safety data sheet loctite all purpose adhesive - Toolbank

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 2 of 13Label elements (DPD):F - Highly flammableXi - IrritantRisk phrases:R11 Highly flammable.R36 Irritating to eyes.R66 Repeated exposure may cause skin dryness or cracking.R67 Vapours may cause drowsiness and dizziness.Safety phrases:S2 Keep out of the reach of children.S16 Keep away from sources of ignition - No smoking.S25 Avoid contact with eyes.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S46 If swallowed, seek medical advice immediately and show this container or label.2.3. Other hazardsSolvents contained in the product evaporate during processing and their vapors can form explosive/highly inflammableair/vapor mixtures.Pregnant women should absolutely avoid inhalation and skin contact.General chemical description:Dispersion adhesiveBase substances of preparation:containing solventsSECTION 3: Composition/information on ingredientsDeclaration of the ingredients according to CLP (EC) No 1272/2008:Hazardous componentsCAS-No.Methyl acetate79-20-9Ethanol64-17-5Acetone67-64-1EC NumberREACH-Reg No.contentClassification201-185-2 >= 40- < 60 % Specific target organ toxicity - singleexposure 3H336Flammable liquids 2H225Serious eye irritation 2H319200-578-6 >= 10- < 20 % Serious eye irritation 201-2119457610-43H319Flammable liquids 2H225200-662-201-2119471330-49>= 5- < 15 % Flammable liquids 2H225Specific target organ toxicity - singleexposure 3H336Serious eye irritation 2H319For full text of the H - statements and other abbreviations see section 16 "Other information".Substances without classification may have community workplace exposure limits available.

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 3 of 13Declaration of ingredients according to DPD (EC) No 1999/45:Hazardous componentsCAS-No.Methyl acetate79-20-9Ethanol64-17-5EC NumberREACH-Reg No.contentClassification201-185-2 >= 40 - < 60 % Xi - Irritant; R36R67F - Highly flammable; R11R66200-578-6 >= 10 - < 20 % F - Highly flammable; R1101-2119457610-43Acetone67-64-1200-662-201-2119471330-49>= 5 - < 15 % R66Xi - Irritant; R36F - Highly flammable; R11R67For full text of the R-Phrases indicated by codes see section 16 'Other Information'.Substances without classification may have community workplace exposure limits available.4.1. Description of first aid measuresGeneral information:In case of adverse health effects seek medical advice.Inhalation:Move to fresh air, consult doctor if complaint persists.SECTION 4: First aid measuresSkin contact:Rinse with running water and soap. Skin care. Remove contaminated clothes immediately.Eye contact:Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting,sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital.Ingestion:Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice.4.2. Most important symptoms and effects, both acute and delayedEYE: Irritation, conjunctivitis.Repeated exposure may cause skin dryness or cracking.Vapors may cause drowsiness and dizziness.4.3. Indication of any immediate medical attention and special treatment neededSee section: Description of first aid measuresSECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media:carbon dioxide, foam, powder, water spray jet, fine water sprayExtinguishing media which must not be used for safety reasons:High pressure waterjet5.2. Special hazards arising from the substance or mixtureIn the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released.5.3. Advice for firefightersWear self-contained breathing apparatus.Wear protective equipment.

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 4 of 13Additional information:Cool endangered containers with water spray jet.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresEnsure adequate ventilation.Keep away from sources of ignition.Wear protective equipment.Avoid contact with skin and eyes.Danger of slipping on spilled product.6.2. Environmental precautionsDo not empty into drains / surface water / ground water.6.3. Methods and material for containment and cleaning upRemove with liquid-absorbing material (sand, peat, sawdust).Dispose of contaminated material as waste according to Chapter 13.6.4. Reference to other sectionsSee advice in chapter 8SECTION 7: Handling and storage7.1. Precautions for safe handlingVentilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Donot smoke, do not weld. Do not empty waste into waste water drains.Also to be noted when processing larger amounts (> 1 kg): during processing and drying after adhesion, ventilate well. Avoidall sources of fire such as stoves and ovens. Switch off all electrical devices such as parabolic heaters, hot plates, storageheaters etc. in good time for them to have cooled down before commencing work. Avoid all sparks, including those occurringat electrical switches and devices.Avoid skin and eye contact.Hygiene measures:Wash hands before work breaks and after finishing work.Do not eat, drink or smoke while working.7.2. Conditions for safe storage, including any incompatibilitiesStore in sealed original container.Do not store together with food or other consumables (coffee, tea, tobacco, etc.).7.3. Specific end use(s)Adhesive

