Emulsions for Adhesives Emulsions for Adhesives - Clariant
Emulsions for Adhesives Emulsions for Adhesives - Clariant
Emulsions for Adhesives Emulsions for Adhesives - Clariant
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
Mowilith<br />
<strong>Emulsions</strong><br />
<strong>for</strong><br />
<strong>Adhesives</strong><br />
Exactly your chemistry<br />
®
2<br />
Welcome to <strong>Clariant</strong>´s<br />
world of emulsions<br />
The world of emulsions has many<br />
different facets. After all, today’s<br />
water based emulsions are<br />
essential base materials <strong>for</strong><br />
numerous applications. There<strong>for</strong>e,<br />
they are present almost<br />
everywhere in our day-to-day life.<br />
They help us solve various tasks,<br />
improve the properties of many<br />
Exactly your chemistry.<br />
products and are important<br />
components in everyday items. In<br />
addition, emulsions are water-based<br />
and almost never require solvent in<br />
the final products. For this reason<br />
they are particularly suitable <strong>for</strong> the<br />
manufacture of environmentalfriendly<br />
products.<br />
R&D Sites<br />
Production Sites
Monomer systems<br />
Vinyl acetate<br />
Vinyl acetate/ethylene<br />
Vinyl acetate/vinyl chloride/ethylene<br />
Vinyl acetate/ethylene/acrylate<br />
Vinyl acetate/VeoVa ®/ethylene<br />
Vinyl acetate/VeoVa ®<br />
Vinyl acetate/maleate<br />
Vinyl acetate/acrylate<br />
Acrylate<br />
Styrene/acrylate<br />
Your world-wide local partner<br />
One of our most important aims at<br />
<strong>Clariant</strong> is to identify and respond<br />
to your needs quickly and backed<br />
by the best technical support. Our<br />
representatives in 120 countries<br />
provide the regional <strong>for</strong>ce to<br />
achieve this. You can rely on us <strong>for</strong><br />
emulsions. Production sites in 27<br />
countries world-wide always guarantee<br />
you short supply routes and<br />
deliveries at minimum delivery<br />
times. Our local technical staff will<br />
<strong>for</strong> emulsions <strong>for</strong> adhesives<br />
be there quickly not only to help<br />
you to solve problems but also <strong>for</strong><br />
joint developments.<br />
Our Research and Development<br />
department is in close contact with<br />
the local representatives and<br />
maintains an intensive transfer of<br />
know-how. Thus you are able to<br />
benefit also from know-how and<br />
expertise acquired at the other<br />
end of the world.<br />
The range of monomer systems <strong>for</strong><br />
our emulsions, as depicted below,<br />
is extremely wide. In this way we<br />
are able to respond directly to your<br />
local production requirements as<br />
well as to different market<br />
requirements in the various regions<br />
across the world.<br />
Exactly your chemistry. 3
4<br />
Adhesive raw materials<br />
from <strong>Clariant</strong><br />
<strong>Clariant</strong> is your best partner to<br />
manufacture almost all types of<br />
waterbased adhesives. You can<br />
benefit from our large research<br />
and development capability, our<br />
global reach and our broad range<br />
of products.<br />
The Mowilith ® group of<br />
environmental-friendly, water<br />
based emulsions comprises a<br />
broad range of products.<br />
Continuous investment in the<br />
improvement of product quality<br />
Applications:<br />
Sticking and Laminating<br />
Wood<br />
Wood/film<br />
Paper/packaging<br />
Plastic/porous substrate<br />
Floor/wall/ceiling<br />
Leather/Textiles<br />
Type of adhesive<br />
Pressure-sensitive adhesives<br />
Contact adhesives<br />
Temperature-activated films<br />
Water-activated films<br />
Exactly your chemistry<br />
and per<strong>for</strong>mance exemplifies our<br />
commitment to the adhesives<br />
industry. Homopolymers and<br />
copolymers based on vinyl acetate<br />
make up the largest share. Due to<br />
their outstanding properties vinyl<br />
acetate/ethylene emulsions are<br />
able to meet even the highest<br />
demands concerning the use on<br />
fast running machines, cohesion<br />
and adhesion towards a large variety<br />
of difficult substrates.<br />
<strong>Adhesives</strong> <strong>for</strong>mulated with<br />
D ca. 50%<br />
LD 160<br />
D ca. 60%<br />
DNN ca. 60%<br />
DH 257<br />
DHS S1<br />
Mowilith ® emulsions are<br />
