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VESTAMID HTplus short - Innov'Days
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VESTAMID ® HTplus<br />
News in PPA<br />
<strong>TAKING</strong> THE HEAT<br />
Evènement CFP<br />
LES PLASTIQUES<br />
TRES TECHNIQUES<br />
19 juin 2012 – Dijon<br />
Evonik Industries AG, Marl<br />
High Performance Polymers<br />
2012-04 / HP-GL-HTP<br />
Page 1
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 2
Position of thermoplastic compounds<br />
Evonik Industries<br />
<strong>TAKING</strong> THE HEAT<br />
Cost driven<br />
Performance driven<br />
= Compounds Evonik Industries<br />
= Films, foams, fibers and other semi<br />
finished products Evonik Degussa<br />
High Performance<br />
Polymers<br />
Engineering<br />
Polymers<br />
Commodity<br />
Polymers<br />
ABS<br />
PVC<br />
PAR<br />
PMMA<br />
PS<br />
PI<br />
PC<br />
PEI<br />
PMMI<br />
PPE<br />
PAI<br />
PPSU<br />
PES<br />
PSU<br />
Transp. PA<br />
SAN<br />
PMI<br />
PEEK<br />
FPs<br />
LCP<br />
PPS PA12<br />
PA4.6<br />
PA11<br />
PBT<br />
POM<br />
PPA<br />
PA612<br />
PA610<br />
PET<br />
PA6 / PA66<br />
PUR<br />
PP<br />
PE PE-LD PE-HD<br />
Our focus<br />
VESTAMID ® HTplus<br />
PA1010<br />
2012-04 / HP-GL-HTP<br />
amorphous<br />
crystalline<br />
Page 3
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 4
VESTAMID ® HTplus<br />
Glass<br />
fiber<br />
Content<br />
Base resin<br />
Non flame retardant<br />
Flame retardant<br />
Bonding to<br />
rubber<br />
Filaments<br />
0% M1000 M1900<br />
F1001 / F1002<br />
<strong>TAKING</strong> THE HEAT<br />
PA6T<br />
PA10T<br />
15% M10315<br />
30% M1033 M1933 R1033 / R1133<br />
50% M1035 R1035<br />
60% M1036<br />
0% M3000<br />
15% M30315<br />
30% M3033<br />
50% M3035<br />
F2001 / F2002<br />
2012-04 / HP-GL-HTP<br />
60% M3036<br />
Page 5
VESTAMID HTplus<br />
Melting point and glass transition temp.<br />
400<br />
Melting point<br />
Glass transition temperature<br />
<strong>TAKING</strong> THE HEAT<br />
Temperature °C<br />
2012-04 / HP-GL-HTP<br />
350<br />
300<br />
250<br />
200<br />
150<br />
100<br />
50<br />
0<br />
295<br />
PA46<br />
75<br />
260<br />
PA66<br />
55<br />
218 220<br />
PA612<br />
50<br />
PA6<br />
55<br />
180<br />
PA12<br />
49<br />
PPA<br />
1000<br />
315<br />
125<br />
PPA<br />
3000<br />
290<br />
125<br />
225<br />
45<br />
PBT<br />
255<br />
74<br />
PET<br />
285<br />
100<br />
PPS<br />
310<br />
215<br />
PEI<br />
350<br />
153<br />
PEEK<br />
230<br />
225<br />
PES<br />
190<br />
220<br />
215<br />
185<br />
PSU<br />
PPSU<br />
Source:<br />
Literature and tests with<br />
EVONIK products<br />
Note: overview of typical max. characteristic temperatures, they may vary depending on individual<br />
polymer structure and the test procedures<br />
Page 6
VESTAMID ® HTplus Base Resin<br />
<strong>TAKING</strong> THE HEAT<br />
VESTAMID ® HTplus belongs to polyphthalamide PPA we offer with two<br />
different base resins: Base resin PA6T/X and base resin PA10T/X.<br />
Both of them are semicrystalline and partially aromatic.<br />
For injection moulding we have created special grades.<br />
VESTAMID ® HTplus M30XY (PA10T/X) is based partially on renewable raw materials.<br />
In comparison to VESTAMID ® HTplus M10XY (PA6T/X) VESTAMID ® HTplus M30XY (PA10T/X) offers a<br />
lower melting temperature.<br />
Thermal properties<br />
T s<br />
/ T m<br />
T g<br />
(1)<br />
(1) Dry as moulded<br />
Melting point<br />
Glass transition temperature<br />
M10XY<br />
+315 °C<br />
+125 °C<br />
M30XY<br />
+290 °C<br />
+125 °C<br />
2012-04 / HP-GL-HTP<br />
Page 7
<strong>TAKING</strong> THE HEAT<br />
VESTAMID ® HTplus M3000 series<br />
- the next generation grade<br />
Fire meets Bio<br />
Product characteristics<br />
+ =<br />
• next generation PPA<br />
• up to 50% renewable<br />
• lower water absorption<br />
• 10% less density<br />
• better dimensional stability<br />
• higher hydrolysis resistance<br />
• improved processing window<br />
added value<br />
VESTAMID ® HTplus M3000 is a PA10T-based Copolyamide. PA10T/X is a<br />
polycondensation product of 1,10-decamethylene diamine (10) and<br />
terephthalic acid (T). As 1,10-decamethylene diamine is derived from castor oil<br />
