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Prezentacija predavanja [31,35 MiB]

Prezentacija predavanja [31,35 MiB]

Prezentacija predavanja [31,35 MiB]

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Fluorodimetilaluminij postoji kao tetramer Me 2AlF 4.<br />

Tetrakoordinirani aluminij postoji i u alkoksidima i<br />

amino-derivatima nastalim reakcijom Me 3Al s<br />

alkoholima ili aminima.<br />

Me<br />

1<strong>31</strong>,2o<br />

Me<br />

Me Me<br />

F<br />

Al<br />

1,947<br />

Al<br />

146,1o<br />

92,3o<br />

F<br />

F<br />

Me<br />

Al<br />

Al<br />

Me<br />

F<br />

Me<br />

Me<br />

Ph<br />

Ph<br />

Al<br />

N<br />

Ph<br />

Ph<br />

a) b)<br />

N<br />

N<br />

Ph<br />

Al N<br />

Tetramer tipa kubana [PhAlNPh] 4 nastaje reakcijom<br />

Ph 3Al s arilaminima pri povišenim temperaturama.<br />

Al<br />

Ph<br />

Al<br />

Ph<br />

Ph

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