04.04.2013 Views

Metamorphic Facies and Metamafic

Metamorphic Facies and Metamafic

Metamorphic Facies and Metamafic

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

<strong>Metamorphic</strong> <strong>Facies</strong> <strong>and</strong> <strong>Metamafic</strong><br />

rocks k (Chapter 25)<br />

Blueschist – Catalina Isl<strong>and</strong>, CA. Image: Darrell Henry


<strong>Metamorphic</strong> <strong>Facies</strong> Concept<br />

Pentii Eskola (1914) Orijärvi region of southern Finl<strong>and</strong><br />

Rocks with K-feldspar + cordierite at Oslo<br />

contained the compositionally p yequivalent q pair p<br />

biotite + muscovite at Orijärvi<br />

• Eskola: difference must reflect differing<br />

physical conditions between the regions<br />

• Concluded that Finnish rocks equilibrated<br />

at llower temperatures <strong>and</strong> dhi higher h pressures<br />

than Norwegian ones<br />

Eskola (1915) developed the concept of metamorphic facies:<br />

"In any rock or metamorphic formation which has arrived at a chemical<br />

equilibrium q through g metamorphism p at constant temperature p <strong>and</strong> ppressure<br />

conditions, the mineral composition is controlled only by the chemical<br />

composition. We are led to a general conception which the writer proposes to call<br />

metamorphic facies."


<strong>Metamorphic</strong> <strong>Facies</strong> Concept<br />

Dual basis for the facies concept<br />

Descriptive: relationship between rock composition <strong>and</strong> its<br />

mineralogy<br />

• A metamorphic facies is set of repeatedly associated<br />

metamorphic mineral assemblages<br />

• If we find specified assemblage or group of compatible<br />

assemblages covering range of compositions in the field, then a<br />

certain ti facies f i may bbe assigned i dtto th the area<br />

Interpretive: range of T <strong>and</strong> P conditions represented by each facies<br />

• Eskola was aware of T-P implications of concept <strong>and</strong> correctly<br />

deduced the relative T <strong>and</strong> P represented by different facies<br />

W i l i l T dP li i<br />

• We can now assign relatively accurate T <strong>and</strong> Pe limits to<br />

individual facies


<strong>Metamorphic</strong> <strong>Facies</strong> Concept<br />

Defined on the basis of mineral assemblages that develop<br />

in mafic rocks<br />

Image: Winter (2001)<br />

Eskola (1920) proposed 5<br />

original facies:<br />

• Greenschist<br />

• Amphibolite<br />

• Hornfels<br />

• Sanidinite<br />

• Eclogite<br />

Eskola (1939) added<br />

• Granulite<br />

• Epidote-amphibolite<br />

• Blueschist<br />

Later additions<br />

• Zeolite<br />

• Prehnite-pumpellyite<br />

• Albite-epidote hornfels<br />

• Hornblende hornfels


<strong>Metamorphic</strong> <strong>Facies</strong> Concept<br />

Defined on the basis of mineral assemblages that develop<br />

in mafic rocks<br />

IUGS IUGS-SCMR SCMR version of<br />

facies diagram<br />

Image: IUCS-SCMR (2007)


<strong>Metamorphic</strong> <strong>Facies</strong> Concept<br />

Defined on the basis of mineral assemblages that develop<br />

in mafic rocks<br />

Table 25-1. Definitive Mineral Assemblages of <strong>Metamorphic</strong> <strong>Facies</strong><br />

<strong>Facies</strong> Definitive Mineral Assemblage in Mafic Rocks<br />

Zeolite zeolites: especially laumontite, wairakite, analcime<br />

Prehnite-Pumpellyite prehnite + pumpellyite (+ chlorite + albite)<br />

Greenschist chlorite + albite + epidote (or zoisite) + quartz ± actinolite<br />

Amphibolite hornblende + plagioclase (oligoclase-<strong>and</strong>esine) ± garnet<br />

Granulite orthopyroxene (+ clinopyrixene + plagioclase ± garnet ±<br />

hornblende)<br />

Blueschist glaucophane + lawsonite or epidote (+albite ± chlorite)<br />

Eclogite pyrope garnet + omphacitic pyroxene (± kyanite)<br />

Contact <strong>Facies</strong><br />

After Spear (1993)<br />

Mineral assemblages in mafic rocks of the facies of contact metamorphism<br />

do not differ substantially from that of the corresponding<br />

regional facies at higher pressure.


