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available feedstock grades Revision 02.2012 - PolyMIM GmbH

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<strong>PolyMIM</strong> <strong>GmbH</strong><br />

polyMIM ® - Simplifying the Complex!<br />

Bad Sobernheim, 2012


AGENDA<br />

� Facts & Figures Polymer-Group<br />

� Facts & Figures <strong>PolyMIM</strong><br />

� Feedstock compounding<br />

� Debinding process<br />

� typical sintering process


FACTS AND FIGURES POLYMER-GROUP<br />

The art of plastics is to offer tailor-made solutions for a variety of<br />

applications by modifying and refining plastics<br />

Foundation 1973<br />

Industry branch Chemical / plastics industry<br />

Business segments Modification and refining of plastics<br />

Business data 2011 - 450 employees<br />

- 150 million €sales<br />

- 180,000 t plastic compounds<br />

- 35 compounding lines<br />

Portfolio Plastics and metal powder compounds<br />

(PVC, PP, PE, PA etc.)<br />

Customer segments Construction, film/packaging materials,<br />

automotive industry, medical, aerospace


CORPORATION AND BUSINESS DIVISIONS POLYMER-GROUP<br />

•Soft PVC<br />

•Rigid PVC<br />

(dryblend / pellets)<br />

•Tollcompounding of Polyolefins and engineering plastics<br />

•Chalk-filled polyolefin compounds<br />

•Long glass fiber reinforced compounds (PP, PA, PET)<br />

•Technical compounds (PA, PBT, TPE, PET)<br />

•Polyolefin compounds<br />

•Polyolefin compounds based on reactive extrusion<br />

•Rigid PVC (dryblend/ pellets)<br />

•Metal Powder Compounds of low-alloy steels, stainless<br />

steels and special alloys<br />

•Coloured master-batches for thermoplastics


LOCATION POLYMER-GROUP GERMANY<br />

Polymer-Group


AGENDA<br />

� Facts & Figures Polymer-Group<br />

� Facts & Figures <strong>PolyMIM</strong><br />

� Feedstock compounding<br />

� Debinding process<br />

� typical sintering process


FACTS AND FIGURES polyMIM<br />

Foundation 2005<br />

Business segments Development, production and sale of<br />

<strong>feedstock</strong> for metal injection molding<br />

applications.<br />

Business data 2012 > 200 t <strong>feedstock</strong><br />

(target figure)<br />

Portfolio - Low Alloys<br />

- Stainless Steels<br />

- Tool Steels<br />

- Titanium und titanium alloys<br />

- Copper and copper alloys<br />

- Heavy-Metal-Alloys<br />

- Tungsten carbide cobalt <strong>grades</strong><br />

Customer segments Automotive, mechanics, consumer goods,<br />

electronics, medical, aerospace<br />

Markets Europe, North America, Asia, South<br />

America


<strong>PolyMIM</strong> ®<br />

your partner in metal powder <strong>feedstock</strong>s<br />

<strong>PolyMIM</strong> your flexible <strong>feedstock</strong> manufacturer<br />

� Wide material range<br />

� Two different binder systems (water and catalytic debinding)<br />

� Custom made <strong>feedstock</strong>s with matched oversize factors<br />

� Support during the complete metal injection moulding process<br />

�Raw Material<br />

� Tooling<br />

MIM<br />

� Injection moulding<br />

� Debinding<br />

� Sintering<br />

� We offer the best match for your application


We adjust our <strong>feedstock</strong> <strong>grades</strong> to your needs<br />

Engineered Powder<br />

8740 D 322 E<br />

Engineered powder concepts<br />

Master Alloy Version<br />

8740 D 222 E<br />

Combination of gas/water atomized powder<br />

and carbonyl iron powder<br />

Pre-Alloy Version<br />

8740 D 120 E<br />

gas or water atomized pre-alloyed powders<br />

3.7 mm<br />

2.9 mm<br />

0 mm


Metal powder mixture<br />

polyMIM Typ 300<br />

Master Alloy Powder<br />

polyMIM Type 200<br />

Pre-alloyed powder<br />

gas or water atomized<br />

polyMIM Type 100<br />

Fe<br />

Fe Cr<br />

Ni<br />

Fe<br />

Master<br />

Fe-Ni-Cr<br />

alloy<br />

Fe-Ni-Cr<br />

alloy<br />

Fe-Ni-Cr<br />

alloy<br />

Fe-Ni-Cr<br />

alloy<br />

8740 D 322 E<br />

(Fe-Ni-Cr alloy)<br />

8740 D 222 E<br />

(Fe-Ni-Cr alloy)<br />

8740 D 120 E<br />

(Fe-Ni-Cr alloy)


