Print MSDS - Miller Electric Company Publications

Miller Electric Company MSDS 18JUN2012 

Table of Contents 

1. 1100 Welding Electrode 

2. 1515 Big Blast 

3. 1718 Zinc Proof 

4. 1755 Hi-Speed 

5. 2207 Foam It Away 

6. 2404 Ram Rod 

7. ‘44’ Rosin Flux Cored Solder 

8. Abrasive Grinding Wheel 

9. Acetone 

10. Acetylene 

11. Acid Flux Cored Solder 

12. Air Tool Lubricant 

13. Battery Acid 

14. Battery Fluid (Alkali) 

15. Battery Terminal Cleaner 

16. Big Brute 

17. C5A- High Temperature 

18. Chain Lube 

19. Contact Cement 

20. Contact Cleaner 

21. Copper Based Welding & Braze Wire & 

Rod 

22. Copper 

23. Cutting Oil 

24. Diesel Fuel 

25. Dry Chemical (Fire Extinguisher) 

26. Duct Tape 

27. Electrical Insulating Varnish 

28. Epoxy Resin 

29. Filled Vinyl & Acrylic Emulsion 

30. Gasoline 

31. Glass Cleaner 

32. Hydraulic Fluid 

33. Knock-Out Weed Killer 

34. Krylon Engine Paint 

35. Liquid Bleach 

36. LPS 3 Heavy Duty Rust Inhibitor 

37. Medaphene Plus Disinfecting Deodorant 

38. Mineral Spirits 

39. Misty Powder Puff Residual Insecticide 

40. Noalox Anti-Oxidant 

41. Oxygen 

42. PB B’Laster 

43. Pressure Treated Wood 

44. Propane 

45. PVC Plastic Pipe 

46. PVC Solvent 

47. Rapid Wrench 

48. Rough Touch Scrubs in a Bucket 

49. Silicone Sealant 

50. Spitfire RTU 

51. Super Carb & Choke Cleaner 

52. Super Electra-Saf 

53. Tin Alloy Solder 

54. TMS Polymeric 

55. Triple “D” 

56. Wasp & Hornet Spray 

57. Wheel Bearing Grease 

58. Windshield Washer Fluid 

59. Xylene 

60. Yellow 77 

61. Zep 45 

62. Zep Clean ‘Ems 

63. Zep Chill Drill 

64. Zep Gold Touch 

65. Zep Measure Up Degreaser 

66. Zep Powerhouse 

67. ATC4 

68. Krylon Seal Coat 

69. Hilti FS One Firestop Sealant 

70. Ideal AquaGel Wire Lube 

71. Masterflow 928 Grout

SAFETY DATA SHEET 

-1- 

SDS NO. 7971-1-X 

DATE REVISED: 05/12/2008 

This Safety Data Sheet complies with European Commission Directive 91/155/EEC, ISO 11014-1 and ANSI Z400.1 

1. PRODUCT AND COMPANY IDENTIFICATION 

Product Name: DUAL SHIELD MILD STEEL AWS A5.20 T-1, T-2, T-9 & T-12 FLUX CORED WELDING ELECTRODES 

Application: Arc Welding 

Classification: AWS A5.20 

Supplier: THE ESAB GROUP, INC., 801 Wilson Avenue, Hanover, PA 17331 

Telephone No.: 1-717-637-8911, 1-800-933-7070 

Emergency No.: 1-717-637-8911 and 1-800-424-9300 (CHEMTREC) 

Web site: www.esabna.com 

2. HAZARDS IDENTIFICATION 

Emergency Overview: Metal wires in varying colors. These products are normally not considered hazardous as shipped. Gloves 

should be worn when handling to prevent cuts and abrasions. 

Some of these products contain nickel and cryolite. Nickel is classified as a skin sensitizer and a suspect carcinogen. Cryolite is 

classified as toxic and dangerous for the environment. Some of these products contain potassium fluorosilicate which is 

classified as toxic by inhalation, skin contact, and ingestion. In the form that these substances are present in these products, 

they do not contribute to a hazard classification of the products. These products contain titanium dioxide which is possibly 

carcinogenic. These products contain quartz, but normally not in an inhalable fraction. Quartz can cause silicosis and may 

cause cancer. 

Skin contact is normally no hazard but should be avoided to prevent possible allergic reactions. 

Persons with a pacemaker should not go near welding or cutting operations until they have consulted their doctor and obtained 

information from the manufacturer of the device. 

When these products are used in a welding process, the most important hazards are heat, radiation, electric shock and welding 

fumes. 

Heat: Spatter and melting metal can cause burn injuries and start fires. 

Radiation: Arc rays can severely damage eyes or skin. 

Electricity: Electric shock can kill. 

Fumes: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or 

irritation of the nose, throat or eyes. Chronic overexposure to welding fumes may affect pulmonary function. 

Prolonged inhalation of nickel compounds above safe exposure limits can cause cancer. Overexposure to 

manganese and manganese compounds above safe exposure limits can cause irreversible damage to the 

central nervous system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, 

muscular weakness, psychological disturbances and spastic gait. 

3. COMPOSITION/INFORMATION ON INGREDIENTS 

These products are preparations of flux-cored wire. 

Ingredients CAS# EINECS# 

Hazard 

classification (1) 

Aluminum 7429-90-5 231-072-3 F; R15 R10 

stablized 

F; R15-17 

pyrophoric 

(2) 

IARC 

NTP (3) 

OSHA 

List (4) 

-- -- -- 

Aluminum Oxide 1344-22-4 215-691-6 No -- -- -- 

Carbon 7440-44-0 231-153-3 No -- -- -- 

Cryolite 15096-52-3 239-148-8 T; R48/23/25 

Xn; R20/22 

N; R51-53 

-- -- -- 

Iron 7439-89-6 231-096-4 No -- -- -- 

Iron Oxide 1309-37-1 215-168-2 No -- -- -- 

Lithium Fluoride 7789-24-2 232-152-0 No -- -- -- 

Magnesium 7439-95-4 231-104-6 No -- -- -- 

Manganese 7439-96-5 231-105-1 No -- -- --

Product Identity: DUAL SHIELD MILD STEEL AWS A5.20 T-1, T-2, T-9 & T-12 FLUX CORED WELDING ELECTRODES 

-2- 

SDS NO. 7971-1-X 


Ingredients CAS# EINECS# 

Hazard 

classification (1) IARC (2) NTP (3) OSHA List (4) 

Nickel 

Potassium Fused Flux 

7440-02-0 231-111-4 Carc. Cat. 3; 

R40-R43 

2B S -- 

Titanium Oxide 

13463-67-7 236-675-5 

No 

2B -- 

-- 

Manganous Oxide 

1344-43-0 215-695-8 

No 

-- -- 

-- 

Potassium Oxide 

12136-45-7 235-227-6 

No 

-- -- 

-- 

Silicon Dioxide (amorphous) 60676-86-0 262-373-8 

No 

-- -- 

-- 

Potassium Silico Fluoride 16871-90-2 240-896-2 T; R23/24/25 -- -- -- 

Silicon 7440-21-3 231-130-8 No -- -- -- 

Silicon Dioxide 14808-60-7 238-878-4 T; R45 1 K -- 

Sodium Fluoride 

Sodium Fused Flux 

7681-49-4 231-667-8 T; R25 

Xi; R36/38, R32 

-- -- -- 


13463-67-7 236-675-5 

No 

2B -- 

-- 


1344-43-0 215-695-8 

No 

-- -- 

-- 

Sodium Oxide 

12401-86-4 215-208-9 

No 

-- -- 

-- 

Silicon Dioxide (amorphous) 60676-86-0 262-373-8 

No 

-- -- 

-- 

Titanium Oxide 13463-67-7 236-675-7 No ## -- -- 

Zirconium 7440-67-7 231-176-9 F; R15-17 -- -- -- 

Zirconium Dioxide 1314-23-4 215-227-2 No -- -- -- 

(1) 

Hazard Classification according to European Council Directive 67/548/EEC, for R-phrases, see Section 16. 

(2) 

Evaluation according to the International Agency for Research on Cancer. 

1 – Human Carcinogen 2B – Possibly carcinogenic to humans 

(3) th 

Classification according to the 11 Report on Carcinogens, published by the US National Toxicology Program. 

K – Known Carcinogen S – Suspect Carcinogen 

(4) 

Carcinogen listing according to OSHA, Occupational Safety & Health Administration (USA). 

## Presently designated to become 2B with publication of monograph. 

“All Position” T-1, T-9 & T 12 Electrodes 

APPROXIMATE COMPOSITION (Wt. %) 

Product Trade Name: 

Dual Shield 

70 Ultra Plus 

Dual Shield 

7000 

Dual Shield 

7100 LC 

Dual Shield 

7100 Ultra 

Dual Shield 

7200 

Dual Shield 

ARC-71 

Dual Shield 

FC-717 

Aluminum -- --



Dual Shield II 

70 Ultra 


70 HYN 



70LC 

-3- 


70LF 


70T-12 

SDS NO. 7971-1-X 



70T-12H4 

Aluminum -- --


“Downhand” T-1 & T-9 Electrodes 

Product Trade Name: Dual Shield 

111-A 


Dual Shield 

111-AC 

Dual Shield 

111-HD 

-4- 

Dual Shield 

111-RB 

SDS NO. 7971-1-X 


Dual Shield 

70-GB 

Dual Shield 

78 

Aluminum -- -- -- 0.1-0.5 -- -- 

Aluminum Oxide


“Downhand” T-2 Electrodes 


Dual Shield 

110 


-5- 

Dual Shield 

T-63 

SDS NO. 7971-1-X 


Dual Shield 

SP 

Aluminum Oxide


following limits can be used as guidance. For information about welding fume analysis refer to Section 10. 

Substance CAS# ACGIH TLV (1) mg/m 3 

-6- 

SDS NO. 7971-1-X 


OSHA PEL (2) mg/m 3 

Aluminum (metal dust) 7429-90-5 10 15*, 5** 

Aluminum Oxide 1344-28-1 10 15*, 5** 

Carbon 7440-44-0 None None 

Cryolite 15096-52-3 2.5 2.5 

Iron and Iron Oxides 7439-89-6 5** 10 (fume) 

Iron Oxide 1309-37-1 5** 10 (fume) 

Lithium Fluoride (as F) 7789-24-2 2.5 2.5 

Manganese & 

Manganese Compounds (as Mn) 

7439-65-5 0.2 5 Ceiling 

Nickel (inhalable fraction) 7440-02-0 1.5 1 

Potassium Fused Flux 



Potassium Oxide 

Silicon Dioxide (amorphous) withdrawn 

13463-67-7 

1344-43-0 

12136-45-7 

60676-86-0 

10 

0.2 

None 

None 

15* 

5 Ceiling 

None 

10 mg/m 3 ** 

%SiO2+2 

Potassium Silico Fluoride (as F) 16871-90-2 2.5 2.5 

Silicon (nuisance dust) 7440-21-3 10*, 3*** 15*, 5** 

Silicon Dioxide (quartz) 14808-60-7 0.025** 10 mg/m³** 

%SiO2+2 

Sodium Fluoride (as F) 7681-49-4 2.5 2.5 

Sodium Fused Flux 



Sodium Oxide 

Silicon Dioxide (amorphous) withdrawn 

13463-67-7 

1344-43-0 

12401-86-4 

60676-86-0 

10 

0.2 

None 

None 

15* 

5 Ceiling 

None 

10 mg/m 3 ** 

%SiO2+2 

Titanium Oxide 13463-67-7 10 15* 

Zirconium & Zirconium Compounds 7440-67-7 5, 10 (STEL) 5 

Zirconium Dioxide 1314-23-4 5, 10 (STEL) 5 

(1) 

Threshold Limit Values according to American Conference of Governmental Hygienists, 2007 

(2) 

Permissible Exposure Limits according to the Occupational Safety & Health Administration (USA) 

Unless noted, all values are for 8 hour time weighted averages (TWA). 

* Total dust, ** Respirable fraction, *** Inhalable fraction. 

NOTE: Some of these products may not contain all of the materials listed. For details of composition, refer to the 

COMPOSITION TABLE in Section 3. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

Appearance: Solid, non-volatile with varying color 

Melting point: >1000°C / >1800ºF 

10. STABILITY AND REACTIVITY 

General: These products are only intended for normal welding purposes. 

Stability: These products are stable under normal conditions. 

Reactivity: Contact with chemical substances like acids or strong bases could cause generation of gas. 

When these products are used in a welding process, hazardous decomposition products would include those from the volatilization, 

reaction or oxidation of the materials listed in Section 3 and those from the base metal and coating. 

The amount of fumes generated from these products varies with welding parameters and dimensions but is generally no more than 5 

to 15 g/kg consumable. Fumes from these products may contain compounds of the following chemical elements: Fe, O, Mn, Zr, Ni, F, 

Na, Si, K, Al, Li and Ti. The rest is not analyzed, according to available standards. 

Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume compounds found in 

Section 8. Manganese and nickel have low exposure limits, in some countries, that may be easily exceeded. 

Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants around the 

welding area can be affected by the welding process and influence the composition and quantity of fumes and gases produced.


-7- 

SDS NO. 7971-1-X 


11. TOXICOLOGICAL INFORMATION 

Inhalation of welding fumes and gases can be dangerous to your health. Classification of welding fumes is difficult because of varying 

base materials, coatings, air contamination and processes. The International Agency for Research on Cancer has classified welding 

fumes as possibly carcinogenic to humans (Group 2B). 

Acute toxicity: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or 

irritation of the nose, throat or eyes. 

Chronic toxicity: Overexposure to welding fumes may affect pulmonary function. Prolonged inhalation of nickel compounds above 

safe exposure limits can cause cancer. Overexposure to manganese and manganese compounds above safe 

exposure limits can cause irreversible damage to the central nervous system, including the brain, symptoms of 

which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and spastic 

gait. Inhalable quartz is a respiratory carcinogen; however, the process of welding converts crystalline quartz to the 

amorphous form which is not considered to be a carcinogen. 

12. ECOLOGICAL INFORMATION 

Welding consumables and materials could degrade/weather into components originating from the consumables or from the materials 

used in the welding process. Avoid exposure to conditions that could lead to accumulation in soils or groundwater. 

Some of these products contain cryolite, which is classified by European Council Directive 67/548/EEC, as toxic to aquatic organisms 

and may cause long-term adverse effects in the aquatic environment. 

13. DISPOSAL CONSIDERATIONS 

Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal and local 

regulations. Use recycling procedures if available. 

USA RCRA: These products are not considered hazardous waste if discarded. 

Residues from welding consumables and processes could degrade and accumulate in soils and groundwater. Welding slag from these 

products typically contain mainly the following components originating from the powder filling of the flux-cored wire: Fe, O, Mn, Zr, Ni, 

F, Na, Si, K, Al, Li and Ti. 

14. TRANSPORT INFORMATION 

No international regulations or restrictions are applicable. 

15. REGULATORY INFORMATION 

Read and understand the manufacturer's instructions, your employer's safety practices and the health and safety instructions on the 

label. Observe any federal and local regulations. Take precautions when welding and protect yourself and others. 

WARNING: Welding fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate 

ventilation. 

ELECTRIC SHOCK can kill. 

ARC RAYS and SPARKS can injure eyes and burn skin. 

Wear correct hand, head, eye and body protection. 

Canada: WHMIS classification: Class D; Division 2, Subdivision A 

Canadian Environmental Protection Act (CEPA): All constituents of these products are on the Domestic Substance List 

(DSL). 

USA: Under the OSHA Hazard Communication Standard, these products are considered hazardous. 

These products contain or produce a chemical known to the state of California to cause cancer and birth defects (or other 

reproductive harm). (California Health & Safety Code § 25249.5 et seq.) 

United States EPA Toxic Substance Control Act: All constituents of these products are on the TSCA inventory list or are 

excluded from listing. 

CERCLA/SARA Title III 

Reportable Quantities (RQs) and/or Threshold Planning Quantities (TPQs): 

Ingredient name RQ (lb) TPQ (lb) 

Product is a solid solution in the form of a solid article. - - 

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National 

Response Center and to your Local Emergency Planning Committee. 

Section 311 Hazard Class 

As shipped: Immediate In use: Immediate delayed


-8- 

SDS NO. 7971-1-X 


EPCRA/SARA Title III 313 Toxic Chemicals 

The following metallic components are listed as SARA 313 “Toxic Chemicals” and potential subject to annual SARA 313 

reporting. See Section 3 for weight percent. 

Ingredient name Disclosure threshold 

Manganese 1.0% de minimis concentration 

Nickel 0.1% de minimis concentration 

16. OTHER INFORMATION 

This Safety Data Sheet has been revised due to modifications to several paragraphs and/or new format. 

This SDS supersedes 7971-1-W. 

Refer to ESAB "Welding and Cutting - Risks and Measures", F52-529 “Precautions and Safe Practices for Electric Welding and 

Cutting” and F2035 “Precautions and Safe Practices for Gas Welding, Cutting and Heating” available from ESAB, and to: 

USA: Contact ESAB at www.esabna.com or 1-800-ESAB-123 if you have questions about this SDS. 

American National Standard Z49.1 "Safety in Welding and Cutting", ANSI/AWS F1.5 “ Methods for Sampling and 

Analyzing Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles 

Generated by Welding and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American Welding 

Society, 550 North Le Jeune Road, Miami, Florida, 33135. Safety and Health Fact Sheets available from AWS at 

www.aws.org. 

OSHA Publication 2206 (29 C.F.R. 1910), U.S. Government Printing Office, Superintendent of Documents, P.O. Box 

371954, Pittsburgh, PA 15250-7954. 

American Conference of Governmental Hygienists (ACGIH), Threshold Limit Values and Biological Exposure Indices, 6500 

Glenway Ave., Cincinnati, Ohio 45211, USA. 

NFPA 51B “Standard for Fire Prevention During Welding, Cutting and Other Hot Work” published by the National Fire 

Protection Association, 1 Batterymarch Park, Quincy, MA 02169. 

UK: WMA Publication 236 and 237, "Hazards from Welding Fume”, “The arc welder at work, some general aspects of health 

and safety". 

Germany: Unfallverhütungsvorschrift BGV D1, "Schweißen, Schneiden und verwandte Verfahren". 

Canada: CSA Standard CAN/CSA-W117.2-01 “Safety in Welding, Cutting and Allied Processes” 

These products have been classified according to the hazard criteria of the CPR and the SDS contains all the information 

required by the CPR. 

R-phrases: R10 – Flammable. 

R15 – Contact with water liberates extremely flammable gases. 

R17 – Spontaneously flammable in air. 

R25 – Toxic if swallowed. 

R32 – Contact with acids liberates very toxic gas. 

R40 – Limited evidence of a carcinogenic effect. 

R43 – May cause sensitization by skin contact. 

R45 – May cause cancer. 

R51 – Toxic to aquatic organisms. 

R53 – May cause long-term adverse effects in the aquatic environment. 

R20/22 – Harmful by inhalation and if swallowed. 

R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed. 

R36/38 – Irritating to eyes and skin. 

R48/23/25 – Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. 

ESAB requests the users of these products to study this Safety Data Sheet (SDS) and become aware of product hazards and safety information. 

To promote safe use of these products a user should: 

- notify its employees, agents and contractors of the information on this SDS and any product hazards/safety information. 

- furnish this same information to each of its customers for these products. 

- request such customers to notify employees and customers for the same product hazards and safety information. 

The information herein is given in good faith and based on technical data that ESAB believes to be reliable. Since the conditions of 

use are outside our control, we assume no liability in connection with any use of this information and no warranty, expressed or implied 

is given. Contact ESAB for more information.

PRO-CHEM, INC. 

1475 BLUEGRASS LAKES PKWY. 

ALPHARETTA, GA 30004 

EMERGENCY/INFO # (800) 241-8180 

ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053 

SECTION 1 – Chemical and Company Identification 

CHEMICAL FAMILY: Wasp and Hornet Killer 

SECTION 2 – Composition on Ingredients 

COMPONENTS 

(Chemical Identity, 

Common Name(s)) 

CAS No. OSHA PEL ACGIH-TLV OTHER LIMITS 

RECOMMENDED 

MATERIAL SAFETY DATA SHEET 

BIG BLAST / 1515 

MARCH 2006 

PAGE 1 

Complies With USDL Safety and Health Regulations, (29 CFR 1910.200) 

% (Opt.) 

Aliphatic hydrocarbon 64742-47-8 Not estab. Not estab. 100 ppm Manu. 60-100% 

Carbon dioxide 124-38-9 5000 ppm 5000 ppm STEL 30000 ppm 3.0 - 7.0% 

Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio, Pennsylvania or Texas is 

described above if known present in regulated concentrations. 

SECTION 3 – Hazards Information 

ROUTE (S) OF ENTRY: EYES? YES INHALATION? YES SKIN? YES INGESTION? YES 

ACUTE HEALTH HAZARDS - Caution. Causes moderate eye irritation. May cause skin irritation. Unlikely 

to be swallowed, but contains petroleum distillates which may present an aspiration hazard if swallowed. 

May be harmful if inhaled. 

CHRONIC HEALTH HAZARDS - Prolonged or frequently repeated skin contact may cause allergic 

reactions in some individuals. Follow label instructions and good chemical hygiene practices to avoid these 

hazards. 

CARCINOGENITY: 

OSHA: NO ACGIH: NO NTP: NO IARC: NO 

SIGNS AND SYMPTOMS OF EXPOSURE: Redness, dryness, scaling or itching skin. Excessive inhalation 

of vapors may cause headaches, stupor, or irritation of throat and eyes. Swallowing may cause irritation of 

stomach and intestines resulting in nausea and vomiting. 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Pre-existing skin and kidney 

conditions may be adversely affected. Follow good chemical hygiene practices to avoid this hazard. 

SECTION 4 – First Aid Measures 

EYES: Flush with plenty of water (for at least 15 minutes lifting eyelids to insure complete 

removal.) Call a physician if irritation persists. 

SKIN: Wash thoroughly with soap and water. Remove contaminated clothing and shoes. 

Launder contaminated clothing before reuse. Call a physician if irritation arises and 

persists. Note to physician: Contains petroleum distillates (>80%). 

INHALATION: Get to fresh air. If breathing has stopped, qualified personnel should administer artificial 

respiration. 

INGESTION: Unlikely from aerosol can. If large quantities are swallowed, call a physician or poison 

control center immediately. Get immediate medical attention. 

SECTION 5 – Fire Fighting Measures 

USA FLAME PROJECTION TEST (ASTM D-3065): 0”, no flashback 

FLAMMABLE LIMITS: No Data LEL: No Data UEL: No Data 

EXTINGUISHING MEDIA: Treat as an oil fire. Water may cause fire to float and spread. Use carbon 

dioxide, dry chemical or foam. 

SPECIAL FIRE FIGHTING PROCEDURES: Use water spray to keep containers cool and vapors down. 

Do not allow runoff to enter sewers or public watercourses. 

Wear self-contained breathing apparatus in chemical fires. 

HAZARDOUS PRODUCTS OF COMBUSTION: Carbon dioxide, carbon monoxide, oxygen, smoke, soot 

and various organic oxidation by-products. 

UNUSUAL FIRE AND EXPLOSION HAZARDS: Aerosol container (pressurized) may burst if heated over 

130F. Combustible contents. 

HEALTH 1 

FIRE 2 

REACTIVITY 1 

P.P.E. A 

SECTION 6 – Accidental Release Measures 

SMALL SPILL: Caution, slip hazard. Wipe up small spills promptly. Thoroughly clean any residues 

with an effective cleaning compound. 

LARGE SPILL: Isolate traffic and ventilate area. Eliminate all ignition sources. Wear protective gear 

as necessary. Dike to prevent spread. Prevent from entering drains, sewers or any watercourse or 

waterway. Pick up with an absorbent material. Put in a suitable container for proper disposal. This 

product is toxic to fish and aquatic invertebrates. 

SECTION 7 – Handling and Storage 

HANDLING: Avoid contact with eyes or clothing. Wash thoroughly with soap and water after 

handling. Do not swallow. Avoid inhaling mist or vapors. Do not deliberately concentrate and inhale 

vapors. Use with adequate ventilation. Keep away from heat, sparks and open flame. Do not use 

around ignition sources such as heat, sparks, open flame, static electricity, electric motors, welding 

arcs, etc. Do not smoke while using. Exposure to temperatures above 130F may cause bursting. 

Direct spray away from face. Replace cap when not in use. Do not puncture or incinerate container. 

Do not apply directly to water. 

STORAGE: Store in a cool (under 130F) dry location away from heat, sparks, open flame, and direct 

sunlight. Keep out of reach of children. Follow label directions carefully. 

SECTION 8 – Exposure Controls/Personal Protection 

EYE PROTECTION: Yes, goggles or approved safety glasses (ANSI Z87) 

SKIN PROTECTION: Not usually needed. If direct contact is possible, wear chemical resistant 

gloves or PPE. 

RESPIRATORY PROTECTIONS: Not usually necessary. Use with adequate ventilation. If PELs or 

TLVs are exceeded (see Section II), follow NIOSH\MSHA 

recommendations. 

ENGINEERING CONTROLS: Ventilation not usually necessary but should be provided in the 

event of overexposure. 

SECTION 9 – Physical and Chemical Properties 

APPEARANCE/ODOR: Clear colorless liquid with a slight petroleum odor. 

PHYSICAL STATE: Liquid 

pH: N/A SPECIFIC GRAVITY (70F): 0.806 

BOILING POINT (Concentrate): 430F MELTING POINT: No Data 

EVAPORATION RATE (Butyl Acetate = 1): No Data 

PRESSURE (psig. @ 70F): 90+ 5 VAPOR DENSITY (AIR=1): Greater than one (1) 

SOLUBILITY IN WATER: Negligible 

VOLATILE ORGANIC COMPOUNDS (VOCs): 0 grams per liter or 0% by weight VOC’s. 

SECTION 10 – Stability and Reactivity 

HAZARDOUS POLYMERIZATION: This product will not undergo hazardous polymerization. 

HAZARDOUS DECOMPOSITION/BY-PRODUCTS: Carbon dioxide, carbon monoxide, oxygen, 

smoke, soot and various organic oxidation by-products. 

CHEMICAL STABILITY: Stable 

INCOMPATIBILITY (Materials to Avoid): Strong oxidizing agents, alkali metals, alkaline earth metals, 

metal acetylhalides and chromium. 

THIS INFORMATION MUST BE ON ALL MSDS’S COPIED AND DISTRIBUTED FOR THIS MATERIAL. 

NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR RESULTS OBTAINED FROM USE. 

PRO-CHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO USER. 

VENDEE/USER ASSUMES ALL RISKS ASSOCIATED WITH USE.

PRO-CHEM, INC. 





SECTION 11 – Toxicological Information 

No Data 

SECTION 12 – Ecological Information 

No Data 

SECTION 13 – Disposal Consideration 

DISPOSAL METHOD: Dispose of in accordance with all applicable local, state, and 

federal regulations. 

RCRA WASTE INFORMATION: If this product becomes a waste, it would not be a hazardous 

waste as defined by RCRA (40 CFR 261). However the waste 

should be properly characterized to evaluate whether its 

composition has been modified prior to disposal. 

SECTION 14 – Transport Information 

DOT INFORMATION: 49 CFR 172.101 

PROPER SHIPPING DESCRIPTION: Consumer Commodity 

HAZARD CLASS: ORM-D 

IDENTIFICATION NUMBER 

None 

PACKING GROUP: 

AIR TRANSPORTATION: 

None 

PROPER SHIPPING DESCRIPTION: Aerosols, non-flammable 

HAZARD CLASS: 2.2 

IDENTIFICATION NUMBER: 

UN 1950 

PACKING GROUP: None 

REPORTABLE QUANTITY (RQ): 49 CFR 172.101: Not applicable 

MARINE POLLUTANTS: None 


BIG BLAST / 1515 

MARCH 2006 

PAGE 2 


HEALTH 1 

FIRE 2 

REACTIVITY 1 

P.P.E. A 

SECTION 15 – Regulatory Information 

US Federal Regulations: 

TSCA (Toxic Substances Control Act) Status: All ingredients are on the TSCA inventory or are 

not required to be listed on the TSCA inventory. 

CERCLA RQ – 40 CFR 302.4 (a) : None Listed 

SARA 313 Components – 40 CFR 372.65 

Name CAS Percentage 

Tetramethrin 7696-12-0 0.1% 

Permethrin 52645-53-1 0.26% 

Piperonyl butoxide 51-03-6 0.52% 

State and Local Regulations: 

California Proposition 65 

None 

SECTION 16 – Other Information 

WARNING! The use of this product is beyond the control of the manufacturer; therefore, no 

guarantee, expressed or implied, is made as to the effects of such or the results to be obtained if not 

used in accordance with directions or established safe practice. The user must assume all 

responsibility, including injury or damage, resulting from its misuse as such, or in combination with 

other materials. The manufacturer warrants only that this product meets the manufacturer's 

specifications for such product. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, 

EXPRESS OR IMPLIED, AS TO DESCRIPTION , QUALITY, MERCHANTABILITY. FITNESS FOR 

ANY PARTICULAR PURPOSE, PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS 

PRODUCT. THE MANUFACTURER SHALL BE IN NO WAY RESPONSIBLE FOR THE IMPROPER 

USE OF THIS PRODUCT. The sole and exclusive remedy against the manufacturer for breach of 

warranty shall be reimbursement of the purchase price of the product in the event that a defective 

condition of the product shall be found to exist. NO OTHER REMEDY (INCLUDING BUT NOT 

LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR 

PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE. 


NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR RESULTS OBTAINED FROM USE. 

PRO-CHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO USER. 

VENDEE/USER ASSUMES ALL RISKS ASSOCIATED WITH USE.

PRO CHEM, INC. 






PRODUCT TYPE: Aerosol 

FORMULA: Proprietary 


CHEMICAL NAME CAS # % WT 313/CHEM SKIN CARCINOGEN PEL TLV-TWA 

Toluene 

Petroleum Distillates, 

108-88-3 30-40 YES YES NO 200 ppm 50 ppm 

Hydrotreated, Light 64742-47-8 1-10 NO NO NO 500 ppm 100 ppm 

Zinc 7440-66-6 10-20 YES NO NO 10 mg/m 3 

(Dust) 

N/E 

Liquefied Petroleum Gas 68476-86-8 35-45 NO NO NO 1000 ppm 1000 ppm 


PRIMARY ROUTES OF ENTRY & EFFECTS OF OVEREXPOSURE: 

EYES: May cause irritation accompanied by stinging, tearing, redness, and swelling of eyes. 

SKIN: May cause mild irritation. Frequent or prolonged contact may cause redness, burning, and 

drying and cracking of skin. Passage of this material into the body through the skin is possible. May 

aggravate existing skin conditions. 

INHALATION: Inhalation of small amounts of vapor or mist is not likely to cause harmful effects. 

Inhalation of large amounts may irritate the upper respiratory tract, cause flu-like symptoms, and 

have a slight anesthetic effect. Prolonged overexposure can cause central nervous system excitation 

followed by central nervous system depression and other central nervous system effects, temporary 

changes in mood and behavior, muscle weakness, loss of coordination, confusion, irregular 

heartbeat, coma, and death. Intentional, prolonged abuse may lead to damage to the central and 

peripheral nervous systems, vision, hearing, liver, kidneys, heart, blood, and brain. 

INGESTION: Can cause gastrointestinal irritation, nausea, fever, vomiting and diarrhea. Aspiration 

of material into the lungs can cause lung inflammation and other lung injury. 


EYES: Flush with large amounts of cool running water for at least 15 minutes while holding upper and 

lower lids open. If irritation persists get medical attention immediately. 

SKIN: Wash with soap and water. If irritation persists seek medical attention. 

INHALATION: Remove to fresh air. Seek medical attention immediately. If breathing stops give 

artificial respiration. 

INGESTION: Do not induce vomiting. Seek medical attention immediately. 


FLASH POINT (of Concentrate Only): 80F 

FLAMMABILITY (as per CSMA Flame Projection Test): Extremely Flammable Spray 

EXTINGUISHING MEDIA: Foam, CO2, Dry Media 

SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus and protective 

clothing. Cool fire exposed containers to prevent rupturing. 

UNUSUAL FIRE & EXPLOSION HAZARDS: Exposure to temperature above 120F may cause bursting. 


ZINK PROOF / 1718 

NOVEMBER 2008 

PAGE 1 


HEALTH 2 

FIRE 3 

REACTIVITY 1 

P.P.E. I 


STEPS TO BE TAKEN IN CASE OF SPILL OR LEAK: Allow propellant to evaporate. Maintain local 

exhaust and adequate ventilation. No smoking. Keep sparks, heat sources and open flame far away 

from spill or leak. Cover with absorbent material and sweep up. Wash area to prevent slipping. 

Dispose of soaked absorbent material in accordance with Federal, State, and local laws. 


KEEP OUT OF REACH OF CHILDREN. For Industrial and Institutional use only. Store in a cool, dry 

area away from heat or open flame. Do not store at temperatures above 120F. 

NFPA CODE 30B RATING: Level 3 Aerosol 


RESPIRATORY PROTECTION: If air concentrations exceed exposure limits listed in Section 2, wear 

NIOSH/MSHA approved respirator with dust filter and organic vapor cartridge. 

VENTILATION: Provide local exhaust to keep air concentrations of ingredients listed in Section 2 below 

acceptable limits. 

PROTECTIVE GLOVES: Use chemical resistant gloves to prevent hand contact. 

EYE PROTECTION: Always wear safety glasses or chemical proof goggles when working with 

chemicals. 


DATA BELOW BASED ON AEROSOL CONCENTRATE ONLY: 

BOILING POINT: >200F VAPOR DENSITY (AIR=1): > 1 

pH: N/A SPECIFIC GRAVITY (H20=1) @ 70F: 1.105 

SOLUBILITY IN WATER: Negligible APPEARANCE/ODOR: Gray Viscous Liquid, Solvent Odor 

DATA BELOW BASED ON TOTAL CONTENTS: 

VAPOR PRESSURE OF CAN (psig@ 72F): 60 TOTAL VOC %: 77.62 


STABILITY: Material Stable 

HAZARDOUS POLYMERIZATION: Will not occur 

INCOMPATIBILITY: Avoid contact with strong oxidizing agents, acids, halogen gases and alkaline 

hydroxides. 

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide, and Zinc Oxide 

fume. 


No data available. 




WASTE DISPOSAL METHOD: Aerosol cans, when emptied and depressurized through normal use, 

pose no disposal hazard and should be recycled. Consult Federal, State and local authorities for 

approved procedures. 


NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR 

RESULTS OBTAINED FROM USE. PROCHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL 

INJURY OR PROPERTY DAMAGE TO USER. VENDEE/USER ASSUMES ALL RISKS ASSOCIATED 

WITH USE.







D.O.T. HAZARD CLASS: Consumer Commodity, ORM-D 


HMIS RATING (Based on Aerosol Concentrate): 

0 – Minimal 1 – Slight 2 – Moderate 3 – Serious 4 – Extreme 

N/A = Not Applicable N/E = Not Established N/D = Not Determined =More Than 


NOTICE: The information contained on this Material Safety Data Sheet is considered accurate as of 

the date of publication. It is not necessarily all inclusive nor fully adequate in every circumstance. The 

suggestions should not be confused with, nor followed in violation of applicable laws, regulations, rules 

or insurance requirements. No warranty, express or implied, of merchantability, fitness, accuracy of 

data, or the results to be obtained from the use thereof is made. The vendor assumes no responsibility 

for injury or damages resulting from the inappropriate use of this product. 


ZINK PROOF / 1718 

NOVEMBER 2008 

PAGE 2 


HEALTH 2 

FIRE 3 

REACTIVITY 1 

P.P.E. I 





WITH USE.

M A T E R I A L S A F E T Y D A T A S H E E T 

HEALTH-2 FLAMMABILITY-2 REACTIVITY-0 PERSONAL PROTECTION-B 

================================================================================================================================================== 

IDENTITY: 1755 HI SPEED - DATED: 12-01-99 

================================================================================================================================================== 

SECTION I - MANUFACTURED FOR: 

PRO CHEM, INC. - 1475 BLUEGRASS LAKES PARKWAY - ALPHARETTA, GA. 30004 - EMERGENCY AND INFORMATION#: (800) 241-8180 

================================================================================================================================================== 

SECTION II - HAZARDOUS INGREDIENTS 

CHEMICAL NAME: ISOBUTANE PROPANE BLEND. 

OSHA PEL: 800 PPM. ACGIH TLV: 800 PPM. % RAW MTL: OTHER LIMITS: CAS#: 75-28-5 ,74-98-6. 

CHEMICAL NAME: PETROLEUM OIL. 

OSHA PEL: 5MG/ M3. ACGIH TLV: 5MG /M3. % RAW MTL: . OTHER LIMITS: CAS#: 64742-53-6. 

================================================================================================================================================== 

SECTION III - PHYSICAL DATA 

BOILING POINT: N A. APPEARANCE: DARK OIL, ODOR OF SULFURIZED OILS. 

SOLUBILITY: INSOLUBLE. SPECIFIC GRAVITY (H20=1): 1.0. 

VAPOR PRESSURE (mm Hg.): MAX 60. MELTING POINT: 

VAPOR DENSITY (AIR=1): N E. EVAPORATION RATE(): N E. 

================================================================================================================================================== 

SECTION IV - FIRE AND EXPLOSION DATA 

FLASH POINT: N A. METHOD USED: 

FLAMMABILITY LIMIT: NON-FLAMMABLE. LEL: N E. UEL: N E. 

EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL, CARBON DIOXIDE. 

SPECIAL FIRE FIGHTING PROCEDURES: SELF CONTAINED BREATHING APPARATUS. 

UNUSUAL FIRE AND EXPLOSION HAZARDS: DO NOT EXPOSE AEROSOLS TO TEMPERATURES ABOVE 130 DEG. F OR THE CONTAINER 

MAY RUPTURE. 

================================================================================================================================================== 

SECTION V - REACTIVITY DATA 

STABILITY: STABLE. CONDITIONS TO AVOID: OPEN FLAME, WELDING ARCS, HEAT. 

INCOMPATIBILITY (MATERIALS TO AVOID): STRONG OXIDIZERS. 

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: CO, CARBON DIOXIDE, SULFUR OXIDES. 

HAZARDOUS POLYMERIZATION: NO. CONDITIONS TO AVOID: NONE KNOWN. 

================================================================================================================================================== 

SECTION VI - HEALTH HAZARD DATA 

ROUTE(S) OF ENTRY: INHALATION? Y. SKIN?N INGESTION?N EYES? N 

HEALTH HAZARDS (ACUTE AND CHRONIC): INHALATION - EXCESSIVE INHALATION OF VAPORS CAN BE HARMFUL AND MAY CAUSE 

HEADACHE, DIZZINESS, ASPHYXIA, ANESTHETIC EFFECTS AND POSSIBLE UNCONSCIOUSNESS. EYES - IRRITATION. SKIN - IRRITATION. 

INGESTION - POSSIBLE CHEMICAL PNEUMONITIS IF ASPIRATED INTO LUNGS. NAUSEA. 

CARCINOGENICITY: U K. NTP? IARC MONOGRAPHS? OSHA REGULATED? 

SIGNS AND SYMPTOMS OF EXPOSURE: EYES - FLUSH WITH WATER FOR 15 MINUTES. IF IRRITATED, SEE PHYSICIAN. SKIN - WASH 

WITH SOAP AND WATER. IF IRRITATED, SEE PHYSICIAN. INHALATION - REMOVE TO FRESH AIR. RESUSCITATE IF NECESSARY. GET 

MEDICAL AID. INGESTION - CALL PHYSICIAN IMMEDIATELY. DO NOT INDUCE VOMITING. 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: MAY AGGRAVATE EXISTING EYE, SKIN, OR UPPER RESPIRATORY 

CONDITIONS. 

EMERGENCY AND FIRST AID PROCEDURES: 

================================================================================================================================================== 

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ABSORB WITH SUITABLE MEDIUM. INCINERATE OR LANDFILL 

ACCORDING TO LOCAL, STATE OR FEDERAL REGULATIONS. KEEP OUT OF SEWERS AND STREAMS. 

WASTE DISPOSAL METHOD: AEROSOL CANS WHEN VENTED TO ATMOSPHERIC PRESSURE THROUGH NORMAL USE, POSE NO DISPOSAL 

HAZARD. 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:DO NOT PUNCTURE OR INCINERATE CONTAINERS. DO NOT STORE 

AT TEMPERATURES ABOVE 130 DEG. F. 

OTHER PRECAUTIONS: AVOID FOOD CONTAMINATION. KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING VAPORS. 

================================================================================================================================================== 

SECTION VIII - CONTROL MEASURES 

RESPIRATORY PROTECTION (SPECIFY TYPE): IF VAPOR CONCENTRATION EXCEEDS TLV, USE RESPIRATOR APPROVED BY U.S. BUREAU 

OF MINES FOR ORGANIC VAPOR. 

VENTILATION: LOCAL EXHAUST: MECHANICAL (GENERAL): 

ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATION BELOW TLV. 

SPECIAL: OTHER LIMITS: 

PROTECTIVE GLOVES: NONE UNLESS SKIN IRRITATION A PROBLEM. EYE PROTECTION: SAFETY GLASSES RECOMMENDED. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: NONE. 

WORK & HYGIENIC PRACTICES: WASH WITH SOAP AND WATER BEFORE HANDLING FOOD. REMOVE CONTAMINATED CLOTHING. 

================================================================================================================================================== 

SECTION IX - SPECIAL PRECAUTIONS 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: 

OTHER PRECAUTIONS: 

================================================================================================================================================== 

SECTION 313 SUPPLIER NOTIFICATION







CHEMICAL FAMILY: Degreaser 


CAS # CHEMICAL NAMES WT % TLV (UNITS) 

111-76-2 2-butoxyethanol < 5 25 (PPM) skin 

N/E = not established 


PRIMARY ROUTE(S) OF ENTRY: Skin contact/absorption and inhalation 

SIGNS AND SYMPTOMS OF OVEREXPOSURE: Gastrointestinal irritation (nausea, vomiting, diarrhea), 

irritation to nose, throat, and respiratory tract. 

TARGET ORGAN EFFECTS: Overexposure to this material (or its components) has been suggested as a 

cause of the following effects in laboratory animals and may aggravate pre-existing disorders or these organs 

in humans: chronic ingestion may cause kidney and liver lesions at high doses. 

IMMEDIATE HEALTH EFFECTS: 

EYES: Corrosive. Exposure may cause noticeable pain, and severe irritation and transient corneal 

injury. 

SKIN: Corrosive. Causes chemical burns. Harmful contact may not cause immediate pain. 

Ethylene glycol monobutyl ether and 2-aminoethanol may be absorbed through the skin. 

INHALATION: Exposure to vapor or mist is possible. Short term inhalation is not likely to cause 

harmful effects: breathing large amounts may be harmful. Symptoms are more 

typically seen at air concentrations exceeding the recommended exposure limits. 

INGESTION: Harmful or fatal if swallowed. Causes chemical burns to mouth, throat and stomach. 

REPRODUCTIVE/DEVELOPMENTAL INFORMATION: No data. 

CARCINOGENIC INFORMATION: This material is not listed as a carcinogen by IARC, NTP, or OSHA. 

LONG TERM EFFECTS: No data. 


EYES: Immediately flush with water. Remove contact lenses, if applicable, and continue flushing 

with water for 15 minutes. Call a physician immediately. 

SKIN: Immediately flush with water for 15 minutes. Call physician if irritation persists. Completely 

decontaminate clothing, shoes, and leather goods before reuse or discard. 

INHALATION: If symptoms develop move victim to fresh air. If symptoms persist, call a physician. 

INGESTION: Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water or 

milk. Call a physician immediately. Never give anything by mouth if victim is unconscious, 

is rapidly losing consciousness or is convulsing. 


FLASH POINT: No Flash at Boil METHOD USED: C.C. Method 

EXPLOSIVE LIMITS: Not Applicable 

AUTOIGNITION TEMPERATURE: Not Applicable 

HAZARDOUS PRODUCTS OF COMBUSTION: Oxides of carbon, oxides of nitrogen, and ammonia 

EXTINGUISHING MEDIA: Not Applicable 

FIRE FIGHTING INSTRUCTIONS: Avoid contact with this material. Avoid walking in spilled 

material. Wear protective clothing for skin and eyes. 


SMALL SPILL: Absorb with an inert solid and scoop up for disposal, then rinse soiled area with water 

down the drain. 

LARGE SPILL: Stop leak at the source and collect into a suitable container, then treat as a small spill. 


FOAM-IT-AWAY / 2207 

FEBRUARY 2009 

PAGE 1 


HEALTH 2 

FIRE 0 

REACTIVITY 0 

P.P.E. B 


HANDLING: Containers of this material may be hazardous when emptied. Since emptied containers retain 

product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be 

observed. 

STORAGE: Store in a cool, dry place. Keep container closed when not in use. 


EYE PROTECTION: Chemical Splash goggle in compliance with OSHA regulations are advised: however, 

OSHA regulations also permit other type safety glasses. Consult your safety representative. 

SKIN PROTECTION: Wear rubber gloves (consult your safety equipment supplier). To prevent repeated or 

prolonged skin contact, wear impervious clothing and boots. 

RESPIRATORY PROTECTION: If workplace exposure limits of product or any component are exceeded 

(see exposure guidelines), NIOSH/OSHA approved air-supplied respirator is advised in the absence of proper 

environmental control. OSHA relations also permit other NIOSH/OSHA respirators (negative pressure type) 

under specific conditions (see your industrial hygienist). Engineering or administrative controls should be 

implemented to reduce exposure. 

ENGINEERING CONTROLS: Provide sufficient mechanical (general and local exhaust) ventilation to 

maintain exposure below level of overexposure (from known, suspected or apparent adverse effects). 


APPEARANCE/ODOR: Thin, green liquid with a floral odor 

pH CONCENTRATE: 11.5 – 12.5 

VAPOR PRESSURE: Unknown VAPOR DENSITY: Unknown 

BOILING POINT: 212F SOLUBILITY IN WATER: Complete 

PERCENT VOLATILE: 90% SPECIFIC GRAVITY (H20=1): 1.05 +/- 0.02 


CHEMICAL STABILITY: Stable 

CONDITIONS TO AVOID: Temperature extremes. 

INCOMPATIBILITY: Chlorine bleach, oxidizers, acids. 

HAZARDOUS DECOMPOSITION: Will not occur. 

HAZARDOUS POLYMERIZATION: Will not occur. 






WASTE DISPOSAL INFORMATION: Dispose of in accordance with all applicable Federal, State, and 

Local regulations. 

RCRA INFORMATION: If this material becomes a waste, it would be considered hazardous under 40 

CFR 261.22, and would be classified as EPA Waste Number D002. 





WITH USE.







DOT INFORMATION: 49 CFR 172.10 

DOT DESCRIPTION: 33440 Class 55 

DOT HAZARD CLASS: 8, NA 1760, II 

HAZARDOUS COMPONENT: Potassium Hydroxide 

REPORTABLE QUANTITY (RQ): 49 CFR 172.101 

NOT APPLICABLE 


US Federal Regulations: 

TSCA (Toxic Substances Control Act) Status 

TSCA (United States) The intentional ingredients of this product are listed. 

CERCLA RQ – 40 CFR 355 Appendix A: None 

SARA 302 Components 40 CFR Appendix A: None 

Section 311/312 Hazard Class 40 CFR 370.2: Immediate (X) Delayed (X) Fire ( ) Reactivity ( ) 

Sudden Release of Pressure ( ) 

SARA 313 Components – 40 CFR 372.65 

CAS # Chemical Names % 

N/A *Glycol Ethers 250 g/L 

North Carolina Administrative Code 2D.1104 and 2B.0610: None 

South Carolina Regulation 62.5 Standard Number 8: Ethylene Glycol Monobutyl Ether < 5.0 


The information accumulated herein is believed to be accurate but is not warranted to be whether originating 

with the company or not. Recipients are advised to confirm in advance of need that the information is current, 

applicable and suitable to their circumstances. This information was compiled from current manufacturer’s 

MSDS’s of the component parts of the product, as well as other sources, such as: 

Code of Federal Regulations 29, Revised as of July 1, 1994. 

Code of Federal Regulations 40, Revised as of July 1, 1994 

ACGIH, Guide to Occupational Exposure Values, 1996. 

ANSI Z129.1-1994, Precautionary Labeling for Hazardous Industrial Chemicals. 

Hazard Communication Handbook, A Right To Know Compliance Guide. Craig A. Moyer & Michael Francis. 

Clark Broadman Company. Ltd. New York, NY 1992 

RCRA Regulations and Keyword Index, Compiled and Published by McCoy and Associates, Inc Lakewood, 

Colorado. 1992. 


FOAM-IT-AWAY / 2207 

FEBRUARY 2009 

PAGE 2 


HEALTH 2 

FIRE 0 

REACTIVITY 0 

P.P.E. B 





WITH USE.







CHEMICAL FAMILY: Drain Opener 


NAME CAS # OSHA PEL ACGIH TLV 

Sulfuric Acid 7664-93-9 1 mg/m 3 0.2 ppm * 

Water, dye N/A N/A 

* - Threshold limit value is mist only Note – No materials listed are subject to SARA Title III reporting 


EFFECTS OF OVEREXPOSURE: 

EYE CONTACT: Corrosive to eyes on contact, including corneal damage or blindness. 

SKIN CONTACT: Corrosive to skin on contact, including inflammation and blistering. 

INGESTION: Will cause abdominal pain, nausea, vomiting, destruction of tissue in the 

gastrointestinal tract. 

INHALATION: Spray mist may cause irritation, burning, destruction of tissue. Symptoms 

may include coughing, choking, pain, or shortness of breath. Severe 

overexposure may lead to fatal lung damage. 

HEALTH HAZARDS: 

1) ACUTE: Causes burns/irritation to eye, skin and respiratory tract. 

2) CHRONIC: Prolonged exposure to spray mist may produce respiratory irritation leading 

to frequent attacks of bronchial infection. 

National Toxicological Program: NO I.A.R.C. Monographs: NO OSHA: NO 


EMERGENCY FIRST AID PROCEDURES: 

EYE CONTACT: Immediately flush with cool running water for at least 15 minutes. Remove 

contact lenses while continuing to flush. Get medical attention. 

INGESTION: Call Physician or Poison Control immediately. Give lots of water to drink. 

DO NOT INDUCE VOMITING. Never give anything by mouth to an 

unconscious person. 

SKIN CONTACT: Immediately flush with water for 15 minutes. Remove clothing and wash 

before reuse. 

INHALATION: Remove to fresh air. If breathing is difficult get medical help. 


FLAMMABILITY LIMITS (% IN AIR): N.A. FLASH POINT (CC): N.A. 

FLAMMABILITY CLASSIFICATION: N.A. 

RECOMMENDED EXTINGUISHING MEDIA: Dry Chemical or CO2 

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should be equipped with protective gear 

including self-contained breathing apparatus. 

UNUSUAL FIRE/EXPLOSION HAZARDS: Product will react violently with water. 


PROCEDURES IF MATERIAL IS SPILLED OR RELEASED: Use proper protective equipment. Dike 

or dam large spills. Absorb spill on inert absorbent material. Pick-up and place in clean DOT specified 

container for disposal. Rinse area with water. 


RAM ROD / 2404 

NOVEMBER 2009 

PAGE 1 


HEALTH 3 

FIRE 0 

REACTIVITY 2 

P.P.E. C 


PRECAUTIONS IN HANDLING AND STORAGE AND OTHER PRECAUTIONS: Practice good industrial 

hygiene in the handling of these products. Avoid spills and splashing of opened products. Store product in 

tightly closed original container. Store in a cool dry place. Provide adequate ventilation. KEEP OUT OF 

REACH OF CHILDREN. 


RESPIRATORY PROTECTION: NIOSH/MSHA approved respirator to prevent breathing spray mists. 

VENTILATION: Local exhaust recommended. 

PROTECTIVE GLOVES: Latex, rubber or neoprene. 

EYE PROTECTION: Safety glasses or splash goggles. 

OTHER PROTECTIVE EQUIPMENT: Rubber apron, boots, as well as an eye wash station are strongly 

recommended. 


BOILING RANGE: 550F SPECIFIC GRAVITY (H20=1): 1.84 

VAPOR PRESSURE (mmHg): 1.0 @ 300F SOLUBILITY IN H20: Complete 

VAPOR DENSITY (AIR=1): None EVAPORATION RATE (WATER=1): >1.0 

REACTIVITY IN WATER: Mixes violently with water with generation of heat. 

APPEARANCE & ODOR: Red to amber liquid with no odor. pH: < 1 


STABILITY: Stable under normal conditions 

INCOMPATIBILITY WITH OTHER MATERIALS: Contact with metals, strong oxidizers, strong alkalies may 

cause high energy release. 

HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen gas on contact with some metals 


CONDITIONS TO AVOID: See incompatibility statement. 






WASTE DISPOSAL PROCEDURES: Dispose of in accordance with local, state and federal pollution 

regulations. 


DOT HAZARD CLASS: Sulfuric Acid, 8 UN 1830, PGII; UN1789, PGII 




This information is believed to be accurate and represents the best information currently available to Pro Chem, Inc. 

However, we make of merchantability or any other warranty, express or implied, with respect to such information, and 

we assume no liability resulting from its use. Users should make their own investigations to determine the suitability 

of the information. 





WITH USE.

KESTER SOLDER 

Material Safety Data Sheet 

Page: 1 of 6 

MSDS Number: 44 Core 

Date Prepared: 31-Aug-01 

Product Identifier As Used On Label: 

Product Use: 

Manufacturer's Name and Address 

SECTION 1 - CHEMICAL PRODUCT AND COMPANY INFORMATION 

KESTER SOLDER 

DIVISION OF LITTON SYSTEMS, INC. 

515 E. TOUHY AVENUE 

DES PLAINES, IL 60018 USA 

Supplier's Name and Address (if different from manufacturer) 

Telephone Number For Information: (847) 297-1600 CHEMTREC 24-Hour Emergency Telephone Number: (800) 424-9300 

NA = Not Applicable NE = Not Established UN = Unknown 

SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS 

HAZARDOUS INGREDIENTS 1 % or greater 

CARCINOGENS 0.1 % or greater 

Lead 

Tin 

Silver 

Bismuth 

Antimony 

Rosin 

NON-HAZARDOUS INGREDIENTS 

"44" ROSIN FLUX CORED SOLDER 

Soldering flux in cored solder for electrical or electronic applications. 

C.A.S. 

Number 

7439-92-1 * 

7440-31-5 

7440-22-4 * 

7440-69-9 

7440-36-0 * 

8050-09-7 

NOTES: * See Section 15 for U.S.A. Regulatory Information. 

Weight 

Percent 

OSHA 

PEL 

ACGIH TLV LD 50 

TWA ingested 

mg/m³ 

g / Kg 

** Composition and weight % of solder alloys varies widely and can be determined by product label. Flux in core is 

typically 1-3% by weight. 

** 

** 

** 

** 

** 

< 3 

mg/m³ 

0.05 

2 

0.01 

NE 

0.5 

NE 

0.15 

2 

0.1 

NE 

0.5 

NE 

NE 

NE 

NE 

NE 

7.0 Rat 

NE 

LC 50 

inhaled 

g / m³ 

NE 

NE 

NE 

NE 

NE 

NE 

OSHA: Occupational Safety and Health Administration 

PEL: Permissible Exposure Limit 

ACGIH: American Conference of Government Industrial Hygienists 

TLV: Threshold Limit Values 

STEL: Short-Term Exposure Limit 

TWA: Time Weighted Average 

C.A.S. Chemical Abstract Service 

Form Number: 1F-RD-G-02-01B

KESTER SOLDER 

Page: 2 of 6 



SECTION 3 - HAZARDS IDENTIFICATION 

EMERGENCY OVERVIEW 

Hot solder can burn eyes and skin. Fumes during soldering are irritating to eyes and may cause 

headache and respiratory system irritation or damage. Prolonged or repeated exposure to rosin 

flux fumes during soldering may result in allergic reaction in a sensitive person, resulting in 

asthma symptoms. 

ECC (Europe) DANGEROUS SUBSTANCES 

HAZARD DESIGNATION: 

G 

PRIMARY EXPOSURE: 

R-PHRASES (Risks to Humans or the Environment): 

R 61 - May cause harm to the unborn child. 

Fumes during soldering may contain droplets of rosin and/or other organic decomposition products. Skin contact from 

handling and decomposition products when heating with soldering iron. 

PRIMARY ROUTES OF ENTRY: Skin Eyes Inhalation Ingestion 

TARGET ORGANS: 

Flux fumes: eyes, mucous membranes and respiratory system. Ingestion of lead metal can affect kidneys, gastrointestinal, 

reproductive and neurological systems. 

POTENTIAL HEALTH EFFECTS OF ACUTE (severe short-term) EXPOSURE: 

INHALATION: Flux fumes during soldering may cause irritation and damage of mucous membranes and respiratory 

system. 

EYE CONTACT: Irritation from contact with smoke from soldering. 

SKIN CONTACT: Possible local irritation by contact with flux or fumes. 

INGESTION: May be harmful if swallowed. 

SKIN ABSORPTION: None. 

POTENTIAL HEALTH EFFECTS OF CHRONIC (prolonged) EXPOSURE: 

Smoke during soldering will contain rosin which is an allergen that can cause eye irritation and respiratory system irritation 

and damage. Repeated inhalation or ingestion of lead can result in systemic poisoning. 

Medical Conditions Generally Aggravated by Exposure: 

Chemical hypersensitivity, asthma and other respiratory conditions, existing eye and skin disorders. Lead: Diseases of the 

blood and blood-forming organs, kidneys, nerves and possibly reproductive systems. 

CARCINOGENICITY/ 

Xn Harmful 

R 62 - Possible risk of impaired fertility. 

R 33 - Danger of cumulative effects. 

R 36/37/38 - Irritating to eyes, respiratory system and skin. 

NTP OSHA IARC Not Listed 

TERATOGENICITY / MUTAGENICITY: See Sections 11 and 15 for additional information. 


KESTER SOLDER 

Page: 3 of 6 



SECTION 4 - FIRST AID MEASURES 

Seek medical assistance for further treatment, observation and support if needed. 

EYE CONTACT: For burns flush immediately with cool water and get medical attention. For fume irritation use eye drops and 

remove from exposure. 

SKIN CONTACT: For burns flush immediately with cool water. If a rash develops from flux fumes, remove person from 

exposure and wash skin with soap and water. 

INHALATION: Remove person from exposure to fumes. 

INGESTION: Not likely to occur. 

SECTION 5 - FIRE FIGHTING MEASURES 

Flammability: No Yes Conditions to avoid: 

Flash Point (T.O.C): NA °F NA °C 

Auto-Ignition Temperature: 

Flammability Limits percent by volume in air: LEL: NA 

UEL: 

Extinguishing Means: Water Carbon Dioxide Alcohol Foam Dry Chemical 

Hazardous Combustion Products: 

Explosion Sensitivity: Impact - None Identified Static Discharge Sensitivity: 

Special Firefighting Procedures: 

Unusual Fire and Explosion Hazards: 

Steps to be Taken if Material is Spilled or Released: 

NE 

NA 

NA °F NA °C 

Carbon monoxide, carbon dioxide. Melted solder above 1000 °F will liberate toxic lead 

and/or antimony fumes. 

Avoid breathing smoke. Wear self-contained breathing apparatus if this material is in the 

vicinity of a fire. 

Flux in cored solder may ignite when the solder melts in a fire. 

SECTION 6 - ACCIDENTAL RELEASE MEASURES 

SECTION 7 - HANDLING AND STORAGE 

Storage Precautions: Exposure to sulfur or to high humidity will tarnish the solder surface. 

Handling Precautions: Do not place flux-cored solder into a hot solder pot because the flux may ignite. 

Yes No 

Melted solder will solidify on cooling and can be scraped up. Use caution to avoid breathing fumes if a gas torch is used to 

cut up large pieces. 

Personal Precautions: Avoid breathing smoke / fumes generated during soldering. Wash hands after handling solder before 

eating or smoking. 


KESTER SOLDER 

Page: 4 of 6 



VENTILATION 

TO BE USED: 

Respiratory Protection: 

SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION 

Provide adequate exhaust ventilation (general and / or local) if necessary to meet exposure requirements. 

Local exhaust ventilation is preferred to minimize dispersion of smoke and fumes into the work area. 

Protective Gloves: Wear rubber or cloth gloves to avoid skin 

contact. 

Eye Protection: 

Other Protective Clothing and Equipment: 

Hygienic Work Practices: 

Physical State at 20 °C: 

Boiling Point (760 mm Hg): 

Vapor Pressure (mm Hg at 20 °C): 

Vapor Density (air = 1): 

Solubility in Water (% by weight): 

pH: 

NA 

Freezing Point (760 mm Hg): 

Appearance and Odor: 

When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator 

or self-contained breathing apparatus should be worn. 

None. 

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 

SECTION 10 - STABILITY AND REACTIVITY 

Safety glasses or goggles should be used. 

Wash hands thoroughly after handling chemicals or solder containing lead before eating or 

smoking. 

Solid 

NA 

NA °F NA °C 

0 

ND 

NA °F NA °C 

Specific Gravity (water = 1 at 25 °C): 

Melting Point: 

Evaporation Rate (butyl acetate = 1): 

Percent Volatile (by volume): 

Volatile Organic Compound (VOC): 

Odor Threshold: 

>212 

Coefficient of Water / Oil Distribution: 

Silver-gray metal in wire, ribbon or preformed shapes with a core of flux, no odor. 

Chemical Stability: Stable Unstable Conditions to avoid: 

Incompatibility (materials to avoid): 

Hazardous Decomposition Products: 

HAZARDOUS POLYMERIZATION: 

Strong acid, strong oxidizers 

NE 

>7 

°F >100°C 

When heated to soldering temperatures, the rosin may be thermally degraded to liberate aliphatic aldehydes, acids and 

terpenes. No lead or antimony are detected in fumes from soldering below 1000 °F (537 °C). 

May Occur 

Will Not Occur 

Conditions to avoid: 

NE 

Not applicable. 

NA 

0 

NE 

% 

NA g / Liter 


KESTER SOLDER 

Page: 5 of 6 



SECTION 11 - TOXICOLOGICAL INFORMATION 

EXPOSURE LIMITS: Not determined for the product. See Section 2 for ingredients. 

Lead can accumulate in bone and body organs, and elimination from the body is slow. Medical examinations are advised for 

persons repeatedly exposed to levels above the exposure limit for lead. Lead is classified as a Group 2B carcinogen by the 

International Agency for Research on Cancer (IARC) and the U.S. Environmental Protection Agency (EPA). Women of childbearing 

age should avoid chronic exposure to lead because of possible effects on reproduction and potential injury to a 

developing fetus. 

Keep out of waterways. 

Waste Disposal Methods: 

Solder can be reclaimed. 

CAUTION: 

DOT (U.S.A.): 

TDG (Canada): Not Regulated 

SECTION 12 - ECOLOGICAL INFORMATION 

SECTION 13 - DISPOSAL CONSIDERATIONS 

Empty containers may contain product residue. Observe all label precautions. 

Not Regulated 

SECTION 14 - TRANSPORT INFORMATION 


KESTER SOLDER 

Page: 6 of 6 



U.S.A.: 

Canada: 

Europe: 

NFPA Rating: 

HMIS Rating: 

Prepared By: 

SECTION 15 - REGULATORY INFORMATION 

All Chemical substances in this product are listed in the EPA (Environmental Protection Agency) TSCA 

(Toxic Substances Control Act) Inventory. 

USEPA - Lead and its compounds are placed in Class B2, probably carcinogenic to humans. 

IARC - Lead and its compounds are placed in Class 2B, possibly carcinogenic to humans. 

*This chemical is subject to the reporting requirements of Section 313 of Title III of the USA Superfund 

Amendment and Reauthorization Act (SARA) of 1986 and 40 CFR, Part 372. 

California Proposition 65: 

WHMIS (Workplace Hazardous Materials Information System) CLASSIFICATION: 

This product has been classified in accordance with the hazard criteria of the Canadian Controlled 

Product Regulations (CPR) and the MSDS contains all the information required by the CPR. 

D2A 

European Council Directive 67/548/EEC 

PREPARATION INFORMATION 

Revision Summary: 

Telephone Number: (847) 297-1600 

This product contains chemicals known to the State of California to cause cancer and 

birth defects or other reproductive harm. 

• DANGEROUS SUBSTANCES HAZARD CLASSIFICATION: 

• R-PHRASES (Risks to Humans or the Environment) 

R 61 - May cause harm to the unborn child. 

R 62 - Possible risk of impaired fertility. 