<strong>Metamorphic</strong> <strong>Facies</strong> Concept<br />

<strong>Metamorphic</strong> field gradient - array of peak metamorphic (max T)<br />

experienced in a metamorphic terrain<br />

Typical<br />

Barrovian-type<br />

metamorphic<br />

field gradient<br />

<strong>and</strong> a series of<br />

metamorphic P-<br />

T-t paths for<br />

rocks found<br />

along that<br />

gradient in<br />

fi field. ld<br />

Image: Winter (2001)


<strong>Metamorphic</strong> <strong>Facies</strong> Concept<br />

<strong>Metamorphic</strong> field gradient<br />

Image: Winter (2001)<br />

<strong>Metamorphic</strong> field<br />

gradients<br />

(estimated PP-T T<br />

conditions along<br />

surface traverses<br />

directly y up p<br />

metamorphic<br />

grade) for several<br />

metamorphic<br />

areas.


<strong>Metamorphic</strong> <strong>Facies</strong> Concept<br />

<strong>Metamorphic</strong> series<br />

Image: Winter (2001)<br />

Miyashiro (1961) initially<br />

proposed five facies series,<br />

most of them named for a<br />

specific representative "type<br />

locality" The series were:<br />

1. Contact <strong>Facies</strong> Series (very<br />

low-P)<br />

22. Buchan or Abukuma <strong>Facies</strong><br />

Series (low-P regional)<br />

3. Barrovian <strong>Facies</strong> Series<br />

(medium (medium-P P regional)<br />

4. Sanbagawa <strong>Facies</strong> Series<br />

(high-P, moderate-T)<br />

5. Franciscan <strong>Facies</strong> Series<br />

(high-P, low T)


Metamorphism of Mafic Rocks<br />

Mineral changes <strong>and</strong> associations that develop with increasing<br />

metamorphic grade<br />

• Hydrous minerals are not common in high-<br />

T igneous mafic protolith, so hydration is a<br />

prerequisite for development of<br />

metamorphic mineral assemblages that<br />

characterize most facies<br />

• Unless water is available, mafic igneous<br />

rocks will remain largely unaffected in<br />

metamorphic terranes, even as associated<br />

sediments are completely re re-equilibrated<br />

equilibrated<br />

• Coarse-grained intrusives are least<br />

permeable, <strong>and</strong> thus most likely to resist<br />

metamorphic changes, while tuffs <strong>and</strong><br />

graywackes are most susceptible


Metamorphism of Mafic Rocks<br />

Mineral changes <strong>and</strong> associations that develop with increasing<br />

metamorphic grade<br />

Plagioclase<br />

• As T is lowered, lo ered the more Ca-rich Ca rich plagioclases become<br />

progressively unstable<br />

• There eeis sa general gee correlation co e o between beweeT <strong>and</strong> dmaximum u An-<br />

content of stable plagioclase<br />

• At low metamorphic grades only albite (An0-3) is stable<br />

• IIn upper-greenschist hi ffacies i oligoclase li l bbecomes stable. bl<br />

• Andesine(~An40) <strong>and</strong> more calcic plagioclases are stable in upper<br />

amphibolite <strong>and</strong> granulite facies<br />

• Excess Ca <strong>and</strong> Al released may released from calcite, calcite an epidote mineral, mineral<br />

titanite, or amphibole, etc., depending on P-T-X<br />

Clinopyroxene breaks down to a number of mafic minerals,<br />

depending on grade. These include chlorite, actinolite, hornblende, epidote,<br />

a metamorphic pyroxene, etc., <strong>and</strong> the one(s) that form are commonly<br />

diagnostic of the grade <strong>and</strong> facies


Metamorphism of Mafic Rocks<br />

Stilbite on basalt (Poona, India). Image: Darrell<br />

Henry (2007)<br />

Mafic Assemblages at Low Grades<br />

Zeolite <strong>and</strong> prehnite-pumpellyite facies<br />

• DDo not talways l ddevelop l - ttypically i ll<br />

require unstable protolith<br />

• Boles <strong>and</strong> Coombs (1975)<br />

showed that metamorphism of<br />

their tuffs in NZ was<br />

accompanied by substantial<br />

chemical changes due to<br />

circulating fluids fluids, <strong>and</strong> that fluids<br />

played important role in<br />

metamorphic minerals that were<br />

stable bl ii.e. strong component of f<br />

hydrothermal metamorphism.


