ma, F. Ni, G. Woo, S. Lo,<br />
P. Roveto, S. Schaus, J. K. Snyder<br />
11:20 803. Calcium catalyzed intramolecular<br />
hydroamination of olefins.<br />
K. Kunchithapatham, J. P. Stambuli<br />
11:40 804. Preparation of enantiopure 5,6dihydro-1,10-phenanthroline<br />
derivatives<br />
with B-ring functionalization.<br />
E. Schoffers, L. Kohler,S.Tran,<br />
R. J. Pradko, E. Driscoll, M. Zeller,<br />
M. W. Perkovic, C. Schmiesing, E. Sinn<br />
12:00 805. Preparation of a psico-oxetanocin<br />
and investigation of the role of neighboring<br />
group participation. Y. Liang,<br />
N. Hnatiuk, J. M. Rowley, B. Whiting,<br />
G. W. Coates, P. R. Rablen, A. R. Howell<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 204A<br />
Molecular Recognition and Self-Assembly<br />
S. Sieburth, Organizer<br />
M. Case, Presiding<br />
8:00 806. Developing a universal reader for<br />
DNA sequencing by transbase tunneling.<br />
P. Zhang, F. Liang, S. Chang, S. Huang,<br />
J. He, X. Chen, S. Li, O. Sankey,<br />
S. Lindsay<br />
8:20 807. Boronic acid functionalized peptidyl<br />
synthetic lectins: Combinatorial library<br />
design and selective recognition of glycoproteins.<br />
K. L. Bicker, J. Sun, M. Harrell,<br />
J. J. Lavigne, P. R. Thompson<br />
8:40 808. Structure activity relationships between<br />
anionic amphiphilic dendrimer assemblies<br />
and antimicrobial properties.<br />
E. Welsch<br />
9:00 809. Phase behavior of repulsive polymer-tethered<br />
colloids. B. Bozorgui,<br />
M. Sen, W. L. Miller, J. P. Pamies,<br />
A. Cacciuto<br />
9:20 810. Colorimetric ion sensing by molecular<br />
tweezers. S. Saha<br />
9:40 811. Metal helicates supported by<br />
chiral tetradentate ligands: Solution dynamics<br />
and structural interconversion.<br />
J. Jung, J. Jo, M. Laskar, M. Pink, D. Lee<br />
10:00 812. Detection of molecular interactions<br />
with modified ferrocene self-assembled<br />
monolayers. M. Ho, P. Li, P. Estrela,<br />
S. Goodchild, P. Migliorato<br />
10:20 813. Arranging virus capsids in 1D<br />
nanoscale arrays using DNA origami.<br />
N. Stephanopoulos, M. Liu, G. J. Tong,<br />
Z. Li, Y. Ke, H. Yan, M. B. Francis<br />
10:40 814. Squaraine catenanes: A new<br />
family of luminescent interlocked molecules.<br />
J. Lee,B.D.Smith<br />
11:00 815. Biomolecular assembly of viral<br />
arrays. J. M. Rego,H.Yi<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
11:20 816. Calcium dependent self-assembly<br />
of liposomes based on a disaccharide<br />
from the red beard marine sponge.<br />
D. Yüksel, B. Lorenz,<br />
L. Álvarez de Cienfuegos, V. Kalsani,<br />
A. Janshoff, K. Kumar<br />
11:40 817. Identifying structure-property relationships<br />
using pyridine-based molecular<br />
gels. J. Chen,A.J.McNeil<br />
12:00 818. Noncovalent polymer assembly<br />
in water and their applications in materials<br />
fabrication. Y. Y. Luk, L. Wu, J. Lal,<br />
K. A. Simon, E. A. Burton<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 204B<br />
Metal-Mediated Reactions and Syntheses<br />
S. Sieburth, Organizer<br />
J. Miranda, Presiding<br />
8:00 819. Preparation of novel 4-aryl- and<br />
4-alkyl-2-silyl-1,3-dienes and their use in<br />
tandem Diels–Alder/Hiyama cross-coupling<br />
reactions. C. S. Junker,<br />
M. E. Welker<br />
8:20 820. Investigating the reactivity of benzylic<br />
nitriles in palladium-catalyzed cross<br />
coupling reactions. M. C. Brannock,<br />
C. B. Gorman<br />
8:40 821. Palladium-catalyzed functionalization<br />
of olefins under oxidative conditions.<br />
N. Selander,K.J.Szabó<br />
9:00 822. Soluble polyethylene oligomers as<br />
supports for NHC ligands. C. Hobbs,<br />
D. E. Bergbreiter, H. S. Bazzi<br />
9:20 823. [2�2] vs. [4�2]: Mechanistic study<br />
on gold-catalyzed oxygen transfer of<br />
alkynyldiketones and alkynylketoesters.<br />
L. Liu, D. Malhotra, G. B. Hammond<br />
9:40 824. Palladium-catalyzed trifluoromethylation<br />
of aryl chlorides and vinyl<br />
sulfonates. E. Cho, T. Senecal, T. Kinzel,<br />
Y. Zhang, S. L. Buchwald<br />
10:00 825. Synthesis of microstegiol, a rearranged<br />
abietane. R. A. Taj, J. R. Green<br />
10:20 826. Regio- and stereoselective<br />
umpolung piperidine synthesis incorporating<br />
�-basic tungsten. D. P. Harrison,<br />
V. E. Zottig, S. Wang, M. Sabat,<br />
W. H. Myers, W. D. Harman<br />
10:40 827. Highly efficient palladium/copper<br />
cocatalytic system for direct arylation of<br />
heteroarenes: The unexpected effect of<br />
Cu(Xantphos)I. J. Huang,J.Chan,<br />
Y. Chen, C. J. Borths, K. D. Baucom,<br />
R. D. Larsen, M. M. Faul<br />
11:00 828. Allylic oxidations of disubstituted<br />
olefins. C. T. Check, W. H. Henderson,<br />
M. J. Vanden Eynden, J. P. Stambuli<br />
11:20 829. Reactivity and properites of dihapto-coordinated<br />
phenols. V. E. Zottig<br />
11:40 830. Oxidant-controlled regioselectivity<br />
in the oxidative arylation of N-acetylindoles<br />
and N-alkylindoles. S. Potavathri,<br />
B. Deboef<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 207<br />
Material, Devices and Switches<br />
S. Sieburth, Organizer<br />
R. Smith, Presiding<br />
8:00 831. Luminescent diphosphine coordination<br />
polymers with fluorene and phenylene<br />
ethynylene chromophores.<br />
T. Maltais,R.C.Smith<br />
8:20 832. Soft and deformable gold nanoparticles<br />
with unique conducting properties.<br />
X. Yu, K. Du, C. Versek, D. Patra,<br />
O. R. Miranda, A. D. Dinsmore,<br />
M. T. Tuominen, V. M. Rotello<br />
8:40 833. Walking transition metal complexes.<br />
D. M. D’Souza, R. Carrillo,<br />
B. A. Blight, J. E. Beves, M. Papmeyer,<br />
D. Howgego, D. A. Leigh<br />
9:00 834. Improving the yield of working<br />
tunnel junctions (Ag TS /SAM//oxide/<br />
EGaIn) through near-surface effects on<br />
the SAM. M. T. Mwangi,W.Reus,<br />
C. Kim, M. D. Schulz, G. M. Whitesides<br />
9:20 835. Intracellular delivery of macromolecular<br />
cargo. S. Tarakkad Krishnaji,<br />
V. Kalsani, K. Kumar<br />
9:40 836. <strong>Chemical</strong> synthesis on SU-8.<br />
K. Qvortrup, K. Taveras, T. E. Nielsen,<br />
O. Thastrup, H. Morgan, S. Birtwell,<br />
G. R. Broder, P. Roach<br />
10:00 837. Facile syntheses of low band<br />
�-conjugated copolymers based on<br />
fused terthiophene and benzothiadiazole.<br />
S. Ku, N. Treat, C. J. Hawker<br />
10:20 838. Combining molecular switches<br />
and quantum dots to create fluorescent<br />
sensors. E. R. Kay, A. B. Greytak,<br />
D. G. Nocera, M. G. Bawendi<br />
10:40 839. Synthesis of carbon nanotubes<br />
of discrete chirality. X. Tian, R. Jasti<br />
11:00 840. Optimization of lumo levels in<br />
low bandgap organic photovoltaic donor<br />
materials through terpolymerization.<br />
R. C. Coffin, C. M. MacNeill, R. E. Noftle,<br />
D. L. Carroll<br />
11:20 841. Synthesis and photochromism of<br />
a unique photoresponive spiro-oxazine<br />
dimer. D. L. Watkins, T. Fujiwara<br />
11:40 842. Helical folding of C 3-symmetric<br />
molecules: Substituent effects on chiral<br />
conformation and exciton-coupled circular<br />
dichroism. E. A. Opsitnick, X. Jiang,<br />
D. Lee<br />
12:00 843. Signal-responsive plastics.<br />
S. T. Phillips<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 205A/B<br />
Process Chemistry: Role of Organic<br />
Chemistry in Early Clinical Drug<br />
Development V Cosponsored by MEDI ‡<br />
A. Abdel-Magid, Organizer<br />
J. Pesti, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 844. Timely chemical process research<br />
is a critical part for efficient drug development.<br />
C. Senanayake<br />
9:15 845. Regioselective synthesis of 1,3,5trisubsituted<br />
pyrazoles via 1,3-dipolar cycloaddition<br />
reactions. L. M. Oh,<br />
G. P. Spoors, H. Wang, S. Shilcrat,<br />
R. Hermann, J. Sisko<br />
9:55 846. Process development of palladium-catalyzed<br />
decarboxylative cross-coupling<br />
of arene carboxylic acids and aryl<br />
bromides. D. Mitchell<br />
10:35 847. Development of a scalable synthesis<br />
of sulopenem: A �-lactam antibacterial<br />
candidate. J. D. Nelson<br />
11:15 848. Stereoselective synthesis of an<br />
all-cis 1,2,3-trisubstituted cyclopropane<br />
carboxylic acid. S. Kiau,<br />
F. Gonzales-Bobes, M. D. Fenster,<br />
S. Kolotuchin, L. Kolla<br />
11:55 Concluding Remarks<br />
WEDNESDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 205A/B<br />
Nanoscaled Materials for Drug Delivery and<br />
Diagnostic Applications<br />
J. Yang, N. Gianneschi, H. Havel,<br />
Organizers, Presiding<br />
1:00 849. Nanoskiving as a route to small<br />
structures. G. M. Whitesides, D. Lipomi,<br />
Q. Xu, R. Rioux, M. Dickey<br />
1:30 850. nab Technology: Tumor targeting<br />
through natural albumin transport via<br />
gp60, caveolin-1, and SPARC. N. Desai<br />
1:55 851. Nanoscale ratiometric dosing formulations<br />
for anticancer combination<br />
chemotherapy. L. D. Mayer<br />
2:20 852. Designed collagen peptide materials<br />
for tissue engineering.<br />
J. Chmielewski<br />
2:45 853. <strong>Chemical</strong>ly modified viral capsids<br />
as targeted platforms for diagnostic imaging<br />
and drug delivery. M. B. Francis<br />
3:10 Intermission<br />
3:15 854. Cooperative nanomaterials to<br />
sensitize, target, image, and treat tumors.<br />
M. J. Sailor,J.Park,L.Gu,<br />
G. von Maltzahn, S. N. Bhatia,<br />
E. Ruoslahti<br />
3:45 855. Programming nanoscale materials<br />
with peptides, enzymes and DNA.<br />
N. C. Gianneschi, M. Chien,<br />
M. P. Thompson, T. Ku, L. M. Randolph,<br />
A. M. Rush<br />
4:05 856. Nanoparticle-based delivery of<br />
siRNA. D. E. Levy, B. Frederick, Z. Ding,<br />
B. Luo, S. Zalipsky<br />
4:30 857. Oligonuceolotide-gold nanoparticles<br />
conjugates as intracellular gene<br />
regulation agents. C. A. Mirkin<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 206A<br />
New Reactions and Methodology<br />
S. Sieburth, Organizer<br />
A. Mattson, Presiding<br />
1:00 858. Seebach’s conjunctive reagent<br />
enables double cyclizations.<br />
B. D. Chandler, J. T. Roland,<br />
E. J. Sorensen<br />
1:20 859. New methods for C–C, C–O, and<br />
C–N bond formation. P. J. Walsh<br />
1:40 860. Sequential semipinacol-Beckmann<br />
rearrangements for the construction<br />
of 1-azaspirocycles. L. K. Sharma,<br />
G. I. Elliott<br />
2:00 861. Base- and ligand-free copper catalysis<br />
for the alkynylation of imines.<br />
C. H. Larsen, C. E. Meyet, C. J. Pierce<br />
2:20 862. Microwave-assisted domino [3,3]sigmatropic<br />
rearrangement of allylic<br />
azides and Overman rearrangements.<br />
A. A. Tjeng, R. Batey<br />
2:40 863. Palladium(II)-catalyzed dehydrogenative<br />
olefination of cyclic enaminones<br />
via oxidative Heck reaction. Y. Yu,<br />
M. J. Niphakis, G. I. Georg<br />
3:00 864. Synthesis of macrocyclic depsipeptides<br />
by cyclodimerization of amino<br />
esters and lactones. S. Kalidindi,<br />
A. B. Beeler, J. A. Porco<br />
3:20 865. Three step route to polycyclic 2,5dihydropyrroles<br />
from �-silyloxy ketones.<br />
M. Brewer, C. Draghici, Q. Huang<br />
3:40 866. Development of novel hetero<br />
Diels-Alder cycloaddition methodology<br />
for the total synthesis of cyclic guanidine<br />
alkaloids. M. Yu, V. Kumbam,<br />
S. Rasapalli<br />
4:00 867. Multicatalytic, asymmetric Michael/Stetter<br />
reaction of salicylaldehydes<br />
and activated alkynes. T. Rovis,<br />
C. M. Filloux, S. P. Lathrop<br />
4:20 868. Synthesis of new chiral vicinal diamines<br />
from isoquinoline and nitromethane.<br />
M. Ahamed,M.H.Todd<br />
4:40 869. Catalytic trifluoromethylation/ fluorination<br />
of aromatic and heteroaromatic<br />
compounds. F. Nowrouzi,R.A.Batey<br />
5:00 870. Stereoretentive and mild halogenation<br />
of cyclic alcohols catalyzed by titanium<br />
(IV) reagents: Evidence for a new<br />
front-side attack mechanism. S. Li,<br />
D. Mondal, S. D. Lepore<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 203<br />
Heterocycles and Aromatics<br />
S. Sieburth, Organizer<br />
C. Anderson, Presiding<br />
1:00 871. Transition metal-catalyzed synthesis<br />
of N-heterocycles from azides: Relationship<br />
between mechanism and<br />
metal. T. G. Driver,B.J.Stokes,<br />
H. Dong, K. Sun, L. Urnezis<br />
1:20 872. Synthesis of highly substituted<br />
quinolines via a tandem ynamide benzannulation/iodocyclization<br />
strategy.<br />
T. P. WIllumstad, P. D. Boudreau,<br />
R. L. Danheiser<br />
1:40 873. �-Carboline library development<br />
via inverse electron demand Diels-Alder<br />
reaction of indoles with 1, 2, 4-triazines.<br />
F. Ni,J.K.Johnson,S.E.Schaus,<br />
J. K. Snyder<br />
2:00 874. Synthetic routes to and reactivity<br />
of bicyclic diazenium salts. J. Wyman,<br />
M. Brewer<br />
2:20 875. Studies toward concise synthesis<br />
of calothrixin and its structural analogs.<br />
O. B. Olubanwo, S. Rasapalli<br />
2:40 876. Beckmann rearrangement and<br />
ring annulation of porphyrin dione<br />
oximes: Novel strategy toward the synthesis<br />
of long wavelength chromophores.<br />
J. Akhigbe,C.Brückner<br />
3:00 877. Syntheses of 3-azido azetidinones<br />
in [bmim][PF6]: A comparative study.<br />
M. S. Chorghade, A. M. Rahatgaonkar,<br />
A. M. Ghatole<br />
3:20 878. Novel application of oxonium<br />
(Meerwein) salts: Total synthesis of indole<br />
alkaloids. V. Kumbam,M.Yu,<br />
S. Rasapalli<br />
3:40 879. Synthesis and properties of novel<br />
benzisoxazole-N-oxides. M. G. Kociolek<br />
4:00 880. Syntheses, structures, modification,<br />
and optical properties of two isomericmeso-tetraaryl-2,3,12,13-tetrahydroxybacteriochlorins.<br />
L. P. Samankumara, M. Zeller,<br />
C. Brückner<br />
4:20 881. Synthesis of novel porphyrinoids<br />
through porphyrin N-oxidation.<br />
S. Banerjee, M. Zeller, C. Brückner<br />
4:40 882. 1,2,3-triazole coordinated boron<br />
complex as efficient reagent for C-B<br />
bond formation. T. Liao,X.Shi<br />
5:00 883. Synthesis of tetrabenzoquadrannulene<br />
(TBQ). B. Kumar,B.T.King<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 204A<br />
Molecular Recognition and Self-Assembly<br />
S. Sieburth, Organizer<br />
S. Saha, Presiding<br />
1:00 884. Coupling molecular recognition<br />
with surface-enhanced resonance Raman<br />
scattering for quantitative TNT sensing.<br />
A. H. Flood, E. H. Witlicki, L. Jensen,<br />
E. W. Wong, J. O. Jeppesen<br />
1:20 885. Metal ion-assembled micro-collagen<br />
heterotrimers. M. A. Case,<br />
L. T. LeBruin, S. Banerjee<br />
1:40 886. Engineering self-assembled platinate<br />
nanostructures for cancer chemotherapy.<br />
A. S. Paraskar,S.Soni,<br />
S. Sengupta<br />
2:00 887. Structural diversity in organic solid<br />
derived from pyrazole-3,5-dicarboxylic<br />
acid and amines. O. Ugono, A. M. Beatty<br />
2:20 888. Highly selective fluorescent sensor<br />
for pyrophosphate in aqueous solution<br />
based on ESIPT turn-on. W. Chen,<br />
Y. Pang<br />
2:40 889. Alkynes of surprises: Acetylenes<br />
are a versatile electron withdrawing<br />
group for nucleophilic aromatic substitution.<br />
J. W. Wackerly, J. L. Katz,<br />
E. Braunstein, S. Carlin, M. Zhang,<br />
N. Staley<br />
3:00 890. Theoretical modeling of self-assembling<br />
DNA base super-structures on<br />
the Au(111) surface. R. E. Kelly,M.Mura,<br />
L. N. Kantorovich<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ORGN<br />
TECH–95
ORGN <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
3:20 891. Control vs. chaos in the assembly<br />
of folding and DNA binding molecules.<br />
B. L. Iverson<br />
3:40 892. Synthesis of shell cross-linked micelles<br />
(SCMs) with Co-salen functionalized<br />
core. Y. Liu,M.Weck<br />
4:00 893. Light controlled guest binding in a<br />
molecular cavitand. O. B. Berryman,<br />
A. C. Sather, J. Rebek Jr.<br />
4:20 894. Odd-even effects on charge transport<br />
across n-alkanethiolate SAMs on<br />
metal/SAM/oxide/EGaIn junction.<br />
M. T. Mwangi, W. Reus, C. Nijhuis,<br />
C. Kim, J. Barber, M. D. Schulz,<br />
G. M. Whitesides<br />
4:40 895. Multicomponent capsular assemblies<br />
of calix[4]resorcinarene: From hexamers<br />
to dimers. O. O. Ugono,<br />
K. T. Holman<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 204B<br />
Metal-Mediated Reactions and Syntheses<br />
S. Sieburth, Organizer<br />
A. Wenzel, Presiding<br />
1:00 896. Development of new palladium<br />
precatalysts and their application to<br />
cross-coupling reactions. Y. Zhang,<br />
S. L. Buchwald, T. Kinzel<br />
1:20 897. Visible light photoredox catalysis:<br />
Applications in synthetic methodology.<br />
J. W. Tucker, J. M. Narayanam,<br />
J. D. Nguyen, S. R. Corey<br />
1:40 898. Metal-catalyzed carbonylative cyclization<br />
of unactivated alkyl halides with<br />
alkenes. E. J. Alexanian<br />
2:00 899. Pd(II) mediated disubstitution of<br />
alkenes by carbon and heteroatom nucleophiles.<br />
B. S. Matsuura, A. Condie,<br />
P. Fink, C. R. Stephenson<br />
2:20 900. Electron-transfer photoredox catalysis:<br />
Development of a phosphine-free<br />
halogenation of alcohols. C. Dai,<br />
J. M. Narayanam, C. R. Stephenson<br />
2:40 901. Development of catalysts for Pdcatalyzed<br />
C–N cross-coupling reactions.<br />
B. P. Fors, S. L. Buchwald<br />
3:00 902. Intermolecular Rh(II)-catalyzed reactions<br />
of �-diazolactones and �-diazolactams:<br />
Remarkable selectivity over tertiary<br />
C-H bond migration. A. DeAngelis,<br />
J. M. Fox<br />
3:20 903. Nickel-catalyzed reductive coupling<br />
of organohalides to electron-deficient<br />
olefins forming 1,4-conjugate addition<br />
products. R. Shrestha,D.J.Weix<br />
3:40 904. Remarkable effect of sulfate additives<br />
on the palladium-catalyzed cyanation<br />
of aryl chlorides. M. Shevlin<br />
4:00 905. Ylide chemistry via Co(III)Corroles:<br />
Axial ligand effects of epoxidation and<br />
N-H insertion reactions with diverse<br />
diazo-compounds. C. Kim, P. X. Zhang,<br />
C. Ludwin<br />
4:20 906. Epoxidation of olefins using chiral<br />
salen vanadium catalysts. J. A. Miranda,<br />
E. J. Martin<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 207<br />
Material, Devices and Switches<br />
96–TECH<br />
S. Sieburth, Organizer<br />
S. Phillips, Presiding<br />
1:00 907. Preparation of polymers conjugated<br />
with �-extended quinone: Optical<br />
and redox properties of the polymers.<br />
E. Yoshikawa, T. M. Swager<br />
‡ Cooperative Cosponsorship<br />
1:20 908. Redox-driven structural folding<br />
and unfolding: Electronic communication<br />
between TTF units anchored onto a C 2symmtric<br />
aryleneethynylene scaffold.<br />
J. Jung, W. Liu, D. Lee<br />
1:40 909. Conjugated polymers that respond<br />
to oxidation with increased emission.<br />
E. L. Dane, T. M. Swager<br />
2:00 910. Role of metal ions and counterions<br />
in the switching behavior of spiropyrans.<br />
S. Giordani, M. Natali, L. Soldi,<br />
C. Aakeroy, J. Desper<br />
2:20 911. Detection of ethylene gas with a<br />
conjugated polymer/copper composite.<br />
B. Esser, T. M. Swager<br />
2:40 912. Metal-induced switching of a hydrazone-based<br />
rotary switch.<br />
I. Aprahamain,X.Su<br />
3:00 913. Polymer electrolyte based room<br />
temperature oxygen microsensors for<br />
aerospace applications. J. C. Xu,<br />
G. W. Hunter, C. Liu<br />
3:20 914. Electronic restoration of damaged<br />
lithium ion batteries. S. A. Odom,<br />
Z. Zhang, W. Weng, S. Kang,<br />
N. R. Sottos, K. Amine, J. S. Moore<br />
3:40 915. Microvascular composite materials<br />
using sacrificial fibers.<br />
A. P. Esser-Kahn, H. Dong, P. Pthakre,<br />
B. Kozola, M. Cale, J. Patrick, S. White,<br />
N. Sottos, J. S. Moore<br />
4:00 916. Multistate [3]catenanes utilizing<br />
highly stable TTF radical dimers.<br />
A. Coskun, J. M. Spruell, D. C. Friedman,<br />
G. Barin, J. Stoddart<br />
4:20 917. Functional materials derived from<br />
renewable sources. R. A. Smaldone,<br />
J. J. Gassensmith, R. S. Forgan,<br />
O. M. Yaghi, J. F. Stoddart<br />
4:40 918. Design and synthesis of rigid 3D<br />
hydrophilic structures for improved properties<br />
of conjugated polymers in water<br />
and postpolymerization strategies for<br />
sensing of proteins and influenza.<br />
B. VanVeller, T. M. Swager<br />
5:00 919. Tuning optical and electronic<br />
properties of arene-based organic semiconductors<br />
via perfluoroalkylation.<br />
H. Sun, M. Billion<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom East<br />
Technical Achievements in Organic<br />
Chemistry Award Symposium<br />
J. Cohen, C. Welch, Organizers, Presiding<br />
2:00 Introductory Remarks<br />
2:05 920. Characterization of drug-eluting<br />
coronary stents by vibrational spectroscopy<br />
and multivariate analysis.<br />
M. F. Chisholm<br />
2:30 921. Isoindolinones as glucokinase activators.<br />
R. F. Kester, S. J. Berthel,<br />
K. R. Guertin, J. Tengi, L. Orzechowski,<br />
L. Qi, J. Grimsby<br />
2:55 922. Development of an asymmetric alkylation<br />
towards an 11�-HSD1 inhibitor.<br />
C. F. Bernard, G. A. Moniz, M. J. Frizzle,<br />
L. M. Brown, C. D. Papageorgiou,<br />
J. S. Tedrow, E. A. Bercot, S. Caille,<br />
S. Cui, S. Wang, M. J. Martinelli,<br />
M. M. Faul, R. D. Larsen, K. B. Hansen<br />
3:20 923. Automated Chemistry: The development<br />
and use of low-cost automated<br />
chemical workstations for performing organic<br />
synthesis, sample preparation, material<br />
testing, and improving productivity<br />
and safety of laboratory operations.<br />
R. Shumate<br />
3:45 924. Synthetic highlights: Examples<br />
from early lead to clinical candidates in<br />
oncology and neuroscience therapeutic<br />
areas. N. Patel<br />
4:10 925. Optimization of oligonucleotide<br />
synthesis at Merck. E. Vazquez<br />
4:35 926. Modifications on the nucleotide<br />
sugar: Manipulation of GPCR activity.<br />
S. R. Shaver<br />
WEDNESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Ballroom<br />
Chemistry for Preventing & Combating<br />
Disease, New Reactions & Methodology<br />
and Total Synthesis of Complex Molecules<br />
A. Abdel-Magid, Organizer<br />
7:00–10:00<br />
927. Synthesis of epi-galiellalactone analogs.<br />
R. Gidlof, M. Johansson, O. Sterner<br />
928. Toward the total synthesis of the transtaganolides/basiliolides.<br />
R. Larsson,<br />
O. Sterner, M. Johansson<br />
929. Gentamicin component separation.<br />
J. Grote, R. Himmelsbach, D. Johnson<br />
930. Syntheses of dioxa-bicyclo[3.2.1]<br />
octane-2,3,4-triol derivative SGLT2 inhibitors.<br />
C. Préville, V. Mascitti<br />
931. Enamide-ene metathesis for constructing<br />
chiral 2-cyclopropylheterocycles: Indole,<br />
quinoline, benzofuran and<br />
chromene. T. Kobayashi,M.Arisawa,<br />
S. Shuto<br />
932. Tuneable nanotools for bioapplications:<br />
Soft organic nanodots as an eco-friendly<br />
alternative to quantum dots. C. Rouxel,<br />
O. Mongin, J. Vabre, Y. Mir, Y. Wei,<br />
A. Pla-Quintana, J. Majoral, A. Caminade,<br />
M. Blanchard-Desce<br />
933. Discovery of antibacterial virulence inhibitors<br />
targeted at Type III protein secretion.<br />
L. K. Tsou, J. Yount, P. Dossa,<br />
H. C. Hang<br />
934. Synthesis of estrogen receptor (ER) antagonist<br />
derivatives for breast cancer.<br />
K. Dao, A. Kozhushuyan, J. A. Hendricks,<br />
H. Pham, R. N. Hanson<br />
935. Towards B vitamin targeted light-activated<br />
cancer drug conjugates.<br />
K. Dhananjay, R. J. Fradette,F.G.West<br />
936. Development of SHIP activators: Potentially<br />
selective cancer therapy.<br />
L. G. Meimetis, M. Nodwell, C. Wang,<br />
L. Yang, A. L. Mui, C. Ong, G. Krystal,<br />
R. J. Andersen<br />
937. Solution- and solid-phase synthesis of<br />
potential anticancer HDAC inhibitors.<br />
T. R. Blum, H. K. Shah, X. Zang,<br />
A. R. Korn, D. M. Wholly, J. S. Miller<br />
938. Controlling biofouling by a kosmotrope<br />
approach for surfaces and materials.<br />
D. Bandyopadhyay, P. Sejwal,<br />
D. Prashar, Y. Y. Luk<br />
939. Singlet oxygen delivery via a fiber opticbound<br />
photosensitizer. M. Minnis,<br />
A. Greer<br />
940. Organic photonic nanoparticles for bioconjugation.<br />
C. Cordovilla,T.M.Swager<br />
941. Targeting Gp120’s binding sites.<br />
C. I. Dogo-Isonagie,S.N.Lam,<br />
C. A. Bewley<br />
942. Encapsulation of neutral and charged<br />
molecules into catanionic surfactant vesicles<br />
for drug delivery applications.<br />
L. H. Rader, J. Park, D. S. English,<br />
F. Khachik, P. DeShong<br />
943. MSN as controlled release devices and<br />
diagnostic tools. P. DeShong,<br />
M. T. Hurley, S. Galanie, D. S. English,<br />
M. Zachariah, C. Wu, Z. Wang, E. Liu,<br />
P. DeMuth<br />
944. Investigation of structure and function<br />
of thin films of nitric oxide synthase and<br />
polyethylenimine formed using the layerby-layer<br />
deposition method.<br />
M. N. Gunasekera, M. Bayachou<br />
945. Targeting IspC in non-mammalian isoprenoid<br />
biosynthesis. D. J. Meyers,<br />
C. L. Freel Meyers<br />
946. Chemogenomic analysis of adipogenesis<br />
using functional proteomics. W. Li,<br />
J. Pawlak, E. Dominguez, E. Saez,<br />
B. Cravatt<br />
947. Inhibition of the serine protease chymase<br />
by silanediols. Y. Bo,C.Cao,<br />
S. M. Sieburth<br />
948. Short, asymmetric synthesis of<br />
silanediol protease inhibitors.<br />
H. Q. Duong, S. Singh, Y. Bo,<br />
S. M. Sieburth<br />
949. Regioselective, iron-catalyzed allylic<br />
sulfonation of allylic carbonates.<br />
M. Jegelka, B. J. Plietker<br />
950. New N-heterocyclic carbene-derived alkylidene<br />
imidazolines. C. E. Knappke,<br />
A. Jacobi von Wangelin, A. J. Arduengo,<br />
III<br />
951. Synthesis of non-racemic enaminones<br />
via 6-exo-dig ketene cyclization. H. Seki,<br />
G. I. Georg<br />
952. Synthesis of vinyl sulfones with aldehyde<br />
and phenylsulfonylacetic acid using<br />
benzyltrimethyl ammonium hydroxide as<br />
base. R. Rengasamy,D.C.Forbes<br />
953. Stereoselective synthesis of the tetracyclic<br />
core of the codeine alkaloid using (-)shikimic<br />
acid as the chiral source.<br />
T. N. Dinh, A. Chen, C. L. Chai<br />
954. Progress toward the synthesis of decahydroquinolines<br />
(DHQs) from 2-alkenyltethered<br />
oxazolium salts. S. A. Habay<br />
955. Towards the total synthesis of leustroducsin<br />
B. P. B. Cranwell,<br />
K. L. Bridgwood, M. R. Huttl,<br />
D. A. Salinger, S. Wittrock, S. V. Ley<br />
956. Flow chemistry for natural product synthesis:<br />
Towards the syntheses of spiragiens<br />
A and B. C. F. Carter,H.Lange,<br />
S. Newton, S. V. Ley<br />
957. Total synthesis of novel analogs of dictyostatin.<br />
E. G. Williams, I. Paterson<br />
958. Electrophilic properties and NMR studies<br />
of triphenylphosphine–trifluoromethanesulfonic<br />
anhydride: An efficient dehydrating<br />
reagent system for the conversion<br />
of aldoximes into nitriles. Z. Moussa<br />
959. Improved preparation of (S)-Z/E-N-(1-<br />
(tert-butyldimethylsilyloxy)propan-2ylidene)-2-<br />
methylpropane-2-sulfinamide<br />
and analogs. X. Shi, H. Chang,<br />
D. G. Walker, R. Chen, W. F. Kiesman<br />
960. Spectroscopic analysis of the (HQ) 3C 60<br />
compound. S. Ahn, J. Yoon, H. Lee,<br />
B. Nam, B. Kim, G. Lee, D. Moon, H. Shin<br />
961. Mild and highly chemoselective deprotection<br />
of methoxymethyl (MOM) ethers<br />
in combination with TMSOTf (TESOTf)–<br />
2,2�-bipyridyl. T. Maegawa, O. Kubo,<br />
K. Senami, Y. Minamitsuji, H. Fujioka<br />
962. Efforts toward an enantiospecific synthesis<br />
of the natural product pleurotin.<br />
D. A. Siler, D. C. Ebner, E. J. Sorensen<br />
963. Soft Lewis acid-catalyzed cycloisomerization<br />
reactions. Z. Wang, Z. Wang<br />
964. Synthesis of 3,5-di-tert-butyl-2-iodocyclopenta-2,4-dienone<br />
via novel ring-contraction<br />
iodination reaction and its application<br />
for syntheses of various<br />
ethynylene functionized cyclopentadienone<br />
rings. X. Chen, T. C. Sandreczki,<br />
X. Bai, J. R. Dias, C. Barnes<br />
965. Synthetic applications of N–O tethered<br />
intramolecular 1,7-C–H insertion reactions.<br />
J. Wang,H.O.Sintim<br />
966. Asymmetric total synthesis of (-)-doliculide:<br />
An exceptionally potent cytotoxic<br />
compound for HeLa cells. A. V. Madduri,<br />
A. J. Minnaard<br />
967. One-step synthesis of nanofibers of aniline<br />
oligomers using benzoquinone oxidant.<br />
S. P. Surwade, S. Agnihotra,<br />
N. Manohar, S. K. Manohar<br />
968. Polystyrene supported aluminum chloride<br />
as an efficient and reusable catalyst<br />
for one-pot preparation of �-aminophosphonates<br />
via three component coupling<br />
reaction of aldehydes, amines, and diethyl<br />
phosphite. B. Tamami, K. Parang,<br />
A. N. Shirazi<br />
969. Esterification of aldehydes and alcohols<br />
with pyridinium hydrobromide perbromide<br />
in water. S. Sayama<br />
970. Intramolecular photocyclization: Cyclopropanation<br />
vs. epoxidation.<br />
M. R. Buchner, K. Ruhland<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
971. Practical synthesis of 6-carboalkoxy-<br />
13-cycloalkyl-5H-indolo[2,1-a] [2] benzazepine-10-carboxylic<br />
acid derivatives.<br />
P. Hewawasam, Y. Tu, T. Hudyma,<br />
R. Gentles, N. Meanwell, J. Kadow<br />
972. Pd/C catalyzed reductive formylation of<br />
indoles and quinolines. R. Gianatassio,<br />
A. Kulkarni,B.Török<br />
973. Synthetic studies toward the cytotoxic<br />
marine peptide lucentamycin A.<br />
S. Ranatunga,U.Pal,J. R. Del Valle<br />
974. Makeover of the halogen/lithium exchange:<br />
Continuous reactor studies.<br />
D. W. Slocum, D. Kusmic, J. C. Raber,<br />
P. E. Whitley<br />
975. Studies towards the synthesis and<br />
structure determination of palmerolide C.<br />
J. Wlochal, S. Eadie, G. J. Florence<br />
976. Preparation of 2,5-disubstituted pyrazolo[4,3-c]cinnolin-3-ones.<br />
D. R. Pitts,<br />
R. M. DiPardo, A. W. Johnson, V. Cofre,<br />
D. C. Beshore<br />
977. Development of aromatic thiol-catalysts<br />
for intramolecular Morita-Baylis-Hillman<br />
and Rauhut-Currier reactions. P. S. Selig,<br />
S. J. Miller<br />
978. Studies towards the synthesis of palmerolide<br />
A. S. Eadie, R. Murray,<br />
G. J. Florence<br />
979. Iron(III) tosylate catalyzed deprotection<br />
of acetals and tetrahydropyranyl ethers.<br />
M. V. Chiodo, P. R. Lazzara, M. E. Olson,<br />
V. V. Angeles, R. S. Mohan<br />
980. Direct asymmetric synthesis of<br />
�-butenolides by bifunctional thiourea<br />
catalyzed coupling of 2-(3H)-furanones to<br />
aldehydes. S. J. Howard,P.D.Bloom<br />
981. Synthetic studies towards the aplyronines:<br />
Potent anticancer marine macrolides<br />
isolated from Aplysia kurodai.<br />
S. J. Fink, L. Y. Lee, I. Paterson<br />
982. Thermal rearrangement of cyclobutadiene<br />
cycloadducts: A novel approach to<br />
5-7-5(6) ring system. J. He,<br />
M. L. Snapper<br />
983. Fluorous benzaldehyde-based multicomponent<br />
reactions for heterocycles.<br />
B. Piqani, S. Ding, T. Xu, W. Zhang<br />
984. Synthesis of quaternary carbon centers<br />
via hydroformylation using a scaffolding<br />
ligand. X. Sun, K. Frimpong,<br />
T. E. Lightburn, K. L. Tan<br />
985. Chlorination of metalated nitriles and<br />
enolates. B. R. Pitta, F. F. Fleming<br />
986. Progress toward antiproliferative agent<br />
popolohuanone E: A general approach to<br />
complex cis-fused decalins featuring catalytic<br />
carbon insertion methodology.<br />
H. Z. Kaplan, J. S. Kingsbury<br />
987. Total synthesis of flinderoles A-C by<br />
gold(I)-catalyzed hydroarylation of indole.<br />
R. M. Zeldin,F.Toste<br />
988. Synthetic studies of tamandarin B side<br />
chain analogs. J. Lee, K. M. Lassen,<br />
M. M. Joullie<br />
989. New designs of polyphenylene dendrimers<br />
for full-color light-emitting diodes.<br />
T. Qin,K.Müllen<br />
990. New C-H functionalization route to heterocycles.<br />
M. Yagoubi, M. C. Willis,<br />
P. Nichols<br />
991. Synthesis of heterobifunctional linkers<br />
for nanomedicinal chemistry.<br />
R. N. Hanson, K. Dao, T. Dunstan,<br />
A. Kozhushuyan, J. A. Hendricks,<br />
H. Pham, V. Ronga<br />
992. Diastereoselective 2-aza-Cope rearrangements<br />
and their applications in diversity-oriented<br />
synthesis.<br />
B. M. Ibbeson, D. T. Blackwell,<br />
D. R. Spring<br />
993. Application of in situ silver-imidazolylidene<br />
complexes in ionic liquid mediated<br />
glycosidation reactions. V. Kumar,<br />
I. J. Talisman, S. V. Malhotra<br />
994. Dual role of ionic liquids as phase transfer<br />
catalysts and solvents for O-glycosidation<br />
reactions. V. Kumar,<br />
I. J. Talisman, S. V. Malhotra<br />
995. Ligand-assisted, copper-catalyzed intramolecular<br />
amination. D. N. Barman<br />
996. Microwave-based methodology for the<br />
preparation of organoselenium compounds.<br />
M. Marques, I. L. Martins,<br />
C. Charneira, A. J. Vieira, A. M. Antunes<br />
997. Total synthesis of spinosyn analogs.<br />
N. Schützenmeister, L. F. Tietze<br />
998. Synthetic studies toward the synthesis<br />
of Bromophycolides. H. Lin, I. Krauss<br />
999. Insertion reactions of titanacyclobutanes.<br />
G. Liu, I. Krauss<br />
1000. Reductive substitution of aromatic<br />
substituted acetonitriles with lithium<br />
naphthalenide and electrophiles. I. Chen,<br />
J. Tsao, T. Tsai, H. Liu, J. Zhu<br />
1001. Synthesis of functionally diverse iodonium<br />
salts via in-situ generated [hydroxy-<br />
(tosyloxy)iodo]arenes as precursors to<br />
18 F-labeling agents. J. Chun,V.W.Pike<br />
1002. Progress toward the synthesis of<br />
marineosins A and B. X. Cai,B.B.Snider<br />
1003. Progress toward the synthesis of 7-hydroxylycopodine<br />
and sauroine. H. Lin,<br />
B. B. Snider<br />
1004. Triphenylphosphine/brominating<br />
agent: An efficient reagent for the preparation<br />
of allylic bromides from allylic alcohols.<br />
P. Taboonpong, W. Chavasiri<br />
1005. New and efficient protocol for the synthesis<br />
of bromosilane using Br 3CCOOEt/<br />
PdCl 2. P. Srithanakit, W. Chavasiri<br />
1006. Electron transfer induced [2�2] cycloaddition<br />
reactions and cycloreversion<br />
reactions of cyclobutane ring. Y. Okada,<br />
K. Chiba<br />
1007. Progress toward the total synthesis of<br />
Brasilicardin A. S. Yi, C. Regan,<br />
M. E. Jung<br />
1008. Multi-drug resistance reversal agents:<br />
Update on the synthesis of euphosalicin.<br />
C. Aichinger, C. R. Lentsch, U. Rinner<br />
1009. Catalytic scaffolding ligands: An efficient<br />
method for directing reactions.<br />
T. E. Lightburn, M. T. Dombrowski,<br />
K. L. Tan*<br />
1010. Approaches to the synthesis of isaindigotidione.<br />
M. Hellal,G.D.Cuny<br />
1011. Nickel-catalyzed cross-couplings of<br />
secondary alkyl nucleophiles with aryl halides.<br />
A. Joshi-Pangu, M. Ganesh,<br />
M. Biscoe<br />
1012. Quick access to the tetracycle of<br />
strychnose alkaloids: Concise racemic<br />
and asymmetric total syntheses of<br />
akuammicine, strychnine. G. Sirasani,<br />
R. B. Andrade<br />
1013. Allyl and crotyl transfer by allyldioxazaborolidines.<br />
M. K. Reilly,<br />
S. D. Rychnovsky<br />
1014. Synthesis and characterization of ferrocenyl<br />
chalcones: Potential compounds<br />
against some diseases.<br />
M. R. Otaño-Vega,<br />
N. Lafontaine-Vargas,<br />
R. Cardona-Couvertier,<br />
I. Montes-González,<br />
A. R. Guadalupe-Quiñones<br />
1015. Intramolecular, thermal [2 � 2] cycloaddition<br />
reactions of allene-ynes: Exploring<br />
the scope, mechanism, and application<br />
to natural product synthesis.<br />
K. M. Brummond, J. M. Osbourn<br />
1016. Intramolecular 1,4-addition of nitrogen<br />
nucleophile and halogen to conjugated<br />
enyne. J. B. Werness, W. Tang, N. Liu<br />
1017. Synthetic studies toward pseudotabersonine<br />
and 5-epi-pseudotabersonine.<br />
B. Cheng, J. D. Sunderhaus,<br />
S. F. Martin<br />
1018. Synthesis of p-benzoquinone methides<br />
via benzannulated enediynyl alcohols.<br />
B. Wen, J. L. Petersen, K. K. Wang<br />
1019. Synthesis of lipophilic dodecyl bis(cycloSaligenyl)<br />
nucleoside monophosphate<br />
triesters. Y. Ahmadibeni, B. Carroll,<br />
G. F. Doncel, K. Parang<br />
1020. Synthesis of branched lipophilic thymidine<br />
�-triphosphate triester conjugates<br />
of anti-HIV nucleosides. Y. Ahmadibeni,<br />
K. Parang<br />
1021. Direct, HF free, synthesis of tetrabutylammonium<br />
organotrifluoroborates.<br />
G. Prakash, F. Pertusati,G.A.Olah<br />
1022. Lewis-acid catalyzed [5�2]-annulation<br />
toward stereoselective formation of functionalized<br />
azapines. J. Woo<br />
1023. Domino reactions based upon the Ruthenium-catalyzed<br />
redox isomerization.<br />
A. W. Franz, B. M. Trost<br />
1024. New highly enantioselective organocatalytic<br />
N-acyliminium cyclization cascades.<br />
M. E. Muratore, C. A. Holloway,<br />
D. J. Dixon<br />
1025. Homoaporphine synthesis via microwave-assisted<br />
direct arylation.<br />
S. Chaudhary, W. W. Harding<br />
1026. Development of a 2-aza-Cope-[3�2]<br />
dipolar cycloaddition strategy for the synthesis<br />
of quaternary proline scaffolds.<br />
M. P. McCormack, S. P. Waters<br />
1027. Practical synthesis of tert-butyl<br />
amides from nitriles. J. C. Baum,<br />
J. E. Milne, J. A. Murry, O. R. Thiel<br />
1028. Metalated nitriles: Preferential S N2 cyclizations<br />
of allylic chlorides. W. Liu,<br />
P. Lu, P. C. Ravikumar,F.F.Fleming<br />
1029. Development of a new method for Rucatalyzed<br />
tandem ring-closing metathesis/hydroacylation.<br />
Y. Nam,<br />
M. L. Snapper<br />
1030. Copper-catalyzed click reactions of<br />
C-6 azidopurine nucleosides.<br />
M. K. Singh, M. K. Lakshman<br />
1031. Diastereoselective routes to �-aryl and<br />
�-alkyl lactones: Mechanistic insights and<br />
model synthetic studies toward highly oxidized<br />
marine diterpenoids.<br />
A. G. Macabeo, A. Kreuzer, O. Reiser<br />
1032. Synthesis of O-vinyl oxime ethers by<br />
iridium-catalyzed isomerization of O-allyl<br />
oxime ethers: Reactivity, Control of stereochemistry,<br />
and application to the synthesis<br />
of pyrroles. H. Wang, L. Anderson<br />
1033. Total synthesis of the indole alkaloid<br />
(�)-subincanadine F. X. Cheng,<br />
S. P. Waters<br />
1034. Asymmetric synthesis of substituted<br />
piperidines via aziridinium intermediates.<br />
S. Jarvis, A. Charette<br />
1035. New ligand for Ullmann type aryl halide<br />
couplings. F. Damkaci, E. Altay<br />
1036. Studies on the regioselectivity of catalytic<br />
carbon insertion. A. F. Kornahrens,<br />
J. A. Dabrowski, J. S. Kingsbury<br />
1037. Bismuth salt-initiated epoxide rearrangement<br />
and addition reactions toward<br />
2,6-disubstituted dihydropyrans: What is<br />
the role of bismuth? R. F. Lambert,<br />
S. E. Ammann, L. C. Speight, Y. Lian,<br />
J. Liu<br />
1038. Factors affecting the rate of Diels-Alder<br />
reactions involving 2-trialkylsilyloxy<br />
furans. N. A. Setterholm, N. D. Serratore,<br />
A. M. Franey, S. K. Bur<br />
1039. Palladium-catalyzed asymmetric difunctionalization<br />
of substituted vinyl phenols.<br />
T. P. Pathak,K.H.Jensen,<br />
M. S. Sigman<br />
1040. Novel AlMe 3-promoted formation of<br />
amides from acids and amines. J. Li,<br />
D. Smith, K. Subramaniam, J. J. Li,<br />
G. D. Vite, B. Chen<br />
1041. Synthesis of regiospecifically fluorinated<br />
vinyl triazoles. R. Kumar,B.Zajc<br />
1042. Rh(I)/diene-catalyzed addition reactions<br />
of aryl/alkenylboronic acids with aldehydes.<br />
C. Xing<br />
1043. Use of transition metal-catalyzed intramolecular<br />
cyclization reactions in the<br />
total synthesis of oroidin-derived alkaloids.<br />
M. R. Bhandari, C. J. Lovely<br />
1044. First total synthesis and structural<br />
confirmation of fluvirucinine A 2 via an iterative<br />
ring expansion. Y. Lee, J. Jung,<br />
H. Yun, S. Lee, Y. Suh<br />
1045. Concise total synthesis of (�)-tetrabenazine<br />
and (�)-�-dihydrotetrabenazine.<br />
S. Paek, N. Kim, H. Moon,Y.Suh<br />
1046. Intermolecular [3�3] cycloadditions of<br />
azides with the Nazarov intermediate.<br />
O. Scadeng,F.G.West<br />
1047. One-pot preparation of alkyl halides<br />
from alkyl diphenylphosphinites.<br />
K. Ruchamanee, W. Chavasiri<br />
1048. Synthesis of succinate diesters as internal<br />
donor for isotactic polypropylene<br />
production process.<br />
N. Sittichokwongkamol, W. Chavasiri<br />
1049. Modular synthetic approach to Amicetin<br />
derivatives. C. M. Serrano,<br />
R. E. Looper<br />
1050. Synthesis of aryl 1,3-butadienes from<br />
the haloallylation of aryl aldehydes using<br />
boron trihalide and subsequent elimination<br />
with DBU. M. Quinn,M.Yao,<br />
G. Kabalka<br />
1051. Copper-catalyzed chlorination of functionalized<br />
arylboronic acids. H. Wu,<br />
J. Hynes<br />
1052. Progress toward the asymmetric total<br />
synthesis of Iriomoteolide 1A.<br />
A. R. Dechert,M.T.Crimmins<br />
1053. Utilizing the nitroso-ene reaction for<br />
the synthesis of hydroxamic acid-based<br />
natural products. R. Banerjee,S.B.King<br />
1054. Minimizing the cost of organic chemistry<br />
experimentation: Low-barrier microscale<br />
high-throughput experimentation.<br />
S. Berritt, S. D. Goble, M. T. Tudge,<br />
D. Conway, S. D. Dreher<br />
1055. Toward the synthesis of Thapsigargin.<br />
C. Huang, K. Brummond<br />
1056. Chiral phosphoramidic acids catalyzed<br />
Mannich reaction. D. Ramella,<br />
S. E. Schaus<br />
1057. Studies directed toward the synthesis<br />
of montamine. E. A. Colby Davie,<br />
M. A. Dion, G. J. Dugas, J. M. St. Louis,<br />
L. E. Lupien<br />
1058. Formation of decahydroquinoline ring<br />
systems from 2-acyl-5-amino-oxazolium<br />
ions. C. H. Basch,S.A.Habay<br />
1059. One-flask synthesis of benzyl phosphonates<br />
from benzylic alcohols mediated<br />
by ZnI 2. R. M. Richardson,<br />
R. J. Barney, D. F. Wiemer<br />
1060. Progress toward the synthesis of embedded<br />
tetrahydrofuranyl isosteres.<br />
C. M. Spencer,C.K.Zercher<br />
1061. Studies toward the synthesis of (5R)polyandrane.<br />
V. A. Cwynar,<br />
M. G. Donahue, S. J. Fretz, D. J. Hart,<br />
G. Mbogo, D. Yang<br />
1062. Withdrawn<br />
1063. Lewis acid catalyzed homo-Nazarov<br />
cyclization of donor-acceptor substituted<br />
cyclopropanes. D. V. Patil,S.A.France<br />
1064. Development of a divergent synthesis<br />
for the modular assembly of the zoanthamine<br />
alkaloids. L. H. Phun,<br />
S. A. France<br />
1065. Radical cyclizations and atom-transfer<br />
radical cyclizations enabled by visible<br />
light photoredox catalysis. J. D. Nguyen,<br />
J. W. Tucker, J. M. Narayanam,<br />
C. R. Stephenson<br />
1066. Photoactivation and photopassivation<br />
of pristine and modified carbonaceous<br />
materials as catalysts for benzylic oxidation.<br />
V. Rajpara, G. Sereda<br />
1067. Regioselective synthesis of tert-allylic<br />
ethers via Gold (I) catalysis.<br />
M. S. Hadfield<br />
1068. Novel Lamellarin alkaloid-inspired libraries<br />
via cycloisomerization/dipolar cycloaddition.<br />
S. Bhagwanth,S.E.Schaus,<br />
J. A. Porco, Jr.<br />
1069. Using chiral, strained olefins to rapidly<br />
assemble complex molecules.<br />
M. T. Taylor,J.M.Fox<br />
1070. Synthesis of trisubstituted-1,2,4-triazoles<br />
as somatostatin subtype-4 receptor<br />
ligands. I. Daryaei, M. Crider<br />
1071. <strong>Chemical</strong> conversion of cellulose biomass<br />
to biofuels. S. F. Panos, J. Kenny,<br />
K. C. Pereira, J. Hegner, B. DeBoef,<br />
B. Lucht<br />
1072. Progress towards the synthesis of isatisine<br />
A. J. D. Mighion,J.L.Moore,<br />
E. J. Sorensen<br />
1073. Synthesis of new rigidified manganese(III)-bis-salicylimine<br />
peroxynitrite decomposition<br />
catalysts for the treatment of<br />
chronic pain. M. Ghaffari, B. Neumann<br />
1074. Asymmetric synthesis of the enantiomer<br />
and six diastereomers of the trisaccharide<br />
portion of PI-080 and Vineomycin<br />
C. Q. Chen, Y. Zhong, G. A. O’ Doherty<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
ORGN<br />
TECH–97
ORGN/PETR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
1075. Synthesis of bis(cycloSaligenyl) pronucleotides<br />
containing two nucleosides<br />
from bis(methoxymethyl)benzene-1,4diol.<br />
Y. Ahmadibeni, R. Tiwari,<br />
G. F. Doncel, K. Parang<br />
1076. Platinum(II) catalyzed rearrangement<br />
of 4-oxaspiro[2.3]hexanes. M. S. Thakur,<br />
A. R. Howell<br />
1077. Stereoselective allylic alcohol epoxidations<br />
using chiral vanadium catalysts.<br />
M. L. McCrea-Hendrick, J. Miranda<br />
1078. New strategies for hydrogen bond donor<br />
catalysis. J. A. Burkett,S.S.So,<br />
A. E. Mattson<br />
1079. Towards the total synthesis of a new<br />
sesquiterpene having a unique carbon<br />
squeleton. W. S. Bechara, D. Marcoux,<br />
A. B. Charette<br />
1080. Synthesis of new Dictyostatin analogs<br />
via an intramolecular NHK approach.<br />
M. Jimenez, W. Zhu, D. Camarco,<br />
A. Vogt, B. W. Day, D. P. Curran<br />
1081. Studies towards total synthesis of procyanidin<br />
B2 and neochamaejasmin A.<br />
R. Demerzhan, S. Schaus<br />
1082. Suzuki cross-coupling: Chemoselectivity<br />
with vinyl boronates and allylic acetates,<br />
benzoates, and carbonates.<br />
B. Kim, M. M. Hussain, H. Hussain,<br />
P. J. Walsh<br />
1083. Fluorous mixture synthesis and spectroscopic<br />
analysis of the phytophthora<br />
mating hormone �1 and the corresponding<br />
bis-MTPA esters. R. Bajpai,<br />
D. P. Curran<br />
1084. Sulfinylnitriles: Sequential carbonate<br />
alkylation and sulfinyl-metal exchange.<br />
D. Nath, F. Fleming<br />
1085. Multivalent activation in phosphate triesters:<br />
Application in the synthesis of bioactive<br />
molecules. R. Chegondi,<br />
C. D. Thomas, P. K. Venukadasula,<br />
S. Jayasinghe, S. Maitra, J. P. Mcparland,<br />
A. Whitehead, J. D. Waetzig,<br />
P. R. Hanson*<br />
1086. Phosphate-mediated, one-pot, sequential<br />
RCM/CM/hydrogenation approach<br />
toward the total synthesis of bioactive<br />
natural products.<br />
P. K. Venukadasula, R. Chegondi,<br />
S. Maitra, C. D. Thomas, P. R. Hanson*<br />
1087. Synthesis of functionalized amino-indanes<br />
via tandem aza-Prins and intramolecular<br />
Friedel-Crafts reactions of aryl Nphosphinylimines.<br />
O. J. Ingham,<br />
H. Kinoshita, A. B. Beeler, J. A. Porco<br />
1088. De novo asymmetric syntheses and<br />
biological evaluation of the analogs of<br />
SL0101. Q. Zhang, B. Wu, M. Shan,<br />
G. A. O’Doherty<br />
1089. Small molecule synthesis: Copper catalyzed<br />
allene formation and substituted<br />
cyclopropenes via dianion chemistry.<br />
M. Hassink,J.Fox<br />
1090. Phosphorus-based oligomers for application<br />
in synthesis. P. K. Maity,<br />
T. B. Samarakoon, A. Rolfe, T. R. Long,<br />
S. Faisal, R. D. Kurtz, P. R. Hanson*<br />
1091. Macrocyles through fragmentation of<br />
fused bicyclic ring systems. A. Bayir,<br />
M. Brewer<br />
1092. Utilizing fumagillol as a scaffold for diversity-oriented<br />
synthesis.<br />
B. R. Balthaser, J. A. Porco,<br />
J. K. Snyder, A. B. Beeler<br />
1093. Progress toward the total synthesis of<br />
(�)-tedanolide. D. Yoo, M. E. Jung<br />
1094. Total synthesis of rhodexin A. D. Yoo,<br />
H. V. Chu, M. E. Jung<br />
1095. Studies in oxidation of sulfides using<br />
pentavalent iodine reagents.<br />
V. G. Shukla, P. D. Salgaonkar,<br />
K. G. Akamanchi<br />
1096. Toward the synthesis of magnesidin, a<br />
tetramic acid. S. R. Pingali<br />
1097. Progress towards the total synthesis<br />
of (S)-jamaicamide C. E. O. De Oliveira,<br />
K. M. Graf, M. L. Brown, M. Paige<br />
98–TECH<br />
‡ Cooperative Cosponsorship<br />
1098. Synthetic applications of indole aryne<br />
cycloadditions: New strategies for the<br />
construction of complex natural products.<br />
N. Chandrasoma, H. A. Brassfield,<br />
N. Brown, D. Luo, A. Nerurkar,<br />
K. R. Buszek<br />
1099. Synthesis of novel Warfarin conjugates.<br />
B. P. Klemm, E. Tsogtbaatar,<br />
P. M. Doyle, D. E. Lewis<br />
1100. High-speed synthesis of 3,6-disubstituted<br />
pyrazolo[1,5-a]pyrimidines applied<br />
to bone morphogenetic protein signaling<br />
inhibitors. J. Liu, G. D. Cuny, P. B. Yu,<br />
X. Xing, K. D. Bloch, R. T. Peterson<br />
1101. Microwave-assisted synthesis of a<br />
naphtho-fused piperidine core via the intramolecular<br />
[4�2] cycloaddition of conjugated<br />
arenynes and alkynes: A model<br />
study for the potential synthesis of the<br />
antitumor agent Scriptaid. J. E. Horta<br />
1102. New SiliaBond ® coupling reagents to<br />
expedite amide synthesis. G. Gingras,<br />
O. Marion, M. Morin, F. Béland<br />
1103. Efficient removal of osmium-based<br />
catalysts using SiliaBond ® metal scavengers.<br />
G. Gingras, S. Potvin, F. Béland<br />
1104. Exploiting bacterial iron acquisition for<br />
antibiotic delivery: Synthesis, iron-binding<br />
properties, and microbiology of the<br />
trihydroxamate siderophore danoxamine,<br />
analogs, and antibiotic conjugates.<br />
T. A. Wencewicz, M. J. Miller<br />
1105. Development of a Mitsunobu-like process<br />
catalytic in phosphine. C. J. O’Brien,<br />
A. L. Carter<br />
PETR<br />
Division of Petroleum<br />
Chemistry<br />
K. Fjare, Program Chair<br />
OTHER SYMPOSIA OF INTEREST:<br />
Heavy Hydrocarbon Resources:<br />
Characterization, Upgrading and<br />
Utilization (see FUEL, Thu)<br />
