ORGANOMETALLICS

ORGANOMETALLICS 

2001

JUN 25 2001, volume 20, issue 13 

1. [1,3]-Metal Shifts in Rhenium Alkynyl Carbene Complexes 

Casey, C. P.; Kraft, S.; Powell, D. R. 

Organometallics, 2001, vol. 20, no. 13, pp. 2651-2653 

2. 5-C5Me5)Fe}2(mu-H)2(mu-eta2:eta2-H2Si-tBu2), a Versatile 

Precursor for Bimetallic Active Species 

Ohki, Y.; Kojima, T.; Oshima, M.; Suzuki, H. 


3. Electrophilic "Fischer Type" Phosphinidene Complexes of 

Molybdenum, Tungsten, and Ruthenium 

Sterenberg, B. T.; Udachin, K. A.; Carty, A. J. 


4. Synthesis of Polymer-Supported Rhodium(I)-1,3- 

Bis(diphenylphosphino)propane Moieties and Their Use in the 

Heterogeneous Hydrogenation of Quinoline and Benzylideneacetone 

Bianchini, C.; Frediani, M.; Mantovani, G.; Vizza, F. 


5. Heteroatom-Substituted Constrained-Geometry Complexes. 

Dramatic Substituent Effect on Catalyst Efficiency and Polymer 

Molecular Weight 

Klosin, J.; Kruper, W. J.; Nickias, P. N.; Roof, G. R.; De Waele, P.; 

Abboud, K. A. 


6. Two Stable Hydrides of Antimony: RSbH2 and R(H)Sb-Sb(H)R (R 

= (Me3Si)2CH) 

Balazs, G.; Breunig, H. J.; Lork, E.; Offermann, W. 


7. Computational Study of Reductive Elimination Reactions to Form 

C-H Bonds from Platinum(II) and Platinum(IV) Centers with Strongly 

Coordinating Trimethylphosphine Ligands 

Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. 


8. Rhodium Complexes of a Chelating 

Bisphosphoniobenzophospholide Cation 

Hap, S.; Nieger, M.; Gudat, D.; Betke-Hornfeck, M.; Schramm, D.


9. Formation of an Unsymmetrical Pt-Ir Tetraalkynyl Complex and 

Investigation into Subsequent Construction of Multimetallic Systems 

Ara, I.; Berenguer, J. R.; Eguizabal, E.; Fornies, J.; Lalinde, E. 


10. Enantioselective Alternating Copolymerization of alpha-Olefins 

with Carbon Monoxide Using a Cationic Palladim-Chiral Diphosphine 

Complex 

Yuan, J.-C.; Lu, S.-J. 


11. Synthesis of Ortho-Palladated Phenol Derivatives. Study of Their 

Reactivity with Carbon Monoxide and Isonitriles 

Vicente, J.; Abad, J.-A.; Fortsch, W.; Jones, P. G.; Fischer, A. K. 


12. New Dihydride- and Alkene-eta6-Arene Complexes of Iridium 

Torres, F.; Sola, E.; Martin, M.; Ochs, C.; Picazo, G.; Lopez, J. A.; Lahoz, 

F. J.; Oro, L. A. 


13. A Catalytic Route to Grafted Silicones 

Chauhan, B. P. S.; Ready, T. E.; Al-Badri, Z.; Boudjouk, P. 


14. The Iminophosphorane Ph3P=NSiMe3 as a Synthon for M-Caryl 

sigma Bonds (M = In, Fe, Ge) Implementing Imino Sidearm Donation 

Wingerter, S.; Pfeiffer, M.; Stey, T.; Bolboaca, M.; Kiefer, W.; 

Chandrasekhar, V.; Stalke, D. 


15. Nucleophilic Addition to the eta2-Alkyne Ligand in 

[CpFe(CO)2(eta2-R-CC -R)]+. Dependence of the Alkenyl Product 

Stereochemistry on the Basicity of the Nucleophile 

Akita, M.; Kakuta, S.; Sugimoto, S.; Terada, M.; Tanaka, M.; Moro-oka, Y. 


16. DFT Study of the Palladium-Catalyzed Cyclopropanation 

Reaction 

Bernardi, F.; Bottoni, A.; Miscione, G. P. 

Organometallics, 2001, vol. 20, no. 13, pp. 2751-2758

17. Formation of Phenylene Oligomers Using Platinum-Phosphine 

Complexes 

Simhai, N.; Iverson, C. N.; Edelbach, B. L.; Jones, W. D. 


18. [Pd2C(O)Me}Cl]n, a Key Product for the Synthesis of 

Acetonylpalladium(II) Complexes 

Vicente, J.; Arcas, A.; Fernandez-Hernandez, J. M.; Bautista, D. 


19. New Types of (Arene)ruthenium Alkynyl Complexes 

Menendez, C.; Morales, D.; Perez, J.; Riera, V.; Miguel, D. 


20. Synthesis and Electrochemical and Theoretical Studies of Fischer- 

Type Alkenyl-Carbyne Tungsten Complexes 

[(dppe)(CO)2(RNC)W2CH2(CH2)nCH2}][BF4] (R = Alkyl, Aryl) 

Zhang, L.; da Silva, M. F. C. G.; Kuznetsov, M. L.; Gamasa, M. P.; 

Gimeno, J.; da Silva, J. J. R. F.; Pombeiro, A. J. L. 


21. 1-Octene Hydrosilylation Catalyzed by Lanthanide and Yttrium 

Hydrides and Hydrocarbyls: A Mechanistic Study and the Role of 

Catalyst Association 

Voskoboynikov, A. Z.; Shestakova, A. K.; Beletskaya, I. P. 


22. Novel, Efficient, Palladium-Based System for the Polymerization 

of Norbornene Derivatives: Scope and Mechanism 

Hennis, A. D.; Polley, J. D.; Long, G. S.; Sen, A.; Yandulov, D.; Lipian, J.; 

Benedikt, G. M.; Rhodes, L. F.; Huffman, J. 


23. Insertion Aptitudes and Insertion Regiochemistry of Various 

Alkenes Coordinated to Cationic (sigma-R)(diimine)palladium(II)(R=- 

CH3, -C6H5). A Theoretical Study 

von Schenck, H.; Stromberg, S.; Zetterberg, K.; Ludwig, M.; Akermark, 

B.; Svensson, M. 


24. alpha,omega-Bis(trichlorostannyl)alkanes: Unravelling the 

Hydrolysis Pathway to Organotin-oxo Oligomers

Zobel, B.; Duthie, A.; Dakternieks, D.; Tiekink, E. R. T. 


25. DFT Study of the Ethylene Hydroformylation Catalytic Cycle 

Employing a HRh-(PH3)2(CO) Model Catalyst 

Decker, S. A.; Cundari, T. R. 


26. Photochemical and Photophysical Reactions of fac-Rhenium(I) 

Tricarbonyl Complexes. Effects from Binucleating Spectator Ligands 

on Excited and Ground State Processes 

Guerrero, J.; Piro, O. E.; Wolcan, E.; Feliz, M. R.; Ferraudi, G.; Moya, S. 

A. 


27. Lewis Acid-Base Adducts of Pentamethylcyclopentadienylgallium 

with Trivalent Group 13-Element Compounds 

Jutzi, P.; Neumann, B.; Reumann, G.; Schebaum, L. O.; Stammler, H.-G. 


28. Generation of Copper(I) Complexes with a Tethered Olefin- 

Phosphine Ligand from CuCl-Mediated Reaction of 

Alkenylzirconocene with R2PCl 

Miyaji, T.; Xi, Z.; Nakajima, K.; Takahashi, T. 


29. Regioselectivities of the Insertion Reactions of Unsymmetrical 

Alkynes with the Nickelacycles 

[&unknown;NiBr(C6H4CH2PPh22)(L)] (L = Tertiary Phosphine) 

Edwards, A. J.; Macgregor, S. A.; Rae, A. D.; Wenger, E.; Willis, A. C. 


30. Structural and Thermochemical Studies of Chiral Nucleophilic 

Carbenes in the Cp*RuCl(L*) (Cp* = eta5-C5Me5; L* = Chiral 

Nucleophilic Carbene) System 

Huang, J.; Jafarpour, L.; Hillier, A. C.; Stevens, E. D.; Nolan, S. P. 


31. Calcium-Mediated Fulvene Couplings. 1. A Survey of 6,6- 

Dialkylfulvenes for the Formation of Bridged and Unbridged 

Calcocenes 

Sinnema, P.-J.; Shapiro, P. J.; Hohn, B.; Bitterwolf, T. E.; Twamley, B. 


32. Spiro-Fused Cyclopentadienes and Novel Pyridinium 

Carbonyltungstates from (1-Alkynyl)carbene Tungsten Complexes and 

exo-Methylene N-Heterocycles. Competition between 1,4-Addition, 1,2- 

Addition, and Metathesis 

Gottker-Schnetmann, I.; Aumann, R.; Kataeva, O.; Holst, C.; Frohlich, R. 


33. Ligand Exchange Reactions of Triphospholyl Metal Carbonyl 

Complexes 

Heinemann, F. W.; Pritzkow, H.; Zeller, M.; Zenneck, U. 


34. Palladium-Catalyzed Coupling Reactions of Biphenylene with 

Olefins, Arylboronic Acids, and Ketones Involving C-C Bond Cleavage 

Satoh, T.; Jones, W. D. 


35. Glass-Catalyzed Conversion of Boronic Esters of Asymmetric 

Diols to Diol Sulfites and Amine Complexes of Boron Halides 

Matteson, D. S.; Hiscox, W. C.; Fabry-Asztalos, L.; Kim, G.-Y.; Siems, W. 

F. 


36. Investigating Pathways of Molecular H2 Exchange in (mu- 

H)2Os3(CO)10 

Aime, S.; Dastru, W.; Gobetto, R.; Reineri, F.; Russo, A.; Viale, A. 


37. Catalytic Carbon-Carbon Bond Activation of sec-Alcohols by a 

Rhodium(I) Complex 

Jun, C.-H.; Lee, D.-Y.; Kim, Y.-H.; Lee, H. 


38. [Cp2(OC)4Mo2(mu-PH2)(mu-H)] as a Useful Building Block 

toward Heterometallic Clusters Containing a Naked Phosphorus Atom 

Bridgeman, A. J.; Mays, M. J.; Woods, A. D. 


39. Hydrolytic Reactivity of a Samarium(II) Organometallic 

Complex: Synthesis and Structure of a Hexametallic Organosamarium 

Oxide Hydroxide, [(C5Me5)Sm]6O9H6 

Evans, W. J.; Allen, N. T.; Greci, M. A.; Ziller, J. W. pp. 3936-3937

2001, volume 20, issue 14 

1. Synthesis of a Dinuclear Complex with a Zr2(mu-NH)2 Core in a 

Two-Phase System 

Bai, G.; Roesky, H. W.; Schmidt, H.-G.; Noltemeyer, M. 


2. Palladium Complexes with a New Hemilabile 

Bis(oxazoline)phenylphosphonite Ligand. Characterization of an 

Unprecedented Chloro Palladium(II)-(eta1-Allyl) Complex 

Braunstein, P.; Naud, F.; Dedieu, A.; Rohmer, M.-M.; DeCian, A.; Rettig, 

S. J. 


3. Ruthenium(II)-MeO-Biphep-Arene Dications: Acetylene Reactions 

and Unexpected Cyclometalation 

Reijer, C. J. d.; Drago, D.; Pregosin, P. S. 


4. Synthesis, Kinetics, and Stereochemistry of P-C Bond Breaking 

and P-C Bond Making Reactions: Ruthenium-Arene Binap Chemistry 

Geldbach, T. J.; Pregosin, P. S.; Bassetti, M. 


5. Synthesis and Structure of New Oxapalladacycles with a Pd-O 

Bond 

Fernandez-Rivas, C.; Cardenas, D. J.; Martin-Matute, B.; Monge, A.; 

Gutierrez-Puebla, E.; Echavarren, A. M. 


6. Synthesis and Oxidation Reactions of the Unsaturated Anion 

[Mn2(CO)6(mu-Ph2PCH2PPh2)]2- 

Liu, X.-Y.; Riera, V.; Ruiz, M. A.; Bois, C. 


7. Zirconium Complexes of Amine-Bis(phenolate) Ligands as 

Catalysts for 1-Hexene Polymerization: Peripheral Structural 

Parameters Strongly Affect Reactivity 

Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. 


8. (Arene)ruthenium Complexes with Bis-(oxazolines): Synthesis and 

Applications as Asymmetric Catalysts for Diels-Alder Reactions

Davies, D. L.; Fawcett, J.; Garratt, S. A.; Russell, D. R. 


9. Ring-Opening Polymerization Behavior of ansa- and Spirocyclic 

ansa-Zirconocene Complexes 

Peckham, T. J.; Nguyen, P.; Bourke, S. C.; Wang, Q.; Harrison, D. G.; 

Zoricak, P.; Russell, C.; Liable-Sands, L. M.; Rheingold, A. L.; Lough, A. 

J. 


10. Synthesis, Characterization, and Catalytic Activities for the 

Polymerization of Olefins Promoted by Zirconium(III) and 

Titanium(III) Allyl Complexes 

Ray, B.; Neyroud, T. G.; Kapon, M.; Eichen, Y.; Eisen, M. S. 


11. Trends in the Structures and Energetics of the Group 14 

Metallocenes (C5H5)2M (M = Si-Pb): A Density Functional Theory 

Study 

Smith, J. D.; Hanusa, T. P. 


12. Migrations of the Carbon Atom of the SC(H)PR3 Ligand in the 

Reduction/Protonation Processes of Heterodinuclear Mn-Re 

Complexes 

Miguel, D.; Li, J.; Morales, D.; Riera, V.; Garcia-Granda, S. 


13. Insertion Reactions of Phenyl Isocyanate and Phenyl 

Isothiocyanate into the Nd-S Bond of [(CH3C5H4)2Nd(mu- 

SPh)(THF)]2: Synthesis and Crystal Structures 

Shen, Q.; Li, H.; Yao, C.; Yao, Y.; Zhang, L.; Yu, K. 


14. Cobaltporphycenes as Catalysts. The Oxidation of Vinyl Ethers 

via the Formation and Dissociation of Cobalt-Carbon Bonds 

Hayashi, T.; Okazaki, K.; Urakawa, N.; Shimakoshi, H.; Sessler, J. L.; 

Vogel, E.; Hisaeda, Y. 


15. Synthesis, Reactivity, and Metal Complexes of Fluorous 

Triarylphosphines of the Formula P(p-C6H4(CH2)3(CF2)n-1CF3)3 (n 

= 6, 8, 10)

Soos, T.; Bennett, B. L.; Rutherford, D.; Barthel-Rosa, L. P.; Gladysz, J. A. 


16. A New Family of Chiral Chelating Diamines with Transition- 

Metal Stereocenters: Synthesis, Structure, and Reactivity of the 

Enantiomerically Pure Dirhenium-Substituted 1,2-Diamine(eta5- 

C5H5)Re(NO)-(PPh3)(CH2N(CH3)CH2CH2- 

(H3C)NCH2)(Ph3P)(ON)Re(eta5-C5H5) 

Alvey, L. J.; Delacroix, O.; Wallner, C.; Meyer, O.; Hampel, F.; Szafert, S.; 

Lis, T.; Gladysz, J. A. 


17. Lithium (S)-1-[2'-(Methoxymethyl)pyrrolidin-1'-yl]-3,5dimethylboratabenzene. 

An Enantiopure Lithium Salt Possessing a 

Novel Polymeric Structure 

Zheng, X.; Herberich, G. E. 


18. Complexation Stabilized Conformational Regulation of Ferrocene 

Bearing Podand Dipeptide Chains (-L-Ala-L-Pro-NHPy) 

Moriuchi, T.; Yoshida, K.; Hirao, T. 


19. Synthesis, Structure, and Catalytic Behavior of rac-1,1'-(3- 

Oxapentamethylene)-Bridged Bis(indenyl) ansa-Lanthanidocenes 

Qian, C.; Zou, G.; Chen, Y.; Sun, J. 


20. Role of Hexacoordinated Silicon Intermediates in the Hydrolysis 

and Racemization Reactions of Silyl Halides 

Ignatyev, I. S.; Schaefer, H. F. 


21. Utilization of Redox and Acid/Base Chemistry for the 

Deprotection of a Mn(dmpe)2-(CCSiMe3)2 Complex 

Fernandez, F. J.; Alfonso, M.; Schmalle, H. W.; Berke, H. 


22. Synthesis, Structure, and Reactivity of Niobocene Imido 

Complexes Containing Alkynyl Ligands. X-ray Crystal Structure of 

[Nb(=NPh)(eta5-C5H4SiMe3)2-(CCPh)]

Antinolo, A.; Fajardo, M.; Lopez-Mardomingo, C.; Lopez-Solera, I.; Otero, 

A.; Perez, Y.; Prashar, S. 


23. Synthesis and Characterization of mu3-eta2,eta2,eta2-C60 

Trirhenium Hydrido Cluster Complexes 

Song, H.; Lee, Y.; Choi, Z.-H.; Lee, K.; Park, J. T.; Kwak, J.; Choi, M.-G. 


24. Participation of (eta3-Allyl)ruthenium(II) Complexes in C-C Bond 

Formation and C-C Bond Cleavage. A Theoretical Study 

Sakaki, S.; Ohki, T.; Takayama, T.; Sugimoto, M.; Kondo, T.; Mitsudo, T.a. 


25. Design and Performance of Rigid Nanosize Multimetallic 

Cartwheel Pincer Compounds as Lewis-Acid Catalysts 

Dijkstra, H. P.; Meijer, M. D.; Patel, J.; Kreiter, R.; van Klink, G. P. M.; 

Lutz, M.; Spek, A. L.; Canty, A. J.; van Koten, G. 