R 33 - Danger of cumulative effects. 

R 36/37/38 - Irritating to eyes, respiratory system and skin. 

• S-PHRASES (Safety Precautions for Storing, Handling and Using the Product) 

S 2 - Keep out of reach of children. 

S 20/21 - When using do not eat, drink or smoke. 

S 23 - Do not breathe the fumes. 

SECTION 16 - OTHER INFORMATION 

Health: 1 Flammability: 1 Reactivity: 0 Special: 

Health: 1 Flammability: 1 Reactivity: 0 Personal Protection: X 

Change of format and new data in most sections. 

D. Bernier Date Prepared: 31-Aug-01 

Supersedes: 

T - Toxic Xn - Harmful 

20-Jun-01 

The information contained herein is based on data considered accurate and is offered solely for information, consideration and investigation. 

Kester Solder extends no warranties, makes no representations and assumes no responsibility as to the accuracy, completeness or suitability of 

this data for any purchaser's use. The Data on this Material Safety Data Sheet relates only to this product and does not relate to use with any 

other material or in any process. All chemical products should be used only by or under the direction of technically qualified personnel who are 

aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication regulations require that employees must 

be trained how to use a Material Safety Data Sheet as a source for Hazard information. 


MATERIAL SAFETY DATA SHEET 02458 Pg. 1 

Issued: 04/30/09 

1. Chemical Product and Contact Information 

Product Name: Abrasive Grinding Wheel Part Numbers: 

(Aluminum Oxide) 810-339, 812-231 

LECO Corporation 

3000 Lakeview 

St. Joseph, Michigan 49085 

Information: 269-983-5531 

Chemtrec: 800-424-9300 

(Chemtrec Int'l: 703-527-3887) 

2. Composition/Information on Ingredients 

OSHA ACGIH Typical % 

Component CAS No. PEL (mg/m3) TLV (mg/m3) by Weight 

Aluminum Oxide 1344-28-1 10 (total) 10 (total) 96 

3. Hazard Identification 


No unusual fire or spill hazard; irritant health hazard. 

Potential Health Effects 

EYES: Dust may irritate. 

SKIN: Some may experience irritation. 

INHALATION: Coughing, shortness of breath. 

INGESTION: No known adverse effects, but not recommended. 

MEDICAL CONDITIONS AGGRAVATED: Persons with chronic respiratory or dermatological 

disorders may be at increased risk from exposure. 

CHRONIC OVEREXPOSURE: Prolonged exposure may affect lung function. 

ACUTE OVEREXPOSURE: Not available. 

CARCINOGENICITY: None. 

P/N: 810-339


4. First Aid Measures 

EYES: Flush with water for at least 15 minutes. 

SKIN: Wash exposed area with soap and water. 

INHALATION: Remove to fresh air. 

INGESTION: Contact a physician. 

5. Fire Fighting Measures 

FLAMMABLE PROPERTIES: Non-flammable. 

Flash Point: None. Method Used: Not applicable. 

Flammable Limits (% by Volume in Air): 

Lower: None. Upper: None. 

AUTO-IGNITION TEMPERATURE: Not applicable. 

HAZARDOUS COMBUSTION PRODUCTS: None. 

EXTINGUISHING MEDIA: Use agent appropriate for surrounding fire. 

FIREFIGHTING INSTRUCTIONS: No special instructions. 

6. Accidental Release Measures 

SMALL/LARGE SPILL: Sweep up and collect for disposal. 

7. Handling and Storage 

HANDLING: No special precautions needed. 

STORAGE: Keep container closed. 

8. Exposure Controls/Personal Protection 

ENGINEERING CONTROLS: Mechanical or local exhaust ventilation recommended. 

RESPIRATORY PROTECTION: NIOSH/MSHA respirator if exposure limits exceeded. 

SKIN AND HAND PROTECTION: Protective gloves recommended. 

EYE AND FACE PROTECTION: Safety glasses with side shields. 

OTHER PROTECTIVE EQUIPMENT: Not available. 

P/N: 810-339


9. Physical and Chemical Properties 

APPEARANCE: Brown to black solid. 

BOILING POINT: Not available. 

FREEZE-MELT POINT: Not available. 

VAPOR PRESSURE (mm): Not available. 

VAPOR DENSITY (air = 1): Not available. 

SOLUBILITY IN WATER: Insoluble. 

SPECIFIC GRAVITY: 2.50 

pH: Not available. 

ODOR: None. 

PERCENT VOLATILES: 0 

EVAPORATION RATE (Butyl Acetate = 1): Not available. 

10. Stability and Reactivity 

CHEMICAL STABILITY: Stable. 

INCOMPATIBILITY: Not available. 

HAZARDOUS DECOMPOSITION PRODUCTS: None. 

HAZARDOUS POLYMERIZATION: None. 

11. Toxicological Information 

None reported. 

12. Ecological Information 

Not available. 

13. Disposal Consideration 

Recycle or dispose of in accordance with federal, state & local regulations. 

14. Transportation Information 

U.S.A. DOT: Not regulated. 

P/N: 810-339


15. Regulatory Information 

U.S. FEDERAL REGULATIONS: 

TSCA STATUS: On Toxic Substance Control Inventory. 

CERCLA REPORTABLE QUANTITY: None. 

SARA TITLE III: 

Section 302 Extremely Hazardous Substances: None. 

Section 311/312 Hazardous Categories: Acute, Chronic. 

Section 313 Toxic Chemicals: Aluminum Oxide 

(Fibrous Forms only) 

RCRA STATUS: Not regulated. 

CANADIAN REGULATIONS: 

WHMIS: Not regulated. 

16. Other Information 

Hazard Index: (0 - 4, 4 = Extreme) 

Health: 1 Fire: 0 Reactivity: 0 

Prepared By: 

Jason Whitt 

Information herein is given in good faith as authoritative and valid; however, no warranty, expressed 

or implied can be made. 

P/N: 810-339

Acetone, NF AX0126 1/1 


Acetone, NF 

1 . Product and company identification 

Product name : Acetone, NF 

Product code : AX0126 

Supplier : EMD Chemicals Inc. 

480 S. Democrat Rd. 

Gibbstown, NJ 08027 

856-423-6300 Technical Service 

Monday - Friday: 8:00 - 5:00 PM 

Synonym : Dimethyl Ketone; 2-Propanone 

Material uses : Other non-specified industry: Analytical reagent. 

Validation date : 02/24/2009 

In case of emergency : 800-424-9300 CHEMTREC (USA) 

613-996-6666 CANUTEC (Canada) 

24 Hours/Day: 7 Days/Week 

2 . Hazards identification 

Emergency overview : DANGER! 

EXTREMELY FLAMMABLE LIQUID AND VAPOR. 

HARMFUL IF INHALED OR SWALLOWED. 

CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. 

VAPOR MAY CAUSE FLASH FIRE. 

MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: RESPIRATORY TRACT, SKIN, EYES, 

CENTRAL NERVOUS SYSTEM. 

Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, 

skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for 

use. Wash thoroughly after handling. 

Physical state : Liquid. 

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion. 

Potential acute health effects 

Inhalation : Toxic by inhalation. Irritating to respiratory system. 

Ingestion : Toxic if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. 

Skin : Irritating to skin. 

Eyes : Irritating to eyes. 

Potential chronic health effects 

Carcinogenicity : No known significant effects or critical hazards. 

Mutagenicity : No known significant effects or critical hazards. 

Teratogenicity : No known significant effects or critical hazards. 

Developmental effects : No known significant effects or critical hazards. 

Fertility effects : No known significant effects or critical hazards. 

Target organs : May cause damage to the following organs: upper respiratory tract, skin, eyes, central nervous system (CNS). 

Medical conditions aggravated by : Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be 

over-exposure 

aggravated by over-exposure to this product. 

See toxicological information (section 11) 

3 . Composition/information on ingredients 

Name CAS number % by weight 

Acetone 67-64-1 100 

4 . First aid measures 

Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, 

occasionally lifting the upper and lower eyelids. Get medical attention immediately. 

Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing 

contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get 

medical attention immediately.

Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, 

provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or 

waistband. Get medical attention immediately. 

Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never 

give anything by mouth to an unconscious person. Get medical attention immediately. 

5 . Fire-fighting measures 

Flammability of the product : Extremely flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, 

with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. 

Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and 

flash back. Runoff to sewer may create fire or explosion hazard. 

Extinguishing media : Use dry chemical, CO2 , water spray (fog) or foam. 

Not suitable : Do not use water jet. 

Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action 

shall be taken involving any personal risk or without suitable training. Move containers from fire area if this 

Hazardous thermal decomposition 

products 

can be done without risk. Use water spray to keep fire-exposed containers cool. 

: Decomposition products may include the following materials: 

carbon dioxide 

carbon monoxide 

Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) 

fire-fighters 

with a full face-piece operated in positive pressure mode. 

Special remarks on fire hazards : Dangerous fire and explosion risk. Vapor may travel a considerable distance to source of ignition and flash 

back. 

6 . Accidental release measures 

Personal precautions : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. 

Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. 

Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. 

Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate 

personal protective equipment (see section 8). 

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform 

the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 

Methods for cleaning up 

Spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into 

sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, 

absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal 

according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose 

of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the 

spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. 

Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate 

waste disposal container. 

7 . Handling and storage 

Handling : Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate 

ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and 

confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made 

from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open 

flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) 

equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid 

fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and 

equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not 

reuse container. 

Storage : Store in accordance with local regulations. Store in a segregated and approved area. Store in original 

container, protected from direct sunlight. Eliminate all ignition sources. Separate from oxidizing materials. 

Keep container tightly closed and sealed until ready for use. Containers that have been opened must be 

carefully resealed and kept upright to prevent leakage. 

8 . Exposure controls/personal protection 

Ingredient Exposure limits 

Acetone ACGIH (United States, 1996). 

STEL: 1782 mg/m³ 15 minute(s). 

TWA: 1188 mg/m³ 8 hour(s). 

OSHA (United States, 1989). 



ACGIH TLV (United States, 1/2008).

TWA: 500 ppm 8 hour(s). 


STEL: 750 ppm 15 minute(s). 


OSHA PEL 1989 (United States, 3/1989). 





NIOSH REL (United States, 6/2008). 



OSHA PEL (United States, 11/2006). 



Consult local authorities for acceptable exposure limits. 

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering 

controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The 

engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. 

Use explosion-proof ventilation equipment. 

Hygiene measures 

Personal protection 

: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and 

using the lavatory and at the end of the working period. Appropriate techniques should be used to remove 

potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations 

and safety showers are close to the workstation location. 

Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk 

assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure 

levels, the hazards of the product and the safe working limits of the selected respirator. 

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when 

handling chemical products if a risk assessment indicates this is necessary. Recommended: butyl rubber 

Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is 

necessary to avoid exposure to liquid splashes, mists or dusts. Recommended: splash goggles 

Skin : Personal protective equipment for the body should be selected based on the task being performed and the risks 

involved and should be approved by a specialist before handling this product. 

Recommended: lab coat 

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the 

requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering 

modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 

9 . Physical and chemical properties 

Physical state : Liquid. 

Flash point : Closed cup: -18.15°C (-0.67°F) 

Auto-ignition temperature : 464.85°C (868.7°F) 

Flammable limits : Lower: 2.6% 

Upper: 12.8% 

Color : Colorless. 

Odor : Pungent. 

Molecular weight : 58.09 g/mole 

Molecular formula : C3-H6-O 

pH : Not available. 

Boiling/condensation point : 56.1°C (133°F) 

Melting/freezing point : -94.2°C (-137.6°F) 

Critical temperature : 234.9°C (454.8°F) 

Relative density : 0.791 

Vapor pressure : Not available. 

Vapor density : 2 [Air = 1] 

Odor threshold : 100 ppm 

Evaporation rate : 6.06 compared with(n-BUTYL ACETATE=1) 

Solubility : Soluble in the following materials: water 

10 . Stability and reactivity 

Chemical stability : The product is stable. 

Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. 

Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. 

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind 

or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. 

Do not swallow. 

Materials to avoid : Extremely reactive or incompatible with the following materials: oxidizing materials and acids. 

Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

Conditions of reactivity : Extremely flammable in the presence of the following materials or conditions: open flames, sparks and static 

discharge, heat, shocks and mechanical impacts and oxidizing materials. 

Dangerous fire and explosion risk. Vapor may travel a considerable distance to source of ignition and flash

ack. 

Extremely explosive in the presence of the following materials or conditions: open flames, sparks and static 

discharge, heat, shocks and mechanical impacts and oxidizing materials. 

11 . Toxicological information 

Acute toxicity 

Product/ingredient name Test Route Species Result 

Acetone LD50 Intravenous Rat 5500 mg/kg 

LD50 Oral Rabbit 5340 mg/kg 

LD50 Oral Rat 5800 mg/kg 

LDLo Oral Human 714 mg/kg 

LDLo Dermal Rabbit 20 mL/kg 

LDLo Intraperitoneal Rat 500 mg/kg 

LDLo Oral Dog 8000 mg/kg 

TDLo Oral Rat 5 mL/kg 

LC50 Inhalation Vapor Rat 50100 mg/m3 

Carcinogenicity 

Classification 

Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA 

Acetone A4 - - - - - 

No known significant effects or critical hazards. 

Mutagenicity 


Teratogenicity 


12 . Ecological information 

Aquatic ecotoxicity 

Product/ingredient name Result Species Exposure 

Acetone Acute EC50 13500 mg/L Daphnia 48 hours 

Acute EC50 8990 mg/L Fish 48 hours 

Acute EC50 23.5 mg/L Daphnia 48 hours 

Acute LC50 5540 mg/L Fish 96 hours 

Acute LC50 >100 mg/L Daphnia 96 hours 

Acute LC50 >100 mg/L Fish 96 hours 

Acute LC50 6900 mg/L Fresh Daphnia - Water flea - Daphnia 48 hours 

water 

magna 

Acute LC50 5.54 to 6.33 ml/L Fish - Rainbow trout,donaldson trout 96 hours 

Fresh water 

- Oncorhynchus mykiss - 1 g 

Acute LC50 8300000 ug/L Fresh Fish - Bluegill - Lepomis 

96 hours 

water 

macrochirus - 5.3 to 7.2 cm - 3.5 to 

3.9 g 

Acute LC50 8120000 to Fish - Fathead minnow - Pimephales 96 hours 

8760000 ug/L Fresh water promelas - 33 days - 22.6 mm - 

0.159 g 

Acute LC50 8098000 to Daphnia - Water flea - Ceriodaphnia 48 hours 

8640000 ug/L Fresh water dubia - Neonate - 100000 ug/L Fresh Fish - Fathead minnow - Pimephales 96 hours 

water 

promelas - Juvenile (Fledgling, 

Hatchling, Weanling) - 0.2 to 0.5 g 

Acute LC50 13300000 ug/L Daphnia - Water flea - Daphnia 48 hours 

Fresh water 

magna -

11300000 ug/L Marine water cm 

Acute LC50 10700000 ug/L Fish - Fathead minnow - Pimephales 96 hours 

Fresh water 

promelas - 25 mm 

Acute LC50 9218000 to Daphnia - Water flea - Daphnia 48 hours 

14400000 ug/L Fresh water magna - Neonate -

equired by the Controlled Products Regulations. 

EU regulations 

Hazard symbol or : 

symbols 

Risk phrases : R11- Highly flammable. 

R36- Irritating to eyes. 

Safety phrases : S2- Keep out of the reach of children. 

S9- Keep container in a well-ventilated place. 

S16- Keep away from sources of ignition - No smoking. 

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 

International regulations 

International lists : Australia inventory (AICS): This material is listed or exempted. 

China inventory (IECSC): This material is listed or exempted. 

Japan inventory (ENCS): This material is listed or exempted. 

Japan inventory (ISHL): Not determined. 

Korea inventory (KECI): This material is listed or exempted. 

New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted. 

Philippines inventory (PICCS): This material is listed or exempted. 

16 . Other information 

National Fire Protection Association 

(U.S.A.) 

: 

Health 130Flammability Special Instability 

Notice to reader 

The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information 

purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the 

necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make 

independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these 

materials and the safety and health of employees and customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO 

REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A 

PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION 

REFERS.




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DR 


acc. to ISO/DIS 11014 

Page 1/10 

Printing date 01/29/2009 Reviewed on 01/29/2009 

1 Identification of substance 

Product details 

Trade name: ACID CORE 

Application of the substance / the preparation: Flux cored solder 

Manufacturer/Supplier: 

Kester Tel.(847) 297-1600 

800 W. Thorndale Ave. Fax.(847) 390-9338 

Itasca, IL 60143 

Information department: 

Emergency information: 

CHEMTREC 24-Hour Emergency Response Telephone Number : (800) 424-9300 

CHEMTREC 24-Hour Emergency Response (Outside US & Canada) Telephone Number : (703) 527-3887 

2 Hazards identification 

WHMIS Hazard Symbols 

< 

Information pertaining to particular dangers for man and environment: 

The product has to be labelled due to the calculation procedure of international guidelines. 

Harmful by inhalation, in contact with skin and if swallowed. 

Danger of cumulative effects. 

Limited evidence of a carcinogenic effect. 

May cause sensitisation by skin contact. 

Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if 

swallowed. 

Possible risk of impaired fertility. 

Possible risk of irreversible effects. 

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. 

NFPA ratings (scale 0 - 4) 

3 1 0 

Health = 3 

Fire = 1 

Reactivity = 0 

HMIS-ratings (scale 0 - 4) 

HEALTH 3 

FIRE 1 

REACTIVITY 0 

Health = 3 

Fire = 1 


GHS label elements 

(Contd. on page 2) 

USA

DR 



Page 2/10 



~ Warning 

3.5/2 - Suspected of causing genetic defects. 

3.6/2 - Suspected of causing cancer. 

3.7/2 - Suspected of damaging fertility or the unborn child. 

3.9/2 - May cause damage to organs through prolonged or repeated exposure. 

~ Warning 

3.1/4 - Harmful if swallowed. 

3.1/4 - Harmful in contact with skin. 

3.1/4 - Harmful if inhaled. 

3.4/1 - May cause an allergic skin reaction. 

4.1/3 - Harmful to aquatic life with long lasting effects. 

Prevention: 

Obtain special instructions before use. 

Do not handle until all safety precautions have been read and understood. 

Do not breathe dust/fume/gas/mist/vapours/spray. 

Avoid breathing dust/fume/gas/mist/vapours/spray. 

Wash thoroughly after handling. 

Do not eat, drink or smoke when using this product. 

Use only outdoors or in a well-ventilated area. 

Contaminated work clothing should not be allowed out of the workplace. 

Avoid release to the environment. 

Wear protective gloves/protective clothing/eye protection/face protection. 

Use personal protective equipment as required. 

Response: 

IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. 

IF ON SKIN: Wash with plenty of soap and water. 

IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. 

IF exposed or concerned: Get medical advice/attention. 

Call a POISON CENTER or doctor/physician if you feel unwell. 

Get medical advice/attention if you feel unwell. 

Specific treatment (see label). 

Specific measures (see label). 

Rinse mouth. 

If skin irritation or rash occurs: Get medical advice/attention. 

Wash contaminated clothing before reuse. 

Storage: 

Store locked up. 

Disposal: 

Dispose of contents/container in accordance with local/regional/national/international regulations. 

(Contd. of page 1) 

USA 

(Contd. on page 3)

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Page 3/10 



3 Composition/Data on components 


Chemical characterization 

Description: Mixture of the substances listed below with nonhazardous additions. 

Dangerous components: 

7440-31-5 tin 0-100% 

7439-92-1 lead 

0-100% 

Danger: 3.1.O/3, 3.1.I/4 

~ 

Warning: 3.7/2 ~ 

7440-50-8 copper 0-100% 

7440-36-0 antimony 0-100% 

7440-69-9 bismuth 0-100% 

7440-22-4 silver 0-100% 

7440-66-6 zinc 0-100% 

7646-85-7 zinc chloride 

Danger: ~ 3.1.O/3; ~ 3.2/1B 

Warning: ~ 4.1.C/1 

142-04-1 anilinium chloride 

Danger: ~ 3.1.O/3, 3.1.D/3, 3.1.I/3, 3.4.S/1; ~ 3.9/1, 3.5/2, 3.6/2; ~ 3.3/1 

Warning: ~ 4.1.A/1 

Additional information: 

Composition and weight percent of solder alloys varies widely and can be determined by product label. 

Flux in core is typically 1-3% by weight. 

4 First aid measures 

≤ 2.5% 

≤ 2.5% 

General information: 

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after 

the accident. 

After inhalation: 

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. 

After skin contact: Immediately wash with water and soap and rinse thoroughly. 

After eye contact: Rinse opened eye for several minutes under running water. 

After swallowing: Seek immediate medical advice. 

5 Fire fighting measures 

Suitable extinguishing agents: 

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 

Special hazards caused by the material, its products of combustion or resulting gases: 

Melted solder above 1000°F will liberate toxic lead and/or antimony fumes. 

In case of fire, the following can be released: 

Carbon monoxide (CO) 

Carbon dioxide (CO2) 


USA

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Nitrogen oxides (NOx) 

Protective equipment: Wear self-contained respiratory protective device. 

6 Accidental release measures 


Person-related safety precautions: 

Ensure adequate ventilation 

Wear protective clothing. 

Measures for environmental protection: Do not allow product to reach sewage system or any water course. 

Measures for cleaning/collecting: 

Melted solder will solidify on cooling and can be scraped up. Use caution to avoid breathing fumes if a gas torch is 

used to cut up large pieces. 

7 Handling and storage 

Handling: 

Information for safe handling: Ensure good ventilation/exhaustion at the workplace. 

Information about protection against explosions and fires: Keep respiratory protective device available. 

Storage: 

Requirements to be met by storerooms and receptacles: No special requirements. 

Information about storage in one common storage facility: Not required. 

Further information about storage conditions: Store in dry conditions. 

8 Exposure controls and personal protection 

Additional information about design of technical systems: No further data; see item 7. 

Components with limit values that require monitoring at the workplace: 

7440-31-5 tin 

PEL 2 mg/m³ 

Metal 

REL 2 mg/m³ 

Tin, Metal 

TLV 2 mg/m³ 

7440-50-8 copper 

PEL 0.1*;1** mg/m³ 

*fume **dusts & mists 

REL 0.1*;1** mg/m³ 

*Copper fume, as Cu **Copper dusts & mists, as Cu 

TLV 0.2*, 1** mg/m³ 

*fume; ** dusts&mists, as Cu 


USA

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PEL 

REL 

TLV 

1 mg/m³ 

Short-term value: 2 mg/m³ 

Long-term value: 1 mg/m³ 

Short-term value: 2 mg/m³ 

Long-term value: 1 mg/m³ 

fume 

7439-92-1 lead 

PEL 0.05* mg/m³ 

as Pb 

REL

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Page 6/10 




Material of gloves: 

Nitrile rubber, NBR 

Natural rubber, NR 

Penetration time of glove material: 

The exact break through time has to be found out by the manufacturer of the protective gloves and has to be 

observed. 

Eye protection: 

R Tightly sealed goggles 

Safety glasses 

9 Physical and chemical properties 

General Information 

Form: Solid 

Color: Silver grey 

Odor: Mild 

Change in condition 

Melting point/Melting range: > 100°C (> 212°F) 

Boiling point/Boiling range: Undetermined. 

Flash point: Not applicable. 

Danger of explosion: Product does not present an explosion hazard. 

Density at 20°C (68°F): > 7 g/cm³ 

Solubility in / Miscibility with 

Water: Not miscible or difficult to mix. 

10 Stability and reactivity 

Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. 

Materials to be avoided: Strong acids, strong oxidizers. 

Dangerous reactions No dangerous reactions known. 

Dangerous products of decomposition: 

Carbon monoxide and carbon dioxide 

Nitrogen oxides 

USA 

(Contd. on page 7)

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Page 7/10 



11 Toxicological information 


Acute toxicity: 

LD/LC50 values that are relevant for classification: 


Oral LD50 350 mg/kg (rat) 

142-04-1 anilinium chloride 


7440-36-0 antimony 


7440-69-9 bismuth 


Primary irritant effect: 

on the skin: Caustic effect on skin and mucous membranes. 

on the eye: Strong irritant with the danger of severe eye injury. 

through inhalation: 

Flux fumes during soldering may cause irritation and damage of mucous membranes and respiratory system. 

through ingestion: May be harmful if swallowed. 

Sensitization: No sensitizing effects known. 

Additional toxicological information: 

The product shows the following dangers according to internally approved calculation methods for preparations: 

Harmful 

Aniline is a blood toxin, causing hemoglobin to convert to methemoglobin, resulting in cyanosis. Prolonged or 

repeated contact may result in decreased appetite, anemia, weight loss, nervous system affects, and kidney, liver, 

and bone marrow damage. 

12 Ecological information 

General notes: 

Do not allow product to reach ground water, water course or sewage system. 

Harmful to aquatic organisms 

13 Disposal considerations 

Product: 

Recommendation: 

Must not be disposed of together with household garbage. Do not allow product to reach sewage system. 

Disposal must be made according to official regulations. 

Uncleaned packagings: 

Recommendation: Disposal must be made according to official regulations. 

USA 

(Contd. on page 8)

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Page 8/10 



14 Transport information 

DOT regulations: 

Hazard class: - 

Not regulated. 

Land transport ADR/RID (cross-border): 

ADR/RID class: - 


Maritime transport IMDG: 

IMDG Class: - 


Marine pollutant: No 

Air transport ICAO-TI and IATA-DGR: 

ICAO/IATA Class: - 


UN "Model Regulation": - 

Environmental hazards: Marine pollutant 

Transport/Additional information: Not dangerous according to the above specifications. 

15 Regulations 

USA The following information relates to product regulation specific to the USA. 

SARA (Superfund Amendments and Reauthorization Act) 

Section 355 (extremely hazardous substances): 

None of the ingredient is listed. 

Section 313 (Specific toxic chemical listings): 

7439-92-1 lead 

7440-36-0 antimony 

7440-50-8 copper 

7440-22-4 silver 


TSCA (Toxic Substances Control Act): 

All ingredients are listed or exempt from listing. 


Chemicals known to cause cancer: 

WARNING: This product contains a chemical(s) known to the State of California to cause cancer. 



USA

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Page 9/10 




Chemicals known to cause reproductive toxicity: 

WARNING: This product contains a chemical(s) known to the State of California to cause birth defects and/or other 

reproductive harm. 

Carcinogenicity categories 

EPA (Environmental Protection Agency) 

7439-92-1 lead B2 

IARC (International Agency for Research on Cancer) 

7439-92-1 lead 2B 

NTP (National Toxicology Program) 

None of the ingredients is listed. 

NIOSH-Ca (National Institute for Occupational Safety and Health) 


OSHA-Ca (Occupational Safety & Health Administration) 


CANADA: The following information relates to product regulation specific to Canada. 

Workplace Hazardous Materials Identification (WHMIS): 

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products 

Regulation (CPR) and the MSDS contains all of the information required by the CPR. 

EUROPEAN UNION 

The following information relates to product regulation specific to the directives of the European Union. 

Risk phrases: 

Harmful by inhalation, in contact with skin and if swallowed. 

Danger of cumulative effects. 

Limited evidence of a carcinogenic effect. 

May cause sensitisation by skin contact. 

Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if 

swallowed. 

Possible risk of impaired fertility. 

Possible risk of irreversible effects. 

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

Safety phrases: 

Keep out of the reach of children. 

Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. 

Wear suitable protective clothing and gloves. 

If swallowed, seek medical advice immediately and show this container or label. 

Special labeling of certain preparations: 

Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. 

16 Other information 

The information contained herein is based on data considered accurate and is offered solely for information, 

consideration and investigation. Kester extends no warranties, makes no representations and assumes no 


USA

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Page 10/10 




responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this 

Material Safety Data Sheet relates only to this product and does not relate to use with any other material or in any 

process. All chemical products should be used only by, or under the direction of, technically qualified personnel who 

are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication 

regulations require that employees must be trained on how to use a Material Safety Data Sheet as a source for 

hazard information. 

Abbreviations and acronyms: 

ADR: Accord européen sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International Carriage of 

Dangerous Goods by Road) 

RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the International 

Transport of Dangerous Goods by Rail) 

IMDG: International Maritime Code for Dangerous Goods 

DOT: US Department of Transportation 

IATA: International Air Transport Association 

IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) 

ICAO: International Civil Aviation Organization 

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) 

GHS: Globally Harmonized System of Classification and Labelling of Chemicals 

NFPA: National Fire Protection Association (USA) 

HMIS: Hazardous Materials Identification System (USA) 

WHMIS: Workplace Hazardous Materials Information System (Canada) 

LC50: Lethal concentration, 50 percent 

LD50: Lethal dose, 50 percent 

USA

Product name: Air Tool Lubricant 

® 


HILTI ® is a registered trademark of Hilti Corp. 

MSDS No.: 139 

Revision No.: 008 

Revision Date: 01/17/07 

Page: 1 of 2 

Description: Petroleum based hydraulic oil 

Supplier: Hilti, Inc. P.O. Box 21148, Tulsa, OK 74121; phone 1800 879 8000 

Emergency # (Chem-Trec.): 1 800 424 9300 (USA, PR, Virgin Islands, Canada); 001 703 527 3887 (other countries) 

COMPOSITION / EXPOSURE LIMITS 

Hazardous Ingredients: CAS Number: TLV: PEL: STEL: 

Petroleum oils, hydrotreated, spent 64742-58-1 5.0 mg/m 3 * 5.0 mg/m 3 * NE 

Petroleum oils, clay treated 64742-62-7 5.0 mg/m 3 * 5.0 mg/m 3 * NE 

Abbreviations: PEL = OSHA Permissible Exposure Limit. TLV = ACGIH Threshold Limit Value. These are 8 hour time-weighted 

averages unless otherwise indicated by "C" (Ceiling) or "STEL" (Short Term Exposure Limit). NE = None Established. * indicates 

“as oil mist”. 

PHYSICAL DATA 

Appearance: Pale amber liquid Odor: Petroleum odor 

Vapor Density: > 8 (Air = 1) Vapor Pressure: < 0.1 @ 100º F 

Boiling Point: Wide range VOC Content: Negligible 

Evaporation Rate: < 1 (n-butyl acetate = 1) Solubility in Water: Negligible 

Specific Gravity: 0.9 pH: Not determined 

FIRE AND EXPLOSION HAZARD DATA 

Flash Point: 415°F, COC Flammable Limits: Not applicable 

Extinguishing Media: CO 2, Dry Chemical, Foam 

Special Fire Fighting 

Procedures: 

Unusual Fire and Explosion 

Hazards: 

Stability: Stable. 

Hazardous Polymerization: Will not occur. 

A self-contained breathing apparatus should be worn when fighting fires involving chemicals. 

None known. Thermal decomposition products can be formed. See below. 

REACTIVITY DATA 

Incompatibility: Strong oxidizers such as chlorine, sodium hypochlorite and calcium hypochlorite. 

Decomposition Products: Thermal decomposition can yield dense smoke, carbon monoxide and oxides of sulfur. 

Conditions to Avoid: Contact with strong oxidizers. 

HEALTH HAZARD DATA 

Known Hazards: Can cause eye irritation. Prolonged and repeated overexposure to oils can lead to skin irritation 

and dermatitis. 

Signs and Symptoms of 

Exposure: 

Routes of Exposure: Dermal. Inhalation. 

None expected. Exposure to oil mists can cause respiratory irritation. Chronic exposure to the 

skin can cause dermatitis. 

Carcinogenicity: No ingredients are classified as a carcinogen by IARC, NTP or OSHA. 

Medical Conditions 

Aggravated by Exposure: 

Eye, skin, and respiratory conditions.

EMERGENCY AND FIRST AID PROCEDURES 

Eyes: Flush with plenty of water. Call a physician if symptoms occur. 

Skin: Wash with soap and water. Launder contaminated clothing before reuse. 

Inhalation: Not considered a route of exposure. Product has a low vapor pressure. 

Ingestion: Do not induce vomiting unless directed by a physician. Seek medical attention. (Note to 

physician: If aspirated into the lungs, can cause chemical pneumonitis). 

Other: Referral to a physician is recommended if there is any question about the seriousness of the 

injury/exposure. 

CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENT 

Ventilation: General (natural or mechanically induced fresh air movements). 

Eye Protection: Safety glasses are required in most industrial settings. 

Skin Protection: Not required. Gloves recommended. 

Respiratory Protection: Not normally required. If exposure to mist is likely, use a NIOSH-approved dust/mist respirator. 

Handling and Storing 

Precautions: 

PRECAUTIONS FOR SAFE HANDLING AND USE 

Avoid prolonged or repeated contact with skin. Avoid breathing mists or vapor. Avoid high 

temperatures. Water contamination should be avoided. 

Spill Procedures: For small spills, wipe away with an absorbent cloth. For larger spills, absorb with inert material. 

Sweep or scoop up and discard. Prevent spread of spill into sewers and watercourses. 

REGULATORY INFORMATION 

Hazard Communication: This MSDS has been prepared in accordance with the federal OSHA Hazard Communication 

Standard 29 CFR 1910.1200. 

HMIS Codes: Health 1, Flammability 1, Reactivity 0, PPE A 

DOT Shipping Name: Not regulated. 

TSCA Inventory Status: Chemical components listed on TSCA inventory. 

SARA Title III, Section 313: This product does not contain any ingredients which are subject to reporting under Section 313 of 

SARA Title III (40 CFR Part 372). 

EPA Waste Code(s): Not regulated by EPA as a hazardous waste 

Waste Disposal Methods: Consult with regulatory agencies or your corporate personnel for disposal methods that comply 

with local, state, and federal safety, health and environmental regulations. 

CONTACTS 

Customer Service: 1 800 879 8000 Technical Service: 1 800 879 8000 

Health / Safety: 1 800 879 6000 Jerry Metcalf (x6704) 

Emergency # (Chem-Trec): 1 800 424 9300 (USA, PR, Virgin Islands, Canada); 001 703 527 3887 (other countries) 

The information and recommendations contained herein are based upon data believed to be correct; however, no guarantee or 

warranty of any kind expressed or implied is made with respect to the information provided. 

MSDS 139, Page 2 of 2

Colonial Chemical Company A Unit of The ESS Group, Inc. 

Manufacturers of Quality Electrolyte and Blended Products. 

78 Carranza Road, Tabernacle, NJ 08088 (609) 268-1200 (609) 268-2117 Fax 


PRODUCT: BATTERY FLUID, ACID 10% - 51% 

MANUFACTURER/DISTRIBUTOR 

Colonial Chemical Company Product Information: (609) 268-1200 

78 Carranza Road Emergency: CMB(800) 457-4280 

Tabernacle, NJ 08088 

IDENTITY 

Chemical Name: Battery fluid, acid; Electrolyte battery acid, Sulfuric acid 

Chemical Family: Mineral Acid, Inorganic acid 

Molecular Formula: H2SO4 

CAS Number: 7664-93-9 

Hazard Class: Corrosive Material, 8 

UN/NA Number: UN 2796 

WHMIS Classification: Class E - Corrosive, Class D1A 

Packaging Group II 

NFPA Ratings: NPCA-HMIS Ratings 

Health: 3 Health: 3 

Flammability: 0 Flammability: 0 

Reactivity: 2 Reactivity 2 

Water Reactive 

EXPOSURE LIMITS 

TLV (ACGIH) 1mg/m - 8 Hr TWA STEL: 3 mg/m 3 

PEL (OSHA) 1 mg/m 3 - 8 Hr TWA 

Aquatic Toxicity: The 48 hour Tlm in flounder is 100-300 ppm. 

PHYSICAL DATA 

Physical State: Liquid 

Appearance: Clear and odorless 

Boiling Point: 10% - 210F 51% - 270F 

Freezing Point: 10% - 25F 51% - -30F 

Vapor Pressure: 0.3 mm Hg at 77F 

Vapor Density: 3.4 

Evaporation Rate: Less than 1 

Water Solubility: 100% soluble 

pH: Less than 1

Battery Fluid, Acid Material Safety Data Sheet 

COMPONENTS 

Sulfuric Acid Water Specific Gravity 

CAS# 7664-93-9 CAS# 7732-18-5 @ 60F 

10.77% 89.23% 1.074 

20% 80% 1.145 

24.85% 75.15% l.180 

28.53% 71.47% l.210 

30% 70% 1.222 

33.33% 66.67% 1.250 

35.15% 64.85% 1.265 

36.99% 63.01% 1.280 

38.05% 61.95% 1.290 

39.25% 60.75% 1.300 

41% 59% 1.315 

47% 53% 1.370 

50.17% 49.83% 1.401 

FIRE AND EXPLOSION DATA 

Flash Point: Will not burn, non-flammable 

Autoignition Temperature: Not combustible 

Flammability Limits in air (%) UEL: Not applicable 

LEL: Not applicable 

Hazards: Reacts with most metals, especially when dilute, to give flammable, potentially 

explosive hydrogen gas. Follow appropriate National Fire Protection Assoc. (NFPA) 

codes. 

Extinguishing Media: Use media appropriate for surrounding material. Use water spray to 

cool containers exposed to fire; do not get water inside containers. 

Special Instructions: Evacuate personnel to a safe area. Keep personnel removed and upwind 

of fire. Generates heat upon addition of water, with possible spattering. Wear full 

protective clothing. Runoff from fire control may cause pollution. Neutralize runoff 

with lime, soda ash, etc. Wear self-contained breathing apparatus if fumes or mists are 

present. 

HAZARDOUS REACTIVITY 

Instability: Stable, but reacts violently with water and organic materials with evolution of 

heat. 

Decomposition: Releases sulfur dioxide at extremely high temperatures. 

Polymerization: Polymerization will not occur. 

Materials to Avoid: Vigorous reactions with water; alkaline solutions; metals, metal powder; 

carbides; chlorates; fuminates; nitrates; picrates; strong oxidizing, 

reducing, or combustible organic materials. Hazardous gases are evolved on contact with chemicals 

such as cyanides, sulfides, and carbides. 

2


HEALTH HAZARD DATA 

Causes severe burns to eyes, skin, and all body tissue. Eye damage may be permanent. 

Destruction of tissue may result from direct chemical reaction with tissue, from thermal burns, 

and from dehydration (removal of water) of the tissue. 

Animal Data: 

Inhalation 1 hour LC50: 347 ppm in rats 

Oral LD50 2140 mg/kg in rats 

The concentrated compound is corrosive to the skin and eyes of animals causing corrosion of 

mucosal surfaces. Toxic effects described in animals from single exposures by inhalation 

include respiratory irritation. 

Exposure to the liquid by skin or eye contact may cause eye corrosion with corneal or 

conjunctival ulceration; or skin burns or ulceration. Ingestion of the liquid may cause severe 

burns to the mucous membranes of the mouth and esophagus. Repeated or prolonged contact 

with mists may cause eye irritation with tearing or blurring of vision; or skin irritation with 

discomfort or rash. Prolonged or repeated exposure may result in impaired lung function and 

possible discoloration and erosion of teeth. Individuals with preexisting diseases of the lungs 

may have increased susceptibility to the toxicity of excessive exposures. 

CARCINOGENICITY 

FIRST AID 

None of the components in this material is listed by IARC, NTP, OSHA, or ACGIH as a 

carcinogen. 

Inhalation: 

Move victim to fresh air. Give artificial respiration ONLY if breathing has 

stopped. Give CPR if there is no breathing AND no pulse. Obtain medical 

attention IMMEDIATELY. 

Ingestion: 

If swallowed, do not induce vomiting. Give large quantities of water. Call a physician. 

Do not neutralize the acid. Never give anything by mouth to an unconscious person. 

Skin or Eye Contact: 

In case of contact, immediately (within seconds) flush eyes or skin with plenty of cold water 

for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. 

While the patient is being transported to a medical facility apply compresses of iced water. If 

medical treatment must be delayed, immerse the affected area in iced water or apply 

compresses of iced water to affected areas. Do not freeze tissue. 

Notes to Physician: 

3


Continued washing of the affected area with cold or iced water will be helpful in removing the 

last traces of sulfuric acid. Creams or ointments should not be applied before or during the 

washing phase of treatment. 

PRECAUTIONS FOR SAFE HANDLING 

SPILLS: 

WASTE: 

STORAGE: 

Good general ventilation should be provided to keep vapor and mist concentrations be- 

low the exposure limits. Have available and wear as appropriate for exposure conditions when 

handling containers or operating equipment containing sulfuric acid: Chemical splash goggles; 

full-length face shield/chemical splash goggle combination; acid-proof gauntlet gloves, apron, 

and boots; long sleeve wool, acrylic or polyester clothing; acid proof suit and hood; and 

appropriate NIOSH/MSHA respiratory protection. In case of emergency or where there is a 

strong possibility of considerable exposure, wear a complete acid suit with hood, boots and 

gloves. If acid vapor or mist are present and exposure limits may be exceeded, wear 

appropriate NOISH/MSHA respiratory protection. 

Always add acid to water - not water to acid. 

EPA and Superfund reportable discharge is 1000 lbs. Stop flow if possible. Use appropriate 

protective equipment during clean up. Soak up small spills with dry sand, clay or 

diatomaceous earth. Dike large spills, and cautiously dilute and neutralize with lime or soda 

ash, and transfer to waste water treatment system. Prevent liquid from entering sewers, 

waterways or low areas. Comply with Federal, State and local regulations. 

Cleaned up material may be a RCRA Hazardous Waste on disposal. Do not flush to surface 

water or sanitary sewer system. Comply with Federal, State and local regulations. If approved, 

neutralize and transfer to waste treatment system. 

Keep out of sun and away from heat, sparks, and flame. Keep container tightly closed to 

prevent leakage. Loosen closure carefully; relieve internal pressure when received and at least 

weekly thereafter. Do not use pressure to empty. Do not wash out container or use it for other 

purposes. Replace closure after each use. 

Date: August 2, 2008 

4

Saft America Inc. 

d/b/a Alcad Standby Batteries 

3 Powdered Metals Drive 

North Haven, CT 06473 

Information: Phone 203-985-2500 

Fax 203-985-2539 


PRODUCT NAME: ALKALINE BATTERY ELECTROLYTE 

POTASSIUM HYDROXIDE SOLUTION 

Battery Fluid, Alkali, 8, UN2797, PGII 

For Chemical Emergency 

Spill, Leak, Fire, Exposure or Accident 

Call CHEMTREC - Day or Night 

800-424-9300 

Date: 06/11/08 

HMIS RATINGS 3 Health 0 Flammability 1 Reactivity 

NFPA RATINGS 3 Health 0 Flammability 1 Reactivity 

1. HEALTH HAZARD INFORMATION 

Effects of Overexposure 

Eye Effects: Contact with electrolyte solution inside battery causes very rapid, sever damage. Extremely corrosive to 

eye tissues. May result in permanent blindness. 

Skin Effects: Contact with electrolyte solution inside battery may cause serious burns to skin tissues. 

Ingestion: Ingestion of electrolyte solution causes tissue damage to throat area and gastro/respiratory tract. 

Inhalation: Electrolyte mist may cause varying degrees of irritation of the nasal mucous membranes and respiratory 

tract tissues. May vary from mild irritation of nasal mucous membranes to damage of lung tissues. 

Carcinogenicity: Not listed as carcinogenic by IARC, NTP, OSHA, ACGIH. 

2. EMERGENCY FIRST AID 

Battery Electrolyte 

Eye Contact: Flush with plenty of water for at least 15 minutes. Get immediate medical attention. 

Skin Contact: Remove contaminated clothing and flush affected areas with plenty of water for at least 15 minutes. 

Seek medical attention if necessary. 

Ingestion: Do not induce vomiting. Dilute by giving water. If available give 2 to 4 cups of milk. Get immediate 

medical attention. Do not give anything by mouth to an unconscious person. 

Inhalation: Remove to fresh air. Give oxygen or artificial respiration if needed. Get immediate medical attention. 

3. SPECIAL PROTECTION INFORMATION 

Respiratory Protection: Use NIOSH-approved dust/mist type respirator for protection against mists. 

Eye Protection: Use chemical safety goggles plus full face shield whenever handling Potassium Hydroxide solution. 

Hand Protection: If exposure to electrolyte solution, or dried salts is likely, use any water-insoluble non-permeable glove, i.e., 

synthetic rubber. DO NOT user leather or wool. 

Other protective Equipment: Face shield, rubber boots, rubber apron or rainwear or equivalent if exposure to electrolyte solution is 

likely. 

Ventilation: Local exhaust as necessary to eliminate mist. 

4. REACTIVITY DATA 

CAUTION: DO NOT ADD SULFURIC ACID. 

Instability: Under normal conditions, material is stable. 

Incompatibilities: Electrolyte will react with aluminum, zinc, tin and other active metals, acid, chlorinated and aromatic hydrocarbons, 

nitrocarbons, and halocarbons. Tricholoroethylene will react with electrolyte solution to form dicloroacetylene which is spontaneously 

combustible. 

Hazardous Polymerization: Material is not known to polymerize. 

MS-E92, Potassium Hydroxide

5. FIRE AND EXPLOSION HAZARDS 

Extinguishing Media: Use water spray, foam, CO2, sand or dry chemicals in the storage area. 

Special Fire Fighting Procedures: Not Flammable. Avoid direct contact. 

Fire and Explosion Hazards Electrolyte solution is corrosive to all human tissues. It will react violently with many organic chemicals, 

especially nitrocarbons and chlorocarbons. Electrolyte solution reacts with zinc, aluminum, tin and other active materials releasing 

flammable hydrogen gas. 

6. INGREDIENTS CAS # EXPOSURE LIMITS QUANTITY 

Potasium Hydroxide 1310-58-3 2 mg/m 3 ACGIH CEILING-Air = 20-25% 

Lithium Hydroxide 1310-66-3 2 mg/m 3 – OSHA Ceiling

Page 1 of 4 


KEM CANADA MFG. EMERGENCY # (905) 456-9444 

4 BLAIR DRIVE CANUTEC # (613) 996-6666 

BRAMPTON, ONTARIO W.H.M.I.S. CLASSIFICATION 

L6T 2H5 D2B, E 

MATERIAL REFERENCE NO: 105700 

SECTION I - MATERIAL IDENTIFICATION AND USE 

---------------------------------------------------------------------- 

|MATERIAL NAME/I.D.: BATTERY TERMINAL CLEANER | 

---------------------------------------------------------------------- 

|CHEMICAL NAME: NOT APPLICABLE |CHEMICAL FAMILY: ALKALINE BLEND | 

---------------------------------------------------------------------- 

|CHEMICAL FORMULA: MIXTURE |MOLECULAR WEIGHT: NOT APPLICABLE| 

---------------------------------------------------------------------- 

|SYNONYMS: NONE | 

---------------------------------------------------------------------- 

|MATERIAL USE: ALKALINE BATTERY POST CLEANER | 

---------------------------------------------------------------------- 

SECTION II - HAZARDOUS INGREDIENTS OF MATERIAL 

---------------------------------------------------------------------- 

| HAZARDOUS | APPROX. %| TLV | C.A.S. NO. | LD 50 | 

| INGREDIENTS | CONCENT. | PPM | | RAT, ORAL | 

---------------------------------------------------------------------- 

|SODIUM METASILICATE | 5.0-10.0 | NO DATA | 6834-92-0 | 1153 MG/KG| 

|TRISODIUM PHOSPHATE | 1.0-5.0 | NO DATA | 7601-54-9 | 2000 MG/KG| 

|DIPROPYLENE GLYCOL | 1.0-5.0 | 150 | 34590-94-8 | 5400 L/KG| 

| METHYL ETHER | | | | | 

| | | | | | 

| | | | | | 

| | | | | | 

| | | | | | 

---------------------------------------------------------------------- 

SECTION III - PHYSICAL DATA FOR MATERIAL 

---------------------------------------------------------------------- 

|PHYSICAL STATE: LIQUID | 

---------------------------------------------------------------------- 

|ODOUR AND APPEARANCE: CLEAR, ORANGE LIQUID; SLIGHT AMMONIA ODOUR. | 

---------------------------------------------------------------------- 

|ODOUR THRESHOLD (PPM) | SPECIFIC GRAVITY | VAPOUR PRESSURE (MM)| 

| NOT AVAILABLE | 1.04 | NOT AVAILABLE | 

---------------------------------------------------------------------- 

|VAPOUR DENSITY (AIR=1)| EVAPORATION RATE |SOLUBILITY IN WATER | 

| > 1 | (WATER = 1)


Page 2 of 4 


SECTION IV - FIRE AND EXPLOSION HAZARD OF MATERIAL 

---------------------------------------------------------------------- 

|FLAMMABILITY: NON-FLAMMABLE | 

|IF YES, UNDER WHICH CONDITIONS: | 

| | 

---------------------------------------------------------------------- 

|MEANS OF EXTINCTION: WATER FOG, CHEMICAL FOAM, CO2 | 

---------------------------------------------------------------------- 

|SPECIAL PROCEDURES: WEAR FULL PROTECTIVE GEAR AND SELF-CONTAINED | 

|BREATHING APPARATUS. COOL FIRE EXPOSED DRUMS WITH WATER. | 

| | 

---------------------------------------------------------------------- 

|FLASH POINT (C) AND METHOD: NONE (TAG CLOSED CUP) | 

---------------------------------------------------------------------- 

|HAZARDOUS COMBUSTION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE, | 

|AMMONIA, OXIDES OF PHOSPHOROUS AND SODIUM. | 

| | 

---------------------------------------------------------------------- 

|UPPER EXPLOSION LIMIT | LOWER EXPLOSION LIMIT | AUTOIGNITION TEMP(C)| 

| NOT AVAILABLE | NOT AVAILABLE | NOT AVAILABLE | 

---------------------------------------------------------------------- 

|EXPLOSION DATA SENSITIVITY| RATE OF BURNING | EXPLOSIVE POWER | 

|TO CHEMICAL IMPACT | | | 

| NOT AVAILABLE | NOT AVAILABLE | NOT AVAILABLE | 

---------------------------------------------------------------------- 

|SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE | 

---------------------------------------------------------------------- 


---------------------------------------------------------------------- 

|CHEMICAL STABILITY: YES | 

|IF NO, UNDER WHICH CONDITIONS: | 

| | 

---------------------------------------------------------------------- 

|INCOMPATIBILITY TO OTHER SUBSTANCES: YES | 

|IF SO, WHICH ONES: STRONG ACIDS, STRONG OXIDIZERS. | 

---------------------------------------------------------------------- 

|REACTIVITY AND UNDER WHAT CONDITIONS: NOT ESTABLISHED | 

| | 

|HAZARDOUS POLYMERIZATION WILL NOT OCCUR. | 

---------------------------------------------------------------------- 

|HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE, | 

|AMMONIA. | 

---------------------------------------------------------------------- 


---------------------------------------------------------------------- 

|ROUTE OF ENTRY: | 

---------------------------------------------------------------------- 

|SKIN CONTACT: YES SKIN ABSORPTION: YES EYE CONTACT: YES | 

| INHALATION: YES INGESTION: YES | 

----------------------------------------------------------------------

Page 3 of 4 

MATERIAL SAFETY DATA SHEET

Page 4 of 4 



SECTION VIII - FIRST AID MEASURES 

---------------------------------------------------------------------- 

|PROCEDURES: | 

|EYES-FLUSH WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS | 

|OPEN. GET MEDICAL ATTENTION IF PAIN OR IRRITATION PERSISTS. | 

|SKIN-FLUSH AFFECTED AREA WITH WATER FOR AT LEAST 15 MINUTES. WHILE | 

|REMOVING CONTAMINATED COTHING. GET MEDICAL ATTENTION IF IRRITATION | 

|PERSISTS. LAUNDER CLOTHING BEFORE REUSE. | 

|INHALATION-MOVE VICTIM TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE| 

|OXYGEN. IF NOT BREATHING, ADMINISTER ARTIFICIAL RESPIRATION AND | 

|THEN GIVE OXYGEN. GET MEDICAL ATTENTION. | 

|INGESTION-IF SWALLOWED DO NOT INDUCE VOMITING. RINSE MOUTH WITH | 

|WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING | 

|PERSON. GET IMMEDIATE MEDICAL ATTENTION. | 

---------------------------------------------------------------------- 

|SOURCES USED: RAW MATERIAL SUPPLIER'S MATERIAL SAFETY DATA SHEETS | 

---------------------------------------------------------------------- 

|ADDITIONAL INFORMATION: NONE | 

---------------------------------------------------------------------- 

SECTION IX - TDG SHIPPING INFORMATION 

---------------------------------------------------------------------- 

| SHIPPING NAME | CLASS | UN NO. | PACKING GROUP | 

| NOT REGULATED | | | | 

---------------------------------------------------------------------- 

|HANDLING PROCEDURES AND EQUIPMENT: AVOID CONTACT WITH EYES AND SKIN.| 

|WEAR RECOMMENDED PROTECTIVE EQUIPMENT WHEN HANDLING CONCENTRATE. | 

|WASH THOROUGHLY AFTER USE. | 

---------------------------------------------------------------------- 

|STORAGE REQUIREMENTS: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP | 

|FROM FREEZING. | 

---------------------------------------------------------------------- 

|SPECIAL SHIPPING INFORMATION: HEATED | 

---------------------------------------------------------------------- 

SECTION X - HMIS HAZARD RATING INFORMATION 

---------------------------------------------------------------------- 

| FLAMMABILITY | REACTIVITY | HEALTH | 

| 1 | 0 | 2 | 

---------------------------------------------------------------------- 

SECTION XI - PREPARATION DATE OF MSDS 

---------------------------------------------------------------------- 

|PREPARED BY: TECHNICAL DEPARTMENT TELEPHONE # (905) 456-9444 | 

|REVISED: JUNE 21, 2009 REPLACES: OCTOBER 25, 2004 | 

---------------------------------------------------------------------- 

DISCLAIMER: 

THE INFORMATION CONTAINED HEREIN IS COMPILED FROM SOURCES BELIEVED TO 

BE RELIABLE. THE MANNER AND CONDITIONS OF USE AND HANDLING MAY INVOLVE 

OTHER AND ADDITIONAL CONSIDERATIONS. WE ACCEPT NO RESPONSIBILTY FOR THE 

ACCURACY, SUFFICIENCY, RELIABILITY OR FOR ANY LOSS OR INJURY RESULTING 

FROM THE USE OF THE INFORMATION.

Page 4 of 4 




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| 1 | 0 | 2 | 

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DISCLAIMER: 






Page 4 of 4 




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| 1 | 0 | 2 | 

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DISCLAIMER: 






DR 



Page 1/4 


1 Identification of substance 

Trade name: CHAIN & WIRE LUBE 

Product codes: HY00200302 

Manufacturer: SEYMOUR OF SYCAMORE 

917 Crosby Avenue 

Sycamore, IL 60178 

(815)-895-9101, www.seymourpaint.com 

Emergency information: CHEMTEL 1-800-255-3924, 813-248-0585 *if located outside the U.S.* 

2 Composition/Data on components 

Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. 

Dangerous components: 

8012-95-1 Petroleum hydrocarbon 45.97% 

110-54-3 n-hexane 12.82% 

74-98-6 propane 12.61% 

64742-89-8 VM&P Naphtha 11.33% 

67-64-1 Acetone 8.96% 

106-97-8 n-butane 7.41% 

3 Hazards identification 

Hazard description: Harmful 

Extremely flammable 

Physical dangers: 

Effects of chronic 

overexposure: 

NFPA ratings (0 - 4): 

HMIS-ratings (0 - 4): 

Extremely flammable liquid and vapor in a pressurized container. Keep away from heat, sparks, and 

flame. 

Has narcotizing effect. 

Extremely flammable. 

Harmful: danger of serious damage to health by prolonged exposure through inhalation. 

Possible risk of impaired fertility 


May cause permanent brain and nervous system damage. Repeated overexposure can also damage 

kidneys, lungs, liver, heart, and blood. Intentional misuse by deliberately inhaling the contents may be 

harmful or fatal. 

Health = 1 

Fire = 4 


Health= 1 

Fire= 4 

Physical Hazard= 3 

4 First aid measures 

After inhalation: Supply fresh air; consult doctor in case of complaints. 

After skin contact: Remove contaminated clothing. Wash exposed area with soap and water. 

After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. 

After swallowing: Contact physician or poison control center. 

5 Fire fighting measures 

Extinguishing agents: CO2, sand, extinguishing powder, or water spray. Fight larger fires with water spray or alcohol resistant 

foam. 

Protective equipment: No special measures required. 

6 Accidental release measures 

Personal safety: Wear protective equipment. Keep unprotected persons away. 

Environmental safety: Do not allow product to reach sewage systems or ground water. 

Clean-up/collection: Ensure adequate ventilation. 

7 Handling and storage 

Fire/explosion protection: Do not spray on a naked flame or any incandescent material. Do not smoke. Protect from electrostatic 

discharges. 

Storage requirements: Observe pressurized container storage regulations. Consult with your local authorities. 

8 Exposure controls and personal protection: 

Components with limit values that require monitoring at the workplace: 

8012-95-1 Petroleum hydrocarbon 

PEL 5 mg/m³ 


USA

DR 



Page 2/4 



110-54-3 n-hexane 

PEL 

REL 

TLV 

1800 mg/m³, 500 ppm 

180 mg/m³, 50 ppm 

176 mg/m³, 50 ppm 

Skin; BEI 


74-98-6 propane 

PEL 1800 mg/m³, 1000 ppm 

REL 1800 mg/m³, 1000 ppm 

TLV Varies mg/m³, 1000 ppm 

67-64-1 Acetone 

PEL 2400 mg/m³, 1000 ppm 

REL 590 mg/m³, 250 ppm 

TLV Short-term value: 1782 mg/m³, 750 ppm 

Long-term value: 1188 mg/m³, 500 ppm 

BEI 

106-97-8 n-butane 

REL 1900 mg/m³, 800 ppm 

TLV Varies mg/m³, 1000 ppm 

Hygienic protection: Keep away from foodstuffs and animal feed. Wash hands after use. 

Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. In cases 

where short and/or long term overexposure exists, a charcoal filter respirator should be worn. If you 

suspect overexposure conditions exist, please consult an authority on chemical hygeine. 

Hand protection: Protective gloves. The glove material has to be impermeable and resistant to the substance. No glove 

recommendation can be given. 

Eye protection: Tightly sealed goggles 

9 Physical and chemical properties: 

General Information: 

Odor: Aromatic 

Boiling point: -44°C (-47°F) 

Flash point: -19°C (-2°F) 

Auto igniting: Product is not self-igniting. 

Danger of explosion: Stable at normal temperatures. Can may burst when exposed to temperatures exceeding 120 

degrees fahrenheit. 

In use, may form flammable/explosive vapour-air mixture. 

Lower Explosion Limit: 1.2 Vol % 

Upper Explosion Limit: 10.9 Vol % 

Vapor Pressure: 40 PSI, 2750 hPa 

Density at 20°C (68°F): 0.73 g/cm³ 

Specific Gravity: Between 0.77 and 0.85 (Water equals 1.00) 

VOC content: 353.9 g/l / 2.95 lb/gl 

VOC content (less exempt solvents): 44.2 % 

MIR Value: 0.65 

Solids content: 46.9 % 

10 Stability and reactivity: 

Conditions to avoid: Do not allow the can to exceed 120 degrees Fahrenheit. Stable at normal temperatures. 

Hazardous Reactions: No dangerous reactions known. 

11 Toxicological information: 

Skin effects: No irritant effect. 

Eye effects: No irritating effect. 

Sensitization: No sensitizing effects known. 

12 Ecological information 

Other information: This product does not contain any chlorofluorocarbons (CFC's), hydrochlorofluorocarbons (HCFC's), 

chlorinated solvents, or ozone depleting substances. 

Ecotoxical effects: 

Aquatic toxicity: Harmful to aquatic organisms. 

Hazardous for water, do not empty into drains. 

Remark: Harmful to fish 

13 Disposal considerations 

DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. 

Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. 


USA

DR 



Page 3/4 



Recommendation: Completely empty cans should be recycled. 

14 Transport information: 

Hazard class: 2.1 

Identification number: N/A 

Label 2.1 

ADR/RID/TDG class: 2 5F Gases 

UN-Number: 1950 

IMDG Class: 2.1 

Packaging group: II 

EMS Number: F-D,S-U 

Marine pollutant: No 

ICAO/IATA Class: 2.1 

Proper shipping name: Aerosols, Flammable 

Consumer Commodity ORM-D 

15 Regulations 

SARA Section 355 (extremely hazardous substances): 

None of the ingredients in this product are listed. 

SARA Section 313 (Specific toxic chemical listings): 

110-54-3 n-hexane 

TSCA: All ingredients are listed. 

CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead. 

California Proposition 65 chemicals known to cause cancer: 

None of the ingredients in this product are listed. 

CANADIAN 

ENVIRONMENTAL 

PROTECTION ACT: All hazardous ingredients for this product appear on the Canadian Domestice Substance List. 

WHMIS Symbols for 

Canada: A - Compressed gas 

D2A - Very toxic material causing other toxic effects 


EPA: A= Known human carcinogen B= Probable human carcinogen 

C= Possible human carcinogen 

D= Not classifiable as to human carcinogenicity: Inadequate human and animal evidence of 

carcinogenicity (or no data is available). 

I: 'Data are inadequate for an assessment of human carcinogeni potential.' 

II: 'Inadequate information to assess carcinogenic potential.' 

110-54-3 n-hexane II 

67-64-1 Acetone I 

IARC: Group 2A: The ingredient is probably carcinogenic to humans. 

Group 2B: The ingredient is possibly carcinogenic to humans. There is limited evidence of 

carcinogenicity. 

Group 3: The ingredient is unclassifiable as to its carcinogenicity to humans. 

Group 2A: The ingredient is probably carcinogenic to humans. 

Group 2B: The ingredient is possibly carcinogenic to humans. There is limited evidence of carcinogenicity. 

Group 3: The ingredient is unclassifiable as to its carcinogenicity to humans. 

ACGIH: A1-designates a confirmed human carcinogen. 

A2-designates a suspected human carcinogen. 

A3-designates an animal carcinogen. 

A4-designates "not classifiable as a human carcinogen". 

67-64-1 Acetone A4 

NIOSH: The following substances are regulated in the United States with reference to occupational exposure 

limits: 

The following substances are regulated in the United States with reference to occupational exposure limits: 

Risk phrases: Extremely flammable. 

Harmful: danger of serious damage to health by prolonged exposure through inhalation. 

Possible risk of impaired fertility 

Safety phrases: Keep out of the reach of children. 

Do not breathe gas/fumes/vapour/spray. 

Do not empty into drains, dispose of this material and its container at hazardous or special waste 

collection point 

Wear suitable protective clothing and gloves. 

If swallowed, seek medical advice immediately and show this container or label. 

Use only in well-ventilated areas. 

USA 

(Contd. on page 4)

DR 



Page 4/4 




16 Other information 

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and 

shall not establish a legally valid contractual relationship. 

Contact: Regulatory Affairs 

Abbreviations and 

acronyms: 

IMDG: International Maritime Code for Dangerous Goods 

DOT: US Department of Transportation 

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) 

PP: Severe Marine Pollutant 

P: Marine Pollutant 

CAS: Chemical Abstracts Service (division of the American Chemical Society) 

NFPA: National Fire Protection Association (USA) 

HMIS: Hazardous Materials Identification System (USA) 

VOC: Volatile Organic Compounds (USA, EU) 

ISO: International Organization for Standardization 

EPA: Environmental Protection Agency 

IARC: International Agency for the Research of Cancer 

NIOSH: National Institute for Occupational Safety and Health 

TSCA: Toxic Substances Control Act 

CPSC: Consumer Product Safety Commission 

USA

ITW Consumer - Devcon/Versachem 

CONTACT CEMENT 

This product appears in the following stock number(s): 

18045 


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Tradename: CONTACT CEMENT 

General use: Flexible, waterproof repairs. After solvent evaporates, product is not hazardous 

Chemical family: Neoprene Adhesive Solution 

MANUFACTURER 


2107 West Blue Heron Blvd. 

Riviera Beach, Florida 33404 


Component Abbr. Weight% ACGIH; TLV-TWA OSHA PEL: Other Limits 

METHYL ETHYL KETONE MEK 30-60 200 ppm TWA ACGIH 200 ppm TWA; 590 

78-93-3 

mg/m3 200 ppm Canada 

N-HEXANE 

n/e 10-30 50 ppm 500 ppm TWA; 1800 

110-54-3 

mg/m3 50 ppm Canada 

TWA 

HEPTANE 

n/e 5-15 400 ppm 500 ppm TWA; 2000 

142-82-5 

mg/m3 n/e 

TWA 

TRADE SECRET (Non-hazardous) 

MIXTURE 

n/e Balance n/e n/e 

"TLV" means the Threshold Limit Value exposure (eight-hour, time-weighted average, unless otherwise noted) established by the American Conference 

of Governmental Industrial Hygienists. "STEL" indicates a short-term exposure limit. "PEL" indicates the OSHA Permissible Exposure Limit. "n/e" 

indicates that no exposure limit has been established. An asterisk (*) indicates a substance whose identify is a trade secret of our supplier and unknown 

to us. 

