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Blast Cleaning Standards: Cutting through the ... - aca conference

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Inhomogeneity of organic coatings and its effect of protection<br />

Sina S. Jamali 1 , Douglas J. Mills 2<br />

1 Intelligent Polymer Research Institute, AIIM Facility, Innovation Campus, University<br />

of Wollongong, NSW Australia 2522<br />

2 School of Science and Technology, University of Northampton, St George’s Avenue<br />

Northampton, NN2 6JD, UK<br />

Presenter email address: Sina.Jamali198@uowmail.edu.au<br />

Summary<br />

An important aspect of polymeric coatings from <strong>the</strong> protection point of view is <strong>the</strong>ir<br />

inhomogeneous nature. Phenomena such as lack of cross-linking, inappropriate pigmentation,<br />

quick solvent evaporation etc may introduce local micro defects. The diffusion rate at <strong>the</strong>se<br />

micro defects is proportional to <strong>the</strong> ionic concentration of <strong>the</strong> solution at which <strong>the</strong> coating is<br />

immersed and <strong>the</strong>refore <strong>the</strong>y have been known as “D” or direct type areas. On <strong>the</strong> o<strong>the</strong>r hand<br />

is <strong>the</strong> highly resistive “I” type area where <strong>the</strong> ionic resistance increases with increasing <strong>the</strong><br />

ionic concentration of environment. It has been revealed that corrosion proceeds <strong>through</strong> <strong>the</strong><br />

ionic conduction pathways within <strong>the</strong> coating layer when <strong>the</strong> metal is protected by an organic<br />

coating. Traditionally it is believed that a certain level of adhesion is a fundamental<br />

requirement to avoid anodic and cathodic areas connecting underneath <strong>the</strong> coating. Therefore<br />

<strong>the</strong> ionic resistance and specifically D type areas play an important role to determine <strong>the</strong> anticorrosive<br />

properties of paint.<br />

In <strong>the</strong> present study a set of organic coatings in <strong>the</strong> form of detached coatings has been<br />

examined using DC technique to determine <strong>the</strong> D/I type ratio. The significance of thickness<br />

and curing condition on D area formation has been also investigated. Consequently coatings<br />

were applied on steel panel and <strong>the</strong> corrosion behaviour was looked at in <strong>the</strong> long term. Also<br />

<strong>the</strong> adhesion strength of coatings was examined by pull-off method. Results indicate that <strong>the</strong><br />

protection efficiency of coating is mainly governed by D/I type ratio but is relatively<br />

insensitive to <strong>the</strong> adhesion strength. A <strong>the</strong>ory of how <strong>the</strong> permselectivity of coating<br />

influences <strong>the</strong> protectiveness will be advanced.

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