Durante & Vivan SpA Revision nr. 1 Dated 10/05 ... - Gemini Coatings

Durante & Vivan S.p.A. Revision nr. 1Dated 10/05/2013VILDUR L202 Printed on 10/05/2013Page n. 1/8SAFETY DATA SHEETSection 1: IdentificationProduct identifierProduct nameVILDUR L202Relevant identified uses of the substance or mixture and uses advised againstIntended useHardener for coating materials or adhesives for industrial and tradeapplications, professional use.USA Importer/DistributorNameGemini Industries, Inc.Full address421 S.E. 27th StreetDistrict and Country73036 El RenoOklahoma(USA)Tel. (800) 262-5710e-mail addressbradw@gemini-coatings.combhansen@gemini-coatings.comDetails of the supplier of the safety data sheetNameDurante & Vivan S.p.A.Full address via G. Garibaldi 23District and Country33080 Ghirano di Prata (PN)ItalyTel. 00390434605211Fax 00390434605204e-mail address of the competent personresponsible for the Safety Data Sheet safety@durante-vivan.comProduct distribution byDurante & Vivan s.p.a.Emergency telephone numberFor urgent inquiries refer to (800) 262-57100039 0434605211 h. 8:00 - 18:00 (Italy Time)Section 2: Hazards IdentificationClassification of the substance or mixtureThis material is considered hazardous by the OSHA Hazard Communication Standard (HCS) (29 CFR 1910.1200).Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.Hazard classification and indicationHazard ClassHazardHazard statementcategoryAcute toxicity - Inhalation 4 Harmful if inhaledSpecific target organ toxicity - singleexposure3 May cause respiratory irritationSensitization - Skin 1B May cause an allergic skin reaction

Durante & Vivan S.p.A. Revision nr. 1Dated 10/05/2013VILDUR L202 Printed on 10/05/2013Page n. 2/8Hazard PictogramsSignal WordHazard StatementsWarningHarmful if inhaledMay cause respiratory irritationMay cause an allergic skin reactionSafety statements- Prevention Wear protective gloves. Avoid breathing dust, fume, gas, mist, vapors and spray. Use onlyoutdoors or in a well-ventilated area. Wash arms, hands and face thoroughly after handling.Contaminated work clothing must not be allowed out of the workplace. Do not eat, drink orsmoke when using this product. Wash contaminated clothing before reuse. Store locked upin a well-ventilated place and keep container tightly closed. Dispose of contents andcontainer in accordance with local, state and federal regulations.- Response If on skin: Wash with plenty of water and soap.If skin irritation or a rash occurs: Get medical advice.If inhaled: Remove person to fresh air and keep comfortable for breathing.Call a doctor if you feel unwell.If exposed or concerned: Call a poison center.- Storage Store locked up in a well-ventilated place and keep container tightly closed.- Disposal Dispose of contents and container in accordance with local, state and federal regulations.Other hazardsContains isocyanates.According to Globally Harmonized System of Classification and Labeling of Chemicals (GHS) the mixture isAquatic Chronic 3: Toxic to aquatic life with long lasting effectsSection 3: Composition/Information on IngredientsName CAS number %* ClassificationALIPHATIC POLYISOCYANATE 125252-47-3 ~100Acute Toxicity 4 - InhalationSkin Sensitization IBSpecific Target Organ Toxicity- Single Exposure 3Aquatic Chronic 3HEXAMETHYLENE-DI-ISOCYANATE 822-06-0 ≤0,25Acute Toxicity 4 - OralAcute Toxicity 1 - InhalationSkin Irritation 2Eye Irritation 2Skin Sensitization IRespiratory Sensitization IB*There is batch-to-batch variation.Section 4: First-Aid MeasuresDescription of first aid measuresEYES:SKIN:Irrigate copiously with clean, fresh water for at least 15 minutes. Seek medical advice.Wash with plenty of water and soap.

