Disposal of leather goods (pdf / 1434 KB) - TFL

Disposal of leather goods

Introduction
Disposal of leather goods
by
Dr. Alois Puentener
Quality & Environment
The consumer has a responsibility not to use the simplest method of disposal -
unfortunately still in common practice - that is, just throwing refuse away. Campaigns to
collect worn and unwanted goods and sporadic recycling initiatives go some way towards
improving the situation. However the best solution would be to make new material or
products from recovered leather. The second best way to dispose of used leather is by
incineration, because leather provides considerable amounts of energy. But this leaves the
problem of dealing with the slag.
Nature of problem
The simplest method of disposal is to return the used natural product leather to nature, e.g.
to compost it. We are therefore studying this carefully. Some initial progress has been
achieved. We have ascertained that organic material like dyes or pigments, retanning
agents, fat liquor may degrade under given biological conditions. However, chrome tanned
leather is hard to compost and the reaction of the remaining metal, which may includes
some inorganic pigment and metal from complex dyes, is not known in detail. Therefore, at
the present time composting trials are mostly performed with metal-free shavings or leather
waste. The composition of a typical wet white shaving waste is shown in table 1.
Table 1: Composition of wet white pre-dried
Water content 10 %
Total dried matter (105°C) 89.7 %
Total organic dried matter (combustion) 89.0 %
Phosphorus (as P2O5 ,calculated) 0.01 %
Potassium (as K2O ,calculated) 0.04 %
Calcium (as CaO ,calculated) 0.2 %
Magnesium (as MgO, calculated) 0.003 %
Nitrogen (as N, calculated) 15.1 %
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Composting method
Wet white waste before composting
Compost, normally placed in a shady corner, is the heart of a biological garden. It requires
heat, moisture and oxygen in order to react aerobically (oxidatively). The compost shown in
table 2 was used in a field test:
Table 2: Composition of standard compost
Greenery 4'500 kg
Fruit waste 500 kg
Wet white shavings and trimmings 320 kg
Initial compost 50 litres
Stone powder 30 kg
Water 330 litres
The compost behaved like a natural garden compost. The reaction process is triggered by
micro-organisms and takes place in three stages (heating, hot stage, cooling) at different
temperatures over a total period of about approximately 6 months. The reaction mass
heats up to a maximum of 70-80°C, thereby harmful biological substances are being
destroyed. The earth organisms then require nitrogen in order to build up their own protein.
In biological enterprises, especially in autumn, when foliage, wood and shrub waste occurs,
there is often too little nitrogen present, and it frequently has to be added. We have seen
that metal-free shavings or metal-free leather, added at the beginning of the composting
process, can provide this additional nitrogen.
However, every compost composition shows behaves differently. Therefore the general
guideline shown in table 3 should be followed for composting leather waste and in
selecting chemicals used for producing metal-free leather.
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Table 3: Composting guideline
1 Shavings or leather waste must be composted together with other organic natural
material.
2 Shavings or leather waste must be reduced to very small pieces and care taken to
make sure that the compost is very well mixed.
3 Aliphatic compounds like natural fat decompose faster than aromatic products
like synthetic syntans.
4 Products of low molecular weight are easier to destroy than those of high
molecular weight or even cross-linked products which are often used for the
finishing process.
5 Avoid problematic chemicals like chlorinated paraffin, nonyl-phenols, some
preservatives and others.
Results
The results of various studies carried out show that excellent compost with a high nutrient
content is obtained by this method. The assumed average analysis of the compost
including leather waste is shown in table 4:
Table 4: Compost analysis
1 pH 6-8
2 Water content 40-50%
3 Organic matter 45-55%
4 Nitrogen (measured on try contains) 1.5 -2.0 %
5 Heavy metal content: i.e. cadmium and mercury less than 1ppm
Heavy metal content: i.e. lead, chromium copper, less than 100ppm
and nickel
Field tests with this compost revealed that nitrogen was released to the soil at a slow rate,
therefore this compost has to be classified as a long term nitrogen fertiliser. This is a very
clear indication that leather is (and should be) a highly stable material. Too much leather in
the compost can slow down the fertilising effect. The heavy metal content should be low to
meet the strict limits set by experts and authorities.
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Conclusion
Wet white must be reduced by a shredding machine
Experience to date indicates that on the strength of these results we can feel justified in
hoping to have found an environmentally acceptable disposal procedure for chrome-free
shavings and leather. In principle, metal free shavings and leather have been found not to
inhibit the biological process of composting and can be used as fertiliser. However, it must
be borne in mind that leather is often produced with unknown chemicals, which may slow
down the composting and fertilising behavior. For every type of leather trials should be
carried out and be verified by drawing up integral environmental balance sheets.
Acknowledgements
Controlling of the composting process with the appropriate tool
I would like to say thank you the many contributors who have helped in the writing of this
paper.
Updated 5.Jan.2004/AP
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