plants, VESTAMID ® HTplus M3000 is partially natural resourced and thus based on<br />
renewable raw materials.<br />
2012-04 / HP-GL-HTP<br />
Page 8
VESTAMID ® HTplus<br />
Properties Base Resin<br />
High level of melting point at +290 °C (M30XY) up to<br />
+315 °C (M10XY)<br />
High level at glass transition temperature +125 °C<br />
Long term heat resistance up to +180 °C<br />
<strong>TAKING</strong> THE HEAT<br />
Heat Deflection Temperature at > +120 °C<br />
Attractive ratio cost / performance<br />
Excellent chemical resistance, e. g. in automotive-fluids<br />
High level of strength and stiffness<br />
Very good dimensional stability<br />
Constant high level mechanical properties (e. g. strength, stiffness,<br />
toughness) in a wide temperature range<br />
2012-04 / HP-GL-HTP<br />
Page 9
Melting point and water absorption<br />
of different polymers<br />
VESTAMID ® HTplus a successful combination of excellent mechanical and<br />
thermal properties and low water uptake<br />
<strong>TAKING</strong> THE HEAT<br />
Melting point [ °C ]<br />
350<br />
300<br />
250<br />
200<br />
150<br />
2012-04 / HP-GL-HTP<br />
PEEK<br />
LCP<br />
PPS<br />
PET<br />
PBT PES<br />
PPSU<br />
PEI<br />
PSU PA11<br />
PA12<br />
0 0<br />
VESTAMID<br />
HTplus<br />
M3000<br />
PA 610<br />
612<br />
PPA<br />
PA66<br />
30 % glass fiber<br />
reinforced polymers<br />
PA6<br />
PA46<br />
2 4 6 8 10 12<br />
Water absorption [ % ]<br />
Test (acc. ISO62) in water by +23°C<br />
Page 10
VESTAMID ® HTplus<br />
Target applications<br />
Material performance as door opener for new applications<br />
<strong>TAKING</strong> THE HEAT<br />
Good<br />
dimensional<br />
stability<br />
Lead free<br />
solderable<br />
High<br />
strength<br />
+<br />
stiffness<br />
Good<br />
ultrasonic<br />
weldable<br />
High heat<br />
deflection<br />
temperature<br />
of<br />
+285°C<br />
Fatigue<br />
creep<br />
resistance<br />
High long<br />
term heat<br />
resistance<br />
up to<br />
+180°C<br />
High<br />
comperative<br />
tracking<br />
index<br />
High<br />
melting<br />
point<br />
of<br />
+290 °C<br />
+315 °C<br />
Excellent<br />
chemical<br />
resistance,<br />
e.g.<br />
automotive<br />
fluids<br />
2012-04 / HP-GL-HTP<br />
Page 11
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 12
VESTAMID ® HTplus for<br />
Metal substitution<br />
Good<br />
dimensional<br />
stability<br />
High<br />
strength<br />
+<br />
stiffness<br />
High heat<br />
deflection<br />
temperature<br />
of<br />
+282 °C<br />
High long<br />
term heat<br />
resistance<br />
up to<br />
+180 °C<br />
High<br />
melting<br />
point of<br />
+320 °C<br />
<strong>TAKING</strong> THE HEAT<br />
Lead free<br />
solderable<br />
Very good<br />
ultrasonic<br />
weldable<br />
Fatigue<br />
creep<br />
resistance<br />
High<br />
comperative<br />
tracking<br />
index<br />
= Basics for metal substitution<br />
Excellent<br />
chemical<br />
resistance,<br />
e.g.<br />
automotive<br />
fluids<br />
2012-04 / HP-GL-HTP<br />
Page 13
VESTAMID ® HTplus<br />
Products<br />
Glass<br />
fiber<br />
content<br />
Base resin<br />
Non flame retardant<br />
Flame retardant<br />
Bonding to<br />
rubber<br />
Filaments<br />
0% M1000 M1900<br />
F1001 / F1002<br />
<strong>TAKING</strong> THE HEAT<br />
PA6T<br />
PA10T<br />
15% M10315<br />
30% M1033 M1933 R1033 / R1133<br />
50% M1035 R1035<br />
60% M1036<br />
0% M3000<br />
F2001 / F2002<br />
15% M30315<br />
30% M3033<br />
50% M3035<br />
Typical grades for metal substitution<br />
2012-04 / HP-GL-HTP<br />
60% M3036<br />
Page 14
Material profile of VESTAMID ® HTplus<br />
High strength, also at elevated<br />
temperatures<br />
High stiffness, also at elevated<br />
temperatures<br />
Good dimensional stability<br />
> 200 MPa<br />
> 15000 MPa<br />
Low / no swelling<br />
<strong>TAKING</strong> THE HEAT<br />
Good chemical resistance<br />
Weather resistance<br />
Low / no influence by moisture / water<br />
Easy processing with injection moulding<br />
VESTAMID ® HTplus GF reinforced good for metal replacement<br />
2012-04 / HP-GL-HTP<br />
Page 15
Tensile strength and modulus in<br />
comparison to metals<br />
<strong>TAKING</strong> THE HEAT<br />
Tensile<br />
Strength<br />
[MPa]<br />
Tensile<br />
Modulus<br />
[GPa]<br />
450<br />
400<br />