Durante & Vivan S.p.A. Revision nr. 1Dated 10/05/2013VILDUR L202 Printed on 10/05/2013Page n. 3/8INHALATION:INGESTION:If skin irritation or a rash occurs: Get medical advice.Remove to open air. If breathing is irregular, seek medical advice.Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Never give anythingby mouth to an unconscious person.Most important symptoms and effects, both acute and delayedFor symptoms and effects caused by the contained substances see chap. 11.Indication of any immediate medical attention and special treatment neededInformation not available.Section 5: Fire-Fighting MeasuresExtinguishing mediaSUITABLE EXTINGUISHING MEDIAThe extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulized water.EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONSNone in particular.Special hazards arising from the substance or mixtureHAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIREDo not breathe combustion products (carbon oxide, toxic pyrolysis products, etc).Advice for firefightersGENERAL INFORMATIONUse jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous forhealth. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose ofcontaminated water used for extinction and the remains of the fire according to applicable regulations.SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERSHardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof,cut proof and antistatic), a depressurized mask with facemask covering the whole of the operator`s face or a self-respirator (selfprotector)in the event of large quantities of fume.Section 6: Accidental Release MeasuresPersonal precautions, protective equipment and emergency proceduresUse breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and thoseinvolved in emergency procedures.Environmental precautionsThe product must not penetrate the sewers, surface water, ground water and neighbouring areas.Methods and material for containment and cleaning upConfine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminatedmaterial should be disposed of in compliance with the provisions set forth in point 13.Reference to other sectionsAny information on personal protection and disposal is given in sections 8 and 13Section 7: Handling and StoragePrecautions for safe handlingBefore handling the product, consult all the other sections of this safety data sheet. Do not eat, drink or smoke during use.Conditions for safe storage, including any incompatibilitiesStore in a well ventilated place.

Durante & Vivan S.p.A. Revision nr. 1Dated 10/05/2013VILDUR L202 Printed on 10/05/2013Page n. 4/8Specific end use(s)Information not available.Section 8: Exposure controls/Personal protectionControl parametersName Type TWA/8h STEL/15minmg/m3 ppm mg/m3 ppmALIPHATICPOLYISOCYANATE(CAS 125252-47-3)HEXAMETHYLENE-DI-ISOCYANATE(CAS 822-06-0)ACGIH - - - -NIOSH - - - -OSHA - - - -ACGIH - 0.005 - -NIOSH 0.035 - 0.14 (C) -OSHA - - - -(C) = CEILING 10 minutesHEXAMETHYLENE-DI-ISOCYANATERoute of exposureAcute localHealth - Derived no-effect level - DNEL / DMELEffects on consumersAcutesystemicChroniclocalChronicsystemicAcutelocalEffects on workersAcutesystemicChroniclocalChronicsystemicOral. - - - - - - 0,5 mg/m 3 1 mg/m 3TLV of solvent mixture: 0,03 mg/m 3Exposure controlsRecommended monitoring procedures: Personal, workplace atmosphere or biological monitoring may be required to determine theeffectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.Engineering measures: Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure toairborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dustconcentrations below any lower explosive limits.Hygiene measures: Ensure that eyewash stations and safety showers are close to the workstation location. Wash hands, forearms andface thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Personal protectionHand protectionProtect hands with work gloves, such as those in latex, PVC or equivalent. The following should be considered when choosing workglove material: degradation, breakage times and permeation. Work glove resistance to preparations should be checked before use, as itcan be unpredictable. Gloves` limit depends on the duration of exposure.Skin protectionWear category professional long-sleeved overalls and safety footwear. Wash body with soap and water after removing overalls.Respiratory protectionIf the threshold value (if available) for one or more of the substances present in the preparation for daily exposure in the workplace orto a fraction established by the company`s prevention and protection service is exceeded, wear a mask with an B or universal filter, theclass (1, 2 or 3) of which must be chosen according to the limit concentration of use.The use of respiratory tract protection equipment, such as masks like that indicated above, is necessary to reduce worker exposure inthe absence of technical measures. The protection provided by masks is in any case limited.If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of anemergency, or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear selfcontained,open-circuit compressed air breathing apparatus or fresh air hose breathing apparatus for use with full face mask, half mask