Chemistry, Production, and Use of<br />
Green Fuels (see FUEL, Wed)<br />
Coal-, Gas-, Biomass- and Waste-to-<br />
Liquids Conversion (see FUEL, Wed &<br />
Thu)<br />
Storch Award: Symposium in Honor<br />
of Chunshan Song (see FUEL, Tue &<br />
Wed)<br />
Catalysis for Energy Storage (see<br />
CATL (probationary), Thu)<br />
SOCIAL EVENTS:<br />
PETR/FUEL Dinner, 6:30 PM: Tue<br />
BUSINESS MEETING:<br />
Executive Committee Meeting,<br />
4:00-6:00 PM: Sat<br />
Business Meeting, 12:00 PM: Tue<br />
SUNDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
Symposium in Honor of Henrik Topsoe<br />
C. Song, Organizer, Presiding<br />
F. Besenbacher, Presiding<br />
9:00 Introductory Remarks<br />
9:05 1. Probing the atomic-scale details of<br />
molecular adsorption on MoS 2 and<br />
CoMoS nanoclusters by STM.<br />
F. Besenbacher<br />
9:35 2. Advances in high-resolution transmission<br />
electron microscopy for catalysis.<br />
S. Helveg<br />
10:05 3. Recent advances in NO adsorption<br />
on Mo sulfide-based hydrotreating catalysts.<br />
N. Topsoe<br />
10:35 Intermission<br />
10:50 4. DFT insights on industrial supported<br />
catalysts. P. Raybaud<br />
11:20 5. Hydrotreating from first principles.<br />
B. Hinnemann<br />
11:50 6. Design rules for CoMo/Al2O3 hydrotreating<br />
catalysts: How to obtain true<br />
type II ‘Co-Mo-S’. E. Hensen,<br />
I. A. Dugulan, R. J. van Veen<br />
Operando and In Situ Spectroscopy<br />
X-ray Methods Sponsored by CATL<br />
(probationary), Cosponsored by COLL, FUEL,<br />
and PETR<br />
SUNDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
Symposium in Honor of Henrik Topsoe<br />
C. Song, Organizer<br />
E. Hensen, U. Ozkan, Presiding<br />
1:30 Introductory Remarks<br />
1:35 7. HDS studies on phosphide catalysts.<br />
T. S. Oyama, H. Zhao, H. Freund,<br />
K. Asakura, R. Wlodarczyk, M. Sierka<br />
2:05 8. Hydrodesulfurization properties of<br />
bimetallic and noble metal phosphide<br />
catalysts. M. E. Bussell, R. H. Bowker,<br />
J. R. Hayes, M. C. Smith, L. E. Bergquist,<br />
G. Savithra, S. L. Brock<br />
2:35 9. Selective adsorption for removing<br />
sulfur with oxidatively regenerable adsorbents<br />
for ultra clean fuels. C. Song,<br />
S. Watanabe, F. Sun, X. Ma<br />
3:05 10. Oxidative desulfurization of diesel<br />
fractions. A. Wang, X. Han, J. Zhang,<br />
X. Wang, X. Li, Y. Hu<br />
3:35 Intermission<br />
3:50 11. Insights into structure-sensitive reactions<br />
using model supported nanoparticle.<br />
S. M. McClure, M. Lundwall,<br />
D. W. Goodman<br />
4:20 12. Thermodynamics and kinetics of elementary<br />
steps in catalysis.<br />
C. T. Campbell<br />
4:50 13. Updating physisorption analyses<br />
for porous solids. W. C. Conner<br />
5:20 14. Lowering down the temperature<br />
synthesis of transition metal carbides:<br />
The case of niobium carbide.<br />
V. Teixeira da Silva, C. A. Chagas Jr.<br />
MONDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
Symposium in Honor of Henrik Topsoe<br />
C. Song, Organizer, Presiding<br />
C. Marshall, Presiding<br />
8:30 Introductory Remarks<br />
8:35 15. Applications of in situ spectroscopy<br />
to the study of catalyzed reactions.<br />
A. Bell<br />
9:05 16. Tailoring of surface chemical properties<br />
using electronic structure theory.<br />
J. K. Norskov<br />
9:35 17. Kinetic characterization of unsupported<br />
ReS 2 as hydrotreating catalyst.<br />
T. Ho, Q. Shen, J. McConnachie<br />
10:05 Intermission<br />
10:20 18. Role of nanatechnology in the development<br />
of new generations of catalysts<br />
for clean fuels production.<br />
H. Topsoe<br />
11:10 19. Atomic-scale insight into transition<br />
metal promotion and oxide supporteffects<br />
for MoS 2 and CoMoS nanoclusters<br />
in hydrotreating. J. V. Lauritsen,<br />
J. Kibsgaard, F. Besenbacher<br />
11:40 20. Developing HDS understanding<br />
based on real feed-stocks.<br />
T. V. Choudhary<br />
MONDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
Symposium in Honor of Henrik Topsoe<br />
C. Song, Organizer<br />
K. Knudsen, S. Oyama, Presiding<br />
1:30 Introductory Remarks<br />
1:35 21. Water gas shift reaction over supported<br />
gold nanoparticles. D. Williams,<br />
M. Shekhar, V. Kispersky, W. Lee, S. Kim,<br />
F. Ribeiro, J. Miller, E. Stach, N. Delgass<br />
2:05 22. On the reaction mechanism of<br />
methanol synthesis and water-gas-shift<br />
on Cu. L. C. Grabow, M. Mavrikakis<br />
2:35 23. Fundamental study of the ring<br />
opening of different component classes<br />
in diesel fuels. K. G. Knudsen,<br />
R. G. Egeberg, D. D. Whitehurst<br />
3:05 24. Hydrogen spillover: Fact and fiction.<br />
R. Prins<br />
3:35 Intermission<br />
3:50 25. Solid nanoparticles to stabilize water-oil<br />
emulsions and catalyze reactions<br />
at the liquid/liquid interface.<br />
D. E. Resasco, J. Faria, S. S. Crossley,<br />
M. Shen<br />
4:20 26. Selective alkane oxidation using<br />
supported Pt(II) and Pt(IV) halides.<br />
C. L. Marshall, E. A. Mader, J. T. Miller<br />
4:50 27. Heteroatom-containing carbon<br />
nanostructures as oxygen reduction reaction<br />
catalysts for PEM fuel cells.<br />
D. von Deak, E. J. Biddinger, U. S. Ozkan<br />
5:20 28. Gold surfaces: The chemical<br />
benchtop of nucleophilic coupling-reactions.<br />
B. Xu, C. M. Friend, R. J. Madix,<br />
A. Wittstock, M. Baümer<br />
5:50 Concluding Remarks<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
K. Fjare, Organizer<br />
8:00–10:00<br />
18. See previous listings.<br />
31, 38, 47, 63, 64, 70, 79. See subsequent<br />
listings.<br />
General Catalysis Sponsored by CATL<br />
(probationary), cosponsored by COLL, FUEL,<br />
and PETR<br />
TUESDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
6th International Symposium on<br />
Hydrotreating/Hydrocracking Technologies<br />
Catalyst Preparation and Characterization<br />
O. Koseoglu, S. Nagamatsu, L. Kraus,<br />
Organizers<br />
8:30 Introductory Remarks<br />
8:35 29. Support effect in hydrodeoxygenation.<br />
D. Laurenti, D. Laurenti,<br />
C. Geantet<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
9:15 30. Criterion CENTERA ® hydroprocessing<br />
catalysts: Improved active site<br />
architecture provides improved ULSD<br />
HDS activity. J. A. Smegal, T. T. Weber,<br />
L. S. Kraus<br />
9:45 31. High throughput experimentation<br />
as an efficient tool for the testing of hydroprocessing<br />
catalysts. J. Find, J. Berg,<br />
S. Vukojevic<br />
10:05 Intermission<br />
10:20 32. Investigations on 1-methyl naphthalene<br />
to (alkyl) benzene over surface<br />
modified USY zeolite. J. Park,<br />
J. Miyawaki, S. Yoon, I. Mochida<br />
10:40 33. Characteristics on HDS of gas oil<br />
over alumina-silica supports. J. Park,<br />
M. Yasudome, J. Miyawaki, S. Yoon,<br />
I. Mochida<br />
11:00 34. Origin of the versatile Brønsted<br />
acidity of amorphous silica-alumina used<br />
as catalytic support in hydrocracking.<br />
P. Raybaud, C. Chizallet<br />
11:20 35. Highly active nickel molybdate<br />
catalysts prepared for deep hydrodesulfurization<br />
of dibenzothiophene. C. Yin,<br />
D. Chen, S. Zhang, C. Liu<br />
11:40 36. Basic properties of supported<br />
transition metal sulfides: Combined DFT<br />
and infrared study. A. Travert, V. Ruaux,<br />
F. Maugé, J. Paul<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom F<br />
Advances in Biomass Pyrolysis and<br />
Catalytic Upgrading<br />
S. Oyama, Organizer<br />
F. A. Agblevor, Organizer, Presiding<br />
9:00 37. Direct coupled catalytic upgrading<br />
of switchgrass pyrolysis bio-oil vapors.<br />
J. Peters, X. Zhang, T. Pham,<br />
A. Gangadharan, R. Galiasso, L. Lobban,<br />
D. Resasco, R. Mallinson<br />
9:30 38. Production of stable biomass pyrolysis<br />
oils using fractional catalytic<br />
pyrolysis. F. A. Agblevor, O. Mante,<br />
R. McClung, T. S. Oyama<br />
10:00 39. Understanding fast pyrolysis of<br />
lignin. P. R. Patwardhan, P. A. Johnston,<br />
R. C. Brown, B. H. Shanks<br />
10:30 40. Studies on heat transfer effects in<br />
the pyrolysis of thick wood particles using<br />
FT-IR imaging. M. Bahng, M. Jarvis,<br />
T. Haas, M. R. Nimlos, B. Donohoe<br />
Surface Science of Catalysis Sponsored by<br />
CATL (probationary), Cosponsored by COLL,<br />
FUEL, and PETR<br />
TUESDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
6th International Symposium on<br />
Hydrotreating/Hydrocracking Technologies<br />
Catalyst Preparation and Characterization<br />
L. Kraus, O. Koseoglu, S. Nagamatsu,<br />
Organizers<br />
1:20 41. Effectiveness of metal organic<br />
frameworks for removal of refractory organosulfur<br />
compound present in liquid<br />
fuels. G. B. Brieva, J. M. Campos-Martin,<br />
S. Al-Zahranib, J. L. Fierro<br />
1:20 43. Optimization of dry catalyst impregnation<br />
in a double cone blender: An<br />
experimental and computational approach.<br />
F. S. Romanski,A.Dubey,<br />
A. W. Chester, M. Tomassone<br />
1:20 44. Effect of ZrSBA-15 support on hydrotreating<br />
catalytic functionalities of Mo,<br />
CoMo, and NiMo catalysts.<br />
M. D. Gudimella, K. K. Soni, S. Garg,<br />
M. Gnanamani, B. Thallada<br />
1:20 42. Development of zeolite based<br />
DMO/VGO hydrocracking catalyst.<br />
S. Tagawa, M. Ushio, J. Futigami,<br />
R. Kuroda, T. Kameoka, K. Nakano,<br />
T. Kagawa, O. R. Koseoglu, A. Al-Somali,<br />
A. Al-Hajji, A. Al-Abdulal, K. Al-Otaibi<br />
Section B<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom F<br />
Renewable Alternatives to Petroleum<br />
B. Anderson, Organizer<br />
R. Radhakrishnan, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 45. Catalytic pyrolysis of cellulose.<br />
F. W. Atadana, F. A. Agblevor<br />
2:00 46. Pyrolysis of substituted anisoles.<br />
D. J. Robichaud, A. M. Scheer,<br />
C. Mukarakate, M. R. Nimlos, G. Ellison,<br />
H. Carstensen, M. W. Jarvis<br />
2:25 47. Mechanism of the thermal decomposition<br />
of furfural: Chemistry of biomass<br />
to biofuels. A. K. Vasiliou,M.R.Nimlos,<br />
G. Ellison, J. W. Daily<br />
2:50 Intermission<br />
3:05 48. Measurement of tar cracking kinetics<br />
in a jet-stirred tank reactor and plug<br />
flow reactor. M. W. Jarvis,<br />
C. Mukarakate, P. Pepiot,<br />
D. J. Robichaud, M. R. Nimlos<br />
3:30 49. <strong>Chemical</strong> kinetics and modeling of<br />
biomass gasification. M. R. Nimlos,<br />
P. Pepiot, D. J. Robichaud, M. W. Jarvis,<br />
K. R. Gaston<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom G/H<br />
6th International Symposium on<br />
Hydrotreating/Hydrocracking Technologies<br />
Non-Conventional Processes<br />
L. Kraus, O. Koseoglu, S. Nagamatsu,<br />
Organizers<br />
3:00 50. Effect of supercritical water on upgrading<br />
reaction of oil sand bitumen.<br />
M. Morimoto, Y. Sugimoto, Y. Saotome,<br />
S. Sato, T. Takanohashi<br />
3:20 51. Thermolytic solvent extraction of<br />
biomass to produce heavy oils in high<br />
yield with low oxygen contents.<br />
C. E. Snape, H. Deng, C. Uguna,<br />
W. Meredith<br />
4:00 52. Development of nano nickel-based<br />
sorbent for ultra-deep desulfurization of<br />
ultra low sulfur diesel for fuel cell applications.<br />
C. S. Shalaby, X. Ma, C. Song<br />
4:40 53. Desulfurization of fuel fractions on<br />
modified adsorbents. M. M. Sugungun,<br />
A. Fayomi, E. Umukoro<br />
5:20 54. Development of high-performance<br />
adsorbent via oxidation modification of<br />
activated carbon for adsorptive denitrogenation<br />
of liquid hydrocarbon streams.<br />
N. LI, X. Ma, Q. Zha, C. Song<br />
WEDNESDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom F<br />
6th International Symposium on<br />
Hydrotreating/Hydrocracking Technologies<br />
Process Development<br />
O. Koseoglu, S. Nagamatsu, L. Kraus,<br />
Organizers<br />
8:30 55. Combined CoMo/NiMo catalyst<br />
system advantages in ULSD production,<br />
part I: Pilot plant studies. L. S. Kraus,<br />
P. J. Gripka<br />
9:00 56. Combined CoMo/NiMo catalyst<br />
system advantages in ULSD production,<br />
part II: Commercial experience.<br />
L. S. Kraus,P.J.Gripka<br />
9:30 57. Arab Light vacuum residue processing<br />
via high space velocity visbreaking<br />
and steam catalytic cracking.<br />
M. M. Fathi, P. Pereira Almao<br />
9:50 58. How does VGO HDS activity depend<br />
on feed boiling point?<br />
T. L. Jørgensen, R. G. Egeberg,<br />
K. G. Knudsen, A. Hidalgo-Vivas,<br />
P. Zeuthen<br />
10:10 59. Hydrotreating performance of<br />
novel catalyst on the support of Beta zeolite<br />
in-situ synthesis from kaolin clay.<br />
A. Duan, G. Wan, Y. Zhang, D. Zhang,<br />
Z. Zhao,R.Li<br />
10:30 Intermission<br />
10:45 60. Hydrotreating of gas oil on Ti-<br />
HMS supported heteropolyacid catalysts.<br />
K. K. Soni, P. E. Boahene, A. K. Dalai<br />
11:05 61. Direct production of gasoline and<br />
diesel from biomass using integrated hydropyrolysis<br />
and hydroconversion (IH 2 ).<br />
T. Marker, L. Felix, M. Linck, M. Roberts<br />
11:25 62. Impact of vaporization on catalyst<br />
deactivation in low pressure ultra-low sulfur<br />
diesel production. H. M. Sweers,<br />
M. Vichailak, L. S. Kraus<br />
Section B<br />
Renaissance Boston Waterfront<br />
Brewster<br />
Renewable Alternatives to Petroleum<br />
R. Radhakrishnan, Organizer<br />
B. Anderson, Organizer, Presiding<br />
9:00 63. Technoeconomic analysis of thermochemical-based<br />
biorefineries for coproduction<br />
of hydrogen and electricity.<br />
R. Braun, L. Hanzon, J. Dean<br />
9:30 Intermission<br />
9:45 64. Energy efficient ultra-fast biofuel<br />
production using ZnO/ La 2O 2CO 3 heterogeneous<br />
catalyst. L. Jin, Y. Zhang,<br />
A. Espinal, J. Dombrowski, M. Lai,<br />
S. Suib<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom F<br />
Chemistry of Petroleum and Emerging<br />
Technologies<br />
K. Fjare, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 65. Upgrading refinery off-gas to highoctane<br />
alkylate. J. Young, M. Mukherjee,<br />
J. Nehlsen<br />
2:00 66. Electronic and steric effects in the<br />
ultrasound-assisted oxidative desulfurization.<br />
F. J. Schattenmann,<br />
D. L. Ramage, S. Hoy IV, N. J. Shurgott,<br />
D. J. Wintergrass<br />
2:25 67. Biodegradation of petroleum refinery<br />
sludge. A. Tewari,S.Guha<br />
2:50 Intermission<br />
3:05 68. Molecular orientation of PAH molecules<br />
and asphaltenes in Langmuir-<br />
Blodgett films using sum frequency generation<br />
spectroscopy. A. Andrews,<br />
A. McClelland, O. Korkeila, A. Krummel,<br />
A. Demidov, Z. Chen<br />
3:30 69. Molecular Dynamics simulations of<br />
aromatic hydrocarbon combustion via the<br />
ReaxFF reactive force field. M. F. Russo,<br />
A. C. van Duin<br />
3:55 70. Decoupled rotation and translation<br />
across molecule sizes and polarities in a<br />
model bitumen. M. Greenfield<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Poster Session<br />
K. Fjare, Organizer<br />
2:00–4:00<br />
71. Quality testing of biodiesel and its blends<br />
with petroleum diesel as an alternative<br />
“Green” fuel according to ASTM methodologies.<br />
C. R. Perkins, J. D. Stuart,<br />
R. S. Parnas, A. A. Provatas<br />
72. Development of Innovation DME process<br />
from natural gas and biomass in Korea.<br />
W. Cho, T. Song, Y. Baek, S. Kim<br />
73. Deactivation mechanism of ZSM-5 during<br />
catalytic steam cracking of n-hexane.<br />
A. Yamaguchi, D. Jin, T. Ikeda, K. Sato,<br />
N. Hiyoshi, T. Inoue, M. Shirai,<br />
F. Mizukami, T. Hanaoka<br />
74. Screening and identifying of flocculantproducing<br />
strain and study on optimization<br />
of fermentation conditions. w. wu,<br />
D. Zhao, Y. Zhang, Q. Liu<br />
75. Study of a membrane reactor for 1-butanol<br />
production. S. Li, T. Williams,<br />
R. Srivastava, R. S. Parnas<br />
76. Investigation into the relationship between<br />
the gravity vector and the flow vector<br />
to enhance separation of coproduct<br />
glycerol in two-phase continuous flow<br />
biodiesel reactor. A. A. Midgette,<br />
S. A. Unker, M. B. Boucher, K. R. Hawley,<br />
J. D. Stuart, R. S. Parnas<br />
THURSDAY MORNING<br />
Section A<br />
Renaissance Boston Waterfront<br />
Pacific Ballroom F<br />
Chemistry of Petroleum and Emerging<br />
Technologies<br />
K. Fjare, Organizer, Presiding<br />
9:00 77. Phase behavior of polycyclic aromatic<br />
hydrocarbon mixtures: Eutectic formation,<br />
deviation from Raoult’s law, and<br />
solid azeotropy. J. W. Rice,J.Fu,<br />
E. M. Suuberg<br />
9:25 78. Investigation of fouling propensity<br />
of different crudes and gas oils.<br />
P. Rahimi, Z. Fan, T. Alem<br />
9:50 Intermission<br />
10:05 79. Micro-ESR: Online measurement<br />
of asphaltene and vanadium in crude oil.<br />
J. White, P. Giammatteo<br />
10:30 80. Investigation on the aggregation<br />
of asphaltene molecules. d. liu,M.Li,<br />
T. Hou, W. Jiang, B. Han, H. Sun<br />
Catalyst for Energy Storage Sponsored by<br />
CATL (probationary), Cosponsored by FUEL<br />
and PETR<br />
PHYS<br />
Division of Physical<br />
Chemistry<br />
M. Johnson, Program Chair<br />
OTHER SYMPOSIA OF INTEREST:<br />
ACS Award in Analytical Chemistry:<br />
Symposium in Honor of Richard Van<br />
Duyne (see ANYL, Mon)<br />
Frank H. Field and Joe L. Franklin<br />
Award for Outstanding Achievement<br />
in Mass Spectrometry: Symposium in<br />
Honor of Catherine Costello (see<br />
ANYL, Tue)<br />
Frontiers of Condensed Phase<br />
Theory and Simulation: A Tribute to<br />
Bruce J. Berne (see COMP, Sun)<br />
Waters: Feisty Little Molecules (see<br />
COMP, Mon)<br />
PETR/PHYS<br />
Fuel Cell Chemistry and Operation II<br />
(see FUEL, Tue)<br />
Surface and Interfacial Phenomena in<br />
Environmental Processes (see ENVR,<br />
Sun)<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–99
PHYS <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
SOCIAL EVENTS:<br />
PHYS Division/Journal of Physical<br />
Chemistry Letters Reception, 5:30<br />
PM: Tue<br />
SUNDAY MORNING<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units<br />
(GP-GPUs)<br />
GPU Computing in Chemistry Cosponsored<br />
by COMP<br />
J. D. Madura, V. Kindratenko, Organizers<br />
T. Dunning, Presiding<br />
8:00 Introductory Remarks<br />
8:05 1. New programming tools for improved<br />
development productivity in GPU<br />
computing. W. W. Hwu<br />
8:45 2. OpenCL: Molecular modeling on heterogeneous<br />
computing systems.<br />
J. E. Stone<br />
9:25 Intermission<br />
9:40 3. Acceleration of implicit solvent electrostatics<br />
with charge coarse-graining on<br />
GPUs. A. V. Onufriev<br />
10:20 4. (Really) Fast macromolecular electrostatics:<br />
Fast algorithms, open source<br />
software, and GPU computing.<br />
J. P. Bardhan, R. Yokota, M. G. Knepley,<br />
L. A. Barba<br />
10:40 5. Solving the many-body field equations<br />
of a point induced dipole potential<br />
on graphics processing units. J. L. Belof,<br />
B. Space<br />
11:00 6. Biomolecular simulations in heterogeneous<br />
computing architectures.<br />
S. Hampton, P. Agarwal<br />
11:20 7. GPU architecture and applications<br />
of GPU-enabled computing. D. Poole<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 107A<br />
PHYS Undergraduate Workshop<br />
M. Johnson, Organizer<br />
W. Polik, Organizer, Presiding<br />
8:00 8. How a national ACS meeting works.<br />
W. F. Polik<br />
8:20 9. Electrons in biomolecules.<br />
J. P. Simons<br />
8:50 10. Metals in biology. A. Palmer<br />
9:20 Intermission<br />
9:35 11. Solar energy conversion and storage.<br />
V. S. Batista<br />
10:05 12. Hydrates, heterogeneous chemistry,<br />
aerosols and climate. S. S. Brown<br />
10:35 Intermission<br />
10:50 13. Challenges for density functional<br />
theory. W. Yang<br />
11:20 14. Spectrochemical analysis.<br />
B. H. Pate<br />
11:50 Concluding Remarks<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 104C<br />
Electrons in Bio-Molecules<br />
Electron Attachment and Electron Transfer<br />
in DNA<br />
J. Simons, Organizer<br />
J. Weber, Organizer, Presiding<br />
8:15 Introductory Remarks<br />
‡ Cooperative Cosponsorship<br />
100–TECH<br />
8:20 15. Mechanisms of low energy electron<br />
(LEE) damage to DNA: From vacuum to<br />
cellular environment. L. Sanche<br />
9:00 16. Anion radical excited states from<br />
low energy electron addition: DNA strand<br />
break formation. M. D. Sevilla,A.Kumar<br />
9:40 17. Ab initio study of the elementary<br />
steps of electron transfer in DNA.<br />
E. Cauët, M. Rooman, R. Wintjens,<br />
J. Liévin<br />
10:00 Intermission<br />
10:20 18. Lesions in DNA subunits: Foundational<br />
studies of molecular structures and<br />
energetics. H. F. Schaefer<br />
11:00 19. Low-energy electron interactions<br />
with hydrated DNA and complex biological<br />
targets. T. M. Orlando<br />
11:40 20. Shedding a new light on photolyases:<br />
Accurate molecular modeling as a<br />
tool for undestanding DNA repairing enzymes.<br />
M. Stenta, M. Dal Peraro,<br />
M. Garavelli, P. Altoè, M. Di Domenico,<br />
A. Bottoni<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, Organizer<br />
V. Batista, Organizer, Presiding<br />
8:20 21. Nanostructured materials for solar<br />
energy conversion: The primary steps for<br />
light to charge. V. Sundstrom<br />
9:00 22. Ultrafast and not so fast spectroscopy<br />
to demystify the flavine photocatalysis<br />
of benzyl alcohol oxidation.<br />
E. Riedle, U. Megerle, M. Wenninger,<br />
R. Lechner, R. Kutta, B. Dick, B. König<br />
9:40 23. Electrochemical and photoelectrochemical<br />
processes in CdSe nanocrystals<br />
tethered to self-assembled monolayers<br />
and conductive polymers on indiumtin<br />
oxide. Z. O. Araci, C. R. Shallcross,<br />
N. R. Armstrong, S. Saavedra<br />
10:00 Intermission<br />
10:20 24. Modulating interparticle charge<br />
transfer in quantum dot solar cells.<br />
P. V. Kamat,K.Tvrdy<br />
11:00 25. Energy transport in �-conjugated<br />
dendritic macromolecules and polyelectrolytes.<br />
V. D. Kleiman<br />
11:40 26. Synthesis and characterization of<br />
Pb-chalcogenide dimer structures.<br />
B. K. Hughes, J. L. Blackburn,<br />
A. J. Nozik, J. M. Luther, O. E. Semonin,<br />
A. G. Midgett, D. K. Smith, M. C. Beard<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, Organizer<br />
V. Vaida, Organizer, Presiding<br />
8:20 27. Physical chemistry and climate:<br />
Molecules and photons to meteorology<br />
via maximization of entropy production<br />
and scale invariance. A. Tuck<br />
9:00 28. Formation of ammonium-water<br />
aerosols and water clusters and their atmospheric<br />
implications. G. C. Shields,<br />
B. Temelso, K. A. Archer, R. M. Shields,<br />
T. E. Morrell<br />
9:20 29. Spectroscopic signatures of acid<br />
dissociation in water clusters.<br />
S. S. Xantheas<br />
10:00 Intermission<br />
10:20 30. Water dimer equilibrium constant<br />
from first-principles calculations.<br />
C. Leforestier, K. Szalewicz,<br />
A. van der Avoird<br />
11:00 31. Direct observation of the dynamics<br />
of carbonic acid/bicarbonate buffer in<br />
aqueous environment. K. Adamczyk,<br />
M. Prémont-Schwarz, D. Pines,<br />
E. T. Nibbering, E. Pines<br />
11:20 32. Calculated vibrational and electronic<br />
spectra of hydrated complexes.<br />
H. G. Kjaergaard<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 105<br />
Challenges for Density Functional Theory<br />
W. Yang, Organizer<br />
X. Li, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:40 33. Density functional theory and the<br />
persistence of chemistry. J. P. Perdew,<br />
L. A. Constantin, K. Burke<br />
9:10 34. Deconstructing density functional<br />
theory and approximations. K. Burke,<br />
A. Cangi, P. Elliott, D. Lee<br />
9:40 35. Discontinuous nature of the exchange-correlation<br />
functional: The key for<br />
strongly correlated systems.<br />
P. Mori-Sánchez, A. J. Cohen, W. Yang<br />
10:10 36. Performance of ab initio and density<br />
functional methods for conformational<br />
equilibria of CnH2n�2 alkane isomers:<br />
A surprisingly difficult<br />
computational target. J. M. Martin<br />
10:25 Intermission<br />
10:45 37. On basic variational principles in<br />
density-functional theory. M. P. Levy<br />
11:15 38. Construction of integrable model<br />
Kohn-Sham potentials. V. N. Staroverov<br />
11:45 39. Using electronic structure theory<br />
to understand the interaction of Lithium<br />
with polycyclic aromatic hydrocarbons:<br />
Problems with density functional theory<br />
due to self-interaction and delocalization.<br />
T. A. Baker, M. Head-Gordon<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Molecular Dynamics and Monte Carlo-<br />
Models and Algorithms Sponsored by<br />
COMP, Cosponsored by PHYS<br />
New Frontiers in Single Molecule Detection<br />
and Single Cell Analysis Sponsored by<br />
ANYL, Cosponsored by BIOL and PHYS<br />
Tautomers and Biology<br />
Computer Handling of Tautomers<br />
Sponsored by COMP, Cosponsored by CINF,<br />
MEDI, and PHYS<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 104C<br />
Electrons in Bio-Molecules<br />
Excited States, Dynamics and Charge<br />
Transfer<br />
J. Weber, J. Simons, Organizers<br />
L. Slipchenko, Presiding<br />
1:30 40. Photochemistry of small DNA fragments<br />
via semiclassical nonadiabatic dynamics.<br />
A. Alexandrova, J. Tully,<br />
G. Granucci<br />
2:10 41. Decay pathways for long-lived excited<br />
states in DNA. B. Kohler,<br />
K. de La Harpe<br />
2:50 42. Conductivity of DNA duplexes<br />
bridging a single walled carbon nanotube<br />
gap. A. A. Gorodetsky,H.Wang,<br />
N. Muren, J. K. Barton, C. Nuckolls<br />
3:10 Intermission<br />
3:30 43. Excited states of DNA, from dimers<br />
to oligomers: Results from some new<br />
quantum-chemical methods.<br />
J. M. Herbert<br />
4:10 44. Cooperative effect in the electronic<br />
properties DNA oligomers. T. Z. Markus,<br />
S. S. Daube, R. Naaman<br />
4:50 45. An electron hops along �-helix over<br />
100 Å. T. Morita, Y. Arikuma,<br />
H. Nakayama, S. Kimura<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, V. Batista, Organizers<br />
L. Chen, Presiding<br />
1:30 46. Integrating photoconversion building<br />
blocks with catalysts for solar fuels<br />
formation. M. R. Wasielewski,<br />
A. P. Samuel, D. T. Co, C. L. Stern<br />
2:10 47. Molecules for singlet fission.<br />
J. C. Johnson, Z. Havlas, A. Akdag,<br />
M. B. Smith, B. R. Stepp, J. Michl<br />
2:50 48. Ultrafast charge separation in a ruthenium<br />
polypyridyl complex with a<br />
�-conjugated ligand. J. D. Henrich,<br />
P. K. Dutta, B. Kohler<br />
3:10 Intermission<br />
3:30 49. Electron transfer in molecular dyads<br />
and tetrads. A. C. Benniston<br />
4:10 50. Enhanced effects in useful light<br />
harvesting organic systems and assemblies.<br />
T. Goodson<br />
4:50 51. Organic photovoltaic cells from<br />
contorted hexabenzocoronenes.<br />
A. A. Gorodetsky, C. Chiu, T. Schiros,<br />
Z. Bullard, M. Palma, M. Cox, I. Kymissis,<br />
C. Nuckolls<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 105<br />
Challenges for Density Functional Theory<br />
W. Yang, X. Li, Organizers<br />
P. Mori Sánchez, Presiding<br />
1:30 52. Density functional theory for kinetics,<br />
catalysis, and organometallic complexes.<br />
D. G. Truhlar<br />
2:00 53. RPA for correlation: Promise and<br />
challenges. F. U. Furche, H. Eshuis<br />
2:30 54. Spin-adapted open-shell RPA and<br />
TDDFT. Z. Li, W. Liu<br />
3:00 55. Nonlocal density functionals for<br />
treating long-range correlations.<br />
O. A. Vydrov, T. Van Voorhis<br />
3:15 Intermission<br />
3:35 56. Density functionals for weak and<br />
strong correlations. M. Head-Gordon<br />
4:05 57. Non-local exchange-correlation<br />
functionals targeting long-range electron<br />
correlation. P. W. Ayers<br />
4:35 58. Improving band gap prediction by<br />
density functional theory: From atoms to<br />
solids. X. Zheng, A. J. Cohen,<br />
P. Mori-Sánchez, W. Yang<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
H. Kjaergaard, Presiding<br />
1:30 59. Influence of water on radical-molecular<br />
reactions on aerosol surfaces:<br />
Perspective from a study of water atmosphere<br />
surface reaction models.<br />
R. J. Buszek, J. S. Francisco<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
2:10 60. Radical-molecule complexes: A<br />
computational and experimental study of<br />
their structures, thermodynamics and reactivity.<br />
J. C. Hansen, J. Clark, S. T. Call,<br />
D. Austin<br />
2:30 61. Association reactions of hydroxyl<br />
radicals with atmospheric species.<br />
M. I. Lester<br />
3:10 62. OH-initiated oxidation of volatile organic<br />
compounds: OH � ethene.<br />
L. J. Butler, B. J. Ratliff, C. C. Womack,<br />
B. W. Alligood, D. E. Szpunar, J. J. Lin,<br />
S. Lee<br />
3:30 Coffee Break<br />
3:50 63. <strong>Chemical</strong> reactions at water and ice<br />
surfaces: Models and dynamics simulations.<br />
B. R. Gerber<br />
4:30 64. Properties of the ice surface from<br />
quantum molecular dynamics simulations.<br />
F. Paesani<br />
4:50 65. Spectroscopic probes of ice surfaces,<br />
clathrate hydrates, and aqueous<br />
clusters. M. Shultz, P. Bisson, T. Vu<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units<br />
(GP-GPUs)<br />
Molecular Dynamics on GPUs Cosponsored<br />
by COMP<br />
V. Kindratenko, Organizer<br />
J. D. Madura, Organizer, Presiding<br />
1:30 66. OpenMM � Folding@home: GPU<br />
molecular dynamics for protein folding on<br />
the millisecond timescale in all-atom detail.<br />
V. Pande<br />
2:10 67. Graphical processing unit acceleration<br />
of coarse grained molecular dynamics<br />
and data analysis. D. N. LeBard,<br />
B. G. Levine, R. DeVane, W. Shinoda,<br />
J. E. Stone, A. Kohlmeyer, K. L. Michael<br />
2:50 68. DL_POLY 3: Hybrid CUDA/<br />
OpenMP porting of the non-bonded<br />
force-field for two-body systems.<br />
C. Kartsaklis, I. Todorov, W. Smith<br />
3:10 Intermission<br />
3:30 69. Multiscaling and coarse grained<br />
models using molecular dynamics on<br />
GPUs: The perfect marriage.<br />
A. Travesset<br />
4:10 70. Adapting AMBER particle mesh<br />
Ewald and generalized Born molecular<br />
dynamics to GPUs. S. Le Grand<br />
4:50 71. Withdrawn<br />
5:10 72. Pretty Fast Analysis: A software<br />
suite for analyzing large scale simulations<br />
on supercomputers and GPU clusters.<br />
D. N. LeBard<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 107A<br />
Physical Chemistry of Spectrochemical<br />
Analysis<br />
B. Pate, Organizer<br />
K. Lehmann, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 73. Stimulated Raman scattering microscopy.<br />
S. Xie, W. Min, B. Saar,<br />
C. Freudiger<br />
2:15 74. Surface enhanced spectroscopy:<br />
From single molecules to non-linear optics.<br />
J. Camden<br />
2:55 75. 2D cell membrane profiling through<br />
ratiometric silver plasmon ruler tracking.<br />
B. M. Reinhard<br />
3:15 Intermission<br />
3:30 76. Nonlinear vibrational microscopy of<br />
cellulose fibers. E. O. Potma<br />
4:10 77. Excited state dynamics of solutionphase<br />
photosynthetic antenna proteins<br />
studied one at a time. R. Goldsmith<br />
4:30 78. New insights on HIV-1 nucleocapsid<br />
protein as a DNA-bending protein: A<br />
single-molecule spectroscopic study.<br />
H. Wang, C. Falk, P. F. Barbara<br />
4:50 79. Predicting the frequency dispersion<br />
of electronic hyperpolarizabilities based<br />
on absorption data and Thomas-Kuhn<br />
sum rules. X. Hu, W. Yang, D. N. Beratan<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Hydrophobic Effect and Solvation<br />
Phenomena Sponsored by COMP,<br />
Cosponsored by PHYS<br />
New Frontiers in Single Molecule Detection<br />
and Single Cell Analysis Sponsored by<br />
ANYL, Cosponsored by BIOL and PHYS<br />
MONDAY MORNING<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
J. Hansen, Presiding<br />
8:00 80. Shape dependence of water cluster-mediated<br />
reactions relevant to the upper<br />
atmosphere. M. A. Johnson<br />
8:40 81. Probing conformation changes and<br />
isomeric populations of complex anions<br />
solvation using low-temperature photoelectron<br />
spectroscopy. X. Wang<br />
9:00 82. Reactions of organic acids with<br />
protonated water clusters: Implications of<br />
cluster growth in the atmosphere.<br />
A. W. Castleman, E. G. Goken<br />
9:40 83. Implementation of dynamical nucleation<br />
theory effective fragment potentials<br />
(DNTEFP) method for modeling aerosol<br />
chemistry. A. Devarajan,<br />
T. L. Windus, M. S. Gordon<br />
10:00 Coffee Break<br />
10:20 84. Vapor-to-particle nucleation: A<br />
molecular perspective. B. C. Garrett,<br />
S. M. Kathmann, G. K. Schenter<br />
11:00 85. Equilibrium properties of aqueous<br />
electrolytes within narrow slit-shaped silica<br />
pores: Molecular dynamics simulation<br />
results to design separation strategies.<br />
D. Argyris, T. A. Ho, A. Striolo<br />
11:20 86. Adsorption of ions to aqueous interfaces<br />
and their effects on evaporation<br />
rates. D. E. Otten, R. M. Onorato,<br />
W. S. Drisdell, R. C. Cohen,<br />
R. J. Saykally<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units<br />
(GP-GPUs)<br />
Electronic Structure Calculations on GPUs<br />
Cosponsored by COMP<br />
J. D. Madura, V. Kindratenko, Organizers<br />
T. Martinez, Presiding<br />
8:00 87. Electronic structure calculations on<br />
graphical processing units.<br />
M. S. Gordon, T. L. Windus, B. M. Bode,<br />
J. Felder, A. Asadchev, V. Allada<br />
8:40 88. Quantum chemistry and ab initio<br />
molecular dynamics on graphical processing<br />
units (GPUs). I. S. Ufimtsev,<br />
T. J. Martinez<br />
9:20 89. Calculating molecular integrals of d<br />
and higher angular momentum functions<br />
on GPUs. A. V. Titov, I. Ufimtsev,<br />
T. Martinez, T. H. Dunning, Jr.<br />
9:40 Intermission<br />
10:00 90. Graphics processing units (GPU)<br />
for correlated quantum chemistry calculations.<br />
A. Aspuru-Guzik<br />
10:40 91. Liouville-von Neumann dynamics<br />
on GPU. J. Jakowski, K. Morokuma<br />
11:00 92. GPU-accelerated variational path<br />
integral Monte Carlo simulations.<br />
R. J. Hinde, R. Harrison, G. Peterson,<br />
V. Kakani, S. Mudhasani<br />
11:20 93. Full acceleration of quantum<br />
Monte Carlo simulations on GPU clusters.<br />
K. Esler, J. Kim, D. Ceperley<br />
11:40 94. Efficient pseudo-random number<br />
generators for biomolecular simulations<br />
on graphics processors. V. A. Barsegov<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 104C<br />
Electrons in Bio-Molecules<br />
Electron Transfer and Bond Cleavage<br />
J. Weber, J. Simons, Organizers<br />
J. Herbert, Presiding<br />
8:20 95. Conformationally-coupled charge<br />
transfer in biomolecules. D. N. Beratan<br />
9:00 96. Electron interaction with biomolecules<br />
in the gas phase and embedded in<br />
superfluid helium droplets. V. Vizcaino,<br />
S. Denifl, T. D. Märk, P. Scheier<br />
9:40 97. Charge-transfer excitations in proteins.<br />
J. D. Hirst<br />
10:00 Intermission<br />
10:20 98. Primary information on DNA oxidative<br />
damage: Photoelectron spectroscopy<br />
of nucleotides in a fully aqueous environment.<br />
S. E. Bradforth,<br />
C. Schroeder, W. Schroeder, R. Seidel,<br />
M. Faubel, B. Winter<br />
11:00 99. Modeling of anions of biological<br />
molecules. M. Gutowski,S.Ling,<br />
M. Haranczyk<br />
11:40 100. Electronic structure and exciton<br />
coupling in prototypical bichromophores.<br />
L. V. Slipchenko<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, V. Batista, Organizers<br />
V. D. Kleiman, Presiding<br />
8:20 101. Controlling coupled electron<br />
transfers in artifical photosynthesis for<br />
solar fuel production. L. Hammarstrom<br />
9:00 102. TiO 2 photocatalysis: New approaches.<br />
A. Fujishima<br />
9:40 103. Structure and organization of photosynthetic<br />
antenna complexes for efficient<br />
excitation energy transfer.<br />
S. A. Kovács, W. P. Bricker, K. W. Leung,<br />
C. S. Lo<br />
10:00 Intermission<br />
10:20 104. Molecular snapshot in solar energy<br />
conversion processes. L. X. Chen,<br />
J. V. Lockard, A. B. Stickrath, X. Zhang,<br />
M. W. Mara, K. Attenkofer<br />
11:00 105. Proton-coupled electron transfer<br />
in solar energy conversion.<br />
S. Hammes-Schiffer<br />
11:40 106. Vernier template directed synthesis<br />
of giant nanorings.<br />
M. C. O’Sullivan, J. K. Sprafke,<br />
H. L. Anderson<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 107A<br />
Physical Chemistry of Spectrochemical<br />
Analysis<br />
K. Lehmann, Organizer<br />
B. Pate, Organizer, Presiding<br />
8:25 107. Chirped-pulse Fourier transform<br />
spectroscopy in the THz region.<br />
K. O. Douglass, E. Gerecht,<br />
D. F. Plusquellic<br />
9:05 108. Development of 2D spectroscopic<br />
techniques for rotational spectroscopy.<br />
B. Dian<br />
9:45 109. Rydberg fingerprint spectroscopy<br />
for spectrochemical analysis.<br />
J. D. Geiser, E. M. Minogue, M. P. Minitti,<br />
P. M. Weber<br />
10:05 Intermission<br />
10:20 110. <strong>Chemical</strong> imaging of “sparse”<br />
systems: Characterizing both physical<br />
and chemical properties. N. Lewis,<br />
J. Dubois, L. Kidder, K. Haber<br />
11:00 111. Laser initiated, metal cation assisted,<br />
dissociation of organic molecules.<br />
D. J. Bellert, I. E. Laboren, O. J. Villarroel<br />
11:20 112. Novel computational method for<br />
comparing vibrational circular dichroism<br />
spectra. J. Shen<br />
11:40 113. Site-specific and vibrational coupling<br />
effects on IR spectra of adsorbed<br />
CO on Pt clusters characterized by DFT<br />
and classical electrostatics.<br />
E. S. Smotkin, M. K. Fuccillo, N. Dimakis<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Room 103<br />
Metals in Biology<br />
Bioinspired Inorganic Synthesis<br />
A. Palmer, Organizer<br />
T. Brunold, Presiding<br />
9:15 Introductory Remarks<br />
9:20 114. Modeling the CUz site in nitrous<br />
oxide reductase: Synthesis and properties<br />
of copper-sulfur complexes.<br />
W. B. Tolman<br />
9:50 Discussion<br />
10:00 115. Heme-copper dioxygen reactivity<br />
to heme-copper oxidases. K. D. Karlin<br />
10:30 Discussion<br />
10:40 116. Synthetic mono- and diiron complexes<br />
as models for high-valent intermediates<br />
of nonheme iron oxygenases.<br />
L. Que, Jr<br />
11:10 Discussion<br />
11:20 117. Bio-inspired approaches to activate<br />
dioxygen using nickel complexes.<br />
C. G. Riordan<br />
11:50 Discussion<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Quantum Effects in Thermodynamics and<br />
Dynamics Sponsored by COMP,<br />
Cosponsored by PHYS<br />
Tautomers and Biology<br />
Predictions of Tautomer Ratios Sponsored<br />
by COMP, Cosponsored by CINF, MEDI, and<br />
PHYS<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 104C<br />
Electrons in Bio-Molecules<br />
Spectroscopic Probes of Structure and<br />
Dynamics<br />
J. Weber, J. Simons, Organizers<br />
A. Alexandrova, Presiding<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
PHYS<br />
TECH–101
PHYS <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
1:30 118. Electronic spectroscopy of nucleic<br />
acids in the gas phase. V. Gabelica,<br />
F. Rosu, L. Joly, E. De Pauw, K. Matheis,<br />
M. M. Kappes, A. Giuliani,<br />
A. Milosavljevic, M. Refregiers, L. Nahon,<br />
R. Antoine, P. Dugourd<br />
2:10 119. Ultraviolet photodissociation of<br />
mononucleotides from cradle to grave.<br />
J. C. Marcum,J.M.Weber<br />
2:50 120. Electron photo-detachment experiments<br />
and UV spectroscopy of entire<br />
proteins in the gas phase. P. Dugourd<br />
3:10 Intermission<br />
3:30 121. Protein conformational dynamics<br />
probed by fluorescence quenching reactions.<br />
J. H. Parks,X.Shi<br />
4:10 122. Electrophilic properties of isolated<br />
biological molecules: Anion photoelectron<br />
spectroscopic studies. K. Bowen<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, V. Batista, Organizers<br />
T. Goodson, Presiding<br />
1:30 123. Progress toward solar water splitting<br />
in the Yale Solar Group. G. Brudvig,<br />
V. Batista, C. Schmuttenmaer,<br />
R. Crabtree<br />
2:10 124. Efficient light-driven water oxidation<br />
by sensitizer-carbon-free catalyst<br />
systems. C. L. Hill, Y. V. Geletii,<br />
Z. Huang, Q. Yin, Y. Hou, D. G. Musaev,<br />
T. Lian<br />
2:50 125. Water oxidation as the electronproton<br />
source in artificial photosynthetic<br />
devices. J. J. Concepcion, Z. Chen,<br />
M. R. Norris, C. R. Glasson, W. Song,<br />
M. K. Brennaman, J. L. Templeton,<br />
T. J. Meyer<br />
3:10 Intermission<br />
3:30 126. Light driven generation of hydrogen<br />
from water: New developments, new<br />
strategies and new results. R. Eisenberg<br />
4:10 127. Light-driven oxidation of water<br />
aiming for solar fuel production.<br />
M. Anderlund<br />
4:50 128. Macrocyclic cobalt complexes as<br />
electrocatalysts for clean and sustainable<br />
energy. B. D. Stubbert,<br />
B. S. Brunschwig, J. R. Winkler,<br />
H. B. Gray<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 105<br />
Challenges for Density Functional Theory<br />
W. Yang, X. Li, Organizers<br />
A. Vela, Presiding<br />
1:30 129. Strategies for meeting challenges<br />
to DFT: Recent applications.<br />
W. A. Goddard<br />
2:00 130. Partition potentials and delocalization<br />
error in density functional theory.<br />
A. Wasserman<br />
2:30 131. Density-based energy decomposition<br />
analysis. Q. Wu, P. Ayers, Y. Zhang<br />
3:00 132. Towards frozen-density embedding<br />
for subsystems connected by covalent<br />
bonds. C. R. Jacob<br />
3:15 Intermission<br />
3:35 133. Comparison of oscillator strengths<br />
calculated by time dependent density<br />
functional theory (TD-DFT) and wavefunction<br />
methods. B. T. Psciuk,<br />
M. M. Allard, J. A. Sonk, S. K. Lee,<br />
J. F. Endicott, H. B. Schlegel<br />
4:05 134. Time-dependent phase-spacedensity<br />
functional theory: A semiclassical<br />
approach. N. T. Maitra<br />
‡ Cooperative Cosponsorship<br />
102–TECH<br />
4:35 135. Accurate binding curves in transition-metal<br />
molecules using a DFT�U(R)<br />
approach. H. J. Kulik, N. Marzari<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
A. Bertram, Presiding<br />
1:30 136. Chirality in the climate system.<br />
F. M. Geiger<br />
2:10 137. Surface interactions and their role<br />
in the uptake and reactivity of atmospheric<br />
gases to environmentally relevant<br />
aqueous solutions. S. T. Ota,<br />
G. L. Richmond<br />
2:30 138. Surfactant control of gas transport<br />
and reactions at the surface of sulfuric<br />
acid. D. K. Burden, A. M. Johnson,<br />
G. M. Nathanson<br />
3:10 139. Collision dynamics as a probe of<br />
interfacial structure. C. Waring,<br />
P. A. Bagot, M. L. Costen,<br />
K. G. McKendrick<br />
3:30 Coffee Break<br />
3:50 140. Interfacial chemistry and climate.<br />
V. H. Grassian<br />
4:30 141. Second harmonic generation<br />
spectroscopic investigations of NO x<br />
compounds at the air/water interface.<br />
E. A. Raymond, P. V. Johnston,<br />
P. E. Teichen<br />
4:50 142. First principles molecular dynamics<br />
simulations of ion adsorption and acid-base<br />
chemistry at the air-water interface.<br />
D. J. Tobias<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units<br />
(GP-GPUs)<br />
GPU Computing in Chemistry Cosponsored<br />
by COMP<br />
J. D. Madura, Organizer<br />
V. Kindratenko, Organizer, Presiding<br />
1:30 143. Quantum reactive scattering calculations<br />
in GPU and mixed GPU-CPU<br />
environments. K. Linehan,<br />
M. H. Alexander, D. P. O’Leary<br />
2:10 144. Stability of molecular dynamics on<br />
GPUs: Is your card better than mine?<br />
O. Isayev<br />
2:30 145. GPUs: Concerns of a professional<br />
software developer. B. Cole, B. Tolbert,<br />
A. Nicholls<br />
2:50 146. Computer-based entropy estimation:<br />
Application to model cavity-ligand<br />
recognition and binding. R. Baron<br />
3:10 Concluding Remarks<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 107A<br />
Physical Chemistry of Spectrochemical<br />
Analysis<br />
B. Pate, K. Lehmann, Organizers<br />
J. Camden, Presiding<br />
1:30 147. SERS approach for bacterial diagnostics.<br />
L. Ziegler<br />
2:10 148. Coherant Raman scattering spectroscopy<br />
in biological imaging and biosensing<br />
applications. J. Ogilvie,<br />
B. Bachler, M. Cui, S. Nichols<br />
2:50 149. Phonon dynamics imaging of carbon<br />
nanotubes and graphene using<br />
broadband time-resolved CARS microscopy.<br />
Y. J. Lee, S. H. Parekh, J. A. Fagan<br />
3:10 Intermission<br />
3:25 150. Optical imaging and control of<br />
electrical spikes in single bacteria.<br />
J. M. Kralj, D. R. Hochbaum, A. E. Cohen<br />
4:05 151. Silver-alkenethiol interaction monitored<br />
by localized surface plasmon resonance.<br />
K. Kalkan,R.Ede<br />
4:25 152. Cation selective conformational<br />
preferences in thrombin binding aptamer:<br />
Steady state Förster resonance energy<br />
transfer approach. C. K. Nandi,<br />
C. Hayden, H. Yang<br />
4:45 153. Developing a novel scanning imaging<br />
technique for magnetic particles in<br />
bioanalytical chemistry. L. Yao,S.Xu<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Room 103<br />
Metals in Biology<br />
Techniques for Monitoring Cellular Metals<br />
A. Palmer, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 154. Novel sensors for mobile zinc and<br />
selected biological applications.<br />
S. Lippard<br />
2:05 Discussion<br />
2:15 155. Metallo-DNAzymesas a new class<br />
of fluorescent, colorimetric and MRI<br />
metal ion sensors. Y. Lu<br />
2:45 Discussion<br />
2:55 156. Biophysical probes of iron metabolism<br />
in eukaryotic cells. P. A. Lindahl<br />
3:25 Discussion<br />
3:35 157. Dynamic imaging of trace metals<br />
by optical and X-ray fluorescence microscopy.<br />
C. J. Fahrni<br />
4:05 Discussion<br />
4:15 158. Photoinduced electron transfer in<br />
small-molecule fluorescent sensors: A<br />
computational investigation.<br />
T. Kowalczyk, C. Lin, T. Van Voorhis<br />
4:30 Discussion<br />
4:35 159. Corrinoid iron-sulfur protein<br />
methyl transferase complexes studied by<br />
solution small-angle X-ray scattering.<br />
N. Ando, Y. Kung, G. Bender,<br />
S. W. Ragsdale, C. L. Drennan<br />
4:50 Discussion<br />
4:55 160. Single-molecule FRET studies of<br />
zinc(II) cytochrome c folding. A. J. Lee,<br />
K. L. Bren, T. D. Krauss<br />
5:10 Discussion<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Thermodynamics and Dynamics of<br />
Complex Systems Sponsored by COMP,<br />
Cosponsored by PHYS<br />
Undergraduate Research Posters<br />
Physical Chemistry Sponsored by CHED,<br />
Cosponsored by PHYS and SOCED<br />
MONDAY EVENING<br />
Section I<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
M. Johnson, Organizer<br />
8:00–10:00<br />
327, 334, 335, 336, 367, 368, 378, 383, 387,<br />
396, 397, 409, 410, 468, 469, 470, 471,<br />
472, 473, 476, 481, 511, 523, 538, 539,<br />
625, 626, 631. See subsequent listings.<br />
TUESDAY MORNING<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
J. Thornton, Presiding<br />
8:00 161. Uptake and release of trace gases<br />
by reaction at seawater and ice surfaces.<br />
J. Donaldson<br />
8:40 162. Towards a more quantitative understanding<br />
of the marine organic nanolayer.<br />
G. Friedrichs<br />
9:00 163. Photoinduced aging of tropospheric<br />
aerosols: What is more important<br />
UV or visible light? C. George,<br />
B. D’Anna, M. Monge, R. Ammar,<br />
T. Rosenoern<br />
9:40 164. Photochemistry laboratory studies<br />
of �-keto-carboxylic acids in water and<br />
ice. M. I. Guzman,A.G.Rincon,<br />
M. R. Hoffmann, A. J. Colussi<br />
10:00 Coffee Break<br />
10:20 165. Freezing of supercooled water<br />
nanodroplets. B. E. Wyslouzil, A. Manka,<br />
J. Wölk, R. Strey<br />
11:00 166. Measurement of heterogeneous<br />
ice nucleation rates in supercooled water<br />
using a high-throughput microfluidic apparatus.<br />
C. A. Stan,B.J.Wiley,<br />
G. F. Schneider, M. Ibanescu,<br />
G. M. Whitesides<br />
11:20 167. Laboratory studies of ice nucleation<br />
on mineral dust and biological particles.<br />
D. Chernoff, M. L. Eastwood,<br />
M. Wheeler, R. Iannone, E. Girard,<br />
A. K. Bertram<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Room 103<br />
Metals in Biology<br />
Structure-Function Connections<br />
A. Palmer, Organizer, Presiding<br />
8:15 Introductory Remarks<br />
8:20 168. Anatomy of a radical enzyme.<br />
C. Drennan<br />
8:50 Discussion<br />
9:00 169. Single-molecule dynamics of<br />
metal regulators and transporters.<br />
P. Chen<br />
9:30 Discussion<br />
9:40 170. Diiron monooxygenases catalyze<br />
the oxidation of hydrocarbons including<br />
methane, toluene, and other compounds.<br />
B. Fox<br />
10:10 Discussion<br />
10:20 171. Recent developments and uses<br />
of theoretical spectrosocopy in bioinorganic<br />
chemistry. F. Neese<br />
10:50 Discussion<br />
11:00 172. Insights into copper coordination<br />
and copper-dioxygen reactivity of<br />
�–synuclein. H. R. Lucas,<br />
S. Debeer George, J. C. Lee<br />
11:15 Discussion<br />
11:20 173. Examining the structure-function<br />
