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Technology Guide Principles – Applications – Trends - hhimawan

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which is one of the strongest permanent magnetic materials)<br />

but are very brittle. This is because chemical<br />

ordering within the intermetallic phases does not allow<br />

dislocations to move. Large intermetallic phase<br />

parts are frequently manufactured by the powder metallurgy<br />

method. In permanent magnets, the powder is<br />

compressed within a magnetic field in order to align<br />

the crystals orientation in a magnetic favourable direction.<br />

<strong>Trends</strong><br />

7 High-temperature alloys.<br />

The high-temperature<br />

properties of nickel-based superalloys seem to be limited<br />

by the melting point of nickel at 1455 °C. However,<br />

these materials can withstand considerable stresses at<br />

temperatures up to 1150 °C (over 80% of the melting<br />

temperature). Much research is being carried out to<br />

improve the temperature capabilities of these alloys.<br />

Academic researchers are talking about the 4. and<br />

5. generation of single-crystal nickel-based superalloys.<br />

Despite tremendous efforts, there is no other material<br />

in sight today that might be able to replace the<br />

nickel superalloys within the next 10<strong>–</strong>20 years. This is<br />

because these alloys have very well balanced properties,<br />

which include ductility at all temperature levels,<br />

combined with high strength at high temperatures.<br />

These alloys also possess fairly good oxidation and fatigue<br />

resistance. Special technical ceramics, alloys<br />

based on platinum group metals (Pt, Rh, Ir), and other<br />

high melting point systems such as Mo-Si are currently<br />

under intensive investigation.<br />

Another strategy for optimising the development<br />

of high-temperature alloys is to reduce density and<br />

production costs by keeping the high-temperature<br />

strength at that level. This allows the overall weight of<br />

the system to be significantly reduced by decreasing<br />

the size of other load bearing parts. This is of specific<br />

interest for moving or rotating parts as the rotating<br />

speed can be considerably increased by using lowerweight<br />

rotating parts.<br />

These two optimisation strategies seem to point in<br />

opposite directions, but both result in a comparable<br />

technological improvement. Though at first sight apparently<br />

different, both optimisation routes can be<br />

found in practically all alloy developments based on a<br />

specific application.<br />

Prospects<br />

5 Cost is an extremely important overall material<br />

factor. Steels in particular can be produced in huge<br />

quantities using low-cost production, forming and<br />

molding processes. Steel will continue to make up<br />

temperature [°C]<br />

5<br />

5<br />

5<br />

2000<br />

1500<br />

1000<br />

500<br />

steels<br />

a large part of car bodies in the near to medium<br />

term, as well as <strong>–</strong> of course <strong>–</strong> being used as a<br />

construction material. Particularly in view of the<br />

increasing cost and shortages of raw materials, the<br />

use of metals is becoming more widespread due to<br />

cost considerations and very efficient recycling<br />

possibilities.<br />

The demand for light metals and high-temperature<br />

metals to increase efficiency and reduce ecological<br />

impact will go on increasing as long as man is technologically<br />

minded. This applies to all kinds of<br />

transportation systems from bicycles to airplanes<br />

and energy production.<br />

Researchers are currently striving to develop leadfree<br />

solder alloys.<br />

Rare earth and precious metals are very expensive<br />

and only available in limited quantities, but are essential<br />

and often not replaceable in many hightech<br />

applications (e. g. energy-efficient lamps).<br />

Prof. Dr. Uwe Glatzel<br />

Dr. Rainer Völkl<br />

Universitiy of Bayreuth<br />

cross-section of a hollow turbine blade<br />

gas temperature in military aircraft turbine engines<br />

material temperature in civil aircraft turbine engines<br />

polycrystalline<br />

nickel-based superalloys<br />

directional solidified<br />

nickel-based<br />

superalloys<br />

gas temperature in civil aircraft turbine engines<br />

improvement by<br />

blade cooling<br />

improvement<br />

by materials<br />

~5-10 K /year<br />

single crystal<br />

nickel-based superalloys<br />

Internet<br />

5<br />

5<br />

5<br />

5<br />

www.worldsteel.org<br />

www.matweb.com<br />

www.tms.org<br />

www.mrs.org<br />

material beyond<br />

nickel-based<br />

superalloys<br />

1950 1960 1970 1980 1990 2000 2010 2020<br />

year<br />

� Increase in combustion gas temperature of aircraft turbine engines<br />

over several decades <strong>–</strong> the efficiency of a turbine is closely<br />

related to the gas temperature. After the Second World War, hightemperature<br />

iron alloys with an upper limit of about 700 °C were<br />

state­of­the­art materials. Nickel­based superalloys replaced iron<br />

alloys in the 1950s and are still the material of choice today. Leaps<br />

in technology meant that hollow turbine blades could be cast in<br />

increasingly sophisticated designs, improving cooling efficiency.<br />

Specifically designed nickel­based superalloys and adapted casting<br />

technologies enabled the change to be made from polycrystalline,<br />

to directionally solidified, to single­crystal turbine blades.<br />

The gas temperature was increased by omitting the detrimental<br />

interfaces between crystallites in single crystals. Due to the strong<br />

safety standards in civilian aircraft engines, nickel­based superalloys<br />

will not be replaced by ceramics in future. But insulation by a<br />

thick ceramic layer is and will be of increasing importance.<br />

13

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