Durante & Vivan S.p.A. Revision nr. 1Dated 10/05/2013VILDUR L202 Printed on 10/05/2013Page n. 5/8or mouthpiece.Eye protectionSafety eyewear should be used when there is a likelihood of exposure. Safety glasses with side shields are recommended.Section 9: Physical and Chemical PropertiesInformation on basic physical and chemical propertiesAppearanceliquidColouryellowishOdouralmost unscentedOdour threshold.Not available.pH.Not available.Melting or freezing point.Not available.Initial boiling point.Not available.Boiling range.Not available.Flash point.218 °C.Evaporation RateNot available.Flammability of solids and gases Not available.Lower inflammability limit.Not available.Upper inflammability limit.Not available.Lower explosive limit.Not available.Upper explosive limit.Not available.Vapour pressure. 42 hPa a 20°CVapour densityNot available.Relative density1.160 Kg/lSolubilityinsoluble. Reacts with waterPartition coefficient: n-octanol/water Not available.Auto-ignition temperature.445 °C.Decomposition temperature.Not available.Viscosity ~ 1250 mPas at 23°CSection 10: Stability and ReactivityReactivityThere are no particular risks of reaction with other substances in normal conditions of use.HEXAMETHYLENE-DI-ISOCYANATE: decomposes at 255°C. Polymerises at temperatures above 200°C.Chemical stabilityThe product is stable in normal conditions of use and storage.Possibility of hazardous reactionsNo hazardous reactions are foreseeable in normal conditions of use and storage.HEXAMETHYLENE-DI-ISOCYANATE: can cause explosive reactions with alcohols and bases. Can react violently with: alcohols,amines, strong bases, oxidant agents, strong acids, water.Conditions to avoidNone in particular, however the usual precautions used for chemical products should be respected.HEXAMETHYLENE-DI-ISOCYANATE: avoid exposure to high temperatures, moisture.Incompatible materialsMaterials to avoid: acids, alcohols, amines, water, alkaline wastes and substances with active hydrogen.HEXAMETHYLENE-DI-ISOCYANATE: alcohols, carboxylic acids, amines and strong bases.Hazardous decomposition productsIn the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.HEXAMETHYLENE-DI-ISOCYANATE: nitric oxide, hydrogen cyanide.

Durante & Vivan S.p.A. Revision nr. 1Dated 10/05/2013VILDUR L202 Printed on 10/05/2013Page n. 6/8Section 11: Toxicological InformationInformation on toxicological effectsMixtureAcute effects: inhalation of this product is harmful.Exposure symptoms may include: stinging and irritated eyes, mouth, nose, throat; cough, respiratory disorders, dizziness, headache,nausea and sickness. In the most serious cases, inhalation of this product may cause larynx and bronchial tube edema and irritation,chemical pneumonia and pulmonary edema.Acute effects: vapour inhalation may irritate the lower and upper respiratory tract and cause cough and respiratory disorders. At higherconcentrations it can also cause pulmonary edema. Ingestion may cause health problems, including stomach pain and sting, nausea andsickness.Upon contact with skin, this product causes sensitization (dermatitis). Dermatitis derives from skin irritation on the areas whichrepeatedly come into contact with the sensitizing agent. Cutaneous lesions may include: erythemas, edemas, papules, vesicles, pustules,scurvies, ulcerations and exudative phenomena, whose intensity varies according to illness seriousness and affected areas. Erythemas,edemas and exudative phenomena prevail during the acute phase. Scurfy skin, dryness, ulcerations and skin thickening prevail duringthe chronic phase.Primary irritations of the skin / mucous membranes (rabbit) slightly irritating. Particular characteristics / effects: in the case of overexposureespecially when performing work without protective gear spray-there is a risk, depending on the concentration, irritation ofthe eyes, nose, throat and respiratory tract. Possible the delayed appearance of disorders and development of a form of hypersensitivity(respiratory disorders, cough, asthma).ComponentsALIPHATIC POLYISOCYANATEAcute toxicityLD50 (Oral) > 2500 mg/kg (rat) (OECD 423 (female)LD50 (Oral) > 2000 mg/kgLC50 (Inhalation) > 0.39 mg/l/4h Method OECD TG 403HEXAMETHYLENE-DI-ISOCYANATELC50 (Inhalation) > 0,124 mg/l/4h RatSection 12: Ecological InformationThis product is dangerous for the environment and the aquatic organisms. In the long term, it have negative effects on aquaticenvironment.ToxicityALIPHATIC POLYISOCYANATEAcuteLC50 Fish (96h) 17.8 mg/l Method OECD TG 203EC50 Daphnia (48h) 9.5 mg/l Method OECD TG 202IC50 (72h) 370 mg/l (Desmodesmus subspicatus)Persistence and degradabilityNot readily degradable.Bioaccumulative potentialInformation not available.Mobility in soilInformation not available.Results of PBT and vPvB assessmentInformation not available.Other adverse effects