26. Interaction of the Bifunctional Lewis Acid 1,2- 

Bis(chloromercurio)tetrafluorobenzene with Aldehydes, Nitriles, and 

Epoxides 

Beckwith, J. D.; Tschinkl, M.; Picot, A.; Tsunoda, M.; Bachman, R.; 

Gabbai, F. P. 


27. Efficient Synthetic Routes to Terminal gamma-Keto-Alkynes and 

Unsaturated Cyclic Carbene Complexes Based on Regio- and 

Diastereoselective Nucleophilic Additions of Enolates on 

Ruthenium(II) Indenyl Allenylidenes 

Cadierno, V.; Conejero, S.; Gamasa, M. P.; Gimeno, J.; Perez-Carreno, E.; 

Garcia-Granda, S. 


28. Unusual Reactivity of "Proton Sponge" as a Hydride Donor to 

Transition Metals: Synthesis and Structural Characterization of 

Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III) 

Hughes, R. P.; Kovacik, I.; Lindner, D. C.; Smith, J. M.; Willemsen, S.; 

Zhang, D.; Guzei, I. A.; Rheingold, A. L. 


29. Geometric Features and Electronic Structures of Six-Coordinated 

Dialkyl and Dithiolate Complexes of Osmium(IV) Porphyrins 

Yang, S.-Y.; Leung, W.-H.; Lin, Z. 


30. Alkyne-Coupling Reactions Catalyzed by OsHCl(CO)(PiPr3)2 in 

the Presence of Diethylamine 

Esteruelas, M. A.; Herrero, J.; Lopez, A. M.; Olivan, M. 


31. Carbonylated Phosphines as Ligands for Catalysis in Supercritical 

CO2 

Hu, Y.; Chen, W.; Xu, L.; Xiao, J. 


JUL 23 2001, volume 20, issue 15 

1. Syntheses and Structures of Manganese Complexes of Borane- 

Lewis Base Adducts, [CpMn(CO)2(eta1-BH3L)] (L=NMe3, PMe3) 

Kakizawa, T.; Kawano, Y.; Shimoi, M. 


2. First Synthesis of Cationic [(eta6-arene)Mn(CO)3] Complexes 

Substituted by Resonance Electron Withdrawing Groups 

Auffrant, A.; Prim, D.; Rose-Munch, F.; Rose, E.; Vaissermann, J. 


3. A Highly Active Anilinotropone-Based Neutral Nickel(II) Catalyst 

for Ethylene Polymerization 

Hicks, F. A.; Brookhart, M. 


4. One-Pot Synthesis for Osmium(II) Azavinylidene-Carbyne and 

Azavinylidene-Alkenylcarbyne Complexes Starting from an 

Osmium(II) Hydride-Azavinylidene Compound 

Castarlenas, R.; Esteruelas, M. A.; Onate, E. 


5. Synthesis of Double and Quadruple Butterfly Fe/E Cluster 

Complexes via a New Type of Selenium-Centered Anions (mu- 

RE)(mu-Se-)[Fe2(CO)6]2(mu4-Se) (E = S, Se, Te) Derived from Novel 

Reaction of [(mu-RE)(mu-CO)[Fe2(CO)6]- with (mu-Se2)Fe2-(CO)6. 

Crystal Structures of mu4-Se-Containing Double Clusters (mu- 

EtS)(mu-PhCH2-Se)[Fe2(CO)6]2(mu4-Se), (mu-p-MeC6H4Se)(mu- 

MeSe)[Fe2(CO)6]2(mu4-Se), and (mu-p-MeC6-H4Te)(mu- 

MeSe)[Fe2(CO)6]2 (mu4-Se) 

Song, L.-C.; Yang, J.; Hu, Q.-M.; Wu, Q.-J. 


6. An Unusual Monomeric Alkenyl-Substituted Pyrazolato Aluminum 

Dichloride and Its Derivatives with Both Terminal and eta2-Pyrazolato 

Ligands 

Zheng, W.; Mosch-Zanetti, N. C.; Blunck, T.; Roesky, H. W.; Noltemeyer, 

M.; Schmidt, H.-G. 


7. (eta5-Pentamethylcyclopentadienyl)phosphinine Ruthenium(II) 

Complexes: eta1- vs eta6-Coordination 

Mezailles, N.; Ricard, L.; Mathey, F.; Le Floch, P. 


8. C-N Coupling Reactions of Allenes and Methylacetylenes with an 

Imidotitanium Complex 

Trosch, D. J. M.; Collier, P. E.; Bashall, A.; Gade, L. H.; McPartlin, M.; 

Mountford, P.; Radojevic, S. 


9. Electronic and Steric Effects in Ligand Substitution at a Transient 

Organometallic Species: The Reaction of W(CO)5-(Cyclohexane)with 

(CH3)nTHF and (CH3)n-Furan (n = 1, 2) 

Krishnan, R.; Schultz, R. H. 


10. Lanthanide(II) Complexes Bearing Linked Cyclopentadienyl- 

Anilido Ligands: Synthesis, Structures, and One-Electron-Transfer 

and Ethylene Polymerization Reactions 

Hou, Z.; Koizumi, T.-a.; Nishiura, M.; Wakatsuki, Y. 


11. Kinetic Investigations on the Redox Reactions of Platinum 

Carbonyl Clusters with Dihydrogen and Acid 

Bhaduri, S.; Lahiri, G. K.; Mukesh, D.; Paul, H.; Sarma, K. 


12. Alcohol Complexes of Tungsten Prepared by Ionic 

Hydrogenations of Ketones 

Song, J.-S.; Szalda, D. J.; Bullock, R. M. 


13. alpha,omega-Bis(trichlorostannyl)alkanes as Bis-(monodentate) 

Lewis Acids toward Halide Ions 

Zobel, B.; Duthie, A.; Dakternieks, D.; Tiekink, E. R. T. 


14. Electrophilic Cationic Palladium(II) Complexes Containing a 

Diimine Ligand with Pendant Thienyl Groups. X-ray Structure of 

IIMe[1,4-bis(2'-(2-thienyl)ethyl)2,3-dimethyl-1,4-diazabutadien e]}+ 

Fang, X.; Watkin, J. G.; Scott, B. L.; Kubas, G. J. 


15. In3I2[C(SiMe3)3]3: Synthesis of a Diiodotrialkyltriindane(5) 

Containing Two In-In Single Bonds 

Uhl, W.; Melle, S.; Geiseler, G.; Harms, K. 


16. Synthesis of Arylstannanes from Arylamines 

Chopa, A. B.; Lockhart, M. T.; Silbestri, G. 


AUG 06 2001, volume 20, issue 16 

1. Formation of Novel 1:1 Adducts Accompanied by Regioselective 

Hydride Transfer from Transition-Metal Hydrido Complexes to 

NAD(P) Models 

Kobayashi, A.; Takatori, R.; Kikuchi, I.; Konno, H.; Sakamoto, K.; 

Ishitani, O. 


2. Ring Contraction of 1,2-Digermacyclohexa-1,4-diene to 

(Germacyclopent-3-enyl)germylene 

Fukaya, N.; Ichinohe, M.; Kabe, Y.; Sekiguchi, A. 


3. Main-Group-Metal Chlorobenzene Complexes 

Korolev, A. V.; Delpech, F.; Dagorne, S.; Guzei, I. A.; Jordan, R. F. 


4. X-ray Structure and Reactivity of (eta4tetraphenylcyclopentadienone)(CO)2-Ru(HOCHMe2): 

Unexpected 

Stability of the Neutral 2-Propanol-Ruthenium(0) Complex with 

Respect to beta-Hydride Elimination 

Jung, H. M.; Shin, S. T.; Kim, Y. H.; Kim, M.-J.; Park, J. 


5. A New Methodology for the Preparation of Cationic 

Organoplatinum(II) Complexes with Hydrogen-Bonding Functionality 

Gallasch, D. P.; Tiekink, E. R. T.; Rendina, L. M. 


6. Physical Organic Chemistry of Transition Metal Carbene 

Complexes. 22. Substituent Effects on the Reversible Cyclization of 

Fischer Carbene Complexes (CO)5W=C(SCH2CH2OH)C6H4Z in 

Aqueous Acetonitrile 

Bernasconi, C. F.; Ali, M. 


7. Synthesis of N-Arylpyrroles, Hetero-Diels-Alder Adducts, and 

Allylic Amines by Reaction of Unfunctionalized Dienes with 

Nitroarenes and Carbon Monoxide, Catalyzed by Ru(CO)3(Ar-BIAN) 

Ragaini, F.; Cenini, S.; Borsani, E.; Dompe, M.; Gallo, E.; Moret, M. 


8. Chelating Diamide Group IV Metal Olefin Polymerization 

Catalysts 

Patton, J. T.; Feng, S. G.; Abboud, K. A. 


9. Reactions of Diruthenium Tetrahydride Complex (eta5- 

C5Me5)Ru(mu-H)4Ru(eta5-C5 Me5) with Vinylsilanes: Formation of a 

mu-Silylene Complex via Successive Si-H and Si-C Bond Cleavage of 

Dimethylvinylsilane 

Takao, T.; Amako, M.-a.; Suzuki, H. 


10. Activation of the Vinylic =C-H Bond of Styrene by a Rhodium- 

Siloxide Complex: The Key Step in the Silylative Coupling of Styrene 

with Vinylsilanes 

Marciniec, B.; Walczuk-Gusciora, E.; Pietraszuk, C. 


11. Evaluation of the Stereoelectronic Parameters of Fluorinated 

Phosphorus(III) Ligands. The Quantitative Analysis of Ligand Effects 

(QALE) 

Fernandez, A. L.; Wilson, M. R.; Prock, A.; Giering, W. P. 


12. Ethylene Bis(2-indenyl) Zirconocenes: A New Class of 

Diastereomeric Metallocenes for the (Co)Polymerization of alpha- 

Olefins 

Schaverien, C. J.; Ernst, R.; Schut, P.; Dall Occo, T. 


13. Synthesis, Structure, and Reactivity of C2-Symmetric 

Bis(phospholyl)zirconium and Bis(phospholyl)hafnium Complexes 

Bellemin-Laponnaz, S.; Lo, M. M.-C.; Peterson, T. H.; Allen, J. M.; Fu, G. 

C. 


14. Electrophilic Binuclear Methylpalladium(II) Complexes: 

Copolymerization of Alkenes and Carbon Monoxide 

Baar, C. R.; Jennings, M. C.; Puddephatt, R. J. 


15. eta1- and eta5-Indenyl and Cyclopentadienyl Tri-tert- 

Butylphosphoraneiminatotitanium Complexes

Guerin, F.; Beddie, C. L.; Stephan, D. W.; Spence, R. E. v. H.; Wurz, R. 


16. Catalytic Fluorination by Halide Exchange with 16-Electron 

Ruthenium(II) Complexes. X-ray Structure of [Tl(mu- 

F)2Ru(dppe)2]PF6 

Barthazy, P.; Togni, A.; Mezzetti, A. 


17. Electronic Communication in Homobimetallic Anthracene- 

Bridged eta5-Cyclopentadienyl Derivatives of Rhodium(I): Generation 

and Characterization of the Average-Valence Species [L2Rh5H4CH2- 

(9,10-anthrylene)CH2C5H4}RhL2]+ 

Carano, M.; Careri, M.; Cicogna, F.; D Ambra, I.; Houben, J. L.; Ingrosso, 

G.; Marcaccio, M.; Paolucci, F.; Pinzino, C.; Roffia, S. 


18. Addition of Nitrogen-Containing Heteroallenes to Iron(II)- 

Hydrides 

Field, L. D.; Shaw, W. J.; Turner, P. 


19. Synthesis and Reactivity of a Diruthenium Diazoalkane Complex 

Gao, Y.; Jennings, M. C.; Puddephatt, R. J.; Jenkins, H. A. 


20. Selective Formation of Homoleptic and Heteroleptic 2,5-Bis(Naryliminomethyl)pyrrolyl 

Yttrium Complexes and Their Performance 

as Initiators of epsilon-Caprolactone Polymerization 

Matsuo, Y.; Mashima, K.; Tani, K. 


21. Methyl Aluminosilsesquioxanes, Models for Lewis Acidic Silica- 

Grafted Methyl Aluminum Species 

Skowronska-Ptasinska, M. D.; Duchateau, R.; van Santen, R. A.; Yap, G. 

P. A. 


22. Group 5 Imido Complexes Supported by Diamido-pyridine 

Ligands: Aryloxide, Amide, Benzamidinate, Alkyl, and 

Cyclopentadienyl Derivatives 

Pugh, S. M.; Trosch, D. J. M.; Skinner, M. E. G.; Gade, L. H.; Mountford, 

P.


23. Redox Potential Selection in a New Class of Dendrimers 

Containing Multiple Ferrocene Centers 

Alvarez, J.; Ren, T.; Kaifer, A. E. 


24. Models for Deep Hydrodesulfurization (HDS). Remote Activation 

of C-S Bonds in Alkylated Benzothiophenes and Dibenzothiophenes by 

Metal Coordination to a Carbocyclic Ring 

Yu, K.; Li, H.; Watson, E. J.; Virkaitis, K. L.; Carpenter, G. B.; Sweigart, 

D. A. 


25. Cationic Zirconium Complexes that Contain Mesityl-Substituted 

Diamido/Donor Ligands. Decomposition via CH Activation and Its 

Influence on 1-Hexene Polymerization 

Schrodi, Y.; Schrock, R. R.; Bonitatebus, P. J. 


26. Organic Synthesis via Transition Metal Complexes, 112. 

Reactivity Enhancement of Group VI Fischer Carbene Complexes by 

Copper and Rhodium Catalysts: Experimental Proof of a Carbene 

Rhodium Complex as an Intermediate 

Gottker-Schnetmann, I.; Aumann, R.; Bergander, K. 


27. Tetrahedral, Highly Coordinatively Unsaturated 14e (Fe) and 15e 

(Co) Hydrocarbyl Complexes Bearing Hydrotris(pyrazolyl)borato 

Ligands (TpR'), TpR'M-R (M = Fe, Co, Ni) 

Shirasawa, N.; Nguyet, T. T.; Hikichi, S.; Moro-oka, Y.; Akita, M. 


28. Hydride Ion Abstraction from Titanocene Cyclic 

Organohydroborates, Cp2Ti2BR2} (R2 = C4H8, C5H10, C8H14), as a 

Function of Solvent 

Plecnik, C. E.; Liu, F.-C.; Liu, S.; Liu, J.; Meyers, E. A.; Shore, S. G. 


29. Catalytic Dehalogenation of Aryl Halides Mediated by a 

Palladium/Imidazolium Salt System 

Viciu, M. S.; Grasa, G. A.; Nolan, S. P. 


30. Crystal Structure of [PPN+][Cr(CO)4NO-]: Calculations and 

Comparisons of Cr(CO)4NO- with Mn(CO)5- 

Sorensen, T. S.; Sun, F.; McDonald, R. 


31. Synthesis of Dimanganese Ruthenium Complexes from the 

Reaction of Ruthenium-Coordinated Thiophenes and Selenophene 

with [(1-Methylnaphthalene)Mn(CO)3]BF4 and Cp2Co 

Choi, D. S.; Lee, I. S.; Son, S. U.; Chung, Y. K. 


AUG 20 2001, volume 20, issue 17 

1. Chemistry of Ruthenium Azirinyl Complexes and Reversed 

Regiospecificity of the Carbonyl Insertion Reaction 

Yang, J.-Y.; Lo, Y.-H.; Huang, S.-L.; Lin, Y.-C. 


2. Samarium-Mediated Tandem Reactions of o-Carborane, Synthesis 

and Molecular Structure of [5:eta1:eta6-Me2Si(C9H5CH2- 

CH2G)(C2B10H10)Sm}2(mu-Cl)][Li(THF)4] (G = NMe2 and OMe) 

Wang, S.; Li, H.-W.; Xie, Z. 


3. Probing the Niobium Metallaaziridine Functionality 

Mindiola, D. J.; Cummins, C. C. 


4. Nucleophilic Carbene Complexes of Manganocene 

Abernethy, C. D.; Cowley, A. H.; Jones, R. A.; Macdonald, C. L. B.; 

Shukla, P.; Thompson, L. K. 


5. Unprecedented Formation of Dinuclear Platinum(II) Complexes 

with mu-Alkenylidene Bridging Ligands from Reactions of 

Pt(dppm)2Cl2 with Alkyl Acetylenes 

Yam, V. W.-W.; Yu, K.-L.; Chu, B. W.-K.; Cheung, K.-K. 


6. Aqueous Organometallic Chemistry with Nitrogen Ligands: 

Synthesis of Hydrophilic Platinum(0) Olefin Complexes 

Kundu, A.; Buffin, B. P. 


7. Formation and Crystal Structure of a Cationic 

Mono(cyclopentadienyl) Complex of Calcium, 

[(C5Me5)Ca(OPPh3)3]+I- 

Jayaratne, K. C.; Fitts, L. S.; Hanusa, T. P.; Young, V. G. 


8. Transfer Hydrogenation of Carbonyl Compounds Catalyzed by a 

Ruthenium-Acetamido Complex: Evidence for a Stepwise Hydrogen 

Transfer Mechanism 

Yi, C. S.; He, Z.; Guzei, I. A.


9. Synthesis, Properties, and Ligating Behavior of the First 

Facultative Tritelluroethers, Te(CH2CH2CH2TeR)2 (R = Me or Ph) 

Barton, A. J.; Levason, W.; Reid, G.; Ward, A. J. 


