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Battery raw materials<br />

An article published in<br />

www.metalbulletin.com<br />

Copyright (c) 2020 Euromoney Global Limited trading as Fastmarkets<br />

Mining and recycling<br />

strategic battery metals<br />

As part of a strategy to diversify its activities, the Germany-based<br />

international plant builder and engineering business <strong>SMS</strong> <strong>group</strong> is applying<br />

its technological expertise to processing ores and the means to recycle<br />

lithium batteries. Chief technology officer Hans Ferkel and senior vice<br />

president for strategic project development Herbert Weissenbaeck discuss<br />

the <strong>group</strong>’s plans and progress with Richard Barrett<br />

Of all the battery metals to have<br />

emerged as a key component of the<br />

energy storage vital for modernday<br />

life, lithium is probably the<br />

best known in the public mind in<br />

view of its widespread use in<br />

rechargeable phones, power tools,<br />

electric vehicles (EVs) and a wide<br />

range of other applications.<br />

While global production of<br />

lithium has grown to meet<br />

climbing demand in recent years,<br />

the issues of exactly where the<br />

metal is mined and processed for<br />

batteries internationally – and<br />

how it can be recycled when<br />

batteries reach the end of their life<br />

– have become strategic. Owing to<br />

large-scale development plans in<br />

the EV industry, there are also<br />

questions about whether lithium<br />

production will be sufficient to<br />

meet future demand within the<br />

next 4-7 years.<br />

Such considerations have<br />

encouraged development of<br />

minerals processing and lithium<br />

battery-grade chemicals<br />

production at the Cinovec project<br />

in the Czech Republic. Towards<br />

the end of September, <strong>SMS</strong> <strong>group</strong><br />

announced that it had been<br />

appointed by Geomet s.r.o., a joint<br />

venture between Australian<br />

mineral exploration and<br />

development company European<br />

<strong>Metal</strong>s and Czech energy giant<br />

CEZ, as the lead engineer for the<br />

project. The Germany-based<br />

international plantmaker will<br />

<strong>SMS</strong> GROUP<br />

supply front-end engineering<br />

design (FEED) for what it says will<br />

be Europe’s first lithium battery<br />

chemicals facility.<br />

The new facility is set to produce<br />

about 22,500 tons of lithium<br />

carbonate or about 25,000 tons of<br />

lithium hydroxide per year (both<br />

of battery grade), as well as tin and<br />

tungsten concentrates from a<br />

by-products recovery circuit. <strong>SMS</strong><br />

<strong>group</strong> will provide the process and<br />

plant technology for the complete<br />

process chain: from ore<br />

comminution, via logistics for<br />

concentrate handling, up to and<br />

including the extractive<br />

metallurgy processes (see graphic of<br />

plant layout).<br />

Under the FEED agreement,<br />

<strong>SMS</strong> <strong>group</strong> will provide full<br />

process integration, from the point<br />

of delivery of ore to the<br />

underground crusher, through to<br />

the delivery of finished batterygrade<br />

lithium chemicals for<br />

battery and cathode<br />

manufacturers. This encompasses<br />

comminution, beneficiation,<br />

Plant design for<br />

battery-grade<br />

lithium chemicals<br />

production<br />

roasting, leaching and purification<br />

as well as the lithium process<br />

flowsheet and the tin/tungsten<br />

recovery circuit delivering metal<br />

concentrates to refineries.<br />

The aim of the FEED is to<br />

deliver a binding fixed-price<br />

lump-sum turnkey Engineering,<br />

procurement, and construction<br />

(EPC) contract with associated<br />

process guarantee and product<br />

specification guarantees for<br />

battery-grade lithium chemicals.<br />

Predicting the need<br />

“In the last few years, we have<br />

gained a strong position within the<br />

fast-growing segment of<br />

technological metals, including<br />

those for battery production,” said<br />

Herbert Weissenbaeck, <strong>SMS</strong><br />

<strong>group</strong> vice president for strategic<br />

project development, at the time<br />

of signing the contract.<br />

<strong>SMS</strong> <strong>group</strong> notes that there is<br />

good reason to believe there will be<br />

increasing lithium project activity<br />

within Europe. “Given the situation<br />

that in Europe lithium ion battery<br />

production capacities equating to<br />

about 200 GWh per year are being<br />

planned or are currently under<br />

construction, and the fact that<br />

about 800 t of lithium carbonate are<br />

needed to produce one gigawatt<br />

hour of battery capacity, the<br />

production volume planned by<br />

Geomet in the first phase of the<br />

project will only cover a small<br />

portion of the medium-term<br />

48 | <strong>Metal</strong> <strong>Market</strong> <strong>Magazine</strong> | November-December 2020