350<br />
300<br />
250<br />
200<br />
150<br />
100<br />
50<br />
0<br />
0<br />
10<br />
20<br />
30<br />
40<br />
50<br />
60<br />
70<br />
80<br />
90<br />
100<br />
400<br />
300<br />
260<br />
15<br />
250<br />
Steel Zinc Alu PTFE VESTAMID<br />
HT-plus<br />
0,75<br />
80<br />
70<br />
21<br />
15<br />
PE<br />
1,2<br />
2012-04 / HP-GL-HTP<br />
200<br />
Page 16
Lotus Exige – Charge air duct<br />
<strong>TAKING</strong> THE HEAT<br />
VESTAMID ® HTplus M1033<br />
Substitution of aluminum die cast<br />
Weight reduction<br />
Burst pressure 2 … 3 bar<br />
Temperature requirements -30 … +180 °C<br />
Chemical resistance to oil, fat, fuel, …<br />
2012-04 / HP-GL-HTP<br />
Page 17
VESTAMID ® HTplus<br />
A Substitute of Metal<br />
Conventional technology:<br />
Metal - die cast<br />
Alternative technology:<br />
PPA – injection moulded<br />
Metal<br />
PPA<br />
<strong>TAKING</strong> THE HEAT<br />
Motivation<br />
Weight reduction of the parts<br />
More design freedom<br />
Cost saving<br />
Thermal and electrical isolation<br />
Reduction of the number of components, different functions<br />
can be integrated in one part<br />
Fewer processing steps (deflashing, sand-blasting, cleaning,<br />
annealing etc. is not necessary)<br />
No surface treatment (like painting or corrosion protection)<br />
Longer life times of the tools (up to 5 times)<br />
2012-04 / HP-GL-HTP<br />
Page 18
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 19
Overview<br />
Drinking water polymers<br />
Evonik Industries - High Performance Polymers<br />
Product portfolio<br />
<strong>TAKING</strong> THE HEAT<br />
Polymers for drinking water applications<br />
VESTAMID ® HTplus<br />
TROGAMID<br />
VESTAMID L<br />
VESTOSINT<br />
Source: www.ennsdorf.gv.at<br />
2012-04 / HP-GL-HTP<br />
Page 20
VESTAMID ® HTplus M16xy-series<br />
General properties<br />
<strong>TAKING</strong> THE HEAT<br />
High High<br />
stiffness stiffness<br />
+ + stability stability<br />
(also with<br />
(also with<br />
water contact)<br />
water contact)<br />
High High<br />
dimension dimension<br />
stability stability<br />
Low Low mold mold<br />
shrinkage shrinkage<br />
Good Good<br />
dynamic dynamic<br />
load load<br />
behavior behavior<br />
VESTAMID ® HTplus<br />
M16xy<br />
VESTAMID<br />
HTplus HTplus<br />
M16xy M16xy<br />
Good Good<br />
hydrolysis hydrolysis<br />
resistance resistance<br />
(warm water)<br />
(warm water)<br />
Excellent Excellent<br />
creep creep<br />
behavior behavior<br />
High High<br />
stress stress<br />
cracking cracking<br />
resistance resistance<br />
Perfect for metal substitution in<br />
• drinking water,<br />
• sanitary and<br />
• industrial<br />
applications with<br />
excellent price / performance ratio<br />
Outstanding Outstanding<br />
chemical chemical<br />
resistance resistance<br />
VESTAMID ® HTplus<br />
Resistant. Versatile. Easy.<br />
2012-04 / HP-GL-HTP<br />
Page 21
Metal substitution<br />
VESTAMID HTplus vs. metals<br />
VESTAMID<br />
HTplus<br />
Brass<br />
Aluminum<br />
Zinc<br />
<strong>TAKING</strong> THE HEAT<br />
Price<br />
Processability<br />
Post treatment / Reworking<br />
o<br />
Volume price + - - -<br />
Density<br />
Stiffness<br />
Heat Distortion Temperature<br />
Creeping beaviour<br />
Dynamic load behaviour<br />
Freedom of design<br />
+<br />
1,7 g/cm 3<br />
o<br />
o<br />
o<br />
o<br />
+<br />
+<br />
+<br />
o<br />
-<br />
8,5 g/cm 3<br />
+<br />
+<br />
+<br />
+<br />
-<br />
-<br />
-<br />
+<br />
o<br />
2,7 g/cm 3<br />
+<br />
+<br />
+<br />
o<br />
-<br />
-<br />
-<br />
+<br />
-<br />
6,7 g/cm 3<br />
+<br />
o<br />
-<br />
o<br />
-<br />
-<br />
-<br />
2012-04 / HP-GL-HTP<br />
Page 22
Metal substitution<br />
Advantages of VESTAMID ® HTplus<br />
Advantage / Benefit<br />
Comments<br />
<strong>TAKING</strong> THE HEAT<br />
No heavy metal pollution<br />
Cost reduction due to<br />
reduced post treatment / reworking<br />
no surface treatment<br />
easier handling<br />
longer life time of production units<br />
Freedom of design<br />
Reduced weight per part<br />
e.g. Pb is used in brass as processing additive: no Pb<br />
emission with VESTAMID ® HTplus, needed due to tightend<br />
legal requirements<br />
deburring, sandblasting, cleaning, annealing not needed<br />