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 5 of 13SECTION 8: Exposure controls/personal protection8.1. Control parametersOccupational Exposure LimitsValid forGreat BritainIngredient ppm mg/m 3 Type Category RemarksMETHYL ACETATE200 616 Time Weighted AverageEH40 WEL79-20-9(TWA):METHYL ACETATE250 770 Short Term ExposureEH40 WEL79-20-9Limit (STEL):ACETONE500 1.210 Time Weighted AverageEH40 WEL67-64-1(TWA):ACETONE1.500 3.620 Short Term ExposureEH40 WEL67-64-1Limit (STEL):ACETONE500 1.210 Time Weighted Average IndicativeECTLV67-64-1(TWA):ETHANOL64-17-51.000 1.920 Time Weighted Average(TWA):EH40 WELPredicted No-Effect Concentration (PNEC):Name on listEthanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Acetone67-64-1Acetone67-64-1Acetone67-64-1Acetone67-64-1Acetone67-64-1Acetone67-64-1Acetone67-64-1EnvironmentalCompartmentaqua(freshwater)aqua (marinewater)aqua(intermittentreleases)sediment(freshwater)soilSTPoralaqua(intermittentreleases)STPsediment(freshwater)sediment(marine water)soilaqua(freshwater)aqua (marinewater)ExposureperiodValuemg/l ppm mg/kg others0,96 mg/L0,79 mg/L2,75 mg/L3,6 mg/kg0,63 mg/kg580 mg/L720 mg/kg21 mg/L100 mg/L30,4 mg/kg3,04 mg/kg29,5 mg/kg10,6 mg/L1,06 mg/LRemarks

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 6 of 13Derived No-Effect Level (DNEL):Name on listEthanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Acetone67-64-1Acetone67-64-1Acetone67-64-1Acetone67-64-1Acetone67-64-1Acetone67-64-1ApplicationAreaRoute ofExposureHealth Effectworker inhalation Acute/short termexposure - localeffectsworker dermal Long termexposure -systemic effectsworker inhalation Long termexposure -systemic effectsgeneral inhalation Acute/short termpopulationexposure - localeffectsgeneralpopulationgeneralpopulationgeneralpopulationdermalinhalationoralLong termexposure -systemic effectsLong termexposure -systemic effectsLong termexposure -systemic effectsworker inhalation Acute/short termexposure - localeffectsworker dermal Long termexposure -systemic effectsworker inhalation Long termexposure -systemic effectsgeneralpopulationgeneralpopulationgeneralpopulationdermalinhalationoralLong termexposure -systemic effectsLong termexposure -systemic effectsLong termexposure -systemic effectsExposureTimeValue1900 mg/m3343 mg/kg bw/day950 mg/m3950 mg/m3206 mg/kg bw/day114 mg/m387 mg/kg bw/day2420 mg/m3186 mg/kg bw/day1210 mg/m362 mg/kg bw/day200 mg/m362 mg/kg bw/dayRemarksBiological Exposure Indices:None8.2. Exposure controls:Respiratory protection:Ensure adequate ventilation.The product should only be used at workplaces with intensive ventilation/extraction. If the ventilation/extraction systembreaks down then respiratory protection (A2 filter and P2 particle filter) must be worn.Hand protection:Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should bereplaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist'sshops.In the case of longer contact protective gloves made from chloroprene rubber are recommended according to EN 374.material thickness > 0.6 mmPerforation time > 10 minutesIn the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter thanthose determined according to EN 374. The protective gloves must always be checked for their suitability for use at thespecific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must bereplaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in therelevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan isdrawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operatingconditions.