10. Novel Tricyclic Sila-Heterocycles: Syntheses and Crystal 

Structure Analyses of rac-2,8-Diethoxy-6,6-diorganyl-3,9-diaza-6silatricyclo[5.2.1.04,8]d 

ec-2-enes 

Merget, M.; Bertermann, R.; Wagner, B.; Tacke, R. 


11. Heterobimetallic Cubane-like Cluster Compounds Prepared as 

the Homologous Series [(eta5-Cp')3Mo3S4M'(PPh3)]+ (M' = Ni, Pd, 

Pt). Crystal Structures Show that Platinum Is Smaller than Palladium 

Herbst, K.; Rink, B.; Dahlenburg, L.; Brorson, M. 


12. Dihapto Coordination of Aromatic Molecules by the 

Asymmetricpi-Bases (Tp = hydridotris(pyrazolyl)-borate; L = tBuNC, 

PMe3, pyridine, 1-methylimidazole, or NH3) 

Meiere, S. H.; Brooks, B. C.; Gunnoe, T. B.; Carrig, E. H.; Sabat, M.; 

Harman, W. D. 


13. The Sensitive Balance between Five-Coordinate Carbene and Six- 

Coordinate Carbyne Ruthenium Complexes Formed from Ruthenium 

Vinylidene Precursors 

Gonzalez-Herrero, P.; Weberndorfer, B.; Ilg, K.; Wolf, J.; Werner, H. 


14. Recycling of Rhodium-Based Hydrosilylation Catalysts; A 

Fluorous Approach 

de Wolf, E.; Speets, E. A.; Deelman, B.-J.; van Koten, G. 


15. Palladium-Catalyzed Reactions of Ditert-butylsiliranes with 

Electron-Deficient Alkynes and Investigations of the Catalytic Cycle 

Palmer, W. S.; Woerpel, K. A. 


16. C-H and C-S Bond Cleavage in Uranium(III) Thiolato Complexes

Arliguie, T.; Lescop, C.; Ventelon, L.; Leverd, P. C.; Thuery, P.; Nierlich, 

M.; Ephritikhine, M. 


17. Cationic Platinum-Complex-Catalyzed Skeletal Reorganization of 

Enynes 

Oi, S.; Tsukamoto, I.; Miyano, S.; Inoue, Y. 


18. Iridacyclopentadiene Reactions with Terminal Alkynes: Tandem 

Cycloaromatization and Orthometalation 

O Connor, J. M.; Closson, A.; Hiibner, K.; Merwin, R.; Gantzel, P.; 

Roddick, D. M. 


19. Stereochemistry of Disilanylene-Containing Cyclic Compounds. 

Synthesis and Reactions of cis- and trans-1,2-Dimethyl-1,2-diphenyl- 

1,2-disilacyclohexane 

Cha, S.-H.; Lee, K.-K.; Kwak, Y.-W.; Choi, H.-J.; Park, Y. S.; Naka, A.; 

Ishikawa, M. 


20. Role of Halide Ions in Divalent Palladium-Mediated Reactions: 

Competition between beta-Heteroatom Elimination and beta-Hydride 

Elimination of a Carbon-Palladium Bond 

Zhang, Z.; Lu, X.; Xu, Z.; Zhang, Q.; Han, X. 


21. Pulse Radiolysis Studies of Water-Soluble Tungsten Hydride 

Complexes: One-Electron Reduction of Metal Hydrides and Hydrogen 

Atom Transfer Reactions 

Cabelli, D. E.; Shafiq, F.; Creutz, C.; Bullock, R. M. 


22. Trends in the Unimolecular Reactions of Triaryl Pnictogen 

Radical Cations Ar3E.+ (E = N, P, As, Sb, Bi): Reductive Elimination 

versus E-C Bond Cleavage 

Grutzmacher, H.-F.; Kirchhoff, D.; Grutzmacher, H. 


23. Synthesis and X-ray Structural Characterization of 

Ru(PPh3)3(CO)(C2H4) and RuH(o-C6H4C(O)CH3)(PPh3)2L (L =

PPh3, CO, DMSO): Ruthenium Complexes with Relevance to the 

Murai Reaction 

Jazzar, R. F. R.; Mahon, M. F.; Whittlesey, M. K. 


24. Macrocyclic Complexes of Niobium(III): Synthesis, Structure, and 

Magnetic Behavior of Mononuclear and Dinuclear Species That 

Incorporate the [P2N2] System 

Fryzuk, M. D.; Kozak, C. M.; Bowdridge, M. R.; Jin, W.; Tung, D.; 

Patrick, B. O.; Rettig, S. J. 


25. Synthesis and Reactivity of Indenyl Ruthenium(II) Complexes 

Containing the Labile Ligand 1,5-Cyclooctadiene (COD): Catalytic 

Activity of [Ru(eta5-C9H7)Cl-(COD)] 

Alvarez, P.; Gimeno, J.; Lastra, E.; Garcia-Granda, S.; Van der Maelen, J. 

F.; Bassetti, M. 


26. Reactions of Zinc Dialkyls with (Perfluorophenyl)boron 

Compounds: Alkylzinc Cation Formation vs C6F5-Transfer 

Walker, D. A.; Woodman, T. J.; Hughes, D. L.; Bochmann, M. 


27. Pentamethylcyclopentadienyl Ruthenium Complexes with Sulfur- 

and Selenium-Donor Ligands 

Zhang, Q.-F.; Cheung, F. K. M.; Wong, W.-Y.; Williams, I. D.; Leung, W.- 

H. 


28. Substitution and Migratory Insertion Reactions of Square-Planar 

Allenylidene Iridium Complexes 

Ilg, K.; Werner, H. 


29. Intramolecular CH Insertion Reactions of 

(Pentamethylcyclopentadienyl)Rhenium Alkynylcarbene Complexes 

Casey, C. P.; Kraft, S.; Kavana, M. 


30. Synthesis and Molecular Structures of Perfluoro-n-alkyl 

Complexes of Platinum(II) and Platinum(IV) Containing

Tetramethylethylenediamine (TMEDA) or 1,2- 

Bis(diphenylphosphino)ethane(DPPE) Ligands 

Hughes, R. P.; Sweetser, J. T.; Tawa, M. D.; Williamson, A.; Incarvito, C. 

D.; Rhatigan, B.; Rheingold, A. L.; Rossi, G. 


31. Structure and Reactivity of the Cationic Nickel Compound 

[(eta3:eta1-Ind(CH2)2N-Me2)Ni(PPh3)][BPh4] 

Groux, L. F.; Zargarian, D. 


32. Generation and Characterization of the 

Tris(pentafluorophenyl)borane Radical Anion 

Kwaan, R. J.; Harlan, C. J.; Norton, J. R. 


33. Synthesis of the Metal-Containing Dinitrile Ligand trans- 

[Ru(CNtBu)22)2-CCN}2] as a Precursor of Polymetallic Species 

Mosquera, M. E. G.; Ruiz, J.; Riera, V.; Garcia-Granda, S.; Diaz, M. R.; 

Bois, C. 


34. Synthesis and Structural Characterization of Monomeric Three- 

Coordinated beta-Diketoiminate Organozinc Derivatives 

Prust, J.; Stasch, A.; Zheng, W.; Roesky, H. W.; Alexopoulos, E.; Uson, I.; 

Bohler, D.; Schuchardt, T. 


35. Unexpected Formation of the Ruthenium Carbonyl Cluster with a 

Trigonal-Bipyramidal Ge2Ru3 Core Accompanied by Loss of 

Germanium Methyl Groups 

Zhang, Y.; Wang, B.; Xu, S.; Zhou, X. 


SEP 03 2001, volume 20, issue 18 

1. Synthesis and Structure of New Binuclear Organopalladium 

Macrocyclic Complexes 

Tsubomura, T.; Tanihata, T.; Yamakawa, T.; Ohmi, R.; Tamane, T.; 

Higuchi, A.; Katoh, A.; Sakai, K. 


2. A Novel Carbons-Adjacent arachno-C2B10 Carborane Tetraanion 

Bearing both Hexagonal and Pentagonal Bonding Faces 

Zi, G.; Li, H.-W.; Xie, Z. 


3. Synthesis, Structure, and Hydrosilylation Catalysis of a Chiral A- 

Frame Rhodium(I) Dimer with Cis Diphosphite Ligands 

Ini, S.; Oliver, A. G.; Tilley, T. D.; Bergman, R. G. 


4. A Novel Full-Sandwich Lanthanacarborane Complex Bearing an 

eta7-Carboranyl Ligand, 7- 

Me2Si(C13H9)(C2B10H11)]2YbIII}2YbII}8(THF)20} 

Wang, S.; Li, H.-W.; Xie, Z. 


5. Novel eta3-Vinylcarbene Complexes Derived from Ruthenium- 

Based Olefin Metathesis Catalysts 

Trnka, T. M.; Day, M. W.; Grubbs, R. H. 


6. In Situ Formation of Mixed Phosphine-Imidazolylidene Palladium 

Complexes in Room-Temperature Ionic Liquids 

Mathews, C. J.; Smith, P. J.; Welton, T.; White, A. J. P.; Williams, D. J. 


7. Facile Rearrangement of Metallacyclopentatrienes to Butadienyl 

Carbenes by a 1,2-Hydrogen Shift 

Becker, E.; Ruba, E.; Mereiter, K.; Schmid, R.; Kirchner, K. 


8. Reactions of Diacetylene Ligands with Trinuclear Clusters. 3. 

Cyclization of Diynes with beta-Amino Moieties on the Metal Core of 

[H2Os3(CO)10]

Tunik, S. P.; Khripun, V. D.; Balova, I. A.; Nordlander, E.; Haukka, M.; 

Pakkanen, T. A.; Raithby, P. R. 


9. C-H Bond Activation in Aqueous Solution: A Linear Free Energy 

Relationship Investigation of the Rate-Limiting Step in the H/D 

Exchange of Alcohols Catalyzed by a Molybdocene 

Breno, K. L.; Tyler, D. R. 


10. Organorhodium Compounds with Novel Bridged 

Dibenzo[b,e]fulvalene Ligands 

Tews, D.; Gaede, P. E. 


11. Binding Selectivity of Dihapto-Coordinated Olefins, Ketones, and 

Aldehydes Utilizing the Asymmetric pi-Basic Metal Fragment (Tp = 

Hydridotris(pyrazolyl)-borate) 

Meiere, S. H.; Harman, W. D. 


12. Synthesis and Molecular Structure of 

Bis(pentamethylcyclopentadienyl) Phospholyl- and 

Arsolylsamarium(III) Complexes: Influence of Steric and Electronic 

Factors 

Nief, F.; Ricard, L. 


13. Thermally Stable Dialkylzirconocenes with beta-Hydrogens. 

Synthesis and Diastereoselectivity 

Wendt, O. F.; Bercaw, J. E. 


14. Platinum(II) Hydride Silanone Complexes and Cyclic Trimers of 

Silanone. A Theoretical Study of Their Geometries, Bonding Nature, 

and Stabilities 

Sakaki, S.; Takayama, T.; Sugimoto, M. 


15. Reactivity of an Acetylenephosphino Gold(III) Precursor: 

Addition to the Triple Bond or Formation of Alkynyl Derivatives 

Bardaji, M.; Laguna, A.; Jones, P. G. 


16. A Novel Chiral Phosphino-Phosphaferrocene: Its Coordination 

Behavior and Application to Palladium-Catalyzed Asymmetric Allylic 

Alkylation 

Ogasawara, M.; Yoshida, K.; Hayashi, T. 


17. Metal Template Promoted Hydroamination of Ethynylphosphines 

and Aniline. Asymmetric Synthesis, Coordination Chemistry, and the 

Imine-Enamine Tautomerism of P-Chiral Iminophosphines 

Liu, X.; Mok, K. F.; Leung, P.-H. 


18. Reactions of Bis(pentafluorophenyl)borane with 

Cp2Ta(=CH2)CH3: Generation and Trapping of Tantalocene 

Borataalkene Complexes 

Cook, K. S.; Piers, W. E.; Woo, T. K.; McDonald, R. 


19. Reversible Carbon-Carbon Double Bond Cleavage of a Ketene 

Ligand at a Single Iridium(I) Center: A Theoretical Study 

Urtel, H.; Bikzhanova, G. A.; Grotjahn, D. B.; Hofmann, P. 


20. Synthesis of Hemilabile Phosphine-Phosphine Oxide Ligands via 

the Highly Selective Pd-Catalyzed Mono-oxidation of Bidentate 

Phosphines: Scope, Limitations, and Mechanism 

Grushin, V. V. 


21. Addition Reactions of Bis(pinacolato)-diborane(4) to Carbonyl 

Enones and Synthesis of (pinacolato)2BCH2B and 

(pinacolato)2BCH2CH2B by Insertion and Coupling 

Ali, H. A.; Goldberg, I.; Srebnik, M. 


SEP 17 2001, volume 20, issue 19 

1. Ti(NMe2)4 as a Precatalyst for Hydroamination of Alkynes with 

Primary Amines 

Shi, Y.; Ciszewski, J. T.; Odom, A. L. 


2. Mass Spectrometric Method for the Rapid Characterization of 

Transition Metal Carbonyl Cluster Reaction Mixtures 

Dyson, P. J.; Hearley, A. K.; Johnson, B. F. G.; Khimyak, T.; McIndoe, J. 

S.; Langridge-Smith, P. R. R. 


3. Measurement of the Barrier to beta-Hydride Elimination in a beta- 

Agostic Palladium-Ethyl Complex: A Model for the Energetics of 

Chain-Walking in (alpha-Diimine)PdR+ Olefin Polymerization 

Catalysts 

Shultz, L. H.; Brookhart, M. 


4. Peralkylated Ytterbium(II) Aluminate Complexes YbAl2R8. New 

Insights into the Nature of Aluminate Coordination 

Klimpel, M. G.; Anwander, R.; Tafipolsky, M.; Scherer, W. 


5. Methanofullerene-Based Palladium Bis-(amino)aryl Complexes 

and Application in Lewis Acid Catalysis 

Meijer, M. D.; Ronde, N.; Vogt, D.; van Klink, G. P. M.; van Koten, G. 


6. Synthesis and Spectroscopic Studies of Novel beta-Diketonate 

Copper(I) Compounds and Solid State Structure of Tetravinylsilane 

Tetrakis Copper(I) 1,1,1,5,5,5-Hexafluoroacetylacetonate (TVST[Cu]hfac) 

Rozenberg, G. G.; Steinke, J. H. G.; Gelbrich, T.; Hursthouse, M. B. 


7. Metal and Ancillary Ligand Structural Effects on Ethylene 

Insertion Processes at Cationic Group 4 Centers. A Systematic, 

Comparative Quantum Chemical Investigation at Various ab Initio 

Levels 

Lanza, G.; Fragala, I. L.; Marks, T. J. 


8. Formation of Coordinated RZn(macrocycle)+ Cations and 

Organozincate Anions from Reactions of Organozinc Compounds and 

Macrocycles 

Fabicon, R. M.; Richey, H. G. 


9. C-C Plasticity in Boron Chemistry: Modulation of the Cc…Cc 

Distance in Mixed Pyrrolyl/Dicarbollide Complexes 

Llop, J.; Vinas, C.; Teixidor, F.; Victori, L.; Kivekas, R.; Sillanpaa, R. 


10. Dynamical Density Functional Study of the Multistep CO 

Insertion into Zirconium-Carbon Bonds Anchored to a Calix[4]arene 

Moiety 

Fantacci, S.; De Angelis, F.; Sgamellotti, A.; Re, N. 


11. Formation and Structure of Heptacoordinate Dihalogeno 

Carbene-C,O Chelate Complexes and Dihalogeno Carbene-C,O 

Chelate Phosphine Complexes of Molybdenum(II) and Tungsten(II): A 

New Class of Fischer Type Carbene Complexes 

Stumpf, R.; Jaeger, M.; Fischer, H. 


12. N/O- and C-Bound (Enolato)palladium Complexes with 

Hydrotris(pyrazolyl)borato Ligands (TpR: R = iPr2, Me2) Obtained 

via Dehydrative Condensation between the Hydroxo Complexes 

TpRPd(Py)OH and Active Methylene Compounds: Factors 

Determining the Isomer Distribution and Dimerization of Cyano 

Compounds 

Kujime, M.; Hikichi, S.; Akita, M. 


13. Reactivity of Substituted Thiophenes toward 

Tris(triethylphosphine)platinum(0), -palladium(0), and -nickel(0) 

Hernandez, M.; Miralrio, G.; Arevalo, A.; Bernes, S.; Garcia, J. J.; Lopez, 

C.; Maitlis, P. M.; del Rio, F. 


14. Synthesis and X-ray Crystal Structure Determination of New 

Zwitterionic Complexes of Titanocene

Burlakov, V. V.; Arndt, P.; Baumann, W.; Spannenberg, A.; Rosenthal, U.; 

Letov, A. V.; Lyssenko, K. A.; Korlyukov, A. A.; Strunkina, L. I.; 

Minacheva, M. K. 


15. B(C6F5)3 as C6F5 Transfer Agent in Zirconium Chemistry: 

Borole Sandwich and Borole-Bridged Triple-Decker Complexes 

Woodman, T. J.; Thornton-Pett, M.; Hughes, D. L.; Bochmann, M. 

Organometallics, 2001, vol. 20, no. 19, pp. 4080 

16. Unusual Reactions of Cationic Bridging Carbyne Complexes of 

Dimethylsilane-Bridged Bis(eta5-cyclopentadienyl)diiron Tricarbonyl 

with Nucleophiles. A Route to Iron-Sulfur Cluster Bridging Carbene 

Complexes 

Wang, R.; Xu, Q.; Sun, J.; Song, L.-C.; Chen, J. 