We adjust our <strong>feedstock</strong> <strong>grades</strong> to your needs<br />

Engineered<br />

powder<br />

mixture<br />

Master Alloy<br />

roughness<br />

Density<br />

as-sintered<br />

Dimensional<br />

accuracy<br />

Price<br />

+ ++ +<br />

+<br />

Powder +/- + -<br />

+/-<br />

+/-<br />

Powder ++ - ++<br />

++<br />

Pre- alloyed<br />

++<br />

polishing<br />

+/-<br />

++ perfect<br />

+ good<br />

+/- acceptable<br />

- less good


Advantages of both binder systems<br />

polyMIM ® water soluble<br />

debinding <strong>feedstock</strong><br />

Environmental friendly binder<br />

system<br />

polyPOM catalytic<br />

debinding <strong>feedstock</strong><br />

Use of existing equipment at<br />

the MIM manufacturer<br />

Excellent surface quality Exceptionally fast debinding<br />

times<br />

Applicable for all materials Exceptional green part strength<br />

Exceptional carbon control<br />

(titanium, CC, special alloys)<br />

Good brown part strength<br />

Automated systems<br />

engineering<br />

We are able to offer the <strong>feedstock</strong> to suit for your<br />

application!


polyMIM ® –<strong>available</strong> <strong>feedstock</strong> <strong>grades</strong> <strong>Revision</strong> <strong>02.2012</strong><br />

Low Alloys<br />

Material Designation<br />

polyMIM FN02 MIM 2200<br />

polyMIM 4605 MIM FN0205<br />

polyMIM FN08 MIM 2700<br />

polyMIM FN0805 ----<br />

polyMIM 100Cr6 1.3505<br />

polyMIM 8620 1.6523<br />

polyMIM 8740 1.6546<br />

polyMIM 42CrMo4<br />

1,7225<br />

MIM 4140<br />

polyMIM 4340 1.6944<br />

polyMIM 16MnCr5 1.7131<br />

polyMIM 1006 mod. --<br />

Stainless Steels<br />

Material Designation<br />

polyMIM 17-4Ph 1.4542<br />

polyMIM 316L 1.4404<br />

polyMIM 316F 1.4404 mod.<br />

polyMIM 304L 1.4306<br />

polyMIM 430 1.4016<br />

polyMIM 440C mod. 1.4125<br />

polyMIM Nitronic 50<br />

polyMIM F75<br />

ASTM XM/19<br />

UNS S20910<br />

Co-28Cr-<br />

6Mo;<br />

ASTM F75<br />

polyMIM IN713C 2.4671<br />

Tungsten Carbide<br />

polyMIM<br />

WC0,8Co13,5<br />

polyMIM<br />

WC0,8Co10<br />

polyMIM<br />

WC0,8Co6<br />

Material Designation<br />

hard metal<br />

hard metal<br />

hard metal<br />

Tungsten Heavy Alloys<br />

polyMIM<br />

W-22Fe33Ni<br />

polyMIM<br />

W-3Fe7Ni<br />

Material Designation<br />

polyMIM W-20Cu<br />

Tool Steels<br />

---<br />

---<br />

Tungstencopper<br />

Material Designation<br />

polyMIM M2 1.3343<br />

Copper Alloys<br />

Material Designation<br />

polyMIM Cu999 ---<br />

polyMIM CuSn8 ---<br />

polyMIM CuNi9Sn6<br />

polyMIM CuNi15Sn8<br />

Niclafor Type<br />

1000<br />

Niclafor Type<br />

1001<br />

Titanium Alloys<br />

Material Designation<br />

polyMIM Ti grade 2 3.7035<br />

polyMIM Ti6Al4V 3.7165


polyPOM –<strong>available</strong> <strong>feedstock</strong> <strong>grades</strong> <strong>Revision</strong> <strong>02.2012</strong><br />