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 7 of 13Eye protection:Goggles which can be tightly sealed.Skin protection:Suitable protective clothingSECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesAppearanceliquidviscousColorlessOdoraromaticOdour thresholdNo data available / Not applicablepHInitial boiling pointFlash pointDecomposition temperatureVapour pressureDensity(25 °C (77 °F))Bulk densityViscosityViscosity (kinematic)Explosive propertiesSolubility (qualitative)Solidification temperatureMelting pointFlammabilityAuto-ignition temperatureExplosive limitsPartition coefficient: n-octanol/waterEvaporation rateVapor densityOxidising propertiesNo data available / Not applicableNo data available / Not applicable< 23 °C (< 73.4 °F); Supplier methodNo data available / Not applicableNo data available / Not applicable0,92 - 0,94 g/cm3No data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableInsolubleNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicable9.2. Other informationNo data available / Not applicableSECTION 10: Stability and reactivity10.1. ReactivityReaction with oxidants.10.2. Chemical stabilityStable under recommended storage conditions.10.3. Possibility of hazardous reactionsSee section reactivity10.4. Conditions to avoidNone if used for intended purpose.10.5. Incompatible materialsNone if used properly.10.6. Hazardous decomposition productsNone known

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 8 of 1311.1. Information on toxicological effectsSECTION 11: Toxicological informationGeneral toxicological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Inhalative toxicity:The toxicity of the product is due to its narcotic effect after inhalation.In the event of protracted or repeated exposure, damage to health cannot be excluded.Vapors may cause drowsiness and dizziness.Skin irritation:Repeated exposure may cause skin dryness or cracking.Eye irritation:Primary eye irritation: irritatingAcute oral toxicity:Hazardous componentsCAS-No.Ethanol64-17-5Acetone67-64-1ValuetypeValue Route ofapplicationExposuretimeSpeciesLD50 13.700 mg/kg oral ratLD50 5.800 mg/kg oral ratMethodAcute inhalative toxicity:Hazardous componentsCAS-No.Ethanol64-17-5Acetone67-64-1ValuetypeValue Route ofapplicationExposuretimeSpeciesLC50 124,7 mg/l inhalation 4 h ratLC50 76 mg/l inhalation 4 h ratMethodAcute dermal toxicity:Hazardous componentsCAS-No.Methyl acetate79-20-9Ethanol64-17-5Acetone67-64-1ValuetypeValue Route ofapplicationExposuretimeSpecies MethodLD50 > 2.000 mg/kg dermal rat OECD Guideline 402 (AcuteDermal Toxicity)LDLo 20.000 mg/kg dermal rabbitLD50 > 15.688 mg/kg dermal rabbitSkin corrosion/irritation:Hazardous componentsCAS-No.Methyl acetate79-20-9Ethanol64-17-5ResultExposuretimeSpecies Methodnot irritating 4 h rabbit OECD Guideline 404 (AcuteDermal Irritation / Corrosion)not irritating rabbit OECD Guideline 404 (AcuteDermal Irritation / Corrosion)Serious eye damage/irritation:Hazardous componentsCAS-No.Methyl acetate79-20-9Ethanol64-17-5Acetone67-64-1ResultExposuretimeSpecies Methodirritating rabbit OECD Guideline 405 (AcuteEye Irritation / Corrosion)Category II rabbit OECD Guideline 405 (AcuteEye Irritation / Corrosion)irritating rabbit OECD Guideline 405 (AcuteEye Irritation / Corrosion)

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 9 of 13Respiratory or skin sensitization:Hazardous componentsCAS-No.Ethanol64-17-5not sensitisingResult Test type Species MethodGuinea pigmaximisation testguinea pigGerm cell mutagenicity:Hazardous componentsCAS-No.Methyl acetate79-20-9Ethanol64-17-5Acetone67-64-1Result Type of study /Route ofadministrationnegative bacterial reversemutation assay (e.gAmes test)negative in vitro mammalianchromosomeaberration testnegative bacterial reversemutation assay (e.gnegativeAmes test)bacterial reversemutation assay (e.gAmes test)Metabolicactivation /Exposure timeSpecies Methodwith and without OECD Guideline 471(Bacterial Reverse MutationAssay)withoutwith and without OECD Guideline 471(Bacterial Reverse MutationAssay)with and without OECD Guideline 471(Bacterial Reverse MutationAssay)Repeated dose toxicityHazardous componentsCAS-No.Acetone67-64-1ResultRoute ofapplicationNOAEL=2500 ppm oral:drinkingwaterExposure time / SpeciesFrequency oftreatment13 weeks ratMethodSECTION 12: Ecological informationGeneral ecological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Do not empty into drains, soil or bodies of water.