17. Double Oxidative Addition of Tin(IV) Halides to Platinum(II): 

Complexes with Pt-Sn and Pt-Sn-Pt Linkages 

Janzen, M. C.; Jennings, M. C.; Puddephatt, R. J. 


18. TRISPHAT Anion. An Efficient NMR Chiral Shift Counterion for 

Cationic Tricarbonyl Manganese Complexes with Planar Chirality 

Planas, J. G.; Prim, D.; Rose, E.; Rose-Munch, F.; Monchaud, D.; Lacour, 

J. 


19. Synthesis and Molecular Structure of 

[Pd2CH2C(O)Me}(HL)][BAr'4] (HL = 6-Me-2,2'-bipyridine, Ar' = 3,5- 

(CF3)2-C6H3), an Intermediate Relevant to Ethene/CO 

Copolymerization 

Stoccoro, S.; Minghetti, G.; Cinellu, M. A.; Zucca, A.; Manassero, M. 


20. Preparation and Structure of Chiral Carbene Complexes of 

Manganese and Iron from Terminal Alkynes 

Semmelhack, M. F.; Lindenschmidt, A.; Ho, D. 


21. Two Luminescent 2D Layered Copper(I)-Olefin Coordination 

Polymers with High Thermal Stability 

Zhang, J.; Xiong, R.-G.; Chen, X.-T.; Che, C.-M.; Xue, Z.; You, X.-Z.


22. Reactions of Zirconacyclopentadienes with CO and Isonitriles 

Takahashi, T.; Tsai, F.-Y.; Li, Y.; Nakajima, K. 


23. First Heterobimetallic Seven-Membered Macrocycle Complex 

with a Fe(0) Cu(I) Donor-Acceptor Bond 

Cui, D.-J.; Li, Q.-S.; Xu, F.-B.; Leng, X.-B.; Zhang, Z.-Z. 


Organometallics 

Volume 20, Issue 20 (October 1, 2001) 

COMMUNICATIONS 

4129-4131 

Metallaaziridine Complexes of Tantalum Derived from 1,8- 

Bis(isopropylamino)naphthalene via -H Activation Patrick Bazinet, 

Glenn P. A. Yap, and Darrin S. Richeson 

4132-4134 

Metalations with Group 4 Alkylmetal(IV) Halides: Expeditious Route 

to Metallocene and Nonmetallocene Procatalysts1 John J. Eisch, 

Fredrick A. Owuor, and Peter O. Otieno 

4135-4137 

Synthesis and Structure of the Octanuclear Manganese(II) Cage [(- 

Cp)Mn{2-NH(4,6-Me2pm)}·Mn{2-N(4,6-Me2Pm)}]4 (Cp = C5H5, pm 

= Pyrimidine) Carmen Soria Aluarez, Andrew D. Bond, Eilis A. 

Harron, Richard A. Layfield, Judith A. McAllister, Christopher M. Pask, 

Jeremy M. Rawson, and Dominic S. Wright 

4138-4140 

A Monolithiated and Its Related 1,3-Dilithiated Benzylsilane: 

Syntheses and Crystal Structures Carsten Strohmann, Klaus Lehmen, 

Arne Ludwig, and Daniel Schildbach 

4141-4143 

A New Approach to the Synthesis of Unsymmetrical Disilenes and 

Germasilene: Unusual 29Si NMR Chemical Shifts and Regiospecific 

Methanol Addition Masaaki Ichinohe, Yoriko Arai, and Akira Sekiguchi , 

Nozomi Takagi and Shigeru Nagase 

4144-4146 

A Bis(oxazolinyl)pyrrole as a New Monoanionic Tridentate 

Supporting Ligand: Synthesis of a Highly Active Palladium Catalyst 

for Suzuki-Type C-C Coupling Clément Mazet and Lutz H. Gade 

4147-4149 

Unexpected Reaction of (trindane)Mn(CO)3+BF4- with Potassium 

tert-Butoxide: Three C-H Insertions and a Haptotropic Shift Nada 

Reginato and Michael J. McGlinchey

ARTICLES 

4150-4160 

Synthesis and Characterization of Triosmium Clusters Containing the 

Bidentate Ligand Ph2PCH2CH2SMe: Detection of an Isomerization 

Reaction Involving Bridging and Chelating Ligand Coordination 

Modes Roger Persson, Magda Monari, Roberto Gobetto, Andrea Russo, 

Silvio Aime, Maria José Calhorda, and Ebbe Nordlander 

4161-4169 

Protonation Reactions of [MH(Cl)(PPh3)2(norbornadiene)] (M = Ru, 

Os) Sheng Hua Liu, Sheng-Yong Yang, Shu Tak Lo, Zhitao Xu, Weng 

Sang Ng, Ting Bin Wen, Zhong Yuan Zhou, Zhenyang Lin, Chak Po Lau, 

and Guochen Jia 

4170-4177 

Reaction of the Cationic Cluster [Os3(-H)(CO)10(-1:2- 

=C=C=CMe2)]BF4 with Triphenylphosphine. Formation and 

Transformations of the -Acetylide Cluster [Os3(-H)(CO)10(PPh3)(- 

CCCMe2PPh3)]BF4 and Two Isomeric Clusters [Os3(- 

H)(CO)9(PPh3)(-:2-CCCMe2PPh3)]BF4 Ol'ga A. Kizas, Vasily V. 

Krivykh, Evgenii V. Vorontsov, Oleg L. Tok, Fedor M. Dolgushin, and 

Avthandil A. Koridze 

4178-4184 

The Role of - Stacking Interactions in Square Planar Palladium 

Complexes. Combined Quantum Mechanics/Molecular Mechanics 

QM/MM Studies Alessandra Magistrato, Paul S. Pregosin,* Alberto 

Albinati,* and Ursula Rothlisberger 

4185-4189 

Formation of Heterodimer Complexes between Analogous Chiral 

Lithium Amides: NMR Spectroscopic and Computational Studies 

Anna Johansson and Öjvind Davidsson 

4190-4197 

Reactivity of [Ru2(-1:1-N=CPh2)(-1:2-PhC=CHPh)(CO)6] with 

Alkynes. Insertion Reactions of Nonactivated Alkynes into Ru-C and 

Ru-N Bonds Javier A. Cabeza, Ignacio del Río, Fabrizia Grepioni, Marta 

Moreno, Víctor Riera, and Marta Suárez 

4198-4206 

C,N-2-[(Dimethylamino)methyl]phenylplatinum Complexes 

Functionalized with C60 as Macromolecular Building Blocks Michel D.

Meijer, Elwin de Wolf, Martin Lutz, Anthony L. Spek, Gerard P. M. van 

Klink, and Gerard van Koten 

4207-4210 

An Easy Synthetic Route to Heteroleptic Samarium Monoalkoxides 

for Ring-Opening Polymerization Initiators. Molecular Structures of 

[(C5Hi-Pr4)SmI(THF)2]2, SmI2Ot-Bu(THF)4, and (C4Me4P)2SmOt- 

Bu(THF) Denise Barbier-Baudry, Sebastian Heiner, Marek M. Kubicki, 

Estelle Vigier, and Marc Visseaux , Abderrafia Hafid 

4211-4215 

X-ray Structure of a Novel Tetrachloro[1.1]silaferrocenophane. 

Hydrolysis-Polycondensation of Poly(ferrocenyldichlorosilane). 

Electrochemical Studies Gérard Calleja, Francis Carré, and Geneviève 

Cerveau , Pierre Labbé and Liliane Coche-Guérente 

4216-4220 

Small Metallacarborane closo-C2B4H6Ru(PPh3)2HCl Formed from 

nido-5,6-C2B8H12 by Ruthenium-Mediated Polyhedral Contraction 

Irina V. Pisareva, Fedor M. Dolgushin, Oleg L. Tok, Vitalii E. Konoplev, 

Kyryll Yu. Suponitsky, Alexandr I. Yanovsky, and Igor T. Chizhevsky 

4221-4229 

Dinuclear [RNi(oxam)NiR] Complexes (oxam = N1,N2-bis(2pyridylmethyl)-N3,N4-bis(2,4,6-trimethylphenyl)oxalamidinate; 

R = 

Me, Ph, CCH, CCPh): Reactions of the Methyl Complex and 

Formation of [Li(THF)]2Li2Ni2Me8 and [Li(THF)]4Ni2Me8 Dirk 

Walther, Michael Stollenz, and Helmar Görls 

4230-4236 

Synthesis and Structure of Yttrium and Lanthanide 

Bis(phosphinimino)methanides Michael T. Gamer, Stefanie Dehnen, and 

Peter W. Roesky 

4237-4245 

Synthesis, Characterization, and Reaction Chemistry of PtCl2[P(m- 

C6H4SO3Na)3]2, an Alkyne Hydration Catalyst Laura W. Francisco, 

Debra A. Moreno, and Jim D. Atwood 

4246-4252 

Cationic Iridium Complexes Bearing Imidazol-2-ylidene Ligands as 

Transfer Hydrogenation Catalysts Anna C. Hillier, Hon Man Lee, Edwin 

D. Stevens, and Steven P. Nolan

4253-4261 

Ancillary Ligand and Olefin Substituent Effects on Olefin Dissociation 

for Cationic Zirconocene Complexes Bearing a Coordinated Pendant 

Olefin Christopher G. Brandow, Arjun Mendiratta, and John E. Bercaw 

4262-4265 

Models for Intermediates in Metallocene-Catalyzed Alkene 

Polymerization: Alkene Dissociation from Cp2Zr[1,2- 

CH2Si(CH3)2CH2CH=CH2][B(C6F5)4] Charles P. Casey, Donald W. 

Carpenetti II, and Hidehiro Sakurai 

4266-4273 

Sequential Bond Energies of Pt(CO)x+ (x = 1 -4) Determined by 

Collision-Induced Dissociation Xiao-Guang Zhang and P. B. Armentrout 

4274-4278 

Electronic Structure of Bispentalene Complexes of Titanium, 

Zirconium, and Hafnium: A Photoelectron Spectroscopic Study Rolf 

Gleiter, Sabine Bethke, Jun Okubo, and Klaus Jonas 

4279-4286 

Cyclopentadienyl Yttrium Complexes Bearing a Fluorinated 

Aryloxide Functionality Roland A. L. Gendron, David J. Berg, Pengcheng 

Shao, and Tosha Barclay 

NOTES 

4287-4290 

Generation and Reactions of Transient 9-Silaphenanthrene Derivative 

Makoto Oba, Minoru Iida, and Kozaburo Nishiyama 

4291-4294 

Formation of Cationic Half-Sandwich Osmium-Vinylidene Complexes 

from [Os(5-C5H5)(PiPr3)2]+ and Terminal Alkynes Miguel Baya, 

Pascale Crochet, Miguel A. Esteruelas, Ana M. López, Javier Modrego, 

and Enrique Oñate




Synthesis of Organosilanylene-Thienylene Alternating Oligomers 

Bearing Ether Side Chains. Peculiar Solvatochromic Behavior in 

Their Fluorescence Spectra Joji Ohshita, Mimi Hashimoto, Toshiyuki 

Iida, Heqing Tang, and Atsutaka Kunai 4295-4297 

Dicarbollide Analogues of the Constrained-Geometry Polymerization 

Catalyst Dae-Hyun Kim, Je Hong Won, Sung-Joon Kim, Jaejung Ko, 

Sang Hern Kim, Sungil Cho, and Sang Ook Kang 4298-4300 

Hydrogen and Dihydrogen Bonding as Important Features of the 

Reactivity of the Bridging Hydride in Pyrazolate-Bridged 

Dialuminum Complexes Zhengkun Yu, Joanne M. Wittbrodt, Aibing Xia, 

Mary Jane Heeg, H. Bernhard Schlegel, and Charles H. Winter 4301- 

4303 

Synthesis of Cyclophanic Chromium(0) Bis(carbene) Complexes Israel 

Fernández, Miguel A. Sierra, María José Mancheño, Mar Gómez- 

Gallego, and Susagna Ricart 4304-4306 

ARTICLES 

Surface Organometallic Chemistry: A New Synthesis of [Re2(CO)6( - 

OH)3] - from [Re(CO)3OH]4 Supported on a Silica Surface Added with 

K2CO3; Evidence of Its Thermal Binding to the Surface via Re-O-Si 

Bonds Confirmed by the Synthesis of the Molecular Models 

[Re2(CO)6( -OH)x( -OSiEt3)3-x] - (x = 0, 1, or 2) by Reaction of 

[Re2(CO)6( -OH)3] - with Et3SiOH Dominique Roberto, Giuseppe 

D'Alfonso, Renato Ugo, and Matteo Vailati 4307-4311 

Iron-Mediated Allylic Substitution Reactions with Chirality Transfer. 

Stereochemistry of the Formation of Diastereo- and Enantiomerically 

Enriched Olefinic and Allylic Tetracarbonyl Iron Complexes Dieter 

Enders, Bernd Jandeleit, Stefan von Berg, Gerhard Raabe, and Jan 

Runsink 4312-4332

Migration Tendencies of Group 14 Element Ligands in the 

Coordination Sphere of Cationic Phosphenium Iron Complexes C. H. 

Suresh and Nobuaki Koga 4333-4344 

Transition Metal Complexes with Sterically Demanding Ligands, 3.1 

Synthetic Access to Square-Planar Terdentate Pyridine-Diimine 

Rhodium(I) and Iridium(I) Methyl Complexes: Successful Detour via 

Reactive Triflate and Methoxide Complexes Stefan Nückel and Peter 

Burger 

4345-4359 

Use of the Extended One-Pot (EOP) Procedure for the Preparation of 

Ethynylated Thiophene Derivatives and Related Palladium- 

Ethynylthiophene Organometallic Oligomers Patrizia Altamura, 

Giorgio Giardina, Claudio Lo Sterzo, and Maria Vittoria Russo 4360- 

4368 

Five- and Six-Coordinate Ruthenium(II) Complexes Containing 2- 

Ph2PC6H4CH=N t Bu and 2-Ph2PC6H4CH2NH t Bu as Chelate Ligands: 

Synthesis, Characterization, and Catalytic Activity in Transfer 

Hydrogenation of Ketones Pascale Crochet, José Gimeno, Santiago 

García-Granda, and Javier Borge 4369-4377 

Synthesis and Reactivity of a Molybdenum(IV) 4 -Butadiene Complex 

Thomas M. Cameron, Ion Ghiviriga, Khalil A. Abboud, and James M. 

Boncella 

4378-4383 

Palladium-Catalyzed Cyclization of 6-Aminohex-1-yne Thomas E. 

Müller, Michael Berger, Manja Grosche, Eberhardt Herdtweck, and 

Franz P. Schmidtchen 4384-4393 

Reaction of Samarium 1,4-Diaza-1,3-diene Complexes with Ketones: 

Generation of a New Versatile Tridentate Ligand via 1,3-Dipolar 

Cycloaddition Joachim Scholz, Helmar Görls, Herbert Schumann, and 

Roman Weimann 4394-4402 

Kinetics and Mechanisms of Methyl Vinyl Ketone Hydroalkoxylation 

Catalyzed by Palladium(II) Complexes Kimberly J. Miller, Terutaka T.

Catalyzed by Palladium(II) Complexes Kimberly J. Miller, Terutaka T. 

Kitagawa, and Mahdi M. Abu-Omar 4403-4412 

Synthesis and Structures of (Dialkylamino)ethylcyclopentadienyl 

Derivatives of Zinc Donald J. Darensbourg, Jacob R. Wildeson, and 

Jason C. Yarbrough 4413-4417 

Doubly Cyclometalated Pyridazines: Contrasting Behavior with 

Palladium and Platinum Jonathan W. Slater, Donocadh P. Lydon, 

Nathaniel W. Alcock, and Jonathan P. Rourke 4418-4423 

Zirconium Phosphinimide Complexes: Synthesis, Structure, and 

Deactivation Pathways in Ethylene Polymerization Catalysis Nancy 

Yue, Emily Hollink, Fred Guérin, and Douglas W. Stephan 4424-4433 

NOTES 

Chelating Monoborane Phosphines: Rational and High-Yield 

Synthesis of [(COD)Rh{( 2 -BH3)Ph2PCH2PPh2}][PF6] (COD = 1,5cyclooctadiene) 

Michael Ingleson, Nathan J. Patmore, Giuseppe D. 

Ruggiero, Christopher G. Frost, Mary F. Mahon, Michael C. Willis, and 

Andrew S. Weller 4434-4436 

New cis- and trans-Arylplatinum(II) Acetylide Compounds 

Containing a Bis(imino)aryl [NCN] Ligand Wilhelmus J. Hoogervorst, 

Cornelis J. Elsevier, Martin Lutz, and Anthony L. Spek 4437-4440 

Incorporation of Three Phenylacetylene Molecules into an RhMo2S4 

Trinuclear Sulfido Cluster Core, Forming Bridging 

Metallathiacyclobutene and Dithiolene Moieties Tomotake Ikada, 

Yasushi Mizobe, and Masanobu Hidai 4441-4444




4445-4447 

An Unusual Hydride-Bridged Aluminum Complex with a Square-Planar 

Tetraaluminum Core Stabilized by 2,5-Bis((Dimethylamino)methyl)pyrrole 

Ligands Jr-Chiuan Chang, Chen-Hsiung Hung, and Jui-Hsien 

4448-4450 

Direct Acetoacetylation of Ferrocene and a 1,1'-Diphosphaferrocene Damian 

Plauk, Arkadiusz Kys, Janusz Zakrzewski, Agnieszka Rybarczyk-Pirek, and Tomasz A. 