e.g. for coloring, structuring, …<br />
up to 5 times higher<br />
reduction of the number of components<br />
( different functions can be integrated in one part)<br />
due to lower density<br />
( lower freight charges)<br />
Conventional techn.<br />
die cast<br />
Metal<br />
Conventional techn.<br />
injection moulding<br />
PPA<br />
VESTAMID ® HTplus<br />
Resistant. Versatile. Easy.<br />
2012-04 / HP-GL-HTP<br />
Page 23
VESTAMID ® HTplus<br />
Generals<br />
VESTAMID ® HTplus M16xy<br />
PA6T/X<br />
semi crystalline,<br />
partly aromatic PA<br />
Grade name<br />
Polymer matrix<br />
VESTAMID ® HTplus M36xy<br />
PA10T/X<br />
semi crystalline, partly<br />
aromatic PA, partly biobased<br />
<strong>TAKING</strong> THE HEAT<br />
320 °C / ~125 °C<br />
1,43..1,71 g/cm 3 (M1633 … M1636)<br />
GRIVORY HTV...1 (EMS)<br />
AMODEL AS-19 (Solvay)<br />
ZYTEL HTN (Du Pont)<br />
T S<br />
/ T G<br />
Density<br />
Competitor grades<br />
290 °C / 125 °C<br />
1,43..1,71 g/cm 3 (M3633 … M3636)<br />
In development stage!<br />
GRIVORY HTV3 (EMS)<br />
• next generation PPA<br />
• lower water absorption<br />
• better dimensional stability<br />
• higher hydrolysis resistance<br />
• improved processing window<br />
RILSAN HT (Arkema)<br />
2012-04 / HP-GL-HTP<br />
Page 24
VESTAMID ® HTplus<br />
Available grades + approvals<br />
Glass<br />
fiber<br />
content<br />
Base resins<br />
0% M1000<br />
Grade name<br />
Dinking water approvals<br />
KTW *) WRAS ACS NSF61 W270<br />
GER GB F USA GER<br />
*) incl. AUT approval<br />
60°C 60°C <br />
<strong>TAKING</strong> THE HEAT<br />
PA10T<br />
PA6T<br />
2012-04 / HP-GL-HTP<br />
30% M1633<br />
40% M1634<br />
50% M1635<br />
60% M1636<br />
0% M3000<br />
30% M3633<br />
40% M3634<br />
50% M3635<br />
60% M3636<br />
60°C 60°C <br />
60°C 60°C <br />
60°C 60°C <br />
60°C 60°C <br />
in development!<br />
Page 25
VESTAMID ® HTplus<br />
Main characteristics<br />
<strong>TAKING</strong> THE HEAT<br />
2012-04 / HP-GL-HTP<br />
Page 26
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 27
VESTAMID ® HTplus for<br />
Plastic & Rubber Composites<br />
<strong>TAKING</strong> THE HEAT<br />
Evonik competency:<br />
VESTAMID® HTplus -polymer modification for<br />
direct bonding to high performance<br />
elastomers, patented process, long term<br />
experience with plastic & rubber composites<br />
based on engineering plastic<br />
Benefits for OEM:<br />
Integration of different functions in one single<br />
part<br />
Improved sealing design<br />
Metal replacement – weight reduction<br />
cost saving potential<br />
Potential applications:<br />
Integrated radial oil seals<br />
Valve covers & oil sump modules<br />
Valve flaps with integrated gaskets<br />
2012-04 / HP-GL-HTP<br />
Page 28
Requirements for thermoplastic<br />
and rubber component<br />
Requirements for the thermoplastic component:<br />
• Short-term heat deflection temperature (HDT-B) > 150 °C, ideally > 180 °C<br />
• possible modification<br />
<strong>TAKING</strong> THE HEAT<br />
Requirements for the elastomer component:<br />
• Vulcanization preferred by radicals (peroxide, amine, sulphur)<br />
• Polar rubber types with reactive groups are preferred<br />
• good demolding properties and short vulcanization time for the 1-step process<br />
2012-04 / HP-GL-HTP<br />
Page 29
VESTAMID ® HTplus for<br />
Plastic & Rubber Composites<br />
Evonik competency:<br />
VESTAMID ® HTplus -polymer modification for direct<br />
bonding to high performance elastomers, patented<br />
process, long term experience with plastic & rubber<br />
composites based on engineering plastic.<br />
<strong>TAKING</strong> THE HEAT<br />
Benefits for OEM:<br />
Integration of different functions in one single part<br />
Improved sealing design<br />
Metal replacement – weight reduction<br />
cost saving potential<br />
Potential applications:<br />
Integrated radial oil seals?<br />
Valve covers & oil sump modules<br />
Valve flaps with integrated gaskets<br />
2012-04 / HP-GL-HTP<br />
Page 30
Production processes for<br />
K & K Composites<br />
1 Mold -<br />
Technology<br />
2 Mold -<br />
Technology<br />
Other Criteria<br />
<strong>TAKING</strong> THE HEAT<br />
Thermoplast<br />
Rubber<br />
One step process<br />
Preferred for similar<br />