relationship in bacterial cytochrome c<br />
peroxidase using protein film voltammetry.<br />
C. F. Becker, S. J. Elliott,<br />
N. J. Watmough<br />
11:35 Discussion<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
11:40 174. Crystal structure of a metalloenzyme<br />
complex involved in bacterial acetogenesis.<br />
Y. Kung,N.Ando,<br />
T. I. Doukov, L. C. Blasiak, G. Bender,<br />
S. W. Ragsdale, C. L. Drennan<br />
11:55 Discussion<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 104C<br />
Electrons in Bio-Molecules<br />
Spectroscopic Probes of Structure and<br />
Dynamics<br />
J. Weber, J. Simons, Organizers<br />
S. Brøndsted Nielsen, Presiding<br />
8:20 175. Molecular and electronic structures<br />
of few open-shell or closed-shell<br />
biomolecular anions. C. Desfrançois,<br />
J. Poully, F. Lecomte, J. Schermann,<br />
G. Grégoire, X. Li, H. Wang, K. H. Bowen<br />
9:00 176. Fragmentation mechanisms of<br />
electronically excited peptides in a cold<br />
ion trap. M. Guidi, J. A. Stearns,<br />
O. V. Boyarkin, T. R. Rizzo<br />
9:40 177. Quantum nonadiabatic dynamics<br />
with perturbative treatment of vibrational<br />
relaxation. A. F. Izmaylov, J. C. Tully,<br />
M. J. Frisch<br />
10:00 Intermission<br />
10:20 178. Single conformation spectroscopy<br />
and isomerization of synthetic<br />
foldamers and crown macrocycles.<br />
T. S. Zwier, W. H. James III,<br />
E. G. Buchanan, S. H. Gellman, L. Guo<br />
11:00 179. Solvatochromism in the gas<br />
phase. A. J. Fleisher, P. J. Morgan,<br />
D. W. Pratt<br />
11:40 180. Ultrafast excited state molecular<br />
dynamics of rhodopsin, bathorhodopsin<br />
and isorhodopsin. I. Schapiro,<br />
M. Olivucci<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, V. Batista, Organizers<br />
M. Anderlund, Presiding<br />
8:20 181. Plasmon enhanced dye-sensitized<br />
solar cells: Current status and multiscale<br />
modeling. G. C. Schatz<br />
9:00 182. Capped and strapped Zn(II) tetraphenyl<br />
porphyrins as sensitizing dyes for<br />
TiO 2. E. Galoppini, C. Lee, K. Chitre<br />
9:40 183. Single crystals of functionalized<br />
nanoparticles as a medium for structural<br />
and spectroscopic studies of photosensitizer<br />
dyes on semiconductor surfaces.<br />
J. B. Benedict, P. Coppens<br />
10:00 Intermission<br />
10:20 184. Nanoparticle based Raman dyes<br />
and chemical mechanism of enhancement.<br />
S. J. Hurst, H. C. Fry,<br />
D. J. Gosztola, T. Rajh<br />
11:00 185. Active photochemical control in<br />
complex systems for solar energy conversion.<br />
N. H. Damrauer<br />
11:40 186. High-density charge carrier injection<br />
into organic and polymer semiconductors.<br />
L. G. Kaake,X.Zhu<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 107A<br />
Physical Chemistry of Spectrochemical<br />
Analysis<br />
B. Pate, K. Lehmann, Organizers<br />
D. Plusquellic, Presiding<br />
8:25 187. Transient optical spectroscopy for<br />
chemical dynamics with fully tunable excitation,<br />
two octaves of probe coverage<br />
and spanning the range from tens of femtoseconds<br />
to milliseconds. E. Riedle<br />
9:05 188. Mid-infrared frequency comb upconversion<br />
spectroscopy.<br />
S. K. Diddams, T. Johnson,<br />
L. Nugent-Glandorf<br />
9:45 189. Real-time mapping of electronic<br />
structure with single-shot 2D photonecho<br />
electronic spectroscopy. E. Harel,<br />
A. F. Fidler, G. S. Engel<br />
10:05 Intermission<br />
10:20 190. Fourier transform spectrometry<br />
with a near infrared supercontinuum<br />
source. P. M. Chu, C. A. Michaels,<br />
T. Masiello<br />
11:00 191. Broadband coherent spectroscopy<br />
in the near infrared using dual coherent<br />
frequency combs. N. R. Newbury,<br />
I. Coddington, E. Baumann, F. Giorgetta,<br />
W. C. Swann, A. Zolot<br />
11:40 192. Resonance enhanced two photon<br />
ionization of group VIII transition<br />
metal carbides. X. Shi, Y. Chang, C. Ng<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 105<br />
Challenges for Density Functional Theory<br />
W. Yang, X. Li, Organizers<br />
N. Maitra, Presiding<br />
8:40 193. Nonempirical density functional<br />
for covalent and noncovalent interactions.<br />
A. D. Becke<br />
9:10 194. Nonempirical fully-nonlocal density<br />
functional for correlation.<br />
A. Ruzsinszky,J.P.Perdew,<br />
G. I. Csonka<br />
9:40 195. Development of new exchangecorrelation<br />
functionals. A. J. Cohen,<br />
P. Mori-Sanchez, W. Yang<br />
10:10 196. Importance of cusps in TDDFT.<br />
Z. Yang, N. T. Maitra, K. Burke<br />
10:25 Intermission<br />
10:45 197. Exact exchange plus local- and<br />
nonlocal-density approximations to the<br />
correlation functional. M. Scheffler<br />
11:15 198. Range separated DFt functionals.<br />
K. Hirao<br />
11:45 199. Analytic structure of functional<br />
derivatives of density-functional approximations.<br />
A. P. Gaiduk, V. N. Staroverov<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Force Field Development Sponsored by<br />
COMP, Cosponsored by PHYS<br />
Tautomers and Biology<br />
Tautomers and Macromolecule-ligand<br />
Complexes Sponsored by COMP,<br />
Cosponsored by CINF, MEDI, and PHYS<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 104C<br />
Electrons in Bio-Molecules<br />
Electron Capture, Radicals and Mass<br />
Spectrometry<br />
J. Weber, J. Simons, Organizers<br />
V. Gabelica, Presiding<br />
1:30 200. Energetics and dynamics of dissociation<br />
of peptide radical anions.<br />
J. Laskin,Z.Yang,C.Lam,I.K.Chu<br />
2:00 Discussion<br />
2:10 201. Elucidating the not so odd behavior<br />
of odd electron biological molecules in<br />
the gas phase using electron predators<br />
and the selective generation of reactive<br />
radical centers. J. L. Beauchamp,<br />
C. Sohn<br />
2:40 Discussion<br />
2:50 202. Electron transfer dissociation reactions<br />
of peptide anions with open-shell<br />
cations: Energetic considerations and<br />
charge transfer reactions. N. C. Polfer,<br />
I. Ugalde, M. L. Easterling, J. Wolff<br />
3:05 Discussion<br />
3:10 Intermission<br />
3:30 203. Electron capture induced dissociation<br />
of doubly charged peptide dications:<br />
What governs the outcome?<br />
S. Brøndsted Nielsen<br />
4:00 Discussion<br />
4:10 204. Negative ion stabilization of zwitterionic<br />
states of gas-phase amino acids.<br />
C. Dessent<br />
4:40 Discussion<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, V. Batista, Organizers<br />
N. Damrauer, Presiding<br />
1:30 205. Basic research in solar photoconversion<br />
at basic energy sciences: Programs<br />
and interests. M. T. Spitler<br />
2:10 206. New light harvesters and redox<br />
shuttles for dye-sensitized solar cells.<br />
J. Hupp<br />
2:50 207. Inverse design of molecular chromophores<br />
for dye-sensitized solar cells.<br />
D. Xiao, R. C. Snoeberger III, L. Martini,<br />
R. H. Crabtree, V. S. Batista<br />
3:10 Intermission<br />
3:30 208. World powered predominantly by<br />
solar and wind energy: The role of materials<br />
science. W. Kohn<br />
4:10 209. Visible light into chemical bonds:<br />
Dynamics and yields of I-I bond formation<br />
in fluid solution and at sensitized interfaces.<br />
G. Meyer, S. Ardo, J. Rowley,<br />
B. Farnum<br />
4:50 210. Computational study of naphthalocyanine<br />
chromophores for infrared solar<br />
cells. E. Jakubikova, R. L. Martin<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 105<br />
Challenges for Density Functional Theory<br />
W. Yang, X. Li, Organizers<br />
A. Wasserman, Presiding<br />
1:30 211. Orbital-free density functional theory<br />
for covalent and metallic materials.<br />
E. A. Carter<br />
2:00 212. Conceptual density functional theory:<br />
The linear response function and<br />
third order derivatives. P. Geerlings,<br />
N. Sablon, T. Fievez, F. De Proft<br />
2:30 213. Intermolecular interactions in density-functional<br />
theory. E. R. Johnson<br />
3:00 214. Recent progress in problems traditionally<br />
hard for density functional theory.<br />
R. Baer<br />
3:15 Intermission<br />
3:35 215. Conical intersections and charge<br />
transfer in density functional theory.<br />
T. J. Martinez, I. S. Ufimtsev,<br />
S. Varganov, C. Isborn, N. Luehr<br />
4:05 216. Calculations of excited state properties<br />
of nanostructures using many body<br />
perturbation theory. G. Galli<br />
4:35 217. Resonance Raman scattering of<br />
charge-transfer complexes using longrange<br />
corrected DFT. L. Jensen<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
L. Williams, Presiding<br />
1:30 218. Uptake kinetics of water adsorbing<br />
to aqueous aerosol. J. P. Reid,<br />
R. E. Miles, K. J. Knox, A. M. Laurain,<br />
H. Tong<br />
2:10 Adam Ahern<br />
2:30 219. Widespread halogen activation by<br />
N 2O 5 heterogeneous chemistry.<br />
J. A. Thornton, J. P. Kercher,<br />
T. P. Riedel, N. L. Wagner, J. Cozic,<br />
J. S. Holloway, W. P. Dube, G. M. Wolfe,<br />
P. K. Quinn, A. M. Middlebrook,<br />
B. Alexander, S. S. Brown<br />
3:10 220. Heterogeneous oxidation trajectories:<br />
Understanding the competition between<br />
functionalization and volatilization<br />
reactions in chemically reduced and oxidized<br />
organic aerosols. K. R. Wilson,<br />
J. D. Smith, J. H. Kroll, S. Kessler,<br />
D. R. Worsnop, H. Bluhm, E. R. Mysak<br />
3:30 Intermission<br />
3:50 221. Direct measurement of the heterogeneous<br />
reaction of N 2O 5 on ambient<br />
aerosol particles. T. H. Bertram,<br />
O. S. Ryder, J. A. Thornton, T. P. Riedel,<br />
E. Fitzgerald, K. A. Prather<br />
4:30 222. Direct detection of the nitrooxyperoxy<br />
radicals in the oxidation of<br />
VOCs by NO3. K. Takematsu,<br />
N. Eddingsaas, S. Barklund, M. Okumura<br />
4:50 223. NOx effects on secondary organic<br />
aerosol formation: Aerosol production<br />
from NO 3 � biogenic hydrocarbons and<br />
potential NO 3 heterogeneous loss.<br />
J. L. Fry, J. Katz, K. Sackinger, L. Zha,<br />
R. C. Cohen, A. W. Rollins,<br />
A. Kiendler-Scharr, S. S. Brown<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Biological Assemblies Cosponsored by<br />
ANYL<br />
E. Baker, Organizer<br />
M. Bowers, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 224. Using ion mobility spectrometry -<br />
mass spectrometry to unravel biomolecular<br />
assembly pathways. A. E. Ashcroft<br />
2:15 225. Metal binding of model Cys 2His 2<br />
zinc-finger peptides in the gas phase.<br />
Y. V. Berezovskaya, C. T. Armstrong,<br />
D. N. Woolfson, P. E. Barran<br />
2:35 226. Conformational conversion from<br />
random assembly to �-sheet in amyloid<br />
fibril formation. C. Bleiholder,<br />
N. F. Dupuis, T. Wyttenbach,<br />
M. T. Bowers<br />
3:15 227. Ion mobility mass spectrometry of<br />
macromolecules: Amyloids and cages.<br />
P. Barran<br />
3:55 228. Gas phase structure of concanavalin<br />
A tetramers is spheroidal rather<br />
than tetrahedral. R. Borrajo, M. Zurita,<br />
J. F. de la Mora<br />
4:15 229. Probing conformational changes<br />
by ion mobility. P. Dugourd<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 107A<br />
Physical Chemistry of Spectrochemical<br />
Analysis<br />
K. Lehmann, Organizer<br />
B. Pate, Organizer, Presiding<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
PHYS<br />
TECH–103
PHYS <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
1:30 230. March to early science and beyond.<br />
A. Wootten<br />
2:10 231. Characterizing the chemistry of<br />
the laser ablation source using chirped<br />
pulse Fourier transform microwave spectroscopy.<br />
S. A. Cooke<br />
2:50 232. Using CP-FTMW spectroscopy to<br />
determine the torsional barriers of methyl<br />
groups attached to an aromatic ring.<br />
R. G. Bird, D. W. Pratt, J. L. Neill,<br />
B. H. Pate<br />
3:10 Intermission<br />
3:25 233. <strong>Chemical</strong> analysis in the submillimeter<br />
spectral region. F. C. De Lucia,<br />
I. R. Medvedev, C. F. Neese,<br />
G. M. Plummer<br />
4:05 234. Synchrotron-based far infrared<br />
spectroscopy of four-membered heterocycles.<br />
J. van Wijngaarden<br />
4:45 235. Room-temperature chirped-pulse<br />
Fourier transform microwave spectroscopy:<br />
Rotational spectra of molecules in excited<br />
vibrational states. S. T. Shipman,<br />
B. Reinhold, B. M. Kriegel, I. A. Finneran,<br />
S. L. Lang<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Room 103<br />
Metals in Biology<br />
Bioinorganic Spectroscopy<br />
A. Palmer, Organizer<br />
T. Brunold, Presiding<br />
1:30 Introductory Remarks<br />
1:35 236. Mössbauer, EPR and DFT studies<br />
of a synthetic Fe III -O- Fe IV �O complex:<br />
Superexchange-driven S � 1àS� 2<br />
spin transition at the Fe IV �O site.<br />
E. Munck<br />
2:05 Discussion<br />
2:15 237. Geometric and electronic structure<br />
contributions to Cu/02 reactivity.<br />
E. I. Solomon<br />
2:45 Discussion<br />
2:55 238. Manganese and iron K-beta X-ray<br />
emission spectroscopy as a probe of biological<br />
catalysis. S. DeBeer<br />
3:25 Discussion<br />
3:35 239. Spectroscopic and electronic<br />
structure studies of pyranopterin molybdenum<br />
enzymes. M. Kirk<br />
4:05 Discussion<br />
4:15 240. NMR, a highly sensitive probe of<br />
second-sphere interactions in paramagnetic<br />
cytochromes. K. L. Bren,<br />
S. E. Bowman, M. D. Liptak<br />
4:30 Discussion<br />
4:35 241. Imaging correlated electrons by<br />
ultrafast polarization phase selective radiation<br />
signatures (PPS-RS): Helping enzyme<br />
electrons do what no electron has<br />
done before. K. Rupnik, S. McGill<br />
4:50 Discussion<br />
4:55 242. Mössbauer studies of mono- and<br />
dinuclear model complexes for the hydrogenases.<br />
C. V. Popescu, M. Singleton,<br />
M. Y. Darensbourg, T. Liu, A. Bilko<br />
5:10 Discussion<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Reaction Rate Theory, Vibrational<br />
Relaxation, and Simulation Methods<br />
Sponsored by COMP, Cosponsored by PHYS<br />
WEDNESDAY MORNING<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
F. Keutsch, Presiding<br />
‡ Cooperative Cosponsorship<br />
104–TECH<br />
8:00 243. Correlation of oxidation state with<br />
the hygroscopic growth and cloud condensation<br />
nuclei (CCN) properties of laboratory<br />
generated secondary organic<br />
aerosols (SOA). P. Massoli, A. Lambe,<br />
A. T. Ahern, L. R. Williams, W. H. Brune,<br />
M. Ehn, P. Miettenen, E. S. Cross,<br />
T. B. Onasch, J. T. Jayne, M. Kulmala,<br />
A. Laaksonnen, D. R. Worsnop,<br />
P. Davidovits, C. E. Kolb<br />
8:40 244. Mechanical probing of icelike water<br />
monolayers. D. Xu, K. M. Liechti,<br />
K. Ravi-Chandar<br />
9:00 245. Hygroscopicity and oxidation of<br />
oxygenated organic aerosol. J. Abbatt<br />
9:40 246. Water uptake and chemical transformations<br />
of aerosols studied by single<br />
particle scanning transmission X-ray microscopy.<br />
A. V. Tivanski<br />
10:00 Intermission<br />
10:20 247. Climate effects on new particle<br />
formation from VOCs emitted from boreal<br />
tree species. A. Kiendler-Scharr,<br />
J. Wildt, M. Dal Maso, T. Hohaus,<br />
E. Kleist, T. Mentel, R. Tillmann,<br />
A. Wahner<br />
11:00 248. Characterizing molecular aerosols<br />
through infrared spectroscopy and<br />
vibrational dynamics. T. C. Preston,<br />
G. Firanescu, R. Signorell<br />
11:20 249. Measurements of size-resolved<br />
chemical mixing state: Implications for<br />
climate. K. A. Prather<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 104C<br />
Electrons in Bio-Molecules<br />
Electron Capture, Electron Detachment and<br />
Charge Transfer<br />
J. Weber, J. Simons, Organizers<br />
A. Holm, Presiding<br />
8:20 250. Proper and improper aminoketyl<br />
radicals in electron-based peptide dissociations.<br />
F. Turecek,T.W.Chung<br />
9:00 251. Electron capture by peptides and<br />
metal ions. E. R. Williams, W. A. Donald,<br />
T. G. Flick<br />
9:40 252. Electronically excited and ionized<br />
states of the photoactive yellow protein<br />
chromophore: Insights from electronic<br />
structure calculations. K. B. Bravaya,<br />
D. Zuev, A. I. Krylov<br />
10:00 Intermission<br />
10:20 253. Propagator interpretations of<br />
biomolecular electron binding energies.<br />
J. V. Ortiz<br />
11:00 254. Spectroscopy of dark states by<br />
anion photodetachment photoelectron<br />
spectroscopy. R. Weinkauf, S. Siegert,<br />
F. Vogeler<br />
11:40 255. Electron tunneling in FeS proteins.<br />
A. Stuchebrukhov<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, V. Batista, Organizers<br />
E. Galoppini, Presiding<br />
8:20 256. Quantum dot solar cells for photovoltaics<br />
and fuels. A. J. Nozik,<br />
M. C. Beard, J. M. Luther, A. Midgett,<br />
O. E. Semonin, B. Hughes, D. Smith,<br />
J. Gao, J. C. Johnson<br />
9:00 257. New aspects of photophysics of<br />
semiconductor nanocrystals from the<br />
perspective of solar energy conversion.<br />
V. I. Klimov<br />
9:40 258. Investigation of multiple exciton<br />
generation in nanoparticle thin films: Systematically<br />
tuning ligand electronics.<br />
J. M. Zemke, D. R. Tyler<br />
10:00 Intermission<br />
10:20 259. Multiexciton generation in semiconducting<br />
nanocrystals. E. Rabani<br />
11:00 260. Theoretical studies of ultrafast<br />
dynamics in carbon nanoscale materials<br />
for solar energy harvesting and storage.<br />
O. Prezhdo<br />
11:40 261. Energy transport in Ru(II) and<br />
Os(II) loaded molecular assemblies.<br />
S. Bettis, B. P. Mehl, D. Wilger, C. Kent,<br />
C. Materese, G. Papoian, M. Waters,<br />
W. Lin, T. J. Meyer, J. M. Papanikolas<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 107A<br />
Physical Chemistry of Spectrochemical<br />
Analysis<br />
B. Pate, Organizer<br />
K. Lehmann, Organizer, Presiding<br />
8:25 262. Aircraft measurements of atmospheric<br />
nitrogen oxides by diode laser<br />
cavity ring-down spectroscopy.<br />
S. S. Brown,W.P.Dubé, N. L. Wagner,<br />
H. Fuchs, R. A. Washenfelder<br />
9:05 263. Absorption detection in nanoliter<br />
detection volumes. H. Loock,<br />
H. Waechter, J. Litman, K. Bescherer<br />
9:45 264. Portable multiple laser continuous<br />
flow cavity-ringdown system for methane<br />
isotopologues. Y. Chen, J. Kessler,<br />
K. K. Lebmann, T. C. Onstott<br />
10:05 Intermission<br />
10:20 265. Off-axis cavity ring down spectroscopy<br />
at low temperatures for laboratory<br />
study of planetary atmospheres.<br />
C. E. Manzanares<br />
11:00 266. New singly resonant continuous<br />
wave optical parametric oscillators.<br />
M. Vainio, M. Siltanen, L. Halonen<br />
11:40 267. Improving photostability of fluorescence<br />
dyes for single molecule spectroscopy<br />
by using molecular cavity quantum<br />
electrodynamics. H. Cang,X.Zhang<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Technology Development Cosponsored by<br />
ANYL<br />
M. Bowers, E. Baker, Organizers<br />
J. McLean, Presiding<br />
8:30 Introductory Remarks<br />
8:35 268. Traveling wave ion mobility separation:<br />
Instrumentation and applications.<br />
K. Giles<br />
9:15 269. FAIMS as a filter for biomarker detection.<br />
A. L. Ferzoco<br />
9:35 270. Ion mobility separations in high<br />
throughput proteomics: A novel approach<br />
to protein detection and quantitation.<br />
M. E. Belov, E. S. Baker, Y. M. Ibrahim,<br />
D. C. Prior, W. F. Danielson,<br />
R. T. Kurulugama, S. Prasad, A. R. Shah,<br />
K. L. Crowell, G. A. Anderson, R. D. Smith<br />
10:15 271. How important is the IMS resolution<br />
for the determination of absolute<br />
cross sections? G. Baykut,M.A.Park<br />
10:55 272. Internal energy content of ions in<br />
a travelling wave ion guide. D. Morsa,<br />
V. Gabelica, F. Rosu, F. Remacle,<br />
E. A. De Pauw<br />
11:15 273. High-resolution ion mobility measurements.<br />
S. J. Valentine, R. S. Glaskin,<br />
S. I. Merenbloom, S. Lee,<br />
F. M. Nachtigall, R. T. Kurulugama,<br />
D. E. Clemmer<br />
Section H<br />
Boston Convention & Exhibition Center<br />
Room 103<br />
Metals in Biology<br />
Nanoparticle and Surface Chemistry for<br />
Biological and Biomedical Applications<br />
A. Palmer, Organizer, Presiding<br />
8:35 Introductory Remarks<br />
8:40 274. Ag nanodot fluorophores enabling<br />
synchronously amplified fluorescence image<br />
recovery (SAFIRe). R. Dickson<br />
9:10 Discussion<br />
9:20 275. Nanoparticle-based probes for<br />
biosensing and in vivo imaging applications.<br />
J. Rao<br />
9:50 Discussion<br />
10:00 276. Imaging and influencing cells<br />
with metal nanoparticles. C. J. Murphy<br />
10:30 Discussion<br />
10:40 277. Metal cation interactions with<br />
DNA-functionalized surfaces studied by<br />
the Eisenthal chi(3) method. F. M. Geiger<br />
11:10 Discussion<br />
11:20 278. Electron tunneling through<br />
M121X mutant azurins on mixed SAM<br />
gold electrodes: Axial ligand effects on<br />
the ET rates of blue copper proteins.<br />
K. Yokoyama, N. Nakamura, H. Ohno,<br />
J. R. Winkler, J. H. Richards, H. B. Gray<br />
11:35 Discussion<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 105<br />
Challenges for Density Functional Theory<br />
W. Yang, X. Li, Organizers<br />
R. Baer, Presiding<br />
8:40 279. Static correlation via constrainedpairing<br />
mean-field theory. G. E. Scuseria<br />
9:10 280. Functional derivatives and differentiability<br />
in density-functional theory.<br />
P. Xiang, Y. A. Wang<br />
9:40 281. TDPM3 for large systems.<br />
D. Neuhauser<br />
10:10 282. Withdrawn<br />
10:25 Intermission<br />
10:45 283. From open-system TDDFT to<br />
first-principles decoherence. X. Li,<br />
W. Liang, C. Isborn, C. Chapman<br />
11:15 284. Theory of excitation broadening<br />
using time-dependent density functional<br />
theory for open quantum systems.<br />
A. Aspuru-Guzik<br />
11:45 285. Time dependent density functional<br />
theory for nonadiabatic electronic<br />
dynamics. V. Krishna<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Applications to Nanoscale and<br />
Biomolecular Systems Sponsored by COMP,<br />
Cosponsored by PHYS<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 104C<br />
Electrons in Bio-Molecules<br />
Electron Capture, Radicals and Mass<br />
Spectrometry<br />
J. Weber, J. Simons, Organizers<br />
N. Polfer, Presiding<br />
1:30 286. Electron capture induced dissociation<br />
of peptides: Does the recombination<br />
energy of the charged groups play a<br />
role in determining the charge partitioning<br />
between c and z ions? A. I. Holm<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
2:10 287. Mechanism of ECD from a radical<br />
chemistry perspective. R. Julian,<br />
B. Moore, T. Ly<br />
2:50 288. Theoretical exploration of C—C<br />
bond fragmentation in model lignin cation<br />
radicals. R. Parthasarathi,D.W.Cho,<br />
A. S. Pimentel, D. Dunaway-Mariano,<br />
P. S. Mariano, P. Langan, S. Gnanakaran<br />
3:10 Intermission<br />
3:30 289. Electron interactions with multiply<br />
protonated betaine clusters.<br />
L. Feketeova, J. Yoo, G. N. Khairallah,<br />
R. A. O’Hair<br />
4:10 290. Uses of electron capture dissociation<br />
in biomolecules. P. B. O’Connor<br />
4:50 Concluding Remarks<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, V. Batista, Organizers<br />
O. Prezhdo, Presiding<br />
1:30 291. Black silicon: Engineering an intermediate<br />
band in silicon for photovoltaic<br />
applications. E. Mazur<br />
2:10 292. Photovoltages and photoinduced<br />
electronic charge separation from a combined<br />
density matrix-ab initio treatment:<br />
Applications to metal clusters adsorbed<br />
on Si slabs, without and with dopants.<br />
D. A. Micha, D. S. Kilin, A. S. Leathers,<br />
J. J. Ramirez<br />
2:50 293. First-principles screening and design<br />
of organic photovoltaic materials on<br />
the World Community Grid.<br />
J. Hachmann, R. Olivares-Amaya,<br />
L. Vogt, S. Atahan, R. S. Sanchez-Carrera,<br />
A. Gold-Parker, E. Lin, A. Aspuru-Guzik<br />
3:10 Intermission<br />
3:30 294. Polarized semiconductor solid oxides<br />
based on ferroelectrics: New materials<br />
for photovoltaic devices. A. M. Rappe<br />
4:10 295. Synthesis, structure, and electronic<br />
properties of compositionally complex<br />
n-doped titanates: Toward the photooxidation<br />
of water. B. M. Bartlett,<br />
T. M. Breault, J. E. Yourey<br />
4:50 296. Single nanowires as molecularscale,<br />
high-efficiency photovoltaic elements.<br />
J. F. Cahoon,T.J.Kempa,<br />
R. Day, C. M. Lieber<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 105<br />
Challenges for Density Functional Theory<br />
X. Li, Organizer<br />
W. Yang, Organizer, Presiding<br />
1:30 297. Challenge of strong correlations:<br />
Prospects of density functionals vs. density-matrix<br />
functionals. E. Gross<br />
2:00 298. Multicomponent density functional<br />
theory: Development of electronproton<br />
functionals. S. Hammes-Schiffer<br />
2:25 299. Weakly interacting subsystems in<br />
DFT. T. Van Voorhis, O. Vydrov<br />
2:55 300. GGA functional satisfying the<br />
large-s constraint. A. Vela,<br />
J. Martin del Campo, J. Gazquez,<br />
S. B. Trickey, J. Pacheco-Kato<br />
3:10 Intermission<br />
3:30 301. Numerical integration along the<br />
adiabatic connection in DFT. A. Savin<br />
4:00 302. Solving the Schrödinger and Dirac-Coulomb<br />
equations. H. Nakatsuji<br />
4:30 Concluding Remarks<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
J. Abbatt, Presiding<br />
1:30 303. Glyoxal perspective on air quality<br />
and climate science. R. Volkamer<br />
2:10 304. Aerosol formation by cloud processing<br />
of methylglyoxal and amines: Kinetics<br />
and products. D. O. De Haan,<br />
H. Takano, V. A. Blasic<br />
2:30 305. Fate of glyoxal in aerosol: Laboratory,<br />
chamber, and ambient studies.<br />
M. M. Galloway, P. S. Chhabra,<br />
A. W. Chan, J. D. Surratt, G. Yu,<br />
R. C. Flagan, J. S. Seinfeld,<br />
F. N. Keutsch<br />
3:10 306. Hydration of methylglyoxal in gasphase:<br />
Optical extinction measurements.<br />
J. L. Axson<br />
3:30 Intermission<br />
3:50 307. Organic aerosol formation and<br />
processing in the atmospheric aqueous<br />
phase: A model perspective. B. Ervens<br />
4:30 308. Monitoring particle phase transitions<br />
with a humidified quartz crystal microbalance.<br />
S. R. Schill,P.K.Hudson<br />
4:50 309. Linking atmospheric aerosol<br />
chemistry and climate properties.<br />
V. McNeill, N. Sareen, A. N. Schwier,<br />
D. Mitroo, E. L. Shapiro<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Structural Analysis & Filtration Cosponsored<br />
by ANYL<br />
M. Bowers, E. Baker, Organizers<br />
P. Barran, Presiding<br />
1:30 Introductory Remarks<br />
1:35 310. Ion mobility-mass spectrometry<br />
as a structural probe of intrinsically disordered<br />
peptides/proteins (IDP).<br />
D. H. Russell<br />
2:15 311. Using differential ion mobility as a<br />
conformational filter for cold ion spectroscopy.<br />
Y. Papadopoulos, A. Svendsen,<br />
O. V. Boyarkin, T. R. Rizzo<br />
2:35 312. Dissociation of gas ions in air before<br />
mass spectrometers using electric<br />
fields from field dependent mobility spectrometers.<br />
G. A. Eiceman<br />
3:15 313. Ion mobility for probing reactions,<br />
energetics and structures of complex organics<br />
formed by intracluster reactions.<br />
M. S. El-Shall<br />
3:55 314. Structural examination of multiply<br />
charged negative oligonucleotides.<br />
M. Vonderach<br />
4:15 315. Molecular classification using projected<br />
ion densities (m/�). H. H. Hill<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 107A<br />
Physical Chemistry of Spectrochemical<br />
Analysis<br />
B. Pate, K. Lehmann, Organizers<br />
E. Riedle, Presiding<br />
1:30 316. New ultrafast science opportunities<br />
at LCLS. P. Bucksbaum<br />
2:10 317. High harmonic generation and<br />
strong field ionization probes of molecular<br />
dynamics. W. Li<br />
2:50 318. New approaches to analysis of<br />
resonant Raman spectra. D. Rappoport,<br />
S. Shim, A. Aspuru-Guzik<br />
3:10 Intermission<br />
3:25 319. Spectroscopic applications based<br />
on shaped ultrashort laser pulses.<br />
M. Dantus<br />
4:05 320. On the dependence of the electronic<br />
properties of ferric (hydr)oxides on<br />
nanoparticle size: Relation to aquatic<br />
chemistry. I. Chernyshova,<br />
S. Ponnurangam, P. Somasundaran<br />
4:25 321. Optical chirality and its interaction<br />
with matter. Y. Tang,A.E.Cohen<br />
4:45 322. Using ligand-detected NMR to<br />
probe the aggregation of amylin.<br />
K. J. Robbins, G. Lin, N. D. Lazo<br />
Frontiers of Condensed Phase Theory and<br />
Simulation: A Tribute to Bruce J. Berne<br />
Applications to Nanoscale and<br />
Biomolecular Systems Sponsored by COMP,<br />
Cosponsored by PHYS<br />
WEDNESDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Challenges for Density Functional Theory<br />
M. Johnson, W. Yang, X. Li, Organizers<br />
6:00–9:00<br />
323. Triplet excitation energy transfer with<br />
constrained density functional theory.<br />
S. Yeganeh, T. Van Voorhis<br />
324. Transferability of fragments in partition<br />
density functional theory. Y. Zhang,<br />
A. Wasserman<br />
325. Physical and chemical content of the<br />
exchange dimensionless gradient.<br />
J. M. del Campo, A. Vela, J. L. Gázquez<br />
326. Adiabatic connection for strictly correlated<br />
electrons. Z. Liu, K. Burke<br />
327. Azobenzene switching on gold surfaces:<br />
Challenges and insights from theory.<br />
C. Chapman, I. Paci<br />
328. Leading corrections to local density approximations.<br />
A. Cangi, D. Lee, P. Elliott,<br />
K. Burke<br />
329. Density functional resonance theory.<br />
D. L. Whitenack, A. Wasserman<br />
330. Local approximations beyond Born-Oppenheimer.<br />
L. Wagner,K.Burke<br />
331. Ab initio modeling of complex interfaces:<br />
Applications in iron corrosion and<br />
metal sintering. Y. Cai, M. Neurock<br />
332. Semiclassics in density functional theory.<br />
D. Lee, A. Cangi, P. Elliott, K. Burke<br />
333. Using hydrogenic orbitals to improve<br />
DFT. J. C. Snyder, J. Ovadia, D. Lee,<br />
K. Ray, K. Burke<br />
334. Reactions between hyperthermal O( 3 P)<br />
and CO 2: Dynamics calculated using<br />
forces from density functional theory may<br />
be as good as it gets. J. T. Paci,<br />
L. Y. Yeung, M. Okumura, J. Zhang,<br />
T. K. Minton, J. M. Martin, J. P. Camden,<br />
G. C. Schatz<br />
335. Describing the electronic and optical<br />
properties of silver clusters using longrange<br />
corrected functionals.<br />
D. W. Silverstein, L. Jensen<br />
336. Thermal effects on reorientation of hydroxide<br />
ions in water: An ab initio molecular<br />
dynamics study. Z. Ma,<br />
M. Tuckerman<br />
337. DFT study of oxidative dehydrogenation<br />
of propane over a VO 2-exchanged<br />
MCM-22 and ZSM-5 zeolites.<br />
S. Wannakao,T.Maihom,<br />
W. Sangthong, B. Boekfa,<br />
P. Khongpracha, J. Limtrakul<br />
338. Withdrawn<br />
339. Ab initio search for global minimum<br />
structures of novel B xH y (x�3-4, y�4�7)<br />
neutral and anionic clusters and theoretical<br />
photoelectron spectroscopic study of<br />
anionic BxHy clusters. J. K. Olson,<br />
A. I. Boldyrev<br />
340. Combustion of asphaltenes. J. Cook,<br />
C. Parish<br />
341. Developing DFT concepts for characterizing<br />
intermolecular interactions in organic<br />
crystals. T. Li, P. W. Ayers, S. Liu<br />
342. Potential energy surfaces and mechanisms<br />
for reactions of CH 3C(O)O 2 with<br />
HO 2 from density functional methods.<br />
J. W. Beattie, J. E. Stevens<br />
343. MP2 melting temperature of water approximated<br />
by pair-wise potentials developed<br />
following the adaptive force matching<br />
method. E. R. Pinnick, S. Erramilli,<br />
F. Wang<br />
344. Theoretical study on reaction of epoxides<br />
and CO 2 to cyclic carbonates.<br />
J. Guo<br />
345. Ionization energies of small silicon clusters:<br />
Vacuum ultraviolet photoionization<br />
experiment and theoretical calculations.<br />
O. Kostko,S.R.Leone,M.A.Duncan,<br />
M. Ahmed<br />
346. Initial steps in methanol steam reforming<br />
on PdZn surfaces. G. K. Smith,<br />
S. Lin, W. Lai, A. Datye, D. Xie, H. Guo<br />
347. Extending the applicability of B3LYP.<br />
I. Zhang, J. Wu, X. Xu<br />
348. Density-functional molecular dynamics<br />
study on interfacial water on TiO 2 anatase<br />
(101) and (001) surfaces. Y. Tateyama,<br />
M. Sumita<br />
349. Potential energy surface and kinetics of<br />
ClO � ClO recombination reaction revisited.<br />
T. Dhilip Kumar, M. Azzurri,<br />
J. R. Barker<br />
350. Efficient reaction force field: From proton<br />
transport to simple organic reactions.<br />
S. Kale, J. Herzfeld<br />
351. Reaction rate constants and mechanistic<br />
detail of the Ni � � Butanone reaction.<br />
I. E. Laboren, O. J. Villarroel, S. J. Dee,<br />
V. A. Castleberry, K. K. Klausmeyer,<br />
D. J. Bellert<br />
352. Binding affinities of crown-type macrocycles<br />
with protonated primary amines.<br />
D. M. Benoist, E. McCullough,<br />
C. Huffman<br />
353. Model palladacycles: A study to revisit<br />
the Endo and Exo-isomers to make a<br />
comparison based on competitive density<br />
functional theories (BLYP and<br />
B3LYP). S. S. Mustakim<br />
354. Ab initio study of target imines and oxazolines<br />
to understand the contributing<br />
factors to the molecular parameters.<br />
S. Mustakim<br />
355. Extended Levy-Nagy and Gorling functionals<br />
for resonance states. Y. Zhang<br />
356. Accuracy of density functional theory<br />
(DFT) in reproducing the enantioselectivity<br />
of reactions involving nitroalkenes.<br />
C. Wong,J.Ran<br />
357. Novel density functional theory studies<br />
on the interaction between electron donating/withdrawing<br />
molecules and graphene<br />
layer. Y. N. Moe, Y. Wang<br />
358. Semi-empirical density functionalbased<br />
thermochemical method for the efficient<br />
approximation of enthalpies of formation.<br />
M. N. Sandberg, D. J. Sandberg,<br />
J. M. Crowley, J. F. Koscielecki,<br />
L. S. Ramos, R. R. Birge<br />
359. Examples of partition density functional<br />
theory in one dimension. R. Tang,<br />
A. Wasserman<br />
360. Computational study of the reactions of<br />
methanol with the hydroperoxyl and<br />
methyl radicals. I. M. Alecu,D.G.Truhlar<br />
361. Correcting systematic errors for spincrossover<br />
phenomena in transition metal<br />
complexes using hybrid DFT.<br />
T. F. Hughes, R. A. Friesner<br />
362. Iron porphyrins with different imidazole<br />
ligands: A comparative study with density-functional<br />
theory. M. Liao, M. Huang,<br />
J. D. Watts<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
PHYS<br />
TECH–105
PHYS <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Boston Convention & Exhibition Center<br />
Hall C<br />
<strong>Chemical</strong> Computations on General<br />
Purpose Graphics Processing Units<br />
(GP-GPUs)<br />
J. D. Madura, M. Johnson, V. Kindratenko,<br />
Organizers<br />
6:00–9:00<br />
363. Toward unforced molecular dynamics<br />
simulations of protein binding. J. Kaus,<br />
M. Zwier, X. Qi, L. Chong<br />
364. Incorporating automatic differentiation<br />
into internal coordinates for potential energy<br />
surface exploration.<br />
J. L. Sonnenberg, H. P. Hratchian,<br />
M. J. Frisch<br />
365. Accelerating correlated quantum chemistry<br />
calculations using graphical processing<br />
units. M. A. Watson,<br />
R. Olivares-Amaya, R. G. Edgar, L. Vogt,<br />
A. Aspuru-Guzik<br />
366. Theoretical investigations of EMIM-Tf 2N<br />
small cluster stability and dynamics.<br />
B. D. Prince, Y. Chiu, J. A. Boatz,<br />
E. J. Maginn<br />
367. Binding energy calculations of 4d and<br />
5d transition metal complexes.<br />
B. B. Averkiev, Y. Zhao, D. G. Truhlar<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Electrons in Bio-Molecules<br />
M. Johnson, J. Weber, J. Simons,<br />
Organizers<br />
6:00–9:00<br />
368. Cooperative effect in the electronic<br />
properties of human telomere sequence.<br />
T. Z. Markus, S. S. Daube, R. Naaman<br />
369. Electronic excitations in solution: Firstprinciples<br />
based QM/MM study.<br />
D. Kosenkov, L. V. Slipchenko<br />
370. Computational approach to study lignocellulosic<br />
biomass conversion to fuels.<br />
Y. A. Kholod, M. H. Lamm, T. L. Windus,<br />
M. S. Gordon<br />
371. Excited state dynamics of solutionphase<br />
photosynthetic antenna proteins<br />
studied one at a time. R. H. Goldsmith,<br />
W. Moerner<br />
372. Electronic excitation cross sections for<br />
low-energy electron (� 18 eV) scattering<br />
from cytosine: Applications in nanodosimetry.<br />
L. Sanche, M. Bazin,<br />
M. Michaud<br />
373. Low-energy-electron interaction with<br />
self-assembled monolayers of DNA containing<br />
O 2 at cryogenic temperatures.<br />
L. Sanche, N. Mirsaleh-Kohan, A. Bass,<br />
P. Cloutier<br />
374. Water makes Heme-Heme protein interface<br />
less repulsive. S. Keinan,<br />
R. Venkatramani, J. M. Nocek,<br />
D. N. Beratan, B. M. Hoffman<br />
375. Calculating redox free energies in solution<br />
and protein with ab initio QM/MM<br />
minimum free energy path method.<br />
X. Zeng, H. Hu, X. Hu, W. Yang<br />
376. 5-Fluorosalicylic acid in its electronically<br />
excited S 1 state. J. W. Young,<br />
A. J. Fleisher, D. W. Pratt<br />
377. Kinetics of electron transfer in<br />
Re(H126)(W122) Pseudomonas aeruginosa<br />
azurin. H. R. Williamson,<br />
L. Sokolova, J. Sykora, J. R. Winkler,<br />
A. Vlcek, H. B. Gray<br />
378. Theoretical study of coherent energy<br />
transfer in photosynthetic systems.<br />
P. Huo,D.F.Coker<br />
379. Comparing theoretical and experimental<br />
evidence to describe systems like<br />
8-oxo-2�-deoxyguanosine (OdG) and<br />
similarly-damaged DNA nucleosides.<br />
A. J. Parker, T. W. Steele, M. Hamm,<br />
C. A. Parish<br />
380. Charge transfer processes in longrange<br />
DNA sequences. E. Sim,H.Kim,<br />
J. Lee<br />
‡ Cooperative Cosponsorship<br />
106–TECH<br />
381. Dynamics of electronic dephasing in the<br />
Fenna-Matthews-Olson complex.<br />
D. Hayes, G. Panitchayangkoon,<br />
K. A. Fransted, J. R. Caram, K. F. Freed,<br />
G. S. Engel<br />
382. Excited state behavior of stacked<br />
nucleobase dimer systems containing<br />
2-aminopurine. J. Liang, S. Matsika<br />
383. Investigation of excited state proton<br />
transfer in green fluorescent protein.<br />
A. McClelland, A. Demidov,<br />
A. Benabbas, Y. Sun, K. Venugopal,<br />
T. Sage, J. van Thor, P. Champion<br />
384. Imaging protein folding dynamics in living<br />
cells. A. Dhar, S. Ebbinghaus,<br />
M. Gruebele<br />
385. Comparison of infrared multiple-photon<br />
dissociation spectra of protonated diglyme<br />
generated using a CO 2 laser and a<br />
free electron laser. M. U. Ehsan,<br />
W. L. Pearson, J. R. Eyler<br />
386. Investigation of membrane-penetrating<br />
peptides: Insights from atomistic and<br />
coarse-grained models. Z. Wu,Q.Cui,<br />
A. Yethiraj<br />
387. Evidence for concerted electron proton<br />
transfer in charge recombination between<br />
FADH – and 306 Trp� in DNA photolyase.<br />
A. A. Zieba, C. Richardson, S. D. Dieng,<br />
Y. M. Gindt, J. M. Schelvis<br />
388. Recent developments in the multiscale<br />
coarse-graining (MS-CG) method: Towards<br />
systematic and accurate CG modelling<br />
of complex systems. A. Das,<br />
H. C. Andersen<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Metals in Biology<br />
A. Palmer, M. Johnson, Organizers<br />
6:00–9:00<br />
389. Withdrawn<br />
390. On the nature of interaction of magnesium<br />
ions with the ribosome. U. Mohanty<br />
391. Electrostatic docking of a supramolecular<br />
host-guest assembly to cytochrome c<br />
probed by bidirectional photoinduced<br />
electron transfer. K. I. Jankowska,<br />
C. V. Pagba, E. L. Piatnitski Chekler,<br />
K. Deshayes, P. Piotrowiak<br />
392. Topological analysis of the active site of<br />
human DNA polymerase � provides insight<br />
on metal ion mutagenicity in DNA<br />
synthesis. R. Chaudret, J. Piquemal,<br />
G. A. Cisneros<br />
393. Computational design of carbonic anhydrase<br />
mimics for carbon dioxide capture.<br />
H. J. Kulik, S. E. Wong, E. Y. Lau,<br />
C. Valdez, S. Baker, J. H. Satcher,<br />
R. D. Aines, F. C. Lightstone<br />
394. Effect of magnesium ion concentration<br />
on the catalytic activity of ribonuclease H:<br />
Does a third metal bound at the active<br />
site modulate endonuclease catalysis?<br />
M. Ho, M. De Vivo, M. Dal Peraro,<br />
M. L. Klein<br />
395. Investigation of multiheme cytochromes<br />
in Shewanella oneidensis MR-1: Developing<br />
a model pathway for electron transfer.<br />
M. A. Firer Sherwood, N. Ando,<br />
C. L. Drennan, S. J. Elliott<br />
396. Investigating electron transfer through<br />
bacterial diheme proteins: Cytochrome c<br />
peroxidases and MauG. K. Ellis,<br />
G. Pulcu, H. Hsu, G. Levine, V. Davidson,<br />
S. Elliott<br />
397. Temperature induced protein motions<br />
indicate link to function. J. Borreguero,<br />
J. He, C. Brown, D. Myles, K. Herwig,<br />
P. Agarwal<br />
398. Methionine ligand lability in monhome<br />
cytochromes c: An electrochemical<br />
study. B. D. Levin, K. Bren, S. J. Elliott<br />
399. Redox reactivity and drug binding in mitoNEET.<br />
D. W. Bak, J. A. Zuris,<br />
M. L. Paddock, P. A. Jennings,<br />
S. J. Elliott<br />
400. Electronic changes in cytochromes c<br />
with functional consequences.<br />
M. D. Liptak,K.L.Bren<br />
401. Metal-cation enhanced deprotonation<br />
of water by photobases. D. Pines,<br />
N. Papiashvily, E. T. Nibbering, E. Pines<br />
402. Thermodynamic studies of carbon dioxide<br />
and carbonic anhydrase with quasichemical<br />
theory. D. Jiao,S.Rempe<br />
403. Copper coordination modes in the<br />
91-96 and 106-113 fragments of the human<br />
prion protein: The second and third<br />
sites. R. Grande-Aztatzi,<br />
L. Rivillas-Acevedo, L. Quintanar, A. Vela<br />
404. Mechanism of C-F reductive elimination<br />
from palladium(IV) fluorides.<br />
E. Tkatchouk, F. Takeru, D. Benitez,<br />
A. E. Strom, P. Tang, T. Ritter,<br />
W. A. Goddard<br />
405. Acidity of complexes of acetylene and<br />
row four transition metals from electronic<br />
structure calculations. J. W. Beattie,<br />
J. E. Stevens<br />
406. Synthesis and characterization of donor-porphyrin-acceptor<br />
triads.<br />
J. Rochford, D. Polyansky<br />
407. Ultrafast energy delocalization in porphyrin<br />
macrocycles: Elucidating a ninetyfold<br />
two photon cross section enhancement.<br />
J. E. Raymond, T. Goodson<br />
408. Circular dichroism study of the cationinduced<br />
conformational differences in<br />
guanosine 5�-monophosphate. M. Panda,<br />
J. A. Walmsley<br />
409. Evolution of intensive plasmon resonances<br />
by the geometric control of colloidal<br />
copper nanoprisms in nonionic microemulsions.<br />
Y. Park,H.Chae<br />
410. Active-site dynamics of the SpvC virulence<br />
factor from Salmonella typhimurium<br />
and density functional model for the catalytic<br />
mechanism of the phosphthreonine<br />
lyase. G. K. Smith, Z. Ke, A. C. Hengge,<br />
D. Xu, D. Xie, H. Guo<br />
411. Hybrid rotational isomer state diffusion<br />
operator method for efficient calculation<br />
of high field electron spin resonance<br />
spectra from molecular dynamics. P. Yin,<br />
M. Ondrechen, D. E. Budil, P. G. Fajer<br />
412. Ultrafast dynamics of ligand substitution<br />
of iron pentacarbonyl in ethanol.<br />
B. Ahr, M. Chollet, B. Adams,<br />
C. Rose-Petruck<br />
413. Colloidal supported metal nanoparticles<br />
(CSMNs) as novel intermediate nanocatalysts<br />
for liquid phase Suzuki cross-coupling<br />
reactions. K. Gude, R. Narayanan<br />
414. Bimolecular encounters: Acid-base<br />
and/or electron transfer in ruthenium (II)<br />
complexes, experiment and theory.<br />
M. Kowalczyk, J. C. Colis, A. Perri,<br />
C. Yun, S. Jang, H. D. Gafney<br />
415. Molecular simulation of the nucleation<br />
and growth of Pd-Ni nanoparticles.<br />
K. D. Watson, S. E. Tatsinkou,<br />
C. Desgranges, J. Delhommelle<br />
416. Modeling orientations of a nitroxide spin<br />
label in 3D space. J. M. McCracken,<br />
D. J. Hirsh<br />
417. Novel ligand-exchange technique for<br />
rapid functionalization of monolayer-protected<br />
gold nanoparticles. Z. Reed,<br />
R. Wallace, S. Cutler, M. Stobiecka,<br />
M. Hepel<br />
418. Gold nanoparticles as drug delivery<br />
vectors. T. Doane, Y. Cheng,<br />
M. E. Kenney, C. Burda<br />
419. Limited proteolysis and circular dichroism<br />
studies of the aggregation of the<br />
amyloid-� protein. K. MacDowell,<br />
N. D. Lazo<br />
420. Zn(II)-OH 2 interactions in metalloenzymes:<br />
Where are the protons?<br />
D. P. Linder<br />
421. Quantum mechanical modeling of a Tripodal<br />
[2]rotaxane. C. Lee, G. Maeng,<br />
H. Kim, K. Sohlberg<br />
422. Recent developments and uses of theoretical<br />
spectrosocopy in bioinorganic<br />
chemistry. F. Neese<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, M. Johnson, V.<br />
Batista, Organizers<br />
6:00–9:00<br />
423. Solar energy conversion with atomic<br />
layer deposition grown WO 3.<br />
S. W. Sheehan,Y.Lin,X.Liu,D.Wang<br />
424. Artificial photosynthetic antennas from<br />
the self-assembly of peptide-porphyrin<br />
complexes. L. Hagens, M. Reca,<br />
M. Warner, D. Kuciauskas, G. A. Caputo<br />
425. Surface chemistry with photo-sensitive<br />
stepped metal–insulator–semiconductor<br />
heterosystems. K. Stella, D. A. Kovacs,<br />
W. Brezna, J. Smoliner, D. Diesing<br />
426. General method for the direct exfoliation<br />
of inorganic layered structures into<br />
atomically-ordered single nanosheets.<br />
P. F. Fulvio, X. Wang, S. M. Mahurin,<br />
G. A. Baker, G. M. Veith, R. R. Unocic,<br />
S. Dai<br />
427. Coherence energy transfer in a photosynthetic<br />
complex.<br />
G. Panitchayangkoon, D. Hayes,<br />
K. A. Fransted, J. R. Caram, E. Harel,<br />
J. Wen, R. E. Blankenship, G. S. Engel<br />
428. P3HT/PCBM composite organic nanoparticles<br />
for solar cell applications: Structure-function<br />
relationships. M. Mathew,<br />
Z. Hu, A. J. Gesquiere<br />
429. Photocatalytic and spectroscopic studies<br />
of an environmentally relevant surface.<br />
F. M. Dukes, N. Asong, M. Shultz<br />
430. Investigation of electrochemical mechanism<br />
of water splitting on titanium oxide<br />
clusters. L. B. Pandey,C.M.Aikens<br />
431. Miscibility of PCBM in P3HT at the molecular<br />
level in polymer solar cells.<br />
B. A. Collins, J. Seok, H. Yan,<br />
C. McNeill, D. Kilcoyne, H. Ade<br />
432. Enhancement of photocurrent in dye<br />
sensitized solar cells incorporating cyclometalated<br />
ruthenium complexes with CuI<br />
as an electrolyte additive: Electrochemical<br />
analysis under dark conditions.<br />
T. Ghaddar<br />
433. New paradigms for semiconductor assemblies<br />
for photovoltaic cells.<br />
D. Venkataraman, B. Venkatraman,<br />
K. Reeves<br />
434. Ultrafast transient absorption and surface<br />
enhanced Raman of photosynthetic<br />
reaction centers linked to silver nanoparticles.<br />
S. J. Murphy, C. Postnikoff,<br />
P. V. Kamat, L. Huang<br />
435. Design and properties of iron based<br />
photosensitizers for dye-sensitized solar<br />
cells. F. A. Jove, Y. Chou, B. B. Wayland,<br />
H. Dai<br />
436. Large, stable graphene quantum dots<br />
with tunable size and energy levels. B. Li,<br />
X. Yan, X. Cui, L. Li<br />
437. Influence of pore loading and pore<br />
shape on the properties of ionic liquids<br />
confined inside nanoporous carbons.<br />
J. D. Monk,F.R.Hung<br />
438. Electrochemical preparation of p-type<br />
ternary metal oxides for solar energy conversion.<br />
C. G. Read,K.Choi<br />
439. 2D Fourier transform spectroscopy of<br />
light harvesting complex II.<br />
S. M. Wichner, P. D. Long, G. S. Engel<br />
440. Light harvesting mechanisms: Excitonphonon<br />
coupling in thiophene macrocycles<br />
at low temperature. D. Flynn,<br />
T. Goodson<br />
441. Energy relaxation dynamics of self-assembled<br />
porphyrin macrocycles.<br />
J. E. Donehue, T. Goodson, Z. S. Yoon<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
442. Electronic energy relaxation in graphenes.<br />
M. L. Mueller,X.Yan,<br />
J. McGuire, L. Li<br />
443. Theoretical analysis of the IR spectrum<br />
of molecular hydrogen adsorbed in<br />
MOF-5. A. J. Green, A. C. Stern,<br />
J. L. Belof, B. Space<br />
444. Photoacoustic effect and sonoluminescence<br />
generated by laser initiated exothermic<br />
chemical reactions in carbon<br />
suspensions. H. Park, G. Diebold<br />
445. Construction of flatly adsorbed porphyrin<br />
self-assembled monolayers on gold<br />
single crystal surfaces. T. Kondo<br />
446. Commercially viable porphyrinoid dyes<br />
for solar cells. C. M. Drain<br />
447. Exciton transport as a quantum engine.<br />
C. A. Rodriguez-Rosario, P. Rebentrost,<br />
A. Aspuru-Guzik<br />
448. High-efficiency exciton dissociation at<br />
poly(3-hexylthiophene)/single-walled carbon<br />
nanotube interfaces in planar nanoheterojunction<br />
photovoltaics. M. Ham,<br />
G. L. Paulus, C. Lee, C. Song,<br />
K. Kalantar-zadeh, W. Choi, J. Han,<br />
