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IX. THERMAL EXPANSIVITY OF SOLIDS

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Sources of Data: Erfling 1939<br />

<strong>THERMAL</strong> EXPANSION <strong>OF</strong> TIN (WHITE)<br />

Other References: Cohen and Olie 1910<br />

Dorsey 1907<br />

Gruneisen 1910<br />

Discussion:<br />

Temp<br />

0<br />

K<br />

0<br />

10<br />

20<br />

30<br />

40<br />

50<br />

60<br />

70<br />

80<br />

90<br />

00<br />

20<br />

447<br />

447<br />

445<br />

441<br />

433<br />

423<br />

412<br />

399<br />

385<br />

371<br />

356<br />

3 24<br />

Taken from NBS 29<br />

I1<br />

II<br />

I1<br />

I1<br />

I1<br />

I1<br />

II<br />

It<br />

II<br />

II<br />

11<br />

Anisotropic. The above values were calculated<br />

from the relation, Mean Value = 1/3 (11 ) +<br />

2/3 (J.), where ( 11 ) and (I.) signify the same<br />

property measured parallel and perpendicular,<br />

respectively, to the tetragonal axis.<br />

Thewlis and Davey (1954) measured the lattice<br />

parameter of grey tin, a brittle form with<br />

diamond-type lattice that is stable below 18OC.<br />

Their data cover the range, -130 to +20°C, and<br />

are, represented by a constant expansion coefficient,<br />

dL/LdT = 4.7 x 10-6deg'1C. See also<br />

Cohen and Olie (1910) . The ordinary ductile<br />

variety (white tin) if pure may transform to<br />

grey tin at low ambient temperatures. but is<br />

stabilized by impurities.<br />

Table of<br />

- 1 3<br />

L dT<br />

per OK<br />

0.<br />

-5<br />

.07 x 10<br />

I1 .3<br />

.6<br />

.9<br />

1.1<br />

1.2<br />

1.3<br />

1.42<br />

1.50<br />

1.56<br />

1.64<br />

11<br />

II<br />

I1<br />

I1<br />

It<br />

I1<br />

II<br />

I1<br />

I1<br />

Selected Values<br />

Temp.<br />

0<br />

K<br />

140<br />

160<br />

180<br />

200<br />

220<br />

240<br />

2 60<br />

273<br />

280<br />

293<br />

300<br />

<strong>IX</strong>-2-1<br />

L<br />

293 - LT<br />

L293<br />

290<br />

255 I'<br />

219 It<br />

183 I'<br />

145 I'<br />

106 I'<br />

66.7 I'<br />

40.7 'I<br />

26.5 'I<br />

0.0<br />

-14.4 'I<br />

--<br />

1 dL<br />

L dT<br />

per OK<br />

1.71 x<br />

1.77<br />

1.82<br />

1.87<br />

1.91<br />

1.95<br />

1.99<br />

2.01<br />

2.03<br />

2.05<br />

2.06<br />

II<br />

11<br />

I1<br />

I1<br />

II<br />

II<br />

II<br />

I1<br />

I1<br />

I1

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