Olszak 

4451-4453 

Four-, Five-, and Six-Membered Silaplatinacycles Obtained from the Reaction of 

an Arylallene with Pt(SiHPh2)2(PMe3)2 Makoto Tanabe, Hideto Yamazawa, and 

Kohtaro Osakada 

4454-4456 

Methyl Group Transfer from ZnMe2 to Arsenic(III), an Alternative Pathway to 

Deprotonation of [CyNHAs(-NCy)]2 Andrew D. Bond, Alexander D. Hopkins, 

Alexander Rothenberger, Robert Wolf, Anthony D. Woods, and Dominic S. Wright 

4457-4459 

Enhanced Reactivity of Cationic vs Neutral Hafnocene Complexes in 

Stoichiometric and Catalytic -Bond Metathesis Reactions Involving Si-H and Si-C 

Bonds Aaron D. Sadow and T. Don Tilley 

4460-4462 

Synthesis and Structure of Stable Tri-tert-butylgermyl-Substituted Stannylene 

and Germylene Wataru Setaka, Kenkichi Sakamoto, Mitsuo Kira, and Philip P. Power 

4463-4465 

Reactivity of Electrophilic Terminal Phosphinidene Complexes: P-P Bond 

Forming Reactions with Phosphines and Diphosphines Brian T. Sterenberg, 

Konstantin A. Udachin, and Arthur J. Carty 

CORRESPONDENCE 

4466-4468 

Reactivity and Acidity of Alkylaluminoxanes Erling Rytter, Jon Andreas Stvneng, 

Jan Lasse Eilertsen, and Martin Ystenes 

ARTICLES 

4469-4475 

Synthesis, Structural, and Theoretical Analysis of Ru4(CO)12(-PF2)(4-P): Is the 

4-P Atom a Three-Electron or a Five-Electron Donor? Samia Kahlal, Weibin Wang, 

Ludmila Scoles, Konstantin A. Udachin, Jean-Yves Saillard, and Arthur J. Carty 

4476-4482

Synthesis, Luminescence, Electrochemistry, and Ion-Binding Studies of 

Platinum(II) Terpyridyl Acetylide Complexes Vivian Wing-Wah Yam, Rowena Pui- 

Ling Tang, Keith Man-Chung Wong, and Kung-Kai Cheung 

4483-4491 

Preparation and Reactions of a Half-Sandwich Dicarbollyl Nickel(II) Complex 

Containing a Dimethylamino Pendent Group Jin-Soon Park, Dae-Hyun Kim, Sung- 

Joon Kim, Jaejung Ko, Sang Hern Kim, Sungil Cho, Chai-Ho Lee, and Sang Ook Kang 

4492-4501 

-Agostic Interactions in Cp*W(NO)(CH2CMe3)2 and Related Nitrosyl Complexes 

Robert Bau, Sax A. Mason, Brian O. Patrick, Craig S. Adams, W. Brett Sharp, and 

Peter Legzdins 

4502-4509 

Electronic Structure of Ruthenium(II) Polyynyl Complexes Olivia F. Koentjoro, 

Roger Rousseau, and Paul J. 

4510-4516 

Unexpected Metallosite-Selective CO Substitution of Heteronuclear Tetrahedral 

(3-S)FeCoM (M = Mo, W) Carbonyl Clusters with Cyclohexyl Isocyanide: 59Co 

NMR and 57Fe Mössbauer Spectra of (3-S)FeCoMo(CO)8-n(5- 

C5H4COMe)(C6H11NC)n (n = 1-3) and Crystal Structures of (3-S)FeCoM(CO)8n(5-C5H4R)(C6H11NC)n 

(M = Mo, W; R = MeCO, MeO2C; n = 1, 2) Li-Cheng 

Song, Chun-Cheng Luo, Qing-Mei Hu, Jiabi Chen, and Hong-Gen Wang 

4517-4523 

Molybdenum and Tungsten Tricarbonyl Complexes with the Tripodal Ligands 

[nBuSn(2-pyridyl)3] and [RSn(methylthiomethyl)3] Dolores Morales, Julio Pérez, 

Lucía Riera, and Víctor Riera , Daniel Miguel 

4524-4528 

Fluorous Phase Soluble Palladium Nanoparticles as Recoverable Catalysts for 

Suzuki Cross-Coupling and Heck Reactions Marcial Moreno-Mañas, Roser Pleixats, 

and Silvia Villarroya 

4529-4536 

Organolanthanide-Based Coordination and Insertion Reactivity of the Anion 

Formed by Deprotonation of -Caprolactam William J. Evans, Cy H. Fujimoto, and 

Joseph W. Ziller 

4537-4541 

Arrhenius Parameters for the Head-to-Tail Dimerizations of 1,1-Diphenylsilene 

and 1,1-Diphenylgermene in Solution Tracy L. Morkin and William J. Leigh 

4542-4553 

Formation of a Stable Rhodium(I) Dihydride Complex and Its Reactions with 

Prochiral Substrates of Asymmetric Hydrogenation Ilya D. Gridnev, Natsuka 

Higashi, and Tsuneo Imamoto

4554-4561 

Decomplexation of Cyclopentadienylmanganese Tricarbonyls under Very Mild 

Conditions: A Novel Route to Substituted Cyclopentadienes and Their Application 

in Organometallic Synthesis Siden Top, El Bachir Kaloun, Stéphanie Toppi, Audrey 

Herrbach, Michael J. McGlinchey, and Gérard Jaouen 

4562-4564 

Disrotatory and Conrotatory Transition Structures for the Fe(CO)3-Templated 

Rearrangement of Methylenecyclopropane to Trimethylenemethane Dean J. 

Tantillo, Barry K. Carpenter, and Roald Hoffmann 

4565-4573 

Synthesis, Structures, and Reactivity of the First Silylene-Linked 

Cyclopentadienyl-Phosphido Lanthanide Complexes Olivier Tardif, Zhaomin Hou, 

Masayoshi Nishiura, Take-aki Koizumi, and Yasuo Wakatsuki 

4574-4583 

Induction of Planar Chirality in Formation of (5:1-1-(1-Cyclohexyl-2- 

(diphenylphosphino)ethyl)indenyl)carbonylrhodium and (5:1-1-(2-Phenyl-2- 

(diphenylphosphino)ethyl)indenyl)carbonylrhodium Daniel C. Brookings, Stephen 

A. Harrison, and Richard J. Whitby , Barry Crombie and Ray V. H. Jones 

4584-4592 

The Elusive 7-Silanorbornadien-7-ylium: Synthesis and Characterization of 

Nitrilium and Oxonium Ions Deriving from 2,3-Benzo-7-silanorbornadien-7-ylium 

Julia Schuppan, Bernhard Herrschaft, and Thomas Müller 

4593-4599 

Selectivity in Gas-Phase Ion Chemistry. Competitive Fast Reactions in a 

Silane/Propene System Carlo Canepa, Andrea Maranzana, Lorenza Operti, Roberto 

Rabezzana, and Gian Angelo Vaglio 

4600-4606 

Heavy Alkali Metal Tris(trimethylsilyl)silanides: A Synthetic and Structural 

Study David M. Jenkins, Weijie Teng, Ulrich Englich, David Stone, and Karin 

Ruhlandt-Senge 

4607-4615 

Catalytic and Photochemical Cyclopropanation of Alkenes with Methyl 

Diazo(trialkylsilyl)acetates: Steric Effects and Thermodynamic Stabilities of 

Cyclopropanes Gerhard Maas , Mechthild Alt, Dieter Mayer, and Uwe Bergsträsser , 

Stepan Sklenak, Prince Xavier, and Yitzhak Apeloig 

4616-4622 

Benzyl Complexes of the Heavier Alkaline-Earth Metals: The First Crystal 

Structure of a Dibenzylstrontium Complex Florian Feil and Sjoerd Harder 

4623-4631 

Competitive Insertion of Isocyanide and Carbon Dioxide into Niobium- and 

Silicon-Amido Bonds M. Isabel Alcalde, M. Pilar Gómez-Sal, and Pascual Royo

4632-4640 

Half-Sandwich Iron(II) and Ruthenium(II) Complexes with the Dicarbollylamino 

Ligand System Jin-Soon Park, Dae-Hyun Kim, Jaejung Ko, Sang Hern Kim, Sungil 

Cho, Chai-Ho Lee, and Sang Ook Kang 

4641-4646 

Reactions of Ruthenium-Benzylidene Complexes with Bis(trimethylsilyl)ethene 

and Trimethylsilylstyrenes: Olefin Metathesis versus -SiMe3 

Elimination/Reductive Elimination Cezary Pietraszuk and Helmut Fischer 

4647-4653 

The O,C,O-Coordinating Pincer-Type Ligand {2,6-[P(O)(OEt)2]2-4-t-Bu-C6H2}- 

in Organotin Chemistry. Halide Exchange, Cyclization, and Novel Coordination 

Mode Michael Mehring, Ioannis Vrasidas, Dagmar Horn, Markus Schürmann, and 

Klaus Jurkschat 

4654-4663 

From Intramolecularly [4 + 1]- and [4 + 2]-Coordinated Tri- and 

Tetraorganosilanes to Hypercoordinated Benzoxasilaphospholes Katja Peveling, 

Markus Schürmann, Ralf Ludwig, and Klaus Jurkschat 

4664-4675 

Organometallic Complexes for Nonlinear Optics. 22.1 Quadratic and Cubic 

Hyperpolarizabilities of trans-Bis(bidentate phosphine)ruthenium -Arylvinylidene 

and -Arylalkynyl Complexes Stephanie K. Hurst, Marie P. Cifuentes, Joseph P. L. 

Morrall, Nigel T. Lucas, Ian R. Whittall, Mark G. Humphrey, Inge Asselberghs, André 

Persoons, Marek Samoc, Barry Luther-Davies, and Anthony C. Willis 

4676-4682 

Rhodium-Catalyzed Formal Hydrocarbamoylation toward an ,-Unsaturated 

Carbonyl Compound Using Aryl Isocyanate and Hydrosilane Takako Muraoka, 

Isamu Matsuda, and Kenji Itoh 

4683-4689 

Syntheses and Structures of New Luminescent Cyclometalated Palladium(II) and 

Platinum(II) Complexes: M(Bab)Cl, M(Br-Bab)Cl (M = Pd(II), Pt(II)), and 

Pd3Cl4(Tab)2 (Bab = 1,3-bis(7-azaindolyl)phenyl, Br-Bab = 1-Bromo-3,5-bis(7azaindolyl)phenyl, 

Tab =1,3,5-tris(7-azaindolyl)phenyl) Datong Song, Qingguo Wu, 

Andrea Hook, Igor Kozin, and Suning Wang 

4690-4694 

Toward an Understanding of the Mechanism of Metal Exchange in (Propargyl 

Alcohol)Co2(CO)6 Clusters: Syntheses and Structures of [5-C5Ph2R2-CC- 

TMS)(Fe(CO)2(-H)]Co2(CO)6, R = Ph or Et James A. Dunn, James F. Britten, Jean- 

Claude Daran, and Michael J. McGlinchey 

4695-4699

Polymetalated Aromatic Compounds. 1. Synthesis of Mono-, Di-, and 

Tripalladated Mesitylene Derivatives José Vicente and Mykhaylo Lyakhovych , Delia 

Bautista , Peter G. Jones 

4700-4704 

Synthesis of (dppe)Pt(3-S)2{Ru(N)Me2}2, (dppe)Pt(3-S)2{Os(N)(CH2SiMe3)2}2, 

and Related Heterometallic Complexes Patricia A. Shapley, Hong-Chang Liang, and 

Nancy C. Dopke 

4705-4712 

Molybdenum Imido Alkylidene Complexes Containing Biphen Ligands that Have 

Silyl Groups Attached through the 6 and 6' Methyl Group Carbon Atoms Kai C. 

Hultzsch, Peter J. Bonitatebus, Jr., Jesper Jernelius, Richard R. Schrock, and Amir H. 

Hoveyda 

4713-4720 

Neutral Hexacoordinate Silicon Tris-Chelates: Structure and Stereodynamics Inna 

Kalikhman, Vijeyakumar Kingston, Olga Girshberg, and Daniel Kost 

4721-4726 

Olefin Polymerization at Aluminum? A Theoretical Study Giovanni Talarico and 

Vincenzo Busico , Peter H. M. Budzelaar 

4727-4733 

Dimerization of Diboradiazacyclobutadienes To Form 

Tetraboratetraazacyclooctatetraenes: Computational Study of Boron-Nitrogen 

Ring Formation and Ring Opening Thomas M. Gilbert and BettyCep D. Gailbreath 

4734-4740 

Synthesis, Spectroscopic, and Substituent-Dependent Self-Assembling Structural 

Characterization of Ferrocenyl-Containing Silanediols, Fc(R)Si(OH)2, R = Me, 

CH2=CHCH2, n-Bu, t-Bu, Ph, c-Hx, Including Transformation to a Ferrocenyl 

Stannasiloxane, [OSiFc(n-Bu)O(t-Bu2)Sn]2 Enrique A. Reyes-García, Francisco 

Cervantes-Lee, and Keith H. Pannell 

NOTES 

4741-4744 

Synthesis and Molecular Structure of a Perfluoroalkyl Complex of Platinum 

Containing a PCP Pincer Ligand Russell P. Hughes, Alex Williamson, Christopher D. 

Incarvito, and Arnold L. Rheingold 

4745-4748 

A Facile Synthesis of 2,2,6,6-Tetramethyl-2-germa-3,5-heptandione: The 

Preparation and Characterization of the First Germa--diketonate Copper(II) 

Complex Kulbinder K. Banger, Claudia Birringer, Rolf U. Claessen, Poay Lim, Paul J. 

Toscano, and John T. Welch


Volume 20, Issue 23 (November 12, 2001) 

REVIEWS 

Preparation and Reactivity of Compounds Containing a Carbon-Xenon Bond 

Hermann-Josef Frohn , Vadim V. Bardin 4750-4762 


Evidence for a Lithium Amidocuprate/Cyclohexenone Complex in Solution Johan 

Eriksson , Öjvind Davidsson 4763-4765 

Activation of Water and of Dioxygen by a Bis(diphenylphosphinopropyl)silyl 

(biPSi) Complex of Ruthenium(II): Formation of 

Bis(diphenylphosphinopropyl)siloxo Cage Complexes. Concomitant Oxygen 

Atom Insertion into a Silicon-Carbon Bond Stephen R. Stobart, Xiaobing (Joe) 

Zhou, Raymundo Cea-Olivares, and Alfredo Toscano 

4766-4768 

Nickel Ethylene Polymerization Catalysts Based on Phosphorus Ligands Neil A. 

Cooley, Simon M. Green, and Duncan F. Wass , Katie Heslop, A. Guy Orpen, and 

Paul G. Pringle 4769-4771 

Novel Trinuclear Trihydride Complexes of Ruthenium Having a Triply Bridging 

Borylene Ligand, {( 5 -C5Me5)Ru}3( -H)3( 3-BX) (X = H, CN, OMe, OEt). 

Synthesis, Structure Determination, and Reaction with Benzothiophene Rei 

Okamura, Ken-ichi Tada, Kouki Matsubara, Masato Oshima, and Hiroharu Suzuki 

4772-4774 

ARTICLES 

Dissociative CO Photosubstitution in M(CO)4(1,4-diazabutadiene) Complexes (M 

= W, Mo) by an Olefin Affording Novel fac-M(CO)3(1,4-diazabutadiene)( 2 - 

olefin) Derivatives Friedrich-Wilhelm Grevels, Klaus Kerpen, Werner E. Klotzbücher, 

and Kurt Schaffner , Richard Goddard and Bruno Weimann , Ceyhan Kayran and 

Saim Özkar 4775-4792 

New Titanium Complexes Having Two Pyrrolide-Imine Chelate Ligands: 

Syntheses, Structures, and Ethylene Polymerization Behavior Yasunori Yoshida, 

Shigekazu Matsui, Yukihiro Takagi, Makoto Mitani, Takashi Nakano, Hidetsugu 

Tanaka, Norio Kashiwa, and Terunori Fujita 4793-4799 

Effects of Conjugated Substituents on the Optical, Electrochemical, and Electron- 

Transporting Properties of Dithienosiloles Joji Ohshita, Hiroyuki Kai, Atsuhiro 

Takata, Toshiyuki Iida, Atsutaka Kunai, Nobuaki Ohta, Kenji Komaguchi, Masaru 

Shiotani, Akira Adachi, Koichi Sakamaki, and Koichi Okita 4800-4805 

Synthesis and Strutures of Germanium(II) Fluorides and Hydrides Yuqiang Ding, 

Haijun Hao, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt

Haijun Hao, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt 

4806-4811 

Mixed Gold(I)-Gold(III) Complexes with Bridging Selenido Ligands. Theoretical 

Studies of the Gold(I)-Gold(III) Interactions Silvia Canales, Olga Crespo, M. 

Concepción Gimeno, Peter G. Jones, Antonio Laguna, and Fernando Mendizabal 

4812-4818 

An Examination of C-H Bond Activation by Cationic TpMe 2Ir(III) Complexes 

David M. Tellers and Robert G. Bergman 4819-4832 

Acac-Promoted Rearrangement of an Alkylaluminophosphonate Tetramer to a 

Decamer Mark R. Mason, Alisa M. Perkins, Vira V. Ponomarova, and Ashwani Vij 

4833-4839 

2 -Alkynyl and Vinylidene Transition Metal Complexes. 7. 1 Hydroamination of 

Neutral Tungsten-Vinylidene Complexes Junes Ipaktschi, Sascha Uhlig, and Ansgar 

Dülmer 4840-4846 

Four Thallium(I) Ions Sandwiched by Two Tetraalkynylplatinate ([Pt(C CR)4] 2- ) 

Fragments: Synthesis and Luminescent Behavior of Pt2Tl4 Species Jesús R. 

