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Viviana's Chemistry Notebook

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addition to this,in order for it to remain the same, nothing must be added to the chemical reaction.<br />

11 In which of the following reactions involving gases would the forward reaction be favored by an<br />

increase in pressure?<br />

A A + B ⇄AB<br />

B A + B ⇄ C + D<br />

C 2A + B ⇄ C + 2D<br />

D AC ⇄ A + C<br />

Question 11: In order to understand this problem, we must look at<br />

Le Chatelier’s principle. Le Chatelier’s principle can predict the effect<br />

of a change in conditions on a chemical equilibrium. Additionally, the<br />

equilibrium will shift in a direction that will decrease the pressure of<br />

each gas closer to what it was originally. Therefore, if the pressure<br />

of A, B, and AB are increased, then the equilibrium will shift and<br />

decrease the total number of molecules and decrease the pressure.<br />

On the other hand, the rest of the equations would end up having an<br />

equal number of molecules on each side, causing there to be no<br />

shift whether pressure is increased or decreased. Therefore, the<br />

answer will be A.<br />

12 Which action will drive the reaction to the right?<br />

A heating the equilibrium mixture<br />

B adding water to the system<br />

C decreasing the oxygen concentration<br />

D increasing the system’s pressure<br />

4HCl(g) + O2(g) ⇄ 2H2O(l) + 2Cl2(g) + 113 kJ<br />

Question 12: Looking at the equation 4HCl(g) + O2(g) ⇄ 2H2O(l) + 2Cl2(g) + 113 kJ, increasing the<br />

systems pressure will direct it to shift to the right. It states that an increase of pressure in a system will<br />

shift towards fewer molecules of gas. This is based off Le Chatelier’s principle, which is used to<br />

predict the effect of a change in conditions on a chemical equilibrium. Therefore, Le Chatelier’s<br />

principle demonstrates that considering that equation, increasing the system’s pressure will cause it<br />

to shift to the right of the container it is being held in. The answer to this question is D.<br />

NO2(g) + CO(g) ⇄ NO(g) + CO2(g)<br />

13 The reaction shown above occurs inside a closed flask. What action will shift the reaction to the<br />

left?<br />

A pumping CO gas into the closed flask<br />

B raising the total pressure inside the flask<br />

C increasing the NO concentration in the flask<br />

D venting some CO2 gas from the flask<br />

146

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