M. S. Strano<br />
449. Exciton migration study of CdSe nanorods<br />
by fluorescence correlation spectroscopy.<br />
S. Roy, D. A. Higgins,<br />
V. Chikan<br />
450. Excited states dynamics in organic high<br />
dielectric materials. M. Guo,T.Goodson<br />
451. Gas phase reactions of Ta and Nb<br />
mono and dications with CO. E. Hull,<br />
T. Windus<br />
452. Time-resolved measurements of charge<br />
injection in organic dye sensitized colloidal<br />
ZnO dispersions. A. S. Huss,<br />
A. Bierbaum, J. E. Saunders,<br />
J. Bohnsack, R. Chitta, K. R. Mann,<br />
W. L. Gladfelter, D. A. Blank<br />
453. Bioinspired electrets for solar energy<br />
conversion. S. Upadhyayula,<br />
R. Bonderer, K. Ashraf, D. Bao, B. Millare,<br />
A. Ferreira, R. Lake, V. Vullev<br />
454. Nanoparticle-based dyads for solar to<br />
electric energy conversion. M. Wu,<br />
L. Wang, P. Mukherjee, D. H. Waldeck<br />
455. Structures and reaction pathways of<br />
methylation of 2-methylnaphthalene with<br />
methanol over H-BEA zeolite.<br />
K. Bobuatong, B. Boekfa, S. Wannakao,<br />
J. Limtrakul<br />
456. Exploring trap-mediated excitation dynamics<br />
in colloidal nanocrystals.<br />
M. Jones, S. S. Lo, G. D. Scholes<br />
457. Quantum chemical calculation of the<br />
hydrogenation reaction of encapsulated<br />
formaldehyde in Na-FAU zeolite.<br />
W. Sangthong, S. Wannakao,<br />
S. Choomwattana, T. Maihom, B. Boekfa,<br />
J. Limtrakul<br />
458. New linear thienothiophene derivative<br />
for organic field effect transistor applications.<br />
S. Atahan-Evrenk,<br />
R. S. Sanchez-Carrera, R. Mondal,<br />
J. Schrier, Z. Bao, A. Aspuru-Guzik<br />
459. <strong>Chemical</strong> erosion of diamond thin-films<br />
by hyperthermal atomic oxygen: Sometimes<br />
the assailant is the protector.<br />
J. T. Paci, Z. Shpilman, I. Gouzman,<br />
E. Grossman, L. Shen, T. K. Minton,<br />
G. C. Schatz, R. Akhvlediani, A. Hoffman<br />
460. Catalytic dehydrogenation of ethylbenzene<br />
to styrene over Fe-ZSM-5 zeolite: A<br />
newly developed density functional theory<br />
(M06-L) in ONIOM scheme.<br />
B. Boekfa, T. Maihom, S. Wannakao,<br />
P. Limtrakul, J. Limtrakul<br />
461. Single molecules of MEH-PPV are<br />
highly polarized in excitation and emission.<br />
M. Traub, G. Lakhwani, J. Bolinger,<br />
P. Barbara<br />
462. Exploration of hybrid materials for exploitation<br />
of hole-transfer photochemistry.<br />
M. P. Shores, A. M. McDaniel,<br />
H. Tseng, A. K. Rappe, N. H. Damrauer<br />
463. Synthesis of silicon nanowire arrays for<br />
solar cells. J. Cheng, S. R. Williams,<br />
S. J. Rathi, K. Kiriluk, R. T. Colloins,<br />
G. L. Frey<br />
464. Strongly binding ruthenium complexes<br />
for optically driven charge transfer between<br />
supramolecular and nanoscale<br />
systems. J. R. Alston,J.C.Poler<br />
465. Combined computational and experimental<br />
study on the role of linker in electron<br />
transfer in porphyrin-anthraquinone<br />
dyads. D. Liu, K. Weerasinghe, X. Zhou,<br />
L. Wang<br />
466. Withdrawn<br />
467. Withdrawn<br />
468. PbSe xTe 1-x and PbS xTe 1-x quantum<br />
dot alloys. D. K. Smith, M. C. Beard,<br />
J. M. Luther, O. E. Semonin, A. J. Nozik<br />
469. Femtosecond dynamics preceding Auger<br />
recombination in intensity-dependent<br />
pump probe spectroscopy of colloidal<br />
semiconductor nanocrystals.<br />
W. K. Peters, B. Cho, R. J. Hill, V. Tiwari,<br />
T. L. Courtney, D. M. Jonas<br />
470. Probing and optimizing dye adsorption<br />
density and binding strength on TiO 2 particles<br />
in DSCSC by optical second harmonic<br />
generation. Y. Chou, J. Zeng,<br />
B. Wayland, H. Dai<br />
471. Photo-initiated multi-electron-transfer<br />
catalysis at twice-reduced cobalt metalloporphyrins<br />
anchored to TiO 2. S. Ardo,<br />
D. Achey, G. J. Meyer<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
M. Johnson, S. Brown, V. Vaida,<br />
Organizers<br />
6:00–9:00<br />
472. Gas-phase water mediated equilibrium<br />
between aldehydes and their geminal diol<br />
counterparts. M. K. Maron,V.Vaida<br />
473. Energy distribution in the triplet channels<br />
of ozone photodissociation.<br />
G. McBane, L. T. Nguyen, R. Schinke<br />
474. Gas phase metal acetylene cluster ions<br />
as model reactors for studying reactivity<br />
of transition metal ions. P. Sharma,<br />
I. Attah, M. El-Shall<br />
475. Gas-liquid scattering using a liquid microjet:<br />
The journey to high vapor pressure<br />
liquids. A. M. Johnson, D. K. Burden,<br />
G. M. Nathanson<br />
476. Probing radical-molecule reactions with<br />
synchrotron photoionization mass spectrometry.<br />
S. Soorkia, A. J. Trevitt,<br />
C. A. Taatjes, D. L. Osborn, T. M. Selby,<br />
K. R. Wilson, S. R. Leone<br />
477. Electron attachment to radicals, products<br />
of ion-ion mutual neutralization, and<br />
electron catalyzed mutual neutralization.<br />
N. S. Shuman, T. M. Miller, C. M. Caples,<br />
A. A. Viggiano<br />
478. Infrared predissociation spectra of<br />
M � (C 6H 6) 1-4(H 2O) 1-2Ar 0-1,M� Li, Na.<br />
J. P. Beck, J. M. Lisy<br />
479. Infrared spectroscopy of Li � (CH 4) 1-<br />
3(H 2O) 3-4 clusters: Promoting H 2O���H 2O<br />
hydrogen bonding via methanation.<br />
O. Rodriguez Jr, J. M. Lisy<br />
480. Photoelectron spectroscopy of the furyl<br />
anion. K. M. Vogelhuber, S. W. Wren,<br />
L. Sheps, W. C. Lineberger<br />
481. Theoretical determined water dimer<br />
spectra in the near IR and visible regions<br />
in the atmosphere. R. E. Kelly,<br />
M. J. Barber, J. Tennyson,<br />
G. C. Groenenboom, A. van der Avoird<br />
482. Thermodynamics and spectroscopic<br />
analysis of carbon dioxide-methane-nitrogen<br />
mixed gas hydrate. H. Lee,<br />
J.Yoon,S.Ahn,B.Nam,B.Kim,G.Lee,<br />
D. Moon, H. Shin<br />
483. Spectroscopic identification of water/<br />
propane interaction: Implications for<br />
clathrate nucleation. T. H. Vu, M. Shultz<br />
484. Study of the hydration interaction acting<br />
between model “lipid” surfaces. C. Eun,<br />
M. L. Berkowitz<br />
485. Temperature-dependence of the absolute<br />
kinetics of hydroxyl radical oxidation<br />
of thiocynate in aqueous solution.<br />
D. K. Gaskins, S. P. Mezyk, T. W. Marin<br />
486. Gas phase reactivity of ClN 3 with positive<br />
and negative ions. N. Eyet, K. Freel,<br />
A. A. Viggiano, M. C. Heaven<br />
487. Solvent-Solute interactions in the gas<br />
phase: A rotationally resolved electronic<br />
spectroscopy study of 4-aminophenol<br />
and its complexes. J. W. Young,<br />
P. S. Walsh, A. J. Fleisher, D. W. Pratt<br />
488. Laminar flow cell for the study of secondary<br />
organic aerosol formation using<br />
photolytic initiation. W. S. McGivern,<br />
A. J. Pettibone<br />
489. Product study of the OH-initiated oxidation<br />
of acrolein. K. Flanders<br />
490. OH-initiated oxidation of n-butane in<br />
the presence of NO x. R. D. Rojas,<br />
K. Flanders, S. Cullipher, T. Dransfield<br />
491. Investigation of the OH � ethene addition<br />
reaction pathways from the<br />
CH 2CH 2OH radical intermediate.<br />
B. J. Ratliff, B. W. Alligood, L. J. Butler,<br />
S. Lee, J. Jr-Min Lin<br />
492. Influence of deuterium substitution on<br />
the terahertz spectra of hydrated molecular<br />
crystals. M. D. King, T. M. Korter<br />
493. Heterogeneous reactions of nitrogen dioxide<br />
with potassium iodide and iodideenriched<br />
sea salt aerosol surrogates.<br />
E. M. O’Neill, R. Z. Hinrichs<br />
494. Ozonolysis of solid polyphenol thin<br />
films: An ATR-FTIR and computational<br />
study. T. Barnum, N. Medeiros,<br />
R. Z. Hinrichs<br />
495. Isomerization potential energy surface<br />
for N 2H 2. R. C. Mayrhofer<br />
496. Microscopic structrure of tetrahydrofuran<br />
hydrate in pore space: MRI tomography<br />
study. j. Zhao, Y. Song, C. Cheng,<br />
K. Xue, L. Yao<br />
497. Experimental study on the separation of<br />
syngas via hydrate formation. Q. Sun<br />
498. Optical properties and associated hygroscopicity<br />
of clay aerosols and their<br />
mixtures with ammonium sulfate.<br />
A. R. Attwood, M. E. Greenslade<br />
499. Theoretical description of phase diagrams<br />
of hydrogen clathrate hydrates.<br />
R. Belosludov, H. Mizuseki, Y. Kawazoe,<br />
O. Subbotin, V. Belosludov<br />
500. Alkene ozonolysis: Selective scavenger<br />
studies of stabilized Criegee intermediates.<br />
G. T. Drozd, N. M. Donahue<br />
501. Atmosphere is a reservoir of electric<br />
charge, mediated by water ion partition.<br />
F. Galembeck, J. S. Bernardes,<br />
T. R. Ducati, L. P. Santos, T. A. Burgo<br />
502. Environmental chamber study on liquid<br />
phase oxidation of isoprene. S. R. Zorn,<br />
Q. Chen, M. I. Guzman, M. Kuwata,<br />
S. Lee, Y. Liu, M. Smith, S. T. Martin<br />
503. Effects of solutes on the interfacial liquid<br />
layer of ice by infrared spectroscopy.<br />
R. L. Walker, R. R. Michelsen<br />
504. Modeling the rovibrationally excited<br />
CH 2CH 2OH radicals from the dissociation<br />
of 2-bromoethanol at 193nm.<br />
B. J. Ratliff, C. C. Womack,X.N.Tang,<br />
D. E. Szpunar, L. J. Butler<br />
505. Determination of the CH 3SO 2 3 CH 3�<br />
SO 2 barrier from the photodissociation of<br />
methylsulfonyl chloride excited at 193<br />
nm. D. E. Szpunar, L. J. Butler, K. Lau,<br />
B. J. Ratliff, X. Tang<br />
506. First principle investigation of hydrogen<br />
transfer between surface adsorbed H 2O<br />
and OH on BaO (001) surface of thin film<br />
BaTiO 3. J. Martirez, W. Al-Saidi,<br />
A. Rappe<br />
507. Impacts of surface-adsorbed catechol<br />
on tropospheric aerosol surrogates: Heterogeneous<br />
chemistry and water uptake.<br />
L. A. Woodill, R. Z. Hinrichs<br />
508. Measurement of total gas phase organic<br />
(TGO) composition.<br />
A. J. Carrasquillo,E.S.Cross,<br />
D. R. Worsnop, S. Herndon, J. Jayne,<br />
J. H. Kroll<br />
509. Characterization of a new rigid walled<br />
chamber for studying the chemistry of atmospheric<br />
organic aerosol. J. Hunter<br />
510. Crystal structures of the type II cyclopentane<br />
clathrate hydrate and the KOHdoped<br />
type II propylene oxide clathrate<br />
hydrate. S. Cryer,C.Y.Jones<br />
511. Study on the generation of charges by<br />
ice friction under atmospheric conditions.<br />
S. Du,T.C.Germann<br />
512. Diminished kinetic rates in successive<br />
oxidation of organic aerosol species.<br />
S. H. Kessler, J. D. Smith, D. L. Che,<br />
K. R. Wilson, D. R. Wornsop, J. H. Kroll<br />
513. Triggering intra-cluster electron capture<br />
with vibrational excitation: An IR study of<br />
the CH 3NO 2�(H 2O) 6 anion. K. J. Breen,<br />
T. L. Guasco, M. A. Johnson<br />
514. Spectroscopy of the �-naphthol-water<br />
complex in the gas phase: Solvation, internal<br />
rotation, and electronic interactions.<br />
A. J. Fleisher, J. W. Young,<br />
D. W. Pratt<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Physical Chemistry of Spectrochemical<br />
Analysis<br />
B. Pate, M. Johnson, Organizers<br />
6:00–9:00<br />
515. Chirped pulse millimeter-wave spectroscopy<br />
of Rydberg-Rydberg transitions.<br />
K. Kuyanov-Prozument, A. P. Colombo,<br />
Y. Zhou, G. B. Park, V. S. Petrovic,<br />
R. W. Field<br />
516. Theoretical calculation of the MCD<br />
spectra for some molybdenyl complexes.<br />
E. Hernandez-Marin, T. Ziegler<br />
517. New prospects of laser induced acoustic<br />
desorption for electron attachment experiments<br />
with biomolecules.<br />
L. An der Lan, S. Denifl, P. Scheier,<br />
T. D. Märk<br />
518. Probing three-body correlations with 3D<br />
electronic spectroscopy. A. F. Fidler,<br />
E. Harel, G. S. Engel<br />
519. Non-Born-Oppenheimer spectroscopy:<br />
Exploring the conical intersection in bovine<br />
rhodopsin. J. R. Caram,<br />
K. A. Fransted, G. G. Griffin,<br />
M. L. Flanagan, G. S. Engel<br />
520. State-resolved molecular beam reflectivity<br />
measurements of CH 4 activation on<br />
Ni(111). N. Chen,V.L.Campbell,<br />
Y. Huang, A. L. Utz<br />
521. Characterization of slip over a solid-liquid<br />
interface using fluorescence recovery<br />
after photobleaching (FRAP).<br />
A. Ponjavic,J.Wong<br />
522. Conformational populations of a fast<br />
folding protein captured by time-resolved<br />
fluorescence energy transfer. N. Bouley<br />
523. Excited state intramolecular charge<br />
transfer in the two rotamers of 3-aminobenzoic<br />
acid as studied by high resolution<br />
Stark spectroscopy. A. J. Fleisher,<br />
P. J. Morgan, D. W. Pratt<br />
524. 2D infrared spectroscopy study of the<br />
inverse temperature transition in elastinlike<br />
peptides. J. Lessing,C.S.Peng,<br />
J. Kim, K. Jones, A. Tokmakoff<br />
525. Two-photon absorption of silver nanoclusters<br />
and 2,6 disubstituted benzobisthiazoles.<br />
T. Goodson, L. N. Upton<br />
526. High resolution time-of-flight mass<br />
spectral analysis of vacuum electrospray<br />
ionization of ionic liquids. B. W. Ticknor,<br />
Y. Chiu<br />
527. Isotope-edited single-molecule surfaceenhanced<br />
Raman spectroscopy of crystal<br />
violet. S. L. Kleinman,K.L.Wustholz,<br />
N. Valley, E. Ringe, E. Phillips,<br />
K. A. Scheidt, G. C. Schatz,<br />
R. P. Van Duyne<br />
528. Combining FCS and interferometry to<br />
extract spectral dynamics from single<br />
chromophores in solution. L. F. Marshall,<br />
J. Cui, X. Brokmann, M. G. Bawendi<br />
529. Withdrawn<br />
530. Multiplexed polarization spectroscopy:<br />
Measuring surface hyperpolarizability.<br />
P. Bisson, M. J. Shultz<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
PHYS<br />
TECH–107
PHYS <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
531. Comparison of the intermolecular dynamics<br />
of confined and low-temperature<br />
bulk benzene. K. M. Manfred,X.He,<br />
J. T. Fourkas<br />
532. Collisional deactivation of the<br />
Ne(2p 5 3p) levels by He. M. H. Kabir,<br />
K. Freel, M. C. Heaven<br />
533. Spectroscopic and ab initio studies of<br />
intramolecular pi-type hydrogen bonding<br />
in 3-cyclopenten-1-ol, 2-cyclopentene-1amine,<br />
and 2-hydroxytetralin.<br />
E. J. Ocola, H. Shin, A. A. Al-Saadi,<br />
J. Laane<br />
534. Terahertz spectroscopy and solid-state<br />
density functional theory of oxidizers<br />
used in improvised explosives.<br />
E. M. Witko, T. M. Korter<br />
535. Modification of the luminescent properties<br />
of rare-earth ions through plasmonic<br />
nanoparticles. J. Seo,M.Rigo<br />
536. Room-temperature study of hydrogen<br />
adsorption on carbon-based nanomaterials<br />
using diffuse reflectance infrared<br />
spectroscopy. J. R. Rocha,D.Zhao,<br />
J. B. Bult, C. Engtrakul, K. J. O’Neill,<br />
J. Barker, H. Zhou, L. J. Simpson,<br />
M. J. Heben, J. L. Blackburn<br />
537. Femtosecond laser spectroscopic studies<br />
of the interface of CdTe/CdSe coreshell<br />
nanocrystals. C. Chuang,C.Burda<br />
538. Manipulating quantum coherence in<br />
room temperature liquids to image<br />
through scattering media. N. Yang,<br />
A. Cohen<br />
539. Anomalous increase in the stability of<br />
human serum albumin upon temperature<br />
cycling. B. L. McClain, K. Nguyen,<br />
A. Austin, M. Schrader<br />
540. Development of an infrared mass spectrometer<br />
instrument based on an electrospray<br />
ion source and a cryogenically<br />
cooled ion trap. M. Z. Kamrath,<br />
C. Leavitt, R. Relph, M. Johnson<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Physical Chemistry Poster Session<br />
M. Johnson, Organizer<br />
6:00–9:00<br />
541. X-ray photoelectron spectroscopy<br />
(XPS) studies of proton transfer in molecular<br />
crystals. J. S. Stevens, S. J. Byard,<br />
S. L. Schroeder<br />
542. Structure of cell membranes revealed<br />
by in situ atomic force microscope.<br />
H. Wang, M. Cai, W. Zhao, X. Hao,<br />
Y. Shan, X. Shang, J. Jiang<br />
543. Kinetic study on chemical oxidative polymerization<br />
of aniline in HCl /NaCl using<br />
hydrogen peroxide. S. Agnihotra,<br />
S. P. Surwade, S. K. Manohar<br />
544. Investigation of molecular rotational activation<br />
energies in room temperature<br />
ionic liquids using 14 N NMR spectroscopy.<br />
T. M. Alam, D. Dreyer,<br />
C. Bielawski, R. Ruoff<br />
545. Computational and spectroscopic investigations<br />
of reversible furan-maleimide<br />
cycloadditions: Parent reaction and derivatized<br />
analogs. R. C. Boutelle,<br />
B. H. Northrop<br />
546. Free energy of association of two and<br />
three �-peptide molecules. J. Mondal,<br />
X. Zhu, Q. Cui, A. Yethiraj<br />
547. Adsorption and dissociation of NH 3 on<br />
clean and hydroxylated TiO 2 rutile (110)<br />
surfaces: A computational study.<br />
J. Chang, H. Chen, J. Lu, S. Ju<br />
548. Association kinetics of polar and nonpolar<br />
protofilaments. G. Reddy<br />
549. Withdrawn<br />
550. Computational design of fluorescent<br />
BINOL-based receptors. J. S. Mancini,<br />
C. Parish<br />
551. Molecular dynamics investigation of<br />
Kinesin cargo-binding domain. S. Fisher,<br />
C. Parish<br />
‡ Cooperative Cosponsorship<br />
108–TECH<br />
552. Vapor-liquid equilibria of copper using<br />
hybrid Monte Carlo Wang-Landau simulations.<br />
T. Aleksandrov, E. A. Kastl,<br />
C. Desgranges, J. Delhommelle<br />
553. Nascent IR probing of HCl (v�0, J) from<br />
collisions with highly excited pyrazine:<br />
Isotope effects in J-changing collisions.<br />
M. D. Smarte, N. A. Sassin,<br />
G. O. Echebiri, A. S. Mullin<br />
554. Structural and dynamic properties of a<br />
revised OSS2 model for water. S. H. Lee,<br />
J. C. Rasaiah<br />
555. Replica exchange Monte Carlo simulations<br />
of derivatized fullerenes on Au(111).<br />
G. Bubnis, H. Mayne<br />
556. Role of structural anisotropies on model<br />
poly-3-methyl thiophene (P3MT) films<br />
and their electrical properties. R. J. Patel,<br />
M. A. Hickner<br />
557. High-resolution infrared spectroscopy<br />
in the O-D stretching region of doublydeuterated<br />
hydronium ion, HD 2O � .<br />
M. A. Roberts, E. N. Sharp-Williams,<br />
D. J. Nesbitt<br />
558. Effect of the shear on the percolation<br />
network and the electric conductivity of<br />
carbon networks/polymer composites:<br />
Monte Carlo simulation study. B. Sung,<br />
G. Kwon<br />
559. Utilization of novel Gemini surfuctantmontmorilonite<br />
clay complexes in<br />
triphase catalysis. N. Shabestary,<br />
D. Rensing<br />
560. Interfacial charge/discharge and ion<br />
transport dynamics on nanoporous carbon<br />
supercapacitors. J. Guo,<br />
S. M. Mahurin, S. Dai, G. M. Brown,<br />
R. W. Shaw<br />
561. Depletion effect on polymers induced<br />
by small depleting particles. J. Kim,<br />
I. Szleifer<br />
562. Flux effect on the melting and wetting of<br />
solder nanowires and nanorods. F. Gao,<br />
K. Rajathurai, Q. Cui, I. Nkengfor-Acha,<br />
Z. Gu<br />
563. Synthesis of lead-free solder nanoparticles<br />
and their application as nano-inks<br />
and nano-pastes. Q. Cui, K. Rajathurai,<br />
F. Gao, Z. Gu<br />
564. Genome sequencing by natural DNA<br />
synthesis. E. E. Roller, K. Ko, Z. Liu,<br />
M. Walsh, X. Huang<br />
565. Impact of nuclear quantum effects on<br />
the liquid-glass transition.<br />
T. E. Markland, J. A. Morrone,<br />
K. Miyazaki, E. Rabani, D. R. Reichman,<br />
B. J. Berne<br />
566. Withdrawn<br />
567. Degeneration of singlet and triplet excited<br />
states in luminescent gold nanoparticles.<br />
C. Zhou, M. Yu, Y. Qin, J. Zheng<br />
568. Advancing the use of the linear solvation<br />
parameter model for organosilicon<br />
compounds for the prediction of physical<br />
properties relevant to their environmental<br />
fate. J. L. Mosey, G. Kozerski<br />
569. Enhanced difluoroboron dibenzoylmethane<br />
derivatives: Photophysics and<br />
applications. R. E. Evans, T. Liu,<br />
G. Zhang, C. Fraser<br />
570. Two-photon absorbing GFP-type chromophores:<br />
Synthetic design and spectroscopic<br />
characterization. T. B. Clark,<br />
T. Goodson III<br />
571. Role of energy threshold played in<br />
MALDI: Studies from the corresponding<br />
measurements of Gly-Gly-His, Glu-Val-<br />
Phe and three matrices. B. Chen,<br />
C. Liang, Y. Lee<br />
572. Synthesis of InP nanocrystal quantum<br />
dots using silylphosphine derivatives as<br />
the phosphorus precursor: Optical and<br />
structural chracterizations. S. Joung,<br />
Y.Moon,Y.Kim,C.Han,S.Jeong<br />
573. Fibonacci code for genetic and epigenetic<br />
dynamics. D. Gurel, O. Gurel<br />
574. Aggregation dynamics of sphericallysymmetric<br />
reactive colloidal particles under<br />
shear stresses. M. C. Hagy,<br />
S. J. Fitzwater, T. H. Pierce, M. Schure,<br />
A. V. Popov, R. Hernandez<br />
575. Computational study of the behavior of<br />
ionic liquids confined inside multi-walled<br />
carbon nanotubes. R. Singh, J. D. Monk,<br />
F. R. Hung<br />
576. Quantum chemical computations of<br />
H/D deuterium isotope effects on 1H and<br />
13C NMR chemical shifts. K. S. Yang,<br />
B. S. Hudson<br />
577. Non-Born-Oppenheimer spectroscopy:<br />
Direct exploration of conical intersections.<br />
K. A. Fransted, J. R. Caram,<br />
G. B. Griffin, G. S. Engel<br />
578. Infrared and computational studies of<br />
vibrations of molecules adsorbed on single-walled<br />
carbon nanotubes. M. Ellison<br />
579. Investigation of the primary photodissociation<br />
channels of chloroacetone at<br />
193nm. B. W. Alligood, B. FitzPatrick,<br />
L. J. Butler, D. Szpunar<br />
580. Use of Cy3 labeled DNA to determine<br />
the transcription rate of single T7 RNAP<br />
molecules. D. R. Nicholas,M.L.Norton,<br />
W. P. Kunin<br />
581. XYG4-OS: An accurate and fast fifthrung<br />
density functional method. I. Zhang,<br />
X. Xu, Y. Jung, W. A. Goddard, III<br />
582. Microscopic rotor driven by the energy<br />
stored in braided DNA molecules.<br />
M. Fernández-Sierra, V. Delgado-Martí,<br />
E. Quiñones<br />
583. Seven polymorphs of human carbonic<br />
anhydrase II exhibit the same packing<br />
motif. R. L. Kwant, P. W. Snyder,<br />
E. T. Mack, D. T. Moustakas, M. J. Butte,<br />
G. M. Whitesides<br />
584. Study of emission of gold and silver<br />
nanoclusters by ultrafast spectroscopy.<br />
S. Yau<br />
585. Modeling photoexcited reactions of<br />
simple molecules in solution. J. Zhang,<br />
D. Coker<br />
586. Molecular modeling studies for thermal<br />
and chemical stabilities of Coprinus cinereus<br />
peroxidase (CiP) mutants. J. Lee,<br />
R. Chang, Y. Kim<br />
587. Structural dynamics of 1,3-Cyclohexadiene<br />
upon electrocyclic ring opening.<br />
C. C. Buehler, P. M. Weber, M. P. Minitti,<br />
S. Deb, J. Bao<br />
588. Low energy, Co � -mediated decomposition<br />
kinetics of acetone into Co � CO �<br />
ethane. O. J. Villarroel, I. E. Laboren,<br />
D. J. Bellert<br />
589. One student’s experience in the ACS<br />
nuclear chemistry summer school program.<br />
S. McCarthy<br />
590. New insights into ligand effects during<br />
quantum dot nucleation and growth.<br />
C. R. Hine,A.Roy,M.M.Maye<br />
591. Photophysical properties of alkylamino<br />
substituted aryl- and diarylidene cyclopentanones.<br />
C. A. Zoto,R.E.Connors<br />
592. Semifluorinated polymer brushes by<br />
surface-initiated atom transfer radical polymerization<br />
(SI-ATRP) on layer-by-layer<br />
macroinitiator modified substrates.<br />
N. C. Estillore, R. C. Advincula<br />
593. Cocrystals of sulfoxides and thioamides.<br />
A. E. Lindeman, C. Elcoate,<br />
S. Lawrence<br />
594. Molecular wire attachment to singlewalled<br />
carbon nanotubes. A. Rimshaw<br />
595. Plasmon-enhanced photoluminescence<br />
of self-assembled CdSe quantum dots.<br />
M. Rigo,J.Seo<br />
596. Elucidation of the role of the central,<br />
flexible region of IAPP in amyloid formation.<br />
G. Liu, S. Sparks, N. D. Lazo<br />
597. Model study of adlayer pattern formation<br />
on hexagonal and square substrates.<br />
G. Berezutskiy, L. Lawrence-Hurt,<br />
G. Bubnis, H. Mayne<br />
598. Negative ion photoelectron spectra of<br />
six-membered nitrogen-containing heterocycles.<br />
S. W. Wren, K. M. Vogelhuber,<br />
L. Sheps, S. Kato, V. M. Bierbaum,<br />
W. C. Lineberger<br />
599. Withdrawn<br />
600. Dynamics at the air/deuterated water<br />
interface: Theory and experiment.<br />
I. V. Stiopkin, C. Weeraman,<br />
P. A. Peiniazek, J. L. Skinner,<br />
A. V. Benderskii<br />
601. Electrochemical properties of ruthenium<br />
sandwich complexes. I. Chacon<br />
602. Patterned polymer brushes on indium<br />
titanium oxide surface using RAFT and<br />
ATRP techniques. M. R. Tria,<br />
R. C. Advincula<br />
603. Conductivity and component diffusion<br />
study of a solid lithium polymer electrolyte<br />
based on the polymer blend of PEG<br />
and PMMA doped with LiTFSI. Y. Meng,<br />
L. J. Smith<br />
604. Primary isotope effect in oxazine dyes:<br />
Fluorescent lifetime study. X. Song,<br />
S. Chen<br />
605. Site selectivity in the growth of copper<br />
islands on Au (111). F. Grillo,<br />
S. M. Francis, N. V. Richardson<br />
606. Computational design of a new type of<br />
Co-Por carbene catalyst involved in the<br />
asymmetric cyclopropanation of alkenes.<br />
C. R. Cioce, J. L. Belof, P. X. Zhang,<br />
B. Space, H. L. Woodcock<br />
607. Electrochemical characterization of biomimetic<br />
bilayers: Insights into drug-membrane<br />
interactions. N. Jarenwattananon,<br />
B. D. Lahiji, M. D. Sykes, M. C. Buzzeo<br />
608. Novel techniques in multiple time scale<br />
molecular dynamics. J. A. Morrone,<br />
T. E. Markland, R. Zhou, B. J. Berne<br />
609. Vibrational spectroscopy of ice Ih, theory<br />
and interpretation. F. li,J.L.Skinner<br />
610. Detection of nitric oxide in vivo using<br />
single-walled carbon nanotube near-infrared<br />
photoluminescence. M. Shandell<br />
611. Velocity-map imaging of scattered molecular<br />
flux: Correlating quantum-state<br />
and translational distributions.<br />
J. Roscioli, D. Bell, D. Nesbitt<br />
612. Conformational control of ubiquitination<br />
in the cullin-RING E3 ligase machinery: A<br />
molecular dynamics study. J. Liu,<br />
R. Nussinov<br />
613. Solid state electrochemistry of Ag(I),<br />
Cu(II) and Au(I) nanofibers: Towards<br />
“nano-electrochemical welding”.<br />
G. R. Bourret, T. D. Lazzara,<br />
T. G. van de Ven, R. B. Lennox<br />
614. Vibrational predissociation spectra in<br />
the shared proton region of protonated<br />
formic acid wires. H. K. Gerardi,<br />
C. M. Leavitt, M. A. Johnson<br />
615. Study of the solid-liquid equilibrium of<br />
succinic acid in different solvents and<br />
modeling using NRTL equation.<br />
A. Orjuela, A. Yanez, D. Miller, C. Lira<br />
616. <strong>Chemical</strong> kinetics of the photochromic<br />
and thermochromic conversion of spiropyran<br />
into merocyanine. T. Buthelezi,<br />
K. K. Smith, O. Grover<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
E. Baker, M. Johnson, M. Bowers,<br />
Organizers<br />
6:00–9:00<br />
617. Long distance influences of targets in<br />
the Belousov-Zhabotinsky Reaction.<br />
S. B. Minchenberg, K. D. Zauderer,<br />
H. M. Hastings, S. G. Sobel<br />
618. Complex band perspective of defect<br />
states in conducting polymers. Q. Lu,<br />
M. Li, X. Lin<br />
619. Interfacial properties and confinement<br />
effects of aqueous electrolytes in microporous<br />
carbon. M. C. Wander,<br />
K. L. Shuford<br />
620. PEGylated and electropolymerizable<br />
linear dendron macromolecules: Stability<br />
and molecular conformation at the airwater<br />
interface. M. L. Felipe, N. Estillore,<br />
R. Advincula<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
621. Thermal fluctuations and reorientations<br />
in solid state proton wires. J. A. Harvey,<br />
U. Viswanathan, J. Fermann,<br />
S. M. Auerbach<br />
622. Electron and energy transfer across a<br />
single amide bridge: MLCT relaxation<br />
processes for an excited ruthenium bipyridine<br />
donor acceptor complex.<br />
R. Rached<br />
623. Sequence dependent preferences of<br />
cations in nucleic acid structures.<br />
Y. G. Yingling, L. Sethaphong, A. Singh<br />
624. Characterization of hygroscopic core:<br />
Organic shell nanoparticles by tandem<br />
particle mobility measurements.<br />
S. A. Nizkorodov, J. Morrison,<br />
A. MacMillan, C. Harmon<br />
625. Ion mobility study of the structure and<br />
binding energy of protonated pyrimidinewater<br />
and pyrimidine-methanol clusters.<br />
A. Hamid, M. S. El-Shall<br />
626. Gas phase sequential reactions of pyridine<br />
and pyrimidine radical cations with<br />
acetylene: Evidence for nitrogen-containing<br />
covalent cyclic adducts. A. Soliman,<br />
M. S. El-Shall<br />
627. Coherence resonance in a single walled<br />
carbon nanotube ion channel. W. Choi,<br />
C. Lee, J. Han, M. Strano<br />
628. Electromigration properties of nanoparticles.<br />
T. L. Doane, Y. Cheng, R. Hill,<br />
C. Burda<br />
629. Ion transport through a hybrid membrane<br />
made of gramadine-A confined in a<br />
nanoporous polymer film. S. Balme,<br />
J. Janot, L. Berardo, F. Henn<br />
630. Ion conductive characteristics of organoboron<br />
ion gels facilely designed by<br />
condensation of cellulose with boric acids<br />
in ionic liquid. N. Matsumi,K.Aoi<br />
631. Structures of bismuth and tin cluster<br />
ions. R. Kelting<br />
THURSDAY MORNING<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
S. Nizkorodov, Presiding<br />
8:00 632. Advances in studying the optical<br />
properties of complex aerosols with organic<br />
components. Y. Rudich<br />
8:40 633. Aerosol optical properties and internal<br />
structure. M. A. Freedman,<br />
C. A. Hasenkopf, K. J. Baustian,<br />
M. E. Wise, K. J. Zarzana, M. R. Beaver,<br />
M. A. Tolbert<br />
9:00 634. Changing optical properties of organic<br />
aerosol. C. D. Cappa, K. R. Wilson,<br />
J. D. Smith, D. L. Che<br />
9:40 635. Wavelength and humidity dependent<br />
aerosol extinction. A. R. Attwood,<br />
R. T. Chartier, M. E. Greenslade<br />
10:00 Coffee Break<br />
10:20 636. Measuring aerosol uptake kinetics<br />
using laser flash photolysis. G. Smith,<br />
L. Renbaum<br />
11:00 637. Role of isoprene epoxydiols in<br />
the formation of isoprene SOA under low-<br />
NO x conditions. N. C. Eddingsaas,<br />
J. D. Surratt, M. Chan, A. W. Chan,<br />
J. H. Seinfeld, P. O. Wennberg<br />
11:20 638. Photochemical aging and the<br />
evolution of atmospheric organic aerosol.<br />
J. H. Kroll, S. H. Kessler,<br />
A. J. Carrasquillo, K. R. Wilson,<br />
D. R. Worsnop<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
C. Schmuttenmaer, V. Batista, Organizers<br />
B. Bartlett, Presiding<br />
8:20 639. Use of sunlight for the photocatalytic<br />
conversion of carbon dioxide and<br />
water vapor to hydrocarbon fuels.<br />
C. A. Grimes<br />
9:00 640. Photocatalytic hydrogen production<br />
with tunable nanorod heterostructures.<br />
P. Alivisatos<br />
9:40 641. Carbon dioxide reduction to form<br />
carbon-carbon bonds: Mechanistic investigation<br />
of systematically tuned pyridine<br />
derivatives. A. J. Morris,<br />
E. L. Zeitler, R. L. Slater, E. B. Cole,<br />
P. S. Lakkaraju, A. B. Bocarsly<br />
10:00 Intermission<br />
10:20 642. Structure-function analyses of<br />
supramolecular and biomimetic designs<br />
for solar fuels catalysts. D. M. Tiede,<br />
K. L. Mulfort, A. M. Scott, S. L. Bender,<br />
O. G. Poluektov, L. M. Utschig,<br />
L. X. Chen, K. L. Mardis<br />
11:00 643. Photo-induced two-, four-, and<br />
six-electron reducing equivalents storage<br />
using mononuclear Ru complexes.<br />
K. Tanaka, T. Fukushima, E. Fujita,<br />
J. Muckerman<br />
11:40 644. Biphasic ionic liquid-supercritical<br />
CO 2 solvent systems for the photocatalytic<br />
reduction of CO 2. D. C. Grills,<br />
E. Fujita<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Macromolecular Structures Cosponsored by<br />
ANYL<br />
M. Bowers, E. Baker, Organizers<br />
A. Ashcroft, Presiding<br />
8:30 Introductory Remarks<br />
8:35 645. Ion mobility of membrane and soluble<br />
complexes. C. Robinson<br />
9:15 646. Ion mobility mass spectrometry<br />
applied to virus structure and assembly.<br />
A. J. Heck<br />
9:55 647. Development of ion mobility-mass<br />
spectrometry as a high-throughput approach<br />
for structural genomics.<br />
B. T. Ruotolo<br />
10:35 648. Ion mobility investigations of protein:carbohydrate:metal<br />
ion non-covalent<br />
complexes. J. A. Leary<br />
11:15 649. Role of charge state on protein<br />
conformation and protein complexes<br />
probed by ion mobility and mass spectrometry.<br />
S. H. Lomeli, C. N. Ferguson,<br />
S. A. Benchaar, R. R. Ogorzalek Loo,<br />
J. A. Loo<br />
THURSDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 104B<br />
Molecular Systems for Efficient Solar<br />
Energy Conversion and Storage<br />
V. Batista, Organizer<br />
C. Schmuttenmaer, Organizer, Presiding<br />
1:30 650. Artifical OEC that is a functional<br />
mimic of the OEC and PSII. D. G. Nocera<br />
2:10 651. Theoretical studies of catalysis for<br />
artificial photosynthesis.<br />
J. T. Muckerman, X. Shen, Y. A. Small,<br />
P. B. Allen, M. V. Fernandez-Serra,<br />
M. S. Hybertsen, E. Fujita<br />
2:50 652. Effect of a cobalt-based oxygen<br />
evolution catalyst on the stability and the<br />
selectivity of photo-oxidation reactions of<br />
aWO 3 photoanode. J. A. Seabold,<br />
K. Choi<br />
3:10 Intermission<br />
3:30 653. Catalytic solar water splitting inspired<br />
by photosynthesis. homogeneous<br />
catalysts with a Mechanical (“Machinelike”)<br />
action. G. F. Swiegers,<br />
G. Dismukes, L. Spiccia,<br />
R. Brimblecombe, A. Koo, J. Chen,<br />
G. G. Wallace<br />
4:10 654. Optimization of energy transfer<br />
processes in photosynthetic systems.<br />
J. Cao<br />
4:50 655. Highly visible light-sensitive TiO 2<br />
photocatalysts toward bioinspired solar<br />
cells. M. Yoon, H. Lee, J. Lee<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 107B<br />
Physical Chemistry of Hydrates, Interfaces,<br />
and Aerosols and their Relationship to the<br />
Climate System<br />
S. Brown, V. Vaida, Organizers<br />
J. Kroll, Presiding<br />
1:30 656. Organic Aerosol formation from<br />
OH oxidation of a series of alkanes and<br />
aldehydes. N. M. Donahue<br />
2:10 657. Unimolecular reactions of precusors<br />
to secondary organic aerosols.<br />
W. Tsang<br />
2:30 658. Effect of molecular structure on<br />
secondary organic aerosol formation.<br />
P. J. Ziemann<br />
3:10 659. Intercomparison study of black<br />
carbon measurements. E. S. Cross,<br />
T. B. Onasch, A. Ahern, W. Wrobel,<br />
J. G. Slowik, J. Olfert, D. Lack,<br />
P. Massoli, C. D. Cappa, J. P. Schwarz,<br />
R. Spackman, D. W. Fahey, A. Sedlacek,<br />
A. Trimborn, J. T. Jayne, A. Freedman,<br />
L. Williams, N. L. Ng, C. Mazzoleni,<br />
M. Dubey, B. Brem, G. Kok,<br />
R. Subramanian, S. Freitag, A. Clarke,<br />
C. E. Kolb, D. R. Worsnop, P. Davidovits<br />
3:30 Intermission<br />
3:50 660. Phase transitions of ammonium<br />
sulfate particles internally mixed with secondary<br />
organic material. S. T. Martin,<br />
M. Smith, M. Kuwata<br />
4:30 661. Binary solid/liquid phase diagrams<br />
of the ammonium malonate and ammonium<br />
hydrogen malonate aqueous systems<br />
with implications for tropospheric<br />
aerosols. K. D. Beyer, M. D. Richardson<br />
4:50 662. Aging of secondary organic aerosols<br />
by carbonyl-amine chemistry.<br />
S. A. Nizkorodov, D. L. Bones,<br />
A. P. Bateman, T. B. Nguyen, Z. Cabral,<br />
L. Q. Nguyen, J. Laskin, A. Laskin<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 106<br />
Recent Advances in Ion Mobility for<br />
Analysis and Characterization of<br />
Macromolecules<br />
Complex Samples Cosponsored by ANYL<br />
M. Bowers, Organizer<br />
E. Baker, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 663. Pushing the limits of LC-MS sensitivity<br />
and throughput using IMS-TOF<br />
MS. R. D. Smith,E.S.Baker,<br />
Y. M. Ibrahim, D. C. Prior,<br />
W. F. Danielson III, K. K. Weitz,<br />
A. R. Shah, G. A. Anderson, M. Belov<br />
2:15 664. Use of sub-monolayer nanoparticulate<br />
matrices for lipid imaging by matrix<br />
implanted laser desorption/ionization<br />
(MILDI) ion mobility MS. A. S. Woods,<br />
E. K. Lewis, J. Post, A. Delvolve,<br />
T. F. Egan, J. A. Schultz<br />
2:35 665. Shape selective studies of complex<br />
systems utilizing travelling wave ion<br />
mobility mass spectrometry. J. Scrivens<br />
3:15 666. Advances in the temporal and<br />
structural measurement of cellular secreteomes.<br />
J. A. McLean<br />
3:55 667. Ion mobility-mass spectrometery<br />
as a tool for investigating aggregation inhibitors<br />
of Alzheimer’s amyloid beta protein.<br />
M. M. Gessel, H. Li, C. Wu, J. Shea,<br />
G. Bitan, M. T. Bowers<br />
4:15 668. Inducing transitions between<br />
states as a means of refining structures<br />
obtained from ion mobility measurements.<br />
D. E. Clemmer<br />
POLY<br />
Division of Polymer<br />
Chemistry<br />
K. Kiick, J. Linhardt, and G. Tew,<br />
Program Chairs<br />
OTHER SYMPOSIA OF INTEREST:<br />
Synthetic Oligosaccharides and<br />
Glycoconjugates for Preventing and<br />
Combating Disease (see CARB, Mon)<br />
Recent Developments in Intellectual<br />
Property Law: Patents, Trade<br />
Secrets, and Trademarks (see CHAL,<br />
Tue)<br />
Undergraduate Research Posters:<br />
Polymer Chemistry (see CHED, Mon)<br />
Nanomaterials for Biological,<br />
Pharmaceutical and Biomedical<br />
Applications (see COLL,Sun,Mon,<br />
Tue, Wed, Thu)<br />
Arthur C. Cope and Arthur C. Cope<br />
Scholars Award Symposium (see<br />
ORGN, Tue)<br />
Nanoscaled Materials for Drug<br />
Delivery and Diagnostic Applications<br />
(see ORGN, Wed)<br />
SOCIAL EVENTS:<br />
POLY/PMSE Plenary Lecture and<br />
Award Reception, 5:30 PM: Wed<br />
SUNDAY MORNING<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
From Molecules to Macromolecules:<br />
Towards Self-Assembling Materials<br />
C. Tang, P. Iovine, Organizers<br />
J. Lavigne, Organizer, Presiding<br />
PHYS/POLY<br />
8:25 Introductory Remarks<br />
8:30 1. Polycatenation under kinetic and<br />
thermodynamic control. J. F. Stoddart,<br />
M. A. Olson, L. Fang, A. Coskun,<br />
A. N. Basuray<br />
9:00 2. Functional and responsive block copolymers.<br />
K. A. Cavicchi<br />
9:20 3. Utilization of molecular rotors to<br />
probe local dynamics in self-assembled<br />
block copolymer materials.<br />
J. D. Biberdorf, C. W. Cone,<br />
D. A. Vanden Bout, B. J. Holliday<br />
9:50 POLY/PMSE Poster Session and Intermission<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–109
POLY <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
10:20 4. Gated molecular baskets and reactivity.<br />
J. D. Badjic,S.Rieth<br />
10:50 5. Supramolecular ionic networks.<br />
M. Grinstaff<br />
11:10 6. IL mPO nIL m – Ionic liquid-based<br />
triblock copolymers. J. Texter, K. Bian,<br />
R. Crombez<br />
11:30 7. Block copolymers as self-assembling<br />
building blocks for functional materials.<br />
R. B. Grubbs<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Polymers for Immunology and<br />
Immunotherapy<br />
Polymers for Vaccines and Immunotherapy<br />
D. Irvine, S. Little, Organizers, Presiding<br />
8:30 8. Polymers for immunology and immunotherapy.<br />
J. A. Hubbell<br />
9:00 9. Infection-mimicking polymers.<br />
D. Mooney<br />
9:30 10. Immunostimulating polyphosphazenes<br />
and their applications in vaccine<br />
delivery. A. K. Andrianov<br />
9:50 11. Synthesis and characterization of<br />
interbilayer-crosslinked multilamellar vesicles<br />
for vaccine delivery. J. J. Moon,<br />
H. Suh, M. Sohail, A. Bershteyn, S. Um,<br />
M. T. Stephan, B. Huang, D. J. Irvine<br />
10:10 POLY/PMSE Poster Session and Intermission<br />
10:40 12. Modulation of the tumor immunoinhibitory<br />
microenvironment with polymeric<br />
co-sustained delivery of small molecule<br />
inhibitors and cytokines.<br />
T. M. Fahmy, J. Park, S. Wrzesinski,<br />
R. Flavell<br />
11:10 13. Combining cell therapy and nanoparticle<br />
drug delivery: <strong>Chemical</strong> cell surface<br />
engineering on live cells using nanoparticles.<br />
D. J. Irvine<br />
11:40 14. Targeting dendritic cells with functionalized<br />
polyanhydride nanoparticles.<br />
B. R. Carrillo-Conde,<br />
A. Chavez-Santoscoy, E. Song, N. Pohl,<br />
M. J. Wannemuehler, B. Narasimhan<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Medical Applications of Polymers<br />
Faculty Entrepreneurship<br />
T. Jozefiak, N. Washburn, Organizers,<br />
Presiding<br />
8:30 15. Medicinal nanoengineering: Multifunctional<br />
polymeric nanoparticles for<br />
medical applications. O. C. Farokhzad<br />
9:00 16. Novel antibiotics: From design to<br />
the clinic. G. N. Tew<br />
9:30 17. Discovery and innovations of aspirin:<br />
From willow bark to polyaspirin.<br />
K. E. Uhrich<br />
10:00 POLY/PMSE Poster Session and Intermission<br />
10:30 18. Dendritic polymers for ocular<br />
wound repair: From concept to clinical<br />
use - the HyperBranch Medical Technology<br />
Story. M. Grinstaff<br />
11:00 19. Marine adhesive proteins and biologically<br />
inspired polymer mimics: Potential<br />
clinical applications.<br />
P. B. Messersmith<br />
11:30 20. Polymeric tissue sealants for surgical<br />
applications: The Cohera Medical<br />
story. E. J. Beckman<br />
‡ Cooperative Cosponsorship<br />
110–TECH<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
New Catalysis in Polymer Synthesis<br />
L. Jia, Organizer<br />
G. Coates, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 21. New catalytic/initiating systems for<br />
ATRP. K. Matyjaszewski<br />
9:00 22. Catalytic copolymerization of ethylene<br />
with polar comonomers: Toward amphiphilic<br />
polyethylenes. J. Daigle,<br />
L. Piche, A. Arnold, J. P. Claverie<br />
9:25 23. Advanced catalysis in metal-catalyzed<br />
living radical polymerization: High<br />
catalytic activity for functional monomers<br />
and rising active iron catalysts. M. Ouchi,<br />
M. Sawamoto<br />
9:50 24. 1,3-Bis(2-pyridylimino)isoindolatocobalt(II)<br />
and ruthenium(II) complexes as<br />
mediators for radical polymerizations of<br />
acrylates and styrene. L. H. Gade<br />
10:15 POLY/PMSE Poster Session and Intermission<br />
10:45 25. Functional group tolerant polymerization<br />
catalysis. A. Berkefeld,<br />
D. Guironnet, B. Neuwald, P. Roesle,<br />
P. Wucher, T. Ruenzi,<br />
I. Goettker-Schnetmann, S. Mecking<br />
11:10 26. Synthesis of comb block copolymers<br />
with molecular weights in the millions<br />
and their assembly in the solid state.<br />
J. Yoo, M. B. Runge, N. B. Bowden<br />
11:35 27. Scalable production of end-group<br />
functionalized precision polyolefins via<br />
living coordinative chain transfer polymerization<br />
of ethene and �-olefins.<br />
J. Wei, R. Wickham, L. R. Sita<br />
12:00 28. Copolymerization of olefins with<br />
polar vinyl monomers. R. F. Jordan<br />
Section E<br />
Westin Boston Waterfront<br />
Grand Ballroom B<br />
General Topics in the Design and Synthesis<br />
of Polymers<br />
D. Garcia, Organizer<br />
I. Gorman, Presiding<br />
8:30 29. Isoconversional kinetic analysis of a<br />
novel triazole resin system for low-temperature-cure.<br />
I. E. Gorman, R. L. Willer,<br />
R. F. Storey<br />
8:50 30. Microwave-assisted MADIX/RAFT<br />
polymerization of acrylamido and vinyl<br />
ester monomers. D. Roy, A. Ullah,<br />
B. S. Sumerlin<br />
9:10 31. Synthesis of novel polymer/urea<br />
peptoid conjugates using RAFT polymerization.<br />
N. Ayres,X.Chen<br />
9:30 32. Unique thermo-induced sequential<br />
gel-sol-gel transition of responsive<br />
multiblock copolymer-based hydrogels.<br />
J. Hu, Z. Ge, Y. Zhou, Y. Zhang, S. Liu<br />
9:50 33. Synthesis of cyclohexylene ring<br />
containing semi-crystalline poly(arylene<br />
ether sulfones) (PAES). B. Zhang,<br />
S. Turner<br />
10:10 34. Investigations on different verdazyl<br />
derivatives for a controlled living<br />
radical polymerization. G. Rayner,<br />
D. M. Haddleton<br />
10:30 35. Synthesis and characterization of<br />
copolyesters containing triptycene units.<br />
Y. Liu, S. Turner<br />
10:50 36. Hydroxy-functional polysilanes by<br />
an acetal protecting group strategy.<br />
V. S. Reuss, H. Frey<br />
11:10 37. PEG-Copolymers with orthogonal<br />
terminal and in-chain functionalities.<br />
C. Mangold, F. R. Wurm, B. Obermeier,<br />
H. Frey<br />
11:30 38. Donor-acceptor polymers incorporating<br />
alkylated dithienyl benzothiadiazole.<br />
H. Zhou, L. Yang, W. You<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
General Topics in the Design and Synthesis<br />
of Polymers<br />
D. Garcia, Organizer<br />
9:30–11:00<br />
39. Optically transparent sulfur-containing<br />
semi-alicyclic polyimide with high refractive<br />
index. Y. Nakagawa,T.Ogura,<br />
T. Higashihara, M. Ueda<br />
40. Polymer electrolyte membranes based<br />
on cross-linked highly sulfonated<br />
multiblock copoly(ether sulfone)s.<br />
K. Nakabayashi, T. Higashihara,<br />
M. Ueda<br />
41. Solution processable oligo(phenylene<br />
thiophene) grafted polymethacrylate:<br />
New material design and synthesis for organic<br />
field effect transistor application.<br />
Z. Hu, E. Reichmanis<br />
42. Synthesis of poly(m-phenyleneisophthalamide)<br />
by direct polycondensation of<br />
isophthalic acid with m-phenylenediamine.<br />
C. Zhang, Y. Shoji,<br />
T. Higashihara, M. Ueda<br />
43. Synthesis of soluble polyacetylene derivatives<br />
by controlled radical polymerization.<br />
K. Luo, J. Rzayev<br />
44. Synthesis of novel polymer/urea peptoid<br />
conjugates using RAFT polymerization.<br />
X. Chen, N. Ayres<br />
45. Novel copolymers of some ring-substituted<br />
2-phenyl-1,1-dicyanoethylenes with<br />
4-fluorostyrene. G. B. Kharas, B. L. Hill,<br />
K. T. Flynn, N. H. Bajaj, Y. Bittar,<br />
M. R. Dow, S. Moloney, T. A. Nguyen,<br />
S. A. Pitts, C. A. Serret, J. Valadez,<br />
A. C. Vallejo<br />
46. Synthesis and cyclopolymerization of divinyl<br />
derivatives of �-amino-�-caprolactam.<br />
H. Tas, L. J. Mathias<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
New Catalysts in Polymer Synthesis<br />
G. Coates, L. Jia, Organizers<br />
9:30–11:00<br />
47. Effect of the branched xylene bridge of<br />
dinuclear constrained geometry catalysts<br />
on their catalytic performance in ethylene<br />
and styrene copolymerization.<br />
N. Thi Le Thanh, N. Thi Le Nhon,<br />
N. Thi Dieu Huyen, W. Lyoo, S. Noh<br />
48. Group transfer polymerization of N,Ndimethylacrylamide<br />
promoted by super<br />
Brønsted acid as an organocatalyst.<br />
K. Fuchise,A.Narumi,R.Sakai,<br />
T. Satoh, S. Kawaguchi, T. Kakuchi<br />
49. Biomimetic hematin catalyst for the synthesis<br />
of conductive polypyrrole in micellar<br />
nanoreactors. S. Ravichandran,<br />
A. Kokil, S. Nagarajan, J. Kumar,<br />
R. Nagarajan<br />
50. Anionic polymerization with monomer<br />
activation: Synthesis of homo and copolymer<br />
based on epichlorohydrin.<br />
S. Doutaz, A. Deffieux<br />
51. Enzymatic ring-opening polymerization in<br />
a continuous-flow system.<br />
J. H. Wosnick, S. Faucher, L. Pereira<br />
52. Investigation of steric and electronic factors<br />
in palladium aryl sulfonate phosphine<br />
ethylene polymerization catalysts.<br />
L. Piche, J. Daigle, R. Poli, J. Claverie<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
Polymers for Immunology and<br />
Immunotherapy<br />
D. Irvine, S. Little, Organizers<br />
9:30–11:00<br />
53. Cytosolic delivery mediated via electrostatic<br />
surface binding of mRNA to degradable<br />
lipid-coated polymeric nanoparticles.<br />
X. Su, D. Kavanagh, D. J. Irvine<br />
54. Transcutaneous delivery of plasmid DNA<br />
and degradable polymer nanoparticles<br />
from multilayer-coated microneedle arrays.<br />
P. C. DeMuth, P. T. Hammond,<br />
D. J. Irvine<br />
55. Micro-patterning of T cell-antigen presenting<br />
cell pair arrays for high-throughput<br />
study of immunological synapses.<br />
H. Jung, M. Kim, J. Choi, J. S. Katz,<br />
M. Kim, J. Doh<br />
56. Assessment of multicellular T-T interactions<br />
using cell-laden PEG-hydrogel microwells.<br />
M. Kim, M. F. Krummel, J. Doh<br />
57. Synthesis and characterization of lipidcoated<br />
micro- and nano-particles co-displaying<br />
antigen and adjuvant as dosesparing<br />
vaccine delivery vehicles.<br />
A. Bershteyn, D. J. Irvine<br />
58. Calcium-alginate hydrogels as a calcium<br />
source for immunomodulation. G. Chan,<br />
D. Mooney<br />
59. Relationship of vaccine efficacy to the kinetics<br />
of DC and T cell responses induced<br />
by PLG-based vaccines. O. Ali,<br />
E. Doherty, D. J. Mooney, D. Emerich<br />
60. Programming dendritic cells in situ for<br />
tolerogenic immunotherapy. R. Sands,<br />
C. Verbeke, E. Silva, T. Kawai, D. Mooney<br />
61. Synthesis and characterization of antibody-nanoparticle<br />
conjugates for locally<br />
sequestered tumor immunotherapy.<br />
B. Kwong, D. J. Irvine<br />
62. Surface functionalization of lymphocytes<br />
as chemotherapeutic controlled release<br />
carriers. B. Huang, D. J. Irvine<br />
63. Guided migration of T cells on nanoscale<br />
ridge/groove patterned surfaces.<br />