component cycle times<br />
Thermoplast<br />
Rubber<br />
Two step process<br />
Preferred for quite different<br />
component cycle times<br />
- Vulcanization time<br />
- Part size<br />
- Number of pieces<br />
Mold technology<br />
- Index plate<br />
- Rotating mold<br />
- Transfer tech.<br />
2012-04 / HP-GL-HTP<br />
Page 31
Tensile test with K&K specimen<br />
Plastic part<br />
<strong>TAKING</strong> THE HEAT<br />
Rubber<br />
Break outside<br />
the bonding area<br />
Plastic part<br />
2012-04 / HP-GL-HTP<br />
Page 32
One step process for tensile test<br />
bars at Evonik Technical Lab Marl<br />
Index plate injection<br />
mold<br />
<strong>TAKING</strong> THE HEAT<br />
thermoplastic<br />
preforms<br />
final K&K-tensile bar<br />
with rubber<br />
component (black)<br />
runner<br />
2012-04 / HP-GL-HTP<br />
Page 33
Bonding mechanism<br />
of K & K - composites<br />
Diffusion of<br />
styrene segments<br />
Radical bonding<br />
by peroxides<br />
Radical bonding<br />
by peroxides and<br />
formation of amides<br />
<strong>TAKING</strong> THE HEAT<br />
SBR EPDM XNBR<br />
PPE PPE PA<br />
2012-04 / HP-GL-HTP<br />
Page 34
K & K - Combination possibilities<br />
Thermoplast ><br />
Rubber<br />
v<br />
VESTORAN<br />
VESTAMID<br />
TROGAMID<br />
VESTAMID<br />
HTplus<br />
(mod. PPE)<br />
(PA612)<br />
(PA-Blends)<br />
(PPA)<br />
SBR<br />
S<br />
-<br />
-<br />
-<br />
<strong>TAKING</strong> THE HEAT<br />
NR/SBR<br />
S<br />
-<br />
-<br />
SBR/NBR<br />
S<br />
-<br />
-<br />
EPDM<br />
P<br />
P<br />
-<br />
XNBR<br />
-<br />
P<br />
P<br />
HNBR<br />
-<br />
P<br />
P<br />
EAM, AEM<br />
-<br />
A<br />
A<br />
VMQ<br />
(P)<br />
(P)<br />
(P)<br />
FKM<br />
-<br />
Bis/P/A<br />
Bis/P/A<br />
Cross linking additive: S = Sulphur, P = Peroxide, Bis = Bisphenole, A = Amine<br />
* = under evaluation<br />
-<br />
-<br />
P<br />
-<br />
P<br />
*<br />
*<br />
P<br />
2012-04 / HP-GL-HTP<br />
Page 35
Summary<br />
• For K&K– technology we offer a a wide product range<br />
of suitable materials and broad experience proven by many<br />
applications worldwide<br />
<strong>TAKING</strong> THE HEAT<br />
• Innovative product solutions enable to cut production costs and<br />
achieve competitive advantage<br />
• The range of material combination possibilities is continuously<br />
enlarged by our ongoing development activities<br />
• Development activities on new K&K-combinations based on<br />
VESTAMID ® HTplus aim at higher temperature and chemical resistant<br />
rubbers e.g. EPDM, FKM, HNBR or AEM.<br />
• The customer receives our professional support in all steps<br />
of the development process<br />
2012-04 / HP-GL-HTP<br />
Page 36
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 37
VESTAMID ® HTplus<br />
Halogen-free flame retardant grades<br />
<strong>TAKING</strong> THE VESTAMID HEAT<br />
® HTplus<br />
PA10T<br />
PA6T<br />
Glass<br />
fiber<br />
content<br />
Base resins Non flame retardand Flame retardant Rubber bondable<br />
0% M1000 M1900<br />
15% M10315<br />
30% M1033 M1933 R1033 / R1133<br />
50% M1035 R1035<br />
60% M1036<br />
0% M3000<br />
15% M30315<br />
30% M3033<br />
50% M3035<br />
Filaments<br />
F1001 / F1002<br />
F2001 / F2002<br />
2012-04 / HP-GL-HTP<br />
60% M3036<br />
Page 38
Data RTI are generic values and preliminary.<br />
Update will follow time schedule page 25.<br />
VESTAMID ® HTplus M1900<br />
Page 39<br />
2012-04 / HP-GL-HTP<br />
<strong>TAKING</strong> THE HEAT
Data RTI are generic values and preliminary.<br />
Update will follow time schedule page 25.<br />
VESTAMID ® HTplus M1933<br />
Page 40<br />
2012-04 / HP-GL-HTP<br />
<strong>TAKING</strong> THE HEAT
VESTAMID ® HTplus M1900 + M1933<br />
RoHS and WEEE<br />
VESTAMID ® HTplus M1900 and VESTAMID ® HTplus M1933 are<br />
free of halogens and red phosphorus.<br />
The products are possible in all colours.<br />
<strong>TAKING</strong> THE HEAT<br />
RoHS: VESTAMID ® HTplus M1900 and VESTAMID ® HTplus M1933<br />
are in compliance with RoHS (2002/95/EC, Restriction of Hazardous<br />
Substances).<br />
WEEE: Parts produced from VESTAMID ® HTplus M1900 and<br />
VESTAMID ® HTplus M1933 are not subject to „selective<br />
treatment“ according the Directive 2002/96/EC on Waste Electrical<br />