Low Alloys<br />

Material Designation<br />

polyPOM 1006 mod. --<br />

polyPOM 42CrMo<br />

1,7225<br />

MIM 4140<br />

polyPOM FN0805 --<br />

polyPOM FN08 MIM 2700<br />

polyPOM 4605<br />

MIM FN0205<br />

Stainless Steels<br />

Material Designation<br />

polyPOM 17-4PH 1.4542<br />

polyPOM 316L 1.4404<br />

polyPOM 410L 1.4024


AGENDA<br />

� Facts & Figures Polymer-Group<br />

� Facts & Figures <strong>PolyMIM</strong><br />

� Feedstock compounding<br />

� Debinding process<br />

� typical sintering process


polyMIM ® and polyPOM <strong>feedstock</strong> compounding<br />

Metal powder polyMIM or polyPOM binder sytem<br />

Feedstock


AGENDA<br />

� Facts & Figures Polymer-Group<br />

� Facts & Figures <strong>PolyMIM</strong><br />

� Feedstock compounding<br />

� Debinding process<br />

� typical sintering process


H 2O<br />

binder<br />

Debinding process<br />

Water soluble debinding Catalytic debinding<br />

Facts:<br />

water bath<br />

•Water temperature 40 to 60°C<br />

•Polyethyleneglycol (PEG) are<br />

dissolved by capillary forces<br />

•Low water circulation during process<br />

HNO 3<br />

formaldehyde<br />

CH 2O<br />

Facts:<br />

Nitrogen/nitric acid atmosphere<br />

•nitrogen/nitric acid atmosphere at<br />

a temperature between 110 and 120°C<br />

•Polyoxymethylene (POM) is<br />

converted into formaldehyde gas


Debinding process<br />

Water soluble debinding<br />

(drying process)<br />

Facts:<br />

vapor<br />

•drying temperature 80 to 100°C<br />

•circulation air or vacuum<br />

air<br />

Catalytic debinding<br />

(cleaning process)<br />

Facts:<br />

nitrogen<br />

formaldehyde - CH 2O<br />

nitrogen N 2<br />

•nitrogen purging time for a clean<br />

atmosphere in the furnace chamber<br />

• cooling down under 70°C


AGENDA<br />

� Facts & Figures Polymer-Group<br />

� Facts & Figures <strong>PolyMIM</strong><br />

� Feedstock compounding<br />

� Debinding process<br />

� typical sintering process


Typical MIM sintering process<br />

After debinding:<br />

Water soluble debinding Catalytic debinding<br />

Backbone<br />

Pores<br />

The debinding process creates an open-porosity throughout the molding with<br />

some residual binder (waxes etc.) left.<br />

The residual binder is removed from the structure during the thermal debinding<br />

process.


Temperature<br />

Typical MIM sintering process<br />

MIM SINTERING PROCESS<br />

Backbone binder<br />

removal<br />

Time<br />

Sintering at approx.<br />

0.8 x T s of metal


polyMIM and polyPOM feasibilities


polyMIM feasibilities<br />

Our offer:<br />

�The optimised <strong>feedstock</strong> system for your application<br />

� Broad material range including Cu alloys, Ti alloys as well as<br />

cemented carbides<br />

� Custom made <strong>feedstock</strong>s with adapted material properties<br />

� Support during the complete injection moulding process<br />

� raw material choice<br />

� tooling<br />

� sampling<br />

� serial production<br />

� equipment selection<br />

<strong>PolyMIM</strong> your fast and flexible partner in the metal injection<br />

moulding business!


POLYMIM <strong>GmbH</strong> your reliable partner!<br />

Thank you for you<br />

attention!<br />

<strong>PolyMIM</strong> <strong>GmbH</strong>, Europe<br />

info@polymim.com<br />

Phone +49 (0) 6751 /85769-0<br />

Fax +49 (0) 6751 /85769-5300

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