K. Kwon, W. Jeong, J. Choi, K. Song,<br />
K. Suh, J. Doh<br />
Section F<br />
Westin Boston Waterfront<br />
Webster<br />
Memorial Symposium in Honor of H. Benoit:<br />
Scattering and Soft Matter Characterization<br />
R. Borsali, G. Hadziioannou, Organizers,<br />
Presiding<br />
1:45 Introductory Remarks by R. Borsali &<br />
G. Hadziioannou<br />
2:00 64. Polymer monolayer dynamics by<br />
capillary wave scattering. H. Yu<br />
2:30 65. Conformations and dynamics of<br />
ring and linear polymer melts from molecular<br />
dynamics simulations. D. Y. Yoon,<br />
C. Jeong, K. Hur, S. Y. Reigh,<br />
R. G. Winkler, N. Lacevic, R. H. Gee<br />
3:00 POLY/PMSE Poster Session and Intermission<br />
4:00 66. Application of random phase approximation<br />
for scattering in crosslinked<br />
polymers. W. Wu<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
4:30 67. Self assembling branched macromolecular<br />
materials based on poly(styrene-b-isoprene)<br />
macromonomers.<br />
H. Harris, K. Fischer, M. Schmidt,<br />
P. J. Lutz<br />
AkzoNobel Award in Outstanding Graduate<br />
Research in Polymer Chemistry in Honor of<br />
Haifeng Gao Sponsored by PMSE,<br />
Cosponsored by POLY<br />
SUNDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Polymers for Immunology and<br />
Immunotherapy<br />
Immunomodulation for Therapy and the<br />
Host Response to Polymeric Biomaterials<br />
D. Irvine, S. Little, Organizers, Presiding<br />
1:30 68. Polymers for immunology and immunotherapy.<br />
W. Saltzman<br />
2:00 69. Immunomodulatory biomaterials.<br />
J. E. Babensee<br />
2:30 70. Investigating the effects of anti-inflammatory<br />
drugs on material biocompatibility<br />
by in vivo fluorescent imaging.<br />
T. Dang, K. M. Bratlie, S. R. Bogatyrev,<br />
X. Y. Chen, D. Chhabra, R. Langer,<br />
D. G. Anderson<br />
2:50 POLY/PMSE Poster Session and Intermission<br />
3:20 71. In vivo assembly of endothelialized<br />
modules in allogeneic animals for tissue<br />
engineering. R. Gupta,<br />
M. D. Chamberlain, M. V. Sefton<br />
3:50 72. Rationally designed biomimetic delivery<br />
system for immunosuppression.<br />
S. R. Little, S. N. Rothstein,<br />
S. Jhunjhunwala<br />
4:20 73. In vivo fluorescence imaging of cathepsin<br />
and macrophage activity for determining<br />
biocompatibility of a chemically<br />
modified alginate library. K. Bratlie,<br />
T. Dang, A. Vegas, T. Vietti, S. Lyle,<br />
R. Langer, D. Anderson<br />
4:40 74. Novel cationic polymer coatings to<br />
regulate foreign body responses. M. Ma,<br />
W. F. Liu, R. Langer, D. G. Anderson<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Medical Applications of Polymers<br />
Panel Discussion on Academic<br />
Entrepreneurship<br />
T. Jozefiak, N. Washburn, Organizers,<br />
Presiding<br />
1:30 75. Gels in biology. G. M. Whitesides,<br />
R. Derda, A. Laromaine<br />
2:00 76. Clinical biomaterials and the faculty<br />
entrepreneur. G. Prestwich<br />
2:30 POLY/PMSE Poster Session and Intermission<br />
3:00 Panel Discussion on Academic Entrepreneurship:<br />
Intellectual Property,<br />
D. Herritt<br />
3:20 Panel Discussion on Academic Entrepreneurship:<br />
Out-Licensing to Pharma/<br />
Biotech B. Pratt<br />
3:40 Panel Discussion on Academic Entrepreneurship:<br />
Government Funding<br />
Sources. A. Kurtz<br />
4:00 Panel Discussion on Academic Entrepreneurship:<br />
VC Funding Sources.<br />
K. Bitterman<br />
4:20 Panel Discussion on Academic Entrepreneurship:<br />
Regulatory Issues.<br />
S. Koepke<br />
4:40 Panel Discussion<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
New Catalysis in Polymer Synthesis<br />
L. Jia, Organizer<br />
G. Coates, Organizer, Presiding<br />
1:30 77. Designed center-surface and center-center<br />
cooperative effects in the catalytic<br />
syntheses of new polymer architectures.<br />
T. Marks<br />
1:55 78. Controlling the architecture and<br />
functionality of heterogeneous polymerizations<br />
with renewable monoterpenes.<br />
R. T. Mathers, J. M. Delancey,<br />
M. D. Cavazza<br />
2:20 79. New palladium-based catalytic system<br />
for nearly alternating ethene/norbornene<br />
copolymerization with living<br />
characteristics. Y. Chen, A. Sen<br />
2:45 POLY/PMSE Poster Session and Intermission<br />
3:15 80. New octahedral catalysts for the<br />
isoselective polymerization of 1-hexene<br />
and propylene. M. Kol<br />
3:40 81. Recent advances in olefin block copolymers:<br />
Polydispersity, phase behavior,<br />
and photonic polyethylene. P. D. Hustad,<br />
J. D. Weinhold, B. G. Landes,<br />
P. L. Roberts, E. Garcia-Meitin,<br />
G. R. Marchand<br />
4:05 82. Orthogonal control of butyl and<br />
long branching in linear low density polyethylene<br />
through tandem catalysis.<br />
E. D. Schwerdtfeger, C. J. Price, J. Chai,<br />
S. A. Miller<br />
4:30 83. Latent ruthenium (II)-based photocatalysts<br />
for ring-opening metathesis polymerization.<br />
M. R. Buchmeiser,<br />
D. Wang, U. Decker, C. Kühnel<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
From Molecules to Macromolecules:<br />
Towards Self-Assembling Materials<br />
C. Tang, J. Lavigne, P. Iovine, Organizers<br />
M. Bockstaller, Presiding<br />
1:30 84. Functional nanostructures from the<br />
self-assembly of metal-containing block<br />
copolymers. I. Manners, G. R. Whittell<br />
2:00 85. Supramolecular polymers from<br />
�-amino-�-caprolactam, a bio-based material.<br />
E. Tarkin-Tas, L. J. Mathias<br />
2:20 86. Side-chain cobalticinium polymers:<br />
A new class of organometallic polymers.<br />
L. Ren, C. G. Hardy, D. Doxie, C. Tang<br />
2:40 87. Macromolecular assemblies of organoboron<br />
block copolymers.<br />
J. N. Cambre, D. Roy, A. P. Bapat,<br />
B. S. Sumerlin<br />
3:10 POLY/PMSE Poster Session and Intermission<br />
3:40 88. Interfacing micro with nano: The<br />
role and potential of biomolecular architectures.<br />
A. M. Hung, J. N. Cha<br />
4:10 89. Toward cucurbit[8]uril-mediated<br />
supramolecular polymerizations in water.<br />
J. M. Zayed, O. A. Scherman<br />
4:30 90. Luminescent properties of boron<br />
complexes arising from polymer and molecular<br />
solid assemblies. G. Zhang, T. Liu,<br />
R. E. Evans, J. Lu, C. L. Fraser<br />
5:00 Concluding Remarks<br />
Section E<br />
Westin Boston Waterfront<br />
Grand Ballroom B<br />
General Topics in the Characterization of<br />
Polymers<br />
D. Garcia, Organizer<br />
W. Feng, Presiding<br />
1:30 91. Multi-technique investigation of<br />
electrodeposited polythiophene films.<br />
W. Feng, D. D. Mastrogiovanni,<br />
A. S. Wan, L. S. Wielunski, E. Garfunkel<br />
1:55 92. Synthesis and multi-detector GPC<br />
characterization of PMMA star polymers.<br />
J. A. Burns, D. M. Haddleton<br />
2:20 93. Attofarad capacitance measurement<br />
on organic thin films with scanning<br />
microwave microscopy. S. Wu,J.Yu<br />
2:45 Poly/PMSE Poster Session and Intermission<br />
3:30 94. Evolution of microstructure during<br />
strain recovery of a shape memory liquid<br />
crystalline elastomer. K. A. Burke,<br />
P. T. Mather<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
From Molecules to Macromolecules:<br />
Towards Self-Assembling Materials<br />
Cosponsored by PMSE ‡<br />
P. Iovine, C. Tang, J. Lavigne, Organizers<br />
2:30–4:00<br />
95. Guided organization of �-DNAs into microring-arrays<br />
from liquid capillary microbridges.<br />
M. Byun, S. Hong, J. Cho, Z. Lin<br />
96. Triply-responsive organoboron block copolymers.<br />
D. Roy,J.N.Cambre,<br />
B. S. Sumerlin<br />
97. Strong silica aerogels crosslinked with<br />
polynorbornene via ring opening metathesis<br />
polymerization (ROMP).<br />
D. Mohite, Z. Larimore, N. Leventis,<br />
C. Sotiriou-Leventis<br />
98. Amphiphilic block copolymer micellesbased<br />
multifunctional ratiometric fluorescent<br />
chemosensor for Hg(II) ions and pH.<br />
J. Hu, S. Liu<br />
99. Organic single-crystal Schottky solar<br />
cells. J. Lim, S. Ferdous, A. L. Briseno<br />
100. Observation of reversible block copolymer<br />
micellization by NMR relaxation.<br />
G. M. Wilmes,D.J.Arnold,<br />
K. S. Kawchak<br />
101. Preparation and characterization of<br />
temperature-responsive amphiphilic<br />
poly(vinylacetate)-b-poly(n-isopropylacrylamide)<br />
diblock copolymer micelles.<br />
E. Helvacioglu, C. Ozguc, S. Sen,<br />
N. Nugay, T. Nugay<br />
102. Electronic properties of substituted anthradithiophene<br />
derivatives. F. Liu,<br />
A. L. Briseno<br />
103. Photon gate transistors based on tetrasubstituted<br />
pyrene starburst semiconductors.<br />
J. Timmons, F. Liu,<br />
A. L. Briseno<br />
104. Synthesis and characterization of supramolecular<br />
polymer networks via ionic<br />
interactions. X. Lin, M. Wathier, B. Suki,<br />
M. W. Grinstaff<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
Medical Applications of Polymers<br />
N. Washburn, T. Jozefiak, Organizers<br />
2:30–4:00<br />
105. Cell attachment materials for combination<br />
of RGDS and �-strand peptide.<br />
M. Wada, M. Yamamoto, Y. Tabata,<br />
Y. Hirano<br />
106. Designing composite gels combining<br />
rigid rod and random coil polymer architecture.<br />
P. D. Hamilton, H. Du, N. Ravi<br />
107. Attachment of �-sheet peptides to<br />
modify the rheological properties of hyaluronic<br />
acid. A. N. Elder,N.M.Dangelo,<br />
S. C. Kim, N. R. Washburn<br />
108. Synthesis of sterically stabilized hyaluronic<br />
acid microspheres for use as antibody<br />
delivery vehicles. J. E. Prata,<br />
T. A. Barth, N. R. Washburn<br />
109. Slow-Degrading salicylate-based poly-<br />
(anhydride ester) microspheres for undelayed<br />
and sustained drug delivery.<br />
R. Rosario-Meléndez,K.E.Uhrich<br />
110. Oligoethyleneimine-functionalized<br />
nanoscale amphiphilic macromolecules<br />
for intracellular delivery of nucleic acids.<br />
S. M. Sparks, C. L. Waite, A. M. Harmon,<br />
C. M. Roth, K. E. Uhrich<br />
111. Salicylate-based poly(anhydride-esters):<br />
A dual system for the delivery of fibroblast<br />
growth factor-2 and the suppression<br />
of inflammation.<br />
R. L. Delgado-Rivera<br />
112. Polymeric chloroquine derivatives for<br />
nonviral gene delivery. H. Liu,<br />
C. M. Jewell, D. J. Irvine<br />
113. Inhibition of in vivo lung tumor growth<br />
by prolonged local delivery of hydroxycamptothecin<br />
using poly(ester-carbonate).<br />
S. T. Yohe, J. A. Kaplan,<br />
J. A. Wolinksy, R. Liu, J. Walpole,<br />
L. R. Chirieac, Y. L. Colson,<br />
M. W. Grinstaff<br />
114. Dual functional polyelectrolyte multilayer<br />
(PEM) film: Microbicidal and anti-inflammatory<br />
drug releasing. S. Wong,<br />
J. Veselinovic, R. A. Rosario,<br />
K. Timachova, A. M. Klibanov,<br />
P. T. Hammond<br />
115. Synthesis of biocompatible caprolactone<br />
based polyurethanes and their use<br />
in the manufacturing of scaffolds for tissue<br />
engineering applications. R. E. Solís,<br />
J. San Román<br />
116. Porous tissue engineering scaffolds by<br />
solvent extraction for sol-gel polymerization.<br />
H. W. Lippincott, D. Schmidt<br />
MONDAY MORNING<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
New Catalysis in Polymer Synthesis<br />
L. Jia, Organizer<br />
G. Coates, Organizer, Presiding<br />
8:00 117. New catalytic strategies for monomer<br />
and polymer synthesis.<br />
R. M. Waymouth, J. L. Hedrick,<br />
M. K. Kiesewetter, E. T. Kiesewetter,<br />
K. Son<br />
8:25 118. Silylium-catalyzed polymerization<br />
of naturally renewable butyrolactonebased<br />
vinyl monomers. G. M. Miyake,<br />
Y. Zhang, E. Y. Chen<br />
8:50 119. Polymerization catalysis towards<br />
poly(�-peptoid)s. D. Zhang,L.Guo<br />
9:15 120. Stereoselective Group 4 initiators<br />
for the one-pot synthesis of multiblock<br />
stereocomplexed polylactides.<br />
M. G. Davidson, S. D. Bull, T. R. Forder,<br />
M. D. Jones, C. J. Frankis<br />
9:40 POLY/PMSE Poster Session and Intermission<br />
10:10 121. Polymerization of �-lactones using<br />
molecular and supported rare-earth<br />
catalysts. C. M. Thomas, N. Ajellal,<br />
J. W. Kramer, G. W. Coates, R. M. Gauvin<br />
10:35 122. Supported catalyst and combinatory<br />
catalyst: Strategy for improving<br />
catalytic activity and product selectivity<br />
of carbon dioxide copolymer. Y. Dong,<br />
Z. Li, X. Wang,F.Wang<br />
11:00 123. Bimetallic catalysts for CO 2- cyclohexene<br />
oxide copolymerizations.<br />
C. K. Williams, M. R. Kember, A. J. White<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
POLY<br />
TECH–111
POLY <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
11:25 124. Asymmetric catalysts for helixsense<br />
selective carbodiimide polymerizations.<br />
B. M. Novak,<br />
J. Budhathoki-Uprety, J. B. Clark,<br />
J. D. Desousa, J. G. Kennemur,<br />
T. Hong-Zhi, G. Tian<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
From Molecules to Macromolecules:<br />
Towards Self-Assembling Materials<br />
J. Lavigne, P. Iovine, Organizers<br />
C. Tang, Organizer, Presiding<br />
8:25 Introductory Remarks<br />
8:30 125. Self-assembling bioactive materials.<br />
S. I. Stupp<br />
9:00 126. TEThER: A flexible mix and match<br />
system for protein-based biotemplating.<br />
A. P. Schoen, S. C. Heilshorn<br />
9:20 127. Hierarchically ordered structures<br />
enabled by evaporative self-assembly:<br />
From conjugated polymers, polymer<br />
blends to diblock copolymers. Z. Lin,<br />
M. Byun, W. Han<br />
9:50 POLY/PMSE Poster Session and Intermission<br />
10:20 128. Self-assembly with organoboron<br />
polymers. F. Jaekle<br />
10:50 129. Block molecular brushes in solution-state<br />
self-assembly: Nanoscopic<br />
precursors with increasing complexity.<br />
Z. Li, J. Ma, C. Cheng, K. L. Wooley<br />
11:10 130. Programming and regulating<br />
self-assembly processes of block copolymers<br />
towards the formation of anisotropic<br />
nanostructures. H. G. Boerner,<br />
H. Kuehnle<br />
11:30 131. From molecules to materials.<br />
C. Nuckolls<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Polymers for Immunology and<br />
Immunotherapy<br />
Polymeric Model Systems for Cellular<br />
Immunology, and Polymers for Vaccines<br />
and Immunotherapy<br />
S. Little, Organizer<br />
D. Irvine, Organizer, Presiding<br />
8:30 132. Dendritic cell motility in microfluidic<br />
chambers. D. A. Hammer,<br />
B. A. Ricart, C. A. Hunter, B. John<br />
9:00 133. Polymer-based micro/nano systems<br />
for the mechanistic study of T cell<br />
biology. J. Doh<br />
9:30 134. Target geometry recognition by<br />
macrophages. N. S. Doshi, S. Mitragotri<br />
9:50 POLY/PMSE Poster Session and Intermission<br />
10:20 135. Injectable cellular “Backpacks”<br />
lead to cell aggregate self-assembly.<br />
A. Swiston, J. Gilbert, D. Irvine,<br />
R. Cohen, M. Rubner<br />
10:40 136. Sterilization of PLG particles by<br />
g-irradiation does not impair their potency<br />
for vaccine delivery. S. Jain,<br />
P. Malyala, M. Pallaoro, M. Giuliani,<br />
H. Petersen, D. T. O’Hagan, M. Singh<br />
11:00 137. High-throughput screening and<br />
characterization of polymer nanoparticle<br />
adjuvants. L. K. Petersen, C. Sackett,<br />
M. Wannemuehler, B. Narasimhan<br />
‡ Cooperative Cosponsorship<br />
112–TECH<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Medical Applications of Polymers<br />
Controlled Delivery of Therapeutics and<br />
Imaging Agents<br />
N. Washburn, T. Jozefiak, Organizers<br />
S. Little, Presiding<br />
8:30 138. Nanostructured materials for potential<br />
biomedical applications prepared<br />
by controlled radical polymerization.<br />
K. Matyjaszewski<br />
9:00 139. Investigation of core-degradability<br />
of shell crosslinked nanoparticles toward<br />
controlled release of guest molecules.<br />
S. Samarajeewa, R. Shrestha, Y. Li,<br />
K. Shanmuganandamurthy, K. L. Wooley<br />
9:20 140. H-gemcitabine: An autocatalytic<br />
drug delivery vehicle for treating cancer.<br />
N. Murthy<br />
9:50 POLY/PMSE Poster Session and Intermission<br />
10:20 141. Multifunctional imaging nanocarriers<br />
for angiography and personalized<br />
medicine. R. Bellamkonda<br />
10:50 142. Engineering the surface of magnetic<br />
nanoparticles by adsorption of double<br />
hydrophilic block copolymers for biomedical<br />
application. S. Louguet,<br />
C. Schatz, R. Epherre, S. Mornet,<br />
E. Duguet, S. Lecommandoux<br />
11:10 143. Controlled protein release from<br />
aptamer-decorated hydrogels.<br />
B. Soontornworajit, J. Zhou, Y. Wang<br />
11:30 144. Preparation and characterization<br />
of encapsulated sirolimus in bioabsorbable<br />
particles. V. Davé, P. Twaddle,<br />
R. Kataria, N. Cowley, H. Cui, A. Nathan<br />
Section F<br />
Westin Boston Waterfront<br />
Webster<br />
Memorial Symposium in Honor of H. Benoit:<br />
Scattering and Soft Matter Characterization<br />
G. Hadziioannou, R. Borsali, Organizers<br />
R. Stein, Presiding<br />
8:30 145. Tribute to Professor Henri C. Benoît:<br />
Structure and dynamics of block copolymer<br />
micelles in oil. S. Choi,<br />
T. P. Lodge, F. Bates<br />
9:00 146. Temperature tunable micellization<br />
of polystyrene-block-poly(2-vinylpyridine)<br />
at Si–ionic liquid interface. H. Lu, D. Lee,<br />
T. P. Russell<br />
9:30 147. Macromolecular design of semiconductive<br />
polymers towards thermodynamically<br />
stable organic photovoltaic active<br />
materials and devices.<br />
G. Hadziioannou, H. CRAMAIL,<br />
E. Cloutet, C. Brochon, G. Fleury,<br />
L. Hirsh, L. Vignau, G. Wantz<br />
10:00 POLY/PMSE Poster Session and Intermission<br />
10:30 148. Hybrid glycopolymers self-assemblies.<br />
I. Otsuka, K. Aissou,<br />
S. Ortega-Murillo, C. Travelet, S. Halila,<br />
S. Fort, C. Rochas, R. Borsali<br />
11:00 149. Polymers for microelectronics.<br />
G. C. Willson<br />
11:30 150. Influence of macromolecular architecture<br />
on the micellization of block<br />
copolymers within homopolymer matrices.<br />
E. Pavlopoulou, K. Chrissopoulou,<br />
S. H. Anastasiadis, G. Portale, W. Bras,<br />
H. Iatrou, S. Pispas, N. Hadjichristidis<br />
Section E<br />
Westin Boston Waterfront<br />
Grand Ballroom B<br />
General Topics in the Characterization of<br />
Polymers<br />
D. Garcia, Organizer<br />
K. Kiick, Presiding<br />
9:00 151. Main-chain liquid crystalline elastomers<br />
as shape memory polymers.<br />
K. A. Burke, P. T. Mather<br />
9:25 152. Characterization of water dynamics<br />
and membrane interactions in midblock-sulfonated<br />
triblock copolymers using<br />
2 H NMR spectroscopy.<br />
S. K. McIntyre,T.M.Alam,H.D.Moore,<br />
T. Saito, M. A. Hickner<br />
9:50 153. Effect of morphology and crystallinity<br />
on enzymatic degradation of poly(ecaprolactone).<br />
N. Vasanthan,<br />
G. Sekosan<br />
10:15 POLY/PMSE Poster Session and Intermission<br />
11:00 154. Structure, composition, and free<br />
polymer content of polymer-grafted<br />
nanoparticles by size exclusion chromatography.<br />
M. N. Tchoul, H. Dong,<br />
J. Pietrasik, W. Chaładaj,<br />
K. Matyjaszewski, R. A. Vaia, J. Jurczak<br />
11:25 155. Eelectrospun syndiotactic polystyrene<br />
fibers: Solvent-induced crystallization.<br />
Y. Cheng, C. Wang<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
From Molecules to Macromolecules:<br />
Towards Self Assembling Materials<br />
C. Tang, J. Lavigne, P. Iovine, Organizers<br />
9:30–11:00<br />
156. Synthesis and well-controlled polymerization<br />
of side-chain ferrocene acrylate<br />
polymers using atom transfer radical polymerization.<br />
C. G. Hardy,<br />
T. C. Tamboue, L. Ren, C. Tang<br />
157. Controlled polymerization of rosin-derived<br />
monomers: A new class of renewable<br />
polymers. Y. Zheng, K. Yao,<br />
D. Chandler, S. Lee, C. Tang,J.Wang,<br />
C. Wang, F. Chu<br />
158. Dansyl substituted poly(acrylate)s: Synthesis,<br />
host-guest complexation, and viscosity<br />
study at molecular and macroscopic<br />
levels. D. Pham,J.Wang,<br />
T. W. Kee, X. Guo, P. Clements,<br />
S. F. Lincoln, R. K. Prud’homme<br />
159. Synthesis and self-assembly of AB 2and<br />
ABC-type miktoarm star polymers.<br />
K. Khanna, R. Sharma, S. K. Varshney,<br />
A. Kakkar<br />
160. New morphologies prepared from stereocomplex<br />
of amphiphilic helical<br />
polypeptides. M. Ueda,A.Makino,<br />
T. Imai, J. Sugiyama, S. Kimura<br />
161. Synthesis of size controlled, functional<br />
hollow nanoparticles via photopolymerization<br />
and self-assembly of random copolymers.<br />
A. Honglawan,S.Yang,<br />
R. G Karunakaran<br />
162. Physical vapor transfer growth of organic<br />
single crystals for optoelectronic<br />
applications. F. Liu, S. Fakhouri,<br />
A. L. Briseno, M. Muthukumar<br />
163. Self-assembled “diamond like” structure<br />
of biodegradable block copolymers.<br />
B. Sannigrahi,K.P.Pemawansa,<br />
J. Doss, I. M. Khan<br />
164. Applications of a boronate ester coordination<br />
polymer for sensing and storing of<br />
benzene. J. E. Link,L.M.Lanni,<br />
J. Southwell, B. M. Rambo, J. J. Lavigne<br />
165. Reversible self-assembly of (2,5-bis(dodecyloxy)-1,4-phenylene)bis(ethyne-2,1diyl)diferrocene<br />
by H-� interaction: A<br />
physically linked ferrocene containing<br />
polymer. X. Chen,X.Bai,<br />
T. C. Sandreczki, J. R. Dias, L. Ouyang,<br />
Y. Liu<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
General Topics in the Characterization of<br />
Polymers<br />
D. Garcia, Organizer<br />
9:30–11:00<br />
166. MCR and image analysis integration<br />
with Raman spectral X,Y maps. D. Garcia<br />
167. Effect of water on gas permeability and<br />
viscoelasticity of perfluorinated and hydrocarbon<br />
type ionomer membranes at<br />
elevated temperature. A. Ohira,<br />
C. Kuroda, N. Takimoto<br />
168. Influence of teos hydrolysis products on<br />
the mechanical properties of solvent cast<br />
poly(methyl methacrylate) films.<br />
M. L. Ferguson, P. R. Watson<br />
169. New conjugated thiophene materials<br />
prepared from automers. A. Bolduc,<br />
Y. Dong, W. G. Skene<br />
170. EDOT and DAT comonomers for conjugated<br />
materials with tuneable photophysical<br />
properties. A. Bolduc,<br />
W. G. Skene<br />
171. Secondary structure transition in spider<br />
silk block copolymer monitored by thermal<br />
analysis and infrared spectroscopy.<br />
W. Huang, S. Krishnaji, X. Hu, D. Kaplan,<br />
P. Cebe<br />
172. New comb-shaped polystyrenes with<br />
syndiotactic backbones: Synthesis and<br />
structure. P. J. Lutz, M. Maaouni,<br />
J. Guenet, O. Gavat<br />
173. Determination of polyhedral oligomeric<br />
silsesquioxane (POSS) and nylon solubility<br />
parameters for predicting dispersion in<br />
polymer composites. R. D. Cook, Y. Wei,<br />
R. Misra, S. E. Morgan<br />
174. Surface modification of ground rubber<br />
tire with acrylic acid and its characterization.<br />
N. Tomar, S. Yagneswaran,<br />
D. Smith, J. R. Cellura<br />
175. Preparation and characterization of sulfonated<br />
Perfluorocyclobutyl (S-PFCB)<br />
membranes for hydrogen production.<br />
J. Park, N. Tomar, R. Jayasinghe,<br />
H. Colon-Mercado, M. Elvington,<br />
D. Hobbs, D. W. Smith<br />
176. Mesophase formation in poly(3-methyl-<br />
4-alkoxythiophene)s. D. Chalasani,<br />
B. L. Lucht, W. B. Euler<br />
177. Study on S/B multiblock copolymer<br />
synthesized by reactive extrusion structure<br />
characterization of the S/B copolymer<br />
and “bubble theory”. F. Hu, D. Wei,<br />
A. Zheng, W. Dai, X. Yuan<br />
178. Syntheses, characterization, and photophysical<br />
properties of new type of curcumin-containing<br />
hyperbranched polymer.<br />
H. Wang, Y. Wang, P. P. Lee,<br />
Y. Chen, C. Huang, J. H. Xin,<br />
K. K. Cheuk<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
MONDAY AFTERNOON<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Medical Applications of Polymers<br />
Polymer Drugs<br />
T. Jozefiak, N. Washburn, Organizers,<br />
Presiding<br />
1:30 179. Therapeutic polymers in medicine.<br />
S. R. Holmes-Farley<br />
2:00 180. Triggered release from and degradation<br />
of polymeric nanoparticles.<br />
A. Almutairi<br />
2:30 181. Synthesis, characterization, and<br />
biomedical assessment of pH-sensitive<br />
brush polymer-drug conjugates. J. Zou,<br />
G. Jafr, E. Themistou, Y. Yap,<br />
P. Alexandridis, A. C. Ceacareanu,<br />
C. Cheng<br />
2:50 POLY/PMSE Poster Session and Intermission<br />
3:20 182. Cytokine-neutralizing gels for local<br />
control of inflammation. N. Washburn,<br />
L. Sun, S. A. Bencherif<br />
3:40 183. Polymer conjugates use as single<br />
agents and combination therapy: A versatile<br />
“technology platform” for tissue repair<br />
and cancer therapy. M. J. Vicent<br />
4:10 184. Rational design of multifunctional<br />
polymer therapeutics for cancer theranostics.<br />
R. Satchi-Fainaro<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
New Catalysis in Polymer Synthesis<br />
L. Jia, Organizer<br />
G. Coates, Organizer, Presiding<br />
1:30 185. Catalyst-transfer condensation<br />
polymerization for precision synthesis of<br />
�-conjugated polymers and block copolymers.<br />
T. Yokozawa<br />
1:55 186. Toward the synthesis of endgroup<br />
functionalized regioregular poly(3alkylthiophene)s<br />
via the “living” Grignard<br />
Metathesis reaction. M. Jeffries-EL,<br />
D. L. Drochner<br />
2:20 POLY/PMSE Poster Session and Intermission<br />
3:00 187. Organocatalytic ring-opening polymerization<br />
of cyclic carbonates: Functional<br />
group diversity and application.<br />
J. L. Hedrick<br />
3:25 188. Controlled polymerizations of<br />
amino acid N-carboxyanhydrides by<br />
TMS-amine for the preparation of homo-,<br />
block- and brush-like polypeptides.<br />
H. Lu, J. Wang, Y. Lin, J. Cheng<br />
3:50 189. Combining catalytic ring-opening<br />
polymerizations for the preparation of<br />
functional hybrid macromolecules.<br />
M. Hillmyer<br />
4:15 190. High throughput techniques in catalysis.<br />
J. Yoder<br />
4:40 191. Carbonylative polymerization of<br />
heterocycles and heteroalkenes. L. Jia<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
From Molecules to Macromolecules:<br />
Towards Self-Assembling Materials<br />
C. Tang, J. Lavigne, P. Iovine, Organizers<br />
J. Tovar, Presiding<br />
1:30 192. DNA-Programmable assembly of<br />
colloidal crystals. C. A. Mirkin<br />
2:00 193. Directed mesoscale assembly of<br />
polymer nanostructures. J. M. Spruell,<br />
C. J. Hawker<br />
2:20 194. Crystallization in ordered polydisperse<br />
polyolefin diblock copolymers.<br />
S. Li, R. A. Register, B. G. Landes,<br />
P. D. Hustad, J. D. Weinhold<br />
2:40 195. Beyond the cage: Divergent assembly<br />
and electropolymerization of<br />
functionalized borasiloxanes. W. Liu,<br />
D. Lee<br />
3:10 POLY/PMSE Poster Session and Intermission<br />
3:40 196. Self-assembling macrocyclic bisureas.<br />
K. Roy, C. Wang, M. D. Smith,<br />
L. S. Shimizu<br />
4:10 197. Functional porous polymers and<br />
organic frameworks. J. Schmidt,<br />
A. Thomas, K. Thiel, C. Bleschke,<br />
S. Blechert, J. Weber<br />
4:30 198. Supramolecular copolymers.<br />
M. Weck<br />
5:00 Concluding Remarks<br />
Section E<br />
Westin Boston Waterfront<br />
Grand Ballroom B<br />
Nanoscience in Polymer Chemistry<br />
Synthesis Development<br />
D. Nelson, Organizer<br />
D. Heller, M. Roll, Presiding<br />
1:30 199. Synthesis of metal-coordination<br />
polymer nanoshells with variable size and<br />
shape. X. Wang<br />
1:50 200. Asymmetrically-functionalized<br />
nanoparticles with orthogonal clickable<br />
functionalities. S. Zhang,G.Sun,<br />
S. Samarajeewa, K. Wooley<br />
2:10 201. Synthesis of CaCO3 and BaCO3<br />
hollow nanospheres templated by polymeric<br />
micelles with core-shell-corona<br />
structure. K. Nakashima, B. Bastakoti,<br />
S. Guragain, Y. Yokoyama, S. Yusa<br />
2:30 202. Versatile approach of azido-terminated<br />
nanoparticles: Click chemistry<br />
functionalization. F. M. Collette,<br />
P. Bertrand, V. Héroguez<br />
2:50 Intermission and POLY/PMSE poster<br />
session<br />
3:20 203. All-organometallic cylindrical micelles<br />
from polyferrocenylsilane blockcopolymers.<br />
L. Chabanne, G. B. Joe,<br />
M. A. Winnik, I. Manners<br />
3:40 204. Synthesis and characterization of<br />
well-defined polylactide nanoparticles by<br />
thiol-ene reaction in miniemulsion.<br />
J. Zou, P. Alexandridis, C. Cheng<br />
4:00 205. Nanobuilding blocks via bromination<br />
of polyhedral phenylsilsesquioxanes.<br />
M. F. Roll, J. W. Kampf, P. Mathur,<br />
R. M. Laine<br />
4:20 206. Novel synthesis approaches to<br />
well-defined mesoporous silica/polymer<br />
composites. L. Cao, L. Huang,M.Kruk<br />
4:40 207. Fabrication of nitroaromatic sensing<br />
devices via initiated chemical vapor<br />
deposition. C. D. Petruczok, S. Yang,<br />
A. Asatekin, K. K. Gleason,<br />
G. Barbastathis<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Bioactive Polymers and Polymer Surfaces<br />
Bioactive Materials<br />
M. Grunlan, S. Lin-Gibson, Organizers<br />
O. T. Mefford, Organizer, Presiding<br />
2:00 208. Anisotropic colloids with controlled<br />
internal compartmentalization.<br />
J. Lahann<br />
2:30 209. Liquid-filled and hollow biodegradable<br />
capsules for biomedical applications.<br />
D. Lensen, D. M. Vriezema,<br />
J. C. van Hest<br />
2:50 210. Bonding of experimental polymeric<br />
ACP adhesives to human dentin.<br />
J. M. Antonucci, D. Skrtic<br />
3:10 POLY/PMSE Poster Session and Intermission<br />
3:50 211. Spontaneous formation of polymer-stabilized<br />
noble metal nanoparticles<br />
using catechol polymers. K. C. Black,<br />
Z. Liu, P. B. Messersmith<br />
4:20 212. Evaluating enzyme activity in polyfunctional<br />
polymer blends. P. Cipi,<br />
J. W. Rawlins<br />
4:40 213. Understanding structure-bioactivity<br />
relationship for Lanthanide containing<br />
polymers. S. S. Kelkar, K. Kizjakina,<br />
T. M. Reineke<br />
Section F<br />
Westin Boston Waterfront<br />
Webster<br />
Memorial Symposium in Honor of H. Benoit:<br />
Scattering and Soft Matter Characterization<br />
R. Borsali, G. Hadziioannou, Organizers,<br />
Presiding<br />
F. Bates, Presiding<br />
2:00 214. Polymeric bicontinuous microemulsions:<br />
Flexible templates for robust<br />
membranes. T. P. Lodge, B. H. Jones,<br />
B. Habersberger, F. S. Bates<br />
2:30 215. Phase behavior and coacervation<br />
of aqueous poly(acrylic acid)-poly(allylamine)<br />
solutions. M. Tirrell<br />
3:00 POLY/PMSE Poster Session and Intermission<br />
3:30 216. Interchain hydrogen-bonding and<br />
co-nonsolvency: Effect of polymers in<br />
aqueous or mixed aqueous solvents.<br />
C. C. Han,J.Hao,G.Yuan,H.Cheng<br />
4:00 217. Neutron scattering as an insight to<br />
polymer mixtures. J. S. Higgins,<br />
J. E. Lipson, R. P. White<br />
4:30 Tribute to H. Benoit and Closing Remarks.<br />
R. Pecora<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
From Molecules to Macromolecules:<br />
Toward Self Assembling Materials<br />
C. Tang, J. Lavigne, P. Iovine, Organizers<br />
2:30–4:00<br />
218. Hierarchically ordered structures enabled<br />
by evaporative self-assembly of<br />
confined comb block copolymer.<br />
M. Byun, N. B. Bowden, Z. Lin<br />
219. One-way shape memory properties of<br />
smectic A liquid crystalline elastomers<br />
triggered by dual transition temperatures.<br />
S. Ahn, P. Deshmukh, R. M. Kasi<br />
220. Modular synthesis of diblock copolymers<br />
for functional polymersomes.<br />
J. S. Katz, D. A. Hammer, J. A. Burdick<br />
221. New, low temperature, reversible photo-responsive<br />
liquid crystal polymer: Synthesis<br />
and testing. M. T. Petr,<br />
J. Soulages, B. Katzman, G. McKinley,<br />
P. T. Hammond<br />
222. Multicompartment/multigeometric micelles<br />
(MCM/MGM) from self-assembled<br />
diblock copolymer blend via kinetic control.<br />
J. Zhu, K. Zhang, Y. Lin, S. Zhang,<br />
K. Wooley, D. Pochan<br />
223. Bio-inspired polymer scaffolds from<br />
well-defined block copolymers of poly<br />
(glycidyl methacrylate) and poly (2-vinyl-<br />
4,4-dimethylazlactone). B. S. Lokitz,<br />
J. Messman, J. Hinestrosa, J. F. Ankner,<br />
S. M. Kilbey II<br />
224. Developing depsipeptides as biomimetic<br />
structures through secondary folding.<br />
M. Nguyen, M. Abdelmelek,<br />
J. Zhang, P. Ren, L. Suggs<br />
225. Nonlinear block polymers: Miktoarm<br />
star and linear-dendritic block polymers,<br />
and polymer-supported dendrimer synthesis.<br />
N. A. Lynd,J.N.Hunt,<br />
K. L. Killops, J. A. Chute,<br />
G. H. Fredrickson, E. J. Kramer,<br />
C. J. Hawker<br />
226. Photocurable polydiene-based block<br />
copolymers. V. F. Scalfani, T. S. Bailey<br />
227. Characterization of self-repairing boronate<br />
polymers. S. Daniel, J. J. Lavigne<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
Medical Applications of Polymers<br />
N. Washburn, T. Jozefiak, Organizers<br />
2:30–4:00<br />
228. In vitro PLGA degradation in the<br />
NEVO sirolimus-eluting stent formulation.<br />
M. L. Johnson, G. Papandreou,<br />
H. Li, C. A. Maryanoff<br />
229. Study on in vitro degradation behavior<br />
of polydioxanone films. M. Deng,<br />
K. Hristov, M. Mooney<br />
230. Wear and oxidation resistant UHMWPE<br />
with improved mechanical properties for<br />
total joint implants. J. Fu, E. Oral,<br />
O. K. Muratoglu<br />
231. Shape memory polymers with PDMS<br />
soft segments. D. Zhang,S.L.Prukop,<br />
M. L. Giese, M. A. Grunlan<br />
232. Novel combination of triblock copolymer<br />
and microfluidic technique for porous<br />
scaffold fabrication. M. Marimuthu,<br />
K. Kandasamy, S. Kim<br />
233. Morphological study of porous sirolimus-containing<br />
poly(lactide-co-glycolide)<br />
discs for biomedical applications.<br />
A. J. Ro, R. Falotico, V. Dave<br />
234. Coagulation-inducing polymer hydrogel<br />
for hemostatic application. B. J. Casey,<br />
A. M. Behrens, Z. I. Tsinas, W. E. Kelley,<br />
J. R. Hess, Z. J. Wu, B. P. Griffith,<br />
P. Kofinas<br />
235. Innovative biomaterial synthesis to minimize<br />
post-implant inflammatory response.<br />
M. Marimuthu, K. Kandasamy,<br />
S. Kim<br />
236. Poly(vinyl alcohol) hydrogel for postsurgical<br />
adhesion prevention. Y. Jiang,<br />
A. Schädlich, R. Schöps, K. Mäder,<br />
T. Naolou, J. Kressler<br />
237. Biocompatibility of novel polyisobutylene-based<br />
thermoplastic polyurethanes.<br />
D. Cozzens, U. Ojha, M. Ruths, R. Faust<br />
238. Impact of ionizing radiation on the<br />
physicochemical properties of novel<br />
polymer therapeutics. S. Bodnar,<br />
J. Griffin, L. Gu, F. Halperin,<br />
A. M. Harmon, I. Harper, B. A. Langowski,<br />
L. Lavelle, R. Rosario-Melendez,<br />
S. M. Sparks, K. E. Uhrich<br />
239. Highly impact resistant surface<br />
crosslinked UHMWPE for total joints.<br />
E. Oral, O. K. Muratoglu<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Scientist in Public Service, Energy, and<br />
Innovation Sponsored by CHED,<br />
Cosponsored by AGRO, ANYL, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY, and<br />
PRES<br />
Undergraduate Research Posters<br />
Polymer Chemistry Sponsored by CHED,<br />
Cosponsored by POLY and SOCED<br />
MONDAY EVENING<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
G. Tew, J. Linhardt, K. Kiick, Organizers<br />
8:00–10:00<br />
54, 55, 60, 107, 112, 114. See previous listings.<br />
337, 339, 342, 396. See subsequent listings.<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
POLY<br />
TECH–113
POLY <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
TUESDAY MORNING<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
From Molecules to Macromolecules:<br />
Towards Self-Assembling Materials<br />
C. Tang, J. Lavigne, Organizers<br />
P. Iovine, Organizer, Presiding<br />
8:25 Introductory Remarks<br />
8:30 240. Anion induced molecular self-assembly:<br />
A Texas-sized approach.<br />
H. Gong, B. M. Rambo, V. M. Lynch,<br />
E. Karnas, J. L. Sessler<br />
9:00 241. Quadruple hydrogen bonded<br />
telechelic supramolecular polymers.<br />
W. P. Appel, E. W. Meijer<br />
9:20 242. Effect of polymer grafting on the<br />
brittle-ductile transition in particle film assemblies.<br />
J. Choi, H. Dong,<br />
K. Matyjaszewski, M. R. Bockstaller<br />
9:50 POLY/PMSE Poster Session and Intermission<br />
10:20 243. Dissipative particle dynamic simulations<br />
of kinetics of block copolymer<br />
self-assembly. E. E. Dormidontova,Z.Li<br />
10:50 244. Mechano-responsive hydrogels<br />
with sacrificial bonds and hidden length.<br />
L. Xiao, C. Liu, X. Jia<br />
11:10 245. Tailoring nanostructure in highly<br />
elastic block copolymer-based hydrogel<br />
networks. C. Guo, T. S. Bailey<br />
11:30 246. Directing nanorod and nanosphere<br />
assembly in and on polymers.<br />
R. J. Composto<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Bioactive Polymers and Polymer Surfaces<br />
Materials for Drug Delivery and Tissue<br />
Engineering<br />
M. Grunlan, S. Lin-Gibson, Organizers<br />
O. T. Mefford, Organizer, Presiding<br />
8:30 247. Examining the intracellular trafficking<br />
mechanisms of glycopolymerbased<br />
DNA delivery vehicles.<br />
P. McLendon, K. Fichter, N. Ingle,<br />
T. M. Reineke<br />
9:00 248. Elastin mimetic, cell adhesive<br />
multiblock hybrid copolymers.<br />
S. E. Grieshaber, A. Farran, K. L. Kiick,<br />
X. Jia<br />
9:20 249. Creation of bioresorbable vascular<br />
prosthetics using electrospinning.<br />
K. Garg, G. L. Bowlin<br />
9:50 POLY/PMSE Poster Session and Intermission<br />
10:30 250. Surface and bulk properties of<br />
bis-phosphonate-modified natural polymers<br />
for bone regeneration. N. Pothayee,<br />
N. Pothayee, K. Sheets, A. Morgan,<br />
J. S. Riffle<br />
11:00 251. Cell penetrating peptide mimics<br />
prepared by ROMP. O. Tezgel,G.N.Tew<br />
11:20 252. Efficient synthesis of doxorubicin<br />
releasing brush polymers by graftthrough<br />
ROMP. J. A. Johnson,<br />
A. O. Burts, B. Lu, Y. Xia, D. A. Tirrell,<br />
R. H. Grubbs<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Medical Applications of Polymers<br />
Gels and Scaffolds<br />
T. Jozefiak, N. Washburn, Organizers,<br />
Presiding<br />
‡ Cooperative Cosponsorship<br />
114–TECH<br />
8:30 253. Structure and application of DNAsurfactant<br />
films for stem cell transfection.<br />
M. Tirrell<br />
9:00 254. Surface functionalized polymersomes<br />
for enhanced cell uptake and<br />
binding to biological targets.<br />
C. Bonduelle, A. Nazemi, R. Amos,<br />
E. Gillies<br />
9:20 255. Protein-engineered biomaterials:<br />
Translatable cell culture in 3 dimensions.<br />
N. H. Romano, S. C. Heilshorn<br />
9:50 256. Surface-modified electrospun fibers<br />
for the enhancement and control of<br />
neurite outgrowth. N. E. Zander,<br />
J. A. Orlicki, A. M. Rawlett, T. P. Beebe<br />
10:10 POLY/PMSE Poster Session and Intermission<br />
10:40 257. Ionic effects and self-assembly<br />
in the solution of the biopolymer aggrecan.<br />
F. Horkay<br />
11:10 258. Effect of macromer hydrophobicity<br />
and initiator chemistry on the free<br />
radical polymerization of PEG-diacrylate<br />
macromers. X. Dai, X. Chen, L. Yang,<br />
S. Foster, A. J. Coury, T. H. Jozefiak<br />
11:30 259. Cationic silicones for use in contact<br />
lens applications. J. K. Stanbro,<br />
D. Schorzman, J. F. Kunzler<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
Polymerizations and Polymer Modifications<br />
that Utilize Thiol-X Click Reactions<br />
Memorial to Charles Hoyle’s<br />
Photopolymerizations Research<br />
A. Lowe, H. Schlaad, Organizers<br />
C. Bowman, Organizer, Presiding<br />
A. Scranton, Presiding<br />
8:30 Introductory Remarks<br />
8:45 260. Cationic photopolymerization of<br />
systems pigmented with carbon black<br />
nanoparticles. A. B. Scranton,<br />
C. C. Hoppe, B. A. Ficek, H. Eom<br />
9:15 261. Functional polymers and polymerprotein<br />
conjugates prepared by RAFT<br />
and thiol-ene reactions. M. Li, H. Li,<br />
A. P. Bapat, P. De, B. S. Sumerlin<br />
9:45 POLY/PMSE Poster Session and Intermission<br />
10:15 262. Dual photo- and thermal cure of<br />
epoxy monomers. J. V. Crivello<br />
10:45 263. Surface engineering with thiolclick<br />
reactions. D. L. Patton,<br />
R. M. Hensarling, B. J. Sparks,<br />
S. B. Rahane, A. LeBlanc<br />
11:15 264. UV-photopolymerized thiol-ene<br />
networks for membrane CO 2 separation.<br />
L. Kwisnek, S. Nazarenko<br />
Section E<br />
Westin Boston Waterfront<br />
Grand Ballroom B<br />
Nanoscience in Polymer Chemistry<br />
Applications and Novel Structures<br />
D. Nelson, Organizer<br />
M. Levine, Presiding<br />
8:30 265. Efficient one-step synthesis of<br />
mechanically strong, flame retardant<br />
polyurea aerogels. N. Chandrasekaran,<br />
S. Mulik, Z. Larimore, G. Churu, H. Lu,<br />
C. Sortiriou-Leventis, N. Leventis<br />
8:50 266. Conjugated polymer nanoparticles<br />
as platforms for efficient energy transfer.<br />
M. Levine, C. Cordovilla, T. Swager<br />
9:10 267. Dispersion of multi-walled carbon<br />
nanotubes in an aqueous medium by water<br />
dispersible- conjugated polymer<br />
nanoparticles. B. Baykal, G. Er, E. Bengu,<br />
D. Tuncel<br />
9:30 Intermission and POLY/PMSE poster<br />
session<br />
10:00 268. Hybrid core@soft shell particles<br />
as adhesive elementary building blocks<br />
for colloidal crystals. C. Deleuze,<br />
M. Delville, V. Pellerin, C. Derail, L. Billon<br />
10:20 269. Synthesis and characterization<br />
via solid state NMR of novel POSS-polyurethane<br />
nanohybrid elastomers.<br />
J. P. Lewicki, B. P. Mayer,<br />
K. Pielichowski, B. Janowski,<br />
R. S. Maxwell<br />
10:40 270. Optimization of deposition conditions<br />
of titanium dioxide in block copolymer<br />
templates. Q. Lou,<br />
P. S. Chinthamanipeta, D. A. Shipp<br />
11:00 271. Synthesis of magnetic nanostructured<br />
polymers and effect of their<br />
morphologies. Y. Zha, R. Maddiker,<br />
T. P. Russell, G. N. Tew<br />
Section F<br />
Westin Boston Waterfront<br />
Webster<br />
Polymer Science and Energy: Current<br />
Directions and Future Opportunities<br />
Financially supported by Division of Polymeric<br />
Materials: Science & Engineering<br />
E. Coughlin, A. L. Briseno, Organizers,<br />
Presiding<br />
8:30 272. Light absorbing polymers for organic<br />
solar cells. I. McCulloch,<br />
M. Heeney, W. Zhang, S. Ashraf<br />
9:00 273. High performance tandem polymer<br />
solar cells. Y. Yang<br />
9:30 274. Organic photovoltaics: The path<br />
to higher performance. R. Gaudiana<br />
10:00 POLY/PMSE Poster Session and Intermission<br />
10:30 275. Routes for using polymers in<br />
photovoltaic applications. T. P. Russell<br />
11:00 276. Recent advances in polymers<br />
and small molecules for organic electronics.<br />
F. Wudl<br />
11:30 277. Organic and hybrid semiconductors<br />
for application in organic light emitting<br />
diodes (OLED) and photovoltaics<br />
(OPV). A. Sellinger<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
General Topics in the Design and Synthesis<br />
of Polymers<br />
D. Garcia, Organizer<br />
9:30–11:00<br />
278. Ring-opening polymerization of �-caprolactone<br />
initiated by yttrium triphenolate<br />
and glycols with �,�-or�,�-dihydroxyl<br />
groups. J. Ling, J. Liu, Z. Shen<br />
279. Studies of �-cyclodextrin cross-linked<br />
polymer as water treatment agent.<br />
Y. Jiang, L. Jing, M. Jia, J. Jiang,<br />
H. Zhang<br />
280. Microfluidic device for producing<br />
monodisperse polymersomes with precise<br />
control. M. A. Stredney,<br />
K. Y. Huang,D.H.Adamson<br />
281. Investigating carborane cages in conjugated<br />
polymers. J. J. Peterson,<br />
M. Werre, Y. C. Simon, E. B. Coughlin,<br />
K. R. Carter<br />
282. Studies on �-cyclodextrin star polymer<br />
using as inhibitor of urease. W. Zhang,<br />
S. Shao, X. Xu, T. Li, X. Fu<br />
283. Synthesis of poly(vinyl acetate)-b-polystyrene<br />
copolymers by a combination of<br />
cobalt-mediated radical polymerization<br />
and RAFT polymerization. H. Jeon,<br />
Y. Yoo, K. Lee, J. Park, B. Ki, J. Youk<br />
284. Polysiloxanes containing polyhedral oligomeric<br />
silsesquioxane groups in the<br />
side chains: Synthesis and properties.<br />
D. Kim, H. Ryu, T. Ko, J. Lee<br />
285. Novel antibacterial hydrogels with triple<br />
antibacterial mechanism. H. Zhang,<br />
A. Sen<br />
286. Synthesis of poly(di(ethylene glycol)<br />
methyl ether methacrylate) macromonomers<br />
and functionalization via click<br />
chemistry. G. Li, D. M. Haddleton<br />
287. Polymerization of vinyl acetate catalyzed<br />
by cyclometalated Ru(II) compounds.<br />
J. Olvera, L. Alexandrova,<br />
R. Le Lagadec<br />
288. Polymerization of �-benzyl-L-glutamate<br />
N-carboxyanhydride by rare earth metal<br />
tris(borohydride) complexes. H. Peng,<br />
J. Ling, Z. Shen<br />
289. Synthesis and characterization of amphiphilic<br />
block copolymers for polymerosomes.<br />
D. Singh, S. Heinhorst,<br />
G. C. Cannon, S. E. Morgan<br />
290. Further understanding of mechanism of<br />
anionic polymerization through bulk polymerization<br />
of styrene at high temperature.<br />
Y. Guan,Y.Zheng,D.Zhou,A. Zheng,<br />
H. Xiao<br />
291. Kinetic investigation of the anionic bulk<br />
polymerization of styrene at high temperature.<br />
A. Zheng,D.Wei,M. Liu,H.Xiao<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
Nanoscience in Polymer Chemistry<br />
D. Nelson, Organizer<br />
9:30–11:00<br />
292. Graphite nanoplatelet/epoxy composites:<br />
Functionalization, processing, and<br />
properties. D. H. Wang, L. Tan,Z.Wang,<br />
H. T. Hahn<br />
293. Switching endgroup polarity and grafting<br />
of hyperbranched polyetherketone to<br />
carbon nanofiber via an A2B monomer.<br />
D. H. Wang, L. Tan<br />
294. One-step polyimide aerogels from anhydrides<br />
and isocyanates.<br />
C. Chidambareswarapattar,<br />
C. Sotiriou-Leventis, N. Leventis<br />
295. Electrospun poly(lactide) nanofibers<br />
containing porphyrin additive. T. Xu,<br />
P. P. Lee, Z. Xue, Y. Chen, Y. Wang,<br />
H. Wang, C. Huang, J. H. Xin,<br />
K. K. Cheuk<br />
296. Dry sol-gel of p-X-C6H4SiH3 (X � H,<br />
CH3,CH3O, F, Cl) to organosilica p-X-<br />
C6H4SiO1.5 with Cp2Ni catalyst. M. Kim,<br />
J. Lee, H. Woo,K.Yang,M.Cho,Y.Ko,<br />
H. Li<br />
297. Synthesis and characterization of novolak<br />
phenolic resin layered silicate nanocomposite.<br />
S. Gang, S. Lee, I. Sung,<br />
C. Kim<br />
298. Bismaleimide reinforced silica aerogels<br />
via surface modification through incorporation<br />
of p-aminophenyltrimethoxysilane.<br />
S. L. Vivod, M. B. Meador, B. N. Nguyen<br />
299. Synthesis and characterization of functionalized<br />
graphene sheets by thermal<br />
exfoliation. A. J. Oyer,D.H.Adamson<br />
300. Fabrication of functional conductive<br />
nanofibers composed of �,�-bi-DNPpoly(2-methoxystyrene),<br />
polystyrene including<br />
single walled carbon nanotubes<br />
for studying material-cell interactions and<br />
gold nanoparticle/synthetic functional<br />
polymer nanofibers for nanobiosensors.<br />
O. Olubi, L. London, D. Gadi,<br />
B. Sannigrahi, M. Atteya, M. D. Williams,<br />
B. Baird, M. Maaza, I. Khan<br />
Design, Discovery, and Directed Evolution<br />
of Enzyme Activities Sponsored by BIOL,<br />
Cosponsored by COMP and POLY<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
TUESDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Bioactive Polymers and Polymer Surfaces<br />
Hydrogels for Tissue Engineering<br />
M. Grunlan, O. T. Mefford, Organizers<br />
S. Lin-Gibson, Organizer, Presiding<br />
1:30 301. Novel hydrogel networks utilizing<br />
self-assembly. G. N. Tew<br />
2:00 302. Self-assembling growth factor<br />
gradients in modular hydrogel scaffolds.<br />
D. L. Elbert, J. Roam, H. Xu, P. Nguyen<br />
2:30 303. Bioactive physical hydrogels for<br />
3D cell culture. B. Liu, W. Shen<br />
2:50 POLY/PMSE Poster Session and Intermission<br />
3:30 304. Engineering biopolymeric hydrogels<br />
for mechanically active tissues.<br />
K. L. Kiick<br />
4:00 305. PDMS star-PEG hydrogels for directed<br />
mesenchymal stem cell differentiation.<br />
D. J. Munoz-Pinto, C. Schoener,<br />
Y. Hou, M. Grunlan, M. S. Hahn<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Medical Applications of Polymers<br />
Interfaces and Combinatorial Methods<br />
N. Washburn, Organizer<br />
T. Jozefiak, Organizer, Presiding<br />
1:30 306. Combinatorial development of<br />
biomaterials for tissue engineering and<br />
drug delivery. D. G. Anderson<br />
2:00 307. Optimizing osteogenic signaling in<br />
mesenchymal stem cells using peptide<br />
derivatized materials. N. M. Moore,<br />
L. A. Smith, M. L. Becker<br />
2:30 308. Facile preparation of highly scattering<br />
metal nanopartical coated polymer<br />
microbeads for sensitive, in situ biomolecular<br />
detection and quantification in<br />
biomedical assays. J. C. Meredith,<br />
J. Lee, I. Gomez<br />
3:00 POLY/PMSE Poster Session and Intermission<br />
3:30 309. Polyelectrolyte multilayered implant<br />
coatings for the treatment of orthopedic<br />
device-associated infections.<br />
J. Moskowitz, M. Blaisse, R. Samuel,<br />
H. Hsu, M. Harris, S. Martin, J. Lee,<br />
M. Spector, P. Hammond<br />
4:00 310. Multi-functional coatings for metallic<br />
