ALINOC® INOCULANT - Elkem
ALINOC® INOCULANT - Elkem
ALINOC® INOCULANT - Elkem
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ALINOC ® <strong>INOCULANT</strong><br />
ISO 9001 ISO 14001 ISO/TS 16949
ALINOC ® <strong>INOCULANT</strong><br />
n More potent than conventional Cabearing inoculants<br />
n More cost effective than other Cabearing inoculants<br />
n Potent ferrite promoting inoculant in ductile iron<br />
n Can be used in both grey and ductile irons<br />
n Very effective preconditioner in low Al grey iron<br />
n High Si inoculants are more effective than low Si inoculants<br />
Alinoc ® inoculants are 67 – 75% Si<br />
based ferroalloys with defined levels of<br />
alu minium and calcium. The in oculant<br />
has a silver grey crystalline appearance<br />
and is especially developed for<br />
inoculation of ferritic ductile iron.<br />
Alinoc ® inoculant is produced at<br />
the <strong>Elkem</strong> Bremanger plant in Norway<br />
and the <strong>Elkem</strong> Chicoutimi plant<br />
in Canada, using special pro duction<br />
methods to ensure maximum uniformity<br />
of compo sition and structure<br />
throughout the product. Both <strong>Elkem</strong><br />
plants have ISO 9001 and ISO 14001<br />
accreditations, in addition to ISO/TS<br />
16949 certificate for <strong>Elkem</strong> Bremanger.<br />
Ferrosilicon alloys that contain<br />
ele ments such as calcium and alu<br />
minium have complex structures<br />
consisting of a number of inter me tallic<br />
compounds. The solidifi cation temperatures<br />
of these compounds vary and<br />
this can lead to extensive segregation<br />
if the alloy is allowed to cool slowly<br />
during casting. Because some of<br />
these compounds are more brittle<br />
and crush more readily, this can lead<br />
Alinoc ® inoculants are produced to the<br />
following chemical specifications:<br />
Production of Alinoc ® Inoculant<br />
to wide variations in compositions of<br />
different particle sizes after crushing<br />
and grading.<br />
At the <strong>Elkem</strong> Bremanger and Chicoutimi<br />
plants, Alinoc ® inocu lant is cast<br />
into thin slabs in iron moulds. This pro<br />
duces a very fine structure and avoids<br />
any risk of segre gation occurring<br />
during solidification. The composition<br />
of Alinoc ® inoculant is therefore consistent<br />
over the entire range of particle<br />
sizes. The phase composition is shown<br />
in Figure 1.<br />
Alinoc ® Alinoc ® 75<br />
Silicon 64 – 70% 70 – 75%<br />
Aluminium 3.5 – 4.5%<br />
Calcium 0.5 – 1.5%<br />
Iron Balance<br />
Si FeSi CaAl Si FeAl Si 2<br />
2 2<br />
3 2<br />
Figure 1: Typical phases in Alinoc ® inoculant.<br />
Alinoc ® is a registered trademark of <strong>Elkem</strong> AS.
Advantages of Alinoc ® Inoculant<br />
Alinoc ® inoculant is a very effective<br />
addition for ductile iron and is especially<br />
potent when used on ferritic<br />
and the mixed ferrite/pearlite grades.<br />
Alinoc ® inoculant may be used both<br />
as ladle and as stream inoculant.<br />
Compared to conventional Ca bearing<br />
inoculants Alinoc ® inocu lant is normally<br />
applied at a reduced addition rate.<br />
Where a two step inoculation is applied,<br />
Alinoc ® inoculant can be used in both<br />
stages with excellent results. In grey<br />
iron it is also possible to combine<br />
Alinoc ® inoculant with Sr bearing<br />
inoculants as a two stage addition<br />
where Alinoc ® inoculant should only<br />
be used as first step inoculant.<br />
Alinoc ® inoculant can be used as a<br />
preconditioner in grey iron and can<br />
also be used to adjust the Al content<br />
of the base iron. Compared to Foundry<br />
Grade FeSi (FG FeSi) the addition rate<br />
can normally be reduced by 10 – 50%.<br />
The example in Figure 2 shows two<br />
samples inoculated with Alinoc ® inoculant<br />
and a Zrcon taining inoculant<br />
cast from the same base metal.<br />
Data from automatic image analysis<br />
for the two samples is presented in<br />
Table 1. These results show that there<br />
is a significant difference in ferrite<br />
content between the two samples.<br />
Figure 2: Comparison of ferrite content between Alinoc ® inoculant (top) and Zr-<br />
containing inoculant (bottom) under equal conditions. Polished (left) and etched<br />
(right). Addition rate 0.3%.<br />
Table 1: Data from automatic image analysis.<br />
Nodule Count N/mm 2<br />
Nodularity [%]<br />
Graphite [%]<br />
Pearlite [%]<br />
Alinoc ® inoculant Zr-containing inoculant<br />
356<br />
90<br />
10<br />
8<br />
335<br />
89<br />
9<br />
15
Case Study<br />
The foundry produces about 10.000<br />
tons of ductile iron castings per year.<br />
They have induction melting and the<br />
iron is treated with pure Mg. Inoculation<br />
is done in two steps using Alinoc ®<br />
inoculant in both. Figure 3 shows the<br />
typical highly ferrritic microstructure in<br />
a grade 400/18 iron.<br />
Application of Alinoc ® Inoculant<br />
Alinoc ® inoculant can be used as ladle<br />
and stream inoculant in both grey and<br />
ductile irons. Addition in the ladle will,<br />
for grey iron normally be 0.2 – 0.3%<br />
and for ductile iron 0.3 – 0.5%. When<br />
Physical Data<br />
Apparent Density 3.1– 3.7 g/cm 3<br />
Bulk Density 1.75 – 2.0 g/cm 3<br />
Melting Range 1300 –1325 °C (liq)<br />
1208 °C (sol)<br />
Figure 3: Microstructure obtained in 30 mm section using Alinoc® inoculant in<br />
a two step inoculation. Polished (left) and etched (right).<br />
added to the stream the addition rate<br />
will be 0.05 – 0.15% in grey iron and<br />
0.1– 0.25% in ductile iron. Used<br />
as a preconditioner, the normal<br />
addition rate will be between<br />
Standard Sizes<br />
In-stream/MSI 0.2 – 0.7 mm<br />
Small Ladle 0.7 – 2 mm<br />
Larger Ladle 2 – 6 mm<br />
0.1 – 0.5% depending on the initial Al<br />
level in the base iron.<br />
Standard Packing<br />
Big Bag 1050 kg on pallet<br />
Big Bag 1500 kg on pallet<br />
Big Bag 500 kg on pallet<br />
Paper Bag 25 kg on pallet<br />
Steel Drum 200 and 220 kg<br />
<strong>Elkem</strong> AS<br />
Foundry Products<br />
Hoffsveien 65B<br />
P.O. Box 5211<br />
Majorstuen<br />
N-0303, Oslo, Norway<br />
Telephone : +47 22 45 01 00<br />
Telefax : +47 22 45 01 52<br />
www.foundry.elkem.com Revised April 2012 © Copyright <strong>Elkem</strong> AS