MSDS - Diversey Inc. - Material Safety Data Sheets

MATERIAL SAFETY DATA SHEETSpitfire® NB SC Non-Butyl Spray & Wipe CleanerHMISNFPAPersonal protective equipmentHealth22Flammability00Physical Hazard / Instability 0 0Version Number: 0Preparation date: 2012-12-071. PRODUCT AND COMPANY IDENTIFICATIONProduct name:MSDS #:Product Code:Recommended use:Spitfire® NB SC Non-Butyl Spray & Wipe CleanerMS03012255892351•Cleaner/Degreaser•ThisproductisintendedtobedilutedpriortouseManufacturer, importer, supplier:Canadian HeadquartersUS HeadquartersDiversey, Inc. - CanadaDiversey, Inc.2401 Bristol Circle8310 16th St.Oakville, Ontario L6H 6P1Sturtevant, Wisconsin 53177-1964Phone: 1-800-668-3131Phone: 1-888-352-2249MSDS Internet Address: www.diversey.comEmergency telephone number: 1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)2. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEWWARNING. CAUSES EYE AND SKIN IRRITATION. MAY BE HARMFUL IF SWALLOWED .Principal routes of exposure:Eye contact. Skin contact. Inhalation.Eye contact:Severe eye irritation.Skin contact:Severe skin irritation.Inhalation:May be irritating to nose, throat, and respiratory tract.Ingestion: May be irritating to mouth, throat and stomach .3. COMPOSITION/INFORMATION ON INGREDIENTSIngredient(s) CAS #Weight % LD50 Oral - Rat(mg/kg)LD50 Dermal -RabbitLC50 Inhalation -RatBenzyl alcohol 100-51-6 10 - 20% 1230 2000 mg/kg 8.8 mg/L (4 h)Diethylene glycol monoethyl ether 111-90-0 5 - 10% 5500 4200 µL/kg >5240 mg/m 3 (4 h)Sodium hydroxide 1310-73-2 0.1 - 1.5% 500 =1350 mg/kg Not availableMonoethanolamine 141-43-5 1 - 5% 1720 1 mL/kg 1025 mg/kg Not available4. FIRST AID MEASURESEye contact:Skin contact:Inhalation:Ingestion:Aggravated Medical Conditions:Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medicalattention.Flush immediately with plenty of water for at least 15 minutes. Get medical attention.If breathing is affected, remove to fresh air. Get medical attention.THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER. DO NOT induce vomitingunless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If swallowed, give a cupful of water or milk.Persons with pre-existing skin disorders may be more susceptible to irritating effectsSpitfire® NB SC Non-Butyl Spray & Wipe Cleaner1 of 4

5. FIRE-FIGHTING MEASURESSuitable extinguishing media:Specific hazards:Unusual hazards:Specific methods:The product is not flammable. Extinguish fire using agent suitable for surrounding fire.Not applicableNone knownNo special methods requiredSpecial protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gearExtinguishing media which must not be used for safety reasons: No information available6. ACCIDENTAL RELEASE MEASURESPersonal precautions:Environmental precautionsand clean-up methods:Use personal protective equipmentClean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place ina chemical waste container. Use a water rinse for final clean-up.7. HANDLING AND STORAGEHandling:Avoid contact with skin, eyes and clothing. Do not taste or swallow. Remove and wash contaminated clothing and footwear before re-use. Washthoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handlingthe empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.Storage:Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.Engineering measures to reduce exposure:No special ventilation requirements General room ventilation is adequate8. EXPOSURE CONTROLS / PERSONAL PROTECTIONPersonal Protective EquipmentEye protection:Hand protection:Skin and body protection:Respiratory protection:Hygiene measures:Chemical-splash goggles.Chemical-resistant glovesNo special protective clothing is required.No special protective clothing is required.Handle in accordance with good industrial hygiene and safety practiceIngredient(s) CAS # ACGIH OSHA MexicoSodium hydroxide 1310-73-2 2 mg/m 3 (Ceiling) 2 mg/m 3 (TWA) 2 mg/m 3 (Ceiling)Monoethanolamine 141-43-5 6 ppm (STEL) 3 ppm (TWA) 6 mg/m 3 6 ppm (STEL) 15 mg/m 33 ppm (TWA)(TWA)(STEL)3 ppm (TWA) 8 mg/m 3(TWA)9. PHYSICAL AND CHEMICAL PROPERTIESPhysical State: LiquidAppearance: Liquid Aqueous solutionSpecific gravity: 1.06Vapor density: No information availableBoiling point/range: Not determinedDecomposition temperature: Not determinedSolubility: Completely SolubleSolubility in other solvents: No information availablePartition coefficient (n-octanol/water): No information availableElemental Phosphorus: 0.00 % by wt.pH: 13.3Explosion limits: - upper: Not determined - lower: Not determinedBulk density: No information availableEvaporation Rate: No information availableColor: Clear PurpleOdor: CitrusMelting point/range: Not determinedAutoignition temperature: No information availableDensity: 8.84 lbs/gal 1.06 Kg/LFlash point: > 200 °F > 93.4 °CViscosity:No information availableVOC: 2.3 % *Dilution pH: 12.4 @ 1:5* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 9450810. STABILITY AND REACTIVITYSpitfire® NB SC Non-Butyl Spray & Wipe Cleaner2 of 4