demand generated in Europe,” it<br />

highlighted in a press release.<br />

The company believes that the<br />

FEED contract appointment, at<br />

what it says is Europe’s largest<br />

hard-rock lithium resource, will put<br />

the company at the forefront of this<br />

developing industry. <strong>SMS</strong> <strong>group</strong><br />

also stated: “Especially, as we see<br />

that off-the-shelf metallurgical<br />

processes are becoming<br />

increasingly inadequate for the<br />

extraction of valuable metals from<br />

non-conventional ores at<br />

reasonable costs and with a<br />

minimum ecological footprint, we<br />

can count on our broad-based<br />

portfolio of technologies and our<br />

extensive know-how in both pyro<br />

and hydrometallurgy, offering our<br />

customers in the technological<br />

metals sector optimized, integrated<br />

solutions.”<br />

Weissenbaeck explained further.<br />

“Around 15 years ago we started<br />

looking at the potential for growth in<br />

metallurgical plants and our volume<br />

of business and we figured out even<br />

back then that it was becoming<br />

obvious that growth in steel<br />

metallurgical plants would be slower<br />

than for new technology metals that<br />

go into products for an electrified<br />

future – like lithium, vanadium,<br />

nickel and cobalt,” he told <strong>Metal</strong><br />

<strong>Market</strong> <strong>Magazine</strong>.<br />

“Of course we supply blast<br />

furnaces and casters and rolling mills<br />

and other metals-making and<br />

forming equipment, but we have<br />

also always had a strong portfolio of<br />

processing lines, which involve quite<br />

a lot of sophisticated chemistry,” he<br />

added. “Descaling of carbon steel<br />

and stainless steels requires the<br />

recovery of acids and the various<br />

caustics involved. In the chemistry<br />

department, we realised that metals<br />

like lithium would develop strong<br />

economic demand and that we had<br />

quite a lot of processing steps<br />

suitable for their extraction from<br />

complex ores in our toolbox.”<br />

He said that, performed in the<br />

right sequence, some of those<br />

processing steps are very suitable for<br />

implementing production routes for<br />

lithium carbonate, lithium<br />

hydroxide, vanadium pentoxide and<br />

vanadium electrolytes.<br />

<strong>SMS</strong> <strong>group</strong> opened its<br />

hydrometallurgical laboratory in<br />

Vienna in 2008. “We started out<br />

'We can count<br />

on our broadbased<br />

portfolio<br />

of technologies<br />

and our<br />

extensive<br />

know-how in<br />

both pyro and<br />

hydrometallurgy'<br />

Slovakian battery manufacturer InoBat Auto offers the latest<br />

developments in lithium-ion battery cells to a range of markets and<br />

applications. The company recently entered into a memorandum of<br />

understanding with Primobius that provides an evaluation<br />

framework towards a potential Primobius-Inobat cooperation to<br />

operate a commercial lithium-ion battery recycling facility in Eastern<br />