Metamorphism of Mafic Rocks<br />

Mafic Assemblages of the Medium P/T Series: Greenschist,<br />

Amphibolite, <strong>and</strong> Granulite <strong>Facies</strong> (most common)<br />

Metamorphism p of mafic rocks is<br />

first evident in greenschist facies<br />

(correlates with chlorite <strong>and</strong> biotite<br />

zones of associated pelitic rocks)<br />

• Typical minerals include<br />

chlorite, hl i albite, lbi actinolite, i li<br />

epidote, quartz, <strong>and</strong> possibly<br />

calcite, biotite, or stilpnomelane<br />

ACF diagram g - The most characteristic mineral<br />

• Chlorite, actinolite, <strong>and</strong> epidote<br />

impart p the ggreen<br />

color from<br />

assemblage of the greenschist facies is: chlorite<br />

+ albite + epidote + actinolite ± quartz<br />

which mafic rocks <strong>and</strong> facies get<br />

their name<br />

Image: Winter (2001)


Metamorphism of Mafic Rocks<br />

Mafic Assemblages of the Medium P/T Series: Greenschist,<br />

Amphibolite, <strong>and</strong> Granulite <strong>Facies</strong> (most common)<br />

Greenschist to<br />

amphibolite facies<br />

transition involves 2<br />

major j mineralogical g<br />

changes<br />

Image: Winter (2001)<br />

1. Transition from albite<br />

to oligoclase (in (increased re sed<br />

Ca-content of stable<br />

plagioclase with T)<br />

22. Transition from<br />

actinolite to<br />

hornblende (amphibole<br />

becomes able to accept<br />

increasing amounts of<br />

aluminum <strong>and</strong> alkalis at<br />

higher T)


Metamorphism of Mafic Rocks<br />

Mafic Assemblages of the Medium P/T Series: Greenschist,<br />

Amphibolite, <strong>and</strong> Granulite <strong>Facies</strong> (most common)<br />

Image: Winter (2001)<br />

ACF diagram<br />

• Typically 2-phase Hbl-Plag<br />

• Most amphibolites are<br />

predominantly black rocks<br />

with up to 30% white<br />

plagioclase l i l<br />

• Garnet occurs in more Al-<br />

Fe-rich <strong>and</strong> Ca-poor mafic<br />

rocks <strong>and</strong> clinopyroxene in<br />

Al-poor-Ca-rich p<br />

ones


Metamorphism of Mafic Rocks<br />

Mafic Assemblages of the Medium P/T Series: Greenschist,<br />

Amphibolite, <strong>and</strong> Granulite <strong>Facies</strong> (most common)<br />

The transition from amphibolite to granulite facies occurs in the range 650-700oC Conversion of felsic gneiss (left)<br />

to charnockite (right -type of the<br />

granulite - opx granitoid).<br />

Kabbaldurga quarry, India Image:<br />

Darrell Henry<br />

• In presence of aqueous fluid, associated pelitic<br />

<strong>and</strong> quartzo-feldspathic rocks (including<br />

granitoids) g ) begin g to melt in this range g at low to<br />

medium pressures , so that migmatites may form<br />

<strong>and</strong> melts may become mobilized<br />

• Not all pelites <strong>and</strong> quartzo-feldspathic rocks reach<br />

granulite facies as a result<br />

• Mafic rocks generally melt at somewhat higher T<br />

• If H 2O is removed by earlier melts remaining mafic rocks<br />

may become depleted in water<br />

• HHornblende rnbl nd ddecomposes mp <strong>and</strong> nd orthopyroxene rth p r n +<br />

clinopyroxene appear<br />

• This reaction occurs over a T interval of at least 50 o C


Metamorphism of Mafic Rocks<br />

Mafic Assemblages of the Medium P/T Series: Greenschist,<br />

Amphibolite, <strong>and</strong> Granulite <strong>Facies</strong> (most common)<br />

Winter (2001)<br />

The granulite g facies is<br />

characterized by the<br />

presence of a largely<br />

anhydrous mineral<br />

assemblage<br />

IIn metabasites b i di diagnostic i<br />

mineral assemblage is<br />

orthopyroxene +<br />

clinopyroxene +<br />

plagioclase + quartz<br />

• GGarnet t is i also l common, <strong>and</strong> d<br />

minor hornblende <strong>and</strong>/or<br />

biotite may be present


Metamorphism of Mafic Rocks<br />

The origin of granulite facies rocks is complex <strong>and</strong> controversial.<br />

