ELECTROCHEMICAL METHODS Fundamentals and Applications - Allen.J.Bard

Major Symbols
xi
Symbol
Meaning
Usual Units
Section
References
Е щ
E F
Em
Eg
E;
Щ
E m
E P
A£ P
Ep/2
£pa
£pc
£ Z
*л
Еф
E\I2
Ещ
Е
Ъ1А
e
e\
e 0
ег%)
erfc(x)
F
f
/(E)
fUk)
G
AG
G
G°
equilibrium potential of an electrode
Fermi level
flat-band potential
bandgap of a semiconductor
initial potential
junction potential
membrane potential
peak potential
(a)|£ pa -£ pc |inCV
(b) pulse height in SWV
potential where / = / p /2 in LSV
anodic peak potential
cathodic peak potential
staircase step height in SWV
potential of zero charge
switching potential for cyclic voltammetry
quarter-wave potential in
chronopotentiometry
(a) measured or expected half-wave
potential in voltammetry
(b) in derivations, the "reversible"
half-wave potential,
E o> + (RT/nF)\n(D R /D 0 ) l/2
potential where i/i^ =1/4
potential where /// d = 3/4
(a) electronic charge
(b) voltage in an electric circuit
input voltage
output voltage
voltage across the input terminals of an
amplifier
error function of x
error function complement of x
the Faraday constant; charge on one
mole of electrons
(a) F/RT
(b) frequency of rotation
(c) frequency of a sinusoidal oscillation
(d) SWV frequency
(e) fraction titrated
Fermi function
fractional concentration of species / in
boxy after iteration к in a simulation
Gibbs free energy
Gibbs free energy change in a chemical
process
electrochemical free energy
standard Gibbs free energy
V
eV
V
eV
V
mV
mV
V
V
mV
V
V
V
mV
V
V
V
V
V
V
V
с
V
V
V
/xV
none
none
С
V" 1
r/s
s- 1
s- 1
none
none
none
kJ, kJ/mol
kJ, kJ/mol
kJ, kJ/mol
kJ, kJ/mol
1.3.2,3.4.1
2.2.5, 3.6.3
18.2.2
18.2.2
6.2.1
2.3.4
2.4
6.2.2
6.5
7.3.5
6.2.2
6.5
6.5
7.3.5
13.2.2
6.5
8.3.1
1.4.2,5.4,5.5
5.4
5.4.1
5.4.1
10.1.1,15.1
15.2
15.1.1
15.1.1
A.3
A.3
9.3
10.1.2
7.3.5
11.5.2
3.6.3
B.1.3
2.2.4
2.1.2,2.1.3
2.2.4
3.1.2