3. HAZARDOUS IDENTIFICATION 

Emergency Overview 

Appearance, form, odor: Amber liquid with hydrocarbon odor 

DANGER!. Extremely Flammable. Eye, skin and respiratory irritant. May cause central nervous system effects. Based on 

animal studies, potential reproductive effects. 

Potential health effects 

Primary Routes of Exposure: Eye. Skin. Inhalation (breathing), skin absorption 

Symptoms of acute overexposure 

Skin: May be absorbed through skin in harmful amounts. Has a drying effect; may irritate. 

Eyes: Irritant 

Inhalation: Causes irritation of the mouth,nose,and throat. Central Nervous System Depression: signs/symptoms can 

include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and 

unconsciousness. 

Ingestion: May cause gastric distress (nausea, vomiting, diarrhea). Aspiration (breathing) of vomitus into lungs may result 

in pneumonitis. 

1 of 5 

1 of 5 

EMERGENCY INFORMATION 

Emergency telephone number 

(CHEMTEL): (800) 255-3924 

(CHEMTEL International): (+01) 813-248-0585 

Other Calls: (561) 845-2425


Effects of Chronic Exposure: May cause dermatitis. Overexposure to methyl ethyl ketone and n-hexane may cause 

peripheral nerve damage (that of arms and legs) and result in muscular weakness and loss of sensation. Long term 

overexposure to solvents have been associated with lung, liver and kidney damage. 

Medical Conditions Recognized as Being Aggravated by Exposure: 

Preexisting pulmonary and dermatological disorders. 

Other: 

Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal 

4. FIRST AID MEASURES 

Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical 

attention if irritation persists. 

Skin Contact: Remove contaminated clothing. Wash area with soap and water. If irritation persists, seek medical 

attention. 

Inhalation: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing 

becomes difficult 

Ingestion: Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give 

anything by mouth to an unconscious person 

5. FIRE FIGHTING MEASURES 

General fire and explosion characteristics: Flammable liquid Class 1B. 

Recommended Extinguishing Media: Carbon dioxide, Dry chemical, foam 

Flash point: -20°F 

Lower Explosive 

Limit: 1% 

Upper Explosive 

Limit: 11.6% 

Method: TCC 

Special Fire-Fighting Procedures: Evacuated unprotected personnel. Firefighters should wear self-contained breathing 

apparatus. Use water spray to cool exposed containers. 

Unusual Fire/Explosion Hazards: 

Vapors may travel from container toward sources of ignition and flashback. 

Hazardous Products of Combustion: 

Thermal decomposition will produce CO, CO2 and various unidentified organic compounds 

6. ACCIDENTAL RELEASE MEASURES 

Spill Control: Avoid personal contact. Eliminate ignition sources. Ventilate area. 

Containment: Dike, contain and absorb with clay, sand or other suitable material 

Cleanup: For large spills, pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or 

other suitable material and dispose of properly. 

Special procedures: Prevent spill from entering drainage/sewer systems, waterways and surface water. Use nonsparking 

tools. 

7. HANDLING AND STORAGE 

Handling precautions: Extremely flammable!. Avoid breathing vapors or mists. Avoid contact with the skin and the eyes. 

Wash thoroughly after handling. Ground container when pouring. Do not use near heat, sparks and open flame. Wear 

appropriate personal protective equipment. 

2 of 5


Storage: Keep in cool and dark place. Avoid direct sunlight. Store away from heat, sparks or open flame. Do not store at 

temperatures above 120 degrees F. Keep containers closed when not in use. Maintain air space in storage containers. 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

Engineering controls: 

Ventilation: 

General; local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to the 

lowest feasible levels when limits have not been established) during the use of this product. 

Other engineering controls: Keep container tightly closed. Observe label precautions. Have emergency shower and eye 

wash available. 

Personal protective equipment 

Eye and face protection: Safety glasses with side shields or splash-proof goggles are recommended 

Skin protection: Chemical-resistant gloves (i.e. butyl) and other gear as required to prevent skin contact. 

Respiratory protection: With good ventilation, none required. An approved respirator (i.e.NIOSH, etc.) should be worn 

when exposures are expected to exceed the applicable limits. 


Specific Gravity: 0.82 

Melting point: n/d 

Vapor Pressure: n/d 


This material is chemically stable. Hazardous polymerization will not occur. 

Conditions to Avoid: Keep away from heat,sparks and flame. 

Incompatabilities: Oxidizing agents, acids, bases, halogenated organic compounds. 

Hazardous Products of Combustion: Thermal decomposition will produce CO, CO2 and various unidentified organic 

compounds 

Conditions under which hazardous polymerization may occur: None. 


Eye Contact: No data available. 

Subchronic effects: No data available. 

Carcinogenicity, tertogenicity and mutagenicity: No data available. 

Boiling Point: 156°F 

Evaporation Rate: Faster than butyl acetate 

VOC: 76% by weight Solubility in water: Insoluble 

pH (5% solution or slurry in water): n/a 

Vapor Density (Air=1): >1 

Other chronic effects: Laboratory studies involving rats indicate some evidence that MEK may be embryotoxic, fetotoxic 

and teratorgenic. 

Toxicological information on hazardous chemical constituents of this product: 

Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 4hr (rat) 

METHYL ETHYL KETONE 

78-93-3 

2737 mg/kg 6840 mg/kg 23500 mg/m3 3 of 5 

/8h


Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 4hr (rat) 

N-HEXANE 

110-54-3 

28710 mg/kg n/d 48000 ppm/4h 

HEPTANE 

142-82-5 

n/d n/d n/d 


MIXTURE 

n/d n/d n/d 

'n/d' = not determined 

_ 


Ecotoxicity: No data available. 

Mobility and persistence: No data available. 

Environmental fate: No data available. 


Please see also Section 15, Regulatory Information. 

Recommended Method of Disposal: Do not dispose of in a landfill. Incineration is the preferred method of disposal. 

US EPA Waste Number: D001/D035 as per 40CFR 261.21 and a TCLP waste per 261.24 (methyl ethyl ketone and 

benzene). 


Proper shipping name: *Adhesives 

Technical name: N/A 

Hazard class: 3 

UN/ID Number: 1133 

Packing group: II 

Emergency Response Guide no: 128 

Other: *Depending upon the size and type of container, this material may be reclassified as "Consumer Commodity, ORM- 

D" for shipments within the United States, or "Limited Quantity" elsewhere. Refer to the appropriate regulation. 


U.S. Federal Regulations 

TSCA: 

All ingredients of this product are listed, or are exempt from listing on the TSCA Inventory. Export notification is required 

under TSCA Sec.12B - see below.. 

The following RCRA code(s) applies to this material if it becomes waste: 

D001/D035 

Regulatory status of hazardous chemical constituents of this product: 

Component Extremely Toxic Chemical** CERCLA RQ (lbs) 12B EXPORT 

Hazardous* 

NOTIFICATION: 

METHYL ETHYL KETONE 

78-93-3 

No No 5000 lbs. (2270 kg) Not required 

4 of 5


Component Extremely Toxic Chemical** CERCLA RQ (lbs) 12B EXPORT 

Hazardous* 

NOTIFICATION: 

N-HEXANE 

110-54-3 

No Yes 5000 lbs (2270 kg) Required 

HEPTANE 

142-82-5 

No No 0.0 Not required 


MIXTURE 

No No 0.0 Not required 

*Consult the appropriate regulations for emergency planning and release reporting requirements for substances on the SARA Section 301 Extremely 

Hazardous Substance List. 

**Substances for which the "Toxic Chemical" column is marked "Yes" are on the SARA Section 313 list of Toxic Chemicals, for which release reporting 

may be required. For specific requirements, consult the appropriate regulations. 

For purposes of SARA Section 312 hazardous materials inventory reporting, the following hazard classes apply to 

this material: Immediate health hazard, Delayed health hazard, Fire hazard 

California regulations: For purposes of the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Prop 65), 

this product does not contain any chemicals known to the State of California to cause cancer and birth defects or other 


Canadian Regulations 

WHMIS Hazard Class: B2 FLAMMABLE LIQUIDS, D2B TOXIC MATERIALS 

All components of this product are on the Canadian Domestic Substances List . 


Hazardous Material Information System (HMIS) rating: 

Health 2* Flammability 3 Physical Hazard 0 

HMIS is a registered trademark of the National Paint and Coatings Assn. 

Revision Date: August/25/2008 

Revision Number: 6 

The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no 

other warranty, express or implied, as to its correctness or completeness, or as to the results of reliance on this document. 

5 of 5

Product Name: QD Contact Cleaner (aerosol) 

Product Number (s): 72130 

Product Use: 

Electronic cleaner 

Manufacturer / Supplier Contact Information: 

In United States: In Canada: In Mexico: 

CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico 

885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G 

Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea 

www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394 

1-215-674-4300 (General) 1-905-670-2291 www.crc-mexico.com 

(800) 521-3168 (Technical) 52-444-824-1666 

(800) 272-4620 (Customer Service) 

24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 

 


DANGER: Extremely Flammable. Harmful or Fatal if Swallowed. Contents Under Pressure. 

As defined by OSHA’s Hazard Communication Standard, this product is hazardous. 

Appearance & Odor: Clear, colorless liquid with alcohol odor 

Potential Health Effects: 

ACUTE EFFECTS: 

EYE: May cause mild irritation including stinging and redness, but does not injure eye. 

SKIN: Single, brief exposures may cause mild irritation. Frequent or prolonged contact may cause more 

severe irritation, defatting of the skin, and dermatitis. 

INHALATION: High vapor concentrations are irritating to the respiratory tract and may cause headaches, 

dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects, 

including death. May cause peripheral nervous system disorder and/or damage. 

INGESTION: Low order of toxicity by ingestion. Main hazard is aspiration into the lungs during swallowing or 

vomiting. Small amounts aspirated into the respiratory system may cause bronchopneumonia or 

pulmonary adema, possibly progressing to death. 

CHRONIC EFFECTS: Overexposure to n-hexane may cause progressive and potentially irreversible damage to the 

peripheral nervous system, particularly in the arms and legs. 

TARGET ORGANS: central nervous system, peripheral nervous system, respiratory system 

Medical Conditions Aggravated by Exposure: skin and respiratory conditions 

See Section 11 for toxicology and carcinogenicity information on product ingredients. 

Page 1 of 7

QD Contact Cleaner (aerosol) 

72130 

 

COMPONENT CAS NUMBER % by Wt. 

Hexane isomers 64742-49-0 75 - 85 

n-Hexane 110-54-3 6.1 

Synthetic isoparaffinic hydrocarbon 64741-66-8 5 - 10 

 

Methanol 67-56-1 < 1 

Carbon dioxide 124-38-9 3 - 8 

Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. 

Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if 

irritation persists. Wash contaminated clothing prior to re-use. 

Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If 

breathing is difficult give oxygen. Call a physician. 

Ingestion: Do NOT induce vomiting. Contact a physician immediately. 

Note to Physicians: Treat symptomatically. Gastric lavage using a cuffed endotracheal tube may be performed at your 

discretion. 

 

Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions. 

(See 16 CFR 1500.3(c)(6) ). 

Flash Point: < 0°F (TCC) Upper Explosive Limit: 9.0 

Autoignition Temperature: 489°F Lower Explosive Limit: 1.7 

Fire and Explosion Data: 

Suitable Extinguishing Media: Class B fire extinguishers, dry chemical, foam or CO2 

Products of Combustion: Fumes, smoke and carbon monoxide 

Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors 

may accumulate in a confined space and create a flammable atmosphere. 

Protection of Fire-Fighters: 

Firefighters should wear self-contained, NIOSH-approved breathing apparatus for 

protection against suffocation and possible toxic decomposition products. Proper eye and 

skin protection should be provided. Use water spray to keep fire-exposed containers cool 

and to knock down vapors which may result from product decomposition. Do not spray 

water directly on fire; product will float and could be reignited on surface of water. 

 

Personal Precautions: Use personal protection recommended in Section 8. 

Page 2 of 7


72130 

Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into 

sewers or storm drains. 

Methods for Containment & Clean-up: Dike area to contain spill. Remove all sources of ignition. Ventilate the area with 

fresh air. If in confined space or limited air circulation area, clean-up workers 

should wear appropriate respiratory protection. Recover or absorb spilled 

material using an absorbent designed for chemical spills. Place used 

absorbents into proper waste containers. 

 

Handling Procedures: Use proper grounding and bonding procedures for transferring materials. Do not use product 

near any source of ignition. Avoid contact with eyes and skin. Avoid breathing vapors. Use 

caution around energized equipment. The metal container will conduct electricity if it contacts a 

live source. This may result in injury to the user from electrical shock and/or flash fire. For 

product use instructions, please see the product label. 

Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F to 

prevent cans from rupturing. 

Aerosol Storage Level: III 

 

Exposure Guidelines: 

OSHA ACGIH OTHER 

COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT 

Hexane isomers 500(v) 1000(v) 500 1000 NE ppm 

n-Hexane 500 NE 50(s) NE NE ppm 

Synthetic isoparaffinic hydrocarbon NE NE NE NE NE 

Methanol 200 250 (v) 200 250 NE ppm 

Carbon dioxide 5000 30000(v) 5000 30000 NE ppm 

Controls and Protection: 

N.E. – Not Established (c) – ceiling (s) – skin (v) – vacated 

Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally 

preferred because it can control the emissions of the contaminant at the source, preventing 

dispersion into the general work area. Use mechanical means if necessary to maintain vapor 

levels below the exposure guidelines. If working in a confined space, follow applicable OSHA 

regulations. 

Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls 

are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved 

cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual 

employee exposure levels. Use a self-contained breathing apparatus in confined spaces and 

for emergencies. 

Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid 

contact, wear splash-proof goggles. 

Skin Protection: Use protective gloves such as nitrile, PVC, Viton. Also, use full protective clothing if there is 

prolonged or repeated contact of liquid with skin. 

Page 3 of 7


72130 

 

Physical State: liquid 

Color: clear, colorless 

Odor: alcohol 

Odor Threshold: ND 


Initial Boiling Point: 140°F 

Freezing Point: < -76°F 

Vapor Pressure: 160 mmHg @ 68°F 

Vapor Density: > 1 (air = 1) 

Evaporation Rate: very fast 

Solubility: negligible in water 

Coefficient of water/oil distribution: ND 

pH: NA 

Volatile Organic Compounds: wt %: 95 g/L: 636.4 lbs./gal: 5.3 

 

Stability: Stable 

Conditions to Avoid: Sources of ignition, temperature extremes 

Incompatible Materials: Strong oxidizers 

Hazardous Decomposition Products: Oxides of carbon 

Possibility of Hazardous Reactions: No 

 

Long-term toxicological studies have not been conducted for this product. The following information is available for 

components of this product. 

Acute Toxicity: 

Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) 

Hexane isomers > 15,000 mg/kg > 2000 mg/kg No data 

n-Hexane 28,710 mg/kg 3000 mg/kg 48,000 ppm/4H 

Synthetic isoparaffinic hydrocarbon No data No data No data 

Methanol 5600 mg/kg 15,800 mg/kg 81,000 mg/m 3 /14H 

Carbon dioxide No data No data 470,000 ppm/30M 

Page 4 of 7


72130 

Chronic Toxicity: 

OSHA IARC NTP 

Component 

Carcinogen Carcinogen Carcinogen Irritant Sensitizer 

Hexane isomers No No No No Unknown 

No No No E (moderate) / Unknown 

n-Hexane 

S (moderate) / 

R (moderate) 

Synthetic isoparaffinic 

hydrocarbon 

No No No E (mild) Unknown 

Methanol 

No No No E (moderate) / S 

(moderate) 

Unknown 

Carbon dioxide No No No No No 

Reproductive Toxicity: No information available 

Teratogenicity: No information available 

Mutagenicity: No information available 

Synergistic Effects: No information available 

 

Ecological studies have not been conducted for this product. The following information is available for components of this 

product. 

Ecotoxicity: n-hexane - 48 Hr EC50 water flea: 3.87 mg/L 

96 Hr LC50 Lepomis macrochirus: 4.12 mg/L 

Persistence / Degradability: No information available 

Bioaccumulation / Accumulation: No information available 

Mobility in Environment: No information available 

 

Waste Classification: The dispensed liquid product is a RCRA hazardous waste for the characteristic of ignitability 

with a waste code of D001. Pressurized containers are a D003 reactive waste. (See 40 CFR 

Part 261.20 – 261.33) 

Any liquid product should be managed as a hazardous waste. Empty aerosol containers may 

be recycled. 

All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more 

stringent than state, provincial or national requirements. 

 

US DOT (ground): Consumer Commodity, ORM-D 

ICAO/IATA (air): Consumer Commodity, ID8000, 9 

IMO/IMDG (water): Aerosols, UN1950, 2.1, Limited Quantity 

Special Provisions: None 

Page 5 of 7 

E – Eye S – Skin R - Respiratory


72130 

 

U.S. Federal Regulations: 

Toxic Substances Control Act (TSCA): 

All ingredients are either listed on the TSCA inventory or are exempt. 

Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): 

Reportable Quantities (RQ’s) exist for the following ingredients: n-hexane (5000 lbs) 

methanol (5000 lbs) 

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to 

the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. 

Superfund Amendments Reauthorization Act (SARA) Title III: 

Section 302 Extremely Hazardous Substances (EHS): None 

Section 311/312 Hazard Categories: Fire Hazard Yes 

Reactive Hazard No 

Release of Pressure Yes 

Acute Health Hazard Yes 

Chronic Health Hazard Yes 

Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements 

of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 

1986 and 40 CFR Part 372: 

n-hexane (6.1%), methanol (0.9%) 

Clean Air Act: 

Section 112 Hazardous Air Pollutants (HAPs): n-hexane, methanol 

U.S. State Regulations: 

California Safe Drinking Water and Toxic Enforcement Act (Prop 65): 

This product may contain the following chemicals known to the state of 

California to cause cancer, birth defects or other reproductive harm: None 

Consumer Products VOC Regulations: This product does not comply with Consumer product VOC regulations and 

cannot be sold for use in California, Connecticut, Maine, Maryland, 

Massachusetts, New Jersey, Ohio and Pennsylvania. 

State Right to Know: 

New Jersey: 75-83-2, 109-66-0, 78-78-4, 96-37-7, 110-54-3, 79-29-8, 67-56-1, 124-38-9 

Pennsylvania: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 67-56-1, 124-38-9 

Massachusetts: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 67-56-1, 124-38-9 

Rhode Island : 75-83-2, 110-54-3, 79-29-8, 67-56-1, 124-38-9 

Canadian Regulations: 

Controlled Products Regulations: 

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the 

MSDS contains all the information required by the Controlled Products Regulations. 

WHMIS Hazard Class: A, B5, D2B 

Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. 

Page 6 of 7


72130 

European Union Regulations: 

RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the 

Council of 27 January 2003. This product does not contain any of the restricted substances as 

listed in Article 4(1) of the RoHS Directive. 

Additional Regulatory Information: None 

 

HMIS® (II) 

Health: 2 

Flammability: 3 

Reactivity: 0 

PPE: B 

Ratings range from 0 (no hazard) to 4 (severe hazard) 

Prepared By: Michelle Rudnick 

CRC #: 599C 

Revision Date: 04/162009 

Page 7 of 7 

NFPA 

Changes since last revision: MSDS reformatted to meet the requirements of the Canadian Controlled Products 

Regulations. 

The information contained in this document applies to this specific material as supplied. It may not be valid for this 

material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' 

knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and 

directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a 

health & safety professional, or CRC Industries. 

ACGIH: American Conference of Governmental Industrial Hygienists 

CAS: Chemical Abstract Service 

CFR: Code of Federal Regulations 

DOT: Department of Transportation 

DSL: Domestic Substance List 

g/L: grams per Liter 

HMIS: Hazardous Materials Identification System 

IARC: International Agency for Research on Cancer 

IATA: International Air Transport Association 

ICAO: International Civil Aviation Organization 

IMDG: International Maritime Dangerous Goods 

IMO: International Maritime Organization 

lbs./gal: pounds per gallon 

LC: Lethal Concentration 

LD: Lethal Dose 

2 

3 

0 

NA: Not Applicable 

ND: Not Determined 

NIOSH: National Institute of Occupational Safety & Health 

NFPA: National Fire Protection Association 

NTP: National Toxicology Program 


PMCC: Pensky-Martens Closed Cup 

PPE: Personal Protection Equipment 

ppm: Parts per Million 

RoHS: Restriction of Hazardous Substances 

STEL: Short Term Exposure Limit 

TCC: Tag Closed Cup 

TWA: Time Weighted Average 

WHMIS: Workplace Hazardous Materials Information 

System

SAFETY DATA SHEET 

-1- 

SDS NO. 08-F 


This Safety Data Sheet complies with European Commission Directive 91/155/EEC, ISO 11014-1 and ANSI Z400.1 


Product Name: ALL-STATE COPPER BASED BRAZING ALLOYS 

Bare P/Ns: 69063000, 69060001,069063001, 69160511, 69060002, 69063002, 69160510, 69160512, 

69060003, 69060004, 69060005 

Application: 

Coated P/Ns: 69063006, 69063020, 69060020, 69063007, 69063021, 69060021, 69060022, 69060023, 

69060025 

41FC P/Ns: 69051101, 69050101, 69053101, 090931, 69050102, 090981, 69001008, 69051100, 

69050100, 69053100, 090906 

Copper Based Brazing Alloys 

Classification: None 

Supplier: THE ESAB GROUP, INC., 801 Wilson Avenue, P. O. Box 517, Hanover, PA 17331 

Telephone No.: 1-717-637-8911, 1-800-933-7070 

Emergency No.: 1-717-637-8911 and 1-800-424-9300 (CHEMTREC) 

Web site: www.esabna.com 


Emergency Overview: Metal rods and coated metal rods in varying colors. These products are normally not considered hazardous 

as shipped. Gloves should be worn when handling to prevent cuts and abrasions. 

Avoid eye contact or inhalation of dust from these products. Skin contact is normally no hazard but should be avoided to prevent 

possible allergic reactions. 

Persons with a pacemaker should not go near brazing operations until they have consulted their doctor and obtained information 

from the manufacturer of the device. 

When these products are used in a brazing process, the most important hazards are heat, radiation, electric shock and brazing 

fumes. 

Heat: Spatter and melting metal can cause burn injuries and start fires. 

Radiation: Arc rays can severely damage eyes or skin. 

Electricity: Electric shock can kill. 

Fumes: Overexposure to brazing fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or 

irritation of the nose, throat or eyes. Chronic overexposure to brazing fumes may affect pulmonary function. 

Overexposure to manganese and manganese compounds above safe exposure limits can cause irreversible 

damage to the central nervous system, including the brain, symptoms of which may include slurred speech, 

lethargy, tremor, muscular weakness, psychological disturbances and spastic gait. 

Flame 

Processing: 

When used with combustible gas equipment (e.g., oxy-acetylene torch), read the use and safety information for 

that equipment. 


These products are solid metal rods and coated metal rods. 

Ingredients CAS# EINECS# Hazard 


IARC (2) NTP (3) OSHA List (4) 

Borax Glass 1330-43-4 215-540-4 No -- -- -- 

Boric Acid 10043-35-3 233-139-2 No -- -- -- 

Copper 7440-50-8 231-159-6 No -- -- -- 

Iron 7439-89-6 231-096-4 No -- -- -- 

Manganese 7439-96-5 231-105-1 No -- -- -- 

Silicon 7440-21-3 231-130-8 No -- -- --

Product Identity: ALL-STATE COPPER BASED BRAZING ALLOYS 

-2- 

SDS NO. 08-F 


Ingredients CAS# EINECS# Hazard 


IARC (2) NTP (3) OSHA List (4) 

Tin 7440-31-5 231-141-8 No -- -- -- 

Zinc 7440-66-6 231-175-3 F; R15-17N; 

R50-53 

-- -- -- 

Proprietary 

Methacryalate/Apliphatic and 

Naphthenic Hydrocarbon 

Compound 

Trade Secret Not known No -- -- -- 

(1) 

Hazard Classification according to European Council Directive 67/548/EEC, for R-phrases, see Section 16. 

(2) 

Evaluation according to the International Agency for Research on Cancer. 

1 – Human Carcinogen 2B – Possibly carcinogenic to humans 

(3) 

Classification according to the 11th Report on Carcinogens, published by the US National Toxicology Program. 

K – Known Carcinogen S – Suspect Carcinogen 

(4) 

Carcinogen listing according to OSHA, Occupational Safety & Health Administration (USA). 

All-State 



All-State Low Fuming 

Bronze Bare 

All-State Low Fuming 

Bronze Flux Coated 

All-State 41FC 

Borax -- 0.5-2.5 0.5-2.5 

Boric Acid -- 3-6 3-6 

Copper 56-62 55-58 55-58 

Iron


-3- 

SDS NO. 08-F 



Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up and placed into a container. Wear 

proper protective equipment while handling these materials. Do not discard as refuse. 

Personal precautions: refer to Section 8. 

Environmental precautions: refer to Section 13. 


Handling: 

Handle with care to avoid stings and cuts. Wear gloves when handling welding consumables. Avoid exposure to dust. Do not ingest. 

Some individuals can develop an allergic reaction to certain materials. Retain all warning and identity labels. 

Storage: 

Keep separate from chemical substances like acids and strong bases, which could cause chemical reactions. 

8. EXPOSURE CONTROL/PERSONAL PROTECTION 

Avoid exposure to brazing fumes, radiation, spatter, electric shock, heated materials and dust. 

Engineering measures: (Brazing operations) 

Ensure sufficient ventilation, local exhaust, or both, to keep brazing fumes and gases from breathing zone and general area. Keep 

working place and protective clothing clean and dry. Train welders to avoid contact with live electrical parts and insulate conductive 

parts. Check condition of protective clothing and equipment on a regular basis. 

Personal protective equipment: (Brazing operations) 

Use respirator or air supplied respirator when brazing in a confined space, or where local exhaust or ventilation is not sufficient to keep 

exposure values within safe limits. Use special care when brazing painted or coated steels since hazardous substances from the 

coating may be emitted. Wear hand, head, eyes, ear and body protection like welders gloves, helmet or face shield with filter lens, 

safety boots, apron, arm and shoulder protection. Keep protective clothing clean and dry. 

Use industrial hygiene monitoring equipment to ensure that exposure does not exceed applicable national exposure limits. The 

following limits can be used as guidance. For information about brazing fume analysis refer to Section 10. 

Substance CAS# ACGIH TLV (1) mg/m 3 OSHA PEL (2) mg/m 3 

Borax Glass (as borates) 1330-43-4 2 ***, 6 (STEL) *** None 

Boric Acid 10043-35-3 None None 

Copper (metal) fume 

7440-50-8 0.2 

0.1 (fume) 

dust/mist 

1 

1 (dust/mist) 

Iron (as iron oxide) 7439-89-6 5** 10 

Manganese & 

Manganese compounds (as Mn) 

7439-96-5 0.2 5 Ceiling 

Silicon (nuisance dust) 7440-21-3 10*, 3*** 15*, 5** 

Tin (metal) 7440-31-5 2 2 

Zinc (metal) 7440-66-6 None None 

(1) 

Threshold Limit Values according to American Conference of Governmental Hygienists, 2010 

(2) 

Permissible Exposure Limits according to the Occupational Safety & Health Administration (USA) 

Unless noted, all values are for 8 hour time weighted averages (TWA). 

* Total dust, ** Respirable fraction, *** Inhalable fraction. 

NOTE: Some of these products may not contain all of the materials listed. For details of composition, refer to the COMPOSITION 

TABLES in Section 2.



Appearance: Metal rods and coated metal rods in varying colors. 

Specific Gravity: 8.3 – 8.5 (H2O = 1) 

Boiling Point: 2595°C/4703°F (copper) 907°C/1665°F (zinc) 

Melting Point: 1600-1900°C/871-1038°F (copper) 419°C/786°F (zinc) 

Vapor Pressure: Not determined (solid). 

Vapor Density: Not determined (solid). 

Evaporation Rate: Not applicable. 

Solubility in Water: None. 

Flash Point: Not flammable. 

Upper/Lower Flame Limit: None. 

Auto-ignition Temperature: None. 

-4- 

SDS NO. 08-F 



General: These products are intended for normal brazing purposes. 

Stability: These products are stable under normal conditions. 

Reactivity: Contact with chemical substances like acids or strong bases could cause generation of gas. 

When these products are used in a brazing process, hazardous decomposition products would include those from the volatilization, 

reaction or oxidation of the materials listed in Section 3 and those from the base metal and coating. 

Fumes from these products may contain compounds of the following chemical elements: B, Cu, Fe, O, Mn, Si, Sn and Zn. The rest is 

not analyzed, according to available standards. 

Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume compounds found in 

Section 8. Manganese has a low exposure limit, in some countries that may be easily exceeded. 

Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants around the 

brazing area can be affected by the brazing process and influence the composition and quantity of fumes and gases produced. 


Inhalation of brazing fumes and gases can be dangerous to your health. Classification of brazing fumes is difficult because of varying 

base materials, coatings, air contamination and processes. The International Agency for Research on Cancer has classified welding 

fumes as possibly carcinogenic to humans (Group 2B). 

Acute toxicity: Overexposure to brazing fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or 

irritation of the nose, throat or eyes. 

Chronic toxicity: Overexposure to brazing fumes may affect pulmonary function. Overexposure to manganese and manganese 

compounds above safe exposure limits can cause irreversible damage to the central nervous system, including the 

brain, symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological 

disturbances and spastic gait. 


Contains zinc which may be toxic to aquatic species and is regulated as an environmental hazard in the European Union. This hazard 

is not anticipated from the handling of brazing consumables but is relevant if consumables enter natural waterways. 

Brazing consumables and materials could degrade/weather into components originating from the consumables or from the materials 

used in the brazing process. Avoid exposure to conditions that could lead to accumulation in soils or groundwater.


-5- 

SDS NO. 08-F 



Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal and local 

regulations. Use recycling procedures if available. 

USA RCRA: These products are not considered hazardous waste if discarded. 

Residues from brazing consumables and processes could degrade and accumulate in soils and groundwater. Brazing residues from 

these products typically contain mainly the following components: B, Cu, Fe, O, Mn, Si, Sn, and Zn. 


No international regulations or restrictions are applicable. 


Read and understand the manufacturer's instructions, your employer's safety practices and the health and safety instructions on the 

label. Observe any federal and local regulations. Take precautions when brazing and protect yourself and others. 

WARNING: Brazing fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate 

ventilation. 

ELECTRIC SHOCK can kill. 

ARC RAYS and SPARKS can injure eyes and burn skin. 

Wear correct hand, head, eye and body protection. 

Canada: WHMIS classification: Class D; Division 2, Subdivision A 

Canadian Environmental Protection Act (CEPA): All constituents of these products are on the Domestic Substance List 

(DSL). 

USA: Under the OSHA Hazard Communication Standard, these products are considered hazardous. 

These products contain or produce a chemical known to the state of California to cause cancer and birth defects (or other 

reproductive harm). (California Health & Safety Code § 25249.5 et seq.) 

United States EPA Toxic Substance Control Act: All constituents of these products are on the TSCA inventory list or are 

excluded from listing. 

CERCLA/SARA Title III 

Reportable Quantities (RQs) and/or Threshold Planning Quantities (TPQs): 

Ingredient name RQ (lb) TPQ (lb) 

Product is a solid solution in the form of a solid article. -- -- 

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National 

Response Center and to your Local Emergency Planning Committee. 

Section 311 Hazard Class 

As shipped: Immediate, delayed In use: Immediate, delayed 

EPCRA/SARA Title III 313 Toxic Chemicals 

The following components are listed as SARA 313 “Toxic Chemicals” and potential subject to annual SARA 313 reporting. 

See Section 3 for weight percent. 

Ingredient name Disclosure threshold 

Copper 1.0% de minimis concentration 

Manganese 1.0% de minimis concentration


-6- 

SDS NO. 08-F 



This Safety Data Sheet has been revised due to modifications to several paragraphs and/or new format. This SDS supersedes 8-E. 

Refer to ESAB “Welding and Cutting - Risks and Measures”, F52-529 “Precautions and Safe Practices for Electric Welding and 

Cutting” and F2035 “Precautions and Safe Practices for Gas Welding, Cutting and Heating” available from ESAB, and to: 

USA: Contact ESAB at www.esabna.com or 1-800-ESAB-123 if you have questions about this SDS. 

American National Standard Z49.1 "Safety in Welding and Cutting", ANSI/AWS F1.5 “Methods for Sampling and Analyzing 

Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles Generated by 

Welding and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American Welding Society, 550 North 

Le Jeune Road, Miami, Florida, 33135. Safety and Health Fact Sheets available from AWS at www.aws.org. 

OSHA Publication 2206 (29 C.F.R. 1910), U.S. Government Printing Office, Superintendent of Documents, P.O. Box 

371954, Pittsburgh, PA 15250-7954. 

American Conference of Governmental Hygienists (ACGIH), Threshold Limit Values and Biological Exposure Indices, 6500 

Glenway Ave., Cincinnati, Ohio 45211, USA. 

NFPA 51B “Standard for Fire Prevention During Welding, Cutting and Other Hot Work” published by the National Fire 

Protection Association, 1 Batterymarch Park, Quincy, MA 02169. 

UK: WMA Publication 236 and 237, “Hazards from Welding Fume”, “The arc welder at work, some general aspects of health 

and safety”. 

Germany: Unfallverhütungsvorschrift BGV D1, “Schweißen, Schneiden und verwandte Verfahren”. 

Canada: CSA Standard CAN/CSA-W117.2-01 “Safety in Welding, Cutting and Allied Processes”. 

These products have been classified according to the hazard criteria of the CPR and the SDS contains all the information 

required by the CPR. 

R-phrases: R15 – Contact with water liberates extremely flammable gases. 

R17 – Spontaneously flammable in air. 

R50 – Very toxic to aquatic organisms. 

R53 – May cause long-term adverse effects in the aquatic environment. 

ESAB requests the users of these products to study this Safety Data Sheet (SDS) and become aware of product hazards and safety 

information. To promote safe use of these products a user should: 

- notify its employees, agents and contractors of the information on this S.D.S and any product hazards/safety information. 

- furnish this same information to each of its customers for these products. 

- request such customers to notify employees and customers for the same product hazards and safety information. 

The information herein is given in good faith and based on technical data that ESAB believes to be reliable. Since the conditions of 

use are outside our control, we assume no liability in connection with any use of this information and no warranty, expressed or implied 

is given. Contact ESAB for more information.


Copper(II) acetylacetonate 

MSDS# 50570 

Section 1 - Chemical Product and Company Identification 

MSDS Name: Copper(II) acetylacetonate 

Catalog Numbers: AC110650000, AC110650250, AC110651000 

Synonyms: 2,4-Pentanedione, metal derivative; Cupric acetylacetonate. 

Company Identification: 

Acros Organics BVBA 

Janssen Pharmaceuticalaan 3a 

2440 Geel, Belgium 

Acros Organics 

Company Identification: (USA) 

One Reagent Lane 

Fair Lawn, NJ 07410 

For information in the US, call: 800-ACROS-01 

For information in Europe, call: +32 14 57 52 11 

Emergency Number, Europe: +32 14 57 52 99 

Emergency Number US: 201-796-7100 

CHEMTREC Phone Number, US: 800-424-9300 

CHEMTREC Phone Number, Europe: 703-527-3887 

---------------------------------------- 

Section 2 - Composition, Information on Ingredients 

CAS#: 13395-16-9 

Chemical Name: Copper(II) acetylacetonate 

%: 99 

EINECS#: 

---------------------------------------- 

236-477-9 

Hazard Symbols: XN 

Risk Phrases: 20/21/22 36/37/38 

Section 3 - Hazards Identification 


Warning! Harmful if swallowed, inhaled, or absorbed through the skin. Causes eye, skin, and respiratory tract irritation. 

Target Organs: Respiratory system, eyes, skin. 

Potential Health Effects 

Eye: Causes eye irritation. 

Skin: Causes skin irritation. Harmful if absorbed through the skin. 

Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. 

Inhalation: Harmful if inhaled. Causes respiratory tract irritation. 

Chronic: No information found. 

Eyes: 

Section 4 - First Aid Measures 

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower 

eyelids. Get medical aid immediately.

Skin: 

Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing 

contaminated clothing and shoes. 

Ingestion: Do not induce vomiting. Get medical aid immediately. Call a poison control center. 

Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is 

Inhalation: 

difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; 

induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper 

respiratory medical device. 

Notes to 

Physician: 

Treat symptomatically and supportively. 

General 

Information: 

Section 5 - Fire Fighting Measures 

As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH 

(approved or equivalent), and full protective gear. Dangerous fire hazard in the form of dust when 

exposed to heat or flame. 

Extinguishing 

Use water spray, dry chemical, carbon dioxide, or chemical foam. 

Media: 

Autoignition 

250 deg C ( 482.00 deg F) 

Temperature: 

Flash Point: Not applicable. 

Explosion Limits: 

Not available 

Lower: 

Explosion Limits: 

Not available 

Upper: 

NFPA Rating: health: 2; flammability: 1; instability: 0; 

General 

Information: 

Spills/Leaks: 

Section 6 - Accidental Release Measures 

Use proper personal protective equipment as indicated in Section 8. 

Vacuum or sweep up material and place into a suitable disposal container. Wear a self contained breathing 

apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). 

Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment. 

Section 7 - Handling and Storage 

Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. 

Handling: 

Use only in a chemical fume hood. 

Storage: Store in a cool, dry place. Store in a tightly closed container. 

Section 8 - Exposure Controls, Personal Protection 

+-------------------- +------------------- +------------------- +----------------- + 

| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs| 

|-------------------- |------------------- |------------------- |----------------- | 

| Copper(II) acetylac|none listed |1 mg/m3 TWA (dust |none listed | 

| etonate | |and mist, as Cu, | | 

| | | except copper | | 

| | | fume) (listed | | 

| | |under Copper | | 

| | | compounds, | | 

| | |n.o.s.).100 mg/m3 | | 

| | |IDLH (dust and | | 

| | | mist, as Cu) | | 

| | | (listed under | | 

| | | Copper | | 

| | |compounds, | | 

| | | n.o.s.). | | 

+-------------------- +------------------- +------------------- +----------------- + 

OSHA Vacated PELs: Copper(II) acetylacetonate: None listed 

Engineering Controls: 

Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only 

under a chemical fume hood. 

Exposure Limits

Personal Protective Equipment 

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face 

Eyes: 

protection regulations in 29 CFR 1910.133 or European Standard EN166. 

Skin: Wear appropriate protective gloves to prevent skin exposure. 

Clothing: Wear appropriate protective clothing to prevent skin exposure. 

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a 

Respirators: NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if 

irritation or other symptoms are experienced. 

Section 9 - Physical and Chemical Properties 

Physical State: Crystalline powder 

Color: blue-gray - blue 

Odor: weak odor 

pH: Not available 

Vapor Pressure: 0.13 hPa @ 163 deg C 

Vapor Density: Not available 

Evaporation Rate: Not available 

Viscosity: Not available 

Boiling Point: 160 deg C @ 9.8 mmHg ( 320.00°F) 

Freezing/Melting Point: 245 deg C (decom) 

Decomposition Temperature: 

Solubility in water: 0.2 g/L (20°C) 

Specific Gravity/Density: 

Molecular Formula: C10H14O4Cu 

Molecular Weight: 261.76 

Section 10 - Stability and Reactivity 

Chemical Stability: Stable under normal temperatures and pressures. 

Conditions to Avoid: Incompatible materials, dust generation, excess heat. 

Incompatibilities with Other Materials Strong oxidizing agents. 

Hazardous Decomposition Products Carbon monoxide, carbon dioxide, 2,4-pentanedione, oxides of copper. 

Hazardous Polymerization Will not occur. 

Section 11 - Toxicological Information 

RTECS#: CAS# 13395-16-9: GL6520000 

LD50/LC50: RTECS: Not available. 

Carcinogenicity: Copper(II) acetylacetonate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. 

Other: The toxicological properties have not been fully investigated. 

Other: Do not empty into drains. 

Section 12 - Ecological Information 

Section 13 - Disposal Considerations 

Dispose of in a manner consistent with federal, state, and local regulations. 

Section 14 - Transport Information 

US DOT 

Shipping Name: Not regulated as a hazardous material 

Hazard Class: 

UN Number: 

Packing Group: 

Canada TDG 

Shipping Name: Not available 

Hazard Class: 

UN Number: 

Packing Group:

European/International Regulations 

US Federal 

TSCA 

European Labeling in Accordance with EC Directives 

Hazard Symbols: XN 

Risk Phrases: 

Section 15 - Regulatory Information 

R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. 

R 36/37/38 Irritating to eyes, respiratory system and skin. 

Safety Phrases: 

S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 

S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 

WGK (Water Danger/Protection) 

Canada 

CAS# 13395-16-9: Not available 

CAS# 13395-16-9 is listed on Canada's DSL List 

Canadian WHMIS Classifications: D1B, D2B 

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations 

and the MSDS contains all of the information required by those regulations. 

CAS# 13395-16-9 is not listed on Canada's Ingredient Disclosure List. 

CAS# 13395-16-9 is listed on the TSCA 

Inventory. 

Section 16 - Other Information 

MSDS Creation Date: 9/02/1997 

Revision #7 Date 7/20/2009 

The information above is believed to be accurate and represents the best information currently available 

to us. However, we make no warranty of merchantibility or any other warranty, express or implied, 

with respect to such information, and we assume no liability resulting from its use. Users should make 

their own investigations to determine the suitability of the information for their particular purposes. In no 

event shall the company be liable for any claims, losses, or damages of any third party or for lost profits 

or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the 

company has been advised of the possibility of such damages. 

--------------------------------------------------------------------------------

Material Safety Data Sheet https://www.cbest.chevron.com/msdsServer/controller?module=com.che... 


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION 

SPECIAL LS DIESEL 2 

Product Use: Fuel 

Product Number(s): CPS203408, CPS203411, CPS203412, CPS203415, CPS203416, CPS203418, CPS203419, 

CPS203420, CPS203423, CPS203424, CPS225116, CPS225119, CPS272105, CPS272111, CPS272116, 

CPS272127, CPS272128, CPS272193, CPS272393, CPS272596 

Synonyms: CALCO SPECIAL LS DIESEL 2, CALCO SPECIAL ULS DIESEL 2, CARB DIESEL, CARB S15 DIESEL, 

CARB S500 DIESEL, CARB ULSD, CHEVRON SPECIAL LS DIESEL 2, CHEVRON SPECIAL ULS DIESEL 2, ULTRA 

LOW SULFUR DIESEL 

Company Identification 

Chevron Products Company 

Marketing, MSDS Coordinator 

6001 Bollinger Canyon Road 

San Ramon, CA 94583 

United States of America 

Transportation Emergency Response 

CHEMTREC: (800) 424-9300 or (703) 527-3887 

Health Emergency 

Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800) 231-0623 or 

(510) 231-0623 

Product Information 

MSDS Requests: (800) 689-3998 

Technical Information: (510) 242-5357 

SPECIAL NOTES: This MSDS covers all Chevron and Calco CARB Low Sulfur Diesel No. 2 Fuels. Red dye is added to 

non-taxable fuel. (MSDS 7098) 

SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS 

COMPONENTS CAS NUMBER AMOUNT 

Diesel Fuel No. 2 68476-34-6 100 %wt/wt 

Distillates, hydrodesulfurized, middle 64742-80-9 0 - 100 %wt/wt 

Distillates, straight run middle (gas oil, light) 64741-44-2 0 - 100 %wt/wt 

Kerosine 8008-20-6 0 - 25 %wt/wt 

Kerosine, hydrodesulfurized 64742-81-0 0 - 25 %wt/wt 

Distillates (petroleum), light catalytic cracked 64741-59-9 0 - 50 %wt/wt 

Naphthalene 91-20-3 0.02 - 0.2 %wt/wt 

Total sulfur None 0 - 0.05 %wt/wt 

SECTION 3 HAZARDS IDENTIFICATION 

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************************************************************************************************************************ 


- COMBUSTIBLE LIQUID AND VAPOR 

- HARMFUL OR FATAL IF SWALLOWED - MAY CAUSE LUNG DAMAGE IF SWALLOWED 

- CAUSES SKIN IRRITATION 

- MAY CAUSE CANCER BASED ON ANIMAL DATA 

************************************************************************************************************************ 

IMMEDIATE HEALTH EFFECTS 

Eye: Not expected to cause prolonged or significant eye irritation. 

Skin: Contact with the skin causes irritation. Skin contact may cause drying or defatting of the skin. Symptoms may 

include pain, itching, discoloration, swelling, and blistering. Contact with the skin is not expected to cause an allergic 

skin response. Not expected to be harmful to internal organs if absorbed through the skin. 

Ingestion: Because of its low viscosity, this material can directly enter the lungs, if swallowed, or if subsequently 

vomited. Once in the lungs it is very difficult to remove and can cause severe injury or death. May be irritating to mouth, 

throat, and stomach. Symptoms may include pain, nausea, vomiting, and diarrhea. 

Inhalation: Mists of this material may cause respiratory irritation. Symptoms of respiratory irritation may include 

coughing and difficulty breathing. 

DELAYED OR OTHER HEALTH EFFECTS: 

Cancer: Prolonged or repeated exposure to this material may cause cancer. Whole diesel engine exhaust has been 

classified as a Group 2A carcinogen (probably carcinogenic to humans) by the International Agency for Research on 

Cancer (IARC). Diesel exhaust particulate has been classified as reasonably anticipated to be a human carcinogen in 

the National Toxicology Program's Ninth Report on Carcinogens. The National Institute of Occupational Safety and 

Health (NIOSH) has recommended that whole diesel exhaust be regarded as potentially causing cancer. Diesel engine 

exhaust is known to the State of California to cause cancer. Contains naphthalene, which has been classified as a 

Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency for Research on Cancer (IARC). 

See Section 11 for additional information. Risk depends on duration and level of exposure. 

SECTION 4 FIRST AID MEASURES 

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with 

water. 

Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical attention if any 

symptoms develop. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or 

thoroughly clean before reuse. 

Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by mouth to an 

unconscious person. 

Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give 

oxygen. Get medical attention if breathing difficulties continue. 

Note to Physicians: Ingestion of this product or subsequent vomiting may result in aspiration of light hydrocarbon 

liquid, which may cause pneumonitis. 

SECTION 5 FIRE FIGHTING MEASURES 

See Section 7 for proper handling and storage. 

FIRE CLASSIFICATION: 

OSHA Classification (29 CFR 1910.1200): Combustible liquid. 

NFPA RATINGS: Health: 0 Flammability: 2 Reactivity: 0 

FLAMMABLE PROPERTIES: 

Flashpoint: (Pensky-Martens Closed Cup) 52 °C (125 °F) (Min) 

Autoignition: 257 °C (494 °F) 

Flammability (Explosive) Limits (% by volume in air): Lower: 0.6 Upper: 4.7 

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. 

PROTECTION OF FIRE FIGHTERS: 

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Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space without 

proper protective equipment, including self-contained breathing apparatus. 

Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and 

gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this 

material undergoes combustion. 

SECTION 6 ACCIDENTAL RELEASE MEASURES 

Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this material is 

released into the work area, evacuate the area immediately. Monitor area with combustible gas indicator. 

Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further 

contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in 

Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent 

materials or pumping. All equipment used when handling the product must be grounded. A vapor suppressing foam 

may be used to reduce vapors. Use clean non-sparking tools to collect absorbed material. Where feasible and 

appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a 

manner consistent with applicable regulations. 

Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802 

as appropriate or required. 

SECTION 7 HANDLING AND STORAGE 

Precautionary Measures: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with explosive 

force. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment, and 

electrical motors and switches. Fire hazard is greater as liquid temperature rises above 29C (85F). 

Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Do not breathe vapor or fumes. Do not breathe mist. 

Wash thoroughly after handling. Keep out of the reach of children. 

Unusual Handling Hazards: WARNING! Do not use as portable heater or appliance fuel. Toxic fumes may 

accumulate and cause death. 

General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems 

and bodies of water. 

Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To 

minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all 

operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable 

atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, 

mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer 

to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association 

(NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended 

Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'. 

General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE AND 

STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use. 

Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may 

rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. 

Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static 

electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be 

completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. 

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 

GENERAL CONSIDERATIONS: 

Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other 

substances in the work place when designing engineering controls and selecting personal protective equipment. If 

engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the 

personal protective equipment listed below is recommended. The user should read and understand all instructions and 

limitations supplied with the equipment since protection is usually provided for a limited time or under certain 

circumstances. 

ENGINEERING CONTROLS: 

Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the 

recommended exposure limits. 

PERSONAL PROTECTIVE EQUIPMENT 

Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses 

with side shields as a good safety practice. 

3 z 7 2008-07-24 14:04


Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may include gloves, 

apron, boots, and complete facial protection depending on operations conducted. Suggested materials for protective 

gloves include: Viton, Chlorinated Polyethylene (or Chlorosulfonated Polyethylene), Nitrile Rubber, Polyurethane. 

Respiratory Protection: Determine if airborne concentrations are below the recommended occupational exposure 

limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an approved respirator that 

provides adequate protection from this material, such as: Air-Purifying Respirator for Organic Vapors. 

When used as a fuel, this material can produce carbon monoxide in the exhaust. Determine if airborne concentrations 

are below the occupational exposure limit for carbon monoxide. If not, wear an approved positive-pressure air-supplying 

respirator. 

Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide 

adequate protection. 

Occupational Exposure Limits: 

Component Agency TWA STEL Ceiling Notation 

Diesel Fuel No. 2 ACGIH 100 mg/m3 -- -- Skin A3 total 

hydrocarbon 

Diesel Fuel No. 2 CVX -- 1000 mg/m3 -- -- 

Kerosine ACGIH 200 mg/m3 -- -- Skin A3 Total 

hydrocabon 

vapor 

Kerosine CVX -- 1000 mg/m3 -- -- 

Kerosine, hydrodesulfurized ACGIH 200 mg/m3 -- -- Skin A3 Total 

hydrocabon 

vapor 

Kerosine, hydrodesulfurized CVX -- 1000 mg/m3 -- -- 

Naphthalene ACGIH 10 ppm (weight) 15 ppm (weight) -- Skin 

Naphthalene OSHA Z-1 50 mg/m3 -- -- -- 

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 

Attention: the data below are typical values and do not constitute a specification. 

Color: Varies depending on specification 


Odor: Petroleum odor 

pH: Not Applicable 

Vapor Pressure: 0.04 kPa (Approximate) @ 40 °C (104 °F) 

Vapor Density (Air = 1): >1 

Boiling Point: 175.6°C (348°F) - 370°C (698°F) 

Solubility: Soluble in hydrocarbons; insoluble in water 

Freezing Point: Not Applicable 

Melting Point: Not Applicable 

Specific Gravity: 0.8 - 0.88 @ 15.6°C (60.1°F) (Typical) 

Viscosity: 1.9 cSt - 4.1 cSt @ 40°C (104°F) 

SECTION 10 STABILITY AND REACTIVITY 

Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling 

conditions of temperature and pressure. 

Incompatibility With Other Materials: May react with strong acids or strong oxidizing agents, such as chlorates, 

nitrates, peroxides, etc. 

Hazardous Decomposition Products: None known (None expected) 

Hazardous Polymerization: Hazardous polymerization will not occur. 

SECTION 11 TOXICOLOGICAL INFORMATION 

IMMEDIATE HEALTH EFFECTS 

Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components. 

Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components. 

4 z 7 2008-07-24 14:04


Skin Sensitization: This material did not cause skin sensitization reactions in a Buehler guinea pig test. 

Acute Dermal Toxicity: LD50: >5ml/kg (rabbit). 

Acute Oral Toxicity: LD50: > 5 ml/kg (rat) 

Acute Inhalation Toxicity: 4 hour(s) LC50: > 5mg/l (rat). 

ADDITIONAL TOXICOLOGY INFORMATION: 

This product contains gas oils. 

CONCAWE (product dossier 95/107) has summarized current health, safety and environmental data available for a 

number of gas oils, typically hydrodesulfurized middle distillates, CAS 64742-80-9, straight-run middle distillates, CAS 

64741-44-2, and/or light cat-cracked distillate CAS 64741-59-9. CARCINOGENICITY: All materials tested have caused 

the development of skin tumors in mice, but all featured severe skin irritation and sometimes a long latency period 

before tumors developed. Straight-run and cracked gas oil samples were studied to determine the influence of dermal 

irritation on the carcinogenic activity of middle distillates. At non-irritant doses the straight-run gas oil was not 

carcinogenic, but at irritant doses, weak activity was demonstrated. Cracked gas oils, when diluted with mineral oil, 

demonstrated carcinogenic activity irrespective of the occurrence of skin irritation. Gas oils were tested on male mice to 

study tumor initiating/promoting activity. The results demonstrated that while a straight-run gas oil sample was neither 

an initiator or promotor, a blend of straight-run and FCC stock was both a tumor initiator and a promoter. 

GENOTOXICITY: Hydrotreated & hydrodesulfurized gas oils range in activity from inactive to weakly positive in in-vitro 

bacterial mutagenicity assays. Mouse lymphoma assays on straight-run gas oils without subsequent 

hydrodesulphurization gave positive results in the presence of S9 metabolic activation. In-vivo bone marrow 

cytogenetics and sister chromatic exchange assay exhibited no activity for straight-run components with or without 

hydrodesulphurization. Thermally or catalytically cracked gas oils tested with in-vitro bacterial mutagenicity assays in the 

presence of S9 metabolic activation were shown to be mutagenic. In-vitro sister chromatic exchange assays on cracked 

gas oil gave equivocal results both with and without S9 metabolic activation. In-vivo bone marrow cytogenetics assay 

was inactive for two cracked gas oil samples. Three hydrocracked gas oils were tested with in-vitro bacterial 

mutagenicity assays with S9, and one of the three gave positive results. Twelve distillate fuel samples were tested with 

in-vitro bacterial mutagenicity assays & with S9 metabolic activation and showed negative to weakly positive results. In 

one series, activity was shown to be related to the PCA content of samples tested. Two in-vivo studies were also 

conducted. A mouse dominant lethal assay was negative for a sample of diesel fuel. In the other study, 9 samples of No 

2 heating oil containing 50% cracked stocks caused a slight increase in the number of chromosomal aberrations in 

bone marrow cytogenetics assays. DEVELOPMENTAL TOXICITY: Diesel fuel vapor did not cause fetotoxic or 

teratogenic effects when pregnant rats were exposed on days 6-15 of pregnancy. Gas oils were applied to the skin of 

pregnant rats daily on days 0-19 of gestation. All but one (coker light gas oil) caused fetotoxicity (increased resorptions, 

reduced litter weight, reduced litter size) at dose levels that were also maternally toxic. 

This product contains naphthalene. 

GENERAL TOXICITY: Exposure to naphthalene has been reported to cause methemoglobinemia and/or hemolytic 

anemia, especially in humans deficient in the enzyme glucose-6-phosphate dehydrogenase. Laboratory animals given 

repeated oral doses of naphthalene have developed cataracts. REPRODUCTIVE TOXICITY AND BIRTH DEFECTS: 

Naphthalene did not cause birth defects when administered orally to rabbits, rats, and mice during pregnancy, but 

slightly reduced litter size in mice at dose levels that were lethal to the pregnant females. Naphthalene has been 

reported to cross the human placenta. 

GENETIC TOXICITY: Naphthalene caused chromosome aberrations and sister chromatid exchanges in Chinese 

hamster ovary cells, but was not a mutagen in several other in-vitro tests. 

CARCINOGENICITY: In a study conducted by the National Toxicology Program (NTP), mice exposed to 10 or 30 ppm 

of naphthalene by inhalation daily for two years had chronic inflammation of the nose and lungs and increased 

incidences of metaplasia in those tissues. The incidence of benign lung tumors (alveolar/bronchiolar adenomas) was 

significantly increased in the high-dose female group but not in the male groups. In another two-year inhalation study 

conducted by NTP, exposure of rats to 10, 30, and 60 ppm naphthalene caused increases in the incidences of a variety 

of nonneoplastic lesions in the nose. Increases in nasal tumors were seen in both sexes, including olfactory 

neuroblastomas in females at 60 ppm and adenomas of the respiratory epithelium in males at all exposure levels. The 

relevance of these effects to humans has not been established. No carcinogenic effect was reported in a 2-year feeding 

study in rats receiving naphthalene at 41 mg/kg/day. This product may contain significant amounts of Polynuclear 

Aromatic Hydrocarbons (PAH's) which have been shown to cause skin cancer after prolonged and frequent contact with 

the skin of test animals. Brief or intermittent skin contact with this product is not expected to have serious effects if it is 

washed from the skin. While skin cancer is unlikely to occur in human beings following use of this product, skin contact 

and breathing, of mists, vapors or dusts should be reduced to a minimum. 

SECTION 12 ECOLOGICAL INFORMATION 

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ECOTOXICITY 

48 hour(s) EC50: 20-210 mg/l (Daphnia magna) 

96 hour(s) LC50: 21-210 mg/l (Salmo gairdneri) 

72 hour(s) EC50: 2.6-25 mg/l (Raphidocellus subcapitata) 

ENVIRONMENTAL FATE 

On release to the environment the lighter components of diesel fuel will generally evaporate but depending on local 

environmental conditions (temperature, wind, mixing or wave action, soil type, etc.) the remainder may become 

dispersed in the water column or absorbed to soil or sediment. Diesel fuel would not be expected to be readily 

biodegradable. In a modified Strum test (OECD method 301B) approximately 40% biodegradation was recorded over 

28 days. However, it has been shown that most hydrocarbon components of diesel fuel are degraded in soil in the 

presence of oxygen. Under anaerobic conditions, such as in anoxic sediments, rates of biodegradation are negligible. 

SECTION 13 DISPOSAL CONSIDERATIONS 

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria 

of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. 

Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct 

determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous 

waste disposal facility. 

SECTION 14 TRANSPORT INFORMATION 

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods 

Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific 

shipping requirements. 

DOT Shipping Description: UN1202, GAS OIL, COMBUSTIBLE LIQUID, III 

IMO/IMDG Shipping Description: UN1202, GAS OIL, 3, III, FLASH POINT SEE SECTION 5 

ICAO/IATA Shipping Description: UN1202, GAS OIL, 3, III 

SECTION 15 REGULATORY INFORMATION 

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES 

2. Delayed (Chronic) Health Effects: YES 

3. Fire Hazard: YES 

4. Sudden Release of Pressure Hazard: NO 

5. Reactivity Hazard: NO 

REGULATORY LISTS SEARCHED: 

01-1=IARC Group 1 03=EPCRA 313 

01-2A=IARC Group 2A 04=CA Proposition 65 

01-2B=IARC Group 2B 05=MA RTK 

02=NTP Carcinogen 06=NJ RTK 

07=PA RTK 

The following components of this material are found on the regulatory lists indicated. 

Diesel Fuel No. 2 07 

Distillates, straight run middle (gas oil, light) 06 

Kerosine 05, 06, 07 

Naphthalene 01-2B, 02, 03, 04, 05, 06, 07 

CERCLA REPORTABLE QUANTITIES(RQ)/EPCRA 302 THRESHOLD PLANNING QUANTITIES(TPQ): 

Component Component RQ Component TPQ Product RQ 

Naphthalene 100 lbs None 55556 lbs 

6 z 7 2008-07-24 14:04


CHEMICAL INVENTORIES: 

All components comply with the following chemical inventory requirements: AICS (Australia), DSL (Canada), EINECS 

(European Union), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United States). 

NEW JERSEY RTK CLASSIFICATION: 

Refer to components listed in Section 2. Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 

34:5A-1 et. seq., the product is to be identified as follows: DIESEL FUEL 

WHMIS CLASSIFICATION: 

Class B, Division 3: Combustible Liquids 

Class D, Division 2, Subdivision A: Very Toxic Material - 


Class D, Division 2, Subdivision B: Toxic Material - 

Skin or Eye Irritation 

SECTION 16 OTHER INFORMATION 


(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *- 

Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the 

National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). 

REVISION STATEMENT: This revision updates the following sections of this Material Safety Data Sheet: 1, 16. 

Revision Date: March 21, 2008 

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: 

TLV - Threshold Limit Value TWA - Time Weighted Average 

STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit 

CAS - Chemical Abstract Service Number 

ACGIH - American Conference of Government IMO/IMDG - International Maritime Dangerous Goods Code 

Industrial Hygienists 

API - American Petroleum Institute MSDS - Material Safety Data Sheet 

CVX - Chevron NFPA - National Fire Protection Association (USA) 

DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA) 

IARC - International Agency for Research on Cancer OSHA - Occupational Safety and Health Administration 

Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI 

MSDS Standard (Z400.1) by the Chevron Energy Technology Company, 100 Chevron Way, Richmond, 

California 94802. 

The above information is based on the data of which we are aware and is believed to be correct as 

of the date hereof. Since this information may be applied under conditions beyond our control and 

with which we may be unfamiliar and since data made available subsequent to the date hereof may 

suggest modifications of the information, we do not assume any responsibility for the results of its 

use. This information is furnished upon condition that the person receiving it shall make his own 

determination of the suitability of the material for his particular purpose. 

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MATERIAL SAFETY DATA SHEET 3M Duct Tape 3900, 3939, 6969 & 3M General Use Duct Tape 2929 & 3M Outdoor 

Masking and Stucco Tape 5959 & 3M Performance Plus Duct Tape 8979 & 8979N & 3M Value Duct Tape 1900 & Scotch(r) 

Polyethylene Coated Cloth Tape 390 02/02/10 


Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly 

utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is 

obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit 

thereon. 

This material safety data sheet (MSDS) is provided as a courtesy in response to a customer request. This product is not regulated 

under, and a MSDS is not required for this product by the OSHA Hazard Communication Standard (29 CFR 1910.1200) because, 

when used as recommended or under ordinary conditions, it should not present a health and safety hazard. However, use or 

processing of the product not in accordance with the product's recommendations or not under ordinary conditions may affect the 

performance of the product and may present potential health and safety hazards. 

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NAME: 3M Duct Tape 3900, 3939, 6969 & 3M General Use Duct Tape 2929 & 3M 

Outdoor Masking and Stucco Tape 5959 & 3M Performance Plus Duct Tape 8979 & 

8979N & 3M Value Duct Tape 1900 & Scotch(r) Polyethylene Coated Cloth Tape 390 

MANUFACTURER: 3M 

DIVISION: Industrial Adhesives and Tapes Division 

ADDRESS: 3M Center 

St. Paul, MN 55144-1000 

Issue Date: 02/02/10 

Supercedes Date: 02/02/10 

Document Group: 26-2650-5 

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) 

Product Use: 

Specific Use: Bundling, Reinforcing, & Sealing 

Intended Use: Industrial use 

SECTION 2: INGREDIENTS 

Ingredient C.A.S. No. % by Wt 

Polyethylene Film over Cloth Scrim Backing None 51 - 99 

Rubber Adhesive Trade Secret 1 - 49 

SECTION 3: HAZARDS IDENTIFICATION 

3.1 EMERGENCY OVERVIEW 

_________________________________________________________________________________________________ 

Page 1 of 7




Odor, Color, Grade: various colored duct tape 

General Physical Form: Solid 

Immediate health, physical, and environmental hazards: The environmental properties of this product present a low 

environmental hazard. This product, when used under reasonable conditions and in accordance with the 3M directions for use, should 

not present a health hazard. However, use or processing of the product in a manner not in accordance with the product's directions for 

use may affect the performance of the product and may present potential health and safety hazards. 

3.2 POTENTIAL HEALTH EFFECTS 

Eye Contact: 

No health effects are expected. 

Skin Contact: 


Inhalation: 


Ingestion: 


3.3 POTENTIAL ENVIRONMENTAL EFFECTS 

This substance does not leach metals or other RCRA (Resource Conservation and Recovery Act) listed TCLP (Toxic Characteristic 

Leaching Procedure) hazardous substances at concentrations that would make the product a hazardous waste. 

SECTION 4: FIRST AID MEASURES 

4.1 FIRST AID PROCEDURES 

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are 

followed. 

Eye Contact: No need for first aid is anticipated. 

Skin Contact: No need for first aid is anticipated. 

Inhalation: No need for first aid is anticipated. 

If Swallowed: No need for first aid is anticipated. 