Berenguer, Juan Forniés, Julio Gómez, Elena Lalinde, and M. Teresa Moreno 4847- 

4851 

Computational Investigation of Ethylene Insertion into the Metal-Methyl Bond of 

First-Row Transition Metal(III) Species Vidar R. Jensen and Walter Thiel 4852- 

4862 

Gas-Phase Synthesis and Characterization of an Azaphosphirenium Ion: The 

First N,P-Analogue of the Aromatic Cyclopropenyl Cation Luiz Alberto B. Moraes 

and Marcos N. Eberlin , Kenneth K. Laali 4863-4868 

Yttrium Hydrido Complexes that Contain a Less "Constrained Geometry" 

Ligand: Synthesis, Structure, and Efficient Hydrosilylation Catalysis Alexander A. 

Trifonov , Thomas P. Spaniol and Jun Okuda 4869-4874 

Influence of the Group 14 Element on the Deprotonation of OsH( 5 -C5H5)(C 

CPh)(EPh3)(P i Pr3) (E = Si, Ge): Two Different Organometallic Chemistries 

Miguel Baya, Miguel A. Esteruelas, and Enrique Oñate 4875-4886 

Electronic Effects on the Stability of Isomeric Alkyl Transition Metal Compounds 

Jeremy N. Harvey 4887-4895

Reactions of Neopentylindium(III) Derivatives with Isopropylphosphorus 

Compounds O. T. Beachley, Jr., Sun-Hua L. Chao, Melvyn Rowen Churchill, and 

Charles H. Lake 4896-4902 

pH-Dependent Transfer Hydrogenation, Reductive Amination, and 

Dehalogenation of Water-Soluble Carbonyl Compounds and Alkyl Halides 

Promoted by Cp*Ir Complexes Seiji Ogo, Nobuyuki Makihara, Yuichi Kaneko, and 

Yoshihito Watanabe 4903-4910 

Synthesis, Characterization, and Photoisomerization Studies of Azo- and 

Stilbene-Containing Surfactant Rhenium(I) Complexes Vivian Wing-Wah Yam, Yu 

Yang, Jiaxin Zhang, Ben Wai-Kin Chu, and Nianyong Zhu 4911-4918 

Cyclometalation Reactions on Rhodium(I). Evidence for a Chelate Effect and 

Competing C-H and C-O Oxidative Additions Sven Sjövall, Carlaxel Andersson, 

and Ola F. Wendt 4919-4926 

1 H and 19 F NMR Investigation of the Reaction of B(C6F5)3 with Water in Toluene 

Solution Tiziana Beringhelli, Daniela Maggioni, and Giuseppe D'Alfonso 4927-4938 

Intermolecular C-H Activation of Hydrocarbons by Tungsten Alkylidene 

Complexes: An Experimental and Computational Mechanistic Study Craig S. 

Adams, Peter Legzdins, and W. Stephen McNeil 4939-4955 

Synthesis and Characterization of Formyl and Hydroxymethyl Complexes 

Derived from Isomeric Cations: cis-Ru(N-N)( 2 -tpy)(CO)2 2+ 2PF6 - (N-N = 2,2'- 

Bipyridine, 4,4'-Dimethyl-2,2'-bipyridine; tpy = 2,2':6',2' '-Terpyridine) Dorothy 

H. Gibson, Jose G. Andino, Srinivas Bhamidi, Bradley A. Sleadd, and Mark S. 

Mashuta 4956-4964 

NOTES 

Alkylation of ( 6 -Arene)Mn(CO)3 Cations with Organozinc Reagents Ming-Chang 

P. Yeh, Chong-Cheng Hwu, An-Tang Lee, and Ming-Shan Tsai 4965-4968 

Aqueous "Green" Organometallic Chemistry: Structure of the Molybdocene 

Monohydride Used for Carbonyl Reduction in Water Louis Y. Kuo, Timothy J. R. 

Weakley, Kukui Awana, and Clara Hsia 4969-4972 

Formation of a Diynedienyl Ligand by Coupling of Hexa-2,4-diyne and Hex-2-yn- 

4-en-4-yl Ligands onto a Triruthenium Cluster Core Javier A. Cabeza, Ignacio del 

Río, Santiago García-Granda, Marta Moreno, and Víctor Riera 4973-4976


Volume 19, Issue 24 (November 27, 2000) 


4929-4931 

Syntheses and Molecular Structures of [Mg4(THFFO)6(OSiPh3)2] and [Al3Mg( 3- 

O)(THFFO)3(Me)6] Relevant to Ziegler-Natta Catalyst Intermediates (THFFO = 

2-Tetrahydrofurfuroxide) Piotr Sobota, Józef Utko, Jolanta Ejfler, and Lucjan B. 

Jerzykiewicz 

4932-4934 

Reduction of a CO Ligand in an Iron Phosphonate Complex with a Neutral 

Borane Compound. Formation of a Formyl Complex with Intramolecular 

Coordination to a Boron Atom Kazuyuki Kubo, Hiroshi Nakazawa, Shinji 

Nakahara, Kazuhiro Yoshino, Tsutomu Mizuta, and Katsuhiko Miyoshi 

4935-4937 

1,2-Thiaborolide: A New Heteroaromatic -Ligand Containing Boron and Sulfur 

Arthur J. Ashe, III, Xiangdong Fang, and Jeff W. Kampf 

4938-4940 

Silylene and Disilene Additions to an Octa-1,3,5,7-tetrayne: Formation of a C-C- 

Linked Quatersilirene 12 Detlev Ostendorf, Wolfgang Saak, and Manfred 

Weidenbruch , Heinrich Marsmann 

4941-4943 

Direct Generation of Thiomethylmanganese Reagents and Their Reactions with 

Electrophiles 1 Makoto Hojo, Rie Sakuragi, Yoshio Murakami, Yu Baba, and Akira 

Hosomi 

ARTICLES 

4944-4956 

Sterically Tunable Phosphenium Cations: Synthesis and Characterization of Bis 

(arylamino)phosphenium Ions, Phosphinophosphenium Adducts, and the First 

Well-Defined Rhodium Phosphenium Complexes Michael B. Abrams, Brian L. 

Scott, and R. Thomas Baker 

4957-4967 

Remarkable Differences in Catalyst Activity and Selectivity for the Production of 

Methyl Propanoate versus CO-Ethylene Copolymer by a Series of Palladium

Complexes of Related C4-Bridged Diphosphines Julian G. Knight, Simon Doherty, 

Anthony Harriman, Edward G. Robins, Michael Betham, Graham R. Eastham, 

Robert P. Tooze, Mark R. J. Elsegood, Paul Champkin, and William Clegg 

4968-4976 

Oxidative-Addition of Organic Monochloro Derivatives to Dinuclear Rhodium 

Complexes: Mechanistic Considerations Cristina Tejel, Miguel A. Ciriano, Andrew 

J. Edwards, Fernando J. Lahoz, and Luis A. Oro 

4977-4984 

Oxidative-Addition of Organic Monochloro Derivatives to Dinuclear Iridium 

Complexes: The Detection of Tautomeric Equilibria and Their Implications on 

the Reactivity Cristina Tejel, Miguel A. Ciriano, José A. López, Fernando J. Lahoz, 

and Luis A. Oro 

4985-4994 

Polynuclear Gold Complexes with Bridging Selenido Ligands. Theoretical 

Studies of Gold-Gold Interactions Silvia Canales, Olga Crespo, M. Concepción 

Gimeno, Peter G. Jones, Antonio Laguna, and Fernando Mendizabal 

4995-5004 

Stable, Cationic Alkyl-Olefin Complexes of Ruthenium(II) and Rhodium(III): 

Effects of Ligand Geometry upon Olefin Insertion/Alkyl Migration Eric L. Dias, 

Maurice Brookhart, and Peter S. White 

5005-5009 

Photolytic Ring-Opening Polymerization of Phosphorus-Bridged [1] 

Ferrocenophane Coordinating to an Organometallic Fragment Tsutomu Mizuta, 

Makoto Onishi, and Katsuhiko Miyoshi 

5010-5015 

, -Bis(trimethylsilyl)-Substituted Benzyl Complexes of Potassium and Calcium 

Florian Feil and Sjoerd Harder 

5016-5025 

Unusual Reductive Coupling of Alkynes and Ketones: Reactivity of Titanacycles 

Supported by Dimethylsilylcalix[4]arene (DMSC) Ligands Oleg V. Ozerov, 

Carolyn P. Brock, Shana D. Carr, and Folami T. Ladipo 

5026-5031 

Nickel-Catalyzed Double Silylation of a Variety of Carbonyl Compounds with

1,2-Bis(dimethylsilyl)carborane Youngjin Kang, Jinsik Kim, Young Kun Kong, 

Jihwa Lee, Soon W. Lee, Sang Ook Kang, and Jaejung Ko 

5032-5038 

Regioselective Metal Exchange Reactions in Linked Clusters Jie Zhang, Yu-Hua 

Zhang, Xue-Nian Chen, Er-Run Ding, and Yuan-Qi Yin 

5039-5048 

Communication between Co2(CO)4dppm Units via Polyferrocenylalkyne 

Linkages Leigh-Anne Hore, C. John McAdam, Joy L. Kerr, Noel W. Duffy, Brian H. 

Robinson, and Jim Simpson 

5049-5062 

Compounds with Unbridged Dative Metal-Metal Bonds of Formula (R3P)2(OC) 

3OsW(CO)5 and Related Complexes Faming Jiang, Hilary A. Jenkins, Kumar 

Biradha, Harry B. Davis, Roland K. Pomeroy, and Michael J. Zaworotko 

5063-5070 

Luminescent Binuclear Gold(I) Ring Complexes William J. Hunks, Mary-Anne 

MacDonald, Michael C. Jennings, and Richard J. Puddephatt 

5071-5076 

Synthesis and Structures of Platinum A-Frame Complexes Mesfin Janka, Gordon 

K. Anderson, and Nigam P. Rath 

5077-5082 

Organometallic Synthesis as a Continuous Process: The Synthesis and Isolation 

of Cr(CO)5( 2 -C3H6) and (C5R5)Mn(CO)2( 2 -C3H6) (R = H and Me) from 

Superheated Liquid Propene Jennifer L. King, Karine Molvinger, and Martyn 

Poliakoff 

5083-5091 

First B-Organyloxy-Substituted Iminoboranes: Preparation, Stabilization, and 

Reactivity Egbert v. Steuber, Gernot Elter, Mathias Noltemeyer, Hans-Georg 

Schmidt, and Anton Meller 

5092-5097 

Synthesis and Luminescence Behavior of Rhenium(I) Triynyl Complexes. X-ray 

Crystal Structures of [Re(CO)3( t Bu2bpy)(C C-C C-C CPh)] and [Re(CO)3 

(Me2bpy)(C C-C C-C CSiMe3)] Vivian Wing-Wah Yam, Samuel Hung-Fai 

Chong, Chi-Chiu Ko, and Kung-Kai Cheung

5098-5106 

The Dihydride-Osmium(IV) Complex [OsH2( 2 -O2CCH3)(H2O)(P i Pr3)2]BF4 as a 

Precursor for Carbon-Carbon Coupling Reactions Miguel A. Esteruelas, Cristina 

García-Yebra, Montserrat Oliván, Enrique Oñate, and María A. Tajada 

5107-5112 

Reaction of GaMe3 with H2NCH2CH2NMe2: Synthesis and Characterization of 

Adducts and Imidogallane Jae E. Park, Byoung-Jae Bae, Kwangyeol Lee, Joon T. 

Park, Hong Young Chang, and Moon-Gun Choi 

5113-5121 

Palladium Complexes Containing a Hemilabile Pyridylcarbene Ligand Jack C. 

C. Chen and Ivan J. B. Lin 

5122-5133 

Evidence for Intramolecular Permutation (Pseudorotation) at the Central 

Antimony Atom and Strong Equatophilicity of an Iron and a Ruthenium Ligand 

in Pentacoordinate Hypervalent Antimony Compounds Koichiro Toyota, Yukiya 

Wakisaka, Yohsuke Yamamoto, and Kin-ya Akiba 

5134-5142 

Synthesis and Structures of Hypervalent Antimony Compounds Bearing an 

Antimony-Group 6 Transition Metal Bond Koichiro Toyota, Yohsuke Yamamoto, 

and Kin-ya Akiba 

5143-5148 

Rhodium-Stabilized o-Quinone Methides: Synthesis, Structure, and 

Comparative Study with Their Iridium Congeners Hani Amouri and Jacqueline 

Vaissermann , Marie Noelle Rager , Douglas B. Grotjahn 

5149-5154 

Skeletal Growth by Condensation of Small Metal Fragments on a Carbido 

Carbonyl Cluster. Synthesis of the Anions [Rh15C2(CO)24X2] 3- (X = Cl, Br, I) and 

Molecular Structure of the Bromo and Iodo Derivatives Alessandro Fumagalli, 

Secondo Martinengo, Giovanni Bernasconi, Luciana Noziglia, Vincenzo G. Albano, 

Magda Monari, and Carlo Castellari 

5155-5159

Cationic Ansa-Zirconocene and Hafnocene Derivatives of a Monoanionic 

Phosphonium-Bridged Bis(permethylcyclopentadienyl) Ligand: Synthesis and 

Structural Characterization of {[Me2P(C5Me4)2]MCl2} + (M = Zr, Hf) and {[Me2P 

(C5Me4)2]ZrMe2} + Jun Ho Shin, Brian M. Bridgewater, and Gerard Parkin 

5160-5167 

Cationic Complexes of Palladium(II) and Platinum(II) as Lewis Acid Catalysts 

for the Diels-Alder Reaction Kristian Pignat, Jacopo Vallotto, Francesco Pinna, 

and Giorgio Strukul 

5168-5173 

Substituted 1,4-Diaza-1,3-butadiene Monocyclopentadienyl Titanium 

Complexes. Crystal Structure of Ti( 5 -C5Me5)( 4 - i PrNCH=CHN i Pr)Me Francisco 

Amor, Pilar Gómez-Sal, Pascual Royo, and Jun Okuda 

5174-5181 

Pyridine Adducts of Chiral Arene Ruthenium Compounds. Diastereoselective 

Synthesis and Characterization J. W. Faller, Brian J. Grimmond, and Michael 

Curtis 

5182-5189 

A Combined Density Functional and Molecular Dynamics Study on Ethylene 

Insertion into the Cp2ZrEt-MeB(C6F5)3 Ion-Pair Mary S. W. Chan and Tom 

Ziegler 

5190-5201 

Synthesis, Molecular Structures, and Dynamics of Primary and Secondary 

Fluoroalkyl Complexes of Palladium(II) with Tetramethylethylenediamine 

(TMEDA) Ligands. Evaluation of the Structural trans-Influences of Methyl and 

Fluoroalkyl Groups as Ligands within the Same Coordination Sphere Russell P. 

Hughes, Jason S. Overby, Alex Williamson, Kin-Chung Lam, Thomas E. Concolino, 

and Arnold L. Rheingold 

5202-5208 

Synthesis and Characterization of Tris(trialkylphosphine)copper(I) 

trimethylsilylchalcogenolates Diem T. T. Tran and John F. Corrigan 

5209-5217 

-Coordination of Silver and Copper to Mercury Bis-alkynyls: Synthesis and 

Structural Characterization Daniela Rais, D. Michael P. Mingos, Ramón Vilar, 

Andrew J. P. White, and David J. Williams 

5218-5230

Alkene and Alkyne Reactivity over a Metal-Oxo Surface Modeled by Calix[4] 

arene-Tungsten(IV): Formation of 1-Metallacyclopropene and Alkylidene 

Complexes Geoffroy Guillemot, Euro Solari,and Carlo Floriani , Nazzareno 

ReCorrado Rizzoli 

NOTES 

5231-5234 

Preparation and First X-ray Structure of a Zirconocene -Keto Ester Enolate 

Thomas Stuhldreier, Helmut Keul, and Hartwig Höcker , Ulli Englert 

5235-5237 

Nonlinear Optical Properties of Redox-Active Mono-, Bi-, and Trimetallic - 

Acetylide Complexes Connected through a Phenyl Ring in the Cp*(dppe)Fe 

Series. An Example of Electro-switchable NLO Response Tania Weyland, Isabelle 

Ledoux, Sophie Brasselet, Joseph Zyss, and Claude Lapinte 

5238-5240 

Isolation of a Catenated Organotelluride Anion in the Sodium Borohydride 

Reduction of Diphenylditelluride Daniel Witthaut, Kristin Kirschbaum, Olaf 

Conrad, and Dean M. Giolando 

5241-5243 

Reaction of [(1-H-Hydronaphthalene)Mn(CO)3] with Pyridine in the Presence of 

Halogenated Solvent: The Role of Ring-Slippage in [(1-H-Hydronaphthalene)Mn 

(CO)3] Seung Uk Son, Kang Hyun Park, and Young Keun Chung 

5244-5246 

Oxidation Products of 1,2,3-Trithia[3]ferrocenophane: Structures of the 

Corresponding Sulfoxide and Sulfone Karin Hassenberg, Joachim Pickardt, and 

Ralf Steudel 

5247-5250 

Syntheses and X-ray Structures of (2,2'-Biphosphinine)-( 5 - 

pentamethylcyclopentadienyl)ruthenium(I) Dimer and Ruthenium(0) Complexes 

Patrick Rosa, Louis Ricard, François Mathey, and Pascal Le Floch


Volume 20, Issue 25 (December 10, 2001) 


5251-5253 

Direct Observation of the Conversion of a Palladium 5-Hexenyl Chelate Complex 

to a Palladium Cyclopentylmethyl Complex Nicholas S. Perch and Ross A. 