medical devices. Z. Song,<br />
T. Deisenroth<br />
4:20 311. Enhancing the performance of<br />
Bio-inspired adhesives. H. Chung,<br />
P. Glass, M. Sitti, N. R. Washburn<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
Polymerizations and Polymer Modifications<br />
that Utilize Thiol-X Click Reactions<br />
Memorial to Charles Hoyle’s Thiol-Ene<br />
Research<br />
A. Lowe, C. Bowman, H. Schlaad,<br />
Organizers<br />
A. Guymon, K. Anseth, Presiding<br />
1:30 312. Modeling cellular microenvironments<br />
using thiol-ene extracellular matrix<br />
mimics. B. D. Fairbanks, M. P. Schwartz,<br />
C. N. Bowman, M. Zaman, K. S. Anseth<br />
2:00 313. Applications of thiol-ene reactions<br />
in adhesives, sealants and coatings.<br />
J. Woods<br />
2:30 314. Thiol-X click chemistries: Scope<br />
and limitations of thiol-Michael, thiol-isocyanate,<br />
thiol-epoxide and thiol-halide reactions.<br />
A. Lowe<br />
3:00 POLY/PMSE Poster Session and Intermission<br />
3:30 315. Introduction to thiol-ene and thiolyne<br />
photopolymerizations.<br />
C. N. Bowman, B. D. Fairbanks,<br />
N. B. Cramer, K. S. Anseth<br />
4:00 316. Physical properties and photo-polymerization<br />
behavior of thiol-ene nanocomposites.<br />
K. Owusu-Adom,<br />
A. Guymon<br />
4:30 317. Thiol-Yne: A versatile tool for polymeric<br />
modification. J. W. Chan,<br />
C. E. Hoyle, A. B. Lowe<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
From Molecules to Macromolecules:<br />
Towards Self-Assembling Materials<br />
C. Tang, J. Lavigne, P. Iovine, Organizers<br />
L. Shimizu, Presiding<br />
1:30 318. Bioinspired synthesis of complex<br />
functional systems. V. Percec,<br />
B. M. Rosen<br />
2:00 319. Self-assembly of benzene-1,3,5tricarboxamides<br />
in polymeric systems.<br />
T. Mes, A. R. Palmans, E. W. Meijer<br />
2:20 320. Supramolecular polymer nanostructures<br />
derived from the amyloid-inspired<br />
self-assembly of optoelectronic<br />
peptides. S. R. Diegelmann, B. D. Wall,<br />
G. S. Vadehra, J. D. Tovar<br />
2:40 321. Nor-seco-cucurbit[n]uril molecular<br />
containers. W. Huang, P. Y. Zavalij,<br />
L. Isaacs<br />
3:10 POLY/PMSE Poster Session and Intermission<br />
3:40 322. Nanotubular assemblies of aromatic<br />
oligoamide crescents and macrocycles.<br />
B. Gong, J. Zhu, W. Feng,<br />
K. Yamato, J. Deng, L. Yuan<br />
4:10 323. Thermally induced morphology<br />
transitions for charged chain end diblock<br />
copolymers synthesized by RAFT.<br />
A. O. Moughton, J. P. Patterson,<br />
R. K. O’Reilly<br />
4:30 324. Using dynamic bonds to access<br />
stimuli-resposnive materials. S. J. Rowan<br />
5:00 Concluding Remarks<br />
Section E<br />
Westin Boston Waterfront<br />
Stone<br />
9th International Biorelated Polymers<br />
Symposium<br />
Biorelated Polymer Delivery Systems<br />
C. Scholz, T. Fujiwara, R. Ottenbrite,<br />
Organizers<br />
A. Coury, Presiding<br />
1:30 Introductory Remarks<br />
1:40 325. Introduction to biorelated polymers<br />
for bioapplications.<br />
R. M. Ottenbrite<br />
2:10 326. Novel synthetic DNA and RNAi<br />
delivery systems. K. Anwer, J. Sparks,<br />
M. Matar, J. Fewell<br />
2:40 POLY/PMSE Poster Session and Intermission<br />
3:10 327. In vitro performances of multi-arm<br />
PEGylated head-tail type polycations as<br />
nonviral gene vector. A. Harada,K.Kono<br />
3:35 328. Complexes of cationic cylindrical<br />
brushes and DNA: Physicochemical characterization<br />
and application in gene<br />
transfection. F. Kuehn, E. Pietrowski,<br />
K. Fischer, H. Luhmann, M. Schmidt<br />
4:00 329. Polyphosphazene as protein stabilizing<br />
and immunostimulating agent for<br />
microneedle vaccine delivery systems.<br />
D. P. DeCollibus, A. Marin,<br />
A. K. Andrianov<br />
4:25 330. In vivo tracking of endothelial progenitor<br />
cells transplanted to rat ischemia<br />
limbs by use of novel cell-labelling MRI<br />
contrast agent. C. A. Agudelo,<br />
Y. Tachibana, A. F. Hurtado,<br />
N. Teramoto, H. Iida, T. Yamaoka<br />
Section F<br />
Westin Boston Waterfront<br />
Webster<br />
Polymer Science and Energy: Current<br />
Directions and Future Opportunities<br />
E. Coughlin, A. L. Briseno, Organizers,<br />
Presiding<br />
1:30 331. Molecular understanding of the<br />
electronic and optical processes in organic<br />
solar cells: The challenges.<br />
J. Bredas<br />
2:00 332. Polymers and composites for efficient<br />
production storage and utilization of<br />
energy. P. J. Hotchkiss, A. Sharma,<br />
A. Haldi, W. J. Potscavage Jr., H. Li,<br />
P. B. Paramonov, S. A. Paniagua,<br />
S. C. Jones, B. Kippelen,<br />
N. R. Armstrong, J. Brédas, S. Barlow,<br />
P. Kim, J. W. Perry, S. R. Marder<br />
2:30 333. Structure-property relations in<br />
polymers for gas separations.<br />
B. D. Freeman, D. R. Paul, J. E. McGrath<br />
3:00 POLY/PMSE Poster Session and Intermission<br />
3:30 334. Polymer hydroxide exchange<br />
membranes for inexpensive fuel cells,<br />
wind/solar electricity storage, and solar<br />
fuel generation. Y. Yan<br />
4:00 335. Need for and the challenges of the<br />
perfect proton conducting polymer/composite.<br />
A. M. Herring<br />
4:30 336. Applications and future trends in<br />
polymer materials for green energy systems:<br />
From energy generation and storage,<br />
to CO 2 capture and transportation.<br />
E. J. Amis,G.S.Zafiris<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
Bioactive Polymers and Polymer Surfaces<br />
M. Grunlan, S. Lin-Gibson, O. T. Mefford,<br />
Organizers<br />
2:30–4:00<br />
337. Thermoresponsive nanocomposite<br />
double network hydrogels. R. Fei,<br />
J. T. George, M. A. Grunlan<br />
338. Characterization of the enzyme-retting<br />
flax fibers. Y. Tian<br />
339. Investigating the effect of the length of<br />
alkyl chain on the antibacterial and hemolytic<br />
activities of oligoguanidines. D. Wei,<br />
Y. Zhang, D. Zhou, Y. Guan, A. Zheng<br />
340. Multiblock copolymers of poly(acrylic<br />
acid-b-styrene) containing peptides as a<br />
drug delivery platform. A. C. Greene,<br />
X. Jia, K. L. Kiick<br />
341. Rapid and robust sealing of plastic-<br />
PDMS interface at room temperature for<br />
disposable Lab-on-a-Chip device.<br />
W. Wu, L. Tang, N. Lee<br />
342. Simultaneous light-induced core degradation<br />
and drug release from nanoscopic<br />
star polymers prepared by an arm-first<br />
ROMP approach. A. O. Burts,<br />
J. A. Johnson, R. H. Grubbs<br />
343. Antimicrobial polypeptides prepared by<br />
combining the ring opening polymerization<br />
of N-carboxyanhydrides and click<br />
chemistry. A. C. Engler, A. Shukla,<br />
H. G. Buss, P. T. Hammond<br />
344. pH responsive polypeptides for siRNA<br />
delivery. A. C. Engler, D. K. Bonner,<br />
H. G. Buss, P. T. Hammond<br />
345. Fine-tuning of surface morphology in<br />
block copolymer thin films. J. Lee,<br />
S. Kim, K. Lee, Y. Kwark<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
General Topics in the Design and Synthesis<br />
of Polymers<br />
D. Garcia, Organizer<br />
2:30–4:00<br />
346. Novel synthesis of isotactic polymer by<br />
free radical polymerization of cd substituted<br />
acrylate. H. Tanaka,M.Niwa,<br />
Y. Matsubara<br />
347. Polybenzoxazine-poly(2,5-benzimidazole)<br />
(PBOA�ABPBI) IPN membranes<br />
via a PPA Sol-Gel method for high-temperature<br />
PEM fuel cell applications.<br />
T. Ko, S. Kim, D. Kim, S. Choi, J. Park,<br />
H. Chang, J. Lee<br />
348. Synthesis and characterization of a<br />
phosphonated graft copolyimide.<br />
N. Srinate, S. Thongyai, P. Prasertham,<br />
R. Weiss<br />
349. Synthesis of symmetric and asymmetric<br />
polyimides containing benzonitrile groups<br />
for dielectric applications. D. Wang,<br />
J. K. Riley, S. P. Fillery, M. F. Durstock,<br />
R. A. Vaia, L. Tan<br />
350. Polymers from renewable and sustainable<br />
natural polyphenol: Use of curcumin<br />
and tetrahydrocurcumin in making polycarbonates,<br />
mixed-polycarbonates, and<br />
polymers having multiple bond types.<br />
F. Dasgupta<br />
351. Arm detachment and arm exchange reactions<br />
of star-like nanogels by dynamic<br />
covalent exchanges of alkoxyamine units.<br />
Y. Amamoto, M. Kikuchi, H. Otsuka,<br />
A. Takahara<br />
352. Solvent and temperature effect in the<br />
living ring opening e-caprolactone/<br />
Cp 2ZrHCl polymerization. A. D. Asandei,<br />
G. Saha, C. P. Simpson<br />
353. In situ generation of activators via<br />
monomer addition for atom transfer radical<br />
polymerization. Y. khan,D.He,<br />
X. Chen, S. K. Noh, W. S. Lyoo<br />
354. Synthetic DNA analogs: Synthesis and<br />
characterization of adenine oligomer.<br />
K. H. Bouhadir, K. M. Usher, L. Abramian<br />
355. Generation of activators via monomer<br />
addition(GAMA) ATRP of MMA using ruthenium(III)<br />
catalyst. X. Chen,D.He,<br />
M. Khan, S. Noh, W. Lyoo<br />
356. Synthesis of macrocyclic polystyrene<br />
using intramolecular atom transfer radical<br />
coupling. E. Tillman, A. Voter<br />
357. Effect of hexafluorobenzene on the<br />
ATRP of polystyrene. P. D. Pickett,<br />
E. S. Tillman<br />
WEDNESDAY MORNING<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Bioactive Polymers and Polymer Surfaces<br />
Hydrogels for Tissue Engineering<br />
M. Grunlan, O. T. Mefford, Organizers<br />
S. Lin-Gibson, Organizer, Presiding<br />
8:30 358. Designing peptide hydrogels for<br />
cellular encapsulation and delivery:<br />
Progress towards engineered cartilage.<br />
J. Schneider, C. Sinthuvanich<br />
9:00 359. Effect of 3D hydogel scaffold<br />
modulus and topology on human bone<br />
marrow stromal cell fate. K. Chatterjee,<br />
S. Lin-Gibson, S. H. Parekh, N. M. Moore,<br />
M. T. Cicerone, M. F. Young, C. G. Simon<br />
9:20 360. <strong>Chemical</strong> and physical patterning<br />
of poly(ethylene glycol) hydrogels in 2D<br />
and 3D via photodegradation.<br />
A. M. Kasko, D. Y. Wong, D. R. Griffin,<br />
J. T. Patterson, J. Reed<br />
9:50 POLY/PMSE Poster Session and Intermission<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
POLY<br />
TECH–115
POLY <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
10:30 361. Injectable, highly flexible and<br />
thermoresponsive hydrogels for mesenchymal<br />
stem cell proliferation and differentiation.<br />
Z. Li, J. Guan<br />
11:00 362. Photo-crosslinked PDMS star-<br />
PEG hydrogels: Fabrication and use as<br />
tissue engineering scaffolds. B. M. Bailey,<br />
Y. Hou, M. A. Grunlan<br />
11:20 363. Synthesis and characterization of<br />
novel photo-cross-linked hydrogels.<br />
M. A. Lackey, N. Sanabria-DeLong,<br />
A. J. Crosby, G. N. Tew<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Frontiers in Polymer Characterization<br />
Scattering and Conjugated Polymers<br />
D. Waldow, D. Nelson, T. Seery,<br />
Organizers<br />
M. Dadmun, Organizer, Presiding<br />
8:30 364. Characterizing nanopatterned surface<br />
using X-ray reflectivity and grazing<br />
incident X-ray scattering. H. Lee,<br />
C. L. Soles, H. Ro, W. Wu<br />
9:00 365. Using neutron scattering to determine<br />
conjugated polymer: Fullerene miscibility<br />
and interfacial structure. W. Yin,<br />
R. Hegde, N. Henry, K. Xiao, J. Browning,<br />
M. Dadmun<br />
9:30 366. Dynamics of conjugated polymers<br />
in solutions: Neutron spin echo and quasi<br />
elastic studies. D. Perahia<br />
10:00 Intermission and POLY/PMSE Poster<br />
Session<br />
10:45 367. Dynamic infra-red spectroscopy<br />
of conjugated polymers.<br />
G. Arbuckle-Keil, F. Weston<br />
11:05 368. Dynamic light scattering applied<br />
to solutions that absorb light. T. A. Seery,<br />
M. DeMesa, K. Moon<br />
11:35 369. Light scattering and atomic force<br />
microscopy: Characterization of compatibilized<br />
polymer blends at a primarily undergraduate<br />
institution. D. Waldow<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
Polymerizations and Polymer Modifications<br />
that Utilize Thiol-X Click Reactions<br />
Thiol-Ene Polymerization Reactions<br />
C. Bowman, H. Schlaad, Organizers<br />
A. Lowe, Organizer, Presiding<br />
A. Guymon, Presiding<br />
8:30 370. New material platforms for biological<br />
and pharmacological applications.<br />
E. Amir, P. Antoni, L. Campos, N. Gupta,<br />
D. Damiron, C. J. Hawker<br />
9:00 371. Clicking renewable resources:<br />
Thiol-ene additions for the synthesis of<br />
monomers and polymers derived from<br />
plant oils and terpenes. M. A. Meier,<br />
O. Türünc, L. Montero de Espinosa,<br />
M. Firdaus<br />
9:20 372. Effect of organoclay functional<br />
group on photopolymerization behavior<br />
and properties in thiol-ene systems.<br />
S. Kim,A.C.Guymon<br />
9:40 373. Polyanhydrides from thiol-ene polymerizations.<br />
B. G. Rutherglen,<br />
R. A. McBath, G. Liddil, Y. Huang,<br />
S. K. Zorn, K. A. Murphy, C. W. McQuinn,<br />
D. A. Shipp<br />
10:10 POLY/PMSE Poster Session and Intermission<br />
10:40 374. Thiol-ene chemistry for the synthesis<br />
and modification of branched organosilicon<br />
polymers. D. Son, C. Rissing,<br />
L. Chen, T. Andersson<br />
‡ Cooperative Cosponsorship<br />
116–TECH<br />
11:10 375. Reversible addition—fragmentation<br />
chain transfer for low stress thiolene/-yne<br />
networks. C. Kloxin, H. Park,<br />
T. Scott, C. N. Bowman<br />
11:30 376. Thiol-ene approaches to dendrimer<br />
synthesis. M. J. Robb, P. Antoni,<br />
L. M. Campos, M. I. Montanez,<br />
M. Malkoch, E. Malmstrom, C. J. Hawker<br />
11:50 377. Thiol-ene chemistry in miniemulsion:<br />
A new route towards 2-pack-in-1pot<br />
waterborne coatings? M. S. Ottink,<br />
R. A. Janssen, B. Klumperman<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
General Topics in the Design and Synthesis<br />
of Polymers<br />
D. Garcia, Organizer<br />
C. Lipscomb, Presiding<br />
8:30 378. Preparation of glycopolymers by<br />
CCTP and click chemistry. Y. Gou,<br />
D. M. Haddleton<br />
8:50 379. Mechanically linked polymers.<br />
A. Y. Van Quaethem, P. Lussis,<br />
A. Duwez, J. Gohy, C. Fustin<br />
9:10 380. Development and characterization<br />
of new biodegradable triblock copolymers<br />
based on poly(vinyl esters).<br />
C. E. Lipscomb, M. K. Mahanthappa<br />
9:30 381. Synthesis of P(VDF-HFP) based<br />
triblock copolymers containing ionic liquid<br />
segments. C. Chanthad,K.Xu,<br />
Q. Wang<br />
9:50 382. Synthesis of fluorescent watersoluble<br />
polymers and their adsorption on<br />
functionalized surfaces. A. de Cuendias,<br />
M. A. O’Connell, F. Gayet,<br />
J. V. Macpherson, P. R. Unwin,<br />
D. M. Haddleton<br />
10:10 383. Effect of cucurbit[n]uril on the<br />
morphology, solubility, and the photophysical<br />
properties of conjugated polymers<br />
in an aqueous medium. M. Artar,<br />
D. Tuncel<br />
10:30 384. Cationic amphiphilic random copolymers<br />
with potential ability of fixation<br />
of organic pollutant in soil. S. Yusa,<br />
M. Inoue, M. Doi, Y. Kamihashi,<br />
Y. Morishima<br />
10:50 385. Hyperbranched poly(ethylene<br />
glycol): A biocompatible, multifunctional<br />
polyether. M. Schömer, D. Wilms,<br />
H. Frey<br />
11:10 386. Luminescent organoboron block<br />
copolymers via RAFT polymerization.<br />
F. Cheng, F. Jäkle<br />
11:30 387. Controlled binary graft copolymerization<br />
of acrylamido monomers onto<br />
cellulose. K. C. Gupta<br />
Section E<br />
Westin Boston Waterfront<br />
Webster<br />
9th International Biorelated Polymers<br />
Symposium<br />
Biorelated Polymer Engineered Systems<br />
T. Fujiwara, C. Scholz, R. Ottenbrite, G.<br />
Tew, K. Kiick, Organizers<br />
A. Guiseppi-Elie, Y. Nagasaki, Presiding<br />
8:30 Introductory Remarks<br />
8:40 388. Implantable polymeric biomaterials:<br />
From replacement body parts to tissue<br />
engineering. A. J. Coury<br />
9:10 389. Bioactive electroconductive hydrogels.<br />
A. Guiseppi-Elie, C. Kotanen<br />
9:40 POLY/PMSE Poster Session and Intermission<br />
10:10 390. Design of hybrid hydrogels with<br />
nanogel and liposomes as cross-linking<br />
domains. Y. Sekine, Y. Moritani,<br />
N. Morimoto, K. Akiyoshi<br />
10:35 391. Enhancing protein resistance<br />
and ion permeability of IPN hydrogels by<br />
incorporation of PMPC. J. Wang, X. Li<br />
11:00 392. Hierarchically structured, hyaluronic<br />
acid-based, BMP-2 releasing hydrogels<br />
for cartilage repair. A. K. Jha,<br />
M. Malik, R. L. Duncan, X. Jia<br />
11:25 393. Glycogen nano-ball for polysaccharide<br />
nanogel engineering.<br />
H. Takahashi, S. Sawada, K. Akiyoshi<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
9th International Biorelated Polymers<br />
Symposium<br />
C. Scholz, T. Fujiwara, R. Ottenbrite,<br />
Organizers<br />
9:30–11:00<br />
394. Anisotropic swelling behavior of the<br />
cornea and determination of its dynamics.<br />
M. Annaka, T. Matsuura, H. Ikeda<br />
395. Polyionic drug carriers by PLA stereocomplexed<br />
hydrogels. D. Abebe,<br />
T. Fujiwara<br />
396. Hyaluronic acid based, heparin decorated<br />
hydrogel particles for cartilage repair.<br />
X. Xu,J.Zhao,X.Jia<br />
397. Multifunctional dendrimer-nanocrystal<br />
hybrids as delivery vehicles. A. O. Ward,<br />
T. Fujiwara<br />
398. Surface modification using unique photoresponsive<br />
spiro dimers. D. L. Watkins,<br />
T. Fujiwara<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
General Topics in the Design and Synthesis<br />
of Polymers<br />
D. Garcia, Organizer<br />
9:30–11:00<br />
399. Triptycene polyimides: A soluble class<br />
of polyimides with high thermal stability.<br />
S. A. Sydlik, Z. Chen, T. M. Swager<br />
400. From oligothiophenes to polythiophenes:<br />
Influence of molecular structure<br />
on crystalline behavior and transistor performance.<br />
L. Zhang, J. Timmons, F. Liu,<br />
A. L. Briseno<br />
401. Template polymerlization of conducting<br />
polymers using sulfonated poly(amic acids).<br />
S. Srisuwan, B. Somboonsub,<br />
M. A. Invernale, G. A. Sotzing,<br />
S. Thongyai, P. Praserthdam, D. Scola<br />
402. Thermally reversible cross-linkable terpolymer.<br />
B. Sharma, N. Tomar, D. Smith,<br />
C. norfolk, W. Dang<br />
403. Polymeric amidines via surfactant free<br />
emulsion polymerization.<br />
S. A. Pendergraph, A. J. Crosby,<br />
K. R. Carter<br />
404. Design and synthesis of nanoscale amphiphilic<br />
macromolecules with optimal<br />
binding properties to human scavenger<br />
receptor A: An investigation into the influence<br />
of stereochemistry and conformation.<br />
S. Hehir, N. M. Plourde, J. Griffin,<br />
P. V. Moghe, K. E. Uhrich<br />
405. 200 nm Spectral shift in poly(3,4-propylenedioxy)thiophenes,<br />
from blue to yellow.<br />
T. Dey, M. A. Invernale,<br />
Z. Buyukmumcu, G. A. Sotzing<br />
406. Characterization and surface grafting of<br />
thermally responsive carboxy functionalized<br />
PNIPAM nanogels synthesized via<br />
RAFT aqueous dispersion polymerization.<br />
M. J. Seeber, B. Zdyrko, J. Rieger,<br />
S. Boissé, C. Tsai, K. Kornev, I. Luzinov<br />
407. Synthesis of telechelic �,�-thiopolyisobutylene<br />
and polyisobutylene-based<br />
polythiourethanes. A. J. Magenau,<br />
T. R. Hartlage, R. F. Storey<br />
408. Rheology and biocompatibility study of<br />
reversible disulfide copolymeric hydrogels.<br />
H. Du, B. Mohr, M. Muthukumar,<br />
P. Hamilton, N. Ravi<br />
409. Alkyl halide polyisoprene chain ends<br />
with late and early transition metals.<br />
A. D. Asandei, H. S. Yu,C.P.Simpson<br />
410. 1,3-dimethylbutadiene radical polymerizations<br />
initiated from benzyl halides.<br />
A. D. Asandei, H. S. Yu,C.P.Simpson<br />
Section G<br />
Westin Boston Waterfront<br />
Galleria<br />
POLY/PMSE Poster Session<br />
Polymerizations and Polymer Modifications<br />
that Utilize Thiol-X Click Reactions<br />
A. Lowe, H. Schlaad, C. Bowman,<br />
Organizers<br />
9:30–11:00<br />
411. Limitations of radical thiol-ene reactions<br />
for polymer-polymer conjugations.<br />
M. M. Stamenovic, S. P. Koo,<br />
A. R. Prasath, A. J. Inglis,<br />
C. Barner-Kowollik, T. Junkers,<br />
W. Van Camp, F. E. Du Prez<br />
412. Dual-stimuli sensitive nanogels fabricated<br />
by self-association of thiolated hydroxypropyl<br />
cellulose. J. Tan, R. Liu,<br />
Y. Huang<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Bioactive Polymers and Polymer Surfaces<br />
Antifouling/Antimicrobial Surfaces<br />
O. T. Mefford, S. Lin-Gibson, Organizers<br />
M. Grunlan, Organizer, Presiding<br />
1:30 413. Bacterial surfactant/polymer films<br />
and coatings based on bis[alkyl]sulphosuccinate<br />
esters. J. Texter, R. Amand,<br />
S. Rhoades, D. Clemens, P. Ziemer<br />
2:00 414. Antimicrobial thin film assemblies<br />
containing quaternary ammonium salts.<br />
J. C. Grunlan, G. Sukhonosova<br />
2:20 415. Novel dually functional zwitterionic<br />
polymers and their anti-biofouling<br />
properties. S. Colak,G.N.Tew<br />
2:40 Intermission<br />
3:00 416. Polymer multilayers for controlled<br />
antimicrobial delivery. A. Shukla,<br />
P. T. Hammond<br />
3:20 417. Single-step pulsed plasma polymerization<br />
of diphenyldiselenide and its<br />
antimicrobial activity. D. Bhattacharyya,<br />
R. R. Deshmukh, T. W. Reid, T. Mosley,<br />
R. B. Timmons<br />
3:40 418. Photopolymerized dimethacrylate<br />
polymers containing in situ generated silver<br />
nanoparticles. Y. Cheng, X. Zhang,<br />
D. N. Zeiger, N. J. Lin, J. M. Antonucci,<br />
S. Lin-Gibson<br />
4:00 419. Amphiphilic silicones prepared<br />
with branched PEO-silanes with siloxane<br />
tethers. R. Murthy, B. M. Bailey,<br />
C. Valentin-Rodriguez, A. Ivanisevic,<br />
M. A. Grunlan<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Frontiers in Polymer Characterization<br />
Chromatography, Surfaces, and Interfaces<br />
D. Nelson, M. Dadmun, T. Seery,<br />
Organizers<br />
D. Waldow, Organizer, Presiding<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
1:30 420. HPLC characterization of polymer<br />
beyond SEC: Temperature gradient interaction<br />
chromatography. T. Chang,<br />
S. Ahn, H. Lee<br />
2:00 421. Comprehensive structural characterization<br />
of macromolecules by automated<br />
2D chromatography. M. Gray,<br />
C. Silverman, P. Kilz<br />
2:20 422. Kinetics of assembly and structure<br />
of polymer brushes at the solid-fluid interface<br />
measured by phase modulated ellipsometry.<br />
S. Kilbey, J. Alonzo,<br />
J. Hinestrosa, C. Deodhar<br />
2:50 Intermission<br />
3:10 423. Surface plasmon resonance (SPR)<br />
methods in the characterization and analysis<br />
of polymer thin films. R. Advincula<br />
3:40 424. Confocal Raman microscopy for<br />
the in situ characterization of polymer adsorption<br />
into nanoporous silica in solution.<br />
B. Jeon, J. Lee, C. Y. Ryu<br />
4:00 425. Correlation of density functional<br />
theory calculations with transmission infrared<br />
spectroscopy of hydrated and dehydrated<br />
Nafion. M. Webber, N. Dimakis,<br />
D. Kumari, M. Fuccillo, E. S. Smotkin<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
Polymerizations and Polymer Modifications<br />
that Utilize Thiol-X Click Reactions<br />
Thiol-Ene Modifications and Thiol-Yne<br />
Polymerizations<br />
A. Lowe, Organizer<br />
H. Schlaad, C. Bowman, Organizers,<br />
Presiding<br />
1:30 426. Free-radical thiol-ene and thiolyne<br />
coupling as selective ligation tools for<br />
glycoconjugation. A. Dondoni<br />
2:00 427. Synthesis of biohybrid conjugates<br />
using thiol-ene click photochemistry.<br />
C. Diehl, H. Schlaad<br />
2:30 428. Combination of controlled radical<br />
polymerization and click reactions to obtain<br />
glycopolymers and their interactions<br />
with lectins. C. R. Becer,M.I.Gibson,<br />
D. A. Mitchell, D. M. Haddleton<br />
2:50 429. Novel functional polymers by terminal<br />
and pendant functionalizations via<br />
thiol-ene and thiol-polyene click reactions.<br />
B. Iván,V.Pálfi, G. Szarka<br />
3:10 Intermission<br />
3:30 430. Thiol-ene click chemistries for the<br />
formation of nanoparticles and encapsulation<br />
of bioactive cargo.<br />
A. E. van der Ende, J. Harrell, J. Katz,<br />
E. Harth<br />
4:00 431. “Thio-click” chemistry and microfluidics:<br />
Straightforward method towards<br />
macroporous and nonporous functional<br />
polymer beads. F. E. Du Prez,<br />
R. Prasath, M. Gokmen<br />
4:30 432. Synthesis of hyperbranched polymers<br />
via cobalt-catalyzed chain transfer<br />
and functionalization by thiol-ene click<br />
chemistry. K. A. McEwan,<br />
D. M. Haddleton<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
General Topics in the Design and Synthesis<br />
of Polymers<br />
D. Garcia, Organizer<br />
N. Tomar, Presiding<br />
1:30 433. Amphiphilic block copolymers of<br />
poly(L-lactide) and poly(2-dimethylaminoethyl<br />
methacrylate): Exploring synthetic<br />
pathways. M. Kryuchkov,<br />
C. Detrembleur, G. Bazuin<br />
1:50 434. Modification of thermoplastic<br />
elastomer gels through nanoparticle addition.<br />
M. C. Berg, R. A. Mrozek,<br />
K. Strawhecker, J. Andzelm,<br />
T. Chantawansri, Y. Sliozberg,<br />
J. L. Lenhart<br />
2:10 435. Di-cationic mono-radical initiator<br />
to combine quasiliving carbocationic polymerization<br />
and atom transfer radical polymerization.<br />
Y. Zhu, R. F. Storey<br />
2:30 436. Design and synthesis of a novel<br />
biodegradable polymer for biomedical<br />
applications. A. L. Garle,S.Kong,<br />
B. M. Budhlall<br />
2:50 437. Effect of reactive diluents on thermally<br />
reversible cross-linked epoxy.<br />
N. Tomar, W. Deng, B. Sharma,<br />
C. Norfolk, D. Smith Jr<br />
3:10 438. Thermal stabilization of poly (acrylonitrile-co-1-vinylimidazole)<br />
melt-spun fiber.<br />
W. Deng, A. Lobovsky, N. Tomar,<br />
T. Wu, S. Iacono, S. Budy, W. Hoffman,<br />
D. W. Smith, Jr, T. Long<br />
3:30 439. Nanoscale vs. microscale gelation<br />
on surfaces of crosslinked polyurethane.<br />
C. Wang, W. Zhang, K. Wynne<br />
3:50 440. Synthesis and characterization of<br />
star-shaped poly(sodium styrenesulfonate)<br />
by atom transfer radical polymerization<br />
of ethyl styrene sulfonate. Y. Li,<br />
X. Yu, J. W. Mays, K. Hong<br />
4:10 441. Synthesis and thermogravimetric<br />
analysis of homo and copolymers of<br />
phosphonated norbornenes.<br />
G. J. Gabriel<br />
4:30 442. Synthesis and characterization of<br />
ionenes for anionic exchange membranes.<br />
X. Yuan, C. J. Cornelius<br />
Section E<br />
Westin Boston Waterfront<br />
Webster<br />
9th International Biorelated Polymers<br />
Symposium<br />
Biorelated Polymer Applications<br />
T. Fujiwara, C. Scholz, R. Ottenbrite,<br />
G. Tew, K. Kiick, Organizers<br />
J. Kressler, Presiding<br />
1:30 Introductory Remarks<br />
1:40 443. Concentrating quaternary charge<br />
at polymer surfaces: Progress in polymer<br />
surface modifiers as a route to contact<br />
antimicrobial coatings. K. J. Wynne<br />
2:10 444. Modification of poly(glycerol adipate)<br />
and its surface activity. T. Naolou,<br />
K. Busse, M. Pietzsch, J. Kressler<br />
2:40 445. Biodegradable polypeptide-bpolylactide<br />
block copolymer micelles<br />
highly stabilized by polyion complex<br />
coating as drug carriers. Y. Ohya,<br />
S. Takeda, Y. Shibata, T. Ouchi,<br />
A. Maruyama<br />
3:05 Intermission<br />
3:35 446. Hydrolytic degradation of polyisobutylene<br />
and poly-lactide based<br />
multiblock copolymers. P. Kulkarni,<br />
U. Ojha, D. Cozzens, R. Faust<br />
4:00 447. Specific protein binding on phospholipid<br />
bilayer array corralled by nonfouling<br />
polymer brushes. Y. Iwasaki,<br />
K. Nakai, K. Morigaki<br />
4:25 448. Block-copolymers of polysiloxanes<br />
and polyoxazolines for biomedical<br />
applications. L. Theogarajan, N. Borjigin,<br />
M. Isaacman, A. Merrithrew<br />
WEDNESDAY EVENING<br />
Westin Boston Waterfront<br />
Grand Ballroom B<br />
POLY/PMSE Plenary Lecture and Awards<br />
Reception Cosponsored by PMSE ‡ and<br />
PRES Financially supported by Royal <strong>Society</strong><br />
of Chemistry<br />
K. Kiick, Organizer, Presiding<br />
5:30 Networking<br />
6:15 Introductory Remarks<br />
6:20 449. Materials to program cells in situ.<br />
D. J. Mooney<br />
7:00 Awards Reception<br />
THURSDAY MORNING<br />
Section A<br />
Westin Boston Waterfront<br />
Grand Ballroom D<br />
Bioactive Polymers and Polymer Surfaces<br />
Bioactive Surfaces<br />
O. T. Mefford, S. Lin-Gibson, Organizers<br />
M. Grunlan, Organizer, Presiding<br />
8:30 450. Protease adsorption and surface<br />
biocatalysis on charged immobilized substrates.<br />
B. E. Feller, J. T. Kellis,<br />
L. G. Cascao Pereira, C. R. Robertson,<br />
C. W. Frank<br />
9:00 451. Novel glycosurfaces by surfaceinitiated<br />
ATRP. A. Mateescu, J. Ye,<br />
R. Narain, M. Vamvakaki<br />
9:20 452. Modification the surface of polyethylene<br />
terephthalate film by UV-initiated<br />
grafting. H. Zhang, Y. Jiang<br />
9:40 Intermission<br />
10:00 453. Tunable interfaces and functional<br />
nano-objects derived from resilin-mimetic<br />
protein Rec1-resilin. N. K. Dutta,<br />
M. Y. Truong, S. Mayavan,<br />
N. Roy Choudhury, M. Kim, C. M. Elvin,<br />
A. J. Hill<br />
10:20 454. Rewritable bioarrays.<br />
J. S. Badyal<br />
10:40 455. Novel approach for visualizing<br />
polymer silica substrates using<br />
BODIPY ® -based fluorescent dye.<br />
O. Borozenko,K.L.Lau,G.Cosa,<br />
S. Giasson, W. G. Skene<br />
Section C<br />
Westin Boston Waterfront<br />
Grand Ballroom E<br />
Polymerizations and Polymer Modifications<br />
that Utilize Thiol-X Click Reactions<br />
Thiol-X Polymerization and Polymer<br />
Modification Reactions<br />
C. Bowman, Organizer<br />
H. Schlaad, A. Lowe, Organizers, Presiding<br />
8:30 456. Thio-bromo “click” chemistry.<br />
from (meth)acrylate chain-end modification<br />
to the synthesis of dendrimers and<br />
dendritic macromolecules. B. M. Rosen,<br />
G. Lligadas, C. Hahn, V. Percec<br />
9:00 457. Thiol-para fluoro click reactions:<br />
From thermoresponsive polymers to glycopolymers<br />
and nanoparticles.<br />
C. R. Becer, K. Babiuch, S. Hornig,<br />
M. Gottschaldt, K. Kokado, Y. Chujo,<br />
U. S. Schubert<br />
9:30 458. Synthesis and modification of multicomponent<br />
and multiclickable polymer<br />
brushes. S. B. Rahane, R. M. Hensarling,<br />
D. L. Patton<br />
9:50 Intermission<br />
10:10 459. Thiol-ene and thiol-oxirane<br />
chemistries for the synthesis and modification<br />
of cylindrical polymer brushes and<br />
surface modification of microspheres.<br />
A. H. Müller, A. S. Goldmann, D. Pirner,<br />
Y. Xu, L. Barner, C. Barner-Kowollik<br />
10:40 460. Transformation of RAFT polymer<br />
end groups by thiol-ene click reaction.<br />
F. M. Winnik,X.Qiu<br />
11:10 461. End group functionalization of<br />
RAFT polymers using thiol – alkyl methanethiosulfonate<br />
click-like chemistry.<br />
P. J. Roth, P. Theato<br />
Section D<br />
Westin Boston Waterfront<br />
Otis<br />
General Topics in the Design and Synthesis<br />
of Polymers<br />
D. Garcia, Organizer<br />
S. Hou, Presiding<br />
8:30 462. Degradable poly(ester-urethane)s<br />
based on poly(�-caprolactone) with crystalline<br />
hard segments. synthesis and<br />
characterizaction. J. E. Báez,<br />
A. Marcos-Fernández<br />
8:50 463. Unmasking of polycarbodiimides:<br />
Polyguanides. J. D. DeSousa,<br />
B. M. Novak<br />
9:10 464. Synthesis of double-brush copolymers<br />
by tandem RAFT polymerization,<br />
ROP, and ROMP. Y. Li, E. Themistou,<br />
J. Zou, Y. S. Yap, C. Cheng<br />
9:30 465. Synthesis and T1 relaxivity of<br />
poly(ethylene glycol) based gadolinium<br />
encapsulated nanoparticles. S. Hou,<br />
S. Tong, J. Zhou, G. Bao<br />
9:50 466. Thiophene-based-ladder polymers<br />
with Pseudo-Geminal-[2.2]paracyclophane<br />
units. S. P. Jagtap,<br />
D. M. Collard<br />
10:10 467. Boronic acid end-functionalized<br />
polycaprolactone as a macromolecular<br />
reagent for the chemical modification of<br />
lignin. A. L. Korich,P.M.Iovine<br />
10:30 468. Hierarchical structures based on<br />
self-assembled diblock copolymers<br />
within honeycomb microstructured porous<br />
films. P. Escalé, M. Save, A. Lapp,<br />
L. Rubatat, L. Billon<br />
10:50 469. Recent developments on the<br />
photocontrolled ring-opening polymerization<br />
of metallocenophanes.<br />
L. Chabanne, I. Matas Ruiz, S. K. Patra,<br />
I. Manners<br />
11:10 470. Dynamic/living conjugated<br />
azomethine polymers: Materials with<br />
postpolymerization property tailoring.<br />
W. Skene, S. Barik<br />
11:30 471. Synthesis and ring-opening polymerization<br />
of �-fluoro-�-caprolactone<br />
monomer. T. F. Al-Azemi,<br />
A. A. Mohamod, N. A. Al-Awadi,<br />
O. M. El-Dusuoqui<br />
Section E<br />
Westin Boston Waterfront<br />
Webster<br />
9th International Biorelated Polymers<br />
Symposium<br />
Biorelated Polymer Synthesis<br />
T. Fujiwara, C. Scholz, R. Ottenbrite,<br />
G. Tew, K. Kiick, Organizers<br />
T. Deming, Y. Ohya, Presiding<br />
8:30 Introductory Remarks<br />
8:40 472. Novel nitroxyl radical containing<br />
nanoparticle: Bioimaging and therapy.<br />
Y. Nagasaki, T. Yoshitomi<br />
9:10 473. Recent developments in use of<br />
transition metal initiators for polypeptide<br />
synthesis. T. J. Deming<br />
9:40 Intermission<br />
10:00 474. Epoxy fatty acid diester/CO2<br />
systems: Solubility, carbonatation kinetics,<br />
and polyurethanes synthesis.<br />
A. Boyer<br />
10:25 475. Iodine-catalyzed synthesis of<br />
mixed cellulose esters. H. N. Cheng,<br />
M. K. Dowd, R. L. Shogren, A. Biswas<br />
10:50 476. Synthesis and biostability of<br />
novel polyisobutylene-based thermoplastic<br />
polyurethanes. D. Cozzens,U.Ojha,<br />
P. Kulkarni, R. Faust, S. Desai<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
POLY<br />
TECH–117
POLY/PMSE <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom A<br />
Frontiers in Polymer Characterization<br />
Dynamics and Size Analysis<br />
D. Waldow, D. Nelson, Organizers<br />
T. Seery, M. Dadmun, Organizers,<br />
Presiding<br />
9:00 477. Analysis of chitosan/DNA nanoparticles<br />
by field flow fractionation.<br />
P. Ma, M. Buschmann, F. M. Winnik<br />
9:30 478. Asymmetric flow field flow fractionation<br />
of amphiphilic dendritic polymers.<br />
A. Lederer, S. Boye, D. Appelhans,<br />
B. Voit<br />
9:50 479. Dynamic swelling, morphology,<br />
and conductivity in thin ionic block copolymer<br />
films. S. A. Petrina, T. Saito,<br />
N. Podraza, M. A. Hickner<br />
10:10 Intermission<br />
10:30 480. Searching for glass transitions in<br />
layer-by-layer assemblies.<br />
J. Lutkenhaus, W. Jang, L. Shao<br />
11:00 481. Glass transitions, segmental dynamics,<br />
and friction coefficients for individual<br />
polymers in multicomponent polymer<br />
systems by chain-level experiments.<br />
L. W. Gill, J. L. White<br />
PMSE<br />
Division of Polymeric<br />
Materials: Science and<br />
Engineering<br />
J. Pyun, D. Schiraldi, C. Soles,<br />
and T. Younkin, Program Chairs<br />
SOCIAL EVENTS:<br />
Breakfast, 7:30 AM: Sun, Mon, Tue,<br />
Wed, Thu<br />
Hospitality Suite, 8:00 PM: Tue<br />
Reception, 5:30 PM: Wed<br />
BUSINESS MEETING:<br />
Executive Committee Meeting, 4:30<br />
PM: Sun<br />
Business Meeting, 5:00 PM: Mon<br />
SUNDAY MORNING<br />
Section A<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom A/B<br />
WCU International Symposium on Energy<br />
Storage and Conversion<br />
Nanostructured Materials for Energy<br />
Applications Financially supported by Dongjin<br />
Semichem Co., Ltd., Office of Research<br />
Affairs, Seoul National University, and WCU<br />
Program of <strong>Chemical</strong> Convergence for Energy<br />
and Environment funded by the Ministry of<br />
Education, Science and Technology (R31-<br />
10013)<br />
P. Theato, J. Jang, Organizers<br />
K. Char, Organizer, Presiding<br />
T. Hyeon, Presiding<br />
8:30 1. Thermoelectric polymer nanocomposites.<br />
J. C. Grunlan,C.Yu<br />
‡ Cooperative Cosponsorship<br />
118–TECH<br />
9:00 2. Nonaqueous sol-gel routes to metal<br />
oxide nanostructures. N. Pinna<br />
9:30 3. Nanostructured polymeric membranes<br />
for fuel cell and water treatment<br />
applications. M. A. Hickner<br />
10:00 4. Colloidal polymerization: A route to<br />
heterostructured semiconductor nanowires<br />
for energy. B. Kim, N. R. Armstrong,<br />
J. Pyun<br />
10:30 PMSE/POLY Poster Session and Intermission<br />
10:45 5. High energy density nanocomposites<br />
based on surface modified BaTiO 3<br />
and ferroelectric polymers. J. W. Perry,<br />
P. Kim, O. Smith, J. P. Tillotson,<br />
S. R. Marder<br />
11:15 6. Fabrication of conducting polymer<br />
nano-materials for energy storage and<br />
conversion. J. Jang<br />
11:45 7. Mechanical and thermal energy<br />
transport in biological and biologically inspired<br />
nanostructures. M. J. Buehler,<br />
Z. Xu<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Multifunctional Nanoparticles for Drug<br />
Delivery and Imaging<br />
Imaging and Therapy Financially supported<br />
by Cerulean Pharma, Inc.<br />
S. Svenson, Organizer, Presiding<br />
J. Gao, S. Boyes, Presiding<br />
8:30 Introductory Remarks<br />
8:35 8. Multistage drug delivery system for<br />
design of enhanced therapeutic systems<br />
and improved contrast agents. B. Godin,<br />
R. E. Serda, E. Tasciotti, X. Lu, T. Tanaka,<br />
P. Decuzzi, M. Ferrari<br />
9:00 9. Targeted multifunctional nanoparticles<br />
for imaging, surgery and therapy of<br />
cancer. R. Kopelman, Y. Koo Lee<br />
9:25 10. Theranostic polymer micelles for<br />
lung cancer imaging and therapy.<br />
G. Huang, S. Yang, L. Wu, C. Khemtong,<br />
C. Kessinger, S. Li, O. Togao,<br />
M. Takahashi, K. Brown, J. Gao<br />
9:50 11. Dendrimer based cancer therapy.<br />
S. N. Goonewardena, S. Choi,<br />
J. R. Baker<br />
10:15 PMSE/POLY Poster Session and Intermission<br />
10:30 12. Polymer-modified gadolinium<br />
nanoparticles for the targeted imaging of<br />
cancer. M. D. Rowe, C. G. Chang,<br />
N. J. Serkova, S. G. Boyes<br />
10:55 13. Multifunctional lipoprotein-derived<br />
nanoparticles for diagnostic and therapeutic<br />
applications in biomedicine.<br />
W. J. Mulder, D. P. Cormode, T. Skajaa,<br />
P. A. Jarzyna, A. Gianella, E. A. Fisher,<br />
Z. A. Fayad<br />
11:20 14. Investigation of large molecule<br />
and nanoparticle pharmacokinetics by<br />
quantitative PET imaging. M. I. Papisov,<br />
A. J. Fischman, V. Belov<br />
11:45 15. Aggregation control of poly(pphenylene<br />
ethynylene)s in water for biological<br />
imaging applications. J. Moon,<br />
A. Nguyen, Y. Ko<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
AkzoNobel Award in Outstanding Graduate<br />
Research in Polymer Chemistry in Honor of<br />
Haifeng Gao Cosponsored by POLY<br />
Financially supported by AkzoNobel<br />
W. Ford, Organizer, Presiding<br />
8:30 16. Novel self-assembling approaches<br />
to functionalized materials. C. J. Hawker<br />
9:00 17. New functional hybrid nanoparticles<br />
using (3-acryloylpropyl)trimethoxysilane<br />
as a crosslinker. A. H. Müller,<br />
J. Yuan, M. Müller, S. Weiss, A. Walther<br />
9:30 18. Polymers and dipolar nanoparticles.<br />
J. Pyun<br />
10:00 PMSE/POLY Poster Session and Intermission<br />
10:15 19. Organic materials and devices for<br />
solar energy conversion.<br />
M. E. Thompson<br />
10:45 20. Achieving the impossible by combining<br />
anionic and atom transfer radical<br />
polymerization. N. Hadjichristidis<br />
11:15 21. Synthesis of polymers with controlled<br />
architectures by ATRP.<br />
K. Matyjaszewski<br />
11:45 Presentation of Award by Rama<br />
Chandran<br />
11:50 22. Synthesis of functional polymers<br />
with controlled architecture by ATRP of<br />
monomers in the presence of crosslinkers:<br />
From stars to gels. H. Gao<br />
Section D<br />
Westin Boston Waterfront<br />
Stone<br />
Green Coating Technologies<br />
D. Webster, J. Rawlins, Organizers,<br />
Presiding<br />
8:30 23. Environmentally friendly non-ionic<br />
and fluorine free surface active amphiphilic<br />
block copolymers for fouling release<br />
applications. H. S. Sundaram, Y. Cho,<br />
C. J. Weinman, M. Y. Paik, M. Dimitriou,<br />
J. Finlay, M. E. Callow, J. A. Callow,<br />
E. J. Kramer, C. K. Ober<br />
9:00 24. Poly(2,5-bis-(N-methyl-N-hexylamino)phenylene<br />
vinylene) (BAM-PPV)<br />
as a replacement for army wash primers.<br />
P. Zarras, C. Webber, C. E. Miller<br />
9:30 25. Thin film fuel cell and water purification<br />
membranes cast from alcohol/water<br />
nanodispersions of disulfonated poly(aryl<br />
ether) copolymers. C. Lee, M. Lee,<br />
J. E. McGrath, J. Park, J. Song,<br />
M. B. Robert, J. Spano, S. Wi, J. Cook,<br />
B. D. Freeman<br />
9:50 26. Single-step and solvent-free synthesis<br />
of conducting poly(3,4-thylenedioxythiophene)<br />
and its copolymer.<br />
D. Bhattacharyya, H. Chelawat,<br />
K. K. Gleason<br />
10:10 PMSE/POLY Poster Session and Intermission<br />
10:30 27. Synthesis of polyurethane dispersions<br />
using novel polypropylene carbonate<br />
polyols. M. J. Nasrullah, P. Thapliyal,<br />
V. V. Sonalkar, C. Gallagher-Lein,<br />
D. C. Webster<br />
10:50 28. Preparation of functional polymer<br />
surfaces by hyperthermal hydrogen induced<br />
cross-linking. C. V. Bonduelle,<br />
S. Karamdoust, D. B. Thompson,<br />
T. Trebicky, G. Davidson, L. W. Lau,<br />
E. Gillies<br />
11:10 29. Epoxy-anhydride curing of epoxidized<br />
sucrose esters of fatty acids.<br />
X. Pan, P. Sengupta, D. C. Webster<br />
11:30 30. Monomer-grafted sucrose ester<br />
resins. T. J. Nelson, D. C. Webster<br />
Section E<br />
Westin Boston Waterfront<br />
Galleria<br />
PMSE/POLY Poster Session<br />
Multifunctional Nanoparticles for Drug<br />
Delivery and Imaging<br />
S. Svenson, Organizer, Presiding<br />
9:30–11:00<br />
31. Synthesis of folate functionalized biodegradable<br />
amphiphilic dendrimer-like star<br />
polymer for targeted cancer cells.<br />
W. Cao, J. Zhou, Y. Wang, L. Zhu<br />
32. CRLX288, a novel polymeric nanoparticle,<br />
slows the release of drug and can<br />
be dosed less frequently than the parent<br />
drug. S. R. Kabir, P. Ng, P. Lim Soo,<br />
J. Podobinski, G. Gangal, R. I. Case,<br />
P. Shum, B. Sweryda-Krawiec,<br />
J. G. Martínez, S. Svenson, S. Eliasof,<br />
D. Lazarus<br />
33. Manipulating the structural conformation<br />
of PB-PEO micelles in water-THF co-solvent<br />
mixtures. E. G. Kelley, T. P. Smart,<br />
C. M. Marino, M. O. Sullivan, T. H. Epps,<br />
III<br />
34. CRLX288, a novel polymeric nanoparticle,<br />
overcomes many of the delivery hurdles<br />
associated with the parent drug.<br />
J. G. Martínez, S. R. Kabir, P. Ng,<br />
P. Lim Soo, J. Podobinski, G. Gangal,<br />
R. I. Case, P. Shum, B. Sweryda-Krawiec,<br />
S. Svenson, S. Eliasof, D. Lazarus<br />
35. CRLX288, a novel polymeric nanoparticle,<br />
significantly improves the therapeutic<br />
window over the parent drug in preclinical<br />
studies in mice. P. Ng,<br />
P. Lim Soo, J. Podobinski, G. Gangal,<br />
R. I. Case, P. Shum, B. Sweryda-Krawiec,<br />
J. Martínez, S. R. Kabir, D. Lazarus,<br />
S. Eliasof, S. Svenson<br />
36. Size-dependent influenza virus inhibition<br />
by multivalent polyglycerol glycoarchitectures.<br />
I. Papp, A. L. Sisson, C. Sieben,<br />
A. Herrmann, R. Haag<br />
37. IT-101 nanoparticle characterization.<br />
R. I. Case, B. Sweryda-Krawiec,<br />
P. Shum, J. Hwang, M. Wolfgang<br />
38. Biodegradable polyglycerol nanogels<br />
with excellent cell penetrating properties.<br />
D. Steinhilber, A. L. Sisson, P. Welker,<br />
K. Licha, R. Haag<br />
39. Antibody-like nanomaterials for cell recognition.<br />
J. Zhou, B. Soontornworajit,<br />
Y. Wang<br />
40. Responsive polymeric magnetic nanoparticels<br />
with liquid crystalline hydrophobic<br />
layer. Y. Zhou,R.M.Kasi<br />
41. Multicompartment/multigeometric micelles<br />
(MCM/MGM) of diblock copolymer<br />
blend via dynamic and static self-assembly.<br />
J. Zhu, K. Zhang, C. Miesch,<br />
T. Emrick, K. Wooley, D. Pochan<br />
SUNDAY AFTERNOON<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
Pushing the Limits of Nanolithography:<br />
Advanced Imaging for Sub 20 nm<br />
Patterning<br />
P. Trefonas, G. Barclay, Organizers,<br />
Presiding<br />
1:00 42. Surface modifying copolymers for<br />
self-assembly of block copolymers in<br />
thin-films. E. Han, M. Kim, Y. Kim,<br />
N. S. Safron, M. S. Arnold, P. Gopalan<br />
1:30 43. Sub-20 nm nanolithography using<br />
templated block copolymers. C. A. Ross,<br />
J. Son, K. W. Gotrik, Y. Jung,<br />
A. Alexander-Katz, J. Chang, A. Hannon,<br />
R. Mickiewicz, K. K. Berggren, Y. K. Yang<br />
2:00 44. Green processing of photoresists in<br />
non-polar fluids for high resolution patterning.<br />
C. K. Ober, C. K. Ouyang, J. Lee,<br />
J. Sha<br />
2:30 PMSE/POLY Poster Session and Intermission<br />
2:45 45. Defect formation during self-assembly<br />
of block copolymer etch masks.<br />
S. Sills, D. B. Millward, R. Malshe<br />
3:15 46. Photoacid generator-attached molecular<br />
glass photoresists. M. Krysak,<br />
C. K. Ober<br />
3:45 47. Imaging hierarchal defects on<br />
coated patterned substrates using nanoprobes.<br />
C. Pratiwada<br />
4:15 48. Self-aligning and self-orienting DNA<br />
origami for sub-lithographic patterning.<br />
K. Kim, K. Sarveswaran, M. Lieberman<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
Section A<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom A/B<br />
WCU International Symposium on Energy<br />
Storage and Conversion<br />
Nanostructured Materials for Energy<br />
Applications Financially supported by Dongjin<br />
Semichem Co., Ltd., Office of Research<br />
Affairs, Seoul National University, and WCU<br />
Program of <strong>Chemical</strong> Convergence for Energy<br />
and Environment funded by the Ministry of<br />
Education, Science and Technology (R31-<br />
10013)<br />
K. Char, P. Theato, Organizers<br />
J. Jang, Organizer, Presiding<br />
J. Grunlan, Presiding<br />
1:30 49. Nanostructured materials for potential<br />
energy-related applications by<br />
controlled radical polymerization.<br />
K. Matyjaszewski, L. McCullough,<br />
J. Yoon, T. Kowalewski, H. Paik<br />
2:00 50. Carbon-containing nanocomposite<br />
materials for energy storage.<br />
B. Hertzberg, S. Boukhalfa,<br />
A. Magasinski, I. Kovalenko, P. Dixon,<br />
G. Yushin<br />
2:30 51. Quantum dot-based nanohybrid<br />
active layers and their relationship with<br />
the performance of light-emitting diodes.<br />
K. Char, W. Bae, J. Kwak, J. Lim<br />
3:00 52. Arranging nanoparticle superlattices<br />
with liquid crystals. X. Zeng,<br />
X. Mang, F. Liu, R. Zhang, A. G. Fowler,<br />
L. Cseh, G. H. Mehl, G. Ungar<br />
3:30 PMSE/POLY Poster Session and Intermission<br />
3:45 53. Self-assembly of rod-coil block copolymers<br />
for organic photovoltaic applications.<br />
R. A. Segalman,V.Ho,<br />
B. W. Boudouris<br />
4:15 54. Synthesis of hollow hematite nanocapsules<br />
and carbon-embedded magnetite<br />
nanocrystals for lithium-ion battery<br />
anodes. Y. Piao, H. Kim, M. Park, B. Kim,<br />
Y. Sung, T. Hyeon<br />
4:45 55. Synthesis and characterization of<br />
block copolymers with polythiophene<br />
segments by the combination of atom<br />
transfer radical polymerization and Kumada<br />
polycondensation. X. Yu, Y. Li,<br />
H. M. O’Niell, M. Kilbey, II, J. W. Mays,<br />
P. F. Britt, K. Hong<br />
5:05 56. Gold cobalt core-shell nanoparticles<br />
and patterning gold nanoparticles<br />
on substrates. B. Kim,J.Pyun<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Multifunctional Nanoparticles for Drug<br />
Delivery and Imaging<br />
Carrier-based Drug Delivery Financially<br />
supported by Cerulean Pharma, Inc.<br />
S. Svenson, Organizer, Presiding<br />
M. Grinstaff, R. Haag, Presiding<br />
1:30 Introductory Remarks<br />
1:35 57. Nanotechnology and its potential in<br />
medicine. R. S. Langer<br />
2:25 58. Acid cleavable multifunctional prodrugs<br />
derived from dendritic polyglycerol.<br />
M. Calderón, P. Welker, K. Licha,<br />
I. Fichtner, R. Graeser, F. Kratz, R. Haag<br />
2:50 59. Structure-activity relationshipinspired<br />
design of novel cisplatin nanoparticles.<br />
S. Sengupta, A. Paraskar<br />
3:15 PMSE/POLY Poster Session and Intermission<br />
3:30 60. Expansile nanoparticles: Synthesis,<br />
characterization, and in vivo efficacy in<br />
lung and mesothelioma tumor models.<br />
M. W. Grinstaff<br />
3:55 61. Polymer micelles for multiple drug<br />
delivery. H. Shin, A. W. Alani, N. Rockich,<br />
G. S. Kwon<br />
4:20 62. Polymeric micelles from bench to<br />
bedside. A. V. Kabanov<br />
Section D<br />
Westin Boston Waterfront<br />
Stone<br />
Akzo Nobel Student Award Symposium<br />
Financially supported by AkzoNobel<br />
J. Thomaides, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 63. Networked nanocomposites derived<br />
from block terpolymers. M. Stefik,<br />
S. Mahajan, H. Sai, T. H. Epps,<br />
F. S. Bates, S. M. Gruner, U. Wiesner<br />
2:05 64. Surface energy/chemistry gradients<br />
for block copolymer thin film studies.<br />
J. N. Albert, M. J. Baney, C. M. Stafford,<br />
J. Y. Kelly, T. H. Epps<br />
2:35 65. Tuning T g by 100 K in multilayer<br />
polymer films and nanostructured block<br />
copolymer/homopolymer blends. S. Kim,<br />