SECTION 5: FIRE FIGHTING MEASURES 

5.1 FLAMMABLE PROPERTIES 

_________________________________________________________________________________________________ 

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Autoignition temperature Not Applicable 

Flash Point Not Applicable 

Flammable Limits - LEL Not Applicable 

Flammable Limits - UEL Not Applicable 

5.2 EXTINGUISHING MEDIA 

Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 

5.3 PROTECTION OF FIRE FIGHTERS 

Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus 

(SCBA). 

Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. 

SECTION 6: ACCIDENTAL RELEASE MEASURES 

Accidental Release Measures: 


SECTION 7: HANDLING AND STORAGE 

7.1 HANDLING 

This product is considered to be an article which does not release or otherwise result in exposure to a hazardous chemical under 

normal use conditions. 

7.2 STORAGE 


SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

8.1 ENGINEERING CONTROLS 


8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 

8.2.1 Eye/Face Protection 

Avoid eye contact. 

8.2.2 Skin Protection 

Avoid prolonged or repeated skin contact. 

_________________________________________________________________________________________________ 

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8.2.3 Respiratory Protection 

Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 

8.2.4 Prevention of Swallowing 


8.3 EXPOSURE GUIDELINES 

None Established 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 

Odor, Color, Grade: various colored duct tape 

General Physical Form: Solid 

Autoignition temperature Not Applicable 

Flash Point Not Applicable 

Flammable Limits - LEL Not Applicable 

Flammable Limits - UEL Not Applicable 

Boiling point Not Applicable 

Density Not Applicable 

Vapor Density Not Applicable 

Vapor Pressure Not Applicable 

Specific Gravity Not Applicable 

pH Not Applicable 

Melting point Not Applicable 

Solubility in Water Nil 

Evaporation rate Not Applicable 

Volatile Organic Compounds Not Applicable 

Kow - Oct/Water partition coef Not Applicable 

Percent volatile Not Applicable 

VOC Less H2O & Exempt Solvents Not Applicable 

Viscosity Not Applicable 

SECTION 10: STABILITY AND REACTIVITY 


Materials and Conditions to Avoid: 

10.1 Conditions to avoid 

None known 

10.2 Materials to avoid 

None known 

_________________________________________________________________________________________________ 

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Hazardous Polymerization: Hazardous polymerization will not occur. 

Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous 

decomposition products may occur as a result of oxidation, heating, or reaction with another material. 

SECTION 11: TOXICOLOGICAL INFORMATION 

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its 

components. 

SECTION 12: ECOLOGICAL INFORMATION 

ECOTOXICOLOGICAL INFORMATION 

Not determined. 

CHEMICAL FATE INFORMATION 


SECTION 13: DISPOSAL CONSIDERATIONS 

Waste Disposal Method: Reclaim if feasible. If product can't be reclaimed, dispose of waste product in a sanitary landfill. 

Alternatively, incinerate the waste product in an industrial, commercial, or municipal incinerator. 

Since regulations vary, consult applicable regulations or authorities before disposal. 

SECTION 14:TRANSPORT INFORMATION 

Not regulated per U.S. DOT, IATA or IMO. 

_________________________________________________________________________________________________ 

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These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for 

complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M’s 

transportation classifications are based on product formulation, packaging, 3M policies and 3M’s understanding of applicable 

current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to 

transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified 

for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory 

requirements. 

SECTION 15: REGULATORY INFORMATION 

US FEDERAL REGULATIONS 

Contact 3M for more information. 

311/312 Hazard Categories: 

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No 

STATE REGULATIONS 


CHEMICAL INVENTORIES 

This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements. 


INTERNATIONAL REGULATIONS 


This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 

SECTION 16: OTHER INFORMATION 

NFPA Hazard Classification 

Health: 0 Flammability: 1 Reactivity: 0 Special Hazards: None 

_________________________________________________________________________________________________ 

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National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are 

presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the 

inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to 

be generated in significant quantities. 

Revision Changes: 

Section 2: Product identification comment was deleted. 

Section 1: Product name was modified. 

Page Heading: Product name was modified. 

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M 

MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY 

OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF 

TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of 

use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely 

within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a 

particular purpose and suitable for user's method of use or application. 

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may 

have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. 

In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 

3M MSDSs are available at www.3M.com 

_________________________________________________________________________________________________ 

Page 7 of 7


Dow Corning Corporation 

South Saginaw Road 

Midland, Michigan 48686 

DOW CORNING CORPORATION 


DOW CORNING 997(R) VARNISH 

24 Hour Emergency Telephone: 

Customer Service: 

Product Disposal Information: 

CHEMTREC: 

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Version: 3.3 


(989) 496-5900 

(989) 496-6000 

(989) 496-6315 

(800) 424-9300 

MSDS No.: 01002015 Revision Date: 2009/01/27 

Generic Description: Silicone resin. 

Physical Form: Liquid 

Color: Brown 

Odor: Solvent odor. 

Note: NFPA = National Fire Protection Association 


Acute Effects 

NFPA Profile: Health 2 Flammability 3 Instability/Reactivity 0 

POTENTIAL HEALTH EFFECTS 

Eye: Direct contact may cause severe irritation. Vapor may cause eye irritation. 

Skin: May cause moderate irritation. 

Inhalation: Vapor may irritate nose and throat. Overexposure by inhalation may cause drowsiness, 

dizziness, confusion or loss of coordination. 

Oral: Aspiration of liquid while vomiting may injure lungs seriously. 

Prolonged/Repeated Exposure Effects 

Skin: Repeated or prolonged contact may cause defatting and drying of skin which may result in 

skin irritation and dermatitis. Repeated skin contact may cause allergic skin reaction. 

Overexposure may injure internally if absorbed. 

Inhalation: Overexposure by inhalation may injure the following organ(s): Nervous system. Liver. 

Kidneys. Lungs. 

Oral: Repeated ingestion or swallowing large amounts may injure internally. 

Signs and Symptoms of Overexposure 

No known applicable information. 

Medical Conditions Aggravated by Exposure





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The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, 

component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 


CAS Number Wt % Component Name 

1330-20-7 30.0 - 60.0 Xylene 

100-41-4 10.0 - 30.0 Ethylbenzene 

64742-94-5 3.0 - 7.0 Heavy aromatic petroleum solvent naphtha 

8001-26-1 3.0 - 7.0 Linseed Oil 

91-20-3




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Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide 

(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. 

Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large 

fires involving chemicals. Determine the need to evacuate or isolate the area according to 

your local emergency plan. Use water spray to keep fire exposed containers cool. 

Unusual Fire Hazards: Vapors are heavier than air and may travel to a source of ignition and flash back. Static 

electricity will accumulate and may ignite vapors. Prevent a possible fire hazard by bonding 

and grounding or inert gas purge. 


Containment/Clean up: Remove possible ignition sources. Determine whether to evacuate or isolate the area 

according to your local emergency plan. Observe all personal protection equipment 

recommendations described in Sections 5 and 8. For large spills, provide diking or other 

appropriate containment to keep material from spreading. If diked material can be pumped, 

store recovered material in appropriate container. Clean up remaining materials from spill 

with suitable absorbant. Clean area as appropriate since spilled materials, even in small 

quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or 

detergents. Dispose of saturated absorbant or cleaning materials appropriately, since 

spontaneous heating may occur. Local, state and federal laws and regulations may apply to 

releases and disposal of this material, as well as those materials and items employed in the 

cleanup of releases. You will need to determine which federal, state and local laws and 

regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding 

certain federal and state requirements. 

Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is 

required. 


Use with adequate ventilation. Traces of benzene (carcinogen) may form if heated in air above 300 F (149 C). Provide 

ventilation to control vapor exposure within inhalation guidelines when handling at elevated temperatures. Review the 

OSHA benzene regulation for detailed information on safe handling requirements. Avoid eye exposure. Avoid skin 

contact. Avoid breathing vapor, mist, dust, or fumes. Keep container closed. Do not take internally. 

Static electricity will accumulate and may ignite vapors. Prevent a possible fire hazard by bonding and grounding or inert 

gas purge. Keep container closed and away from heat, sparks, and flame. 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION 

Component Exposure Limits 

CAS Number Component Name Exposure Limits




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1330-20-7 Xylene Observe xylene limits. OSHA PEL (final rule) and ACGIH 

TLV: TWA 100 ppm, STEL 150 ppm. 

100-41-4 Ethylbenzene OSHA PEL (final rule): TWA 100 ppm, 435 mg/m3. ACGIH 

TLV: TWA 100 ppm, STEL 125 ppm. 

64742-94-5 Heavy aromatic petroleum solvent 

naphtha 

Observe petroleum distillates limits. OSHA PEL (final rule): 

TWA 400 ppm. 

91-20-3 Naphthalene OSHA PEL (final rule): TWA 10 ppm and ACGIH TLV-skin: 

TWA 10 ppm, STEL 15 ppm. 

Engineering Controls 

Local Ventilation: Recommended. 

General Ventilation: Recommended. 

Personal Protective Equipment for Routine Handling 

Eyes: Use chemical worker's goggles. 

Skin: Wash at mealtime and end of shift. If skin contact occurs, change contaminated clothing as 

soon as possible and thoroughly flush affected areas with cool water. Chemical protective 

gloves are recommended. 

Suitable Gloves: Avoid skin contact by implementing good industrial hygiene practices and procedures. Select 

and use gloves and/or protective clothing to further minimize the potential for skin contact. 

Consult with your glove and/or personnel protective equipment manufacturer for selection of 

appropriate compatible materials. 

Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure 

assessment demonstrates that exposures are within recommended exposure guidelines. IH 

personnel can assist in judging the adequacy of existing engineering controls. 

Suitable Respirator: General and local exhaust ventilation is recommended to maintain vapor exposures below 

recommended limits. Where concentrations are above recommended limits or are unknown, 

appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 

CFR 1910.134) and use NIOSH/MSHA approved respirators. 

Personal Protective Equipment for Spills 

Eyes: Use full face respirator. 

Skin: Wash at mealtime and end of shift. If skin contact occurs, change contaminated clothing as 

soon as possible and thoroughly flush affected areas with cool water. Chemical protective 

gloves are recommended.

Inhalation/Suitable 

Respirator: 




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Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR 

1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air purifying 

respirators against exposure to any hazardous chemical is limited. Use a positive pressure air 

supplied respirator if there is any potential for uncontrolled release, exposure levels are 

unknown, or any other circumstance where air purifying respirators may not provide adequate 

protection. 

Precautionary Measures: Avoid eye exposure. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep 

container closed. Do not take internally. Use reasonable care. 

Comments: Traces of benzene (carcinogen) may form if heated in air above 300 F (149 C). Provide 

ventilation to control vapor exposure within inhalation guidelines when handling at elevated 

temperatures. Review the OSHA benzene regulation for detailed information on safe 

handling requirements. 

When heated to temperatures above 150 C (300 F) in the presence of air, product can form 

formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and 

respiratory sensitizer. Vapors irritate eyes, nose, and throat. Safe handling conditions may be 

maintained by keeping vapor conditions within the OSHA permissible exposure limit for 

formaldehyde. 

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require 

added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the 

use of silicone-based materials in aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact 

the Dow Corning customer service group. 


Physical Form: Liquid 

Color: Brown 

Odor: Solvent odor. 

Specific Gravity @ 25°C: 1.002 

Viscosity: 105 cSt 

Freezing/Melting Point: Not determined. 

Boiling Point: > 130 °C 

Vapor Pressure @ 25°C: Not determined. 

Vapor Density: Not determined. 

Solubility in Water: Not determined. 

pH: Not determined. 

Volatile Content: Not determined. 

Flash Point: 77 °F / 25 °C (Pensky-Martens Closed Cup) 

Autoignition Temperature: Not determined. 

Flammability Limits in Air: Not determined. 

Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing 

specifications.


Chemical Stability: Stable. 




Hazardous 

Polymerization: 

Hazardous polymerization will not occur. 

Conditions to Avoid: None. 

Materials to Avoid: Oxidizing material can cause a reaction. 

Hazardous Decomposition Products 

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Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition 

products: Carbon oxides and traces of incompletely burned carbon compounds. Metal oxides. Silicon dioxide. 

Formaldehyde. 


Special Hazard Information on Components 

Carcinogens 


100-41-4 10.0 - 30.0 Ethylbenzene IARC Group 2B - Possibly Carcinogenic 

to Humans. 

91-20-3





8001-26-1 3.0 - 7.0 Linseed Oil Possible skin sensitizer. 


Environmental Fate and Distribution 

Complete information is not yet available. 

Environmental Effects 


Fate and Effects in Waste Water Treatment Plants 


Ecotoxicity Classification Criteria 

Hazard Parameters (LC50 or EC50) High Medium Low 

Acute Aquatic Toxicity (mg/L) 1 and 100 

Acute Terrestrial Toxicity 100 and 2000 

This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993. 

Page: 7 of 11 

Version: 3.3 


This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the 

section concerning the overall ecological safety of this material. 


RCRA Hazard Class (40 CFR 261) 

When a decision is made to discard this material, as received, is it classified as a hazardous waste? Yes 

Characteristic Waste: 

Ignitable: D001 

TCLP: D018 

State or local laws may impose additional regulatory requirements regarding disposal.Call (989) 496-6315, if additional 

information is required. 


DOT Road Shipment Information (49 CFR 172.101) 

Proper Shipping Name: Flammable liquids, n.o.s. 

Hazard Technical Name: Xylene / Ethylbenzene

Hazard Class: 3 


Packing Group: III 

Hazard Label(s): Flammable Liquid 

Ocean Shipment (IMDG) 

Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. 

Hazard Technical Name: Xylene / Ethylbenzene 




Hazard Label(s): flammable liquid 

Air Shipment (IATA) 

Proper Shipping Name: Flammable liquid, n.o.s. 

Hazard Technical Name: Xylene / Ethylbenzene 




Hazard Label(s): Flammable Liquid 




Call Dow Corning Transportation, (989) 496-8577, if additional information is required. 


Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. 

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TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA 

Inventory of Chemical Substances. 

EPA SARA Title III Chemical Listings 

Section 302 Extremely Hazardous Substances (40 CFR 355):

None. 




Section 304 CERCLA Hazardous Substances (40 CFR 302): 


1330-20-7 35.0 Xylene 

100-41-4 10.9 Ethylbenzene 

91-20-3


1330-20-7 30.0 - 60.0 Xylene 

100-41-4 10.0 - 30.0 Ethylbenzene 

New Jersey 





68037-66-1 40.0 - 70.0 Dimethyl, methyl, phenyl, phenylmethyl silicone resin 

1330-20-7 30.0 - 60.0 Xylene 

100-41-4 10.0 - 30.0 Ethylbenzene 

64742-94-5 3.0 - 7.0 Heavy aromatic petroleum solvent naphtha 

8001-26-1 3.0 - 7.0 Linseed Oil 

Pennsylvania 

91-20-3


Prepared by: Dow Corning Corporation 




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Version: 3.3 


These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or 

implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally 

applicable. However, each user should review these recommendations in the specific context of the intended use and 

determine whether they are appropriate. 

(R) indicates Registered Trademark


1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION Page: 1 

24-Hour Emergency Phone Number: 989-636-4400 

Product: D.E.R.* 332 EPOXY RESIN 

Product Code: 19251 

Effective Date: 04/16/04 Date Printed: 04/17/04 MSD: 002199 

The Dow Chemical Company, Midland, MI 48674 

Customer Information Center: 800-258-2436 


Diglycidyl Ether of Bisphenol A CAS# 001675-54-3 100% 



************************************************************************ 

* Yellow liquid. Mild odor. May cause allergic skin reaction. * 

************************************************************************ 

POTENTIAL HEALTH EFFECTS (See Section 11 for toxicological data.) 

EYE: May cause slight temporary eye irritation. Corneal injury 

is unlikely. 

SKIN: Has caused allergic skin reactions in humans. Prolonged 

exposure not likely to cause significant skin irritation. 

Repeated contact may cause skin irritation with local redness. 

Prolonged skin contact is unlikely to result in absorption of 

harmful amounts. 

INGESTION: Very low toxicity if swallowed. Harmful effects not 

anticipated from swallowing small amounts. 

INHALATION: Vapors are unlikely due to physical properties. 

SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: Except for skin 

sensitization, repeated exposures to low molecular weight 

epoxy resins of this type are not anticipated to cause any 

significant adverse effects. 

(Continued on page 2 , over) 

* OR (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY

M A T E R I A L S A F E T Y D A T A S H E E T PAGE: 2 




------------------------------------------------------------------------ 

CANCER INFORMATION: Many studies have been conducted to 

assess the potential carcinogenicity of diglycidyl ether of 

bisphenol A (DGEBPA). Although some weak evidence of 

carcinogenicity has been reported in animals, when all of 

the data are considered, the weight of evidence does not 

show that DGEBPA is carcinogenic. Indeed, the most recent 

review of the available data by the International Agency for 

Research on Cancer (IARC) has concluded that DBEBPA is not 

classified as a carcinogen. 

TERATOLOGY (BIRTH DEFECTS): DGEBPA did not cause birth defects 

or other adverse effects on the fetus when pregnant rabbits were 

exposed by skin contact, the most likely route of exposure, or 

when pregnant rats or rabbits were exposed orally. 

REPRODUCTIVE EFFECTS: In animal studies, did not interfere with 

reproduction. 

4. FIRST AID 

EYES: Flush eyes thoroughly with water for several minutes. 

Remove contact lenses after initial 1-2 minutes and continue 

flushing for several additional minutes. If effects occur, 

consult a physician, preferably an ophthalmologist. 

SKIN: Wash skin with plenty of water. Items which cannot be 

decontaminated, including leather articles such as shoes, belts, 

and watchbands should be disposed of properly. 

INGESTION: No emergency medical treatment necessary. 

INHALATION: Move person to fresh air; if effects occur, consult 

a physician. 

NOTE TO PHYSICIAN: Consider additional thorough skin wash with 

mild non-abrasive soap and plenty of warm water for at least 

15 minutes. No specific antidote. Treatment of exposure 

should be directed at the control of symptoms and the clinical 

condition of the patient. 


FLAMMABLE PROPERTIES 

FLASH POINT: 485, 252C 

METHOD USED: PMCC 

(Continued on page 3) 






------------------------------------------------------------------------ 

AUTOIGNITION TEMPERATURE: Not applicable 

FLAMMABILITY LIMITS 

LFL: Not applicable 

UFL: Not applicable 

HAZARDOUS COMBUSTION PRODUCTS: During a fire, smoke may contain 

the original material in addition to combustion products of 

varying composition which may be toxic and/or irritating. 

Combustion products may include and are not limited to: phenolic 

compounds, carbon monoxide, carbon dioxide. 

OTHER FLAMMABILITY INFORMATION: Container may rupture from gas 

generation in a fire situation. Violent steam generation or 

eruption may occur upon application of direct water stream to 

hot liquids. Dense smoke is emitted when burned without 

sufficient oxygen. 

EXTINGUISHING MEDIA: Water fog or fine spray, dry chemical fire 

extinguishers, carbon dioxide fire extinguishers and foam. Do 

not use direct water stream. May spread fire. Alcohol 

resistant foams (ATC type) are preferred. General purpose 

synthetic foams (including AFFF) or protein foams may function, 

but will be less effective. Water fog, applied gently may be 

used as a blanket for fire extinguishment. 

FIRE FIGHTING INSTRUCTIONS: Keep people away. Isolate fire 

area and deny unnecessary entry. Use water spray to cool fire 

exposed containers and fire affected zone until fire is out and 

danger of re-ignition has passed. Fight fire from protected 

location or safe distance. Consider use of unmanned hose 

holder or monitor nozzles. Immediately withdraw all personnel 

from area in case of rising sound from venting safety device 

or discoloration of the container. Do not use direct water 

stream. May spread fire. Move container from fire area if this 

is possible without hazard. Burning liquids may be moved by 

flushing with water to protect personnel and minimize property 

damage. Water fog, applied gently may be used as a blanket 

for fire extinguishment. 

PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear positive pressure 

self-contained breathing apparatus (SCBA) and protective fire 

fighting clothing (includes fire fighting helmet, coat, pants, 

boots, and gloves). If protective equipment is not available 

or not used, fight fire from a protected location or safe 

distance. 

6. ACCIDENTAL RELEASE MEASURES (See Section 15 for Regulatory 

Information) 

(Continued on page 4 , over)





------------------------------------------------------------------------ 

PROTECT PEOPLE: Isolate area. Keep unnecessary and unprotected 

personnel from entering the area. Use appropriate safety 

equipment. For additional information, refer to Section 8, 

Exposure Controls/Personal Protection. Refer to Section 7, 

Handling, for additional precautionary measures. 

PROTECT THE ENVIRONMENT: Prevent from entering into soil, 

ditches, sewers, waterways and/or groundwater. See Section 

12, Ecological Information. 

CLEANUP: Absorb with material such as sand or polypropylene or 

polyethylene fiber products. Collect in suitable and properly 

labeled containers. Remove residual with soap and hot water. 

Solvents are not recommended for clean up unless the recommended 

exposure guidelines and safe handling practices for the specific 

solvent are followed. Consult appropriate solvent SDS for 

handling information and exposure guidelines. 


HANDLING: Avoid contact with skin and clothing. Wash thoroughly 

after handling. See Section 8, Exposure Controls/Personal 

Protection. 

STORAGE: Recommended pumping and storage temperature range is 

125F to 140F (51C to 60C). Additional storage information on 

this product may be obtained by calling your Dow sales or 

customer service contact. Ask for a product brochure. 


ENGINEERING CONTROLS: Good general ventilation should be 

sufficient for most conditions. 

PERSONAL PROTECTIVE EQUIPMENT 

EYE/FACE PROTECTION: Use safety glasses. 

SKIN PROTECTION: Use protective clothing chemically resistant 

to this material. Selection of specific items such as faceshield, 

gloves, boots, apron or full body suit will depend on 

operation. Remove contaminated clothing immediately, wash 

skin area with soap and water, and launder clothing before 

reuse or dispose of properly. Items which cannot be 

decontaminated, such as shoes, belts and watchbands, should 







------------------------------------------------------------------------ 

be removed and disposed of properly. 

RESPIRATORY PROTECTION: No respiratory protection should be 

needed. 

EXPOSURE GUIDELINE(S): None established. 


APPEARANCE/PHYSICAL STATE: Yellow liquid 

ODOR: Mild 

VAPOR PRESSURE: Not applicable 

VAPOR DENSITY: Not applicable 

BOILING POINT: Not applicable 

SOLUBILITY IN WATER: None 

SPECIFIC GRAVITY: 1.16 


CHEMICAL STABILITY: Stable under recommended storage conditions. 

See Storage, Section 7. 

CONDITIONS TO AVOID: Avoid temperatures above 350C, 662F. 

Potentially violent decomposition can occur above 350C, 662F. 

Generation of gas during decomposition can cause pressure in 

closed systems. Pressure build-up can be rapid. 

INCOMPATIBILITY WITH OTHER MATERIALS: Avoid contact with: 

oxidizing materials, acids, bases. Avoid unintended contact 

with amines. 

HAZARDOUS DECOMPOSITION PRODUCTS: Decomposition products depend 

upon temperature, air supply and the presence of other 

materials. Gases are released during decomposition. 

Uncontrolled exothermic reaction of epoxy resins release 

phenolics, carbon monoxide and water. 

HAZARDOUS POLYMERIZATION: Will not occur by itself. Masses of 

more than one pound (0.5kg) of product plus an aliphatic amine 

will cause irreversible polymerization with considerable heat 

buildup. 

11. TOXICOLOGICAL INFORMATION (See Section 3 for Potential Health 

Effects. For detailed toxicological data, write or call the 

address or non-emergency number shown in Section 1) 

(Continued on page 6 , over) 






------------------------------------------------------------------------ 

SKIN: The LD50 for skin absorption in rabbits is 20,000 mg/kg. 

INGESTION: The oral LD50 for rats is >5000 mg/kg. 

MUTAGENICITY (EFFECTS ON GENETIC MATERIAL): Animal genetic 

toxicity studies were negative. In vitro genetic toxicity 

studies were negative in some cases and positive in other cases. 

12. ECOLOGICAL INFORMATION (For detailed Ecological data, write or call 

the address or non-emergency number shown in Section 1) 


MOVEMENT & PARTITIONING: Bioconcentration potential is moderate 

(BCF between 100 and 3000 or Log Pow between 3 and 5). 

Measured log octanol/water partition coefficient (log Pow) 

is 3.7-3.9. Potential for mobility in soil is low (Koc 

between 500 and 2000). Soil organic carbon/water partition 

coefficient (Koc) is estimated to be 1800-4400. Henry's Law 

Constant (H) is estimated to be 100 mg/L. 

13. DISPOSAL CONSIDERATIONS (See Section 15 for Regulatory Information) 

DISPOSAL: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO 

ANY BODY OF WATER. All disposal methods must be in compliance 







------------------------------------------------------------------------ 

with all Federal, State/Provincial and local laws and 

regulations. Regulations may vary in different locations. 

Waste characterizations and compliance with applicable laws 

are the responsibility solely of the waste generator. 

THE DOW CHEMICAL COMPANY HAS NO CONTROL OVER THE MANAGEMENT 

PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR 

USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS 

ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS 

DESCRIBED IN MSDS SECTION 2 (Composition/Information On 

Ingredients). 

FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options 

include sending to a licensed, permitted: recycler, 

reclaimer, incinerator or other thermal destruction device. 

As a service to its customers, Dow can provide names of 

information resources to help identify waste management 

companies and other facilities which recycle, reprocess or 

manage chemicals or plastics, and that manage used drums. 

Telephone Dow's Customer Information Center at 800-258-2436 

or 989-832-1556 for further details. 


DEPARTMENT OF TRANSPORTATION (D.O.T.): For D.O.T. regulatory 

information, if required, consult transportation regulations, 

product shipping papers or contact your Dow representative. 

CANADIAN TDG INFORMATION: For TDG regulatory information, if 

required, consult transportation regulations, product shipping 

papers, or contact your Dow representative. 

15. REGULATORY INFORMATION (Not meant to be all-inclusive--selected 

regulations represented) 

NOTICE: The information herein is presented in good faith and 

believed to be accurate as of the effective date shown above. However, 

no warranty, express or implied is given. Regulatory requirements 

are subject to change and may differ from one location to another; 

it is the buyer's responsibility to ensure that its activities comply 

with federal, state or provincial, and local laws. The following 

specific information is made for the purpose of complying with 

numerous federal, state or provincial, and local laws and regulations. 

See other sections for health and safety information. 

U.S. REGULATIONS 

====================





------------------------------------------------------------------------ 

REGULATORY INFORMATION (CONTINUED) 

SARA 313 INFORMATION: To the best of our knowledge, this product 

contains no chemical subject to SARA Title III Section 313 supplier 

notification requirements. 

--------------------- 

SARA HAZARD CATEGORY: This product has been reviewed according to the 

EPA "Hazard Categories" promulgated under Sections 311 and 312 of the 

Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and 

is considered, under applicable definitions, to meet the following 

categories: 

An immediate health hazard 

--------------------- 

TOXIC SUBSTANCES CONTROL ACT (TSCA): 

All ingredients are on the TSCA inventory or are not required to be 

listed on the TSCA inventory. 

----- 

--------------------- 

STATE RIGHT-TO-KNOW: This product is not known to contain any 

substances subject to the disclosure requirements of 

Pennsylvania 

--------------------- 

OSHA HAZARD COMMUNICATION STANDARD: 

This product is a "Hazardous Chemical" as defined by the OSHA Hazard 

Communication Standard, 29 CFR 1910.1200. 

CANADIAN REGULATIONS 

==================== 

WHMIS INFORMATION: The Canadian Workplace Hazardous Materials 

Information System (WHMIS) Classification for this product is: 

D2B - skin sensitizer 

Refer elsewhere in the MSDS for specific warnings and 







------------------------------------------------------------------------ 

REGULATORY INFORMATION (CONTINUED) 

safe handling information. Refer to the employer's 

workplace education program. 

- - - - - 

CPR STATEMENT: This product has been classified in accordance with the 

hazard criteria of the Canadian Controlled Products Regulations (CPR) 

and the MSDS contains all the information required by the CPR. 

- - - - - 

HAZARDOUS PRODUCTS ACT INFORMATION: This product contains the following 

ingredients which are Controlled Products and/or on the Ingredient 

Disclosure List (Canadian HPA section 13 and 14): 

COMPONENTS: CAS # AMOUNT(%w/w) 

Diglycidyl ether of 001675-54-3 100% 

bisphenol A 

--------------------- 

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): 

All substances in this product are listed on the Canadian Domestic 

Substances List (DSL) or are not required to be listed. 


MSDS STATUS: Revised Sections 3,4,5,6,7,8,9,10,11,15. 

* OR (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY 

The Information Herein Is Given In Good Faith, But No Warranty, 

Express Or Implied, Is Made. Consult The Dow Chemical Company 

For Further Information.


Nelson Firestop Products 

Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards 

PART I What is the material and what do I need to know in an emergency? 

1. PRODUCT IDENTIFICATION 

TRADE NAME (AS LABELED): FSC3, Joint Fire Protective Coating 

CHEMICAL NAME/CLASS: Filled Vinyl & Acrylic Emulsion 

SYNONYMS: None 

PRODUCT USE: Elastomeric Firestop, Intumescent 

SUPPLIER/MANUFACTURER'S NAME: EGS Nelson Firestop 

ADDRESS: 4135 S. 100 th East Avenue, Suite 100 

Tulsa, Oklahoma 74146 

CHEMTREC EMERGENCY NO.: 1-800-424-9300 (United States) 

BUSINESS PHONE: (918) 627-5530/(800) 331-7325 

DATE OF PREPARATION: January, 2002 

2. COMPOSITION and INFORMATION ON INGREDIENTS 

Ingredient CAS # Percent (max) 

2-Propenoic acid, polymer 052640-81-0 10 – 20 

Aluminum oxide 001344-28-1 5 – 10 

Calcium carbonate 001317-65-3 10 – 20 

Ethylene Glycol 000107-21-1 < 1 

Methenamine 000100-97-0 < 1 

Phenol,isopropylated, phosphate (3:1) 068937-41-7 1 – 5 

Phenol-formaldehyde polymer 009003-35-4 5 – 10 

Polyvinyl Acetate Emulsion NJ801415075P 10 – 20 

Quartz 014808-60-7 < 1 

Triphenyl phosphate 000115-86-6 1 - 5 

FSC3 Joint Fire Protective Coating MSDS 

PAGE 1 OF 7


3. HAZARD IDENTIFICATION 

EMERGENCY OVERVIEW: The chief health hazard associated with overexposure would be the potential to slightly irritate 

the eyes, skin, nose, and other tissues that come in contact with this product or in the event that particulates are 

generated from the product. This product is not flammable or reactive. Emergency responders must wear proper personal 

protective equipment for the releases to which they are responding. 

SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: Under 

normal circumstances of use, this product should not present significant 

health hazards. The most significant routes of occupational overexposure 

would be via inhalation and contact with skin. The symptoms of 

overexposure to this product, via route of entry, are as follows: 

INHALATION: Breathing airborne particulates, if generated during use of 

this product, may irritate the nose, throat, or upper respiratory system. 

Symptoms of such exposure could include nausea, coughing and sneezing, 

tightness of chest. Hypersensitive individuals may experience allergic 

respiratory reaction and wheezing. Symptoms are generally alleviated when 

exposure ends. 

CONTACT WITH SKIN or EYES: Spray applications of this material may 

create aerosols which may be irritating to the eyes. Prolonged eye contact 

can result in permanent damage. Minor skin contact may cause irritation. 

Prolonged skin contact can result in burns. Hypersensitive individuals may 

develop an allergic reaction resulting in dermatitis, rash or hives. 

SKIN ABSORPTION: Harmful if absorbed through the skin. 

INGESTION: Ingestion of this product is unlikely. May be irritating if 

ingested, Reproductive and developmental effects have been reported for 

certain ingredients. Long-term repeated ingestion of small amounts of 

product may cause a decrease in red blood cells or liver and kidney 

damage. Ethylene glycol has been shown to produce teratogenic and 

developmental toxic effects in laboratory animals. Phenol-formaldehyde 

polymer has tested positive as a mutagen. 

INJECTION: Injection of this product is unlikely. 

PART II What should I do if a hazardous situation occurs? 

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM 

HEALTH 

FLAMMABILITY 

REACTIVITY 

PROTECTIVE EQUIPMENT 

EYES RESPIRATORY HANDS BODY 

SEE SECTION 8 

For routine applications. 

(BLUE) 

4. FIRST-AID MEASURES 

Contaminated individuals must seek medical attention if any adverse effect occurs. Rescuers should be taken for medical 

attention, if necessary. Take a copy of label and MSDS to physician or health professional with the contaminated individual. 

SKIN EXPOSURE: Wash with soap and water. Remove contaminated clothing and wash before reuse. Seek medical 

attention if adverse reaction occurs. 

EYE EXPOSURE: If fumes or particulates generated from the product contaminate the eyes, open victim's eyes while under 

gently running water. Use sufficient force to open eyelids. Have the contaminated individual "roll" eyes. The recommended 

minimum flushing time is 15 minutes. Seek medical attention if any adverse effect occurs. 

INHALATION: If fumes or particulates generated from the product are inhaled, remove victim to fresh air. If adverse effect 

occurs after removal to fresh air, seek medical attention. 

INGESTION: Do not induce vomiting. If discomfort or irritation persists, consult a physician. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing dermatitis, and other skin disorders can be 

aggravated by exposure to this product. 

RECOMMENDATIONS TO PHYSICIANS: Treat symptoms. 

(RED) 

(YELLOW) 

See Section 16 for Definition of Ratings 


PAGE 2 OF 7 

2 

0 

0 

B

5. FIRE-FIGHTING MEASURES 

FLASH POINT: > 212º F / 100º C Flash Point Method: Estimated 

AUTOIGNITION TEMPERATURE: Not applicable. 

FLAMMABLE LIMITS (in air by volume, %): 

Lower (LEL): Not applicable. 

Upper (UEL): Not applicable. 

FIRE EXTINGUISHING MATERIALS: Select fire extinguishing media 

appropriate for the surrounding area. 

Water Spray: YES Carbon Dioxide: YES 

Alcohol Foam: YES Dry Chemical: YES 

Other: Any "ABC" Class. 

UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is not 

combustible and does not contribute to the intensity of a fire. When 

involved in a fire, this material may decompose and produce irritating vapors, 

acrid smoke, and toxic gases (e.g., oxides of nitrogen may be evolved). 

Explosion Sensitivity to Mechanical Impact: Not sensitive. 

Explosion Sensitivity to Static Discharge: Not sensitive. 

SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must 

wear Self-Contained Breathing Apparatus and full protective equipment. Move fire-exposed containers if it can be done 

without risk to firefighters. If possible, firefighters should control runoff water to prevent environmental contamination. Rinse 

contaminated equipment with soapy water before returning such equipment to service. No special procedures specific to this 

product. 


RELEASE RESPONSE: Prevent spills from entering drinking water supplies, streams, or sewers. Collect material with an 

inert, noncombustible material and remove for disposal. 

PART III How can I prevent hazardous situations from occurring? 

7. HANDLING and STORAGE 

WORK AND HYGIENE PRACTICES: Avoid contact with eyes, skin and clothing. Do not take internally. Practice good 

personal hygiene to avoid ingestion. Wash clothing before reuse. Use only with adequate ventilation. 

STORAGE AND HANDLING PRACTICES: Store this product in a cool, dry location, away from sources of intense heat. 

Store away from incompatible materials (see Section 10, Stability and Reactivity). 

8. EXPOSURE CONTROLS - PERSONAL PROTECTION 

VENTILATION AND ENGINEERING CONTROLS: No special ventilation and engineering controls are required for use of this 

product. 

RESPIRATORY PROTECTION: None normally required for routine use of this product. Airborne contaminant concentrations 

must be maintained below guidelines listed in Section 2 (Composition and Information on Ingredients). If respiratory 

protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. 

State regulations, or the Canadian CSA Standard Z94.4-93. Oxygen levels below 19.5% are considered IDLH by OSHA. In 

such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary 

self-contained air supply is required under OSHA’s Respiratory Protection Standard (1910.134-1998). 

EYE PROTECTION: Wear goggles to prevent exposure to high vapor or mist concentrations. Wear goggles or safety 

glasses with side shields and a full-face shield to prevent contact due to splashing. 

HAND PROTECTION: Wear Impervious(PVC, latex or nitrile) gloves for routine industrial use. 

BODY PROTECTION: Work clothing with long sleeves, long pants and work boots must be worn. Clothing must be 

laundered before reuse. Disposable tyvek suits may be used during spray applications. 


HEALTH 

NFPA RATING 

FLAMMABILITY 

1 

OTHER 

REACTIVITY 


PAGE 3 OF 7 

0 

0 

See Section 16 for 

Definition of Ratings

9. PHYSICAL and CHEMICAL PROPERTIES 

PHYSICAL STATE: Liquid APPERANCE/ODOR: Red / Mild latex odor. 

RELATIVE VAPOR DENSITY (air = 1): >1 EVAPORATION RATE (n-BuAc = 1): 1 

SPECIFIC GRAVITY (water = 1): Not Available VISCOSITY: Unknown 

SOLUBILITY IN WATER: Appreciable. BOILING POINT: >100ºC (212ºF). 

VAPOR PRESSURE, mm Hg @ 20C: Unknown pH: Not applicable. 

BULK DENSITY (lbs/Cubic Foot) : Not Applicable % Volatiles (gr/L): (70ºF/21ºC): < 250 g/l 


10. STABILITY and REACTIVITY 

STABILITY: Stable. 

DECOMPOSITION PRODUCTS: Carbon dioxide, Carbon monoxide, Low molecular weight hydrocarbons, Aldehydes, 

magnesium carbonate and lime. 


CONDITIONS TO AVOID: Strong oxidizers, strong acids, ammonium salts, flourine, maganese trioxide, oxygen diflouride 

and chlorine trifluoride. 

PART IV Is there any other useful information about this material? 


Ingredient CAS Number LD20 and LC50 

Triphenyl phosphate 000115-86-6 Oral LD50 Rat : 3500 mg/kg; 

Oral LD50 Mouse : 1320 mg/kg 

Carcinogenicity: 

Ingredient IARC IARC IARC NTP NTP OSHA 

Group1 Group 2A Group 2B Known Suspect 

2-Propenoic acid, polymer… No No No No No No 

Aluminum oxide No No No No No No 

Calcium Carbonate No No No No No No 

Magnesium Aluminum Silicate No No Yes No No No 

Phenol, isopropylated, phosphate (3:1) No No No No No No 

Phenol-formaldehyde polymer No No No No No No 

Polyvinyl Acetate Emulsion No No No No No No 

Quartz Yes No No Yes Yes Yes 

Triphenyl Phosphate No No No No No No 

Contains formaldehyde below 0.1% threshold. Product is capable of releasing formaldehyde under certain conditions. 

Exposures during typical applications are expected to be insignificant. Exposure to formaldehyde vapor is a potential 

concern if product is applied under confined space conditions. NTP: Suspect Carcinogen. IARC: Group 2A. OSHA: 

Potential. 

Mutagenicity: Phenol-formaldehyde polymer in this product has tested positive as a mutagen. 

Teratogenicity: Ethylene glycol contained in this product has been shown to produce teratogenic 

effects in laboratory animals. 

Reproductive Toxicity: No information available. 


ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. 

Environmental Fate: No data available for product. 

Ecotoxicity: No data available for product. 


PAGE 4 OF 7


PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and 

local regulations or with regulations of Canada and its Provinces. According to EPA (40 CFR § 261), waste of this product is 

not defined as hazardous. 

14. TRANSPORTATION INFORMATION 

PROPER SHIPPING NAME: Not applicable. 

HAZARD CLASS NUMBER and DESCRIPTION: Nonhazardous. 

UN IDENTIFICATION NUMBER: Not applicable. 

PACKING GROUP: Not applicable. 

DOT LABEL(S) REQUIRED: Not applicable. 

NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): Not applicable. 

TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is not considered as 

dangerous goods by Transport Canada. 

IATA DESIGNATION: This material is not considered as dangerous goods by the International Air Transport Association. 

UPS SHIPPING: This material is not considered as Hazardous Materials by the United Parcel Service. 

Regulatory Chemical Lists: 



CERCLA (Comprehensive Response Compensation and Liability Act): 

(None present unless listed below) 

SARA Title III (Superfund Amendments and Reauthorization Act) 

SARA Section 312/Tier I & II Hazard Categories: 

Health Immediate (acute) Yes 

Health Delayed (chronic) Yes 

Flammable No 

Reative No 

Pressure No 

302 Reportable Ingredients (Identification Threshold 1%): None 

313 Reportable Ingredients (Chemicals present below reporting threshold are exempt): 

Chemical Name CAS WT % 

Acetaldehyde 000075-07-0 .0014 

Acrylamide 00079-06-01 .0008 

Acrylonitrile 000107-13-1 .0002 

Aluminum Oxide 001344-28-1 6.7 

Ammonia 07664-41-7 .12 

Chlorothalonil 001897-45-6 .0404 

Ethyl Acrylate 000140-88-5 .0022 

Ethylene Glycol 000107-21-1 .27 

Formaldehyde 000050-00-0 .0321 

Glycol Ethers RR-00067-9 .011 

Methyl Alcohol 000067-56-1 .0018 

Vinyl Acetate 000108-05-4 .0742 


PAGE 5 OF 7

National Volatile Organic Compound Emission Standards For Architectural Coatings: 

Volatile Organic Content: (gr/L) < 250 g/l 

WHMIS Classification(s): D2 B 

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR). This 

MSDS contains all the information required by the CPR. 

State Requlatory Information: 

California Proposition 65: Warning! This product contains substances known to the state of 

California to cause cancer, birth defects or other reproductive harm. 

Massachusetts Hazardous Substance List (Identification threshold 0.001% (1ppm)): 

Chemical Name CAS # Wt % 

Acetaldehyde 000075-07-0 .0014 

Acrylamide 000079-06-1 .0008 

Acrylonitrile 00107-13-1 .0002 

Ammonia 007664-41-7 .12 

Chlorothalonil 001897-45-6 .0404 

Ethyl Acrylate 000140-88-5 .0022 

Formaldehyde 000050-00-0 .0321 

Quartz 014808-60-7 .2675 

Vinyl Acetate 000108-05-4 .0742 

New Jersey Hazardous Substance List (Identification threshold (0.1%)): 


Aluminum Oxide 001344-28-1 6.7 

Ammonia 007664-41-7 .12 

Ethylene Glycol 000107-21-1 .27 

Pennsylvania Hazardous Substance List (Identification threshold (0.1%): 


Formaldehyde 000050-00-0 .032 

Chemical Inventory Status: 

All Chemicals in this product are listed or exempt from listing in the following countries: 

US CANADA EUROPE AUSTRALIA JAPAN KOREA PHILIPPINES 

TSCA DSL NDSL EINECS/ELINCS AICS ENCS ECL PICCS 

Yes Yes No Not Determined Not Determined Not Determined Not Determined Not Determined 



PREPARED BY: Nelson Firestop Products 

DATE OF PRINTING: January, 2002 

The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy 

of these data or the results to be obtained from the use thereof. Nelson EGS assumes no responsibility for injury to the vendee or third persons 

proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Nelson EGS 

assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety 

procedures are followed. Furthermore, vendee assumes the risk in his use of the material. 


PAGE 6 OF 7


DEFINITIONS OF TERMS 

A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following: 

CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent. 

EXPOSURE LIMITS IN AIR: 

ACGIH - American Conference of Governmental Industrial Hygienists, a 

professional association which establishes exposure limits. TLV - 

Threshold Limit Value - an airborne concentration of a substance which 

represents conditions under which it is generally believed that nearly all 

workers may be repeatedly exposed without adverse effect. The 

duration must be considered, including the 8-hour Time Weighted 

Average (TWA), the 15-minute Short Term Exposure Limit, and the 

instantaneous Ceiling Level (C). Skin absorption effects must also be 

considered. 

OSHA - U.S. Occupational Safety and Health Administration. 

PEL - Permissible Exposure Limit - This exposure value means exactly 

the same as a TLV, except that it is enforceable by OSHA. The OSHA 

Permissible Exposure Limits are based in the 1989 PELs and the June, 

1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 

40191). Both the current PELs and the vacated PELs are indicated. The 

phrase, “Vacated 1989 PEL,” is placed next to the PEL which was 

vacated by Court Order. IDLH - Immediately Dangerous to Life and 

Health - This level represents a concentration from which one can 

escape within 30-minutes without suffering escape-preventing or 

permanent injury. The DFG - MAK is the Republic of Germany’s 

Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National 

Institute of Occupational Safety and Health, which is the research arm 

of the U.S. Occupational Safety and Health Administration (OSHA). 

NIOSH issues exposure guidelines called Recommended Exposure 

Levels (RELs). When no exposure guidelines are established, an entry 

of NE is made for reference. 

HAZARD RATINGS: 

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM : Health Hazard: 

0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic 

exposure hazard); 2 (moderate acute or significant chronic exposure 

hazard); 3 (severe acute exposure hazard; onetime overexposure can 

result in permanent injury and may be fatal); 4 (extreme acute exposure 

hazard; onetime overexposure can be fatal). Flammability Hazard: 0 

(minimal hazard); 1 (materials that require substantial pre-heating before 

burning); 2 (combustible liquid or solids; liquids with a flash point of 38- 

93C [100-200F]); 3 (Class IB and IC flammable liquids with flash points 

below 38C [100F]); 4 (Class IA flammable liquids with flash points 

below 23C [73F] and boiling points below 38C [100F]. Reactivity 

Hazard: 0 (normally stable); 1 (material that can become unstable at 

elevated temperatures or which can react slightly with water); 2 

(materials that are unstable but do not detonate or which can react 

violently with water); 3 (materials that can detonate when initiated or 

which can react explosively with water); 4 (materials that can detonate 

at normal temperatures or pressures). 

NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 

(material that on exposure under fire conditions would offer no hazard 

beyond that of ordinary combustible materials); 1 (materials that on 

exposure under fire conditions could cause irritation or minor residual 

injury); 2 (materials that on intense or continued exposure under fire 

conditions could cause temporary incapacitation or possible residual 

injury); 3 (materials that can on short exposure could cause serious 

temporary or residual injury); 4 (materials that under very short 

exposure causes death or major residual injury). Flammability Hazard 

and Reactivity Hazard: Refer to definitions for “Hazardous Materials 

Identification System”. 

FLAMMABILITY LIMITS IN AIR: 

Much of the information related to fire and explosion is derived from the 

National Fire Protection Association (NFPA). Flash Point - Minimum 

temperature at which a liquid gives off sufficient vapors to form an 

ignitable mixture with air. Autoignition Temperature: The minimum 

temperature required to initiate combustion in air with no other source of 

ignition. LEL - the lowest percent of vapor in air, by volume, that will 

explode or ignite in the presence of an ignition source. UEL - the highest 

percent of vapor in air, by volume, that will explode or ignite in the 

presence of an ignition source. 

TOXICOLOGICAL INFORMATION: 

Human and Animal Toxicology: Possible health hazards as derived 

from human data, animal studies, or from the results of studies with 

similar compounds are presented. Definitions of some terms used in this 

section are: LD 50 - Lethal Dose (solids & liquids) which kills 50% of the 

exposed animals; LC 50 - Lethal Concentration (gases) which kills 50% 

of the exposed animals; ppm concentration expressed in parts of 

material per million parts of air or water; mg/m 3 concentration 

expressed in weight of substance per volume of air; mg/kg quantity of 

material, by weight, administered to a test subject, based on their body 

weight in kg. Other measures of toxicity include TDLo, the lowest dose 

to cause a symptom and TCLo the lowest concentration to cause a 

symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the 

lowest dose (or concentration) to cause lethal or toxic effects. 

Cancer Information: The sources are: IARC - the International 

Agency for Research on Cancer; NTP - the National Toxicology 

Program, RTECS - the Registry of Toxic Effects of Chemical 

Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals on a 

scale of decreasing potential to cause human cancer with rankings 

from 1 to 4. Sub rankings (2A, 2B, etc.) are also used. Other 

Information: BEI - ACGIH Biological Exposure Indices, represent the 

levels of determinants which are most likely to be observed in 

specimens collected from a healthy worker who has been exposed to 

chemicals to the same extent as a worker with inhalation exposure to 

the TLV. Ecological Information: EC is the effect concentration in 

water. BCF = Bioconcentration Factor, which is used to determine if a 

substance will concentrate in life forms which consume contaminated 

plant or animal matter. Coefficient of Oil/Water Distribution is 

represented by log K ow or log K oc and is used to assess a substance’s 

behavior in the environment. 

REGULATORY INFORMATION: 

This section explains the impact of various laws and regulations on the 

material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is 

the U.S. Department of Transportation. SARA is the Superfund 

Amendments and Reauthorization Act. TSCA is the U.S. Toxic 

Substance Control Act. CERCLA (or Superfund) refers to the 

Comprehensive Environmental Response, Compensation, and Liability 

Act. Labeling is per the American National Standards Institute (ANSI 

Z129.1). CANADA: CEPA is the Canadian Environmental Protection 

Act. WHMIS is the Canadian Workplace Hazardous Materials 

Information System. TC is Transport Canada. DSL/NDSL are the 

Canadian Domestic/Non-Domestic Substances Lists. 


PAGE 7 OF 7

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644013-00 

644013-00 MOBILITH SHC RR 221 

MATERIAL SAFETY DATA BULLETIN 

--------------------------------------------------------------------------- 

-------------------------------------------------------------------------- 


-------------------------------------------------------------------------- 

PRODUCT NAME: MOBILITH SHC RR 221 

SUPPLIER: EXXONMOBIL OIL CORPORATION 

3225 GALLOWS RD. 

FAIRFAX, VA 22037 

24 - Hour Emergency (call collect): 609-737-4411 

Product and MSDS Information: 800-662-4525 856-224-4644 

CHEMTREC: 800-424-9300 202-483-7616 

-------------------------------------------------------------------------- 


-------------------------------------------------------------------------- 

CHEMICAL NAMES AND SYNONYMS: SYN. HYDROCARBONS AND ADDITIVES 

INGREDIENTS CONSIDERED HAZARDOUS TO HEALTH: 

This product is not formulated to contain ingredients which have 

exposure limits established by U.S. agencies. It is not hazardous to 

health as defined by the European Union Dangerous 

Substances/Preparations Directives. See Section 15 for a regulatory 

analysis of the ingredients. 

See Section 15 for European Label Information. 

See Section 8 for exposure limits (if applicable). 

-------------------------------------------------------------------------- 


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US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance 

with OSHA 29 CFR 1910.1200 and determined not to be hazardous. 

EFFECTS OF OVEREXPOSURE: No significant effects expected. 

EMERGENCY RESPONSE DATA: White Grease. DOT ERG No. : NA 

http://emmsds.ihspsl.com/netacgi/nph-brs.exe?d...TXT&p=1&u=/msds/search.html&r=6&f=G&Sect3=MRUS (1 of 7) [11/24/2001 5:37:33 AM]

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EYE CONTACT: Flush thoroughly with water. If irritation occurs, call 

a physician. 

SKIN CONTACT: Wash contact areas with soap and water. High pressure 

accidental injection through the skin requires immediate medical 

attention for possible incision, irrigation and/or debridement. 

INHALATION: Not expected to be a problem. 

INGESTION: Not expected to be a problem when ingested. If 

uncomfortable seek medical assistance. 

-------------------------------------------------------------------------- 


-------------------------------------------------------------------------- 

EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. 

SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. 

Use water to keep fire exposed containers cool. Water spray may 

be used to flush spills away from exposure. Prevent runoff from 

fire control or dilution from entering streams, sewers, or 

drinking water supply. 

SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire 

fighters must use self-contained breathing apparatus. 

UNUSUAL FIRE AND EXPLOSION HAZARDS: None. Flash Point C(F): > 

204(400) (ASTM D-93). Flammable limits - LEL: NA, UEL: NA. 

NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0 

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. Metal oxides. 

Elemental oxides. 

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NOTIFICATION PROCEDURES: Report spills as required to appropriate 

authorities. U. S. Coast Guard regulations require immediate 

reporting of spills that could reach any waterway including 

intermittent dry creeks. Report spill to Coast Guard toll free 

number (800) 424-8802. In case of accident or road spill notify 

CHEMTREC (800) 424-9300. 

PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Shovel up and dispose 

of at an appropriate waste disposal facility in accordance with 

current applicable laws and regulations, and product 

characteristics at time of disposal. 

ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers 

or drains and contact with soil. 

PERSONAL PRECAUTIONS: See Section 8 

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HANDLING: High pressure injection under the skin may occur due to the 

rupture of pressurized lines. Always seek medical attention. 

STORAGE: Do not store in open or unlabelled containers. Store away 

from strong oxidizing agents or combustible material. 

-------------------------------------------------------------------------- 


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VENTILATION: No special requirements under ordinary conditions of use 

and with adequate ventilation. 

RESPIRATORY PROTECTION: No special requirements under ordinary 

conditions of use and with adequate ventilation. 

EYE PROTECTION: Generally eye contact is unlikely with this type 

material. If eye contact is likely, safety glasses with side 

shields or chemical type goggles should be worn. 

SKIN PROTECTION: If prolonged or repeated skin contact is likely, oil 

impervious gloves should be worn. Good personal hygiene 

practices should always be followed. 

EXPOSURE LIMITS: This product does not contain any components which 

have recognized exposure limits. 

-------------------------------------------------------------------------- 


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Typical physical properties are given below. Consult Product Data Sheet 

for specific details. 

APPEARANCE: Grease 

COLOR: White 

ODOR: Mild 

ODOR THRESHOLD-ppm: NE 

pH: NA 

BOILING POINT C(F): NE 

DROP POINT C(F): > 246(475) 

FLASH POINT C(F): > 204(400) (ASTM D-93) 

FLAMMABILITY: NE 

AUTO FLAMMABILITY: NE 

EXPLOSIVE PROPERTIES: NA 

OXIDIZING PROPERTIES: NA 

VAPOR PRESSURE-mmHg 20 C: < 0.1 

VAPOR DENSITY: NE 

EVAPORATION RATE: NE 

RELATIVE DENSITY, 15/4 C: 0.909 

SOLUBILITY IN WATER: Negligible 

PARTITION COEFFICIENT: > 3.5 

VISCOSITY AT 40 C, cSt: > 198.0 

VISCOSITY AT 100 C, cSt: NE 

POUR POINT C(F): NA 

FREEZING POINT C(F): NE 


VOLATILE ORGANIC COMPOUND: NE 

NOTE: MOST PHYSICAL PROPERTIES FOR OIL COMPONENT. 

NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES 

FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE 

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STABILITY (THERMAL, LIGHT, ETC.): Stable. 

CONDITIONS TO AVOID: Extreme heat. 

INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. 

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. Metal oxides. 

Elemental oxides. 


-------------------------------------------------------------------------- 

11. TOXICOLOGICAL DATA 

-------------------------------------------------------------------------- 

---ACUTE TOXICOLOGY--- 

ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000 

mg/kg). ---Based on testing of similar products and/or the 

components. 

DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 

2000 mg/kg). ---Based on testing of similar products and/or the 

components. 

INHALATION TOXICITY (RATS): Not applicable ---Harmful concentrations 

of mists and/or vapors are unlikely to be encountered through any 

customary or reasonably foreseeable handling, use, or misuse of 

this product. 

EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score: 

greater than 6 but 15 or less). ---Based on testing of similar 

products and/or the components. 

SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary 

Irritation Index: greater than 0.5 but less than 3). ---Based 

on testing of similar products and/or the components. 

OTHER ACUTE TOXICITY DATA: The acute toxicological results summarized 

above are based on testing of representative [PREV HIT] [NEXT HIT]Mobil 

products. 

---SUBCHRONIC TOXICOLOGY (SUMMARY)--- 

Representative [PREV HIT] [NEXT HIT]Mobil formulations have been tested at the 

[PREV HIT] [NEXT HIT]MobilEnvironmental and Health Sciences Laboratory by 

dermal 

applications to rats 5 days/week for 90 days at doses 

significantly higher than those expected during normal industrial 

exposure. Extensive evaluations, including microscopic 

examination of internal organs and clinical chemistry of body 

fluids, showed no adverse effects. 


---REPRODUCTIVE TOXICOLOGY (SUMMARY)--- 

Dermal exposure of pregnant rats to representative formulations did 

not cause adverse effects in either the mothers or their 

offspring. 

---SENSITIZATION (SUMMARY)--- 

Representative [PREV HIT] [NEXT HIT]Mobil formulations have not caused skin 

sensitization 

in guinea pigs. 

---OTHER TOXICOLOGY DATA--- 

This product is formulated with a synthetic hydrocarbon as the base 

stock. The [PREV HIT] [NEXT HIT]Mobil Environmental and Health Sciences 

Laboratory 

has tested representative synthetic base stocks to assess their 

potential adverse effects on human health. Assessment of human 

health effects was based on acute oral, dermal, and inhalation 

toxicity; eye and skin irritation; subchronic dermal toxicity and 

reproductive studies; guinea pig sensitization; and mutagenicity 

and chromosomal damage assays. None of these base stocks appears 

to pose a health hazard to humans under conditions of expected 

use. 

-------------------------------------------------------------------------- 


-------------------------------------------------------------------------- 

ENVIRONMENTAL FATE AND EFFECTS: Not established. 

-------------------------------------------------------------------------- 


-------------------------------------------------------------------------- 

WASTE DISPOSAL: Product is suitable for burning in an enclosed, 

controlled burner for fuel value or disposal by supervised 

incineration. Such burning may be limited pursuant to the 

Resource Conservation and Recovery Act. In addition, the product 

is suitable for processing by an approved recycling facility or 

can be disposed of at an appropriate government waste disposal 

facility. Use of these methods is subject to user compliance 

with applicable laws and regulations and consideration of product 

characteristics at time of disposal. 

RCRA INFORMATION: The unused product, in our opinion, is not 

specifically listed by the EPA as a hazardous waste (40 CFR, 

Part 261D), nor is it formulated to contain materials which 

are listed hazardous wastes. It does not exhibit the hazardous 

characteristics of ignitability, corrosivity, or reactivity and 

is not formulated with contaminants as determined by the Toxicity 

Characteristic Leaching Procedure (TCLP). However, used product 

may be regulated. 

-------------------------------------------------------------------------- 



-------------------------------------------------------------------------- 

USA DOT: NOT REGULATED BY USA DOT. 

RID/ADR: NOT REGULATED BY RID/ADR. 

IMO: NOT REGULATED BY IMO. 

IATA: NOT REGULATED BY IATA. 

-------------------------------------------------------------------------- 


-------------------------------------------------------------------------- 

Governmental Inventory Status: All components comply with TSCA, and 

EINECS/ELINCS. 

EU Labeling: EU labeling not required. 

U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: 

This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". 

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. 

This product contains no chemicals subject to the supplier notification 

requirements of SARA (313) toxic release program. 

The following product ingredients are cited on the lists below: 

CHEMICAL NAME CAS NUMBER LIST CITATIONS 

------------- ---------- -------------- 

LITHIUM HYDROXIDE (0.13%) 1310-65-2 22 

LITHIUM-SOAP THICKENER (8.95%) 7620-77-1 22 

FATTY ACIDS, C16-22, LITHIUM SALTS 68783-36-8 22 

(1.10%) 

--- REGULATORY LISTS SEARCHED --- 

1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK 

2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293 

3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK 

4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK 

5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK 

26=RI RTK 

Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive 

-------------------------------------------------------------------------- 


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USE: LITHIUM COMPLEX GREASE 

NOTE: PRODUCTS OF EXXON [PREV HIT] [NEXT HIT]MOBIL CORPORATION AND ITS 

AFFILIATED COMPANIES 

ARE NOT FORMULATED TO CONTAIN PCBS. 

------------------------------------------------------------------------- 

Please call the Customer Response Center on 800-662-4525 for formulation 

disclosure. 

************************************************************************* 

For Internal Use Only: MHC: 1* 1* NA 1* 1*, MPPEC: A, TRN: 644013-00, 

CMCS97: 970097, REQ: MRCTEC - LUBES, SAFE USE: L 

EHS Approval Date: 30NOV2000 

************************************************************************* 


************************************************************************* 

Legally required information is given in accordance with applicable 

Information given herein is offered in good faith as accurate, but 

without guarantee. Conditions of use and suitability of the product for 

particular uses are beyond our control; all risks of use of the product 

are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL 

WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF 

MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO 

THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a 

recommendation for uses which infringe valid patents or as extending 

any license under valid patents. Appropiate warnings and safe handling 

procedures should be providedto handlers and users. Use or retransmission 

of the information contained herein in any other format 

than the format as presented is strictly prohibited. ExxonMobil neither 

represents nor warrants that the format, content or product formulas 

contained in this document comply with the laws of any other country 

except the United States of America. 

************************************************************************* 

Copyright 1996 ExxonMobil Corporation, All rights reserved 

[HOME] [SEARCH] [PREV LIST] [CURR LIST] [NEXT LIST] [FIRST DOC] 

[PREV DOC] [CURR DOC] [NEXT DOC] [LAST DOC] [TOP] [PREV HIT] [HELP] 



SECTION I - Material Identity 

Item Name............................... TERESSTIC 68 / HYDRAULIC FLUID 

Part Number/Trade Name.................. TERESSTIC 68 / HYDRAULIC FLUID 

National Stock Number................... 9150P46711-55 

CAGE Code............................... 1ZAY6 

Part Number Indicator................... A 

MSDS Number............................. 194646 

HAZ Code................................ B 

SECTION II - Manufacturer's Information 

Manufacturer Name....................... EXXON MOBILE CORPORATION 

Street.................................. 3225 GALLOWS RD 

City.................................... FAIRFAX 

State................................... VA 

Country................................. US 

Zip Code................................ 22037 

Emergency Phone......................... 609-737-4411 

Information Phone....................... 800-662-4525 

MSDS Preparer's Information 

Date MSDS Prepared/Revised.............. 12MAY04 

Active Indicator........................ Y 

Alternate Vendors 

SECTION III - Physical/Chemical Characteristics 

Appearance/Odor......................... STRAW COLORED LIQUID/MILD ODOR 

Boiling Point........................... NE 

Melting Point........................... NA 

Vapor Pressure.......................... 0.1 

Vapor Density........................... >2.0 

Specific Gravity........................ 1 

Evaporation Rate........................ NE 

Solubility in Water..................... NEG

Chemical pH............................. NA 

Corrosion Rate.......................... NA 

Container Type.......................... R 

Container Pressure Code................. 1 

Temperature Code........................ 4 

Product State Code...................... L 

SECTION IV - Fire and Explosion Hazard Data 

Flash Point............................. 396 

Flash Point Method...................... UNK 

Lower Explosion Limit................... NA 

Upper Explosion Limit................... NA 

Extinguishing Media..................... CARBON DIOXIDE, FOAM, DRY 

CHEMICAL, WATER FOG 

Special Fire Fighting Procedures........ WATER OR FOAM MAY CAUSE 

FROTHING, USE WATER TO KEEP 

FIRE EXPOSED CONTAINERS COOL. 

WATER SPRAY MAY BE USED TO 

FLUSH SPILLS AWAY FROM 

EXPOSURE. PREVENT RUNOFF FROM 

FIRE CONTROL OR DILUTION FROM 

ENTERING STREAMS, SEWERS, OR 

DRING WATER SUPPLY. WEAR SCBA 

Unusual Fire/Explosion Hazards.......... NONE LISTED 

SECTION V - Reactivity Data 

Stability............................... YES 

Stability Conditions to Avoid........... EXTREME HEAT AND HIGH ENERGY 

SOURCES OF IGNITION. 

Materials to Avoid...................... STRONG OXIDIZERS 

Hazardous Decomposition Products........ NONE LISTED 

Hazardous Polymerization................ NO 

Polymerization Conditions to Avoid...... WILL NOT OCCUR 

SECTION VI - Health Hazard Data 

Route of Entry: Skin.................... U 

Route of Entry: Ingestion............... U 

Route of Entry: Inhalation.............. U 

Health Hazards - Acute and Chronic...... [CHRONIC] REPEATED AND/OR 

PORLONGED EXPOSURE MAY CAUSE 

IRRITATION TO THE SKIN, EYES, 

OR RESPIRATORY TRACT. 

Explanation of Carcinogenity............ NO DATA 

Symptoms of Overexposure................ UNDER NORMAL CONDITIONS OF 

INTENDED USE, THIS PRODUCT DOES

NOT POSE A RISH TO HEALTH. 