and Electronic Equipment.<br />
2012-04 / HP-GL-HTP<br />
VESTAMID ® HTplus M1900 <br />
VESTAMID ® HTplus M1933 <br />
Page 41
VESTAMID ® HTplus<br />
electronic industry<br />
VESTAKEEP in Electronics<br />
Application<br />
Coil bobbins, connector, relay housing<br />
Grades<br />
VESTAMID ® HTplus M1900<br />
VESTAMID ® HTplus M1933<br />
<strong>TAKING</strong> THE HEAT<br />
2012-04 / HP-GL-HTP<br />
Process<br />
Injection molding<br />
Requirement for part<br />
HFR V0 at 0,4 mm<br />
RoHS and WEEE.<br />
lead free soldering process.<br />
added value<br />
Less corrosion<br />
Lower fogging behavior<br />
good flow ability<br />
Page 42
Increasingly Stringent Demands on<br />
Properties of Connector Materials<br />
Flame Resistance<br />
Impact Cracking Resistance<br />
Operation Temperature<br />
Vibration Failure Resistance<br />
<strong>TAKING</strong> THE HEAT<br />
IR Soldering Reflow Temp<br />
Thin Wall Design Flow Behaviour<br />
Chemical Resistance<br />
Dust & Debris Proof<br />
Dimensional Stability<br />
Acceptable Pricing<br />
2012-04 / HP-GL-HTP<br />
Page 43
Increasingly Stringent Demands on<br />
Properties of Connector Materials<br />
Operation Temperature<br />
High Melting Temperature<br />
High Glass Transition Temperature<br />
<strong>TAKING</strong> THE HEAT<br />
Temperature [°C]<br />
315<br />
125<br />
Melting Point<br />
Glass Transition Temperature<br />
260<br />
55<br />
290<br />
75<br />
VESTAMID ® HTplus PA 66 PA 46<br />
As high as 200 °C used in oil &<br />
gas control instruments in deserts…<br />
200°C<br />
As low as -60°C used<br />
In the communication<br />
Instruments in the<br />
Antarctica -60°C<br />
2012-04 / HP-GL-HTP<br />
Page 44
Increasingly Stringent Demands on<br />
Properties of Connector Materials<br />
IR Soldering Reflow<br />
Temperature ( ° C)<br />
<strong>TAKING</strong> THE HEAT<br />
0<br />
Radiation: Far or middle-far infrared radiation<br />
Board Surface Temp<br />
During pre-heating<br />
Min 150°C to Max 200°C<br />
Pre-heating stage<br />
90<br />
Stabilised<br />
For 90s<br />
Flux<br />
Activation<br />
4s-10s<br />
60s-180s<br />
Reflow<br />
Max Temp = 260°C<br />
Solder starts to melt<br />
Forced air cooling state<br />
All temperature values are measured on board surface<br />
Time (s)<br />
Note: Thermal profile depends on the size and weight of the assembly,<br />
density of the components. All components must be heated to temperature<br />
Above the minimum reflow temperature (245°C)<br />
Reflow Temperature Resistance<br />
* Defects such as blistering and<br />
charring must not appear<br />
•Materials Tg and HDT must be<br />
above the peak value<br />
Warping Resistance Upon Cooling<br />
•Dimensional stability of materials<br />
at high temperature and its rigidity<br />
during cooling stage (especially<br />
by using convection forced air<br />
cooling method) will dictate<br />
the failure rate<br />
2012-04 / HP-GL-HTP<br />
Page 45
VESTAMID ® HTplus M1933<br />
Spiral flow test 0.5 mm<br />
Excellent and competitive flowability of VESTAMID ® HTplus M1933<br />
VESTAMID® HTplus M1933<br />
PPA 3<br />
Injection moulding conditions<br />
+320°C / +160 °C / 800 bar<br />
<strong>TAKING</strong> THE HEAT<br />
PPA 2<br />
PPA 1<br />
VESTAMID HTplus<br />
M1933<br />
2012-04 / HP-GL-HTP<br />
0 10 20 30 40 50<br />
Flow length [mm]<br />
Page 46
VESTAMID ® HTplus M1933<br />
Spiral flow test 1 mm<br />
Excellent and competitive flowability of VESTAMID ® HTplus M1933<br />
VESTAMID® HTplus M1933<br />
Injection moulding conditions<br />
PPA 3<br />
+320°C / +160 °C / 800 bar<br />
<strong>TAKING</strong> THE HEAT<br />
PPA 2<br />
PPA 1<br />
VESTAMID HTplus<br />
M1933<br />
2012-04 / HP-GL-HTP<br />
0 50 100 150 200<br />
Flow length [mm]<br />
Page 47
The Benefit M1933 can Bring for Connector<br />
VESTAMID ® HTplus M1933<br />
Good dimensional stability and<br />
warpage resistancewarpage resistance<br />
Excellent flowing ability<br />
processing easily<br />
even at thinnest wall part<br />
7.21 mm<br />
<strong>TAKING</strong> THE HEAT<br />
Outstanding toughness compared<br />
to competitors that is easy to be<br />
broken in this structure when assembly<br />
0.39 mm<br />
3.49 mm<br />
0.28 mm<br />
Higher heat resistance and<br />
lower water absorption refuses<br />
