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Emulsions for Adhesives Emulsions for Adhesives - Clariant

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Mowilith<br />

<strong>Emulsions</strong><br />

<strong>for</strong><br />

<strong>Adhesives</strong><br />

Exactly your chemistry<br />

®


2<br />

Welcome to <strong>Clariant</strong>´s<br />

world of emulsions<br />

The world of emulsions has many<br />

different facets. After all, today’s<br />

water based emulsions are<br />

essential base materials <strong>for</strong><br />

numerous applications. There<strong>for</strong>e,<br />

they are present almost<br />

everywhere in our day-to-day life.<br />

They help us solve various tasks,<br />

improve the properties of many<br />

Exactly your chemistry.<br />

products and are important<br />

components in everyday items. In<br />

addition, emulsions are water-based<br />

and almost never require solvent in<br />

the final products. For this reason<br />

they are particularly suitable <strong>for</strong> the<br />

manufacture of environmentalfriendly<br />

products.<br />

R&D Sites<br />

Production Sites


Monomer systems<br />

Vinyl acetate<br />

Vinyl acetate/ethylene<br />

Vinyl acetate/vinyl chloride/ethylene<br />

Vinyl acetate/ethylene/acrylate<br />

Vinyl acetate/VeoVa ®/ethylene<br />

Vinyl acetate/VeoVa ®<br />

Vinyl acetate/maleate<br />

Vinyl acetate/acrylate<br />

Acrylate<br />

Styrene/acrylate<br />

Your world-wide local partner<br />

One of our most important aims at<br />

<strong>Clariant</strong> is to identify and respond<br />

to your needs quickly and backed<br />

by the best technical support. Our<br />

representatives in 120 countries<br />

provide the regional <strong>for</strong>ce to<br />

achieve this. You can rely on us <strong>for</strong><br />

emulsions. Production sites in 27<br />

countries world-wide always guarantee<br />

you short supply routes and<br />

deliveries at minimum delivery<br />

times. Our local technical staff will<br />

<strong>for</strong> emulsions <strong>for</strong> adhesives<br />

be there quickly not only to help<br />

you to solve problems but also <strong>for</strong><br />

joint developments.<br />

Our Research and Development<br />

department is in close contact with<br />

the local representatives and<br />

maintains an intensive transfer of<br />

know-how. Thus you are able to<br />

benefit also from know-how and<br />

expertise acquired at the other<br />

end of the world.<br />

The range of monomer systems <strong>for</strong><br />

our emulsions, as depicted below,<br />

is extremely wide. In this way we<br />

are able to respond directly to your<br />

local production requirements as<br />

well as to different market<br />

requirements in the various regions<br />

across the world.<br />

Exactly your chemistry. 3


4<br />

Adhesive raw materials<br />

from <strong>Clariant</strong><br />

<strong>Clariant</strong> is your best partner to<br />

manufacture almost all types of<br />

waterbased adhesives. You can<br />

benefit from our large research<br />

and development capability, our<br />

global reach and our broad range<br />

of products.<br />

The Mowilith ® group of<br />

environmental-friendly, water<br />

based emulsions comprises a<br />

broad range of products.<br />

Continuous investment in the<br />

improvement of product quality<br />

Applications:<br />

Sticking and Laminating<br />

Wood<br />

Wood/film<br />

Paper/packaging<br />

Plastic/porous substrate<br />

Floor/wall/ceiling<br />

Leather/Textiles<br />

Type of adhesive<br />

Pressure-sensitive adhesives<br />

Contact adhesives<br />

Temperature-activated films<br />

Water-activated films<br />

Exactly your chemistry<br />

and per<strong>for</strong>mance exemplifies our<br />

commitment to the adhesives<br />

industry. Homopolymers and<br />

copolymers based on vinyl acetate<br />

make up the largest share. Due to<br />

their outstanding properties vinyl<br />

acetate/ethylene emulsions are<br />

able to meet even the highest<br />

demands concerning the use on<br />

fast running machines, cohesion<br />

and adhesion towards a large variety<br />

of difficult substrates.<br />

<strong>Adhesives</strong> <strong>for</strong>mulated with<br />

D ca. 50%<br />

LD 160<br />

D ca. 60%<br />

DNN ca. 60%<br />

DH 257<br />

DHS S1<br />

Mowilith ® emulsions are<br />

characterised by the following<br />

features:<br />