Medical Cond. Aggrevated by Exposure.... NONE LISTED 

Emergency/First Aid Procedures.......... [EYE] FLUSH W/WATER IF 

IRRITAITON OCCURS, GET MED. 

ATTN. [SKIN] WASH CONTACT AREAS 

W/SOAP AND WATER, REMOVE 

CONTAMINATED CLOTHING. [INHALE] 

NOT EXPECTED TO BE A PROBLEM, 

HOWEVER IS RESPIRATORY 

IRRITATION, DIZZINESS, NAUSEA, 

OR UNCONSCIOUSNESS OCCUR SEEK 

MED. ATTN. [INGEST] SEEK MED. 

ATTN. IF DISCOMFORT OCCURS. DO 

NOT INDUCE VOMITING. 

SECTION VII - Precautions for Safe Handling and Use 

Steps if Material Released/Spilled...... SHUT OFF AT SOURCE, TAKING 

NORMAL SAFETY PRECAUTIONS. 

RECOVER BY PUMPING OR CONTAIN 

SPILLED MATERIAL 

W/SAND/ABSORBENT AND REMOVE 

MECHANICALLY INTO CONTAINERS. 

IF NECESSARY, DISPOSE OF 

ABSORBED RESIDUES. 

Neutralizing Agent...................... NONE LISTED 

Waste Disposal Method................... IN ACCORDANCE W/STATE, LOCAL, 

AND FEDERAL REGULATIONS. 

Handling and Storage Precautions........ NO SPECIAL PRECAUTIONS ARE 

NECESSARY BEYOND NORMAL GOOD 

HYGIENE PRACTICES. KEEP 

CONTAINERS TIGHTLY CLOSED WHEN 

NOT IN USE. DO NOT STORE IN 

OPEN OR UNLABELED CONTAINERS. 

STORE AWAY FROM STRONG 

OXIDIZING AGENTS AND 

COMUBSTIBLE MATERIALS. DO NOT 

STORE NEAR HEAT, SPARKS, FLAME 

OR STRONG OXIDANTS. 

Other Precautions....................... READ AND UNDERSTAND ALL 

CAUTIONS, LABELS AND MSDS 

BEFORE USING ANY CHEMICAL 

PRODUCT. 

SECTION VIII - Control Measures 

Respiratory Protection.................. IF MISTS ARE GENERATED, WEAR 

APPROVED RESPIRATOR 

Ventilation............................. LOCAL EXHAUST 

Protective Gloves....................... OIL RESISTANT 

Eye Protection.......................... SAFETY GLASSES W/SIDE SHIELDS 

OR CHEMICAL GOGGLES

Other Protective Equipment.............. PROTECTIVE CLOTHING 

Work Hygenic Practices.................. WASH HANDS THOROUGHLY AFTER 

HANDLING 

Supplemental Health/Safety Data......... NONE LISTED 

SECTION IX - Label Data 

Protect Eye............................. YES 

Protect Skin............................ YES 

Protect Respiratory..................... NO 

Chronic Indicator....................... YES 

Contact Code............................ UNKNOWN 

Fire Code............................... UNKNOWN 

Health Code............................. UNKNOWN 

React Code.............................. UNKNOWN 

Specific Hazard and Precaution.......... NONE LISTED 

SECTION X - Transportation Data 

SECTION XI - Site Specific/Reporting Information 

Volatile Organic Compounds (P/G)........ 0 

Volatile Organic Compounds (G/L)........ 0 

SECTION XII - Ingredients/Identity Information 

Ingredient #............................ 01 

Ingredient Name......................... NO HAZARDOUS INGREDIENTS LISTED 

ON MSDS 

CAS Number.............................. 1005 

Percent................................. 0 

NOTICE: For additional information, contact BIOENVIRONMENTAL

MATERIAL SAFETY 

DATA SHEET 

IDENTITY: 

KNOCK OUT WEED KILLER 

G88 

HIMIS 

RATING: 

RATING 

LEGEND: 

Fuel Oil 

CAS NO. 

68476-34-65 

Panasol AN3N 91-20-3 

Isooctyl 2-ethylhexyl ester 2, 4-D 

1928-43-9 

Bromacil 

314-40-9 

Diethylene Glycol Monoethyl Ether 

111-90-0 

Page 1 of 2 

G88 

HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 

Boiling Point 430 0 F Specific Gravity (H 20 = 1) 0.88 Appearance Dark Amber Liquid 

Vapor Pressure (mm Hg) 

Vapor Density (AIR = 1) 

N/E 

N/E 

Evaporation Rate 

(Butyl Acetate =1) 

N/E 

Odor 

Solubility in Water 

Hydrocarbon 

Insoluble 

Stability: Stable X 

Unstable 

Hazardous Polymerization: May Occur 

Incompatibility (Materials to Avoid): Acids and strong oxidizers 

Hazardous Decomposition or Byproducts: CO, CO2 4=extreme,3=serious,2=moderate,1=slight,0=minimal 

NOTE: Blank spaces are not permitted. If any item is not applicable, or 

no information is available, the space must be marked to indicate that. 

Manufacturer's Name Distributed by: 

Emergency Telephone Number 

Handi-Clean Products, Inc. (336) 292-3083 After 5:00 p.m. (336) 454-3662 

Address: 301 Swing Rd. 

Telephone Number for Information Date Prepared 

Greensboro, NC 27409 (336) 292-3083 6/1/2004 

100ppm 

10mg/kg 

N/E 

N/E 

100ppm 

N/E 

N/E 

N/E 

81.00 

13.00 

1.09 

0.98 

5.00 

Special Fire Fighting Procedures: Wear a self contained breathing apparatus with a full face-piece operated in the 

positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment. 

Refer to the personal protective equipment section of this MSDS. 

Unusual Fire and Explosion Hazards: Combustible. Vapors could ignore if exposed to sparks or open flame. 

Conditions to Avoid: High Temperatures 

Section I 

Section II - Hazardous Ingredients/Identity Information 

5mg/m 3 

Section III - Physical/Chemical Characteristics 

Section IV - Fire and Explosion Hazard Data 

Section V - Reactivity Data 

OSHA PEL ACGIH TLV % (optional) 

5mg/m 3 

Flash Point (Method Used): 155 Flammable Limits 

0 F LEL - 

Extinguishing Media: Dry Chemical, CO2 or Foam is recommended 

Will Not Occur 

UEL - 

X

Section VI - Health Hazard Data 

Section VII - Precautions for Safe Handling and Use 

Page 2 of 2 

G88 

Route(s) of Entry: Inhalation? X Skin? X Eyes? X 

Ingestion? X 

Health Hazards (Acute/Potential Health Effects): EYES: May cause mild irritation. Symptoms include stinging, 

tearing and redness. SKIN: May cause mild skin irritation. Prolonged or repeated contact may dry the skin. Absorption 

from prolonged or massive skin contact may cause poisoning. INHALATION: Avoid breathing vapors or mists. May 

cause dizziness, nausea, headache or loss of consciousness. INGESTION: Harmful of fatal if swallowed. Aspiration 

hazard - this material can enter lungs during swallowing or vomiting and cause lung inflammation and damage. 

Health Hazards (Chronic/Long Term Effects): Reports have associated repeated and prolonged occupational 

overexposure to solvents with permanent brain and nervous system damage. 

Signs and Symptoms of Overexposure: Stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, 

airways), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, 

Emergency i and) First Aid Procedures: EYES/SKIN: Immediately flush eyes with plenty of water for at least 15 

minutes. Get medical attention immediately. Remove contaminated clothing and shoes. Wash clothing before reuse. 

INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. 

INGESTION: Seek medical attention immediately. Aspiration hazard: DO NOT induce vomiting or give anything by 

mouth because this material can enter the lungs and cause severe damage. Do not leave individual unattended. 

Steps to Be Taken in Case Material is Released or Spilled: Stop all leaks. Isolate hazard area. Keep unnecessary and 

unprotected personnel from entering. Absorb spill with inert material (e.g. dry sand, earth). Eliminate all ignition 

sources. Prevent runoff from entering drains, sewers, streams or other bodies of water. Absorb unrecoverable product. 

Transfer contaminated absorbent, soil and other materials to containers for disposal. 

Waste Disposal Method: Dispose in accordance with local, state, & federal regulations. See label for further 

Precautions i i to Be Taken in Handling and Storing: Follow all MSDS/label precautions even after container is emptied 

because they may contain product residues. Use with adequate ventilation. Do not get in eyes, on skin or on clothing. 

Store in a cool dry place. Keep container closed when not in use. 

Other Precautions: KEEP OUT OF REACH OF CHILDREN 

Section VIII - Control Measures 

Respiratory Protection (Specify Type): When Required use Organic Vapor Cartridge Ventilation: Good/General 

Protective Gloves: Nitrile or Neoprene Gloves 

Eye Protection: Safety Glasses or Goggles 

Other Protective Clothing or Equipment: Prolonged/repeated contact wear impervious clothing and boots. 

Work/Hygienic Practices: Wash hands with soap and water after using product

00 

— Section 1 — 

Product Identification 

— Section 2 — 


The Sherwin-Williams Company Emergency telephone numbers (216) 566-2917 United States 

Krylon Products Group 

101 Prospect Avenue N.W. Information telephone number (800) 251-2486 

Cleveland, OH 44115 July 20, 2000 ©2000, The Sherwin-Williams Co. 

Engine Paints - 1 ENG1/KRI 

ACGIH ACGIH OSHA OSHA 

Vapor Vapor Vapor 1611 1611 1612 1612 1705 1705 1908 1908 1909 1909 1923 1923 1927 1927 1928 

1928 

CAS CAS No. No. Hazardous Ingredients TLV TLV PEL PEL Units Units Pressure Pressure 

Pressure Universal Universal Engine Chevrolet Ford Ford Dark Ford Chrysler 

(percent by weight) 

(mm Hg) Gray Black Gold Blue Blue Blue Blue Blue 

74-98-6 Propane 2500 1000 P P M 760.0 20 18 18 20 20 20 14 20 

110-54-3 

§ 

Hexane 50 50 P P M 127.0 11 12 11 10 11 10 6 11 

107-83-5 Isohexane Isomers. 

500 500 

 

P P M 250.0 8 8 8 7 8 7 8 

64742-89-8 V. M. & P. Naphtha. 300 

300 

 

P P M 12.0 16 20 18 17 17 17 17 

100-41-4 

§ 

Ethylbenzene 

100 

 

100 

 

P P M 7.1 2 

1330-20-7 

§ 

Xylene 

100 

 

100 

 

P P M 5.9 9 

67-64-1 Acetone. 

500 

 

1000 P P M 180.0 21 25 26 23 21 23 40 21 

78-93-3 

§ 

Mrthyl Ethyl Ketone 

200 

 

200 

 

P P M 70.7 4 

108-10-1 

§ 

Methyl Isobutyl Ketone 

50 

 

50 

 

P P M 16.0 7 

108-65-6 1-Methoxy-2-Propanol Acetate Not Established 1.8 8 5 2 8 8 8 7 8 

7727-43-7 Barium Sulfate 10 10[5] 

Mg/M3 as Dust 

[Resp. Fraction] 

1 

13463-67-7 Titanium Dioxide. 10 10[5] 

Mg/M3 as Dust 

[Resp. Fraction] 

3 2 1 3 

1333-86-4 Carbon Black. 3.5 3.5 Mg/M3 0.5 

§ 

[% Barium] [0.6] 

Weight per Gallon (lbs.) 6.06 5.96 6.03 6.02 6.05 6.02 6.49 6.08 

VOC Less Federally Exempt Solvents - (percent by weight) 64.2 63.6 59.9 63.2 64.9 63.4 45.9 64.3 

Flash Point (°F) < 0 < 0 < 0 < 0 < 0 < 0

Engine Paints ENG/KRI 

Section 3 — Physical Data 

PRODUCT WEIGHT See TABLE EVAPORATION RATE Faster than Ether 

SPECIFIC GRAVITY 0.72-0.78 VAPOR DENSITY Heavier than Air 

BOILING RANGE

Grainger MSDS Lookup 

MSDS Table of Contents 

Click the desired link below to jump directly to that section in the MSDS. 


MAY BE USED TO COMPLY WITH OSHA'S HAZARD COMMUNICATION STANDARD, 29 CFR 

1910.1200. STANDARD MUST BE CONSULTED FOR SPECIFIC REQUIREMENTS. 

HMIS(R*): 

HEALTH 2 

FLAMMABILITY 3 

REACTIVITY 0 

PERSONAL PROTECTION B 

Common Name: 34720 MEDAPHENE DISINFECTANT SPRAY 

Manufacturer: ITW DYMON 

MSDS Revision Date: 8/18/2005 

Grainger Item Number(s): 3U037 

Manufacturer Model Number(s): 

SECTION I 

SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION 

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS 

SECTION IV - FIRE AND EXPLOSION HAZARD DATA 





IDENTITY (AS USED ON LABEL AND LIST): 

34720 MEDAPHENE DISINFECTANT SPRAY 

EPA REG. NO.: 211-32-11694 

NOTE: 

BLANK SPACES ARE NOT PERMITTED. IF ANY ITEM IS NOT APPLICABLE, OR NO 

INFORMATION IS AVAILABLE, THE SPACE MUST BE MARKED TO INDICATE THAT. 

SECTION I 

MANUFACTURER'S NAME: ITW DYMON 

ADDRESS (NUMBER, STREET, CITY, STATE, AND ZIP CODE): 

805 EAST OLD 56 HIGHWAY 

OLATHE, KANSAS 66061 

EMERGENCY TELEPHONE NUMBER: 1-800-535-5053 

TELEPHONE NUMBER FOR INFORMATION: 1-913-397-9889 

DATE PREPARED: AUGUST 18, 2005 

SIGNATURE OF PREPARER (OPTIONAL): REGULATORY DEPT. 

http://complyplus.grainger.com/grainger/msds.asp?sheetid=2820412 

Page 1 of 5 

6/20/2008


SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION 

HAZARDOUS COMPONENTS 

(SPECIFIC CHEMICAL IDENTITY, CAS NO. OSHA PEL ACGIH-TLV 

COMMON NAME(S)) 

ETHANOL 64-17-5 1000 PPM 1000 PPM 

ISOBUTANE 75-28-5 800 PPM 800 PPM 

PROPANE 74-98-6 1000 PPM 2500 PPM 

ORTHOPHENYLPHENOL* 90-43-7 NONE ESTAB. NONE ESTAB. 

HAZARDOUS COMPONENTS OTHER LIMITS 

(SPECIFIC CHEMICAL IDENTITY, RECOMMENDED % (OPT.) 

COMMON NAME(S)) 

ETHANOL 60-100% 

ISOBUTANE 10-30% 

PROPANE 1-5% 

ORTHOPHENYLPHENOL*


USA FLAME PROJECTION TEST: >18", NO FLASHBACK (FLAMMABLE) 

FLAMMABLE LIMITS: NO DATA 

LEL: NO DATA 

UEL: NO DATA 

EXTINGUISHING MEDIA: USE CARBON DIOXIDE, DRY CHEMICAL, FOAM. 

SPECIAL FIRE FIGHTING PROCEDURES - USE WATER SPRAY TO KEEP CONTAINERS COOL 

AND VAPORS DOWN. DO NOT ALLOW RUNOFF TO ENTER SEWERS OR PUBLIC 

WATERCOURSES. WEAR SELF-CONTAINED BREATHING APPARATUS IN CHEMICAL FIRES. 

UNUSUAL FIRE AND EXPLOSION HAZARDS - AEROSOL CONTAINER (PRESSURIZED) MAY 

BURST IF HEATED OVER 130 DEG. F. 


STABILITY: 

UNSTABLE ( ) 

STABLE (X) 

CONDITIONS TO AVOID - EXTREME HEAT, DIRECT SUNLIGHT 

INCOMPATIBILITY (MATERIALS TO AVOID) - STRONG ACIDS AND OXIDIZERS. 

HAZARDOUS DECOMPOSITION OR BYPRODUCTS - CARBON DIOXIDE AND CARBON MONOXIDE 

HAZARDOUS POLYMERIZATION: 

MAY OCCUR ( ) 

WILL NOT OCCUR (X) 

CONDITIONS TO AVOID - NONE KNOWN 


ROUTE(S) OF ENTRY: 

EYES? 

YES 

INHALATION? 

YES 

SKIN? 

YES 

INGESTION? 

NO 

HEALTH HAZARDS (ACUTE AND CHRONIC) - WILL CAUSE EYE IRRITATION UPON 

EXPOSURE AND SKIN IRRITATION WITH PROLONGED EXPOSURE. CAN BE HARMFUL IF 

SWALLOWED OR IF SPRAY MIST IS INHALED. 

CARCINOGENICITY: NONE KNOWN 

NTP? 

NO 

IARC MONOGRAPHS? 

NO 

OSHA REGULATED? 

NO 

SIGNS AND SYMPTOMS OF EXPOSURE - 

IF IN EYES: BURNING SENSATION, WATERING, OR REDNESS. 


Page 3 of 5 

6/20/2008


IF ON SKIN: 

REDNESS, IRRITATION, OR BURNING SENSATION WITH PROLONGED EXPOSURE. 

IF SPRAY MIST IS INHALED: 

COUGHING, STUPOR, DROWSINESS OR LOSS OF CONSCIOUSNESS WITH PROLONGED 

BREATHING OF VAPORS. 

IF SWALLOWED: POSSIBLE GASTROINTESTINAL IRRITATION OR DISTURBANCE. 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE - NONE KNOWN. 

EMERGENCY AND FIRST AID PROCEDURES: 

EYES - FLUSH WITH WATER FOR 15 MINUTES. 

SKIN - WASH LIBERALLY WITH SOAP AND WATER. 

IF ON CLOTHES - WASH BEFORE REUSE. 

INHALATION - REMOVE TO FRESH AIR. 

INGESTION - IF PATIENT IS CONSCIOUS AND ALERT, DILUTE BY DRINKING LARGE 

QUANTITIES OF WATER. DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. ALWAYS 

GET MEDICAL ATTENTION WHEN PRODUCT IS SWALLOWED OR WHEN SYMPTOMS ARE 

SIGNIFICANT OR PERSIST. 


STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - 

SMALL SPILLS (LESS THAN 1 GALLON) MAY BE CONTAINED AND LEFT TO EVAPORATE. 

NOTE: DILUTION WITH WATER WILL REDUCE FLASH POINT. 

LARGE SPILLS (MORE THAN 1 GALLON) SHOULD BE CONTAINED AND COLLECTED (BY 

ABSORPTION OR VACUUMING) THEN EVAPORATED OR DISPOSED OF PROPERLY. 

WASTE DISPOSAL METHOD - THIS PRODUCT IS CONSIDERED A RCRA HAZARDOUS WASTE 

FOR FLAMMABILITY (D001) AS IDENTIFIED IN FEDERAL REGULATIONS 40 CFR 261. 

DISPOSE OF PRODUCT BY USING IN ACCORDANCE WITH LABEL DIRECTIONS OR IN 

COMPLIANCE WITH LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS (CONTACT 

LOCAL OR STATE ENVIRONMENTAL AGENCY FOR SPECIFIC RULES). 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING - DO NOT CONTAMINATE WATER, 

FOOD OR FEED. DO NOT REUSE EMPTY CONTAINERS. KEEP CONTAINERS CLEAN AND 

CLOSED. KEEP OUT OF REACH OF CHILDREN. DO NOT STORE NEAR IGNITION SOURCES 

OR AT TEMPERATURES ABOVE 120 DEG. F. 


RESPIRATORY PROTECTION (SPECIFY TYPE) - GENERAL VENTILATION IS NORMALLY 

ADEQUATE. DON NOT CREATE OR INHALE MISTS OR VAPORS. US AND APPROVED VAPOR 

RESPIRATOR IN TIGHT OR CLOSE AREAS. 

VENTILATION: 

LOCAL EXHAUST - NOT USUALLY NECESSARY 

MECHANICAL (GENERAL) - NORMALLY SUFFICIENT 

SPECIAL - NONE 

OTHER - NONE 

PROTECTIVE GLOVES - YES (RUBBER) 

EYE PROTECTION - YES (GOGGLES OR APPROVED SAFETY GLASSES) 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT - NOT USUALLY NECESSARY. 

WORK/HYGIENIC PRACTICES - WASH HANDS AFTER USING. DON NOT GET INTO EYES, ON 

SKIN, OR CLOTHING. MAY BE HARMFUL IF SWALLOWED, PROTECT FOOD AND DRINK FROM 

CONTAMINATION BY PRODUCT. 


Page 4 of 5 

6/20/2008


WARNING! 

THE USE OF THIS PRODUCT IS BEYOND THE CONTROL OF THE MANUFACTURER; 

THEREFORE, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE AS TO THE EFFECTS OF 

SUCH OR THE RESULTS TO BE OBTAINED IF NOT USED IN ACCORDANCE WITH DIRECTIONS 

OR ESTABLISHED SAFE PRACTICE. THE USER MUST ASSUME ALL RESPONSIBILITY, 

INCLUDING INJURY OR DAMAGE, RESULTING FROM ITS MISUSE AS SUCH, OR IN 

COMBINATION WITH OTHER MATERIALS. THE MANUFACTURER WARRANTS ONLY THAT THIS 

PRODUCT MEETS THE MANUFACTURER'S SPECIFICATIONS FOR SUCH PRODUCT. THIS 

WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO 

DESCRIPTION, QUALITY, MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, 

PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS PRODUCT. THE MANUFACTURER SHALL 

BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT. THE SOLE AND 

EXCLUSIVE REMEDY AGAINST THE MANUFACTURER FOR BREACH OF WARRANTY SHALL BE 

REIMBURSEMENT OF THE PURCHASE PRICE OF THE PRODUCT IN THE EVENT THAT A 

DEFECTIVE CONDITION OF THE PRODUCT SHALL BE FOUND TO EXIST. NO OTHER REMEDY 

(INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY 

TO PERSON OR PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL 

BE AVAILABLE. 

34720 

AUGUST 18, 2005 


Page 5 of 5 

6/20/2008

153-8180 

14 00 


SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NUMBER 

153-8180 

PRODUCT NAME 

Mineral Spirits 

MANUFACTURER'S NAME 

THE SHERWIN-WILLIAMS COMPANY 

101 Prospect Avenue N.W. 

Cleveland, OH 44115 

Telephone Numbers and Websites 

Regulatory Information (216) 566-2902 

www.paintdocs.com 

Medical Emergency (216) 566-2917 

Transportation Emergency* (800) 424-9300 

* for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) 

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS 

% by Weight CAS Number Ingredient Units Vapor Pressure 

100 64742-88-7 Mineral Spirits 

ACGIH TLV 100 PPM 2 mm 

OSHA PEL 100 PPM 

SECTION 3 — HAZARDS IDENTIFICATION 

ROUTES OF EXPOSURE 

INHALATION of vapor or spray mist. 

EYE or SKIN contact with the product, vapor or spray mist. 

EFFECTS OF OVEREXPOSURE 

EYES: Irritation. 

SKIN: Prolonged or repeated exposure may cause irritation. 

INHALATION: Irritation of the upper respiratory system. 

DATE OF PREPARATION 

Mar 22, 2012 

HMIS Codes 

Health 2 

Flammability 2 

Reactivity 0 

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. 

Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: 

the liver 

the urinary system 

SIGNS AND SYMPTOMS OF OVEREXPOSURE 

Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. 

Redness and itching or burning sensation may indicate eye or excessive skin exposure. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE 

None generally recognized. 

CANCER INFORMATION 

For complete discussion of toxicology data refer to Section 11. 

SECTION 4 — FIRST AID MEASURES 

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. 

SKIN: Wash affected area thoroughly with soap and water. 

Remove contaminated clothing and launder before re-use. 

INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. 

INGESTION: Do not induce vomiting. Get medical attention immediately. 

SECTION 5 — FIRE FIGHTING MEASURES 

page 1 of 4

153-8180 

FLASH POINT 

LEL UEL FLAMMABILITY CLASSIFICATION 

105 °F PMCC 

1.0 

6.0 Combustible, Flash above 99 and below 200 °F 

EXTINGUISHING MEDIA 

Carbon Dioxide, Dry Chemical, Foam 

UNUSUAL FIRE AND EXPLOSION HAZARDS 

Closed containers may explode when exposed to extreme heat. 

Application to hot surfaces requires special precautions. 

During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately 

apparent. Obtain medical attention. 

SPECIAL FIRE FIGHTING PROCEDURES 

Full protective equipment including self-contained breathing apparatus should be used. 

Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure 

build-up and possible autoignition or explosion when exposed to extreme heat. 

SECTION 6 — ACCIDENTAL RELEASE MEASURES 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

Remove all sources of ignition. Ventilate the area. 

Remove with inert absorbent. 

SECTION 7 — HANDLING AND STORAGE 

STORAGE CATEGORY 

DOL Storage Class II 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE 

Contents are COMBUSTIBLE. Keep away from heat and open flame. 

Consult NFPA Code. Use approved Bonding and Grounding procedures. 

Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. 


SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION 

PRECAUTIONS TO BE TAKEN IN USE 

Use only with adequate ventilation. 

Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. 

Wash hands after using. 

VENTILATION 

Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. 

Refer to OSHA Standards 1910.94, 1910.107, 1910.108. 

RESPIRATORY PROTECTION 

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator 

approved by NIOSH/MSHA for protection against materials in Section 2. 

PROTECTIVE GLOVES 

Wear gloves which are recommended by glove supplier for protection against materials in Section 2. 

EYE PROTECTION 

Wear safety spectacles with unperforated sideshields. 

OTHER PRECAUTIONS 

Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. 

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES 

PRODUCT WEIGHT 6.42 lb/gal 769 g/l 

SPECIFIC GRAVITY 0.77 

BOILING POINT 300 - 395 °F 148 - 201 °C 

MELTING POINT Not Available 

VOLATILE VOLUME 100% 

EVAPORATION RATE Slower than ether 

VAPOR DENSITY Heavier than air 

SOLUBILITY IN WATER N.A. 

VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 

6.42 lb/gal 769 g/l Less Water and Federally Exempt Solvents 

6.42 lb/gal 769 g/l Emitted VOC 

SECTION 10 — STABILITY AND REACTIVITY 

STABILITY — Stable 

CONDITIONS TO AVOID 

None known. 

page 2 of 4

153-8180 

INCOMPATIBILITY 

None known. 

HAZARDOUS DECOMPOSITION PRODUCTS 

By fire: Carbon Dioxide, Carbon Monoxide 

HAZARDOUS POLYMERIZATION 

Will not occur 

SECTION 11 — TOXICOLOGICAL INFORMATION 

CHRONIC HEALTH HAZARDS 

No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. 

Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. 

TOXICOLOGY DATA 

CAS No. Ingredient Name 

64742-88-7 Mineral Spirits 

LC50 RAT 4HR Not Available 

LD50 RAT Not Available 

SECTION 12 — ECOLOGICAL INFORMATION 

ECOTOXICOLOGICAL INFORMATION 


SECTION 13 — DISPOSAL CONSIDERATIONS 

WASTE DISPOSAL METHOD 

Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. 

Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. 

Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local 

regulations regarding pollution. 

SECTION 14 — TRANSPORT INFORMATION 

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping 

description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of 

transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole 

responsibility of the person offering the product for transport. 

US Ground (DOT) 

May be Classed as a Combustible Liquid for U.S. Ground. 

UN1263, PAINT RELATED MATERIAL, 3, PG III, (ERG#128) 

Bulk Containers may be Shipped as: 

UN1263, PAINT RELATED MATERIAL, COMBUSTIBLE LIQUID, PG III, 

(ERG#128) 

Canada (TDG) 

May be Classed as a Combustible Liquid for Canadian Ground. 

UN1263, PAINT RELATED MATERIAL, CLASS 3, PG III, (ERG#128) 

IMO 

5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity. 

UN1263, PAINT RELATED MATERIAL, CLASS 3, PG III, (41 C c.c.), EmS 

F-E, S-E, ADR (D/E) 

IATA/ICAO 

UN1263, PAINT RELATED MATERIAL, 3, PG III 

SECTION 15 — REGULATORY INFORMATION 

SARA 313 SUPPLIER NOTIFICATION 

(40 CFR 372.65C) 

CAS No. CHEMICAL/COMPOUND % by WT % Element 

No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. 

TSCA CERTIFICATION 

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. 

page 3 of 4

153-8180 

SECTION 16 — OTHER INFORMATION 

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the 

MSDS contains all of the information required by the CPR. 

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other 

additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no 

warranties, express or implied, and assume no liability in connection with any use of this information. 

page 4 of 4


This MSDS complies with OSHA'S Hazard Communication Standard 29 CFR 1910.1200 and OSHA Form 174 

IDENTITY AND MANUFACTURER'S INFORMATION 

NFPA Rating: Health-2; Flammability-2; Reactivity-0; Special-0 HMIS Rating: Health-2; Flammability-2; Reactivity-0; Personal Protection-D 

Manufacturer's Name: AMREP, INC. 

Address: 990 Industrial Park Drive 

Marietta, GA 30062 

DOT Hazard Classification: ORM-D 

Identity (trade name as used on label): 

MISTY POWDER PUFF RESIDUAL INSECTICIDE 

Date Prepared: 03/26/96 Prepared By: LF MSDS Number: 427 Revision- 12 

Information Calls: (770)422-2071 

EMERGENCY RESPONSE NUMBER: 1(800)255-3924 

NOTICE: JUDGEMENT BASED ON INDIRECT TEST DATA 

SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION 

COMPONENTS-CHEMICAL NAMES AND COMMON NAMES 

CAS Number SARA OSHA PEL ACGIH Carcinogen 

(Hazardous Components 1% or greater; Carcinogens 0.1% or greater) 

III LIST (ppm) TLV (ppm) Ref. Source ** 

CYCLOHEXANE 110-82-7 Yes 300 300 d 

PIPERONYL BUTOXIDE 51-03-6 Yes N/E N/E d 

SILICA GEL 1343-98-2 No N/E N/E d 

ISOPROPANOL 67-63-0 No 500 400 d 

ISOBUTANE / PROPANE BLEND 75-28-5 No 800 800 d 

74-98-6 No 1000 1000 d 

Boiling Point: N/A 

SECTION 2 - PHYSICAL/CHEMICAL CHARACTERISTICS 

Specific Gravity (H2O=1): Concentrate Only = 0.818 

Vapor Pressure: PSIG @ 70°F (Aerosols): Max. 60 Vapor Pressure (Non-Aerosols)(mm Hg and Temperature): N/A 

Vapor Density (Air = 1): N/E Evaporation Rate ( = 1): N/E 

Solubility in Water: Insoluble 

Appearance and Odor: White powder with cyclohexane solvent odor. 

Water Reactive: No 

SECTION 3 - FIRE AND EXPLOSION HAZARD DATA 

FLAMMABILITY as per USA FLAME PROJECTION TEST Auto Ignition Temperature Flammability Limits in Air by % in Volume: 

(aerosols) EXTREMELY FLAMMABLE 

N/E 

% LEL: N/E % UEL: N/E 

FLASH POINT AND METHOD USED (non-aerosols): N/A 

EXTINGUISHER MEDIA: Foam, dry chemical, carbon dioxide. 

SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus. 

Unusual Fire & Explosion Hazards: Do not expose aerosols to temperatures above 130°F or the container may rupture. 

SECTION 4 - REACTIVITY HAZARD DATA 

STABILITY [ X ] STABLE [ ] UNSTABLE HAZARDOUS POLYMERIZATION [ ] WILL [ X ] WILL NOT OCCUR 

Incompatibility (Mat. to avoid): Water, aluminum, magnesium, alkalis, oxidizing Conditions to Avoid: Open flame, welding arcs, heat, sparks. 

agents, sodium, amines. 

Hazardous Decomposition Products: CO, CO2 

SECTION 5 - HEALTH HAZARD DATA 

PRIMARY ROUTES OF ENTRY: 

ACUTE EFFECTS: 

[ X ] INHALATION [ ] INGESTION [ ] SKIN ABSORPTION [ ] EYE [ ] NOT HAZARDOUS 

Inhalation: Excessive inhalation of vapors can be harmful and may cause headache, dizziness, anesthetic effects, asphyxia, and possible unconsciousness. 

Eye Contact: Irritation. Can cause possible eye damage. 

Ingestion: Possible chemical pneumonitis if aspirated into lungs. Nausea. 

Skin Contact: Irritation due to defatting of skin. 

CHRONIC EFFECTS: (Effects due to excessive exposure to the raw materials of this mixture) May cause liver, kidney, lung damage, central nervous system 

depression. 

Medical Conditions Generally Aggravated by Exposure: May aggravate existing eye, skin, or upper respiratory conditions. 

EMERGENCY FIRST AID PROCEDURES 

Eye Contact: Flush with water for 15 minutes. If irritated, seek medical attention. 

Skin Contact: Wash with soap and water. If irritated, seek medical attention. 

Inhalation: Remove to fresh air. Resuscitate if necessary. Get medical attention. 

Ingestion: DO NOT INDUCE VOMITING. Drink two large glasses of water. Get immediate medical attention. 

SECTION 6 - CONTROL AND PROTECTIVE MEASURES 

Respiratory Protection (specify type): If vapor concentration exceeds TLV, use respirator approved by U.S. Bureau of Mines for organic vapor. 

Protective Gloves: Neoprene gloves recommended. Eye Protection: Goggles or face shield required. 

Ventilation Requirements: Adequate ventilation to keep vapor concentration below TLV. 

Other Protective Clothing & Equipment: Rubber apron. 

Hygienic Work Practices: Wash with soap and water before handling food. Remove contaminated clothing. 

SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE 

Steps To Be Taken If Material Is Spilled Or Released: Absorb with suitable medium. Incinerate or landfill according to local, state or Federal regulations. DO 

NOT ALLOW INTO SEWER SYSTEMS. Avoid breathing vapors. 

Waste Disposal Methods: Aerosol cans when vented to atmospheric pressure through normal use, pose no disposal hazard. 

Precautions To Be Taken In Handling & Storage: Do not puncture or incinerate containers. Do not store at temperatures above 130°F. 

Other Precautions &/or Special Hazards: KEEP OUT OF REACH OF CHILDREN. Avoid food contamination. Avoid breathing vapors. Remove ignition sources. 

We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. 

** Chemical Listed as Carcinogen or Potential Carcinogen. [a] NTP [b] IARC Monograph [c] OSHA [d] Not Listed [e] Animal Data Only

form #5100-048-01, rev. date 1/13/2009 


GENERAL INFORMATION 

PRODUCT NAME OR NUMBER (as it appears on label) 

Noalox® Anti-Oxidant 

MANUFACTURER’S NAME 

IDEAL INDUSTRIES, INC. 

CATALOG NUMBER 

Document # 6810-005 

All “30” Series 

EMERGENCY TELEPHONE NO. 

(815) 895-5181 

ADDRESS (Number, Street, City, State, Zip Code) 

Becker Place, Sycamore, IL 60178 

HAZARDOUS MATERIAL DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS, HAZARD CLASS NO., HAZARD ID NO. (49 CFR 172.101) 

None 

CHEMICAL DESCRIPTION 

Petroleum-Based Mixture 

FORMULA 

Proprietary 

SECTION I - INGREDIENTS 

CAS REGISTRY NO. %W CHEMICAL NAME(S)* 

Listed as a carcinogen 

in NTP, I ARC or OSHA 

1910(z) (specify) 

9003-29-6

SECTION IV - HEALTH HAZARD INFORMATION 

EFFECTS OF OVEREXPOSURE - Conditions to Avoid 

None normally expected. Upon prolonged contact, may cause temporary eye discomfort. 

THRESHOLD LIMIT VALUE 

Zinc dust or silicon dioxide as dust: 10mg/m. 

PRIMARY ROUTES OF ENTRY Inhalation Skin Contact Other (specify) 


SKIN CONTACT: Wash with soap and water for 15 minutes. 

EYE CONTACT: 

Flush with water for 15 minutes 

INGESTION: 

STABILITY 

UNSTABLE 

STABLE X 

INCOMPATIBILITY (materials to avoid) 

HAZARDOUS DECOMPOSTION PRODUCTS: 

HAZARDOUS 

POLYMERIZATION 

MAY OCCUR 

WILL NOT OCCUR 

Induce vomiting and consult physician or local poison control center. 

X 



Avoid conditions of moisture or high humidity. 

Avoid strong oxidizers, strong acids and water. 

Excessive heat and burning may release oxides of carbon. 


SECTION VI - SPILL AND LEAK PROCEDURES 

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED 

Wipe up, shovel or vacuum spilled material. Clean up spills immediately. 

Use absorbent media. 


Comply with Federal, state and local regulations for solid landfill. 

CERCLA (Superfund) REPORTABLE QUANTITY (in lbs) 

None Required 

RCRA HAZARDOUS WASTE NO. (40CFR 261.33) 

None Required 

VOLATILE ORGANIC COMPOUND (VOC) (as packaged, minus water) 

128 g/l, calculated 

Noalox® Anti-Oxidant 

None 

³ Theoretical lb/gal N/A ³ Analytical lb/gal N/A 

SECTION VII - PERSONAL PROTECTION INFORMATION 

RESPIRATORY PROTECTION (specify type) 

If TLV exceeded, use NIOSH respirator. 

LOCAL EXHAUST (Specify Rate) Necessary above TLV SPECIAL None 

VENTILATION 

MECHANICAL (General) (Specify Rate) 

Recommended in closed areas. 

PROTECTIVE GLOVES (specify type) 

EYE PROTECTION (specify type) 

None normally needed -Neoprene if necessary 

OTHER PROTECTIVE EQUIPMENT 

OTHER None 

Safety glasses or splash goggles. 

Eye fountain in work area is recommended. 

SECTION VIII - SPECIAL PRECAUTIONS 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING 

Store in dry conditions at temperatures between 40 - 120 F. 


Keep away from children, infants and pets. 

SECTION IX - ADDITIONAL INFORMATION 

This product contains the following materials that are subject to the reporting requirements of 

Section 313 of EPCRA: 

CAS # 7440-66-6, Zinc Dust, 20% 

N/A = Not Applicable, N.E. = None Established 

THIS MATERIAL SAFETY DATA SHEET PREPARED BY: 

NAME James R. MacMurdo SIGNATURE 

TITLE Director, Corporate Quality Assurance 

DATE 5/27/2010

Product: PB−B 

Chemical family: Mixture. 

Manufacturer emergency phone 

number: 

PB BLASTER 

Section 1: PRODUCT INFORMATION 

Manufacturer: Truflex/Pang Rubber Products Company, Inc. 

200 East Coshocton Street 

P.O. Box 486 

Johnstown, Ohio 43031. 

Chemtrec 800−424−9300. 

International: 703−527−3887. 

Information phone number: 740−967−9015. 

800−433−8324. 

Supplier: Same as manufacturer. 

Product name: PB BLASTER (MSDS #113) 

Product uses: Penetrating lubricant. 

Catalog number(s): PB−B 

TDG classification: 

Labels required: None 

Emergency response guidebook 

number: 126 

EmS number: 2−13 

AEROSOLS 

UN1950 

Class 2.1. 

Reportable Quantity (DOT): Not applicable. 

Effective date: 2010/9/20 


Last review: 2010/9/20 

NFPA: 

May be shipped as Consumer Commodity ORM−D. 

Section 2: HAZARDOUS INGREDIENTS 

C.A.S. Concentration% wgt/wgt Ingredient Name ACGIH−TLV TWA LD/50 LC/50 

124−38−9 < 2 CARBON DIOXIDE 5000 PPM NOT AVAILABLE NOT AVAILABLE 

34590−94−8 > 3 DIPROPYLENE GLYCOL MONOMETHYL ETHER 100 PPM (SKIN) 5400 UL/KG 

RAT ORAL 

5.5 ML/KG 

RAT ORAL 

10 ML/KG 

RABBIT DERMAL 

NOT AVAILABLE 

64742−57−0 20 − 30 PETROLEUM OIL 5 MG/M3 NOT AVAILABLE NOT AVAILABLE 

PB BLASTER Page 1 of 5

64742−94−5 > 50 NAPHTHA, PETROLEUM > 2 ML/KG 

RABBIT DERMAL 

> 590 MG/M3/4H 

RAT INHALATION 

84133−50−0 > 2 ALKYLOXYPOLYETHYLENEOXYETHANOL NOT AVAILABLE NOT AVAILABLE 

Physical state: Liquid. 

Section 3: PHYSICAL DATA 

Appearance & odor: Amber 

Dark brown. 

Strong aromatic odour. 

Viscous liquid. 

Odor threshold (ppm): Not available. 

Vapour pressure (mmHg): Not applicable. 

Vapour density (air=1): >1 

Volatiles (%) 

By volume: 69.1 

Evaporation rate 

(butyl acetate = 1): >1 

Boiling point (°C): 178 − 215 (352−418°F) 

Freezing point (°C): Not available. 

pH: Not available. 

Specific gravity @ 20 °C: 0.9020 (7.515 lbs/gal) 

Solubility in water (%): Not available. 

Coefficient of water\oil dist.: Not available. 

VOC: 5.194 LBS/GAL (615.8 G/L) 

Flammability: Flammable aerosol. 

Section 4: FIRE & EXPLOSION DATA 

Conditions of flammability: Vapours are heavier than air and may travel along the ground and be ignited by 

flames, sparks or other ignition sources at locations distant from the material 

handling point. 

Heat, sparks and open flames. 

Extinguishing media: Carbon dioxide, dry chemical, foam. 

Special procedures: Self−contained breathing apparatus required. 

Firefighters should wear the usual protective gear. 

Auto−ignition temperature: Not available. 

Flash point (°C), method: Tag Closed Cup. 

66.7 (152°F) 

Lower flammability 

limit (% vol): 

Upper flammability 

limit (% vol): 




Explosion Data 

Sensitivity to static discharge: Take precautionary measures against static discharge. 

Sensitivity to mechanical impact: Contents under pressure. 

Hazardous combustion products: Oxides of carbon (CO, CO2). 

Various hydrocarbons. 

Explosive power: Product (even just residue) can ignite explosively. 

Chemical stability: Product is stable. 

Conditions of instability: None known. 

Hazardous polymerization: Will not occur. 

Section 5: REACTIVITY DATA 

Incompatible substances: Strong acids. 

Strong oxidizing agents. 

Hazardous decomposition 

products: 

See hazardous combustion products. 

Section 6: TOXICOLOGICAL PROPERTIES 

Route of entry: Skin contact, eye contact, inhalation and ingestion. 

Effects of acute exposure 

Eye contact: May cause irritation. 

May cause redness and tearing. 

May cause stinging. 

May cause swelling. 

Skin contact: May cause skin burns. 

May cause mild irritation. 

May cause drying and cracking. 

May cause redness or burning sensation. 

Inhalation: May cause drowsiness. 

May cause kidney and liver damage. 

May cause irritation of the respiratory tract. 

May cause light headedness. 

Ingestion: Can cause irritation to mouth, throat, esophagus and stomach. 

Aspiration hazard if swallowed. 

Effects of chronic exposure: May affect the central nervous system. 

LD50 of product, species & route: Not available for mixture, see the ingredients section. 

LC50 of product, species & route: Not available for mixture, see the ingredients section. 

Exposure limit of material: Not available for mixture, see the ingredients section. 

Sensitization to product: Not available. 

Carcinogenic effects: Not listed as a carcinogen. 

Reproductive effects: Not available. 

Teratogenicity: Not available. 


Mutagenicity: Not available. 

Synergistic materials: Not available. 

Precautionary Measures 

Gloves/Type: 

Respiratory/Type: 

Footwear/Type: 

Section 7: PREVENTATIVE MEASURES 

Chemical resistant gloves. 

Polyvinyl alcohol gloves. 

Nitrile gloves. 

NIOSH approved respirator, if necessary. 

(negative pressure type). 

Impervious boots. 

Clothing/Type: Impervious clothing. 

Other/Type: Eye wash facility should be in close proximity. 

Emergency shower should be in close proximity. 

Ventilation requirements: Explosion proof ventilation equipment. 

Local exhaust and/or general ventilation. 

Leak/Spill: Recover using a pump. 

Eliminate all sources of ignition. 

Dike area to prevent spreading. 

Evacuate all non−essential personnel. 

Prevent entry into drains, sewers, and other waterways. 

Absorb residual material with sand or other absorbent material. 

Stop leak if without risk. 

Wear appropriate protective equipment. 

Ground handling equipment. 

Transfer to an approved container for disposal. 

Notify the appropriate authorities as required. 

Waste disposal: In accordance with municipal, provincial and federal regulations. 

Handling procedures and 

equipment: 

Maintain a good personal hygiene. 

Keep away from heat, sparks, and open flame. 

Use adequate ventilation. 

Wash thoroughly after using, particularly before eating or smoking. 

Wear personal protective equipment appropriate to task. 

Empty containers containing residue may cause a hazard. 

Do not cut, grind, weld or drill empty container. 

Use proper grounding procedures. 

Avoid contact with skin, eyes and clothing. 

Avoid breathing vapor, fumes or mist. 

Launder contaminated clothing prior to reuse. 

Do not ingest. 


Storage requirements: Store away from all sources of ignition. 

Store away from strong acids or oxidizers. 

Special shipping information: See transportation information. 

Section 8: FIRST AID MEASURES 

Skin contact: Remove contaminated clothing. 

Wash with mild soap and water. 

Consult a physician if irritation persists. 

Eye contact: Flush eyes with clear, running water for 20 minutes while holding eyelids open. If 

irritation persists, consult a physician. 

Inhalation: Keep person warm and at rest. 

Remove victim to fresh air. If breathing is difficult administer oxygen. If not 

breathing, have qualified person give artificial respiration. Obtain medical attention. 

Ingestion: If victim is drowsy or unconscious, place on left side with head down. Do not leave 

individual unattended. 

Never give anything by mouth to an unconscious person. 

Do not induce vomiting, seek immediate medical attention. 

Additional information: The above information is believed to be correct but does not purport to be all 

inclusive and shall be used only as a guide. This company shall not be held liable 

for any inaccuracies. 

Section 9: ADDITIONAL INFORMATION 

General note: This material safety data sheet was prepared from information obtained from 

various sources, including product suppliers and the Canadian Center for 

Occupational Health and Safety. 

Data prepared by: Global Safety Management 

3340 Peachtree Road, #1800 

Atlanta, GA 30326 

Phone: 877−683−7460 

Fax: (877) 683−7462 

See www.techtirerepairs.com for the latest MSDSs. 

Web: www.globalsafetynet.com 

Email: info@globalsafetynet.com. 



PROPANE 

MSDS No. 06535400 WHMIS/ENGLISH 

1.0 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NAME: PROPANE 

MANUFACTURER/SUPPLIER: 

Amoco Canada Petroleum Company, Ltd. 

240 - 4 Avenue S. W. 

P. O. Box 200, Station M 

Calgary, Alberta T2P 2H8 

CANADA 

EMERGENCY HEALTH INFORMATION: 

1 (800) 447-8735 

EMERGENCY SPILL INFORMATION: 

1 (613) 996-6666 CANUTEC (Canada) 

OTHER PRODUCT SAFETY INFORMATION: 

(630) 836-5440 

2.0 COMPOSITION/INFORMATION ON INGREDIENTS 

Component CAS# Range % by Wt. 

Propane 74-98-6 100 

(See Section 8.0, "Exposure Controls/Personal Protection", for exposure guidelines) 

3.0 HAZARDS IDENTIFICATION 

EMERGENCY OVERVIEW: Danger! Extremely flammable. Compressed gas. At very high concentrations, can 

displace the normal air and cause suffocation from lack of oxygen. Liquid can cause burns similar to frostbite. 

POTENTIAL HEALTH EFFECTS: 

EYE CONTACT: Extremely cold material; can cause burns similar to frostbite. 

SKIN CONTACT: Liquid can cause burns similar to frostbite. 

INHALATION: At very high concentrations, can displace the normal air and cause suffocation from lack of 

oxygen. See "Toxicological Information" section (Section 11.0). 

INGESTION: Ingestion of liquid can cause burns similar to frostbite. 

4.0 FIRST AID MEASURES 

EYE: Contact with liquid: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate 

medical attention. 

SKIN: Contact with liquid: Immediately flush with plenty of tepid water (105-115°F; 41-46°C). DO NOT USE 

HOT WATER. Get immediate medical attention. 

INHALATION: If adverse effects occur, immediately remove to uncontaminated area. Give artificial respiration if 

not breathing. Give oxygen if breathing is difficult. Get immediate medical attention. 

INGESTION: Get immediate medical attention. 

5.0 FIRE FIGHTING MEASURES 

FLASHPOINT: -156°F(-104°C) (closed cup) 

UEL: 9.5% 

LEL: 2.1% 

AUTOIGNITION TEMPERATURE: 842°F (450°C) 

FLAMMABILITY CLASSIFICATION: Extremely flammable. Compressed gas. 

EXTINGUISHING MEDIA: Stop flow of gas if possible; if not, allow to burn. Do NOT direct water into 

liquid spill. Dry chemical can be used. 

UNUSUAL FIRE AND EXPLOSION HAZARDS: Product gives off vapors that are heavier than air which 

can travel considerable distances to a source of ignition and flashback. Extinguishment of fire before source of vapor

FIRE-FIGHTING EQUIPMENT: Firefighters should wear full bunker gear, including a positive pressure selfcontained 

breathing apparatus. 

PRECAUTIONS: Keep away from sources of ignition (e.g., heat and open flames). Use with adequate 

ventilation. 

HAZARDOUS COMBUSTION PRODUCTS: Burning can produce carbon monoxide and/or carbon dioxide 

and other harmful products. 

6.0 ACCIDENTAL RELEASE MEASURES 

Remove or shut off all sources of ignition. Wear respirator and spray with water to disperse vapors. 

7.0 HANDLING AND STORAGE 

HANDLING: Do not breathe vapors. Ground and bond all lines and equipment. 

STORAGE: Outside storage is recommended. Store in cool, dry, well-ventilated area. Do not store in areas 

containing flammable or combustible products. Do not store at or above 120°F (49°C). Store away from heat, 

ignition sources, and open flame in accordance with applicable regulations. 

SPECIAL PRECAUTIONS: Avoid strong oxidizers. 

8.0 EXPOSURE CONTROLS / PERSONAL PROTECTION 

EYE: Do not get in eyes. Wear chemical goggles. 

SKIN: As needed to prevent contact with liquid - wear gloves, impervious clothing and face shield. 

INHALATION: If ventilation is inadequate, use supplied- air respirator. 

ENGINEERING CONTROLS: Control airborne concentrations below the exposure guidelines. 

EXPOSURE GUIDELINES: 

Component CAS# Exposure Limits 

Propane 74-98-6 ACGIH TLV-TWA: 2500 ppm 

9.0 CHEMICAL AND PHYSICAL PROPERTIES 

APPEARANCE AND ODOR: Gas. Colorless. 


VAPOR PRESSURE: 189 - 208 psig at 100° F 

VAPOR DENSITY: 1.56 at 32°F 

BOILING POINT: -44°F(-42°C) 

MELTING POINT: -310°F(-190°C) 

SOLUBILITY IN WATER: Slight, 0.1 to 1.0%. 

SPECIFIC GRAVITY (WATER=1): 0.51 at 60°F 

10.0 STABILITY AND REACTIVITY 

STABILITY: Burning can be started easily. 

CONDITIONS TO AVOID: Keep away from ignition sources (e.g. heat, sparks, and open flames). 

MATERIALS TO AVOID: Avoid chlorine, fluorine, and other strong oxidizers. 

HAZARDOUS DECOMPOSITION: None identified. 


11.0 TOXICOLOGICAL INFORMATION 

ACUTE TOXICITY DATA: 

EYE IRRITATION: Testing not conducted. See Other Toxicity Data. 

SKIN IRRITATION: Testing not conducted. See Other Toxicity Data. 

DERMAL LD50: Testing not conducted. See Other Toxicity Data. 

ORAL LD50: Testing not conducted See Other Toxicity Data

INHALATION LC50: Testing not conducted. See Other Toxicity Data. 

OTHER TOXICITY DATA: Specific toxicity tests have not been conducted on this product. Our hazard 

evaluation is based on information from similar products, the ingredients, technical literature, and/or professional 

experience. 

This material is an asphyxiant. Asphyxiants may reduce the oxygen concentration in the air to dangerous levels. 

Symptoms of lack of oxygen include increased depth and frequency of breathing, air hunger, dizziness, headache, 

nausea or loss of consciousness. 

No component of this product at levels greater than 0.1% is identified as a carcinogen by ACGIH or the International 

Agency for Research on Cancer (IARC). No component of this product present at levels greater than 0.1% is 

identified as a carcinogen by the U.S. National Toxicology Program (NTP) or the U.S. Occupational Safety and 

Health Act (OSHA). 

12.0 ECOLOGICAL INFORMATION 

Ecological testing has not been conducted on this product by Amoco. 

13.0 DISPOSAL INFORMATION 

Vent vapor at a safe location. Insure dissipation of gas below the lower explosive limit. Consult local ordinances for 

compliance. 

14.0 TRANSPORTATION INFORMATION 

Canadian Transportation of Dangerous Goods 

Shipping Name Liquefied Petroleum Gas ( Propane ) ( NOT ODORIZED ) 

Hazard Class 2.1 

UN Number UN1075 

Packing Group X 

INTERNATIONAL INFORMATION: 

U.S. DEPT OF TRANSPORTATION 

Shipping Name Liquefied Petroleum Gas 

Hazard Class 2.1 

Identification Number UN1075 

Sea (IMO/IMDG) 

Shipping Name Not determined. 

Air (ICAO/IATA) 


European Road/Rail (ADR/RID) 


15.0 REGULATORY INFORMATION 

CANADA INVENTORY (DSL): All of the components of this product are listed on the DSL. 

WHMIS Controlled Product Classification: A, B1, 

U.S. INVENTORY (TSCA): Listed on inventory. 

EC INVENTORY (EINECS/ELINCS): In compliance. 

JAPAN INVENTORY (MITI): Listed on inventory. 

AUSTRALIA INVENTORY (AICS): Listed on inventory. 

KOREA INVENTORY (ECL): Not determined. 

PHILIPPINE INVENTORY (PICCS): Not determined.

Prepared by: 

Environment, Health and Safety Department 

Issued: December 07, 1998 

Supersedes: June 12, 1997 

16.0 OTHER INFORMATION 

This material safety data sheet and the information it contains is offered to you in good faith as accurate. We have 

reviewed any information contained in this data sheet which we received from sources outside our company. We 

believe that information to be correct but cannot guarantee its accuracy or completeness. Health and safety 

precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user's obligation to 

evaluate and use this product safely and to comply with all applicable laws and regulations. No statement made in 

this data sheet shall be construed as a permission or recommendation for the use of any product in a manner that 

might infringe existing patents. No warranty is made, either express or implied.


DiversiTech Corporation 

6650 Sugarloaf Parkway 

Duluth, GA 30097 

March 2009 

Regular Clear PVC Solvent Cement 

MSDS# 5-14, 5-12, 5-10, 5-32 

March 2009 

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION 

Manufactured by: Oatey Company 

Address: 4700 West 160th Stree 

P.O. Box 35906 

Cleveland, OH 44135 

EMERGENCY Phone No.: 1+800.255.3924 Chem-Tel (Chemical Emergencies Only) 

Phone Number for Information: 850-875-1716 Fax: 850-627-2699 

Date Revised: March 2009 

SECTION 2. COMPOSITION 

INGREDIENT % OR CAS NO ACIGH OSHA OTHER 

RANGE TLV TWA PEL TWA 

Acetone 0 - 5% 67-64-1 500 ppm 1000 ppm 

750 ppm STEL 

Cyclohexanone 5 - 10% 108-94-1 25 ppm(skin) 50 ppm 

Tetrahydrofuran 25 - 40% 109-99-9 200 ppm 200 ppm 25 ppm (Mfg) 

750 ppm STEL 

Methyl Ethyl Ketone 45 - 60% 78-93-3 200 ppm 200 ppm 

PVC Resin 10 - 16% 9002-86-2 10 mg/m3 15 mg/m3 

(Non-hazardous) 

SECTION 3. EMERGENCY OVERVIEW 

Clear liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors may cause flash fire. May cause eye and skin irritation. Inhalation of vapors 

or mist may cause respiratory irritation and central nervous system effects. Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney or liver 

disorders. Aspiration hazard. May be fatal if swallowed. Symptoms may be delayed. 

NFPA Hazard Signal: Health: 2 Stability: 1 Flammability: 3 Special: None 

HMIS Hazard Signal: Health: 3 Stability: 1 Flammability: 3 Special: None 

OSHA Hazard Classification: Flammable, irritant, organ effects 

Canadian WHIMS Classification: Class B, Division 1; Class D, Division 2, Subdivision B 

SECTION 4. EMERGENCY AND FIRST AID PROCEDURES 

Page 1 of 4 

Total Pages: 4 

Skin: Remove contaminated clothing immediately. Wash all exposed areas with soap and water. Get medical attention if irritation develops. Remove dried 

cement with Oatey Plumber's Hand Cleaner or baby oil. 

Eyes: If material gets into eyes or if fumes cause irritation, immediately flush eyes with water for 15 minutes. If irritation persists, seek 

medical attention. 

Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing becomes difficult, administer oxygen. Administer artificial 

respiration if breathing has stopped. Seek immediate medical attention. 

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or drowsy. Get immediate 

medical attention by calling a Poison Control Center, or hospital emergency room. If medical advice cannot be obtained, then take the 

person and product to the nearest medical emergency treatment center or hospital. 

Chemical Emergency: P 800-255-3924 

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SECTION 5. FIREFIGHTING MEASURES 

Flashpoint / Method: 0 - 5 Degrees F. / PMCC 

Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume 

Extinguishing Media: Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be innefective as an extinguishing 

agent. 

Special Fire Fighting Procedure: Fire Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in 

areas where chemicals are used or stored. 

Unusual Fire or Explosion Hazards: Extremely flammable liquid. Keep away from heat and all sources of ignition including sparks, flames, lighted cigarettes 

and pilot lights. Containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ignition source and flash back. 

This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. 

Hazardous Decomposition Products: Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen chloride. 

SECTION 6. ACCIDENTAL RELEASE MEASURES 

Spill or Leak Procedures: Remove all sources of ignition and ventilate area. Stop leak if it can be done without risk. Personnel cleaning up the spill should 

wear appropriate personal protective equipment, including respirators if vapor concentrations are high. Soak up spill with an inert absorbent such as sand, 

earth or other non-combusting material. Put absorbent material in covered, labeled metal containers. Prevent liquid from entering watercourses, sewers and 

natural waterways. Report releases to authorities as required. See Section 12 for disposal information. 

SECTION 7. HANDLING AND STORAGE 

Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to outdoors). Wash 

thoroughly after handling. Do not eat, drink or smoke in the work area. Keep product away from heat, sparks, flames and all other sources of ignition. No 

smoking in storage or use areas. Keep containers closed when not in use. 

Storage: Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not in use. 

Other: "Empty" containers retain product residue and can be hazardous. Follow all MSDS precautions in handling empty containers. Do not cut or weld on or 

near empty or full containers. 

SECTION 8. ECOLOGICAL INFORMATION 

This product is not expected to be toxic to aquatic organisms. 

Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l. 

Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L. 

Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L. 

Acetone: 96 hour LC50 for fish is greater than 100 mg/L. 

VOC Information: This product emits VOC's (volatile organic compounds) in its use. Make sure that use of this product complies with local VOC emission 

regulations, where they exist. 

VOC Level: 550 g/l per SCAQMD Test Method 316A. 

SECTION 9. EXPOSURE CONTROLS/PERSONAL PROTECTION 

Ventilation: Open doors & windows. Provide ventilation capable of maintaining emissions at the point of use below recommended exposure limits. If used in 

enclosed area, use exhaust fans. Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of solvent vapors are not exposed 

to electrical fixtures or hot surfaces. 

Respiratory Protection: For operations where the exposure limit may be exceeded, a NIOSH approved organic vapor respirator or supplied air respirator is 

recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial 

hygiene practice. For firefighting, use self-contained breathing apparatus. 

Skin Protection: Rubber gloves are suitable for normal use of the product. For long exposures product chemical resistant gloves may be required such as 

4H(tm) or Silver Shield(tm) to avoid prolonged skin contact. 

Eye Protection: Safety glasses with sideshields or safety goggles. 

Other: Eye wash and safety shower should be available. 

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SECTION 10. PHYSICAL AND CHEMICAL PROPERTIES 

Boiling Point: 151 Degrees F / 66 C 

Melting Point: N/A 

Vapor Pressure: 145 mmHg @ 20 Degrees C 

Vapor Density: (Air = 1) 2.5 

Volatile Components: 86-90% 

Solubility In Water: Negligible 

pH: N/A 

Specific Gravity: 0.89 +/- 0.015 

Evaporation Rate: (BUAC = 1) = 5.5 - 8.0 

Appearance: Clear Liquid 

Odor: Ether-Like 

Will Dissolve In: Tetrahydrofuran 

Material Is: Liquid 

SECTION 11. STABILITY AND REACTIVITY 


Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition. 

Hazardous Decomposition Products: Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen chloride. 

Incompatibility/Materials To Avoid: Oxidizing agents, alkalies, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium 

and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber. 


SECTION 12. DISPOSAL INFORMATION 

Waste Disposal: Dispose in accordance with current local, state and federal regulations. 

SECTION 13. TOXICOLOGICAL INFORMATION 

Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation, coughing, headache, dizziness, dullness, nausea, shortness of breath 

and vomiting. High concentrations may cause central nervous system depression, narcosis and unconsciousness. May cause kidney, liver and lung damage. 

Skin: May cause irritation with redness, itching and pain. Methyl ethyl ketone and cyclohexanone may be absorbed through the skin causing effects similar to 

those listed under inhalation. 

Eye: Vapors may cause irritation. Direct contact may cause irritation with redness, stinging and tearing of the eyes. May cause eye damage. 

Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea. Aspiration during swallowing or vomiting can cause chemical pneumonia 

and lung damage. May cause kidney and liver damage. 

Toxicity: Chronic prolonged or repeated overexposure cause dermatitis and damage to the kidney, liver, lungs and central nervous system. 

Toxicity Data: 

Acetone: Oral rat LD50: 5,800 mg/kg Inhalation rat LC50: 50,100 mg/m3/8 hours 

Cyclohexanone: Oral rat LD50: 1,620 mg/kg Inhalation rat LC50: 8,000 ppm/4 hours. Skin rabbit LD50: 1 mL/kg 

Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg Inhalation rat LC50: 21,000 ppm/3 hours 

Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg Inhalation rat LC50: 23,500 mg/m3/8 hours. Skin rabbit LD50: 6,480 mg/kg 

Sensitization: None of the components are known to cause sensitization. 

Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by NTP, IARC or OSHA. The National Toxicology Program 

has reported that exposure of mice and rats to Tetrahydrofuran (THF) vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their lifetime caused an 

increased incidence of kidney tumors in male rats and liver tumors in female mice. The significance of these findings for human health are unclear at this time, 

and may be related to "species specific" effects. Elevated incidences of tumors in humans have not been reported for THF. 

Mutagenicity: Acetone has been positive in a mammal cell cytogenic analysis but negative in many other assays. At most, acetone is weakly genotoxic. 

Cyclohexanone has been positive in bacterial and mammalian assays. Tetrahydrofuran was positive in a bacterial assay. Methyl ethyl ketone is not considered 

genotoxic based on laboratory studies. 

Reproductive Toxicity: Methyl ethyl ketone and cyclohexanone have been shown to cause embryofetal toxicity and birth defects in laboratory animals. 

Acetone and tetrahydrofuran have been found to cause adverse developmental effects only when exposure levels cause other toxic effects to the mother. 

Medical Conditions Aggravated By Exposure: Persons with pre-existing skin, lung, kidney or liver disorders may be at increased risk from exposure to this product. 

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SECTION 14. TRANSPORTATION INFORMATION 

DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) 

Proper Shipping Name: Consumer Commodity Adhesives 

Hazard Class/Packing Group: ORM-D 3 PGII 

UN/NA Number: None UN1133 

Hazard Labels: None Flammable Liquid 

IMDG Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) 

Proper Shipping Name: Adhesives Adhesives 

Hazard Class/Packing Group: 3, II 3, II 

UN/NA Number: UN1133 UN1133 

Hazard Labels: None (Limited Quantities Class 3 (Flammable Liquid) 

are excepted from labeling) 

RCRA Hazardous Waste Number: U002, U057, U159, U213 

EPA Hazardous Waste ID Number: D001, D035, F005 

EPA Hazard Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content) 

SECTION 15. REGULATIONS 

Hazard Category for Section 311/312: Acute Health, Chronic Health, Flammable 

Section 302 Extremely Hazardous Substances (TPQ): This product does not contain chemicals regulated under SARA Section 302. 

Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: 

Chemical CAS # % 

Methyl Ethyl Ketone 78-93-3 45-60% 

CERCLA 103 Reportable Quantity: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for 

the product, based on the RQ for Tetrahydrofuran (40% maximum) of 1,000 lbs, is 2,500 lbs. Many states have more stringent release reporting requirements. 

Report spills required under federal, state and local regulations. 

California Proposition 65: This product contains trace amounts of chemicals known to the State of California to cause cancer. Under normal use conditions, 

exposures to these chemicals at levels above the State of California "No Significant Risk Level" (NSRL) are unlikely. Oatey strongly encourages the use of 

proper personal protective equipment (PPE) and ventilation guidelines noted in Section 9 to minimize exposure to these chemicals. 

TSCA Inventory: All of the components of this product are listed on the TSCA inventory. 

SECTION 16. MANUFACTURED BY 

Diversitech 

6650 Sugarloaf Parkway, Suite 100 


Phone 1+678.542.3600 

EMERGENCY Phone No. 1 800-255-3924 Chem-Tel (Chemical Emergencies Only) 

SECTION 17. REFERENCE NUMBER AND DATE OF ISSUE 

MSDS Safety Data Sheet: 5-14, 5-12, 5-10, 5-32 Issued 03/30/2009 

This information is, to the best of our knowledge and belief, accurate and reliable as of the date completed. However no representation, warranty or guarantee is made as to its 

accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the completeness and suitability of such information for his own particular use. We do not 

accept liability for any loss or damage that may occur from the use of this information, nor do we offer any warranty against patent infringement. 

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State Chemical Division – State Industrial Products State Chemical Ltd. 

3100 Hamilton Avenue, Cleveland, OH 44114 (216) 861-7114 1745 Meyerside Dr., Unit #1, Mississauga, Ontario L5T 1C6 (905) 670-4669 

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Product Name: RAPID WRENCH 24 Hour Emergency CHEMTREC Number: 800-424-9300 

Product Description: A formulated aerosol lubricant sealer and anti-seize compound. MSDS Number: M00919 


Hazardous Ingredients CAS Number Weight ACGIH OSHA 

Propane 74-98-6 < 20% 2500 ppm 1000 ppm 

Butane 106-97-8 < 10% 800 ppm 800 ppm 

Heptane 142-82-5 < 45% 400 ppm 400 ppm 

Paraffinic Mineral Oil 8042-47-5 < 5.0% 5 mg/m3 as mist 5 mg/m3 as mist 

Paraffin Oil 64742-62-7 < 10% 5 mg/m3 as mist 5 mg/m3 as mist 

Petroleum Distillates 64742-65-0 < 10% 5 mg/m3 as mist 5 mg/m3 as mist 

Graphite 7782-42-5 < 5.0% 2 mg/m3 2.5 mg/m3 

Copper 7440-50-8 < 10% 1 mg/m3 1 mg/m3 


***EMERGENCY OVERVIEW*** 

Extremely flammable. Contents under pressure. Do not puncture, incinerate or expose to temperature above 120°F(49°C). Vapor harmful. Eye, skin and respiratory irritant. 


Routes of Exposure: Exposure may be by inhalation and/or skin or eye contact, depending on conditions of use. To minimize exposure, follow recommendations for proper use, 

ventilation and personal protective equipment. 

Eye Contact: May cause eye irritation. Redness and itching or burning sensation may indicate excessive exposure. 

Skin Contact: May cause skin irritation. Redness and itching or burning sensation may indicate excessive exposure. 

Inhalation: May cause irritation of the respiratory system. May cause nervous system depression. Headache, nausea, dizziness and loss of coordination are indications of 

excessive exposure to vapors or spray mists. Extreme overexposure may result in unconsciousness and possibly death. 

General: Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Prolonged overexposure to solvent 

ingredients may cause adverse effects to the liver, urinary and reproductive systems. 


Eye Contact: Promptly flush with a large amount of water for at least 15 minutes. If irritation persists, consult a physician. 

Skin Contact: Promptly wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before reuse. If irritation persists, consult a physician. 

Inhalation: Remove to fresh air. Restore breathing if necessary. If irritation persists, consult a physician 

Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Seek immediate medical attention. 


Flashpoint: Propellant < 0°F. 

Lower Explosive Limit(LEL): 1.0 Upper Explosive Limit(UEL): 9.5 Autoignition Temperature: NA 

Fire and Explosion Hazards: Vapors will accumulate readily and may ignite explosively. Isolate from heat, electrical equipment, sparks and open flame. Closed ontainers may 

explode (due to build-up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency 

conditions, overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. 

Extinguishing Media: Carbon dioxide, dry chemical, foam. 

Fire Fighting Instructions: Full protective equipment including self-contained breathing apparatus should be used. Water spray maybe ineffective. If water is used, fog nozzles are 

preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme 

heat. 


Remove all sources of ignition. Ventilate area and remove with inert absorbent. Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act 

(RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Dispose of in accordance with all Federal, State and Local Regulations 

regarding waste disposal. 


Keep away from heat, flames, sparks or other sources of ignition. Consult NFPA Code. Use approved bonding and grounding procedures. Contents under pressure. Do not 

puncture, incinerate or expose to temperature above 120°F(49°C). Heat from sunlight, radiators, stoves, hot water and other heat sources could cause container to burst. Do not 

take internally. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Keep out of reach of children. Use only with adequate 

ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. 


Engineering Controls: Local exhaust preferable. General exhaust acceptable if the exposure to materials is maintained below applicable exposure limits. 

Personal Protective Equipment: 

Respiratory: If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted NIOSH-approved organic vapor/particulate 

respirator. 

Eye: Wear approved safety glasses with unperforated sideshields. 

Skin: None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemically resistant 

gloves. 

Other: An emergency eyewash station or source of clean potable water should be available in case of accidental eye contact.


Appearance: Copper. Odor: Solvent. 

Physical State: Liquid aerosol. pH: NA 

Product Weight: 6.05 lb/gal; 724 g/l. Specific Gravity: 0.73 

Boiling Point: < 0 - 238°F; < -18 - 114°C Volatile Volume: 81% 

Melting Point: NA Vapor Density: Heavier than air. 

Evaporation Rate: Faster than Ether. Solubility in Water: NA 

Vapor Pressure@70°F: NA VOC Content: 70.00% (less Federally Exempt Solvents). 




Conditions to Avoid: Heat, sparks, flames or other sources of ignition. 

Incompatibility: None expected. 

Hazardous Decomposition Products: By Fire: Carbon Dioxide, Carbon Monoxide. 


No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. 

Hazardous Ingredients CAS Number LD50 LC50 

Propane 74-98-6 NE NE 

Butane 106-97-8 NE 658 mg/l/4 hr (rat) 

Heptane 142-82-5 4 mg/l/24 hr (goldfish) 4924 mg/l/24-96 hr (mosquito fish) 

Paraffinic Mineral Oil 8042-47-5 NE NE 

Paraffin Oil 64742-62-7 NE NE 

Petroleum Distillates 64742-65-0 NE NE 

Graphite 7782-42-5 NE NE 

Copper 7440-50-8 NE NE 


NA 


Do not incinerate. Depressurize container. Dispose of in accordance with all Federal, State and Local Regulations regarding pollution and waste disposal. Product as supplied is a DOO1 

unspecified ignitable waste. 


DOT Shipping Data: Consumer Commodity, ORM-D. 

Canadian TDG: Shipped in accordance with 49 CFR as part of a transborder shipment authorized under Section 5.2 (1) of the Canadian Transportation of Dangerous Goods. 

For International Shipments by Air: Aerosols, Flammable, 2.1, UN1950. 

For International Shipments by Vessel: Aerosols, Flammable, 2.1, UN1950, Limited Quantity 


TSCA: All ingredients in this product are listed or exempt from listing on the TSCA Chemical Inventory. 

CEPA: All ingredients in this product are listed or exempt from listing on the Canadian DSL/NDSL. 

Proposition 65: This product may contain trace amounts of the following chemicals that are known to the state of California to cause cancer, birth defects or other reproductive harm: 

Benzene 71-43-2 0.009% 

Toluene 108-88-3 0.435% 

SARA 313: This product contains the following toxic chemicals that are subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right- 

To-Know Act of 1986 (40 CFR 372.65C): 

Copper Compound 7440-50-8 8% 

HMIS Classification: Health = 2 Flammability = 4 Reactivity = 0 Personal Protection = B 

WHMIS Classification: Class A; Class B, Division 5; Class D, Division 2B 


NA = Not Available or Not Applicable. 

NE = Not Established 

Read and follow all label directions and precautions before using the product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE 

OR RESALE. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, 

the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consideration, investigation, and 

verification. Any use of these data and information must be determined by the user to be in accordance with applicable Federal, State, and Local Laws and regulations. 

HEALTH AND SAFETY INFORMATION: (216) 861-7114 

Prepared On: October 2008 Replaces: October 2005 Completed By: Regulatory Affairs Specialist.

FICHE SIGNALÉTIQUE 



1. IDENTIFICATION DU PRODUIT CHIMIQUE ET DE LA SOCIÉTÉ 

Nom du produit : RAPID WRENCH Numéro d’urgence CHEMTREC 24 h/24 : 800-424-9300 

Description du produit : produit lubrifiant, étanchéifiant et dégrippant en aérosol Numéro de fiche signalétique : M00919 

2. COMPOSITION/INFORMATION SUR LES INGRÉDIENTS 

Ingrédients dangereux Numéro CAS Poids ACGIH OSHA 

Propane 74-98-6 < 20% 2500 ppm 1000 ppm 

Butane 106-97-8 < 10% 800 ppm 800 ppm 

Heptane 142-82-5 < 45% 400 ppm 400 ppm 

Huile minérale paraffinique 8042-47-5 < 5.0% 5 mg/m3 as mist 5 mg/m3 as mist 

Huile de pétrole 64742-62-7 < 10% 5 mg/m3 as mist 5 mg/m3 as mist 

Distillats de pétrole 64742-65-0 < 10% 5 mg/m3 as mist 5 mg/m3 as mist 

Graphite 7782-42-5 < 5,0% 2 mg/m 3 2,5 mg/m 3 

Cuivre 7440-50-8 < 10% 1 mg/m 3 1 mg/m 3 

3. IDENTIFICATION DES DANGERS 

***SITUATIONS D’URGENCE*** 

Produit extrêmement inflammable. Contenu sous pression. Ne pas percer, incinérer ou exposer à des températures supérieures à 49ºC. Vapeurs nocives. Irrite les yeux, la peau et les voies 

respiratoires. 

EFFETS POSSIBLES SUR LA SANTÉ 

Voies d'exposition : L'exposition peut se faire par inhalation et/ou par contact cutané ou oculaire, selon les conditions d'emploi. Pour minimiser l'exposition, suivre les conseils 

d'utilisation, ventiler et porter un équipement de protection individuelle. 

Contact oculaire : Peut causer une irritation de l'œil. L'exposition excessive peut se traduire par des rougeurs et une démangeaison ou sensation de brûlure. 

Contact cutané : Peut causer une irritation de la peau. L'exposition excessive peut se traduire par des rougeurs et une démangeaison ou sensation de brûlure. 

Inhalation : Peut causer une irritation du système respiratoire. Peut causer une dépression du système nerveux central. L'exposition excessive aux vapeurs ou brouillards de ce 

produit se traduit par des maux de tête, nausées, étourdissements et perte de coordination. L'extrême surexposition au produit présente un danger de perte de 

conscience, voire de mort. 

En général : Certaines publications ont associé la surexposition répétée et prolongée aux solvants à des lésions cérébrales et neurologiques irréversibles. Une surexposition 

prolongée à des solvants peut avoir des effets nocifs sur le foie et sur l'appareil génito-urinaire. 

4. PREMIERS SOINS 

Contact oculaire : Rincer rapidement à grande eau pendant 15 minutes au minimum. Si l'irritation persiste, consulter un médecin. 

Contact cutané : Laver rapidement la peau avec soin à l’eau et au savon. Enlever les vêtements contaminés et les laver avant réutilisation. Si l'irritation persiste, consulter un médecin. 

Inhalation : Faire sortir la victime à l’air frais. Le cas échéant, rétablir la respiration. Si l'irritation persiste, consulter un médecin. 

Ingestion : Ne pas provoquer de vomissement. Ne jamais rien administrer par voie orale à une personne inconsciente. Obtenir des soins médicaux immédiats. 

5. EN CAS D’INCENDIE 

Point d'éclair : Propulseur < -18°C 

Limite d’explosivité inférieure (LEL) : 1,0 Limite d’explosivité supérieure (UEL) : 9,5 Température d’auto-inflammation : néant 

Risques d'incendie et d'explosion : Les vapeurs s'accumulent spontanément et peuvent exploser. Isoler de sources de chaleur, d'équipements électriques, d'étincelles et de flammes 

nues. Les récipients hermétiques exposés à une chaleur extrême présentent un risque d'explosion (en raison de la pressurisation). L'application sur 

des surfaces chaudes nécessite des mesures de précaution particulières. Dans les situations d'urgence, la surexposition aux produits de 

décomposition peut présenter un danger pour la santé. Les symptômes ne sont pas toujours immédiatement visibles. Obtenir des soins médicaux. 

Moyens d’extinction : Dioxyde de carbone, mousse extinctrice, poudre chimique. 

Lutte contre l’incendie : Porter un équipement de protection complet à appareil respiratoire autonome. L'utilisation d'un jet d'eau peut s'avérer inefficace. Pour arroser à 

l'eau, il est préférable d'employer une lance à brouillard. Utiliser de l'eau pour rafraîchir les récipients hermétiques exposés à une chaleur extrême 

pour écarter les risques de pressurisation, voire d'auto-inflammation ou d'explosion. 

6. ÉMISSIONS ACCIDENTELLES 

Éliminer toute source d’inflammation. Ventiler la zone et enlever le produit à l'aide d'un absorbant inerte. Les déchets de ce produit peuvent être considérés dangereux en vertu de la définition 

de 40 CFR 261 de la RCRA (loi américaine sur la conservation et la récupération des ressources). L'inflammabilité des déchets doit être testée afin de déterminer la classe de déchet dangereux 

appropriée. Éliminer conformément à toutes les réglementations fédérales, provinciales et locales en vigueur en matière d'élimination des déchets. 

7. MANUTENTION ET ENTREPOSAGE 

Tenir à l’abri de la chaleur, flammes, étincelles et autres sources d’inflammation. Consulter le code NFPA. Respecter les procédures de liaison et de mise à la terre prévues. Contenu sous 

pression. Ne pas percer, incinérer ou exposer à des températures supérieures à 49ºC. La chaleur du soleil, de radiateurs, poêles, chauffe-eau et autre source de chaleur peut provoquer un 

éclatement du récipient. Ne pas absorber. La concentration et l’inhalation du produit de façon délibérée peuvent être nocives voire mortelles et sont à proscrire. Garder hors de portée des 

enfants. Utiliser uniquement avec une ventilation appropriée. Éviter de respirer les vapeurs ou brouillards de ce produit. Éviter tout contact avec la peau et les yeux. Se laver les mains après 

utilisation. 

8. CONTRÔLE DE L’EXPOSITION / PROTECTION PERSONNELLE 

Moyens techniques : Ventilation aspirante locale conseillée. Une ventilation aspirante générale est acceptable si l'exposition aux substances est maintenue en dessous des limites 

d'exposition réglementaires. 

Équipement de protection individuelle : 

respiratoire : Si la ventilation ne permet pas de maintenir l'exposition individuelle en dessous des limites réglementaires, prévoir le port d'un appareil respiratoire pour particules et 

vapeurs organiques agréé NIOSH. 

oculaire : Porter des lunettes de sécurité à écrans latéraux non perforés. 

cutanée : Aucune protection requise pour l'application normale des produits en aérosol susceptible de produire un contact cutané minimal. En cas de contact prolongé ou répété, 

porter des gants de protection chimique. 

autre : Une station d'eyewash de secours ou une source de l'eau potable propre devrait être disponible en cas de contact d'oeil accidentel.

9. PROPRIÉTÉS PHYSIQUES ET CHIMIQUES 

Aspect : cuivré Odeur : solvant 

État physique : liquide aérosol pH : néant 

Masse volumique : 724 g/l Densité : 0,73 

Point d’ébullition : < -18 à 114°C Volume volatil : 81% 

Point de fusion : néant Densité de la vapeur : plus lourde que l’air 

Taux d’évaporation : plus rapide que l'éther Solubilité dans l’eau : néant 

Tension de vapeur à 21°C : néant Contenu de VOC: 70,00% (moins les solvants exemptés) 

10. STABILITÉ ET RÉACTIVITÉ 

Stabilité : stable. 

Polymérisation dangereuse : ne se produit pas. 

Conditions à éviter : chaleur, étincelles, flammes et autres sources d’inflammation. 

Incompatibilité : aucune présumée. 

Produits de décomposition dangereux : par le feu : dioxyde de carbone, monoxyde de carbone. 

11. INFORMATIONS TOXICOLOGIQUES 

Ce produit ne contient aucun ingrédient déclaré cancérogène par le CIRC, NTP ou OSHA. 

Ingrédients dangereux Numéro CAS LD50 LC50 

Propane 74-98-6 n.e. n.e. 

Butane 106-97-8 n.e. 658 mg/l/4 hr (rat) 

Heptane 142-82-5 4 mg/l/24 hr (goldfish) 4924 mg/l/24-96 hr (mosquito fish) 

Huile minérale paraffinique 8042-47-5 n.e. n.e. 

Huile de pétrole 64742-62-7 n.e. n.e. 

Distillats de pétrole 64742-65-0 n.e. n.e. 

Graphite 7782-42-5 n.e. n.e. 

Cuivre 7440-50-8 n.e. n.e. 

12.INFORMATIONS ÉCOLOGIQUES 

néant 

13. ÉLIMINATION 

Ne pas incinérer. Dépressuriser le récipient. Éliminer conformément à la réglementation fédérale, provinciale et locale en matière d’environnement et d'élimination des déchets. Produit 

comme formulé dans une perte D001 inflammable non spécifiée. 

14. TRANSPORT 

Données D.O.T.: Bien de consommation (Consumer Commodity), AAR-D (ORM-D) 

TMD (Canada) : Expédié en conformité avec 49 CFR dans le cadre d’un envoi transfrontalier autorisé aux termes de la Section 5.2(1) de la loi canadienne sur le transport 

des marchandises dangereuses. 

Pour les expéditions internationales par Air : Aérosols, Inflammables, 2.1, UN1950. 

Pour les expéditions internationales par Vessel : Aérosols, Inflammables, 2.1, UN1950, quantité limitée 

15. INFORMATIONS RÉGLEMENTAIRES 

TSCA : Tous les ingrédients de ce produit figurent ou sont dispensés de figurer sur l’inventaire du TSCA. 

LCPE (Canada) : Tous les ingrédients de ce produit figurent ou sont dispensés de figurer sur les LIS/LES (Canada). 

Proposition 65 : Ce produit peut contenir à l'état de traces les substances chimiques suivantes, déclarées responsables de cancer, malformations congénitales ou autres 

anomalies de la reproduction par l’État de Californie: 

Benzène 71-43-2 0.0009% 

Toluène 108-88-3 0.435% 

SARA 313 : Ce produit contient les substances chimiques toxiques suivantes devant être déclarées aux termes de la section 313 de la loi Emergency Planning and 

Community Right-To-Know Act de 1986 (40 CFR 372.65C) : 

Composé de cuivre 7440-50-8 8% 

Classification HMIS : Santé = 2 Inflammabilité = 4 Réactivité = 0 Protection individuelle = B 

Classification SIMDUT : Classe A; Classe B, Division 5 ; Classe D, Division 2B 

16. AUTRES INFORMATIONS 

néant = non disponible ou sans objet 

n.e. = non établi 

Lire et suivre toutes les instructions et les précautions d’emploi figurant sur l’étiquette avant d’utiliser le produit. Ces produits sont destinés à l’industrie et aux collectivités 

uniquement. CES PRODUITS NE SONT PAS DESTINÉS À UN USAGE DOMESTIQUE OU À LA REVENTE. GARDER HORS DE PORTÉE DES ENFANTS. Bien que les 

informations ci-dessus soient jugées exactes et que les avis exprimés soient ceux d’experts qualifiés, les données fournies ne tiennent pas lieu de garantie ou de déclaration engageant 

la responsabilité juridique de la société. Ces informations sont fournies à des fins d’examen, de recherche et de vérification. L’utilisation de ces informations sera déterminée par 

l’utilisateur, conformément aux lois et réglementations fédérales, provinciales et locales en vigueur. 

INFORMATIONS SUR LA SANTÉ ET LA SÉCURITÉ : (216) 861-7114 

Date de Préparation : Octobre 2008 Remplace : Octobre 2005 Par : Spécialiste des affaires réglementaires.

PLANILLA DE DATOS DE SEGURIDAD DEL PRODUCTO 



1. PRODUCTO QUÍMICO Y DATOS DE LA COMPAÑÍA 

Nombre del producto: RAPID WRENCH Núm. CHEMTREC (emergencias) las 24 horas: 800-424-9300 

Descripción del producto: Producto lubricante, sellador y antiagarrotamiento en aerosol. Núm. MSDS: M00919 

2. COMPOSICIÓN/INFORMACIÓN SOBRE LOS COMPONENTES 

Componentes peligrosos Núm. CAS Peso ACGIH OSHA 

Propano 74-98-6 < 20% 2500 ppm 1000 ppm 

Butano 106-97-8 < 10% 800 ppm 800 ppm 

Heptano 142-82-5 < 45% 400 ppm 400 ppm 

Aceite mineral paraffinic 8042-47-5 < 5.0% 5 mg/m3 as mist 5 mg/m3 as mist 

Aceite de parafina 64742-62-7 < 10% 5 mg/m3 as mist 5 mg/m3 as mist 

Destilados del petróleo 64742-65-0 < 10% 5 mg/m3 as mist 5 mg/m3 as mist 

Grafito 7782-42-5 < 5.0% 2 mg/m 3 2.5 mg/m 3 

Cobre 7440-50-8 < 10% 1 mg/m 3 1 mg/m 3 

3. ENUMERACIÓN DE PELIGROS 

***DESCRIPCIÓN GENERAL DE LAS SITUACIONES DE EMERGENCIA*** 

Extremadamente inflamable. Contenido bajo presión. No perfore, incinere ni exponga a temperaturas superiores a los 120 °F (49 °C). Las emanaciones son nocivas. Irrita ojos, piel y tracto 

respiratorio. 

POSIBLES EFECTOS SOBRE LA SALUD 

Vías de exposición: La exposición podría producirse por inhalación y/o por contacto con los ojos o la piel, dependiendo de la forma de uso. Para minimizar la exposición, siga las 

recomendaciones relativas a uso, ventilación y equipo de protección personal apropiadas. 

Contacto con los ojos: Podría irritar los ojos. El enrojecimiento y el escozor, o bien una sensación de ardor, son síntomas de exposición excesiva. 

Contacto con la piel: Podría irritar la piel. El enrojecimiento y el escozor, o bien una sensación de ardor, son síntomas de exposición excesiva. 

Inhalación: Podría irritar el tracto respiratorio. Podría deprimir el sistema nervioso. Dolor de cabeza, náuseas, mareos y falta de coordinación son síntomas de una exposición 

excesiva a las emanaciones o al producto atomizado. La sobreexposición extrema podría provocar pérdida de conocimiento y posiblemente la muerte de la persona 

afectada. 

Aviso general: Existen informes que han asociado la exposición prolongada y repetida a solventes, con lesiones permanentes en cerebro y sistema nervioso. La sobreexposición 

prolongada a disolventes puede provocar trastornos en hígado, aparato urinario y aparato reproductor. 

4. MEDIDAS DE PRIMEROS AUXILIOS 

Contacto con los ojos: Lávese inmediatamente con abundante agua durante al menos 15 minutos. Si la irritación no desapareciera, consulte a un médico. 

Contacto con la piel: Lave inmediatamente el área afectada con agua y jabón. Quítese la ropa contaminada y lávela antes de volver a usarla. Si la irritación no desapareciera, consulte a un 

médico. 

Inhalación: Traslade a la víctima a un sitio con aire fresco. Si fuera necesario, restaure la respiración. Si la irritación no desapareciera, consulte a un médico 

Ingestión: No induzca el vómito. Jamás administre nada por vía oral a una persona que haya perdido el conocimiento. Obtenga atención médica de inmediato. 

5. MEDIDAS PARA COMBATIR INCENDIOS 

Pto. inflamabilidad: Propelente < 0 °F. 

Límite explosivo inferior (LEL): 1.1 Límite explosivo superior (UEL): 10.0 Temperatura de autoignición: NA 

Riesgo de incendio y explosión: Las emanaciones podrían acumularse y encenderse en forma explosiva. Mantenga alejado de objetos calientes, equipo eléctrico, chispas y 

llamas. Si se los expusiera a calor extremo, los recipientes cerrados podrían explotar (debido al aumento de la presión interna). Cuando se 

aplique sobre superficies calientes habrá que tomar precauciones especiales. La sobreexposición a los productos de descomposición 

generados en situaciones extremas podría suponer un riesgo para la salud. Los síntomas podrían no manifestarse de inmediato. Obtenga 

atención médica. 

Medio extinguidor: Dióxido de carbono, productos químicos en polvo, espuma. 

Instrucciones para combatir incendios: Use un aparato autónomo para respirar e indumentaria de protección. El agua rociada podría resultar ineficaz. Si se utilizara agua, se recomienda usar 

boquillas rociadoras. Puede utilizarse agua para enfriar los recipientes expuestos, a fin de evitar el aumento de presión interna y una posible 

autoignición o explosión debido a calor extremo. 

6. MEDIDAS APLICABLES EN CASO DE DERRAME ACCIDENTAL 

Elimine las fuentes de ignición. Ventile el área y elimine con un absorbente inerte. Los residuos de este producto podrían ser peligrosos según se definen en 40 CFR 261 de la RCRA (Ley de 

Conservación y Recuperación de Recursos). Para determinar el número correspondiente a residuo peligroso según EPA, deberá analizarse los residuos en cuanto a su inflamabilidad. Obedezca 

todos los reglamentos federales, estatales y locales relativos a la disposición final de residuos. 

7. MANIPULACIÓN Y ALMACENAMIENTO 

Mantenga alejado de objetos calientes, llamas, chispas y otras fuentes de ignición. Consulte el Código NFPA. Utilice procedimientos apropiados de conexión y de contacto a tierra. Contenido 

bajo presión. No perfore, incinere ni exponga a temperaturas superiores a los 120 °F (49 °C). El calor proveniente de luz solar, radiadores, hornallas, agua caliente y otras fuentes de calor, 

podría hacer explotar los recipientes. No ingerir. El mal uso intencional (concentración e inhalación deliberada de las emanaciones del contenido) puede resultar nocivo o fatal. Mantenga fuera 

del alcance de los niños. Use únicamente con la ventilación adecuada. Evite inhalar las emanaciones y el producto atomizado. Evite el contacto con los ojos y la piel. Lávese las manos luego de 

manipular este producto. 

8. CONTROL DE EXPOSICIÓN / PROTECCIÓN PERSONAL 

Controles de ingeniería: Se recomienda usar ventilación local. La ventilación general resulta aceptable si la exposición a este producto se mantiene por debajo de los límites de exposición 

permitidos. 

Equipo de protección personal: 

Respiratorio:Si la ventilación no fuera suficiente como para controlar la exposición personal por debajo de los niveles requeridos, use equipo para respirar efectivo contra vapores 

orgánicos/partículas aprobado por NIOSH. 

Ojos: Use anteojos de seguridad (aprobados por la autoridad competente) que cuenten con protección lateral sin perforaciones.

Piel: No es necesario durante la aplicación normal de productos en aerosol, cuando se espera que el contacto con la piel sea mínimo. Si el contacto fuera prolongado o 

repetido, use guantes resistentes a productos químicos. 

Otros: Una estación del eyewash de la emergencia o una fuente del agua potable limpia debe estar disponible en caso de que del contacto visual accidental.ra ojos. 

9. PROPIEDADES FÍSICAS Y QUÍMICAS 

Aspecto: Cobre. Olor: Solvente. 

Estado de agregación: Aerosol líquido. pH: NA 

Peso del producto: 2.74 kg/galón; 724 g/L. Peso específico: 0.73 

Pto. ebullición: < 0 - 212°F; < -18°C a 100°C Porcentaje de volátiles: 81% 

Pto. fusión: NA Densidad de vapor: Más pesado que el aire. 

Velocidad de evaporación: Más rápida que la del éter. Solubilidad en agua: NA 

Presión de vapor a 70 °F: NA Contenido de VOC: 70.00% (menos los solventes exentos por ley federal) 

10. ESTABILIDAD Y REACTIVIDAD 

Estabilidad: Estable. 

Polimerización peligrosa: No se producirá. 

Condiciones a evitar: Objetos calientes, chispas, llamas y otras fuentes de ignición. 

Incompatibilidad: No se espera que se produzca. 

Productos de descomposición peligrosos: durante un incendio: Dióxido de carbono, monóxido de carbono. 

11. INFORMACIÓN TOXICOLÓGICA 

Ningún componente de este producto figura en la lista de carcinógenos de IARC, NTP u OSHA. 

Componentes peligrosos Núm. CAS LD50 LC50 

Propano 74-98-6 NE NE 

Butano 106-97-8 NE 658 mg/l/4 hr (rat) 

Heptano 142-82-5 4 mg/l/24 hr (goldfish) 4924 mg/l/24-96 hr (mosquito fish) 

Aceite mineral paraffinic 8042-47-5 NE NE 

Aceite de parafina 64742-62-7 NE NE 

Destilados del petróleo 64742-65-0 NE NE 

Grafito 7782-42-5 NE NE 

Cobre 7440-50-8 NE NE 

12. INFORMACIÓN ECOLÓGICA 

NA 

13. SUGERENCIAS PARA SU DISPOSICIÓN FINAL 

No incinere. Despresurice el recipiente. Obedezca todos los reglamentos federales, estatales y locales relativos a contaminación y disposición final de residuos. Producto según lo formulado en 

una basura ignitable sin especificar D001. 

14. INFORMACIÓN SOBRE TRANSPORTE 

Datos del embarque según el DOT (Ministerio de Transporte de los EE.UU.): Producto para el consumidor, ORM-D. 

TDG canadiense: Envíos de acuerdo con 49 CFR como parte de un envío que cruce la frontera autorizado según el Artículo 5.2 (1) de la Ley Canadiense de Transporte de Productos Peligrosos. 

Para los envíos internacionales de Air: Aerosoles, Inflamables, 2.1, UN1950. 

Para los envíos internacionales de Vessel: Aerosoles, Inflamables, 2.1, UN1950, cantidad limitada 

15. INFORMACIÓN SOBRE REGLAMENTOS 

TSCA: Todos los componentes de este producto figuran en la lista de inventario de sustancias químicas de TSCA o están exentas de ese requisito. 

CEPA: Todos los componentes de este producto figuran en la lista canadiense DSL/NDSL o están exentos de ese requisito. 

Propuesta 65: Este producto podría contener trazas de las siguientes sustancias químicas que el Estado de California considera que producen cáncer y defectos congénitos, o que 

afectan negativamente la reproducción: 

Benceno 71-43-2 0.0009% 

Tolueno 108-88-3 0.0435% 

SARA 313: Este producto contiene las siguientes sustancias tóxicas sujetas a los requisitos de información del Artículo 313 de la ley de 1986 (40 CFR 372.65C) de Planeamiento 

ante emergencias y Derecho a Estar Informado de la Comunidad: 

Compuesto con cobre 7440-50-8 8% 

Clasificación HMIS: Salud = 2 Inflamabilidad = 4 Reactividad = 0 Equipo de protección personal = B 

Clasificación WHMIS: Clase A; Clase B, División 5; Clase D, División 2B 

16. OTRA INFORMACIÓN 

NA = No disponible o No se aplica. 

NE = No se ha establecido 

Antes de utilizar este producto, lea y obedezca todas las instrucciones y precauciones que figuran en la etiqueta. Este producto es sólo para uso industrial y en establecimientos 

públicos o comerciales. NO ES PARA REVENTA NI PARA USO EN EL ÁMBITO HOGAREÑO. Si bien se considera que los datos contenidos en esta planilla son correctos y que 

las opiniones expresadas son las de calificados expertos, los datos no deberán considerarse como garantía ni como declaración por las que la compañía asuma responsabilidad legal 

alguna. Estos datos se brindan sólo para evaluación, investigación y verificación por parte del cliente. El usuario es quien deberá determinar si cualquier uso que se dé a estos datos e 

información está de acuerdo con las leyes y reglamentos federales, estatales y locales aplicables. 

INFORMACIÓN DE SEGURIDAD Y SALUD: (216) 861-7114 

Preparado Encendido: Octubre 2008 Reemplaza: Octubre 2005 Preparada por: Especialista en reglamentos.

Material Safety Data Sheet HMIS 

May be used to comply with OSHA's 

Hazard Communication Standard, 

HEALTH 

29 CFR 1910.1200. Standard must be 

consulted for specific requirements. 

FLAMMABILITY 

Identity (As Used on Label and List) 

42201, 42210, 42230, 42236, 42272 

Rough Touch® Scrubs in - a - Bucket® 

SECTION I 

Manufacturer's Name 

ITW Dymon 

Address (Number, Street, City, State, and ZIP Code) 

805 East Old 56 Highway 

1 

1 

REACTIVITY 

PERSONAL PROTECTION 

Note: Blank spaces are not permitted. If any item is not applicable, or no 

information is available, the space must be marked to indicate that. 

Olathe, Kansas 66061 

SECTION II - Hazardous Ingredients/Identity 

Information 

Emergency Telephone Number 

1-800-535-5053 

Telephone Number for Information 

1-913-397-9889 

Date Prepared 

August 16, 2007 

Signature of Preparer (Optional) 

Regulatory Dept. 

Hazardous Components (Specific Other Limits 

Chemical Identity, Common Name(s)) CAS No. OSHA PEL ACGIH- 

TLV 

Recommended % (Opt.) 

This product is not known to contain any compound in concentrations requiring reporting under SARA Title III Section 313. 

TSCA: All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory. 

Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio, Pennsylvania or 

Texas is described above if known present in regulated concentrations. 

SECTION III Physical/Chemical Characteristics 

Boiling Point 

Initial >200 o F 

Specific Gravity (H2O = 1) 

@70o F 

Vapor Pressure (mm-Hg @ 70o F) 

No Data 

Melting Point 

Vapor Density (AIR = 1) Greater than 

one (1) 

Evaporation Rate (Butyl Acetate = 1) 

Solubility in Water 

Appearance and Odor - 

Dispersible 

pH 

Opaque white liquid with a fresh citrus scent saturated onto towels. 

SECTION IV - Fire and Explosion Hazard Data 

Flash Point (Method Used) 

Flammable Limits 

LEL 

None to boiling (TCC) Solution on Towel 

No Data 

No Data 

Extinguishing Media - 

Use carbon dioxide, dry chemical, foam, fog or water spray. 

Special Fire Fighting Procedures - 

Keep containers cool and vapors down with water spray. Prevent runoff from entering sewers and public waterways. Wear SCBA in 

chemical fires. 

Unusual Fire and Explosion Hazards - 

None known. 

0.982 

No Data 

No Data 

0 

7.4 + 0.5 

None 

UEL 

No Data

42201, 42210, 42230, 42236, 42272 August 16, 2007 

SECTION V - Reactivity Data 

Stability Unstable Conditions to Avoid - None known 

Stable X 

Incompatibility (Materials to Avoid) - 

Strong oxidizers and acids. 

Hazardous Decomposition or Byproducts - 

Carbon dioxide, carbon monoxide, hydrogen sulfide, sulfur dioxide, smoke and soot. 

Hazardous May Occur Conditions to Avoid - None known 

Polymerization Will Not Occur X 

SECTION VI - Health Hazard Data 

Route(s) of Entry Eyes? 

Inhalation? 

Skin? 

Ingestion? 

Yes 

No 

No 

Yes 

Health Hazards (Acute and Chronic) - 

Caution. Towel may cause eye irritation. 


NTP? 

IARC Monographs? OSHA Regulated? 

None known 

No 

No 

No 

Signs and Symptoms of Exposure - 

Redness, tearing or burning in eyes. Irritation of the throat or stomach, nausea, vomiting, and diarrhea if swallowed. 

Medical Conditions Generally Aggravated by Exposure - 

Pre-existing skin conditions such as dermatitis may be adversely affected by this and other oil and grease effective cleaners. 

Emergency and First Aid Procedures: 

Eyes - Flush with plenty of water for at least 15 minutes lifting eyelids to insure complete removal. See a physician 

immediately. Ingestion - Not a likely exposure route. If a large quantity of liquid is swallowed, do not induce vomiting, call a 

physician or poison control center immediately. Inhalation - Unlikely route as liquid is impregnated on a towel, minimizing 

exposure via this route. Skin - None usually required. Material is designed for skin cleansing. 

SECTION VII - Precautions for Safe Handling and Use 

Steps to be Taken in Case Material is Released or Spilled - Caution, slip hazard. Wipe up small releases with a dry absorbent 

cloth. For large releases, prevent material from entering sewers or drains. Ventilate area and block traffic. Pick up and put in suitable 

container for proper disposal. 

Waste Disposal Method - 

Consult local, state, and federal regulations. Discard empty container or offer for recycling or reuse. 

Precautions to be Taken in Handling and Storing - Do not allow towel contact with eyes. For external use only. Not for use 

around the mouth or eyes for an extended period of time. Do not smoke while using. Do not contaminate water, food or feed by use or 

storage. 

Other Precautions - Follow label directions carefully. Keep away from heat sources. Keep out of reach of children. Keep container 

tightly sealed when not in use. 

SECTION VIII - Control Measures 

Respiratory Protection (Specify Type) 

Not usually necessary. Use with adequate ventilation. Use NIOSH/MSHA approved respirator if PELs or TLVs are exceeded. 

Ventilation Local Exhaust Not usually needed Special None 

Mechanical (General) Acceptable Other None 

Protective Gloves - 

Eye Protection - 

Not necessary 

Not necessary 

Other Protective Clothing or Equipment - 

Not usually necessary. 

Work/Hygienic Practices - 

Normal. Use to wash hands before eating, drinking, smoking, using restrooms, etc. 

WARNING! The use of this product is beyond the control of the manufacturer; therefore, no guarantee, expressed or implied, is made as to the effects of such or the results to be obtained if not used in accordance with directions or established safe 

practice. The user must assume all responsibility, including injury or damage, resulting from its misuse as such, or in combination with other materials. 

The manufacturer warrants only that this product meets the manufacturer's specifications for such product. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO DESCRIPTION , QUALITY, MERCHANTABILITY. FITNESS FOR ANY PARTICULAR 

PURPOSE, PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS PRODUCT. THE MANUFACTURER SHALL BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT. The sole and exclusive remedy against the manufacturer for breach of warranty shall be 

reimbursement of the purchase price of the product in the event that a defective condition of the product shall be found to exist. NO OTHER REMEDY (INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR PROPERTY OR 

ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE.



Page: 1 of 8 

Version: 1.3 


DOW CORNING(R) GENERAL PURPOSE SILICONE SEALANT CLEAR 


Dow Corning Corporation 

South Saginaw Road 

Midland, Michigan 48686 

24 Hour Emergency Telephone: 

Customer Service: 

Product Disposal Information: 

CHEMTREC: 

(989) 496-5900 

(989) 496-6000 

(989) 496-6315 

(800) 424-9300 

MSDS No.: 04036588 Revision Date: 2011/01/24 

Generic Description: Silicone elastomer 

Physical Form: Paste 

Color: Colorless 

Odor: Acetic acid odor 

Note: NFPA = National Fire Protection Association 


Acute Effects 

NFPA Profile: Health 1 Flammability 1 Instability/Reactivity 0 


Eye: Direct contact may cause mild irritation. 

Skin: May cause mild irritation. 

Inhalation: Irritates respiratory passages very slightly. Overexposure by inhalation may cause 

drowsiness, dizziness, confusion or loss of coordination. 

Oral: Low ingestion hazard in normal use. 

Prolonged/Repeated Exposure Effects 

Skin: Repeated or prolonged contact may cause defatting and drying of skin which may result in 

skin irritation and dermatitis. 

Inhalation: No known applicable information. 

Oral: No known applicable information. 

Signs and Symptoms of Overexposure 


Medical Conditions Aggravated by Exposure



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Version: 1.3 




The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, 

component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 



64742-47-8 10.0 - 30.0 Hydrotreated light petroleum distillate 

17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane 

4253-34-3 1.0 - 5.0 Methyltriacetoxysilane 

The above components are hazardous as defined in 29 CFR 1910.1200. 


Eye: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes 

while holding the eyelid(s) open. Obtain medical attention. 

Skin: Remove contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Quickly 

and gently blot or brush away excess chemical. Flush with lukewarm gently flowing water for 

15 minutes. If irritation persists, repeat flushing. If irritation persists, obtain medical advice. 

Inhalation: Remove from the source of contamination or move to fresh air. If irritation persists, obtain 

medical advice. 

Oral: If irritation or discomfort occur, obtain medical advice. 

Notes to Physician: Treat according to person's condition and specifics of exposure. 





Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide 

(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.



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Version: 1.3 



Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large 

fires involving chemicals. Determine the need to evacuate or isolate the area according to 

your local emergency plan. Use water spray to keep fire exposed containers cool. 

Unusual Fire Hazards: None. 


Containment/Clean up: Observe all personal protection equipment recommendations described in Sections 5 and 8. 

Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since 

spilled materials, even in small quantities, may present a slip hazard. Final cleaning may 

require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning 

materials appropriately, since spontaneous heating may occur. Local, state and federal laws 

and regulations may apply to releases and disposal of this material, as well as those materials 

and items employed in the cleanup of releases. You will need to determine which federal, 

state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide 

information regarding certain federal and state requirements. 

Note: See Section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is 

required. 


Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide 

ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid 

skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep container closed. 

Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or 

moisture. This material in its finely divided form presents an explosion hazard. Follow NFPA 654 (for chemical dusts) or 

484 (for metal dusts) as appropriate for managing dust hazards to minimize secondary explosion potential. 


Component Exposure Limits 

CAS Number Component Name Exposure Limits 

64742-47-8 Hydrotreated light petroleum distillate Observe petroleum distillates limits. OSHA PEL (final rule): 

TWA 400 ppm. 

17689-77-9 Ethyltriacetoxysilane See acetic acid comments. 

4253-34-3 Methyltriacetoxysilane See acetic acid comments.



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Version: 1.3 



Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within 

guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm. 

Engineering Controls 

Local Ventilation: Recommended. 

General Ventilation: Recommended. 

Personal Protective Equipment for Routine Handling 

Eyes: Use proper protection - safety glasses as a minimum. 

Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as 

soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are 

recommended. 

Suitable Gloves: Avoid skin contact by implementing good industrial hygiene practices and procedures. Select 

and use gloves and/or protective clothing to further minimize the potential for skin contact. 

Consult with your glove and/or personnel protective equipment manufacturer for selection of 

appropriate compatible materials. 

Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure 

assessment demonstrates that exposures are within recommended exposure guidelines. IH 

personnel can assist in judging the adequacy of existing engineering controls. 

Suitable Respirator: General and local exhaust ventilation is recommended to maintain vapor exposures below 

recommended limits. Where concentrations are above recommended limits or are unknown, 

appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 

CFR 1910.134) and use NIOSH/MSHA approved respirators. 

Personal Protective Equipment for Spills 

Eyes: Use full face respirator. 

Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as 

soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are 

recommended. 

Inhalation/Suitable 

Respirator: 

Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR 

1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air purifying 

respirators against exposure to any hazardous chemical is limited. Use a positive pressure air 

supplied respirator if there is any potential for uncontrolled release, exposure levels are 

unknown, or any other circumstance where air purifying respirators may not provide adequate 

protection. 

Precautionary Measures: Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep 

container closed. Use reasonable care.



Page: 5 of 8 

Version: 1.3 



Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation 

during use to control HOAc within exposure guidelines or use respiratory protection. 

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require 

added precautions. 


Physical Form: Paste 

Color: Colorless 

Odor: Acetic acid odor 

Specific Gravity @ 25°C: 0.99 

Viscosity: Not determined. 

Freezing/Melting Point: Not determined. 

Boiling Point: Not determined. 

Vapor Pressure @ 25°C: Not determined. 

Vapor Density: Not determined. 

Solubility in Water: Not determined. 


Volatile Content: Not determined. 




Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing 

specifications. 


Chemical Stability: Stable. 

Hazardous 


Hazardous polymerization will not occur. 

Conditions to Avoid: None. 

Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous 

vapors to form as described in Section 8. 

Hazardous Decomposition Products 

Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition 

products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. 


Special Hazard Information on Components



Page: 6 of 8 

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Environmental Fate and Distribution 


Environmental Effects 


Fate and Effects in Waste Water Treatment Plants 


Ecotoxicity Classification Criteria 

Hazard Parameters (LC50 or EC50) High Medium Low 

Acute Aquatic Toxicity (mg/L) 1 and 100 

Acute Terrestrial Toxicity 100 and 2000 

This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993. 

This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the 

section concerning the overall ecological safety of this material. 


RCRA Hazard Class (40 CFR 261) 

When a decision is made to discard this material, as received, is it classified as a hazardous waste? NOT ASSESSED 

State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional 

information is required. 


DOT Road Shipment Information (49 CFR 172.101) 

Not subject to DOT. 

Ocean Shipment (IMDG) 

Not subject to IMDG code. 

Air Shipment (IATA)



Page: 7 of 8 

Version: 1.3 



Not subject to IATA regulations. 

Call Dow Corning Transportation, (989) 496-8577, if additional information is required. 


Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. 

TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA 

Inventory of Chemical Substances. 

EPA SARA Title III Chemical Listings 

Section 302 Extremely Hazardous Substances (40 CFR 355): 

None. 

Section 304 CERCLA Hazardous Substances (40 CFR 302): 

None. 

Section 311/312 Hazard Class (40 CFR 370): 

Acute: Yes 

Chronic: No 

Fire: No 

Pressure: No 

Reactive: No 

Section 313 Toxic Chemicals (40 CFR 372): 

None present or none present in regulated quantities. 

Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold. 

Supplemental State Compliance Information 

California 

Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water 

and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other 


None known. 

Massachusetts 

No ingredient regulated by MA Right-to-Know Law present. 

New Jersey



Page: 8 of 8 

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70131-67-8 70.0 - 90.0 Dimethyl siloxane, hydroxy-terminated 


112945-52-5 5.0 - 10.0 Amorphous fumed silica 

17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane 

4253-34-3 1.0 - 5.0 Methyltriacetoxysilane 

Pennsylvania 


70131-67-8 70.0 - 90.0 Dimethyl siloxane, hydroxy-terminated 


112945-52-5 5.0 - 10.0 Amorphous fumed silica 


Prepared by: Dow Corning Corporation 

These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or 

implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally 

applicable. However, each user should review these recommendations in the specific context of the intended use and 

determine whether they are appropriate. 

(R) indicates Registered Trademark

Spitfire RTU Power Cleaner 

HMIS 

NFPA Personal protective equipment 

Health 1 

1 None / Aucune / Ninguno 

Fire Hazard 0 

0 

Reactivity 0 

0 

Version Number: 2 

Product name: 

MSDS #: 

Product Code: 

Recommended use: 



MS0300470 

03702, 03724 

Heavy-Duty Alkaline Cleaner. This product is intended to be used neat . 

Manufacturer, importer, supplier: 

US Headquarters 

Diversey, Inc. 

8310 16th St. 

Sturtevant, Wisconsin 53177-1964 

Phone: 1-888-352-2249 

MSDS Internet Address: www.diversey.com 

Emergency telephone number: 1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l) 



CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN. 

Principal routes of exposure: Eye contact. Skin contact. Inhalation. 

Eye contact: May be mildly irritating to eyes. 

Skin contact: May be mildly irritating to skin. 

Inhalation: None 

Ingestion: None known. 



Preparation date: 2011-03-16 

Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation - 

(mg/kg) 

Rabbit 

Rat 

Benzyl alcohol 100-51-6 0.1 - 1.5% 1230 =2000 mg/kg =8.8 mg/L (4 h) 

2-butoxyethanol 111-76-2 0.1 - 1.5% 470 =220 mg/kg =2.21 mg/L (4 h) 

=450 ppm (4 h) 

Monoethanolamine 141-43-5 0.1 - 1.5% 1720 =1 mL/kg =1025 

mg/kg 

Not available 


Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention. 

Skin contact: Flush immediately with plenty of water. If irritation develops, get medical attention. 

Inhalation: No specific first aid measures are required. 

Ingestion: No specific first aid measures are required. 

Aggravated Medical Conditions: None known 


Canadian Headquarters 

Diversey, Inc. - Canada, Inc. 

2401 Bristol Circle 

Oakville, Ontario L6H 6P1 

Phone: 1-800-668-3131 

1 of 4

Suitable extinguishing media: 

Specific hazards: 

Unusual hazards: 

Specific methods: 

The product is not flammable. Extinguish fire using agent suitable for surrounding fire. 

Not applicable 

None known 

No special methods required 

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH 

(approved or equivalent) and full protective gear 

Extinguishing media which must not be used for safety reasons: No information available 

Personal precautions: 

Environmental precautions 

and clean-up methods: 


Not relevant for the product itself. 

Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in 

a chemical waste container. Use a water rinse for final clean-up. 


Handling: 

Avoid contact with skin and eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. 

Storage: 

Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. 

Engineering measures to reduce exposure: 

No special ventilation requirements General room ventilation is adequate 


Personal Protective Equipment 

Eye protection: No special requirements under normal use conditions. 

Hand protection: No special requirements under normal use conditions 

Skin and body protection: No special requirements under normal use conditions. 

Respiratory protection: No special requirements under normal use conditions. 

Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. 

Ingredient(s) CAS # ACGIH OSHA Mexico 

2-butoxyethanol 111-76-2 20 ppm (TWA) Skin 50 ppm (TWA) 240 

mg/m 3 (TWA) 

Monoethanolamine 141-43-5 6 ppm (STEL) 3 ppm (TWA) 3 ppm (TWA) 6 mg/m 3 

(TWA) 


Appearance: Aqueous solution 

Specific gravity: 1.01 

Vapor density: No information available 

Boiling point/range: Not determined 

Decomposition temperature: Not determined 

Solubility: Completely Soluble 

Solubility in other solvents: No information available 

Partition coefficient (n-octanol/water): No information available 

Elemental Phosphorus: 0.00 % by wt. 

pH: 11.3 

Explosion limits: - upper: Not determined - lower: Not determined 



Bulk density: No information available 

Evaporation Rate No information available 

Color: Clear Red 

Odor: Fresh Pine 

Melting point/range: Not determined 

Autoignition temperature: No information available 

Density: 8.42 lbs/gal 1.01 Kg/L 

Flash point: > 200 °F > 93.4 °C 

Viscosity:No information available 

VOC: 2 % * 

Dilution pH: 11.3 @ RTU 

* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 



75 ppm (STEL) 360 mg/m3 (STEL) 26 ppm (TWA) 120 

mg/m3 (TWA) 

6 ppm (STEL) 15 mg/m3 (STEL) 3 ppm (TWA) 8 

mg/m3 (TWA) 

2 of 4

Stability: 


Hazardous decomposition products: 

Materials to avoid: 


Component Information: 

Chronic toxicity: 

Specific effects 

Carcinogenic effects: None known 

Mutagenic effects: 

None known 

Reproductive toxicity: None known 

Target organ effects: None known 

Environmental Information: No data available 

The product is stable 

Hazardous polymerization does not occur 

None reasonably foreseeable. 

Acids. Strong oxidising agents. 

Waste from residues / unused products: 

Dispose of according to all federal, state and local applicable regulations 

Oral LD50 estimated to be greater than 5000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg. 

See Section 3 


U.S. Regulations 

California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 

RIGHT TO KNOW (RTK) 

Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK: 

Benzyl alcohol 100-51-6 X - X - 

2-butoxyethanol 111-76-2 X X X X 

Sodium xylene sulfonate 1300-72-7 - - - - 

Monoethanolamine 141-43-5 X X X X 

Water 7732-18-5 - - - - 

CERCLA/ SARA 

Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313 

2-butoxyethanol 111-76-2 0.1 - 1.5% X 

Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants 

2-butoxyethanol X 

SARA 311/312 Hazard Categories 

Immediate: - 

Delayed: - 

Fire: - 

Reactivity: - 


None known 


DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 


International Inventories at CAS# Level 

All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). 



3 of 4

Sudden Release of Pressure: 

Canada 

WHMIS hazard class: Non-controlled 

- 


Reason for revision: Not applicable 

Prepared by: 

NAPRAC 

Additional advice: Contains an added fragrance, see "Odor" heading in section 9 for specific description. 

Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, 

express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is 

responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and 

Local laws and regulations. 


4 of 4

MSDS - KP1099 

Click here to go back to MSDS 

Barnes Distribution 

1301 E. 9th Street, #700 

Cleveland OH 44114 

(800) 726-9626 

MSDS Form No. : KP1099 

Item No. : KP1099, KP1099S, 1099 

**** MATERIAL SAFETY DATA SHEET **** 

CARB & CHOKE CLEANER 

Part # KP1099 

**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION **** 

MSDS Name: CARB & CHOKE CLEANER 

Product CAS: (none) 

Product Code: 

Synonyms: 1099; 1099-55; CARB & CHOKE CLEANER; KP1099; KP1099-55; KP1099S 

Company Identification: 

Name: KAR PRODUCTS 

Address: 461 N. THIRD AVE. 

Address: 

City: DES PLAINES State: IL Zip: 60016 

For information, call: 847-296-6111 

Emergency Number: 800-752-7869 

Emergency Agency: 

Number: 

MSDS Creation Date: 7/1/2003 

Supersedes Date: 

Miscellaneous: 

**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** 

Chemical Name CAS MIN MAX 

METHANOL 67-56-1 10 20 

ACETONE 67-64-1 20 40 

METHYL ETHYL KETONE 78-93-3 5 15 

XYLENE 1330-20-7 25 40 

ETHYLENE GLYCOL MONO BUTYL ETHER 111-76-2 1 5 


ITEM OSHA PEL ACGHI TLV OTHER LIMITS 

Page 1 of 6 


http://www.karproducts.com/website/msds.nsf/82fc0a594c19550485256dba004ed923/c64... 

12/2/2004


1 NA 200 PPM NA 

2 1000 PPM 750 PPM NA 

3 200 PPM 200 PPM NA 

4 100 PPM 100 PPM NA 

5 50 PPM 25 PPM NA 

Lbs of VOC per Gallon Coating (minus water): 0 

Coating Density (lbs/gal): 0 

Solvent Density (lbs/gal): 0 

Percent Solvent (volume): 0 

Percent Solids (volume): 0 

Percent Water (volume): 0 

**** SECTION 3 - HAZARDS IDENTIFICATION **** 

NFPA: Health: 2 Fire: 4 Reactivity: 0 Other: 

HMIS: Health: 1 Fire: 2 Reactivity: 0 Special Protection: 


Target Organs: 

Eye: 

MAY CAUSE REDNESS AND BURNING. 

Skin: 

WILL CAUSE DEFATTING OF THE SKIN. 

Ingestion: 

A PRIMARY ROUTE OF ENTRY. HEALTH HAZARDS (ACUTE AND CHRONIC): GENERATED MISTS MAY 

BE SEVERELY 

IRRITATING AND CAUSE DAMANGE TO RESPOIRATORY TRACT IF SWALLOWED.HARMFUL OR FATAL IF 

SWALLOWED. 

Inhalation: 


LONG TER EXPOSURE YEARS TO VAPOR MAY CAUSE LUNG, LIVER, OR KIDNEY DAMAGE. THE 

SOLVENTS LISTED 

HAVE BEEN REPORTED TO AFFECT THE CENTRAL NERVOUSE SYSTEM: XYLENE, METHANOL, METHYL 

ETHYL 

KETONE, ACETONE. 

**** SECTION 4 - FIRST AID MEASURES **** 

Eye: 

WASH EYES WITH WATER FOR LEAST 15 MIN AND CALL A PHYSICIAN IMMEDIATELY. 


Page 2 of 6 

12/2/2004


Skin: 

WASH SKIN WITH LARGE AMOUNTS OF SOAP AND WATER. IF IRRITATION PERSISTS CALL 

PHYSICIAN. 

Ingestion: 

DO NOT INDUCE VOMITING. CALL PHYSICIAN IMMEDIATELY. 

Inhalation: 

REMOVE TO FRESH AIR. START ARTIFICAL RESPIRATION IF NECESSARY. OXYGEN MAY BE 

ADMINISTERED. CALL 

A PHYSICIAN. 

Notes to Physician: 


IF YOU HAVE A MEDICAL CONDITION CONSULT WITH A PHYSICIAN PRIOR TO USING THIS 

PRODUCT. 

Unusual Fire and Explosion Hazards: 

HEATED CANS MAY BURST. 

**** SECTION 5 - FIRE FIGHTING MEASURES **** 

Special Fire Fighting Procedures: 

FIREFIGHTERS SHOULD WEAR NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATING 

APPARATUS. 

CANS MAY RUPTURE WHEN HEATED. 

Extinguishing Media: 

USE WATER FOG, DRY CHEMICAL OR CARBON DIOXIDE. 

Flash Point: 

NA 

Flammable Limits: 

Lower Limit: 

NA 

Upper Limit: 

NA 

AutoIgnition Temperature: 

NA 

General Information: 

FLAMMABLE LIMITS: NOT DETERMINED 

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** 

Disposal: 

DISPOSE AS HAZARDOUS WASTE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL 

REQUIREMENTS. 

Spills/Leaks: 

SAFELY STOP SPILL AT SOURCE. CONTAIN SPILL BY DIKING WITH SOIL OR OTHER INERT 


Page 3 of 6 

12/2/2004


MATERIAL AND 

CAREFULLY NEUTRALIZE WITH DILUTE ACID. MOP, PUMP OR ABSORB WITH INERT MATERIAL AND 

RECLAIM INTO 

SOUND CONTAINERS FOR PROPER DISPOSAL. 

Handling: 

KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME. 

Storage: 

STORE AT TEMPERATURES BELOW 120 F. 

Engineering Controls: 

LOCAL EXHAUST: YES 

MECHANICAL (GENERAL): NONE 

SPECIAL VENTILATION: NONE 

OTHER VENTILATION: NONE 

**** SECTION 7 - HANDLING and STORAGE **** 

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION **** 

Eyes: 

WEAR EYE PROTECTION. WEAR GLASSES OR GOGGLES. 

Skin: 

PROTECTIVE GLOVES: NONE REQUIRED IF SPRAYING. 

Clothing: 

LONG SLEEVE AND LONG PANTS. 

Respirators: 

SELF CONTAINED BREATHING APPARATUS IF ABOVE TLV LIMIT EXCEEDING. 

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES **** 

Appearance/Odor: 

CLEAR LIQUID WITH CHARACTERISTIC SOLVENT ODOR. 

pH: NA 

Vapor Pressure: MM HG: 140MM HG AT 70 DEG F 

Vapor Density: HEAVIER 

Evaporation Rate: FASTER 

Viscosity: 

Boiling Point: 133.0 DEG F 

Freezing/Melting Point: NA 

Decomposition Temperature: 

Solubility: IN WATER: NEGLIGIBLE 

Specific Gravity: .85 

Molecular Formula: N/A 

Molecular Weight: 


% VOLATILE/VOLUME: NO DATA 


Page 4 of 6 

12/2/2004


Chemical Stability: 

STABLE: YES 

Conditions to Avoid: 

HEAT, SPARKS AND OPEN FLAMES. 

Incompatibilities with Other Materials: 

STRONG ACIDS OR BASES, OXIDIZING AGENTS. 

**** SECTION 10 - STABILITY AND REACTIVITY **** 


IN FIRE, WATER, CARBON DIOXIDE, CARBON MONOXIDE, PRODUCTS OF INCOMPLETE COMBUSTION. 

Hazardous Polymerization: 

MAY OCCUR: NO 

**** SECTION 11 - TOXICOLOGICAL INFORMATION **** 

Toxicological Information: 

NEW JERSEY RIGHT-TO-KNOW: METHANOL, METHYL ETHYL KETONE, 2-BUTOXYETHANOL, ACETONE, 

XYLENE. 

WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO 

CAUSE CANCER 

AND BIRTH DEFECTS OR OTHER REPPRODUCTIVE HARM. 

Ecological Information: 

**** SECTION 12 - ECOLOGICAL INFORMATION **** 

**** SECTION 13 - OTHER PRECAUTIONS **** 

Other Precautions: 

WHEN SPRAYING MORE THAN ONE HALF CAN CONTINUOUSLY OR MORE THAN ONE CAN 

CONSECUTIVELY, USE NIOSH 

APPROVED RESPIRATOR. 

Work/Hygienic Practices: 

DO NOT SMOKE WHILE USING. WASH HANDS AFTER USE. 

Transportation Information: 

**** SECTION 14 - TRANSPORT INFORMATION **** 


Page 5 of 6 

12/2/2004


Label Information: 

Regulatory Information: 

Additional Information: 

**** SECTION 15 - REGULATORY INFORMATION **** 

**** SECTION 16 - ADDITIONAL INFORMATION **** 


Page 6 of 6 

12/2/2004

PIRS: Material Safety Data Sheet 

MATERIAL SAFETY DATA SHEET: SUPER ELECTRA SAF AEROSOL 

(000000-000000- - 5491) 

Date of Issue: 

10/19/2004 12:00:00 AM 

Chemical Name & Synonyms: 

N/A 

Chemical Family: 

PETROLEUM/LIMONENE BLEND 

Manufacturer Name: 

MANTEK, DIVISION OF NCH CORP. 

Manufacturer Address: 

BOX 152170 

IRVING, TEXAS 75015 

Prepared By: 

M McDowell/Chemist 

Section I - General Information 

Product Code Number: 

5491 

Supercedes: 

4/16/2001 12:00:00 AM 

Trade Name & Synonyms: 

SUPER ELECTRA SAF AEROSOL 

Formula is a mixture: [√] 

Emergency Phone Number: 

800-424-9300 

Section II - Hazardous Ingredients 

THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS 

Chemical Name (Ingredients) Hazard TLV PEL STEL 

LIGHT ALKYLATE PETROLEUM NAPHTHA FLAM/IRR 100 PPM $1 500 PPM $2 N/E 

D-LIMONENE IRR/COMB N/E 1 N/E 2 N/E 

PROPANE FLAM/ASPHY 1000 PPM#1 1000PPM 2 N/E 

N-BUTANE FLAM/ASPHY 1000 PPM#1 N/E 2 N/E 

$ STODDARD SOLVENT 

# ALIPHATIC HYDROCARBON GASES 

Boiling Point (°F): 340° 

Section III - Physical Data 

Specific Gravity (H 2 0=1): 0.77 

Vapor Pressure (mm Hg): 1964 Color: COLORLESS 

Vapor Density (Air=1): 1.7 Odor: ORANGE 

pH @ 100% : N/E Clarity: TRANSPARENT 

% Volatile by Volume: 100 Evaporation Rate (BuAc=1): 37.8 

H 2 0 Solubility: NEGLIGIBLE Viscosity: NON-VISCOUS 

Section IV - Fire and Explosion Hazard 

Flash Point: 39°F Method Used: SETAFLASH 

Flammable Limits: PRODUCT MIXTURE UEL: 9.5 

LEL: 0.7 Aerosol Level (NFPA 30B): 3 


[√] Foam [ ] Alcohol Foam [√] CO2 

[√] Dry Chemical [√] Water Spray [ ] Other 

NFPA 704 Hazard Rating: 

4-Extreme 

3-High 

2-Moderate 

1-Slight 

0-Insignificant 

https://webpirs2006.nch.com/MSDS/MSDSView.aspx?cn=USA&co=MA&gn=5491... 

Strona 1 z 5 

Health: 2 

Flammability: 4 

Instability: 0 

Special: 

2007-05-19

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go to our website at 

http://www.bclcomputers.com


HIPS TO PREVENT PULMONARY ASPIRATION. IF COMATOSE, A CUFFED ENDOTRACHAEL TUBE WILL PREVENT 

ASPIRATION. 

Section VI - Toxicity Information 

Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By: 

[ ] IARC [ ] NTP [ ] OSHA [ ] ACGIH [ ] Other 

VOC CONTENT: 100% BY WEIGHT, 100% BY VOLUME, 719.0 G/L 

LIGHT ALKYLATE PETROLEUM NAPHTHA 

ORL-RAT TDLo: 10 GM/KG/4W-I 4. 