Widenhoefer 

5254-5256 

Synthesis and Reactivity of the Octahedral d 6 Parent Amido Complexes TpRu(L) 

(L')(NH2) (Tp = Hydridotris(pyrazolyl)borate; L = L' = PMe3, P(OMe)3; L = CO, 

L' = PPh3) and [TpRu(PPh3)(NH2)2][Li] K. N. Jayaprakash, David Conner, and T. 

Brent Gunnoe 

CORRESPONDENCE 

5257-5257 

Configurational Stability at Ruthenium Revisited Heather D. Hansen and John H. 

Nelson 

ARTICLES 

5258-5265 

Racemo-Selective Synthesis of ansa-Zirconocene Derivates from Zirconium 

Biphenolate Complexes Hans-Robert H. Damrau, Eva Royo, Stephan Obert, Frank 

Schaper, Armin Weeber, and Hans-Herbert Brintzinger 

5266-5276 

Bond Angle Effects on the Migratory Insertion of Ethylene and Carbon 

Monoxide into Palladium(II)-Methyl Bonds in Complexes Bearing Bidentate 

Phosphine Ligands John Ledford, C. Scott Shultz, Derek P. Gates, Peter S. White, 

Joseph M. DeSimone, and Maurice Brookhart 

5277-5288 

Ligand-Assisted Heterolytic Activation of Hydrogen and Silanes Mediated by 

Nitrosyl Rhenium Complexes Angela Llamazares, Helmut W. Schmalle, and Heinz 

Berke

5289-5296 

Synthesis and Reactions with Carbon Dioxide of Mono(-alkynyl) Titanocene(III) 

Complexes Cp*2Ti(C CR) (R = Me, t-Bu) and the Corresponding "Ate" 

Complexes [Cp*2Ti(C CR)2Li(THF)n] (R = SiMe3, t-Bu, Ph) Frank G. 

Kirchbauer, Paul-Michael Pellny, Hongsui Sun, Vladimir V. Burlakov, Perdita 

Arndt, Wolfgang Baumann, Anke Spannenberg, and Uwe Rosenthal 

5297-5309 

Synthesis and Characterization of Mixed-Phosphine Osmium Polyhydrides: 

Hydrogen Delocalization in [OsH5P3] + Systems Miguel A. Esteruelas, Agustí 

Lledós, Marta Martín, Feliu Maseras, Raquel Osés, Natividad Ruiz, and Jaume 

Tomàs 

5310-5313 

Reaction of Iodoform and Isopropyl Grignard Reagent Revisited Reinhard W. 

Hoffmann, Michael Müller, Karsten Menzel, Ruth Gschwind, Peter Schwerdtfeger, 

Olga L. Malkina, and Vladimir G. Malkin 

5314-5318 

A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis 

Catalysts Melanie S. Sanford, Jennifer A. Love, and Robert H. Grubbs 

5319-5325 

Syntheses, Structures, and Properties of Three Novel Coordination Polymers of 

Silver(I) Aromatic Carboxylates with Hexamethylenetetramine Exhibiting 

Unique Metal- Interaction Shao-Liang Zheng, Ming-Liang Tong, Song-De Tan, Yu 

Wang, Jian-Xin Shi, Ye-Xiang Tong, Hung Kay Lee, and Xiao-Ming Chen 

5326-5330 

Direct Platinum-Catalyzed Allylation of Anilines Using Allylic Alcohols Shyh- 

Chyun Yang, Yan-Chiu Tsai, and Yi-Jen Shue 

5331-5341 

Nanosized, Starlike Silicon Compounds. Synthesis and Optical Properties of Tris 

[(tert-butyldimethylsilyl)oligothienylenedimethylsilyl]methylsilanes Mitsuo 

Ishikawa, Hitoshi Teramura, Kyung Koo Lee, Wolfgang Schneider, Akinobu Naka, 

Hisayoshi Kobayashi, Yasuhiro Yamaguchi, Maki Kikugawa, Joji Ohshita, Atsutaka 

Kunai, Heqing Tang, Yutaka Harima, Tokio Yamabe, and Takae Takeuchi

5342-5350 

Dendrimer-Phosphine Complexes with Platinum(0) at the Core B. S. Balaji, 

Yasushi Obora, Daisuke Ohara, Shigehiro Koide, and Yasushi Tsuji 

5351-5359 

The Ruthenocenylmethylium Cation: Isolation and Structures of 5 - 

Cyclopentadienyl- 6 -fulvene-ruthenium(II) Salts Stephen Barlow, Andrew Cowley, 

Jennifer C. Green, Tim J. Brunker, and Tony Hascall 

5360-5368 

(-)-2-Menthylindenyl and (-)-2-Menthyl-4,7-dimethylindenyl Complexes of 

Rhodium, Iridium, Cobalt, and Molybdenum Herbert Schumann, Oleg Stenzel, 

Sebastian Dechert, and Frank Girgsdies , Ronald L. Halterman 

5369-5374 

Novel Chalcogenides of Silicon with Bicyclo[2.2.2]octane Skeletons, MeSi 

(SiMe2E)3MR (E = S, Se, Te; M = Si, Ge, Sn; R = Me, Ph) Uwe Herzog and Gerd 

Rheinwald 

5375-5393 

DFT Study of Ethylene Polymerization by Zirconocene-Boron Catalytic Systems. 

Effect of Counterion on the Kinetics and Mechanism of the Process Ilya E. 

Nifant'ev, Leila Yu. Ustynyuk, and Dmitri N. Laikov 

5394-5404 

Olefin Insertion into the Rhodium-Hydrogen Bond as the Step Determining the 

Regioselectivity of Rhodium-Catalyzed Hydroformylation of Vinyl Substrates: 

Comparison between Theoretical and Experimental Results Giuliano Alagona, 

Caterina Ghio, Raffaello Lazzaroni, and Roberta Settambolo 

5405-5412 

Synthesis and Characterization of Primary Cyclopentadienylphosphines and 

Cyclopentadienylarsines Saloua El Chaouch and Jean-Claude Guillemin , Tamás 

Kárpáti and Tamás Veszprémi 

5413-5418 

Synthesis of 1,2-Dihydro-1,2-azaborines and Their Conversion to Tricarbonyl 

Chromium and Molybdenum Complexes Arthur J. Ashe, III, Xiangdong Fang,

Xinggao Fang, and Jeff W. Kampf 

5419-5424 

Iron Aminocarbene Complexes Containing a Double C=C Bond in the N- 

Substituent: Preparation and Reactivity Libor Vyklick , Hana Dvo áková, and 

Dalimil Dvo ák 

5425-5431 

Pyridinecarboxamidato-Nickel(II) Complexes Bun Yeoul Lee, Xianhui Bu, and 

Guillermo C. Bazan 

5432-5439 

Regio- and Stereochemical Aspects of the Substitution Reaction between the 

Molybdenocene and Tungstenocene Dichlorides ( 5 -C5H4-R)2MCl2 (R = CMe3, 

SiMe3; M = Mo, W) and Metallophosphide Anions [(CO)5M'PPh2]Li (M' = Mo, 

W) Virginie Comte, Olivier Blacque, Marek M. Kubicki, and Claude Moïse 

5440-5445 

Dinuclear Trivalent and Mixed-Valence Uranium [(-CH2-)5]4-calix[4]tetrapyrrole 

Complexes with Short Intermetallic Distances Ilia Korobkov, Sandro Gambarotta, 

and Glenn P. A. Yap , Laurence Thompson , P. Jeffrey Hay 

5446-5454 

Binuclear Gold(I) and Mercury(II) Derivatives of Diethynylfluorenes Wai-Yeung 

Wong, Ka-Ho Choi, Guo-Liang Lu, Jian-Xin Shi, Pui-Yan Lai, and Sze-Man Chan , 

Zhenyang Lin 

5455-5463 

Reaction of Tp(PPh3)Ru( 2 -O2CCHPh2) with Carbene and Vinylidene Precursors 

Melanie S. Sanford, Michelle R. Valdez, and Robert H. Grubbs 

5464-5471 

Mechanism of the 3 - 1 - 3 Isomerization in Allylpalladium Complexes: Solvent 

Coordination, Ligand, and Substituent Effects Niclas Solin and Kálmán J. Szabó 

5472-5477 

Synthesis and Structural Investigation of Stable Zirconacyclopentanes Which 

Bear Additional Functional Groups Hongsui Sun, Vladimir V. Burlakov, Anke 

Spannenberg, Wolfgang Baumann, Perdita Arndt, and Uwe Rosenthal 

5478-5484 

Reactions of Carbaalanes with HBF4 and HCl: A 3-Bridging Fluorine Atom in

(AlEt)7(C=CHPh)2(CCH2Ph)3( 3-F) versus a Terminal Chlorine Atom in (AlMe)7 

(AlCl)(CCH2Ph)5H Werner Uhl, Frank Breher, and Bernhard Neumüller , Arne 

Lützen and Wolfgang Saak , Jörg Grunenberg 

NOTES 

5485-5488 

Tridentate Carbene CCC and CNC Pincer Palladium(II) Complexes: Structure, 

Fluxionality, and Catalytic Activity Stephan Gründemann, Martin Albrecht, 

Jennifer A. Loch, Jack W. Faller, and Robert H. Crabtree 

5489-5491 

Synthesis of the First Tris(pentamethylcyclopentadienyl) Hydride Complex, 

(C5Me5)3ThH William J. Evans, Gregory W. Nyce, and Joseph W. Ziller 

5492-5494 

Photochemical Cleavage of Pentamethylcyclopentadienyl-Gallium Bonds: An 

Alternative Approach to the Formation of Digallanes Thomas Pott, Peter Jutzi, 

Wolfgang W. Schoeller, Anja Stammler, and Hans-Georg Stammler


Volume 20, Issue 26 (December 24, 2001) 


5495-5497 

Multiple Tandem Catalysis: Facile Cycling between Hydrogenation and 

Metathesis Chemistry Samantha D. Drouin, Fojan Zamanian, and Deryn E. Fogg 

5498-5500 

Substituent Effects on Germanium-Germanium and Tin-Tin Triple Bonds 

Nozomi Takagi and Shigeru Nagase 

5501-5503 

Synthesis of New -Diketiminato Complexes of Scandium(III): Unprecedented 

Formation of a Multicyclic Aggregate Ana Mirela Neculai, Herbert W. Roesky, 

Dante Neculai, and Jörg Magull 

5504-5506 

Immobilization of a Catalytically Active Rhodium Complex by Electrostatic 

Interactions of Multiply Charged Phosphine Ligands with a Soluble 

Polyelectrolyte and Recovery by Ultrafiltration Ernst Schwab and Stefan Mecking 

5507-5509 

Synthesis and Structure of a Kinetically Stabilized 2-Germanaphthalene: The 

First Stable Neutral Germaaromatic Compound Norio Nakata, Nobuhiro Takeda, 

and Norihiro Tokitoh 

5510-5512 

Dramatic Influence on the Olefinic Geometry in the Nickel(0)-Catalyzed 

Coupling Reaction of 1,3-Dienes and Aldehydes Using N-Heterocyclic Carbene 

as a Ligand Yoshihiro Sato, Rieko Sawaki, and Miwako Mori 

5513-5514 

Synthesis and X-ray Crystal Structure Analysis of a Cp-Substituted 

Phosphaferrocene Gilles Frison, Louis Ricard, and François Mathey 

5515-5517 

Reactions of Zirconacyclopentadienes with Nitrosobenzene. Characterization of 

Zirconacycle Intermediates and Formation of N-Phenylpyrroles Masaaki 

Nakamoto and T. Don Tilley 

ARTICLES

5518-5521 

Synthesis, Characterization, and Properties of Silica-Supported 

Trimethylphosphine Disiloxy Tantalum Hydride, ( SiO)2TaH(PMe3) Mostafa 

Taoufik, Aimery de Mallmann, Eric Prouzet, Guillaume Saggio, Jean Thivolle-Cazat, 

and Jean-Marie Basset 

5522-5531 

Novel Methylpalladium(II) Complexes Bearing Tridentate Imidazole-Based 

Chelate Ligands: Synthesis, Structural Characterization, and Reactivity Thomas 

Rüther, Melanie C. Done, Kingsley J. Cavell, Evan J. Peacock, Brian W. Skelton, 

and Allan H. White 

5532-5536 

m-Terphenyl-Substituted Amidinates: Useful Ligands in the Preparation of 

Robust Aluminum Alkyls Deepa Abeysekera, Katherine N. Robertson, T. Stanley 

Cameron, and Jason A. C. Clyburne 

5537-5541 

Palladium-Catalyzed Double-Silylation Reactions of 3,4-Carboranylene-1,1,2,2tetraethyl-1,2-disilacyclobut-3-ene 

Kyu Ho Song, Il Jung, Shim Sung Lee, Ki-Min 

Park, Mitsuo Ishikawa, Sang Ook Kang, and Jaejung Ko 

5542-5546 

,-Bis(potassiosilyl)alkanes. Synthesis and Characterization of [K(18-crown-6)]2 

[(Me3Si)2Si(CH2)nSi(SiMe3)2] Jaime R. Blanton, Jonathan B. Diminnie, Tianniu 

Chen, Alicia M. Wiltz, and Ziling Xue 

5547-5556 

Chelating Aryloxide Ligands in the Synthesis of Titanium, Niobium, and 

Tantalum Compounds: Electrochemical Studies and Styrene Polymerization 

Activities Lucyna Michalczyk, 1a Susan de Gala, 1b and Joseph W. Bruno 1a 

5557-5563 

Single and Multiple Insertion of Alkynes into Pd-Acyl and Pd-Aryl Bonds in 

Cationic Palladium Complexes with Phosphine-Imine (P~N) Ligands K. Rajender 

Reddy, K. Surekha, Gene-Hsiang Lee, Shie-Ming Peng, and Shiuh-Tzung Liu 

5564-5570 

Reversible Interconversion between , 2 : 2 - and 3, 2 : 2 : 2 -C60 on a Carbido 

Pentaosmium Cluster Framework Kwangyeol Lee, Zel-Ho Choi, Youn-Jaung Cho, 

Hyunjoon Song, and Joon T. Park 

5571-5582

Synthesis of Homo- or Hetero-trinuclear Palladium(II)/Platinum(II) Compounds 

with Bridging Phosphido Ligands. Crystal and Electronic Structures (DFT) of [N 

(PPh3)2]2[Pt3( -PPh2)4(C6F5)4] and of Its Oxidation Product [Pt3(C6F5)4( -PPh2)4] 

Ester Alonso, José María Casas, Juan Forniés, Consuelo Fortuño, Antonio Martín, 

A. Guy Orpen, Constantinos A. Tsipis, and Athanassios C. Tsipis 

5583-5585 

Phenyltrichlorogermane Synthesis by the Reaction of Chlorobenzene and the 

Dichlorogermylene Intermediate Formed from Elemental Germanium and 

Tetrachlorogermane Masaki Okamoto, Takuya Asano, and Eiichi Suzuki 

5586-5590 

One-Step Synthesis of Fluorenyl-Substituted Chlorosilanes: Friedel-Crafts Type 

Cycloalkylation of Biphenyl with (Dichloroalkyl)silane Young-Sang Song, Seong 

Deok Kong, Shah Alam Khan, Bok Ryul Yoo, and Il Nam Jung 

5591-5597 

An Effective and Selective Route to 1,5-Dihydropolyalkylated s-Indacenes: 

Characterization of Their Mono- and Dianions by Silylation. Structure of trans- 

1,5-Bis(trimethylsilyl)-2,6-diethyl-4,8-dimethyl-s-indacene Mohamed R. 

Dahrouch, Paul Jara, Loreto Mendez, Yoany Portilla, Diana Abril, Geraldo Alfonso, 

Ivonne Chavez, and Juan M. Manriquez , Monique Rivière-Baudet, Pierre Rivière, 

Annie Castel, Jacques Rouzaud, and Heinz Gornitzka 

5598-5605 

Organolutetium Complexes in -Bond Metathesis Reactions Involving Silicon. 

Catalysts for the Hydrogenolysis of Si-C Bonds Ivan Castillo and T. Don Tilley 

5606-5613 

Theoretical Studies of Inorganic and Organometallic Reaction Mechanisms. 20. 

Carbon-Hydrogen and Carbon-Carbon Bond Activation of Cyclopropane by 

Cationic Iridium(III) and Neutral Rhodium(I) and Iridium(I) Complexes 

Charles Edwin Webster and Michael B. Hall 

5614-5618 

Ruthenium Carbene Complexes Containing a Triazolidene Cationic Ligand 

Alexandra Chaumonnot, Bruno Donnadieu, Sylviane Sabo-Etienne, Bruno Chaudret, 

Christophe Buron, Guy Bertrand, and Pascal Metivier 

5619-5628 

The Nature of Protonated Decamethylsilicocene, (Me5C5)2Si + H Thomas Müller, 

Peter Jutzi, and Torsten Kühler 

5629-5635

Versatile Coordination Behavior of Aryl-Substituted Phosphiniminate and 

Phosphoranate Anions: Synthesis and Structural Characterization of Lithium 

Complexes with 0 , 1 , and 6 -Arene Coordination Musa Said, Mark Thornton-Pett, 

and Manfred Bochmann 

5636-5641 

Activation of the Propargylic C-H Bond and Formation of the Unsaturated C3S2 

Five-Membered Rings on the RuSSRu Core Hiroyasu Sugiyama, Yoshihiro 

Moriya, and Kazuko Matsumoto 

5642-5647 

Crystal Structure of a Rigid Ferrocene-Based Macrocycle from High-Resolution 

X-ray Powder Diffraction Robert E. Dinnebier, Li Ding, Kuangbiao Ma, Markus A. 