- Excellent adhesion to a large<br />

number of substrates<br />

- High setting speed<br />

- High final bond strength<br />

- High heat resistance and good<br />

ageing properties of the bonds<br />

- According to the needs good<br />

water resistance or re-emulsifiability<br />

of the films<br />

- Safe handling and trouble-free<br />

DC<br />

DLR<br />

DHWR<br />

LDL 2555 W<br />

LDL 2510 W<br />

D 025/1<br />

LDM 1025<br />

working<br />

- Long shelf-life<br />

The largest (in terms of volume)<br />

and most important target markets<br />

<strong>for</strong> water-based emulsion<br />

adhesives are:<br />

1.The wood and furniture industry<br />

2. The paper and packaging industry<br />

3.The construction industry –<br />

floors, walls and ceilings<br />

The overview below shows, in a<br />

summarised <strong>for</strong>m, a selection of<br />

our wide product range <strong>for</strong><br />

DM 104<br />

DM 105<br />

DM1062<br />

DM 107<br />

DM 111<br />

DM 114<br />

Main application<br />

M o w i l i t h ® M o w i l i t h ®<br />

Use dependent on substrate<br />

Use under certain conditions<br />

DM 132<br />

DM 1330<br />

DM 1340<br />

LDM 1355<br />

DM 137<br />

DS 5/1<br />

LDM 2110<br />

LDM 6636<br />

LDM 7255<br />

Exactly your chemistry 5


6<br />

Mowilith ® emulsions <strong>for</strong> technical applications<br />

<strong>Adhesives</strong> <strong>for</strong> every task<br />

Wood gluing<br />

For wood the predominant<br />

assembly method is gluing. The<br />

high demands in this application<br />

area are met perfectly by<br />

adhesives based on polyvinyl<br />

acetate emulsions such as<br />

Mowilith DHS S1 with polyvinyl<br />

alcohol as protective colloid. The<br />

most important applications <strong>for</strong><br />

these adhesives include: assembly<br />

glue, veneer and surface glues,<br />

glues <strong>for</strong> edges and laminating<br />

adhesives <strong>for</strong> laminate sheets. The<br />

final bond strength in general<br />

exceeds the material strength of all<br />

the important types of wood used.<br />

Mowilith DHS S1<br />

Mowilith LDL 2555 W<br />

Mowilith LDL 2510 W<br />

In many cases, water-based wood<br />

glues also need to <strong>for</strong>m waterresistant<br />

bonds. In this application<br />

field, <strong>Clariant</strong> products such as<br />

Mowilith DHWR, LDL 2555 W and<br />

Mowilith LDL 2510 W, used as a<br />

one-pack or a two-pack<br />

<strong>for</strong>mulation in combination with<br />

hardener, can provide the answer.<br />

With adhesives based on these<br />

emulsions it is no problem to meet<br />

the requirements of the durability<br />

classes D3 (<strong>for</strong> Mowilith DHWR<br />

and LDL 2555 W) and D4 (<strong>for</strong> 2 pack<br />

systems with Mowilith LDL 2555 W<br />

and LDL 2510 W) of the European<br />

standard DIN EN 204.<br />

Exactly your chemistry.<br />

Lamination of wood<br />

Wood adhesives in a broader<br />

sense also include adhesives used<br />

in the finishing of chipboard, when<br />

PVC or impregnated paper films<br />

are applied as decorative and<br />

protective coating.<br />

Mowilith DM 105<br />

Mowilith DM 107<br />

Mowilith DM 114<br />

Test of creep strength of furniture film<br />

adhesives, e.g. on "paper films", as a<br />

function of peeling angle, temperature<br />

and load.<br />

Floating parquet glued with a<br />

D3 emulsions


<strong>Adhesives</strong> <strong>for</strong> paper and packaging<br />

In the area of adhesives <strong>for</strong> paper<br />

and packaging, <strong>Clariant</strong>’s water<br />

based emulsions are suitable <strong>for</strong><br />

an extremely wide range of applications.<br />

Apart from the manufacture<br />

and closing of packaging<br />

materials, they are used in adhesives<br />

<strong>for</strong> book binding, <strong>for</strong> lamination<br />

of paper to cardboard, <strong>for</strong> the<br />

manufacture of cardboard boxes<br />

and paper bags as well as <strong>for</strong> the<br />

preparation of spiral paper tubes.<br />

Most of the applications in the<br />

graphics industry are covered<br />

including high gloss film print<br />

lamination. <strong>Emulsions</strong> are also<br />

essential to <strong>for</strong>mulate adhesives <strong>for</strong><br />

cigarette manufacture and packaging.<br />

Mowilith D approx. 50%<br />

Mowilith DH 257<br />

Mowilith DS 5/1<br />

Mowilith DM 111<br />

Mowilith DM 105<br />