J. Torkelson<br />
3:05 PMSE/POLY Poster Session and Intermission<br />
3:20 66. Network formation in a crystallizing<br />
polymer. D. Arora, H. Winter<br />
3:50 67. Tailoring and controlling the physical<br />
properties of silica aerogel-polymer<br />
nanocomposites with surface initiated-<br />
ATRP. D. J. Boday, P. Keng, J. Pyun,<br />
D. A. Loy<br />
4:20 68. Unique helical polycarbodiimides<br />
with reversible dynamic properties based<br />
on arene substituent effects.<br />
J. G. Kennemur, B. M. Novak<br />
Section E<br />
Westin Boston Waterfront<br />
Galleria<br />
PMSE/POLY Poster Session<br />
General Posters<br />
D. Schiraldi, Organizer, Presiding<br />
2:30–4:00<br />
69. Formation of air gap dielectrics by nanoimprint<br />
lithography. B. Erenturk,<br />
K. R. Carter<br />
70. Crystal ordering of isotactic polypropylene<br />
and carbon nanotube composites<br />
under shear stress. R. Judith,<br />
G. Georgiev, Y. Cabrera, L. Wielgus,<br />
P. Cebe<br />
71. Smectic phase and crystallization of multiwalled<br />
carbon nanotubes/isotactic<br />
polypropylene formed through meltquenching.<br />
G. Y. Georgiev, S. Schoen,<br />
D. Ivy, E. A. Gombos, M. B. McIntyre,<br />
P. Cebe<br />
72. Application of nanocarbons to photosensitive<br />
diazo/PVA resist (3). H. Hamana,<br />
K. Harada, M. Nakada, M. Okada,<br />
T. Hiaki, K. Matsuda, S. Takahara,<br />
K. Sugita<br />
73. Amphiphilic macromolecule-lipid complexes<br />
for drug delivery: In vivo tolerability.<br />
A. M. Harmon, M. H. Lash,<br />
K. E. Uhrich<br />
74. Dimethyl sulfoxide plasticized wheat gluten/silica<br />
nanocomposites. S. Hemsri,<br />
R. S. Parnas, A. D. Asandei<br />
75. Formation of hierarchical silica<br />
nanochannels with nanoimprint lithography.<br />
N. R. Hendricks, K. R. Carter,<br />
J. J. Watkins<br />
76. Poly(ethylene oxide) crystal orientation<br />
change under 1D nanoscale confinement<br />
using polystyrene-block-poly(ethylene<br />
oxide) copolymers: Confined dimension<br />
and reduced tethering density effects.<br />
M. Hsiao, J. Zheng, R. Van Horn,<br />
R. Quirk, B. Lotz, E. Thomas, H. Chen,<br />
S. Cheng<br />
77. Dynamic structure study of synthetic resilin<br />
biopolymers. X. Hu, G. Qin, P. Cebe,<br />
D. L. Kaplan<br />
78. Lipid bilayer formation using a PDMS<br />
gasket. Y. Baek, J. Park, S. Choi, T. Jeon<br />
79. Synthesis and characterization of dendron-rod-coil<br />
based molecules for applications<br />
in organic photovoltaics.<br />
T. S. Kale, A. Della Pelle,<br />
A. Nantalaksakul, S. Thayumanavan<br />
80. Cytotoxicity and immune response of<br />
PEDOT nanomaterials with different<br />
shapes in mammalian cells. S. Kim,<br />
J. Jang<br />
POLY/PMSE Poster Session<br />
From Molecules to Macromolecules:<br />
Towards Self-Assembling Materials<br />
Sponsored by POLY, Cosponsored by<br />
MONDAY MORNING<br />
Section A<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom A/B<br />
WCU International Symposium on Energy<br />
Storage and Conversion<br />
Li-Batteries and Supercapacitors Financially<br />
supported by Dongjin Semichem Co., Ltd.,<br />
Office of Research Affairs, Seoul National<br />
University, and WCU Program of <strong>Chemical</strong><br />
Convergence for Energy and Environment<br />
funded by the Ministry of Education, Science<br />
and Technology (R31-10013)<br />
J. Jang, K. Char, P. Theato, Organizers<br />
G. Ungar, S. Tolbert, Presiding<br />
8:30 81. Advances in electrolytes for lithium<br />
ion batteries: A mechanistic understanding.<br />
B. L. Lucht<br />
9:00 82. Nanolayer batteries and spray-assembled<br />
electrodes for electrochemical<br />
energy. P. T. Hammond<br />
9:30 83. High lithiation capacity and rate capability<br />
observed with amorphous MoO 2<br />
electrodes for lithium-ion batteries.<br />
J. H. Ku, J. Ryu, S. Oh<br />
10:00 PMSE/POLY Poster Session and Intermission<br />
10:15 84. Layer-by-layer assembled nanostructured<br />
electrodes for electrochemical<br />
energy applications. S. Lee, S. Chen,<br />
P. T. Hammond, Y. Shao-Horn<br />
10:45 85. Hydrogen storage in metal-organic<br />
framewords. K. Sumida,<br />
Z. R. Herm, H. Choi, E. D. Bloch,<br />
L. J. Murray, M. Dinca, S. S. Kaye,<br />
J. R. Long<br />
11:15 86. Effects of polymorphism on dipolar<br />
reorientation in poly(vinylidene fluoride-co-hexafluoropropylene)<br />
random copolymers.<br />
F. Guan, J. Wang, J. Pan,<br />
Q. Wang, L. Zhu<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Multifunctional Nanoparticles for Drug<br />
Delivery and Imaging<br />
Targeting and Drug Delivery Financially<br />
supported by Cerulean Pharma, Inc.<br />
S. Svenson, Organizer, Presiding<br />
T. Allen, Y. Bae, Presiding<br />
8:30 Introductory Remarks<br />
8:35 87. Nanotechnology-based cancer<br />
therapeutics: View from the NCI Alliance<br />
for Nanotechnology in Cancer.<br />
P. Grodzinski, D. Farrell, K. Ptak,<br />
N. Panaro<br />
9:25 88. Multi-targeted combinations of liposomal<br />
drugs for cancer chemotherapy.<br />
T. M. Allen,E.H.Moase<br />
9:50 89. Multifunctional nanosystems for tumor<br />
imaging and therapy. M. Amiji<br />
10:15 PMSE/POLY Poster Session and Intermission<br />
10:30 90. Medicine nanoengineering: Multifunctional<br />
polymeric nanoparticles for<br />
medical applications. O. C. Farokhzad<br />
10:55 91. pH-responsive cancer nanotechnology<br />
for multidrug resistance and tumor<br />
heterogeneity. Y. H. Bae<br />
11:20 92. Cellular binding and internalization<br />
of aptamer-targeted liposomes and carbon<br />
nanotubes: What matters most?<br />
J. Van den Bossche, W. T. Al-Jamal,<br />
B. Tian, A. Nunes, K. Kostarelos<br />
11:45 93. Multifunctional lipid-based pharmaceutical<br />
nanocarriers for drugs and<br />
genes. V. P. Torchilin<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
ACS Award in the Chemistry of Materials:<br />
Symposium in Honor of Robert D. Miller<br />
Financially supported by IBM Almaden<br />
Research Center and JSR Micro<br />
A. Nelson, Organizer, Presiding<br />
8:30 94. Advanced nanostructured materials<br />
by ATRP. K. Matyjaszewski<br />
9:00 95. Identification and utilization of specific<br />
spatially-anisotropic electronic intermolecular<br />
electrostatic interactions to enhance<br />
acentric order in organic electrooptic<br />
materials. S. J. Benight,<br />
L. R. Dalton<br />
9:30 96. Hybrid organic-inorganic materials<br />
combinations and their application to unconventional<br />
printed electronic circuitry.<br />
T. J. Marks<br />
10:00 97. Using iptycenes to modify polymer<br />
properties. T. D. Swager,<br />
S. A. Sydlik<br />
10:30 PMSE/POLY Poster Session and Intermission<br />
10:45 98. Facile routes to ketene–functionalized<br />
polymers for materials applications.<br />
C. J. Hawker<br />
11:15 99. Organosilicon polymers for microelectronics.<br />
C. Wilson<br />
11:45 100. Award Address (ACS Award in<br />
the Chemistry of Materials Sponsored by<br />
E. I. du Pont de Nemours & Company).<br />
Resurgence of the stars: Synthesis and<br />
applications. R. D. Miller<br />
Section D<br />
Westin Boston Waterfront<br />
Stone<br />
Roy W. Tess Award: Symposium in Honor<br />
of Charles R. Hegedus<br />
Coatings Failure Mechanisms and<br />
Prevention Financially supported by Air<br />
Products and <strong>Chemical</strong>s, Inc.<br />
C. Schoff, Organizer, Presiding<br />
T. Provder, Presiding<br />
8:30 101. What are coatings failures? Why<br />
do they happen? What can we do about<br />
them? C. K. Schoff<br />
9:00 102. Premature film degradation of exterior<br />
architectural coatings.<br />
S. J. Pruskowski<br />
9:30 103. NIST sustainable infrastructure<br />
material program. J. W. Martin,X.Gu,<br />
T. Nguyen, J. Chin<br />
10:00 PMSE/POLY Poster Session and Intermission<br />
10:15 104. Assessment of accelerated corrosion<br />
tests compared to beachfront testing<br />
and proposed evaluation method of<br />
coated panels. K. J. Kovaleski,<br />
C. A. Matzdorf, W. C. Nickerson<br />
10:45 105. Comparison of Fe, Al, and Mg alloys<br />
electrochemical behavior by DC<br />
electrochemical techniques. T. Provder,<br />
F. L. Floyd, S. Avudaiappan, C. V. Patel,<br />
A. Thathajohnpasha, S. Tatti, S. Amin<br />
11:15 106. Coating defects: Cause and solutions.<br />
W. J. Blank<br />
11:45 107. Painting automotive plastics:<br />
Trends and technology. R. A. Ryntz<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
PMSE<br />
TECH–119
PMSE <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
Section E<br />
Westin Boston Waterfront<br />
Galleria<br />
PMSE/POLY Poster Session<br />
General Posters<br />
D. Schiraldi, Organizer, Presiding<br />
9:30–11:00<br />
108. New conjugated polymer for efficient<br />
polymer solar cells. J. Kwon,J.An,<br />
H. Jang, S. Choi, J. Park, M. Lee,<br />
D. Jung, Y. Kim<br />
109. Synthesis and characterization of new<br />
OTFT material based on terthiophene.<br />
S. Kang, D. Lee, K. So, M. Kang,<br />
H. Kang, M. Lee, Y. Kim,S.Kwon<br />
110. Antimicrobial copolyoxetanes with “A”<br />
and “B” pendant groups. A. King,<br />
S. Charkrabarty, P. Kurt, D. Ohman,<br />
L. Wood, K. J. Wynne<br />
111. Label-free FET sensor based on<br />
aptamer-conjugated polypyrrole nanotubes<br />
for vascular endothelial growth factor<br />
(VEGF) detection. O. Kwon, J. Jang<br />
112. Mechanical properties of confined polyethylene<br />
oxide nanolayers. C. Lai,<br />
R. K. Ayyer, A. Hiltner, E. Baer<br />
113. Crystallization of syndiotactic polypropylene<br />
in confined nanolayers.<br />
D. S. Langhe, A. Hiltner, E. Baer<br />
114. Characterization of bio-inspired functionally-graded<br />
materials prepared using<br />
photopolymerization. J. L. Leadore,<br />
J. A. Orlicki, K. E. Strawhecker<br />
115. Morphological changes of hollow silica<br />
by the intermolecular interactions within<br />
block copolymer micelles. H. Lee, Y. Lee,<br />
K. Char<br />
116. Multilayer deposition on patterned hydrogel<br />
particles in a droplet-based microfluidic<br />
system. M. Lee, W. Park,<br />
J. Lim, C. Chung, S. Kwon, S. Lee,<br />
H. Ahn, K. Char<br />
117. 3D culture of mesenchymal stem cells<br />
encapsulated in resilin-like polypeptide<br />
hydrogels. A. Mahara, L. Li, T. Yamaoka,<br />
K. L. Kiick<br />
118. Melt-blended aminopropylisobutyl<br />
POSS-nylon 6 composites: Role of annealing<br />
on crystallinity and thermal/mechanical<br />
properties. H. W. Milliman,<br />
D. A. Schiraldi<br />
119. Optimization of active layer thickness<br />
for high performance organic tandem solar<br />
cells by combining the optical and the<br />
charge transport models. Y. Nam,J.Huh,<br />
W. Jo<br />
MONDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom A/B<br />
WCU International Symposium on Energy<br />
Storage and Conversion<br />
Supercapacitors and Fuel Cells Financially<br />
supported by Dongjin Semichem Co., Ltd.,<br />
Office of Research Affairs, Seoul National<br />
University, and WCU Program of <strong>Chemical</strong><br />
Convergence for Energy and Environment<br />
funded by the Ministry of Education, Science<br />
and Technology (R31-10013)<br />
J. Jang, K. Char, P. Theato, Organizers<br />
J. Long, S. Oh, Presiding<br />
1:30 120. Improved performance in electrochemical<br />
supercapacitors using templated<br />
nanoporous materials.<br />
T. Brezesinski, J. Wang, R. Senter,<br />
B. Dunn, S. H. Tolbert<br />
2:00 121. Ferroelectric polymers and nanocomposites<br />
for electrical energy storage.<br />
J. Li, P. Khanchaitit, K. Han, S. I. Seok,<br />
Q. Wang<br />
‡ Cooperative Cosponsorship<br />
120–TECH<br />
2:30 122. Porous carbon materials from<br />
block copolymer precursors for supercapacitor<br />
applications. E. Kim, M. Zhong,<br />
J. P. McGann, K. Matyjaszewski,<br />
J. F. Whitacre, T. Kowalewski<br />
2:50 PMSE/POLY Poster Session and Intermission<br />
3:05 123. Block copolymer based nanostructured<br />
materials for energy storage<br />
and conversion. U. Wiesner<br />
3:35 124. Degradation mitigation in PEFCs<br />
using composite PEMs. P. Trogadas,<br />
V. K. Ramani<br />
4:05 125. Surface engineering of porous<br />
membrane by electrospinning.<br />
E. Kulkarni, P. Bajracharaya, N. K. Dutta,<br />
N. Roy Choudhury, W. M. Skinner,<br />
T. B. Issa<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Multifunctional Nanoparticles for Drug<br />
Delivery and Imaging<br />
Preparation and Characterization of<br />
Nanoparticles Financially supported by<br />
Cerulean Pharma, Inc.<br />
S. Svenson, Organizer, Presiding<br />
H. Ghandehari, S. Thayumanavan,<br />
Presiding<br />
1:30 Introductory Remarks<br />
1:35 126. Particle replication In non-wetting<br />
templates: A top-down approach to<br />
nanomedicine. J. Wang, S. Tian,<br />
E. M. Enlow, K. P. Herlihy, M. Napier,<br />
J. M. DeSimone<br />
2:00 127. Influence of nanoconstruct architecture<br />
on biodistribution in ovarian tumor-bearing<br />
mice. H. Ghandehari,<br />
A. Ray, S. Sadekar, A. Anwar,<br />
C. Peterson, M. Janat-Amsbury<br />
2:25 128. Novel synthesis of (carboxylic<br />
acid)-telechelic poly (�-caprolactone).<br />
P. T. Hammond<br />
2:50 129. Polylactide-drug nanoconjugates<br />
for cancer targeting and therapy. R. Tong,<br />
L. Tang, N. Gabrielson, T. A. Fan,<br />
J. Cheng<br />
3:15 PMSE/POLY Poster Session and Intermission<br />
3:30 130. Self-crosslinking polymer nanogels<br />
as stable delivery vehicles.<br />
S. Thayumanavan<br />
3:55 131. Paclitaxel-triazine dendrimer constructrs:<br />
Efficacy, toxicity and characterization.<br />
E. E. Simanek,X.Sun,S.Lo,<br />
J. Lim<br />
4:20 132. Novel plasma deposited stability<br />
enhancement coating for amorphous<br />
ketoprofen. S. Bosselmann,<br />
D. E. Owens III, R. L. Kennedy,<br />
M. J. Herpin, R. O. Williams III<br />
4:45 133. Preclinical characterization for<br />
translational cancer nanomedicine: Opportunities<br />
and challenges. J. Clogston,<br />
J. Zheng, A. K. Patri<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
Nano-Scaled Phenomena in Polymeric<br />
Systems<br />
Self-Assembly and Pattern Formation in<br />
Nano-Scale Financially supported by<br />
Mitsubishi <strong>Chemical</strong>, BASF, Dow <strong>Chemical</strong>,<br />
and Kaneka<br />
A. Yee, A. Takahara, J. Wong, Organizers<br />
H. Sue, Organizer, Presiding<br />
J. Douglas, Presiding<br />
1:30 Introductory Remarks<br />
1:35 134. Self-assembling nano-structure of<br />
a block copolymer studied by transmission<br />
electron tomography. H. Jinnai,<br />
H. Sugimori, K. Matsunaga, S. Hong,<br />
T. Kaneko, V. Abetz<br />
2:05 135. DNA-guided assembly of nanosystems.<br />
O. Gang<br />
2:35 136. Effect of filler addition on the texture<br />
evolution in amorphous lamellar<br />
block copolymers. H. Ryu,<br />
M. R. Bockstaller<br />
2:55 137. Gradient composition distribution<br />
of polystyrene-based polymer blends in<br />
cylindrical nanopores. H. Wu,Z.Su,<br />
A. Takahara<br />
3:15 PMSE/POLY Poster Session and Intermission<br />
3:30 138. Highly oriented and aligned line<br />
patterns from block copolymers over<br />
macroscopic distances. S. Hong, D. Lee,<br />
S. Park, T. Xu, T. P. Russell<br />
4:00 139. Morphology of block copolymer<br />
films confined by tunable surface energy<br />
elastomeric films and xerogel substrates.<br />
M. M. Kulkarni, A. Karim<br />
4:20 140. Redispersible polysiloxane-Ptnanoparticles:<br />
Synthesis, characterization<br />
and catalytic use in disiloxane hydrosilylation.<br />
B. P. Chauhan,J.S.Rathore,<br />
A. Sarkar<br />
4:40 141. Particle assembly with double-helix<br />
DNA. D. Sun, A. Stadler,<br />
D. van der Lelie, O. Gang<br />
5:00 142. Cylindical micelles and block comicelles<br />
by crystallisation-driven polymerization.<br />
J. B. Gilroy, T. Gädt,<br />
G. R. Whittell, R. M. Richardson,<br />
M. A. Winnik, I. Manners<br />
Section D<br />
Westin Boston Waterfront<br />
Stone<br />
Roy W. Tess Award: Symposium in Honor<br />
of Charles R. Hegedus<br />
Coatings Failure Mechanisms and<br />
Prevention Financially supported by Air<br />
Products and <strong>Chemical</strong>s, Inc.<br />
C. Schoff, Organizer, Presiding<br />
T. Provder, Presiding<br />
1:30 143. Inorganic nanomaterial applications<br />
in scratch resistant organic coatings.<br />
R. H. Fernando<br />
2:00 144. Prevention of defects in coatings<br />
through the proper use of foam control<br />
additives. I. K. Meier,C.J.Reader,<br />
C. R. Hegedus, C. Louis, W. Chaigneau,<br />
K.T.Lai,R.A.Snow<br />
2:30 145. Associative rheology modifier<br />
technology for zero VOC coatings and<br />
highly tinted paints. J. J. Rabasco,<br />
B. R. Bobsein, D. A. Saucy<br />
3:00 PMSE/POLY Poster Session and Intermission<br />
3:15 146. Recent advances in aliphatic<br />
moisture cure urethane coatings.<br />
E. Squiller,K.Best<br />
3:45 147. Developing a sustainable solution<br />
for scratch and mar resistance in VOC<br />
compliant automotive clearcoats.<br />
D. Bhattacharya, S. Basu, K. McCreight,<br />
N. X. Randall, R. P. Nair<br />
4:15 148. Surfactants: One of many contributing<br />
factors to a coating’s success.<br />
C. R. Hegedus,D.L.Elder<br />
Section E<br />
Westin Boston Waterfront<br />
Galleria<br />
PMSE/POLY Poster Session<br />
General Posters<br />
D. Schiraldi, Organizer, Presiding<br />
2:30–4:00<br />
149. Enhanced photostability of Hemi-22<br />
dye in solid state thin films of DNA-<br />
CTMA. D. Navarathne,Y.Ner,<br />
D. M. Niedzwiedzki, J. G. Grote,<br />
A. V. Dobrynin, H. A. Frank, G. A. Sotzing<br />
150. Weld line behaviour of exfoliated and<br />
toughened polypropylene layered silica<br />
nanocomposites. N. Nugay, O. Ersoy,<br />
S. Sen, T. Nugay<br />
151. Direct patterning of multi-component<br />
polymer brushes. Y. Xu,M.Y.Paik,<br />
M. E. Welch, C. K. Ober<br />
152. Thermal and dielectric properties of<br />
poly (methyl methacrylate–co-4-vinylpyridine):<br />
Conductivity measurements of their<br />
hydrochloride salts. K. Ouaad,<br />
H. Harrar-Ferfara, S. Djadoun<br />
153. Synthesis and characterization of novel<br />
bioactive PVP-based hydrogels.<br />
R. Fogaça,M. A. Ouimet, L. H. Catalani,<br />
K. E. Uhrich<br />
154. Synthesis and characterization of new<br />
blue copolymers containing biphenylenevinylene<br />
and triphenyldiamine.<br />
H. Park, D. Oh, S. Kang, J. Jang, Y. Kim,<br />
S. Kwon<br />
155. Impedance biosensor based on inkjet<br />
printed silver for the detection of antibodies<br />
to a peptide allergen. J. Park,H.Liu,<br />
V. Palumbo, G. Jensen, M. Peczuh,<br />
J. F. Rusling, G. A. Sotzing<br />
156. Organic aerogels derived from the radical<br />
polymerization of bis- and triacrylamides.<br />
S. Park, S. Hwang, K. Kim,<br />
M. D. Cho<br />
157. Self-assembly of chain-end functionalized<br />
responsive polymers synthesized by<br />
RAFT. A. O. Moughton, J. P. Patterson,<br />
R. K. O’Reilly<br />
158. Creation of multifunctional nanoparticle<br />
systems for cancer therapy using layerby-layer<br />
assembly. Z. Poon,<br />
P. T. Hammond<br />
159. Non-woven nylon nanofiber mat as reinforcement<br />
to polyaniline films.<br />
A. Romo-Uribe, L. Arizmendi,<br />
M. E. Romero-Guzman, S. Sepulveda,<br />
R. Cruz-Silva<br />
160. Polymer-derived ceramic composite fibers<br />
with aligned pristine multiwalled carbon<br />
nanotubes. S. Sarkar,J.Zou,C.Xu,<br />
J. Liu, L. An, L. Zhai<br />
AES Science and Technology<br />
Hydrogen as a Resource Sponsored by<br />
COMSCI, Cosponsored by CATL<br />
(probationary), FUEL, I&EC, INOR, and PMSE<br />
MONDAY EVENING<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
D. Schiraldi, Organizer, Presiding<br />
8:00–10:00<br />
36, 38, 40, 41, 71, 72, 73, 74, 75, 76, 77, 79,<br />
80, 108, 111, 112, 113, 117, 118, 149,<br />
151, 153, 157, 159. See previous listings.<br />
192, 195, 196, 197, 198, 199, 200, 202, 245,<br />
278, 279, 280, 282. See subsequent listings.<br />
TUESDAY MORNING<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
Nano-Scaled Phenomena in Polymeric<br />
Systems<br />
Novel Properties Developed due to Nano-<br />
Scale Financially supported by Mitsubishi<br />
<strong>Chemical</strong>, BASF, Dow <strong>Chemical</strong>, and Kaneka<br />
A. Takahara, H. Sue, J. Wong, Organizers<br />
O. Gang, Presiding<br />
A. Yee, Organizer, Presiding<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
8:00 161. Energy release and the induced<br />
ultrahigh optoelectronic enhancements in<br />
metastable polymer films by spin coating.<br />
A. C. Yang, C. C. Chang, P. Lee,<br />
C. H. Tsao, G. Reiter, C. Yuan, J. Tang,<br />
T. L. Lin<br />
8:30 162. Electrical percolation and resistive<br />
switching in silver nanowire-polystyrene<br />
composites. K. I. Winey<br />
9:00 163. Tribiological properties of super<br />
hydrophilic polymer brushes under wet<br />
conditions. M. Kobayashi, M. Terada,<br />
A. Takahara<br />
9:20 164. Recognition of asymmetric nanoclusters<br />
by DNA functionalized surfaces.<br />
C. Chi, D. van der Lelie, O. Gang<br />
9:40 165. Thermal conductivity of nanoscale<br />
polyaniline films. J. Jin, M. P. Manohara,<br />
A. M. Haque, Q. Wang<br />
10:00 PMSE/POLY Poster Session and Intermission<br />
10:15 166. All-conjugated block copolymers<br />
and conjugated polymer/nanocrystal<br />
nanocomposites: From synthesis, selfassembly<br />
to energy application. Z. Lin,<br />
M. He, L. Zhao, F. Qiu, Y. Yang<br />
10:45 167. Nanostructured hybrid materials<br />
based on phosphonic acid derivatives of<br />
terthiophene and imogolite nanotubes.<br />
W. Yah, A. Irie, H. Otsuka, A. Takahara<br />
11:05 168. Layer-by-layer assembly of pHresponsive<br />
diblock copolymer micelles<br />
with temperature-dissolvable cores.<br />
L. Xu, Z. Zhu, S. Sukhishvili<br />
11:25 169. Solvent-free nanofluids as versatile<br />
colloids and ionic liquids. J. Texter,<br />
K. Bian, D. Chojnowski, J. Byrom<br />
Section A<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom A/B<br />
WCU International Symposium on Energy<br />
Storage and Conversion<br />
Solar Cells Financially supported by Dongjin<br />
Semichem Co., Ltd., Office of Research<br />
Affairs, Seoul National University, and WCU<br />
Program of <strong>Chemical</strong> Convergence for Energy<br />
and Environment funded by the Ministry of<br />
Education, Science and Technology (R31-<br />
10013)<br />
J. Jang, K. Char, P. Theato, Organizers<br />
J. Pyun, J. Loos, Presiding<br />
8:30 170. 1D TiO 2 nanostructures for dyesensitized<br />
solar cells. S. Kang, J. Kim,<br />
Y. Sung<br />
9:00 171. Improving efficiency of dye-sensitized<br />
solar cells (DSCs) with energy relay<br />
dyes and light trapping. M. D. McGehee,<br />
M. Grätzel, B. E. Hardin, I. Ding<br />
9:30 172. Selective alignment of dyes for<br />
panchromatic dye-sensitized solar cells.<br />
N. Park, K. Lee, M. Ko, K. Kim<br />
10:00 PMSE/POLY Poster Session and Intermission<br />
10:15 173. Morphological effects on polymer-based<br />
solar cell performance. J. Kiel,<br />
M. E. Mackay, D. Olds, P. M. Duxbury<br />
10:45 174. Template-assisted fabrication of<br />
free-standing nanorod arrays based upon<br />
organic semiconductors for organic solar<br />
cells. N. Haberkorn, P. Theato<br />
11:15 175. Organic-inorganic and organicorganic<br />
interfaces in organic solar cells.<br />
J. Bredas<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Multifunctional Nanoparticles for Drug<br />
Delivery and Imaging<br />
RNAi and Biologics Delivery Financially<br />
supported by Cerulean Pharma, Inc.<br />
S. Svenson, Organizer, Presiding<br />
D. Thompson, K. Miyata, Presiding<br />
8:30 Introductory Remarks<br />
8:35 176. Multimerized siRNA: Novel strategy<br />
for efficient gene silencing. T. Park<br />
9:00 177. Development of a nucleic acid<br />
vector based on non-covalent assembly<br />
of bioresponsive poly(ethylene glycol)poly(vinylalcohol)-adamantane:amino-bcyclodextrin<br />
complexes. D. Wei,<br />
A. Kulkarni, D. H. Thompson<br />
9:25 178. Development of advanced polymer-based<br />
nanodevices for nucleic acids<br />
delivery. K. Miyata, T. Nomoto,<br />
H. Takemoto, H. Kim, Y. Matsumoto,<br />
M. Oba, N. Nishiyama, K. Kataoka<br />
9:50 179. Highly tunable modular dendrons<br />
for DNA binding and delivery. D. K. Smith<br />
10:15 PMSE/POLY Poster Session and<br />
Intermission<br />
10:30 180. High-throughput synthesis of<br />
core-shell nanoparticles for siRNA delivery.<br />
D. J. Siegwart, L. Nuhn, S. Jiang,<br />
A. Vegas, K. Whitehead, P. Fenton,<br />
M. Ma, H. Cheng, K. Love, S. P. Collins,<br />
Y. Li, J. Jang, R. S. Langer,<br />
D. G. Anderson<br />
10:55 181. Nanocarrier cross-linking density<br />
and pH sensitivity regulate intracellular<br />
gene transfer. J. You, D. T. Auguste<br />
11:20 182. Efficient gene delivery using acid-responsive<br />
lipid envelopes for adenovirus.<br />
J. Van den Bossche,<br />
W. T. Al-Jamal, A. Yilmazer, B. Tian,<br />
K. Kostarelos<br />
11:40 183. Synthetic organic nanotubes as<br />
drug delivery vehicles. K. Huang,<br />
J. Rzayev<br />
12:00 184. Synthesis of novel glycopolymers<br />
and glyconanoparticles for biomolecular<br />
recognition processes. Z. Deng,<br />
S. Li, X. Jiang, R. Narain<br />
Section D<br />
Westin Boston Waterfront<br />
Hancock<br />
Novel Polymeric and Nanocomposite<br />
Materials for Defense and Energy<br />
Design and Fabriation of<br />
Composite/Membrane Materials Financially<br />
supported by Air Force Office of Scientific<br />
Research, Eastman <strong>Chemical</strong> Company,<br />
Office of Naval Research, PPG Industries<br />
Foundation, and Army Research Office<br />
P. Costanzo, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 185. Hierarchically structured polymer<br />
composites: Broadly enabling multifunctional<br />
materials. J. L. Lenhart, R. Mrozek,<br />
M. Berg, J. Andzelm, Y. Sliozberg,<br />
K. R. Shull, K. Otim<br />
9:00 186. Modification and characterization<br />
of chemical microenvironments for enzyme<br />
immobilization. M. J. Cooney,<br />
S. D. Minteer<br />
9:20 187. Nanomaterial enabled performance<br />
enhancements for Army coating<br />
and composite systems. J. A. Orlicki,<br />
A. A. Williams, N. E. Zander, W. E. Kosik,<br />
G. R. Martin, F. Levine, J. Escarsega,<br />
A. Farrell, A. M. Rawlett<br />
9:45 PMSE/POLY Poster Session and Intermission<br />
10:15 188. Synthesis and characterization of<br />
allyl-functional polycarbonates and polycarbonate/polysiloxane<br />
block copolymers.<br />
P. Majumdar, H. Bao, R. Sharma,<br />
E. Crowley, J. Bahr, B. J. Chisholm<br />
10:35 189. Porous epoxies formed from reaction<br />
induced phase separation with<br />
block copolymer porogens.<br />
A. B. Schoch, J. L. Lenhart<br />
10:55 190. Proton conductive polymer networks<br />
with high electrochemical selectivity.<br />
K. Xu, C. Chanthad, M. A. Hickner,<br />
Q. Wang<br />
11:15 191. Atomistic simulations of novel<br />
proton exchange membranes for fuel cell<br />
applications. C. V. Mahajan, V. Ganesan<br />
Section E<br />
Westin Boston Waterfront<br />
Galleria<br />
PMSE/POLY Poster Session<br />
Novel Polymeric and Nanocomposite<br />
Materials for Defense and Energy and<br />
General Posters<br />
P. Costanzo, D. Schiraldi, Organizers,<br />
Presiding<br />
9:30–11:00<br />
General Posters<br />
192. Temperature and stoichiometry effects<br />
in Cp2ZrClH-catalyzed living ring opening<br />
polymerization of �-caprolactone.<br />
A. D. Asandei, G. Saha, O. Adebolu<br />
193. Permeability of poly(ether block amide)<br />
(PEBAX): Effect of orientation.<br />
S. R. Armstrong, D. R. Paul, A. Hiltner,<br />
E. Baer<br />
194. Characterization of polymer blends for<br />
proton exchange membranes.<br />
B. Ince-Gunduz, J. Pan, R. Nawrocki, Jr.,<br />
C. Sloan, A. Speranza, J. Wilson,<br />
T. W. Smith, P. Cebe<br />
195. Phase structure of electrospun poly(trimethylene<br />
terephthalate) composite<br />
nanofibers containing carbon nanotubes.<br />
Q. Ma, P. Cebe<br />
196. Silver nanocomposites of functionalized<br />
polymerizable silica precursor.<br />
M. Chauhan,E.Kim,M.Kaur<br />
197. Top-down meets bottom-up: Self-assembly<br />
of patternable block copolymers.<br />
M. A. Chavis, J. K. Bosworth, X. Andre,<br />
M. Paik, E. L. Schwartz, C. K. Ober<br />
198. Electrical properties and nanomorphology<br />
of well-defined conjugated polymer<br />
brushes. J. Chen,J.Alonzo,X.Yu,<br />
K. Hong, J. M. Messman, I. Ivanov,<br />
H. M. Meyer, M. Banerjee, R. Rathore,<br />
J. W. Mays, S. Kilbey<br />
Novel Polymeric and Nanocomposite<br />
Materials for Defense and Energy Posters<br />
199. Progress towards cyclopentadienyl lithium<br />
interactions as a novel supramolecular<br />
synthon. J. T. Foy<br />
200. Smart polymer-protein conjugates by<br />
RAFT polymerization and activated ester<br />
chemistry. H. Li, M. Li, A. P. Bapat,<br />
B. S. Sumerlin<br />
201. Electrospinning sheath-core structure<br />
based on poly(vinyl pyrrolidone) and multiwall<br />
carbon nanotubes. J. Miao,<br />
M. Miyauchi, T. J. Simmons,<br />
J. S. Dordick, R. J. Linhardt<br />
202. Encapsulation of Ag(I) N-heterocyclic<br />
carbene complexes with poly(lactic-coglycolic<br />
acid) (PLGA) and polyethylene<br />
glycol (PEG) using nanoprecipitation<br />
methods and studying effects on cancer<br />
cell lines. N. K. Robishaw, M. J. Panzner,<br />
D. M. Besse, M. Deblock, A. J. Ditto,<br />
Y. H. Yun, W. J. Youngs<br />
203. Polyacrylonitrile electrospun membrane<br />
for microfiltration. R. Wang, Y. Liu,<br />
H. Ma, D. Fang, B. S. Hsiao, B. Chu<br />
Polymer Science and Energy: Current<br />
Directions and Future Opportunities<br />
Sponsored by POLY, cosponsored by PMSE<br />
TUESDAY AFTERNOON<br />
Section D<br />
Westin Boston Waterfront<br />
Hancock<br />
Novel Polymeric and Nanocomposite<br />
Materials for Defense and Energy<br />
Synthesis and Application of<br />
Nanocomposite Materials Financially<br />
supported by Air Force Office of Scientific<br />
Research, Army Research Office, Eastman<br />
<strong>Chemical</strong> Company, Office of Naval Research,<br />
and PPG Industries Foundation<br />
P. Costanzo, Organizer, Presiding<br />
1:00 204. Strategies for loading nanocomposite<br />
materials. K. K. Stokes,<br />
M. C. Berg, F. L. Beyer, J. L. Lenhart<br />
1:25 205. Additive-driven assembly of block<br />
copolymer/nanoparticle composites.<br />
Y. Lin<br />
1:45 206. Functional polymer-based materials<br />
through controlled polymerization<br />
methods. R. B. Grubbs<br />
2:10 207. Quasi-transparent particle fillers<br />
for low scattering composite materials.<br />
S. Ojha, B. Hui, K. Matyjaszewski,<br />
M. R. Bockstaller<br />
2:35 PMSE/POLY Poster Session and Intermission<br />
3:05 208. Nanoparticle dispersion and energy<br />
damping in polymer composites.<br />
A. D. Richardson, O. McNair, G. Strange,<br />
P. J. Costanzo, D. A. Savin<br />
3:30 209. Network constrained surface<br />
phase separation. W. Zhang, C. Wang,<br />
K. J. Wynne<br />
3:55 210. Indirect reinforcement in polymer<br />
nanocomposites. M. E. Mackay<br />
Section A<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom A/B<br />
WCU International Symposium on Energy<br />
Storage and Conversion Solar Cells<br />
Financially supported by Dongjin Semichem<br />
Co., Ltd., Office of Research Affairs, Seoul<br />
National University, and WCU Program of<br />
<strong>Chemical</strong> Convergence for Energy and<br />
Environment funded by the Ministry of<br />
Education, Science and Technology (R31-<br />
10013)<br />
J. Jang, K. Char, Organizers<br />
P. Theato, Organizer, Presiding<br />
Y. Sung, Presiding<br />
1:30 211. Interfacial aspects of polymer<br />
based photovoltaic structures. D. Chen,<br />
T. P. Russell<br />
2:00 212. Effect of additives on nanostructures<br />
in bulk heterojunction polymer cells.<br />
M. Dante, T. Nguyen<br />
2:30 213. Commercialization and industrialization<br />
in DSCs. C. Lee<br />
3:00 PMSE/POLY Poster Session and Intermission<br />
3:15 214. 3D nanoscale organization of<br />
printable solar cells. S. S. van Bavel,<br />
J. Loos<br />
3:45 215. Conjugated polymer/carbon<br />
nanotube composites. L. Zhai<br />
4:15 216. Nanostructured hybrid polymer/<br />
phage templates for the construction of<br />
dye-sensitized solar cells. R. A. Miller,<br />
R. Ladewski, F. Liau, P. T. Hammond,<br />
A. Belcher<br />
4:35 217. Improved crystalline orientation of<br />
poly(3-hexyl thiophene) in bulk heterojunction<br />
polymer solar cells. J. Seok,<br />
M. Balik, H. W. Ade<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Multifunctional Nanoparticles for Drug<br />
Delivery and Imaging<br />
Preclinical and Clinical Applications<br />
Financially supported by Cerulean Pharma,<br />
Inc.<br />
S. Svenson, Organizer, Presiding<br />
P. Lim Soo, S. Eliasof, Presiding<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
PMSE<br />
TECH–121
PMSE <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
1:30 Introductory Remarks<br />
1:35 218. Development of potent stable nucleic<br />
lipid particle (SNALP) formulations<br />
for therapeutic siRNA delivery.<br />
S. C. Semple, A. Lee, A. D. Judge,<br />
J. Heyes, E. Yaworski, L. B. Jeffs,<br />
M. Robbins, L. R. Palmer, S. K. Klimuk,<br />
I. MacLachlan<br />
2:00 219. Phospholipid nanosomes and<br />
polymer nanospheres for the nanotechnology<br />
delivery of biologics, siRNA and<br />
hydrophobic anticancer drugs.<br />
T. P. Castor<br />
2:25 220. Drug delivery systems for combination<br />
chemotherapy: Challenges and<br />
opportunities. L. D. Mayer<br />
2:50 221. CRLX288, a novel polymeric<br />
nanoparticle, significantly improves the<br />
therapeutic window over the parent drug<br />
in preclinical studies in mice. S. Eliasof,<br />
P. Ng, P. Lim Soo, J. Podobinski,<br />
G. Gangal, R. I. Case, P. Shum,<br />
J. G. Martínez, S. R. Kabir, D. Lazarus,<br />
S. Svenson<br />
3:15 222. Rationale for design and early<br />
clinical development of IT-101, a cyclodextrin-polyethylene-glycol<br />
copolymer<br />
nanoparticle delivery of camptothecin.<br />
M. Wolfgang, J. Hwang, S. Svenson,<br />
J. Ryan, T. Synold, Y. Yen<br />
3:40 PMSE/POLY Poster Session and Intermission<br />
3:55 223. High-precision therapeutics<br />
through Medicinal Nanoengineering .<br />
J. Hrkach<br />
4:20 224. Applications of biodegradable and<br />
biocompatible polyacetal drug conjugates<br />
to improve drug delivery.<br />
T. B. Lowinger<br />
4:45 225. Cobalamin nanoparticles for oral<br />
and target drug delivery. R. Zarzycki,<br />
P. Sood, N. Ummaneni, J. L. Gerberich,<br />
D. P. Nowotnik<br />
5:10 226. Development of stable polymer<br />
micelles for the treatment of cancer.<br />
H. Skaff, J. Rios-Doria, A. Carie,<br />
G. Cardoën, B. Burke, K. Sill<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
Nano-Scaled Phenomena in Polymeric<br />
Systems<br />
Physics of Confined Polymers Financially<br />
supported by Mitsubishi <strong>Chemical</strong>, BASF,<br />
Dow <strong>Chemical</strong>, and Kaneka<br />
A. Yee, H. Sue, J. Wong, Organizers<br />
K. Char, Presiding<br />
A. Takahara, Organizer, Presiding<br />
1:30 227. Segmental motion of polystyrene<br />
in its thin film studied by de-focus single<br />
molecule fluorescence microscopy.<br />
Z. Zheng, J. Zhao<br />
2:00 228. Dramatic effects of nanoscale<br />
confinement on glass transition temperature,<br />
physical aging, and diffusion in polymer<br />
flims and nanocomposites.<br />
J. M. Torkelson, S. Kim, H. Deng,<br />
C. M. Evans, R. D. Priestley,<br />
P. Rittigstein, M. K. Mundra, C. B. Roth<br />
2:30 229. Crystallization studies of linear<br />
polymers in carbon nanotube dispersions.<br />
M. L. Minus,S.Kumar<br />
2:50 230. Sharp lower critical solution temperature<br />
transition for novel N-isopropylacrylamide<br />
based polymer. M. E. Alf,<br />
T. Hatton, K. K. Gleason<br />
3:10 231. Using hydrogel stamping to explore<br />
nanoscale porosity formation in<br />
polyelectrolyte multilayers. C. Cho,<br />
N. S. Zacharia<br />
3:30 PMSE/POLY Poster Session and Intermission<br />
‡ Cooperative Cosponsorship<br />
122–TECH<br />
3:45 232. Crowding effects on protein and<br />
nanoparticle solubility, relaxation and rate<br />
processes in fluid mixtures and entropyenthalpy<br />
compensation. J. F. Douglas,<br />
J. Dudowicz, K. F. Freed<br />
4:15 233. Visualizing the motion of polymer<br />
chains at an interface. J. S. Wong<br />
4:35 234. Molecular dynamics study of<br />
block copolymer thin film morphology:<br />
Effect of substrate and free surface.<br />
C. Forrey, K. G. Yager<br />
4:55 235. Fabrication and characterization<br />
of PMMA grafted imogolite nanotubes.<br />
W. Ma, H. Otsuka, A. Takahara<br />
Section E<br />
Westin Boston Waterfront<br />
Galleria<br />
PMSE/POLY Poster Session<br />
General Posters<br />
D. Schiraldi, Organizer, Presiding<br />
2:30–4:00<br />
236. Structural characterization of water soluble<br />
derivatives of cisplatin drugs from<br />
chelation with chitosan. C. E. Carraher,<br />
Jr., A. Francis Robinson<br />
237. 1 H NMR spectroscopy of organotin<br />
polyethers derived from dibutyltin dichloride<br />
and poly(ethylene glycols).<br />
C. E. Carraher, Jr., G. Barot<br />
238. Development of new interfacial system<br />
for the synthesis of ciprofloxacin-containing<br />
organotin poly(ether amines). A. Zhao,<br />
C. E. Carraher, Jr.<br />
239. Enhanced solubility of ciprofloxacin organotin<br />
poly(ether amines). A. Zhao,<br />
C. E. Carraher, Jr.<br />
240. Synthesis of water soluble derivatives<br />
of cisplatin drugs from chelation with chitosan.<br />
C. E. Carraher, Jr.,<br />
A. Francis Robinson<br />
241. Chain length calculations for water soluble<br />
derivatives of cisplatin drugs from<br />
chelation with chitosan.<br />
C. E. Carraher, Jr., A. Francis Robinson<br />
242. Thermal properties of the products of<br />
lignin and organotin halides.<br />
C. E. Carraher, Jr., D. C. Sterling<br />
243. Electrical properties of the products of<br />
lignin and organotiin halides.<br />
C. E. Carraher, Jr., D. C. Sterling<br />
244. Organotin polyether structural similarities<br />
in the inhibiiton of estrogen-sensitive<br />
MCF-7 and non-estrogen-sensitive MDA<br />
cancer cells. M. R. Roner,<br />
C. E. Carraher, Jr., K. Shahi, G. Barot<br />
245. Nanotube forests for electrochemical<br />
energy storage from electrostatic assembly.<br />
L. Shao, W. Jang, J. L. Lutkenhaus<br />
246. Fluorescein derivatives functionalized<br />
silsesquioxnae/bridged silsesquioxane<br />
nanoparticles: Synthesis, characterization<br />
and particle morphology. C. J. Simouth,<br />
J. Binion, H. P. Rathnayake<br />
WEDNESDAY MORNING<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
Nano-Scaled Phenomena in Polymeric<br />
Systems<br />
Nano-Mechanical Behaviour and<br />
Nanocomposites Financially supported by<br />
Mitsubishi <strong>Chemical</strong>, BASF, Dow <strong>Chemical</strong>,<br />
and Kaneka<br />
A. Yee, A. Takahara, H. Sue, Organizers<br />
J. Wong, Organizer, Presiding<br />
J. Zhao, Presiding<br />
8:00 247. Development and applications of<br />
polymer nanocomposites. A. Usuki<br />
8:30 248. Characterization of nanomechanical<br />
behavior of glassy polymers. L. Chen,<br />
Y. Kong, A. F. Yee<br />
8:50 249. Strain hardening induced by polymer<br />
nanoparticles in PA6.<br />
E. Huitrón-Rattinger, A. Romo-Uribe,<br />
M. E. Romero-Guzmán<br />
9:10 250. Nanoscaled deformations in block<br />
copolymer modified epoxies. D. Liu,<br />
H. Sue, Z. J. Thompson, F. S. Bates,<br />
M. A. Hillmyer, M. Dettloff, G. Jacob,<br />
N. Verghese, H. Pham<br />
9:30 251. Properties of poly(3-hexyl thiophene)<br />
under nano-confinement in the array<br />
of ordered TiO 2 nanotubes.<br />
T. R. Foong, A. Sellinger, Y. Shen, X. Hu<br />
9:50 PMSE/POLY Poster Session and Intermission<br />
10:05 252. Ultrathin multilayer thin films<br />
containing nano-objects. K. Char<br />
10:35 253. Preparation of nanocomposites<br />
with in situ synthesized nanoplatelets.<br />
C. S. Southworth, M. F. Milner, L. Sun<br />
10:55 254. Strengthening of epoxy based on<br />
hybrid nanofillers of MWCNT and clay.<br />
D. Sun, C. Chu, H. Sue<br />
11:15 Concluding Remarks<br />
Section D<br />
Westin Boston Waterfront<br />
Stone<br />
Novel Polymeric and Nanocomposite<br />
Materials for Defense and Energy<br />
Fabriaction of Electronic Materials<br />
Financially supported by Air Force Office of<br />
Scientific Research, Army Research Office,<br />
Eastman <strong>Chemical</strong> Company, Office of Naval<br />
Research, and PPG Industries Foundation<br />
P. Costanzo, Organizer, Presiding<br />
8:00 255. Flexible, stretchable, and foldable<br />
electrodes for organic photovoltaics via<br />
oxidative chemical vapor deposition.<br />
M. C. Barr, C. M. Boyce, K. K. Gleason<br />
8:20 256. All-organic electrochromic fabric<br />
for wearable displays. Y. Ding,<br />
M. A. Invernale, G. A. Sotzing<br />
8:40 257. Simple method for making electrochromic<br />
devices containing novel conjugated<br />
polymer chromophores.<br />
M. A. Invernale, K. Lee, Y. Ding, T. Dey,<br />
D. Mamangun, G. A. Sotzing<br />
9:00 258. Series of new vinylene based conjugated<br />
polymers with sulfone phenylene<br />
and different donor co-monomers for energy<br />
applications. T. Nguyen, C. Zhang,<br />
R. Li, S. Sun<br />
9:20 259. Electroactive polymer brushes<br />
and nanocomposite films on ITO electrodes.<br />
B. Kim, R. Shallcross,<br />
N. R. Armstrong, J. Pyun<br />
9:45 PMSE/POLY Poster Session and Intermission<br />
10:15 260. Morphology study of PCBM/<br />
P3HT organic photovoltaic with small angle<br />
neutron scattering. W. Yin,<br />
M. Dadmun<br />
10:35 261. Soluble pegylated polythiophenes:<br />
Synthesis and nitroaromatic<br />
sensing. A. Kokil, T. Ponrathnam,<br />
A. Kumar, R. Nagarajan, J. Kumar<br />
10:55 262. Ternary phase behavior of P3HTb-PEO<br />
compatibilized P3HT/PCBM films.<br />
J. Chen, X. Yu, K. Hong, J. M. Messman,<br />
D. L. Pickel, K. Xiao, B. Sumpter,<br />
M. D. Dadmun, J. W. Mays, S. Kilbey<br />
11:15 263. Functionalized quantum dots<br />
and nanoparticle-polymer composites.<br />
C. Miesch, I. Kosif, J. Lawrence,<br />
T. Emrick<br />
11:40 Concluding Remarks<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Simulation of Hybrid Interfaces and Multi-<br />
Component Polymeric Materials<br />
Biointerfaces Cosponsored by COMP<br />
Financially supported by National Science<br />
Foundation<br />
R. Berry, Organizer<br />
H. Heinz, Organizer, Presiding<br />
8:30 264. Effects of single point mutations<br />
on peptide-mineral interactions: A combined<br />
experimental and computational<br />
approach. C. C. Perry<br />
9:05 265. Is variety the spice of life? Multiscale<br />
molecular simulations support experiments<br />
in nanocarrier/nucleic acid systems<br />
design. P. Posocco, M. Fermeglia,<br />
X. Liu, L. Peng, A. Malek, C. V. Catapano,<br />
D. K. Smith, S. Pricl<br />
9:40 266. Nature of molecular binding at the<br />
peptide/solid hybrid interfaces.<br />
M. Sarikaya, R. Samudrala, A. Jen,<br />
J. S. Evans, C. Tamerler<br />
10:15 PMSE/POLY Poster Session and Intermission<br />
10:30 267. Multiscale simulation of proton<br />
exchange membranes. G. A. Voth<br />
11:05 268. Force-field development for<br />
computer simulation of biomolecular systems:<br />
The GROMOS case. D. Steiner,<br />
W. F. van Gunsteren<br />
11:30 269. Interactions of peptides and<br />
ionic liquids with silica. R. Berry<br />
Section A<br />
Westin Boston Waterfront<br />
Hancock<br />
General Papers/New Concepts in<br />
Polymeric Materials<br />
Energy/Responsive Polymers<br />
D. Schiraldi, Organizer, Presiding<br />
9:00 270. Characterization of perflourocyclobutane/polyvinylidene<br />
diflouride<br />
(PFCB/PVDF) blends for use as fuel cell<br />
proton exchange membranes.<br />
K. A. Finlay, D. A. Dillard, R. B. Moore,<br />
S. W. Case, M. W. Ellis, Y. Li, T. J. Fuller,<br />
S. M. Mackinnon, C. S. Gittleman, Y. Lai<br />
9:20 271. ESR detection of early events in<br />
the fragmentation of perfluorinated model<br />
compounds and relevance to the stability<br />
of polymeric membranes used in fuel<br />
cells. S. Schlick, M. Spulber<br />
9:40 272. <strong>Chemical</strong> degradation studies of<br />
aromatic model compounds for fuel cell<br />
membrane applications. D. M. Savant,<br />
T. A. Zaowdzinski Jr., D. A. Schiraldi<br />
10:00 PMSE/POLY Poster Session and Intermission<br />
10:20 273. Amine-functionalized polymeric<br />
nanocoatings for hydrolytically stable microfluidic<br />
devices. J. Xu, K. Gleason<br />
10:40 274. Hardblock-free thermoplastic<br />
polyurethanes (TPUs) exhibiting shape<br />
memory. X. Gu, P. T. Mather<br />
11:00 275. Study of the nanophase structure<br />
of poly(methacrylic acid) brushes<br />
synthesized via ATRP. E. Soto-Cantu,<br />
C. Deodhar, D. Uhrig, J. P. Hinestrosa,<br />
B. S. Lokitz, J. F. Ankner, S. M. Kilbey<br />
11:20 276. Amphiphilic polyurethanes: Synthesis,<br />
properties, and responsive behavior.<br />
A. Kohut, I. Hevus, A. Voronov<br />
11:40 277. Amphiphilic invertible polymers<br />
for adsolubilization on solid substrates of<br />
different polarity. A. Kohut, A. Voronov,<br />
V. Kislenko, L. Sieburg<br />
Section E<br />
Westin Boston Waterfront<br />
Galleria<br />
PMSE/POLY Poster Session<br />
General Posters<br />
D. Schiraldi, Organizer, Presiding<br />
9:30–11:00<br />
278. Cross-linked PB-PEO hybrid micelles<br />
for targeted delivery. T. P. Smart,<br />
E. G. Kelley, M. O. Sullivan, T. H. Epps III<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
279. Fabrication of cationic polymer nanoparticles<br />
and their antimicrobial properties.<br />
J. Song, H. Kong, J. Jang<br />
280. Copolymer systems for graded index<br />
plastic optical fiber materials. H. Teng,<br />
Y. Okamoto<br />
281. Assemblies of gold nanorods via DNA<br />
hybridization. S. Vial, D. Nykypanchuk,<br />
O. Gang<br />
282. Physical characterizations and biocompatibility<br />
of poly(propylene fumerate)/<br />
methacryl-polyhedral oligomeric silsesquioxane<br />
blends. K. Wang, S. Wang<br />
283. Rheological properties of poly(�-caprolactone)<br />
and its homo-blends. K. Wang,<br />
L. Cai, S. Wang<br />
284. Novel hyperbranched polyester as a<br />
nano-modifier on properties of poly(�-caprolactone).<br />
Y. Wang, H. Wang, Y. Chen,<br />
P. Lee, C. Huang, J. H. Xin, K. Cheuk<br />
285. Synthesis of biocompatible block copolymers<br />
using well-defined polyphosphoester<br />
macroinitiators. E. Yamaguchi,<br />
Y. Iwasaki<br />
286. Effect of carbon fiber and SiC powder<br />
on the ablation properties of the silicone<br />
rubber. E. Kim, T. Lee, S. Shin, K. Kim,<br />
J. Yoon<br />
287. Butadiene initiation with late and early<br />
transition metals from activated halides.<br />
A. D. Asandei, H. S. Yu,C.P.Simpson<br />
288. Polystyrene-polylactide bottlebrush<br />
block copolymer at the air/water interface.<br />
L. Zhao, M. Byun, J. Rzayev, Z. Lin<br />
289. Self-assembly of ultrahigh molecular<br />
weight comb block copolymer at the air/<br />
water interface. L. Zhao, N. B. Bowden,<br />
Z. Lin<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Westin Boston Waterfront<br />
Hancock<br />
General Papers/New Concepts in<br />
Polymeric Materials<br />
Block Copolymers/Assembly<br />
D. Schiraldi, Organizer<br />
K. Wynne, Presiding<br />
1:30 290. Evaulation of the elastomeric<br />
phase development in the synthesis of<br />
high impact polystyrene using model<br />
block copolymers. C. de Anda,<br />
G. Morales, J. Sosa, D. Knoeppel,<br />
C. Garces, R. P. Quirk<br />
1:50 291. Using forced assembly co-extrusion<br />
to confine the self-assembly of elastomeric<br />
block copolymers to enhance<br />
material toughness. T. M. Burt, A. Hiltner,<br />
E. Baer, L. T. Korley<br />
2:10 292. Influence of soft segment molecular<br />
weight on the phase separation of<br />
polyurethane based polymer surface<br />
modifiers with polyoxetane soft segments.<br />
K. M. Brunson, A. Chakravorty,<br />
K. J. Wynne<br />
2:30 293. Directed silica assembly by functionalized<br />
block copolymer based Silicatein<br />
� mimic at neutral pH. G. Macek,<br />
D. H. Adamson<br />
2:50 Intermission<br />
3:10 294. Synthesis and controlled assembly<br />
of nano-rods with hydrodynamic<br />
forces. L. Zhang, J. L. Lutkenhaus<br />
3:30 295. Stimulus-responsive ultrasound<br />
contrast agents from microbubbles stabilized<br />
by polymer-phospholipid assemblies.<br />
A. P. Goodwin, M. A. Nakatsuka,<br />
M. J. Hsu, R. F. Mattrey, S. C. Esener,<br />
J. N. Cha<br />
3:50 296. Confinement effects on the thermochemical<br />
properties of layer-by-layer<br />
assemblies. W. Jang,L.Shao,T.Goh,<br />
J. Lutkenhaus<br />
4:10 297. Preparation of nanostructured titanium<br />
dioxide using block copolymer<br />
templates. P. S. Chinthamanipeta,<br />
Q. Lou, D. A. Shipp<br />
4:30 298. Dynamic viscoelasticity and concentration<br />
dependence of micelle-gel<br />
transition of S mNtBAM n diblock copolymer<br />
solutions. N. Sharma,R.M.Kasi<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Simulation of Hybrid Interfaces and Multi-<br />
Component Polymeric Materials<br />
Multiscale Simulation of Polymeric<br />
Materials Cosponsored by COMP Financially<br />