Neumann, Noppawan Tanpipat, Frank J. J. Leusen, Peter W. Stephens, and Matthias 

Wagner 

5648-5652 

Reactivity of the Substituted Butadienes, Isoprene and Myrcene, with 

Decamethylsamarocene William J. Evans, Dimitrios G. Giarikos, Christopher B. 

Robledo, Voon S. Leong, and Joseph W. Ziller 

5653-5657 

Synthesis and Characterization of a Trigallacycle James D. Hoefelmeyer, Denise 

L. Brode, and François P. Gabbaï 

5658-5669 

Evaluation of Enantiomerically Pure Binaphthol-Based Molybdenum Catalysts 

for Asymmetric Olefin Metathesis Reactions that Contain 3,3'-Diphenyl- or 3,3'- 

Dimesityl-Substituted Binaphtholate Ligands. Generation and Decomposition of 

Unsubstituted Molybdacyclobutane Complexes W. C. Peter Tsang, Richard R. 

Schrock, and Amir H. Hoveyda 

5670-5674 

RuH3(SiCl2Me)(PPh3)3: A Trihydridosilylruthenium Complex with Three 

Nonclassical Ru-H· · · Si Interactions Nicholas M. Yardy and Frederick R. Lemke 

, Lee Brammer 

5675-5681 

Theoretical Studies on Solvent and Substituent Effects of Cuprate Conjugate 

Addition Masahiro Yamanaka and Eiichi Nakamura 

5682-5689 

Synthesis of Molybdenum and Tantalum Complexes that Contain

Diamido/Donor Ligands of the Type [(3,5-Cl2C6H3NCH2CH2)2NMe] 2- or [(3,5- 

Cl2C6H3NCH2)2C(2-C5H4N)(CH3)] 2- James P. Araujo, Denyce K. Wicht, Peter J. 

Bonitatebus, Jr., and Richard R. Schrock 

5690-5699 

Coordination of Carbon Monoxide and Isocyanides to Bis 

(pentamethylcyclopentadienyl)ytterbium and Related Bivalent Ytterbocenes 

Madeleine Schultz, Carol J. Burns, David J. Schwartz, and Richard A. Andersen 1 

5700-5706 

Insertion Reaction of Phenyl Isocyanate into the Ln-C -Bond of 

Organolanthanide Complexes: Synthesis, Characterization, and Crystal 

Structures of {(C5H4CH3)2Ln[ - 1 : 3 -OC(R)NPh]}2 (Ln = Sm, Dy, Er, Ho; R = nbutyl, 

-naphthyl) Xi-geng Zhou, Li-bei Zhang, Ming Zhu, Rui-fang Cai, and Linhong 

Weng , Zi-xiang Huang and Qiang-jin Wu 

5707-5716 

Direct Detection of Wiberg's Silene (1,1-Dimethyl-2,2-bis(trimethylsilyl)silene) 

and Absolute Rate Constants for Its Reactions in Solution Tracy L. Morkin and 

William J. Leigh , Thomas T. Tidwell and Annette D. Allen 

5717-5723 

Formation of Triniobocene Cationic and Neutral Mononiobocene Species as a 

Function of Solvent in the Reaction of Cp2Nb{( -H)2BR2} (R2 = C4H8, C5H10, 

C8H14) with B(C6F5)3 Shengming Liu, Fu-Chen Liu, Gordon Renkes, and Sheldon G. 

Shore 

5724-5730 

Theoretical Studies of Inorganic and Organometallic Reaction Mechanisms. 19. 

Substitution Reaction in Cyclopentadienyl Metal Dicarbonyls Hua-Jun Fan and 

Michael B. Hall 

5731-5737 

Synthesis, Structure, and Characterization of a Bridging Ethylidene 

(Perfluoroalkyl)phosphine Platinum Complex Shannon White, Eric W. Kalberer, 

Byron L. Bennett, and Dean M. Roddick 

5738-5744 

Iron Catalysts for the Head-to-Head Dimerization of -Olefins and Mechanistic 

Implications for the Production of Linear -Olefins Brooke L. Small and A. J. 

Marcucci 

5745-5750 

Rhodium-Catalyzed Activation and Functionalization of the C-C Bond of 

Biphenylene Carl N. Iverson and William D. Jones

5751-5758 

Lanthanide Carboxylate Precursors for Diene Polymerization Catalysis: 

Syntheses, Structures, and Reactivity with Et2AlCl William J. Evans, Dimitrios G. 

Giarikos, and Joseph W. Ziller 

5759-5768 

Density Functional Study on the Hydrido Migration to CO2 and CS2 of the ( 5 - 

C5H4(CH2)3NH3 + )MH(H2PCH2PH2) (M = Fe, Ru, and Os) Complexes Promoted 

by the Protonated Amine Arm. Which Path Does the Reaction Take, Abstraction 

or Insertion? Toshiaki Matsubara and Kazuyuki Hirao 

NOTES 

5769-5770 

Reductive Coupling of Carbonyl Compounds using Silole and Germole Dianions 

Yuxia Liu, David Ballweg, and Robert West 

5771-5773 

Metal-Metal Bond Opening Toward Main Group-Transition Element Rings 

Weng Kee Leong and Guizhu Chen 

5774-5776 

57 Fe NMR of Ferrocenes by 1 H- 57 Fe INEPT Techniques Bernd Wrackmeyer, Oleg 

L. Tok, and Max Herberhold 

5777-5779 

Synthesis and X-ray Crystal Structure of a Soluble Zinc Silicate Polyhedron, 

[(Me2NC6H4NMe2)ZnLi{O3Si(Me3Si)N(2,6-i-Pr2C6H3)}]4 Ganapathi 

Anantharaman, N. Dastagiri Reddy, Herbert W. Roesky, and Jörg Magull 

5780-5783 

Polymeric Chain Structures of Substituted (Dimethylfluorenylsilyl) 

cyclopentadienyl Lithium and Sodium Compounds Wanli Nie, Changtao Qian, 

Yaofeng Chen, and Jie Sun 

5784-5787 

A New Class of Planar-Chiral Ferrocenes: Serendipitous Formation of 1,2- 

Ferrocenediylazaphosphinines Geun-Ho Hwang, Eun-Sook Ryu, Dong-Kyu Park, 

Sang Chul Shim, Chan Sik Cho, and Tae-Jeong Kim , Jong Hwa Jeong , Minserk 

Cheong 

5788-5791 

Zirconium Complexes Containing Bidentate Pyrrole Ligands: Synthesis, 

Structural Characterization, and Ethylene Polymerization Jui-Hsien Huang, 

Liang-Sheng Chi, Ru-Ching Yu, George J. Jiang, Wei-Ta Yang, Gene-Hsiang Lee,

and Shie-Ming Peng

ORGANOMETALLLICS 

2002


Volume 21, Issue 1 (January 7, 2002) 


1-3 

Transformations of Aryl Isocyanide on Guanidinate-Supported 

Organozirconium Complexes To Yield Terminal Imido, Iminoacyl, and 

Enediamido Ligands Tiow-Gan Ong, Dayna Wood, Glenn P. A. Yap, and Darrin S. 

Richeson 

4-6 

Homogeneous Models for Chemically Tethered Silica-Supported Olefin 

Polymerization Catalysts John R. Severn, Robbert Duchateau, Rutger A. van 

Santen, Dianne D. Ellis, and Anthony L. Spek 

7-9 

Disparate Roles of Chiral Ligands and Molecularly Imprinted Cavities in 

Asymmetric Catalysis and Chiral Poisoning Jeong Hwan Koh, Andrew O. Larsen, 

Peter S. White, and Michel R. Gagné 

10-12 

Inorganic-Organic Hybrid Lamella of Di- and Tetranuclear Silver-Carbene 

Complexes C. K. Lee, K. M. Lee, and Ivan J. B. Lin 

13-15 

Chiral ansa-Titanocene Imido Complexes: Novel Synthesis and Effective 

Initiator for Syndiospecific Polymerization of MMA Jizhu Jin and Eugene Y.-X. 

Chen 

ARTICLES 

16-33 

Ligand and Solvent Effects in the Alternating Copolymerization of Carbon 

Monoxide and Olefins by Palladium-Diphosphine Catalysis Claudio Bianchini, 

Hon Man Lee, Andrea Meli, Werner Oberhauser, Maurizio Peruzzini, and Francesco 

Vizza 

34-38 

Mono- and Dinuclear Olefin Reactions at Aluminum Giovanni Talarico , Peter H. 

M. Budzelaar 

39-49 

Synthesis, Photophysical Properties, and Photoinduced Luminescence Switching 

of Trinuclear Diimine Rhenium(I) Tricarbonyl Complexes Linked by an 

Isomerizable Stilbene-like Ligand Shih-Sheng Sun and Alistair J. Lees

50-57 

Structural and Spectroscopic Study of the Dihydrogen Bond in an Imine 

Triosmium Complex S. Aime, E. Diana, R. Gobetto, M. Milanesio, E. Valls, and D. 

Viterbo 

58-67 

Synthesis and Reactivity toward Alkynes of 2-Formyl- and 2- 

Acetylarylpalladium(II) (Aryl = Phenyl and 5-Nitrophenyl) Complexes. 

Formation of Indenols and Indenones José Vicente, José-Antonio Abad, Begoña 

López-Peláez, and Eloísa Martínez-Viviente 

68-73 

Synthesis and Characterization of Allylic and Propargylic Selenols El Hassan 

Riague and Jean-Claude Guillemin 

74-82 

Immobilization of Bis(imino)pyridyliron(II) Complexes on Silica Franz A. R. 

Kaul, Gerd T. Puchta, Horst Schneider, Frank Bielert, Dimitrios Mihalios, and 

Wolfgang A. Herrmann 

83-92 

Toward the Identification of Dormant and Active Species in MAO 

(Methylaluminoxane)-Activated, Dimethylzirconocene-Catalyzed Olefin 

Polymerization Eva Zurek and Tom Ziegler 

93-104 

Synthesis and Reactivity of [Ir(C2H4)2Tpm Me2 ]PF6 (Tpm Me2 = Tris(3,5dimethylpyrazolyl)methane): 

Comparison with the Analogous Tp Me2 Derivatives 

(Tp Me2 = Hydrotris(3,5-dimethylpyrazolyl)borate) Itzia I. Padilla-Martínez, 

Manuel L. Poveda, and Ernesto Carmona , M. Angeles Monge and Caridad Ruiz- 

Valero 

105-112 

Structural Studies of an Array of Mixed Diamine Phosphine Ruthenium(II) 

Complexes 1 Christiane Nachtigal, Samer Al-Gharabli, Klaus Eichele, Ekkehard 

Lindner, and Hermann A. Mayer 

113-120 

Syntheses, Structures, and Sensory Characteristics of the Perfume Ingredient 

Majantol and Its Analogs Sila-majantol and Germa-majantol: A Study on 

C/Si/Ge Bioisosterism Reinhold Tacke, Thomas Schmid, Christian Burschka, Martin 

Penka, and Horst Surburg 

121-126

Ortho-Metalated Benzenethiolate Bridging Dinuclear Palladium(II) Complexes. 

X-ray Structures of [Sn2( -C6H4S)2( t Bu)4] and [Pd2( -C6H4S)( -dppm)2Cl2] 

Marta Cera, Elena Cerrada, Mariano Laguna, José A. Mata, and Helena Teruel 

127-131 

Observation of a Significantly Reduced 1 JC-H Coupling Constant in an Agostic f- 

Element Complex: X-ray Crystal Structure of (ArO)Sm[( -OAr)( -Me)AlMe2]2 

(Ar = 2,6-i-Pr2C6H3) John C. Gordon, 1a Garth R. Giesbrecht, 1b John T. Brady, 1a 

David L. Clark, 1c D. Webster Keogh, 1d Brian L. Scott, 1a and John G. Watkin 1a 

132-137 

Synthesis of Palladium Benzyl Complexes from the Reaction of PdCl2[P(OPh)3]2 

with Benzyl Bromide and Triethylamine: Important Intermediates in Catalytic 

Carbonylation Anna M. Trzeciak, Zbigniew Ciunik, and Józef J. Zió kowski 

138-143 

Intramolecular Coupling Reaction of 1-Aza-1,3-butadiene Ligand and Iminoacyl 

Ligand Giving Amido-Imido Complexes of Tantalum Yutaka Matsuo, Kazushi 

Mashima, and Kazuhide Tani 

144-149 

Synthesis of Verbenindenes: A New Class of Chiral Indenyl Ligands Derived 

from Verbenone Kenneth C. Rupert, Charles Chao Liu, Tam T. Nguyen, Mark A. 

Whitener, and John R. Sowa Jr. 

150-160 

Mechanistic Study on the Platinum-Catalyzed Reaction between 

Disilacyclobutene and Acetylene Song-Yun Kang, Tokio Yamabe, Akinobu Naka, 

Mitsuo Ishikawa, and Kazunari Yoshizawa 

161-170 

Effect of the Coordination to M(II) Metal Centers (M = Zn, Cd, Pt) on the 

Quadratic Hyperpolarizability of Various Substituted 5-X-1,10-phenanthrolines 

(X = Donor Group) and of trans-4-(Dimethylamino)-4'-stilbazole Dominique 

Roberto, Renato Ugo, Francesca Tessore, and Elena Lucenti , Silvio Quici and 

Stefano Vezza , PierCarlo Fantucci and Ivana Invernizzi , Silvia Bruni , Isabelle 

Ledoux-Rak and Joseph Zyss 

171-174 

Organopalladium Complex Promoted Asymmetric Hetero Diels-Alder Reactions 

between a Thiocarbonyl Dienophile and a Phospha-Substituted Cyclic Diene 

Ying Qin, 1a Andrew J. P. White, 1b David J. Williams, 1b and Pak-Hing Leung 1a 

175-181

Nickel(II) Heterocyclic Carbene Complexes as Catalysts for Olefin Dimerization 

in an Imidazolium Chloroaluminate Ionic Liquid David S. McGuinness, Wolfgang 

Mueller, Peter Wasserscheid, Kingsley J. Cavell, Brian W. Skelton, Allan H. White, 

and Ulli Englert 

182-191 

Calcium-Mediated Fulvene Couplings. 2. Survey of 6-Aryl- and 6-Alkylfulvenes 

for Their rac Selectivity in the Synthesis of ansa-Calcocenes Piet-Jan Sinnema, 

Britta Höhn, Robert L. Hubbard, Pamela J. Shapiro, Brendan Twamley, Alexander 

Blumenfeld, and Ashwani Vij 

192-202 

Hydrolysis of Bis((trimethylsilyl)methyl)tin Dihalides. Crystallographic and 

Spectroscopic Study of the Hydrolysis Pathway Jens Beckmann, Markus Henn, 

Klaus Jurkschat, and Markus Schürmann , Dainis Dakternieks and Andrew Duthie 

203-209 

Activation of Propargylic Alcohols Derived from Hormonal Steroids by the 

Indenyl-Ruthenium(II) Complex [RuCl( 5 -C9H7)(PPh3)2]: Experimental and 

Theoretical Evidence of an Allenylidene-Vinylvinylidene Equilibrium Victorio 

Cadierno, Salvador Conejero, M. Pilar Gamasa, and José Gimeno , Miguel A. 

Rodríguez 

210-219 

Rhodium and Iridium Phosphinothiolato Complexes. Synthesis and Crystal 

Structures of Mononuclear [M(cod)(S,P-SC2B10H10PPh2)] and Dinuclear [M2 

(CO)2(S,P- -SC2B10H10PPh2)] (M = Rh, Ir) and Their Performance in Catalytic 

Carbonylation Heung-Sae Lee, Jin-Young Bae, Dae-Hyun Kim, Hoon Sik Kim, 

Sung-Joon Kim, Sungil Cho, Jaejung Ko, and Sang Ook Kang 

220-225 

Lithiation of Diphenyl(triorganosilyl)methanes Michael S. Hill and Peter B. 

Hitchcock 

226-234 

Observation of Low-Energy Metal-Metal-to-Ligand Charge Transfer Absorption 

and Emission: Electronic Spectroscopy of Cyclometalated Platinum(II) 

Complexes with Isocyanide Ligands Siu-Wai Lai, Hiu-Wah Lam, Wei Lu, Kung- 

Kai Cheung, and Chi-Ming Che 

NOTES 

235-238 

Two-Dimensional Luminescent Rectangular Molecular Grids Containing Copper 

(I)-Olefin Bonds as Bridging Spacers Jing Zhang, Ren-Gen Xiong, Xue-Tai Chen,

Ziling Xue, Shie-Ming Peng, and Xiao-Zeng You 

239-242 

Reinvestigation of Nucleophilic Addition to the [(naphthalene)Mn(CO)3] + 

Cation: Hydrogen Migration in [(exo-R- 5 -C10H8)Mn(CO)3] Seung Uk Son, Se- 

Jung Paik, Kang Hyun Park, Young-A Lee, In Su Lee, and Young Keun Chung , D. A. 

Sweigart 

243-246 

Reactions of Perfluoroisopropyl Iodide with Cyclopentadienyl-Rhodium 

Complexes in Methanol. An Unexpected Route to a Rhodium-Fulvalene Complex 

Russell P. Hughes, Trang Le Husebo, Susan M. Maddock, Louise M. Liable-Sands, 

and Arnold L. Rheingold

ORGANOMETALLICS

Create successful ePaper yourself

Delete template?

Save as template?