Europe. InoBat is building a ‘gigafactory’ and it is anticipated that the<br />

company will produce 50,000 tons per year of new batteries after its<br />

full commercial start (expected in 2024).<br />

small just with metallurgical test<br />

work, mainly to complement<br />

process developments around our<br />

main lines of business, but now we<br />

are increasingly dealing with<br />

numerous non-conventional<br />

sources of battery and technology<br />

materials as the easy to mine and to<br />

process ores, such as for example<br />

nickel sulfates, are running out and<br />

that more complex sources, that<br />

require bespoke, environmentally<br />

friendly and energy-efficient<br />

processing solutions, such as – to<br />

stay with the same example – nickel<br />

laterites are receiving increasing<br />

attention.”<br />

He reminded that conventional<br />

sources of nickel are the nickel<br />

sulfates found in the northern<br />

hemisphere, such as the major<br />

deposits of Norilsk, or at Sudbury,<br />

in Canada. “Nickel sulfate<br />

processing more often than not<br />

entails a significant sulfur dioxide<br />

footprint, and so permitting [for<br />

processing] in the Western world is<br />

quite a challenge,” he added.<br />

He pointed to plentiful resources<br />

of laterites in the tropics as the<br />

likely main future sources of nickel,<br />

but added that the incumbent<br />

processing methods for those ores<br />

are rather capex and opex intensive.<br />

“So the industry was spending<br />

quite a lot of money on researching<br />

new routes for that and this was one<br />

of the entry points for us as a<br />

hydrometallurgical laboratory for<br />

test and development work on new<br />

hydrometallurgical routes for the<br />

extraction of nickel and cobalt<br />

concentrates from those sources,”<br />

Weissenbaeck explained.<br />

Over time those activities<br />

increased. <strong>SMS</strong> <strong>group</strong> signed a<br />

contract two years ago with Altech<br />

Chemicals, which produces<br />

high-purity alumina, driven by the<br />

battery industry, which is in high<br />

demand as a coating material for<br />

the separator foils in lithium-ion<br />

batteries. Weissenbaeck noted that<br />

an alumina coating is applied to<br />

those separator foils as a precaution<br />

against battery fires as well as to<br />

inhibit battery charging-depth<br />

degradation. “There is an<br />

increasing demand for that and,<br />

together with Altech, we did a<br />

FEED study for an integrated HPA<br />

plant and – based on that – we<br />

signed a turnkey fixed-price EPC<br />

contract for US$280 million to be<br />

executed on their site in Johor<br />

Bahru, Malaysia,” he highlighted.<br />

“Now the ‘lithium train’ is<br />

leaving the station and accelerating,<br />

and here in Europe especially,” said<br />

Weissenbaeck. “The European<br />

November-December 2020 | <strong>Metal</strong> <strong>Market</strong> <strong>Magazine</strong> | 49<br />