IHL-RAT TCLo: 7500 PPM/13W-I 4. 

HYDROCARBON MISTS DERIVED FROM HIGHLY REFINED PETROLEUM DISTILLATES ARE REPORTED TO HAVE LOW 

ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND SHORT-TERM REPEATED EXPOSURES TO 

HIGH CONCENTRATIONS WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY 

REACTION, LIPOID GRANULOMA FORMATION, AND LIPOID PNEUMONIA. IN ACUTE AND SUB-ACUTE STUDIES INVOLVING 

EXPOSURES TO LOWER CONCENTRATIONS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED NO 

SIGNIFICANT TOXICOLOGICAL EFFECTS. IN LONG TERM STUDIES (UP TO TWO YEARS) NO CARCINOGENIC EFFECTS 

HAVE BEEN REPORTED IN ANY ANIMAL SPECIES TESTED. THESE PETROLEUM DISTILLATES ARE SEVERELY 

HYDROTREATED, SEVERELY SOLVENT EXTRACTED, AND/OR PROCESSED BY MILD HYDROTREATMENT AND 

EXTRACTION. FOR THIS REASON, THEY ARE NOT CLASSIFIED AS CANCER HAZARDS. 3. 

D-LIMONENE 

ORL-RAT LD50: >5 G/KG 3. 

SKN-RBT LD50: >5 G/KG 3. 

SKN-RBT: SEVERELY IRRITATING 3. 

EYE-RBT: SEVERELY IRRITATING 3. 

PROPANE 

NO TOXICITY DATA AVAILABLE 

N-BUTANE 

IHL-RAT LC50: 658 G/M3/4H 4. 

IHL-MUS LC50: 680 G/M3/4H 4. 

Stability 

[√] Stable [ ] Unstable 


AVOID HEAT, HOT SURFACES, SPARKS, AND OPEN 

FLAMES. 

Section VII - Reactivity Data 

Hazardous Polymerization 

[√] Will not occur [ ] May occur 


N/A 

Incompatibility (Materials to Avoid): 

STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH AND CONCENTRATED HYDROGEN PEROXIDE; ACIDS, CLAYS, 

ALUMINUM CHLORIDE, HALOGENS, IODINE PENTAFLUORIDE, VINYL CHLORIDE, PLASTICS, AND RUBBER. 


OXIDES OF CARBON. 

Section VIII - Spill Or Leak Procedures 

Steps to be Taken if Material is Released or Spilled: 

DUE TO THE NATURE OF THE AEROSOL PACKAGING, A LARGE SPILL IS UNLIKELY. FOR A SMALL SPILL, WEAR 

APPROPRIATE PROTECTIVE CLOTHING, VENTILATE THE AREA, ABSORB WITH AN INERT MATERIAL AND TRANSFER ALL 

MATERIAL INTO A PROPERLY LABELED CONTAINER FOR DISPOSAL. USE CARE AS SPILLS MAY BE SLIPPERY. 

Waste Disposal Method(s): 

DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. TYPICAL DISPOSAL IS TO WRAP 

THE EMPTY AEROSOL CONTAINER IN SEVERAL LAYERS OF NEWSPAPER AND DISPOSE OF IN THE TRASH. AEROSOL 

RECYCLING PROGRAMS ARE AVAILABLE IN MANY AREAS. DO NOT PUNCTURE OR INCINERATE THIS CONTAINER. 

Neutralizing Agent: 


Strona 3 z 5 

2007-05-19

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OF GOVERNMENTAL INDUSTRIAL HYGIENISTS, TLV:THRESHOLD LIMIT VALUE, PEL:PERMISSIBLE EXPOSURE LIMIT, 

STEL:SHORT-TERM EXPOSURE LIMIT, MLD:MILD, MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC, ASPHYX:ASPHYXIANT 

PNOS:PARTICLES (INSOLUBLE) NOT OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST, ORL:ORAL, IHL:INHALATION, 

HMN:HUMAN 

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT 

FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR 

THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. 

MANTEK, DIVISION OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or 

disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such 

unrecommended use, storage, or disposal of the product. 

©2006 NCH Corporation All rights reserved. 


Strona 5 z 5 

2007-05-19

Product: TIN SOLDER ALLOY, 35294 

WOLVERINE JOINING TECHNOLOGIES, LLC. 


SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Common Name : TIN SOLDER ALLOY 

Chemical Name : TIN ALLOY 

Formula : Sn 

Product CAS No.: 7440-31-5 

Product Use : Welding/Brazing/Soldering 

Supplier : WOLVERINE JOINING TECHNOLOGIES, LLC. 

Address : 235 KILVERT STREET 

City, St, Zip : WARWICK, RI 02886 

Phone : 1-401-739-9550 

FOR CHEMICAL EMERGENCY CALL CHEMTREC (24 HOURS): 

1-800-424-9300 (US, Canada, Puerto Rico, Virgin Islands) 

1-703-527-3887 (Outside Above Area) 

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS 

INGREDIENT CAS NO. % Wt. 

TIN 

INGREDIENT NOTES 

7440-31-5 99.85 

Page 1 of 8 

Code: EI-35294 

Date: 21 MAR 2000 

Revised: 1 NOV 2010 

Printed: 1 NOV 2010 

NOTE: The percentage by weight values reported for the ingredients in 

this product represent approximate formulation values. 

NOTE: See Section 8 for Exposure Limits and Section 11 for 

Toxicological Information.


Grey to silver wire 

Odorless 

Flash Point: Not Determined 


May cause eye, skin and respiratory tract irritation. 

Harmful if large amounts are swallowed. May cause gastrointestinal 

irritation, abdominal pain, nausea, vomiting and diarrhea. 

Not a fire or explosion hazard in solid form. Finely divided dust may 

ignite and burn rapidly when mixed with air in the proper proportions. 

Toxic metal fumes may be released in a fire situation. 

ROUTES OF ENTRY 

Eyes? YES Skin? YES Inhalation? YES Ingestion? YES 


EYE CONTACT may cause irritation. 

SKIN CONTACT may cause irritation. 

INHALATION may cause irritation of the respiratory tract. Short-term 

overexposure may cause a flu-like illness called metal fume fever. 

Typically metal fume fever begins four to twelve hours after sufficient 

exposure to freshly formed fumes. The first symptoms are a metallic 

taste, dryness and irritation of the throat. Cough and shortness of 

breath may occur along with headache, fatigue, nausea, vomiting, muscle 

and joint pain, fever and chills. The syndrome runs its course in 24-48hrs. 

INGESTION of large amounts is harmful. May cause gastrointestinal 

irritation, abdominal pain, nausea, vomiting and diarrhea. 

NOTE: The potential health effects described above only apply if dust or 

fume is formed. 

CARCINOGENICITY 

NTP? NO IARC? NO OSHA? NO 

CHRONIC HEALTH HAZARDS 

Prolonged or repeated inhalation may cause a benign pneumoconiosis. 

Refer to Potential Health Effects. 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE 

None known. 

NOTE: See Section 8 for Exposure Limits, Section 11 for Toxicological 

Information and Section 12 for Ecological Information. 

Page 2 of 8


EYE CONTACT: Flush eyes with plenty of water. If irritation develops, 

call a physician. 

SKIN CONTACT: Immediately wash skin with soap and plenty of water. If 

irritation persists, call a physician. 

INHALATION: If exposed to excessive levels of metal fumes, remove to 

fresh air and seek medical attention. 

INGESTION: Procedures normally not needed. If large quantities are 

ingested, seek medical advice. 

Flash Point: Not Determined 

Auto-Ignition: Not Determined 

LEL: Not Determined 

UEL: Not Determined 

NFPA HAZARD CLASSIFICATION 

SECTION 5: FIRE-FIGHTING MEASURES 

Health: 1 Flammable: 0 Reactivity: 0 

HMIS HAZARD CLASSIFICATION 

Health: 1 Flammable: 0 Reactivity: 0 Special: B 

EXTINGUISHING MEDIA 

Use dry sand, soda ash, dolomite or other suitable dry powder. Do not 

apply water directly to burning material. Use water to keep 

fire-exposed containers cool. 


Wear NIOSH/MSHA approved positive-pressure self-contained breathing 

apparatus and protective clothing as specified in 29 CFR 1910.156. 


Not a fire or explosion hazard in solid form. Finely divided dust may 

ignite and burn rapidly when mixed with air in the proper proportions. 

Toxic metal fumes may be released in a fire situation. 


Contain spillage and scoop up or vacuum. Notification of the National 

Response Center (800/424-8802) may be required. Refer to EPA, DOT and 

applicable state and local regulations for current response information. 

It is recommended that each user establish a spill prevention, control 

and countermeasure plan (SPCC). Such plan should include procedures 

applicable to proper storage, control and clean-up of spills, including 

reuse or disposal as appropriate (see Section 13: Disposal 

Considerations). 

Page 3 of 8

**NOTE** In the event of an accidental release of this material, the 

above procedures should be followed. Additionally, proper exposure 

controls and personal protection equipment should be used (see Section 

8: Exposure Control/Personal Protection), and disposal of the material 

should be in accordance with Section 13: Disposal Considerations. 



Store in a cool, dry location away from incompatible materials. 

Avoid breathing any dust, mist or fumes resulting from the use of this 

product. 

Avoid contact with any dusts, mists or fumes resulting from the use of 

this product. 


Do not eat, drink, or smoke in work area. 


EXPOSURE LIMITS 

INGREDIENT PEL-OSHA TLV-ACGIH 

TIN 

CAS NO.: 7440-31-5 2 mg/m3 2 mg/m3 

NOTE: Both OSHA and the ACGIH list welding fumes as having an exposure 

limit of 5 mg/m3 (total particulate not otherwise classified). 

However, the ACGIH states that welding fumes must be tested frequently 

for individual components which are likely to be present to determine 

whether specific exposure limits are exceeded. 

NOTE: The permissible exposure limits (PELs), threshold limit values 

(TLVs), potential health effects statements and SARA hazard categories 

may not be applicable as the hazardous ingredients listed are in the 

solid form. If dust, powder or fume is generated then these statements 

will be applicable. 

Unless otherwise noted, all values are reported as 8-hour Time-Weighted 

Averages (TWAs) and total dust (particulates only). All ACGIH TLVs refer 

to the 1999 Standards. All OSHA PELs refer to 29 CFR Part 1910 Air 

Contaminants: Final Rule, January 19, 1989. 


If dust or fume is generated, a NIOSH/MSHA approved respirator may be 

necessary. Follow all requirements for respiratory programs and 

selection set forth in the OSHA regulations (29 CFR 1910.139). 

VENTILATION 

General; local exhaust ventilation as necessary to control any air 

contaminants to within their PELs or TLVs during the use of this 

product. 

Page 4 of 8

PROTECTIVE EQUIPMENT 

Safety glasses (with side shields). 

Body protection as necessary to prevent skin contact. 

Refer to ANSI/ASC Z49.1-94 (Safety in Welding, Cutting and Allied 

Processes), published by the American Welding Society, for further 

information on the selection of personal protective equipment. 

PERSONNEL SAMPLING PROCEDURE 

For TIN: Refer to NIOSH Manual of Analytical Methods (NMAM), 4th 

Edition, Method 7300. 


Appearance: Grey to silver wire 

Odor: Odorless 

Boiling Point: 2260 °C 

Specific Gravity (H2O=1): 7.28 

Melting Point: 232 °C 

Vapor Pressure (mm Hg): 1 mm Hg at 1610øC 

Vapor Density (Air=1): Not Applicable 

Evaporation Rate: Not Applicable 

% Solubility In Water: Insoluble 

pH: Not Applicable 


Stability: Generally considered stable. 

Avoid: None expected. 

INCOMPATIBILITY (Materials to Avoid) 

Acids, bases, oxidizers and halogens. 

Metal salts. 

HAZARDOUS DECOMPOSITION OR BY-PRODUCTS 

Toxic metal oxides are emitted when heated above the melting point. The 

amount of fume evolved increases as the temperature rises. 

Polymerization: Polymerization is not expected to occur. 

Avoid: Not applicable. 


CHEMICAL NAME % Wt. LD50 LC50 

TIN 

CAS NO.: 7440-31-5 99.85 Not Available Not Available 

NOTE: See Sections 3, 8 and 12 for additional information. 

Page 5 of 8

ECOTOXICITY 




US EPA Waste Number: Not Regulated 



Federal, state and local disposal laws and regulations will determine 

the proper waste disposal/recycling/reclamation procedure. All waste 

materials should be reviewed to determine the applicable hazards 

(testing may be necessary). Disposal requirements are dependent on the 

hazard classification and will vary by location and the type of disposal 

selected. 

**NOTE** Chemical additions, processing or otherwise altering this 

material may make the waste management information presented above 

incomplete, inaccurate or otherwise inappropriate. 

As local regulations may vary; all waste must be disposed/recycled/re- 

claimed in accordance with federal, state, and local environmental 

control regulations. 

INTERNATIONAL 

UN Number: Not Regulated 

UNITED STATES 

EPA Waste Number: Not Regulated 

DOT Classification: Not Regulated 

CANADA 

PIN Number: Not Regulated 

TDG Class: Not Regulated 

EC 

DGL: Not Determined 

US FEDERAL REGULATIONS 

TSCA: IN TSCA 

SARA 311 AND 312 HAZARD CATEGORIES 

SECTION 14: TRANSPORT INFORMATION 


Page 6 of 8

IMMEDIATE (Acute) Health Hazard: YES 

DELAYED (Chronic) Health Hazard: NO 

FIRE Hazard: NO 

REACTIVITY Hazard: NO 

Sudden Release of PRESSURE: NO 

SARA SECTION 313 NOTIFICATION 

This product does not contain toxic chemicals subject to the reporting 

requirements of Section 313 of Title III of the Superfund Amendments and 

Reauthorization Act of 1986 and 40 CFR Part 372. 

OZONE DEPLETING SUBSTANCES (ODS) 

This product neither contains nor is manufactured with an ozone 

depleting substance subject to the labeling requirements of the Clean 

Air Act Amendments 1990 and 40 CFR Part 82. 

VOLATILE ORGANIC COMPOUNDS (VOC) 

Not Determined 

US STATE REGULATIONS 

CALIFORNIA: The State of California has a regulation (Proposition 65) 

which identifies specific chemicals known to the State of California to 

cause cancer or birth defects. Proposition 65 requires a disclosure for 

products sold within the State of California containing an identified 

chemical. The following information is required by the State of 

California for this product: 

*WARNING: This product contains chemicals known to the State of 

California to cause cancer. 

*WARNING: This product contains chemicals known to the State of 

California to cause birth defects or other reproductive harm. 

VOLATILE ORGANIC COMPOUND (CARB): Not Determined 

CANADIAN REGULATIONS 

"This product has been classified in accordance with the hazard criteria 

of the Controlled Products Regulations and the MSDS contains all the 

information required by the Controlled Products Regulations." 

DSL/NDSL: DSL 

WHMIS Classification: Uncontrolled Product 

EUROPEAN REGULATIONS 

EINECS: Yes 

OTHER REGULATIONS 

MITI (Japan): Yes AICS (Australia): Yes 

Page 7 of 8

REVISIONS 

Revision Number: 5 

PREPARATION INFORMATION 


Prepared By: Wolverine Joining Technologies, and Wolverine Tube Inc. 

Corporate Environmental, Health and Safety Group. 

Phone Number/Address: See Section 1 

______________________________________________________________________ 

This Material Data Sheet is offered pursuant to OSHA';s Hazard 

Communication Standard (29 CRF 1910.1200). Other government regulations 

must be reviewed for applicability to these products. The information in 

this Material Safety Data Sheet should be provided to all who will use, 

handle, store, transport, or otherwise be exposed to this product. This 

information has been prepared for the guidance of plant engineering, 

operations, and management and for persons working with or handling these 

products. The information presented in the MSDS is premised upon proper 

handling and anticipated uses and is for the material without chemical 

additions/alterations. We believe this information to be reliable and upto-date 

as of the date of publication, but make no warranty that it is. 

Additionally, if this Material Safety Data Sheet is more than three years 

old, please contact the supplier at the phone number listed in Section 1 

to make certain that this sheet is the most current. Copyright Wolverine 

Joining Technologies, LLC. License granted to make unlimited copies for 

internal use only. 

Page 8 of 8

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NAME: TMS Polymeric Products 

MANUFACTURER: Tyco Electronics Corporation 

DIVISION: Ident Label Products 

ADDRESS: 300 Constitution Drive 

Menlo Park, CA 94025-1164 USA 

SUPPLIERS 


RAY3126 

(US, CN Version for International Trade) 

EMERGENCY TELEPHONE NUMBERS: US: CHEMTREC 1-800-424-9300 

CN: CHEMTREC 1-800-424-9300 

Outside North America: 1-703-527-3887 

(Collect calls accepted) 

NON-EMERGENCY HEALTH/SAFETY INFORMATION: North America: 1- 650-361-4907 

CHEMICAL FAMILY: Not applicable – This product is a manufactured article. 

PRODUCT USE: TMS Polymeric Products are typically used for wire and cable identification 

This product is not hazardous when used as recommended or intended. If this product is overheated, charred, or burned the 

health and safety information presented in this MSDS may apply. 

Thermal decomposition and combustion byproducts may be regulated under US-OSHA; CAN-WHMIS; IOSH; ISO; UK-CHIP; or EU Directives (67/548/EEC- 

Dangerous Substance Labelling, 98/24/EC-Chemical Agents at Work, 99/45/EC-Preparation Labeling, 2001/58/EC-MSDS Content, and 1907/2006/EC-REACH). 


EMERGENCY OVERVIEW: TMS Polymeric Products are not hazardous during proper installation, as directed by 

product installation guides. If overheated to degradation, most significantly if the product 

burns, thermal degradation and combustion byproducts may be toxic and should not be 

inhaled. 

The thermal degradation and combustion byproducts will depend on the base polymer 

used, and may include, but are not limited to carbon monoxide, carbon dioxide, organic 

acids (including acetic acid), aldehydes, low molecular weight hydrocarbons, silicon dioxide, 

hydrogen chloride, hydrogen fluoride, hydrogen bromide, fluoro-olefins, and oxides of 

nitrogen, phosphorus and sulfur. 

POTENTIAL HEALTH EFFECTS: 

Thermal degradation and combustion byproducts may be toxic and should not be inhaled. 

ACUTE HEALTH HAZARDS: 

EYES: Contact with molten material may cause thermal burns. 

SKIN: This product is not expected to be a skin irritant. Contact with the molten material my cause thermal 

burns. No harmful effects are expected from skin absorption of this product. 

INGESTION: Ingestion of this product is highly unlikely. There is insufficient information available on this material to 

predict the effects from ingestion. 

INHALATION: In common with most organic materials, thermal degradation and combustion byproducts may be toxic 

and should not be inhaled. (See comments below and the Thermal Degradation and Combustion 

Byproducts Section for more specific information). 

CHRONIC HEALTH HAZARDS: 

None of the ingredients to which users may be exposed and which are present at equal to or greater than 0.1% of the product, 

are listed by OSHA, NTP, or IARC as suspect carcinogens. 

PAGE 1 OF 7 Tyco Electronics Corporation


RAY3126 


MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: 

Overheating the product to charring or burning may produce vapors that may cause eye, skin, nose and throat irritation. 

Persons with pre-existing eye, skin, or respiratory disorders (e.g., asthma conditions) may be more susceptible to the effects of 

these vapors. 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 

Not applicable – This product is a manufactured article. 

Base polymer materials may include polyethylene, olefin copolymers, and fluoropolymers. 


EYE CONTACT: If eye irritation occurs, hold eyelids apart and flush affected area(s) with clean water for at least 15 

minutes. Seek medical attention. 

SKIN CONTACT: First aid is normally not required. After handling product, it is good work practice to wash your hands. 

If molten material contacts skin, cool area immediately in water. DO NOT attempt to remove material 

from the skin. Treat as a burn, and seek medical attention. 

INGESTION: Not a normal route of exposure. However, if swallowed and symptoms develop, seek medical 

attention. 

INHALATION: In case of inhalation where symptoms of exposure develop, move victim to fresh air. If symptoms 

persist, seek medical attention If breathing difficulties develop, oxygen should be administered by 

qualified personnel. If victim is not breathing, move to fresh air and immediately begin artificial 

respiration. Keep victim warm and quiet. Seek immediate medical attention. 

SECTION 5: FIRE-FIGHTING MEASURES 

FLAMMABLE PROPERTIES 

FLASHPOINT: Not determined 

METHOD USED: Not applicable 

FLAMMABLE LIMITS 

UPPER FLAMMABILITY LIMIT (% BY VOLUME): Not available 

LOWER FLAMMABILITY LIMIT (% BY VOLUME): Not available 

AUTOIGNITION TEMPERATURE: Not determined 

SUITABLE EXTINGUISHING MEDIA: 

carbon dioxide X water X dry chemical X foam X other 

Selection of extinguishing media should be based upon the size of the fire, the firefighting training/experience of the individual 

attempting to extinguish or control the fire, and the packaging materials exposed to the fire. 

SPECIAL FIRE FIGHTING PROCEDURES & PROTECTIVE EQUIPMENT: 

Firefighters should wear self-contained breathing apparatus with a full-face piece operated in the positive pressure demand 

mode when fighting fires. Use water spray to cool nearby containers and structures exposed to fire 

UNUSUAL FIRE AND EXPLOSION HAZARDS: 

SENSITIVITY TO STATIC DISCHARGE: None known 

SENSITIVITY TO MECHANICAL IMPACT: None known 

SPECIFIC HAZARDS IN CASE OF FIRE: 

Degradation and combustion byproducts may be toxic and should not be inhaled. 

HAZARDOUS COMBUSTION PRODUCTS: 

Thermal degradation is not significant at temperatures achieved during proper installation, as directed by product installation 

guides. At temperatures higher than those recommended, most significantly if the product burns, the thermal degradation and 

combustion byproducts will depend on the base polymer used and may include, but are not limited to carbon monoxide, carbon 

dioxide, organic acids (including acetic acid), aldehydes, low molecular weight hydrocarbons, silicon dioxide, hydrogen 

chloride, hydrogen bromide, fluoro-olefins, and oxides of nitrogen, phosphorus, and sulfur. 




RAY3126 


PERSONAL PRECAUTIONS: 

Wear appropriate personal protection when responding, as specified under Section 8: EXPOSURE CONTROLS / PERSONAL 

PROTECTION 

ENVIRONMENTAL PRECATIONS: 

Prevent spilled material from entering sewers and waterways. 

SPILL CONTAINMENT & CLEANUP METHODS/MATERIALS: 

Sweep up and collect in a suitable container for disposal or reuse. 


PRECAUTIONS FOR SAFE HANDLING AND STORAGE: 

Handling: Heat resistant gloves are required if hot products are handled after installation. 

Storage: This product is stable under normal conditions. 

OTHER PRECAUTIONS (e.g.; Incompatibilities): 

Avoid heating products beyond temperatures required for normal installation. See installation instructions for proper 

installation procedures. If product chars or burns, immediately stop heating. Avoid inhaling any fumes, which may be given off 

under such circumstances. Allow any vapors to disperse and ventilate before continuing work in the area. 


ENGINEERING CONTROLS/SYSTEM DESIGN INFORMATION: 

Ensure adequate ventilation during application, particularly in enclosed areas. 

VENTILATION: 

Provide general or local exhaust ventilation systems 

RESPIRATORY PROTECTION: 

If installation occurs in a confined, unventilated area, NIOSH/MSHA-approved respirators are recommended. 

EYE PROTECTION: 

If there is a danger of molten material contacting the eyes, use eye/faceshield. 

SKIN PROTECTION: 

If there is a danger of molten material contacting the skin, use heat resistant gloves. If it is necessary to handle products that 

have beed grossly overheated or fire-damaged, wear natural rubber gloves to prevent possible contact with potentially 

corrosive inorganic acid residues. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: 

OSHA, ANSI, or NIOSH guidelines should be followed based on the operation performed. 

EXPOSURE GUIDELINES & LIMITS: 


OSHA Permissible Exposure Limit (PEL/TWA) 

ACGIH Threshold Limit Value (TLV) 

Ontario Occupational Exposure Level (OEL) 

Germany Maximale Arbeitsplatzkonzentrationen (MAK) 

United Kingdom Occupational Exposure Standard (OES) 

TWA – 8-Hour Time Weighted Average/ NE – Not Established 




RAY3126 


APPEARANCE: Plastic tubing and molded parts in a variety of shapes, sizes and colors. 

ODOR: No odor. 

ODOR THRESHOLD: Not applicable 

PHYSICAL STATE: Solid 

pH: Not applicable 

BOILING POINT: Not applicable 

MELTING POINT: 85º – 160º C (185º - 320º F) 

FREEZING POINT: Not available 

VAPOR PRESSURE (mmHg @ 20 º C): Not applicable 

VAPOR DENSITY (AIR = 1): Not applicable 

VOLATILITY (% by Volume) Not applicable 

SPECIFIC GRAVITY (H2O = 1): 

EVAPORATION RATE (Butyl 


acetate=1): Not applicable 

SOLUBILITY IN WATER: Insoluble 

FLASH POINT: Not available 

AUTO-IGNITION TEMPERATURE: Not applicable 

LOWER EXPLOSIVE LIMIT (LEL): Not applicable 

UPPER EXPLOSIVE LIMIT (UEL): Not applicable 

PARTITION COEFFICIENT: Not applicable 

VISCOSITY (centipoise @ 25° C): Not applicable 

DECOMPOSITION TEMPERATURE: Not available 

FLAMMABILITY/HMIS HAZARD CLASSIFICATIONS (US/CN/EU): 


HEALTH: FLAMMABILITY: REACTIVITY: 


STABILITY: This product is stable under normal conditions, at ambient temperature. 

INCOMPATIBILITY (MATERIAL TO AVOID): Avoid overheating of product. 

HAZARDOUS DECOMPOSITION OR BY- See Section 5: FIRE FIGHTING MEASURES (Hazardous Combustion 

PRODUCTS: 

Products). 

HAZARDOUS POLYMERIZATION: Will not occur. No known polymerization conditions to avoid. 

CONDITIONS TO AVOID: Avoid overheating of product. 


ACUTE TOXICITY (Test Results Basis and Comments): 

LD50 (Oral, Rat): Not determined 

LC50 (Inhalation, Rat): Not determined 

ROUTES OF ENTRY/EFFECTS OF ACUTE OVEREXPOSURE: 

Overheating the product to charring or burning may produce vapors that may cause eye, skin, nose and throat irritation. 

SUBCHRONIC/CHRONIC TOXICITY (Test Results and Comments): 




RAY3126 


IRRITANCY OF PRODUCT: Vapours from the heated product may cause irritation of the eyes, skin, nose, and throat. 

SENSITIZATION TO MATERIAL: Persons with pre-existing eye, skin, or respiratory disorders (e.g., asthma conditions) may 

be more susceptible to the effects of vapors produced by burning or charing product. 

CARCINOGENICITY: None of the ingredients to which users may be exposed and which are present at equal to or greater 

than 0.1% of the product, are listed by OSHA, NTP, or IARC as carcinogens. 

REPRODUCTIVE TOXICITY: Not determined. 

TERATOGENICITY: Not determined. 

MUTAGENICITY: Not determined. 

TOXICOLOGICALLY SYNERGISTIC PRODUCTS: Not determined. 


PERSISTENCE & DEGRADABILITY: 

No data available on biodegradation. 

BIO-ACCUMULATIVE POTENTIAL (Including Mobility): 

No data available on bioaccumulation. 

AQUATIC TOXICITY (Test Results & Comments): 

No data available on aquatic toxicity. 

Additional Information 

• No known effects on stratospheric ozone depletion. 

• Water Endangering Class (WGK): NA 


WASTE DISPOSAL 

METHOD: 

Treatment, storage, and disposal must be in accordance with applicable, federal, state, 

provincial, and local regulations. 

HAZARDOUS WASTE If there are local regulations covering the controlled incineration of halogenated materials. 

Then all halogen-containing products will be subject to such regulations. Refer to the product 

literature for identification of halogen-containing products. 

CLASS/CODE: US - Not applicable to material as manufactured for distribution into commerce. 

CN – Not applicable to material as manufactured for distribution into commerce. 

EWC – Not applicable to material as manufactured for distribution into commerce. 


Not Included – Dispose/Recycle as allowed by local jurisdiction for the end-of-life characteristics as-disposed. 

SECTION 14: TRANSPORT INFORMATION 

These products are non-hazardous under Department of Transportation Regulations 49, CFR Section 171.8, IATA, IMO, and 

AFR 71-4. 

GROUND – US-DOT/CAN-TDG/EU-ADR/APEC-ADR: 

Proper Shipping Name Not Subject to HMR 

Hazard Class NA ID Number NA 

Packing Group 

AIRCRAFT – ICAO-IATA: 

NA Labels NA 

Proper Shipping Name Not Subject to DGR 


Packing Group NA Labels NA 



RAY3126 


VESSEL – IMO-IMDG: 

Proper Shipping Name Not Subject to IMDG 


Packing Group 


NA Labels NA 

• Transportation must be in accordance with applicable, federal, state, provincial, and local regulations. 

• Transport requires proper packaging and paperwork, including the Nature and Quantity of goods, per applicable 

origin/destination/customs points as-shipped. Statement of Jurisdictional/Modal Special Provision(s) required. 

• Not restricted for any mode of international transport as finished goods. 

• Not a Marine Pollutant as-shipped per IMO/IMDG. 


INVENTORY STATUS: 

All components are listed on the TSCA; EINECS/ELINCS; and DSL, unless noted otherwise below. 

U.S. FEDERAL REGULATIONS: 

TSCA Section 8b – Inventory Status: All chemicals comprising this product are either exempt or listed on the TSCA 

Inventory. 

TSCA Section 12b – Export Notification: If the product contains chemicals subject to TSCA Section 12b export notification 

they are listed below: 

Chemical CAS # 

None NA 

CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT) 

Chemicals present in the product which could require reporting under the statute: 

Chemical CAS # 

None NA 

SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 

If the product contains chemicals subject to the reporting requirements of Section 313 of SARA Title III, they are listed below. 

Chemical CAS # % wt 

None NA NA 

CERCLA SECTION 311/312 HAZARD CATEGORIES: Note that this product is exempt from these regulations. 

Fire Hazard No 

Pressure Hazard No 

Reactivity Hazard No 

Immediate Hazard No 

Delayed Hazard No 

STATE REGULATIONS (US): 


The following chemicals identified to exist in the product as distributed into commerce are known to the State of California 

to cause cancer, birth defects, or other reproductive harm: 

Chemical CAS # % Wt 

None 

INTERNATIONAL REGULATIONS (Non-US): 

NA NA 

Canadian Domestic Substance List (DSL) 


WHMIS Classifications 

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and 

the MSDS contains all of the information required by the Controlled Products Regulations." 

NPRI and Ontario Regulation 127/01 

This product contains the following chemicals subject to the reporting requirements of Canada NPRI and/or Ont. Reg. 



RAY3126 


127/01: 

Chemical CAS # % Wt 

None N/A N/A 

European Inventory of Existing Commercial Chemical Substances (EINECS) 

All ingredients remaining in the product as distributed into commerce are exempt from, or included on, the European 

Inventory of Existing Commercial Chemical Substances. 

European Communities (EC) Hazard Classification according to directives 67/548/EEC and 1999/45/EC. 

R-Phrases S-Phrases 

None None 


This product may be regulated under additional regulations and laws not identified above, such as for uses other than 

described or as-designed/as-intended by the manufacturer, or for distribution into specific domestic destinations. 


OTHER INFORMATION: 

Distribution into Quebec to follow Canadian Controlled Product Regulations (CPR) 24(1) and 24(2). 

Distribution into the EU to follow applicable Directives to the Use, Import/Export of the product as-sold. 

MSDS/SDS PREPARATION INFORMATION: 

Department Issuing MSDS: Tyco Electronics, Menlo Park 

DATE OF ISSUE: April 3, 2009 SUPERCEDES: March 10, 2009 

DISCLAIMER: 

Tyco Electronics makes no warranties as to the accuracy or completeness of this information and disclaims any liability in 

connection with its use. Tyco Electronics’ obligation shall be only as set forth in Tyco Electronics’ standard terms and 

conditions of sale for this product. In no case will Tyco Electronics be liable for any incidental, indirect or consequential 

damages arising out of the sale, resale, use or misuse of the product. 

The information presented herein was prepared at Tyco Electronics by qualified technical personnel, and to our knowledge it is 

true and accurate. The information and recommendations are furnished for this product with the understanding that the 

purchaser/user will independently determine the suitability of the product for this purpose. The data do not constitute a 

warranty, expressed or implied, statutory or otherwise, nor are they a representation for which Tyco Electronics assumes legal 

responsibility. The data are submitted for the user’s information and consideration only. Any use of this product must be 

determined by the user to be in accordance with the applicable federal, State/Provincial, and local laws and regulations. 

Users are advised that they may have additional disclosure obligations under other national and local laws. Users are advised 

to ensure that this information is brought to the attention of all employees, agents, and contractors handling this product. Users 

of Tyco Electronics products should make their own evaluation to determine the suitability of each such product for the specific 

application and to establish safe handling and installation procedures. Distributors of this product are advised to forward this 

document, or the information contained herein, to every purchaser of this product. 

END 



Section 1: Product & Company Identification 

Product Name: Bee Blast TM Wasp & Hornet Killer 

Product Number (s): 14009 

Manufactured By: 

CRC Industries, Inc. General Information (215) 674-4300 

885 Louis Drive Technical Assistance (800) 521-3168 

Warminster, PA 18974 Customer Service (800) 272-4620 

www.crcindustries.com 24-Hr Emergency (CHEMTREC) (800) 424-9300 

Section 2: Hazards Identification 


Appearance & Odor: Amber liquid, petroleum odor 

CAUTION 

Flammable. Harmful or fatal if swallowed. Eye irritant. Contents under pressure. 

As defined by OSHA’s Hazard Communication Standard, this product is hazardous. 


EYE: May cause moderate eye irritation. 

SKIN: May cause skin irritation. Prolonged contact may allow material to be absorbed 

through the skin 

INHALATION: May cause respiratory irritation. Overexposure to vapors may lead to central 

nervous system effects such as headache and drowsiness, followed by dizziness 

and nausea. 

INGESTION: May cause gastrointestinal discomfort or irritation of the throat. Aspiration of this 

material into the lungs, either while swallowing or vomiting, may lead to chemical 

pneumonitis, which could be fatal. Signs of lung involvement include increased 

respiratory rate, increased heart rate, and a bluish discoloration of the skin. 

CHRONIC EFFECTS: Repeated skin contact may cause contact dermatitis. 

TARGET ORGANS: Central nervous system. 

Medical Conditions Aggravated by Exposure: 

pre-existing skin conditions 

See Section 11 for toxicology and carcinogenicity information on product ingredients. 

Page 1 of 6

Product Name: Bee Blast TM Wasp & Hornet Killer Product Number (s): 14009 

Section 3: Composition/Information on Ingredients 

Section 4: First Aid Measures 

COMPONENT CAS NUMBER % by Wt. 

Hydrotreated light distillate 64742-47-8 90 - 100 

Tetramethrin 7696-12-0 0.200 

Phenothrin 26002-80-2 0.125 

Carbon dioxide 124-38-9 1 - 5 

Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. 

Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician 

if irritation persists. Wash contaminated clothing prior to re-use. 

Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If 

breathing is difficult give oxygen. Call a physician. 

Ingestion: Do NOT induce vomiting due to aspiration hazard. If vomiting occurs, lower head below 

knees to avoid aspiration. Seek immediate medical attention. 

Note to Physicians: None 

Section 5: Fire-Fighting Measures 

Flammable Properties: This product is flammable in accordance with aerosol flammability definitions 

(16 CFR 1500.3(c) (6) ). 

Flash Point: 177 F (PMCC) Upper Explosive Limit: ND 

Autoignition Temperature: ND Lower Explosive Limit: ND 

Suitable Extinguishing Media: Use extinguishers appropriate for a class B fire. 

Products of Combustion: Oxides of carbon 

Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for 

protection against suffocation and possible toxic decomposition products. Proper eye 

and skin protection should be provided. Use water spray to keep fire-exposed 

containers cool and to knock down vapors which may result from product 

decomposition. 

Section 6: Accidental Release Measures 

Personal Precautions: Use personal protection recommended in Section 8. 

Page 2 of 6


Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush 

into sewers or storm drains. 

Methods for Containment & Clean-up: Dike area to contain spill. Ventilate the area with fresh air. If in confined 

space or limited air circulation area, clean-up workers should wear 

appropriate respiratory protection. Recover or absorb spilled material using 

an absorbent designed for chemical spills. Place used absorbents into 

proper waste containers. 

Section 7: Handling and Storage 

Handling Procedures: Avoid breathing vapors. Use outside or with adequate ventilation. Avoid contact with eyes, 

skin and clothing. Do not use near sparks, open flames or other sources of ignition. 

Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F 

to prevent cans from rupturing. 

Aerosol Storage Level: III 

Section 8: Exposure Controls/Personal Protection 

Exposure Guidelines: 

OSHA ACGIH OTHER 

COMPONENT TWA STEL TWA STEL TWA SOURC 

E 

Hydrotreated light distillate NE NE NE NE NE 

Tetramethrin NE NE NE NE NE 

Phenothrin NE NE NE NE NE 

Carbon dioxide 5000 NE 5000 30000 NE ppm 

N.E. – Not Established (c) – ceiling (s) – skin (v) – vacated 

Engineering Controls: Area should have ventilation to provide fresh air. Use local exhaust to prevent accumulation 

of vapors. Use mechanical means if necessary to maintain vapor levels below the exposure 

guidelines. If working in a confined space, follow applicable OSHA regulations 

Respiratory Protection: None required for normal work where adequate ventilation is provided. Use NIOSHapproved 

self-contained positive pressure respirators in low circulation areas and for 

emergencies. 

Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid 

contact, wear splash-proof goggles. 

Skin Protection: Use protective gloves such as neoprene or nitrile. Also , use full protective clothing if there 

is prolonged or repeated contact of liquid with skin. 

Section 9: Physical and Chemical Properties 

Physical State: liquid 

Color: light amber 

Page 3 of 6 

UNIT


Odor: petroleum 


Initial Boiling Point: 420 F 

Freezing Point: ND 

Vapor Pressure: < 0.1 mm Hg 

Vapor Density: > 1 (air = 1) 

Evaporation Rate: < 1 (ether = 1) 

Solubility: negligible in water 

pH: NA 

Volatile Organic Compounds: wt %: 33.0 g/L: 260 lbs./gal: 2.17 

Section 10: Stability and Reactivity 

Stability: Stable 

Conditions to Avoid: Temperature extremes; sources of ignition 

Incompatible Materials: Strong acids, bases and oxidizers 

Hazardous Decomposition Products: Carbon monoxide 

Possibility of Hazardous Reactions: No 

Section 11: Toxicological Information 

Toxicological studies have been conducted on the active ingredient mixture for this product. The following 

information was supplied by the manufacturer of the active ingredient mixture. 

ACUTE EFFECTS 

Component Test Result Route Species 

Active ingredient mixture LD50 > 6.31 g/kg Oral Rat 

Active ingredient mixture LD50 > 2 g/kg Dermal Rat 

Active ingredient mixture LC50 > 5.34 mg/L Inhalation Rat 

CHRONIC EFFECTS 


Component Result 

OSHA: None listed 

IARC: None listed 

NTP: None listed 

Mutagenicity: No information 

Other: None 

Section 12: Ecological Information 

Ecological studies have not been conducted for this product. The following information is available for 

components of this product. 

Page 4 of 6


Ecotoxicity: No information available 

Persistence / Degradability: No information available 

Bioaccumulation / Accumulation: No information available 

Mobility in Environment: No information available 

Section 13: Disposal Considerations 

Disposal: The liquid product is not a RCRA hazardous waste. Full or partial full containers should be punctured 

and drained. Empty containers may be recycled or discarded. Contact your state or local regulatory 

agency for more details. 

All disposal activities must comply with federal, state and local regulations. Local regulations may be more 

stringent than state or national requirements. 

Section 14: Transport Information 

Proper shipping description: 

US DOT (ground): Consumer Commodity, ORM-D 

Special Provisions: None 

Section 15: Regulatory Information 

U.S. Federal 

Toxic Substances Control Act (TSCA): 

All ingredients are either listed on the TSCA inventory or are exempt. 

Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): 

Reportable Quantities (RQ’s) exist for the following ingredients: None 

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the 

National Response Center (800-424-8802) and to your Local Emergency Planning Committee. 

Superfund Amendments Reauthorization Act (SARA) Title III: 

Section 302 Extremely Hazardous Substances (EHS): None 

Section 311/312 Hazard Categories: Fire Hazard Yes 

Reactive Hazard No 

Release of Pressure Yes 

Acute Health Hazard Yes 

Chronic Health Hazard No 

Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting 

requirements of Section 313 of Title III of the Superfund Amendments and 

Reauthorization Act of 1986 and 40 CFR Part 372: 

Tetramethrin, Phenothrin 

Clean Air Act: 

Section 112 Hazardous Air Pollutants (HAPs): None 

Page 5 of 6


State Regulations 

California Safe Drinking Water and Toxic Enforcement Act (Prop 65): 

NONE 

State Right to Know: 

New Jersey: Tetramethrin, Phenothrin, 1,2,4-Trimethylbenzene (< 0.5%) 

Pennsylvania: 1,2,4-Trimethylbenzene (< 0.5%) 

Massachusetts: 1,2,4-Trimethylbenzene (< 0.5%) 

Rhode Island : None 

Additional Regulatory Information: 

Section 16: Other Information 

EPA Registration #55809-3 

NFPA: Health: 2 Flammability: 2 Reactivity: 0 

HMIS: Health: 2 Flammability: 2 Reactivity: 0 PPE: B 

Prepared By: Michelle Rudnick 

CRC #: 00431A 


Changes since last revision: Corrected CAS# in Section 3. 

The information contained in this document applies to this specific material as supplied. It may not be valid for 

this material if it is used in combination with any other materials. This information is accurate to the best of 

CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any 

product, read all warnings and directions on the label. 

CAS: Chemical Abstract Service NA: Not Applicable 

ppm: Parts per Million ND: Not Determined 

TCC: Tag Closed Cup NE: Not Established 

PMCC: Pensky-Martens Closed Cup g/L: grams per Liter 

PPE: Personal Protection Equipment lbs./gal: pounds per gallon 

TWA: Time Weighted Average STEL: Short Term Exposure Limit 


ACGIH American Association of Governmental Industrial Hygienists 

NIOSH National Institute of Occupational Safety & Health 

Page 6 of 6

Section 1: Product & Company Identification 


Product Name: Lithium Complex Wheel Bearing Grease 

Product Number (s): SL3110-SL3119 

Manufactured By: CRC Industries, Inc. (215) 674-4300 

885 Louis Drive, Warminster, PA 18974 

24-Hour Emergency Information: CHEMTREC (800) 424-9300 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 2: Composition/Information on Ingredients 

Component CAS ACGIH OSHA OTHER % 

NUMBER TLV PEL LIMITS 

Lube Oil 500 SUS 64742-52-5 5 mg/m3 5 mg/m3 (mist) 50-70 

Lithium 12 Hydroxyoctadecanoate 7620-77-1 NE NE NE < 10 

Residual Oils 64742-57-0 5 mg/m3 NE NE 10-30 

Nonanedioic acid dilithium salt 38900-29-7 NE NE NE 5-10 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 3: Hazards Identification 


Appearance & Odor: Amber, mild bland petroleum odor. 


Inhalation: Exposure to oil mists or fumes, which may be generated when heated or burned, may 

irritate the nose, throat and upper respiratory tract. 

Eyes: Irritation 

Skin: Irritation 

Ingestion: NA 

Carcinogenicity: OSHA: No IARC: No NTP: No 

Chronic Overexposure: NA 

Medical Conditions Aggravated by Exposure: Pre-existing skin and pre-respiratory conditions. 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 4: First Aid Measures 

Inhalation: Remove to fresh air. Give artificial respiration if necessary. 

Eyes: Flush with large amounts of water for 15 minutes. 

Skin: Remove contaminated clothing and wash area with soap and water. 

Ingestion: Call a physician. Do not induce vomiting. 

--------------------------------------------------------------------------------------------------------------------------------------- 

Page 1 of 3

Product Name: Lithium Complex Wheel Bearing Grease Product Number (s): SL3110-SL3119 

Section 5: Fire-Fighting Measures 

Flashpoint: >300 o F Method: TCC LEL: ND UEL: ND 

Extinguishing Media: Carbon dioxide, dry chemical and foam 

Hazardous Combustion Products: CO2 and carbon monoxide 

Fire-fighting Instructions: Remove containers from fire area if possible. Use self-contained 

breathing apparatus for fire fighting. 

NFPA: Health: 1 Flammability: 1 Reactivity: 0 

HMIS: Health: 1 Flammability: 1 Reactivity: 0 PPE: B 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 6: Accidental Release Measures 

Spill/Leak Procedures: Area should be ventilated. Absorbent should be used to pick up excess material. All 

used and unused product should be disposed of in accordance with federal, state and local regulations. 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 7: Handling and Storage 

Handling Procedures: Store in a cool, dry area. 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 8: Exposure Controls/Personal Protection 

Engineering Controls: Adequate to prevent accumulation of vapors. Use mechanical means if necessary to 

maintain levels below the exposure limits. If working in a confined space, follow applicable OSHA regulations. 

Respiratory: Use NIOSH/MSHA compliant respirators or self-contained breathing apparatus above exposure 

limits. Follow OSHA regulations 29 CFR 1910.134. 

Protective Clothing/Equipment: Wear chemically protective gloves and safety glasses. Use a splash apron and 

boots if splashing occurs. 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 9: Physical & Chemical Properties 

Physical State: Semi-solid Appearance & Odor: Amber, mild bland petroleum 

odor 

Specific Gravity: 0.9 @ 60 o F Boiling Point: ND 

Freezing Point: ND Vapor Pressure: Neg. 

Evaporation Rate: Neg. Vapor Density (air = 1) > than air 

pH: NA Solubility: Neg. 

Volatile Organic Compounds %: 1.5 g/L: 14 lbs./gal: 0.12 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 10: Stability and Reactivity 

Stability: Stable Hazardous Polymerization: No 

Chemical Incompatibilities: Strong oxidizers. 

Materials to Avoid: Strong oxidizing agents. 

Hazardous Decomposition Products: None 

--------------------------------------------------------------------------------------------------------------------------------------- 

Page 2 of 3

Product Name: Lithium Complex Wheel Bearing Grease Product Number (s): SL3110-SL3119 

Section 11: Toxicological Information 

Long-term toxicological studies have not been conducted for this product. See Section 3 of this MSDS for 

acute symptoms of overexposure and carcinogenicity information. 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 12: Ecological Information 

Ecotoxicity: No data available. 

Environmental Fate: No data available for biodegradation. 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 13: Disposal Considerations 

Disposal: This material if discarded may be hazardous waste under U.S. EPA RCRA regulations. All disposal 

activities must comply with federal, state and local regulations. Contact your local or state environmental 

agency for specific rules. Do not dump into sewers, on the ground or into any body of water. 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 14: Transportation Information 

Shipping Name: Not Regulated 

Hazard Class: NA UN Number: NA Packing Group: NA 

Label: NA Placard: NA 

Special Provisions: NA 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 15: Regulatory Information 

TSCA: All components are either listed under TSCA or are exempt. 

SARA Title III: Section 311/312: NA Section 313*: None 

CERCLA/Superfund (RQ): NA 

Extremely Hazardous Substances: No 

California Prop 65: No 

* See section 2 for percentage 

--------------------------------------------------------------------------------------------------------------------------------------- 

Section 16: Additional Information 

Prepared By: Adam M. Selisker Date: March 27, 2002 

Technical Information: (800) 521-3168 CRC #: SL3110 

This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by 

CRC to be accurate. Before using any product, read all warnings and directions on the label. 

CAS: Chemical Abstract Service NA: Not Applicable 

ppm: Parts per Million ND: Not Determined 

TCC: Tag Closed Cup NE: Not Established 

LEL: Lower Explosive Limit g/L: grams per Liter 

UEL: Upper Explosive Limit lbs./gal: pounds per gallon 

PPE: Personal Protection Equipment RQ: Reportable Quantity 

COC: Cleveland Closed Cup TOC: Tag Open Cup 

Page 3 of 3


MSDS Number: 16968ET - 0 

24 Hour Emergency Assistance: CHEMTEL (877) 276-7283 

General Assistance Number: (877) 276-7285 

-------------------------------------------------------------------------------- 

SECTION 1 PRODUCT IDENTIFICATION 

-------------------------------------------------------------------------------- 

MATERIAL IDENTITY: Windshield Washer Fluid Concentrate 

PRODUCT CODES: 16968 

COMPANY ADDRESS:Equilon Enterprises LLC, P. O. Box 4453, Houston, TX. 

77210-4453 

-------------------------------------------------------------------------------- 

SECTION 2 PRODUCT/INGREDIENTS 

-------------------------------------------------------------------------------- 

CAS# CONCENTRATION INGREDIENTS 

Mixture 100 %weight Windshield Washer Fluid 

67-56-1 95 - 99.99 %weight Methanol 

26038-90-4 < 1 %weight Corrosion Inhibitor 

-------------------------------------------------------------------------------- 

SECTION 3 HAZARDS IDENTIFICATION 

-------------------------------------------------------------------------------- 


Appearance & Odor: Blue, clear liquid Alcohol odor 

Health Hazards: Causes severe eye irritation. Highly toxic and may be fatal 

if swallowed. May cause skin irritation. Toxic and harmful if absorbed 

through the skin. Toxic and harmful if inhaled. 

NFPA Rating (Health, Fire, Reactivity): 2, 3, 0 

Hazard Rating:Least - 0 Slight - 1 Moderate - 2 High - 3 

Extreme - 4 

Inhalation: 

Toxic and harmful if inhaled. 

Eye Irritation: 

Severely irritating to the eyes causing pain, redness, swelling and blurred 

vision. 

Skin Contact:

May be irritating to the skin causing a burning sensation, redness and/or 

swelling. Toxic and is harmful if absorbed through the skin. 

Ingestion: 

Highly toxic and may be fatal if swallowed. 

This material and/or components may cause the following effects: 

Developmental Toxicity 

Eye, Blood/Blood Forming Organs, Nervous System 

For additional health information, refer to section 11. 

-------------------------------------------------------------------------------- 

SECTION 4 FIRST AID MEASURES 

-------------------------------------------------------------------------------- 

Inhalation: 

Move victim to fresh air and provide oxygen if breathing is difficult. Get 

medical attention. If the victim has difficulty breathing or tightness of the 

chest, is dizzy, vomiting or unresponsive, give 100% oxygen with rescue 

breathing or CPR as required and transport to the nearest medical facility. 

Skin: 

Remove contaminated clothing, flush with large amounts of water for at least 

15 minutes, by the clock, or longer depending on the concentration amount and 

duration of exposure. If redness, swelling, pain and/or blisters occur, 

transport to the nearest medical facility for additional treatment. 

Eye: 

Immediately flush eyes with large amounts of water for at least 30 minutes, by 

the clock, while holding eyelids open. Transport to nearest medical facility 

for additional treatment. 

Ingestion: 

DO NOT take internally. DO NOT GIVE LIQUIDS TO A DROWSY, CONVULSING OR 

UNCONSCIOUS PERSON. Transport to nearest medical facility for additional 

treatment. 

-------------------------------------------------------------------------------- 

SECTION 5 FIRE FIGHTING MEASURES 

-------------------------------------------------------------------------------- 

Flash Point [Method]: 54 ºF/12.22 ºC [ Tagliabue Closed Cup] 


Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish 

flames. Do not use a direct stream of water. Material will float and can be 

re-ignited on surface of water.

Fire Fighting Instructions: 

WARNING! DANGER! EXTREMELY FLAMMABLE. Clear fire area of all non-emergency 

personnel. Only enter confined fire space with full bunker gear, including a 

positive pressure, NIOSH-approved, self-contained breathing apparatus. Cool 

surrounding equipment, fire-exposed containers and structures with water. 

Container areas exposed to direct flame contact should be cooled with large 

quantities of water (500 gallons water per minute flame impingement exposure) 

to prevent weakening of container structure. 

-------------------------------------------------------------------------------- 

SECTION 6 ACCIDENTAL RELEASE MEASURES 

-------------------------------------------------------------------------------- 

Protective Measures: 

DANGER! EXTREMELY FLAMMABLE! HIGHLY TOXIC. Eliminate potential sources of 

ignition. Handling equipment must be bonded and grounded to prevent sparking. 

Wear appropriate personal protective equipment when cleaning up spills. Refer 

to Section 8. Full protective clothing and self-contained breathing apparatus. 

Spill Management: 

Shut off source of leak if safe to do so. Dike and contain spill. 

FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels. 

FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or 

other suitable material. Place in non-leaking container and seal tightly for 

proper disposal. 

Reporting: 

U.S. regulations require reporting releases of this material to the 

environment which exceed the reportable quantity to the National Response 

Center at (800)424-8802. 

-------------------------------------------------------------------------------- 

SECTION 7 HANDLING AND STORAGE 

-------------------------------------------------------------------------------- 

Precautionary Measures: 

Wash with soap and water before eating, drinking, smoking, applying cosmetics, 

or using toilet. Launder contaminated clothing before reuse. Properly 

dispose of contaminated leather articles such as shoes or belts that cannot be 

decontaminated. EXTREMELY FLAMMABLE. DANGER! Do not take internally. Do 

not taste or swallow. Avoid heat, open flames, including pilot lights, and 

strong oxidizing agents. Use explosion-proof ventilation to prevent vapor 

accumulation. Ground all handling equipment to prevent sparking. Avoid 

contact with eyes, skin and clothing. Wash thoroughly after handling.

Handling: 

Surfaces that are sufficiently hot may ignite liquid material. 

Air-dry contaminated clothing in a well-ventilated area before laundering. 

Storage: 

Keep liquid and vapor away from heat, sparks and flame. Extinguish pilot 

lights, cigarettes and turn off other sources of ignition prior to use and 

until all vapors have dissipated. Use explosion-proof ventilation to prevent 

vapor accumulation while in use. 

Container Warnings: 

Keep containers closed when not in use. Containers, even those that have been 

emptied, can contain explosive vapors. Do not cut, drill, grind, weld or 

perform similar operations on or near containers. 

-------------------------------------------------------------------------------- 

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 

-------------------------------------------------------------------------------- 

Methanol ACGIH TLV TWA: 200 ppmv STEL: 250 ppmv Notation: Skin 

Methanol OSHA PEL - 1989(revoked) TWA: 200 ppmv STEL: 250 ppmv 

Notation: Skin 

EXPOSURE CONTROLS 

Adequate ventilation to control airborne concentrations below the exposure 

guidelines/limits. Eye washes and showers for emergency use. 

PERSONAL PROTECTION 

Personal protective equipment (PPE) selections vary based on potential 

exposure conditions such as handling practices, concentration and ventilation. 

Information on the selection of eye, skin and respiratory protection for use 

with this material is provided below. 

Eye Protection: 

Chemical Goggles and Face Shield, or Safety glasses with side shields 

Skin Protection: 

Use protective clothing which is chemically resistant to this material. 

Selection of protective clothing depends on potential exposure conditions and 

may include gloves, boots, suits and other items. The selection(s) should 

take into account such factors as job task, type of exposure and durability 

requirements. 

Published literature, test data and/or glove and clothing manufacturers 

indicate the best protection is provided by: 

Neoprene, or Nitrile Rubber 

Respiratory Protection:

If engineering controls do not maintain airborne concentrations to a level 

which is adequate to protect worker health, an approved respirator must be 

worn. Respirator selection, use and maintenance should be in accordance with 

the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134. 

Types of respirator(s) to be considered in the selection process include: 

For Vapors: Air Purifying, R or P style prefilter & organic cartridge, 

NIOSH approved respirator. Self-contained breathing apparatus. 

-------------------------------------------------------------------------------- 

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 

-------------------------------------------------------------------------------- 

Appearance & Odor: Blue, clear liquid Alcohol odor 

Substance Chemical Family: Alcohol 

Appearance: Blue, clear liquid 

Flash Point: 54 ºF [Tagliabue Closed Cup] 

Freezing Point: -51 ºF 

pH: 9 - 9.5 


Vapor Pressure: 97 mmHg @ 68 ºF 

VOC Content: 99 %weight 

-------------------------------------------------------------------------------- 

SECTION 10 REACTIVITY AND STABILITY 

-------------------------------------------------------------------------------- 


Avoid heat, sparks, open flames and other ignition sources. 

Materials to Avoid: 

Avoid contact with strong oxidizing agents. 


Thermal decomposition products are highly dependent on combustion conditions. 

A complex mixture of airborne solids, liquids and gases will evolve when this 

material undergoes pyrolysis or combustion. Aldehydes, Carbon Monoxide, 

Carbon Dioxide, Ketones 

and other unidentified organic compounds may be formed upon combustion. 

--------------------------------------------------------------------------------

SECTION 11 TOXICOLOGICAL INFORMATION 

-------------------------------------------------------------------------------- 

Acute Toxicity 

Dermal LDLo

Under RCRA, it is the responsibility of the user of the material to determine, 

at the time of the disposal, whether the material meets RCRA criteria for 

hazardous waste. This is because material uses, transformations, mixtures, 

processes, etc. may affect the classification. Refer to the latest EPA, state 

and local regulations regarding proper disposal. 

-------------------------------------------------------------------------------- 

SECTION 14 TRANSPORT INFORMATION 

-------------------------------------------------------------------------------- 

US Department of Transportation Classification 

Proper Shipping Name: Flammable Liquid, N.O.S. 

Technical Names (s): Methanol 

Identification Number: UN1993 

Hazard Class/Division: 3 (Flammable Liquid) 

Packing Group: II 

Hazardous Substance/Material RQ: Methanol / 5005.005 lbs 

Emergency Response Guide # 128 

International Air Transport Association 


Indentification Number: UN1992 


Proper Shipping Name: Flammable Liquid, Toxic, N.O.S. 

Subsidiary Class: 6.1 (Poisonous Material) 

Technical Name(s): Methanol 

International Maritime Organization Classification 

Hazard Class/Division: 3.2 (Flammable Liquid) 

Indentification Number: UN1992 


Proper Shipping Name: Flammable Liquid, Toxic, N.O.S. 

Subsidiary Class: 6.1 (Poisonous Material) 

Technical Name(s): Methanol 

-------------------------------------------------------------------------------- 

SECTION 15 REGULATORY INFORMATION 

-------------------------------------------------------------------------------- 

FEDERAL REGULATORY STATUS 

OSHA Classification: 

Product is hazardous according to the OSHA Hazard Communication Standard, 29

CFR 1910.1200. 

Comprehensive Environmental Release, Compensation & Liability Act (CERCLA): 

Methanol RQ 5000 lbs Reportable Spill => 5005 lbs or 

670 gal 

Ozone Depleting Substances (40 CFR 82 Clean Air Act): 

This material does not contain nor was it directly manufactured with any Class 

I or Class II ozone depleting substances. 

Superfund Amendment & Reauthorization Act (SARA) Title III: 

There are no components in this product on the SARA 302 list. 

SARA Hazard Categories (311/312): 

Immediate Health:YES Delayed Health:YES Fire:YES Pressure:NO 

Reactivity:NO 

SARA Toxic Release Inventory (TRI) (313): 

Methanol 

Toxic Substances Control Act (TSCA) Status: 

This material is listed on the EPA/TSCA Inventory of Chemical Substances. 

Other Chemical Inventories: 

Australian AICS, Canadian DSL, Chinese Inventory, European EINECS, Korean 

Inventory 

State Regulation 

The following chemicals are specifically listed by individual states; other 

product specific health and safety data in other sections of the MSDS may also 

be applicable for state requirements. For details on your regulatory 

requirements you should contact the appropriate agency in your state. 

New Jersey Right-To-Know Chemical List: 

Methanol (1222) 95 - 99.99 %weight Environmental Hazard 

Methanol (1222) 95 - 99.99 %weight Special Hazard 

Pennsylvania Right-To-Know Chemical List: 

Methanol (67-56-1) 95 - 99.99 %weight Environmental Hazard 

-------------------------------------------------------------------------------- 


-------------------------------------------------------------------------------- 

HMIS Rating (Health, Fire, Reactivity): 2, 3, 0 

Revision#: 0 


Revisions since last change (discussion): The Transportation Information - 

Section 14 of this Material Safety Data Sheet has been revised as of 12/14/00.

Changes have not been made to the health, safety or precautionary messages. 

We encourage you to take the opportunity to reread the sheet and review the 

information contained. 

-------------------------------------------------------------------------------- 

SECTION 17 LABEL INFORMATION 

-------------------------------------------------------------------------------- 

READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF 

PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD 

COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL 

IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND 

MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR 

OTHER RELATED REGULATORY REQUIREMENTS. 

PRODUCT CODES: 16968 

Windshield Washer Fluid Concentrate 

DANGER! 

EXTREMELY FLAMMABLE. MAY BE FATAL IF INHALED. HIGHLY TOXIC AND MAY BE FATAL 

IF SWALLOWED. CAUSES SEVERE EYE IRRITATION. TOXIC AND HARMFUL IF ABSORBED 

THROUGH THE SKIN. MAY CAUSE SKIN IRRITATION. 

Eye, Blood/Blood Forming Organs, Nervous System 

This material and/or components may cause the following effects: 

Developmental Toxicity 

Precautionary Measures: 

Avoid heat, sparks, open flames and other ignition sources. Avoid breathing 

of vapors, fumes, or mist. Do not take internally. Use only with adequate 

ventilation. Avoid contact with eyes, skin and clothing. Keep container 

closed when not in use. Wash thoroughly after handling. 

FIRST AID 

Inhalation: Move victim to fresh air and provide oxygen if breathing is 

difficult. Get medical attention. DO NOT attempt to rescue victim unless 

proper respiratory protection is worn. If the victim has difficulty breathing 

or tightness of the chest, is dizzy, vomiting or unresponsive, give 100% 

oxygen with rescue breathing or CPR as required and transport to the nearest 

medical facility. 

Skin Contact: Remove contaminated clothing, flush with large amounts of water 

for at least 15 minutes, by the clock, or longer depending on the 

concentration amount and duration of exposure. If redness, swelling, pain 

and/or blisters occur, transport to the nearest medical facility for 

additional treatment. 

Eye Contact: Immediately flush eyes with large amounts of water for at least 

30 minutes, by the clock, while holding eyelids open. Transport to nearest

medical facility for additional treatment. 

Ingestion: DO NOT take internally. DO NOT GIVE LIQUIDS TO A DROWSY, 

CONVULSING OR UNCONSCIOUS PERSON. Transport to nearest medical facility for 

additional treatment. 

FIRE 

In case of fire, Use water fog, foam, dry chemical or carbon dioxide (CO2) 

to extinguish flames. Do not use a direct stream of water. Material will 

float and can be re-ignited on surface of water. 

SPILL OR LEAK 

Dike and contain spill. 

FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels. 

FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or 

other suitable material. Place in non-leaking container and seal tightly for 

proper disposal. 

CONTAINS: Methanol, 67-56-1; Corrosion Inhibitor, 26038-90-4 

NFPA Rating (Health, Fire, Reactivity): 2, 3, 0 

HMIS Rating (Health, Fire, Reactivity): 2, 3, 0 

TRANSPORTATION 

US Department of Transportation Classification 

Proper Shipping Name: Flammable Liquid, N.O.S. 

Technical Names (s): Methanol 

Identification Number: UN1993 



Hazardous Substance/Material RQ: Methanol / 5005.005 lbs 

Emergency Response Guide # 128 

Name and Address 

Equilon Enterprises LLC 

P. O. Box 4453 

Houston, TX 77210-4453 

TRANSPORTATION EMERGENCY CHEMTEL (877) 276-7283 

HEALTH EMERGENCY CHEMTEL (877) 276-7283 

ADMINISTRATIVE INFORMATION 

COMPANY ADDRESS: Equilon Enterprises LLC, P. O. Box 4453, Houston, TX. 

77210-4453 

Company Product Stewardship & Regulatory Compliance Contact: Timothy W Childs 

Phone Number: (281) 874-7708 

MSDS FAX-BACK Phone Number: (877) 276-7285

THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO 

US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS 

PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD 

COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE 

INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH 

RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. 

YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR 

DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH 

SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. 

TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT 

TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE 

GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE 

RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE 

UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA, 

IS THE PROPERTY OF EQUIVA SERVICES LLC AND IS NOT TO BE THE SUBJECT OF SALE OR 

EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF EQUIVA SERVICES LLC. 