There is general agreement, however, on two points<br />

1) Granulites represent unusually hot conditions<br />

• T > 700 o C, geothermometry has yielded some very high T, i.e. >1000 o C<br />

• Average geotherm T for granulite facies depths should be ~500oC, suggesting that granulites are products of crustal thickening <strong>and</strong> excess<br />

heating<br />

2) Granulites are dry<br />

• These rocks didn’t melt due to lack of available H 2O<br />

• Granulite facies terranes represent deeply buried <strong>and</strong><br />

dehydrated roots of continental crust<br />

• Touret: fluid inclusions in granulite facies rocks of S.<br />

Norway are CO2-rich, while those in amphibolite facies<br />

rocks k are more H H2O-rich O ih<br />

• H 2O can be removed by H 2O-undersaturated melts


Metamorphism of Mafic Rocks<br />

Mafic Assemblages of the Medium P/T Series: Greenschist,<br />

Amphibolite, <strong>and</strong> Granulite <strong>Facies</strong> (most common)<br />

Winter (2001)


Metamorphism of Mafic Rocks<br />

Mafic Assemblages of the High P/T Series: Blueschist <strong>and</strong><br />

Eclogite <strong>Facies</strong><br />

Mafic rocks (<strong>and</strong> not pelites) develop<br />

Winter (2001)<br />

conspicuous <strong>and</strong> definitive mineral<br />

assemblages under high P/T<br />

conditions<br />

• High P/T geothermal gradients<br />

characterize subduction zones<br />

• Mafic blueschists are recognizable<br />

by color - useful indicators of<br />

ancient subduction zones<br />

• Great density of eclogites suggests<br />

that subducted basaltic oceanic<br />

crust becomes more dense than<br />

surrounding mantle


Metamorphism of Mafic Rocks<br />

Blueschist <strong>Facies</strong> - characterized in metabasites by presence<br />

of sodic blue amphibole stable only at high P (e.g.<br />

glaucophane)<br />

• Association of glaucophane<br />

+ lawsonite is diagnostic.<br />

• Albite breaks down at high<br />

pressure by reaction to<br />

jadeitic j py pyroxene + qquartz:<br />

NaAlSi 3O 8 = NaAlSi 2O 6 + SiO 2<br />

Ab = Jd + Qtz<br />

• Assemblage jadeite +<br />

quartz indicates highpressure<br />

blueschist facies<br />

Winter (2001)


Metamorphism of Mafic Rocks<br />

Eclogite <strong>Facies</strong> - mafic assemblage omphacitic pyroxene +<br />

pyrope-grossular garnet (Christmas-tree rocks)<br />

Winter (2001)<br />

• Along higher geothermal<br />

gradients amphibolite<br />

facies, or even the granulite<br />

ffacies, i may llead d to eclogite l i<br />

facies<br />

• MMuch hof f blueschist, bl hi <strong>and</strong> dall ll<br />

of eclogite facies are<br />

marked by y high-pressure<br />

g p<br />

instability of plagioclase, a<br />

common phase in<br />

metabasites of any other<br />

grade


Metamorphism of Mafic Rocks<br />

<strong>Metamorphic</strong> field gradient (<strong>and</strong> PTt paths)<br />

(upper left) crustal thickening<br />

(clockwise ( (clockwise p path) )<br />

Image: Winter (2001)<br />

(left) shallow magmatism heat heat-flow flow<br />

(above) ( ) model for some types yp of<br />

granulite facies metamorphism<br />

(counter (counter-clockwise clockwise path)


Metamorphism of Mafic Rocks<br />

Winter (2001)<br />

Pressure-Temperature-Time Pressure Temperature Time (P (P-T-t) T t) Paths<br />

Temporal implication of<br />

progressive metamorphism:<br />

that rocks pass through series<br />

of mineral assemblages upon<br />

continuously yequilibrate q to<br />

increasing metamorphic grade<br />

• Consider complete p set of T-P<br />

conditions that rock may<br />

experience during metamorphic<br />

cycle from burial to metamorphism<br />

(<strong>and</strong> orogeny) to uplift <strong>and</strong> erosion<br />

• Such a cycle is called a pressure-<br />

temperature-time i path, h or PP-T-t T<br />

path


Metamorphism of Mafic Rocks<br />

Pressure-Temperature-Time Pressure Temperature Time (P (P-T-t) T t) Paths<br />

<strong>Metamorphic</strong> P-T-t paths may be addressed by:<br />

1) Observing partial overprints of one<br />

mineral assemblage upon another -<br />

Relict minerals may indicate a portion of<br />

either prograde or retrograde path (or both)<br />

depending upon when they were created<br />

2) Apply geothermometers <strong>and</strong><br />

geobarometers to core vs. rim<br />

compositions iti of f chemically h i ll zoned d<br />

minerals to document changing P-T<br />

conditions experienced by a rock<br />

during their growth<br />

Winter (2001)