characterised by the following<br />
features:<br />
- Excellent adhesion to a large<br />
number of substrates<br />
- High setting speed<br />
- High final bond strength<br />
- High heat resistance and good<br />
ageing properties of the bonds<br />
- According to the needs good<br />
water resistance or re-emulsifiability<br />
of the films<br />
- Safe handling and trouble-free<br />
DC<br />
DLR<br />
DHWR<br />
LDL 2555 W<br />
LDL 2510 W<br />
D 025/1<br />
LDM 1025<br />
working<br />
- Long shelf-life<br />
The largest (in terms of volume)<br />
and most important target markets<br />
<strong>for</strong> water-based emulsion<br />
adhesives are:<br />
1.The wood and furniture industry<br />
2. The paper and packaging industry<br />
3.The construction industry –<br />
floors, walls and ceilings<br />
The overview below shows, in a<br />
summarised <strong>for</strong>m, a selection of<br />
our wide product range <strong>for</strong><br />
DM 104<br />
DM 105<br />
DM1062<br />
DM 107<br />
DM 111<br />
DM 114<br />
Main application<br />
M o w i l i t h ® M o w i l i t h ®<br />
Use dependent on substrate<br />
Use under certain conditions<br />
DM 132<br />
DM 1330<br />
DM 1340<br />
LDM 1355<br />
DM 137<br />
DS 5/1<br />
LDM 2110<br />
LDM 6636<br />
LDM 7255<br />
Exactly your chemistry 5
6<br />
Mowilith ® emulsions <strong>for</strong> technical applications<br />
<strong>Adhesives</strong> <strong>for</strong> every task<br />
Wood gluing<br />
For wood the predominant<br />
assembly method is gluing. The<br />
high demands in this application<br />
area are met perfectly by<br />
adhesives based on polyvinyl<br />
acetate emulsions such as<br />
Mowilith DHS S1 with polyvinyl<br />
alcohol as protective colloid. The<br />
most important applications <strong>for</strong><br />
these adhesives include: assembly<br />
glue, veneer and surface glues,<br />
glues <strong>for</strong> edges and laminating<br />
adhesives <strong>for</strong> laminate sheets. The<br />
final bond strength in general<br />
exceeds the material strength of all<br />
the important types of wood used.<br />
Mowilith DHS S1<br />
Mowilith LDL 2555 W<br />
Mowilith LDL 2510 W<br />
In many cases, water-based wood<br />
glues also need to <strong>for</strong>m waterresistant<br />
bonds. In this application<br />
field, <strong>Clariant</strong> products such as<br />
Mowilith DHWR, LDL 2555 W and<br />
Mowilith LDL 2510 W, used as a<br />
one-pack or a two-pack<br />
<strong>for</strong>mulation in combination with<br />
hardener, can provide the answer.<br />
With adhesives based on these<br />
emulsions it is no problem to meet<br />
the requirements of the durability<br />
classes D3 (<strong>for</strong> Mowilith DHWR<br />
and LDL 2555 W) and D4 (<strong>for</strong> 2 pack<br />
systems with Mowilith LDL 2555 W<br />
and LDL 2510 W) of the European<br />
standard DIN EN 204.<br />
Exactly your chemistry.<br />
Lamination of wood<br />
Wood adhesives in a broader<br />
sense also include adhesives used<br />
in the finishing of chipboard, when<br />
PVC or impregnated paper films<br />
are applied as decorative and<br />
protective coating.<br />
Mowilith DM 105<br />
Mowilith DM 107<br />
Mowilith DM 114<br />
Test of creep strength of furniture film<br />
adhesives, e.g. on "paper films", as a<br />
function of peeling angle, temperature<br />
and load.<br />
Floating parquet glued with a<br />
D3 emulsions
<strong>Adhesives</strong> <strong>for</strong> paper and packaging<br />
In the area of adhesives <strong>for</strong> paper<br />
and packaging, <strong>Clariant</strong>’s water<br />
based emulsions are suitable <strong>for</strong><br />
an extremely wide range of applications.<br />
Apart from the manufacture<br />
and closing of packaging<br />
materials, they are used in adhesives<br />
<strong>for</strong> book binding, <strong>for</strong> lamination<br />
of paper to cardboard, <strong>for</strong> the<br />
manufacture of cardboard boxes<br />
and paper bags as well as <strong>for</strong> the<br />
preparation of spiral paper tubes.<br />
Most of the applications in the<br />
graphics industry are covered<br />
including high gloss film print<br />
lamination. <strong>Emulsions</strong> are also<br />
essential to <strong>for</strong>mulate adhesives <strong>for</strong><br />
cigarette manufacture and packaging.<br />
Mowilith D approx. 50%<br />
Mowilith DH 257<br />
Mowilith DS 5/1<br />
