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ALINOC® INOCULANT - Elkem

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ALINOC ® <strong>INOCULANT</strong><br />

ISO 9001 ISO 14001 ISO/TS 16949


ALINOC ® <strong>INOCULANT</strong><br />

n More potent than conventional Ca­bearing inoculants<br />

n More cost effective than other Ca­bearing inoculants<br />

n Potent ferrite promoting inoculant in ductile iron<br />

n Can be used in both grey and ductile irons<br />

n Very effective preconditioner in low Al grey iron<br />

n High Si inoculants are more effective than low Si inoculants<br />

Alinoc ® inoculants are 67 – 75% Si<br />

based ferroalloys with defined levels of<br />

alu minium and calcium. The in oculant<br />

has a silver grey crystalline appearance<br />

and is especially developed for<br />

inoculation of ferritic ductile iron.<br />

Alinoc ® inoculant is produced at<br />

the <strong>Elkem</strong> Bremanger plant in Norway<br />

and the <strong>Elkem</strong> Chicoutimi plant<br />

in Canada, using special pro duction<br />

methods to ensure maximum uniformity<br />

of compo sition and structure<br />

throughout the product. Both <strong>Elkem</strong><br />

plants have ISO 9001 and ISO 14001<br />

accreditations, in addition to ISO/TS<br />

16949 certificate for <strong>Elkem</strong> Bremanger.<br />

Ferrosilicon alloys that contain<br />

ele ments such as calcium and alu­<br />

minium have complex structures<br />

consisting of a number of inter me tallic<br />

compounds. The solidifi cation temperatures<br />

of these compounds vary and<br />

this can lead to extensive segregation<br />

if the alloy is allowed to cool slowly<br />

during casting. Because some of<br />

these compounds are more brittle<br />

and crush more readily, this can lead<br />

Alinoc ® inoculants are produced to the<br />

following chemical specifications:<br />

Production of Alinoc ® Inoculant<br />

to wide variations in compositions of<br />

different particle sizes after crushing<br />

and grading.<br />

At the <strong>Elkem</strong> Bremanger and Chicoutimi<br />

plants, Alinoc ® inocu lant is cast<br />

into thin slabs in iron moulds. This pro­<br />

duces a very fine structure and avoids<br />

any risk of segre gation occurring<br />

during solidification. The composition<br />

of Alinoc ® inoculant is therefore consistent<br />

over the entire range of particle<br />

sizes. The phase composition is shown<br />

in Figure 1.<br />

Alinoc ® Alinoc ® 75<br />

Silicon 64 – 70% 70 – 75%<br />

Aluminium 3.5 – 4.5%<br />

Calcium 0.5 – 1.5%<br />

Iron Balance<br />

Si FeSi CaAl Si FeAl Si 2<br />

2 2<br />

3 2<br />

Figure 1: Typical phases in Alinoc ® inoculant.<br />

Alinoc ® is a registered trademark of <strong>Elkem</strong> AS.


Advantages of Alinoc ® Inoculant<br />

Alinoc ® inoculant is a very effective<br />

addition for ductile iron and is especially<br />

potent when used on ferritic<br />

and the mixed ferrite/pearlite grades.<br />

Alinoc ® inoculant may be used both<br />

as ladle and as stream inoculant.<br />

Compared to conventional Ca bearing<br />

inoculants Alinoc ® inocu lant is normally<br />

applied at a reduced addition rate.<br />

Where a two step inoculation is applied,<br />

Alinoc ® inoculant can be used in both<br />

stages with excellent results. In grey<br />

iron it is also possible to combine<br />

Alinoc ® inoculant with Sr bearing<br />

inoculants as a two stage addition<br />

where Alinoc ® inoculant should only<br />

be used as first step inoculant.<br />

Alinoc ® inoculant can be used as a<br />

preconditioner in grey iron and can<br />

also be used to adjust the Al content<br />

of the base iron. Compared to Foundry<br />

Grade FeSi (FG FeSi) the addition rate<br />

can normally be reduced by 10 – 50%.<br />

The example in Figure 2 shows two<br />

samples inoculated with Alinoc ® inoculant<br />

and a Zr­con taining inoculant<br />

cast from the same base metal.<br />

Data from automatic image analysis<br />

for the two samples is presented in<br />

Table 1. These results show that there<br />

is a significant difference in ferrite<br />

content between the two samples.<br />

Figure 2: Comparison of ferrite content between Alinoc ® inoculant (top) and Zr-<br />

containing inoculant (bottom) under equal conditions. Polished (left) and etched<br />

(right). Addition rate 0.3%.<br />

Table 1: Data from automatic image analysis.<br />

Nodule Count N/mm 2<br />

Nodularity [%]<br />

Graphite [%]<br />

Pearlite [%]<br />

Alinoc ® inoculant Zr-containing inoculant<br />

356<br />

90<br />

10<br />

8<br />

335<br />

89<br />

9<br />

15


Case Study<br />

The foundry produces about 10.000<br />

tons of ductile iron castings per year.<br />

They have induction melting and the<br />

iron is treated with pure Mg. Inoculation<br />

is done in two steps using Alinoc ®<br />

inoculant in both. Figure 3 shows the<br />

typical highly ferrritic microstructure in<br />

a grade 400/18 iron.<br />

Application of Alinoc ® Inoculant<br />

Alinoc ® inoculant can be used as ladle<br />

and stream inoculant in both grey and<br />

ductile irons. Addition in the ladle will,<br />

for grey iron normally be 0.2 – 0.3%<br />

and for ductile iron 0.3 – 0.5%. When<br />

Physical Data<br />

Apparent Density 3.1– 3.7 g/cm 3<br />

Bulk Density 1.75 – 2.0 g/cm 3<br />

Melting Range 1300 –1325 °C (liq)<br />

1208 °C (sol)<br />

Figure 3: Microstructure obtained in 30 mm section using Alinoc® inoculant in<br />

a two step inoculation. Polished (left) and etched (right).<br />

added to the stream the addition rate<br />

will be 0.05 – 0.15% in grey iron and<br />

0.1– 0.25% in ductile iron. Used<br />

as a preconditioner, the normal<br />

addition rate will be between<br />

Standard Sizes<br />

In-stream/MSI 0.2 – 0.7 mm<br />

Small Ladle 0.7 – 2 mm<br />

Larger Ladle 2 – 6 mm<br />

0.1 – 0.5% depending on the initial Al<br />

level in the base iron.<br />

Standard Packing<br />

Big Bag 1050 kg on pallet<br />

Big Bag 1500 kg on pallet<br />

Big Bag 500 kg on pallet<br />

Paper Bag 25 kg on pallet<br />

Steel Drum 200 and 220 kg<br />

<strong>Elkem</strong> AS<br />

Foundry Products<br />

Hoffsveien 65B<br />

P.O. Box 5211<br />

Majorstuen<br />

N-0303, Oslo, Norway<br />

Telephone : +47 22 45 01 00<br />

Telefax : +47 22 45 01 52<br />

www.foundry.elkem.com Revised April 2012 © Copyright <strong>Elkem</strong> AS

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