blister when experiencing IR reflow<br />
2012-04 / HP-GL-HTP<br />
Page 48
VESTAMID ® HTplus M1900 + M1933<br />
Laser marking<br />
<strong>TAKING</strong> THE HEAT<br />
VESTAMID ® HTplus M1900 Black<br />
good contrast,<br />
good sharpness of contour<br />
Produced by Nd:YAG-Laser (1064 Nm)<br />
VESTAMID ® HTplus M1933 Black<br />
good contrast,<br />
good sharpness of contour<br />
Produced by Nd:YAG-Laser (1064 Nm)<br />
2012-04 / HP-GL-HTP<br />
Page 49
VESTAMID ® HTplus M1900 + M1933<br />
Summary<br />
VESTAMID ® HTplus M1900<br />
VESTAMID ® HTplus M1933<br />
<strong>TAKING</strong> THE HEAT<br />
1. Flame retardant system free of halogene and red phosphor.<br />
2. Listing UL94 flame class V0 at 0.4 mm for all colours.<br />
3. Ongoing listing UL94 for RTI values Elec, Imp, Str until 2013. RTI 140 ºC.<br />
4. Products in compliance with RoHS and WEEE.<br />
5. Polymer with lower water uptake than competition PPA.<br />
6. Polymer with better dimensional stability than competition PPA.<br />
7. High glass transition temperature at +125 ºC.<br />
8. Excellent and competitive flowability behavior.<br />
9. Less corrosion than competitive materials.<br />
10.Better fogging behaviour than competition.<br />
11.Excellent laser markable.<br />
2012-04 / HP-GL-HTP<br />
Page 50
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 51
VESTAMID ® HTplus for LED<br />
Longer. Brighter. Whiter.<br />
Evonik competency:<br />
VESTAMID ® HTplus – special polymer modification for<br />
requirements at SMT LED<br />
VESTAMID® HTplus – SMT LED<br />
Compounding technology modified for special additives<br />
<strong>TAKING</strong> THE HEAT<br />
Benefits for OEM:<br />
LED solutions with high performance maintain a<br />
consistent degree of reflection even over a long period<br />
Light natural colour of the material<br />
Superior UV stability<br />
Excellent adhesion to metal and silicone<br />
Potential applications:<br />
High power LED sockets<br />
SMT LED<br />
Thinwall LED<br />
2012-04 / HP-GL-HTP<br />
Page 52
VESTAMID ® HTplus LED<br />
Colour change<br />
PPA 1 PPA 2 VESTAMID HTplus<br />
Storing time in<br />
oven at +260 °C<br />
Start<br />
<strong>TAKING</strong> THE HEAT<br />
8 min<br />
30 min<br />
2012-04 / HP-GL-HTP<br />
Page 53
VESTAMID ® HTplus for<br />
3-D interconnect devices<br />
Evonik competency:<br />
VESTAMID ® HTplus – special polymer<br />
modification for requirements at LDS<br />
processing<br />
Compounding technology modified for special<br />
additives<br />
<strong>TAKING</strong> THE HEAT<br />
Benefits for OEM:<br />
Materials qualified with LPKF<br />
High dimensional stability<br />
Good processability<br />
Suitable for lead-free soldering process<br />
Very small components are possible,<br />
conductor widths of 150 µm and conductor<br />
spacings of 200 µm and even smaller are<br />
possible<br />
Potential applications:<br />
Three-dimensional interconnect devices<br />
Cost-effectice products of high quality<br />
components for electronics<br />
2012-04 / HP-GL-HTP<br />
Source: LPKF<br />
Page 54
VESTAMID ® HTplus for<br />
3-D interconnect devices<br />
<strong>TAKING</strong> THE HEAT<br />
2012-04 / HP-GL-HTP<br />
Page 55
VESTAMID ® HT Plus<br />
machinery industry<br />
VESTAKEEP in Electronics<br />
Application<br />
Gear parts<br />
Grade<br />
VESTAMID ® HTplus M1533<br />
<strong>TAKING</strong> THE HEAT<br />
Process<br />
Injection molding<br />
Requirement for parts<br />
Wear resistance<br />
Dimensional stability<br />
added value<br />
Precise processing<br />
Low sliding coefficient and wear<br />
Good flow ability<br />
2012-04 / HP-GL-HTP<br />
Page 56
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 57
Customer Support (1)<br />
Design support<br />
(CAE- / CAD- Moldflow – Studies)<br />
FE structural mechanical calculations<br />
<strong>TAKING</strong> THE HEAT<br />
Support in processing issues<br />
Colour matching<br />
Injection moulding (One Shot, Two Shot, Composite)<br />
Extrusion (Multi Layer Technology / Corrugated Tubes a.s.o.)<br />
Blow moulding<br />
Application of thermoplastic HPP- materials<br />
Selection of appropriated plastics depending on requirements<br />
Tailor made products<br />
2012-04 / HP-GL-HTP<br />
Page 58
Customer support (2)<br />
<strong>TAKING</strong> THE HEAT<br />