Mowilith DM 111<br />
Mowilith DM 105<br />
Mowilith DM 1062<br />
Mowilith DM 132<br />
Mowilith DM 137<br />
Mowilith LDM 7255<br />
Setting time (s)<br />
12<br />
10<br />
8<br />
6<br />
4<br />
2<br />
0<br />
Mowilith ® D ca. 50%<br />
Polyvinyl alcohol (PVAL)<br />
Dibutyl Phthalate (DBP)<br />
5 10 15 20<br />
Added Quantity of PVAL/DBP (%)<br />
Effect of modification with PVAL and<br />
DBP on the setting time, measured in<br />
the peel test with the Werle Tack<br />
Tester (paper/paper)<br />
The Finat loop test, test method nº 9,<br />
confirms the good surface tack of a film<br />
The Finat loop test, test method nº 9,<br />
based on Mowilith DM 137<br />
confirms the good surface tack of a film<br />
based on Mowilith DM 137<br />
Floor – wall – ceiling<br />
Because of the great variety of<br />
floor and wall coverings, different<br />
substrates and special<br />
per<strong>for</strong>mance requirements, the<br />
<strong>for</strong>mulation of suitable floor and<br />
wall adhesives is often fraught<br />
with complex problems.<br />
The trend clearly goes towards the<br />
solvent-free, water based adhesive<br />
systems, because aqueous<br />
adhesives provide the best solution<br />
to overcome environmental and<br />
odour problems.<br />
<strong>Clariant</strong>’s developments of<br />
emulsions <strong>for</strong> flooring adhesives<br />
<strong>for</strong> various floor coverings, e.g.<br />
carpet, PVC, linoleum, polyolefine<br />
layers as well as <strong>for</strong> parquet<br />
floorings, and others, enable our<br />
customers to <strong>for</strong>mulate adhesives<br />
with very low emission. Consumers<br />
require adhesive systems with<br />
environment protection, e.g. indicated<br />
by the EC 1 label of GEV<br />
which can be fulfilled in <strong>Clariant</strong>’s<br />
innovative emulsions.<br />
Mowilith DM 1340<br />
Mowilith LDM 1355<br />
Mowilith LDM 1025<br />
Testing of the setting-time of a PVC<br />
one-side floor adhesive based on<br />
Mowilith DM 1340.<br />
The weting of surfaces and wet<br />
adhesives strength are measured with<br />
the spring balance <strong>for</strong> predetermined<br />
periods.<br />
Testing of legging property<br />
Exactly your chemistry. 7
Representative Telephone<br />
Fax<br />
Germany<br />
<strong>Clariant</strong> GmbH ++49(0)69-305-2876 ☎<br />
Industriepark Höchst ++49(0)69-305-4748 ☎<br />
Division CEP/BU Dispersionen ++49(0)69-317140<br />
D- 65926 Frankfurt / Main<br />
Benelux<br />
<strong>Clariant</strong> Benelux N.V. ++31-203-989-960 ☎<br />
Division CEP ++31-203-989-963<br />
Diemerhof 36<br />
NL-1112 Diemen<br />
Italy<br />
<strong>Clariant</strong> (Italia) S.p.A. ++39-02-3263-1 ☎<br />
Division CEP ++39-02-3263-2262<br />
Via Traiano 18<br />
20149 Milano<br />
Austria<br />
<strong>Clariant</strong> (Österreich) GmbH ++43-1-801-22422 ☎<br />
Division CEP ++43-1-801-22942<br />
Breitenfurter Str. 239<br />
A-1131 Wien<br />
France<br />
<strong>Clariant</strong> (France) S.A. ++33-1-4696-9689 ☎<br />
Division CEP ++33-1-4696-9930<br />
70, Avenue du Général de Gaulle<br />
F-92058 Paris La Défense Cédex<br />
EUROPE<br />
Representative Telephone<br />
Fax<br />
www.clariant.com www.cep.clariant.com<br />
<strong>Clariant</strong> International AG, Division Celluloseether & Polimerisate, BU <strong>Emulsions</strong><br />
Rothausstrasse 61, CH-4132 Muttenz/Schweiz, Telefon ++41 61 469 62 89, Fax ++41 61 469 65 86<br />
Spain<br />
<strong>Clariant</strong> Ibérica, S.A. ++34-93-306-8111 ☎<br />
Division CEP ++34-93-306-8334<br />
Via Augusta, 252-260<br />
E-08017 Barcelona<br />
<strong>Clariant</strong> Quimicos (Portugal) Lda.<br />
E.N. Lisboa - Sintra<br />
Estrada Nacional 249, Km. 14,2 ++351-21-926-9700 ☎<br />
Apartado 191 ++351-21-926-9817<br />
P-2726-901 Mem Martins Codex<br />
Turkey<br />
<strong>Clariant</strong> Boya ve Kimyevi ++90-212-693-9420-27 ☎<br />
Maddeler San. ve Tic. A.S. ++90-212-693-9405<br />
Division CEP<br />
Basin Ekspress Yolu Ziyal Is Merkezi<br />
TÜR-34540 Günesli Istanbul/Turkiye<br />
Slovenia<br />
<strong>Clariant</strong> Polisinteza P.O. ++386-66-580-522 ☎<br />
Dekani 3 A, 66271 Dekani ++386-66-580-497<br />
Slowenija<br />
Greece<br />
<strong>Clariant</strong> Hellas S.A. ++301-2896-100 ☎<br />
2, Oulof Palme Street& ++301-2851-330<br />
39, Grigoriou Lambraki Street<br />
P.O. Box 504 02<br />
GR-141 23 Lykovrissi