Durante & Vivan S.p.A. Revision nr. 1Dated 10/05/2013VILDUR L202 Printed on 10/05/2013Page n. 7/8See Section 10Section 13: Disposal ConsiderationsWaste treatment methodsReuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing thisproduct should be evaluated according to applicable regulations.Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.CONTAMINATED PACKAGINGContaminated packaging must be recovered or disposed of in compliance with national waste management regulations.Section 14: Transport InformationThe product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) andby Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association(IATA) regulations.Section 15: Regulatory InformationU.S. Federal regulationsClean Water Act (CWA) 307Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)Clean Air Act Section 602 Class I SubstancesClean Air Act Section 602 Class II SubstancesDEA List I Chemicals (Precursor Chemicals)DEA List II Chemicals (Essential Chemicals)No component listedHexamethylene-1,6-diisocyanateNo component listedNo component listedNo component listedNo component listedEPA List of Lists, 2012Regulatory NameDiisocyanates (includes only 20chemicals)Hexamethylene-1,6-diisocyanateCAS Number/313 CategoryCode IEPCRA302EHSTPQ IIEPCRA304EHS RQ IIICERCLARQ IVEPCRA313TRI VRCRACode VIN120 - - - 313 - -822-06-0 - - 100 313# - -CAA112(r)RMPTQ VII# indicates member of EPCRA Section 313 diisocyanate category.I 313 Category Code: Emergency Planning and Community Right-to Know Act Section 313 Category CodeII EPCRA 302 EHS TPQ: Extremely Hazardous Substance Threshold Planning Quantity (Emergency Planning and Community RighttoKnow Act Section 302 Category Code)III EPCRA 304 EHS RQ: Extremely Hazardous Substance Reportable Quantity (Emergency Planning and Community Right-to KnowAct Section 304 Category Code)IV CERCLA RQ: Reportable Quantity (Comprehensive Environmental Response, Compensation, and Liability Act)V EPCRA 313 TRI: Toxics Release Inventory (Emergency Planning and Community Right-to Know Act Section 313 Category Code)VI RCRA Code: Resource Conservation and Recovery Act CodeVII CAA 112(r) RMP TQ: Risk Management Plan Threshold Quantity (Clean Air Act Section 112(r))State Components listed NoteNew York Hexamethylene-di-isocyanate -New Jersey Hexamethylene-1,6-diisocyanate -Pennsylvania - -# - Substance is on the Special Health Hazard Substance List

Durante & Vivan S.p.A. Revision nr. 1Dated 10/05/2013VILDUR L202 Printed on 10/05/2013Page n. 8/8E - Substance is on the Environmental Hazard ListS - Substance is on the Special Health Hazard Substance ListCalifornia Prop. 65Ingredient name Cancer ReproductiveNSRL or MADL(µg/day)ALIPHATIC POLYISOCYANATE No No NoHEXAMETHYLENE-DI-ISOCYANATE No No NoSection 16: Other informationsGENERAL BIBLIOGRAPHY1. Hazard Comunication Standard (HCS 2012)2. NTP. 2011. Report on Carcinogens, Twelfth Edition. Research Triangle Park, NC: U.S. Department of Health and Human Services,Public Health Service, National Toxicology Program. 499 pp.3. OSHA website4. NIOSH - Registry of Toxic Effects of Chemical Substances5. IARC website6. Clean Water Act, P.L. 92-500 Section 307 (33 U.S.C. 1317), Toxic and pretreatment effluent standards7. Clean Air Act, P.L. 88-2068. Emergency Planning and Community Right-to Know Act (EPCRA) commonly known as SARA Title III.9. Superfund Amendments and Reauthorization Act (SARA)10. Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)11. Controlled Substances Act, 21 U.S.C. § 802, Definition 34 (list I) and 35 (list II).12. LIST OF LISTS - Consolidated List of Chemicals Subject to the Emergency Planning and Community Right- To-Know Act(EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean AirAct13. 6 NYCRR part 59714. New Jersey Worker and Community Right to know Act N.J.S.A.15. Pennsylvania Worker and Community Right to know Act16. California Safe Drinking Water and Toxic Enforcement Act17. The Merck Index. - 10th Edition18. Handling Chemical Safety19. INRS - Fiche Toxicologique (toxicological sheet)20. Patty - Industrial Hygiene and Toxicology21. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition22. ECHA websiteNote for users:The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify thesuitability and thoroughness of provided information according to each specific use of the product .This document must not be regarded as a guarantee on any specific product property.The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with thecurrent health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.