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35720-24876-100R-11/26/2001

form #5100-048-01, rev. date 3/10/06 

HMIS Rating 

WHMIS Hazard 

Class: Non-Hazardous 






YELLOW 77 ® Wire Pulling Lubricant 





(815) 895-5181 



HAZARDOUS MATERIAL DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS, HAZARD CLASS, HAZARD ID NO. (49 CFR 172.101) 

None 


FORMULA 

Water-Wax Emulsion 

Proprietary 






7732-18-5



None normally expected. Upon prolonged contact, may cause temporary eye 

discomfort. 


N.E. 

PRIMARY ROUTES OF ENTRY Inhalation Skin Contact Other (specify) 


SKIN CONTACT: Wash with soap and water for 15 minutes. 

EYE CONTACT: 

Flush with water for 15 minutes. Inhalation - Move to fresh air. 

INGESTION: 

Induce vomiting. Consult physician or local poison control center. 


STABILITY 

UNSTABLE 

STABLE X 



HAZARDOUS 


MAY OCCUR 


X 


Avoid strong oxidizers. 

None 

Excessive heat and burning may release oxides of carbon and nitrogen 




Wipe up, shovel or vacuum spilled material. Clean up spills immediately 

as they can be dangerously slippery. 





None Required 

None Required 

None 


2.7gms./ltr 




None normally required. 

LOCAL EXHAUST (Specify Rate) None SPECIAL None 

VENTILATION 







OTHER None 

Safety glasses or splash goggles. 

Eye fountain in work area is recommended. 



Store at temperatures between 40 - 120° F. Avoid freezing. 




If material is used in extreme heat (>120° F), prolonged and repeated exposure could pose a risk 

of pulmonary disease. Exposure below mist TLV (5mg/m) appears to be without risk. 

All components used in this product are exempt from the T.O.S.C.A chapter 15 reporting requirements. 



NAME James R. MacMurdo SIGNATURE 

TITLE Director, Corporate Quality Assurance 

DATE 02/11/09 

YELLOW 77 ® Wire Pulling Lubricant

Zep, Inc. 

1310 Seaboard Industrial Blvd. 


1-877-I-BUY-ZEP (428-9937) 

www.zep.com 

Printing date: 09/16/11 

Safety Data Sheet 

Section 1. Chemical Product and Company Identification 

Product name ZEP 45 

Product use Aerosol Lubricant 

Product code 0174 

Date of issue 09/16/11 

Emergency Telephone Numbers 

For MSDS Information: 

Compliance Services 1-877-I-BUY-ZEP (428-9937) 

For Medical Emergency 

(877) 541-2016 Toll Free - All Calls Recorded 

For Transportation Emergency 

CHEMTREC: (800) 424-9300 - All Calls Recorded 

In the District of Columbia (202) 483-7616 

Prepared By 

Compliance Services 



Supersedes 03/19/09 

Section 2. Hazards Identification 

Emergency overview 

*Hazard Determination System (HDS): Health, Flammability, Reactivity 

WARNING! 

VAPOR HARMFUL. CAUSES EYE, SKIN AND RESPIRATORY 

TRACT IRRITATION. HARMFUL IF INHALED OR ABSORBED 

THROUGH SKIN. CONTENTS UNDER PRESSURE. 

2 1 0 

NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all 

prescribed safety precautions, including the use of proper personal protective equipment. 

Acute Effects Routes of Entry Dermal contact. Eye contact. Inhalation. 

Eyes Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. 

Skin Causes skin irritation. Skin inflammation is characterized by itching, scaling, reddening or, 

occasionally, blistering. 

Inhalation Avoid inhalation of vapor, spray or mist. Over-exposure by inhalation may cause respiratory 

irritation. Can cause central nervous system (CNS) depression. Symptoms and signs include 

headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of 

consciousness. 

Ingestion Aspiration hazard if swallowed. Can enter lungs and cause damage. 

Chronic effects Repeated or prolonged exposure to the substance can produce damage to central nervous system, 

peripheral nervous system, kidneys, liver and heart. May cause hearing impairment or change. 

Prolonged skin contact may cause dermatitis with drying and cracking of skin. 


Trichloroethylene: Classified + (Proven) by OSHA. Classified Group 2A (Probable for Human) 

by IARC. Group 2 (Reasonably Anticipated To Be Human Carcinogen) by NTP. 

Product/ingredient name 

ACGIH IARC EPA NIOSH NTP OSHA 

Trichloroethylene - 2A - - Possible + 

Tetrachloroethylene - 2A- - Possible - 

Section 3. Composition/Information on Ingredients 

Additional Information: See Toxicological Information (Section 11) 

Name of Hazardous Ingredients CAS number % by Weight 

TRICHLOROETHYLENE; acetylene trichloride; 1-chloro-2,2-dichloroethylene 79-01-6 40 - 50 

PARAFFIN OIL; blend of heavy and light naphthenic petroleum distillate 64742-52-5 15 - 25 

MINERAL SEAL OIL; mineral oil; petrolatum 64741-44-2 5 - 15 

TETRACHLOROETHYLENE; perchloroethylene; perc; carbon bichloride 127-18-4 1 - 10 

Calcium alkylnaphthalenesulfonate Proprietary 1 - 10 

DIETHYLENE GLYCOL MONOBUTYL ETHER; 2-(2-butoxyethoxy)-ethanol; butyl carbitol 112-34-5 1 - 10 

PRIMARY AMYL ACETATE, MIXED ISOMERS: 3-METHYL BUTYL ACETATE; 2- 123-92-2: 628-63-7


Material Safety Data Sheet Product Name ZEP 45 

Section 4. First Aid Measures 

Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower 

eyelids. Check for and remove any contact lenses. Get medical attention immediately. 

Skin Contact Wash affected area with soap or mild detergent and water. Remove contaminated clothing and shoes. Continue 

to rinse for at least 10 minutes. Wash clothing before reuse. Get medical attention if irritation develops. 

Inhalation Move exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give 

oxygen. Get medical attention immediately. 

Ingestion Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting unless directed to do 

so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. 

Never give anything by mouth to an unconscious person. Get medical attention immediately. 

Section 5. Fire Fighting Measures 

National Fire Protection Association (U.S.A.) 

Flash Point Not applicable. 

2 


1 0 


Flammability Non-flammable. (CSMA) 

Fire hazard CONTENTS UNDER PRESSURE. Container explosion may occur under fire conditions or 

when heated. Vapors may accumulate in low or confined areas or travel a considerable distance 

to a source of ignition and flash back. 

Fire-Fighting 

Procedures 

Use dry chemical or CO2. Cool closed containers exposed to fire with water. Wear special 

protective clothing and positive pressure, self-contained breathing apparatus. 

Section 6. Accidental Release Measures 

Spill Clean up Large spills are unlikely due to packaging. 

Section 7. Handling and Storage 

Handling Put on appropriate personal protective equipment (see section 8). Avoid contact with eyes, skin and clothing. Do not 

breathe vapor or mist. Use only with adequate ventilation. Watch for accumulation in low confined areas. 

Storage Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 

10) and food and drink. Keep away from heat, sparks and flame. Do not puncture or incinerate container. Do not store 

above the following temperature: 49°C (120.2°F). Keep out of the reach of children. 

Section 8. Exposure Controls/Personal Protection 

Product name Exposure limits 

TRICHLOROETHYLENE; acetylene trichloride; 1-chloro-2,2dichloroethylene 

PARAFFIN OIL; blend of heavy and light naphthenic petroleum 

distillate 

Personal Protective Equipment (PPE) 

Eyes 

Body 

ACGIH TLV (United States). 



OSHA PEL (United States). 




TWA: 5 mg/m³ 8 hour(s). Form: Mist 



NIOSH REL (United States, 6/2009). 


STEL: 10 mg/m³ 15 minute(s). Form: Mist 

MINERAL SEAL OIL; mineral oil; petrolatum OSHA PEL (United States). 

: 5 mg/m³ 8 hour(s). Form: Mist 


: 5 ppm 8 hour(s). Form: Mist 

TETRACHLOROETHYLENE; perchloroethylene; perc; carbon 

bichloride 

PRIMARY AMYL ACETATE, MIXED ISOMERS: 3-METHYL 

BUTYL ACETATE; 2-METHYL BUTYL ACETATE 









CARBON DIOXIDE ACGIH TLV (United States). 



Recommended: Safety glasses. 

Recommended: Chemical-resistant gloves. Viton 

Page: 2/4



Respiratory Use with adequate ventilation. Provide exhaust ventilation or other engineering 

controls to keep the airborne concentrations of vapors below their respective 

occupational exposure limits. Use a properly fitted, air-purifying or air-fed 

respirator complying with an approved standard if a risk assessment indicates this 

is necessary. 

Section 9. Physical and Chemical Properties 

Physical State 

pH 

Boiling Point 

Specific Gravity 

Solubility 

Liquid. [Aerosol.] 


87.22°C (189°F) 

1.137 

Insoluble in the following materials: cold water and 

hot water. 

Section 10. Stability and Reactivity 

Color Brown. Oily liquid. 

Odor Sweet. [Strong] 

Vapor Pressure Not available. 

Vapor Density Not available. 

Evaporation Rate


Section 14. Transport Information 


Regulatory information UN number Proper shipping name Classes PG* Label 

DOT Classification None. 

Consumer commodity ORM-D ORM-D - 

IMDG Class Not determined. Not available. Not available. - 

NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to 

the Bill of Lading with your shipment. 

PG* : Packing group 

Section 15. Regulatory Information 


SARA 313 toxic chemical notification and release reporting: 

Product name 

Trichloroethylene 

Tetrachloroethylene 

Diethylene glycol monobutyl ether 

Clean Water Act (CWA) 307: Trichloroethylene (RQ 100 lbs.) 

Clean Water Act (CWA) 311: Trichloroethylene (RQ 100 lbs.) 

Clean Air Act (CAA) 112 regulated toxic substances: Trichloroethylene; Tetrachloroethylene; 

Diethylene glycol monobutyl ether 

All Components of this product are listed or exempt from listing on TSCA Inventory. 

TSCA 8(a) IUR: Distillates (petroleum), hydrotreated heavy naphthenic; Distillates (petroleum), 

straight-run middle 

United States inventory (TSCA 8b): Not determined. 


California Prop 65 

Section 16. Other Information 

WARNING: This product contains a chemical or chemicals known to the state 

of California to cause cancer, birth defects or other reproductive harm.: 

Trichloroethylene; Tetrachloroethylene 

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any 

liability whatsoever for the accuracy or completeness of the information contained herein. 

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. 

Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 

*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks 

Although these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to 

relay the meanings of this scale.


ZEP MANUFACTURING COMPANY 

Acuity Specialty Products Group, Inc. 

P.O. BOX 2015 

ATLANTA, GA 30301 

1- 877- I - BUY- ZEP 

Issue Date 

Supersedes 

Product No. 


and Safe Handling and Disposal Information 

11/01/95 

05/03/95 

SECTION I - EMERGENCY CONTACTS 

SECTION II - HAZARDOUS INGREDIENTS 

** D-LIMONENE ** orange distillate; citrus terpene; cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)-; CAS# 5989-27-5; RTECS# 

GW6360000; OSHA PEL N/D; TLV - N/D; EFFECTS - CBL SEN; % IN PROD - < 5 

@ -Reportable under the SARA 313 Toxic Release Inventory 

SECTION III - HEALTH HAZARD DATA 

SPECIAL NOTE: MSDS data pertains to the product as dispensed from the container. Adverse health effects would not be expected under 

recommended conditions of use (diluted) so long as prescribed safety precautions are practiced. 

ACUTE EFFECTS OF OVEREXPOSURE: 

This product can be an eye irritant. Inflammation of eye tissue is characterized by redness, watering, and/or itching. One of the ingredients in 

this product has caused sensitization reactions in a small percentage of the general population. 

CHRONIC EFFECTS OF OVEREXPOSURE: 

There are no known effects from chronic exposure to this product. None of the ingredients are listed as carcinogens by IARC, NTP, or 

OSHA. 

EST'D PEL/TLV: Not established 

PRIMARY ROUTES OF ENTRY: N/A 

HMIS CODES: HEALTH 0; FLAM 0; REACT 0; PERS. PROTECT N/A; CHRONIC HAZ NO 

FIRST AID PROCEDURES: 

SKIN: This product is formulated for use on skin. If irritation occurs, wash skin with soap and water. Get medical attention if irritation persists. 

EYES: Immediately flush eyes with plenty of water for at least 15 minutes. If irritation develops, consult a physician. 

INHALE: This route of exposure is not likely due to product nature. 

INGEST: This route of exposure is not likely due to product nature. 

PROTECTIVE CLOTHING: No special measures are required. 

EYE PROTECTION: No special measures are required. 

RESPIRATORY PROTECTION: No special measures are required. 

VENTILATION: No special measures are required. 

Product Name 

Hand Cleaning Towel 

1000 

SECTION IV - SPECIAL PRECAUTION INFORMATION 

SECTION V - PHYSICAL DATA 

BOILING POINT (F) - N/A SPECIFIC GRAVITY - 

VAPOR PRESSURE(mmHg) - N/A EVAPORATION RATE ( =1) - N/A 

VAPOR DENSITY(AIR-1) - N/A pH(CONCENTRATE) - N/A 

SOLUBILITY IN WATER - N/A 

pH(USE DILUTION OF) - N/A 

VOC CONTENT (CONCENTRATE) - 3.3% 

APPERANCE AND ODOR - AN ORANGE TOWEL WITH AN ORANGE FRAGRANCE. 

SECTION VI - FIRE AND EXPLOSION DATA 

FLASH POINT(F) (METHOD USED): N/A 

FLAMMABLE LIMITS:LEL: N/A UEL: N/A 

EXTINGUISHING MEDIA: Carbon dioxide, dry chemical and foam. 

SPECIAL FIRE FIGHTING: None 

UNUSUAL FIRE HAZARDS: Potential fire hazard if exposed to an ignition source. 

ZEP CLEAN 'EMS 


Acuity Specialy Products Group, Inc. 

Compliance Services 1-877-I-BUY-ZEP 

For Medical Emergency: 

INFOTRAC 


For a Transportation Emergency: 

CHEMTREC 

(800) 424-9300 - All Calls Recorded 


Page: 1/2

Product No. 1000 Product name: ZEP CLEAN 'EMS 


SECTION VII - REACTIVITY DATA 

STABILITY: Stable 

INCOMPATIBILITY(AVOID): Heat, flame, spark, strong acids and/or oxidizers. 

POLYMERIZATION: Will not occur. 

HAZARDOUS DECOMPOSITION: Carbon dioxide, carbon monoxide, and other unidentified organic compounds. 

SECTION VIII - SPILL AND DISPOSAL PROCEDURES 

STEPS TO BE TAKEN IN CASE MATERIALS IS RELEASED OR SPILLED: 

Observe safety precautions in sections 4 & 9 during clean-up. Spills are not expected due to the nature of the product. If material is dropped 

or contaminated, pick up and place in a suitable waste container. Wash area with a detergent solution and rinse well with water. 

WASTE DISPOSAL METHOD: 

This product is not considered a hazardous waste under RCRA. Place used product in an appropriate waste container. Care should be 

taken to prevent contact with all ignition sources. 

RCRA HAZ WASTE NOS: N/A 

SECTION IX - SPECIAL PRECAUTIONS 

PRECAUTIONS TO BE TAKEN WHEN HANDLING AND STORING 

Store tightly closed container in a dry area at temps. between 40-120 degrees F. Keep product out of eyes. Keep out of the reach of children. 

SECTION X - REGULATORY INFORMATION 

DOT PROPER SHIPPING NAME: INDUSTRIAL CLEANERS N.O.I.,LIQUID KEEP FROM FREEZING 

NOTE: DOT information applies to larger package sizes of affected products. For some products, DOT may require alternate names and 

labeling in accordance with packaging group requirements. 

DOT HAZARD CLASS: NA DOT PACKING GROUP: 

DOT I.D. NUMBER: DOT LABEL/PLACARD: 

EPA TSCA CHEMICAL INVENTORY - ALL INGREDIENTS ARE LISTED 

EPA CWA 40CFR PART 117 SUBSTANCE(RQ IN A SINGLE CONTAINER): NONE 

EPA CAA: N/A

NOTICE 

Thank you for your interest in, and use of, this product. Acuity Specialty Products 

Group is pleased to be of service to you by supplying this Material Safety 

Data Sheet for your files. Acuity Specialty Products Group is concerned for 

your health and safety. This product and all others supplied by Acuity Specialty 

Products Group companies can be used safely with proper protective equipment 

and proper handling practices consistent with label instructions and the MSDS. 

Before using any this product, be sure to read the complete label and the Material 

Safety Data Sheet. 

As a further word of caution, Acuity Specialty Products Group wishes to advise 

that serious accidents have resulted from the misuse of “emptied” containers. 

“Empty” containers retain residue (liquid and/or vapor) and can be dangerous. 

DO NOT pressurize, cut, weld, braze, solder, drill, grind or expose such containers 

to heat, flame, sparks, or other sources of ignition; they may explode or 

develop harmful vapors and possibly cause injury or death. Clean empty containers 

by triple rinsing with water or an appropriate solvent. Empty containers 

must be sent to a drum reconditioner before reuse. 

TERMS AND ABBREVIATIONS 

Listed Alphabetically by Section 

SECTION II: HAZARDOUS INGREDIENTS 

CAR: Carcinogen - A chemical listed by the National Toxicology Program 

(NTP), the International Agency for Research on Cancer (IARC) or OSHA as a 

definite or possible human cancer causing agent. 

CAS#: Chemical Abstract Services Registry Number - A universally accepted 

numbering system for chemical substances. 

CBL: Combustible - At temperatures between 100°F and 200°F chemical gives 

off enough vapor to ignite if a source of ignition is present as tested with a 

closed cup tester. 

CNS: Central Nervous System depressant that reduces the activity of the brain 

and spinal cord. 

COR: Corrosive - Causes irreversible injury to living tissue (e.g. burns). 

DESIGNATIONS: Chemical and common names of hazardous ingredients. 

EIR: Eye Irritant Only - Causes reversible reddening and/or inflammation of eye tissues. 

EXPOSURE LIMITS: The time weighted average (TWA) airborne concentration 

at which most workers can be exposed without any expected adverse effects. 

Primary sources include ACGIH TLVs, and OSHA PELs. 

ACGIH: American Conference of Governmental Industrial Hygienists 

CEILING: "The concentration that should not be exceeded in the workplace 

during any part of the working exposure." Source, ACGIH 

OSHA: Occupational Safety and Health Administration. 

PEL: Permissible Exposure Limit - A set of time weighted average exposure 

values, established by OSHA, for a normal 8-hour day and a 40-hour workweek. 

PPM: Parts per million - unit of measure for exposure limits. 

(S) SKIN: Skin contact with substance can contribute to overall exposure. 

STEL: Short Term Exposure Limit - Maximum concentration for a continuous 

15-minute exposure period. 

TLV: Threshold Limit Value - A set of time weighted average exposure limits, 

established by the ACGIH, for a normal 8-hour day and a 40-hour workweek. 

FBL: Flammable - At temperatures under 100°F, chemical gives off enough vapors 

to ignite if a source of ignition is present as tested with a closed cup tester. 

HAZARDOUS INGREDIENTS: Chemical substances that are determined to 

be potential health or physical hazards based on the criteria established in the 

OSHA Hazard Communication Standard - 29 CFR 1910.1200 

HTX: Highly toxic - the probable lethal dose for a 70 kg (150 lb.) man, which 

may be approximated as less than 6 teaspoons (2 tablespoons) 

IRR: Irritant - Causes reversible effects in living tissues (e.g. inflammation) - 

primarily skin and eyes. 

N/A: Not Applicable - Category is not appropriate for this product. 

N/D: Not Determined - Insufficient information to make a determination for this 

item. 

RTECS#: Registry of Toxic Effects of Chemical Substances - an unreviewed 

listing of published toxicology data on chemical substances. 

SARA: Superfund Amendment and Reauthorization Act - Section 313 designates 

certain chemicals for possible reporting for the Toxic Chemical Release Inventory. 

SEN: Sensitizer - Causes allergic reaction after repeated exposure. 

TOX: Toxic - The probable lethal dose for a 70 kg (150 kg) man is one ounce 

(2 tablespoons) or more. 

SECTION III: HEALTH HAZARD DATA 

ACUTE EFFECT: An adverse effect on the human body from a single exposure 

with symptoms developing almost immediately after exposure or within a 

relatively short time. 


CHRONIC EFFECT: Adverse effects that are most likely to occur from repeated 

exposure over a long period of time. 

EST'D PEL/TLV: This estimated, time-weighted-average, exposure limit, developed 

by using a formula provided by the ACGIH, pertains to airborne concentrations 

from the product as a whole. This value should serve as guide for 

providing safe workplace conditions to nearly all workers. 

HMIS CODES: Hazardous Material Identification System - a rating system 

developed, by the National Paint and Coating Association for estimating the 

hazard potential of a chemical under normal workplace conditions. These risk 

estimates are indicated by a numerical rating given in each of three hazard areas 

(Health/ Flammability/Reactivity) ranging from a low of zero to a high of 4. 

The presence of a chronic hazard is indicated by a "YES". Consult HMIS training 

guides for Personal Protection letter codes, which indicate necessary protective 

equipment. 

PRIMARY ROUTE OF ENTRY: The way one or more hazardous ingredients 

may enter the body and cause a generalized systemic or specific-organ toxic effect. 

ING: Ingestion - A primary route of exposure through swallowing of material. 

INH: Inhalation - A primary route of exposure through breathing of vapors. 

SKIN: A primary route of exposure through contact with the skin. 

SECTION IV: SPECIAL PROTECTION INFORMATION 

Where respiratory protection is recommended, use only MSHA and NIOSH approved 

respirators and dust masks. 

MSHA: Mine Safety and Health Administration 

NIOSH: National Institute for Occupational Safety and Health. 

SECTION V: PHYSICAL DATA 

EVAPORATION RATE: Refers to the rate of change from the liquid state to 

the vapor state at ambient temperature and pressure in comparison to a given 

substance (e.g. water). 

pH: A value representing the acidity or alkalinity of an aqueous solution 

(Highly Acidic pH = 1; Neutral pH = 7; Highly Alkaline pH = 14) 

VOC CONTENT: The percentage or amount in pounds per gallon of the product 

that is regulated as a Volatile Organic Compound under the Clean Air Act 

of 1990 and various state jurisdictions. 

SOLUBILITY IN WATER: A description of the ability of the product to dissolve 

in water. 

SECTION VII: REACTIVITY DATA 

HAZARDOUS DECOMPOSITION: Breakdown products expected to be 

produced upon product decomposition by extreme heat or fire. 

INCOMPATIBILITY: Keep product away from listed substances or conditions 

to prevent hazardous reactions. 

POLYMERIZATION: Indicates the tendency of the product's molecules to combine 

with themselves in a chemical reaction releasing excess pressure and heat. 

STABILITY: Indicates the susceptibility of the product to decompose spontaneously 

and dangerously. 

SECTION VIII: SPILL AND DISPOSAL PROCEDURES 

RCRA WASTE NOs: RCRA (Resource Conservation and Recovery Act) 

waste codes (40 CFR 261) applicable to the disposal of spilled or unusable 

product from the original container. 

SECTION X: TRANSPORTATION DATA 

CWA: Clean Water Act - Federal law that regulates chemical releases to bodies 

of water. 

RQ: Reportable Quantity - The amount of the specific ingredient that, when 

spilled to the ground and, can enter a storm sewer or natural watershed, must be 

reported to the National Response Center, and other regulatory agencies. 

TSCA: Toxic Substances Control Act - A federal law requiring all commercial 

chemical substances to appear on an inventory maintained by the EPA. 

DISCLAIMER 

All statements, technical information, and recommendations contained herein 

are based on available scientific tests or data that we believe to be reliable. The 

accuracy and completeness of such data are not warranted or guaranteed. We 

cannot anticipate all conditions under which this information and our products, 

or the products of other manufacturers in combination with our products, may 

be used. Acuity Specialty Products Group assumes no liability or responsibility 

for loss or damage resulting from the improper use or handling of our products, 

from incompatible product combinations, or from the failure to follow instructions, 

warnings, and advisories in the product label and Material Safety Data 

Sheet 

(rev 06/02)

Zep, Inc. 



1-877-I-BUY-ZEP (428-9937) 

www.zep.com 



Product name LUBEZE DRILL CHILL 

Product use Aerosol Cutting Oil 











Prepared By 








WARNING ! 

CAUSES EYE IRRITATION. CONTENTS UNDER PRESSURE. 

1 1 0 



Acute Effects Routes of Entry Eye contact. Inhalation. 


Skin May cause skin irritation. Skin inflammation is characterized by itching, scaling, or reddening. 

Inhalation Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. 

Ingestion May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause 

damage. 

Chronic effects Prolonged or repeated contact may dry skin and cause irritation. Repeated or prolonged exposure 

to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial 

infection. 



Product/ingredient name 

None. 


ACGIH IARC EPA NIOSH NTP OSHA 



MINERAL OIL; Hydrotreated middle petroleum distillates 64742-46-7 80 - 90 

BLEND OF ISOBUTANE & PROPANE 74-98-6; 75-28-5 1 - 10 

Eye Contact 

Skin Contact 

Inhalation 

Ingestion 



Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and 

remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. 

Flush affected skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. 

Get medical attention if irritation develops. 

Move exposed person to fresh air. If irritation persists, get medical attention. 

Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting unless directed to do 

so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. 


Page: 1/3



Material Safety Data Sheet Product Name LUBEZE DRILL CHILL 


Flash Point Not available. 

1 


1 0 


Flammability Non-flammable. (CSMA) 

Fire hazard CONTENTS UNDER PRESSURE. In a fire or if heated, a pressure increase will occur and the 

container may burst. Bursting aerosol containers may be propelled from a fire at high speed. 

Fire-Fighting 

Procedures 

Use an extinguishing agent suitable for the surrounding fire. 


Spill Clean up Spills are unlikely due to packaging. 


Handling 

Storage 

Put on appropriate personal protective equipment (see section 8). Avoid contact with eyes, skin and clothing. Do not 

ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Empty containers retain product residue 

and can be hazardous. Wash thoroughly after handling. 

CONTENTS UNDER PRESSURE. Store away from direct sunlight in a dry, cool and well-ventilated area, away from 

incompatible materials (see section 10) and food and drink. Do not puncture, incinerate or store the container at 

temperatures above 49°C (120°F) or in direct sunlight. Keep out of the reach of children. 



MINERAL OIL; Hydrotreated middle petroleum distillates ACGIH TLV (United States). 




BLEND OF ISOBUTANE & PROPANE ACGIH TLV (United States). 





Eyes 

Body 

Respiratory 


pH 

Boiling Point 


Solubility 

Safety glasses. 

Recommended: Neoprene gloves. Nitrile gloves. Rubber gloves. 

Use with adequate ventilation. Provide exhaust ventilation or other engineering 


occupational exposure limits. 


Liquid. [Aerosol. ] 



0.91 

Insoluble in the following materials: cold water and 

hot water. 


Color Dark Brown. 

Odor Solvent-like. 

Vapor Pressure Not determined. 

Vapor Density Not determined. 

Evaporation Rate Not determined. 

VOC (Consumer) 10.0% 0.76 lb/gal 90.8 g/l 

Stability and Reactivity The product is stable. 

Incompatibility 

Reactive or incompatible with the following materials: oxidizing materials. 


Hazardous Decomposition Products carbon oxides (CO, CO2), sulfur oxides (SO2, SO3 etc.) 

Section 11. Toxicological Information 


Page: 2/3


Section 12. Ecological Information 

Environmental Effects Not available. 

Aquatic Ecotoxicity 


Section 13. Disposal Considerations 

Material Safety Data Sheet Product Name LUBEZE DRILL CHILL 

Waste Information 

Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or 

regional authorities for additional information. 

Waste Stream Classification: - [Non-hazardous waste] 



DOT Classification 

IMDG Class 

Consumer commodity ORM-D - 







No products were found. 

Clean Water Act (CWA) 307: No products were found. 


Clean Air Act (CAA) 112 regulated toxic substances: No products were found. 













ZEP Inc. 

11627 178th Street 

Edmonton, Alberta T5S 1N6 

1-877-I-BUY-ZEP (428-9937) 

www.zep.com 



Product name GOLD TOUCH 

Product use Hand Cleaner. 





Technical Services Group 

Telephone (780) 453-8100 

(Business Hours 8:00am - 5:00pm) 

For Medical or Transportation Emergency 

CANUTEC (24 Hours) 

(613) 996-6666 - Call Collect 

Prepared By 







CAUTION 

MAY CAUSE EYE IRRITATION. 



Acute Effects Routes of Entry Not applicable. 

Eyes May cause eye irritation. Inflammation of the eye is characterized by redness, watering and 

itching. 

Skin No known acute effects of this product resulting from skin contact. 

Inhalation No known acute effects of this product resulting from inhalation. Inhalation not likely under 

normal use conditions. 

Ingestion No data on acute toxicity of the product when ingested. 

Chronic effects No known chronic effects from exposure. 




PROPYLENE GLYCOL; 1,2-dihydroxypropane,1,2-propanediol 57-55-6 1 - 5 


Eye Contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and 

remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. 

Skin Contact This product is formulated for use on the skin. Discontinue use if irritation and redness develop. 

Inhalation Inhalation not likely under normal use conditions. 

Ingestion Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an 

unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention. 

Flash Point 



None. 

Flammable Limits Not applicable 

Flammability Non-combustible. 

Auto-ignition Temperature 

Fire-Fighting Procedures Use an extinguishing agent suitable for the surrounding fire. 

Fire hazard No known significant effects or critical hazards. 

Products of Combustion carbon oxides (CO, CO2) and sulfur oxides (SO2, SO3 etc.) 

Explosion hazard 

Page: 1/3



Material Safety Data Sheet Product Name GOLD TOUCH 

Spill Clean up Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry 

material and place in an appropriate waste disposal container. 


Handling 

Storage 

Avoid contact with eyes. Do not ingest. Wash contaminated clothing before reusing. Do not reuse container. 

Protect from freezing. Store between the following temperatures: 40°F - 120°F (4.4°C - 49°C). Keep out of the reach of 

children. 



No exposure limit value known. 


Eyes 

Hands and 

Body 

Respiratory 


pH 

Boiling Point 


Solubility 

No special protection is required. 

No special protection is required. 

No special ventilation requirements. 


Freezing Point 

Slightly Viscous liquid. 

8.5 - 9.5 

100°C (212°F) 

1.03 

Easily soluble in the following materials: cold water 

and hot water. 


Color Amber. 

Odor Lemon-lime. 



Evaporation Rate 1 (Water = 1) 

VOC (Consumer) 0 (g/l). 



None identified. 


Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be 

produced. 


Carcinogenicity Ingredients: Not listed as carcinogen by OSHA, NTP or IARC. 



Environmental Effects No known significant effects or critical hazards. 





Waste must be disposed of in accordance with applicable regulations. Consult your local or regional authorities for additional information. 

Waste Stream Non-hazardous waste 



TDG Classification Not regulated. 

IMDG Class 


Page: 2/3 

Additional information



Material Safety Data Sheet Product Name GOLD TOUCH 


the Bill of Lading with your shipment. Limited Quantity: Small quantities of controlled goods are not regulated as Dangerous 

Goods according to TDG regulations. 


Canada 

WHMIS (Canada) Not controlled under WHMIS (Canada). 

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information 

required by the Controlled Products Regulations. 





Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Zep Sales & Service, A Unit of Zep Inc. 



1-877-I-BUY-ZEP (428-9937) 

www.zep.com 




Product name MEASURE UP #8 - MULTI-PURPOSE 

DEGREASER CONCENTRATE 

Product use General Purpose Degreaser 


Date of issue 04/28/08 Supersedes 08/22/03 





INFOTRAC: (877) 541-2016 Toll Free - All Calls 

Recorded 




Prepared By 







WARNING ! 

CAUSES EYE AND SKIN IRRITATION. 

1 0 0 



Acute Effects Routes of Entry Dermal contact. Eye contact. 


Skin No known acute effects of this product resulting from skin contact. Prolonged or repeated 

contact may dry skin and cause irritation. 

Inhalation Over-exposure by inhalation may cause respiratory irritation. 

Ingestion May be harmful if swallowed. May irritate digestive tract. 

Chronic effects Prolonged or repeated contact may dry skin and cause irritation. 




SODIUM SILICATE; water glass 1344-09-8 1 - 5 

DIPROPYLENE GLYCOL METHYL ETHER; dipropylene glycol monomethyl ether 34590-94-8 1 - 5 

SODIUM DODECYLBENZENE SULFONATE; linear alkyl aryl sodium sulfonate; Sodium 

DDBSA 

25155-30-0 1 - 5 


Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Check for and remove any 

contact lenses. Get medical attention. 

Skin Contact Rinse with plenty of running water. If irritation persists, get medical attention. 

Inhalation If inhaled, remove to fresh air. If irritation persists, get medical attention. 

Ingestion Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an 

unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention 

immediately. 

Page: 1/3



Flash Point Not applicable 

Flammable Limits Not applicable 

Flammability Non-combustible. 

Fire hazard Not applicable. 

Fire-Fighting 

Procedures 



Material Safety Data Sheet Product Name MEASURE UP #8 - MULTI- 

PURPOSE DEGREASER 

CONCENTRATE 


Spill Clean up Put on appropriate personal protective equipment (see section 8). Dilute with water and mop up, or absorb with 

an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on 

the contaminated surface and dispose of according to local and regional authority requirements. 


Handling 

Storage 

1 0 0 

Avoid contact with eyes, skin and clothing. Do not ingest. Wash thoroughly after handling. 

Keep container tightly closed. Store between the following temperatures: 40°F - 120°F (4.4°C - 49°C). Keep out of the 

reach of children. 



SODIUM SILICATE; water glass Supplier Suggested (United States). 

CEIL: 2 mg/m³ 

DIPROPYLENE GLYCOL METHYL ETHER; dipropylene glycol ACGIH TLV (United States, 2003). Skin 

monomethyl ether 



OSHA PEL (United States, 2003). Skin 



Eyes 

Body 

Respiratory 


pH 

Boiling Point 


Solubility 


For prolonged or repeated handling, use gloves. Nitrile gloves. 

Rubber gloves. Neoprene gloves. 

Use with adequate ventilation. A respirator is not needed under normal and 

intended conditions of product use. 


Liquid. 

11.5 - 12.5 

104.44°C (220°F) 

1.04 




Color Clear. Green. 

Odor Mild. 



Evaporation Rate 1 compared with Water 

VOC (Consumer) 4.87% 0.42 (lb/gal) 51 (g/l). 



Slightly reactive or incompatible with the following materials: oxidizing materials and acids. 


Hazardous Decomposition Products None identified. 



Product/ingredient name Result Species Dose Exposure 

Sodium Silicate LD50 Oral Rat 3300 mg/kg - 

Dipropylene Glycol Methyl Ether LD50 Dermal Rabbit 13000 mg/kg - 

LD50 Oral Rat 5220 mg/kg - 

Sodium Dodecylbenzene Sulfonate LD50 Oral Mouse 2000 mg/kg - 


Page: 2/3







Material Safety Data Sheet Product Name MEASURE UP #8 - MULTI- 

PURPOSE DEGREASER 

CONCENTRATE 


Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or 

regional authorities for additional information. 




DOT Classification 

IMDG Class 


None. - - 

Not available. Not available. Not available. - 









Clean Water Act (CWA) 311: Sodium Dodecylbenzene Sulfonate 

Clean Air Act (CAA) 112 regulated toxic substances: No products were found. 













ZEP Inc. 



1-877-I-BUY-ZEP (428-9937) 

www.zep.com 




Product name ZEP POWERHOUSE 

Product use Stripper 






Telephone (780) 453-8100 

(Business Hours 8:00am - 5:00pm) 



DANGER ! 

CAUSES EYE BURNS. CAUSES SKIN IRRITATION. MAY BE 

HARMFUL IF ABSORBED THROUGH SKIN. 

CONTENTS UNDER PRESSURE. 

For Medical or Transportation Emergency 

CANUTEC (24 Hours) 

(613) 996-6666 - Call Collect 

Prepared By 







Acute Effects Routes of Entry Dermal contact. Eye contact. Inhalation. 

Eyes Causes eye burns. Direct contact with the eyes can cause irreversible damage, including 

blindness. 

Skin Causes skin irritation. May be harmul if absorbed through the skin. Prolonged exposure may 

result in skin burns and ulcerations. Skin inflammation is characterized by itching, scaling, 

reddening or, occasionally, blistering. 

Inhalation Avoid breathing vapors, spray or mists. Over-exposure by inhalation may cause respiratory 

irritation. Can cause central nervous system (CNS) depression. 

Ingestion May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause 

damage. Ingestion may cause nausea, weakness and central nervous system effects. 

Chronic effects Overexposure of this product by inhalation or absorption can produce central nervous system 

depression resulting in headache, nausea and/or dizziness. Repeated or prolonged exposure to 

spray or mist may produce respiratory tract irritation leading to frequent attacks of bronchial 

infection. Repeated or prolonged contact with spray or mist may produce chronic eye irritation 

and severe skin irritation. Contains material which may cause damage to the following organs: 

blood, kidneys, lungs, liver, upper respiratory tract, skin, eyes, central nervous system (CNS), 

ears. 




ETHANOL; ethyl alcohol; grain alcohol 64-17-5 10 - 30 

HYDROCARBON PROPELLANT; blend of propane and n-butane 74-98-6; 106-97-8 3 - 7 

MONOETHANOLAMINE; 2-aminoethanol; MEA 141-43-5 1 - 5 

ISOPROPYL ALCOHOL; ipa; dimethylcarbinol; 2-propanol 67-63-0 1 - 5 

ETHYLENE GLYCOL MONOBUTYL ETHER; 2-butoxyethanol; butyl cellosolve 111-76-2 1 - 5 

METHANOL; methyl alcohol; wood alcohol; columbia spirits 67-56-1 1 - 5 

Page: 1/4



Eye Contact 

Skin Contact 

Inhalation 

Ingestion 

Flash Point 

Material Safety Data Sheet Product Name ZEP POWERHOUSE 

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and 

remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. 

Flush affected skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 

10 minutes. Wash clothing before reuse. Get medical attention if irritation develops. 

Move exposed person to fresh air. If irritation persists, get medical attention. 

Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be 

kept low so that vomit does not enter the lungs. If affected person is conscious, give plenty of water to drink. 



Closed cup: 29.4°C (84.9°F) 

Flammable Limits Not available. 

Flammability Non-flammable. (CSMA Method) 

Auto-ignition Temperature 

Fire-Fighting Procedures Use an extinguishing agent suitable for the surrounding fire. Cool closed containers exposed to 

fire with water. Fire-fighters should wear appropriate protective equipment. 

Fire hazard CONTENTS UNDER PRESSURE. In a fire or if heated, a pressure increase will occur and 

the container may burst, with the risk of a subsequent explosion. Bursting aerosol containers 

may be propelled from a fire at high speed. 

Products of Combustion carbon oxides (CO, CO2) and nitrogen oxides (NO, NO2 etc.) 

Explosion hazard 


Spill Clean up Large spills are unlikely due to packaging. 


Handling 

Storage 

Put on appropriate personal protective equipment (see section 8). Store and use away from heat, sparks, open flame 

or any other ignition source. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Do not 

breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Observe label precautions. Wash 

contaminated clothing before reusing. Wash thoroughly after handling. 

CONTENTS UNDER PRESSURE. Do not puncture, incinerate or store the container at temperatures above 49°C 

(120°F) or in direct sunlight. Keep away from food, drink and animal feeding stuffs. Keep out of the reach of children. 



Ethanol ACGIH TLV / OSHA PEL (United States). 


Propellant; Blend of Isobutane, Propane and n-Butane ACGIH TLV / OSHA PEL (United States). Notes: Propane 


Monoethanolamine OSHA PEL / ACGIH TLV (United States). 


OSHA /ACGIH (United States). 


Ethylene Glycol Monobutyl Ether ACGIH TLV (United States). 

TWA: 20 ppm 8 hour(s). Form: 

OSHA PEL (United States). Skin 

TWA: 50 ppm 8 hour(s). Form: 

Isopropyl Alcohol ACGIH TLV (United States). 




ACGIH/OSHA (United States). 



Eyes 

Hands and 

Body 

Respiratory 


Recommended: Neoprene gloves. Nitrile gloves. Rubber gloves. 

Use with adequate ventilation. Provide exhaust ventilation or other engineering 


occupational exposure limits. 

Page: 2/4




pH 

Boiling Point 


Solubility 

Freezing Point 

Liquid. [Aerosol.] 

10.5 - 11.5 

98.3°C (208.9°F) 

0.97 





Color Clear. Colorless. 

Odor Pine. 



Evaporation Rate 1000 mg/kg - 



propan-2-ol LC50 Inhalation Vapor Rat 16000 ppm 4 hours 

LD50 Dermal Rabbit 5030 mg/kg - 



2-butoxyethanol LC50 Inhalation Gas. Rat 450 ppm 4 hours 

LC50 Inhalation Vapor Guinea pig >633 ppm 1 hours 

LD50 Dermal Guinea pig >2000 mg/kg - 


LD50 Oral Guinea pig 1200 mg/kg - 


methanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours 

LC50 Inhalation Gas. Rat 64000 ppm 4 hours 

LC50 Inhalation Vapor Rat 64000 ppm 4 hours 










Waste must be disposed of in accordance with applicable regulations. Consult your local or regional authorities for additional information. 


Page: 3/4






TDG Classification 1950 Aerosols, non-flammable 2.2 - 

IMDG Class 



the Bill of Lading with your shipment. Limited Quantity: Small quantities of controlled goods are not regulated as Dangerous 

Goods according to TDG regulations. 


Canada 

WHMIS (Canada) Class A: Compressed gas. 

Class D-2B: Material causing other toxic effects (Toxic). 

2 

Additional information 

Explosive Limit 

and Limited 

Quantity Index 

1 

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information 

required by the Controlled Products Regulations. 





Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

41303 

05 00 


SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NUMBER 

41303 

PRODUCT NAME 

KRYLON® Crystal Clear Spray Coating 

MANUFACTURER'S NAME 

SHERWIN-WILLIAMS CANADA INC. 

KRYLON Products Group 

Vaughan, ON L4K 4T8 

Telephone Numbers and Websites 

Product Information (800) 832-2541 

Regulatory Information (216) 566-2902 

www.paintdocs.com 

Medical Emergency (216) 566-2917 

Transportation Emergency* (800) 424-9300 

* for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) 

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS 

DATE OF PREPARATION 

Nov 28, 2010 

% by Weight CAS Number Ingredient Units Vapor Pressure 

14 74-98-6 Propane 



13 106-97-8 Butane 



17 108-88-3 Toluene 


OSHA PEL 100 ppm (Skin) 

OSHA PEL 150 ppm (Skin) STEL 

3 64742-94-5 Medium Aromatic Hydrocarbons 

ACGIH TLV Not Available 0.12 mm 

OSHA PEL Not Available 

0.4 91-20-3 Naphthalene 


ACGIH TLV 15 PPM STEL 


OSHA PEL 15 PPM STEL 

41 67-64-1 Acetone 


ACGIH TLV 750 PPM STEL 


4 763-69-9 Ethyl 3-Ethoxypropionate 

ACGIH TLV Not Available 1.11 mm 

OSHA PEL Not Available 

SECTION 3 — HAZARDS IDENTIFICATION 

ROUTES OF EXPOSURE 

INHALATION of vapor or spray mist. 

EYE or SKIN contact with the product, vapor or spray mist. 

EFFECTS OF OVEREXPOSURE 

EYES: Irritation. 

SKIN: Prolonged or repeated exposure may cause irritation. 

INHALATION: Irritation of the upper respiratory system. 

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. 

HMIS Codes 

Health 2* 

Flammability 4 

Reactivity 0 

page 1 of 4

41303 

Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: 

the liver 

the urinary system 

the cardiovascular system 

the reproductive system 

SIGNS AND SYMPTOMS OF OVEREXPOSURE 

Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. 

Redness and itching or burning sensation may indicate eye or excessive skin exposure. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE 

None generally recognized. 

CANCER INFORMATION 

For complete discussion of toxicology data refer to Section 11. 

SECTION 4 — FIRST AID MEASURES 

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. 

SKIN: Wash affected area thoroughly with soap and water. 

Remove contaminated clothing and launder before re-use. 

INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. 

INGESTION: Do not induce vomiting. Get medical attention immediately. 

SECTION 5 — FIRE FIGHTING MEASURES 

FLASH POINT 

LEL UEL EXTINGUISHING MEDIA 

Propellant < 0 °F 

0.8 

12.8 Carbon Dioxide, Dry Chemical, Foam 


Containers may explode when exposed to extreme heat. 

Application to hot surfaces requires special precautions. 

During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately 

apparent. Obtain medical attention. 


Full protective equipment including self-contained breathing apparatus should be used. 

Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure 

build-up and possible autoignition or explosion when exposed to extreme heat. 

SECTION 6 — ACCIDENTAL RELEASE MEASURES 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

Remove all sources of ignition. Ventilate the area. 

Remove with inert absorbent. 

SECTION 7 — HANDLING AND STORAGE 

STORAGE CATEGORY 

Not Available 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE 

Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. 

During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off 

stoves, electric tools and appliances, and any other sources of ignition. 

Consult NFPA Code. Use approved Bonding and Grounding procedures. 

Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, 

and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. 

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION 

PRECAUTIONS TO BE TAKEN IN USE 


Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. 

Wash hands after using. 

This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels 

only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are 

ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). 

VENTILATION 

Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. 

Refer to OSHA Standards 1910.94, 1910.107, 1910.108. 


If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator 

approved by NIOSH/MSHA for protection against materials in Section 2. 

page 2 of 4

41303 

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this 

product, underlying paint, or the abrasive. 

PROTECTIVE GLOVES 

None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical 

resistant gloves. 

EYE PROTECTION 

Wear safety spectacles with unperforated sideshields. 


Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. 

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES 

PRODUCT WEIGHT 6.07 lb/gal 727 g/l 

SPECIFIC GRAVITY 0.73 

BOILING POINT

41303 

SECTION 13 — DISPOSAL CONSIDERATIONS 


Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. 

Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. 

Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. 

SECTION 14 — TRANSPORT INFORMATION 

US Ground (DOT) 

May be classed as Consumer Commodity, ORM-D 

UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) 

Canada (TDG) 

May be classed as Consumer Commodity, ORM-D 

UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) 

IMO 

May be shipped as Limited Quantity 

UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D) 

SECTION 15 — REGULATORY INFORMATION 

SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION 

CAS No. CHEMICAL/COMPOUND % by WT % Element 

108-88-3 Toluene 17 

91-20-3 

TSCA CERTIFICATION 

Naphthalene 0.3 

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. 

SECTION 16 — OTHER INFORMATION 

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the 

MSDS contains all of the information required by the CPR. 

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other 

additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no 

warranties, express or implied, and assume no liability in connection with any use of this information. 

page 4 of 4

Hilti (Canada) Corporation 

® 

HILTI ® is a registered trademark of Hilti Corp. 

MSDS No.: 259C 


Revision Date: 08-27-09 

Page: 1 of 2 

Product identifier: 


FS-ONE High Performance Intumescent Firestop Sealant 

Product use: Impedes the passage of fire, smoke and water through fire-rated walls and floors for up to 4 hours. 

Supplier: Hilti (Canada) Corporation, 2360 Meadowpine Blvd., Mississauga, Ontario L5N 6S2 

Originator Hilti, Inc., P. O. Box 21148, Tulsa, Oklahoma, USA 74121 

Emergency number: Chem-Trec: 1 800 424 9300 

INGREDIENTS INFORMATION 

Ingredient CAS Number % (wt.) LC50, (rat) LD50 (rat) TLV STEL 

Polyacrylate dispersion 

Calcium carbonate 

Mixture 

01317-65-3 

30 - 40 

15 - 20 

N/Av 

N/Av 

N/Av 

N/Av 

N/E 

10 mg/m 

N/E 

3 N/E 

Zinc borate 138265-88-0 10 - 15 N/Av N/Av NE N/E 

Ammonium polyphosphate 

Talc 

68333-79-9 

14807-96-6 

05 - 10 

05 - 10 

N/Av 

N/Av 

N/Av 

N/Av 

N/E 

2 mg/m 

N/E 

3 Expandable graphite 12777-87-6 01 - 05 N/Av N/Av 2 mg/m 

N/E 

3 Ethylene glycol 00107-21-1 01 - 05 10,876 mg.kg 4,700 mg/kg 100 mg/m 

N/E 

3 N/E 

Polybutene 

Ferric oxide 

09003-29-6 

01309-37-1 

01 - 05 

01 - 05 

N/Av 

N/Av 

N/Av 

N/Av 

N/E 

5 mg/m 

N/E 

3 Glass filament 65997-17-3 01 - 05 N/Av N/Av 5 mg/m 

N/E 

3 (T) N/E 

Water 

Silicon dioxide 

07732-18-5 

14808-60-7 

01 - 05 

< 0.2 

N/Av 

N/Av 

N/Av 

N/Av 

N/E 

0.1 mg/m 

N/E 

3 N/E 

PHYSICAL PROPERTIES 

Appearance / Physical state: Red paste. Odour: Odourless. 

Specific gravity (at 20ºC): 1.5 VOC Content: 75.0 g/L 

Vapour pressure (at 20ºC): 23 mbar Vapour density: Not applicable. 

Evaporation rate: Not determined. Boiling point: Not determined. 

Freezing point: Not determined. pH: Not determined. 

Coefficient of H20 / oil distrib: Not determined. Solubility in water: Soluble. 

FIRE AND EXPLOSION DATA 

Flash point / Method: Nonflammable. Flammable limits: Not applicable. 

Conditions of flammability: Not applicable. Auto-ignition temperature: Not applicable. 

Means of extinction: As appropriate for surrounding fire (e.g. Water, CO 2, Dry Chemical, Foam). 

Special fire fighting 

procedures: 

Hazardous combustion 

products: 

Sensitivity to mechanical 

impact / static discharge: 

None known. A NIOSH-approved self-contained breathing apparatus (SCBA) should be worn 

when fighting fires involving chemicals. 

Thermal decomposition products such as oxides of carbon and nitrogen can be produced under 

fire conditions. See below. 

Not susceptible to mechanical impact or to a static discharge. 

REACTIVITY DATA 

Stability: Stable. Conditions of reactivity: None known. 

Incompatible materials: Strong acids, peroxides and oxidizing agents. 

Hazardous decomposition 

products: 

None known. Thermal decomposition can yield oxides of carbon and nitrogen.

TOXICOLOGICAL PROPERTIES 

Routes of exposure: Skin contact Skin absorption Eye contact Inhalation Ingestion 

Acute effects of exposure: Eyes: Can cause irritation or watering but injury is unlikely. Skin: Prolonged or repeated 

contact can cause irritation. Inhalation: No effects expected. Ingestion: Not a likely route of 

exposure. Considered to have a low acute oral toxicity. 

Chronic effects of exposure: IARC classifies silica dust as a Group 1 carcinogen based upon studies of workers in industries 

where there has been long-term and chronic exposure to silica dust. This product is a paste 

and does not pose a dust hazard; therefore, this classification is not relevant. 

Synergistic materials: None known. 

FIRST AID MEASURES 

Eyes: Flush with plenty of water. Call a physician if symptoms occur. 

Skin: Wash with soap and water. Seek medical attention if any effects persist. 

Inhalation: No ill effects expected. Should discomfort occur, move to fresh air. 

Ingestion: Do not induce vomiting unless directed by a Physician. Contact a physician immediately. 

Other: Referral to a physician is recommended if there is any question about the seriousness of the 

injury/exposure 

PREVENTATIVE MEASURES 

Engineering controls: General (natural or mechanically induced fresh air movements). 

Eye protection: Safety glasses with side shields are recommended. 

Skin protection: Impermeable gloves reccomended. 

Respiratory protection: None normally required. 

Other: No additional measures are normally required. 

Handling procedures and 

equipment: 

For industrial use only. Keep out of reach of children. Keep container closed when not in use. 

Do not get into the eyes. Avoid prolonged or repeated contact with the skin. Practice good 

hygiene; i.e., wash after using and before eating or smoking. 

Storage requirements: Store in a cool dry area. Keep from freezing. Store between 5º and 25º C. 

Spill, leak or release: Immediately wipe away spilled material before it hardens. Place in a container for proper 

disposal in accordance with all applicable local, state, or federal requirements. 

Waste disposal: Consult with regulatory agencies or your corporate personnel for disposal methods that comply 

with local, provincial, and federal safety, health and environmental regulations. 

Special shipping instructions: Avoid temperature extremes. Keep from freezing. 

WHMIS classification: D2A, D2B 

REGULATORY INFORMATION 

HMIS codes: Health 1, Flammability 0, Reactivity 0, PPE A 

TDG shipping name: Not regulated. 

Prepared by: Hilti, Inc., Tulsa, 

OK USA 

PREPARATION INFORMATION / CONTACTS 

Date of Preparation: 

August 27, 2009 

MSDS 259C, Page 2 of 2 

Emergency phone 

number: 

Customer Service: Hilti (Canada) Corporation, Mississauga, Ontario; 1 800 363 4458 

Health / Safety contacts: Hilti, Inc., Tulsa, OK USA; 1 800 879 6000, Jerry Metcalf (x1003704) 

1 800 424 9300 

Abbreviations used: N/E = None Established. N/A = Not Applicable. N/Av = Not Available. R = as “respirable 

fraction”. IARC: International Agency for Research on Cancer. HMIS: Hazardous Materials 

Identification System 

The information and recommendations contained herein are based upon data believed to be correct; however, no guarantee or 

warranty of any kind expressed or implied is made with respect to the information provided.

form #5100-048-01, rev. date 3/10/06 




Aqua-Gel ® IIP Pourable Wire Pulling Lubricant 







(815) 895-5181 



HAZARDOUS MATERIAL DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS, HAZARD CLASS, HAZARD ID NO. (49 CFR 172.101) 

None 


Polymer-based Mixture 

FORMULA 

Proprietary 






7732-18-5



None normally expected. Upon prolonged contact, may cause temporary eye discomfort. 


PRIMARY ROUTES OF ENTRY Inhalation Skin Contact 

N.E. 

Other (specify) 


SKIN CONTACT: Wash with soap and water. 

EYE CONTACT: 

Flush with water 

INGESTION: 

Do not induce vomiting. Consult physician or local poison control center. 


UNSTABLE CONDITIONS TO AVOID 

STABILITY 

Avoid prolonged storage at temperatures exceeding 190 F. 

STABLE X 



HAZARDOUS 


Avoid strong oxidizers and nitrites. 

In the unlikely event of combustion or dried residue, oxides of carbon and nitrogen may be released. 

MAY OCCUR 


X 




Wipe up, shovel or vacuum spilled material. Clean up spills immediately 

as they can be dangerously slippery. 




N/A 


N/A 


1.2 gms / ltr 


None 



None normally required. 

LOCAL EXHAUST (Specify Rate) None SPECIAL None 

VENTILATION 



OTHER None 





None normally required. Safely glasses or splash goggles recommended. 

Eye fountain in work area is recommended but not necessary. 



Store at temperatures between 40 -180 F. Avoid freezing. 




Extreme temperatures of combustion or burning and contact with nitrites could result in the formation of nitrosamines 

which are potential carcinogens. This condition is unlikely to occur. 



NAME James R. MacMurdo 

SIGNATURE 

TITLE Mgr., Construction Market Development 

DATE 9/21/2010 

Aqua-Gel ® IIP Pourable Wire Pulling Lubricant

Safety data sheet 

MASTERFLOW 928 GRT 

Revision date : 2009/02/18 Page: 1/6 

Version: 1.1 (30367938/MDS_GEN_US/EN) 

1. Substance/preparation and company identification 

Company 

BASF Agricultural Products de Puerto Rico 

State Road No. 2, km. 47.3 

Manati PR 00674 

2. Composition/information on ingredients 

CAS Number Content (W/W) Chemical name 

14808-60-7 30.0 - 60.0 % crystalline silica 

65997-15-1 15.0 - 40.0 % Cement, portland, chemicals 

1309-37-1 3.0 - 7.0 % Iron oxide 

1305-78-8 3.0 - 7.0 % calcium oxide 

7778-18-9 1.0 - 5.0 % Calcium sulphate 

112945-52-5 1.0 - 5.0 % Silica 

1309-48-4 0.5 - 1.5 % magnesium oxide 

1317-65-3 0.5 - 1.5 % Limestone 

3. Hazard identification 


24 Hour Emergency Response Information 

CHEMTREC: 1-800-424-9300 

Outside of the United States, 

call: (001)703-527-3887 

BASF HOTLINE: 1-800-832-HELP 

WARNING: MAY BE HARMFUL IF INHALED. 

CONTAINS MATERIAL WHICH CAN CAUSE CANCER. 

Can cause moderate irritation due to abrasive action. 

In combination with water, repeated or prolonged dermal exposure can cause moderate to severe alkali burns. 

Keep container tightly closed. 

Avoid inhalation of dusts. 

Avoid ingestion. 

Avoid contact with the skin, eyes and clothing. 


Potential health effects 

Primary routes of exposure 

Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for 

gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. 



Irritation:





The product has not been tested. The statement has been derived from the properties of the individual 

components. 

Information on: calcium oxide 

Corrosive! Damages skin and eyes. 

Repeated dose toxicity: 

Information on: crystalline silica 

This product may contain greater than 0.1% crystalline silica. 

Repeated exposure to high concentrations results in silicosis, a lung disease characterized by 

coughing, difficult breathing, wheezing, scarring of the lungs, and repeated, non-specific chest 

illnesses. 

Information on: Iron oxide 

Chronic exposures have been known to produce pneumoconiosis (chronic inflammatory and fibrotic 

lung disease). 

The substance may cause increase in lung mass and lung tissue changes after repeated inhalation. 

The product has not been tested. The statement has been derived from products of a similar structure 

and composition. 

Potential environmental effects 

Aquatic toxicity: 

At the present state of knowledge, no negative ecological effects are expected. 

There is a high probability that the product is not acutely harmful to aquatic organisms. 

The product has not been tested. The statement has been derived from products of a similar structure and 

composition. 

4. First-aid measures 

If inhaled: 

After inhalation of dust. Keep patient calm, remove to fresh air. If difficulties occur: Obtain medical attention. 

If on skin: 

After contact with skin, wash immediately with plenty of water and soap. Under no circumstances should 

organic solvent be used. If irritation develops, seek medical attention. 

If in eyes: 

Flush with copious amounts of water for at least 15 minutes. 

If swallowed: 

Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce vomiting 

unless told to by a poison control center or doctor. 

5. Fire-fighting measures 

Flash point: The substance/product is non-combustible. 

Suitable extinguishing media: 

foam, water spray, dry extinguishing media, carbon dioxide 

Unsuitable extinguishing media for safety reasons: 

water jet 

Hazards during fire-fighting: 

carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black 

Protective equipment for fire-fighting: 

Wear a self-contained breathing apparatus. 

Further information: 

The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing 

water must be disposed of in accordance with official regulations.





6. Accidental release measures 

Personal precautions: 

Avoid dust formation. Avoid contact with skin and eyes. Use personal protective clothing. Handle in 

accordance with good building materials hygiene and safety practice. 

Environmental precautions: 

Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. 

Cleanup: 

Avoid raising dust. 

For small amounts: Pick up with suitable appliance and dispose of. Dispose of absorbed material in 

accordance with regulations. 

For large amounts: Pick up with suitable appliance and dispose of. Dispose of absorbed material in 

accordance with regulations. 

7. Handling and storage 

Handling 

General advice: 

Avoid dust formation. Avoid inhalation of dusts. Avoid skin contact. Pour downwind and allow as little free fall 

as possible while emptying bags into equipment. Breathing must be protected when large quantities are 

decanted without local exhaust ventilation. 

Protection against fire and explosion: 

Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept 

handy. Keep away from sources of ignition - No smoking. Dust can form an explosive mixture with air. 

Storage 

Storage incompatibility: 

General: Segregate from metals. Segregate from acids. Segregate from lyes. Segregate from oxidants. 

Segregate from foods and animal feeds. 

8. Exposure controls and personal protection 

Components with workplace control parameters 

crystalline silica 

OSHA TWA value 2.4 millions of particles per cubic foot of air 

Respirable ; TWA value 0.1 mg/m3 Respirable ; TWA value 

0.3 mg/m3 Total dust ; 

ACGIH TWA value 0.025 mg/m3 Respirable fraction ; 

Cement, portland, chemicals OSHA PEL 5 mg/m3 Respirable fraction ; PEL 15 mg/m3 Total dust ; 

Iron oxide 

ACGIH TWA value 10 mg/m3 ; 

ACGIH TWA value 5 mg/m3 Respirable fraction ; 

calcium oxide 

OSHA PEL 5 mg/m3 ; 

ACGIH TWA value 2 mg/m3 ; 

Calcium sulphate 

OSHA PEL 5 mg/m3 Respirable fraction ; PEL 15 mg/m3 Total dust ; 

ACGIH TWA value 10 mg/m3 Inhalable fraction ; 

magnesium oxide 

OSHA PEL 15 mg/m3 Total particulate ; 

ACGIH TWA value 10 mg/m3 Inhalable fraction ; 

Limestone 

OSHA PEL 5 mg/m3 Respirable fraction ; PEL 15 mg/m3 Total dust ;





Personal protective equipment 

Respiratory protection: 

Wear respiratory protection if ventilation is inadequate. 

Hand protection: 

Chemical resistant protective gloves, Manufacturer's directions for use should be observed because of great 

diversity of types. 

Eye protection: 

Tightly fitting safety goggles (chemical goggles). 

Body protection: 

Body protection must be chosen based on level of activity and exposure. 

General safety and hygiene measures: 

Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts. In order to prevent contamination 

while handling, closed working clothes and working gloves should be used. Handle in accordance with good 

building materials hygiene and safety practice. When using, do not eat, drink or smoke. Hands and/or face 

should be washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned 

and skin-care agents applied. Gloves must be inspected regularly and prior to each use. Replace if necessary 

(e.g. pinhole leaks). 

9. Physical and chemical properties 

Form: powder 

Odour: odourless 

Colour: grey 

Melting point: Unspecified 

Relative density: No data available. 

Viscosity, dynamic: No data available. 

10. Stability and reactivity 

Conditions to avoid: 

Avoid dust formation. 

Substances to avoid: 

strong acids, strong bases, strong oxidizing agents 

Hazardous reactions: 

The product is stable if stored and handled as prescribed/indicated. 

11. Toxicological information 

Chronic toxicity 


Information on: crystalline silica 

The International Agency for Research on Cancer (IARC) has classified this substance as a Group 1 (known) 

human carcinogen. 

----------------------------------





Other information: 

Based on our experience and the information available, no adverse health effects are expected if handled as 

recommended with suitable precautions for designated uses. 

The product has not been tested. The statements on toxicology have been derived from products of a similar 

structure and composition. 

12. Ecological information 

Environmental toxicity 

Other ecotoxicological advice: 

Ecological data are not available. 

13. Disposal considerations 

Waste disposal of substance: 

Dispose of in accordance with national, state and local regulations. 

Recommendations: Use excess product in an alternate beneficial application. 

Container disposal: 

Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after 

being thoroughly cleaned. 

14. Transport information 

Land transport 

USDOT 

Sea transport 

IMDG 

Air transport 

IATA/ICAO 

15. Regulatory information 

Federal Regulations 

Registration status: 

TSCA, US released / listed 

Not classified as a dangerous good under transport regulations 



OSHA hazard category: IARC 1, 2A or 2B carcinogen, NTP listed carcinogen, Chronic target organ 

effects reported, OSHA PEL established, ACGIH TLV established





SARA hazard categories (EPCRA 311/312): Acute, Chronic 

State regulations 

State RTK 

CAS Number Chemical name State RTK 

14808-60-7 crystalline silica MA, NJ, PA 

65997-15-1 Cement, portland, chemicals MA, NJ, PA 

1305-78-8 calcium oxide MA, NJ, PA 

7778-18-9 Calcium sulphate MA, PA 

1309-48-4 magnesium oxide MA, NJ, PA 

1317-65-3 Limestone MA, PA 

CA Prop. 65: 

THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE 

CANCER. 

16. Other information 

HMIS III rating 

Health: 2¤ Flammability: 0 Physical hazard: 1 

HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the substance 

possesses essentially no hazard; a rating of four indicates high hazard. 

Local contact information 

NTU/R NA 

END OF DATA SHEET

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