supported by National Science Foundation<br />
H. Heinz, Organizer<br />
R. Berry, Organizer, Presiding<br />
1:30 299. Exploring peptide-surface binding:<br />
A molecular simultation perspective.<br />
T. Walsh, R. Notman, S. M. Tomasko<br />
2:05 300. Multiscale modeling paradigm for<br />
complex materials and their interfaces.<br />
T. Cagin<br />
2:40 301. NanoModel: Multiscale modeling<br />
of nanostructured polymeric materials.<br />
H. Weiss<br />
3:15 Intermission<br />
3:30 302. Molecular dynamics simulation of<br />
thermoset fracture with micromechanics<br />
analysis integration. J. C. Moller,<br />
L. Ward, V. Bechel, R. Berry,<br />
T. Breitzman, E. Iarve, D. Mollenhauer,<br />
M. Unroe<br />
4:05 303. From the atomistic to the mesoscale<br />
and back: Hierarchical simulation<br />
models for multicomponent systems.<br />
C. Peter, K. Kremer<br />
4:30 304. Multiscale molecular modeling: A<br />
nano-engineering tool for the design of<br />
hybrid organic/inorganic materials.<br />
S. Pricl<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
General Papers/New Concepts in<br />
Polymeric Materials<br />
Conductive/Electronic Polymers<br />
D. Schiraldi, Organizer<br />
T. J. Simmons, Presiding<br />
1:30 305. Biomimetic, hierarchical, multidimensional<br />
patterning of conductive polymers<br />
on high-aspect-ratio microstructures.<br />
P. Kim, L. D. Zarzar, A. K. Epstein,<br />
J. Aizenberg<br />
1:50 306. New method to prepare conjugated<br />
polymers: Polyarylsiloxane as precursors<br />
to conjugated polymers. K. Lee,<br />
G. A. Sotzing<br />
2:10 307. Conjugated polymers prepared inside<br />
assembled solid-state devices.<br />
D. D. Mamangun, M. A. Invernale,<br />
Y. Ding, M. S. Yavuz, G. A. Sotzing<br />
2:30 308. Patterned, oscillating, pH-responsive<br />
actuation of polymeric microstructures<br />
in fluid. L. D. Zarzar,P.Kim,<br />
J. Aizenberg<br />
2:50 Intermission<br />
3:10 309. Controlling porosity in conjugated<br />
microporous polymer networks.<br />
R. Dawson,D.J.Adams,A.I.Cooper<br />
3:30 310. Photovoltaic cells with low<br />
bandgap polymer of thienothiophene derivatives.<br />
W. Bae, C. Scilla, W. Jo,<br />
E. B. Coughlin<br />
3:50 311. High � core-shell nanoparticle<br />
polymer composites for RF magnetodielectric<br />
applications. T. Yang,<br />
R. N. Brown, P. Kofinas<br />
4:10 312. Electrospun polyvinylpyrrolidone<br />
and cellulose fibers with magnetic nanoparticles<br />
for electromagnetic applications.<br />
T. J. Simmons,J.Miao,<br />
M. Miyauchi, J. S. Dordick, R. J. Linhardt<br />
4:30 313. Synthesis and characterization of<br />
sterically crowded polyanions with tunable<br />
charge densities. Y. Li,M.Mao,<br />
S. R. Turner<br />
Section D<br />
Westin Boston Waterfront<br />
Stone<br />
General Papers/New Concepts in<br />
Polymeric Materials<br />
Hydrogels/Aerogels<br />
D. Schiraldi, Organizer, Presiding<br />
1:30 314. Swelling kinetics of hydrogels of<br />
cellulose acetate. C. G. dos Santos,<br />
V. A. Oliveira, V. R. Botaro, V. A. Leão<br />
1:50 315. Photocleavable polymer side<br />
groups to spatially alter hydrogel properties<br />
and cellular interactions. J. S. Katz,<br />
V. V. Ramanan, M. Guvendiren,<br />
J. A. Burdick<br />
2:10 316. Injectable in-situ physical and<br />
chemical crosslinkable hydrogels. H. Du,<br />
B. Mohr, M. Muthukumar, P. D. Hamilton,<br />
N. Ravi<br />
2:30 317. Visoelastic and dynamic light<br />
scattering characterization of helix-coil<br />
hybrid hydrogels. M. Muthukumar,<br />
P. D. Hamilton, B. Mohr, S. Kaushal,<br />
H. Du, N. Ravi<br />
2:50 Intermission<br />
3:10 318. Mechano-responsive hydrogels<br />
via biomimetic approaches.<br />
S. E. Grieshaber, L. Xiao, C. Liu, X. Jia<br />
3:30 319. Porous monolithic silicon carbide<br />
aerogels from polyacrylonitrile-coated 3D<br />
silica networks. A. G. Sadekar,<br />
N. Chandrasekaran, C. Sotiriou-Leventis,<br />
N. Leventis<br />
3:50 320. pH-tailoring electrical and mechanical<br />
behavior of polymer-clay-nanotube<br />
aerogels. L. Liu, M. D. Gawryla,<br />
J. C. Grunlan, D. A. Schiraldi<br />
4:10 321. Effects of freezing conditions on<br />
the morphology and mechanical properties<br />
of clay aerogels. Y. Wang,<br />
M. D. Gawryla, D. A. Schiraldi<br />
4:30 322. New interconnected macroporous<br />
oxide materials by phase separation of<br />
bis(trimethoxysilyl)hexane with poly-<br />
(acrylic acid). J. J. Heikkinen, V. Telkki,<br />
O. E. Hormi<br />
WEDNESDAY EVENING<br />
POLY/PMSE Plenary Lecture and Awards<br />
Reception Sponsored by POLY,<br />
Cosponsored by PMSE and PRES<br />
THURSDAY MORNING<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Simulation of Hybrid Interfaces and Multi-<br />
Component Polymeric Materials<br />
Polymers, Fibers and Nanocomposites<br />
Cosponsored by COMP Financially supported<br />
by National Science Foundation<br />
R. Berry, Organizer<br />
H. Heinz, Organizer, Presiding<br />
8:30 323. Molecular dynamics simulations<br />
of responsive semi-fluorinated interfaces.<br />
G. S. Grest, F. Pierce, D. Perahia<br />
9:05 324. Modeling of energy dissipation in<br />
supramolecular polymers. J. Andzelm,<br />
C. Rinderspacher, R. Lambeth, A. Rawlett<br />
9:40 325. Modeling of thermal transport in<br />
polymer nanocomposites. B. L. Farmer,<br />
V. Varshney, S. S. Patnaik, A. K. Roy<br />
10:15 Intermission<br />
10:30 326. Wetting phenomena on solid<br />
nanofibers. M. A. Amat, G. C. Rutledge<br />
11:05 327. Modeling nanoporous structure<br />
by radical polymerization: Brownian dynamics<br />
simulation approach. K. Kim,<br />
S. Park, S. Hwang, M. Cho<br />
11:30 328. Atomistic level description of<br />
quantum dots/organic ligands by ab initio<br />
calculations. R. V. Belosludov,<br />
H. Mizuseki, A. Kasuya, Y. Kawazoe<br />
Section A<br />
Westin Boston Waterfront<br />
Hancock<br />
General Papers/New Concepts in<br />
Polymeric Materials<br />
Nanocomposites<br />
D. Schiraldi, Organizer<br />
R. Tiwari, Presiding<br />
8:40 329. Exposed hydroxyapatite (HA) particles<br />
on the surface of photo-crosslinked<br />
poly(�-caprolactone)/HA nanocomposites<br />
and promoted MC3T3 cell responses.<br />
L. Cai, S. Wang<br />
9:00 330. Polymeric nanocomposites based<br />
on HIPS/silver nanoparticles: Effect of silver<br />
nanoparticles partially oxidized on the<br />
reaction evolution and morphology.<br />
G. Morales, F. Soriano-Corral,<br />
L. Ramos de Valle<br />
9:20 331. Percolation behavior of multiwalled<br />
carbon nanotubes/high density<br />
polyethylene composites and melt processing:<br />
Re-aggregation time scale as a<br />
factor in the formation of MWCNT networks.<br />
F. Yepez Castillo,B.P.Grady,<br />
D. E. Resasco<br />
9:40 332. Dielectric and EMI shielding behavior<br />
of PTT/MWCNT composites in microwave<br />
region. A. Gupta, V. Choudhary<br />
10:00 Intermission<br />
10:20 333. Binary nanocomposites of<br />
Maghnia bentonite and poly (methyl<br />
methacrylate–co-4-vinylpyridine) prepared<br />
using neutral Ni(II)�-benzoinoxime<br />
complex as initiator. S. Djadoun,<br />
H. Harrar-Ferfara, K. Ouaad<br />
10:40 334. PMMA-silica-ionic liquid hybrid<br />
membranes: Toward excellent mechanical<br />
properties/ionic conductivities compromise.<br />
F. Gayet,L.Viau,F.Leroux,<br />
S. Monge, J. Robin, A. Vioux<br />
11:00 335. Polyimide/organosilicate hybrid<br />
polymers with improved thermal and optical<br />
properties. Y. Jung,S.Kim,Y.Yang,<br />
E. Cho, B. Sohn<br />
11:20 336. Moisture susceptibility of hydrophobic<br />
nanoclay composites.<br />
E. Dunkerley,D.F.Schmidt<br />
11:40 337. TPO nanocomposites: Effect of<br />
maleic-anhydride grafted PP (PP-g-MA)/<br />
organoclay (OC) ratio on morphology and<br />
mechanical properties. R. R. Tiwari,<br />
D. R. Paul<br />
Section C<br />
Westin Boston Waterfront<br />
Commonwealth Ballroom C<br />
General Papers/New Concepts in<br />
Polymeric Materials<br />
Biological Aspects<br />
D. Schiraldi, Organizer<br />
K. Schreck, Presiding<br />
8:40 338. Polyethylene glycol (PEG): A potential<br />
substrate for promoting cell selfassembly.<br />
Y. Lu, J. Dai, Q. Meng<br />
9:00 339. Bio-elastomer based on resilinlike<br />
polypeptides. L. Li, K. L. Kiick<br />
9:20 340. Photopolymerized methacrylate:<br />
Thiol-ene networks for dental restorative<br />
applications. K. M. Schreck,<br />
N. B. Cramer, C. Couch, J. E. Boulden,<br />
J. W. Stansbury, C. N. Bowman<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
PMSE<br />
TECH–123
PMSE/PROF <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
9:40 341. Enhanced PC12 cell responses to<br />
polyethylene glycol diacrylate-based hydrogels<br />
grafted with photo-polymerizable<br />
poly-L-lysine. L. Cai, S. Wang<br />
10:00 Intermission<br />
10:20 342. Effect of soft block molecular<br />
weight on surface-accessible charge<br />
concentration in antimicrobial coatings.<br />
M. L. Gupta, K. Brunson, A. Chakravorty,<br />
P. Kurt, J. C. Alvarez, F. Luna-Vera,<br />
K. J. Wynne<br />
10:40 343. Synthesis of guanidine-based<br />
polymers with chain extension for antibacterial<br />
cellulose fibers. L. Qian,<br />
Y. Guan, A. Zheng, H. Xiao<br />
11:00 344. P[AB] copolyoxetanes: A novel<br />
class of biocide. P. Kurt, S. Chakrabarty,<br />
A. Wood, D. Ohman, L. Wood,<br />
K. J. Wynne<br />
11:20 345. Poly(�-caprolactone) and its homo-blends:<br />
Regulated material properties<br />
and cell responses. K. Wang, L. Cai,<br />
S. Wang<br />
Section D<br />
Westin Boston Waterfront<br />
Stone<br />
General Papers/New Concepts in<br />
Polymeric Materials<br />
Thermoset/Polymer Mechanics<br />
D. Schiraldi, Organizer<br />
R. Mrozek, Presiding<br />
8:40 346. Effects of submicron and nanoscale<br />
core-shell rubber on the volume<br />
shrinkage in the cure of vinyl ester resins.<br />
Y. Huang, H. Chang, J. Huang, T. Hsu,<br />
Y. Hsieh<br />
8:40 347. Reaction mechanism and products<br />
of the thermal conversion of hydroxy-containing<br />
polyimides.<br />
J. H. Hodgkin, M. Liu, B. N. Dao, A. J. Hill<br />
9:00 348. NEXAFS characterization and mechanical<br />
testing of engineered epoxy/<br />
substrate interfaces. A. B. Schoch,<br />
D. A. Fischer, J. L. Lenhart<br />
9:20 349. Synthesis and characterization of<br />
unmodified and modified resole phenolic<br />
resins. D. T. Watkins, M. Hosur,<br />
M. Reeves, A. Ludwick, M. Moore<br />
9:40 Intermission<br />
10:00 350. Curing of cyanate esters utilizing<br />
frontal polymerization. V. Viner<br />
10:20 351. Effect of crosslinking density on<br />
the photomechanical behaviors of azoliquid<br />
crystalline polymer networks.<br />
K. Lee, T. J. Bunning, T. J. White<br />
10:40 352. Impact of sol molecular weight<br />
on the mechanical properties and fracture<br />
behavior of elastomeric polysiloxanes.<br />
R. A. Mrozek, P. J. Cole, J. L. Lenhart,<br />
M. C. Berg, K. R. Shull, K. J. Otim<br />
11:00 353. Stress relaxation behavior and<br />
mechanical properties of functionalized<br />
polyolefins. R. H. Brown, J. M. Pickel,<br />
A. K. Naskar<br />
11:20 354. Dynamic-covalent macromolecular<br />
stars. A. P. Bapat,D.Roy,<br />
B. S. Sumerlin<br />
THURSDAY AFTERNOON<br />
Section B<br />
Westin Boston Waterfront<br />
Grand Ballroom C<br />
Simulation of Hybrid Interfaces and Multi-<br />
Component Polymeric Materials<br />
Inorganic Interfaces and Biomaterials<br />
Cosponsored by COMP Financially supported<br />
by National Science Foundation<br />
H. Heinz, Organizer<br />
R. Berry, Organizer, Presiding<br />
1:00 355. Withdrawn<br />
‡ Cooperative Cosponsorship<br />
124–TECH<br />
1:35 356. Molecular simulation studies of<br />
oxide and mineral interfaces.<br />
S. C. Parker, T. Shapley, R. Zhu,<br />
M. Molinari<br />
2:10 357. Toward understanding nonbonded<br />
interactions at a single-wall carbon<br />
nanoturbe-DNA nucleobase interface.<br />
B. Akdim, S. N. Kim, R. N. Naik,<br />
R. Pachter<br />
2:45 Intermission<br />
3:00 358. Turning weakness into strength:<br />
How protein materials balance strength,<br />
robustness and adaptability.<br />
M. J. Buehler<br />
3:35 359. Molecular modeling investigation<br />
of binding and activity of horseradish peroxidase<br />
immobilized on a PHEMA polymer<br />
brush. Z. Kuang,S.M.Lane,<br />
B. L. Farmer, R. R. Naik, R. A. Vaia<br />
4:00 360. Molecular models and methods to<br />
understand self-assembly of inorganicbioorganic<br />
multiphase materials.<br />
H. Heinz<br />
4:25 361. <strong>Chemical</strong> signaling across an array<br />
of biomimetic microcapsules.<br />
A. Bhattacharya, A. C. Balazs<br />
Section A<br />
Westin Boston Waterfront<br />
Hancock<br />
General Papers/New Concepts in<br />
Polymeric Materials<br />
New/Green Materials<br />
D. Schiraldi, Organizer<br />
S. Worley, Presiding<br />
1:30 362. Novel generation of biodegradable<br />
elastomers with highly tunable mechanical<br />
and degradation properties.<br />
M. Nunes Pereira, D. Sarkar, S. Mureli,<br />
L. Ferreira, J. Karp<br />
1:50 363. Unclicking the “click”: A photo-releasable<br />
1,2,3-triazole in block copolymers.<br />
E. S. Sterner, T. Tsai, E. Coughlin<br />
2:10 364. Stimuli responsive polymer nanotubes<br />
by initiated chemical vapor deposition.<br />
G. Ozaydin-Ince, G. Demirel,<br />
K. K. Gleason, M. C. Demirel<br />
2:30 365. Novel thioester-based degradable<br />
polymers: Synthesis, drug release and<br />
application. M. J. Boerakker,<br />
T. A. Kockelkoren, I. T. Arkesteijn,<br />
J. G. Lebouille, P. Bruin, M. R. Houben,<br />
T. Blezer, W. Wetzels, A. A. Dias,<br />
R. W. Bolderman, F. H. van der Veen,<br />
J. G. Maessen<br />
2:50 Intermission<br />
3:10 366. Polymeric coatings containing<br />
mixed tocopherols to improve the UV and<br />
heat resistance of leather. C. Liu,<br />
N. P. Latona, L. Liu, M. L. Aldema-Ramos<br />
3:30 367. Effects of branched crystal structures<br />
on gas permeability of poly(lactic<br />
acid) membranes. H. Sawada,<br />
Y. Takahashi, S. Miyata, S. Kanehashi,<br />
S. Sato, K. Nagai<br />
3:50 368. Mechanism of decomposition of<br />
antimicrobial N-halamine siloxane coatings.<br />
H. B. Kocer, A. Akdag,<br />
S. D. Worley, R. M. Broughton, Y. Wu<br />
4:10 369. Effect of phenyl derivatization on<br />
several properties of N-halamine antimicrobial<br />
siloxane coatings. H. B. Kocer,<br />
S. D. Worley, R. M. Broughton,<br />
T. S. Huang<br />
PROF<br />
Division of Professional<br />
Relations<br />
R. Libby, Program Chair<br />
BUSINESS MEETING:<br />
Executive Committee Open Meeting,<br />
4:00 PM: Tue<br />
SUNDAY MORNING<br />
Combating Disease: The Role of<br />
Biotechnology-based Small Businesses<br />
Sponsored by SCHB, Cosponsored by PROF<br />
Non-Tenure Track Faculty Swimming<br />
Outside the Tenure Stream Sponsored by<br />
WCC, Cosponsored by CPT and PROF<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 158<br />
Tribute to Tom Kucera: The Ultimate<br />
Professional Cosponsored by CWD<br />
E. A. Nalley, Organizer<br />
B. Moriarty, Organizer, Presiding<br />
1:30 1. Tom Kucera: A reflection on the life<br />
of a man of great courage, integrity, and<br />
honor. J. P. Shoffner<br />
2:00 2. Tom Kucera and Chemistry Day.<br />
D. S. Crumrine<br />
2:30 3. Tom Kucera, career counselor.<br />
D. L. Miner<br />
3:00 Intermission<br />
3:15 4. Tom Kucera showed us how! We all<br />
can. . .because. J. A. Summers-Gates<br />
3:45 5. Tom Kucera: The ultimate professional.<br />
E. A. Nalley<br />
4:15 6. Lighthouse on the stormy seas of a<br />
troubled world. A. Pavlath<br />
Building Businesses Based on the<br />
Integration of Basic & Applied Research<br />
Sponsored by SCHB, Cosponsored by PROF<br />
Non-Tenure Track Faculty Swimming<br />
Outside the Tenure Stream Sponsored by<br />
WCC, Cosponsored by CPT and PROF<br />
The Chemistry of Beer and Brewing<br />
Sponsored by YCC, Cosponsored by CHED,<br />
PROF, and SCHB<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 159<br />
Genesis of a <strong>Chemical</strong> Business<br />
Cosponsored by BMGT, SCHB, and YCC<br />
A. C. Myers, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 7. Discovery to delivery: How Purdue<br />
Research Foundation transforms Purdue<br />
University inventions to start-up companies<br />
and commercialization opportunities.<br />
J. D. Gortat<br />
9:05 8. The university in the genesis of<br />
chemical businesses: Then and now.<br />
P. T. Kissinger<br />
9:35 9. Becoming a biotechnology company.<br />
S. J. McKenzie<br />
10:05 10. Genesis of a CRO in organic and<br />
medicinal chemistry. P. Meltzer<br />
10:35 Concluding Remarks<br />
Sustaining a <strong>Chemical</strong> Business with<br />
Federal Grants & Contracts Sponsored by<br />
SCHB, Cosponsored by BMGT, PROF, and<br />
WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 159<br />
Senior Chemists Interface with Local, State<br />
and National Government Cosponsored by<br />
SCTF<br />
M. R. Smith, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 11. ACS Senior Chemists Task Force:<br />
An overview. E. Pearce, C. H. Brown,<br />
H. Cheng<br />
1:55 12. Review of the ACS State Government<br />
Affairs program. J. Brown<br />
2:15 13. Establishing a successful state<br />
government affairs network: The Tennessee<br />
example. J. K. Sanders,<br />
P. J. MacDougall<br />
2:35 Intermission<br />
2:50 14. Tennessee Government Affairs<br />
Committee’s role as a STEM resource for<br />
Tennessee in the Race to the Top – including<br />
the who, what, when, where, and<br />
why. R. A. Woodall<br />
3:10 15. First encounters in chemistry: A<br />
one year pilot program to improve instruction<br />
in the local public elementary<br />
schools. W. M. Seymour<br />
ACS Scholars Program Results: Stories<br />
Highlighting 15 Successful Years Sponsored<br />
by PRES, Cosponsored by CMA, CTA, CWD,<br />
PROF, WCC, and YCC<br />
Best Practices for Entrepreneurs: Panel<br />
Discussion Sponsored by SCHB,<br />
Cosponsored by PROF and YCC<br />
Women at the Forefront of Preventing and<br />
Combating Disease Sponsored by WCC,<br />
Cosponsored by BIOL, MEDI, and PROF<br />
TUESDAY MORNING<br />
Mastering Technical Sales in a Small<br />
Business Sponsored by SCHB, Cosponsored<br />
by PROF<br />
Women Chemists of Color (WCoC) Summit:<br />
Getting to the Table Sponsored by PRES,<br />
Cosponsored by CMA, JSD, PROF, and WCC<br />
TUESDAY AFTERNOON<br />
True Stories of Success from <strong>Chemical</strong><br />
Entrepreneurs Sponsored by SCHB,<br />
Cosponsored by PROF and YCC<br />
Women Chemists of Color Summit: Staying<br />
at the Table Sponsored by PRES,<br />
Cosponsored by BMGT, CMA, COMSCI, JSD,<br />
PROF, and YCC<br />
TUESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
153C<br />
Town Hall Forum & Poster Session<br />
Cosponsored by BMGT, SCHB, and YCC<br />
A. C. Myers, Organizer, Presiding<br />
5:00–7:00<br />
16. Social networking your way through the<br />
job market. C. B. Hollandsworth,<br />
W. S. Case<br />
17. Forming a lesbian, gay, bisexual, and<br />
transgender community in the chemical<br />
sciences. G. L. Heard,B.C.Chan<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
18. Subdivisions: Creating diversity within<br />
the Division of Professional Relations.<br />
A. C. Myers, C. J. Bannochie,<br />
J. C. Crawford<br />
19. Legacy of Dr. Henry A. Hill.<br />
L. M. Watkins<br />
20. Workings and rewards of the YCC Leadership<br />
Development Workshop: An insider’s<br />
pitch. U. I. Zakai, D. S. Sherwood,<br />
R. S. Konduri, I. F. Thorpe, P. Tao<br />
WEDNESDAY MORNING<br />
A Small Business Guide to Intellectual<br />
Property Sponsored by SCHB, Cosponsored<br />
by CHAL and PROF<br />
WEDNESDAY AFTERNOON<br />
Integrated Marketing for Small, Science-<br />
Focused Businesses Sponsored by SCHB,<br />
Cosponsored by PROF<br />
THURSDAY MORNING<br />
Computer Modeling: The Wave of the<br />
Future and its Benefits for Small Business<br />
Owners Sponsored by SCHB, Cosponsored<br />
by CINF, COMP, and PROF<br />
SCHB<br />
Division of Small<br />
<strong>Chemical</strong> Businesses<br />
J. Sabol, Program Chair<br />
OTHER SYMPOSIA OF INTEREST:<br />
Developing and Losing Your<br />
Intellectual Property (see CHAL, Wed)<br />
Where’s the Good Stuff? Consumer<br />
Health Information, and Social<br />
Networking Resources and Services<br />
(see CINF, Mon )<br />
Non-Tenure Track Faculty Swimming<br />
Outside the Tenure Stream (see WCC,<br />
Sun)<br />
Careers in Chemistry (see SOCED,<br />
Sun)<br />
Senior Chemists Interface with Local,<br />
State and National Government (see<br />
PROF, Mon)<br />
Nutrition and Brain Aging (see AGFD,<br />
Tue)<br />
SOCIAL EVENTS:<br />
Social Hour, 5:00 PM: Mon<br />
Reception, 5:00 PM: Mon<br />
Coffee, 8:30 AM: Wed<br />
BUSINESS MEETING:<br />
Executive Committee Meeting,<br />
3:45 PM: Mon<br />
Business Meeting, 4:15 PM: Tue<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
Combating Disease: The Role of<br />
Biotechnology-based Small Businesses<br />
Cosponsored by PROF<br />
M. Chorghade, Organizer, Presiding<br />
9:00 Introductory Remarks<br />
9:05 1. Fascinating adventures in development<br />
of a drug from conception to commercialization:<br />
A personal perspective.<br />
M. S. Chorghade<br />
9:30 2. Novel strategies for the treatment of<br />
genetically-resistant colorectal cancer.<br />
P. Manivasakam, P. R. Chjaturvedi<br />
9:55 3. EMPIRIKO: Refinement of clinical trials.<br />
P. Randhawa<br />
10:20 Intermission<br />
10:35 4. Say that again: How big is the market<br />
for your product? L. Einck<br />
11:00 5. When is the good time to start: Any<br />
time is a good time. R. S. Rajur<br />
11:25 6. <strong>Chemical</strong> genomics: How do we<br />
combat disease. C. P. Austin<br />
11:50 7. Bridging the gap: Academic excellence<br />
to a fundable enterprise.<br />
T. J. McMurry<br />
12:15 Concluding Remarks<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
Building Businesses Based on the<br />
Integration of Basic & Applied Research<br />
Cosponsored by PROF<br />
M. Chorghade, Organizer, Presiding<br />
1:00 Introductory Remarks<br />
1:05 8. Building contract research businesses<br />
based on integration of basic and<br />
applied research: Value creation and new<br />
opportunities in medicinal chemistry and<br />
drug discovery. M. S. Chorghade<br />
1:30 9. V-LABS, INC., in the carbohydrate<br />
and polysaccharide sectors: Problem<br />
solving for the pharmaceutical, food, biotech<br />
industries. S. V. Vercellotti,<br />
J. R. Vercellotti<br />
1:55 10. Novel pyrrolobenzodiazepine dimer<br />
(PBD) DNA minor groove binders for the<br />
treatment of genetically-resistant cancers<br />
with DNA mismatch repair deficiencies.<br />
P. R. Chaturvedi, P. Manivasakam<br />
2:20 11. Solving the puzzle of the unused<br />
inks and other chemical materials.<br />
S. Bhatia<br />
2:45 Intermission<br />
3:00 12. PCI Synthesis: The only constant is<br />
change. E. Price<br />
3:25 13. CiVentiChem: Creating better<br />
chemistry. B. Venepalli<br />
3:50 14. New businesses based on the RCM<br />
reaction. R. H. Grubbs<br />
4:15 15. Practical drug discovery strategy.<br />
C. M. Baldino<br />
4:40 Concluding Remarks<br />
The Chemistry of Beer and Brewing<br />
Sponsored by YCC, Cosponsored by CHED,<br />
PROF, and SCHB<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
Sustaining a <strong>Chemical</strong> Business with<br />
Federal Grants & Contracts Cosponsored by<br />
BMGT, PROF, and WCC<br />
C. White, Organizer<br />
J. White, Presiding<br />
9:00 Introductory Remarks<br />
9:10 16. Maximizing your potential for success<br />
by knowing your options in the<br />
Small Business Innovation Research<br />
(SBIR) program. C. Mabry<br />
9:50 17. Commercializing your invention:<br />
Getting to step one. J. R. White<br />
10:30 18. Financing technology and product<br />
development with the Federal SBIR program.<br />
D. C. Demirjian<br />
11:10 19. Bootstrapping your high tech<br />
business using federal R&D funding.<br />
L. Bowen<br />
11:50 Concluding Remarks<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
GSSPC, HIST, I&EC, INOR, NUCL, ORGN,<br />
POLY, PRES, SCHB, and WCC<br />
Genesis of a <strong>Chemical</strong> Business Sponsored<br />
by PROF, Cosponsored by BMGT, SCHB, and<br />
YCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
Best Practices for Entrepreneurs: Panel<br />
Discussion Cosponsored by PROF and YCC<br />
J. Sabol, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:35 20. Opening remarks for best practices<br />
for entrepreneurs panel discussion.<br />
M. Strem, E. Price, L. Evans, J. Steig<br />
1:55 Panel Discussion<br />
3:25 Concluding Remarks<br />
MONDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Sci-Mix<br />
J. Sabol, Organizer<br />
M. Chorghade, Presiding<br />
8:00–10:00<br />
16. See previous listings.<br />
21. SCHB: The Division of Small <strong>Chemical</strong><br />
Businesses. M. Chorghade, S. Seeling,<br />
S. Vercellotti, J. Sabol<br />
22. Photochemical reactions of some phenols<br />
and amines. J. Zhang<br />
28, 47. See subsequent listings.<br />
TUESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
Mastering Technical Sales in a Small<br />
Business Cosponsored by PROF<br />
D. Jarvis, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:40 23. Five sales essentials for entrepreneurs.<br />
R. Bauman<br />
9:25 24. Get your point across in 30 seconds.<br />
D. Jarvis<br />
10:10 Intermission<br />
10:20 25. How to launch new technologies.<br />
C. Steger<br />
11:05 26. Getting professional help.<br />
D. Jarvis<br />
11:50 Concluding Remarks<br />
Chemistry: The Future-proof Profession<br />
Sponsored by BMGT, Cosponsored by CEPA,<br />
SCHB, SOCED, and WCC<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
True Stories of Success from <strong>Chemical</strong><br />
Entrepreneurs Cosponsored by PROF and<br />
YCC<br />
J. Sabol, Organizer<br />
J. Lauterbach, Presiding<br />
1:00 Introductory Remarks<br />
1:05 27. Progressive summer research internships:<br />
Foundations for a career in research<br />
as a medicine man.<br />
R. S. Chorghade, P. Manivasakam,<br />
M. S. Chorghade<br />
1:35 28. Sensors for medicine and biotechnology<br />
from interdisciplinary university research:<br />
The Cantimer story.<br />
M. P. Eastman, T. L. Porter, R. Stracey,<br />
R. Stewart<br />
2:05 29. Starting a research program in a<br />
very small chemical business.<br />
J. H. Lauterbach<br />
2:35 Intermission<br />
2:45 30. Birth, infancy and adolescence of<br />
Midwest <strong>Chemical</strong> Safety, LLC: What defines<br />
success? H. J. Elston<br />
3:15 31. It all started over a beer: From the<br />
classroom to commercialization.<br />
A. Beard<br />
3:45 Concluding Remarks<br />
Chemistry: The Future-proof Profession<br />
Sponsored by BMGT, Cosponsored by CEPA,<br />
SCHB, SOCED, and WCC<br />
TUESDAY EVENING<br />
Town Hall Forum & Poster Session<br />
Sponsored by PROF, Cosponsored by BMGT,<br />
SCHB, and YCC<br />
WEDNESDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
A Small Business Guide to Intellectual<br />
Property Cosponsored by CHAL and PROF<br />
Financially supported by Osha Liang LLP<br />
C. Burton, Organizer, Presiding<br />
8:30 Coffee<br />
8:45 Introductory Remarks<br />
8:50 32. A rocket scientist takes aim at demystifying<br />
the patenting process: A<br />
primer on obtaining patent protection for<br />
your inventions. T. D. Hain<br />
9:20 33. Timing is everything: When to file a<br />
patent application. C. Burton<br />
9:50 34. Information disclosure in a U.S.<br />
patent application. B. Rothermel<br />
10:20 Intermission<br />
10:35 35. Trademark strategies and considerations.<br />
L. T. Mikeska<br />
11:05 36. Protecting trade secrets in the<br />
current economy. K. B. Drake<br />
11:35 37. Negotiating a technology licensing<br />
agreement. L. Witbeck<br />
12:05 Concluding Remarks<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
Integrated Marketing for Small, Science-<br />
Focused Businesses Cosponsored by PROF<br />
M. Stegman, Organizer, Presiding<br />
PROF/SCHB<br />
1:30 Introductory Remarks<br />
1:35 38. Marketing communications and its<br />
impact on your business. M. Stegman<br />
1:50 39. Successful public relations and<br />
marketing communications planning.<br />
M. Linn<br />
2:15 40. What can graphic design do for<br />
your business? M. Stegman<br />
2:40 41. Integrating social media into your<br />
marketing mix. C. Tanowitz<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–125
SCHB/CCS/CCPA/CWD/CEPA/CEI <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
CMA/CPT/CTA/COMSCI<br />
3:05 Intermission<br />
3:20 42. Breakout Sessions: Work with the<br />
experts. M. Stegman, M. Linn,<br />
C. Tanowitz<br />
4:50 43. Integrated marketing for small, science-focused<br />
businesses. M. Stegman,<br />
M. Linn, C. Tanowitz<br />
5:10 Concluding Remarks<br />
THURSDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 212<br />
Computer Modeling: The Wave of the<br />
Future and its Benefits for Small Business<br />
Owners Cosponsored by CINF, COMP, and<br />
PROF<br />
M. V. Petrova, Organizer, Presiding<br />
8:30 Introductory Remarks<br />
8:35 44. Best practices in scientific computer<br />
modeling. M. V. Petrova<br />
9:05 45. New wave of computational tools<br />
for the leads selection in biomedical industry.<br />
A. D. Costache,D.D.Knight,<br />
J. Kohn<br />
9:35 46. Computational modeling of soft<br />
condensed matter and biomaterials.<br />
J. Ghosh<br />
10:05 47. First-principles computational approach<br />
for the characterization and design<br />
of novel organic electronic materials.<br />
R. S. Sanchez-Carrera, A. Aspuru-Guzik<br />
10:35 Intermission<br />
10:50 48. Recent advances in structurebased<br />
drug design. W. Sherman<br />
11:20 49. Computer simulation of ligand<br />
binding to a flexible protein target.<br />
P. W. Payne<br />
11:50 50. FAST Predictions of protein stability<br />
and flexibility. D. R. Livesay, H. Wang,<br />
D. J. Jacobs<br />
12:20 51. Patentability of computer simulations<br />
and models. N. Malgeri<br />
12:50 Concluding Remarks<br />
CCS<br />
Committee on <strong>Chemical</strong><br />
Safety<br />
TUESDAY AFTERNOON<br />
Laboratory Safety Sponsored by PRES,<br />
Cosponsored by CCS, CHAS<br />
CCPA<br />
Committee on<br />
Chemistry and Public<br />
Affairs<br />
K. Omberg, Program Chair<br />
MONDAY MORNING<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
‡ Cooperative Cosponsorship<br />
126–TECH<br />
CWD<br />
Committee on Chemists<br />
with Disabilities<br />
J. Summers-Gates, Program<br />
Chair<br />
SUNDAY AFTERNOON<br />
Tribute to Tom Kucera: The Ultimate<br />
Professional Sponsored by PROF,<br />
Cosponsored by CWD<br />
MONDAY AFTERNOON<br />
ACS Scholars Program Results: Stories<br />
Highlighting 15 Successful Years Sponsored<br />
by PRES, Cosponsored by CMA, CTA, CWD,<br />
PROF, WCC, and YCC<br />
CEPA<br />
Committee on Economic<br />
and Professional Affairs<br />
T. Hubler, Program Chair<br />
TUESDAY MORNING<br />
Chemistry: The Future-proof Profession<br />
Sponsored by BMGT, Cosponsored by CEPA,<br />
SCHB, SOCED, and WCC<br />
TUESDAY AFTERNOON<br />
Chemistry: The Future-proof Profession<br />
Sponsored by BMGT, Cosponsored by CEPA,<br />
SCHB, SOCED, and WCC<br />
CEI<br />
Committee on<br />
Environmental<br />
Improvement<br />
E. Warren, Program Chair<br />
SUNDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 253C<br />
Chemistry and the Environment Film Series<br />
Tara, Journey to the Heart of the Climate<br />
Machine Cosponsored by CHED and ENVR<br />
E. Warren, Organizer, Presiding<br />
7:00 1. Chemistry and the Environment film<br />
series and discussion: “Tara, Journey to<br />
the Heart of the Climate Machine”.<br />
E. Warren<br />
CMA<br />
Committee on Minority<br />
Affairs<br />
L. Watkins, Program Chair<br />
MONDAY AFTERNOON<br />
ACS Scholars Program Results: Stories<br />
Highlighting 15 Successful Years Sponsored<br />
by PRES, Cosponsored by CMA, CTA, CWD,<br />
PROF, WCC, and YCC<br />
TUESDAY MORNING<br />
Women Chemists of Color (WCoC) Summit:<br />
Getting to the Table Sponsored by PRES,<br />
Cosponsored by CMA, JSD, PROF, and WCC<br />
TUESDAY AFTERNOON<br />
Women Chemists of Color Summit: Staying<br />
at the Table Sponsored by PRES,<br />
Cosponsored by BMGT, CMA, COMSCI, JSD,<br />
PROF, and YCC<br />
CPT<br />
Committee on<br />
Professional Training<br />
K. Larive, Program Chair<br />
SUNDAY MORNING<br />
Non-Tenure Track Faculty Swimming<br />
Outside the Tenure Stream Sponsored by<br />
WCC, Cosponsored by CPT and PROF<br />
SUNDAY AFTERNOON<br />
Non-Tenure Track Faculty Swimming<br />
Outside the Tenure Stream Sponsored by<br />
WCC, Cosponsored by CPT and PROF<br />
MONDAY MORNING<br />
Excellence in the Undergraduate Chemistry<br />
Curriculum: A Global Perspective<br />
Sponsored by PRES, Cosponsored by CPT<br />
and SOCED<br />
MONDAY AFTERNOON<br />
Excellence in the Undergraduate Chemistry<br />
Curriculum: A Global Perspective<br />
Sponsored by PRES, Cosponsored by CPT<br />
and SOCED<br />
CTA<br />
Committee on<br />
Technician Affairs<br />
J. K. Barrett, Program Chair<br />
MONDAY AFTERNOON<br />
ACS Scholars Program Results: Stories<br />
Highlighting 15 Successful Years Sponsored<br />
by PRES, Cosponsored by CMA, CTA, CWD,<br />
PROF, WCC, and YCC<br />
TUESDAY AFTERNOON<br />
Fragrance Design: A Creative Challenge<br />
Sponsored by I&EC, Cosponsored by CTA<br />
and WCC<br />
COMSCI<br />
Committee on Science<br />
D. Nelson, Program Chair<br />
MONDAY MORNING<br />
Hydrogen Production and Application<br />
Reforming, WGS, or Gasification Sponsored<br />
by FUEL, Cosponsored by COMSCI<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exposition Center<br />
Room 211<br />
AES Science and Technology Hydrogen as<br />
a Resource Cosponsored by CATL, FUEL,<br />
I&EC, INOR, and PMSE<br />
D. Nelson, Organizer<br />
K. Glasgow, M. Cesa, Organizers,<br />
Presiding<br />
1:00 Introductory Remarks<br />
1:10 1. Enabling renewable integration and<br />
electrification of the transportation sector<br />
using wind generated hydrogen.<br />
G. M. Sverdrup,D.M.Steward<br />
1:50 2. Inexpensive solar electrolyzer for the<br />
poor of the non-legacy world.<br />
D. G. Nocera<br />
2:30 3. Fuel cells and the energy landscape.<br />
H. D. Abruna<br />
2:50 4. Hydrogen storage in carbon materials.<br />
D. Qu<br />
3:10 5. Economic factors in the future energy<br />
systems. J. Reilly<br />
3:50 Discussion<br />
4:10 Concluding Remarks<br />
Hydrogen Production and Application<br />
Reforming and H2 Storage Sponsored by<br />
FUEL, Cosponsored by COMSCI<br />
TUESDAY MORNING<br />
Hydrogen Production and Application<br />
Membrane Technology and H 2 Application<br />
Sponsored by FUEL, Cosponsored by<br />
COMSCI<br />
TUESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exposition Center<br />
Room 211<br />
Formal and Informal Education Platforms<br />
for Sustainable Energy Systems<br />
J. Bell, N. Bentenitis, Organizers<br />
R. Wingfield, Presiding<br />
D. Nelson, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:40 6. MIT energy studies minor: An alternative<br />
approach to energy education.<br />
J. Steinfeld,A.C.Graham<br />
2:10 7. Defining energy technician jobs and<br />
sharing educational resources.<br />
M. Docherty<br />
2:40 8. Creating solutions for the public in<br />
wind power development. R. Snyder<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.
3:10 9. Models and resources for informal<br />
sustainable energy systems education.<br />
R. C. Wingfield Jr.<br />
3:40 Panel Discussion<br />
4:00 Concluding Remarks<br />
Hydrogen Production and Application<br />
Biological and Solar Methods Sponsored by<br />
FUEL, Cosponsored by COMSCI<br />
Women Chemists of Color Summit: Staying<br />
at the Table Sponsored by PRES,<br />
Cosponsored by BMGT, CMA, COMSCI, JSD,<br />
PROF, and YCC<br />
IAC<br />
International Activities<br />
Committee<br />
J. Benham, Program Chair<br />
SUNDAY AFTERNOON<br />
Connections to Germany and Europe:<br />
Education and Research Opportunities<br />
Sponsored by CHED, Cosponsored by, IAC,<br />
PRES, SCTF, SOCED, WCC, and YCC<br />
JSD<br />
Joint Subcommittee on<br />
Diversity<br />
T. Q. Gray, Program Chair<br />
TUESDAY MORNING<br />
Women Chemists of Color (WCoC) Summit:<br />
Getting to the Table Sponsored by PRES,<br />
Cosponsored by CMA, JSD, PROF, and WCC<br />
TUESDAY AFTERNOON<br />
Women Chemists of Color Summit: Staying<br />
at the Table Sponsored by PRES,<br />
Cosponsored by BMGT, CMA, COMSCI, JSD,<br />
PROF, and YCC<br />
SCTF<br />
Senior Chemists Task<br />
Force<br />
E. Pearce, Program Chair<br />
SUNDAY AFTERNOON<br />
Connections to Germany and Europe:<br />
Education and Research Opportunities<br />
Sponsored by CHED, Cosponsored by CHED,<br />
IAC, PRES, SCTF, SOCED, WCC, and YCC<br />
MONDAY AFTERNOON<br />
Senior Chemists Interface with Local, State<br />
and National Government Sponsored by<br />
PROF, Cosponsored by SCTF<br />
SOCED<br />
<strong>Society</strong> Committee on<br />
Education<br />
M. Carroll and S. Majorski,<br />
Program Chairs<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 103<br />
Nutritional Chemistry Symposium<br />
Cosponsored by AGFD<br />
S. Majorski, Organizer, Presiding<br />
10:45 Introductory Remarks<br />
10:50 1. <strong>Chemical</strong> composition, antioxidant<br />
activity, and cancer antiproliferation effects<br />
of grape, apple, and tomato pomaces.<br />
J. W. Parry, J. Liu, H. Li, K. Zhou,<br />
L. Zhang<br />
11:20 2. Application of chemistry to food.<br />
J. W. Finley<br />
11:50 3. Molecules to mozzarella: The<br />
chemistry of cheese. M. H. Tunick<br />
12:20 Discussion<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 103<br />
Careers in Chemistry<br />
What it’s Like in the Real World and How Do<br />
I Get the Job? Cosponsored by AGFD<br />
S. Majorski, Organizer, Presiding<br />
2:00 Panel Discussion. L. Thackery,<br />
J. W. Finley, M. Tunick<br />
Connections to Germany and Europe:<br />
Education and Research Opportunities<br />
Sponsored by CHED, Cosponsored by CHED,<br />
IAC, PRES, SCTF, SOCED, WCC, and YCC<br />
MONDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 103<br />
Eminent Scientist Lecture<br />
Dendrimer-Based Nanomedicine<br />
11:45 Introductory Remarks<br />
11:55 4. Dendrimer-based nanomedicine:<br />
Its impact on biology, pharma delivery,<br />
MRI imaging, and polyvalent targeted<br />
therapies. D. A. Tomalia<br />
12:35 Luncheon<br />
12:50 Discussion<br />
Excellence in the Undergraduate Chemistry<br />
Curriculum: A Global Perspective<br />
Sponsored by PRES, Cosponsored by CPT<br />
and SOCED<br />
MONDAY AFTERNOON<br />
Excellence in the Undergraduate Chemistry<br />
Curriculum: A Global Perspective<br />
Sponsored by PRES, Cosponsored by CPT<br />
and SOCED<br />
Undergraduate Research Posters<br />
Agricultural and Food Chemistry Sponsored<br />
by CHED, Cosponsored by AGFD and SOCED<br />
Undergraduate Research Posters<br />
Analytical Chemistry Sponsored by CHED,<br />
Cosponsored by ANYL and SOCED<br />
Undergraduate Research Posters<br />
Biochemistry Sponsored by CHED,<br />
Cosponsored by BIOL and SOCED<br />
Undergraduate Research Posters<br />
<strong>Chemical</strong> Education Sponsored by CHED,<br />
Cosponsored by SOCED<br />
Undergraduate Research Posters<br />
Environmental Chemistry Sponsored by<br />
CHED, Cosponsored by ENVR and SOCED<br />
Undergraduate Research Posters<br />
Geochemistry Sponsored by CHED,<br />
Cosponsored by GEOC and SOCED<br />
Undergraduate Research Posters<br />
Inorganic Chemistry Sponsored by CHED,<br />
Cosponsored by INOR and SOCED<br />
Undergraduate Research Posters<br />
Medicinal Chemistry Sponsored by CHED,<br />
Cosponsored by MEDI and SOCED<br />
Undergraduate Research Posters<br />
Nanotechnology Sponsored by CHED,<br />
Cosponsored by SOCED<br />
Undergraduate Research Posters<br />
Physical Chemistry Sponsored by CHED,<br />
Cosponsored by PHYS and SOCED<br />
Undergraduate Research Posters<br />
Polymer Chemistry Sponsored by CHED,<br />
Cosponsored by POLY and SOCED<br />
TUESDAY MORNING<br />
Chemistry: The Future-proof Profession<br />
Sponsored by BMGT, Cosponsored by CEPA,<br />
SCHB, SOCED, and WCC<br />
TUESDAY AFTERNOON<br />
Chemistry: The Future-proof Profession<br />
Sponsored by BMGT, Cosponsored by CEPA,<br />
SCHB, SOCED, and WCC<br />
WCC<br />
Women Chemists<br />
Committee<br />
A. Charlebois and<br />
J. Iriarte-Gross, Program Chairs<br />
OTHER SYMPOSIA OF INTEREST:<br />
Women Chemists of Color Summit:<br />
Staying at the Table (see PRES, Tue)<br />
Anna Jane Harrison: ACS President,<br />
Her Science and Her Legacy (see<br />
HIST, Mon)<br />
Fragrance Design: A Creative<br />
Challenge (see I&EC, Tue)<br />
Encouraging Disadvantaged<br />
Students into Careers in the<br />
<strong>Chemical</strong> Sciences (see PRES, Tue)<br />
SOCIAL EVENTS:<br />
JSD Reception, 6:30-8:00 PM: Mon<br />
Eli Lilly Poster Session and<br />
Reception, 11:00 AM-12:00 PM: Tue<br />
“Just Cocktails”, 4:00-6:00 PM: Tue<br />
Women in Industry Breakfast,<br />
7:30-9:00 AM: Mon<br />
WCC Luncheon, 12:00-1:30 PM: Tue<br />
BUSINESS MEETING:<br />
WCC Executive Session,<br />
8:00 AM-5:00 PM: Sat<br />
COMSCI/IAC/JSD/SCTF/SOCED/WCC<br />
SUNDAY MORNING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 209<br />
Non-Tenure Track Faculty Swimming<br />
Outside the Tenure Stream Cosponsored by<br />
CPT and PROF<br />
A. Charlebois, J. Iriarte-Gross, R. Libby,<br />
Organizers<br />
G. Webster, L. Sremaniak, Organizers,<br />
Presiding<br />
9:30 Introductory Remarks<br />
9:35 1. Non-tenure track faculty and their<br />
presence (or absence) in the ACS.<br />
G. H. Webster, L. S. Sremaniak<br />
10:00 2. Water is different outside the<br />
stream: Advantages in non-tenure track<br />
positions. R. Zibuck, M. Barber<br />
10:25 3. Finding my niche as non-tenure<br />
track faculty. C. L. Lavoie<br />
10:50 Intermission<br />
11:05 4. I didn’t know what an adjunct was.<br />
B. A. Davis<br />
11:30 5. Joint appointment model for faculty/learning<br />
center collaborations: The development<br />
of the SAGE program.<br />
D. A. Canelas,D.M.Hall<br />
11:55 Concluding Remarks<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 209<br />
Non-Tenure Track Faculty Swimming<br />
Outside the Tenure Stream Cosponsored by<br />
CPT and PROF<br />
A. Charlebois, J. Iriarte-Gross, R. Libby,<br />
Organizers<br />
G. Webster, L. Sremaniak, Organizers,<br />
Presiding<br />
2:00 Introductory Remarks<br />
2:05 6. The brass ring and the reality of contingency<br />
in higher education. C. Warren<br />
2:30 7. Leap of faith: Accepting a nontenure<br />
track position which “might” turn into a<br />
tenure-track position. D. Warner<br />
2:55 8. Recent trends in the ACS salary survey<br />
data for non-tenure track faculty.<br />
J. R. Allum, A. M. Gaffney<br />
3:20 Intermission<br />
3:35 9. Who’s teaching whom: A report on<br />
the results of the faculty status survey<br />
conducted by the ACS Committee on<br />
Professional Training. S. Harris<br />
4:00 10. Non-tenure track faculty: Perspectives<br />
from the institutional side.<br />
L. S. Sremaniak<br />
4:25 Concluding Remarks<br />
Connections to Germany and Europe:<br />
Education and Research Opportunities<br />
Sponsored by CHED, Cosponsored by CHED-<br />
IAC, GDCh, IAC, NESACS, PRES, SCTF,<br />
SOCED, WCC, and YCC<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
TECH–127
WCC/YCC <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
MONDAY MORNING<br />
Anna Jane Harrison: ACS President, Her<br />
Science and Her Legacy Sponsored by HIST,<br />
Cosponsored by WCC<br />
Chemistry and Policy: Solving Problems at<br />
the Interface<br />
The Interface, Health, Environment, and<br />
Security Sponsored by CHED, Cosponsored<br />
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,<br />
HIST, I&EC, INOR, NUCL, ORGN, POLY,<br />
PRES, SCHB, and WCC<br />
Sustaining a <strong>Chemical</strong> Business with<br />
Federal Grants & Contracts Sponsored by<br />
SCHB, Cosponsored by BMGT, PROF, and<br />
WCC<br />
MONDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 209<br />
Women at the Forefront of Preventing and<br />
Combating Disease Cosponsored by BIOL,<br />
MEDI, and PROF Financially supported by<br />
Applied <strong>Chemical</strong> Technology subdivision of<br />
I&EC<br />
A. Charlebois, J. Iriarte-Gross, R. Libby,<br />
Organizers<br />
C. Chow, M. Kane, Organizers, Presiding<br />
1:00 Introductory Remarks<br />
1:10 11. Responsive PARACEST MRI<br />
agents for molecular imaging.<br />
J. R. Morrow, S. Dorazio, J. Hammell,<br />
L. Buttarazzi<br />
1:40 12. Characterization of host cell-HIV<br />
protein-RNA interactions as novel antiviral<br />
targets. K. Musier-Forsyth,C.Jones,<br />
J. Sadaatmand, L. Kleiman<br />
2:10 13. Making the m1G37 base in tRNA: A<br />
tale of two enzymes. Y. Hou<br />
2:40 Intermission<br />
2:55 14. Discovery and characterization of<br />
the novel FAAH inhibitor PF-04457845: A<br />
clinical candidate for the treatment of inflammatory<br />
pain. K. Ahn<br />
‡ Cooperative Cosponsorship<br />
128–TECH<br />
3:25 15. Targeting the cardiac muscle cell:<br />
Identification and evaluation of prototype<br />
protein kinase D (PKD) inhibitors for heart<br />
failure. L. Monovich, O. Ordayfio,<br />
K. Beattie, R. Burgis, M. Capparelli,<br />
J. Chapo, L. DiPietro, I. Enyedy,<br />
G. Gamber, C. Gaul, D. Hood,<br />
V. Hosagrahara, C. Jewell, K. Koch,<br />
W. Lee, H. Lehmann, D. Lemon,<br />
E. Meredith, T. McKinsey, K. Miranda,<br />
N. Pagratis, M. Pancost, A. Patnaik,<br />
D. Phan, C. Plato, M. Qian, V. Rajaraman,<br />
C. Rao, O. Rozhitskaya, T. Ruppen,<br />
J. Shi, S. Siska, N. Soldermann,<br />
C. Springer, M. van Eis, R. Vega,<br />
A. von Matt, W. Yan, L. Yang, T. Yoon,<br />
J. Zhang, N. Zhu, Q. Zhu<br />
3:55 16. Berries, wine and chocolate: Combating<br />
the chemistry of oxidative DNA<br />
damage. C. J. Burrows<br />
4:25 Concluding Remarks<br />
ACS Scholars Program Results: Stories<br />
Highlighting 15 Successful Years Sponsored<br />
by PRES, Cosponsored by CMA, CTA, CWD,<br />
PROF, WCC, and YCC<br />
TUESDAY MORNING<br />
Chemistry: The Future-proof Profession<br />
Sponsored by BMGT, Cosponsored by CEPA,<br />
SCHB, SOCED, and WCC<br />
Frank H. Field and Joe L. Franklin Award for<br />
Outstanding Achievement in Mass<br />
Spectrometry: Symposium in Honor of<br />
Catherine Costello Sponsored by ANYL,<br />
Cosponsored by WCC<br />
Women Chemists of Color (WCoC) Summit:<br />
Getting to the Table Sponsored by PRES,<br />
Cosponsored by CMA, JSD, PROF, and WCC<br />
TUESDAY AFTERNOON<br />
Chemistry: The Future-proof Profession<br />
Sponsored by BMGT, Cosponsored by CEPA,<br />
SCHB, SOCED, and WCC<br />
Fragrance Design: A Creative Challenge<br />
Sponsored by I&EC, Cosponsored by CTA,<br />
I&EC-ACTS, and WCC<br />
Frank H. Field and Joe L. Franklin Award for<br />
Outstanding Achievement in Mass<br />
Spectrometry: Symposium in Honor of<br />
Catherine Costello Sponsored by ANYL,<br />
Cosponsored by WCC<br />
YCC<br />
Younger Chemists<br />
Committee<br />
S. Pazicni, Program Chair<br />
SUNDAY MORNING<br />
Social Networking: The Next Generation<br />
Sponsored by CHED, Cosponsored by CINF<br />
and YCC<br />
SUNDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 159<br />
The Chemistry of Beer and Brewing<br />
Cosponsored by CHED, PROF, and SCHB<br />
T. Matos, Organizer<br />
W. S. Case, Organizer, Presiding<br />
2:00 Introductory Remarks<br />
2:05 1. Skunky beer in a whole new light.<br />
M. Forbes<br />
2:30 2. Is it beer? Is it wine? Investigations<br />
into native <strong>American</strong> fermentation traditions.<br />
M. Thomson<br />
2:55 Intermission<br />
3:10 3. Pedagogy of beer. R. Barth<br />
3:35 4. Chemistry of beer: Where science<br />
meets the liberal arts. A. Beard<br />
4:00 Concluding Remarks<br />
Connections to Germany and Europe:<br />
Education and Research Opportunities<br />
Sponsored by CHED, Cosponsored by CHED,<br />
IAC, PRES, SCTF, SOCED, WCC, and YCC<br />
Social Networking: The Next Generation<br />
Sponsored by CHED, Cosponsored by CINF<br />
and YCC<br />
MONDAY MORNING<br />
Genesis of a <strong>Chemical</strong> Business Sponsored<br />
by PROF, Cosponsored by BMGT, SCHB, and<br />
YCC<br />
MONDAY AFTERNOON<br />
ACS Scholars Program Results: Stories<br />
Highlighting 15 Successful Years Sponsored<br />
by PRES, Cosponsored by CMA, CTA, CWD,<br />
PROF, WCC, and YCC<br />
Best Practices for Entrepreneurs: Panel<br />
Discussion Sponsored by SCHB,<br />
Cosponsored by PROF and YCC<br />
TUESDAY AFTERNOON<br />
True Stories of Success from <strong>Chemical</strong><br />
Entrepreneurs Sponsored by SCHB,<br />
Cosponsored by PROF and YCC<br />
Women Chemists of Color Summit: Staying<br />
at the Table Sponsored by PRES,<br />
Cosponsored by BMGT, CMA, COMSCI, JSD,<br />
PROF, and YCC<br />
TUESDAY EVENING<br />
Town Hall Forum & Poster Session<br />
Sponsored by PROF, Cosponsored by BMGT,<br />
SCHB, and YCC<br />
Photographing or recording<br />
meeting sessions and/or<br />
activities other than your own<br />
are prohibited at all official<br />
ACS events without written<br />
consent from ACS.