Stability:Polymerization:Hazardous decomposition products:The product is stableHazardous polymerization does not occurNone reasonably foreseeable.11. TOXICOLOGICAL INFORMATIONAcute toxicity:Component Information:Chronic toxicity:Specific effectsCarcinogenic effects:Mutagenic effects:Reproductive toxicity:Target organ effects:Oral LD50 estimated to be 3000 - 4000 mg/kg . Dermal LD50 estimated to be > 2000 mg/kg.See Section 3None knownNone knownNone knownNone knownNone known12. ECOLOGICAL INFORMATIONEnvironmental Information:No data available13. DISPOSAL CONSIDERATIONSWaste from residues / unused products:This product, as sold, if discarded or disposed, is a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Dispose incompliance with all Federal, state, provincial, and local laws and regulations.RCRA Hazard Class: D002 Corrosive Waste14. TRANSPORT INFORMATIONDOT/TDG/IMDG: Please refer to the Diversey HazMat Library, http://naextranet.diversey.com/dot/, for up to date shipping information.DOT Bill of Lading Description:IMDG Bill of Lading Description:CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUIDCLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID15. REGULATORY INFORMATIONInternational Inventories at CAS# LevelAll components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL).U.S. RegulationsCalifornia Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65RIGHT TO KNOW (RTK)Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:Benzyl alcohol 100-51-6 X - X -Diethylene glycol monoethyl ether 111-90-0 - - - -Sodium xylene sulfonate 1300-72-7 - - - -Sodium hydroxide 1310-73-2 X X X XMonoethanolamine 141-43-5 X X X -Alcohol ethoxylates 68439-46-3 - - - -Water 7732-18-5 - - - -CERCLA/ SARAIngredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313Diethylene glycol monoethyl ether 111-90-0 5 - 10% XSodium hydroxide 1310-73-2 0.1 - 1.5% 1000Ingredient(s) CAA HAP CAA ODS CWA Priority PollutantsSpitfire® NB SC Non-Butyl Spray & Wipe Cleaner3 of 4

Diethylene glycol monoethyl etherXSARA 311/312 Hazard CategoriesImmediate:xDelayed:-Fire: -Reactivity:-Sudden Release of Pressure: -CanadaWHMIS hazard class: D2B Toxic materials16. OTHER INFORMATIONReason for revision:Prepared by:Additional advice:Not applicableNAPRAC•Containsanaddedfragrance,see"Odor"headinginsection9forspecificdescription•ThisproducthasbeenclassifiedinaccordancewithhazardcriteriaoftheControledProductsRegulations and the MSDS contains all the information required by the Controlled ProductsRegulationsNotice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User isresponsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial andLocal laws and regulations.Spitfire® NB SC Non-Butyl Spray & Wipe Cleaner4 of 4