<strong>SMS</strong> GROUP


Battery raw materials<br />

<strong>SMS</strong> <strong>group</strong> chief technology<br />

officer Hans Ferkel said the<br />

company formed Primobius<br />

as a 50:50 joint venture with<br />

Neometals to recycle battery<br />

raw materials<br />

governments have a tendency<br />

towards becoming autonomous<br />

when it comes to the supply of<br />

battery materials,” he added.<br />

He is consequently confident<br />

that the FEED deal with Geomet in<br />

the CEZ / European <strong>Metal</strong>s joint<br />

venture will not be the last one.<br />

“There are other countries that<br />

want to have their own lithium<br />

battery chemicals facilities to fuel<br />

the growing number of batterygigafactories.<br />

We are participating<br />

in this trend and are anticipating<br />

having the edge over others,<br />

especially here in Europe,” he said,<br />

adding that, as a supplier that has<br />

invested in getting its toolbox and<br />

processing steps lined up in order<br />

to master the underlying<br />

processing challenges, <strong>SMS</strong> <strong>group</strong><br />

sees itself as very well positioned.<br />

Compact timeframe<br />

There are 14 months to complete<br />

the FEED project for the Cinovec<br />

project, but then what will the<br />

timeframe be to start building the<br />

commercial plant to process ore<br />

from that mine if all goes to plan?<br />

“In projects of this nature, the<br />

length of the local permitting<br />

processes is more often than not<br />

becoming the main determinant for<br />

the project timeline,” said<br />

Weissenbaeck. “Apart from that,<br />

the execution time for this<br />

particular project, depending on<br />

the chosen execution strategy and<br />

structure, is not expected to differ<br />

much from what one would expect<br />

for a greenfield medium-size<br />

processing plant complex in a<br />

location with substantial existing<br />

industrial infrastructure, such as<br />

the infrastructure at Cinovec."<br />

How will <strong>SMS</strong> <strong>group</strong> organize its<br />

<strong>SMS</strong> GROUP<br />

‘The Primobius<br />

recycling<br />

process targets<br />

the recovery<br />

of valuable<br />

materials from<br />

consumer<br />

electronic<br />

batteries ’<br />

project team from across the<br />

diverse range of engineers and<br />

technologists in the company? “We<br />

will put together all the people who<br />

are willing and able to work on this<br />

project – that is very important,”<br />

said chief technology officer Hans<br />

Ferkel. “Because sometimes if you<br />

want to have a big change in a<br />

company, you need people who are<br />

willing to change and interested in<br />

it. If you ask, then you will find<br />

people in the company who are<br />

willing and you can educate people,<br />

who may not be the absolute<br />

experts on something but, if they<br />

are willing to do it, they can learn it<br />

quickly, building not only on the<br />

distinct DNA of an engineering<br />

company with a strong track record<br />

in disruptive innovation, but also<br />

on the substantial groundwork<br />

already completed by European<br />

<strong>Metal</strong>s over the last 5 years,” he<br />

stressed. The FEED project team is<br />

expected to exceed 100 people.<br />

Alpha and omega<br />

In addition to expanding its<br />

in-house expertise in ore processing<br />

technology, the company is also<br />

investing in technologies for the<br />

other end of the battery supply<br />

chain, having recently acquired a<br />

stake in lithium-ion battery recycler<br />

Primobius GmbH.<br />

“We talk a lot about the<br />

ingredients you need to make<br />

batteries to drag out of the earth to<br />

the manufacturers of these kinds of<br />

batteries, but still then you have to<br />

close the loop,” said Ferkel. “That is<br />

the reason that we have formed this<br />

50:50 joint venture with Neometals<br />

called Primobius,” he explained.<br />

The Primobius recycling<br />

process targets the recovery of<br />

valuable materials from consumer<br />

electronic batteries, including<br />

devices with lithium cobalt oxide<br />

cathodes and nickel-rich electric<br />

vehicle and stationary storage<br />

battery chemistries (with lithiumnickel-manganese‐cobalt<br />

cathodes). Primobius notes that its<br />

technology supports multiple<br />

chemistries and formats,<br />

sometimes without prior<br />

discharging of the batteries. A wet<br />

shredding process is used to<br />

reduce the risk of fire hazard and a<br />

combined off-gas system with<br />

filtering and wet scrubbing is used<br />

to remove volatile organic<br />

compounds and dust.<br />

“We are trying to use a<br />

hydrometallurgical approach to<br />

recycle all the most important<br />

ingredients out of these materials.<br />