Polymer Testing<br />
Existence of a wide range of test equipment<br />
Approvals<br />
Quality control<br />
Service of polymer testing and analysis<br />
Quality standards<br />
Laser Technologies (Evonik Laser center with experiences in :)<br />
Laser Marking (2D and 3D)<br />
Laser Welding<br />
Laser Sintering (Rapid prototyping)<br />
Laser Direct Structuring (3D MID-Technology)<br />
2012-04 / HP-GL-HTP<br />
Page 59
Key competence for metal<br />
substitution:<br />
Finite-Element-Method for<br />
Analysis in Structural<br />
Mechanics
Workflow in FEM analysis<br />
geometry / technology<br />
CAD-model<br />
import<br />
challenge<br />
blackbox<br />
<strong>TAKING</strong> THE HEAT<br />
preprocessor<br />
• discretisation/mesh<br />
• material model<br />
• boundary conditions/<br />
loads<br />
• contact<br />
solver<br />
{F}=[K]*{u}<br />
postprocessor<br />
interpretation of results<br />
preprocessing<br />
solution<br />
postprocessing<br />
2012-04 / HP-GL-HTP<br />
Page 61
Injection Moulding Simulation<br />
Injection moulding<br />
simulation with<br />
Autodesk Moldflow<br />
Insight 2010:<br />
filling<br />
<strong>TAKING</strong> THE HEAT<br />
fibre orientation<br />
warpage and shrinkage<br />
2012-04 / HP-GL-HTP<br />
Page 62
Metal-substitution of a splined shaft<br />
VESTAMID ® HTplus M1035<br />
Fig.1: Original splined steel tube<br />
Challenge:<br />
original part: splined shaft for car seat adjustment<br />
determination of the transmissible moment on a splined shaft<br />
made from VESTAMID HTplus M1035<br />
if necessary: change the part design to show equal or better<br />
performance than the original steel tube<br />
optimize design to realize a significant reduction in weight<br />
<strong>TAKING</strong> THE HEAT<br />
Fig.2: Simulation results<br />
Fig.3: Light weight construction optimized for injection molding<br />
Results:<br />
equal stiffness and 30% lighter part design<br />
integration of the shaft lock down device direct in the<br />
injection moulding and design of the part<br />
reduction costs for the assembling<br />
devation between analytical solution and simulation
Agenda<br />
<strong>TAKING</strong> THE HEAT<br />
<br />
<br />
<br />
<br />
<br />
High Performance Polymers<br />
Position of PPA polyphthalamide<br />
VESTAMID ® HTplus<br />
Main characteristics<br />
Performance and properties<br />
<br />
<br />
<br />
<br />
<br />
VESTAMID ® HTplus for metal substitution<br />
VESTAMID ® HTplus for drinking water<br />
VESTAMID ® HTplus K&K technology<br />
VESTAMID ® HTplus FR grades<br />
VESTAMID ® HTplus specialities<br />
Customer support<br />
Summary<br />
2012-04 / HP-GL-HTP<br />
Page 64
Summary<br />
<strong>TAKING</strong> THE HEAT<br />
Polyphthalamide PPA offers high performance in applications at<br />
elevated temperatures also in combination with high mechanical load.<br />
Evonik has a long experience in High Performance Polymers and has<br />
complete backward integration.<br />
A selection of grades VESTAMID ® HTplus are available to use the<br />
performance of PPA for electronic applications and other market<br />
segments.<br />
Additional developments are in the pipeline.<br />
Customers are served with material, testing and processing know how<br />
of our application technology and technical marketing experts.<br />
2012-04 / HP-GL-HTP<br />
Page 65
Your questions – our solutions<br />
<strong>TAKING</strong> THE HEAT<br />
Low Low shrinkage shrinkage<br />
and and warpage warpagerequired<br />
required<br />
??<br />
Superior Superior wear wear<br />
resistance resistance<br />
??<br />
High High operating operating<br />
temperatures<br />
temperatures<br />
up up to to 180 180 °C °C and and more more<br />
??<br />
VESTAMID ®<br />
HTplus<br />
Excellent Excellent creep, creep,<br />
fatigue fatigueand and modulus modulus<br />
(metal (metal substition) substition)<br />
??<br />
Constant Constant mechanical mechanical<br />
properties properties<br />
independent independent from from<br />
water water absorption absorption<br />
??<br />
Excellent Excellent chemical chemical<br />
resistance resistance<br />
??<br />
2012-04 / HP-GL-HTP<br />
Page 66
Page 67<br />
2012-04 / HP-GL-HTP<br />
<strong>TAKING</strong> THE HEAT
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