Metamorphism of Mafic Rocks<br />

Pressure-Temperature-Time Pressure Temperature Time (P (P-T-t) T t) Paths<br />

Ch Chemical i l zoning i profiles fil across a<br />

garnet from Tauern Window.<br />

Conventional P-T diagram g (pressure (p increases<br />

upward) showing three modeled "clockwise"<br />

P-T-t paths computed from the profiles<br />

Winter (2001)


Metamorphism of Mafic Rocks<br />

Pressure-Temperature-Time Pressure Temperature Time (P (P-T-t) T t) Paths<br />

Winter (2001)<br />

Some examples of<br />

modeled PP-T-t T t paths<br />

representing common<br />

types of<br />

metamorphism<br />

t hi<br />

The paths p illustrated are<br />

schematic, <strong>and</strong> numerous<br />

variations are possible,<br />

depending upon style of<br />

deformation <strong>and</strong> the rates<br />

of thickening, heat<br />

transfer, magmatism, <strong>and</strong><br />

erosion, i etc.<br />

t


Winter (2001)<br />

Metamorphism of Mafic Rocks<br />

Pressure-Temperature-Time Pressure Temperature Time (P (P-T-t) T t) Paths<br />

Path (a) is considered typical P-T-t<br />

path for orogenic belt with crustal<br />

thickening<br />

• P increases >> T, because of time lag<br />

required i dffor hheat t ttransfer f (P equilibrates ilib t<br />

nearly instantaneously, but heat conducts<br />

very slowly through rocks)<br />

• Thickened crustal block quickly<br />

reaches P max while being relatively cool<br />

• NNew geotherm h iis hi higher, h bbut transient, i<br />

<strong>and</strong> lasts only as long as the thickened<br />

crust <strong>and</strong> subduction-related heat<br />

generation lasts


Winter (2001)<br />

Metamorphism of Mafic Rocks<br />

Pressure-Temperature-Time Pressure Temperature Time (P (P-T-t) T t) Paths<br />

Path (a) is considered typical P-T-t<br />

path for orogenic belt with crustal<br />

thickening<br />

• Erosion soon affects thickened crust<br />

<strong>and</strong> dPb P begins i tto ddecrease bbefore f rocks k<br />

can equilibrate with higher orogenic<br />

geotherm<br />

• T still increasing due to slow heat<br />

transfer so that P-T-t path has a<br />

negative g slope p following gPmax<br />

• Reach Tmax when cooling effect of<br />

uplift <strong>and</strong> erosion catches up to the<br />

increased d geotherm, so that thermal<br />

perturbation of crustal thickening is<br />

dampened <strong>and</strong> begins to fade


Winter (2001)<br />

Metamorphism of Mafic Rocks<br />

Pressure-Temperature-Time Pressure Temperature Time (P (P-T-t) T t) Paths<br />

Path (b): rocks heated <strong>and</strong> cooled<br />

at virtually constant pressure by<br />

magmatic intrusion at shallow<br />

levels<br />

• P-T-t path for contact<br />

metamorphism<br />

• Depending upon extent of magmatic<br />

activity <strong>and</strong> its contribution to crustal<br />

mass, any path transitional between (a)<br />

<strong>and</strong> (b) may y occur.<br />

represents gradation from high-P<br />

(Barrovian) regional metamorphism to<br />

“regional-contact g metamorphism” p with<br />

numerous plutons to local contact<br />

metamorphism


Metamorphism of Mafic Rocks<br />

Pressure-Temperature-Time Pressure Temperature Time (P (P-T-t) T t) Paths<br />

We may assume that the general form of a path such as (a)<br />

represents p a typical yp rock during gorogeny g y<strong>and</strong> regional g<br />

metamorphism<br />

1. Contrary to classical treatment of<br />

metamorphism metamorphism, T <strong>and</strong> P do not both increase in<br />

unison as a single unified "metamorphic grade."<br />

2. Pmax <strong>and</strong> Tmax do not occur at the same time<br />

• In usual case of "clockwise" P-T-t paths, Pmax<br />

occurs much earlier than Tmax.<br />

• Tmax should represent p maximum ggrade<br />

at which<br />

chemical equilibrium is "frozen in" <strong>and</strong><br />

metamorphic mineral assemblage is developed<br />

• This occurs at P well below Pmax which is<br />

This occurs at P well below Pmax, which is<br />

uncertain since a mineral geobarometer should<br />

record the pressure of Tmax

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!