Mowilith DM 1062<br />

Mowilith DM 132<br />

Mowilith DM 137<br />

Mowilith LDM 7255<br />

Setting time (s)<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

Mowilith ® D ca. 50%<br />

Polyvinyl alcohol (PVAL)<br />

Dibutyl Phthalate (DBP)<br />

5 10 15 20<br />

Added Quantity of PVAL/DBP (%)<br />

Effect of modification with PVAL and<br />

DBP on the setting time, measured in<br />

the peel test with the Werle Tack<br />

Tester (paper/paper)<br />

The Finat loop test, test method nº 9,<br />

confirms the good surface tack of a film<br />

The Finat loop test, test method nº 9,<br />

based on Mowilith DM 137<br />

confirms the good surface tack of a film<br />

based on Mowilith DM 137<br />

Floor – wall – ceiling<br />

Because of the great variety of<br />

floor and wall coverings, different<br />

substrates and special<br />

per<strong>for</strong>mance requirements, the<br />

<strong>for</strong>mulation of suitable floor and<br />

wall adhesives is often fraught<br />

with complex problems.<br />

The trend clearly goes towards the<br />

solvent-free, water based adhesive<br />

systems, because aqueous<br />

adhesives provide the best solution<br />

to overcome environmental and<br />

odour problems.<br />

<strong>Clariant</strong>’s developments of<br />

emulsions <strong>for</strong> flooring adhesives<br />

<strong>for</strong> various floor coverings, e.g.<br />

carpet, PVC, linoleum, polyolefine<br />

layers as well as <strong>for</strong> parquet<br />

floorings, and others, enable our<br />

customers to <strong>for</strong>mulate adhesives<br />

with very low emission. Consumers<br />

require adhesive systems with<br />

environment protection, e.g. indicated<br />

by the EC 1 label of GEV<br />

which can be fulfilled in <strong>Clariant</strong>’s<br />

innovative emulsions.<br />

Mowilith DM 1340<br />

Mowilith LDM 1355<br />

Mowilith LDM 1025<br />

Testing of the setting-time of a PVC<br />

one-side floor adhesive based on<br />

Mowilith DM 1340.<br />

The weting of surfaces and wet<br />

adhesives strength are measured with<br />

the spring balance <strong>for</strong> predetermined<br />

periods.<br />

Testing of legging property<br />

Exactly your chemistry. 7


Representative Telephone<br />

Fax<br />

Germany<br />

<strong>Clariant</strong> GmbH ++49(0)69-305-2876 ☎<br />

Industriepark Höchst ++49(0)69-305-4748 ☎<br />

Division CEP/BU Dispersionen ++49(0)69-317140<br />

D- 65926 Frankfurt / Main<br />

Benelux<br />

<strong>Clariant</strong> Benelux N.V. ++31-203-989-960 ☎<br />

Division CEP ++31-203-989-963<br />

Diemerhof 36<br />

NL-1112 Diemen<br />

Italy<br />

<strong>Clariant</strong> (Italia) S.p.A. ++39-02-3263-1 ☎<br />

Division CEP ++39-02-3263-2262<br />

Via Traiano 18<br />

20149 Milano<br />

Austria<br />

<strong>Clariant</strong> (Österreich) GmbH ++43-1-801-22422 ☎<br />

Division CEP ++43-1-801-22942<br />

Breitenfurter Str. 239<br />

A-1131 Wien<br />

France<br />

<strong>Clariant</strong> (France) S.A. ++33-1-4696-9689 ☎<br />

Division CEP ++33-1-4696-9930<br />

70, Avenue du Général de Gaulle<br />

F-92058 Paris La Défense Cédex<br />

EUROPE<br />

Representative Telephone<br />

Fax<br />

www.clariant.com www.cep.clariant.com<br />

<strong>Clariant</strong> International AG, Division Celluloseether & Polimerisate, BU <strong>Emulsions</strong><br />

Rothausstrasse 61, CH-4132 Muttenz/Schweiz, Telefon ++41 61 469 62 89, Fax ++41 61 469 65 86<br />

Spain<br />

<strong>Clariant</strong> Ibérica, S.A. ++34-93-306-8111 ☎<br />

Division CEP ++34-93-306-8334<br />

Via Augusta, 252-260<br />

E-08017 Barcelona<br />

<strong>Clariant</strong> Quimicos (Portugal) Lda.<br />

E.N. Lisboa - Sintra<br />

Estrada Nacional 249, Km. 14,2 ++351-21-926-9700 ☎<br />

Apartado 191 ++351-21-926-9817<br />

P-2726-901 Mem Martins Codex<br />

Turkey<br />

<strong>Clariant</strong> Boya ve Kimyevi ++90-212-693-9420-27 ☎<br />

Maddeler San. ve Tic. A.S. ++90-212-693-9405<br />

Division CEP<br />

Basin Ekspress Yolu Ziyal Is Merkezi<br />

TÜR-34540 Günesli Istanbul/Turkiye<br />

Slovenia<br />

<strong>Clariant</strong> Polisinteza P.O. ++386-66-580-522 ☎<br />

Dekani 3 A, 66271 Dekani ++386-66-580-497<br />

Slowenija<br />

Greece<br />

<strong>Clariant</strong> Hellas S.A. ++301-2896-100 ☎<br />

2, Oulof Palme Street& ++301-2851-330<br />

39, Grigoriou Lambraki Street<br />

P.O. Box 504 02<br />

GR-141 23 Lykovrissi

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