We first shred the batteries and<br />

then we have finally the black<br />

mass, containing the most valuable<br />

elements – for example cobalt,<br />

manganese, carbon and lithium –<br />

and this needs to be recycled at a<br />

very high level of perhaps 90% or<br />

more because this is very efficient<br />

and then we can close the loop,”<br />

Ferkel added.<br />

Having undertaken laboratoryscale<br />

testing, the company is now<br />

building a 1,000 tpy pilot plant in<br />

Germany at the site of the <strong>group</strong>’s<br />

foundation and major engineering<br />

workshops in Hilchenbach, which<br />

will start operation next year. It<br />

will take “all batteries coming out<br />

of the field, or ones that have been<br />

rejected during manufacture<br />

because of some quality problems,<br />

which also have to be recycled,”<br />

said Ferkel. Its output will be the<br />

ingredients needed to make new<br />

batteries.<br />

If the technology scales up<br />

successfully, Ferkel said that a<br />

commercial-scale recycling plant<br />

with a capacity of 20,000 tpy of<br />

battery input or more is envisaged.<br />

“In the intermediate step we can<br />

really test all these things,” he<br />

added.<br />

According to Primobius, it is<br />

likely that over 15 million tonnes<br />

of lithium-ion batteries could be<br />

discarded globally from 2020-30,<br />

so the need for technologies to<br />

recycle them is ever more pressing<br />

Herbert Weissenbaeck, <strong>SMS</strong><br />

<strong>group</strong> vice president for strategic<br />

project development, said the<br />

company realised that metals like<br />

lithium would develop strong<br />

demand and that <strong>SMS</strong> <strong>group</strong><br />

already had many processing<br />

steps suitable for their extraction<br />

from complex ores<br />

<strong>SMS</strong> GROUP<br />

50 | <strong>Metal</strong> <strong>Market</strong> <strong>Magazine</strong> | November-December 2020


and in an increasing number of<br />

nations recycling is mandatory.<br />

Funding the future<br />

For speed in a competitive arena,<br />

the battery recycling project<br />

partners have found the money to<br />

fund the pilot project from their<br />

own resources. “For the battery<br />

recycling, we are doing everything<br />

on our own, to be quick and keep<br />

the key know-how in the company<br />

and own the intellectual property<br />

needed ultimately to earn<br />

money,” Ferkel explained.<br />

Later on, for a commercialscale<br />

plant, decisions will be made<br />

on when and whether to involve<br />

partners to source funding for<br />

larger scale projects.<br />

The timeframe for the<br />

Primobius pilot is set. “We will<br />

start next year. We want to test all<br />

the batteries and get the products<br />

out of it and then deliver those to<br />

potential customers for these<br />

types of chemicals in order to<br />

make new batteries. So we want to<br />

have this done next year,” Ferkel<br />

concluded.<br />

Reinventing <strong>SMS</strong> <strong>group</strong><br />

While <strong>SMS</strong> <strong>group</strong> has a long-established<br />

range of plant and technologies, including<br />

meltshops, steel and non-ferrous rolling<br />

mills, processing lines, and forging and<br />

extrusion equipment for international<br />

markets that it continues to serve, it is also<br />

consciously diversifying its activities to<br />

supply rapidly emerging markets, such as<br />

the battery metals projects described in the<br />

main article, plus scandium, niobium,<br />

silicon and various rare earths.<br />

Demand for metals that have historically<br />

been more or less the captive by-products of<br />

the production of other metals – sometimes<br />

used as the definition of a minor metal – has<br />

catalysed the development of processes and<br />

technologies to enable their production from<br />

unconventional sources or via advanced<br />

recycling schemes, and sometimes both.<br />

It is the potential growth in demand for<br />

equipment needed for those new markets<br />

that has stimulated <strong>SMS</strong> <strong>group</strong>’s<br />

diversification and a degree of reinvention.<br />

While the smelting, rolling and finishing of<br />

industrial metals like steel and aluminium<br />

remain core parts of the company’s portfolio,<br />

pyrohydrolysis, hydrolytic distillation,<br />

oxidative precipitation and fluidised bed<br />

technology, together with other techniques<br />

of extractive metallurgy, have become an<br />

extended part of the company’s range in<br />

recent years.<br />

In addition to the example of the project<br />

with Altech on high-purity alumina (see<br />

main article), Australian mining corporation<br />

TNG Limited, based in Perth, Australia,<br />

and <strong>SMS</strong> <strong>group</strong> plan to implement a process<br />

