Research Theme 7:MAGNETOHYDRODYNAMICAND ELECTROCHEMICALPHENOMENA INREMELTING PROCESSESA. Kharicha, E. Karimi-Sibaki, M. Wu, A. LudwigAims and key objectives• To understand the interaction between phasedistribution and magnetohydrodynamicswhen strong electric currents are applied;• To predict the electrical current path in thepresence of strong spatial and temporalvariation of electric conductivity;• To solve process instabilities and predict the formationof defects in the electroslag remelting process(ESR) and vacuum arc remelting (VAR) process;• To understand electrochemical apects of theESR process;• To predict the thermal and solidification characteristicsduring remelting of different metallic alloys;• To explore the origin of the coherent arcbehaviour in the VAR process;abFigure 7:(a) Melting during the electroslag remelting process (ESR) process and (b) cathode spots distribution during the vacuumarc remelting (VAR) process. Red and yellow colours show a high electric current density. During ESR the formation of metaldroplets happens in a turbulent slag flow constantly heated by the strong electric current. In the figure the slag has beenmasked out. During VAR the electric current is extremely localised inside the so-called cathode spots, which move rapidly overthe surface of the electrode.18 Research Theme 7: Magnetohydrodynamic and Electrochemical Phenomena in Remelting Processes
Summary of key progress:1. We have developed a three dimensionalmultiphase model ofthe electroslag refining processesthat accounts for the interactionbetween electromagnetism, dropletformation and interface instabilities.2. We are modelling the ionic transportto understand the electricalbehavior of an electrolyte.3. We have applied the model to studyindustrial scale ESR to predict thepool depth and consequently thequality of the final ingot of process.This includes modelling of meltingof ESR electrodes.4. We related the electrical signal tophysical phenomena occurringinside the ESR process such as:droplet formation, interface instabilities,electrochemistry and intensityof the mould current. These resultsare now fully used for controllingthe process.5. We analysed the composition ofslag skin to understand the mechanismof its formation and its abilityto transfer electric current.6. For the VAR process, the effect ofarc behaviour, side-arcing, and gascooling were explored. We foundthat the origin of the arc behaviouris related to the collective motion ofcathode spots.7. Impacts of process parameterssuch as applied electrical currentfrequency were predicted and fullyverified in industrial plants.Potential long-term impact:In order to decrease CO 2production,the developments of new generationof metallurgical processes using electriccurrents are planned by the worldleading industrial groups. Strong currentswill be transferred through plasmaand high temperature electrolytesto achieve production of new metallicalloys. Fundamental knowledge builtby our research has the potential tosolve complex physical, technical anddesign issues that can arise duringthese crucial developments.Selected impacts:1. Invited (keynote/plenary) lecture:• A. Kharicha: “Collective motion of cathode spots in the VAR process”,plenary, 8 th Int. Workshop on Mechanisms of Vacuum Arcs, Padova, Italy,Sept. 16-19, 2019.• A. Ludwig, M. Wu, A. Kharicha: “Recent Developments in Multiphase/MultiphysicsCFD Simulations in Steelmaking”, keynote, 8 th Int. Conf. on Mod.& Simul. of Metall. Processes in Steelmaking (STEELSIM2019), Toronto,Canada, Aug. 13-15, 2019.• A. Kharicha: “Modelling MHD applied in Metallurgy”, American Universityof Beirut, host Prof. M. Darwish, Lebanon, Dec 26. 2018• A. Kharicha, E. Karimi-Sibaki, M. Wu M, A. Ludwig: “Modeling of electricallyinduced flows”, keynote, Electromagnetic Processing of Materials (EPM2018), Hyogo, Japan, Oct. 14-18, 2018.2. In 2017 the group was invited by Wiley’s Steel Research Int. Journal to writea scientific review article on the Electro Slag Remelting (ESR) process3. In 2016, Dr. Karimi-Sibaki won a share of INTECO-ASMET award for hisscientific contribution in the field of Metallurgy4. In 2017, a figure from the paper “Toward Modeling of ElectrochemicalReactions during Electroslag Remelting (ESR) Process” appeared as thecover picture of the journal of Steel Research InternationalSelected publications:1. E. Karimi-Sibaki, A. Kharicha, J. Bohacek, M. Wu, A. Ludwig: “A ParametricStudy of the Vacuum Arc Remelting (VAR) Process: Effects of Arc Radius,Side Arcing, and Gas Cooling”, Metall. Mater. Trans. (2019) 1-14.2. E. Karimi-Sibaki, A. Kharicha, J. Bohacek, M. Wu, A. Ludwig: “Contributionof an Electro-Vortex Flow to Primary, Secondary, and Tertiary Electric CurrentDistribution in an Electrolyte”, J. Electrochem. Soc. 165 (2018) E604-153. E. Karimi-Sibaki, A. Kharicha, M. Wu, A. Ludwig, J. Bohacek: “Confrontationof the Ohmic approach with the ionic transport approach for modeling theelectrical behavior of an electrolyte”, Ionics 24 (2018) 2157–65.4. E. Karimi-Sibaki, A. Kharicha, M. Wu, A. Ludwig, J. Bohacek: “Modelingelectrochemical transport of ions in the molten CaF2 –FeO slag operatingunder a DC voltage”, Appl. Math. Comput. 357 (2018) 357-73.5. A. Kharicha, E. Karimi-Sibaki, M. Wu, A. Ludwig, J. Bohacek: “Review onModeling and Simulation of Electroslag Remelting”, Steel Res. Int. 89(2018) 1700100:1-20.6. E. Karimi-Sibaki, A. Kharicha, M. Wu, A. Ludwig, J. Bohacek: “TowardModeling of Electrochemical Reactions during Electroslag Remelting (ESR)Process”, Steel Res. Int. 88 (2017) 1700011:1-8.7. A. Kharicha, M. Wu, A. Ludwig, E. Karimi-Sibaki: “Simulation of the ElectricalSignal During the Formation and Departure of Droplets in the Electro SlagRemelting Process”, Metall. Mater. Trans. B 47 (2016) 1427-34.8. E. Karimi-Sibaki, A. Kharicha, J. Bohacek, M. Wu, A. Ludwig: “On Validityof Axisymmetric Assumption for Modeling an Industrial Scale ElectroslagRemelting Process”, Adv. Eng. Mater. 18 (2016) 224-30.9. E. Karimi-Sibaki, A. Kharicha, J. Bohacek, M. Wu, A. Ludwig: “A DynamicMesh-Based Approach to Model Melting and Shape of an ESR Electrode”,Metall. Mater. Trans. 46 (2015) 4854-67.19