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 10 of 1312.1. ToxicityHazardous componentsCAS-No.Methyl acetate79-20-9Methyl acetate79-20-9Methyl acetate79-20-9Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Ethanol64-17-5Acetone67-64-1Acetone67-64-1ValuetypeValueAcuteToxicityStudyExposuretimeSpeciesLC50 250 - 350 mg/l Fish 96 h Brachydanio rerio (new name:Danio rerio)MethodOECD Guideline203 (Fish, AcuteToxicity Test)EC50 1.026,7 mg/l Daphnia 48 h Daphnia magna OECD Guideline202 (Daphnia sp.AcuteImmobilisationTest)EC50 > 120 mg/l Algae 72 h Scenedesmus subspicatus (newname: Desmodesmussubspicatus)OECD Guideline201 (Alga, GrowthInhibition Test)LC50 14,2 g/l Fish 96 h Pimephales promelas OECD Guideline203 (Fish, AcuteToxicity Test)EC50 9.268 - 14.221 mg/l Daphnia 48 h Daphnia magna OECD Guideline202 (Daphnia sp.AcuteImmobilisationTest)EC50 > 5.000 mg/l Algae 7 d Scenedesmus quadricauda OECD Guideline201 (Alga, GrowthInhibition Test)NOEC 2 mg/l chronicDaphnia10 dLC50 8.120 mg/l Fish 96 h Pimephales promelas OECD Guideline203 (Fish, AcuteToxicity Test)EC50 6.098,4 mg/l Daphnia 48 h Daphnia magna OECD Guideline202 (Daphnia sp.AcuteImmobilisationTest)12.2. Persistence and degradabilityHazardous componentsCAS-No.Methyl acetate79-20-9Ethanol64-17-5Acetone67-64-1Result Route ofapplicationDegradability Methodreadily biodegradable aerobic > 70 % OECD Guideline 301 D (ReadyBiodegradability: Closed BottleTest)readily biodegradable aerobic 80 - 85 % OECD Guideline 301 D (ReadyBiodegradability: Closed BottleTest)readily biodegradable aerobic 81 - 92 % EU Method C.4-E (Determinationof the "Ready"BiodegradabilityClosed BottleTest)12.3. Bioaccumulative potential / 12.4. Mobility in soilHazardous componentsCAS-No.Methyl acetate79-20-9Ethanol64-17-5Acetone67-64-1LogKow Bioconcentrationfactor (BCF)0,18-0,310,24ExposuretimeSpecies Temperature Method12.5. Results of PBT and vPvB assessmentHazardous componentsCAS-No.PBT/vPvB

MSDS-No.: 475899V001.0Ethanol64-17-5Acetone67-64-1Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 11 of 13Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and veryBioaccumulative (vPvB) criteria.Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and veryBioaccumulative (vPvB) criteria.12.6. Other adverse effectsNo data available.SECTION 13: Disposal considerations13.1. Waste treatment methodsProduct disposal:Dispose of waste and residues in accordance with local authority requirements.Disposal of uncleaned packages:Use packages for recycling only when totally empty.Waste code08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 12 of 13SECTION 14: Transport information14.1. UN numberADR 1133RID 1133ADNR 1133IMDG 1133IATA 113314.2. UN proper shipping nameADRRIDADNRIMDGIATAADHESIVESADHESIVESADHESIVESADHESIVESAdhesives14.3. Transport hazard class(es)ADR 33RID 33ADNR 33IMDG 33IATA 3314.4. Packaging groupADRRIDADNRIMDGIATAIIIIIIIIII14.5. Environmental hazardsADRRIDADNRIMDGIATAnot applicablenot applicablenot applicablenot applicablenot applicable14.6. Special precautions for userADRRIDADNRIMDGIATASpecial provision 640DTunnelcode: (D/E)Special provision 640DSpecial provision 640Dnot applicablenot applicable14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Codenot applicableSECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureVOC content 75 %

MSDS-No.: 475899V001.0Loctite All Purpose Adhesive (UK), TG NINGBO PASCO Page 13 of 13(VOCV 814.018 VOC regulationCH)15.2. Chemical safety assessmentA chemical safety assessment has not been carried out.SECTION 16: Other informationThe labelling of the product is indicated in Section 2. The full textof all abbreviations indicated by codes in this safety data sheet are as follows:R11 Highly flammable.R36 Irritating to eyes.R66 Repeated exposure may cause skin dryness or cracking.R67 Vapours may cause drowsiness and dizziness.H225 Highly flammable liquid and vapor.H319 Causes serious eye irritation.H336 May cause drowsiness or dizziness.Further information:This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It isintended to describe our products from the point of view of safety requirements and is not intended to guarantee anyparticular properties.