enabling the production of CO 2<br />

-neutral<br />

hydrogen as the Mount Peake titanium/<br />

vanadium/iron project is developed in the<br />

Northern Territory of Australia. The<br />

hydrogen produced will be used as a<br />

reducing agent to make the production of<br />

titanium, vanadium and iron from<br />

fine-grained titanomagnetite concentrate<br />

carbon-neutral.<br />

Under the umbrella of its New Horizons<br />

programme, many other projects are under<br />

way that are also not connected directly with<br />

the <strong>group</strong>’s traditional core business.<br />

<strong>SMS</strong> GROUP<br />

Additive manufacturing<br />

“For example, powder metallurgy [and 3D<br />

printing] are not in our core business yet,”<br />

said Ferkel, but the company has already<br />

made significant in-roads into that area.<br />

“We sold a metal-powder atomization plant<br />

to Outokumpu as equipment as a service<br />

and we are also looking to our own plants<br />

that we are selling to see where we can use<br />

3D printed parts,” he added.<br />

The atomization plant for Outokumpu<br />

– scheduled to become operational in early<br />

2022 – will be designed for an annual<br />

production of up to 330 tons of stainless steel<br />

powder. It is also a first for <strong>SMS</strong> <strong>group</strong> in<br />

being the first ever facility that the company<br />

is supplying under a subscription contract.<br />

One of the established advantages of<br />

additive manufacturing is its ability to make<br />

parts that can be designed on a computer<br />

with advanced design software, but which<br />

are impossible to actually make by using<br />

conventional machining techniques. “Some<br />

things are not possible if you try to produce<br />

it by conventional drilling or cutting, so you<br />

Forging of the first billet on the highspeed<br />

open-die forging press supplied<br />

by <strong>SMS</strong> <strong>group</strong> to Gustav Grimm in<br />

Remscheid, Germany<br />

have to produce it by a flow model or<br />

similar,” Ferkel elaborated. “It can be nice<br />

looking, but then no-one can produce it.<br />

With 3D printing, you can produce such<br />

parts and that is also something we can use<br />

in our plant at different sites,” he added.<br />

A manufacturer of high-alloy forgings,<br />

Gustav Grimm Edelstahlwerk GmbH &<br />

CO. KG, based in Remscheid, Germany,<br />

started running a 31.5/34-MN high-speed<br />

open-die forging press supplied by <strong>SMS</strong><br />

<strong>group</strong> earlier this year (see photo). For the<br />

first time, the plantmaker installed an<br />

additively manufactured machine<br />

component in an open-die forging press.<br />

Made from aluminium alloy, the<br />

3D-printed hydraulic manifold block is<br />

much lighter and more compact than one<br />

conventionally made from steel, and has a<br />

flow-optimized design.<br />

Changing mindset<br />

Introducing such new technologies and<br />

concepts into <strong>SMS</strong> <strong>group</strong> – a company with<br />

a mechanical engineering heritage<br />

stretching back well over a century – can<br />

raise challenges.<br />

“That is another reason why you need an<br />

interdisciplinary team because sometimes,<br />

also, you need someone to sign for it that this<br />

component will work and then you must be<br />

sure,” said Ferkel. “If you confront someone<br />

with perhaps 30 years on normal technology<br />

of manufacturing things, then to change this<br />

guy to be able to think in a 3D-printed<br />

manner – that needs some time. So you<br />

always need this mix of young,<br />

open-minded people that challenge the<br />

more experienced people and finally<br />

something useful comes out,” he explained.<br />

Ferkel described the site of one of <strong>SMS</strong><br />

<strong>group</strong>’s major workshops, at Hilchenbach in<br />

Germany, where the 1,000 tpy pilot<br />

lithium-ion battery recycling plant<br />

described in the main article is being built, as<br />

the “cradle of the <strong>SMS</strong> <strong>group</strong>.” He said that<br />

it also shows how the <strong>SMS</strong> <strong>group</strong> is able to<br />

reinvent itself again and is also able to<br />

change: “It is not just a physical change but a<br />

mindset change,” he concluded.<br />

November-December 2020 | <strong>Metal</strong> <strong>Market</strong> <strong>Magazine</strong> | 51


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