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Chapter 15: Solutions - Weironline.net

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Objectives<br />

Section <strong>15</strong>.2 Solution Concentration<br />

• State the concentrations of<br />

solutions in different ways.<br />

• Calculate the concentrations<br />

of solutions.<br />

Vocabulary<br />

concentration<br />

molarity<br />

molality<br />

mole fraction<br />

Table <strong>15</strong>-3<br />

Figure <strong>15</strong>-11<br />

The strength of the tea corresponds<br />

to its concentration. The<br />

darker cup of tea is more<br />

concentrated than the<br />

lighter cup.<br />

462 <strong>Chapter</strong> <strong>15</strong> <strong>Solutions</strong><br />

You have learned about the process of solvation and the factors that affect<br />

solubility. The concentration of a solution is a measure of how much solute<br />

is dissolved in a specific amount of solvent or solution. How would you<br />

describe the concentration of the solutions in Figure <strong>15</strong>-11? Concentration<br />

may be described qualitatively using the words concentrated or dilute. In general,<br />

a concentrated solution, as shown on the left in Figure <strong>15</strong>-11, contains<br />

a large amount of solute. Conversely, a dilute solution contains a small amount<br />

of solute. How do you know that the tea on the right in Figure <strong>15</strong>-11 is a more<br />

dilute solution than the tea on the left?<br />

Expressing Concentration<br />

Although qualitative descriptions of concentration can be useful, solutions are<br />

more often described quantitatively. Some commonly used quantitative<br />

descriptions are percent by either mass or volume, molarity, and molality.<br />

These descriptions express concentration as a ratio of measured amounts of<br />

solute and solvent or solution. Table <strong>15</strong>-3 lists each ratio’s description.<br />

You may be wondering if one<br />

Concentration Ratios<br />

Concentration description Ratio<br />

Percent by mass �<br />

mass<br />

of<br />

�<br />

solute<br />

� 100<br />

mass<br />

of<br />

solution<br />

volume of solute<br />

Percent by volume ��� � 100<br />

volume of solution<br />

Molarity �<br />

moles<br />

o<br />

�<br />

f solute<br />

liter<br />

of<br />

solution<br />

Molality<br />

Mole fraction<br />

moles of solute<br />

���<br />

kilogram of solvent<br />

�����<br />

moles of solute<br />

moles of solute � moles of solvent<br />

description is preferable to another.<br />

The description used depends on<br />

the type of solution analyzed and<br />

the reason for describing it. For<br />

example, a chemist working with a<br />

reaction in an aqueous solution<br />

most likely refers to the molarity<br />

of the solution, because he or she<br />

needs to know the number of particles<br />

involved in the reaction.

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